NCD001810365_19980112_Martin-Marietta Sodyeco Inc. (Clariant)_FRBCERLA SAP QAPP_Sandoz Chemical Analytical Results-OCR

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I MARTIN MARIETTA -SODYECO JANURAY 19BB
SANDZO CHB1ICAL CORPORTATION
I ANALYTICAL RESULTS
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_r .•.• -· -" ·?·•··· • ·a.January L, 1988
Mr. Bill Archer
Sandoz Chemical Corporation
PO Box 669246
Charlotte, North Carolina 28266
Dear Mr. Archer:
GENERAL ENGINEERING LABORATORIES
1313 As.hley River Road P.O. Box 30712
Charleston, S.C. 29407 Charleston, S.C. 29417
Phone [phone]
Please find enclosed herewith the Appendix IX Analytical Results for the following wells at your Charlotte, North Carolina Facility:
• C-_2-!A
• WQ-5AI
• WQ-6·
• WQ-32-I
The Quality Control data for these samples has: :,o '.Jern 'nclude:1 in your report. There is a section in the report that explains the QA/QC procedures that are used by General Engineering Laboratories. In the instances' where percent recoveries are low for spiked samples, the results have been confirmed by duplicate analysis. When low percent recoveries are documented in two consecutive analyses, it is assumed that there is a matrix interference causing the problem. ·
There is a section in the report that gives an overview of the analytical methodolc :;ies that are used in Appendix IX testing. As a general rule, the EPA Solid and Hazardous Waste Methodologies SW-846 are used for, the analytical procedures. There are instances where the Fedenl Rei::ister, 40 CFR, Part I 36, the EPA 600-Series Methodologies, and Standard Methoc'.s for the Analysis of Water and Wastewater, 16th Edition, are used for analytical and quality control procedures. ·
If you hQve any questions concerning,these data or the methdologies, please do not hesitate to call me at [phone]. We look forward to worki1,g with you on future projects.
enclosures
fc:sndc0l 1288
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SECTION I.
SECTION 2.
SECTION 3.
SECTION 4.
SECTION 5.
TAilLE OF CONTENTS
APPEND1X IX ANALYTICAL PROCEDURES
APPEND TX IX ANALYTICAL RESULTS
EXPLANATION FOR QUALITY CONTROL DATA
QUALITY CONTROL RESULTS
CHAIN OF CUSTODY DOcm-mNT A TION
tENERAL ENGINEERING LAllORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803) 55/i-~:71
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' Appendix IX Procedures
January 12, 1988
•,
General Engineering Laboratories
Page 1
APPENDIX IX ANALYTICAL PROCEDURES
EPA Manual Sw-846 "Test Methods for Evaluating Solid Waste" discusses the preferred analytical procedures for determining Appendix IX parameters. The SW-846 manual does not, however, provide specific details for the full Appendix IX Analysis. Therefore we have developed an Appendix IX test program which utilizes the best analytical procedures currently available to provide the most reliable data and the lowest possible detection limit. This program is based on experience gained through conversations with EPA personnel and other environmental laboratories involved in Appendix IX testing, EPA sponsored seminars on Appendix IX testing, and review of limited recovery data developed in our laboratory. The compounds are divided into seven groups as described below:
Group 1: Metals
Metals analyses are carried out according to the procedures dc:scribed in SW-846 Method 6010. The EPA publication "Methods for Chemical Analysis of Water and Wastes," EPA-600/4-79-020, March 1979, is also used in these analyses. With the exception of Arsenic, Selenium, and Mercury, all analyses are done by Inductively Coupled Plasma (TCP). Arsenic and Selenium are analyzed by Zeeman Furnace and Mercury is analyzed by Cold Vapor. The Mercury procedure is described in SW-846 Method 7470.
Group 2: General Chemistry Parameters
SW-846 Method 9010 is used to analyze Appendix IX samples for total cyanide. The sulfides analysis is performed according to Method 9030.
Group 3: Base/Neutral Extractable Compounds
SW-846 Method 3510 is used for the extraction of both Acid and Base/Neutral Organic ~om pounds from the water matrix. One liter of the sample is adjusted to pH greater than 11 m a separatory funnel and extracted thr-:e times with r.ie:.hylene chloride. The e:,tract volumes are concentrated by Kudema-Danish cc :centration techniques and reconstituted to a known volume before analysis. The concentrat-~d extracts may then be combined with the concentrated Acid fraction, described below, and analyzed by Gas Chromatography/Mass Spectrometry (GC/MS) procedures as described in SW-846 lvfe:.hod 8270. SW-846 Method 3050 is used for the sonication extracarion of acid and base/neutral or::;:-nic compounds from the sludge or solid matrix. Approximately 30 grams of sample are sonically extracted with a 50:50 mixture of methylene chloride and acetone. Each sample is sonicated three separate times. The extract volumes are concentrated by Kudema-Danish concentration techniques and reconstituted to a known volume before analysis. The concentrated extract is then analyzed by Gas Chromatography/Mass Spectrometry (GC/MS) procedures as described:in SW-846 Method 8270.
' Group 4: Acid Extractable Compounds
As noted above SW-846 Method 3510 is also used for the extraction of the Acid Extractable Organic Compounds from the water matrix. Following the extraction of the Base/Neutral Compounds, the pH of the sample is adjusted to less than 2 and again extracted three times with methylene chloride. The extract volumes are concentrated by Kudema-Danish concentration techniques and are reconstituted to a known volume before
~•ERAL ENGINEERING LABORATORIES • 1313 Ashley. River Rd • Charleston, SC 29407 • (803) 556 .:, I 7 I
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Appendix IX Procedures
Ja~uary 12, 19.88
General Engineering Laboratories
Page 2
analysis. The concentrated extract may then be combined with the concentrated Base/Neutral fraction and analyzed by Gas Chromatography/Mass Spectrometry (GCflvIS) procedures as described in SW-846 Method 8270.
The extraction of acid extractables from the solid matrix is performed as described above in the base/neutral procedure. There is no pH adjustment for the base/neutral or acid extraction for solid samples.
Group 5: Pesticides and Herbicides
Gas Chromatography (GC) techniques are used to analyze the sample for organochlorine pesticides. organophosphorus pesticides, and herbicides. SW-846 Methods 8080, 8140, and 3150 are followed for these analyses. The EPA "Manual of Analytical Methods for the Analysis of Pesticides in Humans and Environmental Samples," June 1980, is also referenced for these analytical methods. The pesticide method for a liquid sample requires three extractions of a one-liter sample with methylene chloride. The extract is concentrated by Kuderna-Danish concentration techniques and reconstituted to a known volume before analysis. The herbicide method calls for three extractions of one liter of an acidified sample with diethyl ether. The extracted herbicide compounds are hydrolyzed to acids with aqueous Potassium Hydroxide. The acid forms of the herbicides partition to the aqueous phase and are themreextracted with two volumes of diethyl ether. The extract volumes are concentrated by Kuderna-Danish concentration techniques and reconstituted to a known volume. The acids are reconverted to methyl esters which are· then extracted from the water with benzene. Detection and quantitation of the compounds is made by selective gas chromatographic separations using a 63Ni electron capture detector.
The extraction for organochlorine pesticides and organophosphorus pesticides from a solid matrix is performed usir,g the SW-846 Method 3550 Sonication method. The extracts are concentrated by Kuderna-Danish concentration techniques and reconstituted to a known volume before analysis. The instrumental analysis for the solid extract is the same as for the liquid extract.
Group 6: Volatile Ori:anic Compounds
The purge and trap procedure described'in SW-846 Method 5030 is used for the sample introduction of volatile halocarbons and volatile aromatics. A twenty-five r:.illiliter aliquot oi the sample is placed in a specially-designed purge vessel at ambient temperature. The vessel is sealed and an inert purge gas (Helium) is pass.ed through the vessel. The vessel is designed to insure that the volatile halocarbons and aromatics are efficiently transferred from the aqueous phase to the vapor phase. 'The purge gas flows from the purge vessel through an adsorbent bed where the volatiles are adsorbed. After purging is completed, the trap is heated and backflushed with the inert gas to desorb the compounds and transfer them onto the gas chromatogaph column. The GC is temperature programmed to separate the volatile organic compounds, which are then detected by the mass spectrometer. The analytical techniques for volatile organic compounds are described is SW-846 Mehods 8010, 8015, 8020, and 8030.
In the analysis of solid samples for volatile organic compounds, a known amount of sample is weighed and extracted with a knov.in amound of methanol. This methanol is then diluted with deionized water and purged via the purge and trap system of the mass spectrometer.
IGE:-IERAL ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29~07 • [phone]
,m GENERAL ENGINEERING LABORATORIES
Engil'leering 'Consulting
.Chemical Analysis
Laboratory Certification Number 10120
1313 Ashley River Road
Charleston, S.C. 29407
CLIENT: SANDOZ CH81ICALS CORPORATION
PO BOX 669246
CHARLOTTE
CCNTACT: MR. BILL ARCHER
CC/FC: SNDC/APP9
, NC 28266
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
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------------------------------------,-------------------------------------------
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PARAMETER
SAMPLE ID
LAB ID
SAMPLE TYPE
DATE RECEIVED:
COLLECTED BY 1
C-2-1.A WQ-5A I
13.5'-15' 12/08/87
87120314
15
12/09/87
SNDC i
87120315
11
12/09/87
SNOC
WQ-6
12/08/87
87120316
11
12/09/87
-SNOC
WQ-32-1
12/09/87
87120372
I I
12/10/87
SNDC
------------------------------------------··-------------------------------------
CYANIDE
SULFIDE
APPENDIX IX -METALS
P«TIMCNY
ARSENIC.
BARI LN
BERYLLILN
CADMI l.t1
CHROH!lt!
COBALT
COPPER
LEAD
MERCURY
NICKEL
SELENILN
SILVER
THALLIUM
TIN
VANADIUM
ZINC
APPENDIX IX -VOLATILES
ACETONE
AC ETON !TR I LE
ACROLEIN
ACRYLONITR I LE
ALLYL CHLORIDE
BENZENE
BIS(2-CHLOROHETHYLETHYL)ETHER
BROMODICHLOROMETHANE
BROMOFORM
CARBON DISULFIDE
CARBON TETRACHLORIDE
CHLOROBENZENE
CHLOROETHANE
{0,1 ppm
< 0. 1 ppm
<0,10 ppm
0,88 ppm
147 ppm
<0,20 ppm
(0.20 ppm
9.28.ppm
3.86 pi;m
8,96 ppm
21 ,8 ppm
I • 4 p',pm
5.51 ppm
I ,57 ppm
{1.00 ppm
<0,10' ppm
<0,10 ppm
14,2 ppm
37.9 ppm
<1000,ppb
<1000 ppb
<1000 ppb
<1000 ppb
<1000 ppb
<500 ppb
<IOOO'ppb
<1000 ppb
<1000 ppb
<1000 ppb
< 1000 'ppb
<1000 1ppb
<1000 ppb
<O,I ppm
<O, I ppm
<0,005 ppm
<0.005 ppm
0.15 ppm
<0.010 ppm
<0.010 ppm
<0.05 ppm
<0.05 ppm
<0.05 ppm
0 .020 ppm
0.0006 ppm
<0.05 ppm
<0.005 ppm
(0,05 ppm
<0,005 ppm
<O, 10 ppm
<0,05 ppm
0.17 ppm
(40 ppb
{40 ppb
(40 ppb
<40 ppb
<40 ppb
<20 ppb
{40 ppb
<40 ppb
<40 ppb
<40 ppb
<40 ppb
556 ppb
(40 ppb
(0,1 ppm
(0,1 ppm
<0.005 ppm
<0.005 ppm
I .46 ppm
<0.010 ppm
<0.010 ppm
0,20 ppm
<0.05 ppm
0. I 4 ppm
0.019 ppm
<O .5 ppb
0,15 ppm
<0.005 ppm
<0.05 ppm
<0.005 ppm
<0.10 ppm
0. I 5 ppm
0.17 ppm
(100 ppb
(100 ppb
<100 ppb
(100 ppb
(100 ppb
(50 ppb
<100 ppb
<100 ppb
<I 00 ppb
<100 ppb
(100 ppb
(100 ppb
<100 ppb
< u • I ppm
<O.I ppm
<0.005 ppm
<0.005 ppm
<0.10 ppm
<0.010 ppm
<0.010 ppm
<0.05 ppm
<0.05 ppm
<0.05 ppm
0.008 ppm
<0.5 ;,pb
<0.05 ppm
<0.005 ppm
<0,05 ppm
(0,005 ppm
(0,10 ppm
<0,05 ppm
(0,05 ppm
(1000 ppb
<1000 ppb
<1000 ppb
<1000 ppb
(1000 ppb
<500 ppb
<1000 ppb
<1000 ppb
<1000 ppb
{1000 ppb
{1000 ppb
10200 ppb
{1000 ppb
~ GENE~AL ENGINEERING LABORATORIES -.
' ' !~: ►• 1313 Ashley River Road P_Q. Box 30712
Charleston, S.C. 29407 Charleston, S.C. 294 I 7
. 1,eering Consulting Phone [phone]
\ ical Analysis
1boratory Certification Number 10120
I CLIENT: SANDOZ CHEMICALS CORPORATION
~ONTACT1
PO BOX 669246 DATE: 01/ 12/B8
CHARLOTTE , NC 28266
HR, BILL ARCHER
IC/FC: SNC•C/APP9 , PAGE NO, : 2
-------------------------------------------------------------------------------
SAMPLE ID C-2-IA WQ-5Al lJQ-6 WQ-32-1 I 13,5'-15'' 12/08/87 12/08/87 12/09/87
LAB 10 87120314 · 87120315 87120316 · 87120372 I "bATE RECEIVED: 12/09/87 12/09/87 12/09/87 12/10/87
-------------------------------------------------------------------------------
~HLOROFORl1 7320 ppb: (40 ppb < I 00 ppb (1000 ppb
HLOROPREtiE <1000 ppb (40 ppb (100 ppb (1000 ppb
IBROMOCHLOROMETHANE (1000 ppb (40 ppb < I 00 ppb < I 000 ppb
l,2-0IBR0/10-3-CHLOROPROPANE <1000 ppb (40 ppb (100 ppb (1000 ppb
12-0 I BROMOE: THANE (1000 ppb (40 ppb (100 ppb <1000 ppb
RANS-I ,4-DICHLOR0-2-BUTENE <1000 ppb (40 ppb < I 00 ppb (1000 ppb
01 CHLOROD I FLUOROt1ETHANE <1000 ppb (40 ppb < I 00 ppb <1000 ppb
• , I-DI CHLDROETHANE (1000 ppb (40 ppb < I 00 ppb (1000 ppb
1 2-D!CHLOROETHANE <1000 ppb <40 ppb < I 00 ppb <1000 ppb
1,1-DICHLOROETHYLENE <1000 ppb (40 ppb {100 ppb (1000 ppb
IRANS-1,2-DICHLOROETHYLENE {1000 ppb (40 ppb < I 00 ppb (1000 ppb
,2-DICHLOROPROPANE <1000 ppb (40 ppb < I 00 ppb < I 000 Hb C!S-1 13-DICHLOROPROPENE (1000 ppb (40 ppb < I 00 ppb < I 000 ppb
(RANS-I 1 3-011:HLOROPROPENE <1000 ppb (40 ppb (100 ppb < I 000 ppb
1 4-DIOXANE (1000 ppb (40 ppb (100 ppb (1000 ppb
TH':'L BENZ EtlE 6840. ppb (40 ppb (100 ppb (1000 ppb (H'I'l.. HETn,\CRYLATE (1000 ppb (40 ppb < I 00 ppb (1000 ppb
HEXANONE (1000 ppb (40 ppb < I 00 ppb (1000 ppb
SOBUTYL ALCOHOL <1000 ppb (40 ppb < I 00 ppb (1000 ppb
HETHACRYLONITRI LE <1000 ppb (40 ppb < I 00 ppb < I 000 ppb
IETHYL BROMIDE (1000 ppb (40 ppb (100 ppb (1000 ppb
ETHYL CHLORIDE <1000 ppb {40 ppb (100 ppb {1000 ppb
METHYLENE BROM I DE ' (1000 ppb (40 ppb (100 ppb {1000 ppb
*ETHYLENE CHLORIDE <1000 ppb (40 ppb <100 ppb (1000 ppb
ETHYL ETHYL KETONE (1000 ppb (40 ppb (100 ppb {1000 ppb
ETHYL I OD I DE <1000 ppb {40 ppb {100 ppb < I 000 ppb
METH'('. HETHACRYLATE (1000 ppb (40 ppb < I 00 ppb < I 000 ppb
,-METHYL-2-PENTANONE (1000 ppb (40 ppb (100 ppb <1000 ppb
ROPIONITRILE <1000 ppb <40 .ppb < I 00 ppb <1000 ppb
PYRIDINE <1000 ppb (40 ppb <100 ppb < I 000 ppb
ITYRENE <I 000 ppb (40 ppb (100 ppb < I 000 ppb
,I 1 112-TETRACHLOROETHANE <1000 ppb (40 ppb <100 ppb (1000 ppb
I 11 1 212-TETRACHLOROETHANE <1000 ppb (40 ppb 4030 ppb (1000 ppb
-ETRACHLOROETHYLENE (1000 ppb (40 ppb (100 ppb < I 000 ppb
OLUENE 1880 ppb {40 ppb (100 ppb (1000 ppb
,I ,I-TRICHLOROETHANE <1000 ppb (40 ppb (100 ppb (1000 ppb
I
GENERAL ENGINEERING LABORATORIES
1313 Ashley River Road P.O. Box 30712
Engineering Consulting
remical Analysis
Charleston, S.C. 29407 Charleston, S.C. 29417
Phone [phone]
Laboratory Certification Number 10120
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CLIENT: SANDOZ CHEMICALS CORPORATION',
PO BOX 669246
CHARLOTTE , NC 2B266 CCt,fTACT: HR. BILL ARCHER
DATE: 01/12/88
CC/FC1 SNDC/APP9 PAGE NO.: 3 ______________________________________ ( -----------------------------------------
SAMPLE ID 1 C-2-IA WG-5AI
13.5'--15' 12/08/87
LAB ID 1 87 I 20 3 I 4 87120315
12/09/87 ·' DATE RECEIVED: 12/09/87
WG-6
12/08/87
87120316
12/09/87
WG-32-I
12/09/87
87120372
12/1 J/87 --------------------------------------------------------------------------------
1,1 ,2-TRICHLOROETHANE <1000 ppb (40 ppb (100 ppb (1000 ppb TRICHLOROETHYLENE <1000 ppb (40 ppb < 1 00 ppb < 1000 ppb TRICHLOROFLUORONETHPt-lE (1000 ppb (40 ppb <100 ppb <1000 ppb 1,2,3-TRICHLOROPROPPl'~E < I 000: ppb (40 ppb (100 ppb (1000 ppb VINYL ACETATE <1000 ppb (40 ppb (100 ppb (1000 ppb VINYL CHLORIDE <1000 ppb (40 ppb (100 ppb < I 000 ppb XYLENE <TOTAL> 199000 ppb 852 ppb . ' APPENDIX. IX -PESTICIDES (100 ppb <1000 ppb
ALDRIN <io ppb (10 ppb (10 ppb < 10 ppb ALPHA-BHC (10 ppb < I 0 ppb < I 0 ppb (10 ppb BETA-BHC <IO ppb (10 ppb <IO ppb < I 0 ppb DELTA-BHC (10 ppb <IO ppb (10 ppb < I 0 ppb GAl1NA-BHC < I 0 ppb < I 0 ppb (10 ppb (10 ppb CHLORDANE (10 ppb (10 ppb < 10 ppb (10 ppb 2,4-0 (10 ppb (10 ppb (10 ppb (10 ppb 4-4'-DDD (10 ppb (10 ppb (I 0 ppb < I 0 npb 4,4'-DDE (10 ppb (10 ppb < l 0 ppb (I 0 ppb 4 14'-DDT (10 ppb < I 0 ppb (10 ppb <10 ppb DIELDRIN (10 ppb <IO ppb < I 0 ppb < 1 0 ppb ENDOSULFAN I < I 0 ppb < I 0 ppb < I 0 ppb (10 ppb ENDOSULFAN I I <IO ppb < I 0 ppb (10 ppb (10 ppb ENDOSULFAN SULFATE <IO pµb (10 ppb (10 ppb < I 0 ppb ENDRIN <IO ppb (10 ppb (10 ppb <10 ppb ENDRIN ALDEHYDE <IO ppb <IO ppb < I 0 ppb < I 0 ppb HEPTACHLOR <10 pp:b (10 ppb (10 ppb (10 ppb HEPTACHLOR EPOXIDE <10 ppb <IO ppb (10 ppb (10 ppb METHOXYCHLOR <IO ppb <IO ppb < I 0 ppb < I 0 ppb METHYL PARATHION <IO ppb <IO ppb <IO ppb (10 ppb PARATHICN <IO ppb (10 ppb (10 ppb <10 ppb PCB 1016 (150 ppb <150ppb <150 ppb (150 ppb PCB 1221 <150 ppb <150 ppb <150 ppb <150 ppb PCB 1232 <150 ppb (150 ppb (150 ppb <150 ppb PCB 1242 <150 ppb <150 ppb <150 ppb <150 ppb PCB 1248 (150 ppb <150 ppb <150 ppb <150 ppb PCB 1254 (150 ppb (150 ppb <150 ppb (150 ppb PCB 1260 (150 ppb <150 ppb <150 ppb <150 ppb
ffl . .
• GENERAL ENGINEERING LABORATORIES -~ gineering Consulting
lhemical Analysis
Laboratory Certification Number
I
10120
1313 Ashley River Road
Charleston, S.C. 29407
CLIENT: SANDOZ CH811CALS CORPORATICt-1
PO BOX 669246
CHARLOTTE , NC 28266
CCt-lTACT: HR. BILL ARCHER
CC/FC: SNDC/APP9
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
D,;TE t O 1/12/88
PAGE NO.: 4
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SAMPLE ID 1 C-2-lA WQ-5AI
13,5'-15' 12/08/87
LAB ID 87120314
DATE RECEIVED: 12/09)87
87120315
12/09/87
WQ-6
12/08/87
87120316.
12/09/87
WQ-32-1
12/09/87
87120372
12/10/87
--------------------------------------------------------------------------------
PCB 1262
SI LVEX
2,4,5-T
TOXAPHENE
APPENDIX IX -BIN COMPOiJ'IDS
ACENAPHTHENE
ACENAPHTHYLENE
ACE,OPHENONE
2-ACETYLAHINOFLUORENE
4-AHINOBI PHENYL
ANILINE
ANTHRACENE
ARAHITE
BENZ O(A)ANTHR,,CENE
BENZO(B)FLUORANTHENE
BENZO<K)FLUORANTHENE
BENZO<SHl>PERYLENE
BENZO(A)PYRENE
BENZYL ALCOHOL
BIS<2-CHLOROETHOXY>ETHER
BIS(2-CHLOROETHYL)ETHER
BIS<2-ETHYLHEXYL)PHTHALATE
4-8ROHOPHENYL PHENYL ETHER
BUTYL BENZYL PHTHALATE
P-CHLOROAN I LINE
CHLOROBENZILATE
2-CHLORONAPHTHALENE
4-CHLOROPHENYL PHENYL ETHER
CHRYSENE
DIALLATE
DIBENZ<AH)ANTHRACENE
DIBENZOFURAN
DI -N-BUTYL PHTHALATE
0-DICHLOROBENZENE
H-DICHLOROBENZENE
P-DICHLOROBENZENE
<150 ppb
<10 p'.pb
(10 ppb
<10 ppb
8430 lppb
(330 ppb
. <330 ppb
<330 ppb
<330 ;ppb
(330 'ppb
6290 ppb
(330 ppb
<330 :ppb
<330 ppb
(330 ppb
(330 ppb
(330 ppb .
<330 ppb
(330 ppb
(330 ppb
324 ppb
(330 ppb
<330 ppb
1100 ppb
<330 ppb
<330 ,ppb
(330 'ppb
1100 ppb
(330 ppb
(330 ppb
10600 ppb
649 ppb
I 060 ppb
(330 ppb
(330 ;ppb
<150 ppb
<IO ppb
<IO ppb
<IO ppb
<IO ppb
(10 ppb
<IO ppb
(10 ppb
(10 ppb
<IO ppb
<IO ppb
<IO ppb
<IO ppb
(10 ppb
<10 ppb
<10 ppb
<IO ppb
<10 ppb
< 10 ppb
<10 ppb
<IO ppb
<IO ppb
<10 ppb
<IO ppb
(10 ppb
<IO ppb
<IO ppb
<10 ppb
<IO ppb
< 10 ppb
(10 ppb
<10 ppb
300 ppb
12 ppb
34 ppb
<150 ppb
(10 ppb
<10 ppb
<10 ppb
<10 ppb
<10 ppb
<10 ppb
(10 ppb
<10 ppb
(10 ppb
<IO ppb
(10 ppb
<10 ppb
<10 ppb
<10 ppb
<IO ppb
<IO ppb
(10 ppb
(10 ppb
<IO ppb
(10 ppb
(10 ppb
<10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
<10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
<IO pp b
(150 ppb
<IO ppb
(10 ppb
<IO ppb
<10 ppb
(10 ppb
<10 ppb
<IO ppb
<IO ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
(10 ppb
<IO ppb
(10 ppb
(10 ppb
<IO ppb
(10 ppb
20 ppb
(10 ppb
<IO ppb
(10 ppb
(10 ppb
(10 ppb
(IO ppb
<IO ppb
<10 ppb
2300 ppb
40 ppb
216 ppb
~ GENERAL ENGINEERING LABORATORIES
1313 Ashley River Road P.O. Box 30712 ..... Charleston, S.C. 29407 Charleston, S.C. 294 I 7
' Phone [phone] :nf eering Consulting :h ical Analysis
.aboratory Certification Number 10120
I
CL! ENT: SANDOZ CHEMICALS CORPORATION
ICCNTACT:
PO BOX 669246 DATE 1 01/12/88
CHARLOTTE , NC 28266
HR, BILL ARCHER
I CC/FC: SNDC/APP9 PAGE NO, : 5
--------------------------------------------------------------------------------
SAMPLE ID C-2-IA WQ-5AI WQ-6 WQ-32-1
I 13,5'-15' 12/08/87 12/08/87 12/09/87
, LAB ID 87120314 87120315 87120316 87120372 ·' I DATE RECEIVED: 12/09/87 12/09/87 12/09/87 12./10/87
----------------------------------------:---------------------------------------
.3,3'-DICHLOROBENZIDINE (330 ppb < 10 ppb < I 0 ppb < 10 ppb
DIETHYL PHTHALATE (330 ppb < I 0 ppb < I 0 ppb (10 ppb
THIONAZ IN (330 ppb ( 10 ppb < I 0 ppb (10 ppb
DIHETHOATE . (330 ppb (10 ppb (10 ppb < I 0 ppb
IP-( DIMETHYLAHINOJAZOBENZENE (330 ppb_ < 10 ppb (10 ppb ( I 0 ppb
7, 12-DIMETHYLBENZ<AlANTHRACENE (330 ppb < I 0 ppb (10 ppb (10 ppb
3, 3' -DIMETHYLBENZ ID !ME (330 ppb (10 ppb < I 0 ppb (10 ppb I a, a-DIMETHYLPHENETHYU'J'1INE (330 ppb (10 ppb < 10 ppb ( I 0 ppb
DIMETHYL PHTHALATE (330 ppb < I 0 ppb (10 ppb (10 ppb
M-DINITROBENZENE (330 ppb, < I 0 ppb ( I 0 ppb < 10 ppb 12, 4-DINITROTOLUENE (330 ppb < 10 ppb · < 10 ppb < I 0 ppb
2, 6-DINITROTOLUENE (330 ppb' ( 10 ppb < I 0 ppb ( I 0 ppb
DI -N-OCTYL PHTHALATE (330 ppb' (10 ppb (10 ppb < 10 ppb
DIPHENYLAMINE · (330 ppb! < 10 ppb < 10 ppb < 10 ppb I DISULFOTON (330 ppb (10 ppb (10 ppb ( I 0 ppb
ETHYL HETHANESULFONATE (330 ppb. (10 ppb (10 ppb < 10 ppb
FAMPHUR (330 ppb (10 ppb (10 ppb < I 0 ppb I FLUORANTHENE 3890 ppb ( 10 ppb ( I 0 ppb < I 0 ppb
FLUORENE 11000 ppb < I 0 ppb < 10 ppb (10 ppb
HEXACHL0R0BENZ8!E (330 ppb < I 0 ppb (10 ppb (10 ppb I HEXACHL0ROBUTADIENE (330 ppb. (10 ppb < I 0 ppb < I 0 ppb
HEXACHL0ROCYCL0PENTADIENE <330 ppb. (10 ppb (10 ppb < I 0 ppb
HEXACHL0ROETHANE (330 ppb. < I 0 ppb (10 ppb (10 ppb
HE/ACHL0R0PR0PENE (330 ppb < I 0 ppb < I 0 ppb < I 0 ppb I IND ENO( I , 2, 3-CD) PYRENE (330 ppb < I 0 ppb (10 ppb < I 0 ppb
ISODRIN (330 ppb, (IQ ppb (10 ppb < I 0 ppb
IS0PHORONE (330 ppb < I 0 ppb < I 0 ppb < I 0 ppb 11 S0SAFROLE (330 ppb <10 ppb (10 ppb (10 ppb
KEPONE (330 ppb (10 ppb (10 ppb < I 0 ppb
METHAPYRILENE ·· (330 ppb . (10 ppb (10 ppb < I 0 ppb
13-METHYLCHOLANTHRENE (330 ppb (10 ppb < 10 ppb (10 ppb
METHYL METHANESULFONATE (330 ppb <10 ppb (10 ppb < I 0 ppb
2-METHYLNAPHTHALENE 6060 ppb, (10 ppb < I 0 ppb (10 ppb I NAPHTHALENE 2460 ppb . (10 ppb < I 0 ppb (10 ppb
1,4-NAPTHOQUINONE (330 ppb (10 ppb (10 ppb (10 ppb
1-NAPHTHYLAMINE (330 ppb < I 0 ppb < I 0 ppb (10 ppb
I
~ GENERAL ENGINEERING LABORATORIES .. .
1313 Ashley River Road P.O. Box 30712
. Chariest.on, S.C. 29407 Charleston, S.C. 29417
:lineering Consulting Phone [phone]
: mica! Analysis
·1oratory. Certification Number 10120
CLIENT: SANDOZ CHEMICALS CORPORATION
I PO BOX 669246 DATE: 01/12/88
CHARLOTTE I NC 28266
Cc.'.fTACT 1 MR. BILL ARCHER
I CC/FC: SNDC/APP9 PAGE NO. 1 6
--------------------------------------1 _________________________________________
I SAMPLE ID C-2-IA W!l-5AI W!l-6 W!l-32-1
13.5'-15' 12/08/87 12/08/87 12/09/87
' LAB ID I 87120314 87120315 87120316 87120372 ·' I DATE RECEIVED: 12/09/87 12/09/87 12/09/87 12/10/87
--------------------------------------------------------------------------------
I 2-NAPHTHYLAMINE (330 ppb (10 ppb < I 0 ppb (10 ppb
0-NITROANI LINE (330 P,Pb (10 ppb < I 0 ppb (10 ppb
H-NITROANI LINE (330 ppb (10 ppb (10 ppb < I 0 ppb
I P-NITR0ANILINE (330 ppb (10 ppb <10 ppb (10 ppb
NITR08ENZENE · <330 ppb < I 0 ppb 52 ppb (10 ppb
4-NITRO!lUINOLINE 1-0XI DE (330 ppb (10 ppb (10 ppb < I 0 ppb
I N-NITROS0DI-N-BUTYLAHINE (330 ppb < I 0 ppb <I0 ppb (10 ppb
N-NITROSODIETHYLAMINE <330 ppb < I 0 ppb <10 ppb (10 ppb
N-N ITROS0D INETlf(LAHINE (330 ppb (10 ppb (10 ppb (10 ppb
N-NITR0SODIPHENYLANINE <330 ' (10 ppb <10 ppb (10 ppb ppb
I N-NITROSODIPR0PYLAHINE (330 ppb < I 0 ppb < I 0 ppb (10 ppb
N-N I TR0Sc.'1ETHYLETHYLAM I NE (330 ppb (10 ppb <10 ppb < I 0 ppb
N-NITROSOMORPHOLINE (330 ppb (10 ppb (10 ppb < I 0 ppb
I N-NITROSOPIPERIDINE (330 ppb (10 ppb <I0 ppb < I 0 ppb
N-NITROS0PYRROLI DINE (330 ppb <10 ppb <I0 ppb < I 0 ppb
5-NITR0-0-TOLUIDINE (330 ppb (10 ppb < I 0 ppb (10 ppb
I PC DIBENZO-P-DIOXINS Not Det'd Not Det'd Not Det'd Not Det'd
PC DIBENZ0FURANS t~ot De1t 'd Not Det'd Not Det'd Not Det'd
PENTACHL0R0BENZENE (330 ppb 00 ppb <10 ppb < I 0 ppb
PENTACHLOR0ETHANE <330 ppb < I 0 ppb <10 ppb < I 0 ppb
I PENTACHLORONITROBENZENE <330 ppb (I 0 ppb < I 0 ppb (10 ppb
PHENACETIN (330 ppb < I 0 ppb (10 ppb < I 0 ppb
PHENANTHRENE 21800 ppb (10 ppb (10 ppb < I 0 ppb
I P-PHEN'ILENED I AMI NE (330 ppb (10 ppb (10 ppb < I 0 ppb
PHORATE (330 ppb (10 ppb <I0 ppb (10 ppb
2-PI COLINE (330 ppb (10 ppb <10 ppb < I 0 ppb
I PRONAMIDE (330 ppb (10 ppb <IO ppb < I 0 ppb
PYRENE 1560 ppb (10 ppb (10 ppb < I 0 ppb
SAFR0LE (330 p'pb (10 ppb (10 ppb < I 0 ppb
APPENDIX IX -ACID COMPOUNDS
I 2-CHLOROPHENOL (10 ppb (10 ppb < I 0 ppb < I 0 ppb
P-CHL0RO-H-CRESOL < I 0 ppb < I 0 ppb <10 ppb < I 0 ppb
0-CRESOL < I 0 PP.b < I 0 ppb < I 0 ppb < I 0 ppb
I H-CRESOL < I 0 ppb < I 0 ppb < I 0 ppb <10 ppb
P-CRES0L < I 0 ppb < I 0 ppb < I 0 ppb < I 0 ppb
2,4-DICHL0ROPHENOL (10 ppb (10 ppb <10 ppb (10 ppb
I
, m GENERAL ENGINEERING LABORATORIES . 1313 Ashley River Road
Charleston, S.C. 29407
Engineering Consulting
temical Analysis
Laboratory Certification Number 10120
I CLIENT1
I C!NTACT1
SANDOZ CHEMICALS CORPORATION .
PO BOX 669246
CHARLOTTE , NC 2B266
HR. BILL ARCHER
I CC/FC: SNOC/APP9
SAMPLE ID C-2-IA
I 13.5'-15'
' LAB ID
WCl-5AI
12/08/87
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
lJCl-6
12/08/87
DATE: 01/12/88
PAGE NO, 1 7
WCl-32-1
12/09/87
,, I --------------------------------------------------------------------------------DATE RECEIVED1
87120314
12/09/87
87120315
12/09/87
87120316
12/09/87
87120372
12/10/87
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2,6-DICHLOROPHENOL
2,4-DIHETHYLPHENOL
4,6-DINITRO-O-PH840L
2 ,4-DINITROPHENOL
2-SEC-BUTYL-4 1 6-DINITROPHENOL
HEXACHLOROPHENE
0-NITROPHENOL
P-NITROPHENOL
PENTACHLOROPHENOL
PHENOL
2,3 1 41 6-TETRACHLOROPHENOL
2,4,5-TRICHLuROPHENOL
2 1 41 6-TRICHLOROPHENOL
ACID DIGESTION
DIGESTION FOR MERCURY ANALYSIS
EXTRACTION & CONCENTRATION
{10 ppb
< 10 ppb
(10 ppb
(10 ppb
(10 ppb
< I 0 ppb
(10 ppb
11900 ppb
(10 ppb
(10 ppb
<10 ppb
(10 ppb
(10 ppb
YES
YES
YES
{10 ppb < 10 ppb (10 ppb
(10 ppb < 10 ppb {10 ppb
< 10 ppb < 10 ppb (10 ppb
(10 ppb < 10 ppb (10 ppb
(10 ppb (10 ppb (10 ppb
(10 ppb < 10 ppb < 10 ppb
( I 0 ppb < 10 ppb (10 ppb
< I 0 ppb {10 ppb < I 0 ppb
(10 ppb ( 10 ppb (10 ppb
44 ppb ( 10 ppb 14 ppb
<10 ppb · < l 0 ppb (10 ppb
<10 ppb < 10 ppb <10 ppb
( l O ppb (10 ppb <10 ppb
YES YES YES
YES YES · YES
YES YES YES
~ GENERAL ENGINEERING LABORATORIES
1313 Ashley River Road
Charleston, S.C. 29407
11ngineering Consulting
lhemical Analysis
Laboratory Certification Number 10120
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CL! ENT: SANDOZ CHEMICALS
PO BOX 669246
CHARLOTTE
CORPORATJ ON.
CONTACT1 MR, BILL ARCHER
SAMPLE ID
LAB JO
, NC 2B266
1 TRIP
BU'.~~K
12/08/87
SAHPLE TYPE 1
DATE RECEIVED:
87120327
12
12/09/87
SNDC PARAMETER COLLECTED BY :
APPENDIX IX -VOLATILES
ACETct-lE
ACETONITRILE
ACROLEIN
ACRYLONITRI LE
ALLYL CHLORIDE
BENZENE
Bl S( 2-CHLOROMETHYLETHYUETHr:R
BROMOD I CHLOROMETHPNE
BRC'.'10FORt1
CARBC'o'~ DI SUL FI DE
CARB!l'l TETRACHLORIDE
CHLOROBENZENE
CHLOROETHA'lE
CHLOROFORM
CHLOROPRENE
DI BROMOCHLOROMETHANE
1, 2-DI BRC'.'10-3-CHLOROPROPANE
1,2-DIBROMOETHANE
TRANS-I ,4-DICHLOR0-2-BUTENE
DICHLORODIFLUOROMETHANE
1,1-DICHLOROETHANE
1 ,2-DICHLOROETHANE
1, 1-DI CHLOROETHYLENE
TRANS-I ,2-DICHLOROETHYLENE
1,2-DICHLOROPROPANE
CJS-1 ,3-DICHLOROPROPENE
TRANS-1,3-DICHLOROPROPENE
1,4-DIOXANE
ETHYLBENZENE
ETHYL METHACRYLATE
2-H EXAN ll~ E
I SO BUTYL ALCOHOL
METHACRYLONITRILE
<10 ppb
<10 ppb
< 10 ppb
<10 ppb
<10 ppb
<10 ppb
<l O ppb
<10 ppb
<10 ppb
< 1 0 pp b
(10 ppb
(10 ppb
<10 ppb
(10 ppb
(10 p·pb
<10 ppb
<10 ppb
< l 0 ppb
<10 ppb
(10 ppb
(10 ppb
(10 ppb
<10 ppb
<IO ppb
(10 ppb
<IO ppb
<10 ppb
< l 0 ppb
(10 ppb
<10 ppb
<10 ppb
< l 0 ppb
<IO ppb
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
ffl GENERAL ENGINEERING LABORATORIES -'
l ngineering Consulting
hemical Analysis
laboratory Certification Number 10120
1313 Ashley River Road
Charleston, S.C. 29407
CLIENT: SANDOZ CHEMICALS CORPORATION
PO BOX 669246
CHARLOTTE , NC 28266
CO-ITACT I HR. BI LL ARCHER
CC/FC: SNDC/APP9
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
DATE 1 0 1/ 1 2/88
PAGE NO.: 2
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--------------------------------------------------------------------------------SAMPLE ID I TR IP ,
·'
BLANK
12/08/87
LAB ID 87120327
DATE RECEIVED: 12/09/87
--------------------------------------------------------------------------------
METHYL' BR01I DE
METHYL CHLORIDE
METHYLENE BRCNI DE
METHYLENE CHLORIDE
METHYL ETHYL KETONE
METHYL I OD IDE
METHYL METrACRYLATE
4-11ETHYL-2-PENTANONE
PROP! ONITRI LE
PYRIDINE
STYRENE
1; 1, 1, 2-TETRACHLOROETHANE
1,1,2,2-TETRACHLORQET!W-jE
TETRACHLOROETHYLENE
TOLUENE
11 11 1-TRICHLOROETHANE
1,1,2-TRICHLOROETHANE
TRICHLOROETHYLENE
TR I CHLOROFLUORot1ETIW-jE
t,2,3-TRICHLOROPROPANE
VINYL ACETATE
VINYL CHLORIDE
XYLENE (TOTAL>
<tO ppb
(10 ppb
< t O ppb
<to ppb
<10 ppb
(10 ppb
(10 ppb
<tO ppb
<to ppb
<10 ppb
<tO ppb
<t O ppb
<10 ppb
<tO p~b
<10 ppb
<to ppb
<10 ppb
<10 ppb
<10 ppb
<10 pp_b
(10 ppb
<10 ppb
<tO ppb
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Appendix IX Quality Control Data
January 12, 1988
General Engineering Laboratories
~age 1
QUALITY CONTROL DATA
The EPA Quality Assurance/Quality Control protocols require that 10% of all sample analyses be performed in duplicate, 10% of all analyses are QC spikes to evaluate the accuracy and precision of the test, and 10% of all analyses are blanks for background and contamination detennination. This ONQC data is provided in this data package. The QC identifications are as follows:
• Duplicate Analysis -The "Manual for Quality Assurance/Quality Control" for General Engineering Laboratories contains a section for evaluation of QC data. This section outlines acceptable limits for duplicate analyses. If the criteria for acceptance are not met, the out-of-control situation must be reported to supervisory personnel and, corrective action must be outlined and documented.
Spike An:1iysis -Actual samples are fortified with spiking mixtures that are outlined by the US EPA. If it is not practical to spike the actual sample, this spike must still be performed. Deionized water spikes must be used in these cases. The "Manual for Quality Assurance/Quality
Control" for General Engineering Laboratories contains a section for evaluation of QC data. This section outlines acceptable limits for spiked analyses. If the criteria for acceptance are not met, the out-of-control situation must be reported to supervisory personnel and corrective action must be outlined and documented. A general acceptance range for the metals and general chemistry parameters is 80 to 120%. The following criteria are established by the EPA for acceptance of organic am.lyses:
Fraction Surrogate Compoiilld Acceptance Range,%
Volatile 1 ; 1-Dichloroeth y l ene 61-145 Volatile Trichloroethylene 71-120 Volatile ,.::hlorobenzene 75-130 Volatile Toluene 76-125 Volatile Benzene 76-127
Base/Neutral 2,4-Dinitrotoluene 20-98 Base/Neutral Di-n-butyl phthalate 10-125 Base/Neutral r:·rer:e 20-130 Base/Neutral 1,4-Dichlorobenzene 30-1 IO
Acid Phenol 12-89 Acid 4-Chloro-3-Methylphenol 23-97 Acid 4-Nitrophenol 10-80
• Blank Analysis -If a blank indicates high background or contamination, this out-of-control situation must be reported to supervisory personnel and corrective action mu:;t be outlined and documented. Blank data is recorded in laboratory notes books at General Engineering Laboratories. Organic data for GC/MS is also stored electronically. Blank data is not included in this data package. ·
GENERAL ENGIJ\'EERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29-107 • [phone]
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Appendix IX Quality Con.Im! Data
January 12, 1988 General Engineering Laboratories
Page 2
The EPA methods for analysis of wastewater samples for organic contamination by
GC/MS require that every sample, blank, and spike be fortified with surrogate spiking
solutions. These surrogate spike compounds must be analyzed and quantitated and a
percent recovery reported. The EPA has established acceptance criteria guidelines for these
surrogate spikes. The ranges are relatively wide for acceptance of data, but it must be
noted that these spikes are performed on real-time samples. Matrix interferences,
background, and unregulated contamination may cause problems with the analyses of
compounds of interest Therefore, it is not unusual to see low recoveries with surrogate
spikes. The established criteria for acceptance of surrogate spike recoveries for organic
analyses by the EPA is shown in the following table:
Fraction Surroi;ate Compound Acceptance Range,%
Volatile Toluene-d8 86-119 Volatile 4-Bromofluorobenzene 85-121 Volatile 1,2-Dichloroethane-d4 77-120
Base/Neutral Nitrobenzene-ds 41-120 Ease/Neutral 2-Fluorobiphenyl 44-119 Base/Neutral p-Terphenyl"d14 33-128
Acid Phenol-ds 15-103 Acid 2-Fluorophenol 23-121 Acid 2,4,6-Tribromophenol 10-130
If the acceptance criteria for the surrogate 'Spiking compounds are not achieved, the sample
must be re-extracted and re-analyzed. The corrective action must be documented.
I GENERAL ENGINEERING LABORATORIES • 1313 Ashley Ri\'er Rd • Charleston, SC 29407 • (803) S:6•Sl71
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Appendix IX Quality Control Results
January 12, 1988
General Engineering Laboratories
Page 1
QUALITY CONTROL RESULTS
Group I: Metals -Duplicate Data (mg/L)
Element Replicate I Replicate 2 % Difference
Aluminum 50.2 48.2 4.0% Barium 1.50 1.46 2.7% Beryllium <0.010 <0.01.0 Cadmium <0.010 <0.010 Chromium 0.20 0.20 0.0% Cobalt <0.05 <0.05
Copper 0.16 .· 0.14 14% Iron 66.8 60.1 11% Lead 0.017 0.019 12% Magne··ium 53.1 52.5 1.1% Manganese 2.93 2.65 11% Nickel 0.15 0.15 0.0% Silver <0.05 <0.05 Scdium 13.6 11.8 15% Vanadium 0.17 0.15 13% Zinc 0.18 0.17 5.9%
Group I: Metals -Matrix Spike Data (mg/L)
Theoretical Actual
E1ement Yield Yield % Recovery
Aluminum 26.4 26.8 102% Barium 2.00 1.94 97% Beryllium 0.50 0.465 93% C~dmium 0.50 0.465 93% Chromium 2.60 2.44 94% Cobalt 0.50 0.47 94% Copper 2.58 2.46 95% Iron 35.9 36.1 101% Lead 0.100 0.106 106% Magnesium 27.8 28.4 102% Manganese 1.96 1.94 99% Nickel 2.58 2.46 95% Silver 0.20 0.17 85% Vanadium 1.34 1.17 87% Zinc 1.34 1.20 90%
Group 2: General Chemistry Parameters -Duplicate Data (mg/L)
Element Re.plicate 1 Replicate 2 % Difference
Cyanide <0.1 <0.1 Sulfide 1.50 1.46 2.7%
I GE:-.;ER,\L ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803) 556-~ l 71
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, Appendix IX Quality Control Result.!
January 12, 1988
General Engineering Laboratories
Page 2
Group 2: General Chemistry Parameters -Spike Data (mg/L)
Theoretical Actual
Element Yield Yield % Recovery
Cyanide 1.00 1.14 114%
I Sulfide 1.00 1.02 102%
Group 3: Base/Neutral Extractables -Duplicate Data (µg/L) for GEL 87120316 (WQ-6)
Element Rep]icate I Replicate 2
1,3-Dichlorobenzene 12.0 8.0
1,4-Dichlorobenzene 34.0 22.0
1,2-Dichlorobenzene 300.0 284.0
Jrichlorobenzene 8.0 16.0 ,,
Group 3: Base/Neutral Extractables -Spike Data (µg/L)
Compound
Acenaphthene
Dibutyl Phthalate
Pyrene
N-Nitroso-n-propylamine
1,4-Dichlorobenzene
Theoretical
Yield
107.0
106.0
1100.0
103.0
·102.0
Actual
Yield
92.0
80.0
72.0
98.0
104.0
% Difference
33%
35%
5%
50%.·
% Recovery
86%
75%
72%
95%
102%
Group 3: Base/Neutral Extractables -Surrogate Spike Data i:1g/L) for GEL 87120314
(C-2-lA)
Theoretical Actual
Compound Yield Yield % Re~overy
Nitrobenzene-d5 100.0 34.0 34%*
2-Fluorobiphenyl 1100.0 ·'6.0 46%
Terphenyl-d14 100.0 0.0 0%*
Group 3: Base/Neutral Extractables -Surrogate Spike Data (µg/L) for GEL 87120315
(WQ-5AI)
Theoretical
Compound Yield
Nitrobenzene-d5 100.0
2-Fluorobiphenyl 100.0
Terphenyl-d14 100.0
Actual
Yield
52.0
62.0
66.0
% Recovery
52%
62%
66%
•This recovery is outside the EPA recommended range for surrogate spike recovery. These results were
confirmed by duplicate analysis. A matrix interference is therefore suspected.
GENER,\L ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803) 556-~ I ii
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Appendix IX Quality Control Results
January 12, 1988
General Engineering Laboratories
Page 3
G~oup 3: Base/Neutral Extractables -Surrogate Spike Data (µg/L) for GEL 87120316
(WQ-6)
Theoretical Actual
Compound Yield Yield % Recovery
Nitrobenzene-ds 100.0 72.0 72%
2-Fluorobiphenyl · 100.0 90.0 90%
Terphenyl-d14 100.0 78.0 78%
Group 3: Base/Neutral Extractables -Surrogate Spike Data (µg/L) for GEL 87120372
(WQ-32-I)
Theoretical Actual
Compound Yield Yield % Recovery
Nitrobenzene-ds 100.0 56.0 56%
2-Fluorobiphenyl 100.0 66.0 66%
TeFJ)henyl-d14 100.0 52.0 52%
; I Group 4: Acid Extractables -Duplicate Data (µg/L) for GEL 87120316 (WQ-6)
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Element
Phenol
Replicate 1
44.0
Group 4: Ac:d Extractables -Spike Data (µg/L)
Element
Phenol
4-Chloro-3-methyl phenol
4-Nitrophcnol
Theoretical
Yield
206.0
216.0
214.0
Replicate 2
22.0
Actual
Yield
30.0
132.0
54.0
% Difference
50%
% Recovery
39%
61%
25%
Group 4: Acid Extractables -Surrogate Spike Data (µg/L) for GEL 87120314 (C-2-lA)
Compound
2-fluorophenol
Phenol-ds
Tribromophenol
Theoretical
Yield
200.0
200.0
200.0
Actual
Yield % Recovery
34.0 17%*
34.0 17%
32.0 16%
Group 4: Acid Extractables -Surrogate Spike Data (µg/L) For GEL 87120315 (WQ-5AI)
Compound
2-Fluorophenol
Phenol-ds
Tribromophenol
Theoretical
Yield
200.0
200.0
200.0
Actual
Yield
76.0
62.0
76.0
% Recovery
38%
31%
38%
•Tois recovery is outside the EPA recommended range for surrogate spike recovery. These results were
confirmed by duplicate analysis. A matrix interferehce is therefore suspected.
I GENERAL ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803} 556-8171
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, Appendix IX Quality Control Results
January 12, 1988
'
General Engineering Laboratories
Page 4
Group 4: Acid Extractables -Surrogate Spike Data (µg/L) for GEL 87120316 (WQ-6)
Compound
2-Fluorophenol
Phenol-ds
Tribromophenol
Theoretical
Yield
200.0
200.0
200.0
Actual
Yield % Recoverv
94.0 47%
144.0 72%
92.0 46%
Group 4: Acid Extractables -Surrogate Spike Data (µg/L) for GEL 87120372 (WQ-21-I)
Theoretical Actual
Compound Yield Yield % Recovery
2-Fluorophenol 200.0 62.0 31%
Phenol-ds 200.0 42.0 21%
Tribro'mophenol 200.0 62.0 31%
I Group 5: Pesticides -Duplicate Data (µg/L) for GEL 87120316 (\VQ-6)
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Compound Replicate I Replicate 2 % Difference
Pesticides None Detected None Detected
Group 5: Pesticides -Spike Data (µg/L)
Theoretical Actual
Element Yield Yield % Recovery
Lindane 104.0 26.7 26%
Endrin 106.0 48.7 46%
Aroclor-1254 100.0 35.0 35%
Group 5: Herbicides -Duplicate Data (µg/L) for GEL 87120316 (WQ-6)
Element Replicate 1 Replicate 2 % Difference
Herbicides None Detected None Detected
Group 5: Herbicides -Spike Data (µg/L)
Theoretical . Actual
Element Yield Yield % Recovery
2,4-D 1250.0 373.0 30%
2,4,5-TP 1250.0 348.0 28%
Group 6: Volatile Organics -Spike Data,(µg/L)
GENERAL ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 2~-107 • (803) :'56-8171
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Appendix IX Quality Control Results
January 12, I 988
Element
Benzene
Toluene
Chlorobenzene
1,1-Dichloroethylene
Trichloroethylene
Theoretical
Yield
20.0
20.0
20.0
20.0
20.0
Actual
Yield
21.5
20.9
2.1.2
20.5
20.7
General Engineering Laboratories
Page 5
% Recovery
108%
104%
106%
103%
103%
Group 6: Volatile Organics -Surrogate.Spike Data (µg/L) for GEL 8712031~ (C-2-lA)
Compound
1,4-DCA-~
Toluene-ds
BFB
Theoretical
Yield
25.0
25.0
25.0
' Actual
Yield % Recovery
13.5 54%*
23.5 94%
24.0 96%
Group 6: Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120315 (WQ-5AI)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-~ 25.0 21.8 87% Toluene-ds 25.0 24.2 97% BFB 25.0 23.0 92%
Group 6: Volatile Organics -Surrogate Spike Data (µg/L) for GEL 871'.2.J316 (WQ-6)
Compound
l,4-DCA-d4
Toluene-ds
BFB
Theoretical
Yield
25.0
25.0
25.0
Actual
Yield % Recovery
20.8 83%
24.2 97% 22.2 89%
Group 6: Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120327 (Volatile Trip Blank)
Compound
1,4-DCA-~
Toluene-d8
BFB
Theoretical
Yield
25.0
25.0
25.0
Actual
Yield
23.5
23.8
25.8
% Recovery
94%
95%
103%
•This recovery is outside the EPA recommended range for surrogate spike recovery. These results were confirmed by duplicate analysis. A matrix interference is therefore suspected.
I GENERAL ENGINEERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803) :'.'6-.-::71
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Appendix IX Quality Control Results
January 12, 1988 General Engineering Laboratories
Page 6
Group 6: Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120372 (WQ-32-I)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-dt 25.0 23.2 93% Toluene-d3 25.0 23.5 94% BFB 25.0 26.0 104%
I GENERAL ENG!l\'EERING LABORATORIES • 1313 Ashley River Rd • Charleston, SC 29407 • (803) 556-, ! "l
GENERAL ENGINEERING LABORATORIES
Environmental Engineering and Analytical Services
,,ly F. Greene
P idcnt
George C. Greene, P.E., Ph.D.
\'ice PrcslJcnl
Sltcgistration :\o. 9103
Laboratory Ccrtiric:itions:
FL ES71561S7:94
:\C :!33
SC 101:!0
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January 22, 1988
Mr. Bill Archer
Sandoz Chemical Corporation
PO Box 669246
Charlotte, North Carolina 28266
Dear rvrr. Archer:
VA 00151
~,\OP ,\pprovcd
Please find enclosed herewith the Quality Control results for the analyses on the
following locations at your Charlotte, North Carolina Facility:
• CR-1
• CR-2
• CR-3
• CR-4
• LC-1
• LC-2
• E-1-5
• WQ-35-I
• WQ-35-D
There is an explanation for the QA/QC procedures that are used by General
Engineering Laboratories :hat accompanies the QC data.
If you have any questions concerning these data or the methdologies, please do not
hesitate to call me at (80'.i) 556-8171. We look forward to working with you on fu•ure
projects.
enclosures
fc:sndcOI 2288
Projects
2040 Savage Road • Charleston. SC 2941-l / P. 0. Box 30712 • Charleston, SC 29417
Phone(S03)556-8171 • FAX[phone]
•,: ; 'm,, GENERAL ENGINEERING LABORATORIES
' '
, ... -Engineei;ing Consulting
crmical Analysis
Llioratory Certification Number
I CLIENT:
10120
1313 Ashley River Road
Charleston, S.C. 29407
CORPORATION
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
I CONTACT:
SANDOZ CHEM! CALS
PO BOX 669246
CHARLOTTE
MR. BILL ARCHER
, NC 28266
DATE: 1•2/08/37
RELEASED, BY: Cl~«J -~z. GEORGE ~GREENE PE, PHD J PAGE NO.: 1 CC/FC: SNDC/SNDC3
' I --------------------------------------------------------------------------------
I
SAMPLE ID LC-1
12/01/87
LC-2
12./01/87
LAB ID 87120085 87120086
PARAMETER ,: DATE RECEJ\!ED: 12/02/87 12/02/87
I-------------------------------------------------------------------------------
CHLOROBENZENE <10 ppb <10 ppb
1 1,2-DICHLOROBENZENE (10 ppb (10 ppb
ETHYL BrnZENE (10 ppb (10 ppb
TETRACHLOROETHYLENE (10 ppb (10 ppb
I TOLUENE (10 ppb (10 ppb
TRICHLOROETHYLENE (10 ppb (10 ppb
XYLENE (10 ppb (10 ppb
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Jl}) \ ~-
Engineei;ing Consulting
C,mical Analysis
L!toratory Certification Number
I
CLIENT:
I CONTACT:
SANDOZ CHEM! CALS
PO BOX 669246
CHARLOTTE
MR. BILL ARCHER
10120
GENERAL ENGINEERING LABORATORIES
1313 Ashley River Road
Charleston, S.C. 29407
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone] I 7 I
CORPORATION
, NC 28266
DATE: 12/08/87
RELEASErY: C(f1t;zu, _)
-; GEORGE Cf. GREENE PE, PHD
! PAGE r,o. : I I CC/FC: SNDC/SNDC3 --------------------------------------------------------------------------------
SAMPLE ID
I
LAB ID
CR-I
12/01/87
CR-2
12/01/87
CR-3
12/01/87
CR-4
12/01/87
I PARAMETER DATE RECEJ\/ED:
87120081
12/02/87
87120082
12/02/87
871200U
12/02/87
87120084
12/0 2/87
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--------------------------------------------------------------------------------
CHLOROBENZENE < 1 0 ppb (10 ppb < 1 0 ppb < 1 0 ppb
1 , 2-D I CHLOROBENZENE < 10 ppb < 10 ppb < 10 ppb < 1 0 ppb
ETHYL BENZ ENE < 1 0 ppb (10 ppb (10 ppb (10 opb
TETRACHLOROETHYLENE (10 ppb <10 ppb (10 ppb (10 ppb
TOLUENE < 1 0 ppb < 1 0 ppb (10 ppb < I 0 ppb
TR: CHLOROETH'/LENE (10 ppb (10 ppb (10 ppb (10 ppb
X'/LEME (10 PP9 < 1 0 ppb (10 ppb (10 ppb
tl)) \ J~· .
GENERAL ENGINEERING LABORATORIES
Engineering Consulting
caemical Analysis
Lfooratory Certification Number
CLIENT:
10120
1313 Ashley River Road
Charleston, S,C, 29407 '
CORPORATION
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
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CONTACT:
SANDOZ CHEM! CALS
PO BOX 669246
CHARLOTTE
MR, BILL ARCHER
, NC 28266 '---r',-'F7'~ ;a J~
RELEASED BY: ~
GEO , JclEENE E, PHO CC/FC: SNDC/SNDC3 '--\ PAGE t.fO. : l ----------------------------------------------------------------------------------SAMPLE ID WQ-35-I
PARAMETER
CHLORDBENZ ENE
LAB ID
SAMPLE TYPE
DATE RECEIVED:
COLLECTED BY :
1 ,2-DICHLOROBENZENE
ETHYL BENZENE
TETRACHLOROETHYLENE
TOLL ENE
TRI CHLOROETHYLENE
XYLENE
12/09/87
87120371
11
l 2/10/87
SNDC
37600 ppb
9650 ppb
<1000 ppb
<1000 ppb
<1000 ppb
<1000 ppb
1600 ppb
18 GENERAL ENGINEERING LABORATORIES
Engineering Co'nsulting
,mica! Analysis
Laboratory Certification Number 10120
1313 Ashley River Road
Charleston, S.C. 29407
I CLIENT: SANDOZ CHEMICALS CORPORATION
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
PO BOX 669246 DATE: 12/21/87 ·
I CHARLOTTE , NC 28266 ~ ,,,,I /'
~.-GEOR E C. GREENE PE I PHO
CCNTACT1 HR. BILL ARCHER RELEASrD Y:lfljd/ll{v
I==~~=~-~~=~~~==----------------------------------------------------~~~=-~~:~_: SAMPLE ID WQ-35-D
I LAB ID 87120428
PARAMETER . DATE RECEIVED: I 2/11/87 I-------------------------------------------------------------------------------
CHLOROBENZENE
11,2-DICHLOROBENZENE
ETHYL BENZENE
TETRACHLOROETHYLENE
I TOLUENE ·
TRICHLOROETHYLENE
XYLENE
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II
II
II
II
II
II
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i I
22100 ppb
6500 ppb
<5000 ppb
<5000 ppb
<5000 ppb
<5000 ppb
(5000 ppb
m· Engineering Consulting
lemical Analysis
Laboratory Certification Number 10120
GENERAL ENGINEERING LABORATORIES
1313 Ashley River Road
Charleston, S.C. 29407
P.O. Box 30712
Charleston, S.C. 29417
Phone [phone]
I CLJENT1 SANDOZ CHEMICALS CORPORATION
PO BOX 669246 ~ -i_L7 l • CHARLOTTE , NC 28266 , //J I CCNTACT I MR. Bl LL ARCHER RELEASED BY: ,,.,,,.,m-..u r./' /
GEO GE C...-G~EENEt E, PHD CC/FC: SNDC/SNDC3 -' )PAGE NO. 1 I
I 11 ----------------SAMPLE-ID----:--E-1-5 _________ ---------------------------------
I I PARAMETER
LAB ID
DATE RECEIVED 1
23.5'-24'
87120196
IV07/87 ------------------------·--------------------------------------------------------1 I CHLOROBENZ cHE
I, 2-DI CHLOROBENZENE
I ETHYL BENZ EtiE
TETRACHLOROETHYLENE
TOLUENE
I TR I CHLOROETHYLENE
XYLENE ··
II
II
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11
11
II
II
II
<35 ppb
<35 ppb
(35 ppb
<35 ppb
I 07 ppb
<35 ppb
50 ppb '
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Sandoz-Charlotte Quality Control Data
January 22, 1988
General Engineering Laboratories
Page 1
QUALITY C.ONTROL DATA
The EPA Quality Assurance/Quality Control protocols require that 10% of all sample
analyses be performed in duplicate, 10% of all analyses are QC spikes to evaluate the
accuracy and precision of the test, and 10% of all analyses are blanks for background and
contamination determination. This QA/OS:, data is provided in this data package. The QC
identifications are as follows:
• Duplicate Analysis -The "Manual for Quality Assurance/Quality Control" for
General Engineering Laboratories contains a section for evaluation of QC data.
This section outlines acceptable limits for duplicate analyses. If the
criteria for acceptance are not met, the out-of-control situation must be reported
to supervisory personnel and corrective action must be outlined :J.11d
documented.
• · Spike Analysis -Actual samples are fortified with spiking mixtures that are
qutlined by the US EPA. lf it is not practical to spike the actual
sample, this spike must still be performed. Deionized water spikes must be
used in these cases. The "Manual for Quality Assurance/Quality
Control" for GenerJl Engineering Laboratories contains a section for evaluation
of QC data. This section outlines acceptable limits for spiked analyses. If the
criteria for acceptance are not met, the out-of-control situation must be reported
to supervisory personnel and corrective action must be outlined and
documented_ A general acceptance range for the metals and general chemistry
parameters is 80 to 120%. The following criteria are established by the EPA for
acceptance of organic analyses:
Fraction Surro&ate Compound Acceptance Range.%
Volatile 1, 1-Dichloroethylene 61-145
Volatile Trichloroethylene 71-120
Volatile Chlorot :nzene 75-130
Volatile Toluene 76-125
Volatile Benzene 76-127
Base/Neutral 2,4-uinitrotoluene 20-98
Base/Neutral Di-n-butyl phthalate 10-125
Base/Neutral Pyrene 20-130
Base/Neutral 1,4-Dichlorobenzene 30-110
Acid Phenol 12-89
Acid 4-Chloro-3-Methylphenol 23-97
Acid 4-Nitrophenol 10-80
• Blank Analysis -If a blank indicates high background or contamination, this
out-of-control situation must be reported to supervisory personnel and
corrective action must be outlined and documented. Blank data is recorded in
laboratory notes books at General Engineering Laboratories. Organic data for
GC/MS is also stored electronically. Blank data is not included in this data
package.
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Sandoz-Charlotte Quality Control Data
, Uouary 22, 1988 General Engineering Laboratories
Page 2
• · • 'The EPA methods for analysis of wastewater samples for organic contamination by
. GC/MS require that every sample, blank, and spike be fortified with surrogate spiking
solutions. These surrogate spike compcunds must be analyzed and quanr.itated and a
percent recovery repcrted. The EPA has established acceptance criteria guidelines for these
surrogate spikes. The ranges are relatively wide for acceptance of data, but it must be
noted that these spikes are performed on real-time samples. Matrix interferences,
background, and unregulated contamination may cause problems with the analyses of
compounds of interest Therefore, it is not unusual to see low recoveries with surrogate
spikes. The established criteria for acceptance of surrogate spike recoveries for organic
analyses by the EPA is shown in the following table:
Fraction Surr01~ate Compound Acceptance Range,%
Volatile Toluene-d8 86-1 I 9
Volatile 4-Bromofluorobenzene 85-121
Volatile 1,2-Dichloroethane-<4 77-120
Base/Neutral Nitrobenzene-d5 41-120
Base/Neutral 2-Fluorobiphenyl 44-119
Base/Neutral p-Terphenyl-d14 33-128
, Acid Phenol-d5 15-103
Acid 2-Fluorophenol 23-121 Acid 2,4,6-Tribromophenol 10-130
[f tlie acceptance criteria for the surrogate spiking compounds are not achieved, the sample
must be re-extracted and re-analyzed. The.corrective action must be documented.
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S;mdoz-Charlotte Quality Control Results
· ' January 22, 1988 General Engineering Laboratories
Pagel
QUALTIY CONTROL RESULTS
Sandoz Volatile Organics -·· Spike Data (µg/L)
Element
Benzene
Toluene
Chlorobenzene
1, 1-Dichloroethy lene
Trichloroethy lene
Theoretical
Yie)d
20.0
20.0
20.0
20.0
20.')
Actual
Yield
21.2
19.4
21.0
17.6
22.8
% Recovery
106%
97%
105%
88%
114%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120081 (CR-1)
T'.eoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-ck 25.0 17.8 71% Toluene-d8 25.0 26.8 107% BFB 25.0 24.7 99%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120082 (CR-~.)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-ck 25.0 17.9 72%
Toluene-ds 25.0 25.5 102%
BFB 25.0 25.0 100%
Sandoz Volatile Or;anics -Surrogate Spike Data (µg/L) for GEL 87120083 (CR-3)
Theoretical Actual
Compound Yie1d Yield % Recoverv
1,4-DCA-ck 25.0 17.9 72%
Toluene-d8 25.0 25.5 102%
BFB 25.0 26.1 104%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120084 (CR-4)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-ck
Toluene-d8
BFB
25.0
25.0
25.0
18.6
25.8
24.2
74%
103%
98%
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Sandoz-Charlotte Quality Control Results
, • Ja1iuary 22, 1988
General Engineering Laboratories
Page 2
-3and6z Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120085 (LC-1)
Compound
1,4-DCA-di
Toluene-d8
BFB
Theoretical
Yield
25.0
25.0
25.0
Actual
Yield % Recovery
17.0 68%
25.5 102%
25.5 102%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120086 (LC-2)
Theoretical Actual
Compound Yield Yield % Recoverv
1,4-DCA-di 25.0 16.1 64%
Toluene-d8 25.0 25.5 106% BFB. 25.0 27.0 108%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120196 (E-1-5)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-di 25.0 19.2 77%
T0luene-d8 25.0 25.2 101% BFB 25.0 25.0 100%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120371 (WQ-35-I)
Theoretical Actual
Compound Yield Yield % Recovery
1,4-DCA-di 25.0 23.6 94%
Toluene-d8 25.0 24.4 98% BFB 25.0 25.3 101%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120428 (WQ-35-D)
Theoretical Actual
CoP19ound Yield Yield % Recoverv
1,4-DCA-di 25.0 23.4 94%
Toluene-d8 25.0 24.2 97% BFB 25.0 26.0 104%
Sandoz Volatile Organics -Surrogate Spike Data (µg/L) for GEL 87120428 (Duplicate of
LC-1)
Theoretical Actual
Compound Yield Yield % Recoverv
1,4-DCA-di 25.0 17.8 71%
Toluene-d8 25.0 25.6 102%
BFB 25.0 25.l 100%
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Sandoz-Charlotte Quality Control Results
lad!iary 22, 1988
.. ,.
General Engineering Laboratories
Page 3
Sandoz Volatile Organics -Duplicate Data (µg/L) for GEL 87120085 (Duplicate ofLC-1)
Element
Chloroform
Toluene
Replicate I
3.00
None Detected
Replicate 2
4.00
3.00
% Di Terence
33.0%