NCD001810365_20020917_Martin-Marietta Sodyeco Inc. (Clariant)_FRBCERLA SAP QAPP_Surface Water and Sediment Sampling Results-OCR

I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Septembcr17,2002
Mr. Karim Pathan
Hazardous Waste Section
Division of Solid Waste Management
401 Oberlin Road
Raleigh, North Carolina 27605
Subject: Surface Water and Sediment Sampling Results
Clariant Mount Holly East Facility
EPA ID# NCO 001 810 365
Dear Mr. Pa than:
' i.l l SEP 1 9 2002
'
On behalf of the Clariant Corporation, Camp Dresser & McKee (COM) is pleased to submit this
letter report documenting the results of surface water and sediment sampling and analysis frmn
the vicinity of the Mt. Holly East Facility. TI1ese activities have been identified as follow-up
actions in the RCRA Corrective Action Environmental Indicator (El) Detenninations for the
Clariant Mount Holly East Facility (EPA ID# NCO 001 810 365) completed in September 1997
and October 2000.
Background
Previous surface water and sediment samples from the Catawba River and Long Creek were
collected in October 1986 and April 1987. Table 1 summarizes the results of the October 1986
and April 1987 sampling. No evidence of significant contamination was detected, although one
low level detection of o-dichlorobenzene was found in surface water and several low-level
detections of xylene, fluorene, and phcnanthrene were found in sediment. Several tributaries
(drainage swales, primarily) to Long Creek and the Catawba River did show higher levels of
contaminants, including trichlorcthylene, tetrachloroethylene, and chlorobenzene, in addition to
o-dichlorobenzene, xylene, fluorene, and phenanthrene.
The initial 1997 evaluation of the Mount Holly East Facility's status under the RCRlS Corrective
Action Environmental Indicator (EI) Event Code CA725 (Human Exposure Controlled
Determination) resulted in an "IN" determination, indicating that more information was
needed (September 30, 1997 letter from R. Grover to J. Carter). Sampling was to be conducted
to determine if surface water and sediment were contaminated above appropriately protective
risk-based levels. If the results indicated that these media are contaminated above such levels
then following the EI RCRIS code CA725 reasoning, a determination would be made if there arc
P:\Clariant -5256\Sed Sampling & Wall Survey 34095\Repor1s\kp8-26-02.doc
.RA·
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CDM
Mr. Karim Pathan
September 17, 2002
Page 2
complete pathways of human exposure, if such exposures are significant, and if the possible
significant exposures are within acceptable limits.
An EI evaluation for the Clariant Mount Holly East Facility was prepared in October 2000 by
the Hazardous Waste Section (HWS). At that time, it was determined that more information
was required with respect to the RCRIS code CA725, specifically with regard to surface water
and sediment contamination (October 27, 2000 letter from K. Pathan to J. Pafford). Additional
surface water and sediment sampling from Long Creek (on-site) and the Catawba River
(adjacent to the site) was conducted on June 20-21, 2002.
Surface Water and Sediment Sampling and Analysis Work Plan
A brief work plan dated March 2002 entitled "Surface Water and Sediment Sampling Work
Plan" for Long Creek, the Catawba River and other on-site tributaries was prepared and
submitted to the HWS. The work plan included the following sections: Introduction and
Objective, Sampling Locations, Sampling and Analysis Procedures and Protocols, QA/QC
Measures, Reporting, and Health and Safety Plan. The 1-IWS section responded to the work
plan for surface water and sediment sampling in a letter from Karim Pa than to Gary Sanderson
dated May 15, 2002. The comments provided by the 1-IWS and a response to comments is
provided as follows:
Comment
1. Section 1.1. Assuming all of the contaminants are n1oving from the source area to the stream
via ground water, the objectives should include a discussion of ground water flow and the
hydrogeology. The discussion should include the identity of any preferential ground water
flow paths and a flownet illustrating ground water flow in both plan view and cross section.
The flownet will be used to support the sampling locations.
Response
Groundwater flow paths have been conceptually determined, but sufficient groundwater data
is generally not available to support creation of detailed flownets. Conceptually, the
groundwater flows from CERCLA Areas A/Band C south towards Long Creek, a local
discharge feature. The Catawba River, which bounds the site to the west, is a regional
groundwater discharge area, and a local discharge area for much of the water recharging the
site. Groundwater contours and cross-sections of CERCLA Areas A/Band _Care presented in
P:\Clariant • 5256\Sed Sal'Tl)ling & Well &Jrvey 34095\Reports\kpB-26-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Mr. Korim Pathan
September 17, 2002
Page 3
Figures 1, 2, and 3.1 These cross-sections assisted in determining the surface water and
sediment sampling locations. By and large, contaminated groundwater is found throughout the
CERCLA areas and the RCRA area. Other than variations in magnitude of contamination,
specific, isolated plumes are generally not present. The sample locations were chosen based on
their general locations downgradient of each of these areas. Since the purpose of this study is
to determine if surface water and sediment are contaminated above appropriately protective
risk-based levels, the sample location selection was deemed sufficient for the stated objective.
Com111e11t
2. Section 2.1. Specific sample locations should be reevaluated and altered if necessary after
considering comment #1.
Response
Please refer to the discussion under comment No. 1.
Com111e11t
3. Section 2.1. What does sediment sampling involve? Will it include analysis of the soil matrix,
pore waler, or both?
Response
The protocol used for sampling of sediments is discussed in detail in the Work ·Plan and in this
report in the Surface Water and Sediment Sampling Procedures section. If a thin water level was
noted upon receipt of the sediment samples by the laboratory, the samples were gently mixed
for uniform homogenization as per the Standard Operating Procedures of Paradigm Analytical
Laboratories, Inc. TI1e sediment matrix (solids, pore water, and voids) is then weighed and
analyzed according to U.S. EPA methodology. Volatile compounds analyses were performed
via Method 5030 Purge and Trap and Method 8260B. Semi-volatile analyses were performed
and via Method 8270C and extraction was performed via SW846 Method 3545 using accelerated
solvent extraction (ASE).
Comme11t
1 The cross-sections were initially developed for the semi-annual Evaluation ofRCRA & CERCLA Remedial
Action Effectiveness reports. The most rec~nt report was completed in May 2002.
P.\Clarian1 • 5256\Sed Sarrpling & Welt Survey 34095\Repcrts\kpB-2&-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CDM
Mr. Karim Pathan
September 17, 2002
Page 4
4. Section 2.1. As Clariant knows surface water samples can be affected by many factors
including stream flow, weather conditions, rainfall, etc. Consequently if contaminants are
found in surface water samples then the concentrations of contaminants achtally discharging to
the surface water is probably higher. Another method of defining the area where contaminated
ground water is discharging to a stream is by monitoring piezometers installed into the
streambed. Water quality data from the piezometers provide a good indication of the ground
water quality discharging into the stream. This data, in conjunction with the surface water
samples collected under low flow conditions, can also provide a good indication of how the
contaminants and contaminant concentrations change as they move from the subsurface
environment to surface water. The HWS encourages Clariant to consider the installation of
piezometers and the collection of ground water samples at each surface water sample location.
Response
The installation of piezometers would be helpful in determining the area where impacted
groundwater is discharging into a stream. The purpose of this study is to determine if surface
water and sediment are contaminated above appropriately protective risk-based levels. This
objective was considered achievable without identifying the possible locations where
contaminated groundwater is discharging to Long Creek and the Catawba River. Future
investigations of surface water and sediment, if deemed necessary, may examine likely
discharge points in more detail.
Comment
5. Section 2.1. Sample location CR-O. If the sample location is located downstream of the
facilities wastewater treatment discharge then how will Clariant differentiate the contaminants
discharging via ground water and those discharged through the wastewater discharge?
Response
Sample CR-O was collected to better understand the cumulative effect of Clariant's operations
on the Catawba River. The purpose of sample CR-0 was not to aid in differentiating the effects
of impacted groundwater versus discharge from the NPDES point discharge location, but to
determine if surface water and sediment are contaminated above appropriately protective risk-
based levels. Clariant monitors the NPDES discharge effluent in accordance with all NPDES
regulations.
Comment
P:IClariant -5256\Sed Sampling & Wall SLJrvey 340951Reportslkp8-26-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
0
0
R
D
CDM
Mr. Karim Pathan
September 17, 2002
Pages
6. Table 3-2. A] litre amber glass container will be required for the semi-volatile organics.
Response
A 1-litef amber glass container was used for the semi-volatile organic sampling.
Surface Water and Sediment Sampling Locations
COM conducted surface water and sediment sampling in Long Creek, the Catawba River and
an on-site tributary to the Catawba River. Actual sample locations are shown on Figure 4. Both
surface water and sediment was collected at each location. On the day of the sampling event,
no water was flowing in the tributary to the Catawba River located in Area E; therefore no
surface water sample was collected from the TRJB location. Each sample location is described
as follows:
LC-A. Background surface water and sediment sample location for Long Creek. This sample
was collected from a point approximately 300 feet cast of Bclmeade Drive from a location that
is upgradient of all Clariant hazardous waste operations. Plant operations have hist6rically
taken place west of Belmcade Drive.
LC-B. Long Creek sample location, downgradient of Area C and drainage swale east of
Building 42. This sample serves to assess Area C impact and further gauge effectiveness of
the Arca C remedial system. The sediment sample was collected from a depositional area
characterized by a pooling of water along a straight section of the creek. Xylene, fluorene and
phenanthrene were previously found in sediment near this location.
LC-C. Long Creek sample location, downgradient of Area A/Band drainage swale west of
Building 53. This sample serves to assess Area A/B impact and further gauge effectiveness
of the Area A/B remedial system. O-Dichlorobenzene was previously found in surface water
at this location. Sediment was collected from a depositional area caused by a creek bend.
LC-D. Long Creek sample location, downgradient of the closed landfill (SWMU53). This
sample serves to assess combined impacts· from all potential upgradient sources (including
Areas A/Band C) and the closed landfill. Sediment was collected from a depositional area
caused by a bend in the creek. Phenanthrene was previously found in sediment near this
location.
P:\Clariao1 -5256\Sed Salll)ling & Well Survey 34095\Reports\kp8•26-02.doc
I
I
I
I
D
I
I
I
I
I
I
I
D
I
I
Mr. Karim Pathan
September 17, 2002
Page 6
CR-Al. Background surface water and sediment sample location for the Catawba River. This
sample was collected from a point at least 1000 feet north of the northern property boundary
and is used to determine background for the near-shore sediments and surface water.
CR-A2. Background surface water and sediment sample location for the Catawba River. This
sample was collected from a point at least 1000 feet north of the northern property boundary.
This sample was used to determine background for the mid-river sediments and surface
water.
CR-D. Catawba River sample location, downgradient of the facility discharge location. This
sample was collected from 100 to 200 feet downstream of the facilities wastewater treatment
discharge point. This sample is used to assess the potential impact to surface water and
sediment from the facilities wastewater discharge.
CR-Cl. Catawba River sample location, downgradient of the RCRA area. This sample is used
to assess the potential impact to near-shore surface water and scditnent from potentially
contaminated groundwater discharging from the RCRA area.
CR-C2. Catawba River sample location, downgradient of the RCRA area. This sample is used
to assess the potential impact to mid-river surface water and sediment from potentially
contaminated groundwater discharging from the RCRA area.
CR-Bl. Catawba River sample location, downgradient of CERCLA Area D. This sample is
used to assess the potential impact to near-shore surface water and sediment from potentially
contaminated groundwater discharging from CERCLA Area D.
CR-B2. Catawba River sample location, downgradient of CERCLA Arca D area. This sample
is used to assess the potential impact to n1id-river surface water and sediment fron1
potentially contaminated groundwater discharging from CERCLA Area D.
TRIB. Tributary to Catawba River sample location, downgradient of CERCLA Area E. This
sample was collected several hundred feet cast of the Catawba River from the tributaries
most upstream point. The tributary was dry during the sampling event; therefore, surface
water samples were not collected but sediment samples were collected. This sample serves to
assess Area E impact and further gauge effectiveness of the Area E remedial system.
Anthracene, fluorene and phenanthrene were previously found in this tributary.
P:\Clanan1 • 5256\Sed Sampling & Well Survey 34095\Raports\kpS-26-02.doc
••
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
I
Mr. Karim Pathan
September17,2002
Page 7
Surface Water and Sediment Sampling Procedures
Surface water and sediment sampling from Long Creek (on-site) and the Catawba River
(adjacent to the site) was conducted on June 20-21, 2002. Surface water sampling was
conducted during low flow conditions to provide for the most conservative estimate of
potential water quality impact. Sampling occurred after several days of little or no
precipitation, which lessened the impact of storrnwater runoff. Flow in the Catawba River is
gener~lly lowest between the months of Jtme through December. Flow is generally 25 to 65
percent higher in the period January through May as compared to the rest of the year.
However, because precipitation during the fall of 2001 and the spring/summer of 2002 was
significantly below normal, flow in the Catawba River, and to a certain extent, Long Creek, is
below normal. In fact, prior to sample collection, Mount Holly, NC was in the midst of a four
month drought classified as an "04 Drought-Exceptional".
COM subcontracted with Normandeau Associates of Aiken, South Carolina to provide a boat
and assist in sample collection in the Catawba River. Surface water samples from Long Creek
and the Catawba River tributary were collected at mid-depth, at least 3 feet from shore, with a
dipping cup.
Surface water samples were collected as discrete grab samples. Surface water from the Catawba
River was taken just above the river bottom, at both the near-shore and mid-river locations.
Sampling from near the bottom provides the most conservative estimate of potential
contamination from groundwater discharge, prior to mixing with the entire water colmnn.
Sampling was conducted as per the Work Plan with the following exceptions. Surface water
samples from the Catawba River were taken using polyethylene tubing lowered to
approximately 1 foot above the river bottom. To collect a sample, a small centrifugal pump was
activated to pull water from near the river bottom through the length of the tubing. After
pumping for a short time, the top of the tubing was crimped to prevent sample release, the
pump was disconnected, the entire length of tubing was raised to surface level, and the water
collected in the tube was emptied into the appropriate sample containers. This method ensured
that sampled water did not pass through the pump prior to collection. Between sample
locations, the tubing was decontaminated using tap water and soap (Liquinox®), and rinsed
thoroughly with organic/analyte-free water and isopropyl alcohol after each sample.
Sediment samples from both Long Creek and the Catawba River were collected as per the Work
Plan using a Petite Ponar sampler. Sediment was collected from the top six inches of sediment
since the potential for any significant human or ecological exposure to deeper sediments is
unlikely. Sediment sampling from Long Creek was conducted at least three feet away from
shore. Depositional areas were favored as sampling locations. Sediment samples collected
P.IClarian1. 5256\Sed Sa~ing & Well Survey 34095\Reports\kp8-26-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
I
0
0
R
I
Mr. Karim Pathan
September 17, 2002
Page 8
frorn depositional areas are noted in the sediment sample location descriptions. Depositional
areas include the inside of river bends, downstream of islands, downstream of obstructions, and
areas of flow reversal.
Surface Water and Sediment Sampling Analytical Results
Samples were analyzed for volatile organic compounds by method 8260B, semi-volatile organic
compounds by method 8270C, and inorganics (RCRA metals) by methods 6010B and 7470.
Sediment samples were also analyzed for total organic carbon (TOC). Attachment 1 presents
the analytical laboratory results from all surface water and sediment samples. Samples were
placed in an iced cooler and shipped to Paradigm Analytical Laboratories in Wilmington, North
Carolina via FedEx overnight delivery, for analysis. Samples were submitted for standard
laboratory turn-arotmd time of two weeks. Sample notes were recorded in a dedicated field
book and logged for grid, depth, and soil description. Surface water and sediment sample
analytical results are compared to applicable Standards, Criteria or Guidance values (SCGs).
Exceedances of SCGs are n_oted in the data tables and within the text below. Figure 4 presents
the surface water and sediment sampling locations and identifies the compounds detected
above method detection limits.
Quality Ass11ra11ce/Q11ality Co11trol
11iree duplicate samples were co11ected to assess potential contaminant analysis variability.
Sample "DUP-1" is a duplicate sediment sample of "TRIB". Sample "DUP-2". is a duplicate
surface water and sediment sample of "CR-Bl". Sample "DUP-3" is a duplicate surface water
sample of "CR-1". Duplicate samples were analyzed for VOCs, SVOCs, RCRA metals and TOC
(sediment only). Two trip blanks were used to assure proper storage and handling of samples
and shipping containers. Sample occurred over a two-day period and the samples were
shipped to the analytical laboratory at the end of each day's sample collection. One trip blank
accompanied each sample shipment. Trip blanks will be analyzed for VOCs by method 8260B
only.
Two constih1cnts were detected in the trip blanks. Toluene and methylene chloride were
detected at 2 and 5 µg/1, respectively. The analytical laboratory suggests that the glass
manufach1rer contaminated the glassware used to collect surface water samples. Attachment 2
presents a letter of documentation from the Paradigm Analytical Laboratories discussing the
contaminated trip blanks. Due to this contamination, toluene detections in surface water
samples CR-Al, CR-A2, CR-Bl, DUP-2, and sediment sample FB-SD should be regarded
cautiously.
P:\Clariant -5256\Sod Sampling & Well Survey 34095\Reportslkp8-26-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CDM
Mr. Karim Pathan
September 17, 2002
Page 9
Two equipment field blanks were used to assure the proper decontamination of sampling
equipment. One field equipment blank was collected by pouring organic/analyte-free water
through the discrete surface water sampling device, A second field equipment blank was
collected by pouring organic/analyte-free water through the sediment sampling device. Both
samples were collected after all other sampling was complete, and after the equipment has been
decontaminated. The field blanks were analyzed for VOCs and SVOCs. Three constituents
were detected in the field blanks. The FB-SW sample, collected from the surface water sampling
device, was found to contain acetone and diethylphthalate at concentrations of 36 and 14 µg/1,
respectively. The FB-SD sample, collected from the sediment sampling device, was found to
contain toluene at 1 µg/1 and Thallium at 0.0114 mg/I. The North Carolina Class C Surface
Water water quality standard (WQS) for Thallium is 0.004 mg/I.
Surface Water Analytical Results
Table 2 presents the analytical results for organic constituents in surface water samples. Surface
water results were compared to North Carolina Surface Water Standards as described in 15A
NCAC 02B.0216 for class WS-IV watersheds. The area of the Catawba River adjacent to the
Clariant facility is classified as WS-lV (water supply-highly developed), which means the river
is used as a source of potable water.
Surface water samples were also analyzed for RCRA metals. TI1e concentration of RCRA metals
was below quantitation limit (BQL) for all metals in all surface water samples.
Sediment A11alytica/ Results
Sediment sample results for organic constituents are presented in Table 3. Three PAH
compounds (anthracene, fluorene, and phenanthrene).in sediment sample CR-D were found to
exceed EPA Region 4 Waste Management Division sediment screening values for hazardous
waste sites. The sediment screening values are derived from statistical interpretation of effects
databases obtained from the literature as reported in publications from the State of Florida, the
National Oceanic and Atmospheric Administration, and a joint publication by Long et al.2,3,4
These values are based on ecological toxicity associated with a low probability of tmacceptable
risks to ecological receptors, which are generally significantly more stringent tl1an human
toxicity screening levels. The sediment screening values for these three PAI-ls represent
Contract Laboratory Program's (CLP) practical quantification limit (PQL). Sediment SCGs were
2 MacDonald Environmental Sciences, Ltd. Approach to the Assessment of Sediment Quality in Florida Coastal
Waters. Florida Department of Environmental Protection. November 1994.
3 Long, E.R. and LG. Morgan. 1991. The Potential for Biological Effects of Sediment-Sorbed Contaminants Tested
in the National Status and Trends Program. NOAA Technical Memorandum NOS OMA 52.
4 Long, E.R .. D.D. MacDonald, S.L. Smith, and F.D. Calder. I 995. "Incidence of Adverse Biological Effects with
Ranges of Chemical Concentrations in Marine and Estuarine Sediments." Environmental Management 19(1):81-97.
P:\Clarian! • 5256\Sed Sampling & Well Su,vey 34095\Reports\kp8•26-02.doc
I
I
••
I
I
D
0
I
I
I
I
I
I
I
I
I
g
D
CDM
Mr. Karim Pathan
September 17, 2002
Page 10
identified through consultation with NCDENRs Hazardous Waste Section (HWS). Where no
HWS-identified SCG existed for a particular parameter, additional screening values were
identified in USEPA (on-line) documents.
PAI-Is are ubiquitous and naturally occurring in soil and typically found at elevated
concentrations in highly urbanized areas due to emissions from furnaces, automobiles, and
other combustion processes.s Backgrotind values of PAI-Is in surface soil of urbanized areas
range into the thousands of parts per million. SCGs for these compounds, as specified in the
EPA Region 4 Waste Management Division sediment screening values for hazardous waste
sites, arc significantly lower than commonly observed background levels. It is unlikely
however, that background sediment contamination would result in the concentrations
observed. Anthracene and phenanthrene were impurities in raw material previously used at
the Clariant facility. According to Clariant personnel, fluorene has never been used at the
facility although other PAHs containing fluorine have been used at the facility.
Bis(2-ethylhexyl)phthalatc was detected at a concentration of 840 µg/kg in sediment sample
DUP-1 in exceedance of the EPA Region 4 Waste Management Division Sediment Screening
Value for hazardous waste sites of 182 µg/kg. Sample DUP-1 is a duplicate of sample TRIB.
Bis(2-ethylhexyl)phthalate was not detected above the quantitation limit of 400 µg/kg in
sediment sample TRIB. Bis(2-cthylhexyl)phthalate is a colorless, oily liquid with a slight odor.
It is primarily used as one of several plasticizers_in polyvinyl chloride (PVC) resins for
fabricating flexible vinyl products. It is also used to manufacture vinyl gloves used commonly
used for medical examinations and surgery. Because sediment sampling was conducted using
both plastic trowels and disposable vinyl gloves, it is possible that the detection of bis(2-.
ethylhexyl)phthalate is partially attributable to the sample equipment which came in contact
with the collected sediment (no equipment blanks were collected from the gloves or plastic
trowels).
lnorganics detected in sediment samples are presented in Table 4. Of the constih1ents detected,
none were found at levels exceeding the SCGs.
Catawba River Dept/1 Profiles
Three depth profiles in the_ Catawba River were prepared along a line perpendicular to the
riverbank, across the entire width of the river at sample locations CR-B1/CR-82, CR-Cl/CR-C2,
and CR-D. Although the Work Plan indicated four depth profiles would be completed, only
three were performed since the bathymetry of the River at the upstream (background) location
was not needed. River depth was estimated through use of on board sonar (fish finder)
5 Manahan, S.E. 1984. Environmental Chemistry, 4th Ed. Willard Grant Press. Boston.
P:IClariant -5256\Sed SarTl)ling & Well Survey 34095\Repons\J<.pB-26-02.doc
I
I
I
I
I
I
I
I
n
D
I
I
I
I
I
I
I
I
CDM
Mr. Karim Pathan
September 17, 2002
Page 11
equipment at regular intervals. Figure 5 presents the results of the three depth profiles. The
river was found to be generally 8 to 10 feet in depth at most locations. Adjacent to CERCLA
Area D at sample locations CR-B1/CR-B2, a center channel of the river was apparent with a
maximum depth of almost 14 feet. In the other two depth profiles, the river bottom profile was
generally flat. Because of this, it is difficult point to specific areas of potential discharge of
groundwater from the Clariant site, except perhaps at sample location CR-B2, where more of a
defined channel was apparent. Chlorobenzene was detected in sediment at location CR-B2 at a
concentration of 25 µg/kg, which is well below the SCG. Chlorobenzene was not detected in
sediment or surface water at any other location. Chlorobenzene is a common contaminant in
groundwater at the Clariant site, and the detection of chlorobenzene in sediment is likely
related to contaminated groundwater discharging to the channel area.
Conclusions
The initial 1997 evaluation of the Mount Holly East Facility's status under the RCRlS Corrective
Action El Event Code CA725 (Human Exposure Controlled Determination) resulted in an "IN"
determination, indicating that more information was needed (September 30, 1997 lctter from R.
Grover to J. Carter). The results presented herein can be used to determine if surface water and
sediment are contaminated above appropriately protective risk-based levels. No surface water
samples were detected to contain constih1ents above SCGs. Surface water was not expected to
be contaminated above risk-based levels due to the volume and flow velocity in the Catawba
River. The discharge of groundwater contaminants into Long Creek and the Catawba River is
not causing unacceptable impacts to surface water. No additional surface water sa1npling is
recommended to as part of the EI evaluation process.
Only one sediment sample was detected to contain three PAHs above EPA Region 4 Waste
Management Division sediment screening values for hazardous waste sites. Since only one out
of twelve sediment samples detected PAHs, it is recommended that three additional sediment
samples from the immediate vicinity of sample CR-D be collected and analyzed for semi-
volatiles via Method 8270C. Additional sampling will provide a greater degree of confidence
and provide a more accurate assessment of the sediment PAH concentrations near CR-O. TI1e
validity of the anthraccne, fluorene, and phenanthrene concentrations will then be determined.
The samples are to be collected 100 to 300 feet downstream of the facilities wastewater
treatment discharge point. One sample is to be collected upstream of CR-D, and a two samples
will be collected downstream of CR-D. These samples will be used to assess the potential
impact to sediment from the facilities wastewater discharge.
P.\Clariant • 5256\Sed Sampling & Well Survey 34095\fleports\kpS-26-02.doc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
CDM
Mr. Karim Pathan
September 17, 2002
Page 12
If the additional sediment samples confirm contamination above SCGs, then following the EI
RCRJS code CA725 reasoning, a determination is to be made if there are complete pathways of
human exposure, if such exposures are significant, and if the possible significant exposures arc
within acceptable limits. '
If there are any questions or comments you may have, please do not hesitate to contact Gary
Sanderson, Clariant Plant Services Manager, at [phone] or me at [phone].
Very tmly yours,
~v:z-.-
)ohn Boyer
Camp Dresser & McKee
cc: G. Sanderson, Clariant
T. Grant, COM
R. Tabachow, CDM
Attachment 1 -Analytical Results from Paradigm Analytical Laboratories, Inc.
Attachment 2 -Case Narrative from Paradigm Analytical Laboratories, Inc.
P:\Clarianl • 5256\Sed Sampling & Well Survey J4095\Reports\kp8-26-02.c!oc
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Table 1
Catawba River, Long Creek and Tributaries -Sm·face Water and Sediment Sample Results
October 1986 and April 1987
Mt. Holly East Facility, Mount Holly, North Carolina
Surface Water
Sample Location Parameter
Long Creek
LC-1 ND
LC-2 o-Dichlorobenzenc
LC-3 ND
Tributnries to Long Creek
A-1 Trichloroethylenc
Tetrachloroethylcnc
Chlorobenzene
o-Dichlorobcnzene
A-1 (s11mple collected on 4/87) Trichloroethylenc
Tetrachloroethylcnc
Chlorobenzcne
A-2 ND
C-1 ND
Catawba River
CR-I ND
CR-2 ND
CR-3 ND
CR-4 ND
CR-5 ND
CR-6 ND
CR-7 ND
Tribul,1T)'. to Catawba River
B-1 ND
B-2 ND
1. All samples taken October, 1986 except where noted.
2. Sample locations shown on figure 1.
ND= non detect
Sediment
µg/1 Parameter
Xylene
Fluorcne
Phcnnnthrene
8.0 ND
Phcnnnthrcnc
330 Trichlorocthylene
460 Tctrnchlorocthylene
110 Chlorobenzene
18 Fluorenc
Phcnnnthrene
5 (not snmplcd)
7
23
Anthrnccne
Fluorcne
Phenanthrcne
l'hcnnnthrcne
ND
ND
ND '
ND
ND
ND
ND
Anthracene
Fluorene
Phenanthrene
fluorcne
Phenanthrcnc
11g/l
8.7
1.4
17
2.1
28
22
22
1.9
5.3
1.0
2.1
3.7
3.6
1. 1
2.5
72
2.0
14
a>MUitl,,f•~·<Om1nJctlon•ci--tk,r,s p:\clariant-5256\sed sampling & well surory 34095\rep()r/s\analytical-results
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Table 2
Catawba River, Long Creek and Tributaries -Surface Water Sample Results
June 2002
Mt. Holly East f'ncility, Mount Holly, North Carolina
S11rfacc Water Surface lVater SCGs
Sample Location Parameter
Long Creek
LC-A BQL
LC-B Chlorobcnzcne
1,2-Dichlorobcnzene
LC-C Chlorobenzcne
1,2-Oichlorobcnzene
LC-D BQL
Catawb.i River
CR-Al Toluene
CR-AZ Toluene
CR-Bl Toluene
CR-1!2 BQL
CR-Cl BQL
CR-C2 BQL
CR-D BQL
TRIB Not Collcctcdr
OAiOC Sam12les
DUP-1 (TRIil) Not Collcctcdr
DUP-2 (CR-Ill) Toluene
DUP-3 (CR-Cl) BQL
FB-SW Acetone
Dicthylphthal.itc
Trip Blank Toluene
Trip Blank Methylene chloride
Toluene
BQL = below quantitation limits
SCGs = Standards, Criteria or Guidance vnlucs
"Constituent was detected in trip blank.
ftg/1 ftg/1
8 488",b
9 488a.b
5 488'.b
6 488a,b
2· 1 I'
I' 1 I'
2· Ha
]' 11"
36 sood
14 5,000"
2' 11'
5 1,600"
2· 11'
a. These water quality standards apply to surface water that are classified WS-fV as
described in JSA NCAC 02B.0216.
b. Standnrd is for chlorinated benzenes.
c. A sample locntion TRIB is a tributary of the Cat.iwba River. On the day of sampling, the tributary
was dry and a surface wnter sample was not collected.
d. Standard from DWQ Provisional Surfoce Water Standard for Class C surface wnters.
For these constituents, standards not available in 15A NCAC 02B.0216.
e. Standard from NC 2L Groundwater Protection Standard for the protection of the groundwaters
of North C.irolina as specified in 15A NCA C 2L.0200.
Dicthylphthalate standard is not available in 15A NCAC 02B.0216.
CDM
romultlng. englnttrlng. -. opoqtiom p:\c/arifmt -5256\srd sampling & wrll surocy 34095\n>porls\analytirn/-results
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Tab]c 3
Catawba River, Long Creek and Tributaries -Sediment Sample Results
June 2002
Mt. Holly East Facility, Mount Holly, North Cnrolina
Sediment Sediment SCGs
Sample Location Parameter µg/kg µg/kg
Lone Creek
LC-A BQL
LC.fl BQL
LC-C BQL
LC-D BQL
Catawba River
CR-Al BQL
CR-A2 BQL
CR-Bl Acelone 260 1,100,000'
CR-B2 Chlorobenzene 25 220,0003
CR-Cl BQL
CR-C2 BQL
CR-D Anthrncene 63,000 33Qb
Fluorene 10,000 330b
Phen;mthrene 9,000 330b
TRIB BQL
OA[QC S;imv.:les
DUP-1 (TRIB) Bis(2-ethylhexyl)phthalate 840 182b
DUP-2 (CR-Bl) Acetone
DUl'-3 (CR-CI) Not Analyzedc
Fil-SD Toluene (in ug/1)
* Constituent was detected in trip blank.
BQL = below quantitation limits
SCGs = Standards, Criteria or Guidance values
BOLD values exceed listed sediment SCGs.
100 1,100,000'
1' 11 d
a. Fish tissue concentration for EPA risk levels calculated for both a human health cancer risk of 10·5 nnd
a noncancer hazard quotient of 1 (USEPA, 1995a, b). Screening values presented in:
www.epa.gov/waterscience/ cs/voll / appdx_d.pdf
Screening value for this constituent not available in EPA Region 4 Waste Management Division
Sediment Screening Values for Hazardous Waste Sites.
b. EPA Region 4 Waste Management Division Sediment Screening Values for Hazardous Waste Sites.
Values represent Contract Laboratory Program's (CLP) practical quantification limit (PQL).
c. Duplicate sample did not include a duplicate sediment sample. Aqueous duplicate only.
d. The following water quality standards apply to surface water that are classified WS-IV as
described in 15A NCAC 02B.0216.
References:
USEPA. 1995n. Intcgrnted Risk Information System (IRIS). Online. U.S. EPA, Office of Health and
Environmental Assessment, Environmental Criteria and Assessment Office, Cincinnati, OH.
USEPA. 1995b. Health effects assessment summary tables FY 1995. EPA/540/R-95/036.
U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response, Washington, DC
a>l\'I
~· ~. «>nnrunlon. --p: \clariant -5256\sed sampling & well surocy 34095\ reports\analytiail-rrsu//s
- --- - - ----_,_
Table 4
Analytical Results -Inorganics
Sediment Sampling
-
~,ft. Holly East Facility, t\fount Holly, North Carolina
-
Screening Sediment Sample ID (all values in mg/kg)
Analyte Method Level
(mg/kg) CR-Al CR-A2 CR-Bl DUP-2' CR-B2 CR-Cl CR-C2 CR-D LC-A LC-B
RCRA Metals
.
Arsenic 6010-B 70' BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Barium 6010-B 750c BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Cadmium 6010-B 9.6c BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Chromium 6010-B 370' 5.92 2.46 9.24 10.9 10.0 8.86 8.73 7.9 9.32 18.2
Copper 6010-B 270( 8.81 11.0 11.5 14.0 12.6 · 9.27 16.5 12.8 4.85 BQL
Lead 6010-B 218' 4.74 1.65 6.08 6.08 6.81 3.96 5.63 3.56 1.72 1.88
Mercury 7470/7471 0.71' BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Nickel 6010-B ]5.9d BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Selenium 6010-B NIA BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Silver 6010-B 2" BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL
Thallium 6010-B NIA' BQL 1.91 BQL BQL BQL BQL BQL BQL 1.76 2.14
Zinc 6010-B 124d 18.3 9.98 27.8 34.4 27.2 20.4 29.6 20.6 12.8 10.7
Total Organic
Carbon LYDKHN N/A · 990 3,900 10,000 14,000 11,000 5,000 11,000 7,700 BQL 700
NI A= Not Applicable
a. DUP-2 is a duplicate sample of CR-Bl.
b. DUP-1 is a duplicate _sample of TRJB.
c. NC DWQ Sediment Screening Levels
d. EPA Region 4 Waste Management Division Sediment Screening Values for Hazardous \Vaste Sites
e. A soil screening level was not listed in the NC D\VQ Sediment Screening Leve"is or
the EPA Region 4 Waste Management Division Sediment Screening Values for Hazardous VVaste Sites.
-- --
LC-C LC-D TRJB DUP-16
BQL BQL BQL BQL
BQL BQL BQL BQL
BQL BQL BQL BQL
4.80 9.76 39.9 37.4
2.92 8.03 30.0 29.3
1.71 2.04 12.0 67.4
BQL BQL 0.0226 BQL
BQL BQL 7.75 8.25
BQL BQL BQL BQL
BQL BQL BQL BQL
BQL BQL BQL BQL
8.03 II.I 63.6 71.1
800 BQL 7,500 11,000
p:\clariant -5266\sed sampling & well survey 34095\reports\analytical-resuits
-
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I fe· 1 in. = 170 n.. Approximate Sea ·
CDIVI
Avenue sue JOO 5400 GlellWOrthodC.orlo~J,;i 27612 con~ulting R;i,Jelgh, ND
engineering Tet [phone]
conl/rucrion F.ix: (S19) 781-5630 operation~
DESIGNED KJ
DRAWN KJ
CHECKED JB
APPROVED JS
DATE 04A12
~
0
~. C1ariant
D
X 05 X 0
CJ
0
SUB 0 STA o 0
0o
0o 0o o 0 [ J 0 Oo ½,t~ j 0o Oo
Oo 0 00
C:
CERCLA AREAS LAN VIEW AND C-P
FIGURE 1
FILE: T 'CV.C,"'1lf'PN; l>•o,,r!s
1.AYDIITF...-,1
f EB02,Aec_CE1>C1.A_ rvoc
I
600
560
520
480
4·10
400
360
320
0
a>l\t1
eon,u.ting, 540D Glenwood Avenue Suf.e JOO
engln.,ering R.1leigh, North C,1rloliru 27612
con£1ruclion Tel: (919) 71:17•5620
opt:r•fion, F,1x: (919) 7!! 1·5630
North
A
PC·lAI/D --Approximate Ground Surface
R-1 WQ·5AI/D
South
A'
600
•• ·.•.: ••••••••••••••• ~-••• ■ •••• •.· •••••••••••• ·.,· •••••••••••••• ............ ■
+---
,.~···········.· .. · .. ·-······.·. Water T?ble · ············· 560
40
DESIGNED
DRAWN
CHECKED
APPROVED
DATE
~l.75 ug/1
SBo..33 ft. -
580
80
NR
NR
"
" •m
--
120
----
:,
.. ,
' ' , , 2,458 ugfl
. ····---....... ···---~--"----·E'"'=,,.-'_"_·•_1_,_ .. _. ______ .JI..-----► .... ....
520
480 ~ u.
c·
·······················1· ····-··.,_··· ······· ..... ..;..... -I 'T---· i ----i-·__::-J;oOug/l
-i--575
1689.9 ug/1
!??.t4t ft. ·-·► ------.~ ~ >
440@
579 578
160 200 240
577
280
Distance, Feet
320
576 50 ug/l - ------------400
360
320
360 400 440 480 520 560 600
~ Clariant
1,505 ug/1 = TVOC Concentration
572.38 ft.= Water level Elevation
..,,. ~ Screened Interval
.---Open Interval
- -500 ug/1 -• Total VOC Concentration Isopleth
(Inferred)
Equipotential Lines
575
··► Groundwater Flmv Lines
TVOC concentrations from groundwater samples
collected in February, 2002.
f/U: P.\CI..APUN'T'\R,H RCP0PTS\ff"'1l\/O[CH XLS
CERCLA AREA C CROSS SECTION A-A'
FEBRUARY 2002
FIGURE 2
F!I .. E •~•'""''"-•·•••• LJIYOUl; C,o .. ,,<1000 F,...,,
ICDIVI
can,uling 5400 Glcl"lWOOd Averiue Suite 300
eno-mecrl'IIJ R.1 lelgh. North C.,r!oh/\.1 276 12
con<ltucri,;,n Tet [phone]
operation, Fa: (919) 7! 1-5630
640
600
560
~ 520
w µ.
c'
-f r. ~ 480 w
440
400
360
0
East
C
WQ-345/l/D
CMW-20 R-16
0.22 ugfl
50 100 150 200
DESIGNED ~•~•-----------
DRAWN --"N,,_R __________ _
CHECKED ~J•~------,-----
APPROVED ~J~•-----------
DATE
250
576
300
Approximate Ground Surface
(
578
350
Distance, Feet
400
580
450 500
WQ-6
WQ-291/D
1.54 ug/1
577.97 ft.
IVQ-30
West
C'
Long
Creek~
640
600
560
520
37.4 ugfl = TVOC Concentration
578.30 ft.= Water Level Elevation
-~ Screened Interval
..---Open Interval
- -S00ug/1-• ;; Total VOC Concentration Isopleth
(Inferred) ~ µ.
c' B ~
Equipotential Lines
> ~ 480 W 580
Groundwater Flmv Lines
440 TVOC concentrations from groundwater samples
collected in February, 2002.
NS= Not Sampled
400
360
550 600 650 700 750
~-Clariant
800 Hff, P.\CLARIA!lf"\~/ll ~EPOR1$\HBGJ\X-~£CH XL.<
CERCLA AREA C CROSS SECTION C-C'
FEBRUARY 2002
FIGURE 3
C!laECTOg v. l \G•&'<'.V,.g "'-'""'-"E gE~O~T&>Mt<EJEUl\
flE ........... _._ •• ,. t.AYotn·c ..... , ..... nF,_.
I
I
I
I
Previous samples
CR6 and CRl are
112 to 1 mile down fiver ._
I QJM
con~ulting · enginee1in9 • con~truction -oper,11ions II File P:\CL"lriartt-5256\sed sampling & well survey 34095\reporb\f:igl.apr
CR-C2
SW -BOl
SD-BOL
,..,.,=--~ .. CR-C1
CR-B2
SW-BOL
SD -Chklrobenzene 25 ug/kg CR-B1
•
Catawba River
.__ Direction of Flow
SW -Tolu•n• 1 Ug/1
SD-BOL ~----:..
Property Boundary
CR-A1
SW -Toluene 2 ug,1
SD-BOL
600."""====~•.,,,,====~600.:a..====.aa1200Feet
Approximate scale in feet
• LC1
A. LC-A
BOL
Previous sw/sed sampling location
Surface water and sediment sample from October
1986 and April 1987.
June 2002 Surface water/sediment
sampling location
Surface wafer samples are denoted by "SW-"
Sediment samples are denoted by "SD-"
Below Quantitation Lim its
Figure No. 4
Surface Water and Sediment Sample Results -June 2002
Clariant Mt. Holly East Facility
I
I
I
I
0.
I 2·
-;; 4
I
,; 6· ,5
A. 8· • Cl
10
I 12
14 ·
I
I 0
2
I -;; 4 ,;
-" 6 ;;_ • 8 Cl
I 10
12
14
I
I
0
I 2 ;; 4 ~ :::,
.,; 6
I A. ~ 8 Cl
10
I 12
14
I
I
I
~
~ .5
\
\
¼
Figure 5
Catawba River Depth Profiles
Mt. Holly East Facility, Mount Holly, North Carolina
Depth Profile of Catawba River
Across CR-B (Near CERCLA Area D)
Cat.iwba river is ripproximately 500 feet wide at CR·H
A, represents June 2002 surface water/5{'diment sampling location
CR-B2
Depth Profile of Catawba River
Across CR-C (Near RCRA Area)
C1t;iwba river is approximately 500 feet wide at CR-C
... represents June 2002 surfoce water h,cdiml'nl 5;m1pling location
CR-C2
~ &
~
'\
' "\
-----._,,
Depth Profile of Catawba River
Across CR-D (Near southern end of the property)
Catawba river is approximately 500 feet wide at CR-D
A represents June 2002 surface water/sediment sampling location
.
.
I
CR-Cl A/
./
I
CR-0£/
I
. ,I
p:\dariant -5256\scd sampling well survey 34095\reports\catawba depth profiles
I
I
I
I
I
I
I
I
••
I
I
I
I
I
I
I
I
I
I
Attachment 1
Analytical Results from Paradigm Analytical
Laboratories, Inc.
P;\Clariant • 5256\Sed Sampling & We!I Survey 34095\Reports\kpB-16-02.doc
m
I
I
I
I
I
I
I
n
D
I
I
I
I
I
I
Mr. John Boyer
PARADIGM ANALYrICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington, North Carolina 28405
(9 I 0) 350-I 903
Fax [phone]
July 11, 2002
Camp, Dresser & McKee
5400 Glenwood Ave Suite 300
Raleigh, NC 27612
Report Number: G175-261
Client Project ID: CLARIANT
Dear Mr. Boyer,
Enclosed are the results of the analytical services performed under the
referenced project. Copies of this report and supporting data will be retained
in our files for a period of five years in the event they are required for future
reference. Any samples submitted to our laboratory will be retained for a
maximum of thirty (30) days from the date of this report unless other
arrangements are requested.
If there are any questions about the report or the services performed during this
project, please call for assistance. We will be happy to answer any questions or
concerns which you may have.
Thank you for using Paradigm Analytical Labs for your analytical services.
We look forward to working with you again on any additional analytical needs
which you may have.
Sincerely,
Labo.
J. Patric · Weaver
N.C. Certification #481 S.C. Certification #99029
Clienl Sample ID: LC-A
Clienl Projecl ID: CLARIANT
Lab Sample ID: 46614
Lab Projecl ID: G175-261
Matrix: Water
Compound
Acetone
Acrolein
l\crylonilrile
Benzene
Bromobenzene
Bromochloromelhane
Bromodichloromethane
Bromoform
Bromomethane
2-Bulanone
n-Butylbenzene
sec-Butylbenzene
lert-Bulylbenzene
Carbon disulfide
Carbon lelrachloride
Chlorobenzene
Chloroelhane
2-Chloroelhyl vinyl elher
Chloroform
Chloromelhane
2-Chlorololuene
4-Chlorololuene
Oibromochloromethane
1,2-Dibromo-3-chloropropane
Dibromomethane
1,2-Dibromoelhane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-0ichlorobenzene
lrans-1,4-Dichloro-2-bulene
1, 1-Dichloroelhane
1, 1-Dichloroelhene
1,2-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Oichlorodifluoromethane
Diisopropyl elher (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
25
100
100
1
1
1
1
25
1
5
5
1
1
5
1
1
1
1
1
5
Dale Analyzed: 6/27/02
Analyzed By: EES
Dale Collecled: 6/20/02
Dale Received: 6/21 /02
Dilution: 1
Result
(ug/L)
BOL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BO[,
BQL
BOL
BOL
BQL
BQL
BQL
BQL
Flags: BQL = Below Ouanli'R/t:'. ~hification #481 S.C. Certification #99029
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Reviewed by:~ I
Page 1 of 2 I
I
I
I
I
I
I
I
I
I
n
D
D
I
I
I
I
I
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46614
Lab Project ID: G175-261
M.1trix: Water
Compound
2-Hexanone
lodomelhane
lsopropylbcnzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentano ne
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroethane
1, 1,2 ,2-T etrachloroethane
T etrachlorocthcne
Toluene
1,2,3-Trichlorobenzene
1,2,'1-Trichlorobenzene
Trichloroethene
1, 1.1-Trichloroethane
1, 1,2-Trichloroeth.1ne
Trichlorofluoromethane
1,2 ,3-T richloropropane
1,2,4-Trirnethylbenzene
1,3,5-T rirnethylbenzene
Vinyl chloride
rn-,p-Xylene
o-Xylenc
Surrogate Spike Recoveries
Compound
Bromofluorobenzenc
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Flags: BOL = Below Ouc1ntitation limit
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/L)
5
1
1
5
5
1
1
1
1
1
1
2
Spike
Added
(ug/L)
10
10
10
Date Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
Surrogate
Result ¾Rec
(ug/L)
10.2 102
10.2 102
10.3 103
N.C. Certification #48 I S.C. Certification #99029
•
Reviewed byk
Page 2 of 2
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46615
Lab Project ID: G175-261
Results for Volatiles
by GCMS 82608
Matrix: Soil %Solids: 77.3
Compound Quantitation
Limit (ug/KG)
Acetone 65
Acrolein 130
Acrylonilrile 130
Benzene 6.5
Bromobenzene 6.5
Bromochloromethane 6.5
Bromodichloromethane 6.5
Bromoform 6.5
Bromomethane 6.5
2-Bulanone 32
n-Bulylbenzene 6.5
sec-Bulylbenzene 6.5
lerl-Bulylbenzene 6.5
C;ubon disulfide 6.5
Carbon tetrachloride 6.5
Chlorobenzene 6.5
Chloroelhane 6.5
2-Chloroelhyl vinyl ether 6.5
Chloroform 6.5
Chloromethane 6.5
2-Chlorotoluene 6.5
4-Chlorololuene 6.5
Dibromochloromethilne 6.5
1,2-Dibrorno-3-chloropropane 6.5
Oibrornomethanc 6.5
1,2-Dibromoelhane (EDB) 6.5
1.2-Dichlorobenzene 6.5
1,3-Dichlorobenzene 6.5
1,4-Dichlorobenzene 6.5
trans-1,4-Dichloro-2-butene 6.5
1, 1-Dichloroelhane 6.5
1, 1-Dichloroelhene 6.5
1,2-Dichloroelhane 6.5
cis-1.2-Dichloroethene 6.5
lrans-1,2-dichloroelhene G.5
1,2-Dichloropropane 6.5
1,3-Dichloropropane 6.5
2,2-Dichloropropane 6.5
1, 1-Dichloropropene 6.5
cis-1,3-Dichloropropene 6.5
lrans-1,3-0ichloropropene 6.5
Dichlorodifluoromethane 6.5
Diisopropyl ether (DIPE) 6.5
Elhylbenzene 6.5
Hexachlorobuladiene 6.5
Dale Analyzed: 7/3/02
Analyzed By: EES
Dale Collected: 6/20/02
Dale Received: 6/21/02
Dilution: 1
Result
(ug/KG)
BOL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BOL
BOL
BQL
BOL
Flags: BQL O Below Quanlitation Limit N.C. Certification #481 S.C. Certification #99029
•
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
0
I
I
I
I
I
I
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46615
Lab Project ID: G175-261
Matrix: Soil
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1.1, 1,2-T etrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-T richlorobenzene
1,2,4-Trlchlorobcnzene
T richloroethene
1, 1, 1-Trichloroethane
1, 1.2-Trichloroethane
T richlorofluorornethane
1,2.3-T richloropropane
1,2.4-T rimethylbenzene
1,3.5-Trimethylbenzene
Vinyl chloride
rn-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
8ro"mofluorobcnzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
by GCMS 82608
%Solids: 77.3
Quantitation
Limit (ug/KG)
6.5
6.5
6.5
6.5
26
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
13
6.5
Spike
Added
(ug/KG)
50
50
50
All results are corrected for dilution.
Date Analyzed: 7 /3/02
Analyzed By: EES
Date Collected: 6120102
Date Received: 6/21 /02
Dilution: 1
Surrogate
Result
(ug/KG)
50.4
51.1
49.8
Result
(ug/KG)
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
¾Rec
101
102
100
Flags: BQL = Below OuantitaUQSl Limi\_,.fi 1. #4S l l'L L. Le, d 1ca IOTT S.C. Certification #99029
Reviewed by: l-
Page 2 of 2
Client Sample ID: LC-8
Client Project ID: CLARIANT
Lab Sample ID: 46616
I.ab Project ID: G175-261
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane ·
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Bulylbenzene
sec-Bulylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzcne
Chloroelhane
2-Chloroethyl vinyl elher
Chloroform
Chlorometh~me
2-Chlorotoluene
~-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibromomethane
1,2-Dibromoethane (EDS)
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1 ,1-Dichlorobenzene
trans-1.4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1.2-0ichloroelhene
trans-1.2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/L)
25
100
100
1
1
1
25
1
1
5
1
1
1
5
1
1
5
1
1
1
1
5
Date Analyzed: 6127102
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21 /02
Dilution: 1
Result
(ug/l)
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
BOL
BOL
BOL
SOL
SOL
8
SOL
SOL
SOL
SOL
BOL
BOL
SOL
SOL
BOL
SOL
9
SOL
BOL
BOL
BOL
SOL
SOL
SOL
SOL
BOL
SOL
SOL
BOL
SOL
SOL
SOL
BOL
BOL
SOL
Flags: SOL= Below Ouantit'l.tioJJ..Li)llit 'fj · #48J N.L. 1...-ert1 1cat1on S.C. Certification #99029
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Reviewed by~ I
Page 1 of 2
I
I
I
I
I
I
I
I
I
m
8
D
I
m
I
I
I
I
I
I
·····------·-7 --• -•
Results for Volatiles
by GCMS 82608
Client Sample ID: LC-B Date Analyzed: 6/27/02
Client Project ID: CLARIANT Analyzed By: EES
Lab Sample ID: 46616 Date Collected: 6/20/02
Lab Project ID: G175-261 Date Received: 6/21/02
Matrix: Water Dilution: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hexanone 5 BQL
lodomelhane BQL
lsopropylbenzene BQL
4-lsopropyltoluene BQL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BQL
Methyl-tert-butyl ether (MTBE) BQL
Naphthalene BQL
n-Propyl benzene BQL
Styrene BQL
1, 1, 1,2-T etrachloroelhane BOL
1, 1,2,2-Tetrachloroethane BQL
T etrachloroethene BQL
Toluene BQL
1,2,3-Trichlorobenzene BQL
1,2,4-Trichlorobenzene BQL
T richloroethene BQL
1. 1, 1-Trichloroethane BQL
1, 1,2-Trichloroethane BQL
T richlorolluoromelhane BOL
1,2,3-Trichloropropane BQL
1,2 ,4-Trirnelhylbenzene 1 BQL
1,3,5-Trimethylbenzene 1 BQL
Vinyl chloride BOL
rn-,p-Xylene 2 BQL
a-Xylene BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec
Compound (ug/L) (ug/L)
Bromofluorobenzene 10 10.3 103
1.2-Dichloroethane-d4 10 10.2 102
Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilution.
Flags: BQL = Below Quantilatio,11 Ljqiit . .
8 N.L. Lert1ficat1on #4 I S.C. Certification #99029
•
Reviewed by:k
Page 2 of 2
Client Sample ID: LC-8
Client Project ID: CLARIANT
Lab Sample ID: 46617
Lab Project ID: G175-261
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Ct1lorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromelhane
2-Chlorotoluene
4-Chlorotoluene
Dibromoch!oromethane
1,2-Dibromo-3-chloropropane
Dibrornomethzme
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1, 4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1 ,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
%Solids: 77.0
Quantitation
Limit (ug/KG)
65
130
130
6.5
6.5
6.5
6.5
6.5
6.5
32
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6,5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
Date Analyzed: 713102
Analyzed By: EES
Date Collected: 6120102
Date Received: 6121102
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
8QL
BQL
8QL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Flags: BQL = Below Quantitation Limit N.C. Certification #481 S.C. Certification #99029
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Reviewed by:L I
Page 1 of 2 I
I
m
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
Results for Volatiles
by GCMS 82608
Client Sample ID: LC-B Dale Analyzed: 7/3/02
Client Project ID: CLARIANT Analyzed By: EES
Lab Sample ID: 46617 Date Collected: 6/20/02
L:ib Project ID: G175-261 Dale Received: 6/21/02
M;1trix: Soil ¾Solids: 77.0 Dilution: 1
Compound Quantitation Result
limit (ug/KG) (ug/KG)
2-Hexanone 6.5 BOL
lodomethane 6.5 BOL
lsopropylbenzene 6.5 BOL
4-lsopropylloluene 6.5 BQL
Methylene chloride 26 BQL
4-Melhyl-2-penlanone 6.5 BQL
Methyl-lert-bulyl ether (MTBE) 6.5 BOL
Naphthalene 6.5 BQL
n-Propyl benzene 6.5 BQL
Styrene 6.5 BOL
1, 1, 1.2-Telrachloroelhane 6.5 BQL
1, 1,2 .2-T elrachloroelhane 6.5 BOL
T etrachloroelhene G.5 BOL
Toluene 6.5 BOL
1,2 ,3-T richlorobenzene G.5 BOL
1,2,4-Trichlorobcnzene G.5. BOL
T richloroethcne G.5 BOL
1, 1, 1-T richloroethane G.5 BOL
1, 1,2-Trir.hloroethane 6.5 BOL
T richlorofluoromethane G.5 BOL
1,2,3-T richloropropane 6.5 BOL
1,2,4-Trirnethylbenzcne 6.5 BOL
1,3,5-Trimethylbenzene G.5 BOL
Vinyl chloride G.5 BOL
rn-,p-Xylene 13 BOL
a-Xylene 6.5 BOL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 49.4 99
1,2-0ichloroethane-d4 50 50.1 100
Toluene-dB 50 49.1 98
Comments:
AH results are corrected for dilution.
Flags: BOL = Below Ouanlil<1Ji0Ali.Plil .fi · #4S l ]'LL. LCI11 1cat10n . S.C. Certification #99029
Reviewed by~
Page 2 of 2
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46618
Lab Project ID: G175-261
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromororm
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl elher
Chloroform
Chloromethane
2-Chlorololuene
4-Chlorotolucne
Oibromochloromethane
1,2-Dibromo-3-chloropropane
Oibromomethane .
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1.2-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2 ,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzerie
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/L)
25
100
100
1
1
1
1
25
1
1
1
5
1
5
5
5
Date Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21102
Dilution: 1
Result
(ug/L)
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
5
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
6
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BQL
BQL
BO~
BOL
BQL
BOL
BQL
BOL
BOL
BOL
Flags: BOL = Below Ouantitati()Q Limit "fi • #481 N.L. Lert1 1cat10n S.C. Certification #99029
•
Reviewed by~
P~ge 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B
m
I
I
I
I
I
I
I
I
I
0
I
I
I
I
I
I
I
--·-----------. ---------------------·---,
Results for Volatiles
by GCMS 82608
Clienl Sample ID: LC-C Date Analyzed: 6127/02
Clienl Projecl ID: CLARIANT Analyzed By: EES
Lab Sample ID: 46618 Dale Collected: 6120102
Lab Projecl ID: G175-261 Dale Received: 6121/02
Matrix: Water Dilution: 1
Compound Ouantitation Result
Limit (ug/L) (ug/L)
2·Hexanone 5 BOL
lodomelhane BOL
lsopropylbenzene BOL 4-lsopropyltoluene 1 BOL Methylene chloride 5 BOL 4-Methyl-2-pentanone 5 BQL
Methyl-tert-butyl ether (MTBE) BOL Naphthalene BQL n-Propyl benzene BQL Slyrene BQL
1, 1, 1,2-T etrachloroethane BOL
1, 1,2,2-Telrachloroethane BOL
T etrachloroelhene BQL
Toluene BOL
1,2,3-Trichlorobenzene 1 BQL
1,2,4-Trichlorobenzene 1 BQL
T richloroethene BOL
1 , 1, 1-Trichloroelhane BQL
1, 1,2-Trichloroethane BOL
Trichlorofluoromethane BOL
1,2,3-Trichloropropane BOL 1,2,4-Trirnelhylbenzene BOL 1,3,5-Trirnethylbenzene BQL
Vinyl chloride 1 BOL m-,p-Xylene 2 BQL o-Xylene BOL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rec Compound (ug/L) (ug/L)
Bromofluorobenzene 10 10.2 102 1.2-Dichloroethane-d4 10 10.1 101 Toluene-dB 10 10.2 102
Comments:
All results are corrected for dilution.
Flags: BOL = Below Quantitation Limit
N.C. Certification #481 S.C. Certification #99029
•
Reviewed by:~
Page 2 of 2
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46619
Lab Project ID: G175-261
Results for Volatiles
by GCMS 82608
Matrix: Soil %Solids: 76.1
Compound Quantilation
limit (ug/KG)
Acetone 66
Acrolein 130
Acrylonitrile 130
Benzene 6.6
Bromobenzene 6.6
Bromochloromethane 6.6
Bromodichloromethane 6.6
Bromoform 6.6
Bro mo methane 6.6
2-Butanone 33
n-Butylbenzene 6.6
sec-Bulylbenzene 6.6
tert-Bulylbenzene 6.6
Carbon disulfide 6.6
Carbon tetrachloride 6.6
Chlorobenzene 6.6
Chloroethane 6.6
2-Chloroethyl vinyl ether 6.6
Chloroform 6.6
Chloromethane 6.6
2-Chlorotoluene 6.6
4-Chlorololuene 6.6
Oibron1ochloromethane 6.6
1,2-Dibrorno-3-chloropropane 6.6
Dibromomethane 6.6
1.2-Dibromoethane (EDB) 6.6
1,2-Dichlorobenzene 6.6
1,3-Dichlorobenzene 6.6
1,4-Dichlorobenzene 6.6
trans-1,4-Dichloro-2-butene 6.6
1, 1-Dichloroelhane 6.6
1.1-Dichloroelhene 6.6
1.2-Dichloroothane 6.6
cis-1,2-Dichloroethene 6.6
lrans-1,2-dichloroelhene 6.6
1.2-Dichloropropane 6.6
1,3-Dichloropropane 6.6
2,2-Dichloropropane 6.6
1, 1-Dichloropropene 6.6
cis-1,3-Dichloropropene 6.6
trans-1,3-0ichloropropene 6.6
Dichlorodifluoromethane 6.6
Diisopropyl ether (DIPE) 6.6
Elhylbenzene 6.6
Hexachlorobutadiene 6.6
Date Analyzed: 7 /3/02
Analyzed By: EES
Date Collecled: 6/20/02
Date Received: 6/21/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
801,
BQL
BOL
BOL
BOL
BQL
BOL
BOL
Flags: BQL = Below Ouantitatio.A L~it · fi 1-#481 N.L. Lcrt1 1ca 10n S.C. Certification #99029
•
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
H
0
u
E
I
I
I
I
I
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46619
Lab Project ID: G175-261
Matrix: Soil
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2 ,3-T richlorobenzene
1,2 ,4-T richlorobenzene
Trichloroethene
1, 1, 1-T richloroelhane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2.4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
rn-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzenc
1,2-Dichloroethane-d4
Toluene-dB
Comi-nents:
Results for Volatiles
by GCMS 82608
%Solids: 76.1
Quantitation
Limit (ug/KG)
6.6
6.6
6.6
6.6
26
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
6.6
13
6.6
Spike
Added
(ug/KG)
50
50.
50
All results ~ue corrected for dilution.
Flags: BQL = Below Ouantitation Limit
Date Analyzed: 7 /3/02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
Dilution: 1
Surrogate
Result
(ug/KG)
50.4
52.2
49.9
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
%Rec
101
104
100
N.C. Certification #481 S.C. Certification #99029
•
Reviewed by: k
Page 2 of 2
. ' .... , .. ,,. ........... ,a,~••._,•,. • .._,, • ._, a.J£1..,'-'J.~J.Vl\,1t'-', II 'I'-'•
Results for Volatiles I by GCMS 8260B
Client Sample ID: TRIB Date Analyzed: 713102 I Client Project ID: CLARIANT Analyzed By: EES
Lab Sample ID: 46620 Date Collected: 6/20102 Lab Project ID: G175-261 Date Received: 6121102
I Matrix: Soil %Solids: 79.9 Dilution: 1
Compound Quantitation Result
Limit (ug/KG) (ug/KG) I Acetone 63 BOL
Acrolein 130 BOL
Acry/onitrile 130 BOL I Benzene 6.3 BOL
Bromobenzene 6.3 BOL
Bromochloromethane 6.3 BOL I Bromodichloromethane 6.3 BOL
Bromoform 6.3 BOL
Bromomethane 6.3 BOL 2-Butanone 31 BOL I n-Butylbenzene 6.3 BOL
sec-Butylbenzene 6.3 BOL
tert-Butylbenzene 6.3 BOL I Carbon disulfide 6.3 BOL Carbon tetrachloride 6.3 BOL • Chlorobenzene 6.3 BOL
I Chloroethane 6.3 BOL
2-Chloroethyl vinyl ether 6.3 BOL
Chloroform 6.3 BOL
Chlorornethane 6.3 BOL I 2-Chlorotoluene 6.3 BOL
4-Chlorotoluene 6.3 BOL
Dibromochloromelhane 6.3 BOL I 1,2-Dibromo-3-chloropropane 6.3 BOL
Oibromomethane 6.3 BOL 1,2-Dibromoethane (EDB) 6.3 BOL 1,2-0ichlorobenzene 6.3 BOL I 1,3-Dichlorobenzene 6.3 BOL 1,4-0ichlorobenzene 6.3 BOL trans-1,4-Dichloro-2-butene 6.3 BOL I 1, 1-Dichloroethane 6.3 BOL 1, 1-Dichloroethene 6.3 BOL 1,2-Dichloroethane 6.3 BOL I cis-1.2-Dichloroethene 6.3 BOL trans-1,2-dichloroethene 6.3 BOL 1,2-Dichloropropane 6.3 BOL
1,3-Dichloropropane 6.3 BOL I 2,2-Dichloropropane 6.3 BOL, 1, 1-Dichloropropene 6.3 BOL cis-1,3-Dichloropropene 6.3 BOL I trans-1,3-Dichloropropene 6.3 BOL
Dichlorodifluoromethane 6.3 BOL Diisopropyl ether (DIPE) 6.3 BOL
I Ethylbenzene 6.3 BOL Hexachlorobutadiene 6.3 BOL
Reviewed by:k-I
Flags: BQL = Below Ouantitation Limit
S.C. Certification #99029 Page 1 of 2 I N.C. Certification #481
B
I
I
I
I
I
I
D
u
I
I
I
I
I
I
I
Client Sample ID: TRIB
Clienl Projecl ID: CLARIANT
Lab Sample ID: 46620
Lab Project ID: G175-261
Results for Volatiles
by GCMS 8260B
Matrix: Soil • %Solids: 79.9
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-T etrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroelhene
·1, 1, 1-Trichloroethane
1, 1,2-Trichloroethane
T richlorofl uorometh;me
1.2 ,3-T richloropropane
1,2,4-Trimethylbcnzene
1,3,5-Trimcthylbenzenc
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Quantitation
Limit (ug/KG)
6.3
6.3
6.3
6.3
25
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
6.3
G.3
6.3
13
6.3
Spike
Added
(ug/KG)
50
50
50
Date Analyzed: 7/3/02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
Dilulion: 1
Surrogate
Result
(ug/KG)
49.7
51.0
50.1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BOL
%Rec
99
102
100
Flags: BOL = Below Ouantil'l,tipo.,Liriiit .fi . #4S l N.L. Lert1 1cat1on S.C. Certification #99029
•
Reviewed by: k_
Page 2 of 2
Client Sample ID: DUP-1
Client Project ID: CLARIANT
Lab Sample ID: 46621
Lab Project ID: G175-261
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibromometh;rne
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1.4-Dichlorobenzene
trans-1.4-Dichloro-2-butene
1.1-Dichloroethane
1, 1-Dichloroethene
1.2-Dichloroethane
cis-1,2-Dichloroethene
lrans-1,2-dichloroethene
1.2-Dichloropropane
1.3-Dichloropropane
2.2-Dichloropropane
1, 1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
1-fexachlorobutadiene
Results for Volatiles
by GCMS 8260B
Dale Analyzed: 7/3/02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
%Solids: 63.7 Dilution: 1
Quantitation
Limit (ug/KG)
78
160
160
7.8
7.8
7.8
7.8
7.8
7.8
39
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
Result
(ug/KG)
BOL
BOL
SOL
BOL
SOL
BOL
BOL
BOL
SOL
SOL
SOL
SOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
SOL
BOL
SOL
SOL
SOL
BOL
BOL
BOL
SOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BO~
BOL
BOL
BOL
BOL
BOL
BOL
BOL
. Reviewed by:k
Flags: BOL ~ Below Ouantit~~O.Q L[q,it . .
481 1~.L. Cet11ficallon # S.C. Certification #99029 Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
Client Sample ID: DUP-1
Client Project ID: CLARIANT
I.ab Sample ID: 46621
Lab Project ID: G175-261
Matrix: Soil
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropylloluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T ctrachloroclhane
1, 1 ,2 ,2-T etrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trlchlorobenzene
T richloroelhene
1, 1, 1-T richloroethane
1, 1,2-Trichloroelhane
T richlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimcthylbenzcne
1,3,5-Trimcthylbenzcne
Vinyl chloride
m-.p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobcnzene
1,2-Dichloroelhane-d4
Toluene-dB
Comments:
Results for Volatiles
by GCMS 82608
%Solids: 63. 7
Quantitation
Limit (ug/KG)
7.8
7.8
7.8
7.8
31
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
7.8
16
7.8
Spike
Added
(ug/KG)
50
50
50
All results are corrected for dilution.
Flags: BQL = Below Quantilalion Limit
Date Analyzed: 713102
Analyzed By: EES
Date Collected: 6120/02
Date Received: 6121/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
GQL
BQL
BQL
BQL
BQL
Surrogate
Result %RC?c
(ug/KG)
49.6 99
52.5 105
49.8 100
N.C. Certification #481 S.C. Certification #99029
•
Reviewed by:l-
Page 2 of 2
Client Sample ID: lC-D
Client Project ID: ClARIANT
lab Sample ID: 46622
lab Project ID: G175-261
Matrix: Water
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromelhane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethnne
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibrornomelhane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroelhene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dlchloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Oichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
Quantitation
limit (ug/l)
25
. 100
100
1
25
1
5
1
1
1
5
1
1
1
5
1
1
1
1
1
1
1
1
5
Date Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
Dilution: 1
Result
(ug/l)
BOl
BQl
BOl
BQl
BQl
BQl
BQl
BQl
BQL
BQL
BOL
BOL
BQL
BQl
BQl
BQl
BQL
BQl
BQL
BQL
BQl
BQL
BOL
BOl
BOL
BOl
BQL
BOl
BOL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BO~
BQL
BOL
BQL
BQL
BQl
BOL
BOl
Flags: BQl = Below Ouantit:i.t(oP,Lil'Qit .fi -#481 l'LL. Lert1 1Cat10n S.C. Certification #99029 P;-ige 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
I
I
I
I
I
I
I
I
I
I
I
I
D
E
I
I
-----. -----,
Results for Volatiles
. by GCMS 82608
Client Sample ID: LC-0 Date Analyzed: 6/27102
Client Project ID: CLARIANT Analyzed By: EES
Lab Sample ID: 46622 Dale Collected: 6/20/02
Lab Project 10: G175-261 Date Received: 6/21/02
Matrix: Water Dilution: 1
Compound Quantitation Result
limit (ug/L) (ug/L)
2·Hexanone 5 BOL
lodomelhane BOL
lsopropylbenzene BOL
4-lsopropylloluene 1 BQL
Methylene chloride 5 BQL
4-Melhyl-2-penlanone 5 BQL
Melhyl-lert-butyl ether (MTBE) BOL
Naphthalene BOL
n•Propyl benzene BOL
Styrene BOL
1, 1, 1,2-Telrachloroelhane BQL
1, 1,2,2-Tetrachloroethane BOL
T etrachloroethene 1 BOL
Toluene 1 BQL
1,2 ,3-T richlorobenzene BOL • 1,2,4·Trichlorobenzene BQL
Trichloroethene BQL
1, 1, 1-Trichloroethane BOL
1, 1,2·Trichloroethane BQL
T richlorofluoromethane BQL
1,2,3·Trichloropropane BOL
1,2,4·Trimethylbenzene BOL
1,3,S·Trimethylbenzene BOL
Vinyl chloride 1 BQL
m-,p-Xylene 2 BOL
o-Xylene BOL
Surrogate Spike Recovmies Spike Surrogata
Added Result ¾Rec Compound (ug/L) (ug/L)
Bromofluorobenzene 10 10.2 102 1,2-Dichloroelhane-d4 10 10.3 103 Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilution.
Reviewed by: l-
Flags: BQL ~ Below Ouanlitalio,J..Li!llil
N .L. certification #48 I S.C. Certification #99029 Page 2 of 2
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID: G175-261
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomelhane
2-Butanone
n-Butylbenzene
sec-Butylbenzenc
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroelhyl vinyl ether
Chloroform
Cllloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-ch/oropropane
Dibromomethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1 , 1-0ichlorocthane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2 ,2-Dichloropropane
1, 1-Dichloropropene
cis-1 ,3-Dichloropropene
trans-1,3-0ichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
%Solids: 72.5
Quantitation
Limit (ug/KG)
69
140
140
6.9
6.9
6.9
6.9
6.9
6.9
34
6.9
6.9
6.9
6.9
6.9
'6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6.9
6,9
6.9
6.9
6.9
Date Analyzed: 7 /3/02
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21/02
Dilution: 1
Result
(ug/KG)
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
Flags: BOL = Below Quantit~o(:_L~~rtification #481 S.C. Certification #99029 Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
u
I
I
I
I
I
u
u
I
I
I
I
I
I
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID: G175-261
Results for Volatiles
by GCMS 82608
Matrix: Soil %Solids: 72.5
Compound Quantitation
limit (ug/KG)
2-Hexanone 6.9
lodomethane 6.9
lsopropylbenzene 6.9
4-lsopropyltoluene 6.9
Melhylene chloride 28
4-Methyl-2-pentanone 6.9
Melhyl-tert-butyl ether (MTBE) 6.9
Naphthalene 6.9
n-Propyl benzene 6.9
Styrene 6.9
1, 1, 1,2-Tetrachloroethane 6.9
1, 1,2,2-Tetrachloroethane 6.9
Tetrachloroethene 6.9
Toluene 6.9
1,2,3-Trichlorobenzene 6.9
1,2,4-Trichlorobenzene 6.9
Trichloroethene 6.9
1, 1, I-Trichloroethane 6.9
1, 1,2-Trichloroethane 6.9
Trichlorofluoromethane 6.9
1,2,3-Trichloropropane 6.9
1,2,4-Trimelhylbenzene 6.9
1,3,5-Trimethylbenzene 6.9
Vinyl chloride 6.9
m-,p-Xylene 14
o-Xylene 6.9
Surrogate Spike ~ecoverios
Compound
Bromofluorobenzene
1,2-Dichloroelhane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Spike
Added
(ug/KG)
50
50
50
Date Analyzed: 7/3/02
Analyzed By: EES
Dale Collected: 6/20/02
Date Received: 6/21/02
Dilution: 1
Surrogate
Result
(ug/KG)
49.6
51.2
49.4
Result
(ug/KG)
BOL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
%Rec
99
102
99
Flags: BQL = Below Quantita.t\ori,Lip:Jil 'fj . #481 N.L. LCrll 1cat1on S.C. Certification #99029
Revi-ewed by~
Page 2 of 2
Client Sample ID: Trip Blank
Client Project ID: CLARIANT
Lab Sample ID: 46624
Lab Project ID: G175-261
Matrix: Water
Compound.
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroelhyl vinyl ether
Chloroform
Chloromelhane
2-Chlorololuene
4-Ch!orotoluene
Dibromochloromethane
1,2-Dibrorno-3-chloropropane
Dibromomethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzcne
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1, 4-Dichloro-2-bulene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroelhene
trans-1,2-dichloroelhene
1,2-Dichloropropane
1,3-Dichloropropane
2 ,2-Dichloropropane
1.1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobuladiene
Results for Volatiles
by GCMS 8260B
Quantitation
limit (ug/L)
25
100
100
1
1
1
1
25
1
1
1
1
1
5
1
1
1
5
5
1
1
1
1
1
1
5
1
Dale Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/20/02
Dale Received: 6/21/02
Dilution: 1
Result
(ug/L)
BOL
BQL
BOL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL.
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Flags: BOL = Below Quanlilalion Limit
8 N.C. Certification #4 I S.C. Certification #99029
Reviewed by~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Client Sample ID: Trip Blank
Client Project ID: CLARIANT
Lab Sample ID: 46624
Lab Project ID: G175-261
Matrix: Water
Compound
2-Hexanone
lodomclhane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Mcthyl-tert-butyl eth~r (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroethane
1, 1,2,2-Tetrachloroethane
T elrachloroethcne
Toluene
1,2 ,3-T richlorobenzcne
1,2,4-Trichlorobenzene
Trichloroethcne
1. 1, 1-Trichlorocthane
1.1.2-Trichloroethane
T richlorofluorometh_;me
1.2.3-T richloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Results for Volatiles
by GCMS 82608
Quantitation
limit (ug/L)
5
5
5
1
t
2
Spike
Added
(ug/L)
10
10
10
Date Analyzed: 6/27102
Analyzed By: EES
Date Collected: 6/20/02
Date Received: 6/21 /02
Dilution: 1
Result
(ug/L)
BOL
BQL
BOL
BQL
5
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
2
BOL •
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BOL
BOL
BQL
BOL
Surrogate
Result ¾Rec
(ug/L)
10.1 101
100 100
10.3 103
Flags: BOL = Below Ouantitajip1J..Lir:nit .fi .
481 I N.L. Cert, 1cat10n # S.C. Certification #99029
Reviewed by:~
Page 2 of 2
·---------------· ·-------------~.._.. ........................ ...,.__,, ---••'-'•
Results for Semivolatile Base/Neutral Extractables
by GCMS8270
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46614
Lab Project ID: G175-261
Matrix: Water
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
~':.nzi:iL<!lPYrene
Benzo[b]fluoranthene
Benzo[g,h.~perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)melhane
Bi s(2-~h IClrClethyl)et~':.r ___
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline . ... . --··-··---·· -·-•·----•---· 2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di-n-octylphthalate -.. ··--.. ---_., ______
Dibenzo[a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1 ,4-Dichlorobenzene -·-------·----3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrololuene
2 ,6-Dinitrotoluene ---·. ·---------·-· Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Melhylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 6/26/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL -------·--------·------·--·-·--. 10 BQL
10 BOL
10 BQL
10 BQL
10 BOL
10 BQL
10 BQL
10 BQL
10 BQL
10 BOL
20 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
20 BQL
10 BQL
10 BQL
10 BQL
10 BOL
10 BQL
N.C. Certification #4RI s1r. Certification #99029 P'age 1 o "2
•
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
H
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46614
Lab Project ID: G175-261
Matrix: Waler
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 6/26/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
Spike Percent
Result Recovered
9.5 95
10.1 101
11.2 112 I Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BOL = Below Ouanlilalion Limit.
Reviewed By:~
N.C. Certification #4RI S.f'. Certification #99029 !Sage 2 of2 .
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270 Client Sample ID: LC-A
Client Project ID: CLARIANT
lab Sample ID: 46615
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002 Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
~enz~[a]pyrene
Benzo[b ]fluoranthene
Benzo[g,h,i)perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)melhane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline ---·--···-··---------2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
~i-n-oc!y!_p_tith,i~ate
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2.4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
%Solids: 77.3
······-··· ---------··· -
Quantitation
Limit (ug/KG)
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
800
400
400
400
400
400
400
400
Analyzed By: MRC
Dilution: 1
--------····-----··--·--·••''
Result
(ug/KG)
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
BOL
SOL
BQL
BQL
SOL
SOL
BQL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
SOL
BOL
BQL
SOL
SOL Hexachlorobutadiene 400 SOL Hexachlorocyclope_ritadiene _____________ ---~~~--____ -----···· __ §9L__ __ Hexachloroethane 400
lndeno(1,2,3-c,d)pyrene 400
lsophorone 400
2-Methylnaphthalene 400
N-Nitrosodi-n-propylamine 400
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
SOL
BQL
SOL
BQL
SOL
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46615
Lab Project ID: G175-261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nilroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
%Solids: 77 .3
Quantitation
Limit (ug/KG)
400
400
400
400
400
400
400
400
400
Spike
Added
10
10
10
Dale Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BOL
BQL
BQL ----·-
BOL
BOL
BOL
BOL
Spike Percent
Result Recovered
7.5 75
8.1 81
10.4 104 I Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Ouanlitation Limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
~
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-B
Client Project ID: CLARIANT
Lab Sample ID: 46617
Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphthene
Acenaphlhylene
Anlhracene
Benzo[a)anthracene
Benzo[a)pyrene
Benzo[b)Ouoranlhene
Benzo[g,h,ijperylene
Benzo[k]Ouoranlhene
Bis(2-chloroelhoxy)melhane
Bis( 2-chloroethyl )ether
Bis(2-chloroisopropyl)elher
Bis(2-elhylhexyl)phlhalate
4-bromophenyl phenyl ether
Bulylbenzylphthalaie
4-Chloroaniline -. ·-·· .. -· ··-·-·-----------2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphlhalate
Di-n-octylphlhalate
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphlhalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene ''••-······-· Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
1-lexac~l~nJcy~!openladiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 77.0
Quantitation
Limit (ug/KG)
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410 ---·--·--·---------·
810
410
410
410
410
410
410
410
410
810
410
410
410
410
410
Dale Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL -----------BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-B
Client Project ID: CLARIANT
Lab Sample ID: 46617
Lab Project ID: G175-261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 77.0
Quantitation
Limit (ug/KG)
410
410
410
410
410
410
410
410
410
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
Spike Percent
Result Recovered
6.5 65
6.5 65
8.9 89 I Comments:
Results are corrected for %solids and dilution where applicable. I Flags:
I
I
I
I
I
I
I
u
BQL = Below Quantitation Limit.
Reviewed By:~\,_____
N.C. Certification #48 I S.C. Certification #99029 Page 2 of 2
•
•·••-•-•~••• ••••••a... .. ..._ .. ...., •• ....., ....., •• ...._......., .. .._, .... ..._,. ...... a:,u, Al"-'..-•
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46618
Lab Project ID: G175-261
Matrix: Water
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a ]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
_Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline ---·--------2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di:n:_ocl}'ph.lh.<lli'l~e
Oibenzo[a,h]anlhracene
Dibenzofuran ·
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphlhalate
Dimelhylphthalale
2,4-Dinilrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachloroberizene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Melhylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 6/26/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 s1r: Certification #99029 Page1o2
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
I
I
t l'lntU.11\.JIH t'\1'1/\.LI J 1\.,./\L L/\DUK.I\IUKl.r.;:o:,, IJ"wL.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Clienl Sample ID: LC-C
Clienl Projecl ID: CLARIANT
Lab Sample ID: 46618
Lab Projecl ID: G175-261
Malrix: Water
Compound
N-Nilrosodiphenylamine
Naphlhalene
2-Nilroaniline
3-Nilroaniline
4-Nilroaniline
Nilrobenzene
Phenanlhrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d 14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Dale Collecled: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 6/26/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
9.3 93
8.7 87
11. 1 111 I Comments:
I Flags:
I
I
I
I
I
I
I
I
Resulls are correcled for %solids and dilulion where applicable.
BQL = Below Quanlilalion Limil.
Reviewed By:~
N.C. Certification #1,~J., 2 ~-f· Certification #99029
•
r/\nt\VI\JIVI J-\l'f/\LI IH .. ,/\L L/\DVKJ\IVKlt-;"'.), U'i\..,.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46619
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
_!:lenz!'.'['.l]PYrene
Benzo[b]Ouoranthene
Benzo[g,h,i]perylene
Benzo[k]Ouoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
_l)i~n~octylp~l~<'lli3(e
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1, 4-Dichlorobenzene .. ---------------3,3'-Dichlorobenzidine
Dielhylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene ........ -------Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
.Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 76.1
Quantitallon
limit (ug/KG)
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
810
400
400
400
400
400
400
400
400
810
400
400
400
400
400
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
EiOL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
·~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46619
Lab Project ID: G175:261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 76.1
Quanlitation
Limit (ug/KG)
400
400
400
400
400
400
400
400
400
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
7.5 75
7.9 79
10.1 101 I Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
• .n.1,,u . .J'1uin ,u.,/\Ll I n..,J\L LJ\nVKI\IUKJt;S, JNL.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270 · Client Sample ID: TRIB
Client Project ID: CLARIANT
Lab Sample ID: 46620
Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a Jpyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroelhyl)ether
Bis(2-chloro isopropyl )ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline -· ·-· ··-·····-·--· 2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di-n-octylphthalate __
Dibenzo[a,hjanthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate.
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene -... ·-----.. ·---· ..... Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 79.9
Quantitation
Limit (ug/KG)
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
400
800
400
400
400
400
400
400
400
400
800
400
400
400
400
400
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 ol 2
'•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270 Client Sample ID: TRIB
Client Project ID: CLARIANT
lab Sample ID: 46620
Lab Project ID: G175-261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1 ,2 .4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 79.9
Quantitation
Limit (ug/KG)
400
400
400
400
400
400
400
400
400
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
5.2 52
6.0 60
7.2 72
I Comments:
' Flags:
I
I
I
I
I
I
' I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantilation limit.
Reviewed By:~
N.C. Certification #4Rl s1r. Certification #99029 · F"age 2 o 1
~
Results for Semivolatile Base/Neutral Extraclables
byGCMS 8270
Client Sample ID: DUP-1
Clienl Project ID: CLARIANT
Lab Sample ID: 46621
Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphlhene
Acenaphlhylene
Anlhracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g ,h ,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroelhoxy)methane
_Bis(2-chloroelhyl)elher
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phlhalate
4-bromophenyl phenyl ether
Bulylbenzylphlhalale
4-Chloroaniline ··-· ·-··· ···----·-···--2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalale
Di-n-octylp~l~;:i_l~(l: ___
Dibenzo[a,h]anlhracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene -. ---------·-------------3,3'-Dichlorobenzidine
Dielhylphlhalale
Dimethylphlhalate
2,4-Dinitrololuene
2 ,6-Dinitrololuene --···--------------·-Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobuladiene
l--iex'3c~l~ro<:y_<:(openladiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Melhylnaphlhalene
N-Nilrosodi-n-propylamine
%Solids: 63.7
Quanlitation
Limit (ug/KG) _
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
490
990
490
490
490
490
490
490
490
490
990
490
490
490
490
490
Dale Collected: 6/20/2002
Date Received: 6/21/2002
Dale Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
840
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
D
I
•
I
I
I
I.
.-n.n.111.11\JJn /\J~I\LI t lL/\L L/\UUKAIUKJI!.:~, JNL.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: DUP-1
Client Project ID: CLARIANT
lab Sample ID: 46621
lab Project ID: G175-261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 63.7
Quantitation
Limit (ug/KG)
490
490
490
490
490
490
490
490
490
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQl
BQl
BQl
BQl
BQL
BQl
BQL
BQl
BQl
Spike Percent
Result Recovered
5.5 55
6.3 63
8.0 80 I Comments:
U Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation limit.
Reviewed By:~
N.C. Certification #LIR! Sfr. Certification #99029 .. P'age2o 7
•
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46622
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 6/28/2002
Lab Project ID: G175-261
Matrix: Water
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a)pyrene
Benzo[b Jnuoranlhene
Benzo[g,h,i]perylene
Benzo[k)nuoranthene
Bis(2-chloroethoxy)methane
_ Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phlhalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline ·-. ----··---··--·-------2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphlhalate
Di-n-octylphlhalate
Dibenzo[a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene --•--------------------3,3'-Dichlorobenzidine
Diethylphthalale
Dimelhylphthalale
2,4-Dinitrotoluene
2,6-Dinitrotoluene --·· ------Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroc}'clope11t<l~~r1-~ _
Hexachloroethane
lndeno( 1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
.10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #4Rl S.C. Certification #99029 Page 1 of 2
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
........... ...,. .. ....,,, •• l'U~/1..LII. J.1.'-..,rl..LI J...,rl.UVl'\./\.IVI\.Jr,.:,, JJ"<j\.,,.
Results for Semivolatile Base/Neutral Extractables
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46622
Lab Project ID: G175-261
Matrix: Waler
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
by GCMS 8270
Quantitation
Limit (ug/L)
10
10
10
10
10
Date Collected: 6120/2002
Date Received: 6/2112002
Date Analyzed: 6/2812002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL ---------------------Nitro benzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-T erphenyl-d 14
10
10
10
10
Spike
Added
10
10
10
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
9.4 94
9.8 98
11.6 116 I. Comments:
I Flags:
D
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BOL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
•
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID: G175-261
Matrix: Soil
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b ]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl}ether
Bis(2-chloroisopropyl}ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Bulylbenzylphthalate
4-Chloroaniline .. ···-. ··-·-·-· ------------2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Bulylphthalale
!Ji:n-octylp~~alclte
Dibenzo[a,h]anlhracene
Dibenzofuran
1,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1,4-Dichlorobenzene
%Solids: 72.5
Quantitatlon
Limit (ug/KG)
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390 -·. --... , -··--·-·---·--3 .3'-Dichlorobenz idine 790
Dielhylphthalale 390
Dimethylphthalate 390
2,4-Dinitrololuene 390
2,6-Dinitrotoluene 390 ... ----·-·-·-Fluoranthene 390
Fluorene 390
Hexachlorobenzene 390
Hexachlorobutadiene 390
_!:!ex.'l_chlorocyclopentadiene 790
Hexachloroethane 390
lndeno(1.2,3-c,d)pyrene 390
lsophorone 390
2-Methylnaphthalene 390
N-Nitrosodi-n-propylamine 390
f,-
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL.
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL ----····--BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
•
I
,1
I
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
I
I
' ' I
I
I
I
I
I.
nu<Aun,1vt AJ~I\LY I JL/\L L/\llUl</\TUl<IES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Clienl Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID: G175-261
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d 14
%Solids: 72.5
Quantitatlon
Limit (ug/KG)
390
390
390
390
390
390
390
390
390
Spike
Added
10
10
10
Date Collected: 6/20/2002
Date Received: 6/21/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
' BQL
BQL
BQL
BQL
BQL
BOL
BQL
Spike Percent
Result Recovered
7,3 73
7,6 76
9,7 97 I Comments:
1· Flags:
I
' I
I
I
I
u
D
Resulls are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit
Reviewed By:~
N.C Certification #4RJ "'-F-Certification #99029 f:fage T""of2 .
¥
1 nnnu1ua.1 n.J'lr~.LJ.I 11'--'I'I.I.J L<l'lUVnn.1vn11c.,.::,, 11~\..,.
Results for Metals I
Client Sample ID: LC-A Analyzed By: RML I Client Project ID: CLARIANT Date Collected: 6/20/02
Lab Sample ID: 46614 Date Received: 6/21/02
Lab Project ID: . G175-261 Matrix: Water I Balch ID: 2349 2346
.Metals Result Quanlitation OF Units Method Date I
Limit Analyzed
I Antimony BQL 0.0600 1 MG/L 6010B 7/2102
Arsenic BQL 0.0100 1 MG/L 6010B 7/2/02
Beryllium BQL 0.0100 1 MG/L 6010B 712102 I Cadmium BOL 0.0100 1 MG/L 6010B 712102 Chromium BOL 0.0100 1 MG/L 6010B 7/2102
Copper BQL 0.0200 1 MG/L 6010B 7/2/02 I Lead BQL 0.0050 1 MG/L 6010B 7/2102
Mercury BOL 0.0003 1 MG/L 7470 6/24/02
Nickel BQL 0.0400 1 MG/L 6010B 712/02 I Selenium BQL 0.0100 1 MG/L 6010B 7/2/02
Silver BQL 0.0100 1 MG/L 6010B 7/2/02 -.
Thallium BOL 0.0100 1 MG/L 6010B 712/02 I Zinc BQL 0.0200 1 MG/L 6010B 712102
I Comments
BQL = Below Quantitation Limits I DF = Dilution Factor
J = Between MDL and RL
I;
' I
I
I
I
R~;,-By,\i,._ I
N.C. Certification #481 S.C. Certification #99029 I
I
I
I
••
I
I:
I.
I
I
I
I
Ir,
I
I.
I
•
I
u
I
I rt,l'\.n.LJ'JV!l'.I /'lJ,I\.Ll J J\...,/\L L/\OUKAlUKlt.~, JNL:.
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46615
Lab Project ID:
Batch ID:
G175-261
2355 2358
Results for Metals
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 9.32
Copper 4.85
Lead 1.72
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium 1.76
Zinc 12.8
Comments
BQL = Below Quantitation Limits
OF= Dilution Factor
J = Between MDL and RL
Limit
7.76 1 MG/KG
1.29 1 MG/KG
1.29 1 MG/KG
1.29 1 MG/KG
1.29 1 MG/KG
2.59 1 MG/KG
0.647 1 MG/KG
0.0227 1 MG/KG
5.17 1 MG/KG
1.29 1 MG/KG
1.29 1 MG/KG
1.29 1 MG/KG
2.59 1 MG/KG
Analyzed By: RML
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Solids 77.33
Method Date
Analyzed
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7 /1/02
6010B 7/1/02
6010B 7 /1/02
7471 7/2/02
6010B 7/1/02
6010B 7/1/02
6010B 7 /1/02
60106 7/1 /02
6010B 7 /1/02
,
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
••••.._,,.._,,..._.,,. 1a1~,,._._,. lJ.'-'<"LI .1..J£')..U'---.ll\,r,,.JVI\.ll.'.,.,J, 11'1~.
Results for Metals I
Client Sample ID: LC-B Analyzed By: RML ·I Client Project ID: CLARIANT Date Collected: 6/20/02 Lab Sample ID: 46616 Date Received: 6/21/02
I Lab Project ID: G175-261 Matrix: Water Balch ID: 2349 2346
Metals Result Quantitation DF Units Method Date I
limit Analyzed
I Antimony BQL 0.0600 1 MG/L 6010B 7/2/02 Arsenic BQL 0.0100 1 MG/L 6010B 7/2/02 Beryllium BQL 0.0100 1 MG/L 60108 7/2/02 -:I Cadmium 8QL 0.0100 1 MG/L 60108 7/2/02 Chromium 8QL 0.0100 1 MG/L 60108 7/2/02 Copper 8QL 0.0200 1 MG/L 60108 7/2/02 I Lead BQL 0.0050 1 MG/L 6010B 7/2/02 Mercury BQL 0.0003 1 MG/L 7470 6/24/02 Nickel BQL 0.0400 1 MG/L 6010B 7/2/02 I Selenium BOL 0.0100 1 MG/L 6010B 7/2/02 Silver BQL 0.0100 1 MG/L 6010B 7/2/02 ...
Thallium BQL 0.0100 1 MG/L 6010B 7/2/02
I Zinc BQL 0.0200 1 MG/l 6010B 7/2/02
Comments I
BQL = Below Quantilalion Limits ., DF = Dilution Factor
J = Between MOL and Rl
I
I
I
I
I
I
I
N.C. Certificaiion #481 S.C. Certification #99029 Reviewed By:~ I
I·
I
I
I
I
I:
I
1-
1-.
I
I
I
I
I
I
I
I
rg
a
Results for Metals
Clienl Sample ID: LC-B
Client Projecl ID: CLARIANT
Lab Sample ID: 46617
Lab Project ID: G175-261
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 18.2
Copper BQL
Lead 1.88
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium 2.14
Zinc 10.7
Comments
BQL = Below Quanlilalion Limits
DF = Dilution Faclor
' J = Between MDL and RL
Limit
7.80 1 MG/KG
1.30 1 MG/KG
1.30 1 MG/KG
1.30 1 MG/KG
1.30 1 MG/KG
2.60 1 MG/KG
0.650 1 MG/KG
0.0241 1 MG/KG
5.20 1 MG/KG
1.30 1 MG/KG
1.30 1 MG/KG
1.30 1 MG/KG
2.60 1 MG/KG
Analyzed By:
Dale Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/20/02
6/21/02
Soil
76.97
Date
Analyzed
7/1/02
7/1 /02
7/1/02
7/1/02
7/1/02
7/1/02
7/1 /02
7/2/02
7 /1/02
7/1/02
7/1/02 • 7/1/02
7/1/02
.Reviewed By:~
-----------
Results for Metals I
Client Sample ID: LC-C Analyzed By: RML I Client Project ID: CLARIANT Date Collected: 6/20/02
Lab Sample ID: 46618 Date Received: 6/21/02
Lab Project ID: G175-261 Matrix: Water I Batch ID: 2349 2346
Metals Result Quantitation DF Units Method Date I
Limit Analyzed
Antimony BQL 0.0600 1 MG/L 6010B 7/2/02 I Arsenic BQL 0.0100 1 MG/L 6010B 712102
Beryllium BQL 0.0100 1 MG/L 6010B 7/2/02 :1 Cadmium BQL 0.0100 1 MG/L 6010B 7/2/02 ' '
Chromium BQL 0.0100 1 MG/L 6010B 7/2/02
Copper BQL 0.0200 1 MG/L 6010B 7/2/02 I Lead BQL 0.0050 1 MG/L 6010B 7/2/02
Mercury BQL 0.0003 1 MG/L 7470 6/24/02
Nickel BQL 0.0400 1 MG/L 6010B 7/2/02 I Selenium BQL 0.0100 1 MG/L 6010B 7/2/02
· Silver BQL 0.0100 1 MG/L 6010B 7/2/02 .•
Thallium BQL 0.0100 1 MG/L 6010B 7/2/02
Zinc BQL 0.0200 1 MG/L 6010B 7/2/02 I
Comments I
BQL ; Below Quantitation Limits I DF; Dilution Factor
J ; Between MDL and RL
I
I
I
I
I
I
Reviewed By:~
I
N .C. Certification #481 S.C. Certification #99029 I
I
,,
·I·
I
I ...
I
I
I
I
I
I
I
I
I
I
a
ri\K/\Ut\JJVI /\J'I/\Ll l lLAL LAtlUKAlUKH~S, INC.
Results for Metals
Client Sample ID: LC-C
Client Project ID: CLAR/ANT
Lab Sample ID: 46619
Lab Project ID: G175-261
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony SOL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 4.80
Copper 2.92
Lead 1.71
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc 8.03
Comments
SOL= Below Quantitation Limits
OF= Dilution Factor
J = Between MDL and RL
Limit
7.04 1 MG/KG
1.17 1 MG/KG
1.17 1 MG/KG
1.17 1 MG/KG
1.17 1 MG/KG
2.35 1 MG/KG
0.586 1 MG/KG
0.0237 1 MG/KG
4.69 1 MG/KG
1.17 1 MG/KG
1.17 1 MG/KG
1.17 1 MG/KG
2.35 MG/KG
Analyzed By:
Date Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471
6010B
6010B
6010B
6010B
6010B
N.C. Certification #48 I S.C. Certification #99029
RML
6/20/02
6/21/02
Soil
76.14
Date
Analyzed
7/1/02
7/1/02
7/1/02
7/1/02
7/1/02
7/1 /02
7/1/02
7/2/02
7/1/02
7/1/02
7/1/02 •
7 /1/02
7/1/02
Reviewed By:~
Results for Metals
Client Sample ID: TRIB
Client Project ID: CLARIANT
Lab Sample ID: 46620
Lab Project ID: G175-261
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 39.9
Copper 30.0
Lead 12.0
Mercury 0.0226
Nickel 7.55
Selenium BQL
Silver BQL
Thallium BQL
Zinc 63.6
Comments
BQL = Below Quantitation Limits
OF = Dilution Factor
J = Between MDL and RL
Limit
7.22 1 MG/KG
1.20 1 MG/KG
1.20 1 MG/KG
1.20 1 MG/KG
1.20 1 MG/KG
2.41 1 MG/KG
0.602 1 MG/KG
0.0214 1 MG/KG
4.82 1 MG/KG
1.20 1 MG/KG
1.20 1 MG/KG
1.20 1 MG/KG
2.41 1 MG/KG
Analyzed By: RML
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Solids 79.87
Method Date
Analyzed
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
7471 7/2/02
6010B 7 /1/02
6010B 7 /1/02
6010B 7/1/02 -~
6010B 7/1/02
6010B 7/1/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By: 6-
I
I
I
I
I
I
I
I
I
I
I
I
I ,,
I· ,, ,,
I
I
I
I
I
I
I·
I
I
I
I
.................. '-", •• l'U~r .. LII II'-.,r\.Ll LJr1'UVRt\.JVn.J~.:,, JJ,,.\..,.
Client Sample ID: DUP-1
Client Project ID: CLARIANT
Lab Sample ID: 46621
Lab Project ID:
Batch ID:
G175-261
2355 2358
Results for Metals
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 37.4
Copper 29.3
Lead 67.4
Mercury BOL
Nickel 8.25
Selenium BQL
Silver BQL
Thallium BOL
Zinc 71.1
Comments
BOL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
7.98 1 MG/KG
1.33 1 MG/KG
1.33 1 MG/KG
1.33 1 MG/KG
1.33 1 MG/KG
2.66 1 MG/KG
0.665 1 MG/KG
0.0291 1 MG/KG
5.32 MG/KG
1.33 1 MG/KG
1.33 1 MG/KG
1.33 1 MG/KG
2.66 1 MG/KG
Analyzed By: RML
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Solids 63.71
Method Date
Analyzed
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
7471 712102
6010B 7 /1/02
6010B 7 /1 /02
6010B 7/1/02
6010B 7 /1 /02
6010B 7/1/02
•
N.C. Certification #481 S.C. Certification #99029 Reviewed By:L
Results for Metals
Client Sample ID: lC-D
Client Project ID: CLARIANT
lab Sample ID: 46622
lab Project ID: G175-261
Batch ID: 2349 2350
Metals Result Quantitation OF Units
Antimony BQL
Arsenic BQl
Beryllium BQl
Cadmium BQl
Chromium BQl
Copper BQl
Lead BQL
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc BQL
Comments
BQl = Below Quantitation limits
DF = Dilution Factor
J = Between MDL and Rl
limit
0.0600 1 MG/l
0.0100 1 MG/l
0.0100 1 MG/l
0.0100 1 MG/l
0.0100 1 MG/l
0.0200 1 MG/l
0.0050 1 MG/L
0.0003 1 MG/L
0.0400 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/l
0.0100 1 MG/l
0.0200 1 MG/L
Analyzed By:
Date Collected:
Date Received:
Matrix:
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7470
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RMl
6/20/02
6/21/02
Water
Date
Analyzed
7/2/02
7/2/02
7/2/02
7/2/02
7/2/02
7/2/02
7/2/02
6/24/02
7/2/02
7/2/02
7/2/02 .•
7/2/02
7/2/02
Reviewed By:k
I
I
I
I
I
I
I
I
I
I·
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID:
Batch ID:
G175-261
2355 2358
Results for Metals
Metals Result Quantilalion DF Units·
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 9.76
Copper 8.03
Lead 2.04
Mercury 8QL
Nickel BOL
Selenium BOL
Silver BOL
Thallium BOL
Zinc 11.1
Comments
BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
8.11 1 MG/KG
1.35 1 MG/KG
1.35 1 MG/KG
1.35 1 MG/KG
1.35 1 MG/KG
2.70 1 MG/KG
0.676 1 MG/KG
0.0246 1 MG/KG
5.41 1 MG/KG
1.35 1 MG/KG
1.35 1 MG/KG
1.35 MG/KG
2.70 1 MG/KG
Analyzed By: RML
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil'
Solids 72.54
Method Date
Analyzed
6010B 7/1/02
6010B 7/1/02
6010B 7/1/02
60108 7/1/02
60108 7/1/02
60108 7/1/02
60108 7/1/02
7471 712/02
60108 7/1/02
6010B 7/1/02
6010B 7/1/02 •
60108 7 /1/02
6010B 7/1/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
l"J-\.1\.t'\UIUlH J-\.l'lt'\LI 11\..,t'\LJ LJt'\DVl\./'\IVl\lr..~, 11'1\....-.
Results for lnorganics
Client Sample ID: LC-A
Client Project ID: CLARIANT
Lab Sample ID: 46615
Lab Project ID: G175-261
Parameter
TOC
Note:
Result Quantitation
Limit
BQL 260
BQL = Below Quantitation Limit
Analysis performed by Kemron.
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Procedure
LYDKHN
Date
Analyzed
6/27/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:k
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
0
I
B
I
I
I
I
g
Results for lnorganics
Client Sample ID: LC-B
Client Project ID: CLARIANT
Lab Sample ID: 46617
Lab Project ID: G175-261
Parameter Result
TOC 700
Note:
BQL = Below Quantitation Limit
Analysis performed by Kemron.
Quantitation
Limit
260
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Procedure Date
Analyzed
LYDKHN 6/27/02
•
N.C. Certification #481 S.C. Certification #99029 Reviewed By: ~
Results for lnorganics
Client Sample ID: LC-C
Client Project ID: CLARIANT
Lab Sample ID: 46619
Lab Project ID: G175-261
Parameter Result Quanlilation
Limit
TOC 800 240
Note:
BQL = Below Quantitation Limit
Analysis performed by Kemron.
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Procedure
LYDKHN
Date
Analyzed
6/27/02
N.C. Certification #48 I S.C. Certification #99029 Reviewed By:~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
D
I
I
I
I
n
I
Results for lnorganics
Client Sample ID: TRIB
Client Project ID: CLARIANT
Lab Sample ID: 46620
Lab Project ID: G175-261
Parameter
TOC
Note:
Result Quantitation Units
Limit
7500 280 mg/kg
BQL = Below Quantitalion Limit
Analysis performed by Kemron.
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Procedure Date
Analyzed
L YDKHN 6/27/02
•
N.C. Certification #48 I S.C. Certification #99029 Reviewed By:~
Results for lnorganics
Client Sample ID: DUP-1
Client Project ID: CLARIANT
Lab Sample ID: 46621
Lab Project ID: G175-261
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Parameter Result Quantitation Units Procedure Date
Analyzed
TOC 11000
Note:
BQL = Below Quanlilation Limit
Analysis performed by Kemron.
Limit
290 mg/kg LYDKHN
N .C. Certification #48 I S.C. Certification #99029
6/27/02
Reviewed By: L
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
n
I
I
I
I
I
I
I
I
I
I
I
D
I
a
R
Results for lnorganics
Client Sample ID: LC-D
Client Project ID: CLARIANT
Lab Sample ID: 46623
Lab Project ID: 8175-261
Parameter
TOC
Note:
Result Quantitation Units
Limit
BQL 270 mg/kg
SOL= Below Quanlitation Limit
Analysis performed by Kemron.
Analyzed By: Kemron
Date Collected: 6/20/02
Date Received: 6/21/02
Matrix: Soil
Procedure Date
Analyzed
L YDKHN 6/27/02
•
N.C. Certification #481 S.C. Cerlification #99029 Reviewed By: k
-· -

-
-------------...., __ .....,...,, •u ~-• COC# ': '
I ..... . l 2627 Northchase Parkway SE, Wilmington, NC 28405 Chain-of Custo<:ly Record & Analytical Request
I or_l Phone: [phone] FAX: [phone] Page
Client: C.D~ Project ID: <.: <../\ J\..-1 /W T Date: ,/'-vlui.. Report To: Ji) \'tf'J 1?~'1<'L
Address: S°"I.()\) <'., c,."N,J D,h1 1\--1 f Contact: j~\'1,-j 11~'\~ Turnaround: , TO C....0'(\.-.
Address: llf'll.8 ~ \-\ 1.I'<.. 'L.1f;l"L Phone:<\ \q_ -1"i7 -.S'I, 1-o Job Number: 0-Sb --".?'<01\S
. Quote#: 4 /01 Fax: '?<jjl -~13" P.O. Number: Invoice To: j (\ \"IN ("]~~<I'
·<'· ,. ' Preservatives '' · Analvses · Comments: : ; ........ ._
Please specify any speclal.reportln1
,,-.. .·,·;:.:_:, . 1_.. : :.-.-( .. ,': ~ ...,
f · re" ulrements : . . ~t,> •Sample ID Date ·Time Matrix !:/'
,.J :~·;_t:;,i~ 1_.i ~ ,::, \,} · ; ,~ .. ,n.-:1, · •• •: : ·:'". V ,::, ..,, f? Y.l
i: :e ~ t's ~ ~ C!7S--26/ ~ "-~
LC-f-\ 1. /-...,, ;)(i 10 vJ '.3 I 1 l I
LC-{\ ,ji.-. O~\O s \ I 1 I \ (.:,~ lo,,o~, v('w-,uce.,'/1'1 r
LC.-(3 ~ , .. ~ lll ov w ? \ 1 / \ 0 ~ ,'\ 'ie Wl:~c>. ':;[~ "--
' \ -Lc.-CT d,_,. l<;>\\~ S' \ I \ ) \._
(..C..-<-(. \i. .. li>1U w '] I ? \ 1
LC -c. c:... It..~ l-t,~~ s-\ \ I I
TR 113 (;, h~ l 'l..'·'" .s \. \ \ \
D\..\ P-I d.,_· -s 1 \ ' ' -'LC.-D '-Ii. " l I:;, 1,,-J 'l I 1 \ ' L..c, -0 GjL.., 1,1,n S' \ l \ I • . ' . ~ .... -· ,. -
State Certification Requested ,eunqu1sm,u HY uate ume Received By Date Time Temperature
I ,A--~ -6 /;;,/il. 1?:,o /J -I ~~ blzrl., IQ:/0 J~/0c NC ' SC __ ._ Other I ,/ ' I IJ ,1 f't ' SEE REVERSE FOR
TERMS Ai",/D CONDITIONS
i-:-.•~i ----------------

-
--
I
I
I
I
I
I
I
H
I
I
n
D
E
I
I
I
I
I
...... , ......................... ..., ....... .....,, .. ..., ............. ...,.. .................. .....,.....,, "'''""'
Results for Semivolatile Base/Neutral Extractables
by GCMS8270
Client Sample ID: LC-B
Client Project ID: Clariant
Lab Sample ID: 47093
Lab Project ID: G175-265
Matrix: Water
Compound
Acenaphlhene
Acenaphlhylene
Anthracene
Benzo[a]anthracene
Benzo[a)pyrene
Benzo[b Jnuoranthene
Benzo[g, h, ijperylene
Benzo[k]ftuoranthene
Bis(2-chloroelhoxy)melhane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-elhylhexyl)phlhalale
4-bromophenyl phenyl ether
Bulylbenzylphthalale
4-Chloroaniline .... -------------2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-11-Butylphthalate
Di-n-octylphtt1;:,late
Dibenzo[a,h)anlhracene
Dibcnzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ...... ···--····-3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2 ,4-Dinitrololuene
2,6-Dinilrololuene
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10 ... •'•••--.. -------------··· 10
10
10
10
' 10
20
10
10
10
10 -----·-·--·--·-· Fluoranthene 10
Fluorene 10
Hexachlorobenzene 10
Hexachlorobutadiene 10
Hexachlorocyc!Di:>~ntadiene 20
Hexachloroethane 10
lndeno(1,2,3-c,d)pyrene 10
lsophorone 10
2-Methylnaphlhalene 10
N-Nitrosodi-n-propylamine 10
Date Collected: 6/26/2002
Dale Received: 6/27/2002
Dale Analyzed: 7/9/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
13QL ---·•---.. ··-· ---BOL
13QL
BQL
BOL
13QL
BQL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029
Page 1 of 2
~
• ,,,. ... ,,,.._,._.VIY• 11'J ,.,,.....,_. .a •"-'<•LI &..1, .. ._.....,.<t. ............... :n..1, •• •"-'•
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: LC-B
Client Project ID: Clariant
Lab Sample ID: 47093
Lab Project ID: G175-265
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nilroaniline
Nitrobenzene
Phenanlhrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Dale Collected: 6/26/2002
Date Received: 6/27/2002
Date Analyzed: 7/9/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
8.1 81
8.4 84
10.8 108
Comments:
Flags:
Results are corrected for %solids and dilution where applicable.
BOL = Below Quantitation Limit.
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
•
I
I
D
n
0
u
PARADIGM ANALYTICAL LABORATORIES, INC.
2627 Northchase Parkway S.E.
Wilmington. North Carolina 28405
[phone]
Mr. John Boyer
Camp, Dresser & McKee
5400 Glenwood Ave Suite 300
Raleigh, NC 27612
Report Number: G175-262
Client Project ID: Clariant
Dear Mr. Boyer,
Fax [phone]
July 11, 2002
Enclosed are the results of the analytical services performed under the
referenced project. Copies of this report and supporting data will be retained
in our files for a period of five years in the event they are required for future
reference. Any samples submitted to our laboratory will be retained for a
maximum of thirty (30) days from the date of this report unless other
arrangements are requested.
If there are any questions about the report or the services performed during this
project, please call for assistance. We will be happy to answer any questions or
concerns which you may have.
Thank you for using Paradigm Analytical Labs for your analytical services.
We look forward to working with you again on any additional analytical needs
which you may have.
Sincerely,
al Laboratories, Inc.
Labor Director
J. Patrick Weaver
N.C. Certification #481 S.C. Certification #99029
···-----·--·---· ----·-,
Results for Volatiles I by GCMS B2608
Client Sample ID: CR-A2 Date Analyzed: 6/27 /02 I Clienl Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46843 Date Collected: 6/21/02
Lab Project ID: G175-262 Date Received: 6/22/02
Matrix: Waler Dilution: 1 I
Compound Quantitation Result
limit (ug/L) (ug/L) I Acetone 25 BQL
Acrolein 100 BQL
Acrylonitrile 100 BQL I Benzene BQL
Bromobenzene BQL
Bromochloromethane 1 BOL
Bromodichloromethane 1 BOL I Bromoform 1 BQL
Bromomelhane 1 BOL
2-Butanone 25 BOL. I n-Butylbenzene BOL
sec-Butylbenzene 1 BOL
tert-Butylbenzene 1 BQL I Carbon disulfide BQL
Carbon tetrachloride BQL • Chlorobenzene 1 BOL
Chloroethane 1 BOL I 2-Chloroethyl vinyl ether 5 BOL
Chloroform BQL
Chloromethane BOL I 2-Chlorololuene BQL
4-Chlorotoluene BOL
Oibromochloromelhane 1 BOL
1,2-Dibromo-3-chloropropane 5 ElQL I Dibromomelhane BOL
1,2-Dibromoelhane (EDB) BQL
1,2-Dichlorobenzene BQL I 1,3-Dichlorobenzene BQL
1,4-Dichlorobenzene 1 BQL
trans-1,4-Dichloro-2-butene 5 BQL I 1.1-Dichloroethane BQL
1, 1-Dichloroelhene BQL
1,2-Dichloroethane BOL
cis-1,2-Dichloroethene BQL I trans-1,2-dichloroelhene BQL
1,2-Dichloropropane BQL
1.3-Dichloropropane BQL I 2,2-Dichloropropane BOL
1, 1-Dichloropropene BOL
cis-1,3-Dichloropropene BOL
R trans-1,3-Dichloropropene 1 BOL
Dichlorodifluoromethane 5 BQL
Diisopropyl ether (DIPE) BOL
Elhylbenzene BQL I Hexachlorobutadiene BQL
Reviewed by~ D
Flags: BQL = Below Ouanlilalion Limit
S.C. Certification #99029 Page 1 of 2 N.C. Certification #481 I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
rAK/\Ul\.1lVJ /\l~J\Ll' I IL/\L LJ\HUKJ\IUKII:!,~, INC.
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46843
Lab Project ID: G 175-262
Matrix: Water
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropylloluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroethane
1, 1,2,2-T etrachloroethane
T etrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2 ,4-T richlorobenzene
T richloroethene
1, 1, 1-Trichloroethane
1, 1,2-Trichloroelhane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trirnethylbenzene
1.3,5-Trirncthylbenzene
Vinyl chloride
rn-,p-Xylene
o-Xylcne
Surrogate Spike Recoveries
Compound
Bromofluorobenzcne
1,2-Dichloroelhane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/L)
5
1
1
5
5
1
1
2
Spike
Added
(ug/L)
10
10
10
Date Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/21 /02
Date Received: 6/22/02
Dilution: 1
Result·
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
Surrogate
Result ¾Rec
(ug/L)
10.1 101
10.0 100
10.2 102
Flags: BQL = Below Ouantitajip1J.Lio1it . .
8 N.l... t..ert1ficat1on #4 I S.C. Certification #99029
•
Reviewed by:k
Page 2 of 2
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46844
Lab Project ID: G175-262
Results for Volatiles
by GCMS 82608
Matrix: Soil %Solids: 77.5
Compound Quantitation
limit (ug/KG)
Acetone 65
Acrolein 130
Acrylonitrile 130
Benzene 6.5
Brornobenzene 6.5
Bromochloromethane 6.5
Bromodichloromethane 6.5
Bromoform 6.5
Bromomethane 6.5
2-Bulanone 32
n-Bulylbenzene 6.5
sec-Butylbenzene 6.5
tert-Butylbenzene 6.5
Carbon disulfide 6.5
Carbon tetrachloride 6.5
Ch!orobenzene 6.5
Chloroelhane 6.5
2-Chloroethyl vinyl ether 6.5
Chloroform 6.5
Chloromethane 6.5
2-Chlorotoluenc 6.5
4-Chlorotoluene 6.5
Dibromochloromethane 6.5
1,2-Dibromo-3-chloropropane 6.5
Dibromornethane 6.5
1,2-Dibromoelhane (EDB) 6.5
1,2-Dichlorobenzenc 6.5
1,3-Dichlorobcnzene 6.5
t ,4-Dichlorobenzene 6.5
frans-1,4-Dichloro-2-butene 6.5
1, 1-Dichloroelhane 6.5
1, 1'.Dichloroelhene 6.5
1.2-Dichloroethane 6.5
cis-1,2-Dichloroelhene 6.5
trans-1,2-dichloroethene 6.5
1,2-Dichloropropane 6.5
1,3-Dichloropropane 6.5
2 .2-0ichloropropane 6.5
t, t-Dichloropropene 6.5
ds-1,3-Dichloropropene 6.5
lrans-1.3-Dichloropropene 6.5
Dictilorodifluoromethane 6.5
Diisopropyl ether (DIPE) 6.5
Elhylbenzene 6.5
Hex.Jchlorobuladiene 6.5
Date Analyzed: 7/4/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BOL,
BQL
BQL
BQL
BQL
BQL
BQL
BOL
Flags: BOL ~ Below Ouantita\ii!re,_ir!.'1:11ification #481 S.C. Certification #99029
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
D.
I
I
D
n
I
I
I
I
,,.,.,:.,u11•..,__,,.L, a...., ...... ....,. ................................. ,
Client Sample ID: CR-A2
Client Project ID: Clarion!
Lab Sample ID: 46844
Lab Project ID: G175-262
Matrix: Soil
Compound
2-l-lexanone
lodomelhane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-penlanone
Melhyl-tert-bulyl ether (MTBE)
Naphthalene
n-Propyl benzene
Slyrcne
1, 1, 1,2-T elrachloroelhane
1, 1,2,2-Telrachloroelhane
T etmchloroethene
Toluene
1,2 ,3-T richlorobenzene
1,2 ,4-T richlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2-T richloroethano
T richlorofluorornelhane
1,2 ,3-T richloropropane
1,2,4-Trirnelhyllienzene
1,3,5-T rimethylbenzene
Vinyl chloride
rn-,p-Xylcnc
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
Results for Volatiles
by GCMS 8260B
%Solids: 77.5
Quantitation
Limit (ug/KG)
6.5
6.5
6.5
6.5
26
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
6.5
13
6.5
Spike
Added
(ug/KG)
50
50
50
J\11 results are corrected for dilution.
Dale Analyzed: 7/4/02
Analyzed By: EES
Date Collected: 6/21/02
Dale Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
Surrogate
Result ¾Rec
(ug/KG)
48.7 97
52.3 105
48.9 98
Flags: BOL = Below Ouanlilaliori-.lio,il 'fi · #48 l N.L..· L.ert1 1catJOn S.C. Certification #99029
•
Reviewed.by:l-
Page 2 of 2
l rt,.l'\.£"'.._,l'.JJTl , .. l~l._LI .... •'-'l•LI ...... ,._..,.._,.._.,., .... .._,. .... .o.;,._,, l.l ''-'•
Clicnl Sample ID: CR-A 1
Client Project ID: Clari;int
Lab Sample ID: 46845
Lab Project ID: G 175-262
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
2-Butanone
n-Butytbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobcnzene
Chloroelhane
2-Chloroelhyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotolucne
Dibrornochloromethane
1,2-Dibromo-3-chloropropane
Oibromomethane
1.2-Dibromoelhane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
lrans-1.4-Dichloro-2-bulene
1.1-Dichloroelhane
1, 1-Dichloroelhene
1.2-Dichloroelhane
cis-1.2-Dichloroethene
lrans-1,2-dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2,2-Dichloropropane
1. -1-0ichloropropene
r:is-1,3-Dichloropropene
lrans-I,3-Dichloropropene
Dich!orodifluoromethane
Diisopropyl ether (DIPE)
Elhylbenzene
Hex;:ichloroOutadiene
Flags: BQL ~ l3elow Ouanlilalion Limit
Results for Volatiles
by GCMS 82608
%Solids: 64.7
Quantitation
Limit (ug/KG)
77
150
150
7.7
7.7
7.7
7.7
7.7
7.7
39
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
Dale Analyzed: 7 /4/02
Analyzed By: EES
Dale Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
IJOL
BOL
IJOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
N.C. Certification #481 S.C. Certification #99029
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Reviewed by:~ I
Page 1 of 2 I
I
I
I
I
I
I
I
I
D.
I
I
R
I
I
I
I
I
Client Sample ID: CR-A 1
Client Project ID: Clariant
Lab Sample ID: 46845
Lab Project ID: G 175-262
Matrix: Soil
Compound
2-Hexanone
lodomethnne
lsopropylbenzene
4-lsopropylloluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T etrachloroelhane
1, 1,2,2-Tetrachloroelhane
T etrachloroelhene
Toluene
1,2,3-Trichlorobenzene
.1,2,4-Trichlorobenzene
Trichloroethcne
1, 1, 1-T richloroelhane
1, 1,2-Trichloroethane
T rich lorofluoromcthane
1,2,3-Trichloropropane
1,2,4-Trimelhylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
rn-,p-Xylene
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dicliloroelhane-d4
Toluene-dB
Comments:
Results for Volatiles
by GCMS 82608
%Solids: 64.7
Quantitation
Limit (ug/KG)
7.7
7.7
7.7
7.7
31
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
7.7
15
7.7
Spike
Added
(ug/KG)
50
50
50
All results are corrected ror dilulion.
Dale Analyzed: 7/4/02
Analyzed By: EES
Dale Collected: 6121/02
Dale Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
Surrogate
Result %Rec
(ug/KG)
47.6 95
53.2 106
50.1 100
Flags: BOL ; Below OuanlitaJiof).j.irJ]jt . . 8 N.L. Lert1ficat10n #4 I S.C. Certification #99029
•
Reviewed by: k
Page 2 of 2
Client Sample ID: CR-A 1
Client Project ID: Clariant
Lab Sample ID: 46846
Lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chlorocthane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Oibromochlorometh.:ine
1,2~Dibromo-3-chloropropane
Oibromomethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1.4-Dichlorobenzene
trans-1,4-Dichloro-2-bulene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
lrans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2 ,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorohutadiene
Results for Volatiles
by GCMS 82608
Quantitation
limit (ug/L)
25
100
100
1
1
25
1
5
1
1
1
5
1
1
1
5
5
1
1
Date Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
. (ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOI,
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Flags: BQL = Below Quantilatiorl-l.irpjt 'fj 1, #481 N. c. Lcrt1 1ca 10n S.C. Certification #99029
-~
Reviewed by:L
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
B
I
I
n
I
I
I
I
l/'\n.r'\u1,_11~1 r1.1,r,u1 .,.._,n,u u,,,.._,.._,..,.,,,.._.._,.._,1.0..:..u, 1J,.....,.
Client Sample ID: CR-A 1
Client Project ID: Clariant
lab Sample ID: 46846
lab Project ID: G175-262
Matrix: Water
Compound
2'Hexanone
lodomelhane
lsopropylbenzene
4-lsopropylloluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2,2-Telrachloroethane
T etmchlorocthene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1. 1 ,2-T richloroeth;me
T rich lorofluorornethane
1,2 ,3-T richloropropane
1.2,4-Trirnethylbenzene
1.3,5-T rimethylbenzene
Vinyl chloride
m-.p-Xylene
a-Xylene
Surrogate Spike Recoveries
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/l)
5
1
5
5
1
1
1
1
2
Spike
Dale Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BOl
BQl
BQL
BQl
BQL
BQL
BOl
BQl
BOL
BOl
BQl
BOl
BOL
BQl
BOl
BOl
BOl
BQl
BOl
BOl
BQl
BOl
BOL
BQl
BOl
Surrogate
2
Added Result ¾Rec
Compound
Bromolluorobenzene
1.2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Flags: BQl = Below Ouantilation limit
(ug/L) (ug/l)
10 10.3
10 10.1
10 10.3
N_C Certification #48 I S.C Certification #99029
103
101
103
Reviewed by: k
Page 2 of 2
• ,1.a,i1..a.,-.,..,,,,._ ........ LI_.••'-''"_._, JLJJ1...,.'-"au1o&'-"•'•a:.u, aJ,.._,.
Clienl Sample ID: CR-B2
Clienl Projecl ID: Clariant
Lab Sample ID: 46847
Lab Projecl ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
2-Bulanone
n-Bulylbenzene
sec-Butylbenzenc
lcrl-Bulylbenzene
Carbon disulfide
Carbon tetrachloride
Clilorobcnzene
Chlorocthane
2-Chloroelhyl vinyl ether
Chloroform
Chlorornethane
2-Chlorololuene
4-Chlorotoluene
Dihromochloromcthane
I,2-0ibrorno-3-chloropropane
Dibrornomethane
1,2-Dibromoelhane (EDB)
1,2-0ichlorobenzene
1,3-Dichlorobenzene
1,4-0ichlorobcnzene
lrans-1,4-0ichloro-2-butene
1, 1-Dichloroelhane
1, 1-Dichloroethene
1.2-Dichloroclhane
cis-1,2-Dichloroelhene
lrans-1,2-dichloroclhene
1,2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1. 1-Dichloropropene
cis-1,3-Dichloropropene
lrans-1,3-Dichloropropene
Oichlorodifluoromethane
Oiisopropyl elher (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
25
100
100
1
1
1
25
1
1
5
1
5
1
1
5
1
1
1
1
1
1
5
1
1
1
Date Analyzed: 6127102
Analyzed By: EES
Dale Collected: 6121/02
Dale Received: 6122102
Dilulion: 1
Result
(ug/l)
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
Flags: BOL a Below Ouanlilatior\-lifjljt 'fi • #481 N. L. \..-ert1 icallon S.C. Certification #99029
•
Reviewed by: l-
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
R
I
I
I
I
I
I
I
I
I
I
I
I
I
u
I
•
I
I
I
m
I
I
I
I
I
.. ' ..... , ........ '--" ... , .. ,., .. ...., ••• .....,, • ...., ._,,,...,.'-'""'••'-"•'".a..:.u, •1 •'-'•
Results for Volatiles
by GCMS 8260B
Client Sample ID: CR-B2 Date Analyzed: 6127102
Client Project ID: Clariant Analyzed By: EES
lab Sample ID: 46847 Date Collected: 6121102
lab Project ID: G175-262 Dale Received: 6122102
Matrix: Water Dilution: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hexanone 5 BQl
lodomelhanc BQl
lsopropylbenzene BQL
4-lsopropyltoluene 1 BQL
Methylene chloride 5 BQl
4-Melhyl-2-penlanone 5 BQl
MethyJ.tert-bulyl ether (MTBE) BOL
Naphthalene BQL
n-Propyl benzene BQl
Styrene BQl
1, 1, 1,2-Tetrachloroethane BOl
1, 1,2 ,2-T elrachloroethane BQl
T elrdchloroelhene 1 BQL
Toluene 1 BQl
1,2,3-T richlorobcnzene BQl
1,2,4-Trichlorobenzcne BQl
T richloroethene BQl
1, 1, 1-T richloroethane BQl
1. t ,2-Trichloroethane BQl
T richlorofluoromelhane BQl
1,2,3-Trichloropropane BOl
1,2,4-Trimclhylbenzene BQl
1,3,5-Trimcthylbenzene 1 BQl
Vinyl chloride 1 BOl m-,p-Xylene 2 BQL o-Xylenc BQL
Surrogate Spike Recoveries Spike Surrogate
·Ad.ded Result ¾Rec Compound (ug/L) (ug/L)
Bromofluorobenzcne 10 10.1 101
1,2-Dichloroelhane-d4 10 10.6 106 Toluene-dB 10 10.2 102
Comments:
All results are corrected for dilution.
Flags: BOL = Below Ouanlitation Limit
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
.. , .. ..., ................... •••.......................... a.,~ ... .., ......... ~ ............................ ,
Results for Volatile~ I by GCMS 82608
Client Sample ID: CR-B2 Date Analyzed: 7/4/02 I Client Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46848 Date Collected: 6/21/02 ·
Lab Project ID: G175-262 Date Received: 6/22/02
Matrix: Soil %Solids: 59.4 Dilution: 1 I
Compound Quantitation Result
Limit (ug/KG) (ug/KG) I Acetone 84 BQL
Acrolein 170 BQL
Acrylonitrile 170 BOL I Benzene 8.4 BQL
Bromobenzene 8.4 BOL
Bromochloromethane 8.4 BQL
Bromodichloromethane 8.4 BQL I Bromoform 8.4 BQL
Bromomethane 8.4 BQL
2-Butanone 42 BOL I n-Butylbenzene 8.4 BQL
sec-Bu!ylbenzene 8.4 BQL
tert-Butylbenzene 8.4 BOL I Carbon disulfide 8.4 BOL
Carbon tetrachloride 8.4 BQL • Chlorobenzene 8.4 25
Chl01oethane 8.4 BOL I 2-Chlorocthyl vinyl ether 8.4 BOL
Chloroform 8.4 BOL
Chloromethanc 8.4 BOL I 2-Chlorotoluene 8.4 BQL
4-Chlorololuene 8.4 BQL
Dibromochloromethane 8.4 BQL
I 1.2-Dibromo-3-chloropropane 8.4 BOL
Dibromomcthane 8.4 BQL
1,2-Dibromoethane (EDB) 8.4 BOL
1,2-Dichlorobcnzene 8.4 BOL I 1,3-Dichlorobenzene 8.4 BQL
1,4-Dichlorobenzcne 8.4 BQL
trans-1,4-Dichloro-2-butene 8.4 BQL I 1, 1-Dichloroethane 8.4 BOL
1, 1-Dichloroethene 8.4 BOL
1.2-Dichloroethane 8.4 BQL
cis-1,2-Dichloroethene 8.4 BQL I trans-1,2-dichloroethene 8.4 BQL
1,2-Dichloropropane 8.4 BQL
1,3-Dichloropropane 8.4 BQL I 2 ,2-Dichloropropane 8.4 BQL
1, 1-Dichloropropene 8.4 BQL
cis-1.3-Dichloropropene 8.4 BOL I trc1ns-1,3-Dichloropropene 8.4 BQL
Dichlorodifluoromethane 8.4 BQL
Diisopropyl ether (DIPE) 8.4 BQL
Elhylbenzene 8.4 BQL I Hexachlorobutadiene 8.4 BQL
Reviewed by:~ I
Flags: SOL " Below Ouantitation Limit
S.C. Certification #99029 Page 1 of 2 I N.C. Certification #48 I
I
I
I
I
I
I
I
u
D
I
m
I
D
u
m
I
I
I
I
r J-\. R.l\. l-' I'-• JH J\.l,J-\.L.l l l\....,i-\.1.J LJ-\.UVRl'llVl\.llJ..:,, 11, \....,.
Results for Volatiles
by GCMS 82608
Client Sample ID: CR-B2 Date Analyzed: 714102
Client Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46848 Date Collected: 6121102
Lab Project ID: G175-262 Date Received: 6122102
Matrix: Soil %Solids: 59.4 Dilution: 1
Compound Quantitation Result
Limit (ug/KG) (ug/KG)
2-Hexanone 8.4 BOL
lodomelhane 8.4 BOL
lsopropylbenzene 8.4 BQL
4-lsopropyltoluene 8.4 BOL
Methylene chloride 34 BOL
4-Melhyl-2-penlanone 8.4 BOL
Methyl-tert-butyl ether (MTBE) 8.4 BOL
Naphthalene 8.4 BQL
n•Propyl benzene 8.4 BQL
Styrene 8.4 BQL
1, 1, 1,2-T elrachloroelhane 8.4 BQL
1.1.2,2-Telrachloroelhane 8.4 BOL
T etmchlorocthene 8.4 BQL
Toluene 8.4 BQL
1,2 ,3-T richlorobenzene 8.4 BQL
1,2,4· Trichlorobenzene 8.4 BOL
Trichloroelhcnc 8.4 BOL
-1, I, 1-Trichloroelh:Jne 8.4 BQL
I, 1,2.Trichloroelhanc 8.4 BQL
Tr ichlorol luoromethane 8.4 BOL
1,2,3-Trichloropropane 8.4 BOL
1,2,4-Trimelhylbcnzene 8.4 BOL
1,3,S·Trirnethylbenzene 8.4 BOL
Vinyl chloride 8.4 BOL
m·,p-Xylcne 17 BOL
o•Xylcne 8.4 BOL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rec
Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 51.2 102
1,2-Dichloroelhane-d4 50 52.8 106
Toluene-dB 50 50.4 101
Comments:
All results are corrected for dilution.
Reviewed by:L
Flags: BOL; Below Ouantilationl.irpjt N.C. Lcrtification #481 S.C. Certification #99029 Page 2 of 2
Client Sample ID: CR-Bl
Client Project ID: Clarianl
Lab Sample ID: 46849
Lab Project ID: G175-262
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
2-Bulanone
n-Butylbenzene
sec-Butylbenzene
lert-Bulylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroelhane
2-Chloroethyl vinyl ether
Chloroform
Chloromelhane
2-Chlorotoluene
4-Chlorololuene
Dibromochloromethane
1,2-0ibrorno-3-chloropropLlne
Dibromomethanc
1,2-Dibromoelhane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
lrans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroelhene
1.2-Dichloroethane
cis-1,2-Dichloroethene
lrans-1.2-dichloroelhene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
ds-1.3-Dichloropropenc
trans-1,3-Dichloropropene
Dichlorodifluoromelhane
Diisopropyl ether (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 8260B
%Solids: 56.5
Quantitation
Limit (ug/KG)
180
350
350
18
18
18
18
18
18
89
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
18
Dale Analyzed: 714/02
Analyzed By: EKR
Dale Collected: 6/21/02
Dale Received: 6122102
Dilution: 2
Result
(ug/KG)
260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Flags: BQL = Below QuantilaJi9n Li'))jl N.C. Lcrtification #481 S.C. Certification #99029
-.
Reviewed by:~
P.ige 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
D
I
I
I
I
u
I
I
I
I
Results for Volaliles
by GCMS 82608
Clienl Sample ID: CR-B1 Dale Analyzed: 7/4/02
Client Project ID: Clariant Analyzed By: EKR
Lab Sample ID: 46849 Dale Collecled: 6/21 /02
Lab Projecl ID: G175-262 Dale Received: 6/22/02
Matrix: Soil %Solids: 56.5 Dilulion: 2
Compound Ouantitation Result
limil (ug/KG) (ug/KG)
2-Hexanone 18 BQL
lodomelhane 18 BQL
lsopropylbenzene 18 BQL
4-lsopropylloluene 18 BOL
Methylene chloride 71 BQL
4-Melhyl-2-penlanone 18 BOL
Melhyl-lert-bulyl elher (MTBE) 18 BOL
Naphlhalene 18 BOL
n-Propyl benzene 18 BOL
Styrene 18 BOL
1, 1, 1,2-T elrachloroelhane 18 BQL
1, 1.2 ,2-T elrachloroelhane 18 BQL
Telrachloroethene 18 BOL
Toluene 18 BQL
1,2 ,3-T richlorobenzene 18 BQL
1,2 ,4-T richlorobenzene 18 BOL
Trichloroethene 18 BOL
I, 1, 1-Trichloroethane 18 ) BQL
1, 1,2-Trichloroethane 18 BOL
Trichlorofluoromelhane 18 BQL
1,2,3-Trichloropropanc 18 BQL
I,2,•I-Trimelhylbenzene 18 BQL
1,3.5-Trimelhylbenzene 18 BQL
Vinyl chloride 18 BOL
rn-,p-Xylene 35 BOL
o-Xylene 18 BOL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rec
Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 49.1 98
1,2-Dichloroelhane-d4 50 51.5 103
Toluene-dB 50 50.1 100
Comments:
All results are corrected for dilution.
Flags: BQL = Below Quantilationl.irpjt .fi • #481 N.C. Lert1 JCation S.C. Certification #99029
•
Reviewed by:l-
Pnge 2 of 2
Client Sample ID: CR-81
Client Project ID: Clariant
lab Sample ID: 46850
lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromelhane
Bromoform
Bromomethane
2-Butanone
n-Bulylbenzene
sec-Butylbenzene
lert-Bulylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroelhyl vinyl ether
Chloroform
Chloromcthane
2-Chlorotoluene
4-Chlorotolucne
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibrornomethane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroelhane
1, 1-Dichloroelhene
1,2-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
lrans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
Quantitatlon
Limit (ug/L)
25
100
100
1
1
1
1
1
25
1
1
1
5
1
5
1
1
5
1
1
1
1
1
1
1
1
1
5
1
1
1
Date Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/21/02
Dale Received: 6/22/02
Dilution: 1
Result
(ug/L)
BOL
BOL
SOL
BQL
BOL
BOL
BOL
SOL
BOL
BOL
SOL
SOL
BOL
BOL
BOL
BOL
BOL
SOL
BOL
BQL
BOL
SOL
BQL
SOL
BOL
BOl
BOL
BOL
BOL
BOL
BOL
BOL
SOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
SOL
BOL
BOL
Flags: SOL= Below Ouantitalln::~i'E~rtification #481 . s.c. Certification #99029
Reviewed by:k
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
u
I
I
I
I
I
I
l'/\K/\Ul\JlVI /\!~/\Lt J ILJ\1.J L/\DUK.1\IU.Klt."'.':t, ll'lL.
Results for Volatiles
by GCMS 8260B
Client Sample ID: CR-B1 Date Analyzed: 6127 /02
Client Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46850 Date Collected: 6/21/02
Lab Project ID: G 175-262 Date Received: 6/22/02
Matrix: Waler Dilution: 1
Compound Quantitation Result
Limit (ug/l) (ug/l)
2-Hexanone 5 BOL
lodomclhane 1 BQL
lsopropylbenzene BQL
,4-lsopropylloluene 1 BOL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BQL
Methyl-tert-butyl ether (MTBE) BOL
Naphthalene BOL
n-Propyl benzene BOL
Styrene BQL
1, 1, 1,2-T etrachloroethane 1 BOL
1.1.2.2-Tetrachloroethane 1 BOL
T etrachloroethene BOL
Toluene 2
1,2,3-Trichlorobenzene BQL •
1,2,4-Trichlorobenzene BQL
Trichloroethene BQL
1, 1, 1-T richloroethane BOL
1, 1,2-T richloroethane ·1 BOL
T richlorofluoromethane 1 BOL
1.2,3-Trichloropropane BOL
1,2,4-Trimcthylbcnzene BOL
1.3,5-T rimcthylbenzcnc BOL
Vinyl chloride BOL
rn-.p-Xylcne 2 BOL
a-Xylene BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rec
Compound (ug/l) (ug/l)
Bromofluorobenzene 10 10.3 103
1.2-Dichloroethanc-d4 10 10.2 102
Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilution.
Reviewed by:~
Flags: BOL = Below Ouantitation Limit
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
rf\K/\lJl\.:JJVJ /\1"/\LI J ILJ\L Lf\UUK.1\1 UKll1.,.".'), 11"'--·
Results for Volatiles
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46851
Lab Project ID: G 175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroelhyl vinyl ether
Chloroform
Chloromelh:-'lne
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
t .2-Dibromo-3-chloropropane
Dibrornomelhane
1,2-Dibromoethane (EDB)
1,2-0ichlorobenzene
1,3-0ichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butcnc
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichtoropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Oichlorodifluoromethane
Diisopropyl ether (Of PE)
Ethylbenzene
l-lexachlorobuladiene
by GCMS 8260B
Quantitation
Limit (ug/L)
25
100
100
1
1
25
1
1
1
1
5
1
5
5
1
1
1
1
1
1
5
Date Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BOL
BOL
SOL
BOL
SOL
SOL
BOL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Flags: BQL ~ Below Quantitatioru.irJlit 'fi • #481 N.L. 1...ert1 ication S.C. Certification #99029
Reviewed by:k
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
I
I
I
I
D
I
I
I
I
I
---------··-·-· ··------·---·-----·------~-,
Results for Volatiles
by GCMS 82608
C/ienl Sample ID: CR-C2 Date Analyzed: 6/27 /02
Clienl Projecl ID: Clarianl Analyzed By: EES
Lab Sample ID: 46851 Date Collecled: 6/21/02
Lab Project ID: G175-262 Dale Received: 6/22/02
Matrix: Water Dilulion: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hexanone 5 BQL
lodomethane BQL
lsopropylbenzene 1 BQL
4-lsopropyltoluene 1 BQL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BQL
Melhyl-tert-butyl elher (MTBE) 1 BQL
Naphthalene 1 BQL
n-Propyl benzene BQL
Styrene BQL
1.1.1,2-Telrachloroethane BQL
1, 1,2 ,2-T etrachloroelhane BOL
T etrachloroethene BQL
Toluene BQL
1,2 .3-T richlorobenzene BOL
1,2,4-Trichlorobenzene BQL
Trichloroethene BOL
1, 1, 1-Trichloroethane BOL
1, 1,2-T richloroethane BQL
T rich lorofluoromethane BQL
1,2.3-Trichloropropane BQL
1,2,4-Trimelhylbenzene BOL
1,3,5-T rimethylbenzene BQL
Vinyl chloride 1 BOL m-,p-Xylene 2 BQL
o-Xylene BOL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec Compound (ug/L) (ug/L)
Bromofluorobenzene 10 10.1 101
1.2-Dichloroelhane-d4 10 10.2 102
Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilulion.
Reviewed by:L
Flags: BQL = Below Quanlitaf()>_'ti'r'~rtification #481 S.C. Certification #99029 Page 2 of 2
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46852
Lab Project ID: G175-262
Results for Volatiles
by GCMS 82608
Matrix: Soil %Solids: 58.8
Compound Quantitation
Limit (ug/KG)
Acetone 85
Acrolein 170
Acrylonitrile 170
Benzene 8.5
Bromobenzene 8.5
Bromochloromethane 8.5
Bromodichloromethane 8.5
Bromoform 8.5
Bromomelhane 8.5
2-Butanone 43
n-Butylbenzene 8.5
sec-Bulylbenzene 8.5
tert-Butylbenzene 8.5
Carbon disulfide 8.5
Carbon tetrachloride 8.5
Chlorobenzene 8.5
Chloroethane 8.5
2-Chloroethyl vinyl ether 8.5
Chloroform 8.5
Chloromethanc 8.5
2-Chlorotoluene 8.5
4-Chlorololuene 8.5
Dibromochloromethane 8.5
1.2-Dibromo-3-chloropropane 8.5
Dibromomethane 8.5
1.2-Dibromoethane (EDB) 8.5
1,2-Dichlorobenzene 8.5
1.3-Dichlorobenzene 8.5
1,4-0ichlorobenzene 8.5
trans-1,4-Dichloro-2-butene 8.5
1, 1-0ichloroethane 8.5
1, ·J-Oichloroethene 8.5
1.2-Dichloroelhane 8.5
cis-1,2-Dichloroelhene 8.5
lrans-1,2-dichloroethene 8.5
1,2-Dichloropropane 8.5
1,3-Dichloropropane 8.5
2,2-Dichloropropane 8.5
1, 1-Dichloropropene 8.5
cis-1,3-0ichloropropene 8.5
trans-1,3-0ichloropropene 8.5
Oichlorodifluoromethane 8.5
Diisopropyl ether (DIPE) 8.5
Ethylbenzene 8.5
Hexachlorobutadiene 8.5
Date Analyzed: 7/4/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BQL
BOL
Flags: BQL = Below Ouantit;i,tioµ,Li)llit .fi • #481 l'l .l... l..ert1 1cauon S.C. Certification #99029
Reviewed by:~
Page 1 ot 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
••
I
I
I
I
I
I
I
I
I
B
D
I
I
I
I
I
I
rf-\K/\UI\JJ\11 f-\J~/\LI J 1\..-/\IJ L/\DVI\.J-\IVKJr...:,, II~\..,.
Results for Volatiles
by GCMS 8260B
Client Sample ID: CR-C2 Date Analyzed: 7/4/02
Client Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46852 Date Collected: 6/21 /02
Lab Project ID: G175-262 Dale Received: 6/22/02
Malrix: Soil %Solids: 58.8 Dilution: 1
Compound Quantitation Result
Limit (ug/KG) (ug/KG)
2-Hexanone 8.5 BOL
lodomelhane 8.5 SOL
lsopropylbenzene 8.5 SOL
4-lsopropyltoluene 8.5 SOL
Methylene chloride 34 SOL
4-Melhyl-2-pentanone 8.5 SOL
Melhyl-tert-butyl ether (MTBE) 8.5 SOL
Naphthalene 8.5 SOL
n-Propyl benzene 8.5 SOL
Styrene 8.5 SOL
1, 1, 1,2-Tctrachloroethane 8.5 BOL
1.1,2 ,2-Tclrcichloroethane 8.5 SOL
T clrc1chlorocthcne 8.5 BOL
Toluene 8.5 SOL
1,2 .3-T richlorobcnzene 8.5 BOL
1,2,4-Trichlorobenzene 8.5 SOL
Trichloroethcnc 8.5 SOL
1, 1, 1-T richloroethane 8.5 SOL
1.1,2-Trichloroethane 8.5 SOL
Trichlorofluorornethane 8.5 SOL
1.2.3-Trichloropropane 8.5 SOL
1.2 ,1I-T rimethylbenzene 8.5 SOL
1,3,5-Trime~hylbenzene 8.5 SOL
Vinyl chloride 8.5 SOL
rn-.p-Xylene 17 SOL
o-Xylenc 8.5 SOL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec
Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 51.1 102
1,2-Dichloroclhane-d4 50 54.0 108
Toluene-dB 50 50.2 100
Comments:
All results are corrected for dilution.
Flags: SOL~ Below Ouantilalioo..litJ\il 'fj _ #4S l N_L_ Lert1 1cat1on S.C. Certification #99029
Reviewed by~
Page 2 of 2
Flags:
r/\l\_J-\l./1\Jl,.l l'\.J"lt,LJ .J J'-..,f'.11.., .l..Jf"1.UV.l\.rl..lVI\.IC.>J', u,..._,_
Results for Volatiles I
by GCMS 82608
Client Sample ID: CR-C 1
Client Project ID: Clariant
Lab Sample ID: 46853
Lab Projecl ID: G175-262
Matrix: Waler
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomelhane
2-Bulanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Cc1rbon tetrachloride
Chlorobenzene
Chloroeth~ne
2-Cllloroethyt vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
.4-Clilorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibromomethane
1,2-Dibrornoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-0ichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichtoroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene ·
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
I
Quantitation
Limit (ug/L)
25
100
100
25
1
5
1
5
1
5
1
1
1
1
1
5
Date Analyzed: 6/27 /02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BQL ~ Below Quantitalioll-liljljt . fi . #481 N.L. 1....ert1 1cat1on S.C. Certification #99029
Reviewed by: L
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
B
I
I
I
I
I
I
l'AKAIJlbM ANALYTICAL LAHUKAIUKlt<;:S, INC.
Results for Volatiles
by GCMS 82608
Clienl Sample ID: CR-C1 Date Analyzed: 6/27/02
Client Project ID: Ckiriant Analyzed By: EES
Lab Sample ID: 46853 Date Collected: 6/21 /02
Lab Project ID: G175-262 Date Received: 6/22/02
Matrix: Water Dilution: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hcxanone 5 BQL
lodomethane BQL
lsopropylbenzene BQL
4-lsopropyltoluene BQL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BQL
Metl1yl-tert-butyl ether (MTBE) BQL
Naphthalene BQL
n-Propyl benzene BQL
Styrene BQL
1, 1, 1,2-Tetrachloroethane BOL
1, 1,2 ,2-T etrachloroethane BOL-
T clrachloroethene BQL
Toluene BQL
1,2 ,3-T richlorobenzene BQL •
1,2,4-Trichlorobenzene BQL
T richloroethene BQL
1, 1, 1-T richloroethane BQL
1, 1,2-T richloroethane BQL
T richlorofluoromcthane BOL
1,2,3-Trichloropropane BQL
1,2,4-Trirnethylbcnzene BQL
1,3,5-Trimethylbenzene BQL
Vinyl chloride 1 BQL
rn-,p-Xy!cnc 2 BQL
a-Xylene BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result %Rae
Compound (ug/L) (ug/L)
Bromolluorobcnzene 10 10.5 105
1,2-Dichlorocthane-d4 10 10.4 104
Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilution.
Reviewed by: k
Flags: BQL ~ Below Ouantitaliorui!Jljt _fi . #481 N_C. 1._,ert1 1cat1on S.C Certification #99029 Page 2 of 2
l'AKAUJliM ANALYTICAL LAHUKAIURIES, INC.
Client Sample ID: CR-C1
Client Project ID: Clariant
Lab Sample ID: 46854
Lab Project ID: G 175-262
Results for Volatiles
by GCMS 8260B
Matrix: Soil %Solids: 63.2
Compound Quantitation
Limit (ug/KG)
Acetone 79
Acrolein 160
Acrylonitrile 160
Benzene 7.9
Bromobenzene 7.9
Bromochloromethane 7.9
Bromodichloromethane 7.9
Bromoform 7.9
Bromomcthane 7.9
2-Butanone 40
n-Butylbenzene 7.9
sec-Butylbenzene 7.9
tert-Butylbenzene 7.9
Carbon disulfide 7.9
Carbon tefr3chloride 7.9
Chlorobenzene 7.9
Chloroethane 7.9
2-Chloroethyl vinyl ether 7.9
Chloroform 7.9
Chloromethane 7.9
2-Chlorotoluene 7.9
4-Chlorotoluene 79
Dibrornochloromethane 7.9
1,2-Dibromo-3-chloropropane 7.9
Dibromomclhane 7.9
1.2-Dibromoethane (EDB) 7.9
1,2-Dichlorobenzene 7.9
1.3-Dichlorobenzene 7.9
1,4-Dichlorobenzene 7.9
trans-1,4-Dichloro-2-butene 7.9
1, 1-Dichloroethane 7.9
1, 1-Dichloroethene 7.9
1,2-Dichloroethane 7.9
cis-1,2-Dichloroethene 7.9
trans-1.2-dichloroethene 7.9
1.2-Dichloropropane 7.9
1,3-Dichloropropane 7.9
2.2-Dichloropropane 7.9
t, 1-Dichloropropene 7.9
cis-1,3-0ichloropropene 7.9
lrans-1.3-Dichloropropene 7.9
Dichlorodifluoromethane 7.9
Diisopropyl ether (DIPE) 7.9
Ethylbcnzene 7.9
Hexachlorobutadiene 7.9
Flags: BQL = Below Ouantitation Limit
Date Analyzed: 7/4/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
N.C. Certification #481 S.C. Certification #99029
~
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
----------··-·-· ··----------·-------------,
I Results for Volatiles
by GCMS 8260B
I Client Sample ID: CR-C1 Date Analyzed: 7 /4/02
Client Project ID: Clarianl Analyzed By: EES
Lab Sample ID: 46854 Dale Collected: 6/21/02
Lab Project ID: G 175-262 Dale Received: 6/22/02 I Matrix: Soil ¾Solids: 63.2 Dilution: 1
Compound Quantitation Result
I Limit (ug/KG) (ug/KG)
2-Hexanone 7.9 SOL
lodomelhane 7.9 BQL
I lsopropylbenzene 7.9 BQL
4-lsopropylloluene 7.9 BQL
Methylene chloride 32 BQL
4-Melhyl-2-penlanone 7.9 BOL I Melhyl-lert-bulyl ether (MTBE) 7.9 BOL
Naphthalene 7.9 BOL
n-Propyl benzene 7.9 BOL
I Styrene 7.9 SOL
1, 1.1,2-Tetrachloroelhane 7.9 BOL
1, 1,2.2-Telrachloroethane 7.9 SOL
I T etrachloroclhene 7.9 BOL
Toluene 7.9 BOL
1,2,3-Trichlorobenzene 7.9 SOL
1,2,4-Trichlorobenzene 7.9 BOL
I Trichloroethene 7.9 BOL
1, 1, 1-T richloroethane 7.9 BOL
1, 1.2-Trichloroclhane 79 BOL
I T richlorofluoromethane 7.9 SOL
1,2,3-Trichloropropane 7.9 BOL
1.2,4-T,irncthylbenzene 7.9 BOL
1.3,5-Trimclhylbenzene 7.9 BOL I Vinyl chloride 7.9 BOL
m-,p-Xylenc .... 16 BOL
a-Xylene 7.9 BOL
I Surrogate Spike Recoveries Spike Surrogate • Added Result %Rec
Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 50.3 101
1,2-Dictiloroelhane-d4 50 54.8 110
I Toluene-dB 50 49.5 99
Comments:
D All results are corrected for dilution.
D
I
Reviewed by: L
I
Flags: BOL = Below OuanlilaJioll..l.ir;,vt .fi . #481 N.L. LCrll 1cat1on S.C. Certification #99029 Page 2 o1 2
IJia .. ,•.L.O'I'-JJ•I , ............... .._,, • ..._,,._,,,.._..._, .. .._,, ... ..., ..... a:,._,,
Clienl Sample ID: CR-D
Clienl Projecl ID: Clariant
Lab Sample ID: 46855
Lab Projecl ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Bulylbenzene
sec-Bulylbenzene
lert-Bulylbenzene
Carbon disulfide
Carbon lelrachloride
Chiaro benzene
Chloroclhane
2-Chloroethyl vinyl elher
Chloroform
Chlorometh.:me
2-Chlorololuene
4-Chlorotoluene
Dibromochloromethane
1.2-Dibromo-3-chloropropane
Dibromomethane
1,2-Dibromoelhane (EDB)
1,2-Dichlorohenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethnne
1, 1-0ichloroethene
1,2-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-0ichloropmpane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl elher (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/l)
25
100
100
1
25
1
1
5
5
1
5
1
1
1
1
1
1
5
Date Analyzed: 6/27/02
Analyzed By: EES
Dale Collecled: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/l)
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
Flags: BOL = Below OuantilalioruilJlit . fi • #481 N .c. LCrll ,catJOn S.C. Certification #99029
Reviewed by:~
, Page fol 2
I
I
I
I
I
I
I
I
I
I
·1
I
I
I
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
0
I
I
I
t'I\KAUIGJVI l\1'11\Ll J ILI\L LI\ISUKAJUKll',:S, INL.
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46855
Lab Project ID: G175-262
Matrix: Water
Compound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1.1.2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2 ,3-T richlorobenzene
1,2 ,4-T richlorobenzene
Trichloroethene
1, 1.1-T richloroethane
1, 1,2-Trichloroethane
T richlorofluoromethanc
I,2.3-Trichloropropane
1.2,4-Trimelhylbenzene
1,3,5-Trimelhylbenzene
Vinyl chloride
rn-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1.2-Dichloroethane-d4
Toluene-dB
Comments:
All resulls are corrected for dilution.
Results for Volatiles
by GCMS 82608
Quantitation
Limit (ug/L)
5
1
1
1
5
5
1
2
Spike
Added
(ug/L)
10
10
10
Date Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BOL
Surrogate
Result ¾Rec
(ug/L)
10.1 101
10.4 104
10.3 103
Flags: BOL = Below Ouantil,~ioDJ..ipiit 'fj . #4.SJ · N.L. Lert1 1cat10n S.C. Certification #99029
•
Reviewed by:~
Page2 of 2
rAKf\UllJIVI f\1~1\LY 111.,f\L Lf\HUKAIUKII',~, 11~1.,.
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46856
Lab Project ID: G175-262
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Bulylbenzene
lcrt-Bulylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Oibromomethane
1.2-Dibromoethane (EDB)
1,2-0ichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1.1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-0ichloropropane
1,3-0ichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
lrans-1,3-Oichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 82608
%Solids: 62.0
Quantitation
Limit (ug/KG)
81
160
160
8.1
8.1
8.1
8.1
8.1
8.1
40
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
Date Analyzed: 7/4/02
Analyzed By: EKR
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
801,
BQL
BQL
BOL
BOL
BOL
BQL
BQL
Flags: BOL = Below Ouantitc1,t(oo..Liµiit . fi . #4S J N. 1.... 1...ert1 1cat10n S.C. Certification #99029
•
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
n
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
u
I
I
I
I
I
I
1 i1.l\../'\Ul'l_JJ1'1 /'\J"li1.Lrl l l\,..,i1.Lr Lr/'\UVJV'\lVRIC..iJ, 11"1\...,.
Client Sample ID: CR-D
Client Project ID: Clarianl
Lab Sample ID: 46856
Lab Project ID: G175-262
Matrix: Soil
Compound
· 2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Melhyl-2-penlanone
Melhyl-lert-bulyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Telrachloroelhane
1, 1,2.2-Telrachloroelhane
T elrachloroethene
Toluene
1,2 ,3-Trichlorobenzene
1,2,4-Trichlorobenzene
Trichlorocthcne
1, 1, 1-T richloroethanc
1, 1,2-Trichloroethane
T richlorofluorometh~me
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-T,imethylbcnzcne
Vinyl chloride
rn-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Brornofluorobenzene
1.2-Dichloroelhane-d4
Toluene-dB
Comments:
Results for Volatiles
by GCMS 82608
%Solids: 62.0 ·
Quantitation
Limit (ug/KG)
8.1
8.1
8.1
8.1
32
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
8.1
16
8.1
Spike
Added
(ug/KG)
50
50
50
All results are corrected for dilution.
Date Analyzed: 7/4/02
Analyzed By: EKR
Dale Collected: 6/21 /02
Dale Received: 6/22/02
Dilution: 1
Surrogate
Result
(ug/KG)
48.5
50.4
50.1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
¾Rec
97
101
100
Flags: BQL = Below Quanlilation.l.irjljl .fi . #481 N.C. Lert1 tcalion S.C. Certification #99029
Reviewed by:~
Page 2 of 2
1 n.l\..t'I.UIUH'I /'I.J'tn.1.Jt .1 t\...,n.LJ l.J/'l.1.)Vft..t\.lVl\1£..:,, IJ't'-.,.
Client Sample ID: DUP-2
Client Project ID: Clariant
Lab Sample ID: 46857
Lab Project ID: G 175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Bulylbenzene
sec-Butylbenzene
lert-Butylbcnzene
CiJrbon disulfide
CiJrbon tetrachloride
Chlorobenzene
Chloroeth3nc
2-Chloroelhyl vinyl elher
Chloroform
Chloromethane
2-Chlorololuene
4-Chlorotolucne
Dibromochloromethane
1 .2-Dibromo-3-chloropropane
Dibromomelhane
1,2-Dibromoethane (EDB)
1.2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroelhene
1,2-Dichloroclhane
cis-1,2-Dichloroethcne
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
tr.ins-1.3-Dichloropropene
Dichlorodilluorometh::Jne
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
25
100
100
1
1
1
25
5
5
1
5
1
1
1
5
Date Analyzed: 6127102
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
Flags: BQL ~ Below Quantitation Limit N.C. Certification #48 I S.C. Certification #99029
', •
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
H
D
I
t"/\K/\UIGJVI /\l~ALYTIL/\L LAHUKAlUKlt<:S, INC.
Results for Volatiles
by GCMS 82608
Client Sample ID: DUP-2 Date Analyzed: 6/27/02
Client Project ID: Clariant Analyzed By: EES
Lab Sample ID: 46857 Dale Collected: 6/21 /02
Lab Project ID: G175-262 Dale Received: 6/22/02
Matrix: Water Dilution: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hexanone 5 BQL
lodomethane BQL
lsopropylbcnzene 1 BQL
4-lsopropyltoluene BQL
Methylene chloride 5 BQL
4-Methyl-2-penlanone 5 BQL
Melhyl-lert-butyl ether (MTBE) BQL
Naphthalene BQL
n-Propyl benzene BQL
Styrene BOL.
1, 1.1,2-T elrachloroethane BQL
1.1,2.2-T elrachloroethane 1 BQL
T etrachloroethene 1 BOL
Toluene 1
1,2,3-Trichlorobenzene BOL •
1,2,4-Trichlorobenzene 1 BQL
T richloroethcne 1 BOL
1, 1, 1-T richloroethane 1 BQL
1, 1,2-T richloroethane BOL
Trichlorolluoromethane BOL
1,2,3-T richloropropane BOL
1,2 ,4-T rimelhylbcnzene BOL
1,3,5-Trimethylbenzene BQL
Vinyl chloride 1 BQL rn-,p-Xylene 2 BQL
a-Xylene 1 BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec
Compound (ug/L) (ug/L)
Bromofluorobenzene 10 10.1 101
1,2-Dichloroelhane-d4 10 10.3 103 Toluene-dB 10 10.3 103
Comments:
All results are corrected for dilution.
Reviewed by: L-
Flags: BOL = Below Ouantitalion Limit
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
Y/\KAUll..,JVI /\J~/\Ll I IL/\L L/\HUKJ\IUKJI',;:,, IJ~l,.
Client Sample ID: DUP-2
Client Project ID: Clariant
Lab Sample ID: 46858
Lab Project ID: G175-262
Matrix: Soil
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobnnzene
Chloroethane
2-Chloroethyl vinyl ether
. Chloroform
Chlorornethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1,2-Dibromo-3-chloropropane
Dibromomelhane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzcne
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-0ichloroethene
trans-1,2-dichloroelhene
1,2-Dichloropropane
1,3-Dichloropropane
2.2-Dichloropropane
1. 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Oichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethylbenzene
Hexachlorobutadiene
Flags: BOL = Below Quantitation Limit
Results for Volatiles
by GCMS 8260B
%Solids: 53.1
Quantitation
Limit (ug/KG)
94
190
190
9.4
9.4
9.4
9.4
9.4
9.4
47
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
9.4
Date Analyzed: 7/4/02
Analyzed By: EKR
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/KG)
100
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BOL
BOL
BQL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029
•
Reviewed by:~
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
H
I
I
I
I
I
I
I
I
I
I
I
I
I
•
0
D
I
I
I
I
I
I
PAKAUIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GCMS 82608
Client Sample ID: DUP-2 Date Analyzed: 7/4/02
Client Project ID: Clariant Analyzed By: EKR
Lab Sample ID: 46858 Date Collecled: 6/21/02
Lab Projecl ID: G175-262 Date Received: 6/22/02
Matrix: Soil %Solids: 53.1 Dilution: 1
Compound Quantitation Result
Limit (ug/KG) (ug/KG)
2-Hexanone 9.4 BQL
lodomethane 9.4 BQL lsopropylbenzene 9.4 BQL
4-lsopropylloluene 9.4 BQL
Methylene chloride 38 BQL
4-Methyl-2 -pentanone 9.4 BQL
Methyl-tert-butyl ether (MTBE) 9.4 BQL
Naphthalene 9.4 BQL
n-Propyl benzene 9.4 BQL
Styrene 9.4 BQL
1, 1, 1,2-T elrachloroethane 9.4 BQL
1, 1,2,2-Tetrachloroelhane 9.4 BQL
T ctrachlorocthene 9.4 BOL Toluene 9.4 BQL
1,2 ,3-T richlorobenzene 9.4 BQL
1,2.4-Trichlorobenzene 9.4 BQL
T richlorocthene 9.4 BQL
1, 1 , 1-T richloroethane 9.4 BQL
1, 1.2-Trichloroctt1ane 9.4 BQL T richloroftuoromethane 9.4 BQL
1,2.3-Trichloropropane 9.4 BQL
1,2.4-Trirnethylbenzene 9.4 BQL 1,3,5-T rimethylbenzene 9.4 BQL Vinyl chloride 9.4 BOL m-,p-Xylene 19 BQL a-Xylene 9.4 BQL
Surrogate Spike Recoveries Spike Surrogate
Added Result ¾Rec Compound (ug/KG) (ug/KG)
Bromofluorobenzene 50 48.8 98
1,2-Dichloroethane-d4 50 51.4 103
Toluene-dB 50 50.0 100
Comments:
All results are corrected for dilution.
Flags: BQL = Below Ouanlitalioo-J..itnit ·r, · #481 N.L. LCl11 1catt0n S.C. Certification #99029
Reviewed by: -k
Page 2 of 2
l'AKAUlliM ANAIXIILAL LA HU KAI UKII',~, INL
Results for Volatiles
by GCMS 8260B
Client Sample ID: DUP-3
Client Project ID: Clarianl
Lab Sample ID: 46859
Lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomelhane
2-Butanone
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorololuene
4-Chlorotoluene
Dibromochloromelhane
1,2-Dibromo-3-chloropropane
Dibromomethane
1,2-Dibromoethane (EDB)
1,2-0ichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1.3-Dichloropropane
2 ,2-Dichloropropane
1, 1-Dichloropropene
cis-1.3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Ethyl benzene
Hexachlorobutadiene
Flags: BOL = Below Ouantitation-li!Jlil -fi 1-#481 N _ L. L.ert1 1ca 100
Quantitation
Limit (ug/l)
25
100
100
1
1
1
25
1
1
5
1
1
1
1
5
1
1
5
1
1
1
1
1
5
1
1
Date Analyzed: 6/27/02
Analyzed By: EES
Dale Collected: 6/21 /02
Date Received: 6/22/02
Dilution: 1
Result
. (ug/L)
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
S.C Certification #99029
' •
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Reviewed by: k I
Page 1 of 2 I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
I
I
I
r/\.l\.1\VI\J1H 1\1'"1/\LI I J\..,J\L LJ-\DUl\.1\IUl\.lt,:O,, JJ'",L,.
Client Sample ID: DUP-3
Client Project ID: Clariant
Lab Sample ID: 46859
Lab Project ID: G175-262
Matrix: Water
COmpound
2-Hexanone
lodomethane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-Tetrachloroethane
1, 1,2 .2-T etrachloroethane
T etrachloroethene
Toluene
t .2,3-Trichlorobenzene
1,2,'1-Trichlorobenzene
T richloroethene
1, 1, 1-T richloroethane
1, 1,2-Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-T rimethylbcnzene
Vinyl chloride
m-,p-Xylcne
a-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are corrected for dilution.
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
5
1
5
5
1
2
Spike
Added
(ug/L)
10
10
10
Date Analyzed: 6/27/02
Analyzed By: EES
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Surrogate
Result
(ug/L)
10.0
10.4
10.3
Result
(ug/L)
SOL
BOL
BOL
BOL
SOL
BOL
SOL
BOL
BOL
SOL
SOL
BOL
BOL
BOL
BOL
SOL
BOL
BOL
BOL
SOL
BOL
BOL
BOL
BOL
BOL
SOL
%Rec
100
104
103
Flags: SOL= Below OuantitaUon..lirpjt •r, -#4S l N .L. Lert1 1cat10n S.C. Certification #99029
Reviewed by:~
Page 2 of 2
PAKAUl(jlVI ANALY I ICAL LAHUKAJUKIJ<;:-i, ·INC.
Client Sample ID: FB-SW
Client Project ID: Clariant
Lab Sample ID: 46860
Lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromornelhane
2-Bulanone
n-Bulylbenzene
sec-Bulylbenzene
tert-Bulylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobcnzene
Chloroelhane
2-Chloroethyl vinyl ether
Chloroform
Chloromcthane
2-Chlorotoluene
4-Chlorotoluene
Oibromochloromethane
1,2-Dibrorno-3-chloropropane
Dibrornomelhane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1.4-Dichlorobenzene
lrans-1,4-Dichloro-2-bulene
1, 1-Dichloroelhane
1, 1-Dichtoroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
c:is-1,3-Dichloropropene
lrans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Elhylbenzene
Hexachlorobutadiene
Results for Volatiles
by GCMS 8260B
Quantitatlon
Limit (ug/L)
25
100
100
1
1
25
5
5
1
5
1
1
5
Dale Analyzed: 6/30/02
Analyzed By: RNP
Dale Collected: 6/21 /02
Dale Received: 6/22/02
Dilution: 1
Result
(ug/L)
36
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BOL
BQL
BOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BQL
Flags: BOL = Below Ouantita\ipn Lin.Ji! . I N.C. Lertifical!on #48 S.C. Certification #99029
Reviewed by:l-
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
g
D
D
D
t'AKAU!bl\1 ANALY I !CAL LAISUKAIUK!t;:S, 11'/L.
Clienl Sample ID: FB-SW
Clienl Projecl 10: Clarianl
Lab Sample ID: 46860
Lab Projecl ID: G175-262
Matrix: Water
Compound
2-Hexanone
lodomelhane
lsopropylbenzene
4-lsopropylloluene
Melhylene chloride
4-Melhyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1.1.2-T etrachloroethane
1, 1,2,2-Tetrachloroethane
T etrachloroethene
Toluene
1,2,3-T richlorobenzene
1,2.4-Trichlorobenzene
Trichloroethene
1, 1, 1-T richloroethane
1.1.2-Trichloroethane
T rich lorofluoromethane
1.2 .3-T richloropropane
1,2,4-T rimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroelhane-d4
Toluene-d8
Comments:
All results are corrected for dilution.
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
5
1
1
5
5
1
1
2
Spike
Added
(ug/L)
10
10
10
Dale Analyzed: 6130102
Analyzed By: RNP
Dale Collecled: 6121102
Dale Received: 6122102
Dilulion: 1
Surrogate
Result
(ug/l)
10.0
10.1
10.2
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
%Rec
100
101
102
Flags: BQL = Below OuanlitaJiofl..l_irJlit N.C. Lertificalion #481 S.C. Certification #99029
Reviewed by: L
Page 2 of 2
l'/\KAUll,JVI 1\1~/\LY IIL/\L L/\nUK/\lUKIJ',C:,, ll~L.
Clienl Sample ID: FB-SD
Client Projecl ID: Clarianl
Lab Sample ID: 46861
Lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonilrile
Benzene
Bromobenzene
Bromochloromelhane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Bulylbenzene
scc-Butylbenzene
lert-Bulylbenzene
Carbon disulfide
C;irbon lelr8chloride
Chlorohenzene
Chloroethane
2-Chloroelhyl vinyl elher
Chloroform
Chloromethanc
2-Chlorotoltiene
4-Chlorototuene
Dibromochloromcthcme
-1 ,2-Dibromo-3-chloropropane
Dibrornomelhane
1,2-Dibromoelhane (EDB)
1,2-Dichlorobcnzene
1,3-Dichlorobenzcne
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroelhane
1. 1-Dichloroelhene
1,2-Dichloroelhane
cis-1,2-Dichloroethene
trans-1,2-dichloroethene
1,2-0ichloropropane
1.3-Dichloropropane
2 .2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl elher (DIPE)
Ethylbenzene
Hcxachlorobutadiene
Results for Volatiles
by GCMS 8260B
Quantitation
Limit (ug/L)
25
100
100
1
25
1
5
5
1
5
1
1
1
5
1
Date Analyzed: 6130102
Analyzed By: RNP
Date Collecled: 6121102
Date Received: 6122102
Dilution: 1
Result
(ug/L)
BOL
BOL
BOL
· BOL
SOL
BOL
SOL
SOL
BOL
BOL
BOL
BOL
BOL
BOL
130L
BOL
BOL
BOL
BOL
130L
BOL
SOL
BOL
BOL
SOL
BOL
BOL
BOL
BOL
BOL
SOL
BOL
BOL
BOL
BOL
SOL
BOL
BO!,
SOL
SOL
BOL
BOL
BOL
BOL
SOL
Flags: BOL ~ Below Ouantita\l5'_'tli'e~rtification #481 S.C Certification #99029
•
Reviewed by: k
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
PARADIGM ANALYTICAL LABORATORIES, INC.
I Results for Volatiles
by GCMS 82608
I Client Sample ID: FB-SD Date Analyzed: 6/30/02
Clienl Projecl ID: Clariant Analyzed By: RNP
lab Sample ID: 46861 Date Collected: 6/21 /02
I lab Project ID: G175-262 Date Received: 6/22/02
Matrix: Water Dilution: 1
.I Compound Quantitation Result
Limit (ug/L) (ug/l)
2•Hexanone 5 BOL
lodomethane BOl I lsopropylbenzene BOl
4-lsopropyltoluene BOL
Methylene chloride 5 BQL
I 4-Methyl-2-pentanone 5 BOl
Methyl-tert-butyl ether (MTBE) BQL
Naphthalene BQL
I n-Propyl benzene BOl
Styrene BQL
1, 1, 1,2-T etrachloroethane BOL
1, 1,2,2-T etrachloroethane BQL
I T etrachlorocthene BOL
Toluene 1
1,2 ,3-Trichlorobenzene BQL
1.
1.2 ,4-T richlorobenzene BQL
Trichloroethene BOl
1, 1, 1-Trichloroethane BQL
1, 1,2-Trichloroethanc BOl I T richlorofluoro methane BOl
1,2,3-T rich1oropropane BOl
1,2,'1-Trimethylbcnzene 1 BQl
I 1,3,5-Trirncthylbcnzene 1 BOL
Vinyl chloride 1 IJQL
rn-.p-Xylcnc 2 BOl
g a-Xylene BQL
Surrogate Spike Recoveries Spike Surrogate
D Added Result %Rec
Compound
Brornofluorohenzene
I 1,2-Dichloroethane-d4
Toluene-dB
Comments:
m All results arc corrected for dilulion.
m
I
I
I Flags: BQl = Below OuantitalionJ..ifJlit 'fj , #481 N .L. Lert1 1cat1on
(ug/l) (ug/l)
10 10.1 101
10 10.0 100
10 10.1 101
S.C. Certification #99029
•
Reviewed by:k
Page 2 of 2
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: Trip Blanks
Client Project ID: Clariant
Lab Sample ID: 46862
Lab Project ID: G175-262
Matrix: Waler
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Bulanone
n-Butylbenzene
sec-Bulylbenzene
tert-Butylbenzene
Ci:ubon disulfide
Cm bon tetrachloride
Chlorobenzene
Chlorocthane
2-Chloroelhyl vinyl ether
Chlorofoi-m
Chloromethane
2-Chlorotoluene
4-Chlorololuene
Dibromoch!oromethane
1,2-Dibromo-3-chloropropane
Oibromornethane
1.2-Dibromoethane (EDB)
1.2-Dichlorobenzene
1,3-0ichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1, 1-Dichloroethane
1, 1-Dichloroethene
1.2-Dichloroethane
r.is-1,2-0ichloroelhcne
lrans-1,2-dichloroethene
1.2-Dichloropropane
1,3-Dichloropropane
2 .2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-0ichloropropene
trans-1.3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ether (DIPE)
Elhylbenzene
Hcxachlorobutadie11e
Results for Volatiles
by GCMS 82608
Quantitation
limit (ug/L)
25
100
100
1
1
25
5
1
5
1
5
1
1
1
1
1
5
Date Analyzed: 7/1/02
Analyzed By: RNP
Date Collected: 6/21/02
Date Received: 6/22/02
Dilution: 1
Result
(ug/L)
BOL
BOL
BOL
BOL
BOL
BQL
BQL
BQL
BOL
BQL.
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BOL
OOL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BQL
BQL
BQL
Flags: BOL = Below Ouantitation..lilpjt 'fi . #481 N.L. 1._,ert1 1cat1on S.C. Certification #99029
Reviewed by:L
Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I
I
Y/\K/\Ul\.JJVI /\1"1/\Ll 11\..../\L L/\.llVKJ\IUKtr.~, H'i\..,.
Client Sample ID: Trip Blanks
Client Project ID: Clariant
Lab Sample ID: 46862
Lab Project ID: G175-262
Matrix: Water
Compound
2-Hexanone
lodomelhane
lsopropylbenzene
4-lsopropyltoluene
Methylene chloride
4-Methyl-2-pentanone
Methyl-tert-butyl ether (MTBE)
Naphthalene
n-Propyl benzene
Styrene
1, 1, 1,2-T elrachloroelhane
1, 1,2.2-Telrachloroelhane
Tetrnchloroethene
Toluene
1,2,3-Trichlorobenzene
1.2.4-Trichlorobenzene
T richloroethene
1, 1, 1-T richloroethanc
1, 1,2-Trichloroelhane
Trichlorofluoromethane
1,2,3-T richloropropane
1,2,4-Trimethylbenzenc
1,3,5-Trimcthylbenzene
Vinyl chloride
m-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Results for Volatiles
by GCMS 82606
Quantitation
limit (ug/L)
5
1
5
5
1
1
1
1
1
2
Spike
Date Analyzed: 7/1/02
Analyzed By: RNP
Dale Collected: 6/21/02
Dale Received: 6/22/02
Dilution: 1
Result
. (ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
Surrogate
2
Added Result %Rec
Compound
Bromofluorobenzcne
1,2-Dichloroelhanc-d4
T oluene-cl8
Comments:
All results are corrected for dilution.
Flags: BQL = Below Quantilation.Lirpjt . . N.C. Lert1ficat1on #481
(ug/l) (ug/L)
10 10.2 102
10 10.7 107
10 9.9 99
S.C. Certification #99029
~
Reviewed by: l\;_ .
Page 2 of 2
l'AKAUll,M ANALYTICAL LAHURATURIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46843
Lab Project ID: G175-262
Matrix: Water
Date Collected: 6/21/2002
Dale Received: 6/22/2002
Dale Analyzed: 6/28/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a)anthracene
~~nzCl[a Jeyri•me _
Benzo[b ]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether _
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di~n-octylphthal,:itt1 __
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1 ,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene . -··· ... ----
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hex,:ic~l_orocyclopenladiene
Hexachloroethane
lndeno( 1,2 ,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL --------
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
. ···-······ ---···--·---------·--··-·· 10 BQL
10 BQL
10 BQL
10 BQL
10 BQL ------10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
20 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
20 BQL --·-·------10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
N.C. Certification #4RI s_r_ Certification #99029 'Page 1 of2
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
PAKAUH;M ANALYTICAL LAHUKAIUKIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46843
Lab Project ID: G 175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nilroaniline
3-Nitroaniline
4-Nitroaniline
Quantitation
Limit (ug/l)
10
10
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL -----------------c--c------------=c Nitrobenzene 10 BQL
Phenanthrene
Pyrene
1 ,2 ,4-T richlorobenzene ·
Surrogate Spike Recoveries
10
10
10
Spike
Added
BQL
BQL
BQL
Spike Percent
Result Recovered
I 2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
10
10
10
6.2 62
6.0 60
11.3 113 a Comments:
0 Flags:
D
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #4R I srr· Certification #99029 f'age 2 o 7
•
PARADIGM ANALYflCAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46844
Lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/1/2002
%Solids: 77.5
Quanlilation
Compound Limit (ug/KG)
Acenaphthene 390
Acenaphthylene 390
Anthracene 390
Benzo[a]anthracene 390
Benzo[a]pyrene_ 390
Benzo[b ]Ouoranthene 390
Benzo[g,h,ijperylene 390
Benzo[k]fluoranthene 390
Bis(2-chloroethoxy)methane 390
Bis(2-chloro~thyl)~)~er 390
Bis(2-chloroisopropyl)ether 390
Bis(2-ethylhexyl)phthalate 390
4-bromophenyl phenyl ether 390
Butylbenzylphthalate 390
4-Chloroaniline 390 --··-···---------2-Chloronaphthalene 390
4-Chlorophenyl phenyl ether 390
Chrysene 390
Di-n-Butylphthalate 390
[)i:n-octylp~ th.ii~)~ __ 390
Dibenzo[a,h]anthracene 390
Dibenzofuran 390
1.2-Dichlorobenzene 390
1,3-Dichlorobenzene 390
1,4-Dichlorobenzene 390 -------···-··----3,3'-Dichlorobenzidine 780
Diethylphthalate 390
Dimethylphthalate 390
2,4-Dinitrotoluene 390
2,6-Dinitrotoluene 390 ···-· ·---·•---------~-Fluoranthene 390
Fluorene 390
Hexachlorobenzene 390
Hexachlorobutadiene 390
Hexachloro~y_c~opent~diene 780
Hexachloroethane 390
lndeno(1,2,3-c,d)pyrene 390
lsophorone 390
2-Methylnaphthalene 390
N-Nitrosodi-n-propylamine 390
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BOL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BOL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BOL
BOL
BOL
BOL
BQL
BOL
BQL
BOL
BOL
BOL
BQL
BOL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
l'AKAUlt;M ANALYTICAL LAISUKAIUKl1':S, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46844
Lab Project ID: G 175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitrcianiline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-T erphenyl-d 14
%Solids: 77.5
Quantitation
Limit (ug/KG)
390
390
390
390
390
390
390
390
390
Spike
Added
10
1 ()
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/1/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
7.3 73
6.9 69
9.2 92
I Comments:
I Flags:
I
I
a
I
0
I
0
D
Results are corrected for %solids and dilution where applicable.
BOL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #4R! s1r. Certification #99029 F"age 2 o "1
l'AKAUlbM ANALY I ILAL LAHUKAIUKIE:S, INL.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A 1
Client Project ID: Clariant
Lab Sample ID: 46845
Lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
%Solids: 64.7
Quantitalion
Compound Limit (ug/KG)
Acenaphthene 490
Acenaphthylene 490
Anthracene 490
Benzo[a]anthracene 490
Benzo[a]pyrene 490
Benzo[b]fluoranthene 490
Benzo[g,h,i]perylene 490
Benzo(k]fluoranthene 490
Bis(2-chloroethoxy)methane 490
Bis(2-chloroelhyl)ether 490
Bis(2-chloroisopropyl)ether 490
Bis(2-elhylhexyl)phlhalate 490
4-bromophenyl phenyl ether 490
Butylbenzylphthalate 490
4-Chloroaniline 490 .. -· .. --------·-2-Chloronaphthalene 490
4-Chlorophenyl phenyl ether 490
Chrysene 490
Di-n-Butylphthalale 490
Di-n-octylphlhalate _ 490
Dibenzo(a,h]anthracene 490
Dibenzofuran 490
1,2-Dichlorobenzene 490
1,3-Dichlorobenzene 490
1,4-Dichlorobenzene 490 -····-·-·---------------3,3'-Dichlorobenzidine 970
Diethylphlhalate 490
Dimethylphthalate 490
2,4-Dinitrotoluene 490
2,6-Dinitrotoluene 490 ----..... ----------Fluoranthene 490
Fluorene 490
Hexachlorobenzene 490
Hexachlorobutadiene 490
Hexachlorocyc:lopentadiene 970
Hexachloroethane 490
lndeno(1,2,3-c,d)pyrene 490
lsophorone 490
2-Methylnaphthalene 490
N-Nitrosodi-n-propylamine 490
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL -------BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
'~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
D
I
I
I
I
I
I
I
I
I
I
l'AKAUIGM ANALYIILAL LAHUKAIUKl~S, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-A 1
Client Project ID: Clariant
Lab Sample ID: 46845
Lab Project ID: G175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
%Solids: 64.7
Quanlitatlon
Limit (ug/KG)
490
490
490
490
490
490
490
490
490
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
5.8 58
4.4 44
7.2 72 4-T erphenyl-d 14
I Comments:
I Flags:
m
I
0
D
D
m
Results are corrected for %solids and dilution where applicable.
BQL = Below Quanlitation Limit.
Reviewed By:~.,.__
N.C. Certification #481 S.C. Certification #99029 P~gezot 2
•
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-A1
Client Project ID: Clarianl
Lab Sample ID: 46846
Lab Project ID: G 175-262
Matrix: Water
Dale Collected: 6/21/2002
Dale Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Quantitation
Compound Limit (ug/L)
Acenaphthene 10
Acenaphthylene 10
Anlhracene 10
Benzo[a]anthracene 10
Benzo[a]pyrene 10
Benzo[b]fiuoranthene 10
Benzo[g,h,i]perylene 10
Benzo[k]fiuoranthene 10
Bis(2-chloroethoxy)methane 10
!3is(2-chlor?e,'.!'x!)e)~~~-10
Bis(2-chloroisopropyl)ether 10
Bis(2-ethylhexyl)phthalale 10
4-bromophenyl phenyl ether 10
Butylbenzylphthalate 10
4-Chloroaniline 10 ······· ···-···-------------------------2-Chloronaphthalene 10
4-Chlorophenyl phenyl ether 10
Chrysene 10
Di-n-Butylphthalate 10
Di-n-octylphthalate 10
Result
(ug/L)
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL .... -· ·--···--·----·--------·---·-----------------------·-Dibenzo[a,t1]anthracene 10
Dibenzofuran 10
1,2-Dichlorobenzene 10
1,3-Dichlorobenzene 10
1,4-Dichlorobenzene 10
3,3'-Dichlorobenzidine 20
Diethylphthalate 10
Dimethylphthalate 10
2,4-Dinitrotoluene 10
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
10
10
10
10
10
20
10
10
10
10
10
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
•
I
I
I
I
I
I
I
I
I
I
I
I
I
B
D
I
I
I
I
rAKAUll,JVI 1\1~1\Ll 11\...J\L LJ\DVIU\.IVl\lt.::), ll~\...,.
Results for Semivolatile Base/Neutral Extractables
by GCMS8270
Client Sample ID: CR-A1
Client Project ID: Clariant
Lab Sample ID: 46846
Lab Project ID: G175-262
Matrix: Water
Compound
N-Nilrosodiphenylamine
Naphthalene
2-Nilroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2 ,4-T richlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d 14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
Spike Percent
Result Recovered
7.5 75
7.2 72
11.7 117
I
I
I
I
I
I
I
I
I.
I Comments:
I Flags:
I
I
I
I
I
0
D
u
Results are corrected for %solids and dilution where applicable.
BQL = Below Ouanlilalion Limit.
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
rJ-\1\.J-\UJ\.JIJVI /\l''H\.LI J l\.,1\.L Ll\DUKJ\IUKl.t,~, ll~l....
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-B2
Client Project ID: Clariant
Lab Sample ID: 46847
Lab Project ID: G175-262
Matrix: Water
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo(a]pyrene
Benzo[b ]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
.§is/2-_<:~loro~_thyl)e_ther
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline
... ·······--·· 2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di-n-octylp~thalat': _____
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene . -------Fluoranthene
Fluorene
· Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocycloper1!adi_e_rie_.
Hexachloroethane
lndeno( 1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20 --·--·"··----··
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL -. --------
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
·~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
B
I
u
I
I
I
I
I
I
I
I
I
l'AKAUIGM ANALYTI<.:AL LABUKA:J'UKIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-B2
Client Project ID: Clariant
lab Sample ID: 46847
lab Project ID: 8175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nilrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
Quanlitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Spike
Result
6.3
6.5
11.7
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQl
BQL
Percent
Recovered
63
65
117
I Comments:
I Flags:
I
I
I
n
D
D
D
6
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
•
r/\Kf\Ul\.JJYI /\1~/-\LI Jl\..,f-\L Lf-\DVIV\.IVl\1.1'.,.::,, 11"\.....
Results for Semivolalile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-B2
Client Project ID: Clariant
lab Sample ID: 46848
lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a)anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo(g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroElthyl)_ethE_J~--
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline .......... ----· 2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di~n-octylphth,ilat~---
Dibenzo[a,h ]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1,4-Dichlorobenzene
-·········-··-'" ·-· 3,3'-Dichlorobenzidine
· Diethytphthalate
Dimethytphthalate
2 .4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachto~c,~yc::topentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 59.4
Quanlitation
Limit (ug/KG)
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
1400
720
720
720
720
720
720
720
720
1400
720
720
720
720
720
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQl
BOL
BQL
BQL
BQL
BQl
BQL
BQL ------·-BQL
BQl
BQL
BQL
BQl
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQl
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029
Page 1 of 2
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
H
I
m
I
I
I
I
I
I
ffl
PAKAUll;M ANALYTICAL LAlSUKAI UKrn:S, !NL.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-82
Client Project ID: Clariant
Lab Sample ID: 46848
Lab Project ID: G 175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2 ,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 59.4
Quantitation
Limit (ug/KG)
720
720
720
720
720
720
720
720
720
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BOL
BOL
BOL
BQL
BOL
BOL
BOL
BQL
Spike Percent
Result Recovered
6.9 69
6.3 63
9.2 92
I.
0 Comments:
D Flags:
u
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BOL = Below Quantilation Limit.
Reviewed By:~
N.C. Certification #4R I s,r. Certification #99029 t5age2o2 .
•
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-B1
Client Project ID: Clariant
Lab Sample ID: 46849
Lab Project ID: G 175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
%Solids: 56.5
Quantitation
Compound Limit (ug/KG)
Acenaphthene 830
Acenaphthylene 830
Anthracene 830
Benzo[a)anthracene 830
. Benzo[a)pyrene 830
Benzo[b]nuoranthene 830
Benzo[g,h,i]perylene 830
Benzo[k)nuoranthene 830
Bis(2-chloroethoxy)methane 830
Bis(2-chloroethyl)ether 830
Bis(2-chloroisopropyl)ether 830
Bis(2-ethylhexyl)phthalate 830
4-bromophenyl phenyl ether 830
Butylbenzylphthalate 830
4-Chloroaniline 830
2-Chloronaphthalene 830
4-Chlorophenyl phenyl ether 830
Chrysene 830
Di-n-Butylphthalate 830
J2i:n-oc_tylp_ht~i3/~te 830
Dibenzo[a,h]anthracene 830
Dibenzofuran 830
1,2-Dichlorobenzene 830
1,3-Dichlorobenzene 830
1,4-Dichlorobenzene 830 .. ·--···--··· -·--··~----3,3'-Dichlorobenzidine 1700
Diethylphthalate 830
Dimethylphthalate 830
2,4-Dinitrotoluene 830
2,6-Dinitrotoluene 830
Fluoranthene 830
Fluorene 830
Hexachlorobenzene 830
Hexachlorobutadiene 830
t-lexa~~lorocy_c!e>pentadiene 1700
Hexachloroethane 830
lndeno(1,2,3-c,d)pyrene 830
lsophorone 830
2-Methylnaphthalene 830
N-Nitrosodi-n-propylamine 830
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
~
I
I
I
I
I
I
I
I
I
I
I
•
I
I
I
I
I
I
I
I
I
I
I
I
I
PAKAU!l,M ANALYTICAL LAISUKAIUKJJ<;~, INL.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Clienl Sample ID: CR-B1
Clienl Projecl ID: Clarianl
Lab Sample ID: 46849
Lab Projecl ID: G175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nilroaniline
4-Nilroaniline
Nitrobenzene
Phenanlhrene
Pyrene
1,2,4-Trichlorobenzene
%Solids: 56.5
Quantitation
Limit (ug/KG)
830
830
830
830
830
830
830
830
830
Spike
Added
Date Collected: 6/21/2002
Dale Received: 6/22/2002
Dale Analyzed: 7/2/2002
Spike
Result
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered Surrogate Spike Recoveries
D 2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d14
10
10
10
7.0 70
7.4 74
9.2 92
D Comments:
D Flags:
I
I
I
I
I
I
I
I
Resulls are correcled for %solids and dilulion where applicable.
BOL = Below Quanlilalion Limit.
N.C. Certification #48 I S.C. Certification #99029 ' Page2of2 ·
l'AKAUlliJVI I\J,I\Ll I IL-1\L LJ\nUKJ\JUKlte>, 11,L-.
Results for Semivolatile Base/Neutral Extraclables
by GCMS 8270
Client Sample ID: CR-B1
Client Project ID: Clariant
Lab Sample ID: 46850
Lab Project ID: GH5-262
Matrix: Water
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroelhoxy)methane
_Bis(2-chloroelhyl)elher
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalale
4-Chloroaniline -····--·-----··--2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Bulylphthalate
Di-n-octylphthalale
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
_ Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029
Page 1 of 2
•
I
I
I
I
I
I
I
I
I
I
u
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
l'ARAOIGM ANALYTICAL LAHUKAlUKll'::S, INL.
Results for Semivolalile Base/Neutral Extractables
by GCMS8270
Client Sample ID: CR-B1
Client Project ID: Clariant.
Lab Sample ID: 46850
Lab Project ID: G 175-262
Matrix: Waler
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
Quanlitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Spike
Result
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
Percent
Recovered
D 2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
10
10
10
8.1
7.7
11.9
81
77
119
D Comments:
H Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Ouantitation Limit.
Reviewed By:~
N.C. Certification #4~Jge i5of;_. Certification #99029
•
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46851
Lab Project ID: G_175-262
Matrix: Water
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a Janthracene
Benzo[a)pyrene
Benzo[b )Ouoranthene
Benzo[g ,h ,i]perylene
Benzo[k]Ouoranthene
Bis(2-chloroelhoxy)methane
!=3i!;l2-chloroethyl )ether
Bis(2-chloroisopropyl)ether
Bis(2-elhylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphlhalate
4-Chloroaniline ----------· 2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalale
Di-n-octylphthalate __
Dibenzo[a.h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene -----------3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2 ,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
_ He~achlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nilrosodi-n-propylamine
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
•
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
I
I
I
l'AKAUll,M ANAL\'TILAL LAHUKAIURIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46851
Lab Project ID: G 175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nilroaniline -.. •-----. -·--·-Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Dale Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
7.3 73
7.1 71
11.3 113
I
I
I
I
I
I
I
I
u
0 Comments:
D Flags:
m
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certifica_tion #4~!ge ;>0f;. Certification #99029
F/\1\/\UJ\JlVJ f\.J"'lf\LI J 1\..-f\L LJ-\OUI\J\IUI\IC..O::,, Jl"t\..,.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46852
Lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anlhracene
Benzo[a]pyrene
Benzo[b Jnuoranthene
Benzo[g,h,i]perylene
Benzo[k]nuoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphlhalate
4-Chloroaniline
2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Bulylphlhalale
Di:n-_octylp~lhalati:
Dibenzo[a,h]anlhracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidine
Dielhylphthalate
Dimethylphlhalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobuladiene
Hexac~le>ro~Y.?~opentadiene
Hexachloroethane
lndeno( 1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 58.8
Quantitation
Limit (ug/KG)
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
830
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL .. ······--··--. ···-·•·-···-·-····----···-1700 BQL
830 BQL
830 BQL
830 BOL
830 BQL
830 BQL
830 BQL
830 BQL
830 BQL
1700 BQL
830 BQL
830 BQL
830 BQL
830 BOL
830 BQL
N.C. Certification #481 S.C. Certification #99029
Page 1 of 2
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
g_
0
0
B
I
I
I
I
I
I
I
PAKAUJ(jM ANALYTICAL LAHUKAIUMH;S, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS8270
Client Sample ID: CR-C2
Client Project ID: Clarianl
Lab Sample ID: 46852
Lab Project ID: G 175-262
Matrix: Soil
Compound
N-Nilrosodiphenylamine.
Naphthalene
2-Nitroaniline
3-Nilroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d 14
%Solids: 58.8
Quantitation
Limit (ug/KG)
830
830
830'
830
830
830
830
830
830
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Dale Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1 .
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent •
Result Recovered
6.9 69
7.5 75
9.2 92
Comments:
Flags:
Results are corrected for %solids and dilution where applicable.
BQL = Below Quanlilation Limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page 2 of 2
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-C1
Client Project ID: Clarianl
Lab Sample ID: 46853
Lab Project ID: 8175-262
Matrix: Waler
Date Collected: 6/21/2002
Dale Received: 6/22/2002
Dale Analyzed: 6/28/2002
Compound
Acenaphlhene
Acenaphlhylene
Anlhracene
Benzo[a]anlhracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g, h, i]perylene
Benzo[k]fluoranthene
Bis(2-chloroelhoxy)melhane
Bis(2-chloroelhyl)elher __
Bis(2-chloroisopropyl)ether
Bis(2-elhylhexyl)phlhalale
4-bromophenyl phenyl ether
Bulylbenzylphlhalale
4-Chloroaniline ... -.. ··-------· ·-----
2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphlhalale
Di:n-oc:ty!_phl~~lale
Dibenzo[a,h]anlhracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene .. ---... ·-·-·---· 3,3'-Dichlorobenzidine
Dielhylphlhalale
Dimelhylphlhalate
2,4-Dinilrololuene
2,6-Dinilrotoluene
Fluoranlhene
Fluorene
Hexachlorobenzene
Hexachlorobuladiene
Hexachlorocyclop_e::itadiene
Hexachloroelhane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Melhylnaphlhalene
N-Nilrosodi-n-propylamine
Quantitatlon
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL.,
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
•
I
I
I
I
I
' I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
u
I
m
I
D
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolalile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-C1
Client Project ID: Clariant
Lab Sample ID: 46853
Lab Project ID: G175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Quanlilalion
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Spike
Result
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
Percent
Recovered
10 7.3 73
10 7.5 75
Surrogate Spike Recoveries
U · 2-Fluorobiphenyl
. · Nitrobenzene-d5
10 12.0 120 4-Terphenyl-d 14
E Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #4R I s1r. Certification #99029 JYage•2 0 }' I
•
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-C1
Client Project ID: Clariant
Lab Sample ID: 46854
Lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Dale Analyzed: 7/2/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b Jfluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
~~\3:~hloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Bulylbenzylphthalate
4-Chloroaniline
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
_l?i~n:octy!p_hthalate
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ------·--3,3'-Dichlorobenzidine
Diethylphthalale
Dimelhylphthalate
2,4-Dinitrotoluene
2 ,6-Dinilrololuene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 63.2
Quantitation
Limit (ug/KG)
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
720
1400
720
720
720
720
720
720
720
720
1400
720
720
720
720
720
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL,
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #4~90 ~o½ Certification #99029
--~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
m
I
I
t'AKAUl(;M ANALYTICAL LAHUKAIUKIJ<:S, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS8270
Client Sample ID: CR-C1
Client Project ID: Clariant
Lab Sample ID: 46854
Lab Project ID: G175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nilrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d14
%Solids: 63.2
Quantitation
Limit (ug/KG)
720
720
720
720
720
720
720
720
720
Spike
Added
10
10
10
Dale Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
7.4 74
7.7 77
9.7 97 I Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quanlilation Limit.
Reviewed By:~
N.C. Certification #4R I S.C. Certification #99029 Page2of2 ·
~
PARADIGM ANALYflCAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46855
Lab Project ID: 8175--262
Matrix: ·water
Date Collected: 6/21/2002
Date Received: 6/2212002
Date Analyzed: 6/28/2002
Compound
Acenaphlhene
Acenaphthylene
Anlhracene
Benzo[a ]anlhracene
Benzo[a]pyrene. -····-
Benzo[b]fluoranlhene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline .. -.. -···· ... ,. --·-------
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Bulylphthalate
Di~n-c,ctylpht~al'.:(e
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1.3-Dichlorobenzene
1,4-Dichlorobenzene ·-----·---·---------··--· 3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene ·---... ·····--------· Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobuladiene
1-lexachlorocyclopE:':~~iJ_~~----··
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
Quanlitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20 ---~--10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029
Page 1 of 2
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
0
D
u
PARADIGM ANALYfICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46855
Lab Project ID: G175-262
Matrix: Water
Compound .
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
Quanlitatlon
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 6/28/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
SOL
SOL
SOL
BOL
BOL
SOL
BOL
BOL
BOL
Spike Percent
Result Recovered
7.4 74
7.8 78
11.9 119 I· Comments:
I· Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BOL = Below Ouantitation Limit.
Reviewed By:~
N.C. Certification #481 S.C. .Certification #99029 Page 2 ol 2
~
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46856
Lab Project ID: G175-262
Matrix: Soil
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
. Acenaphthene
Acenaphthylene
Anthracene
Benzo[a)anthracene
Benzo[a)pyrene
Benzo[b)fluoranthene
Benzo[g ,h ,i]perylene
Benzo[k)fluoranthene
Bis(2-chloroethoxy)methane
13i~(2-chlo(oethXl)eth e~--...
Bis(2-chloroisopropyl)ether
Bis(2-elhylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline
·-····-·--·-····--·-------2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di-n-octylphthalate
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ·-----· ---·-··-3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
. ····-·····-·· -Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
_f-!E_Jx~c~lc,rocy_clopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nitrosodi-n-propylamine
%Solids: 62.0
Quantitation
Limit (ug/KG)
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
1900
3700
1900
1900
1900
1900
1900
1900
1900
1900
3700
1900
1900
1900
1900
1900
Analyzed By: MRC
Dilution: 2
Result
(ug/KG)
BQL
BQL
63000
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10000
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #4IV,,9e~t><;; Certification #99029
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
a
n
I
m
0
D
m
PARAUIGM ANALYTICAL LAHUKAIUKlt<:S, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46856
Lab Project ID: G175-262
Matrix: Soil
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2.4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyt
Nitrobenzene-d5
4-Terphenyl-d 14
%Solids: 62.0
Quantitation
Limit (ug/KG)
1900
1900
1900
1900
1900
1900
1900
1900
1900
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 2
Result
(ug/KG)
BQL
BQL
BOL
BQL
BQL
BQL
9000
BQL
BOL
Spike Percent ~
Result Recovered
3.1 63
3.3 66
4.6 92
I Comments:
I· Flags:
I
I
I
I
I
I
m
a
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #4Rl S.C. Certification #99029 · i"age 2 of 2
l'i\J<i\UJ(jM ANALYTICAL LABORATORIES, INC.
Results for Semivolalile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: DUP-2
Client Project I_D: Clariant
Lab Sample ID: 46857
Lab Project ID: G175-262
Matrix: Water
Dale Collected: 6/21/2002
Dale Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
Acenaphlhene
Acenaphlhylene
Anlhracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b ]fluoranthene
Benzo[g,h,ijperylene
Benzo[k]fluoranlhene
Bis(2-chloroethoxy)methane
_Bis(2-chloroethyl)ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalale
4-bromophenyl phenyl ether
Bulylbenzylphlhalate
4-Chloroaniline ·-·· ----•---··· ---------2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphlhalale
Di-n-oclylphthalale --·-
Dibenzo[a,h]anthracene
Dibenzofuran
1.2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ····----.. -----.. 3,3'-Dichlorobenzidine
Diethylphthalate
Dimelhylphlhalale
2,4-Dinilrololuene
2,6-Dinilrotoluene ·---·----·-----
Fluoranlhene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
. Hexachlorocyclopentadiene
Hexachloroethane
lndeno( 1,2,3-c,d)pyrene
lsophorone
2-Melhylnaphlhalene
N-Nitrosodi-n-propylamine
Quantilalion
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #48Jage ~fS2 Certification #99029
·~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
I
I
I
m
I
u
rt-\.1\_f-\l.Jl\.JJ\'J /\l't/1.Ll l ,.._,n.L l..J/1.DVR.t1.lVftlt~, 11,.._,.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: DUP-2
Client Project ID: Clariant
Lab Sample ID: 46858
Lab Project ID: G 175-262
Matrix: Soil
Compound
N-Nilrosodiphenylamine
Naphthalene
2-Nilroaniline
3-Nitroaniline
4-Nilroaniline
Nilrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-T erphenyl-d 14
%Solids: 53.1
Quantitation
Limit (ug/KG)
1200
1200
1200
1200
1200
1200
1200
1200
1200
Spike
Added
10
10
10
Dale Collected: 6121 /2002
Dale Received: 6122/2002
Dale Analyzed: 71212002
Analyzed By: MRC
Dilution: 1
Result
(ug/KG)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
7.2 72
7.6 76
10.0 100
D Comments:
E Flags:
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quanlilation Limit.
Reviewed By:~
N.C. Certification #4R! S.C. Certification #99029 Page 2 of 2
•
rf-\n/-\U]\.:Jl\11 J-\.l"fJ-\.Ll 1 JL,/\.L l.JJ-\.OVJ\.f-\.lVl\1£,.-:,, IJ"IL,.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: DUP-3
Client Project ID: Clariant
Lab Sample ID: 46859
Lab Project ID: G175-262
Matrix: .. water
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Bis(2-chloroelhoxy}melhane
Bis(2-chloroethyl)elher
Bis(2-chloroisopropyl}elher
Bis(2-elhylhexyl)phthalale
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline --··----------2-Chloronaphlhalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Bulylphlhalale
Di-n-oclylphlhalate
Dibenzo[a,h]anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ----···----------------3,3'-Dichlorobenzidine
Diethylphthalate
Dimelhylphthalate
2,4-Dinitrololuene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroelhane
lndeno( 1,2,3-c,d}pyrene
lsophorone
2-Melhylnaphlhalene
N-Nitrosodi-n-propylamine
Quantitation
Limit {ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10 .
Analyzed By: MRC
Dilution: 1
Result
{ug/L)
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BOL
BQL
BOL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N.C. Certification #481 S.C. Certification #99029 Page1ol2 .
•
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
I
0
D
I.
l'ARAUH;M ANALYTICAL LABORATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
byGCMS8270
Client Sample ID: DUP-3
Client Project ID: Clariant
Lab Sample ID: 46859
Lab Project ID: G175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2.4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
Quantitatlon
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 612112002
Date Received: 6122/2002
Date Analyzed: 712/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent -~
Result Recovered
5.0 50
5.0 50
9.3 93
m Comments:
I Flags:
I
I
I
I
I
I
I
I
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantitation Limit.
Reviewed By: k
N.C. Certification #4Rt '-F Certification #99029 'Page Z" or-2'
t'/\KAUIIJJVI /\1~/\Ll I 1\.,/\L L/\ISUK/\1 UKIJ<,~, ll~C.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: FB-SW
Client Project ID: Clariant
Lab Sample ID: 46860
Lab Project ID: G175-262
Matrix: Waler
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Quantitation Result
Compound Limit (ug/L) (ug/L)
Acenaphthene 10 BOL Acenaphlhylene 10 BOL
Anlhracene 10 BQL
Benzo(a]anlhracene 10 BQL
Benzo[a]pyrene 10 BQL
Benzo(b]fluoranlhene 10 BQL
Benzo[g,h,i]perylene 10 BQL
Benzo[k]fluoranlhene 10 BQL
Bis(2-chloroelhoxy)methane 10 BQL Bis(2-chloroethyl)ether 10 BQL Bis(2-chloroisopropyl)ether 10 BQL • Bis(2-ethylhexyl)phthalate 10 BQL
4-bromophenyl phenyl ether 10 BQL
Butylbenzylphthalate 10 BQL
4-Chloroaniline 10 BQL
2-Chloronaphlhalene 10 BQL
4-Chlorophenyl phenyl ether 10 BOL
Chrysene 10 BQL
Di-n-Bulylphthalate 10 BQL
Di-n-octylphthalate 10 BQL ------------------------~=~ Dibenzo[a,h]anthracene 10 BQL
Dibenzofuran 10 BQL 1,2-Dichlorobenzene 1 O BOL
1,3-Dichlorobenzene 10 BQL
1,4-Dichlorobenzene 10 BQL
3,3'-Dichlorobenzidine 20 BQL
Diethylphthalate 10 14
Dimelhylphlhalate 10 BQL
2,4-Dinitrotoluene 10 BQL
2,6-Dinitrololuene 10 BQL
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroelhane
lndeno( 1 ,2 ,3-c,d)pyrene
lsophorone
2-Melhylnaphlhalene
N-Nilrosodi-n-propylamine
10 BOL
10 SOL
10 BQL
10 BQL
20 BQL
10 BQL
10 BQL
10 BQL
10 BQL
10 BQL
N.C. Certification #481 S.C. Certification #99029 Page 1 of 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
w
a
0
D
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: FB-SW
Client Project ID: Clariant
Lab Sample ID: 46860
Lab Project ID: G175-262
Matrix: Water
Compound
N-Nilrosodiphenylamine
Naphthalene
2-Nilroaniline
3-Nilroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
Surrogate Spike Recoveri!'s
2-Fluorobiphenyl
Nitrobenzene-d5
4-Terphenyl-d 14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Dale Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent
Result Recovered
6.0 60
6.4 64
9.9 99 E Comments:
Results are corrected for %solids and dilution where applicable.
I Flags:
I
I
I
I
I
I
I
I
BQL = Below Quantitation Limit.
Reviewed By:~
N.C. Certification #~aie 2is-Certification #99029
rt\..n.J\..l.llUJ'i'I /\.l"IJ-\.L,111'-,,J-\.LJ 1 .. H\.UV~\..IVI\.ILoJ, Il"I'-,,.
Results for Semivolatile Base/Neutral Extractables
byGCMS 8270
Client Sample ID: FB-SD
Client Project ID: Clariant
Lab Sample ID: 46861
Lab Project ID: G175-262
Matrix: Water
Date Collected: 6/21/2002
Date Received: 6/22/2002
Date Analyzed: 7/2/2002
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a)anthracene
!3~nzo[a)eyrene -----
Benzo[b)Ouoranthene
Benzo[g,h,i]perylene
Benzo(k)0uoranthene
Bis(2-chloroethoxy)methane
_ Bis(2-chloroethyl )ether
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-bromophenyl phenyl ether
Butylbenzylphthalate
4-Chloroaniline ·-___ ,, ___________
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Di-n-Butylphthalate
Di-n-octylphthalate _
Dibenzo(a,h)anthracene
Dibenzofuran
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene ... -·· --... ---------· -··---· 3,3'-Dichlorobenzidine
Diethylphthalate
Dimethylphthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene .. ··········--·--·--Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobuladiene
1-l~xach.loro~X~lopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
lsophorone
2-Methylnaphthalene
N-Nilrosodi-n-propylamine
Quanlitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
20
10
10
10
10
10
10
10
10
20
10
10
10
10
10
Analyzed By: MRC
Dilution: 1
Result
(ug/L)
BQL
BQL
BOL
BQL
BQL ---·-----·---BOL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BQL
BOL
BQL
BOL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
N.C. Certification #48 I S.C. Certification #99029 Page 1 ol 2
•
I
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
u
D
D
l'AKAUIGM ANALYTICAL LABOKATORIES, INC.
Results for Semivolatile Base/Neutral Extractables
by GCMS 8270
Client Sample ID: FB-SD
Client Project ID: Clariant
Lab Sample ID: 46861
Lab Project ID: G175-262
Matrix: Water
Compound
N-Nitrosodiphenylamine
Naphthalene
2-Nilroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
Phenanthrene
Pyrene
1.2,4-Trichlorobenzene
Surrogate Spike Recoveries
2-Fluorobiphenyl
Nilrobenzene-d5
4-Terphenyl-d 14
Quantitation
Limit (ug/L)
10
10
10
10
10
10
10
10
10
Spike
Added
10
10
10
Date Collected: 6/21/2002
Date Received: 6/22/2002
Dale Analyzed: 7/2/2002
Analyzed By: MRC
Dilution: 1
Result
, (ug/L)
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Spike Percent •
Result Recovered
6.4 64
6.7 67
9.7 97
I Comments:
I Flags:
I
I
I
I
I
I
m
D
Results are corrected for %solids and dilution where applicable.
BQL = Below Quantilalion Limit.
Reviewed By:~
N.C. Certification #481 S.C. Certification #99029 Page2of2 ·
l'AKAUIGM ANALYTILAL LAHUKAJUKJJ<:S, INC.
Results for Metals I
Client Sample ID: CR-A2 Analyzed By: RML I Client Project ID: Clari ant Date Collected: 6/21/02
Lab Sample ID: 46843 Date Received: 6/22/02
Lab Project ID: G175-262 Matrix: Water I Batch ID: 2351 2350
Metals Resutt Quantitation OF Units Method Date I
Limit Analyzed
I Antimony BQL 0.0600 1 MG/L 6010B 7/3/02
Arsenic BQL 0.0100 1 MG/L 60108 7/3/02
Beryllium 8QL 0.0100 1 MG/L 60108 7/3/02 I Cadmium 8QL 0.0100 1 •MG/L 60108 7/3/02
Chromium BQL 0.0100 1 · MG/L 6010B 7/3/02
Copper 8QL 0.0200 1 MG/L 60108 7/3/02 I Lead BQL 0.0050 1 MG/L 60108 7/3/02
Mercury 8QL 0.0003. 1 MG/L 7470 6/25/02
Nickel BQL 0.0400 1 MG/L 60108 7/3/02 I Selenium BQL 0.0100 1 MG/L 60108 7/3/02
Silver 8QL 0.0100 1 MG/L 60108 7/3/02.'
Thallium 8QL 0.0100 1 MG/L 6010B 7/3/02
I Zinc 8QL 0.0200 1 MG/L 60108 7/3/02
I Comments
8QL = Below Quantitation Limits I DF = Dilution Factor
J = Between MDL and RL
I
I
I
I
I
I
Reviewed By:~
I
N.C. Certification #481 S.C. Certification #99029 I
I
I
I
u
0
E
I
I
I
I
I
I
I
0
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Metals
Client Sample ID: CR-A2
Client Project ID: Clari ant
Lab Sample ID: 46844
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 2.46
Copper 11.0
Lead 1.65
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium 1.91
Zinc 9.98
Comments
BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
6.45 1 MG/KG
1.08 1 MG/KG
1.08 1 MG/KG
1.08 1 MG/KG
1.08 1 MG/KG
2.15 1 MG/KG
0.538 1 MG/KG
0.0237. 1 MG/KG
4.30 1 MG/KG
1.08 1 MG/KG
1.08 1 MG/KG
1 08 1 MG/KG
2.15 1 MG/KG
Analyzed By:
Date Collected:
Date Received:
Matrix:
Solids
Method
60106
6010B
6010B
6010B
6010B
6010B
6010B
7471
60106
60106
60106
60106
60106
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Soil
77.47
Date
Analyzed
7/3/02
7/3/02
713102
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02 •
7/3/02
7/3/02
Reviewed By:k
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID: CR-A 1
Client Project ID: Clariant
Lab Sample ID: 46845
Lab Project JD:
Batch ID:
G175-262
2355 2358
Results for Metals
Metals Result Quantilalion OF Units
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Comments
BQL
8QL
BQL
8QL
5.92
8.81
4.74
BQL
8QL
8QL
8QL
BQL
18.3
8QL = Below Quanlilalion Limits
OF= Dilution Factor
J = Between MDL and RL
Limit
7.86 1 MG/KG
1.31 1 MG/KG
1.31 1 MG/KG
1.31 . 1 MG/KG
1.31 1 MG/KG
2.62 1 MG/KG
0.655 1 MG/KG
0.0284 . 1 MG/KG
5.24 1 MG/KG
1.31 1 MG/KG
1.31 1 MG/KG
1.31 1 MG/KG
2.62 1 MG/KG
Analyzed By: RML
Dale Collected: 6/21/02
Dale Received: 6/22/02
Matrix: Soil
Solids 64.71
Method Date
Analyzed
60108 7/3/02
60108 7/3/02
60108 7/3/02
60108 7/3/02
60108. 7/3/02
60108 7/3/02
60108 7/3/02
7471 7/3/02
60108 7/3/02
60108 7/3/02
60108 7/3/02.
60108 7/3/02
60108 7/3/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By: k
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
I Results for Metals
I Client Sample ID: CR-A1 Analyzed By: RML
Client Project ID: Clari ant Date Collected: 6/21/02
I Lab Sample ID: 46846 Date Received: 6/22/02
Lab Project ID: G175-262 Matrix: Water
Batch ID: 2351 2350
I Metals Result Quantitation DF Units Method Date n Limit Analyzed
Antimony BQL 0.0600 1 MG/L 6010B 7/3/02
Arsenic BQL 0.0100 1 MG/L 6010B 7/3/02 0 Beryllium BQL 0.0100 1 MG/L 6010B 7/3/02
Cadmium BQL 0.0100 . 1 MG/L 6010B 7/3/02
Chromium BQL 0.0100 1 MG/L 6010B 7/3/02
m Copper BOL 0.0200 1 MG/L 6010B 7/3/02
Lead BOL 0.0050 1 MG/L 6010B 7/3/02
Mercury BOL 0.0003 . 1 MG/L 7470 6/25/02 • Nickel BQL 0.0400 1 MG/L 6010B 7/3/02
Selenium BOL 0.0100 1 MG/L 6010B 713102.
Silver BQL 0.0100 1 MG/L 6010B 7/3/02 •
I Thallium BOL 0.0100 1 MG/L 6010B 7/3/02
Zinc BQL 0.0200 1 MG/L 6010B 7/3/02
I
Comments
I BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
I
I
I
I
m
I
I
Reviewed By: k I N.C. Certification #481 S.C. Certification #99029
PARADIGM ANALYTICAL LABORATORIES, INC.
·Results for Metals
Client Sample ID: CR-B2
Client Project ID: Clariant
Lab Sample ID:
Lab Project ID:
Batch ID:
46847
G175-262
2351 2350
Metals Result Quantilation
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Comments
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
0.0600
0.0100
0.0100
0.0100
0.0100
0.0200
0.0050
0.0003 .
0.0400
0.0100
0.0100
0.0100
0.0200
Analyzed By: RML
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Water
OF Units Method Date
Analyzed
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 7470 6/25/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02
1 MG/L 60108 7/3/02.
1 MG/L 60108 7/3/02
1 MG/L 6010B 7/3/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
I
I
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I. -
I
I
I
I
I
m
I
I
•
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Metals
Client Sample ID: CR-B2
Client Project ID: Clari ant
Lab Sample ID: 46848
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 10.0
Copper 12.6
Lead 6.81
Mercury BOL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc 27.2
Comments
BQL = Below Quantitation Limits
OF = Dilution Factor
J = Between MDL and RL
Limit
10.1 1 MG/KG
1.68 1 MG/KG
1.68 1 MG/KG
1.68 1 MG/KG
1.68 1 MG/KG
3.37 1 MG/KG
0.842 1 MG/KG
0.0330. 1 MG/KG
6.74 1 MG/KG
1.68 1 MG/KG
1.68 1 MG/KG
1.68 1 MG/KG
3.37 MG/KG
Analyzed By: RML
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Solids 59.35
Method Date
Analyzed
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
7471 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02·•
6010B 7/3/02
6010B 7/3/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:L
l'AKAUl(jM ANALYTICAL LAHUKAJUKJJ<:S, INC.
Results for Metals
Client Sample ID: CR-B1
Client Project ID: Clari ant
Lab Sample ID: . 46849
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result · Quantitation OF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 9.24
Copper 11.5
Lead 6.08
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc 27.8
Comments
BQL = Below Quantitalion Limits
OF= Dilution Factor
J = Between MDL and RL
Limit
9.49 1 MG/KG
1.58 1 MG/KG
1.58 1 MG/KG
1.58 1 MG/KG
1.58 1 MG/KG
3.16 1 MG/KG
0.791 1 MG/KG
0.0351 1 MG/KG
6.33 1 MG/KG
1.58 1 MG/KG
1.58 1 MG/KG
1.58 1 MG/KG
3.16 1 MG/KG
Analyzed By:
Date Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Soil
56.46
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02~
7/3/02
7/3/02
Reviewed By:~
I
I
I
I
R
D
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
u
u
I
I
I
I
'I
I
I
r1\I\./\Ul\Jll'I 1\1'1/\LI 11\..,/\L L/\DVJ\J-\.IVJ\.IC.C,, IJ"I\..,.
Results for Metals
Client Sample ID: CR-B1
Client Project ID: Clariant
Lab Sample ID: 46850
Lab Project ID: 8175-262
Batch ID: 2351 2350
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium BQL
Copper BQL
Lead BQL
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc BQL
Comments
BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
0.0600 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 . 1 MG/L
0.0100 1 MG/L
0.0200 1 MG/L
0.0050 1 MG/L
0.0003 . 1 MG/L
0.0400 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0200 1 MG/L
Analyzed By:
Date Collected:
Date Received:
Matrix:
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7470
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Water
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
6/25/02
7/3/02
7/3/02
7/3/0i•
7/3/02
7/3/02
Reviewed By: l-
rJ\Kf\Ul\Jll'l /U'lf\LI 11\.....1\L L/\DVK/\IUJ(II!,;_-,, 11',.\.,..
Results for Metals I
Client Sample ID: CR-C2 Analyzed By: RML I Client Project ID: Clariant Date Collected: 6/21/02 Lab Sample ID: 46851 Date Received: 6/22/02 Lab Project ID: G175-262 Matrix: Water I Batch ID: 2351 2350
Metals Result Quantitation OF Units Method Date I
Limit Analyzed
I Antimony BQL 0.0600 1 MG/L 6010B 7/3/02 Arsenic BQL 0.0100 1 MG/L 6010B 7/3/02 Beryllium BQL 0.0100 1 MG/L 6010B 7/3/02 I Cadmium BQL 0.0100 1 MG/L 6010B 7/3/02 Chromium BQL 0.0100 1 ·MG/L 6010B 7/3/02 Copper BQL 0.0200 1 MG/L 6010B 7/3/02 I Lead BQL 0.0050 1 MG/L 6010B 7/3/02 Mercury BQL 0.0003 . 1 MG/L 7470 6/25/02 Nickel BQL 0.0400 1 MG/L 6010B 7/3/02 I Selenium BQL 0.0100 1 MG/L 6010B 7/3/02 Silver BQL 0.0100 1 MG/L 6010B 7/3/02· Thallium BQL 0.0100 1 MG/L 6010B 7/3/02
I Zinc BQL 0.0200 1 MG/L 6010B 7/3/02
Comments I
BOL = Below Quantitation Limits
I DF = Dilution Factor
. J = Between MDL and RL
I
I
I
I
I
I
Reviewed By: k I
N.C. Certification #481 S.C. Certification #99029 I
I
I
a
0
n
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYflCAL LABORATORIES, INC.
Results for Metals
Client Sample ID: CR-C2
Client Project ID: Clarianl
Lab Sample ID: 46852
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 8.73
Copper 16.5
Lead 5.63
Mercury BQL
Nickel BQL
Selenium BQL.
Silver BQL
Thallium BQL
Zinc 29.6
Comments
BQL = Below Quantilalion Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
8.95 1 MG/KG
1.49 1 MG/KG
1.49 1 MG/KG
1.49 . 1 MG/KG
1.49 1 MG/KG
2.98 1 MG/KG
0.746 1 MG/KG
0.0298 . 1 MG/KG
5.97 1 MG/KG
1.49 1 MG/KG
1.49 1 MG/KG
1.49 1 MG/KG
2.98 1 MG/KG
Analyzed By: RML
Dale Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Solids 58.80
Method Date
Analyzed
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
7471 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02 ~
6010B 713/02
6010B 7/3/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:k_
1-'ARAUIGM ANALYTICAL LABORATORIES, INC.
Results for Metals I
Client Sample ID: CR-C1 Analyzed By: RML I Client Project ID: Clariant Date Collected: 6/21/02
Lab Sample ID: 46853 Dale Received: 6/22/02 I Lab Project ID: G175-262 Matrix: Water
Batch ID: 2351 2350
I Metals Result Quantitation DF Units Method Date
Limit Analyzed I Antimony BQL 0.0600 1 MG/L 6010B 7/3/02
Arsenic BQL 0.0100 1 MG/L 60108 7/3/02 I Beryllium BQL 0.0100 1 MG/L 60108 7/3/02 Cadmium BQL 0.0100 1 ·MG/L 60108 7/3/02 Chromium BQL 0.0100 1 MG/L 60108 7/3/02
I Copper BQL 0.0200 1 MG/L 60108 7/3/02
Lead BQL 0.0050 1 MG/L 60108 7/3/02
Mercury BQL 0.0003. 1 MG/L 7470 6/25/02
Nickel BQL 0.0400 1 MG/L 60108 7/3/02 I Selenium BQL 0.0100 1 MG/L 60108 7/3/02 • Silver BQL 0.0100 1 MG/L 60108 7/3/02
Thallium BQL 0.0100 1 MG/L 60108 7/3/02 I Zinc BQL 0.0200 1 MG/L 60108 7/3/02
I
Comments
I BQL = Below Quantitalion Limits
DF = Dilution Factor
J = Between MDL and RL
I
I
I
I
I
I
Reviewed By:~
I
N.C. Certification #48 I S.C. Certification #99029 I
I
I
I
I
a
D
I
I
I
I
I
I
I
I
r /\. 1\.1\l.J I \J J\'I /\.J't/\LI 11\...,/\.L L/\DVl\.l\lVI\.Jt.:,, 11 't \..,.
Results for Metals
Client Sample ID: CR-C1
Client Project ID: Clari ant
Lab Sample ID: 46854
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result Quanlitalion DF Units
Antimony BQL
Arsenic BQL
Beryllium BOL
Cadmium BOL
Chromium 8.86
Copper 9.27
Lead 3.96
Mercury BOL
Nickel BQL
Selenium BQL
Silver BOL
Thallium BQL
Zinc 20.4
Comments
BQL = Below Quanlitalion Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
8.48 1 MG/KG
1.41 1 MG/KG
1.41 1 MG/KG
1.41 1 MG/KG
1.41 1 MG/KG
2.83 1 MG/KG
0.706 1 MG/KG
0.0296 . 1 MG/KG
5.65 1 MG/KG
1.41 1 MG/KG
1.41 1 MG/KG
1.41 1 MG/KG
2.83 1 MG/KG
Analyzed By:
Dale Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Soil
63.19
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02•
7/3/02
7/3/02
l't\KAUH.,JVI t\Nt\LY I ILAL Lt\HUKAJUJ<lt<;:S, INL.
Results for Metals I
Client Sample ID: CR-D Analyzed By: RML I Client Project ID: Clari ant Date Collected: 6/21/02
Lab Sample ID: 46855 Date Received: 6/22/02 I Lab Project ID: G175-262 Matrix: Water
Batch ID: 2351 2350
Metals Result Quantitation DF Units Method Date I
Limit Analyzed I Antimony BQL 0.0600 1 MG/L 60108 7/3/02
Arsenic BQL 0.0100 1 MG/L 60108 7/3/02
Beryllium BQL 0.0100 1 MG/L 60108 7/3/02 I Cadmium BQL 0.0100 . 1 MG/L 60108 7/3/02
Chromium BQL 0.0100 1 .MG/L 60108. 7/3/02
Copper BQL 0.0200 1 MG/L 60108 7/3/02 I Lead BQL 0.0050 1 MG/L 60108 7/3/02
Mercury BQL 0.0003 . 1 MG/L 7470 6/25/02
Nickel BQL 0.0400 1 MG/L 60108 7/3/02 I Selenium BOL 0.0100 1 MG/L 60108 7/3/02
Silver BQL 0.0100 1 MG/L 60108 713/0Z'
Thallium BQL 0.0100 1 MG/L 60108 7/3/02 I Zinc BQL 0.0200 1 MG/L 60108 7/3/02
I
Comments
BQL = Below Quantilation Limits I OF= Dilution Factor
J = Between MDL and RL
I
I
I
I
I
I
Reviewed By:~
I
N.C. Certification #481 S.C. Certification #99029 I
I
I
I
•
R
u
n
m
I
I
I
I
I
I
I
I
I
D
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Metals
Client Sample ID: CR-O
Client Project ID: Clari ant
Lab Sample ID: 46856
Lab Project ID: G175-262
Batch ID: 2355 2358
Metals Result Quantitation OF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 7.90
Copper 12.8
Lead 3.56
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc 20.6
Comments
BQL = Below Quantitation Limits
OF= Dilution Factor
J = Between MDL and RL
Limit
8.34 1 MG/KG
1.39 1 MG/KG
1.39 1 MG/KG
1.39 1 MG/KG
1.39 1 MG/KG
2.78 1 MG/KG
0.695 1 MG/KG
0.0301 1 MG/KG
5.56 1 MG/KG
1.39 1 MG/KG
1.39 MG/KG
1.39 MG/KG
2.78 1 MG/KG
Analyzed By:
Date Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Soil
62.01
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02.
7/3/02 ~
7/3/02
7/3/02
Reviewed By: k
PARADIGM ANALYTICAL LABORATORIES, INC.
I Results for Metals
Client Sample ID: DUP-2 Analyzed By: RML I Client Project ID: Clari ant Date Collected: 6/21/02
lab Sample ID: 46857 Date Received: 6/22/02 I lab Project ID: G175-262 Matrix: Water
Batch ID: 2351 2350
I Metals Result Quantitation OF Units Method Date
limit Analyzed I Antimony BQL 0.0600 1 MG/l 6010B 7/3/02
Arsenic BQL 0.0100 1 MG/l 6010B 7/3/02 I Beryllium BQL 0.0100 1 MG/l 6010B 7/3/02
Cadmium BQL 0.0100 1 MG/l 6010B 7/3/02
Chromium BOL 0.0100 1 MG/l 6010B 7/3/02
Copper BQL 0.0200 1 MG/l 6010B 7/3/02 I lead BOL 0.0050 1 MG/l 6010B 7/3/02 Mercury · BQL 0.0003 . 1 MG/l 7470 6/25/02
Nickel BQL 0.0400 1 . MG/l 6010B 7/3/02 I Selenium BQL 0.0100 1 MG/L 6010B 7/3/02 • Silver BQL 0.0100 1 MG/l 6010B 7/3/02
Thallium BQL 0.0100 1 MG/l 6010B 7/3/02 I Zinc BQL 0.0200 1 MG/l 6010B 7/3/02
I
Comments
BQL = Below Ouanlitation limits I DF = Dilution Factor
J = Between MDL and Rl
I
I
I
I
I
I
Reviewed By:l-
I
N.C. Ce11ification #481 S.C. Ccl1ification #99029 I
I
I
R
0
E
I.
I
I
I
I
I
I
I
I
I
I
t'l\.KJ\l.Jl\.,IVI f-\l'll\LI IIL/\L L/\llU.Kf\lUKtr.,~, IJ'i\.,.
Results for Metals
Client Sample ID: DUP-2
Client Project ID: Clariant
Lab Sample ID: 46858
Lab Project ID: 8175-262
Batch ID: 2355 2358
Metals Result Quantitation OF Units
Antimony SOL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium 10.9
Copper 14.0
Lead 6.08
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc 34.4
Comments
BQL = Below Quantitation Limits
OF = Dilution Factor
J = Between MDL and RL
limit
9.58 1 MG/KG
1.60 1 MG/KG
1.60 1 MG/KG
1.60 1 MG/KG
1.60 1 MG/KG
3.19 1 MG/KG
0.798 1 MG/KG
0,0339 . 1 MG/KG
6.38 1 MG/KG
1.60 1 MG/KG
1.60 1 MG/KG
1.60 1 MG/KG
3.19 1 MG/KG
Analyzed By:
Date Collected:
Date Received:
Matrix:
Solids
Method
6010B
6010B
6010B
6010B
60108
60108
60108
7471
6010B
6010B
60108
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Soil
53.10
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02 •
7/3/02
7/3/02
PARADIGM ANALYTICAL LAHUKAIUKlt:~, INC.
Client Sample ID: DUP-3
Client Project ID: Clariant
lab Sample ID: 46859
Lab Project ID:
Batch ID:
G175-262
2351 2350
Results for Metals
Metals Result Quantitation OF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium BQL
Copper BQL
lead BQL
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc BQL
Comments
BQL = Below Quanlitalion Limits
OF= Dilution Factor
J = Between MDL and Rl
Limit
0.0600 1 MG/l
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 . 1 MG/L
0.0100 1 .MG/L
0.0200 1 MG/L
0.0050 1 MG/L
0.0003 . 1 MG/L
0.0400 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0200 1 MG/L
Analyzed By: RML
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: · Waler
Method Date
Analyzed
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02
7470 6/25/02
6010B 7/3/02
6010B 7/3/02
6010B 7/3/02.
6010B 7/3/02
6010B 7/3/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:k_
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
m
I
u
D
I
I
I
I
I
I
I
I
rf\Kf\Ulb!VJ /\.r''I/\LI J IL.AL LI\HUKAlUJ<lt.~, IJ"1L,.
Results for Metals
Client Sample ID: .FB-SW
Client Project ID: Clariant
Lab Sample ID: 46860
Lab Project ID: G175-262
Batch ID: 2352 2350
Metals Result Quantilation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium BQL
Copper BQL
Lead BQL
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium BQL
Zinc BQL
Comments
BQL = Below Quantitation Limits
DF = Dilution Factor
J = Between MDL and RL
Limit
0.0600 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0200 1 MG/L
0.0050 1 MG/L
0.0003 . 1 MG/L
0.0400 1 MG/L
0.0100 1 MG/L
0.0100 MG/L
0.0100 MG/L
0.0200 1 MG/L
Analyzed By:
Date Collected:
Date Received:
Matrix:
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7470
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21102
6/22/02
Water
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
6/25/02
7/3/02
7/3/02
7/3/02 ••
7/3/02
7/3/02
Reviewed By: k
t'AKAUlliM ANALYTICAL LAISUKAIUKtt<,::>, INC.
Results for Metals
Client Sample ID: FB-SD
Client Project ID: Clariant
Lab Sample ID: 46861
Lab Project ID: G175-262
Batch ID: 2352 2350
Metals Result Quantitation DF Units
Antimony BQL
Arsenic BQL
Beryllium BQL
Cadmium BQL
Chromium BQL
Copper BQL
Lead BQL
Mercury BQL
Nickel BQL
Selenium BQL
Silver BQL
Thallium 0.0114
Zinc BQL
Comments
BQL ; Below Quantitalion Limits
DF; Dilution Factor
J ; Between MDL and RL
Limit
0.0600 1 MG/L
0.0100 1 MG/l
0.0100 1 MG/l
0.0100 1 MG/l
0.0100 1 MG/l
0.0200 1 MG/L
0.0050 1 MG/L
0.0003 -1 MG/L
0.0400 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/L
0.0100 1 MG/l
0.0200 1 MG/l
Analyzed By:
Date Collected:
Date Received:
Matrix:
Method
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7470
6010B
6010B
6010B
6010B
6010B
N.C. Certification #481 S.C. Certification #99029
RML
6/21/02
6/22/02
Water
Date
Analyzed
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
7/3/02
6/25/02
7/3/02
7/3/02
7/3/02.
7/3/02
7/3/02
Reviewed By: k
I
I
I
I
I
I
D
B
I
I
I
I
I
I
I
I
I
I
I
iiiiiii"Uiiii' "''iilll-' 1..., L,..IV\.lllll91~. -
2627 Northchase Parkway SE, Wilmington, NC 28405 --I!!!!!!! l!!!!!9 == = ;;;a1 iiiitoclpii,:' .. ; . -
Chain-of Custody Record & Analytical Request
Phone: [phone] FAX: [phone] ·/ or :?----Page~-
Client:
Address: <"' u o 61...,,...., l,'u ~ i? N•
Address: /1.M.l/t l:.1-t t l'<L :z._1.1,\-i:
Quote #· 'i I o ·1 .
Sample ID Date Time
c.. IL-f\'L ,/2.,/,, C'i5'1
C..IL-1\-1.... &/,,1,t OH''1
C{l-f\\ ,,,,1 ... ()C(J2
C(L-rr \ l./t., l~L 0~'JL
(_jl -\31..-'lhl~L-\001
Cll-ffl .... "h., I,, t (} 01
(R-Ot c.j-i., I .1.. \ u1 \
(..(1.-\31 6jJ. ,/-i I 11J L
C{l-c.2-~ ji.,/,, \\:(}"J
C...:CL-c 'L ,1-l-') ,·, I\'. v3
Relinquished By Date
I, /\li--.~2. b\ 1-.\ -
Project ID: Ci..()-(1.,<. t<N ("" Date: ik,) C1-Report To: Jt>i'tN 11 u Yo-?"\.
Contact: j \,) 1-'tt-J ~,c-,.__ Turnaround: ::;,o
Phone: ~ 1o.. 1 ~, -s/;z.v Job Number: S-2. ~-f. -3 '-< 0'1 -s
Fax· '7s--,-s;--pu PO Number· Invoice To·
Preservatives · Analvses Comments:
Please specify any special reporting
{ (. reguirements
Matrix J "I Q \, CI ?_r::;---:: r; z_ v " '.) a ~ '-J ~ -..0 ~ ~ ""' ~ ...... ~ -V.
\,) 3 I '3 \ I
.s I I ' I
.s I I I \
1,-1 -:3 \ '1 \ \
\.J 's l '1 t \
s \ I I \
5 \ I \ I
vJ '] ' J . l I -. . ··-
1,-.l 's \ 1 \ I
..
s: I \ I. \ '
Time Received By Date Time Temperature State Certification Requested .. ·----···· JZ./4,i_ t/2.Z/JL IL I '1 O () . 10: IC) () .·1.,L-_ NC SC Other '
. ------' sr,E Rl:Y[R.':il: l'OI-:
TERMS AND CONDITION.<;
. --·-·· ---· ---· ·-·· --------·---· ......
2627 Northchase Parkway SE W'lmington NC 28405 ' I ' -r a y 1ca equ . Chain of Custody Reco d & An I IR est
LUL/f 1: . , . , , (
Phone: [phone] FAX: [phone] Page 'l ofL
::lien!: CO/'f\. Project ID: (~f)tv~ Date: b It.~ I)"\.. Report To: J. Clo~
\ddress: {,--;,flee Contact: J O\'r,J Gt,'t...'1\... Turnaround: ~:lo-
\ddress: Phone: ~ Job Number: ~U/, -J 'I,:>~'(
2uote #: 'ti 07 Fax: P.O. Number: Invoice To: J-Q-~
. )J''; ,_.>' '. ·, ··. . •·· ·,·;:~ ··,,:·•.;:-!·'-.• . -··. Analvses Comments: · . Preserv11tives.·;-c . . . :; ·. ,\,·{ ~)" '. ~:'._,. Please specify any special reporting . . . ' . . .. ~;.: ' ..... : . '·~ '11,_:~--:~~-;'. i . . i .... : .. reauirements · ..
;'; . Sample ID. .Date· ,Time MaJrix ,J J Gir7s--z 6 .· .-' . -' -" 0 ::,
. -:·:·-_':_:, '-:1_i1_1·.·''·: •i!•:-~ ~t. .(l~l,•~·· V 1 .... .!' ~ (_,, ... ~.y . ?f~·-: 'i'· "t~-'t :·.' ·', 1,,;._ /~ ~ ~ t ' ~-.---L(_-
C.il -c.. \ (,,l2-l)61 \\ '1..l I,) 1, I '] I I
C....ll-C.. 1 , l \2. '-> \ I I I
(_{!_ -f) 11 S 1 v J I :, l I
c.,.(l -~ I(<; 1 > \ I ~ I
Ov-.{) -1--\/J '.1 I ) I I
Pv"i'-2.. -s l I \ \
01AP-3 -vJ 1 \ 'J \ I
(IJ -s...;) 11~-1 w 1 ) 7 \ l
f{3 -So ~ J ~ ) ? \ I JyLp ~a/LL Cttc.itt 1,s-1
---rPi n RlfJ Yr,
I .. I} ;)._ V • {J#. 'TWJ1:/ n /4 h ~
·•: 'Relinquished By Date Time !,leceived By ·' Date Time Temperature State Certificatior0Request6'.......,
'., ,P, ~ 6 /,i_, ~, t .. , u ~~ t,/zz/oz.. /D:fo 0.'1 ·c.. NC SC Other '/ -' . • . I
; SEE REVERSE FOR \,. TERMS AND CONDITIONS -- - - - -----lfl/\1 --------
I
I
I
I
I
D
u
n
D
u
E
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-A2
Client Project ID: Clariant
Lab Sample ID: 46844
Lab Project ID: G175-262
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Parameter Result Quantitation Units Procedure Date
limit Analyzed
TOC 3900 260 mg/kg LYDKHN 7/2/02
Note:
BQL = Below Quantitation Limit
Analysis performed by Kemron. ·
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
PARADIGM ANALYrICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-A1
Client Project ID: Clariant
Lab Sample ID: 46845
Lab Project ID: G 175-262
Parameter Result Quantitation
Limit
TOC 990 300
Note:
BQL = Below Quanlilation Limit
Analysis performed by Kemron.
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Procedure
LYDKHN
Date
Analyzed
7/2/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
I
I
I
I
I
I
I
I
I
B
I
I
I
I
I
I
I
I
I
I
I
I
I
I
U·
D
E.
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-B2
Clienl Project ID: Clariant
Lab Sample ID: 46848
Lab Project ID: G175-262
Parameter Result Quantitation Units
Limit
TOC 11000
Note:
BQL = Below Quantilalion Limit
Analysis performed by Kemron.
330 mg/kg
Analyzed By: Kemron
Date Collected: 6/21/02
Dale Received: 6/22/02
Matrix: Soil
Procedure Date
Analyzed
LYDKHN 7/2/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-B1
Client Project ID: Clariant
Lab Sample ID: 46849
Lab Project ID: G175-262
Analyzed By: Kemron
Date Collected: 6/21 /02
Date Received: 6/22/02
Matrix: Soil
Parameter Result Quantitation Units . Procedure Date
TOC 10000
Note:
BQL = Below Quanlitalion Limit
Analysis performed by Kemron.
Limit Analyzed
380 mg/kg LYDKHN 7/2/02
•
N.C. Certification #481 S.C. Certification #99029 Reviewed By:~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
I
I
I.
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-C2
Client Project ID: Clariant
Lab Sample ID: 46852
Lab Project ID: G175-262
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Parameter Result Quantitation Units Procedure Date
Limit Analyzed
TOC 11000 440 mg/kg LYDKHN 7/2/02
Note:
BQL = Below Quantitation Limit
Analysis performed by Kemron.
N.C. Certification #48 I S.C. Certification #99029
•
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-C1
Client Project ID: Clariant
Lab Sample ID: 46854
Lab Project ID: G175-262
Parameter Result Cluantitation Units
Limit
TOC 5000 320 mg/kg
Note:
BQL = Below Quanlitation Limit
Analysis performed by Kemron.
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Procedure Date
Analyzed
L YDKHN 7/2/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By: k
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
D
u
I
I
I
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYrICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: CR-D
Client Project ID: Clariant
Lab Sample ID: 46856
Lab Project ID: G175-262
Parameter Result Quantitation
Limit
TOC 7700 350
Note:
BQL = Below Quantitalion Limit
Analysis performed by Kemron.
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Procedure
LYDKHN
Date
Analyzed
7/2/02
N .C. Certification #481 S.C. Certification #99029 Reviewed By:~
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for lnorganics
Client Sample ID: DUP-2
Client Project ID: Clariant
Lab Sample ID: 46858
Lab Project ID: G175-262
Parameter Result Quantitation
Limit
TOC 14000 360
Note:
BOL = Below Quanlitalion Limit
· Analysis perfom,ed by Kemron.
Units
mg/kg
Analyzed By: Kemron
Date Collected: 6/21/02
Date Received: 6/22/02
Matrix: Soil
Procedure
LYDKHN
Date
Analyzed
7/2/02
N.C. Certification #481 S.C. Certification #99029 Reviewed By: k
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
.._.. ~,-. ~---"WII~"' ;.,.._:---. tl!l'JI
2627 Northcha~e Parkway SE, Wilmington, NC 28405 -·-·----·== =a Chain-of Custody Record & Analytical Request
.;;a:oClili· ''.-Ii -C ......... .
Phone: [phone] FAX: [phone] Page__,'l_of -:2----
Client: <: D""-Project ID: {,u')-{l,\t<N(°" Date: -'~/_i.._, ~) _c_'L ___ _ J~ 1 'tf'J f1u Y.Y\, Report To: ________ _
Address: <--u" <'>Le\111"1><111 wr Contact: J \) 1,...) ~..;?---Turnaround: _~_r_o _____ _
Address: /!M \fl. b rt t "' (_ '2..1. i, \ 'l.c Phone: 3.10.. 1tJ -s/,'2.v Job Number: S"2S'b-3'Y o'i S"
Quote#; '-/IQ] Fax: tr\ -S-1'10 P.O. Number: _______ _ Invoice To: __ ~ __ € ____ _
Comments:
. Please specify any special reporting
· reouirements
c... ~-l\'L ,/2.i/,i 0'\5'1 3 I 1
CJL-f\-1-t/.,1,t OH''-\ .s \
C/1..-Pt\ ,,,,,.,.
0'( J 2. .s I I l l
ca. -A-\ <./ l\ /~1.. O~:lL t,J '.3 \ \
Cit -\31-'/.,/~1..-lOO'.l w '? l 1
C...(l-tl"1... <.. ].., 1 .. 1001 \ I \
(R-0\ <-11-, I .-i.. ~~'.I' s \ I I
C(l-0\ 1,,jJ_,/,1 \ s:il l vJ '3 ' J \
C{l-c.i... ~ )i.,/ \\ \ 1:0'.} vJ 's I 1 \
<...:(L -<. "L ,1-p),, 1\1.vJ I \ \ '
1---------------+---'---,------~--'---''---'----1--'---+--'---t---'---+--"--'---+-~-------------·· ..
Relinquished By Date Time Received By Date Time Temperature State Certincation Requested t--.fr-t-"?'s----'----+----;--irl---+--"T71~::-:------'-----t-....,.--,,----t----t---'----+-----------------·--
1, Al,"':') 6(1.\ ti \I.too JZ /1A · /1/li/.Jz. 10:10 O .,~G · 1 I. "I~ vi< NC . SC ____ 011cr __
, SEE REVERSE FOR
TERMS AND CONDITIONS
.. ~ ..... 'V-a.&Ji.'-..Jt,.a. ~1 ~r1.&..J& & .a.v.t"'-A.J ...... nuv~.lV.l"\...lr....:,, J.J."111'-..,. '·1 (
2627 Northchase Parkway SE, Wilmington, NC 28405
Phone: [phone] FAX: [phone]
Chain-of Custody Record & Analytical Request
COC# c: .. 1 .,,~ I
Client: c_ 0t(',.
Address: ~ .. ~ d\l"'
Address:
Quote#: l.fto,
.. ,, r: .,-
·:..,-,_-i.,t,·' . .-.-.,,,-. _, ,.:
(.tl..-<..\ 1.l2.~)~
C(l-l..)
(_(L -C)
c_(l -~
OlA-<> -'2-
P11-...{'-'L
(h ..... P-3
~G-Sw?
f{3 -So
Project ID: (~r,,v~
Contact: j O\'r,J {3,t, 'I,()\__
Phone: A f.
Fal(: . ~
. >"·' PreserYaties .,,,,_._._., ••... ,_,1.,, .¥.,
..J i
" 0 .::, V 1 .... r-~ ~ ~ __ ,_,;
\\ 't.1 \,) 1 ' .
'J
I \1. 't. >
\I~ 1 v J :, \
ll ,1 ~ I I
~ 'J. l ;,
s l -vJ '1 \ 'J \
/1~1 w lo 7
I \~l J !) ) 7 \
Date
6 1.. \ ,1 I«• u
Page '1 ofL---
Date: b h .. 0, I:)'\.. Report To: .J · \)'-''-kl-.._
Turnaround: ~1:o.
Job Number: ~U-/,-J'I v ~~
P.O. Number: Invoice To: J • Q.~
I -.l
~ ~
\
\
· Date Time Temperature
t,,/zz/o /or10 0.t"C..... NC __ SC __ Other __
SEE REVERSE FOR
TERMS AND CONDITIONS
I
I
I
I
I
0
m
•
I
I
I
I
I
I
I
I
.1
I
I
Attachment 2
Case Narrative from Paradigm Analytical
Laboratories, Inc.
P:\Clariant • 5256\Sed Sampling & Well Survey 34095\Reports\kpS-16-02.doc
I
I
I
I
B
0
I
I
I
I
I
.I
I
I
I
I
I
I
PARADIGM ANALYfICAL LABORATORIES, INC.
Date: July 22, 2002
Paradigm project ID: GI 75-262
COM ID: Clariant
CASE NARRATIVE
Twenty samples of water and soil were received at Paaradigm Analytical on June 21,
2002 for analyses as indicated on the chain of custody. The samples were received in·
lemperatme and holding time protocols. All analyses were completed in holding time and
without quality control exceptions.
Toluene was detected in many of the water samples below 5 ug/L. S;nnples reported as
Below Quant ital ion Limit (BQL) for toluene actually had hits just below the reporting
limit. Even the trip blank sent with this project showed a low-level hit for toluene.
The laboratory believes toluene was in the sample vials as provided by the manufacturer,
Eagle-Picher Environmental Services. Eagle-Picher prepares the sample containers from
pre-cleaned materials and adds the preservative before closing and shipping the vials. The
vials arc not opened until the sampler fills them in the field.
Toluene hits reported below 5 ug/L may have been introduced by the vial manufacturer.
For this reason, low-level toluene data should be used cautiously.
N .C. Certification #481 S.C. Certification #99029
I
I
I
D
I
I
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYflCAL LABORATORIES, INC.
Client Sample ID: Trip Blanks
Client Project ID: Clarianl
lab Sample ID: 46862
lab Project ID: G175-262
Matrix: Water
Compound
Acetone
Acrolein
Acrylonitrile
Benzene
Bromobenzene
Brornochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone
n-Butylbenzene
sec-Bulylbenzene
tcrl-Bulylbenzene
C;:ubon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethyl vinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotolucne
Dibromochlororncthanc
1,2-Dibromo-3-ctiloropropanc
Dibromornethane
1,2-Dibromoelhane (EDB)
1,2-Dichloro!Jenzene
1.3-Dichlorobenzene
1,4-Oichlorobenzene
trans-1,4-Dichloro-2-butene
1 , 1-Dichloroethane
1, 1-Dichloroethene
1,2-Dichloroethane
cis-1,2-Dichloroethene
lrans-1,2-dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1, 1-Dichloropropene
cis-1,3-Dichloropropene
lrans-1,3-Dichloropropene
Dichlorodifluoromethane
Diisopropyl ethe.r (DIPE)
Elhylbenzene
Hcx;:,chlorobuladiene
Results for Volatiles
by GCMS 82608
Ouantitation
limit (ug/l)
25
100
100
1
1
25
5
5
1
5
1
1
1
5
1
1
Dale Analyzed: 7 /1 /02
Analyzed By: RNP
Dale Collected: 6/21/02
Dale Received: 6/22/02
Dilution: 1
Result
(ug/L)
BQl
BOl
BQl
BQl
BQl
BOL
BQl
BOl
BQl
BOl
BOl
BQl
BQl
BQl
BQl
BOl
BOl
BQl
BQl
BQl
BOl
BOL
BOl
BOl
BOl
BOl
BQl
BOl
BOl
BOl
BOl
BOl
BOl
BOl
BOl
BOl
BQl
BQl
BOl
BOl
BQl
BOl
BOL
BOl
BOl
Flags: BQl = Below OuanlilW.C:~r:i!rtification #481 S.C. Certification #99029
Reviewed by:k
Page 1 of 2
I
I
D
R
I
I
I
I
I
I
I
I
I
I
I
I
I
PARADIGM ANALYTICAL LABORATORIES, INC.
Results for Volatiles
by GCMS 82608
Clienl Sample .ID: Trip Blanks Date Analyzed: 7/1/02
Client Project ID: Clariant Analyzed By: RNP
Lab Sample ID: 46862 Date Collected: 6/21/02
Lab Project ID: G175-262 Date Received: 6/22/02
Matrix: Water Dilution: 1
Compound Quantitation Result
Limit (ug/L) (ug/L)
2-Hexanone .5 BQL
lodomethane BQL
lsopropylbenzene BQL
4-lsopropylloluene 1 BQL
Methylene chloride 5 BQL
4-Methyl-2-pentanone 5 BQL
Methyl-tert-butyl ether (MTBE) 1 BQL
Naphlhalene BQL
n-Propyl benzene 1 BQL
Styrene 1 BQL
1 ,.1, 1,2-Tetrachloroethane 1 BQL
1, 1 ,2 .2-T etrachloroethane 1 BQL
T etrachloroethene BQL
Toluene 2
1,2,3-Trichlorobenzene
1.2,4•Trichlorobenzene
Trichloroethene
1, 1, 1-Trichloroethane
1, 1,2•Trichloroethane
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m-,p-Xylene
o-Xylene
Surrogate Spike Recoveries
Compound
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-dB
Comments:
All results are correcled for dilution.
Flags: BOL = Below Ouantitatioll-lil)ljt .fi· -#4S I N.L. Lert1 1cat10n
BQL
1 BQL
1 BQL
BQL
1 BQL
1 BOL
BQL
1 BOL
BQL
1 BQL
2 BQL
BQL
Spike Surrogate
Added Result %Rec
(ug/L) (ug/L)
10 10.2 102
10 10.7 107
10 9.9 99
Reviewed by: L
S.C. Certification #99029 Page 2 of 2