NCD003446721_19900201_Celeanse Corporation - Shelby Fiber_FRBCERCLA RD_30% Remedial Design Report-OCR

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Westinghouse Environmental
and Gootechnical Services. Inc.
4000 DeKalb Technology Parkway. NE
Suite 250
Atlanta. Georgia 30340
[phone]
FAX [phone]
OPERABLE UNIT 2
30% REMEDIAL DESIGN REPORT
HOECHST CELANESE/SHELBY, NORTH CAROLINA
WESTINGHOUSE PROJECT 4124-85-0S0N
DOCUMENT CONTROL BS0S0N-0201
Prepared For:
HOECHST CELANESE CORPORATION
Shelby, North Carolina
Prepared By:
WESTINGHOUSE ENVIRONMENTAL AND
GEOTECHNICAL SERVICES, INC.
February 1990
Senior Environmental Engineer
Everett W. Glover, Jr., P.E.
Project Manager
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A Westinghouse Electric Corporation subsidiary
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Operable Unit 2 30% Remedial D~sign Report
Hoechst Celanes'e/Shelby, NC
Westinghouse Project ~124-85-050N
Document Contrell 85050N-0201
List of Figures
List of Tables
List of Appendices
EXECUTIVE SUMMARY
1.0 INTRODUCTION
TABLE OF CONTENTS
1.1 Site Description
1.2 Site History and Regulatory status
1.3 Project Description and Type
2.0 DESIGN BASIS
2.1 Waste Characteristics
2.2 Waste Volumes
2.3 Waste Treatment Processes
3.0 PRELIMINARY DESIGN CRITERIA AND PERFORMANCE
STANDARDS
3-1 Definitions
3.2 Pre-Excavation Site Investigation
3.3 Site Work
3.3.1 Clearing and Grubbing
3.3.2 Stream Sediment Excavation
3.3.3 Performance Criteria
3.4 Area Requirements
3.5 Spill Prevention Measures
3.6 Environmental Controls
3.7 Materials Handling
3.8 Solidification
3.8.1 General
3.8.2 Process Description
3.8.3 Solidification Demonstration Test
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3.8.4 Performance Requirements-Solidification
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page ii
3.9 Thermal Treatment
3.9.1 General
3.9.2 Description
3.9.3 Thermal Test Burn
3.9.4 Monitoring
3.9.5 Ancillary Functions
3.9.6 Operations Manual
3.9.7 Thermal Treatment Unit Pollution Control
Equipment
3.9.8 Performance Requirements-Incineration
3.10 Contractor Quality Assurance/Quality Control
3.11 Decontamination
3.12 Permitting
3.13 Chemical Analysis
3.14 Remedial Design
3.15 Community Relations Activities
3.16 Cleanup Verification for Stream Sediments
4.0 QUALITY ASSURANCE/QUALITY CONTROL
4.1 Project Organization and Responsibility
4.2 Quality Assurance Objectives for Measurement
Data
4.3 Sampling Procedures
4.4 Sample Custody
4.5 Calibration Procedures and Frequencies
4.5.1 Field Equipment
4.5.2 Laboratory Equipment
4.6 Analytical Procedures
4.7 Data Reduction, Verification, and Reporting
4.8 Internal Quality Control Checks
4.9 Performance and System Evaluation
4.10 Preventive Maintenance
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document control 85050N-0201
Page iii
4.10.1 General
4.10.2 Sampling and Analytical Equipment
4.10.3 Support Equipment
4.11 Specific Routine Procedures Used to Assess
Data Precision, Accuracy, and completeness
4.12 Corrective Action
4.13 Quality Assurance Reports to Management
5.0 HEALTH AND SAFETY PLAN
5.1 Organization and Staff Responsibilities
5.1.1 Personnel
5.2
5.1.2 On-Site Personnel
5.1.3 site Security
Work Practice Controls
5.2.1 Standing Orders
5.2.2 Site organization
5.3 site Control
5.3.1 Pit Excavation
5.3.2 stream Excavation
5.4 Safety Precautions
5.4.1 Liquids/Sludges
5.4.2 Dusts
5.4.3 Vapors/Gases
5.4.4 Physical Hazards
5.4.5 Weather Conditions
5.5 Education and Training
5.6 Medical surveillance
5.7 Ambient Field Monitoring
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page_iv
5.8 Levels of Protection
5.9 Safety Equipment List
5.9.1 First Aid
5.9.2 Fire-Fighting
5.9.3 Communications
5.9.4 Decontamination Equipment
5.9.5 Sanitation/Hygiene
5.10 Decontamination Procedures
5.11 Contingency Plans
5.11.1 Local Sources of Assistance
5.11.2 National/Regional Sources of Assistance
5.12 Amendments to site Specific Health and Safety
Plan
6.0 SAMPLING ANALYSIS PLAN
6.1
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6.7
6.8
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6.11
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Sampling Handling
Sample Identification
Sampling Procedures
Specific Sampling Procedures
6.4.1 Treated Scrubber and Stormwater Samples
6.4.2 Solidified Material
6.4.3 Incinerator Ash
6.4.4 Stream Sediments
6.4.5 Stack Sampling
Sample Custody
Equipment Decontamination
Calibration Procedures and Frequencies
Analytical Procedures
Data Reduction, Verification, and Reporting
Internal Quality Control Checks
Preventive Maintenance
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Figure
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Page v
site Plan
List of Figures
Title
GRU and Burn Pit Locations
Stream Sediment Needing Remediation
Location of Remedial Equipment and
Excavation areas
Schematic of Typical Solidification
System
Proposed Incinerator Sampling Points
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page vi
List of Tables
Title Page
Maximum Concentration of Contaminants 3-17
for the Toxicity Characteristics
Recommended Sample Containers, Preservation 6-2
and Holding Times
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Appendix
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IV
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document control BSOSON-0201
Page vii
List of Appendices
Title
Topographic Map of Site
Metal Emissions from Hazardous Waste Incineration
Air Permit Application
MSDS Ethylene Glycol
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page ES-1
EXECUTIVE SUMMARY
This remedial design report describes the engineering services
and remedial action necessary for the design of the recommended
remedial action at the Hoechst Celanese site in Shelby, North
Carolina. Westinghouse will conduct and perform all work
required as described in the work plan to prepare a remedial
design (RD) for the on-site incineration remedial action
alternative developed in the feasibility study (FS). This
alternative was selected and summarized by the U.S.
Environmental Protection Agency (EPA) in the Record of Decision
(ROD) for the Shelby site dated March 28, 1989.
The RD will provide the technical aspects of the project
including the plans, design drawings and performance
specifications needed to accomplish the remedial action
recommended in the ROD. The recommended remedial action
consists of:
o excavation of glycol recovery unit (GRU) sludges,
plastic chips, burn pit residuals and selected stream
sediments
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on-site incineration of GRU sludges and associated
contaminated soils
chemical fixation (solidification) of incinerator ash,
plastic chips, burn pit residuals, and selected stream
sediments
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page ES-2
on-site disposal of inert, solidified material
regrading and revegetation, where necessary
monitoring
This report constitutes the 30% design. The report contains
sections on Introduction, Design Basis, Preliminary Design
Specifications, Health and Safety, Quality Assurance/Quality
Control, and Sampling and Analysis. Other sections of the
remedial design such as Test Burn Plan will be contained in
later submissions.
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1.1 site Description
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Page 1-1
1.0 INTRODUCTION
The Hoechst Celanese site is a 469-acre property occupied by a
polyester resin and fiber production facility (Figure 1-1). The
site is located in south-central Cleveland County east of North
Carolina Highway 198. It is approximately 1 mile north of
Earl, North Carolina and 6 miles south of Shelby. The nearest
major city is Charlotte, North Carolina, 35 miles east of
Shelby.
The plant facilities consist of the plant production area,
wastewater treatment area, former waste disposal areas, former I sludge landfarm area, and recreation and wooded areas. The
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majority of the land surface reflects cultural modification by
construction, and by cutting and filling. The original soil
profile has probably been either truncated or covered across
much of the site, and was never conclusively identified as
undisturbed during the field investigations of the Remedial
Investigation (RI). The plant production area is predominantly
covered with buildings and paved or gravelled areas. However,
to the east, toward the wastewater treatment area, the site
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-=~--:·. '•. . .
R[P'ICl:IU:tD flOI LMXSBlltG 11/2 IIIN, llUDIWO..E 111111
~ Westinghouse Environmental ~ and Geotechnical Services, Inc.
0 .... -' --
FIGURE 1-1
SITE LOCATION MAP
HC/SHELBY
SCALE IN rur
WESTINGHOUSE PROJECT 4124-85-OSON
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 1-3
becomes more open, with the majority of the land covered by
impoundments, with grass and access roads in between. The
former sludge landfarm is north of the plant production area and
is overgrown with coarse grasses. The recreation area and
wooded area to the south have no facilities related to the plant
process.
Adjacent land use is rural; some residences are located within 1
mile of the site.
1.2 Site History and Regulatory Status
Fiber Industries, Inc., a joint venture of Celanese Corporation
and Imperial Chemicals, Incorporated, (ICI), was the original
owner of the plant and operated it from 1960 until 1983 when the
Celanese Corporation bought out ICI's share of the facility.
American Hoechst and Celanese merged in 1987 to form Hoechst
Celanese. It is now operated as the Hoechst Celanese, Shelby
Facility. Operations at the Shelby facility began in April,
1960. Manufacturing operations included the production of
polyester polymer resin and filament yarn. The principal
chemicals involved in polymer production are dimethyl
terephthalate and ethylene glycol. Other small quantity
additives include titanium dioxide and antimony trioxide.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 1-4
The Hoechst Celanese wastewater treatment plant was constructed
in phases concurrent with the manufacturing plant, and became
fully operational in the mid-1960's. In 1973, the plant was
expanded with the addition of a polishing pond, two emergency
spill ponds, and an additional aeration basin. The treated
effluent from the wastewater treatment plant is piped to a
discharge point on Buffalo Creek.
Several areas around the plant have been used for waste
disposal. Normal plant wastes (primarily polyester and
miscellaneous trash) were disposed of in old burning pits
located just north of the aeration basins. North and east of
the burning in pits, glycol recovery unit (GRU) sludge was
buried in trenches during the early 1960 1 s.
Two other areas of buried waste are located to the north of the
main plant. The polymer and fiber landfill contains primarily
non-hazardous inert materials such as excavation spoil,
construction waste and yarn. The construction debris landfill
contains items such as old cinder blocks and steel strapping
bands.
Investigation of the Hoechst Celanese site began in October 1981
when Hoechst Celanese contracted with Westinghouse to install 23
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 1-5
groundwater monitor wells. In conjunction with the groundwater
monitor well installation program, Westinghouse also conducted a
hydrogeologic evaluation. Subsequently, Hoechst Celanese
initiated a groundwater sampling and analysis program under the
supervision of Davis & Floyd Laboratories, Inc. Westinghouse
also conducted an electromagnetic survey and excavated test pits
at the site.
In October 1984, the Hoechst Celanese, Shelby Facility was
proposed for EPA's National Priorities List (NPL). Also, in
October 1984, there were a series of meetings between the EPA
and Hoechst Celanese to discuss the preparation of a Work Plan
for a Remedial Investigation (RI) and Feasibility study (FS) by
Hoechst Celanese's contractor, Westinghouse. Concurrent with
this, EPA's contractor, Camp, Dresser & McKee, Inc. (CDM),
prepared a report that included a review of the data collected
during previous site investigations and identified information
deficiencies and data gaps to provide a basis for development of
Remedial Investigation activities. These events resulted in the
submission of a draft Work Plan by Westinghouse, on behalf of
Hoechst Celanese, with the final Order on Consent to perform the
RI/FS on March 10, 1986. In June 1986, the EPA added the site
to the NPL.
The RI report for the site was final in July 1987 and
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 1-6
determined that two areas of the site needed to be addressed:
former glycol recovery unit waste pits and other adjacent
disposal pits, and groundwater contaminated by the waste in
those pits. Due to the groundwater contamination and the
potential for it to move off site, EPA approved Westinghouse's
proposal for a two-phased clean-up action. These two phases are
identified as Operable Unit 1 (OU 1), which focuses on
remediating contaminated groundwater, and Operable Unit 2
(OU 2), which addresses remediation of the sludges and soils
associated with the former glycol recovery unit trenches, of the
burn pit areas, and of specific stream sediments.
The Operable Unit FS for the groundwater was completed in
February 1988. The ROD for OU 1 Remedial Action was signed
March 23, 1988, and required extraction and treatment of
contaminated groundwater associated with the site. Hoechst
Celanese agreed to conduct the Remedial Action for OU 1 in a
partial consent Decree dated June 30, 1988. The decree has
since been entered with the Court. construction of the
extraction and treatment systems are complete, and they are
operational.
The FS for OU 2 Remedial Action was final in February 1989.
This remedial action will address'contaminant source control at
the site. A Consent Decree on OU 2 was signed by Hoechst
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 1-7
Celanese on June 19, 1989 and submitted to EPA for processing.
The selected remedial action for the Hoechst Celanese, Shelby,
Facility is outlined in the ROD and includes the following
remediation activities:
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excavation of approximately 2000 cubic yards of glycol
recovery unit (GRU) sludges. The 2000 cubic yards
includes a known GRU volume of 1500 cubic yards plus an
additional 1 foot of soil below the GRU/soil interface
excavation of approximately 1200 cubic yards of burn
pit residuals
excavation of approximately 600 cubic yards of plastic
chips
excavation of approximately 110 cubic yards of stream
sediments
incineration of GRU sludges and associated soils
chemical fixation (solidification) of incinerator ash,
plastic chips, burn pit residuals, and stream sediments
on-site disposal of solidified materials
o regrading and revegetating, where necessary
o monitoring
The anticipated date for Operable Unit 2 remedial activities is
third quarter (November), 1990, extending.the remediation
process into the second quarter (May), 1991.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 1-8
1.3 Project Objective and Scope
The objective of this phase of the project is to prepare a
Remedial Design for the source material that will remove and
treat the major source of contamination on the site, and thus,
mitigate further groundwater contamination. The remedial action
addresses the GRU material, burn pit materials, plastic chip,
and stream sediments. Included in this report are the Basis of
Design, Performance Specifications, Quality Assurance/Quality
Control Plan, Health and Safety Plan, and Sampling and Analysis
Plan. Other plans and drawings such as the Trial Burn Plan,
Monitoring Plan, and Project Operations Plan, and design
drawings and plans will be supplied at later submissions of the
design report.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 2-1
2.0 DESIGN BASIS
2.1 waste Characteristics
The GRU sludges are predominately ethylene glycol distillation
bottoms (polyester ligimers) containing lesser concentrations of
other identified and unidentified organics. The sludges
typically contain some heavy metals with antimony being the
predominant element. Antimony is present up to 6,000 mg/kg. .A
complete description of the waste is included in the Remedial
Investigation (RI) and Feasibility Study (FS).
From a study done by Westinghouse Research and Development (R&D)
and Industrial and Environmental Analysts (IEA) the following
information is estimated for the GRU material:
0 moisture -40% average range 6-40%
0 carbon -36.1%
0 hydrogen -7.8%
0 oxygen -54.8%
0 nitrogen -0.003%
0 sodium -0.004%
0 chlorine -0.03% average range 0.013-0.05%
0 ash -1. 3%
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0 lead
0 chromium
0 upper
heating
value
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 2-2
-0.75 mg/kg average range <0.02-53 mg/kg
-3.0 mg/kg average range 1.5-40.0 mg/kg
-5440 BTU/lb average range <2000-7800 BTU/lb
From IEA, the following EP Toxicity analyses are estimated for
the GRU incinerator ash:
0 arsenic -0.2 mg/kg
0 barium -< 0.1 mg/kg
0 cadmium -< 0.01 mg/kg
0 chromium -< 0.03 mg/kg
0 lead -< 0.005 mg/kg
0 mercury -< 0.0005 mg/kg
0 selenium -< 0.005 mg/kg
0 silver -< 0.05 mg/kg
Other materials to be remediated include plastic chips, burn pit
residuals, and contaminated stream sediments.
From the Expanded Characterization Study done by Westinghouse,
the following analyses are expected for the burn pit residuals:
0 moisture -23% average range 21-26%.
0 antimony -26 mg/kg average range <20-33 mg/kg
0 lead -32 mg/kg average range 9-93 mg/kg
0 chromium -238 mg/kg average range 30-490 mg/kg
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 2-3
o upper -2950 BTU/lb average range <2000-5800 BTU/lb
heating value
Stream sediments were sampled and analyzed during Remedial
Investigation (RI) performed by Westinghouse. Phthalate
concentrations in the stream sediments range from 1,500 to
13,000 ug/kg. Polynuclear aromatic hydrocarbon (PAH) compounds
in the stream sediments were elevated at levels ranging from
1,400 to 10,000 ug/kg. The sediments also contain high
concentrations of organic compounds.
2.2 waste Volumes
Volume estimates of the GRU, burn pit materials, and plastic
chips (collectively known as the source material) were made
based on data obtained from the test drilling and trenching
operations. The volume estimates for the in-place materials are
1800 cubic yards (cy) for GRU material, 1200 cy of burn pit
materials and 600 cubic yards of plastic chips and 110 cubic
yards of stream sediments. These estimates include a 20%
contingency to account for removal of adjacent soils and
inaccuracy in the estimating. Figure 2-1 shows the approximate
location of GRU and burn pit materials. Figure 2-2 shows the
approximate location of stream sediments requiring remediation.
The EPA Record of Decision and subsequent agreements require the
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NO AH
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NOTE
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) \ a i RECREATION' ~ l POND '
~""=,-0
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THE BURN PITS, GLYCOL RECOVERY
SLUDGE PITS AND AREA OF GRU SLUDGE
TRACKltJG WERE 1 AXEN FROM HISTORIC,6.J_
AERIAL PHOTOS.
DR .... WN Bl
0£Cl([0 DY
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Westinghouse Environmental
and Geotechnical Services, Inc.
- - -
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LEGEND
• EXISTING MONITOR WELL.
~ BURN PIT
E -EQUALIZATION BASIN C -CLARIFIER
D -DIGESTER
PB AERATION BASIN
SP SLUDGE POND
EP EMERGENCY POND
PP POLISHlNG POND
,.
IOU l■ft!I
FIGURE 2-1
GENERAL WAS TEW ATER PLANT AREA HC/SHELBY N.C.
TREATMENT
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.,,,. . •
( PLANT PROOUCTION AREA
·-·,
C
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D
·, ·,
~ Westinghouse Environmental
"@ and Geotechnical Services, Inc.
·,
ION
~-PROPERTY
LINE
·,. 1/. ,------.,.-\
NOTE, DARKER STREAM SEGMENTS
INDICATE THOSE REQUIRING
REMEDIATION
400 800 -' - -SCALE lN FEET
FIGURE 2-2
STREAM SEGMENTS NEEDING REMEDIATION
HC/SHELBY N.C.
WESTINGHOUSE PROJECT 4124-85-OSON
45O5ONO4
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Operable Unit 2 ·30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 2-6
GRU material to be removed and incinerated to the GRU-soil
interface on the sides and to the GRU-soil interface plus 1 foot
on the bottom, approximately 2000 cubic yards. A thorough
discussion of the volume calculations and area cross-sections
are included in the FS for Operable Unit 2.
2.3 waste Treatment Processes
Thermal treatment of the GRU materials will be accomplished
using a rotary kiln incinerator with a primary and secondary
combustion chamber and air pollution control device(s).
Additionally, the thermal treatment system will consist of
materials handling equipment, control room, other ancillary
equipment for routine operation.
With prior EPA approval, the plastic chips, burn pit residuals,
and contaminated stream sediments may be blended with the GRU
waste to provide a more uniform feed to the incinerator, or may
be excavated and solidified prior to reburial on site. Final
disposal of all solidified residuals will be in one section of
the present disposal area. Incinerator ash will be solidified
prior to disposal.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-1
3.0 PRELIMINARY DESIGN CRITERIA
AND PERFORMANCE STANDARDS
3.1 Definitions
Owner: Hoechst Celanese
Shelby, North Carolina
Engineer: Westinghouse Environmental
and Geotechnical Services, Inc.
Contractor: GDC Engineering, Company
3.2 Pre-Excavation site Investigation
In order to facilitate the cleanup of the Hoechst Celanese site,
site investigations will be conducted to document the
I pre-excavation site conditions. Using the services of a
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registered land surveyor in the state of North Carolina, the
area will be surveyed to one foot contours. Specific emphasis
will be placed on identifying routes of surface drainage.
This information will be used to support the surface drainage
management plans. Limited foundation investigations will be
conducted in the staging area to determine suitability and
design parameters for supporting various components of the
incinerator. A survey of stream sediments will be conducted to
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-2
aid in the determination of sediment quantity and locations so
that the removal strategy can be finalized. The survey will
consist of using a base topographic map (1 in.= 200 ft) and
walking the stream to identify the areas of maximum sediment
I deposition. These areas will then be identified on the base
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topographic map. Once they are identified, estimates of size
and depth will be made. This information will be used to select
load-out points for the sediment removal operations.
Baseline air monitoring will be conducted for 2 to 4 weeks prior
to remediation activities for constituents of concern as
identified in the site Health and Safety Plan. Air monitoring
will be conducted in the activity areas as well as along the
site perimeter and will be used as screening to determine
I appropriate level of protection. Data from the air monitoring
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will be used to quantify ambient conditions prior to initiation
of site remediation activities.
3.3 site work
3.3.1 Clearing and Grubbing
Prior to start of excavation of contaminated materials, the
source area and the designated construction area will be
prepared by clearing and grubbing topsoil and vegetation from
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-3
the source area, stockpile areas, treatment area, storage area,
the facility structure areas, and new haul roads. Topsoil and
vegetation from cleared areas will be stockpiled. This material
will be later reused as backfill for final fine grading and
backfill over solidification material to promote grass growth.
Prior to the clearing and grubbing activities, the limits of the
administration area, stream sediment area, stockpile area, waste
water storage area, incineration and solidification areas, and
haul roads will be established. Included in this activity will
be the establishment of the drainage and runoff control, access
roads, and utility corridors associated with the facility
structures. In addition, specific stockpile areas will be
designated for GRU sludge material and non-GRU waste material.
3.3.2 stream Sediment Excavation
The contaminated stream sediments are generally located in the
bends of the creek bed as it winds down the drainage. The base
of the stream bed is exposed rock which is washed clean of
sediment build-up for many sections. The sediments washed from
the rock have been deposited in the eddies and still basins
along the stream. Prior to remediation, the Contractor will
survey the stream to identify areas of sediment. Based on this
information, access points will be identified for approval by
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the Engineer.
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-4
The type and nature of the deposits allow specialized removal
techniques rather than standard methods such as backhoe and dump
truck.
The Contractor will utilize high pressure hoses to slurry the
sediment. A vacuum truck will be used for "spot removal" of the
alluvial deposits identified as contaminated. Flexible vacuum
hose can be extended a maximum of 400 feet from the truck and
require no equipment for movement of the intake end of the
hose. The truck will be able to utilize existing accesses to
reach in other areas. Much of the sediment deposits with
limited clearing needed.
The excavation of the sediments will start at the upstream end
of the stream, working down the drainage so cleaned areas are
above contaminated areas. The procedure is to block off a small
section of the drainage, set up a pump and bypass pipeline, and
begin the washing process. After sediment removal is complete,
the system will be moved downstream to the next section of the
drainage. This procedure will be repeated as necessary until
the entire segment is cleaned. Downstream contamination will be
minimized locally at each sediment deposit using a darn. This
approach will minimize the potential for the recontamination of
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-5
cleaned areas or movement of contamination to downstream clean
areas. Once the stream sediments have been removed, the water
will be treated and discharged to Hoechst Celanese's water
treatment system.
This approach requires that remediation be timed to coincide
with the dry periods to limit the need for major diversion of
the surface water. Temporary or contingency water diversion can
be accomplished by use of a temporary upstream dam and sump with
pumping as needed. The discharge water could be pumped via a
temporary PVC pipeline or discharge hose to a point the ravine
below the active area of sediment removal.
3.3.3 Performance criteria
During the site work, particularly the handling of contaminated
material, the Contractor will be required to take precautionary
measures to eliminate nuisance or hazardous dust conditions.
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I chemical treatment. EPA approved dust suppressants may be
applied to all piles of stored soils. Active excavation areas
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and treatment areas will be treated with dust suppressants on an
as-needed basis.
Particular attention will be given to the excavation of the
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-6
stream sediments. During excavation of the sediments, the
stream will be diverted to limit downstream migration of
I contaminants. A topographic map of the area is included as
Appendix I.
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1-
3.4 Area Requirements
The thermal treatment equipment required for this project is
expected to occupy an area of approximately 100 feet by 100
feet, including operational clearances around the equipment.
The GRU area requiring remediation and area available for the
treatment equipment is shown as Figure 3-1.
Other areal requirements proximate to the remediation area
include, but are not limited to, the area for stockpiling
contaminated soils for incineration or solidification, the
storage of construction equipment and supplies, and stockpiles
of supplemental clean backfill material. The areas for
equipment and stockpiles will be designated at the 60% design
submission. These areas will utilize structures or materials to
protect against the weather, particularly rain, to improve
operations and limit weather delays.
3.5 Spill Prevention Measures
Spill prevention measures will be performed and monitored by
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.,j \ ' I :::--' \ ( ...............
---'----830 \\ .......... ,,
I I
1GIJ7
,, ,, ,, LJ ,, ,, ,,
El ,,
~ Westinghouse Environmental
~ and Geotechnical Services, Inc.
''°
... :: POUSHNo::::
POND •2:::
§00 ...... . . . . . .
8
· : : : POLJSHNG; : ·
FIGURE 3-1
APPROXIMATE LOCATION OF TREATMENT
EQUIPMENT AND EXCAVATION AREAS
HOECHST CELANESE -SHELBY, N.C.
WESTINGHOUSE PROJECT 4124-85-OSON 5O5ONO1.DGN
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document control 85050N-0201
Page 3-8
site personnel whenever the potential exists, and/or the
contamination of clean areas occurs as a result of spills of
potentially contaminated soil. Spill prevention will be
accomplished with the use of standardized protocols for each
remedial operation, and spill response actions which limit the
effects of spills by use of engineered controls.
Spill potential will exist at essentially every phase of source
remediation. All material and debris resulting from
contaminated soils removal will be immediately contained and
stockpiled for incineration or solidification. The method of
containment will minimize the potential for spillage as a result
of heavy equipment operator error and accidents occurring during
the transport and stockpiling of contaminated materials.
Effective spill controls will be employed.
3.6 Environmental controls
Environmental effects including heat, dry soil conditions, wind,
and rain can potentially result in changes in ambient air
quality (entrainment of dust, volatilization, and spread of
contamination to otherwise uncontaminated areas (surface
run-off). Engineered controls include wetting dry surfaces,
constructing berms or sediment nets across drainage paths, and
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-9
totally encapsulating containment devices for stockpiled soils
to prevent the infiltration of precipitation. Routine
inspections will be made to assess the conditions and
effectiveness of the controls. since there are residents
adjacent to the plant site, noise and night remediation
activities should be minimized.
Rainwater will not be allowed to accumulate in holes created as
a result of excavation. As soon as possible, holes created by
the removal of contaminated materials, will be refilled with
solidified material, uncontaminated soil, be covered with a tarp
or other material or use of another acceptable technique to
prevent the accumulation of rainwater.
Excavation area control measures will be detailed in the
Contractor erosion control plan and instituted prior to start of
construction. Those measures will be modified or upgraded, as
needed, throughout the construction activity. Efforts to
minimize erosion and to control storm water during site
preparation and excavation activities will include the use of
hay bales or fabric filters. Waste material for solidification
will be deposited in the stockpile areas where it will be bermed
and covered with plastic to protect it from rainfall. The area
will be shaped to permit and facilitate surface water runoff to
a collection system. Drainage ditches and/or intercept berms
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-10
will be provided as necessary to control surface water runoff.
Similar methods will also be used around the excavation areas
such that the area around the excavation shall have a berm to
I preclude surface water entering the excavation. Sumps and
collection points will be capable of pumping water to the I storage tank for treatment prior to discharge.
I Stockpile areas will be covered and have secondary containment
I with a sump to collect rainfall run-off. water collected as a
result of run-on or run-off will be treated to the National I
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Pollutant Discharge Elimination System (NPDES) limits prior to
discharge. The treated water will be discharged to the
wastewater polishing pond or used as make-up water for
solidification.
3.7 Materials Handling
Based on experience from the RI and FS, it appears that all
wastes can be removed with conventional construction equipment
such as backhoes or front end loaders. Also, since the burn pit
and GRU materials are in generally discrete areas, they should
be excavated with only a minor amount of adjacent soil or waste
type being removed along with the material planned for removal.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-11
Site exploration at the site identified that the burn pit
material was a mixture of black stained soil and construction
scrap that had been co-disposed with GRU material. The
construction scrap was crushed drums, steel strapping, and other
miscellaneous material. The construction scrap lends itself to
mechanical separation.
Material handling equipment will be operated in a manner to
limit spills and fugitive dust emissions and minimize noise and I offensive odors. The removal of dry particulates may call for
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special attention to fugitive dust emissions. Material handling
and waste feed systems shall be provided which are capable of
conveying and/or pumping and/or screw feeding contaminated soils
separately or in combination (e.g., mixing supplemental fuel
with soils to enhance their handling characteristics) with the
thermal treatment unit. The soil feed system capacity shall be
consistent with the incinerator feed capacity and the production
burn schedule. The material handling and feed system shall
include the provision for the collection of samples for feed
composition and feed rate determination.
The .Contractor will detail in his proposal the material handling
equipment to be used, proposed mixing method for waste feed,
material handling methods and other pertinent information
regarding material handling.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document control 85050N-0201
Page 3-12
3.8 Solidification
3.8.1 General
The terms "Solidification and Stabilization" are used to
describe a treatment process designed to accomplish one or more
of the following: a) improve handling and physical
characteristics of the waste, b) decrease the surface area
across which transfer of loss of contained pollutants can occur,
c) limit the solubility of, or to detoxify, hazardous
constituents contained in the waste.
Solidification/stabilization can be accomplished in many ways.
The following are the major waste fixation systems:
0 cement-based processes
o pozzolanic processes
0
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thermoplastic techniques
organic polymer techniques
surface encapsulation techniques
self-cementing techniques
o glassification
3.8.2 Process Description
Waste feed from the solidification stockpile will pass through a
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-13
mechanical separation process to separate out oversize I construction rubble, strapping, drums and other materials which
I could adversely affect the solidification process. All oversize
material will be decontaminated with high pressure steam and
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backfilled in the excavation in a designated area. Materials
passing through the mechanical separator (undersize) will be fed
onto the pugmill weigh belt. The solidifying agent(s) will be
added to the pugmill to create the design mix for stabiliza-
tion. After the specified mix time, the material will be belt
discharged to a truck, transported to the northern end of the
plant area excavation, and spread to cure in a cell.
Once the solidification process is approved by the Engineer, the
Contractor will initiate production operations. The non-GRU and
incinerator ash stream will be stabilized through the pugmill.
Stabilized waste will be sampled and trucked to the waste
excavation. Each day's production will be backfilled in a
designated fill area in the excavation. Should the Toxicity
Characteristic Leaching Procedure (TCLP) or ethylene glycol
tests not meet the specification requirements, the designated
location placement method will allow for its isolation, removal
and pretreatment if necessary.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-14
3,8,3 Solidification Demonstration Test
For the purpose of the design and for the Contractor selection
process, it is assumed that a 20% admixture of cement to source I material will be sufficient to meet the performance goals. In a
manner similar to the Test Burn, the Contractor will perform I solidification demonstration test(s) to determine the
I appropriate solidifying agent and admixture. The Contractor
solidification pugmill and ancillary equipment will be mobilized
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to the site, erected and installed in accordance with the
approved Remedial Design. Mechanical separation and feed system
to the pugmill will be installed on the prepared foundations.
Utilities will be installed and start-up and demonstration test
will be conducted at the Engineer's design mix for non-GRU I wastes material type and incinerator ash. The mix proportions,
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and operation conditions and rates will be recorded. Test
samples of each mix will be taken and Toxic Characteristics
Leaching Procedure tests and ethylene glycol concentration tests
will be performed. The concentration of ethylene glycol will be
limited to less than 1 mg/1. Adjustments will be made to the
solidification mix by the Engineer until these parameters are
achieved for the range of wastes believed to exist in the
stockpile. The Contractor will prepare a mix demonstration test
report to document the solidification performance testing.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-15
3.8.4 Performance Requirements-Solidification
Burn pit residuals, plastic chips, stream sediments, and
incinerator ash will be solidified prior to backfilling in order
I to ensure remediation goals are met. Quality assurance/ quality
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control samples of the soils will be tested for Toxic
Characteristic Leaching Procedure parameters and ethylene
glycol. Table 3-1 lists the TCLP parameters. In order to
provide for recoverability of a day's mix, should it not pass
these tests, each day's mix production will be placed back into
the excavation in a staked-off and demarked "cell" so that it
can be recovered and resolidified, if necessary. Solidified
material failing the TCLP parameter analysis will be excavated
and returned for further solidification treatment. Solidified
material will be considered failing TCLP parameter analysis when
the leachate exceeds the levels listed in Table 3-1 or the
ethylene glycol concentration exceeds 1 mg/1. Additional
details on solidification will be supplied by the contractor in
later design submittals.
Figure 3-2 shows typical solidification control and process
equipment. Actual equipment may be different than that shown.
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--- -
~
/ ·---'\. /;>
·:~ ':-·:
DRA'"N BY
Cl-£CKEO IIY
- --
DOUBLE
SCREW
FEEDER
• HOPPER
-----
-+J-Jll--REAGENT SILO
Westinghouse Environmental
and Geotechnical Services, Inc.
PUGMILL
WEIGH BELT CONVEYOR
POWER GENERATOR
AIR COMPRESSOR
----
FIGURE 3-2
SCHEMATIC OF A TYPICAL
SOUDIFICATJON SYSTEM
HC/SHELBY N.C.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-17
TABLE 3-1
MAXIMUM CONCENTRATION OF CONTAMINANTS
FOR THE TOXICITY CHARACTERISTICS
contaminant
arsenic
barium
benzene
cadmium
carbon disulfide
carbon tetrachloride
chlordane
chlorobenzene
chloroform
chromium
o-cresol+
m-cresol+
p-cresol+
2,4-D
1,2-dichlorobenzene
1,4-dichlorobenzene
1,2-dichloroethane
1,1-dichloroethylene
2,4-dinitrotoluene
endrin
heptachlor (and its hydroxide)
hexachlorobenzene
hexachlorobutadiene
hexachloroethane
isobutanol
lead
lindane
mercury
methoxychlor
methyl ethyl ketone
ni tr·obenzene
pentachlorophenol
phenol
pyridine
selenium
silver
tetrachloroethylene
2,3,4,6-tetrachlorophenol
toluene
toxaphene
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Final Toxic Characteristic
Regulatory Level (mg/1)
5.0
100.0
0.5
1.0
400.0
0.5
0.03
100.0
6.0
5.0
200.0
200.0
200.0
10.0
300.0
7.5
0.5
0.7
0.1
0.02
0.008
0.02
0.5
3.0
1000.0
5.0
0.4
0.2
10.0
200.0
2.0
1.0
100.0
4.0
1.0
5.0
0.7
100.0
1000.0
0.5
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-18
TABLE 3-1
MAXIMUM CONCENTRATION OF CONTAMINANTS
FOR THE TOXICITY CHARACTERISTICS
(Continued)
contaminant
trichloroethylene
2,4,5-trichlorophenol
2,4,6-trichlorophenol
2,4,5-TP (Silvex)
vinyl chloride
Final Toxic Characteristic
Regulatory Level (mg/1)
0.5
400.0
2.0
1.0
0.2
+ o-,m-, and p-cresol concentrations are added together and
compared to the threshold.
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3.9 Thermal Treatment
3.9.1 General
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Page 3-19
Incineration is an engineered process that uses thermal
decomposition via oxidation to convert a waste to a less bulky,
toxic or noxious material. The principal products of
incineration from a volume standpoint are carbon dioxide, water,
and ash, while the products of primary concern due to their
environmental effects are compounds containing sulfur, nitrogen,
halogens, and heavy metals.
If the gaseous combustion products of incineration contain
undesirable compounds, secondary treatment such as after
burning, scrubbing, or filtration is required to lower their
concentrations to acceptable levels prior to atmospheric
release. The solid and liquid effluents from the secondary
treatment processes may require treatment prior to ultimate
disposal. The variables having the greatest effect on the
complete oxidation of the wastes are waste combustibility,
residence time, flame temperature, and turbulence in the
reaction zone.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-20
There are several types of categories of incinerators available
today that may be used to thermally decompose hazardous
materials. These include:
o multiple-hearth furnace
o fluidized-bed incinerator
0
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liquid-waste incinerator
waste-gas flare
direct-flame incinerator
o catalytic combustor
0 rotary kiln
o wet-air oxidation unit
0
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molten-salt incinerator
multiple-chamber incinerator
ship-mounted incinerator
From the Feasibility Study, it was determined that rotary kiln
incineration was the appropriate technology for the wastes at
the Hoechst Celanese, Shelby Facility.
3.9.2 Description
The rotary kiln incineration system proposed for the Shelby
Facility consists of a feed system, a rotary kiln, a secondary
combustion chamber, and an air pollution control system. The
rotary kiln is a direct rotating chamber that volatilizes
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
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the organics in the waste material. The secondary combustion
chamber utilizes supplemental fossil fuel to maintain
destruction temperatures up to approximately 2200 degrees
Fahrenheit. The combustion off-gases from the secondary chamber
go into the air pollution control system for quenching and
particulate removal before exiting the system through the
exhaust stack.
Waste/soil mixture is continuously supplied to the rotary kiln
by a feed system consisting of a transfer belt conveyor, hopper
conveyor, and a screw feeder. By adjusting the speed of the
feed screws, the feed rate to the kiln can be controlled within
the desired range.
The rotary kiln is a inclined refractory-lined cylinder which
turns about an axis inclined 2 to 4 degrees from the
horizontal. The kiln rotates, continually exposing the waste
material surfaces to the heat and oxygen as the feed moves
through the chamber. The kiln utilizes a fossil fuel burner to
vaporize the moisture and organic contaminants, and remove them
from the waste feed. The volatiles are partially burned in the
kiln and then pass into the secondary combustion chamber. The
combustion residue and ash exits the kiln through a wet ash
collection system that minimizes ingress of ambient air.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
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The exhaust gases from the kiln enter the secondary chamber
where they are heated up to 1800 to 2200°F by a fossil fueled
burner and combustion air control system. Contaminants in the
flow stream are destroyed by the conditions that prevail in the
secondary combustion chamber.
Waste gases from the secondary combustion chamber are processed
in an air pollution control system. Resulting gases are
released to the environment, and wastewater and sludge are
I treated on site before discharge. An elaborate system of
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instrumentation and sampling provides feedback to the operator
so that the incineration process will operate within specified
clean air standards. The system's operation will be documented
as required by EPA and state regulatory agencies.
3.9.3 Thermal Test Burn
Before the Hoechst Celanese, Shelby Facility can be remediated,
a test burn will be performed to prove the thermal treatment
system's capability of meeting the cleanup objectives while
operating within the environmental constraints.
The test burn task is the consummation of a long series of
construction activities directed at site installation, erection,
and start-up of the thermal treatment units. The first phase of
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-23
the test burn activity is erection of the thermal treatment unit
and ancillary systems. Equipment and materials will arrive at
the site and will be erected and installed on the prepared
foundations. Utility hookups will be made and the pre-assembled
system modules will be "plugged" together. Initial warm-up and
system start-up activities will conclude the preparation
activities for the test burn.
Once the system has been proven out, the contractor will, with
the overview of the Engineer, EPA, and the State Air Division,
conduct, in accordance with 40 CFR 270.62 and 264.343 and the
Test Burn Work Plan, a series of performance tests known as the
test burn. The Test Burn Work Plan will contain a description
of all pertinent systems and sub-system components (i.e. air
pollution controls, thermal unit, feed system, etc.), sampling,
and analytical work.
During the test burn, GRU sludges will flow through the feed and
preprocessing systems into the incinerator. Primary and I secondary incineration wfll occur under extreme conditions. Ash
handling and collection, gas scrubbing, and air pollution
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control systems will all be operated and monitored through the
Contractor's instrumentation and control system. During the
burns, operating conditions will be recorded, and samples of ash
will be collected and analyzed for specific parameters.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-24
Adjustments to the throughput, temperature, pressure, combustion
concentrations, preprocessing, and other operational
characteristics will be made until the following performance
parameters are met:
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destruction removal efficiency (DRE) >99.99%
(ethylene glycol and trichloroethylene)
particulate emissions <180 mg/dscf
(corrected to 7% oxygen in gas)
hydrogen chloride emissions (HCL) < the greater
of 4 lb/hr or
1% untreated
stack gas level
antimony removal* >96% *
Appendix II details antimony emissions calculations
Results from the test burn will provide pertinent data on the
thermal treatment unit while operating under extreme conditions
(i.e. minimum temperature, maximum feed rate). The validity and
reliability of the test data are assured through the use of
approved procedures such as those outlined by the QA/QC plan
which is submitted with or prior to the Test Burn Plan. The
Test Burn Plan will specify the number and duration of tests
which typically consist of a minimum of three test runs, taking
approximately 8 hours each, using the same waste feed with each
test and using a different set of operating conditions. A
prerequisite for the test burn is the control of a uniform
hazardous constituent concentration in the feed so that a
reliable DRE may be determined. For the test, the Contractor
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-25
will provide a uniform supply of GRU material which has been
sampled and analyzed to establish the concentrations of the
waste constituents used in calculating the DREs. The Test Burn
Plan will be developed by the Contractor with the assistance of
the Engineer and submitted in a subsequent revision to the
remedial design.
The Contractor will document all operational conditions, perform
all required sampling and analyses, and submit a Test Burn
Report to the Engineer for his review and submittal to the state
and EPA. The Engineer will review the test burn data and
determine if acceptable DREs and other operational parameters
were achieved.
If acceptable DREs and operating parameters were not achieved,
the Engineer will not approve the thermal treatment unit for
full-scale operation. The results of the test burn shall be
analyzed and causes of deficiencies evaluated. The Contractor
shall make the required changes to the thermal treatment unit or
his operational procedures to bring the thermal treatment unit
in compliance with the specified operating parameters and DREs.
A second test burn shall then be performed by the Contractor.
Upon successful completion of a test burn, the Engineer with EPA
concurrence will approve full-scale operation contingent on
specified operating conditions as developed from the test burn.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-26
The testing of the unit will conclude, as specified by the Test
Burn Plan, with a report which presents and summarizes the
collected data and all of the relevant calculations. A complete
report of the test burn will be prepared by the Engineer and be
presented to the EPA following the completion of the test burn
and receipt of analytical results. While waiting for the sample
analyses results, the incinerator will be operated in a manner
most likely to ensure compliance with the performance standards
not to exceed 720 hours.
Commencement of full-scale incineration of the GRU materials
will depend on the evaluation and approval period required by
the governing agencies for the formal acceptance or rejection of I the planned remedial action; however, other remedial activities
I will proceed in the interim period. The Engineer will prepare
the report on the test burn and submit it to the EPA for
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approval.
3.9.4 Monitoring
The incineration system will be monitored for combustion
temperature, waste feed rate, combustion gas velocity, oxygen
concentration, carbon monoxide and carbon dioxide
concentration. POHCs and metals will be monitored during the
trial burn. The proposed sampling points and parameters to be
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Operable unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-27
measured are shown as Figure 3-3.
During site remediation, the operation and performance of the
thermal treatment system will be centrally monitored from the I control room. All pertinent flow rates (e.g., feed rate,
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exiting residue, cooling water), operating temperature (e.g.,
primary and secondary chambers, exiting stack gas) and
combustion gas concentrations (e.g., oxygen, carbon monoxide,
carbon dioxide) must be recorded continuously and the records be
made available for inspection. Deviations from operating
conditions will be identified by an alarm, and if specified
regulatory conditions are violated or major system upsets occur,
all waste feed will be stopped immediately.
3.9.5 Ancillary Functions
Automatic cut-off devices must be in place. All waste feed will
be stopped when deviations from operating conditions, levels
above regulatory limits, or major system upsets occur.
The Contractor will prepare operations and emergency manuals to
cover routine operations of the plant, and indicate the
appropriate response to be taken during system upset and
operational deviations. The Contractor will ensure operators
are given adequate training before being assigned to operational
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MATERIAL HANDLING
AND WASTE FEED SYSTEM
SOLi OS
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POHC
ASH BTU
-
ASH CONVEYOR
ANO COOLER
TEMPORARY
ASH STORAGE BIN METALS
DE~ IIY
DR,t,.WN BY
0£Cl<ED DY
n.E ~o. •50-2
- -
EMERGENCY
COMBUSTJON SYSTEM
... ✓.D.
'· AIR ®'
~FUEL
om
RECYCLE
WATER
OR WASTEWATER
DISCHARGE
--- -
J, AIR
~
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WATER TREATMENT
Westinghouse Environmental
and Geotechnical Services, Inc.
T
SECONDARY COMBUSTION
CHAMBER
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CONTROL SYSTEM
, -_L,f ~--;
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TEMPORARY SLUDGE
STORAGE BJN
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TEMPORARY SLUDGE
STORAGE BIN
STACK
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POHC PARTICULATE ~-----j METALS
02, CO2• CO
STACK
SAMPI. JNG
I NDUCEO FAN
PARTICULATE
COLLECT I ON
GASES
,hiGEND CD TEMPERA TUR[
0 FLOW
® PRESSURE
@ OXYGEN
-
l.',,P DIFFERENT JAL PRESSURE
FIGURE 3-3
PROPOSED SAMPLING POINTS
INCINERATOR PERFORMANCE
HG/SHELBY N.C.
FOR ASSESSING
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-29
duties. All employees assigned to remediation activities will
have 40-hour health and safety training and have current medical
monitoring consistent with 29 CFR 1910.120.
3.9.6 Operations Manual
The Contractor shall prepare an operations manual which shall be
submitted to and approved by the EPA and Engineer. The
operations manual shall include, but not limited to, the
following:
0 procedures for the routine operation of the thermal
treatment unit
the o a section covering procedures which shall indicate
appropriate response to be taken under emergency
conditions (i.e., partial or complete stoppage of
auxiliary fuel feed to all or one burner, partial
complete stoppage of GRU feed, puffing or sudden
occurrence of fugitive emissions, combustion
temperature too high or too low, etc.)
or
3.9.7 Thermal Treatment Unit Pollution Control Equipment
The pollution control equipment used must limit particulate
emissions to 180 mg/dscf (corrected to 7% oxygen in the exhaust
gas) and remove greater than 96% of the antimony in the feed.
Scrubber water effluent, if discharged, must meet OCPSF
guidelines.
The Contractor will detail the air pollution controls for the
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-30
thermal treatment unit including a description, specifications,
drawings, and utility requirements. The Contractor will
identify the air pollution control residues, and treatment, and
ultimate disposal plans for solids, sludges, and liquids.
Complete specifications shall be provided on the wet scrubber
system. This includes, but is not limited to, scrubber type,
construction materials, design ranges of air and liquid flow
rates and location and method of operational controls. The
Contractor will provide a complete description of the scrubber
wastewater treatment system (if utilized). The Contractor will
describe disposal techniques for spent scrubber water, other
wastewaters, and sludges. These items will be included in
subsequent submittals.
3.9.8 Performance Requirements-Incineration
The incineration system will be operated in accordance with the
technical requirements of RCRA performance standards as
specified in 40 CFR 264.343.
The requirement for destruction removal efficiency (DRE) for
ethylene glycol and trichloroethylene is greater than 99.99%.
These are the principal organic hazardous constituents (POHC)
planned for this project.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Page 3-31
Particulate emissions must be less than 180 mg/dscf or 0.08
grains/dscf (corrected to 7% oxygen in the flue gas).
Hydrogen chloride (HCl) emissions are limited to 4 lb/hr or 1%
of the untreated stack gas level, whichever is greater. It is
anticipated that scrubbing to limit hydrogen chloride emissions
is not required because of the low chlorine content of the GRU
material.
Effluent gas discharged will be controlled to meet all
applicable federal and state environmental regulations. The
incineration system will be operated in negative pressure mode
to limit fugitive emissions.
For antimony emission controls, it is assumed that all antimony
in the feed is volatile and is present in the secondary chamber
exhaust gases. To comply with the "Guidance on Metals and
Hydrogen Chloride Controls for Hazardous Waste Incinerators",
EPA, March 2, 1989, it is planned that more than 96% of the
antimony in the feed will be removed from the exhaust gases.
Scrubber water collected from air pollution control equipment
must be reused or treated to meet Hoechst Celanese's NPDES
discharge requirements. Treated scrubber water will be
collected and analyzed for the parameters listed on the National
Pollutant Discharge Elimination System (NPDES) prior to
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-32
discharge. The treated water will be discharged into the
polishing ponds prior to the NPDES outfall.
3.10 contractor Quality Assurance/Quality Control
Throughout the remediation of the Hoechst Celanese, Shelby
Facility, a quality assurance and quality control (QA/QC) plan
will be used by the Contractor. The Contractor will develop a
QA/QC plan for use on remediation activities. The QA/QC plan
will be prepared in accordance with EPA's Interim Guidelines and
Specifications for Preparing Quality Assurance Project Plans.
The QA/QC plan will include information on the following
elements:
o sampling and analysis
o sampling procedure
o chain-of-custody requirements
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equipment calibration
analytical procedures
data reduction, validation, and reporting
internal quality control checks
performance and system audits
procedures for assessing data precision, accuracy, and
completeness
corrective action
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-33
Implementation of this plan will assure that the remedial action
is implemented properly and that adequate samples are taken and
appropriate analyses performed to provide valid and reliable
data.
J.11 contractor Health and Safety
The Contractor will develop a site health and safety plan in
accordance with 29 CFR 1910.120. Its purpose will be to
establish requirements for protecting the health and safety of
operating personnel during all activities at the site. The plan
will contain safety information, instructions and procedures,
and exclusion zone designations, and will be periodically
reviewed by the Contractor. The Engineer and Hoechst Celanese
will review and modify the plan, as needed, and submit it to EPA
for approval. The Health and Safety Plan will include the
I following elements:
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work practice controls
site controls
safety precautions
job activities
education and training
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Westinghouse Project 4124-85-0SON
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medical surveillance
ambient field monitoring
levels of protection
list of safety equipment
decontamination procedures
contingency plans
3.12 Permitting
In accordance with 40 CFR 300.68(a) (3), a federal Resource
Conservation and Recovery Act (RCRA) permit is not required on
an on-site Superfund remedial action pursuant to Section 106 of
the Superfund Amendment and Reauthorization Act (SARA).
However, SARA does contain provisions which require remedial
actions to meet all legally applicable or relevant and
appropriate standards. Performance standards are specified
under RCRA for hazardous waste incinerators and these standards
will be achieved during the operation of the thermal treatment I unit. However, the site may require a State air quality permit I for incineration activities. For this submittal, it is assumed
that an air permit is required, The Contractor will supply
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information and fill out the appropriate paperwork to obtain a
State air quality permit. A copy of the air quality permit
application is included as Appendix III. Discussions with the
Corps of Engineers indicate that a 404 permit for stream
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 3-35
remediation is not required.
3.13 Sampling and Analysis
The Contractor will develop a Sampling and Analysis Plan in
accordance with the EPA Region IV Standard Operating Procedures
and Quality Assurance Manual (SOPQAM). The Engineer and Hoechst
Celanese will review and modify the plan, as needed, and submit
it to EPA for approval.
The Sampling and Analysis Plan will include information on the
following elements:
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sample identification
sampling procedures
specific sampling procedures
sample custody
equipment decontamination
calibration procedures and frequencies
analytical procedures
data reduction, verification, and reporting
internal quality control checks
preventive maintenance
specific routine procedures used to access data,
precision, accuracy, and completeness
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3.14 Remedial Design
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 3-36
Hoechst Celanese has been directed to develop and submit to the
EPA 30%, 60%, 90%, and final design packages. Information
contained in this submittal constitutes the 30% design. The
Engineer will develop the design submittals with the support of
the contractor for the 60%, 90%, and final designs. Drawings
will include, but are not limited to, equipment drawings, site
layout, scrubber and stormwater treatment plans, if required,
backfilling plan, and schedule. Also, design specifications
will be developed for treatment and operation. The Engineer
will be EPA's focal point regarding questions about the design
submittals.
3.15 community Relations Activities I
I The Contractor may be asked to participate in community meetings
I regarding remediation activities. In the past, there have been
5 public meetings and 2 informal meetings in the community
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activities may be the subject of community meetings.
3.16 Cleanup Verification for stream Sediments
The EPA Record of Decision states that stream sediments will be
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Westinghouse Project 4124-85-050N
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removed in those stream sections identified in the Feasibility
study. To ensure that all contaminated stream sediments
exceeding cleanup criteria have been recovered for treatment,
verification samples will be collected and analyzed for the
appropriate parameters. Verification sampling will be performed
by the Engineer and analyzed for TCL organics (See Section
6.4.4). Additional stream sediments will be removed if the
cleanup criteria are not met. The action guidelines for soils
exceeding the cleanup goals will include the collection of
additional grab samples to better define the excavation
requirements.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
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Page 4~1
4.0 QUALITY ASSURANCE/QUALITY CONTROL
4.1 Project organization and Responsibilities
Westinghouse Environmental and Geotechnical Services, Inc.
(Westinghouse) will be the engineers of record for the source
remediation design at the Shelby facility. The project will be
under the direction of Mr. Everett w. Glover, Jr., P.E., and he
will be supported by Messrs. Alan M. Lubell, P.E., and Philip
Shipley of Westinghouse and Mr. William R. Carter, P.E. of
Hoechst Celanese (HC). Analytical services will either be
provided by Industrial a~d Environmental Analysts, Inc., (IEA)
or Davis and Floyd, Inc. Credentials for Westinghouse, IEA, and
Davis and Floyd, Inc., were submitted with Westinghouse Document
Control 85050H-0123, dated October 25, 1988, and the reader is
referred to the referenced document for details.,
The quality assurance auditing and monitoring will be conducted
by both Westinghouse and HC. Overview of the field operations
will be performed by the Site Manager for Westinghouse and/or
the project engineer for HC. The Contractor responsible for
installation and operation of the Thermal Treatment Unit {TTU)
will provide a Contractor Quality Control Plan (CQCP) in general
accordance with EPA's Interim Guidelines and Specifications for
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Preparing Quality Assurance Project Plans. Westinghouse and
Hoechst Celanese will review the CQCP and transmit it to EPA for
review and approval.
The personnel assigned quality assurance responsibilities shall
be familiar with this Quality Assurance/Quality Control Plan for
the project and will be qualified to observe and evaluate
techniques. Westinghouse personnel shall also be cognizant of
the requirements of the Westinghouse corporate quality assurance
program which is incorporated by reference, in addition to the
CQCP.
In carrying out their duties, the quality assurance personnel
shall have access to all work areas. They shall have the
freedom to identify potential quality problems; initiate,
recommend, or provide solutions to quality problems through
designated channels; verify implementation of solutions; and
ensure that further processing or action is controlled until
proper disposition of unsatisfactory conditions has occurred.
Quality assurance personnel shall have access to HC project
management and to Westinghouse branch and corporate management
at all levels as required to resolve problems or coordinate
quality concerns.
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Westinghouse Project 4124-85-0SON
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4.2 Quality Assurance Objectives for Measurement Data
The field work will require the use of certain types of
equipment having acceptable limits of accuracy and precision.
These limits are presented in the following sections:
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portable pressure gages with a range of -10 inches of
water column to± 10 inches of water column. Duplicate
analyses shall agree within± 10%. The pressure gages
shall be calibrated with a U-tube manometer.
portable pressure gages with a range of Oto 100 psi.
Duplicate analyses shall agree within 1 psi. The
pressure gages shall be calibrated with compressed air.
portable thermocouples with a range of 32°F to
2200°F. Duplicate analyses shall agree within
6°F. The thermocouples shall be calibrated with a
thermal sand bath.
portable pH meters accurate to the hundreths place.
Duplicate analyses shall agree within 0.1 pH units.
Results shall be recorded to the nearest 0.1 pH unit.
portable specific conductance meters with an _analog
scale and with a maximum error of± 2.5% plus the probe
error. Duplicate analyses shall agree within± 10%.
Results shall be recorded to the nearest 10 units for
readings under 1000 umhos/cm, and to the nearest 100
units for units for readings over 1000 umhos/cm.
thermometers reading in degrees Celsius or Fahrenheit
with a range of -20 to 110 C or -30 to 120°F or
greater. Replicate readings should agree within
±1°. Results should be recorded to the nearest
degree.
engineer's
0.01 foot.
0.01 foot.
rule or tape, manufactured accurate to the
Results should be recorded to the nearest
The calibration and maintenance of the field equipment will be
discussed further in the Calibration Procedures and Frequencies
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Westinghouse Project 4124-85-0SON
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portion (Section 4.5) of this plan.
The laboratory work shall be done following the EPA Contract
Laboratory Program {CLP) Statements of Work for Organic and
Inorganic Analyses and the CLP QA procedures. These documents
are incorporated by reference.
4.3 sampling Procedures
Samples may be taken of incinerator feed, soil, stream
sediments, scrubber treatment waters, scrubber air emissions,
sludges, ash, and solidified materials at the Shelby Facility.
The specific sampling procedures to be used are included in the
Sample and Analysis Plan. The containers and preservatives to
be used will be supplied by the laboratory in accordance with
their QC manual, or by a qualified supplier such as I-Chem.
Samples will be packaged and sent as environmental samples and
transported to the laboratory by courier (i.e. Federal
Express). Packaging requirements for environmental samples are:
1. Complete all documents, tags, and forms
appropriate to the samples to be shipped.
2. Ensure that all bottles have the appropriate
labels affixed and all appropriate tags are
securely fastened.
3. Mark the sample volume level on each container
with an indelible marker.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Secure container lids to prevent leaks. Tape the
lids for added leak protection, except for water
samples in VOA vials. Use custody seals on lids.
Secure the drain plug, if present, at the bottom
of the cooler or shipping carton used for sample
transport with duct tape.
Place approximately 1 inch of vermiculite or
equivalent in the bottom of the liner as a
cushioning material and as an absorbent in case of
leakage.
Seal each sample container in individual plastic
bags, and place upright in the lined cooler or
shipping carton.
8. Repackage ice in small, sealed plastic bags and
place loosely in the cooler or shipping carton.
Reuseable, prepackaged ice packs may be used
instead of ice. Do not pack ice so tightly that
it may break glass bottles or prevent addition of
sufficient cushioning material.
9. Place small containers, such as 40 ml septum vials
for VOAs, in small sealed plastic bags. When
shipping these with larger containers, additional
cushioning material will be added to prevent them
from being crushed.
10. Fill the remaining space in the lined cooler or
shipping carton with cushioning material.
11. Place the documents accompanying the samples in a
sealed, large plastic bag attached to the inside
of the cooler or shipping carton lid.
12. Close the lid of the cooler or shipping carton and
fasten the latch.
13. Affix signed custody seals to both ends of the
cooler or shipping carton in such a manner that
they must be removed or broken in order to open
the cooler or shipping carton.
14. Wrap duct or fiber tape around both ends of the
cooler or shipping carton several times, each time
slightly overlapping the custody seal.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 4-6
15. Mark the cooler or shipping carton on the outside
with the following information: name and address
of laboratory, return address, and arrows
indicating the "This End Up" on all four sides.
4.4 sample custody
The sample custody and chain-of-custody procedures will be
as follows:
1.
2.
3 •
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Place the sample in an appropriate bottle and log
the following information in the field notebook:
0 sample number
0 date
0 name(s) of sampler(s)
0 time (military)
0 location
0 comments
Fill in sample label with:
o sample number
0 date
0 time (military)
Place samples in coolers or shipping cartons. Samples
are to remain in the custody of the samplers until they
are brought to the sample processing area.
Complete chain-of-custody forms including:
o sample number(s)
o date
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
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name and number
of sampler(s)
time (military)
type (grab or composite)
number of samples
volume of bottles
5. Relinquish the samples to the person designated to
receive them and have the chain-of-custody form signed,
and record the time and date of transfer.
6. Log the name of the individual receiving the sample and
the time relinquished in the sampler's field notebook.
7. Tape the lids closed and affix custody seals over the
sample lids.
8. Prepare sample tags, signed by the sampler(s) and
attach to the bottle. Record the tag numbers in the
remarks column on the appropriate chain-of-custody
form.
9. Record the sample numbers, receipt of samples, tag
numbers, date and time samples were taken, etc., in the
sample tracking log books (one for organic samples and
one for inorganic samples).
10. Package the samples and deliver according to the
protocols described in this plan or store in a
designated refrigerator until packed for shipping.
4.5 Calibration Procedures and Frequencies
4.5.1 Field Equipment
Portable pH meters will be checked before each use for
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
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mechanical and electrical functions, weak batteries, and cracked
or fouled electrodes. The meter will be checked against buffer
solutions at pH 4 and 7 before sampling. The buffer solution
containers should be refilled each day of use from fresh
solution stock. Portable pH meters to be used will be accurate
to the hundredths place. Duplicate analyses shall agree within
0.1 pH units. Results shall be recorded to the nearest 0.1 pH
unit.
Portable specific conductance meters will be checked before use.
Batteries will be checked and the internal calibration
procedures followed using the manufacturer's instruction guide.
Portable specific conductance meters to be used must be supplied I with an analog scale and with a maximum error of ±2.5 % plus the
I probe error. Duplicate analyses shall agree within ±10 %.
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Portable Ecolyzer explosimeter/oxygen meter (or equivalent)
shall be accurate to within± 0.2 % concentration. Oxygen
readings will be recorded to 0.1 %. The portable
explosimeter/oxygen meter will be checked before use for the
battery charge. The instrument has a built-in, self-checking
system which checks the warning lamps and available alarms to
confirm operation, and will be checked before each day's use.
The oxygen sensor will be cleaned and/or replaced as needed. A
functional check will be performed by breathing on or placing a
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Operable Unit 2 JO% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 4-9
hand over the probe (oxygen meter) and/or using a calibration
gas (explosimeter), per the manufacturer's recommendations.
Portable photoionization detector (HNu or equivalent) must be
calibrated in parts per million (ppm) by volume of benzene
(isobutylene). Range will be 0.1 to 2000 ppm with a lower
detection limit of 0.1 ppm. Values will be recorded to the
nearest mark on the scale times the multiplication factor. The
HNu will have the battery, lamp, and fan checked before each
field use. Isobutylene will be used as a calibration gas before
each day's field use to check the sensitivity of the lamp. The
unit will then be checked with organic vapor from a magic marker
or similar volatile substance. The probe will be cleaned and/or
replaced as needed.
Portable Foxboro organic vapor analyzer (OVA) (or equivalent)
must have reporting values in ppm, with a range from o to 1000
ppm. The OVA must have a sensitivity to 0.1 ppm for methane. J Values will be recorded to the nearest mark on the scale times
I the multiplication factor. The organic vapor analyzer (OVA)
will be checked before each field use. The battery charge,
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probe/side pack assembly leakages, and possible cylinder
leakages will be checked. A step-by-step start-up procedure
from the instruction manual will be followed for the OVA, and
the OVA's response will be checked with organic vapor from a
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 4-10
magic marker or similar volatile substance.
Equipment such as thermometers, engineer's rules, surveyor's
tapes and other measuring devices will not be calibrated.
4.5.2 Laboratory Equipment
Industrial and Environmental Analysts, Inc. (IEA) is proposed as
the primary supplier of analytical services on this project.
IEA has a quality assurance/quality control program in place and
has been used on the Feasibility study for OU 2 and Operable
Unit 1 remedial action portions of the project. Their QA/QC
manual contains the procedures and frequency of calibration for
the type of equipment used by the laboratory.
4.6 Analytical Procedures
The analytical procedures to be used are those in the Contract
Labor,atory Program scopes of work for organic and inorganic
analyses, or those modified and approved by EPA for this
project.
4.7 Data Reduction, verification, and Reporting
Data reduction during the remedial action reporting task will be
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
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the responsibility of the individual providing the evaluation
and/or writing the report, and verified by a second person for
completeness and needed corrections. Checked and/or corrected
data will be initialed and dated by the individual performing
the task.
For the laboratory, data reduction and verification are covered
in the testing and QA procedures followed by the laboratory.
4.8 Internal Quality control Checks
Spikes, blanks, and duplicate samples will be analyzed to
provide a quality control check for the laboratory.
Data packages can be submitted to EPA for review, if requested,
or the results of the QA checks can be addressed as part of the
submittal of routine monitoring reports. The QA samples will
include:
o Spiked Samples: Selected samples will be spiked by the
laboratory with surrogate compounds to check for
analytical recovery.
o Blank Samples: Distilled/deionized water and
organic-free water will be used as a reagent or method
blank. These samples will be submitted from the field
along with other water samples taken from the site and
numbered accordingly. ·
As a Westinghouse quality control check, the following samples
will be sent to the laboratory:
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Duplicate Samples: Selected samples will be duplicated
simultaneously from the same source under similar
conditions, placed in separate containers, and sent to
the laboratory for analysis.
Equipment Blanks: Control samples will be selected
after equipment decontamination to assess the
thoroughness of the cleaning procedures.
The Westinghouse quality control samples will be submitted from
the field along with other samples and numbered accordingly.
The QA/QC samples will comprise up to 10% of the total number of
samples. Internal laboratory QA/QC samples such as matrix
spikes and matrix spike duplicates will be in accordance with
the CLP protocols.
4.9 Performance and system Evaluation
In addition to the internal quality control checks, EPA
personnel or their oversight contractors may audit the project
and periodically split samples with the sampling team. Access
will be provided for Agency personnel at reasonable times, and
the scheduling of the audit(s) will be at the discretion of EPA.
4.10 Preventive Maintenance
4.10.1 General
Project team members need to be able to respond rapidly to a
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 4-13
variety of incidents, using both routine and specialized
equipment. This equipment will be maintained in acceptable
condition at all times, or will be noted as unsuitable until
repaired and/or recalibrated.
4.10.2 sampling and Analytical Equipment
The sampling and analytical equipment for air, soils, surface
water, sludges, and solidified material will be maintained to
manufacturer's specifications and in operational condition.
Routine preventive maintenance, inspections, and checkouts will
be conducted by the members of the field crew to assure proper
operation of the various pieces of equipment.
4.10.3 support Equipment
Support equipment is defined as all equipment not previously
discussed that may, at some point, be required for completing an
environmental monitoring or measurements task. Support
equipment will be periodically inspected by the person
responsible for its use to maintain the performance standards
for proper and efficient execution of tasks and
responsibilities. Appropriate and sufficient replacement parts
will be available for these categories of equipment so that
sampling and monitoring tasks are not substantially impeded or
delayed.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 4-14
4,11 specific Routine Procedures used to Assess Data
Precision, Accuracy, and completeness
The CLP methods and procedures incorporate the methods to
evaluate the data precision and accuracy of analyses, and
completeness of reporting required for each parameter. EPA
600-4-79-020 methods and procedures (and/or SW-846) incorporate
requirements to assure quality of the data.
4,12 Corrective Action
Each individual responsible for specific or general tasks will
be knowledgable of the requirements of this Quality
Assurance/Quality Control Plan as they relate to that work task,
and the proper performance of the work according to those
requirements.
If an audit discovers that these requirements are not being met,
or if a similar finding is made during a routine work
evaluation, corrective measures will be taken immediately to
bring the work into compliance. Major discrepancies will result
in stopping the work effort until the corrective action has been
performed.
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Westinghouse Project 4124-85-0SON
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4,13 Quality Assurance Reports to Management
Quality assurance reports concerning field quality assurance
checks or audits will be periodically incorporated in the I progress reports. If necessary, separate quality assurance
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reports will be written.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
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Page 5-1
5,0 HEALTH AND SAFETY PLAN
5.1 organization and Staff Responsibilities
s.1.1 Personnel
Lead organization Management
The lead organization for health and safety is Westinghouse,
whose management is responsible for providing the necessary
equipment, facilities, personnel, and support for field
activities. Certain aspects of field support may be delegated
to HC or the Contractor's personnel for implementation. In this
event, Westinghouse management is responsible for quality
assurance on the tasks.
The Contractor is responsible for providing the necessary
equipment, facilities, personnel, and support of their field
activities. The Contractor shall provide a health and safety
officer who will direct the development of their site health and
safety plan, train employees, and provide overall management of
the Contractor's health and safety requirements covered in the
site health and safety plan. The health and safety plan will be
in conformance with the requirements of 29 CFR 1910.120.
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Certain aspects of field support may be delegated to HC
personnel for implementation. In this event, Westinghouse
management is responsible for quality assurance on the tasks.
Technical Support
Off-site technical support will be provided by individuals with
I specific expertise, as needed. This may include chemists,
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engineers, industrial hygienists, toxicologists, etc.
Assignment of off-site technical personnel will be made by
Westinghouse.
Medical Support Staff
The medical support staff includes company retained physicians,
medical personnel administering the medical monitoring programs,
in-house medical personnel and medical services personnel near
the site who may be called upon in an emergency.
s.1.2 On-Site Personnel
Site management duties for Westinghouse will be provided by Ms.
Madelyn Streng, or an alternative designated by the Project
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Operable unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-3
Manager, and for HC by Mr. Bill Carter. The Westinghouse Site
Manager is responsible for Westinghouse activities, including
coordinating health and safety activities for the project, and
reports to Westinghouse management. The Site Manager will
coordinate daily with Mr. Carter to see that the appropriate
level of health and safety precautions are being taken.
Specific duties for the Westinghouse Site Manager include:
o assigning Westinghouse field teams to specific tasks
and ensuring that all team members are qualified
o initiating the site safety program during a pre-
mobilization site safety meeting
o conducting on-site health and safety meetings as
required by changes in site activities, amendments to
the site safety plan, or other situations with the
potential for impact on the health and safety of site
personnel
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selecting and maintaining personal protective equipment
enforcing compliance with the site safety plan
controlling entry and exit from limited access areas
o monitoring site personnel for signs of stress
Following employee training under the auspices of an acceptable
site health and safety plan, a site safety coordinator working
under the direction of the health and safety officer may be
utilized for the continued safety and health surveillance. The
site safety coordinator with the health and safety officer
concurrence shall have authority to act on all health and safety
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-4
measures and to establish new controls as needed. The
qualifications and experience of the Contractor's health and
safety personnel shall be included in the Contractor's site
health and safety plan, and will be subject to review by the
Westinghouse. If the Engineer determines that the personnel
assigned are not providing adequate controls, the Contractor
shall be required to obtain the services of other health and
safety personnel.
The health and safety officer shall be the Contractor's
representative, with over all responsibility for the
preparation, implementation, and enforcement of the site health
and safety plan. The health and safety officer shall have
specialized experience in the hazardous waste or chemical
industry with hazards similar to those anticipated on this
project. The health and safety officer shall have a broad
working knowledge of state and federal occupational safety and
health regulations. In addition, the health and safety officer
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I and in the development of respiratory protection programs. The
name, qualifications, and work experience of the health and
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safety officer shall be included in the site health and safety
plan.
The site safety coordinator shall be the Contractor
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-5
representative assigned to the site on a full-time basis for the
duration of the project with functional responsibility for
implementation and enforcement of the site health and safety
plan. The site safety coordinator shall have experience in the
chemical or hazardous waste industry, a sound working knowledge
of federal and state occupational safety and health regulations,
and experience in air monitoring techniques and the
administration of respiratory protection programs. The site
safety coordinator shall also have current certification in CPR
and multimedia first aid. His or her name, qualifications, and
work experience shall be included in the site health and safety
plan.
The health and safety officer shall be qualified in first aid
I and CPR. In addition other first aid and CPR qualified
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personnel shall be available on-site. Certifications shall be
by the American Red Cross.
A site safety coordinator shall be present for each shift. The
health and safety officer shall conduct periodic inspections as
necessary to determinE! the overall effectiveness of the site
health and safety plan. Any deficiencies shall be submitted to
the Westinghouse in writing and the site health and safety plan
will be modified accordingly. Should the deficiencies be of a
nature to present an immediate danger, the health and safety
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Westinghouse Project 4124-85-0SON
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officer shall stop all work in the area, initiate changes as
required immediately and will notify the Westinghouse and
Hoechst Celanese.
s.1.J site security
Site security will be provided by Hoechst Celanese Security.
s.2 work Practice controls
s.2.1 standing orders
The Site Manager shall. develop and post a set of standing orders
governing work practices and shall ensure than each person
I entering the site is aware of these standing orders. Standing
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orders may be altered/amended based on the development of new
information. At a minimum, standing orders will include the
following:
o Activities which require hand-to-mouth contact such as
eating, drinking, smoking, etc. are prohibited except
in designated. areas.
0 All personnel on-site must be briefed on all known
hazards associated with the area prior to entry.
s.2.2 Site organization
The following site organization will be used for incineration
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Operable unit 2 30% Remedial Design Report
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Westinghouse Project 4124-85-0SON
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and solidification system installation and soil sampling.
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Exclusion Zone: A 25-foot corridor around the
excavation and treatment system. The area will be
clearly marked and can be amended by the Site Manager
as dictated by site conditions.
Contamination Reduction Zone; The permanent
decontamination pad will be used for contamination
reduction.
Support Zonei The support zone will be the area
directly adjacent to the decontamination pad.
The general layout of the site, specific organizational areas
and locations of emer9ency services will be detailed in later
submittals.
5.3 Site Control
The following site control will be implemented during remedial
action at the Shelby Facility.
5.3.1 Pit Excavation
The areas to be excavated will be enclosed by the exclusion
zone. The exclusion ,:one will be clearly marked with barrier
tape to limit unauthorized entry. From the exclusion zone is
the contamination reduction corridor in which field personnel
I and support equipment will be decontaminated. The support zone
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will be located adjacent to the contamination reduction zone.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-8
5. 3. 2 stream Excavati,::,n
A cooridor on either side of the stream, will be considered the
exclusion zone during the stream excavation task. Figure 2-2
depicts the layout of the streams requiring excavation.
5. 4 Safety Precaution:s
The waste types expected to be encountered during this phase of
work at the Shelby Facility may be in the form of liquids/
sludges, solids, dusts, and vapors/gases. Appendix IV contains
a Material Safety Data Sheet (MSDS) for ethylene glycol.
5.4.1 Liquids/Sludges
Liquids/sludges may be difficult to contain and are easily
splashed onto unprotected body surfaces. Caution will be
exercised when workinq with or near suspected contaminant-
containing liquids. Avoid spillage of contaminated liquids or
sludges.
5.4.2 Dusts
Dust or fugitive emissions are particulate in nature and, like
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Westinghouse Project 4124-85-0SON
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vapors, are readily inhaled into the respiratory system.
Particulates will become more pronounced during dry conditions,
particularly during the excavation and transport of waste
material. Methods such as covering and wetting will be
implemented, as necessary, to curtail fugitive emissions.
5.4.3 Vapors/Gases
Vapors may displace oxygen in low-lying or enclosed areas, may
or may not excite the olfactory senses, and are readily inhaled
into the respiratory system. Monitor areas where vapors may be
present with an organic vapor analyzer (OVA). Position persons
upwind of work activities (whenever possible) until
contamination levels are established and appropriate personal
protection levels are achieved.
5.4.4 Physical Hazards
Excavation/construction may cause serious injury to fingers,
hands and feet which may be inadvertently caught in moving
machinery. Extreme care should be taken to avoid contact with
moving parts. Loose clothing should also be secured (for
example, taping loose portions of Tyvek coveralls) to minimize
the potential for entanglement with moving machinery.
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Westinghouse Project 4124-85-0S0N
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5.4.5 Weather conditions
Weather-related hazards may also occur during the excavation/
construction process. Cold weather may cause frostbite and
hypothermia (a dangerous decrease in body temperature).
Lightning storms may be particularly hazardous to individuals
working with metal equipment. Tall structures attract lightning
strikes and pose the hazard of electrocution to personnel.
Individuals should take cover indoors if threatening weather
approaches.
Field operations during the summer months can create a variety
of hazards to the employee. Heat cramps, heat exhaustion, and
heat stroke can be experienced, and if not remedied, can be
health or life threatening. Therefore, it is important that all
employees be able to recognize symptoms representative of these
conditions as well as being capable of remedying the situation
as quickly as possible.
In the case of heat cramps or heat exhaustion, "Gatorade" or its
equivalent is suggested as part of the treatment regime. This
type of liquid refreshment will replace needed electrolytes to
the system. Without these electrolytes, body systems cannot
function properly, thereby enhancing the represented health
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Page 5-11
hazard. Therefore, when working in situations where the ambient
temperatures and humidity are high and especially where
protection Levels A, B, and Care required, the health and
safety officer must:
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0
assure that all employees drink plenty of fluids
("Gatorade" or its equivalent)
assure that frequent breaks are scheduled so
overheating does not occur
o revise work schedules, when necessary, to take
advantage of the cooler parts of the day (i.e. 5:00
a.m. to 11:00 a.m. and 6:00 p.m. to nightfall)
When protective clothing must be worn, especially Levels A and
B, the suggested guidelines relating ambient temperature and
maximum wearing time per excursion are:
Ambient Temperature Maximum Wearing Time per Excursion
Above 90 degrees F 15 minutes
85 -90 degrees F 30 minutes
80 -85 degrees F 60 minutes
70 -80 degrees F 90 minutes
60 -70 degrees F 120 minutes
50 -60 degrees F 180 minutes
A method of measuring the effectiveness of an employee's rest-
recovery regime is by monitoring the heart rate. The "Brouha
guideline" is one such method.
o Count the pulse rate for the.last 30 seconds of the
first minute of a 3-minute period, the last 30 seconds
of the second minute, and the last 30 seconds of the
third minute.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 5-12
Double the count.
If the recovery pulse rate during the last 30 seconds of the
first minute is at 110 beats/minute or less and the deceleration
between the first, second and third minutes is at least 10
beats/minute, then the work-recovery regime is acceptable. If
the employee's heart rate is above that specified, a longer rest
period will be required, accompanied by an increased intake of
fluids.
5.5 Education and Training
Westinghouse and the Contractor shall staff all work positions
in the exclusion and contamination reduction zones with
personnel who have successfully completed a classroom
occupational hazards training program that meets or exceeds the
I requirements of 29 CFR 1910.120. certification shall be
submitted for each person assigned to such work indicating that
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he/she has successfully completed an OSHA training program prior
to entering the site.
Training shall include at a minimum:
o hazard communication to conform with 29 CFR 1910.1200
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acute and chronic effects of toxic chemicals
routes of exposure (skin penetration, inhalation, and
ingestion) and specific operations that could result in
exposure
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
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Page 5-13
need for personal protection (effectiveness and
limitations)
proper use and fitting of all types of respirators to
be used on site (to include drills in donning an
emergency respirator)
medical surveillance program
on-site prohibitions including:
facial hair which interferes with respirator seal
contact lenses
eating, smoking, chewing
personal articles such as watches, rings, etc.
working when ill
establishing on-site work zones
engineering controls and safety work practices
associated with employee's work assignment, including
dust control measures and use of buddy system
5.6 Medical surveillance
All Westinghouse and Contractor personnel will be enrolled and
current in the medical monitoring program meeting the following
minimum requirements:
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baseline physical examination prior to any hazardous
waste site operations
annual physical examination by anniversary of baseline
examination
exit physical examination for personnel terminating
employment or exiting work associated with hazardous
waste site activities
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
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Page 5-14
5.7 Ambient Field Monitoring
5.7.1 organic Vapor
During field operations ambient air quality will be continuously
monitored with an OVA. The following methods will be adhered to
for the specific work task.
Excavating
0 establish air quality in background
o monitor personnel breathing zones
0 action levels/elevations in breathing zones will be
initially maintained in Level D. If air quality
exceeds 5 ppm over background on an OVA then Level C
will be implemented.
I Decontamination
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o establish background air quality
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monitor breathing zone
Level D protection will be required for decontamination
operations
Rotary Kiln sampling
o establish background air quality
o monitor breathing zones
0
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maintain Level D protection, if air quality exceeds 5
ppm over background implement Level C protection.
Protection level for air quality monitoring may be
revised depending on the Contractor health and safety
plan.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-O5ON
Document Control 85O5ON-O2O1
Page 5-15
5.8 Levels of Protection
Level D Protection:
Dl -
D2 -
Tyvek coverall, hard hats, inner surgical gloves, outer
chemical resistent work gloves, steel toe and shank
(chemical resistant) boots, safety glasses or safety
goggles, hearing protection during noisy operations,
and no jewelry worn on hands.
In consideration of site conditions, Level D2 may be
enacted by the discretion of the site manager. This
level includes all level Dl protection with the option
to omit Tyvek coveralls and outer chemical gloves.
Level C Protection:
Saranax coverall or Tyvek coverall, hard hats, inner surgical
gloves, outer chemical resistent work gloves, steel toe and
shank (chemical resistant) boots, booties, hearing protection
during noisy operations (if applicable), respirator, GMC-H or
equivalent cartridges. This level will be invoked if breathing
air in the working area exceeds background by 5 ppm on an OVA.
5.9 Safety Equipment List
5.9.1 First Aid
A first aid kit will be located in the support area. This
equipment will be used for minor injuries and for temporary
emergency care (prior to transport only). Any more serious
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Page 5-16
injuries will be reported to the site medical personnel.
5.9.2 Fire-Fighting
A 30 lb dry chemical fire extinguisher will be located in the
support area and on the excavation and treatment equipment
during field operations. In the event of a fire, the Hoechst
Celanese emergency response team, on duty, will be notified by
the plant emergency alarm system or by calling 4200, then the
fire department.
5.9.3 communications
Verbal communications will be appropriate for Level D
operations. Hand signals may be necessary if Level C protection
is needed.
5.9.4 Decontamination Equipment
Decontamination equipment will consist of water hoses, brushes,
polyethylene sheeting, trash cans, polyethylene trash bags,
aluminum foil, paper towels, alconox soap.
5.9.5 Sanitation/Hygiene
1.
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Hand, face, and arm washing. Potable water and soap
will be provided and stored in the support area.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-17
Latrines. Located on site.
s.10 Decontamination Procedures
Sampling equipment will be decontaminated prior to its initial I use, between sampling at separate locations, and after
I completion of the sampling event. The intent of the
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decontamination effort is to minimize the potential for creating
false data responses in the sample analyses resulting from
cross-contamination, or from introducing contamination from
external sources. Decontamination procedures will be:
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Bailers, spoons, buckets, and small pieces of
equipment:
1. Wash in Alconox and tap water solution
2. Rinse with tap water
3 • Rinse with isopropyl alcohol
4. Rinse with deionized water
5. Wrap in aluminum foil
6. Seal foil with custody seal if equipment is to be
stored for later use
Outside of polyethylene hoses:
1. Wash in Alconox and tap water solution
2.
3.
4.
5.
Rinse with tap water
Rinse with deionized water
Place in plastic bags
Seal plastic bag with custody seal if hoses are to
be stored for later use
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document control 85050N-0201
Page 5-18
Equipment potentially contaminated during source remediation
will require decontamination at specific points during
remediation. Generally, potentially contaminated equipment will
require decontamination traveling from the contaminated area
(exclusion zone) to the contamination reduction zone, and prior
to leaving the site. Potentially contaminated equipment that
will contact otherwise uncontaminated items or areas will also
require decontamination. All potentially contaminated materials
including disposable clothing will be collected for on-site
treatment or disposal. Controls implemented to prevent spillage
and discharge of decontamination solutions will be inspected for
condition and effectiveness.
Decontamination procedures for larger equipment used in
remediation will be:
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items will first be cleaned with a pressurized steam
cleaner
items will then be washed with a solution of Alconox or
trisodium phosphate and water
items will then be rinsed with tap water
water used for decontamination will be collected and
treated to meet the NPDES limits prior to disposal
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-19
s.11 contingency Plans
s.11.1 Local Sources of Assistance
o Hospital:
Address:
Directions:
o Ambulance:
0 Fire Department:
0 Local Police:
0 state Police:
0 Job site:
Name: Cleveland Memorial Hospital
201 Grover street
Shelby, N.C. 28150
Turn right at plant entrance onto
Highway 198 North. After 2 miles,
this road merges with Highway
226. Follow 226 N for 6 miles
(also merges with Highway 74) to
DeKalb Street, entrance is
immediately on right.
Go to HC Security for HC ambulance
first. In the event the HC
ambulance is unavailable, call
482-4422.
HC, then 482-4422
HC, then 482-8311
HC, then 482-8311
Pull alarm or dial 4200 on HC
phones.
s.11.2 National/Regional Sources of Assistance
1.
2.
3.
4 •
5.
6.
SOSON019
Westinghouse Environmental and
Geotechnical Services, Inc.
EPA (RCRA-Superfund Hotline)
Project Manager
(Everett w. Glover, Jr.)
Chemtrec (24-hours)
Bureau of Explosives (24-hours)
(Association of American Railroads)
Communicable Disease Center
,(Biological Agents)
1-404-458-9309
1-800-424-9346
1-404-458-9309
1-800-424-9300
1-202-293-4048
1-404-633-5313
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Page 5-20
7.
8.
9.
National Response Center, NRC
(Oil/Hazardous Substances)
DOT, Office of Hazardous
Operations
DOT, (Regulatory Matters)
10. u. s. coast Guard
(Major incidents)
11. Pesticide Health Hotline
12. Corporate Health & Safety Officer
13. Georgia occupational Medicine
(Westinghouse Health Consultants)
1-800-424-8802
1-202-426-0656
1-202-426-2075
1-800-424-8802
1-800-858-7378
1-404-452-1911
1-404-458-7041
s.12 Amendments to site Specific Health and Safety Plan
This site specific health and safety plan is based on
I information available at the time of preparation. Unexpected
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conditions may arise which require reassessment of site safety
procedures. It is important that personnel protective measures
be thoroughly assessed by the site manager and/or the designated
site safety officer prior to and during the site activities.
Unplanned activities and/or changes in the hazard status should
initiate a review of and may initiate changes in this plan.
Changes in the anticipated hazard status or unplanned activities
are to be submitted on "Amendments to Site Specific Health and
Safety Plan".
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Page 5-21
Amendments must be approved by the plan author and the Corporate
Health and Safety Officer prior to implementation of the
amendment.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-201
Page 6-1
6.0 SAMPLING ANALYSIS PLAN
The objective of the Sampling and Sample Analysis Plan is to
describe the equipment, methodologies, shipping and handling,
hygiene, and analytical procedures to be used in collecting and
analyzing stream sediments, at the Shelby facility and in
evaluating the effectiveness of the incineration and
solidification.
6.1 sample Handling I
I The specific procedures for collecting all types of samples are
I detailed in Section 6.4. Bottle selection for each sample will
be based on the analysis to be performed. If samples are to be
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performed using Contract Laboratory Program (CLP) protocols, the
guidelines as outlined in Table 6-1 will be used to determine
what bottles are needed. The EPA Region IV Standard Operating
Procedures and Quality Assurance Manual (SOPQAM), April, 1986
will dictate the preservative to be used. Bottle requirements
for samples to be analyzed through a subcontract laboratory will
be determined by the laboratory performing the analysis.
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-201
Page 6-2
Table 6·1
RECCJ4HENDED SAMPLE CCNTAINERS, PRESERVATION, AND HOLDING TIMES
Holding
Parameter Container Preservative Time Reference
Liquid -Low to Mediun Concentration Sanples
Alk.al inity 500-ml or 1-liter Cool, 4°C 14 days C
polyethylene with
polyethylene or
polyethrlene lined
closure
Acidity 500-ml or 1-liter Cool, 4°C 14 days C
polyethylene with
polyethylene or
pol yet hr ene lined
closure
Biochemical Oxygen 1/2-gal. Cool, 4°C 48 hrs. C
Demard (BOO) polyethylene with
pol yethrene
closure
Chloride 500-ml or 1-liter None 28 days C
polyethylene with
polyethylene or
polyethylene
closure 1
lined
Chlorine Residual In-situ, beaker or None Analyze C
buck.et Inmediately
Color 500-ml or 1-liter Cool, 4°C 48 hrs. C
polyethylene with
polyethylene or
polyeth,lene lined
closure
Conductivity 500-ml or 1-liter cool, 4°c 28 days C
polyethylene with (determine on
polyethylene or site if
polyethylene
closure1 lined possible)
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-201
Page 6-3
Table 6-1, Continued
RECCMMENDED SA.'IPLE CONTAINERS, PRESERVATION, AND HOLDING TIMES
Holding
Parameter Container Preservative Time Reference
Liquid -Low to Mediun Concentration Sanples (continued)
Chromillll, Hexavalent 1·liter polyethylene Cool, 4°c 24 hrs. C
with polyethylene
closure
Cyanide 1·liter or Ascorbic 14 days C
1/2-gal Lon Acid2•3
polyethylene with Sodiun
polyethylene or Hydroxide pH>
polyethylene lined 12, Cool 4 °c
closure
EP Toxicity 1-gal. glass (anber) Cool, 4°c ASAP· NS B
with Teflon liner
Fluoride 1-liter polyethylene None 28 days C
or 1/2-gal.
polyethylene with
polyethylene or
polyethylene
closure1
lined
Metals 1-liter polyethylene SOX Nitri/ 6 months C
with polyethylene Acid, pH <2
lined closure
Metals, Dissolved 1-liter polyethylene Filter on 6 months C
with polyethylene site2 50 X
lined closure Nitric Acid,
pH <2
Oil and grease 1-liter widemouth SOX 28 days C
glass with Teflon Sutfuric2
lined closure Acid, pH <2
Cool, 4°c
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-201
Page 6-4
Table 6-1, Contirued
RECOIMENOED SAIIPLE CONTAINERS, PRESERVATION, AND HOLDING TIMES
Container Preservative
Holding
Time Reference
I Liquid· Low to Mediun Concentration Sanples (continued)
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Organic COfTl)Ound
Extractable and
Pesticide Scan
No Residual Chlorine
Present
Residual Chlorine
Present
Organic COfTl)Ounds
Purgeable (VOA)
No Residual Chlorine
Present
Residual Chlorine
Present
Organic COfTl)Ounds
Specified and
Pesticides
(Non-Priority
Pollutants such as
Herbicides)
Organic Halides
Total (TOX)
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1-gal. arrber glass
or 2 1/2-gal. amber
glass with Teflon
lined closure
1-gal. arrber glass
or 2 1/2-gal. arrber
glass with Teflon
lined closure
2 40-ml vials with
Teflon lined septun
caps
2 40-ml vials with
Teflon lined septun
caps
1-gal. arrber glass
or 2 1/2-gal. anber
glass with Teflon
lined closure
250-ml arrber glass
with Teflon lined
septun closure
Cool, 4°C
Add 3 ml 10%
Sodiun
Thiosulfate per
gallon, Cool,
4°c
4 drops Cone.
Hydrochloric
Acid, Cool,
4°c
Footnote 6
Footnote 7
Cool, 4°c
C
47 days5 C
47 days5 C
14 days C
14 days C
47 days7 C
ASAP -NS D
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-201
Page 6-5
Table 6·1, Contirued
RECOIMENDED S~PLE CONTAINERS, PRESERVATION, AND HOLDING TIMES
Container Preservative
Holding
Time Reference
I Liquid -Low to Mediun Concentration Sanples (continued)
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pH
Phenols
Phosphate-Or tho
Phosphorus, Total
Dissolved
Solids, Settleable
Solids (Total and
Suspended, etc.)
Sul fates
Sulfides
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In-situ, beaker or
bucket
1-liter antler glass
with Teflon lined
closure
500-ml or 1-liter
polyethylene with
polyethylene or
polyethylene lined
closure
500-ml or 1-liter
polyethylene with
polyethylene or
polyethylene lined
closure
1/2·gal.
polyethylene with
polyethylene closure
500-ml or 1-liter
polyethylene with
polyethylene or
polyethylene
closure1 lined
500-ml or 1-liter
polyethylene with
polyethylene or
polyethylene
closure1 lined
500-ml or 1-liter
polyethylene with
polyethylene or
polyethylene lined
closure1
None Analyze C
Inmediately
SOX Sulfuric 28 days C
Acid, pH <2
Cool, 4°c
Filter-on-site 48 hrs. C
Cool, 4°c
Filter-on-site 28 days C
SOX Sulfuric
Acid, pH <2
Cool, 4°c
Cool, 4°c 48 hrs. C
Cool, 4°c 7 days C
Cool, 4°c 28 days C
2 ml Zinc
Acetate2 Cone.
7 days C
Sodiun Hydro~ide
to pH >9 Cool,
4°c
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-201
Page 6-6
Table 6-1, Contirued
RECCNHENDED SAMPLE CONTAINERS, PRESERVATION, AND HOLDING TIMES
Container Preservative
Holding
Time Reference
I Liquid -Low to Mediun Concentration Sanples (continued)
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Terrperature In-situ, beaker or None
bucket
Turbidity 500-ml or 1-liter Cool, 4°c
polyethylene with
polyethylene or
polyethrene lined
closure
Soil, Sediment or Sludge -Low to Mediun Concentration
E.P. Toxicity
Metals
Nutrients Including:
Nitrogen,
Phosphorus, Chemical
Oxygen Demand 4
Organics -
Extractable
Organics· Purgeable
(VOA)
Other Inorganic
Compounds
Including Cyanide
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8-oz. widemouth
glass with Teflon
lined closure
8-oz. widemouth
glass with Teflon
lined closure
500-ml polyethylene
with polyethylene
closure or 8 oz.
widemouth glass with
Teflon lined closure
8 oz. widemouth
glass with Teflon
lined closure
4-oz. (120 ml)
widemouth glass with
Teflon lined closure
Cool, 4°C
Cool, 4°c
Cool, 4°c
Cool, 4°c
Cool, 4°c
SOO·ml polyethylene Cool, 4°c
with polyethylene
closure or S·oz.
widemouth glass with
Teflon lined closure
Oetermi ne On C
Site
48 hrs. C
ASAP -NS 8
6 months A
ASAP A
ASAP A
ASAP A
ASAP A
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control SSOSON-201
Page 6-7
Table 6·1, Continued
REC(J,fMENDED SAMPLE CONTAINERS, PRESERVATJ(lj, AND HOLDING TIMES
Container Preservative
Holding
Time Reference
I Soil, Sediment or Sludge -Low to Medilffl Concentration (continued)
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Toxicity
Characteristics
Leaching Procedure
(TCLP)
Air Quality
Principal Organic
Hazardous
Constituents
Particulates
Metals
Abbreviations:
Footnotes:
8·oz widemouth glass Cool, 4°c
with Telflon Lined
Closure
Glass Container N/A
containing Tenex
sorbent cartridge
Perticulate-
Sarrpl ing Train
Particulate-
Sarrpl ing Train
N/A
N/A
ASAP= As Soon As Possible
NS Not Specified
ASAP -Holding
Times for
Extract Per
Protocols for
Analytical
Fraction
ASAP
ASAP
ASAP
E
F
G
H
1. Use indicated container for single parameter requests, 1/2 gallon polyethylene container
for rrultiple parameter requests except those including BOO, or 1-gallon polyethylene
container for rrultiple parameter request which include BOD.
2. Must be preserved in the field at time of collection.
3. Use ascorbic acid only if the sairple contains residual chlorine. Test a drop of sairple
with potassiun iodide-starch test paper; a blue color indicates need for treatment. Add
ascorbic acid, a few crystals at a time, until a drop of sairple produces no color on the
indicator paper. The add an additional 0.6 g of ascorbic acid for each liter of sairple
volune.
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Westinghouse Project 4124-85-0SON
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Page 6-8
Table 6-1, Contil"IJE!d
RECCMHENDED SAMPLE CONTAINERS, PRESERVATION, AND HOLDING TIMES
Footnotes: (Continued)
4. May include nitrogen series (anmonia, total Kjeldahl nitrogen, nitrate-nitrite), total
phosphorus, chemical oxygen demand and total organic carbon.
5. Sa~les nust be extracted within 7 days and extract fflJSt be analyzed within 40 days.
6. Collect the s~le in a 4 oz. soil VOA container which has been pre-preserved with four
drops of 10 percent sodiun thiosulfate solution. Gently mix the s~le and transfer to a
40 ml VOA vial that has been pre-preserved with four drops concentrated HCl, cool to
,oc.
7. See Organic Con-pounds -Extractable. The Analytical Support Branch should be consulted
for any special organic COOl)Ound analyses in order to check on special preservation
requirements and or sa/ll)le voli..me.
References:
A. US-EPA, Region IV, Envirorvnental Services Division, "Analytical Support Branch, Operations
and Quality Control Manual 11, June 1, 1985 or latest version.
B. EPA Method 1310, Extraction Procedures, "SW 84611 , US-EPA, Office of Sol id Wastes,
Washington, DC, 1986.
C. 40 CFR Part 136, Federal Register, Vol. 49, No. 209, October 26, 1984.
0. EPA Interim Method 450.1, "Total Organic Halide11, US·EPA, ORD, EMSL, Physical and Chemical
Methods Branch, Cincinnati, Ohio, Noverrber 1980.
E. 40 CFR Part 261, Federal Register, Vol. 51, No. 114, June 13, 1986, pg. 21686.
F. EPA Method 30, Volatile Organic Sarrpling Train, "SU 84611 , US-EPA, Office of Solid Waste,
Uashigton, DC, 1986.
G. EPA Method 5, Determination of Particulate Emissions from Stationary Sources, 40CFR 60
Appendix A.
H. EPA Modified Method 12, Determination of Particulate Emissions from Stationary Sources,
40CFR 60 Appendix A.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-201
Page 6-9
6.2 Sample Identification
Each sample collected at the site will be identified by a unique
sequence of numbers and letters. The identification number for
a given sample assigned in the field by the sampling team, will
be recorded in a field notebook and placed on the container
label. Additionally, the sample identification number will be
recorded on the Chain-of-Custody form. Sample identification
numbers will be assigned according to the following format:
SH-XX-YY-ZZ
where SH is an abbreviation for the site name
XX is a sample type identifier
YY is the sample location identifier
ZZ is the sequential sample from that location
Sample type identifier to be used in the sequence are as
follows:
IA-Incineration Ash
SO-Solidification Sample
ss-stream Sediment
WW-Treated scrubber water, treated stormwater, miscellaneous
waters,etc.
SE-Trial burn exhaust gases, operational exhaust gases
WF-Waste Feed, miscellaneous feed
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Page 6-10
As an example, the identification sequence:
SH-S0-04-02
represents a solidification sample obtained from the Shelby
site. The sample associated with this identification sequence
represents the second solidification sample and the fourth
sampling location.
6.3 sampling Procedures
Samples shall be taken of waste feed solidified soils, treated
scrubber water and stormwater runoff, stack gases and
incinerator ash. A through discussion of sampling procedures
for incinerator stack gases will be in the trial burn plan and
are not detailed here; however, routinue stack monitoring is
included in the following sections. The containers and
preservatives to be used by Westinghouse will be supplied by the
laboratory in accordance with the QC procedures. General
sampling and packaging protocols shall include:
1. Complete all documents, tags, and forms appropriate to
the samples to be shipped.
2.
3 •
4 •
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Ensure that all bottles have the appropriate report
labels affixed or all appropriate tags securely
fastened.
Mark the sample volume level on each container with an
indelible marker.
Secure container lids to prevent leaks. Use signed or
initialed custody seals on lids.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Secure the drain plug at the bottom of the cooler or
shipping carton used for sample transport with duct
tape, if present.
Place approximately 1 inch of vermiculite (or other
suitable material) in the bottom of the liner as a
cushioning material and an absorbent in case of
leakage.
Seal each sample container in individual plastic bags,
and place upright in the lined cooler or shipping
carton.
Repackage ice or chemical ice (blue ice) in small,
sealed plastic bags and place loosely in the cooler or
shipping carton. Pack ice so that it will not break
glass bottles and will allow addition of sufficient
cushioning material.
Place small containers, such as 40 milliliter (ml)
septum vials for VOAs, in small sealed plastic bags.
When shipping these with larger containers, additional
cushioning material will be added to prevent them from
being crushed.
Fill the remaining space in the lined cooler or
shipping carton with vermiculite or other suitable
material.
Place the documents accompanying the samples in a
sealed, large plastic bag attached to the inside of the
cooler or shipping carton lid.
Close the lid of the cooler or shipping carton and
fasten the latch.
Affix signed custody seals to both ends of the cooler
or shipping carton in such a manner that they must be
removed or broken in order to open the cooler or
shipping carton.
Wrap duct or fiber tape around both ends of the cooler
or shipping carton several times, each time slightly
overlapping the custody seal.
Mark the cooler or shipping carton on the outside with
the following information: name and address of
laboratory, return address, arrows indicating the "This
End Up" on all four sides, label cooler or shipping
carton as "Environmental Samples" and as "Fragile".
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Page 6-12
6.4 Specific sampling Procedures
The specific sampling procedures are outlined in the following
paragraphs. The sampling procedures first include methods used
for collecting treated scrubber and stormwater samples, followed
by solidified materials, incinerator ash, stream sediments and
stack gases.
6,4.1 Treated scrubber and Stormwater Samples
The sample code for treated scrubber and stormwater samples is
WW. Sample numbers will start with 101 and progress
arithmetically to the highest number needed.
Sampling Method
1. Make sure the pH and conductivity meters have been
calibrated before sampling begins. Check calibration of
meters periodically during sampling. Record information in
sample notebook.
2. Monitor pH, conductivity, and temperature every
three-to-five minutes until the readings are stable. Stable
conditions will be indicated when the pH readings are within
0.5 units, the conductivity readings are within 50 micro
mhos per centimeter and the temperature is within 2°c.
3. Collect the sample from the end of the treatment plant after
the water is processed though the treatment devices.
4. Add the proper preservatives to the sample bottle. After
placing the cap on the sample container, attach the
completed sample tag to the container.
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5. Record all required information in the field logbook,
chain-of-custody form, and sample log sheet.
Sampling Frequency and Analyses
The treated scrubber and stormwater will be analyzed daily
during the trial burn, and weekly thereafter. Analysis will be
for the parameters listed in the National Pollutant Discharge
I Elimination System (NPDES) permit.
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6,4,2 Solidified Material
The sample code for solidified material is so. Sample numbers
will start with 101 and progress arithmetically to the highest
number needed.
Sampling Method
The procedures for sampling solidified samples are as follows:
1. Using a scoop or trowel, fill the appropriate number of
eight-ounce glass jars 3/4 full with sample: sample depths
may vary from o to 1 foot.
2. Attach an identifying label or tag to the bottle.
3. Mark the location with a numbered stake and locate the
sample point on a sketch of the site.
4. Record all required information in the field logbook,
chain-of-custody form, and sample log sheet.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-201
Page 6-14
Sampling Frequency and Analyses
One sample will be taken for every 100 cubic yards of solidified
material and analyzed for TCLP and ethylene glycol.
6.4.3 Incinerator Ash
The sample code for incinerator ash is IA. Sample numbers will
start with 101 and progress arithmetically to the highest number
needed.
Sampling Method
The procedures for sampling incinerator ash samples are as
follows:
1. Using a scoop or trowel, fill the appropriate number of
eight-ounce glass jars 3/4 full with sample. Sample depths
may vary from o to 1 foot.
2. Attach an identifying label or tag to the bottle.
3. Record all required information in the field logbook,
chain-of-custody form, and sample log sheet.
Sampling Frequency and Analyses
One sample of the ash will be taken for every 20 tons of
incinerator feed material and analyzed for ethylene glycol.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Page 6-15
6.4.4 stream Sediments
The purpose of the stream sediment sampling is to establish
whether contaminants have been removed from the stream beds.
The sample code for stream sediments is ss. Sample numbers will
start with 101 and progress arthmetically to the highest number
needed.
Sampling Method
The procedures for sampling the stream sediments are as follows:
1. Samples can be collected directly into hand-held sample
containers, or may be taken using a dipper. Sediment
samples can be collected using stainless steel spoons. The
collected sediment will then be placed into eight-ounce
glass jars. Sample depths may vary from o to 6 inches.
2. Attach an identifying label or tag to the bottle.
3. Mark the location with a numbered stake and locate the
sample point on a sketch of the site.
4. Record all required information in the field logbook,
chain-of-custody form, and sample log sheet.
Sampling Frequency and Analyses
One sample will be taken for every 50 feet of stream reach where
sediment was removed. Those stream reaches containing no
sediment will not be sampled.
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6.4.5 stack Sampling
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
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Page 6-16
The purpose of the stack sampling is to establish whether POHCs,
particulates, or other contaminants have been emitted into the
atmosphere. The sample code for exhaust gases from stack
samples is SE. Sample numbers will start with 101 and progress
arthmetically to the highest number needed.
Sampling Method
The stack shall be sampled in accordance with the "Standard
Method for Sampling Stacks for Particulate Matter In: 1971 Book
of ASTM Standards Part 23 ASTM Designation D-2928-71.
Philadelphia, PA. 197111 • All information shall be recorded in
the field logbook, chain-of-custody form, and sample log sheet.
sampling Frequency and Analyses
Stack samples will be collected continuously for oxygen, carbon
dioxide and carbon monoxide. Stack sampling during the trial
burn will be addressed in the trial burn plan.
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Westinghouse Project 4124-85-050N
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6,5 sample custody
The sample custody and chain-of-custody procedures will be as
follows:
1. Place the sample in an appropriate bottle and log the
following information in the field notebook:
0 sample number
0 date
0 name of sampler(s)
0 time (military)
0 location or station identifier
0 any comments
I 2. Fill in sample tag with:
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o sample number
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date of collection
time (military) of collection
parameters to be analyzed
samplers name(s)
o location or station identifier
3. Place samples in coolers or shipping cartons. Samples are to
remain in the custody of the samplers until they are brought
to the decontamination area or the support area.
4. Complete chain-of-custody forms including:
o sample number(s)
0 date
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Westinghouse Project 4124-85-050N
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project name and number
samplers' name(s)
time (military)
type (grab or composite)
number of samples
volume of bottles
tag number
signatures of personnel releasing samples
5. Relinquish the samples to the Site Manager, a person
designated by the Site Manager, or the sample packager,
with the chain-of-custody form signed with the date and time
noted.
6. Log the name of the individual receiving the sample and the
time relinquished in the sampler's field notebook by the
sampler.
7. Tape the lids closed and affix signed or initialed custody
seals over the sample lids.
8. Prepare sample tags, signed by the sampler(s) and attached
to the bottle. Record the tag numbers in the remarks column
on the appropriate chain-of-custody form.
9. Record the sample numbers, receipt of samples, tag numbers,
date and time samples were taken, in the field office sample
tracking log books.
10. Package the samples and deliver according to the protocols
described in this plan. Samples may be stored in a site
refrigerator until packed for shipping, if necessary.
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
· Document Control 85050N-201
Page 6-19
6.6 Equipment Decontamination
The sampling equipment will be decontaminated prior to its
initial use, between sampling locations, and after completion of
the sampling event. The intent of the decontamination effort is
to minimize the potential for creating false data responses in
the sample analyses resulting from cross-contamination, or from
introducing contamination from external sources.
Decontamination procedures will be:
o Samplers, spoons, buckets, and small pieces of
equipment:
0
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1.
2.
3.
4.
Wash in Alconox and tap water solution
Rinse with tap water
Rinse with isopropyl alcohol
Rinse with deionized water
5. Wrap in aluminum foil, if appropriate
6. Seal foil with custody seal if equipment is to be
stored for later use
Outside of polyethylene hoses:
1. Wash in Alconox and tap water solution
2.
3 •
4.
5.
Rinse with tap water
Rinse with deionized water
Place in plastic bags
Seal plastic bag with custody seal if hoses are to
be stored for later use
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-201
Page 6-20
6.7 Calibration Procedures and Frequencies
The Quality control Manual provided by the laboratory contains
the procedures and frequency of calibration for the equipment
used in the laboratory.
6.8 Analytical Procedures
The analytical procedures to be used by the laboratory will be
listed in their Laboratory Quality Control Manual. The
procedures listed will generally follow USEPA 600-4-79-020
Methods for Chemical Analysis of Water and Waste and American
Society for Testing Materials, Annual Book of ASTM Standards,
Part 31, Water Atmospheric Analysis, Philadelphia, PA. 1974,
p40-42. Sample analyses will be conducted within recommended
EPA holding times.
6.9 Data Reduction, verification, and Reporting
The laboratory data reduction and verification are covered in
the testing and QA procedures followed by the laboratory (i.e.,
CLP methodologies, etc.).
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-201
Page 6-21
6.10 Internal Quality control Checks
Split samples of the solidified material, stream sediments,
treated wastewater, and incinerator ash will be analyzed to
provide a quality control check for the laboratory. Duplicate
incinerator stack gases will analyzed as a quality control
check.
As a Westinghouse quality control check, the following QA checks
will be incorporated into the field samples being sent to the
laboratory:
Duolicate Samples: Samples will be duplicated simultaneously
from the same source under similar conditions, placed in
separate containers and assigned a non-sequential sample
number. One duplicate sample will be collected for every 20
sampling locations, per type of sample (e.g., one duplicate
per 20 solidification samples). If less than 20 of a
particular type of sample are collected, one duplicate will
be collected.
Equipment Blanks: Control samples will be selected after
equipment decontamination to assess the thoroughness of the
cleaning procedures.
Trip Blanks: Laboratory prepared deionized water samples in
40 ml septum jars will accompany each water shipment.
Blanks: For treated water samples, laboratory prepared
sample containers with deionized water will be exposed to
the work site atmosphere.
Matrix Spike/Matrix Spike Duplicate: Triple volumes will be
collected for selected samples. Two of the samples will be
spiked at the laboratory and analyzed to determine the
effects the site specific matrix may have an analyses.
The Westinghouse quality control samples will be submitted from
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Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-201
Page 6-22
the field along with other sediment water samples or stack
sample taken from the site and numbered accordingly.
6.11 Preventive Maintenance
Project team members must be able to respond rapidly to a
variety of incidents, using both routine and specialized
equipment. Due to the unpredictable nature of sampling programs
of this type, equipment must be in a continual state of
preparedness. Therefore, preventive maintenance is critical.
The sampling and analytical equipment for air, solidified
material ash, treated waters, and sediments will be maintained
to manufacturer's specifications and in operational condition.
Routine preventive maintenance, inspections, and checkouts will
be conducted by the members of the field crew, to assure proper
operation of the various pieces of equipment.
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(II' Y \' 1, , ' 1 ,,, '\ . ,\ '· ,;; j , .... fl •-~-ll)l .. · · · 'c··;~,,.cc·
I\, '\\ \ \\ \ ' 'I I'"\ fi I .'./·' ,,r· 'I ' ' '---~\---~ \' \ I, (i -\-=_-••e~r
\
I \
\
r,":;'\ NT 5v5T[M
PUMP IN & OUTER TIER . (&1 G SYSTEM ~ MONITOR WELLS -ABOVE GRADE
--1---i-l
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\\ -/ __ ,. ..
_ . ..-
/ ... L ------.
\ ' \ \
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. \ , ' ;if d l-~'4-:)U(t~ 1½ i \\ ' · 1 '!/Ji/ ... >( --
~\ ~,,,,,';'C 'W I \,·/ /lfi((«((D((~,~\\'1 ~~"'~,~~' -~I\~~~\
, \ ~,--. ~-' • (!( , / \\~ ~ .~~j I'):; i, "-S~:11~ ~,::d}) !!v; \: / / ' I/ I' ~-J;j -1 ~\ I'\~~\ ~\ '~ t~-: -.\ \• ~~~~,~~1:W;0'%/\,::,.; ;/I ·'.-1/ / ,4/, /,/ , " O" • 1 .,, • ~\•C '7¾///2/1// ,'
-I" , , " • , " '" . ' . ., • . . J;(' "' " '• \" .... ,. ,. ·R' . /
. ' I ' / II '' " I ' . .... /
I\ \\I I' IR~~'" -."/ ........ /
\ \\ " ~ t,·,~),~• ~ //
• -y~~ ~~· ' --< I .,> ,,,,
j //
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\P/estinghouse ,-. u n cJ (~ e o t c c: h . t n v I r o n r11 e n t c n co Services ' nc-•
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\ \
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\
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\ '
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\ \ \ \
\ ___ \
• I
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' • T
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\
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\
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AHlAS TO GE rrnsrnv
CN EITHER SIDE OR ED ARE 30 FT.
FEArUnE TO nAOIUS Fn

□
~

\
\
BE PROT[CTCO.
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\ I ' ' \ \
\ \
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5050N020
APPENDIX II
METAL EMISSIONS FROM HAZARDOUS
WASTE INCINERATION
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1.
2 .
3.
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0SON
Document Control 85050N-0201
Appendix II-1
METALS CONTROLS FOR HAZARDOUS WASTE INCINERATIONS
Tier I Approach
0 Sets limits based on feed rates
0 Assumes no removal of metals in bottom ash or by air
pollution devices
0 It passes the Tier I limits, no trial burn for metals
is required
Tier II Approach
0 Sets emmisions limits based on health risks using
dispersion coefficients for worst-case facilities
0 Allows for removal of metals in bottom ash and by air
pollution devices
o Compliance determined by stack emmissions tests
Tier III
0 Allows higher emission rates than Tier III limits
without exceeding health risk numbers
0 Established using dispersion modeling
Stack Height
Feed Rate
Exhaust Flow Rate
Complex .Terrain
Rural Area
Volatile Antimony
Volatile Chromium
Assumptions
Air Pollution Controls Are Used
10 Meters
1 ton/hr
10 meters/sec
100%
5%
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Appendix II-2
DATA FROM THE REMEDIAL INVESTIGATION
Soil Antimony
Soil Chromium
5050N020
Range
50-25,000 mg/1
<1.5 -40 mg/1
Average
5,000 mg/1
10
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1.
2 •
Feed Rate
Antimony
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Appendix II-3
TIER I ANALYSIS
5000 mg/kg x 10-6 x 2000 lb/ton x 1 ton/hr=
= 10 lb/hr
Chromium
10 mg/kg x 10-6 x 2000 lb/ton x 1 ton/hr=
= 0.02 lb/hr
Plume Rise
Flow Rate -10 meters/sec
Exhaust Temperature -6oo°K
Plume Rise -16 meters (Table B-1)
3. Effective Stack Height
4 •
Effective stack Height= Stack Height+ Plume Rise
Effective Stack Height= 10 + 16 = 26 meters
Allowable Feed Rate
o Antimony
0 Chromium
0.3 lb/hr (Table B-3)
7.9 x 10-6 (Table B-5)
5. Results
0 Antimony and Chromium fail Tier I analysis
5050N020
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Air Pollution
Control Device
Wet Scrubber (WS)
Venturi Scrubber
Venturi Scrubber
Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Appendix II-4
ESTIMATED REMOVAL EFFICIENCIES
Percent Removal
Antimony Chromium
40 50
(VS-20) 20 90
(VS-60) 40 98
Electrostatic Precipitator (ESP-1) 80 95
Electrostatic Precipitator (ESP-4) 90 99
Fabric Filer (Baghouse) 90 95
Proprietary Wet Scrubber 95 95
VS-20/WS 96 97
Combination of Devices 99 99
5050N020
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Appendix II-5
TIER II ANALYSIS
1. Assumptions
Adequate air pollution control devices (APCD) to meet
Tier II analysis
2. Feed Rates
0
0
Antimony
10 lb/hr x 454 gm/lb x 1 hr/60 minx 1 min/60 sec=
= 1.26 gm/sec
Chromium
0.02 lb/hr x 454 gm/lb x 1 hr/60 minx 1 min/60 sec=
= 0.0025 gm/sec
3. Stack Emissions
0
0
Antimony
1.26 gm/sec x 100% volatile -removal by APCD
= 1.26 gm/sec -removal by APCD
Chromium
0.0025 x 5% volatile -removal by APCD
= 1.25 x 10-4 gm/sec -removal by APCD
4. Allowable Stack Emissions
0
0
Antimony: 3.6 x 10-2 gm/sec (Table B-7)
Chromium: 1.0 x 10-4 gm/sec (Table B-9)
I 5. Percent Removal Required to Meet Allowable Emissions
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0
0
5050N020
Antimony: 96%
Chromium: 20%
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-050N
Document Control 85050N-0201
Appendix II-6
TIER III ANALYSIS
1. Computer Modeling
2.
0
0
use comprehensive data available to characterize
incinerator
determine type of terrain -flat, rolling, and complex
o detemine if rural or urban
0 develop site-specific meteorological data
o model hypothetical incinerators as well as actual
incinerator
o use appropriate model(s)
EPA estimate on modeling time
0
0
0
0
50 to 100 hours
may be more if more models are required
does not include itme for the development of
meteorological data or running of meteorological
preprocessor (RAMET)
Reference Air Concentration
Antimony -0.3 mg/m3 (Table I-3)
Chromium -1.2 x 10-2 mg/m3 (Table I-2)
5050N020
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Operable Unit 2 30% Remedial Design Report
Hoechst Celanese/Shelby, NC
Westinghouse Project 4124-85-0S0N
Document Control 85050N-0201
Appendix II-7
REFERENCE
EPA, "Draft Guidance on Metals and Hydrogen Chloride
Controls for Hazardous Waste Incinerators," March 2, 1989.
5050N020
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Nonh C.ro!lna Oepanm,nt of Natural Rnourcn and Community D,velopment
Envlronm,nu.l M,1n1gomenr Comrn1silon
AIR PERMIT APPLICATION'
GENERAL INl'OR.l\1ATIC>N
INSTRUCTIONS ON BAO.'
•Tc, con1tr1,.11;t and opuue Air Emiulon Sour~u and Control Oevlces In ic;,ord1n~• wll.h N. C. Gonoril Statutes Chapur 141, Anlclc 21.
A
page I oi I
PLEASE TYPE OR PRINT. ATTACH APPROPRIATE EMISSION SOURCE AND CONTROL DEVICE FORl\1S FOR EACH SOURCE
LISTED IN ITEl\16 BELOW.
I. Facility Name (Company, Establishment, fown, Etc,): Date FOR DEM USE ONLY
DATE RECEIVED:
2. Site Location (St./Rd./Hwy.): City Zip Codn County
Latitude Lon11irude SIC Code
3. ."1a,llng Addren (P. 0. Box/St./Rd./Hwy.):
'
City State lip Code Phone "'ith Ar .. Code
4. Applicant Tochnical Contact: Title Phone with Area Code PERMIT NUMBER:
DATE ISSUED:
..
S. Descriptton of operation conducted at above facility:
6. List each EMISSION SOURCE •nd CONTROL DEVICE for which applicati,,n is made. AISign an ID NUMBER to each emiS1ion source
Jnd control device which uniquely identifies that ~urce. Atuch appropriite emission source and control device forms for each.
F.MISSION SOURCE ID NO. CONTROL DEVICE IONO.
I lJSE SEPARATE SHEET(SI 1r NEEDED
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\ 1 a., i mum f ac iii t y ,1':'P,:•''.::':'.,t':'.'.o~n,_-__: ____ :=::::::::=:.H::::.:::ou::r'..'.''.__:/ D:::a~y'..._ ___ ~::::==::.:D:'.:•~Y'._'.I:_:/ W::_:ee:..'.k'..._ ___ __:::.=:::=::.'.W~e::•::k~•I_:)'_'.. ''..:..'.."
.,. :'-Jame J.nd Jddress rJt ~nginecrmg firm that prepared application or plan~:
9. 5;gn,1ture or (t'.iPOmible pe1son or company otflcl.11:
Date ----------------------------------------------
)igner"\ ,\lame 1TYPE OR PRINT) Title Phone w1lh Are.1 C1Jcte
FORM AQ-Z:l
i"lo·-,,.'
I
I GENERAL DATA FOR PROCESSES OR FUEL BURNING SOURCES B
page i of 3
',OTE: DO NOT USE THIS FORM FOR INCINERATORS. USE FORM "F".
lrLL\SE TYPE OR PRINT. ATTACH TO THE GENERAL INFORMATION FORM "A". IF APPLICABLE, ATTACH AIR POLLUTION
CONTKOL DEVICE FORM "C" USE SEPARATE FORM FOR EACH SOURCE.
1_1._E_m_,,_,,_·u_n_S_o_u_rc_•_•_nd-lD_N_o_._(_F_R_O_M_G_E_N_E_R_A_L_IN_F_O
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A_'_' , __ I_T_E_M_6_)_: ----------------
2. Oc-;cription of Proce5,!l or Fuel Burning Source Including Air Control Device:
I ··---· . ----------
··--------------
13.Pe-;-;;;;~-Application is mad• for (CHECK ONE ONLY):
I ) N•w Source ( ) Existing Source ( ) Modification -Last Permit No, _____ _
Commence Conuruction Date , 19 Operation Oat• , 19
l-1. Muirnum.Source Operation: ___ HoursiOay ___ Days/Week
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·'. Air Conu.minints Maximum Actual Emisiiions Emi~;sjon
Lmitted: Brfore Control After Control Euimate Control
(lb/hr) (lb/hr) Method• Device••
P Jrticuldtes ........... --
Sulfur Dioxide . . . . . . . .
Nicrogrn Dioxide .......
C.ubon Monoxide ...... ·---
Hydrocarbons (VOC) . . . . I -
Lead . . . . . -
I -------·
t)ther ( )
. ---+ -·-------·-·--
Other I I . I
•REFER TO BACK OF GENERAL INFORMATION FORM",\" FOR EMISSION ESTIMATION CODE
.. ATTACH AIR CONTROL DEVICE FORM "C"
Control
E ffl cie ncy %
----
-
6 T,,.pt:ofSource:
t:HECK Or-.E
! ,\ GENERAL PROCESS -Source not covered by B ,nd C below. (Complete items 7, 8, 18 throu_ef, 22)
1 l 8
I I (
GENERAL PROCESS WITH IN-PROCESS FUEL -Source where products of combu>tion contact materl•ls heated.
(Complete item, 7, 8, 9, 13, 14, 18 throu~h 22)
FUEL BURNING SOURCE (boil•"• etc.) -Source whore produ,:ts of combustion ,re tor ti,• primary purpo,e ul pro-
:Jucing he.1.t or power by indire-ct heat tram fer. (Complete ittms 9 throu~h 22)
--·---------------------
• , . Prons~ Operation: { ) Continuous ( ) Batch -Normal Batch Time ______ No. Batches per O.tv ____ _
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~-Process Name _____________ _
'.1aterills Entering Process•'.
:_Include ln-proce,s Solid Fuels)
i \1,x. Requested
Input Rates (lb/hr) i Permit Input ,.,;," r= '""'' I '"" ""'"'
I:. ···-~-~~~~~~=:~-------__ -_-_-_-_-_-_-_-_-_-_-__ -. -------·-----------~~~-= -=-=:
(. -----~---------·
!). --,---... ~------------------
[. ···•-------·-------------· --------·
F.
TOTAL WEIGHT ENTERING PROCESS le-____ _,_ __________ _
'IJO M)T LIST '-«Y '.'OLA TILE HYDROC,\RBONS, USE HYDROCARBON EMISSION SOURCES FORM"("
I.
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111.
DATA FOR PROCESSES OR FUEL BURNING SOURCES -continued
Type of Fuel Burning Source:
( ) Industrial Boiler ( ) lnscltutional/Residential Boller ) Ele,:vlc Utlllly Boiler
( ) Ocher _____________________ Make ,tlld Model No.
rype of Solid Fuel Burning Equipment Used:
( ) Hand fired ( ) Overfeed Scoker
( ) Spreader Stoker ( ) Tra-.lina Grace
( ) Underfeed Stoker ( ) Shaking Grate
( ) Pulverized
( ) Wet Bed
( ) Ory Bed
B
page 2 of 3
( ) Oum (speeifiy) __________________________________ _
Is collected fly.uh reinjectedl ( ) NO ( ) YES Percent Reinjei:ced _______ __;
Combustion Air: Percent Excess Air _____ __.;% Natural ( ) Induced
Specify method and schedule of tube cle•nlng:
I ( ) L•nclng ( ) Tube Blowing -------------
) Ocher _________ Schedule _________ _
12. Boller Horsepower Rating ________ _ Boller Steam Flow (lb/hr)
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116.
Fuel Burning Source Heat Input: Maximum ______ Million BTU/hr Average ______ Million BTU/hr
ruel Data: Primary Fuel Type(,) (specify) __________________________ _
Standby Fuel Type(s) (specify) ____________________ _
FUEL TYPE FUEL USAGE Max.% Max.%
Max. Design Max. AClual Annual Sulfur Ash BTU Value
(1.u/hr) (sill/hr) 11.J/vrl· (STU/1.ol)
:16 Fuel Oil --·-·--·---------11•1/hr) (aiiJ/hr) (121/yr) (STU/1•1I
;;S rue! Oil ---~-----.. ~=r------(gill/hr) (gal/hr) !a;~lvr) (STU/&lll
"4~uel011 -----·--
(lb/h1) (lb/hr/ (ion/yr) I
ltHU/lbl
Coal -----+----·-·-----· ---------·-
( lb/hr d,y) (lb/hr dry) (ton/yr dry) I (STU/lb)
'•!'2!~-~ ------·---~--· ------·-----·-----------r__.U)QQ_ -
Other !
If, combination of fuels is used, specify the muimum BTU/hr heat input for ••ch:
:'oel Oil _______________ Coal ________ Wood _____ _
Toul muimum heat input in million BTU/hr of 2.11 indirect tired fuel burning sources within propertv bound,arits excluding th.tt
indicated .ilbc.i'f'e-:
Fuel Oil _________ ---Coal _______ Wood ______ Other ____ ---·-·· I 1-,-_-T_o_t,J_·_N_o ___ o_f_l_n_d_ir-•Cl_fi_ir_e_d_fu_e_l_b_u_r_nl_n_g-,-ou-,-~-,-w-ith-in-p,-o-pe-,1-y_b_o_u_n_d_M_l_es_: ___________________ _
I :3.
I
ruel Oil ____________ Coal ________ Wood
Are there MW Tu1'iti'f'e emis5ions \HOrage µHes, product h.indlina:, haul roJids, etc.)? No {
comments below, the type, site, estimated emissions and control measures.
Describe ,my li~uid or solid waste'.\ gcnen.ted and method of disposal:
. Other _____________ _
Yes (
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21.
22.
r· Io..,,..
DATA FOR PROCESSES OR FUEL BURNING SOURCES -continued B
Suck or t.:miuion Point O.ua:
H•ight Above Ground (ft,)
Volumetric Flow R•te
(ACFM)
Inside Ar•• (s<l, ft.)
Velocity (ft,/sec,)
Is scaffolding available for ,ource testing/
I I No ( ) Yes
Gu Temperanm, (Deg. F)
Are sampling poru ovailablel
( ) No ( ) Yu
?•&•3oi3
Direction of Exit
(up, down or horizontal)
Is rain cap or other obsuuctlon over
stack! ( I No ( ) Yes, (specify)
Stack ID No. ________ -Sources with • common
stack will have the same suck number.
Indicate monitoring and recording instruments Inst.tiled on suck:
( ) Opacity Monitor ( ) S02 Monitor ( ) NOx Monitor ) Other ________________ _
Attach or sketch • flow diagram of the process or fuel burning source. Include air control device(s), (SEE INSTRUCTIONS ON
BACK OF THIS PAGE):
13. Commt:nu:
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L"<STRUCTIONS
FLOW DlAGRAM FOR PROCESSES OR fl[JEL BURNING SOURCES
INCLUDING AIR CONTROIL DEVICES
Draw • compieu, flow dial!J'3nl of th• procns or fuel bumln110111''10 lndudlnn air conlrol de-tlco(s). lndiau, .all equipment, nw1 flow of
mou,rw, loutlon of dln,cc hudnL inlet and oudet tempenwm, and .alt flo• races. Glvo flow ntet f« waist u,ed eldler a cooOnc «
.. suubbln1-lndlcou, polluun1 collected and emisaioM exhausted to die acn,osphere, If • sc,j.ent « a mix of tol-, inks, palnb or
other volatile liquid mixes ate uted, complele the Hydrocari>on Emialon Soo,rces Fonn "E ", All mollrilll1 etrl«inC dlls procea snould
appear In Item S, paae I.
FOR EXAMPLE:
l.
' ..
" ,.
8.
9.
10.
I l"-llUII
IUClll hlHIOI
Rock, sr,vel, Wld, fine,, etc. -200,000 lb,/hr ur 100 tons/hr.
Rock, ,.-.vel, ~nd, fines, etc. -200,000 lbs/hr or 100 ions/hr.
Ory ,ggregate -199,000 lbs/hr or 99.50 tons/hr.
5
J
"'O I '"I"" l tvtlll (L(Htlll
7
111(1
30,000 C F/11 @ 180" F; I,()()() lbs/hr p,rticulatc entering cyclone; 80'l6 c-1clone efficicno-y.
800 lbs/hr ~turned to dry •l!IIT•P••·
Orv ~1mre1ate entering vibrating s.cre-ens -199,800 lbs/hr.
30,000 CF/11 (,j) 180"F: particulate, to «rubber -200 lbs/hr.
Wa1er 200 GP/11; ><rubber etticltncy -90'/4.
28,000 CFM@ 14-0• F; p.1.rt1cul1te emi~lons to ,Umo,phtrc -20 lbs/hr.
Asph•lt productlon 219,800 tb,1hr or 109.9 ton>ihr.
11101
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l"I_IIIHII rio• .....
C I
AIR POLLUTION CONTROL OE VICE
I PLEASE TYPE OR PRINT. ATTACH TO GENE.RAL INFORMATION FORM "A". SUPPLY DESIGN DATA, SPEC I FICA fl~'.~:. ;A~:~
AVAILABLE ENGINEERING DRAWINGS.
Air Control Df'ice and 10 No. (FROM GENERAL INFORMATION FORM "A", ITEM 6)
2. If there are several device,; in ,eries, liu each unit in series starting at the emi:i1iun s.ource.
I (11 _ -----(2) ---· ____ (3) _________ TOTAL UNITS __ _
1 _3_._lnd,cate Emis,ion Source and ID No. that Control Device(,) is installed on:
4. N.iifl"3tive Oescript1on of Control Devicc(s):
I
I Manufacturer
----~-----.-~-----
Model Name ~1odel Number
5. Estimated Cost of Control Device Period of Tir,e Control Device is Estirn.a.ted to be Adequate:
, ___ 1_ .. _-_-=:::_·::::_-_-_-_-_-_____________ :::::::::::_-_Y_•_•_" ________________ _
6. Permit Application is made for (CHECK ONE ONLY):
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7.
( ) New Source ( ) Existinq Source ( ) Modification -La>t Pormit No. _________ _
Commence Construction Date __ _ _____ ,19 __ Operation Date ____________ , W.
Emission P.ilrameters:
Pnllu1>nt(1) Controlled
Emission Rate Before Control (lb/hrl •
Emission Rat• After Control (lb/hr) 0
RernovJI Efficiency Percent(%) =
PART.
( )
P.:inide Size Oistr1bu1ion of P.:inicula,es Entering Lontrol l)evice (% Micrvn):
.. 0· 1 ___ ,,11) ___ 10·25
co
I I
voe
( )
LEAD
( )
___ 50.100
OTHER OTHER
--------------------------------------------------
G.t) Co1l<iitium J.t Control Dtvice: INLET INTERMEDIATE LOCATIONS O\JTLET
Flow Rlte (ACFM) •
femperature (D•~-I') ,
Velocity (tt./sec.) ,
Pre)'.iurc Drop (in. H10) •
Moi)turt \%) =
I ~;,rnbc Ultimate Disposal ot Collectea Materials:
-----------·-· --
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·---··-----------
-------------
----------------~--------------------· -----------
iU. St.1,:k or [mission Point Oil.ta:
~fri,;;:ht Abov, l nside Area
f~rc,und (ft.} (sq. ft.)
'
-~----··· _ _] ___ ~
Ii \CJtfolding a..,,Jilabl, ior )ources te'iitln~?
,: i ·°'o i I Yes
:Jirection of Exit
(up, down, or horizontal)
! Are there obstruction'ii O'ier the ,tlck?
( ) ,"o I ) Ye<, (specify)
-----~---~-A.re 53mp!ing ports .1...,,ailable !
I I ,'so ( ) Yes
------------------------'-----------------------· ..... ----
11. \..vmments;
-----------·-·····--
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.:_ -'
STJPPLEMENTAL DATA FOR AIR CONTROL DEVICES
••• "CYCLONE" (MECHANICAL SEPARATORS) •••
C
1 Efficiency (%) I Volumetric Flow I Pressure Drop (in. H10)
1 Rate (ACfM) 1
! :,
I I
Baffles or Louver, (specify) [ Poslllvn in Series
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------'--------t--------t-------~--------------------! Cyclone Body Di,meter Cyclone Body Height (ft.)
Cyclone Dimensions (inches)
Inlet Outlet '(inches)
I Cyclone Cone Hei~ht \ft.I
Wet Spray \ No. of Noules
( ) Nu ( I Yes !
Liquid Used (specify) Flow Rate (GPM) J Makeup R~te (GPM)
. j
i % Recirculatea
A proccn flow diagram mu\t be .a.tu.coed If cyclone is routed to another cydone or other equipment, show sketch of entire 'iy'5tern.
evs:LQ~I! IJHGDll"I • T
CHfCK AP9ROPUATt ounn COllFIGURAT:QN BHCW SKETC!4 On< ER
COtlftGURATIOl-1
ON OUG~Atl oucr --..I
Below eoor reoor
INLET I H[!GHT
DIMENSION
CONE ICON[
I Ht!GHT
13.
••• "MUL TICYCLONE" •••
l;ffici,ncy (%)
Position in Series
'[ Volumetric flow
i Rate (ACFM)
No. of Cones I Pressure Drop (In. ti 20)
I
# ______ ot _______ Units
'
Louvers
( I No ( ) Yts
Inlet Dim•nsion of Individual
Cyclone (lnche,)
Outlet Dimension of Individual
Cyclone (Inches)
Individual Cyclone
Diameter (inches)
fl-Inlet T;;;;-;;;,rature
, (Deg. F)
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14. ••• "FILTRATION" (BAGHOUSE) •••
------~---------------~----------~------------------
Efliclencv (%) Volumetric Fluw FIiter Surface Air to-filter Area f:latlo Pre,sure Drop (1n. 1120)
R~t• (ACFM) Area (sq. ft.) (ft./mm.)
·---·--····---·-~-------~------------------------------
TYPE Of FILTER flL TER MAT(RIAL llAt; CLEANINl;
( ) Fabric Filter (BAGHOUSE) ( ) Fiberglas, ( ) Nylon ( ) ,\lechan,wl I Eo11ic
( \ P,cked Bed ( ) Mat Filter
Panel Filter
Other __
No. of Compartments
( ) Nomex ( ) Teflon ( ) Reverse Flow )
( ) Wool ( ) D,,cron ( ) Simple il>~ )
( ) Cotton ( ) O,ion C11llaps,
) Other ________ _ ( ) Other _ ..
/ inlet Temperature Position In Series
Ai, Pulse
Rin~ed Bag
Coll.1pse
Time Between Cle.1ning
(mins./hr.) I (Deg, F) ;:___ of __________ U11its
:5 ••• "AFTERBURNER" (FUME INCINERATOR)•••
rvpt" uf Atte1burner: f EfficiP-ncy (%) Volumetric Flow j Position in Seriei ---·
) llirect flame Rate (CFM) I "'------·----ot ··----·····-~nits
1, i C..1t.alytic
! ) Other ---···
l
_________________ .....,_~------1------··-----···-----·-··-
?,1aximum Burner Ratinq
,:Million BTU/hr)
! Cornbustion Chiimber
i Temp. (Deg. F)
'
I Retention Time I fuei Type ___ _
'(,ec.) Uwge ----·----·--•--__
Combustion ChJ.mber Dimensions (ft.): ________ Length _______ Qlameu~,
--·----------------------------------------·--··-------
: !_!i_:
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SUPPLEMENT AL DAT A ~-OR AlR CONTROL DEVICES -conrinued C
I 16 --------------------,--------.---------,----------------
•••"SCRUBBER"•••
Pase 3 ot 3
Type of Scrubber:
I ( ) Venturi
( ) Impingement Pl•te
( ) Pac~ed Tower
( ) Orifice Type
( ) Cyclonic
( ) Condenser
( ) Other
\Efficiency(%) 1i Volumetric Flow / POiition in Series
i \ Rat<: \ACFM) ! rt ____ of., ____ Unlu
~ -------·-·-
) Gra.ity Tower I ( ) .\fat Eliminator
I Liquid Scrubbing Medium
1 •nd Additives (specify)
,
1
Pre\surc Drop
(in. H20)
I
l Inlet Temperature
I (De11. F)
! Mi,t Eliminator Filter Area i (sq. ft,)
1 Toul Liquid Injection (GPM) [Ma_k_e_U_µ_R_•_te_( G_P_M_) ----
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G..., Flow
( ) Countercurrent
{ ) Concurre11t
Venturi Inlet Arca (sq, in.)
Scrubber
D,u:
Packed or Surfa~ Are• (sq. ft.)
Pl.ite Tower
Dau;
-----
,. ',.
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! i -~------------------.. ______ _
Throat Are, (sq. in.) : Throat Velm:iiy (ft./sec.)
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fixed Throat
Vari.tile Thro11
P•cking Depth (ft.) I Type of Pad:lng: No. of Plates
_J (.) Rings ( ) Saddles
f Type of Plate,
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( I Other ____ _ -----· -----
••• "ELECTROSTATIC PRECIPITATOR" ••• ---------
E tficiency ( % ) iVolumetrlc Flow Rate (CFM) J Total Collection Plate
! Area ( sq. ft.)
Pressure Drop
(in H20)
Inlet 1' cinperature
, (Deg. F)
I Re,ilH1\liCy of
l'ollutant (OHM-CM)
: Ga, Viscosity (poise)
'
Charging Field Strength (volu)
!
i Collecting Field Strength (volt<)
I
I PR[CIPIT ATOR TYPE
Singk StaKe ( ) Low Voltage ( ) Hot Side
CLEANING METHOD
( ) Plat• Rapping ( ) Wd>llin~
I lwo Stage ( ) Hll!h Voltage ( ) Cold Side I i ) Other ____________________ _
( ) Pine Vibrating ( ) None
\ ) Other ··--
,------------------~--r------------· ----·-----
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Corona Power
iW,m/ 1000 dm)
l8.
Typ~ of Adwrption:
; Electrical Usage (kw./hr.)
I i
( ) One-P;iss Rl"~eneratiYt' ( ) Recircul.ating
No. ot COmpartmcnu i~o. of Cells/Comp. 1 Position in Series
I ! ;t ___ of _______ Units
-----------_!
"'** ",\DSURPTION'' •••
Efficiency (%) i Volumetric Flow Race (ACH1)
1· } One-Pas\ Nonregenerative ( ) Q[her _________ _
Regenerative Method:
i ) f)'1~,arded (
\ Chrmical (
Thermal ( dry heati
Therma.i (stcami
, ) Ott1er ---·------------------
f'rt-.~ur~ Drop
\in H~i)l
i Inlet Temperature
[ (Deg. fJ
Siu ,)t ,\(horbent !:led I ft.)
L~ngtll __________ , Width _
-----------------------·-·-
i Adsorption Material:
i ( ) Activated Carbon
I ( ) Hydrous Silicated
; Position in Serie1
. :t _______ ot -----· ______ Ur1it'i
: ( I Other ____________ _
,! .~o. of Compartments
---, -----·-· -·· .. ---··---
,i How are emissions controlled (Juring
' i regcnerJ.tion !
I • ··-~-------~-----------•• -••• -----~----·-----------------------
Height OiJnu•tc,
Regcni:rJtlve ')..:hedule: M.u.imurn Time for Desorption ----------·----------
• Length of Time to Maximum SAturauon _____ _
I AREA DIAGRAM D
I Show all surrounding buildings ind ro;,ds within 1500 feet of the equlprmnt covered by this •Ppliutlon. Attach a site di•gram identify·
inii tich emis,ion source loution(s), property boundaries ind building (structure) dimensions (height, width, ind lenglh),
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ti ORTH
INSTRUCTIONS
1. lntlic,tt location a.nd type of building by the use of sm•II
numhercd circles with the decrlption below.
2. Show ro.1d~ .u lines ~presenting the ro~d edges. lndiute
nre~t n1mes and highway numben.
J. )how wooded or de~red Mea by approximate boundary
\ine, ,u1d the words "woods", "cleared", "comfitld", etc.
1500 feet
1000 feet
500 feet
X
CODE
( I)
(2)
(3)
(4)
(5)
(6)
( 7)
(8)
(9)
(10)
Example:
/
DESCRIPTION
( 1) Church
(1) Ke,iaence
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i: 0 \/ I ' • :-: '.j
HYDROCARBON EMISSION SOURCES E
:,.,jOTE: For emis~ion sources of volatile organic compounds including spray Cooths, paintinte, flnlshini;i, prlntin& and sol"w"ent u!tage.
I PLEASE TYPE OR PRINT. ATTACH TO THE GENERAL INFORMATION FORM "A". IF APPLICABLE.ATTACH AIR POLLUTION
LONTROL DEVICE FORM "C".
1 _1_. _E_m_i•-•-io_n_s_· o_urc_•_•_n_d_l_D_N_O_. -( F_R_O_M_G_E_N_E_R_A_L_I_N_F_O_R_M_A_T-IO_N_F_O_R_M_" :~ EM_6_) -
' Prnce,s Demiption (INDICATE NO. OF IDENTICAL PROCESSES -BOOTHS, FINISHING LINES, ETC.): ________ _
I
3. Permit Applic,tion Is made for (CHECK ONE ONLY):
I ( ) New Source ( ) Existing Source ( ) Modification -Lan Permit No.
CommenccConmuction D,te --------• 19 __ Operation Date __________ , 19 __ _
____ Hours/Day ____ Day,1Weck ____ WeekJ/Ye•r 1:· .Maximum Source Op•ratlon:
,. Li« all VOLATILE ORGANIC COMPOUNDS u used: USE NEXT PAGE (PRODUCT ANALYSIS WORKSHEET) TO DETERMINE
IF PRODUCT IS REACTIVE (R) OR NONREACTIVE (NR) AS DEFINED BY 15 NCAC 2D .0518.
I TOTAL
VOLATILE
BY WEIGHT
voe
EMISSION
RATES
•
PRODUCT NAME
---~--·-·-------· -
R NR
PRODUCT
WEIGHT
(lb/gal)
PRODUCT
USAGE
(gal/day) X (lb/gal) • _____ x
----------X
(lb/day) (ton/yr)
I
_______ x
-----------·------X
·-------------------X
X
2
=
--------I ·-··
--.. __ .... ·------. -·--·-·-------------------- X
--------------·----------X
l!SE Sf.PARA TE SHEET(S) IF NEEDED TOTAL • ----. 16. fJ·e~cr1bi: the stor.i2e .tnd handling methods use<.l in employ in" the orgat1ic products jj~~~d·-~·b~ve~-~i~d;the ultimate dispo,JJ me1h~t1s
nt the rolle-t::ted w,ute .and wa.new.aler. ___________ _:_ _____________ . __ _
I -~----··--· ---------·-----------------
---
-------------------------· -----.
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7. ~u• I.H:.t" (o,1ting U1>erations:
Di:-~nbe r\rt1des l:3eing Cuared:
-----•-------·-------·---------·--------------··-----' \1t'llwll ol Sorav:
i' } Airles\ 1. } Air Atomize t ) Electrosutic
Exhaust
Control:
i l None
) WJterNash
( ) Drv Filter
i ) Baffle,
Oth<r __________ _
No. of 8.tk.e Oven~ I .\1ethod of I Heating:
Steam
Electric
0HrsOrd.V (%)
) Other _______ _
)tack flow
Rate (CFMI
( ) Adsorption
( ) Incineration
I ) Direct Fired
( ) Other
-I Control-Efflclencv
! Parti,ulAte____ --~~
i Hv,Jroc.ubon _________ -;b
----·-------------·--------------
1 Fuol Type
----i U,age
I .... -. s·(li:~~~ ·r;;;;;;;·ir~ OprrJlioni:
Dt>\{;1 ,be A.1 tide_,; 8eing Uegreased:
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:;~~ll;'J.\l'I" J"ype:
:. ! Open r <>P Vaoor ( I Cold Cle,ning ( ) Convevori,ed I I Other
T .rnk (.1pacitv ! ~1.akeup Ra1e
!~allon,) ! (glllon,/dav)
I Exhauu Control: None
Adsorption
Other __ _
( ) :)uria.ce Condensers
( ) Closed Loop
I PRODUCT ANALYSIS WORKSHEET
(SOL VENTS, PAINTS. FINISHING MA T£RIALS, ETC.) E
:..•,:~e 2 ..:if 1
I INSTRUCTIONS: COMPLETE ONE SHEET FOR EACH TYPE OF PRODUCT. GIVE CHEMICAL NAMES, NOT BRANO NAMES OR
ABBREVIATIONS. FOLLOW THESE PROCEDURES IN DETERMINING WHETHER OR NOT A PRODUCT OF VARIOUS
SOLVENTS 15 REACTIVE (R) OR NONREACTIVE (NR).
IA)
IC)
GROUP THE CONSTITUENTS ACCORDING TO WHETHER OR NOT THEY FIT THE DESCRIPTION IN CLASS 11), 1.21,
(3) OR NONE OF THE ABOVE CLASSES. IF A CONSTITUENT COULD FALL IN TWO GROUPS, IT IS PLACED IN THE
MORE LIMITED GROUP.
DETERMINE THE VOLUME PERCENT OF ALL LIQUID CONSTITUENTS OF THE PRODUCT AS APPLIED. (THIS SHOULD
TOTAL 100%.)
TOTAL THE VOLUME PERCENT FOR EACH CLASS (1, 2, AND J). IF THE VOLUME PERCENT FOR ANY CLASS
EXCEEDS THE PERCENT LIMIT FOR THAT CLASS OR IF THE TOTAL FOR CLASSES (1), (2), (3) EXCEEDS 20 PERCENT.
THEN THE PRODUCT IS REACTIVE. IF NONE OF THESE LIMITS ARE EXCEEDED, THE PRODUCT IS NONREACTIVE.
I Product Name Product No. This Product is Cla.uifitd as:
( ) Reac1ive (R) ( ) Nonreactive (NR)
I PRODUCT COMPOSITION
ORGANIC I CLASS ----DESCRIPTION OF ORGANIC CLASS NAME OF CONSTITUENTS
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( 1)
(3)
A COMBINATION OF HYDROCARBONS, ____________ _
ALCOHOLS, ALDEHYDES, ESTERS, OR
KETONES HAVING AN OLEFIN IC OR
CYCLOOLEFINIC TYPE: OF UNSATURA-..
TION EXCCPT PERCHLOROETHYLENE
-I PERCENT
,\ COMBINATION OF AROMATIC
HYDROCARBONS WITH EIGHT OR
MORE CARBON ATOMS TO THE
MOLECULE EXCEPT ETHYLl!ENZENE
-S PERCENT
A C0.'1t!INATION OF ETHYLBENZENE,
KETONES HAVING IJRANCHED
HYDROCARBONSTRUCfUK~
TRICHLOROETHYLENE, OR
TOLUENE
-·10 PERCENT
ALL SOLVENTS NOT LISTED ABOVE
SUB-TOTAL:
SUB-TOTAL=
SUB-1 OTAL =
--·--------------
I Product U>dge \gal/hr)------------------------~-=----.. -__ -_-__ -
TOTA!. •
Product W.,l!ht ilb/gal) _ .I Wt!ight of '-'Oi,uile'> in product (lh/gaJ)
Total% ¥Olltile5 by ll'Oiume in produce
% BY VOLUME: OF THE
TOT AL VOLA f !LES
ACTUAL % LIMIT
5%
100%
I IF THE TOTAL REACTIYE PRODUCf EMISSIONS EXCEED 40 POUNDS/DAY FROM YOUR FACILITY, DESCf\lUL i HE
CONTROL METHODS EMPLOYED FOR MEETING COMPLIANCE WITH UEM REGULA flON 15 NCAC :D .0518:
I ----·
I INCINERATOR F
-p•lof2
LEASE TYPE OR PRINT. ATTACH TO THE GENERAL INFORMATION FORM "A", IF APPLICABLE, ATTACH AIR POLLUTION
(ONTROL U~VICE FORM "C".
1. Em,..,on Source •no ID NO. (FROM GENERAL INFORMATION FORM "A", ITEM 6):
Incinerator LJescription:
.\1anutact1.Jrer Model Name Model Number
~Permit Application Is mado for (CHECK ONE ONLY): ■"· ( ) New Source ( ) Existing Source ( ) Modification -Last Permit No.
Commence Construction Date____________ , 19___ Operation Date----------, 19 __ _
Maximum Source Operation: ____ Hours/Day ____ Days/Woek ____ Weeks/Yeas
lype of Waste Burned:
(See codes on next page)
Maximum Charging Rate (lb/hr) Tons/Year Burned Tot.l Waste Generated (lb/day)
Design I Actual
-··----------·-------'--------'--------.L..-----------'-------------l"-· __ c_o_m_b_u_11_ib __ 1_._-_-==---i_. __ .--N_o_n_,o_m_b_u_n_ib_1e_-::._-::._:-:_% ____ M_o--,is_tu_re_:::-::.-_% ____ H_e_a_t_v...,a_1u_•_-_-_-_-_-,:_-_:-_-_-_-_:-_-___ (_B_r_u_1_1b_)
7. Primary t:hambe(: Secondary Chamber: Secondary Chamber Type of Feed
V ft V I Retention Time: ( ) Manual olume ______ cu. . o ume ____ cu. ft.
Temperjture ____ " F Temperature ____ ° F econ s -----I S d ( ) Automatic
---------'-------------'.-,---------'------,--------8. Burner Dal.I: BURNER RA TING (BTU/HR) / ~.IR FLOW (CFM) Exc<ssAir(%) I Primary· Seconduy i Overtire I Underflre
·····---·---------------~---------_..---
Is there a pr~hur timer/ ( ) No ( ) Y•s. Preheating Tirn• _________ Min.
Auxiliary Fuel D•t.1: Primary Fuel Type(s) ___________________ _
Seconduy Fuel Type(,) ________ _
I FUEL fYPE FUEL USAGE I Max.% ! MaK. % i '
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NatlJrJ.I (l.is
::z·i f'11el Oil
Other ···----·-
1\ir Com.aminanu
Emitted:
f' .1.rti1·u1.Hes
Sulfur Dioxide
Nitro~en Dioxide ..
(JrbcJn Monu-.1tl~ .
Hydroc.ubon~ iVOC).
L•:Jd.
Ut11er I ----
!
Mal(. Desiifl Max. Actual I Annual . -
I (SCFI (SCF) ISCF/y,I
lgiJ/hrl I
f gJl/hr) l1iJ/yrl
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M>-Xlmum Actual Emissions
B,fore Control
(lbs/hr)
After Control
(lbs/hr)
Other I____ I
Sulfu, Ash -·-•·---·
--·
!
I Emission'
I E11imate I
j Method•
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!
Control
Device-"•
'REFER TO 0ACK OF GENERAL INFORMATION FORM "A" FOR EMISSION ESTIMATION CODE
••"-HACH APPP.OPRIATE AIR CONTROL DEVICE FORM "C"
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BTU Value
(BTU/SCFI
-----· I (BTU/1,II
·--i
I i
Control
Efficiency %
I INCINERATOR -continued F
~--Ci°c,oibe an\' liquid or solid waste, generatea ,nd method oi disposal:
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13.
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14.
Suck or Emisiion Point O.ata:
Height Above Ground (ft,) Inside Area (sq. ft.) GaJ Temperatur,, (Deg. F)
Volumetric Flow Rate Velocity (ft./sec.)
(ACFM)
Are sampling poru available? I ( ) No ( ) Yes
I
ha RCRA pennit required by th• N. C. Department of Hum•n Resources? ( ) No
Direction of Ex it
(up, down, or horiiontaJ)
Is rain cap ur other obstruction over
stack? ( ) No ( ) Yes, (specify)
( ) Yes
If yes, has a RCRA permit application been submitted/ ______ Dau: ____________ , 19 __ _ I ---------------------------------------------
15.
116.
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CODE
I 0
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3
I 4
5
I 6
List ALL incln<rated HAZARDOUS WASTE specified in the RESOURCE CONSERVATION AND RECOVERY ACT (RCRA)
(40CFR 261) in the comments section below:
Cumment!.:
----------------------------------------------------. --------·-··
••• TYPE OF WASTE BURNED CODIE TABLE •••
PrindpaJ components. usual source. and typical moisture content
lliihJy combustible WB!t<. paper. wood. cardboard cartons. (lnclu,hng up to 107, treoted paptr,, pla>Tic or mDber S<:ropsi;
from commercial and industrial sources: lOo/" moisru~.
Combustible wane. paper, carton,, mp, wood scraps, combustible lloor sweeping,; irorn domestic. 1..·omniercial, .1nd inJm-
trial so\UCCS: 25 1,~ moistwe,
Rubb~h und garbs~; from r~ideotial sourcei; SO'lr-moisture.
Predominantly animal and ,·•gctable waste: from restaurants, hotels, markets. in,titutional, commercial and club sources;
":'Oo/u mvi:.lu1"t:.
Carcasse!, organs. solid organic wastei; from hospitals, bboratorie~. )lau&Jlterhouse.s. animal pounds, and similar '.'>ourc.cs:
85% moisture.
Gaseous and semi-liquid industnaJ pr~ss waste: variable moi!iru~. Describe in Jet.all under comments.
4:iolid and semi-goUd by-product waslf. such as rubber, plastics. wood waste. etc., from industrial operatlom; ~:.:malJli:
urnl\tu.n:. DeKribe in de(ail u1hirr comm(nts.
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DERSONAL PROTECTIVE EQUIPMENT
EMPLOYERS SHALL PROVlDE AND ENSURE THAT EMPLOYEES USE QPPROPRIATE
DROTECTIVE CLOTHING CNO EQUIPMENT NECESSARY TO PREVENT REPEATED OR
PROLONGED SKIN CONTACT WiTH THIS SUBSTANCE. FACE S~iELDS SHALL COMPLY
:~JTI~ 2'3CFR1'31O. 133 (Pl (2), <,Al (4J, <A) 15). AND <Al (6).
EMPLOYERS SHALL ENSURE THAT CLOTHING CONTA~INATED WITH THIS SUBSTANCE
:s PLACED !N CLOSED CONTAINERS FDR STORAGE UNTIL :, CAN BE D'.3CARDED OR
UNTIL THE EMPLOYER PROVIDES FOR THE REMOVAL OF THE CONTAMINANT FROM THE
CLOTHING. IF THE CLOTHING IS TO BE LAUNDERED OR OTHERWISE CLEANED TO
REMOVE THE CONTAMINANT, THE EMPLOYER SHALL INFORM THE PERSON PERFORMING
~HE CLEANING OF THE HAZARDOUS PROPERTIES OF THE SUBSTANCE.
ACGIH "GUIDELINES FOR SELECTION OF CHEMICAL PROTECTIVE
:L□THING'' :NDICATES THE FOLLOWING ~ATERIALS AND
JROTECTIVE RATINGS BY INDEPENDENT VENDORS AGAINST
aTHYLENE GLYCOL:
'::XCELLENT/GOOD:
.',,ATURAL '1UE<BER
'iEOPRENE
,JJTR11._E ''UE<E<ER
COOL YETl•!VUc.NE
:JOI._ 'l:JRET'.--iA!\JE
POLYVINYL CHLORIDE
GOOD/<='AI,'<:
81, _ _r:v·,. c;,uBBER
~EOPRENE/NATURAL RUBBER
~I I TR-~! __ ;;::,: DOL '/'..) 1 !\','(: __ :~~:....:1_C)H IDS
:HLOR!NAT~D POLY~Tt◄YLC~F
~ 7'l ~~NE-;·:iUT (=ID I f,\:C .;•: . ..1 Bb1.:~ ,1
,Jl TON
,0 A! f1/GOOD:
'-JEDPRE:-.JE / ST'I RENE-· BUT1::'~[I T ::~\,:·_::-:-.-: .1I~BE ~
r;c.GGL_ES
"::..,.,p· __ C'/F::Rr:; SHALL ':'iR[1'.,; I L1E ~:1.•,J[J -::>.r:::;u:-~.,: . 1(.:..1-:·· -::-'fi(:'"i:_c::'/~:::~-:'.=: · . .:S:': :;c,: __ ;:;'.::);+-::i,<□0!=-
·.:;,c.:r::-i::";V 1:;QGGL_ES WHl[;~ r::<):'l",::J: __ '{ wr.··r!-~ ;._>;+CF~{-·):U~ 1.-~.::,(i,:;; (2) --!~) it~-) ',..Ji--lERE -:-Y.IS
_:~U!D ~!AY CONTAC~ ---~~ ~YES.
::·,.;vo:_:~) eir~ :-i• ~SSING DP:TcJ~J (5)
: · .. ~j ,:: .. -:: □ m
--~:.1~'::::!•1IC1':lL ::;iRT~·::.Dr1::-: -~:::SPTR\'.:1TOq
:,..i·,-:-• AN CJRGA\'Jll~ ',:i-=IP[:q :.~~::iR-r 1::::!DGt=:
-SEL~-CONTQINED B~EqT~·~ING ~POAf~A·r~s
WIT!~ A F\J~L ~OCE-~IECE
-SUP □L:::D-•QIR ~~s=r~A"'['QR