NCD003446721_19910513_Celeanse Corporation - Shelby Fiber_FRBCERCLA SPD_Final Report Mini-Trial Burn Testing at Mobile Incinerator - Revision 0-OCR

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REPORT NO.:
PROJECT NO.:
DATE:
TYPE:
TITLE:
199-91-69
1212-002
May 13, 1991
FINAL REPORT
MINI-TRIAL BURN TESTING AT
MOBILE INCINERATOR
LOCATED AT THE
HOECHST CELANESE SITE
SHELBY, NORTH CAROLINA
Revision O
AUTHOR: Michael 0. White
Industrial & Environmental Analysts, Inc.
'REPARED FOR: GDC Engineering and
Hoechst Celanese
Shelby, North Carolina
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TABLE OF CONTENTS
SECTION NO. PAGE NO.
1.0 PROJECT DESCRIPTION ................................... l
1.1 OVERVIEW ....................................... l
1.2 PROCESS DESCRIPTION .............................. l
1.3 PROJECT APPROACH ................................ 2
1.3. l Field Effort ................................... 2
1.3.2 Laboratory Analyses .............................. 2
2.0 SUMMARY OF RESULTS .................................. 5
2.1 STACK EMISSIONS .................................. 5
2.2 PROCESS STREAMS ................................. 6
2.3 DATA LIMITATIONS ................................. 7
3.0 SAMPLING PROCEDURES ................................. 13
3.1 PRESAMPLING ACTIVITIES ........................... 13
3.1. l Equipment Calibration ............................ 13
3.1.2 Glassware Preparation ............................ 13
3.1.3 Sample Media Preparation . . . . . . . . . . . . . . . . . . . . . . . . . 14
3.2 PROCESS STREAM SAMPLING ......................... 14
3.3 STACK GAS SAMPLING .............................. 14
3. 3 .1 Sampling Point Determinations -
EPA Method 1 ................................ 14
3.3.2 Flue Gas Velocity and Volumetric
Flow Rate -EPA Method 2 . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.3.3 Flue Gas Composition and Molecular
Weight -EPA Method 3 .......................... 15
3.3.4 Flue Gas Moisture Content -
EPA Method 4 ................................ 15
3.3.5 Particulate Matter & HCl -
EPA Method 5 & 26 ............................. 15
3.3.6 Metals -EPA Multiple Metals Train ................... 15
3.3. 7 Naphthalene -Modified
Method 5 (SW846-0010) .......................... 16
3.3.8 Volatile POHC's and PICs -
EPA Method 0030 .............................. 16
4.0 PROJECT SPECIFIC QUALITY CONTROL MEASURES .............. 17
4.1 FIELD DATA REDUCTION ............................ 17
4.2 LABORATORY ANALYSIS DATA REDUCTION .............. 17
4.3 DATA VALIDATION ................................ 18
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4.4 INTERNAL QUALITY CONTROL CHECKS
AND FREQUENCY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.4.1 Field Sampling QC Checks and
Frequency ................................... 18
4.4.2 Laboratory QC Check ............................ 19
4.5 PROJECT AUDITS .................................. 20
4.5.performance Audits ................................ 20
LIST OF TABLES
TABLE PAGE NO.
• 1.0 PROCESS OPERATIONAL PARAMETERS ........................ 3
2.0 SAMPLING & ANALYTICAL SUMMARY ........................ 4
3.0 SAMPLING PARAMETERS ................................. 8
~ 4.0 FLUE GAS EMISSIONS SUMMARY ............................ 9
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5.0 ANALYTICAL RESULTS FOR PROCESS STREAMS ................ 10
6.0 DESTRUCTION AND REMOVAL EFFICIENCY . . . . . . . . . . . . . . . . . . . 11
• 7.0 VOST RESULTS ........................................ 12
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PROJECT ABSTRACT
IEA was contracted to provide technical support during minibum testing of a rotary kiln
incinerator located at the Hoechst Celanese site in Shelby, North Carolina. A single test run was
completed on April 30, 1991. Testing was observed by EPA personnel and their subcontractor.
Samples of the waste feed, ash, makeup water and flue gas were collected and analyzed for
several parameters of interest: ethylene glycol, chromium, arsenic and antimony. Several other
parameters were investigated on a stream specific basis.
Flue gas samples that were collected demonstrated the pollution control devices easily met
RCRA permit requirements for particulate and HCI. Ethylene glycol was not found in the ash
or the stack gas at detectable levels. The waste feed was spiked with naphthalene to assist in
the demonstration of the incinerator's capability to destroy difficult to incinerate compounds.
Naphthalene was not detected in the waste feed. Naphthalene was detected in the flue gas
sample, however, the associated laboratory blank was reported at such elevated levels that the
quantity reported in the flue gas sample is questionable. When the data is blank corrected, the
unit meets 99.99% DRE requirements .
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1.0 PROJECT DESCRIPTION
1.1 OVERVIEW
Industrial & Environmental Analysts, Inc. (IEA) was contracted through a joint effort between
Hoechst Celanese and GDC Engineering to provide technical support during minibum activities
at the facility located in Shelby, North Carolina .
Testing was completed on the transportable hazardous waste incinerator to demonstrate
compliance with the Resource Conservation and Recovery Act (RCRA) 40 CPR Part 264.343,
Subpart 0, Performance of Hazardous Waste Incinerators. The test program was configured to
demonstrate the unit is capable of treating hazardous waste by incineration within the following
emission limits:
• 99.99 percent destruction and removal efficiency (DRE) for each identified
principal organic hazardous constituent (POHC).
• 99 percent removal efficiency of HCl or 1.8 kg/hr (4 lb/hr) of HCl emission,
whichever is greater, and
• Particulate emissions less than 180 mg/dscm (0.08 gr/dscf) corrected to 7 percent
oxygen (0.05 gr/dscf uncorrected).
• The minibum program was been designed by GDC, Celanese and Westinghouse Environmental
Division to demonstrate the capabilities of the incinerator to effectively destroy difficult-to-
incinerate materials within the performance parameters set forth in the applicable regulations.
IEA was responsible for the collection (or observing the collection) of representative samples
• from all related process streams and the stack locations. IEA was also responsible for the
analysis performed during this program, whether completed by IEA or by one of our
subcontractors.
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1.2 PROCESS DESCRIPTION
The unit tested featured a rotary kiln followed by a secondary combustion chamber. Pollution
control is accomplished by a fabric filter followed by a packed tower wet scrubber system.
Operation conditions for several key parameters are provided in Table 1. Retention time for the
combustion gas was 4 seconds as defined by GDC.
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1.3 PROJECT APPROACH
1.3.1 Field Effort
IEA was contracted to collect a single set of samples during representative operating conditions
at the unit tested. Table 2 summarizes the number and types of samples collected during the
minibum effort .
1.3.2 Laboratory Analyses
The analytical workload was be coordinated through several different laboratories, each of which
are specially prepared and experienced at performing specific types of analyses. IEA, Research
Triangle Laboratories, and Triangle Laboratories, Inc., performed analyses for this program.
IEA has worked with each of these laboratories on previous programs and have developed
steady, reliable relationships with each. We are confident that the data provided by these
laboratories was collected and reported within all appropriate QC requirements associated with
the approved methodologies utilized .
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PROCESS OPERATIONAL PARAMETERS
Operation nme 6-7 7-8 8-9 9-10 10-11 11-12 12-13 13-14 14-15 15-16 16-17 17-18 18-19 19-20
:i:§2 ti~~ lfffil 1:i;a~
Maximum 4.26 3.82 4.22 4.83 8.00 5.91 8.00 5.59 8.00 5.88 8.00 5.59 5.23 8.00
Primary Exhaust i:emp, f
Ag~1~a; n r n rn:&20 ii§?$ h/ii#!F H$'t $ mi§$§ f:$1~ 1/§fi. i!M? J@if JJ$ilf ••• R/§$§ W$!li
Secondary Exhaust Temp, f •Ax~i~g;f••• t• ·•··•rr••••••·•••··•·•?••·•••·•·•rn >5;fstj ••·•b.i'f/:,}i ?Ji?§~ ji/t:W
sec
Maximum
Stack CO, ppm
Stack 02, %
Minimum
Maximum
Stack CO2,%
13-May-91
6.3
7.1
5.33 1.87
7.24 6.84
1.6 1.6
6.2
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TABLE2
SAMPLING & ANAL YT/CAL SUMMARY
Hoechst Celanese MiniBurn Program
Samples for Analysis Total
Analytical Mini QC No. of
Methods Burn MS PE Blanks Analyses
Waste Feed
POHCs
-ethylene glycol GC/FID 1 1 --1 3
-napthalene 8270/BN 1 1 --1 3
Metals 7000 1 1 --1 3
Chloride AOAC 6.187 1 ---- --1
Scrubber Water
Volatiles 8040 1 ----1 2
Metals 6010 1 ----1 2
BNAs 8270 1 -- --1 2
Ash
POHCs
-ethylene glycol GC/FID 1 1 --1 3
-napthalene 8270/BN 1 1 --1 3
Metals 7000 1 1 --1 3
Flue Gas
POHCs
-ethylene glycol M5/GC-FID 1 ----1 2
-napthalene 0010/8270 1 --3 1 5
Particulate MS 1 ----1 2
Chloride EPA M26 1 ----1 2
Metals EPA 1 ----1 2
VOST 5040 3 --3 2 8
Analytical
Laboratory
IEA
IEA
IEA
IEA
IEA
IEA
IEA
IEA
IEA
IEA
IEA
TLI
IEA
IEA
TLI
RTL
Metals of interest include chromium, antimony and arsenic (added during field effort).
POHC for this project is napthalene .
EPA provided all performance samples.
All analyses performed by IEA except the following flue gas samples:
VOST Research Triangle Laboratories, RTP, NC
Napthalene, metals Triangle Laboratory, RTP, NC
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2.0 SUMMARY OF RESULTS
On April 29th and 30th, IEA completed source sampling on the incinerator located at the
Celanese site. Tables 3 through 8 summarize the results of the tests completed by IEA.
The following subsections are brief discussions of the reported results. The final subsection is
a discussion of the data limitations .
2.1 STACK EMISSIONS
Particulate -An extremely low concentration for particulate was reported. After a 2-hour
sample, less than 5 milligrams of particulate was collected. The particulate was visible on the
filter as faint red in color, no substantial buildup on the filter pad. The front half rinse container
a very light residue, again faint red, along the bottom of the beaker. Considering the type of
control devices at this source, the particulate results were well within the expected range. The
blanks were below detection limits (0.1 mg) .
Chloride - A small amount of chloride was detected. The reported quantity was well below
RCRA requirements. The front half and back half components of this sample train were
analyzed separately. o chloride was detected in the back half. The reported data was blank
corrected in accordance with the method. Even uncorrected, the chloride emissions were e negligible.
Ethylene glycol -This compound was not present in the stack sample at detectable levels. IEA
reported a fairly high detection limit due to the large volume of water collected during the stack
sampling effort. It is suspected that in this case, that collection of a large gas volume actually
• increases detection limits rather than improving them. The analytical method reports results on
a ug/mL basis, therefore, the greater the number of mL, the higher the value reported for total
ug collected considering the following equation:
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ug detected/ mL analyzed x mL collected = ug
Metals -The metals results were also very low, again attributed somewhat to the exceptional
particulate control device. Chromium was present in the gaseous and solid form (front and
back half). Antimony was detected as a solid and arsenic was detected as a gas. Blanks and
surrogate recoveries were all within acceptable ranges as defined in the method.
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Naphthalene -The modified Method 5 results presented for naphthalene requires further
clarification. The results appear such that the incinerator was emitting measurable amounts of
the naphthalene. However, further review of available information shows the laboratory blank
was nearly as high as the reported amount for the flue gas sample (lab blank 523 ug, sample 637
ug). Discussions with Triangle Laboratories QA personnel reveal that such data is typically
clarified by stating the reported sample amounts should be considered highly questionable and
are likely to be below quantitation limits unless the reported value is at least 5 times the reported
blank value ( or in this case 5 x 523) .
Volatile Organics -The VOST results presented show some presence of chlorinated compounds.
(The waste feed sample also reported low quantities of chloride.) The recoveries for the samples
were outside of the acceptance limits for one of the three surrogate compounds. The
interference of several tentatively identified compounds (siloxanes) are suspected as the cause
for the low recovery. The VOST audit results did not have the same problem. There were no
significant contributions in the field bias blank. The trip blank was clean .
2.2 PROCESS STREAMS \
Chloride - A single sample for chloride was analyzed and found to contain 12 ppm. This result
is only 2 ppm over the reported detection limit.
Ethylene Glycol -The waste feed sample contained 3,200 ppm ethylene glycol. The matrix
spike had a 47% recovery. This recovery is considered typical for samples previously analyzed
by IEA from this site. Ethylene glycol, the major organic contaminant at this site, was not
detected in the ash sample. The matrix spike for this sample was reported at 61 % . This
further demonstrates that the incinerator is effectively destroying hazardous compounds within
the waste feed stream .
Metals -Of the three metals investigated, antimony was found to in the greatest concentration
in both the waste feed and the ash.
Matrix spike recoveries for both samples were within acceptable ranges. The makeup water did
not contain any detectable levels of the metals of interest.
Naphthalene -This compound was not detected in the ash or the waste feed.
Volatiles and BNAs -Only the makeup water was analyzed for these compounds. No detectable
levels of any compounds of interest were reported.
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2.3 DATA LIMITATIONS
The most significant data point to be discussed pertains to the reported presence of naphthalene
in the flue gas sample. The amount reported when compared to the amount in the laboratory
blank did not contain a significant difference. It is suspected that the XAD-2 resin used for the
sampling and the appropriate blanks contained elevated levels of naphthalene.
The XAD resin used for this project was provided to IEA by Triangle laboratories, Inc. (fLI) .
In accordance with IEA's standard operating procedure for modified Method 5 sampling, the
XAD resin traps were sent to TLI to be cleaned and loaded with XAD. The traps prepared by
TLI are packed with 40 grams ofprecleaned XAD resin purchased from Supelco, the only U.S.
manufacturer of XAD resin. The traps are also spiked with surrogate compounds prior to being
taken into the field. In addition, TLI maintains a stock of resin, from the same Lot Number
provided by Supelco, to use for the laboratory blank that will analyzed in conjunction with the
field samples. The XAD from the sample, field blank and the lab blank were all from the same
lot number. Supelco has been contacted to obtain any existing QC information relevant to this
lot of XAD. Preliminary conversations with Supelco reveal that Supelco acknowledges the
receipt of a questionable batch of XAD from their commercial supplier, Rohm and Haas .
As stated by IEA at the beginning of the field sampling effort, naphthalene is a common
laboratory contaminant. Naphthalene is often found in XAD resin and the solvents used in
precleaning the resin as well. IEA had expressed concern over the use of naphthalene primarily
for these reasons. Considering the spiking levels and gas flow rates, IEA could have reported
a concentration of naphthalene of 120 ug and still met the 99.99% requirements. This margin
• was within contamination range historically encountered by TLI.
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IEA recommends that the reported naphthalene values be recognized as non-detected and the
minibum results be accepted as passing 99.99% DRE requirements .
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TABLE3
SAMPLING PARAMETERS
Run No.
Date
Start Time
Stop Time
Nozzle Diameter, in.
Barometric Pressure, in. Hg
H~! §~m/:>ildii:tlrn1l)H:Hil!l\1lli ?
Volume Metered, cf
Avg. DGM Temp, F
AVG Delta H, in of H20
AVG Delta H, in of Hg
DG M Calibration Factor
Y§illmil2I@~\1Q2\lils1~m~§?it w
Total Water Collected, ml
Volume of Water Vapor, sci
Mm~mr~t~&Rifl~~~Gril/:iit
Moisture, % (at saturation)
Dry Mole Fraction, 100-0/oM
CO2 at Stack, % dry
02 at Stack, % dry
CO+ N2, % dry
Dry Molecular Weight, lb/lb mole
Wet Molecular Weight, lb/lb mole
Excess Air at Stack, %
Stack Area, sq.in. (for 42 in.ID)
Static Pressure, in. of H20
Stack Pressure, in. of Hg
Avg. Stack Temp., F
Avg. Sqroot of Delta P
SDE Average
Pilot Coefficient
§!~s~@~~Y~I2sllxi~lllm >
Stack Flowrn,te .
M5/HCL Metals
30-Apr 30-Apr
7:53 7:53
10:39 10:39
0.376 0.376
30.02 30.02
95.701 95.391
78.9 75.9
2.17 2.12
0.1599 0.1556
0.9990 0.9990
41.6 42.5
0.6225 0.5833
6.2 6.2
12.5 12.5
81.3 81.3
29.49 29.49
25.15 24.70
139.5 139.5
1385.4 1385.4
-0.10 -0.10
30.01 30.01
171.4 172.2
0.5033 0.4993
12.647 12.556
0.84 0.84
MM5
30-Apr
12:31
18:39
0.376
30.02
187.948
86.4
2.11
0.1550
0.9990
Eth Glycol
30-Apr
12:31
18:39
0.376
30.02
184.736
93.0
2.06
0.1516
0.9990
1~?I$zij 1 : 1zzil!z1 ;;i
2815.1 2674.5
43.5 43.5
0.5796 0.5849
6.0 6.0
12.8 12.8
81.2 81.2
29.47 29.47
24.65 24.71
148.2 148.2
1385.4 1385.4
-0.10 -0.10
30.01 30.01
173.0 172.8
0.4974 0.4893
12.515 12.310
0.84 0.84
Flowrates calculated based on measured flue gas moisture content.
Rewsed 09-May-91
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TABLE4
I FLUE GAS EMISSIONS SUMMARY
Ethylene
Parameter Particulate Chromium Naphthalene Glycol
Front Half Rinse, mg 3.5 Blank
• Particulate Filter, mg 0.1 Corrected
Front Half Total, mg 3.6 0.010 ND@3
Back Half, mg NA 0.332 NA ND@28
Total Collected, mg 3.600 0.332 0.114 31.0
Grain Loading, gr/dscf 0.00059 0.00005 0.00001 0.00269
Grain Loading, gr/act 0.00031 0.00003 0.00000 0.00132
• Grain Loading, gr/dscf @) 7% 02 0.00097 0.00009 0.00002 0.00459
Emission Rate, lb/Hr 0.05012 0.00432 0.00076 0.21128
Emission Rate, g/sec 0.00576
Chloride Antimony
Front Half Rinse, mg
• Particulate Filter, mg
Front Half Total, mg 0.023 0.757
Back Half, mg ND@.072 ND@0.46
Total Collected, mg 0.02 0.757
Grain Loading, gr/dscf 0.00000 0.00012
Grain Loading, gr/act 0.00000 0.00006
Grain Loading, gr/dscf @ 7% 02 0.00001 0.00020 • Emission Rate, lb/Hr 0.00032 0.00986
Arsenic
Front Half Rinse, mg
Particulate Filter, mg
Front Half Total, mg ND @0.86 • Back Half, mg 1.070
Total Collected, mg 1 . 1
Grain Loading, gr/dscf 0.00017
Grain Loading, gr/act 0.00009
Grain Loading, gr/dscf @ 7% 02 0.00012
Emission Rate, lb/Hr 0.01393 • Flowrates calculated based on measured flue gas moisture content.
Practical Quantitation Limits: Particulate 0.1 mg
Chromium 0.02 ug
Antimony 0.25 ug
Arsenic 0.25 ug
I Naphthalene 2.0 ug
Chloride 10 ug/L
Ethylene Glycol 31 mg
Revised 13-May-91
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TABLE5
I ANAL YT/CAL RESULTS FOR PROCESS STREAMS
Method Matrix Spike Detection
Run2 Blank Spiked Detected Recovery Limits
Waste Feed
• Naphthalene, mg/kg ND ND ------0.25
Ethylene Glycol, mg/kg 2,800 ND 1900 3200 47% 10
"' Chromium, mg/kg 20 ND 40 54 85% 6.0
Antimony, mg/kg 890 ND 100 1100 2100/o 4.0
Arsenic, mg/kg 1.8 ND 8.2 6.2 54% 1.0 • Chloride, mg/kg 12 ND -- ----
Ash
Naphthalene, mg/kg ND ND ------0.39
• Ethylene Glycol, mg/kg ND ND 36 22 610/o 10
Chromium, mg/kg 28 ND 40 62 85% 6.0
Antimony, mg/kg 220 ND 100 320 100% 4.0
Arsenic, mg/kg 2.2 ND 8.4 8.4 74% 1.0
• Makeup Water
Chromium, mg/L <0.03 ND ------0.03
Antimony, mg/L <0.2 ND -- -- --0.2
Arsenic, mg/L < 0.005 ND ---- --0.005
Volatiles, ug/L • Methylene Chloride 8 ND ------5
BNAs ND ND ------
• ND -Not detected .
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DESTRUCTION AND REMOVAL EFFICIENCY
Naphthalene Naphthalene
Reported Corrected
• Waste Feed
Concentration, mg/kg Spiked Spiked
Waste Feed Rate, lb/hr 5,500 5,500
POHC Feed Rate, lb/hr 8.0 8.0 • POHC Feed Rate, g/sec 1.0080 1.0080
Stack Gas
• Amount Detected, ug 617 114
Volume Gas Sampled, dscf 182.979 182.979
Stack Gas Flowrate, dscfm 9,252 9,252
POHC Emission Rate, g/sec 0.00052 0.00010 • DRE,% 99.948 99.990
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TABLE?
VOST RESULTS
Run ID 2A 28 2C
Sam{J_/ing_ Parameters
Start Time 12:50 13:50 17:20
Stop Time 13:30 14:29 18:00
Volume Sampled, L 19.750 19.000 18.960
Meter Temp, C 25.7 29.9 32.0
Barometric, in.Hg 30.02 30.02 30.12
Volume Sampled, DSL 19.437 18.442 18.337
Gas Flowrate, DSCFM 9,213 9,213 9,213
Detected Amounts, ng_
Chloromethane 350 a,b 870 a,b 340 b
Vinyl chloride 140 b 190 b 160 b
Chloroethane 110 b 160 b 75 b
Trichlorofluoromethane 40 b BQL 26 b
Acetone 7,400 b,c 8,900 b,c 3,100 b,c
Carbon disulfide 260 b 1,100 b,c 340 b
Methylene chloride 190 b 120 b 210 b
2-Butanone 700 b 1,000 b 140 b
Chloroform 140 b 140 b 110 b
Carbon tetrachloride 92 b 86 b 82 b
Benzene >2,400 a,c >3,000 b,c >2,300 a,c
2-Chloroethyl Vinyl Ether 25 32 BQL
Toluene 120 170 110
2-Hexanone 170 300 88
Tetrachloroethene 36 BQL BQL
Ethylbenzene 30 37 21
Xylenes (total) 60 68 40
Styrene 600 640 530
Surrogate Recovery, %
1 ,2-Dichloroethane-d4 18 a 22 a 26 a
Toluene-dB 99 96 90
4-Bromofluorobenzene 82 82 87
a -Data dropout observed due to excessive amounts of sample compounds.
b -Internal standard recovery affected due to sample peak co-elution.
Results considered quantitative estimate.
c -Point exceeded 1 000 ng calibration range.
BQL -Below Quantitation Limit
Field
Blank
--
--
--
--
--
--
--
BDQ
25
BDQ
BDQ
370
1100
44
BDQ
BDQ
BDQ
BDQ
BDQ
.BDQ
BDQ
BDQ
BDQ
BDQ
BDQ
80
99
78
13-May-91
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3.0 SAMPLING PROCEDURES
Table 2 summarizes the sampling and analysis effort completed for this project. The following
subsections provide descriptions and/or refer to applicable methodologies to be employed for this
project. Any deviations from the specified methodologies are outlined in this Report.
3.1 PRESAMPLING ACTIVITIES
Presampling activities include equipment calibration, sample media preparation, precleaning of
sample train glassware, and other miscellaneous tasks. Each of these activities are described or
referenced in the following subsections. Other presampling activities include such details as
team meetings, equipment packing and shipment, travel, equipment setup, mobile laboratory
setup, and the finalization of all details leading up to the coordinated initiation of the sampling
program.
3.1.1 Equipment Calibration
Undoubtedly the most important aspect of presampling preparation, the inspection and calibration
of the equipment, is a crucial step in assuring the successful completion of the field effort.
Equipment is inspected for proper operation and durability prior to calibration. Calibration of
the equipment is conducted in accordance to the procedures outlined in the EPA document
entitled Quality Assurance Handbook for Air Pollution Measurement Systems; Volume III -
Stationary Source Specific Methods" (EPA-600/4-77-027b). All calibrations were performed
prior to the field sampling effort.
3.1.2 Glassware Preparation
Sample train glassware and sample containers were precleaning to avoid contamination of the
sample from the collection container or devices. Cleaning procedures for the sample train
glassware are summarized below. Sample containers were purchased precleaned to specified
EPA protocols.
• VOST glassware and containers (organics) -soap and water wash, DI rinse, oven
dry at 150 C for 2 hours. Sorbent tubes are prepared in accordance to SW846,
Method 0030.
• Method 5 glassware (particulate/RC!) -soap and water wash, DI rinse, acetone
rinse, air dry.
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• Method 5 glassware (metals) -soap and water wash, 15 % nitric acid rinse, DI
water rinse, air dry.
• Modified Method 5 glassware (naphthalene) -soap and water wash, DI rinse,
acetone rinse, methylene chloride rinse, methanol rinse and air dry.
3.1.3 Sample Media Preparation
All sample reagents were checked in accordance to IEA' s existing quality control program to
minimize the probability of using contaminated solvents. This includes the use of spectro-grade
solvents from the same lot and the collection and analysis of appropriate blanks. All filters for
the particulate trains will be desiccated and weighed to the nearest 0.5 mg .
VOST tubes were conditioned and QC'd in accordance to procedures called out in SW-846,
Third Edition, Method 0030. XAD resin was prepared and QC'd in accordance to the
procedures outlined in SW846 Method 0010.
3.2 PROCESS STREAM SAMPLING
Samples from the process streams (all non-flue gas sampling streams) were collected by plant
personnel. The collection technique of these samples was discussed with IEA personnel to
assure representative sampling and adequate volume .
3.3 STACK GAS SAMPLING
The following subsections describe the types of equipment and techniques used by IEA for
• collection of stack gas samples. Specific procedures to be followed are contained in the EPA
Method procedure given in 40 CFR 60 Appendix A, EPA-SW-846, or Methods Manual for
Compliance With the BIF Regulations, EPA/530-SW-91-010.
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3.3.1 Sampling Point Determination -EPA Method 1
The number and location of sampling or traverse points were determined in strict compliance
with the procedures outlined in EPA Method 1.
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3.3.2 Flue Gas Velocity and Volumetric Flow Rate -EPA Method 2
Velocity measurements were made using type-S pilot tubes conforming to the geometric
specifications outlined in EPA Method 2 and with inclined oil manometers. Each pitot tube has
been assigned a calibration coefficient of 0. 84. Stack gas temperatures were measured with
Type K thermocouples equipped with digital readouts.
3.3.3 Flue Gas Composition and Molecular Weight -EPA Method 3
Multi-point, integrated sampling were used to obtain a constant rate sample of flue gas
concurrent with each traversing type emission test. A stainless steel probe affixed to the
traversing sample probe ran to a diaphragm pump to deliver gas to a Tedlar bag for subsequent
Orsat analysis .
3.3.4 Flue Gas Moisture Content -EPA Method 4
• Flue gas moisture was determined in conjunction with each traversing, isokinetic sampling
method.
•
3.3.S Particulate Matter and HCI -EPA Method S and 26
An EPA Method 5 combined with EPA Method 0050 (isokinetic version) sampling train was
used to simultaneously collect particulate
matter and HCI/Cl2• Each test run was two hours in sampling time duration and will collected
a minimum of 60 dry standard cubic feet (dscf) of flue gas. Glass nozzles and quartz fiber
filters were used. All isokinetic sampling trains are Nutech Model 2010 designs: Modification
• to this method included an additional front half DI water rinse for chloride analysis.
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3.3.6 Metals -EPA Multiple Metals Train
The sample and analytical procedures outlined in the EPA Draft Method of the BIF Methods
Manual was used to collect and determine the metals of interest for this test program (Sb, As,
Cr). The sample run was two hours sampling time duration and collected more than 60 dscf.
Glass nozzles and quartz fiber filters were used. IEA used a Nutech Model 205 glassware set
contained in the Nutech 2010 sampling system.
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3.3.7 Naphthalene -Modified Method 5 (SW846-0010)
The sampling and analytical procedures outlined in Method 0010 of the SW846 was followed
to collect and determine concentrations of naphthalene. A sample aliquot of the extracted and
concentrated sample after preparation will also be submitted for GC/MS analysis using Method
8270. Glass fiber filters, precleaned XAD-2 sorbent resin, and a glass nozzle were used.
Sample train recovery featured a 50:50 mix of methylene chloride and methanol.
3.3.8 Volatile POHCs and PICs -EPA Method 0030
A Volatile Organic Sampling Train (VOST) equipped with pre-cleaned Tenax and
Tenax/charcoal sorbent cartridges was used collect flue gas samples for analysis of volatile
organics, according the procedures outlined in EPA Method 0030 of EPA-SW-846. IEA uses
a Nutech Model 280 VOST sampling system. A total of four pairs were collected at a rate of
0.5 liters per minute. Sample time was 40 minutes per pair to yield a 20 liter sample .
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4.0 PROJECT SPECIFIC QUALITY CONTROL MEASURES
Specific QC measures were .used to endure the generation of reliable data from sampling and
analysis activities. Proper collection and organization of accurate information followed by clear
and concise reporting of the data is a primary goal in all projects.
4.1 FIELD DATA REDUCTION
Appendix A of this Plan presents the standardized forms that were used to record field sampling
data. The data collected was reviewed in the field by the Field Team Leader and at least one
other field crew member. Errors or discrepancies were noted on the data sheet and in the
Project Summary Log Sheet. Appendix A also provides the calculation worksheets used in the
field to check on isokinetic sampling conditions and a listing of formulas to be used to reduce
the field data.
4.2 LABORATORY ANALYSIS DATA REDUCTION
Analytical results was reduced to concentration units specified by the analytical procedure, using
the equations given in the analytical procedures. If units are not specified, data from the
analysis of liquid samples were reported in units of ug/L. Data from the analysis of gas samples
will be reported as ug/m3• This will be calculated by dividing the total weight of the substance
• detected by the volume of gas sampled.
The concentration of compounds identified in a sample will be calculated using the internal
standard method. The internal standards are similar in analytical behavior to compounds of
interest. The calculated concentration is based upon the chromatographic peak ares and response
• factors obtained from the calibration standards according to the following equation:
•
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where: = Concentration of the specific internal standard.
Cx = Concentration of the compound being measured.
The data generated will include the following information:
• •
Compound; and
Concentration
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4.3 DATA VALIDATION
Data validation is the process of filtering data and accepting or rejecting it on the basis of sound
criteria. IEA supervisory and QC personnel use validation methods and criteria appropriate to
the type of data and the purpose of the measurement. Records of all data will be maintained,
even that judged to be an "outlying" or spurious value. The persons validating the data has
sufficient knowledge of the technical work to identify questionable values .
Field sampling data has been validated by the Field Team Leader and/or the Field QC
Coordinator based on their judgment of the representiveness of the sample, maintenance .and
cleanliness of sampling equipment and the adherence to an approved, written sample collection
procedure .
Analytical data was validated by the subcontractor laboratory QC or supervisory personnel using
criteria outlined in the Laboratory QA Manual. IEA uses results from field and laboratory
method blanks, replicate samples and internal QC samples to further validate analytical results.
Analytical results on field blanks and replicate field samples are valuable for validation of
sample collection also. IEA QC personnel will review all subcontractor laboratory raw
analytical data to verify calculated results presented .
The following criteria will be used to evaluate the field sampling data:
• • • •
Use of approved test procedures
Proper operation of process being tested
Use of properly operating and calibrated equipment
Leak checks conducted before and after tests
e 4.4 INTERNAL QUALITY CONTROL CHECKS AND FREQUENCY
Quality control checks were performed to ensure the collection of representative samples and the
generation of valid analytical results on these samples. These checks will be performed by
project participants through the program under the guidance of the QA Director and Field and
• Laboratory QC Coordinators.
4.4.1 Field Sampling QC Checks and Frequency
I IEA 's checks for the process data collection and sampling aspects of this program included the
following:
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1. Use of standardized checklists and field notebooks to ensure accuracy and
completeness, traceability, and comparability of the process information and
samples collected.
2. Field checking ofstandardized forms by a second person to ensure accuracy and
completeness.
3. Strict adherence to the sample traceability procedures
4. Submission of field biased blanks .
5. Leak checks of sample trains before and after sample collection.
Calibration of the field sampling equipment was performed prior to the field sampling effort.
Copies of the calibration sheets are provided in the Appendices .
Leak checks of the sample trains were conducted in accordance with the protocol called out for
each method. Leak checks were conducted prior to and at the end of sample collection .
Field-biased blanks ofreagents and collection media (deionized water, filters, impinger solutions,
VOST tubes, etc.) were placed in appropriately cleaned and sized sample containers in the field
and handled in the same ways as actual field samples, to provide a QC check on sample
handling .
For the Miniburn program, sample collection QC checks and frequency for samples to be
analyzed in the laboratory are listed below:
• • • • •
One field bias blank VOST train and one trip blank .
One blank M5/Particulate-HC1 train .
One blank metals train sample .
One blank ethylene glycol train sample
Three pairs of VOST tubes collected from an audit cylinder.
Method blanks were also be provided with the various sample sets. These blanks are portions
of analytical reagents, filters, sorbent media and recovery reagents set aside and not transported
to the field. Method blanks will be obtained for each reagent and sampling media lot.
4.4.2 Laboratory QC Check
IEA's Quality Control program for laboratory analysis makes use of a number of different types
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of QC samples to document the validity of the generated data. The following types of QC
samples were used during the program.
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Method Blanks -Method blanks contain all the reagents used in the preparation
and analysis of samples and are processed through the entire analytical scheme
to assess spurious contamination arising from reagents, glassware, arl are:
materials used in the analysis.
Calibration Check Samples -One of the working calibration standards which is
periodically used to check that the original calibration is still valid .
Laboratory Control Samples (LCS) -These samples are generated from spikes
prepared independently form the calibration concentrates. The LCS are used to
establish that an instrument or procedure is in control. An LCS is
normally carried through the entire samples preparation and analysis procedure
also.
Surrogate Spikes -Samples requiring analysis by GC/MS are routinely surrogate-
spiked with a series of deuterated analogues of the components of interest. It is
anticipated that these compounds would assess the behavior of actual components
in individual program samples during the entire preparative and analysis scheme .
4.5 PROJECT AUDITS
IEA's Quality Assurance Program includes both performance and system audits as independent
checks on the quality of data obtained form sampling, analysis, and data gathering activities.
Every effort is made to have the audit assess the measurement process in normal operation.
Either type of audit may show the need for corrective action.
4.5.1 Performance Audits
The sampling, analysis, and data handling segments of a project are checked in performance
audits. IEA participated in several audits to assess the precision and accuracy of the sampling
and analysis effort .
IEA completed a performance audit of the meter boxes used for the flue gas sampling. IEA did
not receive copies of the data sheets for the meter box audit, however, IEA was notified that
both boxes were within 2 % agreement with the audit device.
IEA completed a VOST audit during the field sampling effort. Results are summarized in Table
8. IEA also submitted three audit XAD traps for analyses. TLI reported that none of the audit
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samples contained detectable amounts of any semivolatile compounds. All of the surrogate
recoveries and internal standards associated with the semivolatile analyses met the requirement
s specified in SW846 8270. IEA and TLI suspects the XAD traps were not spiked. The
Appendices of this report contains all necessary information to evaluate the reported data.
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TABLEB
AUDIT RESULTS
Run ID Audit b Audit c
VOLATILE ORGANICS
Samo.ling_ Parameters
Start Time 17:10 17:40
Stop Time 17:30 18:00
Volume Sampled, L 9.800 9.850
Meter Temp, C 25.0 24.0
Barometric, in.Hg 30.20 30.20
Volume Sampled, DSL 9.726 9.808
Detected Amounts, ng
Vinyl chloride 220 170
Carbon disulfide 25 130
Methylene chloride 75 52
Chloroform 1600 a 1700 a
Carbon tetrachloride 780 820
Benzene 1000 1000
Tetrachloroethene 820 850
Surrogate R!!covery, %
1 ,2-Dichloroethane-d4 76 75
Toluene-dB 95 93
4-Bromofluorobenzene 73 73
;;; :; Pi>'iM JQ2JJ&J& 1ooohg 2m1B~;;;{ig;;;~;;gJ. f)it:i::r:::::::::::::•:::::.:.:_: :>:·:-:-:-·--····
SEMIVOLATILE ORGANIC! Audit a Audit b
XAD47 XAD74
No compounds detected
Quantitation limits:
Phenolic Compounds 50 micrograms
All Others 10 micrograms
Surrogate Recovery, %
Terphenyl-d14 0 0
Phenol-d5 51 50
2,4,6-Tribromophenol 77 87
1,4-Dibromobenzene-d4 42 33
Pyrene-d10 89 88
Audit d
18:15
18:35
9.850
23.0
30.20
9.842
190
56
49
1600 a
830
1000
900
74
95
79
Audit c
XAD67
0
49
78
53
84
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Plant \jo:f.,c,>,.~ C,e., .. ,f'l..i..E.-·,::/~--Sample Date A.\"Do~\
Sample Location .:S::~c..,~~-eA\bR.. Recovery Date ~
Run No. f-116€(:,-2. Recovered by ~
Filter Number(s) -~..::..--_7u ______________________ _
MOISTURE
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Final Volume (wt) Bt;<:,~.bff,l.~ r/<,..'6 4s",µ ml (g) Final wt
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RECOVERED SAMPLE
FIiter container number(s)
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Sealed
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173 "l,.._<,:;(j 1i, 1.<
/77 7 C:::7 0-) 1'(,~
I 7 3 Z....'(7 5b IL/,,:-'
17~ z.s;-/ n--l'i, >
( 7 z_ 'Z.£'D.· ri /7,,S-
I 71 ~ n 7v
/71) l77 l.. 5 I ct I~
.
• • • • • --
EMISSIONTESTINGFIELDDATA PG,,e-3 °+-3 ;1mmm:@illt!ANJ)$NP\¢tl¥i\%i#Mi@N& MPAtS.1 HM!i:/$.AMBitN~CP,Q'AJitP.N.MM tfa$AMR(il;)t£$1¥H iMR.UNNQM~i@Ff@MiHi• l-teecks+-Ce.Lo~e.;~ '-(/J,(7{ .J_<A..LL',,,._~,.c,.,/--..r S-<,,...c....L ,v._J->,.._~ /' 7 ·
I 7 $ , I 7 3, '-/ 7 IS:, {, <{' C , 1-< -z_, l J / 7 ~ 2-'t 7 -Z.'{~ 65 C I ?""7 ( ?'":ti
<!l. LI. G.• <... I 7 3 -z.. s-6 2...;.,.. (, 6 '-(_ ? n 6,'2.7 'L.., J I? 3. 'L.~3 2.'ts' t-t 4-<r 77 O,"c..t° . C.' l( { 7 3 Z..:S""o c..'-<{ ':5' <f 6 n
C.2..Y 2,</ i7"3 'Z.~ Z36 (, 6 4-<" 11"?
0, z.. g--C.., Cf 17 :, z.~6 ~? 6C 4 (f 'l"7 2c,."' . ;J, 2. 7 2.., 3 1 72 C..'t y 2.y_r (I, I.I~ ~ ?S-6, 7-v {),?_,( 2.,? /7 "">, 2-s-S-vtJ t,J '{~ 'e? ('.)' Z-6 z.' z.... I 7 3 L.S"</ 2.9-; lt ff..> %Y-0, Z.6. -z.' -z.. 17~ z..s---o 23s ,( 's . 'f ~ '{ 7 Zo
I
I
•
•
•
•
•
•
,
~b..\-
~<'G
~~
'
rn
PARTICULATE SAMPLE RECOVERY
AND INTEGRITY DATA SHEET
Plant \-\ o'2.C ',\'S\ ¼->,-..r-, v,l.'<'c...'.;;;)E
Sample Location ~,...,.c..,.-.i.E.-2.A,cR
Run No. M N\,S. -Z. -----='----------
Sample Date
Recovery Date
Recovered by
Filter Number(s) __ w=-i...:....J~--------------------
MOISTURE
lmpinqers
Final Volume (wt) st; c;,z. ~ ml (g)
Net Volume (wt) ____ _,.,,1 _L1_IO_, _if ____ ml (g)
Silica Gel
Final wt
Initial wt
Net wt
74S.-:s. 9
~-'$0.cg
r.s. g Description of impinger water _______ _ _ _____ % spent
______ Sil gel color
Total moisture= ________ g
RECOVERED SAMPLE
Filter container number(s)
Description of particulate on filter
Probe rinse
container no.
blank ------container no.
impinger contents
container no.
------container no.
blank
Samples stored and locked
Remarks
Sealed
Liquid level
marked/sealed
Liquid level
marked/sealed
Liquid level
marked/sealed
Liquid level
marked/sealed
-----
-----
-----
-----
-----
LABORATORY CUSTODY
Received by
Remarks
')<.A~-2. (,'\
2,Si:,,'2.
~te,.2..
<o,o
')(_ ~ -b--z (.-z"
:.5"6 .. 0
~
~,'D
Date -----
eic:,m£ \ {b.::,~Lf°:2_
\ \ 7 0 ,2... \ 001.0
' ~q<.,,.o ~°'11. 0
17'-i. -Z... l i O .J
• • • • • • -.. EMISSION TESTING FIELD DATA
;; 2:••··· : R~TANP:Ottx:;·; : i PAtSi ,< $AMB4iNG:J:iQQ'.A.1lP.N;~;;; 1$AMR4S•xxeg••·············· T BO.N:iNQM$..t;R••·············•<•••·:•························· /to~ck~+-C.J~--" li.//3o/~1 :r~'-':..,.,-... :h.-'St-......j<--M ~-L.1 ~ · l ' I -1,vte..+.../J
\lLll-:30 .oz.. -o. I 7 ~ <.( c..... ei, 'l"( S--Ft-c..1~ .. , c;.1~.,,· ;,,-.., 1 :.
'-1-z.,. Lr l,')3, o.;'}J ->T2._ S°'?? S-'TZ. 15°' o,ol Lt< o.ooS-?,Ye..-
13.-1 0. 07.s".3 t/"%3.'514' o.z.i-z,3, /7o zs, ?-s-f ·'-15 ,(L '::.i.< ;;::--4n, lo O,Z-7 ?.'27 171 2S-7 "2.S-2'... J5 6r 3.0 (3 .. 7..
/3-3
"' ,D f3 -6
• --• • • • •
EMISSION TESTING FIELD DATA /> ~ ~., F L .:< -'< ;: ,:.:JtUAN:t:t't.No;:pf-tY.C .. ,:.>.,:::,:,:r:c: .:JPAt1;: ·::/.:$AM.e.1:,JN~J¥.Qq.41:1oft::,.: :•II$AMi14SJ1Xes::L< ::Jf.3.Qt:fNUM:e.e8?2f{LX:;;;·_·_._ l-+o~c1\s~ C.e, «-.S,. 1//3-.,)-,, :r.'G< .. •.-~.-C...i--.,.clc.... M .... ·-\.-h-I ·t -,f'v:..11.-fo-_/:;. ·
B-6A,f t.. D orr_c,_/21 ~3-Z, 3oi./ 6,2..~ Z, I ( 7Z-. z.sr . '2--ry CD 7::.----9.7'1
.
I,< S36, /?...... 0."2-l( z_.,e; 17 <-z<('J 2..-Y') ~r 77 &f,-o
7;::'
7. <..... 1-73 A -3-m
?.... I /7?__ <rs
0 IC 6 \.., I., 17 2 ~ -l{ q-u
1,4 17 2.. "I ,S
? { q 17Z IA--s-' /0 0 o. Z. 7 c,'I:. 17 3 ZS3 47 s.v / 10 ',. 0, z. 7 <., ~ 17 2.. I+--/, // 7)
() '?..., </ -Z,<l I 7 Z:. 47 .,.-/I) t). Z I \. .r-17 .. , 76 11..u .
I
I
•
•
•
•
•
,
'
PARTICULATE SAMPLE RECOVERY
AND INTEGRITY DATA SHEET
Plant \-\o~',\~ ~Lv\~tS~
Sample Location ~c.1 '-l.~~e.. Run No. --,(--'N\=e;'-=,-R>"--=L''"";""";0=-'--'-{n-'--_"'1 L-"·=-2..---
Sample Date
Recovery Date
Recovered by
Filter Number(s) l-l -r-,... __ ..._~--------------------
lmoinqers
MOISTURE
~
Final Volume (wt) &:0."2 B~1 .Z e<-,"'l.t:> ~-G:,.e, ml (g)
Initial Volume (wtl41~D ';514-.\ S1oi. to +'S'l.~ ml (g)
Net Volume (wt) 1 4 11 , ml (g)
Silica Gel
Final wt <',,,~.'c:i g
lnitlalwt 62) . .?, gCo2.::5,,fo~
Net wt -z,3, Z--g Description of lmpinger water ___.0~.\'-"6::>-c==S: ____ _ C:V %spent -~.......=c---\ ~ \:,\-.Jc, Sil gel color
Total moisture = __ __._/ 1-/'-'/:',"-'-{_.-'-j __ g
RECOVERED SAMPLE CW\ L. ~ '-"" .-:, -C.-{' $ • c?S\. Filter container number(s) /'l\'i"L -z. PG' -J";::,~ ~ Description of particulate on filter :t ( \ it:,'v!\ a;i~ )
Probe rinse
container no. <n,L-2.-'r\-\ ~D...,-(.,:,'S,\:,
?~ v'.».--,.~ blank
container no. Mn..· ~ 1..-f<lN'I(.. -r 1-\ 1-.10 ~ • C.-'::.o
lmpinger contents '\ container no. M,L·"Z -:S::-N\~ -uS\, ( z ~ 1:-N'..P blank
container no. M'\\..·'i?,l..-"\t-:1'<:..-'DY\P-e.6'1.:::.
Samples stored and locked
Remarks
Liquid level
marked/sealed -'tf ... s~---
Liquid level
marked/sealed -~-e.-cs.=---
Llquid level CD a;i
marked/sealed $/'{If:
Liquid level
marked/sealed -~~-:'::> __ _
LABORATORY CUSTODY
Received by
Remarks Date -----
-
rn
EPA Method3
Dry Molecular Weight Determination
PLANT . H-,. ~~i: uJ °'-~
SAMPLING LOCATION
DATE
RUN NO.
OPERATOR -~K~L-\(_-'-"::;._--:::=v--------------
AMBIENT TEMPERATURE f":!. ---'-----------------ANAL YTlCAL METHOD O r.s --k-
SAMPLE TYPE j Single-Point Grab
c=::J_§ingle-Point Integrated Cl2:J Multi-Point Integrated (fill out Sampling Rate Data) SAMPLING SYSTEM LEAK-CHECKED V
nme: nme: nme:
Run 1 Run2 Run 3 GAS % % %
CO2 &,D t,V C, (
02 /2,8 ( z, f I 2-, f
co
N2
epa3.wk1
-• • • •
SAMPLING RATE DATA
Time Traverse pt. Qfpm % dev·
Qavg
• % dev = (Q-Qavg)/Qavg x 100%
Must be <10%
Average Molecular Weight of
Volume Multiplier Stack Gas (Dry Basis)
% Md, lb/lb-mole
£.o 0.44
(Z., 'i 0.32
0.28
0.28
TOTAL
• •
-
rn
EPA Method3
Dry Molecular Weight Determination
PLANT fuer,'f'."v\ e~~
SAMPLING LOCATION -~-=· =~=c.;1~\'-.l.c..~='-=--'-'-"""'"'=----------
DATE ei \ "be, 1 ..... \
RUN NO.
OPERATOR
AMBIENT TEMPERATURE """\ ,S 0 -----------------ANALYTICAL METHOD 0£,'6:f,::S
SAMPLE TYPE I Single-Point Grab
j Single-Point Integrated :===~ 5<" j Multi-Point Integrated (fill·out Sampling Rate Data) SAMPLING SYSTEM LEAK-CHECKED UO'o
nme: ,--rco nme: \"1\o nme:
Run 1 Run2 Run3 GAS % % %
CO2 ~. 2.. &-2 G. 2
02 . \2 .,S l Z.6 ,z..£
co ~ / ~
N2 'o\ -~ ro1 -~ '2, \. '?::,
epa3.wk1
-• • •
SAMPLING RATE DATA
Time Traverse pt. Qfpm % dev· o,~-o
;~Cie) \
-z
.,.,,
4
' ~
\02:e:, Cc,
Qavg
• % dev = (Q-Qavg)/Qavg x 100%
Must be <10%
Average Molecular Weight of
VOiume Multiplier Stack Gas (Dry Basis)
% Md, lb/lb-mole
~-?. 0.44 -Z,1.:)
\Z.S. 0.32 ,4,oo
~ 0.28 ,,.-----
'c\-~ 0.28 z2.,1o
TOTAL 7.C\."S
• • -
I
NOZZLE CALIBRATION
I
Date __ 4 ___ [ z_-s._,)_°"\'~\ __ _ Calibrated by
Nozzle
identification D1, in. D2, in. D3, in. delta D, in. Davg
number • .[-\ G -'::>f& o.~,\ D.~TZ.. o.~72 a .s··rz
\~ G - \ '?:J/":-7 r-..'l::,76 0 -~,7. D.b"1~ 0. ~ '1\,,
Kl---~~ o . .sC\'2... o.~c..::, 0.-s\S, D . ~ <;, ::> • '16-13;:_ o.':),\o " '<.. '1 lc, D -~-rt C . ~ "T<c:, ::iz
where:
• D1, D2, D3 = nozzle diameter measured on a different diameter, in .
Tolerance = measure within 0.001 in.
delta D = maximum difference in any two measurements, in.
Tolerance= 0.004 in.
Davg = average of D1, D2, and D3 .
•
•
•
,
'
•
I
•
•
•
EPA METHOD 4
MOISTURE IN STACK GAS BY WET BULB-DRY BULB MEASUREMENT
Plant
Date Run No.
Location Sampled
Cale By
Barometric pressure (in. Hg)
Stack static pressure (in H20)
Absolute pressure of stack
Pbar ± (P/13.6)
Wet bulb temperature (°F)
Dry bulb temperature (°F)
Temperature Difference (Ta-Tw)
Vapor pressure of HiO
(from table belowJ
Partial pressure of H2o
(Ps VP) ( 4 T)
pp = (VP) -
2800 (1.3)( Tw)
[ ( ) -(
PP =
= p =
=
= Ps =
= Tw =
= Td =
= 4T =
= VP =
= pp
) l ( )
= • ( ) -
2800 (1.3)( ) t),6 7 flio
70,(2:-
1..---) ~6 j}1t,t
% Moisture by volume= M I J,(' tt f.11
< /6, 6 I> I pp 55: 2 =<; •!70°1-M = (100) = (100) =
PS ( ft:?'t( 2-)
VAPOR PRESSURES OF WATER
'
~f-.0,§ Ja,
YbZ
F
·O
2
4
I • 10
12
14
14
11
20
22
24
24
27
21
20 ..
31
32
In.Ho
0.0374
0.0<417
0.0463
0.0517
0.0571
0,0031
o .....
0.07GI
o.OMG
0.0932
0.1025
0.1127
0.124&
0.1370
0.1~ o.,soz·
0.1607
0.UM7
0.1710
0.1802
F In.HQ
33 0.1171 .. 0.18$5 .. 0.ao35 .. 0.2111
37 o.uoo
31 0.%202 .. O.Z363 .. 0.2470
41 O.a574
42 0.2477
43 0.2712 .. 0.2191 .,. ...... .. 0.3120
47 0.3240 .. 0.3304 .. o ..... .. 0.3020
51 0.37&4 ., 0.3005
WBDBCALC.SHT 5/90
F In.Ho
63 0.4062 ... 0.4203 .. o ..... .. 0.4UO
17 o ..... .. 0.4151 .. 0.5035 .. 0.6211
41 0.5407
42 o .... 1
63 o=. .. o.eooo .. o.om .. 0.4'4Z
47 0 ..... .. o ..... .. 0.1144
70 O.T.182
71 0.75'1
72 o::v11 ·---
F In.Ho. F In.Hg
70 0.1113 113 1 ... 1
74 o ..... .. uno
75 0.1750 05 1 ....
74 ,O.DO-<a .. 1.712
77 0.11352 07 1.711
71 o ..... .. 1.118
79 o.a;aa .. 1.&71 .. 1.03a 100 1.113a
11 u, .. 101 1 ... 2
12 . 1.102 102 Z.062 .. 1.13& 103 Z.114 ... 1.11, 104 2.178
15 1.213 105 U◄3 .. 1.263 104 2.310
17 1.203 107 2.370 .. 1.335 101 ......
10 1.371 100 2.521 .. 1.422 110 2.504
01 1.447 ,,, Ll73
02 1.513 112 2.74'1
F In.HQ F In.Ho F In.Hg: F ln.HQI F. in.Hg
113 LUO 133 ..... 163 1.15") 170 ,i.01 1113 20.27
114 2.811 1 .. 5.G31 164 ...... 174 13.37 104 Z0.70
111 ...... 135 1.155 1 .. l.!Si' 175 13.a7 105 21.14
114 S.001 135 1..102 111 1.1n 174 13.H 1H 21.50 117 s.1 .. 137 l.'42 117 l.;t1 177 14.30 107 aa.a.s
111 ·-131 i.515 111 0.200 171 U.82 108 aa.sa
110 3.3151 130. 5.732 111 8.424 170 ,,.oo , .. 2LOO
120 3.444 140 I.HI 150 0."2 110 15.20 200 23.47 m ,..._,. 141 4 .... 141 e.w 111.1 15.a.3 201 23 ...
122 i.642 142 8.190 102 10.1Z 112 ti.Pl 202 24.40
123 s.744 143 4.350 163 10.34 113 14.34 203 24Jl7
124 ..... 144 0.613 154 10.11 114 10.70 204 .....
12.S 3Jl$4 . 14" I.MO 111 10.U 115 17.07 20.S 20,00
124 4.043 144 ..... 1aa 11.12 184 .17 . .U 204 20.53 127 4.174 147 7.024 147 11..11 117 17.82· 207 27.07 121 ..... 144 7.202 , .. 11.65 1U 11.21 201 27.G:z
120 4.404 140 7.314· 1 .. 11.0:, 1ao ta.et 200 21.11
130 4.W 150 , .... 170 12..ZO 100 18.01 210 211.75
131 ◄..47 ,., 7.75Q 171 1Ltl 101 10."2 211 20.33
132 .c.nz 152 7.052 172 12.77 "' 1'1.M 212 29.92
() ,, r-y
I
EPA,METHOD 1
TiAvERSE POINT LocAinoN FOR CIRCULAR oucTs
,• \~·.J: . •
•
1/4.tt_L-4 ~I-l\j';fl,,'r,,.:,;
PLANT C'e/+n-,,~i ~-
}¥/ ~ "~) CITY 5tfrl&y . STATE A)~
SAMPLING LOCATION Cl1Ccd4-1'..f/4-< f·v,-1. l ~ INSIDE OF FAR WALJ:: TO OUTSIDE
OF NIPPLE, (DISTANCE A} </ti'/ ' t ' ~1~ ' INSIDE OF NEAR WALL TO OUTSIDE ·3
{., , I ,.,""'
OF NIPPLE, (DISTANCE B) ' ,_
NEAREST UPSTREAM DISTURBANCE sz. i
DISTURBANCE ,.
NEAREST DOWNSTREAM DISTURBANCE I f!r ,
DISTURBANJ-j
SAMPLER (! . /J ~f DATE 1//., -</,.,.. SCHEMA TIC OF SAMPLING LOCATION • I ,
TRAVERSE PRODUCT OF TRAVERSE DISTANCE
POINT FRACTION STACK COLUMNS 2 AND 3 FROM OUTSIDE OF NIPPLE
NUMBER OF STACK I.D. I.D. (TO NEAREST 1/8-INCH) DISTANCE B (SUM OF COLUMNS 4 & 5)
I • (,' '-I l-/~ /. l'J l II 7. '8" -5' -f. c;--
'2 . 1011( /:Z.. 2.....-,£ r:
~ ?P//. I 8, ,/ ->--f_ r -
• Lt ?(?, fl . . <; L ,.._
3 S. /_ -J r
c;-~,, c; 1/1,a ~>'i ~
6 t / ' . L r-9£"; .,( Ljo. z...... ~ Y~-· z. -) 7 -
• I"\
'
{) ,t,)h.,,-,,u.L-
J,;: {( P, tr ~ ( ID 7.? 7-; r ,
2-+o,,. J;-1' 1/.,, (/ (,, 7 't f{/
~ .PIA /v Y /2, 9 12 ;;:;
Lf Jo,( '50 ¼
a;-PUlN i "" ff i; • ,
7{ ? '}/ POINT 3. ' :.-.. 12.~ I ..,-_
I
..... ,,. POINT ~-6 l~ ,
lf o, 7 lfo ?/{( ~ ~ 30~1 •j POINT 5. .-,.,
i· ... , 36.3
POINT 6. 40.7
'
' epa1 circ.wk1
I
PRELIMINARY VELOCITY TRAVERSE
EPAMETHOD2
PLANTtcuENT it,£ 6-kd(el1-tce:sr:'
• SOURCE J ///( , · •· ,'
DATE </, 25 'T I
STACK I.D. (irtches)
BAROMETRIC PRESSURE (in. Hg) 36. I 2
STACK GAUGE PRESSURE (in. H20) -"'-"6,4Q,,_,_J __ _
• OPERATORS (' D ( L
•
•
•
'
PITOT No.LU.,,,..,, , TYPE s , coEFF a. J'Y ~l'"f"~ TRAVERSE POINT LAvouT scHEMAT1c
TRAVERSE
POINT
NUMBER
A-, .... , , <
LI
'2_
L
I .
/-. -
J
VELOCITY
HEAD
(in. H20)
EJ ,O<i,,-
n .tJ '1
(),/[)
,? ' I !J o. l) ~
f! ' 0 c.,
V
.,,, /, .. :, l-/
A",.,., I. , ,
STACK
TEMP
(OF)
I &i-5
J /,,, 7.,
i /Al.I
I !.t/
I/. J_/
I(,.</
·-... /'/,.,, .
/1,.-Z '7/.
TRAVERSE VELOCITY STACK
POINT
NUMBER
It /)/-I_ I,. q s µ,/--, 'P--t,¥",4:¼--..f..-t:-tF-,.L----l
,.
~~ '~ '),I., ;/y.,.-•
'(,,Z, I A.I..~"
A.h I," I -/IA
. -
f 9,((6
s.sy
/;,iveMGE/ SQRT{,!, ')_l/;2._ I LA.
POST PITOT LEAK CHECK PASSED~
MEASUREMENT DEVICE
_...,__f t3 µ,cf 0-10" MANOMETER . ·
Cio /, · MICROMETER§
O z.) MA.GNEHELIC
_ L _ _'f:__ y' 6 OTHER ,.---,! --------
~~!FAILED
EXPLAIN:
f-r-ttfl 2) r (1 c; "--" /c {v/ }S",2__\ t,,,..,,r'--
prevelo.wk1
~t: /...+.. I ?[ ✓ -L-6· 'J? /7, c/ <-,)
{6J'rf2---
'J 6° 'J 7 2-~-('/.Ch;
~J~ l,J~c.r:~
>BY[)
( 8 ,,C/.5
~
• • • • • • -
EPA Method3
Dry Molecular Weight Determination
RUN NO. -z.A
OPERATOR
AMBIENT TEMPERATURE 10 °/ -----------------ANAL YT1CAL METHOD O e't-J,,f\~
SAMPLE TYPE ! Single-Point Grab
! Single-Point Integrated
:=I =><=::;:::a:-, Multi-Point Integrated (fill· out Sampling Rate Data) SAMPLING SYSTEM LEAK-CHECKED *S.
TI me: \ o ,z..::: Time: loo'=, Time: ~cAo Run 1 Run2 Run3 GAS % % %
CO2
~-\ 6. \ C:::, . \
02 12 .A \ 2..~ \c..s
co ~ ~ _,...---------
N2 .S \ .-s. <3\ ."\ o\.~
epa3.wk1
SAMPLING RATE DATA
Time Traverse pt. Qfpm o/o dev•
C::,""l"'i:.::, \
z
:3.
4. ,. c:::::.
O'OS "4 b
Qavg
.
• % dev = (Q-Qavg)/Qavg x 100%
Mustbe<10%
Average Molecular Weight of VOiume Multiplier Stack Gas (Dry Basis) % Md, lb/lb-mole
G. \ 0.44 '2 -~'c,
\Z.s 0.32 -4_.DO
,,,.,,--0.28 ,..-------
'e)\ . .:1 0.28 -z.' ·'°'
TOTAL 2=\.-S
-
I V
<----------------MM5 ----------------> POINT DELTA P SQRT DP DGM IN DELTA H STACK T
bl 0.22 0.4690 79 1.85 172 • 0.22 0.4690 80 1.85 172
0.22 0.4690 81 1.85 172
0.21 0.4583 82 1.80 173
b2 0.28 0.5292 83 2.36 173
0.28 0.5292 83 2.36 173
0.30 0.5477 82 2.53 173
0.29 0.5385 82 2.40 172 • b3 0.30 0.5477 82 2.50 173
0.32 0.5657 81 2.70 172
0.29 0.5385 81 2.40 173
0.32 0.5657 81 2.70 173
b4 0.26 0.5099 82 2.20 173
0.25 0.5000 81 2.10 173
0.26 0.5099 82 2.20 173 • 0.23 0.4796 83 1.94 174
b5 0.23 0.4796 84 1.94 174
0.21 0.4583 86 1.80 174
0.24 0.4899 87 2.00 174
0.24 0.4899 88 2.00 174
b6 0.21 0.4583 90 1.80 174
0.19 0.4359 90 1. 60 174 • 0.19 0.4359 90 1:60 173
0.19 0.4359 91 1.60 173
al 0.19 0.4359 88 1.60 173
0.19 0.4359 89 1.60 173
0.19 0.4359 89 1.60 173
0.19 0.4359 90 1.60 173 • a2 0.24 0.4899 90 2.00 173
0.23 0.4796 90 1. 94 173
0.23 0.4796 90 1.94 172
0.23 0.4796 88 1. 94 173
a3 0.27 0.5196 88 2.30 172
0.27 0.5196 88 2.30 17.Z 3
0.27 0.5196 86 2.30 172 • 0.25 0.5000 87 2.13 173
a4 0.27 0.5196 86 2.30 172 0.28 0.5292 86 2.40 173 3 0.26 0.5099 86 2.20 17,2'
0.26 0.5099 86 2.20 173 a5 0.27 0.5196 86 2.30 173
0.28 0.5292 86 2.40 173 • 0.28 0.5292 86 2.40 173
0.28 0.5292 87 2.40 173 a6 0.27 0.5196 }3:1 ft 3--.-4-e z_. 3 172
0.26 0.5099 8£i7 -i!---.---3-0"2,<.. 173
0.26 0.5099 8-'rri 2.20 173
0.26 0.5099 .2-8 c 7 2.20 173 , --------------------------------------------------AVG 0.4974 86.4 2.11 173.0
I
--• • • • • • -.. v c.,.,/
<----------------H5/HCL -----------------> <----------------Metals --------
POINT DELTA P SQRT DP DGH Ill DELTA H STACK T POINT DELTA P SQRT DP DGH IN DELTA H STACK T ---------------------------------------------------------------------------------a6 0.29 0.5385 69 2.48 170 bl 0.28 0.5292 66 2.36 170 a6 0.28 0.5292 70 2.40 170 bl 0.27 0.5196 68 2.27 61 171 as 0.29 0.5385 72 2.48 170 b2 0.32 0.5657 70 J.,fil -;_, 171 as 0.29 0.5385 74 2.48 171 b2 0.32 0.5657 72 2.69 172 a4 0.29 0.5385 75 2.48 171 b3 0.34 0.5831 13 2.86 171 a4 0.28 0.5292 76 2.40 171 b3 0.34 0.5831 74 2.86 171 a3 0.27 0.5196 11 2.30 171 b4 0.27 0.5196 74 2.27 171 a3 0.26 0.5099 11 2.22 171 b4 0.26 0.5099 75 2.19 172 a2 0.26 0.5099 11 2.22 171 b5 0.25 0.5000 75 2.11 172 a2 0.27 0.5196 78 2.30 171 b5 0.25 0.5000 75 2.11 172 al 0.24 0.4899 19 2.05 171 b6 0.20 0.4472 76 1.68 172 al 0.22 0.4690 81 1.88 172 b6 0.20 0.4472 11 1.68 172 bl 0.21 0.4583 78 1.79 172 al 0.25 0.5000 75 2.10 172 bl 0.21 0.4583 80 1. 79 171 al 0.24 0.4899 11 2.00 172 b2 0.24 0.4899 82 2.05 172 a2 0.28 0.5292 78 2.40 172 b2 0.24 0.4899 83 2.05 172 a2 0.26 0.5099 78 2.20 173 b3 0.24 0.4899 82 2.05 172 a3 0.25 0.5000 76 2.10 172 b3 0.25 0.5000 80 2.14 172 a3 0.26 0.5099 76 2.20 172 b4 0.33 0.5745 79 2.82 171 a4 0.28 0.5292 75 2.40 172 b4 0.33 0.5745 79 2.82 172 a4 0.28 0.5292 75 2.40 172 b5 0.30 0.5477 79 2.56 171 a5 0.27 0.5196 75 2.30 173 b5 0.30 0.5477 70 2.56 171 as 0.27 0.5196 75 2.30 -1-'/:3"" i 7 Z.
b6 0.22 0.4690 79 1.88 171 a6 0.24 0.4899 76 2.00 172 b6 0.21 0.4583 79 1. 79 171 a6 0.21 0.4583 76 1.80 173
---------------------
AVG 0.5033 78.9 2.2 171.4 AVG 0.4993 75.9 2.12 172.2
<----------------Ethylene ----------------->
' POINT DELTA P SQRT DP DGM IN DELTA H STACK T ---------------------------------------------------a6 0.22 0.4690 66 2.36 170
0.22 0.4690 68 2.27 171
0.22 0.4690 70 2.61 171 7 0.21 0.4583 72 2.69 172
a5 0.28 0.5292 73 2.86 171 I 0.28 0.5292 74 2.86 171
0.30 0.5477 74 2.27 171
0.29 0.5385 75 2.19 172
a4 0.30 0.5477 75 2.11 172
0.25 0.5000 75 2.11 172
0.20 0.4472 76 1.68 172
0.20 0.4472 77 1. 68 172 • a3 0.25 0.5000 75 2.10 172
0.24 0.4899 77 2.00 172
0.28 0.5292 78 2.40 172
0.26 0.5099 78 2.20 173
a2 0.25 0.5000 76 2.10 172
0.26 0.5099 76 2.20 172
0.28 0.5292 75 2.40 172 • 0.28 0.5292 75 2.40 172
al 0.27 0.5196 75 2.30 173
0.27 0.5196 75 2.30 173
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
b6 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172 • 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
b5 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172 • b4 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
b3 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172 • 0.24 0.4899 76 2.00 172
b2 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172
bl 0.24 0.4899 76 2.00 172
0.24 0.4899 76 2.00 172 • 0.24 0.4899 76 2.00 172
0.21 0.4583 76 1.80 173
---------------------------------------------------AVG 0.4957 76.0 2.0 172.1 ,
'
SENT BY:xerox Telecopier 7020 5-2-91 2154307436➔ 919194601765;# 2
I
m
' VOST DATA SHEET
• ·, ..... , Sli1nnle Tl-all, TemMralureS
Clook SmnpUno Flotam$ler G•Sampl1 Prob11 1atCond. DryOa.s Pump Time l1m& Rftdlng Volume Temp Outisl ..... vacuum 124 hr) (min) 11/mlnl flllera) ('C) {'C)-("C) /In Hg) • l~S'rl r, 6, ... ~.0(0 .:l'+n i _,.<"" 3 1~= s-<J>,s;-..3~.l :;.:is , .... _,,,-.!l ,~ ', p,5 ....... , ~~ ... , ,, '-+ ,, ,,., _,,,. (). ";; ➔" 0 -,u ,., ;')' 1./ r°'J1• ~"' ",> 'I/'{. '1 .:t\.i , 'l,, ~!, (J. I 'I. :, ,_ ~~ f ,; II~." ;i .. ., q ')_"7 '-I • 141:~c Ut, fr). 7,:0
• "10" 0,5-
8-mple Tl'IIJI 1,0, COmmenta:
Tenair. Tel\lll<JCharccal
$Anu,le 41 ,,,,
R1>1d Blank • Trm Blank
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•
•
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•
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I
VOST
Client He,
Facility Sk.L] f::.
Source ::i=bc j1 f,:\:-o..e,k.
Run No. d fl
Project No.
DGM No . v,-,it.;i_
Train Leak Check • Initial: Va,:; I '1
Train Leak Check -Anal: Vac Ii
Clock Sampling Rotameter
Time Time Reading
(24 hr) (min) (Vmln)
p-0-I •• ,, _,...,:;:,,,
"
J'.J>!>O 0 t"J.7
---/ '.,$'7.:::, 7.t{ 0 .::;
/./Dtl /0 0, '!,°
(</0§ '" 0,,;
l't I 0 ,o o,,;
J <+ I .(" .}..S •. 5'
I 'f.:tl 31 o.5'
Jc.{~[,, 'T,7 0.>
lt-/cJ'I. 5 !:>9-~
Sample Trap 1.0.
DATA SHEET
~o ,-.,fl
Date <-I /:411
Flow Rate (1pm) o-5
DGM y atlpm
Barometric Pressure Y,· led,
Operator ~~txit.;
In Hg 0. 5 A In Hg/ loo sec.
In Hg g,r; A In Hg/ c.o sec.
Sample Train Temperatures
Gas Sampl< Probe 1st Cond. Dry Gas Pump
Volume Temp Outlet Meter Vacuum
(liters) ("C) ("C) (°C) (in Hg)
5/.. •5oo ~..;<11 I ::;l • ;l1 ~
~.s-~--16 I .., .:J'f 9 • ,',
fol. 0 ~qf I :i. 30 '. s-
b:3. </ ~4<6 I ( "-" q .. ~
l, ~-.50 ~'/'1 I( 36 q_ ~
b?-7~ j'f'7 '!, ;,o /0 &
70.,., olt,"o 11 ::,,o II, o
7--1 • /00 ~5''1 t, 31 /IC
7;:: <;oo
Comments:
Tenax Tenax/Charcoal
Sample 7.!l 77
Reid Blank
Trip Blank
'
•
VOST DATA SHEET
Client t,, Date 'fb,0/v • Facility -'-1:J' I "7+ Flow Rate (1pm) o. S'
Source -z:"' C: I >'I • <;,j-.J,_ DGM y atlpm
Run No. ~Ct. Barometric Pressure ;;o. (=,_
Project No. Operator t<M51,;.fr
DGM No. \rrl1,;,
• Train Leak Check -Initial: Vae ,;i ':1. In Hg 0-3. a In Hg/ 60 sec.
Train Leak Check -Final: Vac ,;,.t_ In Hg f>. I a In Hg/ kC sec.
Sample Train Temperatures
Clock Sampling Rotameter GasSamplE Probe 1st Cond. Dry Gas Pump • Time Time Reading Volume Temp Outlet Meter Vacuum
(24 hr) (min) (Vmln) (liters) (OC) (OC) (°C) (In Hg)
/7 :20 () o.s-'i,7. S'-(o o?'-11> .;,_e, ~;:,. :?,
/ 7;;,,,; ~
0 ~ JT.'Ji -6 ,;, '-{ 3 Jq ?'.:, "f
/ 7 ..,_ (0 o.~ ~;i. 500 a:,O ,,,.,, .,, <-.. '"I
/1 ?< I. '' "'· 5 1 'f. a ,:;,,,./-, { g :,.:,_ <../, • 17.+o A> /i.'5 ~b. I _')r.f4-l(, 5., o../
/'7<f5 ',~ o.~ ,-2.S:-o,4'-; I<-/-'.\P ,.J_
175(:) ~0.5' C). i ool.o ,'J S°D D., '=<:i. 4
/70 ?'f' o, $"' oo":5.t .;i Str I"!, <, .:,.._ <f
/t;.rJO 'to. 'b OOb s'
•
• Sample Trap I.D. Comments:
Tenax Tenax/Charcoal
Sample '¼, 7i
Field Blank
Trip Blank
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I
VOST DATA SHEET
Client
Facility 2ho(1-!7 Source :Cv,, ct ~ s+,._ c./<..._
Run No. l
Project No.
DGM No. 11:r. "" 2
Train Leak Check -Initial: Vac .:? ?:
Train Leak Check -Final: Vac ~ z
Date
Flow Rate (1pm)
DGM y atlpm
Barometric Pressure
Operator
In Hg c, • cl 6. In Hg/ C,,6 sec.
In Hg \!:<SS.f'itrl..lg/ __ sec.
t.f:ho/ <r I • o. s; (£IN\
.3D, /?,
~
Sample Train Temperatures
Clock Sampling Rotameter GasSamplE Probe 1st Cond. Dry Gas Pump
Time nme Reading Volume Temp Outlet Meter Vacuum
(24 hr) (min) (Vmln) (liters) (•C) (•C) (°C) (In Hg)
la. ,a. (j "· > ']I, 000 .;;,_ '-(-q l"'.3 ="',.;i s-
I$' ._ .::, -.s-/c>.€' .:>,<-ff I ;:, .,_~ ~-
I q, '.}1 /3 {).~ 1£'.?; ., ",._ I' ~::,_ ':,
I !l !>"' '5" o.f,[; /i,./S-_) ,;-.:, I;,._ 3~ 0
~ 1'ff Lj _.,t;-o.~ ~ ... :-~ ::, ;)1 I '"s >~ s-
I g -fs ~ 0-~ ..;i.'-/,1,/, ~s-::,, Ju 31 S"'
1-&S~ '.:, 5" ◊.~> ;i.7_(; .... <""I }--{, 31 4-
I ~.5"l S {,,"' . $"" .;i, ::, 9?J
Sample Trap I.D. Comments:
Tenax Tenax/Charcoal
Sample g: \ 7.1,
Reid Blank
Trip Blank
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VOST DATA SHEET
Client 1--\ c., Date • Facility s lia.l b;i Flow Rate (1pm)
Source J\vd,./--Ci~ DGMy atlpm
Run No. A..,J:-t" B Barometric Pressure
Project No. Operator
DGM No . 1/"f ""'s6-
• Train Leak Check • Initial: Var; IS.=,' In Hg 0 6. In Hg/ b 0 sec.
Train Leak Check • Final: Vac IJ,.i In Hg i> 6. In Hgti.• sec.
Sample Train Temperatures
Clock Sampling Rotameter Gas SamplE Probe 1st Cond. Dry Gas Pump • Time Time Reading Volume Temp Outlet Meter Vacuum
(24 hr) (min) (Vmin) (liters) (°C) (OC) (°C) (In Hg)
17{0 0 0.5 'i:3./00 -ci.O ,x s-,;,._ cJ
17/ b 1-, 0.'>° "I&.;;).. -.;lo c.:i:.--°'l•l'>
11.;,,0 ,o o.5 q~.""---o o>.S--~-0 ,-z.:,_< 16" 0 .c. IOI. o~ -~o "'~ ., • 0 • 1~0 c).O I o;i_ 1M
•
• Sample Trap I.D. Comments:
Tenax Tenax/Charcoal
Sample 74, '7Q
Field Blank
Trip Blank
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VOST DATA SHEET
Client (., Date
Facility $ltt/b Row Rate (1pm)
Source 14uJ..-r} .....Q_.-., DGM Y atlpm
Run No. AuJ·,-t-C:... Barometric Pressure
Project No. Operator
DGM No. \1-r ",3
Train Leak Check· Initial: Vac I c.. In Hg 0. 3 l>. In Hg/ bo sec.
Train Leak Check • Anal: Vac _,/'""&'---In Hg o. ~ t,. In Hg/ "o sec.
Sample Train Temperatures
Clock Sampling Rotameter GasSamplE Probe 1st Cond. Dry Gas
Time Time Reading Volume . Temp Outlet Meter
(24 hr) (min) (Vmln) (liters) (OC) (OC) (°C)
/F{D 0 0.5" 5. ooo -;,.o d,<f
11'0, b o.> 7.1 -o\O :.'f
I ?5°/ JI ,i) C: 10. '-/ -.;).d ~"' 115"> 1G" o. G'" ,.., '-1 !; ..>.o )<J-
l<Db ;,o -1<1.9{0
Sample Trap I.D. Comments:
Tenax Tenax/Charooal
Sample ,</, 7'1
Field Blank
Trip Blank
Pump
Vacuum
(In Hg)
..:,_
~
L
-"-
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(._,
VOST DATA SHEET
Date
Flow Rate (1pm)
DGM y atlpm
Barometric Pressure
Client
Facility
Source
Run No.
Project No. -------Operator --------D GM No. v-r ,.. .:,__
Train Leak Check -Initial: Vac / i In Hg _o __ a. Jn Hg/ -, o sec.
Train Leak Check • Anal: Vac f il-In Hg c, a. In Hg/ 1, o sec.
Sample Train Temperatures
Clock Sampling Rotameter Gas Sample Probe 1st Cond. Dry Gas .Pump
nme Time Reading Volume Temp Outlet Meter Vacuum
(24 hr) (min) (Vmln) (liters) (°C) (OC) (OC) (In Hg)
19'15 0 O.~ 17_ o -.:lo a.-::. ~
/ J f Z-::;,. 10 Q • 0: ol-'-. 0 -1'1 .;i.) ..;i_
JP,~ 1-/7 o,";f ;;) 1,· •. ~ -11 o<3 ..:i_
('p ">r;-.,;i.e -.;lb. '3 S'
Sample Trap I.D. Comments:
Tenax Tenax/Charcoal
Sample ?'f '71
Field Blank
Trip Blank
'
~ , • 1 , ;. ·,· • • , + f , r ~ * , f f * r .f' * ,. t f * ·• * * * * * ~ * * * * * * * ~ * t t * * * * * * * * * * * * * * * * * * * * * * :f. :f. * * * * * * * * * * ~ * f' * -f: * * * * , i,OC i-.NGINEl'RING 20:00:01 * , SHtLBY. NC Tue Apr 30 1991 ' cPA HOURLY REPORT ' ' ' ' ' ,·,1,:c.i:R !PT lON VALUE MlN AVERAr,E MAX UNITS * I * ' f I\ i U~ S(;L J 0 WA~.Tc FEED 0. 18 0.00 2.60 8.00 r ~H ' ' ~: ! L/"J TEMPf'RATURE 1::S06 1602 DEG F *
f<: l LN 1iRA~T -0.$6 -0.50 IN H'd *
* ' .sec r fl"IPERA Ti.IRE 1650 17 33 DEG F * ' sec % OXYGEN I ., " . 14 3.95 % 02 * • ' :,(;(: 0111'NCri TOTAL WATER FLOW 0 GPM • uUFNC:H TEMPERATURE 406 405 DEG F * ::iC.C 8/1, i:.,HC1t _I~. E DP 2.46 1 .81 6. 21 6.84 IN H;~O ' ' ' .':..ck1Jf.:.KE.R T1)1 AL C1\USTil: !'LOW 0 GALLGii.S
' HACK HMPERAT URE 175 1 7 1 DEG F ' • ' ;~ T At .. t< VELOCITY 0.0 482.3 FPM ' ::-:·1·1,,(;1', CO2 2.81 2.80 r 10 7.53 % CO2 * ' >:-. l i\CV oz 16.46 1 1. 49 11.% 16.68 % 02 ' * ';TACK co 1. 7 7./:' 1 .9 2.0 PPM ' ' .'.iA1:,: co i 7% 0? REF) 5.2 PPM ' ' (,0 7% ROLLING AVERAGE: 2. ·:J PPM • * C:OM811S T ION EffJCIENCY 99.99 100.0 %CE * • ' ~.(:RI IP.BER ll::MPrRATl.lRE 175.0 171 .0 DEG " • '.:-i(_'.RR! lMP.tR PH 6.8 6.8 Pf; f
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' !,t·,4•*~'f'**'•**'*••******'************************************************************
i GDC ENGINEERING 7:00:01 • SHELBY. NC Tue Apr 30 1991 t EPA HOURLY REPORT ( ' * • I l.il:SCRIPTION VALUE MIN AVERAGE MAX UNITS * ' * * fil L N SOLID WASTE FEED 3. 10 0.00 2.69 4.26 TPH • ' ,: I LN TEMPERATURE 1631 1620 DEG F * >:ILN DRArT -0.67 -0.49 IN H20 * * * sec TEMPERATURE 1757 1750 DEG F * • ' sec % OXYGEN 4.40 3, "/0 % 02 * ' ~.c:c QUENCH rDTAL WATER FLOW 1488 GPM ' • (JI.it.NCH TEMPERATURE 406 405 DEG F' * • sec RAGHOIJSE DP 5.28 4.61 5.01 5. 73 [N H20 ' * • ' SCRUBBER TOTAL CAUSTIC FLOW 0 GALLONS * S!ACi< TEMPERATIIRE 1/8 170 DEG F • ' SIAO, VELOCITY 501. 0 449.7 FPM ' ST AO. CO2 6. 7f, 0.:11 6. 77 6. 75 % CO2 * -~.T/\(:~, o:~ 12.49 I 2. 03 12.01 2 1. 18 % 02 ' ST /1CK co 1. I 0. 7 1. 6 1. 8 PPM * s·1AO. co I 7% 02 REFl 2.~ PPM * c:o 7% ROLLING AVERAGE 2.6 PPM • COMBIJST[ON EFFJCIENCY 100.0 100.0 ":"{,(:[: • !'.CRUBBER TEMPERATURE 178. 0 170. 2 L1f_G
' SC:RHUKHER PH 6.8 () • ,<.
•
•
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11>·:',CRlPT [ON
~-JLN SOLi[J WAS·1·E ~~ED
~::. ~ l'l :·t-r1Pf.'~Af; :~::-
.. ,:: N :_·1~.t\F,
·.M."ERI\ TURI:
sec% OXYGEN
Sr:!: OIJENCH TOT AL WATER FLOW
Olll'NCH HMPERA TIIRE
$(:(: RAGHOUSE OP
.C.C:Ri1kBE:R TOTAL C:AllST IC FLOW
SlACK TEMPERATURE
STl\f:K VH.0(.!TY
·STACK CO2
STA(:~: 0?
Sl A(:1<: CO
:, f M:e: CO 1 /% 02 REF I
CO 7% ROLLING AVERAGE
i:•!'1P,1ISTlON 1:FFICIENCY
SC:RURRER TEMPERATURE
:;U-iRI 1t:\Btk PH
VALi.ii:
-0. 7 4
1757
4.69
1502
406
5.66
0
170
518.0
6.84
12.40
I. 8
2.9
2. 7
100.0
170. 0
I). 8
iue Apr 30 1991
NIN
4.69
6.54
11. 7ti
I. 6
AVERAGf-
2.38
1629
-0.4~
1757
4.28
405
5. 10
175
510.8
6.39
12.50
1. 6
100.0
174.8
6.8
,!•;. *
*
3.82 TPH * DEG F ' IN H20 ' * DEG F ' % 02 *
GPM •
DEG F * 6.:JO IN H20 ' *
GALLONS *
DEG F * FPM ' 7.36 % COi * 1;,. 77 % 02 *
2.2 PPM * PPM * PPM * %CE ' DEG F * PH *
' ZfJfft~+f•f+*;z,f*~***~l*•****************************i**********************~**********
GDC ENG INFER ING 9:00:01 ' SHELBY, NC Tue Apr 30 1991 '
' EPA HOURLY REPORT ' ' ' • ' *
• ijfSC:R I PTION VALUE MIN AVERAGE MAX UNITS •
• *
' ,. J L.N iOL ID WASTE FEED 2.56 0.61 2.40 4.22 TPH ' f ULN TEMPERATURE 1570 1636 DEG F * ,: I LN DRAFT -0.24 -0.50 IN H20 ' ' *
* sec IFMPERATURE 1730 1759 DEG F ' • * sec % OXYGEN 4.73 4. 51 % 02 * • sec ilUENCH TOiAL WATER FLOW 1480 GPM * QUENCH TEMPERATURE 406 405 DEG F •
* :~(;C l:lAGHOUSE Oto 5. :, I 4.90 5.48 6.47 IN H20
' *
' :,CRI 1B13t=R TOTAL CAUSTIC FLOW 0 GALLONS • • ' .STACK TEMPERATURE 170 170 DEG F •
' ,;T t,O. VELOCITY 495.0 502.3 FPM •
' .~TACK CO2 6.66 6.25 6.96 6.94 % CO2 * • SfACK (_){. 12.49 12.20 12.24 l:i.31 % 02 ' Sf AO: co 1. 8 1. f, 1. 8 2.4 PPM •
' ST /\Ck r.:o I. 7% 02 REF) :J. 0 PPM •
' co 7% ROLLING AVERAGE 2.9 PPM * • ' (:UMBu:;r !ON EFFICIENCY 100.0 100.0 %CE *
f SCRUBBER TEMPERATURE 170.0 170.2 DEG F '
' '.:>CRRiiBBER PH 6.8 6.8 PH *
flTl~~*~fll*''****************************f**********'************~**********************
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'*'''frff,Jf~*'**'***~'*'**************~************************************~***••~~****
C1DC ENGINEERING 10 :00: 0·1 *
' SHELBY. NC Tue Apr 30 1991 ' • EPA HOURLY REPORT ' ' ' * * * DESC:RIPT JON VALUE MIN AVERAGE MAX UNITS *
' * * ,: f I N :;ouo WASTE FEED 3. 10 0. 18 2.92 4.83 TPH * ' KILN TEMPERATURE 1557 1579 DEG F *
* ,. ! LN DRAFT -0.26 -0.50 IN H20 *
* * ' sec TEMPERATURE 172 1 1735 DEG F * ' sec % OXYGEN 3.85 4.84 % 02 * • s,:c OIJENCH TOT l1L WATER FLOW 1466 GPM *
' (JIJENCH TEMPERATURE 404 405 DEG F *
' sec BAGHOUSE DP 5.27 4.60 5.73 6.03 IN H20 •
* *
* SCRtl88ER TOTAL CAUSTIC FLOW 0 GALLONS ' * STACK TEr-lPERATURE I 7 1 170 DEG F *
* Sf ACK VELOCITY 465.0 498.3 FPM ' * STACK CO2 6."i7 6.32 6.57 7. 10 % COc * * SI A(:1. 02 12.28 11. 84 12.62 1?.80 % 02 ' ' STACK co 2.0 1 . 6 I. R 2.R PPM * * .0.IM:f. t:() ( 7% 02 REF/ 3.2 PPM * * GO 1% ROLLING AVERAGE '.J. 0 PPM * ' r;c/Mi3UST JON EFFICIENCY 100.0 100.0 %CE *
* ''-CRUBBER TEMPERATURE 1 71 . 0 170. 3 DEG F ,
* .\C:RRi.lf<,~Efl PH 6.8 6.8 PH * 1••~•~t¥~~***************************************f***************~***********************
' GDC ENGINEERING 11: 00: 01 *
f SHELBY. NC Tue Apr 30 1991
' EPA HOURLY REPORT
• * *
' 1JFSC:R I PT I ON VALLIE MIN AVERAGE MAX UNITS ' * ' * f'.TLN :;Ol.ID WASIE FEED :~ . 1 ·; 0.00 2.94 8.00 TPH ' ' KILN HMPERATURt 1536 1555 DEG F •
'-.li.N DRAFT -0.26 -0.49 IN H2\J * f * • * :~C;C: ff MP ERA TIIRl'. 1720 1720 DEG F •
f sec % OXYGEN 4.69 4.39 % 02 *
* :-.cc OUENCH TOTAL WATER FLOW 1419 GPM * ' CJIIENCH TEMPERATURE 404 405 DEG F *
* ~.(;(: P.AGHOIISE OP 5.02 4.37 5.47 6. 12 IN H20 ' ' *
* '.)CRU88ER iOTAL CAUSTIC FLOW 0 GALLONS * • • STACK TEMPERA TLIRE 1 7 I 111 DEG F * ' :)!"A(:~; V~LOC !TY 0.0 490.0 FPM *
* STACK CO:? 6.46 6. :?O 6.66 6.99 % CO2 *
* S; f1C:~, n:~ 12.49 12.00 12.40 12.90 % o;~ ' * .:..:;TA(:t< co 1. 8 I. 6 1. 9 2.4 PPH
:;TACK co 1. 7% 02 REF) 3.0 PPM f
f co 7% ROLLING AVERAGE 3. 1 PPH * • ' 1:C,Hkll$ T ION EFFICIENCY 100.0 100.0 %CE ' :0.CRUBBER HM PERA TURE 171. 0 17 1. 0 DEG F * t :,Ck RI IKBF ~ PH 6.8 6.8 PH ' **ilfli*~••tttit******'*********•tf**'***l~tf*ftfltt,tft*•******'**~*************~***'***
•
•
••
CiDC ENGINEERING 12:00:01 ' SHELBY, NC Tue Apr 30 1991
EPA HOURLY REPORT ' f • • ' * 1kSCR [ PT f ON VALUE MIN AVERAGE MAX UNITS ' *
!<ft.N SOL I (j WASTE FEED 3.53 0.00 2.69 5.91 TPH ' K_[ Lt~ TEI-IPERATIJRE 1552 1545 DEG F ' i: I LN DRAt'T -0,28 -0.50 IN H20 •
' • • sec fEr-iPERATURE 1719 1719 DEG F •
' sec % OXYGEN 3.59 4,36 % 02 ' • :~CC: ()I IENCH TOTAL WATER FLOW 1402 GPM •
\Jl 1ENCH T EMPfRA HIRE 405 40fi DEG F •
~{';C; flM,HOiiSE DP 5.56 3.65 5.20 6.45 IN H:'0 ' ' •
' ~-CRIJ P.i3 ER TOTAL CAUSTIC FLOW 0 GALLONS • • * STACI< TEMPERATURE 172 173 DEG F * '....:.TJ\(:f': VFl.OCITY 441. 0 186.3 FPM ' ST /1C K CO2 6.83 6.34 6.59 7. 12 % CO2 ' ' ~.!"A(;f<; O? 12.09 11. 70 12.38 1 :'. 78 % 02 * ' Sl ACI< co 1. 9 1 . 5 1. 8 2.0 PPM * r ::, ! ACf', co 17% 02 REF) ~.o PPM ' cc, 7% ROLLING AVERAGE 3.0 PPM * • ' (:C,MkUSTION EFFICIENCY 100.0 100.0 %CE *
SCRUBBER TEMPERA Tl.IRE 172.0 172.6 DEG F *
~-CRRl.lf;flfR PH 6.8 6.8 PH *
ll•~,1,,l******'**'*'''~'********************~*********'*************~*******************
•
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•
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I 1fffft~f•tffff,,Zi~f*~~'''**'*************'**************************************''**'~*
GOC ENGINEERING ·13: 00: 00 ' SHELBY. NC Tue Apr 30 1991
EPA HOURLY REPORT * ' * I * Ot.SC:RTPT !ON VALUE MIN AVERAGE MAX UNITS * •
I", i.LN .SOLID WASTE FEED 3.61 0.00 3.04 8.00 T PH ' ,. 1 LN TEMPERATURE 1540 1544 DEG F * ~: I 1.N DRAFT -0.52 -0.52 IN H20 •
* f :~.cc 1 EMPl:'RATURE 1 7 15 171 7 DEG F * • ' sec % OXYGEN 3. 91 4.08 % 02 •
* .sec Cil ll'NCH TOTAL WATER. FLOW 1230 GPM • DUENC:H TEMPERATURE 404 405 DEG F *
' '.)CC Bi\GHOUSE DP 5. 10 4.99 5.50 6. 71 IN H20 *
* f :'.i:Rll8Hl:R TOTAL CAUSTIC Ft.OW 0 GALLONS * • STACK TEMPERATURE 17:l 172 DFG F * STACt< Vf:.LOCi TY 0.0 207.9 FPM •
' Si ACK CO2 t).82 6. 13 6. 72 7.28 % CO2 * ' STACK 02 12.03 1 \. 53 12.22 12.84 o/., O? *
* STACK co 2.0 1. 5 1. 8 2. 1 PPM * ' STAC:h co I 7% 02 REF) 3. I PPM * ' co 7% ROLLING AVERAGE 2.9 PPM * • ' COMRiJS T [ON EFFICIENCY 100.0 100.0 %CE • SCRIJBP.ER TEMPERATURE 173.0 17 2. 1 DEG F * ' :c,(:RR1 l[HlfR PH 6.8 6.8 PH X
f~~flilt,++~f¥**f****+~***************~***************************'******'****~***¥******
•
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••
'
* •·
Dr::.SCR T PT lON
GDC ENGINEERING
SHELBY. NC
EPA HOURLY REPORT
~ii.N SO(.fO WASTE FEED
>. l LN TEMPtRATIJRE
Ki 1.1'1 DR1\FT
SC:C TEMPERATURE
fCC % OXYGEN
:'.i:C: QUENCH TOTAL WATER FLOW
tiiJENCH TEMPERA HIRE
:-.i':1: RAGHOI iSE DP
S1.R1J~BER TOTAL CAUSTIC FLOW
STACK TEMPERATURE
,0T1\CK VEi.OCl TY
STAC,. CO2
Sfl\(Y 02
STACK CO
SI.ACK CO 17% 02 REF)
CO 7% ROLLING AVERAGE
COMKIJSTION EFFICIENCY
SCRUBBER TEMPERATURE
VALUE
.L 54
1549
-0.48
1716
3.93
991
406
5.40
0
1 7 1
631. 0
6.F
12. 12
1. 9
J.O
2.9
100.0
1 71 . 0
14:00:01 ' Tue Apr 30 1991 ' *
*
*
MIN AVERAGE MAX UNITS ' * 0.07 c'..) 8 5.59 TPH
1542 DEG F * -0.48 IN H20 ' * 17 13 DEG F * 4.06 % o·> •
GPM * 40'i DEG F * .'J.99 5.69 5.96 IN H20
*
GALLONS •
172 DEG F
133. I FPM f
6.38 6. 77 7. 21 % CO2 ' 11 . 55 12. 15 12.58 % 02 •
1. 6 1. 8 ;~. 4 PPM * PPM ' PPM * 100.0 %CE •
172 .o DEG F * 6.8 6.8 PH ' ~-CRR1 IH8t.H PH
lfff~ifilflllt~,.¥~***************************~*****~******•*•********************•**•***
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f GDC ENGINEERING 15:00:01 * SHELBY. NC Tue Apr 30 1991 ' EPA HOURLY REPORT •
*
' * DESCRIPTION VALUE MIN AVERAGE MAX UNITS *
' ' • nu, SOLID WASTE FEED 2.24 0.00 2.86 8.00 fPH *
' ~:I LN TEMPERA TIJRE 1555 1547 DEG F •
f ,.I LI'< DRAFT -0.39 -0.49 IN H"O ' ' * :.:.cc l~MPERAJ"IJRE 17 15 17 15 OEG F * • sc:c % OXYGEN 3.88 3.98 % 02 ' * sec fJl.iENCH TOTAL WATER FLOW 591 GPM '
' OIIENCH TEMPERA HIRE 402 40b DE!3 F ' * ::-:cc BM;HOUSE DP 5.72 4,95 5.~j 6. /0 IN HlO ' ' ' ' '.~C.RU~EEK TOTAL CAUSTIC FLOW 0 GALLONS ' • •~T /1CK TEMPERATURE 173 17:l DEG F ' ' :-.l!\Lh Vi::LOCT'f Y 0.0 330.2 FPM
:-:. r /\Ch CO2 6. 74 6.50 6.13 7. 21 % CO:' * '..:.TAC.~: o;~ 12. I"/ 11. 5S 12. I 5 12. 51 % o·.• *
:)T /I.CK co I. 8 I. 6 1. 9 2 . :, PPM ' ' .'~f1\C~: co i7% 02 REF) 2.9 PPM ' co 7% ROLLING AVERAGE 2.9 PPM * • C:OM81.JSTTON EFFICIENCY 100.0 100.0 %CE * SCRUBBER TEMPERATURE 1'/:J. 0 1'/3.0 DEG F ' • SCHRIIHBER PH 6.8 6.8 PH
,,11;,,,,.t*~'***''*'''*''***********'*******'*****'**********~*****i*'*'******~**~******
:
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Uf:-S(;RIPTION
,;oc ENGil,EERING
SHELBY. NC
EPA HOURLY REPORT
~IL.N SOI.ii.I WAs·1·E FEED
,ILN TEMPERAll.lRE
r<. I 1 .. N CiRAFi"
'.i:i: iH-IPERATIJRf
sec.% OXYGEN
',•:C OilENC;H TUiAL WATER FLOW
(j, IENCri TEMPERATURE
:;i:(: >lAGHO!ISb DP
',,.~:1iF8EP. fOTAL CAUSTIC FLOW
STA(:K H:MPERA TIJRE
.'..;TACY 1./t:1.0CiTY
STACK (;0/
~~.T /1(;~: li2
cc, j A(:,: (.0
~IAf:K CO 17% 02 REF)
CO 1% ROLLING AVERAGE
UiMt;lhTiijf•i EFFICIENCY
',CRURRER T EMPtRATURE
>,i":KRl.1K~.fk f)H
VALUE
:J. 64
1564
-0.41
1 721
3. 31
0
406
6.32
0
178
668.0
7.2.J
11. 56
1. 9
2.8
2.9
100.0
178.0
6.i3
16:00:01
Tue Apr 30 1991
MIN
0.00
.5. 18
11. 31
1 . 7
AVERAGE
2. 61
1557
-0.49
17 1 7
3.87
40b
5. 92
17 3
392.6
6. 8.J
1 2 . 0 ii
1. 9
100.0
172.8
6.8
MAX
5.88
6.87
·r. 42
I:-:. l 1
2.2
UNITS
TPH
DEG F
IN H:'0
DEG F
% 02
GPM
DtG F
IN H:~1)
llALLO!·~S
DEG F
FPM
% CO?
% 02
f.'PM
PPM
PPM
%CE
DEG F
PH
*
' *
' *
'
'
' *
'
GDC ENGINEERING 17:00:01 • ' :;HELBY. NC Tue Apr 30 1991 f
* FPA HOURLY REPORT * * * • ' ' f OESCRiPTION VALUE MIN AVERAGE MAX UNITS *
* ' nu, SOLID WASTE FEElJ I. 5 I 0.00 2.76 8.00 TPH * ,:]LN TEMPFRATIIRE 1559 1555 DEG F * ' HLN DRAFT -0.49 -0.49 IN H20 * * * • • sec: TEMPERATURE 1715 1718 DEG F * ' sec % OXYGEN 4.25 3. 81 % 02 * f sec QUENCH TOTAL WATER FLOW 0 GPM <
' QUENCH TEMPERA Tl.IRE 406 405 DEG F * ' sec BN,HOUSE OP 6.69 .5. 54 6.07 6.96 IN H20 ' * ' S!:RUHBER TOTAL CAUSTIC FLOW 0 GALLONS * • ' STACr: TEMPERATLIRE 171 172 DEG F * * STACK \iELOCIT'I 494.0 413. 0 FPM * STAO: CO2 6.67 6.54 6.82 7.30 ,, CO2 * ,,
:'.TACK 02 12, '.'1 11. 51 12.03 12,48 % 02 * STACK co I. 9 I. 7 2.0 2.2 PPM * ;;,rAc~: co (7% O'> ,_ REF) 3. 1 PPM ' (:(j 7% ROLLING AVERAGE 3. 1 PPM ' • ' (:C!Mk1iSTION EFFICIENCY 100.0 100.0 %CE * • :,C:RURBER TEMPERATURE 171. 0 172.4 DEG F • ~C:KRi.J88ER PH 6.8 6.8 PH I
1~~,,,, .. ,~'***'******'*****'*****'**************'**************''****~***********•~*~***
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iiF.SC:k i PTION
GDC ENGlNEl'RING
SHELBY, NC
i'PA HOURLY REPORT
>:11.,; 30LID WASH FEED
,, 1 l.N TEMPERATi.JRF
,:lt.N DRAFr
,;cc fEMPERATLJRE
sec% OXYGEN
sec OiJENCH TOTAL WATER FLOW
OilENCH TEMPERATURE
:,.U: 8AGHOUSE OP
,-,CR•iB~,tR TOT AL CAUSTIC FLOW
STAC~ TEMPERATIJRE
:-. f /\i:V, VELOCITY
,'.f AC,. C:O2
s 1 I\Cr. 02
'.-:·iACr. CO
2.TA(:~: CO l 7% 02 REF)
CO 7% ROLLING AVERAGE
COMHIISTION EFFICIENCY
,.CRlil:lBFR TEMPERATURE
:..:.C:KK!.!~81::R PH
VALUE
2. 16
1 i:i96
-0,48
1729
4, 14
0
40f,
6,57
0
171
458,0
/,OJ
12,04
1, 8
2.8
3, 1
100.0
171, 0
6.8
1$:00:01
Tue Aor· 30 1991
MIN AVERAGE
0,00 2.84
1564
-0.51
1718
3,88
405
b.48 t5. ?6
172
4:J 1, 5
6,69 6.89
11, 4:J 12.07
·1. / 1. y
100,0
172. 1
6,8
MAX
5.59
! . 29
7.49
12, :Jg
UNITS
PH
DEG F
IN H20
DEG F
% 02
GPM
DEG F
IN H,._,1-,
GALLON:,
DEG F
FPM
% CO,
~ o·, 'o
PPM
PPM
PPM
%CF.
DEG F
PH
'
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' *
*
*
t
*
t
*
' *
' ' * ' ' ' *
*
' ' * *
*
*
'
'
*
' '
'
'
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•
•
• •
iif:SCR I PT ION
GDC ENGINEERING
SHELBY, NG
EPA HOURLY REPORT
,.ji_N SOLID WAST!' FEED
,. I LN rEMPERATURE
,. I I_N DRAFT
:'.c,: T EMPER/\TI_IRE
sec% OXYGEN
sec QI_IENCH TOTAL WATER FLOW
OIJENCH TEMPERATURE
.0.CC: flAGHOI_ISE OP
~CHi<SBER TOTAL CAUSTIC FLOW
:;TAC,: TEMPERATURE
STACK VELOCITY
STACK CO2
ST AC~; 02
:,TAC,: CO
SiAi.~ CO i7~ 02 REF)
CO 7% ROLLING AVERAGE
COM!o1il'.T ION EFFJClt:NCY
SCRIJBBER TEMPERATURE
:,,:RRI IHfll:H PH
VALUE
2. 70
1627
-0.68
1741
:L 49
0
406
b.94
0
1 7 1
495.0
7.3b
l 1 . 7 2
1. 9
2.9
3.0
100.0
1 71 . 0
6.k
19:00:01
Tue Aor 30 1991
MIN AVERAGE
I. 04 2.73
1590
-0.52
1724
3.94
40h
5.33 6.62
171
488.0
6.62 7 .l14
11. 60 12.00
1. 6 1. ~
100.0
171 .. 3
6.8
MAX
.5. 23
7.24
7.44
12. 46
2. 1
UNITS
TPH
DEC, F
IN H20
DEG F
% 02
GPM
DECi F
IN H20
GALI ONS
DEG F
FPM ~. CO2 ~. 02
PPM
Pf-'f-1
PPM
%CE
DEG F
PH
* • •
*
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* * * •
*
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* * •
*
*
* *
* *
*
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CASE NARRATIVE
Triangle Laboratories, Inc
801-10 Capitola Dr.
Research Triangle Park, NC 27713
[phone]
DATE: May 10, 1991
CLIENT P.O. NO: 1422
TLI NO: 18045
OBJECTIVE: Analysis five of MM5 train samples for naphthalene
METHOD
The XAD cartridges used for sampling were pre-spiked with
100 nanograms (ng) of terphenyl-d14 prior to sampling. The XAD,
filter, and solvent rinse portions of the MM5 train samples were
spiked with 100 micrograms (ug) of phenol-d5 , 1,4-dibromobenzene-
d4, 2,4,6-tribromophenol, and pyrene-d 10 prior to extraction.
The samples were Soxhlett extracted for 16 hours with methylene
chloride. The impinger rinse and condensate portions of the MM5
train samples, if present, were spiked with 100 ug of nitroben-
zene-d5, 2-fluorobiphenyl, 1 ,3,5-trichlorobenzene-d3 , and anthra-
cene-d10 prior to extraction. The samples were then extracted
with methylene chloride using a separatory funnel. All extracts
were combined and concentrated to one milliliter prior to analy-
sis. The semivolatile naphthalene analysis is based on the
guidelines of Method 8270.
The internal standards 1 , 4-d i ch l orobenzene-d , naphthalene-
d8, acenaphthene-d 10 , phenanthrene-d 10 , chrysene-j12 , and peryl-
ene-d10 were added such that the concentration was 40 ug/mL
immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC CONDITIONS:
Column: J&W DB-5, 30m X .32mm X 25micron
film thickness
Program: 40C hold 3 min to 300C at BC/min
hold 4.5 min
MS CONDITIONS:
Instrument: TRI0-1 , Lab Base data system
Scan: 35-510 amu at 1s/scan
Ion Source: 180C
Interface: Capillary 275C
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REPORT
CASE NARRATIVE
Triangle Laboratories, Inc
801-10 Capitola Dr.
Research Triangle Park, NC 27713
[phone]
Included with the case narrative are the chain of custody
sheets, instrument log pages and tracking forms and wet laborato-
ry information.
The data are reported as quantitation reports, chromato-
grams, interim reports, and spectra of detected compounds. The
quantitation report header describes the sample and calibration
injection ID, 'data file' and 'RF file' respectively. The sample
name, dilution factor, TLI project number, date of report, and
analysis date are also listed in the quantitation report header.
The raw areas and scan numbers found on the quantitation report
are from the interim report. The RF is from the continuing
calibration. All initial and continuing calibration data is
located in the back of the data package. The !SID is the inter-
nal standard identifier. Those compounds matched to naphtha 1 e-
ne-d 8, for example, are flagged with !SID number 14. The
amounts for the target compounds are reported in ug. The sample
calculations are listed below in the Sample Calculations section
of the narrative. If the target compound is detected, a code of
'D' is reported. If the target compound is detected but the
amount is below the quantitation limit, a code of 'E' or estimat-
ed is reported. If the target compound is not detected, a code
of 'ND' is reported. Amounts reported for target compounds that
are not detected are calculated using an area of 20 counts.
Compounds flagged with the code 'IS' are internal standards.
RESULTS
As noted in the METHOD section, the XAD cartridges used for
sampling were pre-spiked with terphenyl-d 14 at a level of 100
nanograms. This level is too low to be observed by Method 8270.
No recovery information is given for this surrogate. Also noted
is the fact that the surrogates nitrobenzene-d 5 , 2-
fluorobiphenyl, 1,3,5-trichlorobenzene-d3 , and anthracene-d 10 were added only to those samples that contained impinger and
condensate portions, i.e. samples MM5-2, MM5-FB, and the labora-
tory blank SBLK 05/01/91. No recovery information for these
surrogates is listed for the AUDIT samples.
The majority of the surrogate recoveries were normal in the
naphthalene analysis, although the recovery of nitrobenzene-d5 was lower than normal in the MM5-FB sample. All other surrogate
recoveries appear normal for the MM5 train matrix.
There was a large amount of naphthalene in the laboratory
2
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CASE NARRATIVE
Triangle Laboratories, Inc
801-10 Capitola Dr.
Research Triangle Park, NC 27713
[phone]
blank and in the samples MM5-2 and MM5-FB. In all cases the
amount of naphtha 1 ene exceeded the ca 1 i brat ion range in a 11 of
the samp 1 es. Naphtha 1 ene is a known component of both the XAD
resin used for sampling and the methylene chloride solvent used
for extraction. Naphthalene should not be considered truly
present in either of these two samples since the level of naph-
thalene in the samples does not exceed the level of naphthalene
in the laboratory blank by a factor of five, the QC control
limit.
As requested on May 10, 1991, all AUDIT samples are being
reprocessed and a 11 ana 1 ytes on the Method 8270 Table 2 ana 1 yte
list will be reported. IEA will be notified when this data is
ready .
3
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CASE NARRATIVE
Triangle Laboratories, Inc
801-10 Capitola Dr.
Research Triangle Park, NC 27713
[phone]
SAMPLE CALCULATIONS
Response Factor, RF:
RF= (Area X * Amount Int Std)
(Area Int Std* Amount X)
Amount in samples, ug:
Amount, ug =
where:
X = Analyte
(Area X * Amt Int Std* OF)
(Area Int Std* RF X)
Int Std= internal standard
Amt Int Std= amount of internal standard= 40 ug
RF X = response factor of X from the continuing calibration
OF= dilution factor
L{\__~ '-~ &-
Nancy Bragg
Report Generation Manager
4
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TRIANGLE LABORATORIES, INC.
801-10 Capitola Drive DATA FILE:F0427 SAMPLE ID MMS-AUOIT A
Reeearch Triangle Park, NC 27713 RF FILE: F0422 OILN FACTOR
Telephone: [phone] DATE: 05/09/91
TLI Project Number: 18045
ANALYSIS DATE: 05/08/91
Q U A N T I T A T I O N R E P 0 R T TLI ID: 43.212,1
-----------------------------------------------------------------------------------------------------NAME AREA RF SCAN ISIO AMOUNT, ug CODE QUAN LIMIT
-----------------------------------------------------------------------------------------------------
1,4-0ichlorobenzene-d4 503 249 IS
14 Naphthalene-de 1277 461 14 IS
23 Naphthalene 115 • 8870 464 14 4.07 E 10
28 Acenaphthene-d10 1075 771 26 IS
47 Phenanthrene-d10 2364 1026 47 IS
57 Chryeene-d12 2384 1488 57 IS
64 Perylene-d12 2258 1690 64 IS
------=---========================-===========================================================================
S U R R O G A T E SUMMARY AREA RF SCAN ISIO AMOUNT CODE ~ RECOVERY
--------------------------------------------------------------------------------------------------------------
74 Terphenyl-d14 0 . 7391 0 57 .00 NO .o
75 Phenol-d5 · 912 1. 4249 229 50.95 D 50.9
11 2,4,6-Tribromophenol 202 .0979 914 28 76.71 0 16.1
81 1 ,4-D1bromobenzene-d4 390 .7385 469 42.01 D 42.0
84 Pyrene-d10 5294 .9979 1274 57 89.00 0 89.0
CODES: NO= Not Detected; O = Detected; E = Eetimated; IS = Internal Standard
I.
••
00-05-91 15:21
Sample:HH5-AUDIT A
FD427
100
XFS
0 Min '
2 9
l . . ! . ' 5.0
18045
4,2
' .,.
' ' 10.0
•
Triangle Labs, Inc. ·
1274
10.!7
7''1
9 5
1113
~ J,
' ' ' ' 15.0 20.0
•
1~88
' ' ., ' 25.0
[phone]
Instrument F
1690
'
454890 C 1 TI
ti
' 30.0
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0
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?.iif /9~J/9f"li
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QJ
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.-··r;,,_,,:, ~~i .. ,\.::. :.:i!··,f.:.r1c.11
! )-··-:\) :i.. ·t:.1r• DS) c::i,:) :.L ~-:, :··1E;i·: '/ J t't.lfi 5.. :": E·
.(+·-· Hr·c,mc:;n!··!•.'~-:•!·-,\_, \-··;.:·,r:'.·:-::·r:\' ::. E•-1.'
.:1. ;~:, ;:::, I'.\.· r,, :-··: i::-:-:· --
149 Di-r1--c:tvlohtl1aiate
~~:~:_;2 t:_i'='n z ,;:::, ( t:1 > ~: l u·::::: :,·· ~(fI t. hen F::
,::;:, :···; ;:-.: c.: ( i-·: ) -f . : , )' , , ·•.:. t·, ,:-:? n ,,·.:·
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••
08-05-91 15:27
SaMple:HH5-AUDIT A
FD427 464 (8,734)
100· 1 8
XFS <l 4
68 77 127,
0 I I ~ I
18045
150 '
FD42?'464 (8.734) REFINE
100· 1 8
XFS·
-:J"'.-.r Triangle Labs, Inc.·
200 ' 250 300 '
150 ' 200 ' 250 ' 300 '
CLP2 26 (9.034)
100-
XFS·
Naphthalene
1; 8
350 ' 400
350 ' 400
[phone]
Instrument F
4288
' 450 ' 500
4288
' 450 ' 500
FIND
100
6375 127, 129
51 / / 11jt2 / 0.J,..,..;~,'1,...-'+-......,,i---...~~..,....~-,--........,~......--..,..~..,.....~~.....,.~--r~...,....~,-.-,~ ................ ~....,...~-r--o
M/z 50 ' 100 150 , 200 , 250 , 300 , 350 400 ' 450 500
• -• ••
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14
23
28
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TRIANGLE LABORATORIES, HIC.
801-10 Capitola Drive
Research Triangle Park, NC
Telephone: [phone]
Q U A N T I T A T I O N
27713
DATA FILE:F0428
RF FILE: F0422
DATE: 05/09/91
SAMPLE IO
OILN FACTOR
TLI Project Number: 18045
ANALYSIS DATE:
R E P O R T TLI IO: 43.212.2
HMS-AUDIT 8
05/08/91
======-----=--===========---=-==============----===============-------=============----=-----========
NAME AREA RF SCAN ISID AMOUNT, ug CODE QUAN LIMIT
-----------------------------------------------------------------------------------------------------
1,4-Dichlorobenzene-d4 391 248 IS
Naphthalene-dB 1163 461 14 IS
Naphthalene 0 .8870 0 14 . 77 ND 10
Acenaphthene-d10 964 771 28 IS
Phenanthrene-d10 2172 1026 47 IS
Chrysene-d12 2178 1487 57 IS
Perylene-d12 2111 1690 64 IS
========================================================================-==================-=--===============
S U R R O G A T E S U M M A R Y AREA RF SCAN ISID AMOUNT CODE % RECOVERY
--------------------------------------------------------------------------------------------------------------
74 Terphenyl-d14 0 • 7391 0 57 .00 ND .0
75 Phenol-dS 701 1.4249 229 1 50.30 D 50.3
77 2,4,6-Tribromophenol 205 .0979 914 28 87.D8 D 87 .1
81 1,4-Dibromobenzene-d4 241 .7385 469 1 33.36 D 33.4
64 Pyrene-d10 4766 .9979 1274 57 87.73 D 87.7
CODES: t-1D = Hot Detected; D = Detected; E = Eetimated; IS= Internal Standard
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08-05-91 16:08
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TRIANGLE LABORATORIES, INC.
801-10 Capitola Drive
Reeearch Triangle Park, NC 27713
Telephone: [phone]
DATA FILE:FD429 SAMPLE ID
RF FILE: F0422 OILH FACTOR
DATE: 05/09/91
TLI Project Number: 18045
ANALYSIS DATE:
Q U A N T I T A T I O N REPORT TLI ID: 43.212.3
MM5-AUOIT C67
05/08/91
===========================================================================================--=----=-=
NAME AREA RF SCAN ISID AMOUNT, ug CODE QUAN LIMIT
1,4-0ichlorobenzene-d4 376 249 IS
14 Naphthalene-dB 1132 481 14 IS
23 Naphthalene 0 .8870 0 1 4 .80 ND 10
28 Acenaphthene-d10 953 771 28 IS
47 Phenanthrene-d10 2204 1026 47 IS
57 Chryeene-d12 2206 1,,187 57 IS
64 Pery1ene-d12 2080 1689 64 IS
==============================================================================================================
S U R R O G A T E SUMMARY AREA RF SCAN ISID AMOUNT CODE • RECOVERY
--------------------------------------------------------------------------------------------------------------
74 Terphenyl-d14 0 .7391 0 57 .00 ND .0
75 Phenol-d5 653 1.4249 229 48. 74 D 48.7
77 2,4,6-Tribromophenol 183 .0979 914 28 78.37 D 78.4
81 1,4-0ibromobenzene-d4 370 .7385 469 53.22 D 53.2
84 Pyrene-d10 4599 . 9979 1274 57 83.56 D 83.6
CODES: ND::: Hot Detected; D::: Detected; E::: Estimated; IS::: Internal Standard
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08-05-91 16:49
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18045
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TRIANGLE LABORATORIES, INC.
801-10 Capitola Drive
Research Triangle Park, NC 27713
Telephone: [phone]
DATA FILE:F0430 SAMPLE IO MM5-2
RF FILE: F0422 DILN FACTOR
DATE: 05/09/91
TLI Project Number: 18045
ANALYSIS DATE: 05/08/91
Q U A N T I T A T I O N R E P O R T TLI ID: 43.212.4
=-========================-------------------------=----------------------------=-===================
NAME AREA RF SCAN ISIO AMOUNT, ug CODE QUAN LIMIT
1,4-Dichlorobenzene-d4 351 249 IS
14 Naphthalene-dB 1037 464 14 IS
23 Naphthalene 14648 .8870 469 14 637.24 0 10
28 Acenaphthene-d10 1034 771 28 IS
47 Phenanthrene-d10 2684 1027 47 IS
57 Chrysene-d12 2836 1488 57 IS
64 Perylene-d12 3247 1690 64 IS
------========================================================================================================
S U R R O G A T E S U M M A R Y AREA RF SCAN ISIO AMOUNT CODE X RECOVERY
--------------------------------------------------------------------------------------------------------------
72 Nitrobenzene-dS 362 • 5101 461 14 27.36 0 27.4
73 2-Fluorobiphenyl 1767 .9220 668 28 74.17 0 74.2
74 Terphenyl-d14 0 .7391 0 57 .00 NO .0
75 Pheno1-d5 870 1. 4249 230 69.63 0 69.6
77 2,4,6-Tribromophenol 210 .0979 915 28 82,80 0 82.8
81 1,4-Dibromobenzene-d4 620 . 7385 472 95. 77 0 95.8
82 1,3,5-Trichlorobenzene-d3 668 .4254 404 14 60.59 0 60.6
83 Anthracene-d10 3958 .4874 1035 47 121.04 0 121.0
84 Pyrene-d10 5290 . 9979 1274 57 74.76 0 74.8
CODES: NO= Not Detected; 0 = Detected; E = Eetimated; IS= Internal Standard
I,
08-05-91 17:29
Sa~ple:MM5-2 18045
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FD430 469 (8.817)
100
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200 ' 250 . 300 ' 350 .
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100 1 8 100
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TRIAHGLE LABORATORIES, INC.
801-10 Capitola Drive
Reeearch Triangle Park, NC 27713
Telephone: [phone]
DATA fILE: FD431
RF FILE: F0422
DATE: 05/09/91
TLI Project Number:
ANALYSIS
SAMPLE ID MMS-FB
DILN FACTOR
18045
DATE: 05/08/91
Q U A N T I T A T I D N R E P O R T TLI IO: 43.212.5
=========================---------=-===========================----==================================
NAME AREA RF SCAH ISID AMOUNT, ug CODE QUAN LIMIT
1,4-Dichlorobenzene-d4 393 248 IS
Naphthalene-dB 1141 462 14 IS
Naphthalene 4081 .8870 466 14 181.34 D 10
Acenaphthene-d10 1004 771 28 IS
Phenanthrene-d10 2578 1027 47 IS
Chrysene-d12 2472 1487 57 IS
Perylene-d12 2422 1690 64 IS
• ==---===-==-======================----------============================----------============================
S U R R O G A T E SUMMARY AREA RF SCAN ISID AMOUNT CODE ·x RECOVERY
--------------------------------------------------------------------------------------------------------------
72 Nitrobenzene-d5 141 . 5101 462 14 9.67 D 9.7
73 2-Fluorobiphenyl 1618 .9220 867 28 69.90 D 69.9 • 74 Terphenyl-d14 0 .7391 0 57 .00 ND .0
75 Phenol-dS 856 1. 4249 229 61.23 D 61. 2
77 2,4,6-Tribromophenol 133 .0979 915 28 54. 12 D 54, 1
81 1 ,4-D1bromobenzene-d4 539 .7385 469 74.34 D 74.3
82 1,3,5-Trichlorobenzene-d3 723 .4254 403 14 59.81 D 59.6
83 Anthracene-d10 3890 . 4874 1035 47 123.86 D 123.9
• 84 Pyrene-d10 4837 .9979 1274 57 78.45 D 78.4
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08-05-91 10:10
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Sa~ple:MM5-FB 18045
FD431 466 (8.767)
100 1 8
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100· 1 8
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Triangle Labs, Inc:
200 ' 250 300 ' ' ' 350 400
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450 500
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TRIANGLE LABORATORIES, IHC.
801-10 Capitola Drive
Research Triangle Park, NC
Telephone: {919) 544-5729
Q U A N T I T A T I O N
27713
DATA FILE:F0426 SAMPLE IO
RF FILE: F0422 DILN FACTOR
DATE: 05/09/91
TLI Project Number: 18045
ANALYSIS DATE;
R E P O R T TLI IO:
SBLK 5/01/91
05/08/91
======--=============================================================================================
HAME AREA RF SCAN ISID AMOUNT, ug CODE QUAN LIMIT
-----------------------------------------------------------------------------------------------------
1,4-0ichlorobenzene-d4 457 249 IS
Naphthalene-dB 1462 463 14 IS
Naphthalene 16974 .8870 469 14 523.66 D 10
Acenaphthene-d10 1328 771 28 IS
Phenanthrene-d10 3073 1027 47 IS
Chrysene-d12 2922 1488 57 IS
Perylene-d12 3033 1690 64 IS
---============----===============---=========================================================================
S U R R O G A T E SUMMARY AREA RF SCAN ISIO AMOUNT CODE % RECOVERY
--------------------------------------------------------------------------------------------------------------
72 Nitrobenzene-d5 443 .5101 461 14 23.77 0 23.8
73 2-Fluorobiphenyl 2063 .9220 667 28 67.39 0 67.4
74 Terphenyl-d14 0 • 7391 0 57 o.oo NO a.a
75 Phenol-d5 806 1.4249 229 ., 49.49 0 49.5
77 2,4,6-Tribromopheno1 227 .0979 914 28 69.82 0 89.8
81 1,4-0ibromobenzene-d4 310 .7385 471 36.75 0 36.7
82 1 ,3,5-Trichlorobenzene-d3 685 .4254 404 14 44.09 0 44.1
83 Anthracene-d10 s, 86 .4874 1035 47 138.48 0 138. 5
84 Pyrene-d10 6525 .9979 1274 57 89.51 0 89.5
CODES: HD= Not Detected; 0 = Detected; E = Estim::i.ted; IS= Internal Standard
-
08-05-91 14:50
Sample:SBLK 050191
FD426
100
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·d !:... ;iJ +' L
J_:
(Cl q· ;_:_; GJ '-: · f"-_; :...:s, ·T
L .
r.l-
-· ,j_• Li
·_;_·
fli ;l1 ,,, +1 tli C
I
1J .--! ,....., ....
j )-'-i-'+· Ll
Qi+'
'--U 1.-:; .::::·
;ii -,
,--! L iJ u , .. >-r-;
I -, .. ·,-! !i.J ;J!
::::i Cl".i ;.i.,
~-r--
Q; '.Li
L
,,
-:t· re -,_, i• -r··-c-j-s ... ,.:,_, <i •!J <j" \{':; L·,
rl :>~ C--i
•
;_:,• tJ ,Si ,S -(i '.;J rS! ;s: -~-
(:-_r" rr··
L(l
Li
.,,j-· <.t·
fc~;
!9 ~-:, :.S, S (0 C-1 I·· "..::i· t"9 G !'...'J GJ G r:;:
U'·
,:s ,~: @ D in ,., 8 r--.;-i t:J o 0 8 s., r·-J r·-~ 1--n::: r---. ·-G re!
CCi Ci"·
-Ci
• • • • • .. -
-
08-05-91 14:50
Sample:SBLH 050191
FD426 469 (8.817)
100· 1 8
1/.FS ·
100 1, 8
102 127 129 5164 \. '•/
18045
.:;,..1
Triangle Labs, Inc. [phone]
Instrument F
409600
401408
0 I -ii ,. 87 ,I
150 ' 200 250 300 ' 350 ' 400 ' 450 ' 500
CLP2 26 (9,034)
100·
1/.FS ·
Naphthalene
1 8
6375 12~_ 129 _
FIND
1130
51 / / 11i12 / , 0 ....... ~......_-......,.._...~ ........... ...,......~~-~.........-~......,...~,.,..-~-,-~-~~-r"'--,-....~~___...,.~...-,-~..-,.--
M/z 5°0 100 150 • 200 250 ' 300 ' 350 , 400 ' 450 , 500
-• • • • • • -..
I
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I
1
Mr. Hike White
IEA, Inc,
PO Box 12846
Research Triangle Park, HC 27709
Dear Mike,
P 02
Mny 8, 1991
Following is an interim analysis report for the quick-
turnaround multi-metals analysis •
Sample ID:
lA = P'ilter Paa 2A ~ Blank Filter Pad
ill = Probe Rinse 2B = Blank Probe R!nse
wan11 al>'-Impinger 2C Blnnk Impinger
/1~ I e,,, IP
Concentrntions, ppm Total trapped, ug
l.A+lB l.C+lD 2A+2B 2C lA+lB lC+lD 2A+2B 2C
1'ntimony 2.2 <0.25 <0.25 <0.25 757 <460 <27 <54
Arsenic <0.25 0.58 <0.25 <0.25 <86 1070 <27 <54
Chromium 0.03 O.l.6 <.02 0.024 10.J 332 < 2 5.2
Volwme(m.l)
Analyzed 102 50 l.00 50
Volume(ml)
Received 344 1843 109 216
The analyses were performed according to the EPA Draft Method:
Metnooo1ogy tor determination of Metals Emissions in Exhaust GQses from Ha;:ardous waste I.ncineration an(I similar combustion Processes.
All volumes used to ootain the reported data ore inc:tuded o;n
r-·~r• 1~--"~'"'"'·~?·... 'J\:;it2.!. t:ru.ppect amounts are calculated from the
.-~;ncer,tt"-Ht..1 OT'Jf; f.H'.1<.l 'tfOlmnes.. F:Ll ter ~nan trt"id 5:.:.•i·i::.;:.~ .::iT:r; ~~~:-... ~
i:'-:.:•~J.t~.'-.!'i~<l 2-~ out;...J..io.\~J. i~""i t.i.:.~ tuet~,.ud priol._. to anal yGiC..;,
··-··--· -· ···-···--------------------~
ll01-1D Cnp/tu/e O,lvc
Durham, NC2i713
(,19-544-5729
Yri8"flle Lal>orltlOrle•, Irle.
P.O. Bo,: 13485
R,,,.,,,,,r;1, Trmng/t, 1',vh; NC :Q709
Fax II 919-544-5491
'
1
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I
P 03
peige 2
Data ~ere obtained under at least the quality controls that are outlined in the method. AluminWII and iron ware scanned prior to analysis, and no spectral· interferenc,es were indicated. The final solutions were spiked as follows:
Practical A2 AJ Quantitation Lim.it
Ae Spi.lc;e :z ppn 0.625 ppm 0.25 ppm t Re=v. l.02 " 951
Sb Spike 2 ppm 0.625 ppm 0.25 ppm I Recov. 96 ' 94%
er Sp:IJu, 0.04 ppm 0.25 ppm 0.02 ppm % Recov. ll3 t 96%
Ir you require any additional information or clarification, please call me .
sincerely,
lJ/tfJ,,~
William R. Nadlin Inorganic Lab Manager
/Ocl\-~ ~4,.-' Data Sheet : !EA samples 12-A--7-+-,pt : 01 Order # : 9105038 Lab Due Date : 05/08/91 ·oject # : 1133_010 Client : llll Name : !EA-Air Dept. lrest fraction/Results uni ts Book/Page Comment Protocol CR_Ol I~ <::'.'..o,o3 mg/L S'-B-'i I ~l':'..(t:c.t) , !S~ r~s-1 ly.{ ZO,C) mg/L l .CR_02 ,,o.i4 ..:28 mg/kg MF (ref) ·5_ b-1-1 I e.M fd.')_-s o_H( :;i. 0 mg/kg \J,, i ,,,,, / $:1..11 (3o3cJ S-}-'\\ l}o.l½,Y-, PB _01 ft1! <:0,005 i'g/L ill ~2. µ-< ~o.ooS mg/L ~ • lfo PB_02 ,Q.3A( mg/kg / 5. '1 .. ' ..., )YA ~/kg SB _01 w< ~ o. :+.0 mg/L 5-8--41 iR.R(IC~) e,"~ /~ 1-, • !.24 <a.~o mg/L \l,-i SB_02 __93,(( d-dD mg/kg M F(:r:.cP·l s-6-'i1 ~ R9o mg/kg ~L .WHY OVA No Results ef-A No Results 10-ir No Results .,,,,.--· ,12-A llQ Results .INF _01 O.l-A No Results ,,. No Results OJ•'A INF _03 Ol'if 110 Resul1_s • or:i( No Results INF _04 OH( No Results . 01'·A \ . 110 Results As. it(:<O, 00 5 ~/l ( '1,"' ) S' -8 -'11 '/?q_kfl. I;, 3-< • €1 ·re1->lilo J~o .. oat; As r--.~IL ~) ,.,~~: ;). ). ~!~ twJ /K1 ' t\<; .'.:';! , I. 8
• Data Sheet Ot 03 Order I 9105038 OJeCt I !l33_010 ~est Fraction Resu Its uni ts INF JS O!·A llo_Re_s~!ts_ OS·A 110 Results • !4·A 110 Resu Its lS·A 110 Results !6·C No Results GCS 01 OS-A .;l<i(oo • -.(ttSM~~~-.-p~.-p-.~0~000-~11 14-A < I<> !S·A 16-A --< ~10 -CS 02 OJ-A < 10 -f. ( c I M~~ DP,lLt, Io GCS_BI OJ-8 No Result:; _,cs _s2 CMP _03 • vs _03 • • ' 16-8 No Results 16-C No Results !)·A No Results 18-A llo Results 19-A llo_fesuJ ts l l ·A No l{_esu I ts 13-A 110 Results ~-~ ...,.i:t ~l . -noa,ikg ~ !EA Samples Lab Due Date OSiDBi91 Client 1133 Name !EA-Air Dept. BookiPage comment Protocol ___ e~)c 7J~ ,s ... ~.q•·~ ~I / t_ scCCl .u., / :s1n111!, ~-\. --I ' \; ~ , \,_\, ~=o;,~r,, )b-1~' ' ,1, / OSi06i91 OS/06/91 OS/06i91 OSi06i91 OSi06/91
• Data Sheet !EA samoies
'Pt : 02
Order i 9105038 lab Due Date : OS/08/91
·oject I 1133_010 Client 1133
Name : !EA-Air Dept.
-~est fraction Resu I ts Uni ts BooK/Page Comment Protocol
Cl_02 04 · A (l. mg/Kg "1/l' ;o;,D I sl"6(11 AM
INF _OS 04-A No Resu1ts
•
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•
1
IEA Project No.:
Matrix:
IEA
REF. NO.
lls3.OI0 .. l
1\~3 (;lu .. 7
j /32 .OI0-7
ANALYSIS
DATE
-S-b-'H
S -~-'ii
S" -f/··'11
SA= Spike Added
SR= Sample Results
TEST
PARAMETER
' ... I:::·,'--
'. _,\.G)
SSR = Spike Sample Results
Corresponding Samples:
FORM QCSPK Rev 082890
INORGANIC QC SUMMARY
SPIKE RESULTS
SPIKE RESULTS
SA SR
~o '.:I 0
·oo
~."Z. ti=
INTERNAL
(mg/~
CONTROL
LIMITS
SSR %R
5~ 70~·.,, -+ ?S"?o -
~ :,/0 ~ .:l 5 '7.
<::~ i :)s:
\
%R = (SSR -SR)/ (SA) • 100
Spike Source:
Lot No.:
I
•
•
•
IEA Project No.:
Matrix:
IEA
REF. NO.
ANALYSIS
DATE
l\)'?,_c:,IO_lc S-2i-"\\
i)"!i:'> \l(Q_(D 5-~-'J\
I 5 ·1 010. IO s:: -8-'i I
SA= Spike Added
i\33-\o_JV
! ·---~.-:.:.
TEST
PARAMETER
• SR= Sample Results
SSR = Spike Sample Results
•
Corresponding Samples:
•
• FORM QCSPK Rev 082890
'
INORGANIC QC SUMMARY
SPIKE RESULTS
SPIKE RESULTS
SA SR
<0,03
<'O, :::>.O
<'.'0, Cc;',
INTERNAL
CONTROL
(mg/L) LIMITS
SSR %R
-M 9':i ::;:iS"7,
147 5:1 ::;:;i '5" 17.
_{l, 01~ ~,-clS"l.
' ' '
%R = (SSR -SR)/ (SA) • 100
Spike Source
Lot No.:
I
•
•
•
IEA Project No.:
Matrix:
IEA
REF. NO.
i\)"Lo(()-3
I\}:, o\C-3
113) ~ (1\ /)_)
ANALYSIS
DATE
SA= Spike Added
i [ 3'.>_0l o....:::~
~--' '
TEST
PARAMETER
._. SR = Sample Results
SSR = Spike Sample Results
•
Corresponding Samples:
•
• FORM QCSPK Rev 082890
'
INORGANIC QC SUMMARY
SPIKE RESULTS
SA
SPIKE RESULTS
SR
(mg/j<~
ss!t
(, ~
'3,:),0
f?. ':l
%R
7A.f;e;
/f1f) ::z 'j
INTERNAL
CONTROL
LIMITS
~s ff/,
;;is "7.. ;;is er;.
%R = (SSR -SR)/ (SA) * 100
Spike Source
Lot No.: -
•
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•
•
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•
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rn
IEA Project No.:
Matrix:
IEA
REF. NO,
II ~~-C\0_\a,
I Ir? ·-C\O_( ~
I\ ~·Lo\o.-\ ~
ANALYSIS
DATE
s -B-"1\
5-£·..<\\
<,:..'ij-'t I
SA= Spike Added
SR= Sample Results
TEST
PARAMETER
SSR = Spike Sample Results
Corresponding Samples:
FORM QCSPK Rev 082890
INORGANIC QC SUMMARY
SPIKE RESULTS
SPIKE RESULTS
SA SR
<D,0'3
f:Q.~0 ...:.o.uQS°
INTERNAL
CONTROL
(mg/L) LIMITS
SSR %R !
O. I~ "s :::i.5 '1 °
o.~J :l~ ;;is:: CJ?.
('.),o3 z '.1.14'/:' ~s <:!l,
%R = (SSR -SR)/ (SA) * 100
Spike Source
Lot No.:
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GC/MS PURGEABLES
SW-846 METHOD 8240
IEA Sample Number: /133-LO·{
Sample Identification:
Date Analyzed:
Number
l
2
3
4
5
6
7
8
9
10
11
12
13
14
15
1.6
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
Compound
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloramethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chlorornethane
1,1-Dichloroethane
~~2-Dichloroethane
1,1-Dichlaroethene
1,2-Dichloroethene (total)
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
·4-Methyl-2-pentanone
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
Comments:
BQL Below Quantitation Limit
By:
Quantitation
Limit
(ug/L)
100
5
5
5
10
100
5
5
5
5
lQ ..
10
5
10
5
5
5
5
5
5
5
5
50
5
50
5
5
5
5
5
5
5
50
10
5
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL · . m 'o-&--,_ dJ\~
BQL,,-
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL O nw o
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
· BQL
BQL
•
I
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•
•
•
•
'
GC/MS PURGEABLES
SW-846 METHOD 8240
IEA Sample Number:
Sample Identification:
Date Analyzed:
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
Comments:
compound
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Dibromochloromethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
1,1-Dichloroethane
~,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene {total)
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Et.hylbenzene
2-Hexanone
Methylene chloride
4-Methyl-2-pentanone
Styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl acetate
Vinyl Chloride
Xylenes (total)
BQL Below Quantitation Limit
By:
Quantitation
Limit
(ug/L)
100
5
5
5
10
100
5
5
5
5
10.
10
5
10
5
5
5
5
5
5
5
5
50
5
50
5
5
5
5
5
5
5
50
10
5
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
I
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GC/MS PURGEABLES
SW-846 METHOD 8240
IEA Sample Number: I /33-m
Sample Identification:
Date Analyzed:
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
1.6
17
1B
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
compound
Acetone
Benzene
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
carbon disulfide
carbon tetrachloride
Chlorobenzene
Oibromochloromethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
1,1-Dichloroethane
~,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethene (total)
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Methylene chloride
·4-Methyl-2-pentanone
styrene
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Vinyl acetate
Vinyl chloride
Xylenes (total)
Comments: .f,-1 tt.hQhfc.,:. OSof(;,03
BQL Below Quantitation Limit
By:
Quantitation
Limit
(ug/L)
)
100
5
5
5
10
100
5
5
5
5
lQ.
10
5
10
5
5
5
5
5
5
5
5
50
5
50
5
5
5
5
5
5
5
50
10
5
Results
concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
I
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BASE/N"EtlTRAL EXTRACT;\BLES
SW-846 METHOD 8270
IEA Sample Number:
Sample Identification:
Date Extra=ed:
Date Ana.l.y:z:ea:
l
2
3
4
5
6
7
8
9
10
ll
12.
l3
14
15
16
17
18
19
20
21.
22
23
24
25
26
27
28
29
30
31
32
33
34
JS
36
37
38
39
C0mp0un'1
Aeanaphthana
Acenaphthy.l.ena
Anthracena
Bea.:o(a)anthracena
BeJ1%0(b)fluorantllene
Ban:o(k)fluoranthene
Bea.:o(g,h,i)pery.l.ene
Benzo(a)pyrcne
8ea.:y .l. a.l.cobo.l.
bU(2--Cllloroeciioxy)metllane
bu(2--Cblaroethyl)etbar
bb(2--Cllloro1aopropyl)etber
bb(2-&thyl.haxyl)phthalate
4-Bromaphanyl phanyl etller
Bea.:y.l. bucyl phth..uate
4-:CbJornsnilfne
2-chloronaphtbalene
4-cb.lorophenyl phenyl ether
Chryaene
Dil>anzo(a,h)lliltbracana
Dlban:oturan
Di-n-butylphthalata
1,J-DlchJ.orctJenzena
1,4-Dichlorobanzena
1,2-D1.chlcrobanzena
3,3'-Olc:hlcrobenzicil.ne
Diethyl phthalate
Dimethyl phth..uata
2, 4-0lnltroeo.l.uana
2,6-Dlnltroto.l.uena
Di-n--oct:ylphtha.J.ata
Fluora.nthena
Fluorene
Haxachlcrobenzene
Haxachlorcbutadiene
Baxacnlcrcc:yclopentadiene
aexachloroethane
Indeno(l,2,3--cd)pyrene
Isophorone
FORM 8270B (l) Rev. 060689
By1
Quan citation
LJ.mi.t
(ug/kg)/~
. Js,o
Raau.l.ts
concencracic:i
(ug/,r &tk
IIQL
IIQL
IIQL
IIQL
IIQL
BQL
BQL
BQL
IIQL
IIQL
IIQL
IIQL
IIQL
IIQL
IIQL
BQI.
BQI.
BQI.
BQI.
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SQL
SQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
•
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BASE/N"EllTRAL EXTRACTABU:S
SW-846 METHOD 8270
IEA sample Number:
samp~e Idant~ficatian:
Date Extra=ed:
Date Analyzed:
,, -~,_._ ,..,._ ·~v, -:-:;._; -_r
Number ccmpaun.d
l Acanapbtha.aa
2 Acan4pbthylena
3 Aut,hracena
4 Ben.zc(a)antnracena
5 Ben.zc(b)fluoranchana
6 B11Ul%o(k)flucran=e
7 Banzo(g,b,i.)peryiena
B Banzo(a)pyrena
9 Benzyl aicchol
10 bJ.a(2-ch.l.orcedlcxyJmathana u bJ.a(2--Cblorn...:llyl)ethar
u. bJ.a(2-ch.l.oroiaopropyl)atbar
l3 bia(2-Etbylhal<yl)phtbaLl.ta
l4 4-Brcmopbanyl phanyl ether 15 Banzy l butyl plithalata
16 4J'bJoroan111ne
17 2-ch.l.oron.apbtbalena
18 4-Chlorophanyl phanyl ether 19 Cllrysena
20 01.bonzo(a,b)antbracana
21 Dll>anzoturan
22 01-n-butyiplitilalato
23 l.J-01ch.lorooenzana
24 l.4-01chlorcbenzena
25 l,2-Dlclllorcbaozena
26 3,3'-D1cblorobanzid1no
27 D1at11yl pbtbalate
28 Oimac..b.y l plithalata
29 2,4-0l.n.l.trotoluane
30 2,6-Dl.n.l.trotoluene
31 01-n-octylpbtbalata
32 P'luoranthena
33 Fluorene
34 Baxachlorobanzene
JS Haxachlcrobutadieae
36 Hexacnlorocyclopentadiene
37 Baxachlorcethane
38 Indeno(l,2,3-cd)pyrene
39 rsopnorcne
FORM 8270B (l) Rev. 060689
Byt mCi(;£.. '
Quanti.taticn
Limit
(ug/kgy'~
3qo
'Y
1eo
3?o
1
90
Ra■ults
Concancrac:l.cn
(ug/~&/h..-
BQt.
BQt.
BQt.
BQt.
BQt.
BQt.
BQt.
BQt.
BQr.
BQr.
BQr.
BQt.
BQL
BQr.
llQt.
!!QI:.
BQL
!!QI:.
BQL
BQL
BQt.
BQL
BQt.
BQL
BQL
BQL
BQI.
BQL
BQL
BQL
BQI.
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
•
:
•
•
•
•
•
•
•
BASE/NEUTRAL EXTilACTABLES
SW-846 METHOD 8270
IEA Sampi.e Num.ber:
samp~e Idancifica~icn:
Date Extrac1:ed:
Date Arul.l.y:z:ed:
Number
~
43
44
45
46
47
48
49
50
compound
2-Hat.b.ylnap.b.tllai.ene
ll'&pht.b.alana
2-Hit.rt'!anj J 1 ne
3-Hi.troanilina
4-ffitrcan; J 1 na
Ni.t:rc.be=ane
N-Hi.troso-di.-n-~ropylamina
N-Hi.troeodi.phenyla.au.na
Pbanant:hrana
Pyrene
1,2,4-Tri.chlorooen:z:ene
By1
Quani:1tat1on
LJ.m..i.t
( !UJ/kJ:; >/ tJ,JJ ,__
,:.. 3to
Ho
lqSD ,,~
rt5"1:>
r '3~o
Raa11i.te
concan1:ra1:1on
( WJ/kr;, / b1i1-,...
BQL.
BQL.
BQL.
BQL..
BQI..
BQr.
BQI..
BQr.
BQr.
BQI..
BQL.
(iJ,(w,.,b_{k.1...__ :'.,.,r,0s:? ''«fw&J! (!' i I nClt1<-,-l(. . comrnen .. .,, ):>rs 'f<tp,,•\ Aio.r-i,~1 SOL Balow Q11an1:ita1:1on LJ.ml.t
FORM B270B (2) Ra,r. 060689
• rn
•
•
•
•
•
•
•
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number:
Sample Identification:
Date Extracted:
Date Analyzed:
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzoic acid
Benzo(a)anthracene
Benzo(b)fluoranthene
_Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzyl alcohol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Benzyl butyl phthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chloro-3-methylphenol
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
1,4-Dichlorobenzene
1,2-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octylphthalate
Fluoranthene
FORM 8270 (1) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
so
10
10
10
10
10
20
10
10
10
10
10
10
20
10
20
10
10
10
10
10
10
10
10
10
20
10
10
10
10
so
so
10
10
10
10
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
I
I
•
•
•
•
•
•
I
•
. O ~ -~ J • , • • • • I
I r:t ,·1
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number: II 33--to-q
Sample Identification: ' • ' •. , •' -I ;',' ,i,..
Date Extracted:
Date Analyzed:
Number
40
41
42
43
44
45
46
47
48
49
50
Compound
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
Isophorone
2-Methylnaphthalene
2-Methylphenol (o-cresol)
4-Methylphenol (p-cresol)
Naphthalene
51 2-Nitroaniline
52 3-Nitroaniline
53 4-Nitroaniline
54
55
56
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
57 N-Nitroso-di-n-propylamine
58 N-Nitrosodiphenylarnine
59 Pentachlorophenol
60 Phenanthrene
61 Phenol
62
63
Pyrene
1,2,4-Trichlorobenzene
64 2,4,5-Trichlorophenol
65 2,4,6-Trichlorophenol
Comments:
BQL Below Quantitation Limit
FORM 8270 (2) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
10
10
10
10
10
10
10
10
50
so
50
10
10
50
10
10
so
10
10
10
10
10
10
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
• rn
I
•
•
•
•
•
•
I
•
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number: 11:U--lo-B
Sample Identification:
Date Extracted:
Date Analyzed:
Number
l
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16'
17
18
19
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzoic acid
Benzo(a)anthracene
Benzo(b)fluoranthene
.Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzyl alcohol
bis(2-Chloroethoxy)rnethane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Brornophenyl phenyl ether
Benzyl butyl phthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chloro-3-rnethylphenol
20 2-Chlorophenol
21 4-Chlorophenyl phenyl ether
22 Chrysene
23
24
25
26
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
27 1,4-0ichlorobenzene
28
29
30
31
32
33
34
1,2-Dichlorobenzene
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dirnethylphenol
Dimethyl phthalate
4,6-Dinitro-2-rnethylphenol
35 2,4-Dinitrophenol
36 2,4-Dinitrotoluene
37
38
2,6-Dinitrotoluene
Di-n-octylphthalate
39 Fluoranthene
FORM 8270 (l) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
so
10
10
10
10
10
20
10
10
10
10
10
10
20
10
20
10
10
10
10
10
10
10
10
10
20
10
10
10
10
50
so
10
10
10
10
-
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
, r O • -"• • ' ' •
I
I ~J · 1
I
•
•
•
•
•
•
' ,
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number:
Sample Identification: ~~' I ;· -b\ { ~ r-\ -(~.[~J ;~
cc\,\i!! Date Extracted:
Date Analyzed:
Number
40
41
42
43
44
45
46
47
48
49
so
Compound
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-cd)pyrene
_Isophorone
2-Methylnaphthalene
2-Methylphenol (o-cresol)
4-Methylphenol (p-cresol)
Naphthalene
51 2-Nitroaniline
52 3-Nitroaniline
53 4-Nitroaniline
54
55 '
56
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
57 N-Nitroso-di-n-propylamine
58 N-Nitrosodiphenylamine
59
60
61
62
63
64
65
Comments:
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1,2,4-Trichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
BQL ~ Below Quantitation Limit
FORM 8270 (2) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
10
10
10
10
10
10
10
10
50
50
50
10
10
50
10
10
50
10
10
10
10
10
10
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
•
I
•
•
•
•
•
•
I
BASE/NEUTRAL .:XTRACT:illl.ES
SW-846 METI!OD 8270
IEA Sample Number:
Samp!e Identification:
Cate E.xtract:ea:
Date Aoal.y:ted: Byr
Quant:i.tation
Limit Number compound (ug/kgy'~
l AcanA;>hthane 200 2 AcenApllthy lane 200 3 Anthracene 200 4 B1Ul.%o(a)ancilracene 200 5 B1Ul.%0(b)fluorant:hane 200 6 Besu:o(k)fluoran=e 200 7 Banzo(g,h,i)perylen.e 200 8 Banzo(A)pyrena 200 9 81Ul.Zyl. alcohol 400 l0 bia ( 2-Chloroetilcxy) mat:nane 200 ll bia(2-Chloroethyl)ether 200 u. bia(2-Chloroiaopropyl)ether 200 l3 bia(2-Ethylhaxyl)phtllal.ate 200 l4 4-Brcmcpnenyl phenyl ether 200 lS Ben:yl butyl phthal.ate 200 l6 4-Ch.larr'! II Di ] 1 C 0 400 I l7 2-Chloronaplltha.l.sna 200 l8 4-Ch.lorophenyl phenyl et:her 200 l9 Chrysene 200 20 D1.ban:::o(a,h)ant:llracene 200 21 Dibanzofuran 200 22 Di-n-but:ylpht:halate 200 23 l.l-Dichlorailanzena 200 24 1,4-0ichlorobenzene 200 25 l,2-DLc:hlorobenzene 200 26 3,3'-Dichlorobenzidl.ne
27 Diethyl phthalate 200 28 D1.mathy l phthal.ate 200 29 2,4-0ini.trot:oluena 200 . 30 2,6-Dini.trotoluena 200 31 Di-n-oct:ylphthal.ate 200 32 P'luora.nthona 200 33 Fluorene 200 34 Haxachlarobenzene 200 35 Hexachlarcburadiene 200 36 Baxachlorocyclcpent:adiene 200 37 Haxachloroethane 200 38 Indeno(l,2,J-cd)pyrene 200 39 !aophorcne 200
FORM 82708 ( 1 I Rev. 060689
Raaults
concencrat:i.cn
(ug/xr fil:h:
sor. sor.
sor.
BQL
BQL
BQL
BQL
llQt,
llQt,
sor.
llQt,
SQI.
llQt,
llQt,
SQI.
BQL
BQL
BQL
BQL
BQL
BQL
BQI,
BQL
BQL
BQL
BQL
BQL
BQL
BQL
8Qt,
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQI,
•
I
•
•
•
•
•
•
I
•
IEA Sample Number:
Sampia Idantificaticn:
Da.te E.xtract:ed.:
Date AnA.l.y:i:ea:
. \ \. ·,, s:'J :,;:
BASE/NEOTRAL EXTRACT:.BLES
SW-846 H.ETHOD 8270
/I 3~-/b
Sv6Jli1
":· j ·, i ~\ !
ay,
Quam:itation
Limit ~-t~ar compound <ug/kg>/ i!.il ,__
,40
~ '•42
43
44
45
46
47
48
49
50
2-Mathylnapllthalane
Naphthalene
2-Hitrcaailina
3-Hitrcanilina
4--Hitrcanilina
Nitrcl:>anzena
H--Hitroao--<ii-n-propylrunina
N--HitrcaodJ.phenylamina
P!lanaD.tilrena
Pyrene
l,2,4-Tric!ll.orctlan:ana
B(IL Below Quantitation LJ.mi.t
FORM 82708 (2) Rrr. 060689
200 ,:_
200
1000
1000
1000
200
200
200
200
200
200
Rasulta
eoncan=ation
(ug/kg>/~
BQI'.
BQI'.
BQI'.
BQI'..
BQI'..
BQI'.
BQI'..
BQI'.
BQI'.
BQL.
!!Qt.
• I t::t O l
I
•
•
•
•
•
•
I
I
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number:
Sample Identification:
Date Extracted:
Date Analyzed:
Nwnber
1
2
3
4
5
6
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzoic acid
Benzo(a)anthracene
Benzo(b)fluoranthene
7 Benzo(k)fluoranthene
8 Benzo(g,h,i)perylene
9 Benzo(a)pyrene
10
11
12
13
14
15
16
17
18
19
20
21
Benzyl alcohol
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Benzyl butyl phthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chloro-3-methylphenol
2-Chlorophenol
4-Chlorophenyl phenyl ether
22 Chrysene
23
24
25
26
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butylphthalate
1,3-Dichlorobenzene
27 1,4-Dichlorobenzene
28 1,2-Dichlorobenzene
29 3,3'-Dichlorobenzidine
30
31
2,4-Dichlorophenol
Diethyl phthalate
32 2,4-Dimethylphenol
33 Dimethyl phthalate
34 4,6-Dinitro-2-methylphenol
35 2,4-Dinitrophenol
36 2,4-Dinitrotoluene
37
38
2,6-Dinitrotoluene
Di-n-octylphthalate
39 Fluoranthene
FORM 8270 (1) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
50
10
10
10
10
10
20
10
10
10
10
10
10
20
10
20
10
10
10
10
10
10
10
10
10
20
10
10
10
10
50
50
10
10
10
10
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
rt • rn
I
•
•
•
•
•
•
I
•
BASE/NEUTRAL/ACID EXTRACTABLES
SW-846 METHOD 8270
IEA Sample Number:
Sample· Identification:
i\ 33-to
SV'Bc1SI
Date Extracted:
Date Analyzed:
Number compound
40
41
42
43
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
44 Hexachloroethane
45 Indeno(l,2,3-cd)pyrene
46
47
48
49
_Isophorone
2-Methylnaphthalene
2-Methylphenol (o-cresol)
4-Methylphenol (p-cresol)
50 Naphthalene
51 2-Nitroaniline
52 3-Nitroaniline
53
54
55'
56
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
57 N-Nitroso-di-n-propylamine
58 N-Nitrosodiphenylamine
59 Pentachlorophenol
60 Phenanthrene
61 Phenol
62
63
Pyrene
1,2,4-Trichlorobenzene
64 2,4,5-Trichlorophenol
65 2,4,6-Trichlorophenol
Comments:
BQL Below Quantitation Limit
FORM 8270 (2) Rev. 050589
By:
Quantitation
Limit
(ug/L)
10
10
10
10
10
10
10
10
10
10
10
50
50
50
10
10
50
10
10
50
10
10
10
10
10
10
. ,_ .:.::__
Results
Concentration
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
,
I
•
•
•
•
•
,
'
JC WATER SEMIVOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY
Lab Name=------------=----------------Contract: ------
Lab Code: SAS No.: SDG No.:
Matrix ..Spike -EPA Sample No.: I13-3-I0-q
--w 'Jy_ . ·,1 I \::; . c· ; , : .'\('.;i_ ,, r . '· ,___..,, , ' ..... ,., l --.., ,...., ,~ t·.:..?,..__ ! I ·\ ~, --/··. j L.~
I ' I SPIKE ,.
V I I ADDED
I COMPOUND I (ug/L)
I SAMPLE I MS I MS I QC ICONCENTRATIONICONCENTRATIONf t !LIMIT: !' (ug/L) I (ug/L) I REC CI REC. I I
I Phenol I .;!010
I 2-Chlorophenol I ~ l>'i).
I 1,4-Dichlorobenzene __ l Jell
I N-Nitroso-di-n-prop.(l)I I c-o
I 1,2,4-Trichlorobenzene_l I O'-l
I 4-Chloro-3-methylphenolJ ()oO
I Acenaphthene I l u-o
I 4-Nitrophenol I ~OQ I 2,4-Dinitrotoluene I lU~
I Pentachlorophenol I ~00
I Pyrene I wo
I I 1=-1---..:-. I I. Cj/ 1_ltlr.__112-e• I I laq 1~127-12: I I .'s'l-I '57 fJ6-9·. I I ~ I Q, 141-lll I 1 _ _J,[01<.1L:,p,_ __ 1 ½ fJ 9-9 E I I /Lf;) I :JI 123-9; 1 1 sf? 1 ss l46-1H I I //8 1~110-8C I I 7;,J t_]J_l24-9c I I IQ 1.2k_l 9-10" I I ~ 1~126-127 I I l _______ l _______ l_....c._l __ _
I I SPIKE I MSD I MSD I I ADDED I CONCENTRATION I i " QC LIMITS I COMPOUND I (ug/L) I (ug/L) I REC : I RPO : I RPO I REC. I I f 8s I I~ 1-----1------I Phenol I ~00 I l~I I 42 112-89 I 2-Chlorophenol I a°" I I! i., I I I 40 l27-12J I 1,4-Dichlorobenzene __ l \UO I ~ I So I 1:; I 23 f)6-97 I N-Nitroso-di-n-prop.(l) I la o I I ~~ I t) I )8 141-116 I 1,2,4-Trichlorobenzene I Loo I v;,l I lol I g I 28 IJ9-98 I 4-Chloro-J-methylphenoll ~~ I £S1' I J(p I 7 I 42 l2J-97 I Acenaphthene I l~O I (.,J. I (a:l I rip I Jl I 46-118 I 4-Nitrophenol I ~OI> I 1~8 I f.d I I so 110-80 I 2,4-Dinitrotoluene I Joo I Bo
l~I to I )8 I 24-96 I Pentachlorophenol I j,l\l'\l I ns I I I\,, I 50 I 9-10) I Pyrene I fllO I 9S" I I l,, I Jl 126-127 I I I I I I I
(1) N-Nitroso-di-n-propylamine
; Co-luon to be used to flag i:-ecovery and RPO val_!JeS vith an a!:;terisk "" Values outside of QC limits ______ _ -----
RPO: D out of -f> II 0utsTct~ limit:; Spikc-,-R~e~c-o-very: 0---"o,._· u-t ·of. .... ~d outside limit::; ··------COMME~lTS:
ot,l-cc.. M'\,.:,6?u~~ (,~~+ FOR.'1 III :;v-1
PtA~td 'i0;/J<, ,,rrj f:'PO (.)l,_ 0JccJ ,:::(,c+' l)vL-n-(c . I
I
I
•
•
•
•
•
•
'
•
A R:ESEAllCH
TllIANGLE
• ..: LAl30RATORIES
VOST GC/MS REPORT
prepared for
INDUSTRIAL & ENVIRONMENTAL ANALYSTS, INC .
by
RESEARCH TRIANGLE LABORATORIES, INC .
Thomas G. Conally
Laboratory Manager
RTL ID# 10501D
May 6, 1991
--1612 Carpenter Fletcher Road • Durham, North Carolina 27713 • [phone] • FAX: [phone] --
A Member of the Andersen Technology Group
•
I
•
•
•
•
•
•
'
•
Scope:
INTRODUCTION
To analyze (VOST) Tenax/Charcoal cartridges for the target compound list (TCL) and
tentatively identify the 10 greatest Non-TCL peaks by Desorb-Purge-Trap-Desorb Gas
Chromatography Mass Spectrometry (DPTD GC/MS) .
Method Summary:
Sample cartridges are analyzed by desorb-purge-trap-desorb gas chromatography /mass
spectrometry (DPTD GC/MS). Daily analytical checks are performed on cartridge blanks
and reagent water. The daily GC/MS performance test required for this method is
described in SW 846, Method 8240. The key Abundance Criteria for 4-Bromofluorobenzene
(BFB) must be met before any samples are analyzed. All standards, blanks and samples
· are spiked with a known amount of BFB to maintain a constant check of system
performance.
Sample Desorption:
Calculations:
The DPTD GC/MS procedures are those described in SW 846 Method 5040. The spiked
sample cartridge is placed in the thermal desorption apparatus (Nutech 8533) and desorbed
In the VOST system by heat to 200 • C for 1 O minutes. Consideration Is given for Individual
analysis of cartridges. The desorbed components then pass Into the bottom of the water
column, are purged from the water and collected on the internal analytical sorbent trap.
After the 10-minute desorption period, the compounds are desorbed from the analytical trap
into the GC/MS system .
All compounds detected that coincide with those of the Target Compound List (TCL) are
calculated using equation #1 and response factors derived from in-house standards. All
tentatively identified compounds are calculated, using equation #2 and a standard TIC
response factor of one (1.0). Compounds quantified by equation #2 are qualified as being
estimates .
Eqn #1:
Eqn #2:
Where:
[X) = Ax . (/SJ
A,s · RF
[X) = Ax · [/SJ
A,s • 1.0
[X) = amount of compound, ng
[/SJ = amount of internal standard, ng
Ax= response of compound
A,s = response of Internal standard
RF = response factor
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ANALYTICAL CONDITIONS
Equipment:
HP 5970 GC/MS/DS tuned to BFB criteria
GC Conditions:
Column:
Temp 1
Time 1
Ramp Rate
Temp2
Time2
VOCOL (Supelco),
Length 60 m,
Film thickness 1.5 µ m,
o ·c
4.0 minutes
6.0 • C/minute
160 ·c
o minutes
Internal diameter 0. 75 mm,
Construction of Borosilicate glass
with fused silica ends
Mass Spectrometer Conditions:
Run Time
Scan Range
Scan Delay
Ion Source Temp
Electron Multiplier
Separator Temp
Sample Chronicle:
Client
RTL Project ID
Analysis Type
Date of Collection
Date Received
Date Authorized
Date Analyzed
Date Reported
25 minutes
35 • 260 AMU
1.25 minutes
2oo·c
2000 ± 200 EV
225•c
IEA
10501D
VOST Pairs
Not Supplied
05/01/91
05/01/91
05/02 · 05/03/91
05/06/91
I
Narrative:
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Footnotes:
•
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Nine VOST pairs were received with eight (B) pairs for analysis. One sample was to be
used as a backup n analytical problems were incurred. IEA requested a one week
turnaround for the report. If possible, a report delivery date of 5/6/91 was also requested.
Several notable occurrences were observed during the sample analysis, (see each report
respectively noting the footnotes below).
• Samples 2A through 2C showed high levels of organics and at some points data drop
out was observed due to detector saturation. In all three samples RTL's first internal
standard co-eluted with a high level sample peak and only partial data was obtained for
that retention time. Quality Control measures were violated and analysis was stopped
until confirmation with IEA (Mike White) was obtained to continue.
• When high sample concentrations were observed, RTL highly recommended sample
spllt1ing In order to obtain the best quantltable data possible and to deter data drop out
and possible GC/MS system shut down. No spllt1ing was requested on 5/3/91 .
RTL remains available to assist with questions concerning these reports or sampling
procedures.
• · Data drop out was ob_served due to excessive amounts of sample compounds causing
detector and column saturation. None or limited data was available for several scans.
When co-elution with other target compounds occurred, distortion and low recoveries
were usually observed. Amounts detected are estimates and usually much more could
have been present. RTL's column saturation is considered to be 10,000 ng per
compound .
•. RTL:s internal standard recovery was affected due to sample peak co-elution and data
drop out (see above). All associated peaks, therefore, are calculated using an external
standard from RTL's Method Blank. The results are qualnied as being estimates due to
the interference.
•· RTL:s established calibration range is 20 to 1000 ng. Column saturation Is at
approximately 10,000 ng. When amounts detected are greater than 1000 ng, they are
qualified as estimates. Extrapolated concentrations just above the calibration range are
considered to be fairly good estimates with the reliabillty decreasing as the concentration
increases.
• · No library data base entries were retrieved in order to tentatively identify this compound.
Possibly not enough Ions were available for a match due to the analytical method for
VOST analysis .
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REFERENCES
Federal Register, 44, 69464, December 3, 1979
Protocol for the Collection and Analysis of Volatile POHCs Using VOST, EPA-600/8-84-007 available from
ORD Publications, Center for Environmental Research Information, Cincinnati, Ohio 45268
NIOSH Manual of Analytical Methods, HEW Publication No. (NIOSH) 75-121, available from Superintendent
of Documents, U. S. Government Printing Office, Washington, D.C. 20402
Supelco Bulletin 769, "Determination of Organic Vapors In the Industrial Atmosphere", 1977: Supelco, Inc.,
Bellefonte, PA 16823
Test Methods for Evaluation of Solid Waste, SW 846 Methods 0030, 8240, 5040, 5030
Compendium of Methods for the Determination of Toxic Organic Compounds In Air, PB87-168688, Battelle
Columbus Laboratories, Columbus, Ohio
• RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 I RTLID: 10501 D-1 Analyzed: 05/02/91
File ID: T7928 Reported: 05/06/91
Sample ID: Trip Blank Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d4 74
Toluene-cl, 90
4-Bromofluorobenzene 72
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane BQL
75-01-4 Vinyl Chloride BQL
74-83-9 Bromomethane BQL
75-00-3 Chloroethane BQL
• 75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL
67-64-1 Acetone BQL
75-15-0 Carbon Disulfide BQL
75-09-2 Methylene Chloride BQL 540-59-0 1,2-D1chloroethene BQL
75-34-3 1, 1-Dichloroethane BQL
78-93-3 2-Bu1anone BQL
• 67-66-3 Chloroform BQL 107-06-2 1,2-Dichloroethane BQL
71-55-6 1, 1, 1-Trlchloroethane BQL
56-23-5 Carbon Tetrachloride BQL
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene BQL
79-01-6 Trichloroethene BQL
78-87-5 1 2-Dichloro□ro□arie BQL
•
75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL
10061-02-6 trans-1,3-Dichloropropene BQL
79-00-5 1.1.2-Trichloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL
108-10-1 4-Methyl-2-pentanone BQL
110-75-8 2-Chloroettivl Vinvl Ether BQL
•
108-88-3 Toluene BQL 591-78-6 2-Hexanone BQL 127-18-4 Tetrachloroethene BQL 108-90-7 Chlorobenzene BQL
100-41-4 Ethyl benzene BQL 1330-20-7 Xylene (total) BQL 100-42-5 Styrene BQL 79-34-5 1 1 2 2-Tetrachloroethane BQL
I Quantitation Limit (ng): 20 BQL: Below Quantitation Limit
I
I RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA I RTLID: 10501D-1
Received: 05/01/91
Analyzed: 05/02/91
File ID: T7928 Reported: 05/06/91
Sample ID: Trip Blank Description: VOST Pair
•
Tentatively Identified Compounds
• Results Retention Molecular
Compound (ng) Time. Weight
(minutes) (AMU)
carbon dioxide 1300 1.78 44
•
•
•
Comments:
I
•
I RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 I RTL ID: 10501 D-2 Analyzed: 05/02/91
File ID: T7929 Reported: 05/06/91
Sample ID: Field Blank Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d4 80
Toluene-cl, 99
4-Bromofluorobenzene 78
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane BQL
75-01-4 Vinyl Chloride 25
74-83-9 Bromomethane BQL
75-00-3 Chloroethane BQL
• 75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL 67-64-1 Acetone 370
75-15-0 Carbon Disulfide 1100
75-09-2 Methylene Chloride 44 540-59-0 1,2-Dichloroethene BQL
75-34-3 1, 1-Dichloroethane BQL 78-93-3 2-Butanone BQL
• 67-66-3 Chloroform BQL 107-06-2 1,2-Dichloroethane BQL
71-55-6 1, 1, 1-Trichloroethane BQL
56-23-5 Carbon Tetrachloride BQL
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene BQL
79-01-6 Trichloroethane BQL 78-87-5 1.2-Dichloronroruane BQL
•
75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL
10061-02-6 trans-1,3-Dichloropropene BQL 79-00-5 1.1 2-Trichloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL
108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroetlivl Vinvl Ether BQL
•
108-88-3 Toluene BQL 591-78-6 2-Hexanone BQL 127-18-4 Tetrachloroethene BQL
108-90-7 Chlorobenzene BQL
100-41-4 Ethyl benzene BQL 1330-20-7 Xylene (total) BQL
100-42-5 Styrene BQL 79-34-5 1 1.2 2-Tetrachloroethane BQL
I Quantitation Limit (ng): 20 BQL: Below Quantitation Limit
•
I RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA I RTL ID: 10501 D-2
Received: 05/01/91
Analyzed: 05/02/91
File ID: T7929 Reported: 05/06/91
Sample ID: Field Blank Description: VOST Pair
•
Tentatively ldentffied Compounds
• Results Retention Molecular
Compound (ng) Time Weight
(minutes) (AMU)
1, 1,2-Trlchloro-1,2,2-trifluoroethane 250 4.00 186
Trimethylsilanol 510 6.34 90
Hexamethyldisiloxane 2800 9.02 162 •
•
•
Comments:
•
•
I
I RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 I RTL ID: 10501 D-3 Analyzed: 05/02/91
File ID: T7930 Reported: 05/06/91
Sample ID: Audit B Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d4 76
Toluene-cJ. 95
4-Bromofluorobenzene 73
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane BQL
75-01-4 Vinyl Chloride 220
74-83-9 Bromomethane BQL 75-00-3 Chloroethane BQL
• 75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL 67-64-1 Acetone BQL 75-15-0 Carbon Disulfide 25
75-09-2 Methylene Chloride 75 540-59-0 1,2-Dichloroethene BQL 75-34-3 1, 1-Dichloroethane BQL 78-93-3 2-Butanone BQL
• 67-66-3 Chloroform 1600 • 107-06-2 1,2-Dichloroethane BQL 71-55-6 1, 1, 1-Trichloroethane BQL 56-23-5 Carbon Tetrachloride 780
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene 1000
79-01-6 Trichloroethane BQL 78-87-5 1 2-DichloronroMne BQL
• 75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL
10061-02-6 trans-1,3-Dichloropropene BQL 79-00-5 1 1 2-Trichloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL 108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroettivt Vinvt Ether BQL
•
108-88-3 Toluene BQL 591-78-6 2-Hexanone BQL 127-18-4 Tetrachloroethene 820 108-90-7 Chlorobenzene BQL 100-41-4 Ethyl benzene BQL 1330-20-7 Xylene (total) BQL 100-42-5 Styrene BQL 79-34-5 1 1 2 2-Tetrachloroethane BQL
• Quantitation Limit (ng): 20 BQL: Below Quantitation Limit
See Footnotes: •
I
• RESEARCH TRIANGLE LABORATORIES, INC.
I Client: IEA
RTL ID: 10501 D-3
Received:
Analyzed:
File ID: T7930 Reported:
Sample ID: Audit B Description:
•
Tentatively Identified Compounds
• Results Retention
Compound (ng) Time
(minutes)
Carbon dioxide 94 2.47
1, 1,2-Trlchloro-1,2,2-trifluoroethane 32 3.99
•
•
•
Comments:
•
'
•
05/01/91
05/02/91
05/06/91
VOST Pair
Molecular
Weight
(AMU)
44
186
• RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 ' RTL ID: 10501 D-4 Analyzed: 05/02/91
File ID: T7931 Reported: 05/06/91
Sample ID: Audit C Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d4 75
Toluene-cl, 93
4-Bromofluorobenzene 73
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane BQL
75-01-4 Vinyl Chloride 170
74-83-9 Bromomethane BQL
75-00-3 Chloroethane BQL
• 75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL
67-64-1 Acetone BQL
75-15-0 Carbon Disulfide 130
75-09-2 Methylene Chloride 52 540-59-0 1,2-Dichloroethene BQL
75-34-3 1, 1-Dichloroethane BQL
78-93-3 2-Butanone BQL
67-66-3 Chloroform 1700" • 107-06-2 1,2-Dichloroethane BQL 71-55-6 1, 1, 1-Trichloroethane BQL
56-23-5 Carbon Tetrachloride 820
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene 1000
79-01-6 Trichloroethene BQL
78-87-5 1 2-Dichloroorooane BQL
• 75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL 10061-02-6 trans-1,3-Dichloropropene BQL
79-00-5 1.1.2-Trichloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL 108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroettivl Vinvl Ether BQL
• 108-88-3 Toluene BQL 591-78-6 2-Hexanone BQL 127-18-4 Tetrachloroethene 850 108-90-7 Chlorobenzene BQL
100-41-4 Ethylbenzene BQL 1330-20-7 Xylene (total) BQL
100-42-5 Styrene BQL 79-34-5 1 1 2 2-Tetrachloroethane BQL
Quanlilation Limit (ng): 20 BQL: Below Quantitation Limit
See Footnotes: '
•
• RESEARCH TRIANGLE LABORATORIES, INC.
• Client: IEA Received: 05/01/91 • RTL ID: 10501D-4 Analyzed: 05/02/91
File ID: T7931 Reported: 05/06/91
Sample ID: Audit C Description: VOST Pair
•
Tentatively Identified Compounds
• Results Retention Molecular
Compound (ng) Time Weight
(minutes) (AMU)
Carbon dioxide 1600 1.61 44
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Comments: •
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•
RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91
RTL ID: 10501 D-5 Analyzed: 05/02/91
File ID: T7932 Reported: 05/06/91
Sample ID: Audit D Description: VOST Pair
Surrogate Percent Recovery
1,2-Dichloroethane-d4 74
Toluene-<\, 95
4-Bromofluorobenzene 79
CAS Number Target Compound Results (ng)
74-87-3 Chloromethane BQL
75-01-4 Vinyl Chloride 190
74-83-9 Bromomethane BQL
75-00-3 Chloroethane BQL
75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL
67-64-1 Acetone BQL
75-15-0 Carbon Disulfide 56
75-09-2 Methylene Chloride 49 540-59-0 1,2-Dichloroethene BQL
75-34-3 1, 1-Dichloroethane BQL
78-93-3 2-Butanone BQL
67-66-3 Chloroform 1600° 107-06-2 1,2-Dichloroethane BQL 71-55-6 1, 1, 1-Trichloroethane BQL
56-23-5 Carbon Tetrachloride 830
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene 1000
79-01-6 Trichloroethene BQL
78-87-5 1.2-Dichlorooro=ne BQL
75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL
10061-02-6 trans-1,3-Dlchloropropene BQL 79-00-5 1.1 2-Trichloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL
108-10-1 4-Methyl-2-pentanone BQL
110-75-8 2-Chloroettivl Vinvl Ether BQL
108-88-3 Toluene BQL 591-78-6 2-Hexanone BQL 127-18-4 Tetrachloroethene 900 108-90-7 Chlorobenzene BQL
100-41-4 Ethyl benzene BQL 1330-20-7 ..Xylene (total) BQL
100-42-5 Styrene BQL 79-34-5 1 1.2 2-Tetrachloroethane BQL
Quantitation Limit (ng): 20 BQL: Below Quantitation Limit
See Footnotes: c
,
RESEARCH TRIANGLE LABORATORIES, INC.
' Client: IEA
RTL ID: 10501 D-5
Received: 05/01/91
Analyzed: 05/02/91
File ID: T7932 Reported: 05/06/91
Sample ID: Audit D Description: VOST Pair
•
Tentatively Identified Compounds
• Results Retention Molecular
Compound (ng) Time Weight
-(minutes) (AMU)
Carbon dioxide 2100 1.61 44
•
•
•
Comments: •
' ,
, RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 ' RTL ID: 10501D-6 Analyzed: 05/02/91
File ID: T7933 Reported: 05/06/91
Sample ID: 2A Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d4 ltla
Toluene-ct, 99
4-Bromofluorobenzene 82
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane 350 a,b
75-01-4 Vinyl Chloride 140 b
74-83-9 Bromomethane BQL
75-00-3 Chloroethane 110•
75-69-4 Trichloroftuoromethane 40" • 75-35-4 1, 1-Dlchloroethene BQL
67-64-1 Acetone 7400 b,c
75-15-0 Carbon Disulfide 260"
75-09-2 Methtene Chloride 190" 540-59-0 1,2-D chloroethene BQL
75-34-3 1, 1-Dichloroethane BQL
78-93-3 2-Butanone 700 b
67-66-3 Chloroform 140" • 107-06-2 1,2-Dichloroethane BQL 71-55-6 1, 1, 1-Trlchloroethane BQL
56-23-5 Carbon Tetrachloride 92 b
· 108-05-4 Vinyl Acetate BQL 71-43-2 Benzene >2400 a,c
79-01-6 Trichloroethene BQL 78-87-5 1.2-Dichloronronane BQL
•
75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL 10061-02-6 trans-1,3-Dlchloropropene BQL 79-00-5 1.1,2-Trlchloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL 108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroetlivl Vinvl Ether 25
•
108-88-3 Toluene 120 591-78-6 2-Hexanone 170
127-18-4 Tetrachloroethene 36 108-90-7 Chlorobenzene BQL
100-41-4 Ethyl benzene 30 1330-20-7 Xylene (total) 60 100-42-5 Styrene 600 79-34-5 1 1 2 2-Tetrachloroethane BQL
• Quantitalion Limit (ng): 20 BQL: Below Quanlitatlon Limit
See Footnotes: a,b,c
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'
RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA
RTL ID: 10501 D-6
FIie ID: T7933
Sample ID: 2A
Tentatively Identified Compounds
Compound
4,4-Dimethyl-2-oxetanone
Dihydro-3-methylene-2,5-furandione
Trlmethylsilanol
Hexamethyldisiloxane
Dimethylhexene Isomer
5-Methyl-2-hexanone
Octamethyltrisiloxane
Octanal
Unknown PNA
Nonanal
Comments:
NA: Not Available
See Footnotes: •
Results
(ng)
b 1900
b 1100
b 5900
b 4200
550
b 630
b 920
b 830
b 1300
b 870
Received:
Analyzed:
Reported:
Description:
Retention
Time
(minutes)
2.16
3.81
6.36
9.32
10.63
14.63
15.80
21.79
24.00
24.48
05/01/91
05/02/91
05/06/91
VOST Pair
Molecular
Weight
(AMU)
100
112
90
162
112
114
236
128
NA
142
, RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 ' RTLID: 10501D-7 Analyzed: 05/03/91
File ID: T7937 Reported: 05/06/91
Sample ID: 2B Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-d, ""•
Toluene-cl,, 96
4-Bromofluorobenzene 82
• GAS Number Target Compound Results (ng)
74-87-3 Chloromethane 870 b
75-01-4 Vinyl Chloride 190 b
74-83-9 Bromomethane BQL
75-00-3 Chloroethane 160 b
• 75-69-4 Trichlorofluoromethane BQL 75-35-4 1, 1-Dichloroethene BQL
67-64-1 Acetone 8900 b,c
75-15-0 Carbon Disulfide 1100•··
75-09-2 Methylene Chloride 120" 540-59-0 1,2-Dichloroethene BQL
75-34-3 1, 1-Dichloroethane BQL
78-93-3 2-Butanone 1000 b
67-66-3 Chloroform 140 D • 107-06-2 1,2-Dichloroethane BQL 71-55-6 1, 1, 1-Trichloroethane BQL
56-23-5 Carbon Tetrachloride as•
108-05-4 Vinyl Acetate BQL 71-43-2 Benzene >3000 b,c
79-01-6 Trlchloroethene BQL
78-87-5 1 2-Dichloronronane BQL
• 75-27-4 Bromodichloromethane BQL 10061-01-5 cis-1,3-Dichloropropene BQL
10061-02-6 trans-1,3-Dichloropropene BQL 79-00-5 1 1.2-Trlchloroethane BQL
124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL
108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroettivl Vinvl Ether 32
•
108-88-3 Toluene 170 591-78-6 2-Hexanone 300
127-18-4 Tetrachloroethene BQL 108-90-7 Chlorobenzene BQL
100-41-4 Ethyl benzene 37 1330-20-7 Xylene (total) 68
100-42-5 Styrene 640
79-34-5 1.1 2.2-Tetrachloroethane BQL
I Quantitation Limit (ng): 20 BQL: Below Quantitation Limit
See Footnotes: a.•.•
'
,
RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA ' RTL ID: 10501D-7
Received:
Analyzed:
File ID: T7937 Reported:
Sample ID: 28 Description:
•
Tentatively Identified Compounds
• Results Retention
Compound (ng) Time
(minutes)
Dihydro-3-methylene-2,5-furandione b 1300 3.84
(1-Methylethyl)cyclopropane b 1000 6.04
Trimethylsilanol b 4400 6.39 • Hexamethyldisiloxane b 2900 9.42
5-Methyl-2-hexanone b 810 14.65
Octamethyltrisiloxane b 890 15.82
Octanal b 1300 21.82 • Undecane b 650 22.99
Unknown PNA b 1500 24.02
Unknown hydrocarbon b 1700 24.50
•
Comments:
• See Footnotes: b
I
I
05/01/91
05/03/91
05/06/91
VOST Pair
Molecular
Weight
(AMU)
112
84
90
162
114
236
128
156
-
.
, RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA Received: 05/01/91 ' RTL ID: 10501 D-8 Analyzed: 05/03/91
File ID: T7938 Reported: 05/06/91
Sample ID: 2C Description: VOST Pair
• Surrogate Percent Recovery
1,2-Dichloroethane-<14 LU a
Toluene-<\, 90
4-Bromofluorobenzene 78
• CAS Number Target Compound Results (ng)
74-87-3 Chloromethane 340 ...
75-01-4 Vinyl Chloride 160 • 74-83-9 Bromomethane BQL 75-00-3 Chloroethane 75 •
75-69-4 Trichlorofluoromethane 26" • 75-35-4 1, 1-Dichloroethene BQL 67-64-1 Acetone 3100 b,c
75-15-0 Carbon Disulfide 340 •
75-09-2 Methylene Chloride 210" 540-59-0 1,2-D1chloroethene BQL 75-34-3 1, 1-Dichloroethane BQL 78-93-3 2-Butanone 140 •
67-66-3 Chloroform 110" 107-06-2 1,2-Dichloroethane BQL • 71-55-6 1, 1, 1-Trichloroethane BQL 56-23-5 Carbon Tetrachloride 82 • 108-05-4 Vinyl Acetate BQL 71-43-2 Benzene >2300a,c
79-01-6 Trichloroethene BQL 78-87-5 1.2-Dichlorooro=ne BQL 75-27-4 Bromodlchloromethane BQL 10061-01-5 cls-1 ,3-Dichloropropene BQL • 10061-02-6 trans-1,3-Dlchloropropene BQL 79-00-5 1.1 2-Trichloroethane BQL 124-48-1 Dibromochloromethane BQL 75-25-2 Bromoform BQL 108-10-1 4-Methyl-2-pentanone BQL 110-75-8 2-Chloroethvl Vinvl Ether BQL 108-88-3 Toluene 110 591-78-6 2-Hexanone 88 • 127-18-4 Tetrachloroethene BQL 108-90-7 Chlorobenzene BQL 100-41-4 Ethyl benzene 21 1330-20-7 Xylene (total) 40 100-42-5 Styrene 530 79-34-5 1.1 2 2-Tetrachloroethane BQL
Quantitation Limit (ng): 20 BOL: Below Quantitalion Limit I See Footnotes: a.•.c
I
, RESEARCH TRIANGLE LABORATORIES, INC.
Client: IEA ' RTL ID: 10501 D-8
Received: 05/01/91
Analyzed: 05/03/91
File ID: T7938 Reported: 05/06/91
Sample ID: 2C Description: VOST Pair
•
Tentatively Identified Compounds
• Results Retention Molecular
Compound (ng) Time Weight
(minutes) (AMU)
4,4-Dimethyl-2-oxetanone b 2100 2.16 100
Fluorotrimethylsilane b 1400 2.37 92
Trimethylsilanol b 3500 6.36 90 • Hexamethyldisiloxane b 3800 9.32 162
Octamethyltrisiloxane b 1300 15.86 236
Unknown PNA b 64Q 19.45 -
Unknown hydrocarbon b 370 21.79 -• Unknown• b 290 23.44 -
Unknown• b 480 23.99 -
Nonanal b 420 24.54 142
•
Comments:
• See Footnotes: •·•
I
I
,
f\5 Flf o<5 / ?J Isa. ,u/G.. •
/Vl.5 /o{a,,.._/:.: /7 / J / Sc~ l,.
M5H::/J)Cf <73/0/sr(z •
•
•
•
•
I
I
•
•
•
•
SAMPLE ANALYTICAL DATA FORM
Plant NG -Sl, L( ~I Run number --'~=->----Sample location ---""""""',-.;"'c""t..:,,...,-=--:-"=..:::c..---~----------Relative humidity---.....:::'---"-'='--""''------------------
Sample
type
Acetone rinse
filter(s)
Sample
·identifiable
/
/
Liquid level marked
and/or container sealed
Acetone rinse container number · C .S-. -----------~~----Acetone rinse voltime (V8W) __ ··-----'-------...z~e:....--•ml Acetone blarik residue concentration (C •) ml
w "' • ·c1v1w = (
Date and time of wt
Date and.time of wt
Date and time of wt
Date·and time of wt
Weight of
Filter(s) container
Date and time of wt
Date and time of wt
·Date and time of wt
Date and time of wt
) ( ) ( ) = ----~---g ___________ Gross wt
___________ Gross wt
(6(.,-7167 g
/()(,_ '7161' g
___________ Gross wt ___ -___ g
_____________ Gross wt g
Average gross wt lot, 7/6 & g
_Tare wt /0 b. 7153 g
Less acetone blank wt (W1 )
particulate in acetone rinse (m1 )
___ c:,-'---_g
number -------'-------------
Gross wt W I. (2
· Gross wt <f 'f I. i.
Gross wt t.f '-f I. (,
g
g
g
Gross wt ______ g
•· Average gross wt __ '-/_'f_/_._6_· __ g
Tare wt 'flff. s g
•
I
Less filter blank wt. (F8 ) C> g
Weight of particulate on filter(s) (mf) 0. I g
Weight of particulate in acetone rinse g
Total weight or particulate (m0 ) 8. 6 M g
~: In no case should a blank residue >0.01 mg/g or 0.001% of
the weight of acetone used be subtracted from the sample weight.
Remarks
Signature of analyst __ M~u'--'-"/4J=-'---'l0"--(Q;2:--'--'_'-=-_______ _ ;
Signature of reviewer-----------'----------
-.. • • • • • •
WESTON Analytics Use Only Custody Transfer Record/Lab Work Request
Refriaerator#
1-1 1 , r _ I #fTvne Container
-..J:i.s;o~e~c.~"~.s,-,..::_-!,....e.g~151c..~· ·.:,.·gg~-~:...__ ____ t~===::.._t---+-+-t---+--t---t--1---+---j Client Volume
Work Order --~;:::::::;/;:::::::;=. ___________ l-:P:-r-es_e_rv-at::-iv-e---1--+--ir--+---+--+---t--f---j---j
Date Rec'd. 'fh~ 9/ Date Due -------1-------+--+-+--+---+--t--+--+--+--II
RFW Contact a."'-\ I'\ eet-ev-ANALYSES ~ e3z-0
Client ContacVPhone 5¼,.;a. 0 / r, REQUESTED
IWA Use Only
Lab ID
A-
c..,
X A /J
V LI ()
VAO
Matrix: W • Water
S-Soll 0-011
SE• Sediment A• Air
SO. Solid WI· Wipe
Client ID/Description
'-i7
(,., 7
OS· Drum Solids X -Other
DL • Drum Liquids
F • Fish
L -EP/TCLP Leachate
Item/Reason ~liM"ished bv ~y ...... hu
II nA . • I
RFW 21-21-001/A-12/88
Matrix
i
.J_
Date
Collected
, 1 / .
I
Special Instructions: Po J-1 c Av-J..,+ s.o..wp k-s
~ 1.4.,. "'" "Te-~..\-
nate Time
2\Zo
Item/Reason Relinouished bv Received bv Date Time
1-41~
'
..
WESTON Analytics
Use Onlv
Samples Were:
1 Shipped or Hand-
Delivered
NOTES:
2 Ambient or Chilled
NOTES:
3 Received Broken/
Leaking (Improperly
Sealed)
y N
NOTES:
4 Properly Preserved
y N
NOTES:
5.Received Within
Holding Ti mes
y N
NOTES:
COC Tape Was:
1 Present on Outer
Package Y N
2 Unbroken on Outer
Package Y N
3 Present on sample
y N
4 Unbroken on Sample
NOTES: Y N
COC Record Was:
1 Present Upon Receipt
of Samples Y N
Discrepancies Between
Sample Labels and COC
Record? Y N
NOTES:
7-115
-
.. ).S;Rl;L ~ ENVIROrliENTAL ,.
. ' ANALYSTS, INC.
,_~_0CI0 WESTO_N PKWY.
,CARY, N.C. 27513
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~3Q_O0 WESTON_-PKWY. • REGULATORY CLASSIFICATION -PLEASE SPECIFY
;CARY, N:C:27513
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ANALYSTS, INC.
3000 WESTON PKWY.
CARY, N.C. 27513 .
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• •• • • • ••
CHAIN.OF CUSTODY REC<fRD •
, , 'F.IEl'.D'.REMARKS'.:., :'.";·•: _::: ::.· ..•. ,,_,
<I: ·"" , _:P.:~ v1J,,_: l,i ~ ;f..., /\S '. rv\,!,<:l.v-~>•:> -rv\ t-ll..:k._ ,
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C,.AIN O~CUST00Y REC~RD •
REGULATORY CLASSIFICATION • PLEASE SPECIFY
D NPDES □ DRINKiN~ WATER □ AGRA □ .OTHER _· ---~~-·-· _-:_·!~~· _
ml 14226~
WF-Z-Ph
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vn 1>
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flusTRIAL & ENV1RclMeNTAL ·
ANALYSTS, INC.
3000 WESTON PKWY.
CARY, N.C. 27513
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=::!!!!::::::===-. • an environmental
testi_ng· .. company
3000 WESTON PKWY.
. . ' "CARY, N.C. 27513
REGULATORY CLASSIFICATION -PLEASE SPECIFY
□ NPDES □ DRINKING WATER DRCRA 'erorHER ------~----
..... ~::;880:.IECJd#~~ ];{{~0:~l1tI~~~~:·,:t~RR0JEC NA..ME~~~t>-~";~
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