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HomeMy WebLinkAboutNCD000813592_20000808_GA-Pacific Corp Hdwd Saw_FRBCERCLA RI_Draft Remedial Investigation Report-OCRI I I I I I I I I I I I I I i I I I I Response Action Contract For Remedial, Enforcement Oversight, and Non-time Critical Removal Activities at Sites of Release or Threatened Release of Hazardous Substances In EPA Region VIII U.S. EPA Contract No. 68-W5-0022 Draft Remedial Investigation Report Georgia-Pacific Hardwood Site Plymouth, North Carolina . Work Assignment No.: 027-RICO-04RF Document Control No.: 3280-027-RT-RIRT-08101 August 8, 2000 Prepared for: U.S. Environmental Protection Agency Region IV Atlanta, Georgia Prepared by: CDM Federal Programs Corporation 2030 Powers Ferry Road, Suite 490 Atlanta, Georgia 30339 RECEIVED SEP O 12000 SUPERFUND SECTION I I I I ·• I I I I ,I I I I I .• I I ,' I I I Prepared by: Response Action Contract For Remedial, Enforcement Oversight, and Non-time Critical Removal Activities at Sites of Release or Threatened Release of Hazardous Substances In EPA Region VIII U.S. EPA Contract No. 68-WS-0022 Draft Remedial Investigation Report Georgia-Pacific Hardwood Site Plymouth, North Carolina Work Assignment No.: 027-RICO-04RF Date: Terence Chu~ a ger Date: Mike rofit Te9'111cal Rz5iew~f?' -, ,.,,--- [?,,,t,•1 r, Cvctl,l:Yf-.,1/ Approved by: _____________ _ Date: Gary P. Clemons, Ph.D. Region 4 Program Manager CDM Federal Progroms Corporation I I I I •• I I I I I I I ,·, I I I I I Executive Summary The Georgia-Pacific Hardwood Sawmill Site (hereinafter referred to as the "Georgia- Pacific Site" or "the site"), is defined as the 24-acre area located on Plywood Drive · .,__ within the city limits of Plymouth, North Carolina. Contaminants consisting primarily \, ·4,. \r-'I o\" of dioxins/ furans, polynuclear aromatic hydrocarbons, pentachlorophenol, pesticides, ~" _ yl} p~hlorinated..b.iJ2henyls, and a few heavy metals were released into the 'if'-. · v~ environment during past sawmill wood treating operations. Having been placed on f"t;(J ~ I the National Priorities List in 1999, a remedial investigation and feasibility study of 1/ the Georgia-Pacific Site is thus required as promulgated by the Comprehensive Environmental Response, Compensation, and Liability Act and the National Contingency Plan. This document is the draft Remedial Investigation Report and was prepared by CDM Federal Programs Corporation in cooperation with U.S. Environmental Protection Agency Region IV Science and Ecosystem Support Division. Soil, surface water, sediment, al}1 ~oundwater samples, both onsite and offsite, were collected by Science and EcosiMem Support Division personnel and sample analyses were performed by the EPA' s Contract Laboratory Program. Dioxins and Furans were analyzed by an EPA Special Purchase Agreement laboratory because of the special requirement for dioxins and furan analyses. Analytical results, were validated ~-\/ l:JQ _'jf. J,y the Science and Ecosystem Support Division Quality Assurance personnel. {f'\\~~ ~ /following is a summary of the analytical results: The ~ ~ -:\ . f t Analyses of soil sam Jes collected indicate extensive contamination by ij~:r ~~ i \j' ~\) d1oxms urans, polynuclear aromatic hydrocarbons, polychlorinated biph_enyls, and inorganics. This contamination seemed to be focused in an area centrally located on the site property where most past operations were located. ~ was indication of offsite contamination from site related constituents, ~ever the concentrations were lower than onsite concentration. • Surface waters at the site discharge into the Roanoke River. Analyses of <...( surface water and sediment samples collected from the intermittent drainage J '--ditches located onsite indicate contamination by arsenic and manganese in VJ ~' ~ surface water, and by dioxins/ furans, acetone, methyl ethyl ketone, ~ /'poly;uclear aromatic hydrocarbons, arsenic, lead, and zinc in sediments. +¥ c_l,o-''t, ~-"' ;;-{-. ) d1' .:_1,V.. -f- CDM Federal Pmi:r:mu CorporJ1i,t: ~ SPIN 28/EXSUM.WPD •~ ~;'lo '1."' ii I I I I I I I I I I I I i I I I I Executive Summary The site is underlain by a shallow surficial unconfined aquifer. Groundwater flow at the site is likely toward the Roanoke River, where it discharges. Analyses of groundwater samples at the site indicate contamination by arsenic and manganese. Concentrations of some other contaminants such as aluminum, iron, and manganese are above other criteria such as Secondary Drinking Water Maximum Contaminant Levels (MCLs). Following a initial review of the RI data, EPA prepared site specific removal action levels of nine constituents of concerns and performed a removal action at the site. The removal action consisted of excavation of soil from contaminated grids and ultimately shipping soil, debris, buildings, and tanks offsite. Following the removal action, EPA Science and Ecosystem Support Division personnel sampled the bottom and sides of the excavations to confirm compliance to site specific removal action levels and then the site was backfilled with clean soil. Based on the results of the RI and considering the removal action data, the following actions are recommended: V. ✓ CDM Federal Proi,:rJm.1 Corporation SPIN 28/EXSUM.WPO Remedial action objectives for soil and groundwater contamination at the site should be established based on human health exposure risks, as well as the potential for future contaminant migration from one medium to another (e.g., soils to groundwater). Alternatives for reducing soil and groundwater contamination at the site to achieve the established remedial action objectives should be evaluated, and the most cost-effective alternative for each implemented. iii I I I I I I I I I I I I I I I I I I I List of Acronyms ASTs bis Above ground storage tanks below land surface BBLES Blasland, Bouck & Lee, Engineers and Scientists, Inc BRA Baseline Risk Assessment CDM Federal CDM Federal Programs Corporation CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CFR Code Federal Regulations CLP coc COPC cPAH cy EPA FS HSWA MCL MCLG ms! MW NCP ND NPL Contract Laboratory Program Contaminant of Concern Contaminant of Potential Concern Carcinogenic Polynuclear Aromatic Hydrocarbon cubic yard Environmental Protection Agency Feasibility Study Hazardous and Solid Waste Amendments Maximum Contaminant Level Maximum Contaminant Level Goal mean sea level Monitor Well National Contingency Plan not detectable National Priorities List OCDD Octachlorodibenzodioxin PAH PCB PCP PRP QA QC RCRA RI CDM Federal Prn1:rnn1s Corpomtion SPIN 2B/EXSUM.WPD polynuclear aromatic hydrocarbon polychlorinated biphenyl Pentachlorophenol Potentially Responsible Party Quality Assurance Quality Control Resource Conservation and Recovery Act Remedial Investigation iv I I I I I I I I I I I I I I I I I I I List of Acronyms (continued) ROD RPM SAP SESD SIP SSI SSRAL svoc TAL TCDD TCE TCL TEF TEQ voe Record of Decision Remedial Project Manager Sampling and Analysis Plan Science and Ecosystem Support Division Site Inspection Prioritization Screening Site Inspection Site specific removal action level Semi-volatile organic compound or Extractables Target Analyte List 2,3,7,8-Tetrachlorinated dibenzodioxin Trichloroethene Target Compound List toxicity equivalent factor toxicity equivalent value Volatile organic analyte 2378TCDD TEQ 2,3,7,8 tetrachlorodibenzodioxin toxicity equivalent concentration CDM Federal Pmi:rnm• Cmporntion SPIN 28/EXSUM.WPO V I I I I I I I I I ,,, I I I I I I I CONTENTS EXECUTIVE SUMMARY ................................................... . LIST OF ACRONYMS ...................................................... . 1.0 INTRODUCTION ................................................... . 1.1 Purpose of Report ............................................ .. 1.2 Site Description ............................................... . 1.3 Environmental Setting ......................................... . 1.4 Site Operations History ........................................ . 1.5 Previous Sampling Investigation Results ......................... . 1.6 Nature of Problem ............................................. . 1.7 RI Field Investigation Summary ................................. . 1.8 Removal Action ............................................... . 1.9 Overview of Report ............................................ . 2.0 SOIL SAMPLING INVESTIGATION ................................... . 3.0 4.0 5.0 6.0 2.1 Purpose and Scope ............................................ . 2.2 Methods ..................................................... . 2.3 Summary .................................................... . SURFACE WATER/SEDIMENT SAMPLING INVESTIGATION .......... . 3.1 Purpose and Scope ............................................ . 3.2 Methods ..................................................... . 3.3 Summary .................................................... . GROUNDWATER SAMPLING INVESTIGATION ....................... . 4.1 4.2 4.3 Purpose and Scope ............................................ . Methods ..................................................... . Summary .................................................... . CONTAMINANT FATE AND TRANSPORT ANALYSIS ................. . 5.1 Contaminant Migration ........................................ . 5.2 Contaminant Persistence ....................................... . QUALITY ASSURANCE REPORT ..................................... . 6.1 Controlling Documents ........................................ . 6.2 Field Investigation ............................................. . 6.3 Field Quality Control Procedures ................................ . 6.4 Data Validation ............................................... . CDM Federal Programs Corporation SPINB2/SECT4 ii iv 1-1 1-1 1-2 1-8 1-11 1-12 1-13 1-14 1-15 1-16 2-1 2-1 2-1 2-3 3-1 3-1 3-1 3-1 4-1 4-1 4-1 4-1 5-1 5-1 5-7 6-1 6-1 6-1 6-1 6-1 vi I I I I I I, I I I I I I I I I 6.5 Data Evaluation ............................................... . 6.6 Precision, Accuracy, Representativesness, Comparability, Completeness 6.7 Audits ...................................................... . 7.0 RI SUMMARY AND CONCLUSIONS ................................. . 8.0 REFERENCES ....................................................... . APPENDIX A APPENDIXB CDM Federal Programs Corporation SPINB2/SECT4 RI Analytical Data and Quality Assurance Data Removal Action Remaining Soil Analytical Data 6-1 6-1 6-1 7-1 8-1 vii I I a I I' I I I I I I I 11 I I I I I I Tables 2-1 2-2 2-3 2-4 2-5 3-1 3-2 3-3 3-4 4-1 4-2 5-1 5-2 Soil Sampling Summary -Volatile and Extractable Organics ........... . Soil Sampling Summary -Pesticides and PCBs ...................... . Soil Sampling Summary -Dioxins and Furans ....................... . Soil Sampling Summary-Inorganics ............................... . Removal Action.Confirmation Analysis ............................ . Surface Water Sampling Summary ................................. . Sediment Sampling Summary -Dioxins/Furans ..................... . Sediment Sampling Summary -Organics ........................... . Sediment Sampling Summary -lnorganics .......................... . 2-5 2-23 2-41 2-59 2-89 3-3 3-4 3-5 3-6 Groundwater Sampling Field Measurements . . . . . . . . . . . . . . . . . . . . . . . . . 4-3 Groundwater Sampling Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4-4 Estimated Physical and Chemical Properties of the Contaminants of Concern 5-2 Estimated Degradation Potential of the Contaminants of Concern. . . . . . . 5-9 CDM Federal Programs Corporation SPINB2/SECH viii I I I I I I I I I I I I I I I I t I I Figures 1-1 Site and Surrounding Properties Map 1-2 Former Site Usage and Features .................................... . 2-1 Onsite and Off site Soil Sampling Locations ........................... . 2-2 P AHs and cPAHs Detected in Onsite Soil ............................ . 2-3 PAHs and cP AHs Detected in Offsite Surface Soil ..................... . 2-4 PCBs Detected in Onsite Soil ....................................... . 2-5 Dioxins and Furans (TEQ) Detected in Onsite Soil ..................... . 2-6 Dioxins and Furans (TEQ) Detected in Onsite Subsurface Soil ........... . 2-7 Metals Detected in Onsite Soil ...................................... . 3-1 Surface Water/Sediment Sampling Locations ........................ . 3-2 Inorganic Contaminant Distribution in Surface Water ................. . 3-3 Dioxin/Furan Contaminant Distribution in Sediment ................. . 3-4 VOC Contaminant Distribution in Sediment ......................... . 3-5 P AH Contaminant Distribution in Sediment ......................... . 3-6 Inorganic Contaminant Distribution in Sediment ..................... . 4-1 Groundwater Sampling Locations .................................. . 4-2 Inorganic Contaminant Distribution in Groundwater .................. . CDM Federal Programs Corporation SPINB2JSECT~ 1-3 1-5 2-2 2-78 2-79 2-81 2-83 2-84 2-88 3-3 3-8 3-10 3-11 3-13 3-14 4-2 4-8 ix I I t I ,I I ., ,, I I ·t I I I I .I I I 1.0 Introduction 1.1 Purpose of Report The Georgia-Pacific Hardwood Sawmill Site (hereinafter referred to as the "Georgia- Pacific Site" or "the site"), is defined as the 24-acre area located on Plywood Drive within the city limits of Plymouth, North Carolina. Contaminants consisting primarily of dioxins/ furans, polynuclear aromatic hydrocarbons (PAHs), pentachlorophenol (PCP), pesticides, polychlorinated biphenyls (PCBs), and a few heavy metals were released into the environment during past sawmill wood treating operations. The site was placed on the National Priorities List (NPL) in October of 1999. Having been placed on the NPL, a remedial investigation and feasibility study (RI/FS) of the Georgia-Pacific Site is thus required as promulgated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the National Contingency Plan (NCP). The purpose of the RI/FS process is to gather, as quickly and cost-effectively as possible, enough information about the site to support an informed risk management decision regarding which remedy appears to be most appropriate for the site. The RI serves as the mechanism for collecting data to characterize site conditions, determine the nature and extent of the waste, assess risk to human health and the environment, and conduct treatability testing as necessary to evaluate the potential performance and cost of the treatment technologies being considered. The FS serves as the mechanism for development, screening, and detailed evaluation of alternative remedial actions. The various steps, or phases, of the RI/FS process are briefly described below: • • COM FeJcrnl Programs Corporation SPINBVSEC1.WPD Scoping: -the initial planning phase of the RI/FS, including the preliminary assessment and site investigation Site Characterization -definition of the nature and extent of contamina- tion, identification of applicable or relevant and appropriate require- ments (ARARs), and development of the baseline risk assessment 1-1 I I I I I I I I I •• I I I I I I • • • Section 1 Introduction Development and Screening of Alternatives -identification of potential treatment technologies, screening of these technologies, assembly of the technologies into alternatives, and screening of the alternatives Treatabilit;y Investigations -bench-or pilot-scale testing to assess the feasibility of a technology Detailed Analysis of Alternatives -further refinement of the alternatives, analysis of the alternatives with respect to nine evaluation criteria, and comparison of the alternatives against each other. The RI and FS are conducted concurrently so that data collected in the RI influence the development of remedial alternatives in the FS, which in turn affects the data needs and scope of the treatability studies and any additional field investigations. The purpose of this report is to document the results of the RI field investigation performed by EPA for the Georgia-Pacific Site, and provide the information needed to perform a human health and ecological risk assessment assessing the impacts of contamination at the site, and a feasibility study evaluating potential remediation alternatives, if necessary. This document is submitted to EPA in accordance with Work Assignment No. 027-RICO-0401 under Contract No. 68-WS-0022. 1.2 Site Description 1.2.1 Location The Georgia-Pacific Site is located on Plywood Drive within the city limits of Plymouth, Washington County, North Carolina, approximately 0.5 miles east of the downtown district. The geographic coordinates of the site are 35'52' 27" North latitude and 76°44' 27.5" West longitude. 1.2.2 Physical Features The site is approximately 24 acres in size, and is bounded to the north by the Roanoke River, to the west by Atlantic Coast Railroad property, to the east by residential properties, and to the south by the Plymouth High School and the Boy Scouts of America property. A map of the site and surrounding properties is provided in Figure 1-1. The site terrain is flat, low-lying with elevation increasing south of the CDM Federal Prui:nims Corporarion SPINB2/SEC1.WPD 1-2 0 250' - - Roanoke River 500' - --' Georgia-Pacific Hardwoods a Pl outh, North Carolina GEORGIA PACIFIC Sl1E Scouts 0 Hut I c:::::J I ...... \ ... ... :\ ~ Footbol~ Field ✓ LEGEND: ... ... ... ~ ~ Site Map 0 N 0 0 0 0 0 0 0 0 0 PROPERlY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA RIVER TREE LINE RAILROAD Figure No. 1-1 ~ CDM Federal ~IUDII CorporaUon ~.__·-__ .,_ .... _-_· __ .. ____ __,_ ________________________ ..J.._..:.7!.:./0::.:0:..___J I I I I I I I I I I I I I I I ., Section 1 Introduction site. Portions of the site are exposed hard packed dirt, gravel, asphalt, or concrete, while other areas are overgrown with grass, trees, and heavy vegetation. The site is presently unoccupied, and some of the former structures used in the past have been demolished. Recently, the removal action activities further demolished and removed other structures and materials from the site and all that remains is one smoke stack. Figure 1-2 depicts the site layout including all the former structures. As indicated in Figure 1-2, the site has been subdivided into five separate areas to allow for a better description and understanding of former activities at the site. These five areas are described below. 1.2.2.1 Former Finished Wood Products Storage Area/Outerbanks Contractors Asphalt Mixing Plant This is the area that starts at the entrance to tl1e site and continues to the south of the former railroad spur bed where finished wood products were stored. This area was also subsequently used by Outerbanks Contractors for its asphalt mixing plant operations (see Section 1.4). It is bordered to the south by the perimeter drainage ditch; to the north by the former railroad bed spur; and abuts the property boundaries to the east and west. Most of the surface cover in this area is vegetated with a variety of grasses. Significant features in this area include a pre-fabricated metal storage shed erected by Outerbanks Contractors and the access gate to the site from Plywood Road (installed recently by EPA). The area in and around the metal storage shed is the location of several containers (drums, cans, canisters, bags, etc.). Prior to a removal action conducted by the PRPs (see Section 1.8), approximately 200 cubic yards of asphalt stockpiled in numerous piles were located in the center of this area. The asphalt stockpile area was roughly rectangular in shape with dimensions of approximately 260 feet by 230 feet (approximately 1.4 acres). During the removal action, the property owner eliminated approximately 50% of the asphalt piles by recycling the asphalt, and moved the remaining asphalt to the front of the storage shed. CDM Fedeml Pm!:ra1m Corporation SPINB2/SEC1.v'IPD 1-4 I I I I I I I I I I ,. I I I I I I I 0 -300' -600' Georgia-Pacific Hardwoods j __ P_l.._m_o_u_t_h_,_N_o_r_th_-_c_a_ro_l_i_n_a---t • / I N / LEGENQ; -···-RIVER EDGE r--v-y-TREE LINE ----PROPERTY BOUNDARY --- -INTERMITTENT DRAINAGE DITCH • • . MARSHY AREA ~ RAILROAD Figure No. Former Site Usage & Features 1-2 ~ CDM Federal Pr,:1,rame Corporation ~ ,_,, __ • .... 6/00 ~--------------------------- I I I I I '_lj I I I I I ,I I I I I I I I I Section 1 Introduction Prior to the removal action, two 400-gallon aboveground storage tanks (ASTs), one 800-gallon AST, and one 2,500-gallon tanker trailer were also located in this area. During the removal action, the two 400-gallon ASTs were removed from the site. The remaining two tanks were left onsite, by request of the property owner, to be recycled later. A septic tank located in the south-central part of this area was also discovered during the removal action and left in place with a piece of concrete placed over the entrance. 1.2.2.2 Former Finished Wood Products Storage/Employee Parking Area This is the area extending from the Roanoke River south to the bed of the former railroad spur where finished wood products were stored and employee vehicles were parked. A portion of this area was also used by Outerbanks Contractors for their asphalt mixing operations. It is bordered to the south by the former railroad spur bed; to the north by the Roanoke River; to the west by the property boundary; and to the east by the Raw Timber Process Area. Most of the surface cover in this area is vegetated with a variety of grasses, shrubs, and saplings. Significant features include the office house located inside the entrance gate from Plywood Road and the pier on the Roanoke River (in the western comer of the site) that was constructed after 1984. Approximately 200 cubic yards of soil stockpiled in two piles are also located at the western margin of this area. The source of the soil is unknown. 1.2.2.3 Former Raw Timber Process Area The Former Raw Timber Process Area is located in the north-central section of the site, extending from the Roanoke River to the former locations of several finished wood product storage sheds and a dry kiln. This area supported the timber process buildings where raw timber logs were debarked, sawed, planed, and (in some instances) surface treated with a liquid anti-stain formulation (dilute pentachlorophenate to prevent staining from mold and mildew growth) and allowed to dry. It was also used by Outerbanks Contractors for its asphalt mixing plant COM Federal Programs Cnrpnrntion SPINB2/SEC1.WPD 1-6 I I I I I I I I I I I I I I I I I I I Section 1 Introduction operations. The area is bordered to the south by the former railroad bed spur; to the north by the Roanoke River; to the east by an intermittent drainage ditch; and to the west by the Former Finished Wood Products Storage/Employee Parking Area. Most of the surface cover in this area is a mix of remnant buildings, foundations, and concrete pads with a dense cover of grasses, shrubs, and trees. Significant features prior to the removal action included a machine shop building, log deck ramp, boiler house and stack, and concrete foundations and storage pads. During the removal action, the boiler house and machine shop were demolished, and most of the demolition debris was transported offsite. Only the machine shop brick was left onsite in this area, at the request of the property owner. Prior to the removal action, one 20,000-gallon AST, and one 7,500-gallon tanker trailer were also located in this area. These two tanks were thought to contain petroleum products. During the removal action, the tanker trailer was removed from the site. The remaining 20,000 AST was left onsite, by request of the property owner, to be recycled later. 1.2.2.4 Former Raw Timber Receiving Area The Former Raw Timber Receiving Area is located in the easternmost portion of the site where raw timber logs were received and stored prior to processing. This area is bordered to the south by the Former Finished Wood Products Storage Area/Outerbanks Contractors Asphalt Mixing Plant; to the north by the Roanoke River; to the west by the Former Raw Timber Process Area; and abuts the property boundary and perimeter intermittent drainage ditch to the east. Most of this area's surface cover is densely vegetated with a variety of shrubs and trees. 1.2.2.5 Intermittent Drainage Ditches This area is comprised of the following two intermittent drainage ditches: • COM Fcdernl Pru1:rnms C.irpnratinn SPINB2/SEC1.WPD Perimeter Intermittent Drainage Ditch -this ditch borders the property boundary from the site access gate on Plywood Road to its confluence with the Roanoke River at the northern corners of the property. 1-7 I I I I I I I I I I I I I I I I I I I Section 1 Introduction • Raw Timber Process Area Intermittent Drainage Ditch -this ditch extends from the former railroad spur bed to its confluence with the Roanoke River, separating the Raw Timber Process Area from the Raw Timber Receiving Area. 1.2.3 Demography The estimated population within a 4-mile radius of the site is approximately 7,000. The nearest residence is located approximately 700 feet east of the site. The Plymouth High School is located 0.27 miles south of the site. A Boy Scouts of America facility is located adjacent to the Plymouth High School. The land to the north of the site, and immediately north of the Roanoke River, is classified as wetlands. Access to the site is restricted by a gate; however, there are no fences around the property. A zone of dense woods separates the site from the Plymouth High School, the Boy Scouts of America facility, and residential properties. There has been visual evidence that people trespass onsite and use the docks for recreational fishing in the Roanoke River. 1.2.4 Surrounding Land/Water Use The principal land use in the immediate vicinity of the site is residential and institutional. The citizens of Plymouth have water supplied from one of three sources: the city of Plymouth Public Works Water System, the Washington County system, or private wells. The city and county water supplies are obtained from 4 municipal wells located within 1-2 miles southwest of the site. It is not known how many private or community wells are currently being used within a four-mile radius of the site. There are no surface water intakes located within a fifteen-mile surface water pathway downstream from the site. 1.3 Environmental Setting 1.3.1 Physiography /Topography Washington County, North Carolina lies in the Atlantic Coastal Plain Physiographic Province. This portion of the Atlantic Coastal Plain is primarily characterized by CDM Fe<lcral ProJ.:r.tms Cmporatiun SPINB2/SEC1.WPO 1-8 I I I I I I I I I I I I I I I I I I I Section 1 Introduction extensive, flat coastal swamps and marshes. Approximately half of the land mass within a four-mile radius of the site is wooded marsh or wetland. The elevation of the site is approximately 5 feet above mean sea level (ms!), and is slightly below 5 feet ms! in the nearby wetland areas. Elevations increase to 15 feet ms! to the south of the site. 1.3.2 Climate/Meteorology The climatological data for Washington County, North Carolina is representative of the climate in the Plymouth area. Northwestern Washington County has a mean annual precipitation of approximately 50 inches and a mean annual lake evaporation of 41 inches. Therefore, the net annual precipitation is 9 inches. The 2-year, 24-hour rainfall is approximately 4 inches. 1.3.3 Geology The regional geology of Washington County is characterized by complexly interbedded sediments. The sediments are unconsolidated and consist primarily of sand, silt, and clay transported by streams from the adjacent uplands of the Piedmont and Blue Ridge Provinces. The surficial sediments at the site are approximately 25 feet thick, and are underlain by a confining layer which is 25 feet thick. The primary geologic units in the Plymouth area are the Yorktown and Duplin Formations. The Yorktown is generally characterized by fine-grained sands interspersed with varying amounts of silt, clay, and shell beds, and sandy and silty limestones, while the Duplin Formation contains fossiliferous sand, sandy limestone, silty limestone, and calcareous silty sand. The majority of the onsite soil is described as Tarboro sand, while the soil in the adjacent wetlands and the small stream surrounding the property is described as Muckalee loams. Tarboro sand is an excessively drained soil normally found on low broad ridges commonly adjacent to the Roanoke River. The surface layer of this soil is low in organic matter content. Permeability is rapid and the available water capacity is low. The soil is well suited to most urban uses and provides a good support for most structures. The Muckalee loam is a nearly level, poorly drained hydric soil. It is subject to frequent flooding. CDM Fed~r.11 Programs Curporntion SPINB2/SEC1.WPO 1-9 I I I I I I I I I I I I I I I I I I I Section 1 Introduction 1.3.4 Hydrogeology The surficial aquifer in the area of the site is comprised of approximately 25 feet of surficial deposits, underlain by a 25-foot confining layer. Depth to the water table in the surficial aquifer at the site typically varies from 3.5 to 5 feet below land surface (bis). Although no water level measurements have been collected at the site, typical hydrogeology for such a site dictates that groundwater in the surficial aquifer most likely flows toward and discharges into the Roanoke River during normal baseflow conditions in the Roanoke River. The surficial aquifer and the 25-foot confining layer are underlain by 40 feet of sand and marl of the Yorktown Formation. The Yorktown Aquifer is a confined aquifer which serves as a major source of water for portions of Washington County. The Yorktown Aquifer is underlain by the confined Pungo Aquifer, which can be reached 90 feet below the land surface. The Yorktown Aquifer is underlain by a 25-foot confining layer. Below this confining layer, the Castle Hayne Aquifer can be reached at a depth of approximately 115 feet bis. The extent of water withdrawal from the aquifers overlying the Castle Hayne in the vicinity of the site is unknown; no groundwater targets have been identified for aquifers in the area other than the Castle Hayne. The Castle Hayne Aquifer serves as the principal source of groundwater in the Plymouth area, and consists of porous and permeable limestone, sandy limestone, and sand. Hydraulic conductivity values in the Castle Hayne Aquifer range from 15 ft/ day to 200 ft/ day. The Castle Hayne Aquifer in the Plymouth area can be reached from 150 to 180 feet bis. Recharge to the surficial aquifer is directly from precipitation. Recharge to the underlying groundwater system occurs primarily in the upland interstream areas where the sand layers crop out. Discharge from the system occurs by seepage to streams, estuaries and the ocean. Movement of water from the recharge areas to discharge is controlled primarily by the hydraulic gradients of the dipping beds. COM Federnl Proi:rams Cmporn1ion SPINB2/SEC1.WPD 1-10 I I I I I I I I I I I I I I I I I I I 1.3.5 Surface Water Hydrology Section 1 Introduction The site is located immediately to the south of the Roanoke River. The Roanoke River receives surface water from the site through direct runoff, and from several onsite intermittent drainage ditches. The surface water pathway flows in an northeasterly direction along the Roanoke River for approximately 6 miles, where it flows into the Albemarle Sound. Surface waters in the Albemarle Sound flow eastward towards the Atlantic Ocean for the remainder of the 15-rnile surface water pathway. 1.3.6 Wildlife and Natural Resources The Roanoke River is classified as a "Class C" river with an "Sw" supplemental designation. Class C waters are protected for aquatic life propagation and survival, fishing, wildlife, secondary recreation, and agriculture. A fish consumption advisory has been in effect for a period of years along the lower Roanoke River due to elevated levels of dioxin in fish tissue. There are extensive wetlands around the site; however, there are no known critical habitats of Federally-listed endangered species within the vicinity of the site. There are several endangered and threatened species in Washington County, North Carolina, including the bald eagle as a state and federally- designated endangered species, and the golden eagle and the Waccamaw killifish as state-designated endangered and threatened species. 1.4 Site Operations History The site was originally owned and operated by the Atlas Plywood Company. There is no information regarding Atlas's operations and waste management practices. Georgia-Pacific reportedly bought the facility in 1950, and operated the facility until 1980 employing approximately 400 workers. Site operations involved debarking, sawing, and planing rough hardwood timber from logs. Surface treatment of some finished lumber took place using a conveyor belt and dip vat. The sawmill facility was permanently closed after a 1983 fire destroyed the sawmill. Georgia-Pacific sold the property to Decatur Partnerships, and the site was leased to Outerbanks Contractors who used a portion of the site as an asphalt mixing plant, employing approximately 10 workers. Allegedly, during the time of the asphalt mixing plant operations, a spill of trichloroethene (TCE) caused by the North Carolina Department CDM Fe<leml Prn):rntns Corporation SPINB2/SEC1.WPD 1-11 I I I I I I I I I I I I I I I I I I I Section 1 Introduction of Transportation occurred in the Former Finished Wood Products Storage Area/Outerbanks Contractors Asphalt Mixing Plant area of the site. The amount of the spill was not determined for this report. The entire site is currently unoccupied and inactive. The wood treating process at the site involved passing wood through a dip vat located on a conveyor system, where the wood was surface coated with preservatives and/ or insecticides. After treatment, the wood was reportedly allowed to drip dry directly onto the ground or onto concrete pads before being placed in the lumber storage areas. The dip vat solutions contained pentachlorophenate, sodium meta borate, lindane, and other chlorophenol compounds. Georgia-Pacific's Resource Conservation and Recovery Act (RCRA) Part A Permit Application identified process wastes associated with the facility included spent oil containing metals (D001-ignitable/D007-chrornium, D008-lead), spent halogenated degreasing solvents (F001), spent non-halogenated degreasing solvents (F003/F005), and bottom sediment sludge from the treatment of wastewater from the wood treating process (K001). The amount of waste generated on a yearly basis by Georgia-Pacific was estimated to be 20,000 pounds of D001/D007 /D008 waste, 375 pounds of F001/F003/F005 wastes, and 16,300 pounds of K001 waste. Wastes were either incinerated onsite or transported to the county landfill. 1.5 Previous Sampling Investigation Results Prior investigations at the site include the Preliminary Assessment conducted by the North Carolina Division of Health Services on December 6, 1985, the Phase I Screening Site Inspection (SSI) conducted by the NUS Corp. on October 11, 1989, the Phase II SSI conducted by Greenhorne & O'Mara Inc. in September 1991, the Site Inspection Prioritization (SIP) conducted by the Dynamac Corp. on April 15, 1994, and the Expanded Site Inspection conducted by the North Carolina Department of Environment, Health, and Natural Resources in June 1995. Sampling was performed only during the Phase II SSI and the Expanded Site Inspection. During the Phase II SSI, 4 surface soil samples, 2 drainage ditch soil samples, and 3 temporary well point groundwater samples were collected. During the Expanded Site Inspection, 5 surface CDM Federal Programs Corporation SPINB2/SEC1.WPD 1-12 I I I I I I I I I I I I I I I I I I Section 1 Introduction soil samples, 1 drainage ditch soil sample, and 3 surface water/ sediment samples from the Roanoke River were collected. The analytical results from these investigations indicated that onsite soils have been contaminated as a result of past operations. ·Elevated levels of dioxin/furan isomers, metals, pesticides/PCB's, as well as purgeable and extractable organic compounds were identified in the soils in the dip vat area during both sampling investigations. Elevated levels of many of these compounds were also detected in the sediment samples from the drainage ditches which carry site runoff to the Roanoke River. In addition, the Phase II 551 results indicate that onsite groundwater may have been contaminated with VOCs, pesticides, and metals. However, no groundwater samples were collected during the 1995 ES! to confirm these results. Surface water runoff from the site has resulted in site-related contamination in the Roanoke River. Sediment samples collected during the 1995 ES! indicated the presence of elevated levels of aluminum, arsenic, iron, lead, pentachlorophenol, (3 and/ or 4) methyl phenol, benzo(b/k) fluoranthene, the dioxin/furans congeners 2,3,7,8- tetrachlorodibenzodioxin (TCDD), 1,2,3,7,8-pentachlorodibenzodioxin, 1,2,3,4,7,8- hexachlorodibenzodioxin, octachlorodibenzodioxin, and 2,3,7,8-tetrachlordibenzofuran. 1.6 Nature of Problem As indicated above, many chemicals have been identified as having contaminated various media at the site. Dioxin and pentachlorophenol are two of the principal contaminants found in the onsite surface soil and river sediments. General physical, chemical, and toxicity characteristics of these contaminants are presented below: • CDM Federal Prn,:rnms Corporacion SPINB21SEC1.WPD Dioxin -Chlorinated dibenzo-p-dioxins are a class of compounds referred to as dioxins. One form of dioxin, TCDD, is the most toxic form of dioxin in humans. It is a colorless solid with no known odor. TCDD does not occur in nature. Exposures to high levels of TCDD can cause chloracne, a severe skin lesion that usually occurs on the head and upper body. There is suggestive evidence that TCDD may cause liver damage, and is suspected of causing cancer. 1-13 I I I I I I I I I I I I I I I I I I I • Section 1 Introduction Animal studies also suggest that exposure to high levels of dioxin may cause liver damage in certain species. Exposure can also cause loss of appetite, weight loss, digestive disorders, and death. Dioxin exposure may also result in abnormal reproduction of offspring. Exposure to TCDD has been proven to cause cancer in certain animals. Pentachlorophenol -Pure pentachlorophenol exists as colorless crystals with a very sharp odor when hot, but little odor at room temperature. · Pentachlorophenol in impure form can appear dark gray to brown dust, beads, or flakes. Pentachlorophenol does not occur naturally. It is widely used as a wood preservative for power poles, fence posts, lumber, etc. Short-term exposures to pentachlorophenol can reportedly cause harmful effects on the human liver, kidneys, skin, blood, lungs, nervous system, and intestinal tract, and can cause death. The inhalation of the sodium salt of pentachlorophenol by animals has proven to be extremely toxic. Thus, the results of the previous investigations indicate a threat to human health and the environment may exist at the site. However, because the previous investigations did not fully define the nature and extent of the contamination, further site characterization was required to identify and assess the health and environmental concerns related to the exposure routes substantiated through the previous investigations. 1.7 RI Field Investigation Summary The primary objective of this RI was to provide the additional data needed to adequately support a baseline human health and ecological risk assessment, and to provide a basis on which to recommend a subsequent cost-effective remedial action plan, if necessary. Note that this RI focused on all aspects of the Georgia-Pacific Site south of the Roanoke River. Because, the Roanoke River is a large and complex surface water body that may have been affected by many other sites or sources of contamination upstream of the Georgia-Pacific Site, the sampling and analysis of Roanoke River samples was not included in this RI. Instead, a separate RI is currently being conducted for the Roanoke River which can better address the potential multi-site releases of contamination to this surface water body. CDM Federal Pmi::rnm, Corporation $PIN82/SEC1.WPD 1-14 I I I I I I I I I I I I I I I I I I I Section 1 Introduction The first step in the remedial investigation, after the project plans were developed, was a field investigation. The field investigation included the following tasks: • • • Soil Sampling -A total of 70 surface soil and 67 subsurface soil samples (not including duplicates) were collected from various locations on-and offsite. The number of soil samples collected from the various areas are as follows: Area Sawmill Plant Area School and Boy Scout Area Residential Areas Surface Soil Samples 55 7 8 Subsurface Soil Samples 67 0 0 . All of the surface and subsurface soil samples were sent to a CLP laboratory for complete TCL/TAL analyses, except one. One of the surface soil samples was not analyzed for VOCs. In addition, 60 of the surface soil samples and 19 of the subsurface soil samples were analyzed for dioxins/ furans by a CLP laboratory. Surface Water/Sediment Sampling-A total of 3 surface water and 7 sediment samples (not including duplicates) were collected from the intermittent drainage ditches onsite. All the surface water/ sediment samples were sent to a CLP laboratory for complete TCL/T AL analyses. In addition, all the sediment samples were sent to a CLP laboratory for analysis of dioxins/ furans. Temporary Well Installation and Groundwater Sampling-A total of 5 temporary shallow monitor wells were installed. Groundwater samples were then collected from these 5 temporary monitor wells, as well as 9 existing shallow monitor wells installed previously at the site. All groundwater samples were sent to a CLP laboratory for complete TCL/T AL analyses. 1.8 Removal Action In August 1999, after the RI field investigation was completed and the analytical results were received from the CLP laboratories, the PRPs conducted a removal action at the site under order by EPA to "abate the imminent and substantial endangerment of the public health, welfare, or the environment that may be presented by the actual or threatened release of hazardous substances at or from the site." All the activities conducted during the removal action are described in detail in the Removal Action Summary Report(BBL Environmental Services, 1999, later referred to as BBLES). COM Federal Pm1;m1m Cmptir-Jtitm SPINB2/SEC1.WPD 1-15 I I I I I I I I I I I I I I I I I I I Section 1 Introduction As indicated in the above sections, two buildings were demolished and three storage tanks were removed from the site during this removal action. The main activity of the removal action, however, was the removal of soil with concentrations of contaminants (as determined from the RI sampling investigation data and data collected during the removal action) exceeding the following site-specific removal action levels (SSRALs): • • • • • • • • • 2,3,7,8-TCDD; 1 ug/kg Dioxin expressed as 2,3,7,8-TCDD toxic equivalent quotient; 1 ug/ kg Pentachlorophenol ; 25 mg/ kg Total PAHs; 100,000 ug/kg Total cPAHs; 50,000 ug/kg Arsenic ; 30 mg/kg Chromium (total) ; 200 mg/kg Chromium VI ; 90 mg/kg Lead; 400 mg/kg Soils exceeding these criteria were excavated and transported offsite to a secure landfill. The excavated areas were then backfilled and compacted to pre-existing grade with clean soil. Prior to conducting the soil removal activities, several additional soil samples were collected from specific site areas to better characterize the soil concentrations. In addition, after conducting the soil removal activities and prior to backfilling, several confirmation samples of soils were collected to ensure that all the soil exceeding the removal action levels was removed. The original RI soil sampling data and the subsequent excavated grid confirmation sample data are presented and discussed in Section 2. 1. 9 Overview of Report The remainder of this report contains descriptions and results of the sampling activities performed during the RI and the Removal Action. Brief summaries of the remaining sections are presented below: • COM Federal Program~ Corporation SPIN82/SEC1.WPO Sections 2, 3, and 4, discuss the results of the soil, surface water/ sediment, and groundwater sampling investigations, respectively. Each of these sections describes the purpose of the investigation, outlines 1-16 I I I I I I I I I I I I I I I I I I I • • • COM Ft:<leral Pni11rums Corporation SPINB2/SEC1.\"/PO Section 1 Introduction the methodology for sampling, and summarizes the results of the investigation. Section 5 presents the results of the contaminant fate and transport analysis. Section 6 presents the Quality Assurance Report which summarizes and quantifies the RI analytical data and especially the quality control data. Section 7 summarizes the results of the remedial investigation and presents the conclusions reached based on these results. 1-17 I I I I I I I I I I I I I I I I I I I 2.0 Soil Sampling Investigation 2.1 Purpose and Scope The amount of pre-remedial investigation data and information accumulated on the GP Site was insufficient to complete a baseline risk assessment to adequately develop a practical and effective remediation plan for the site. In August 1998, the USEP A Region IV SESD prepared a Remedial Investigation (RI) Work Plan to obtain the additional data needed. The Work Plan described the field investigation methods and procedures for collection of onsite and offsite soil for determining the nature of, and the areal and vertical extent of contamination in soils at the site. Upon receipt and review of the analytical results of the RI, EPA determined that a removal action was necessary at the site to address the potential of impact on human health and the environment. Prior to the mobilization of removal action contractor, EPA established site-specific action levels for nine constituents of concern (COCs) detected in soil and intermittent drainage ditch sediment at the site. These site specific action levels (SSRALs) are provided in Section 1.8 of this report. The RI analytical data were compared to the SSRALs and grids were identitied where the action levels were exceeded. Once a grid was excavated, soil samples were collected to confirm that the remaining soils were below SSRALs. The RI and removal action confirmation analytical data will be discussed in the subsequent sections. 2.2 Methods 2.2.1 Remedial Investigation Soil Sampling For the RI field investigation, a grid system was established throughout the GP site property as shown in Figure 2-1. Figure 2-1 also shows the general offsite sampling locations at various residential, school, and Boy Scout properties. Fifty-five grids were used for the onsite sampling. For the surface soil sample collection, one composite sample was prepared by collecting five aliquots within each grid. As stated in the Work Plan, one aliquot was collected from the center of each grid. The four other aliquots were located approximately 35 feet, 60 feet or 85 feet from the center of the CDM Federal Programs Corporation SPIINB2/SEC2.WPD 2-1 0 250' - - -- - Roanoke River 500' -I Georgia-Pacific Hardwoods I Plymouth, North Carolina Scouts 0 Hut c:2201-SLA ■ GP-202-SI..A • <:> ■ GP-203-SLA Football Field LEGEND: OP-205-SU. • 211c O Onsite and 0ffsite Soil Sampling Locations N 0 0 0 D SURFACE SOIL SAMPLE LOCATION 0 0 0 0 0 0 COMPOSITE SURFACE SOIL SAMPLE LOCATION GRID RIVER TREE LINE RAILROAD Figure No. 2-1 ~ CDM Federal Pr!'.!,"•ms Corporation ~.__•_-__ "_"""_-_• __ ... ______ .1.... _____________________________ L_..:7!../.:;:o::::o __ ...J i L i I ' I I I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation grid, based on the grid sizes of 100 by 100 feet, 150 by 150 feet and 200 by 200 feet, respectively, at angles 0°, 90°, 180°, and 270° from north. Some deviations to this sampling procedure were necessary due to conditions encountered at the site. In some grids only the grab sample from the center could be collected and in other grids some of the aliquot locations were not collected or were collected at different locations within a grid other than the distance or angles described above. The surface soil samples were collected from Oto 6 inches below land surface (bis). The samples were analyzed for volatile (VOA) and extractable organic compounds (SVOAs), pesticides, polychlorinated biphenyls, metals, dioxins, and dibenzofurans. The VOA soil sample was collected as a grab sample from the center of the grid. For the subsurface soil, a grab sample was collected from the center of each grid at a depth of 18 to 24 inches bis. In addition, subsurface soil samples were collected from grids 25 through 55 at a depth interval of 35 to 42 inches bis. As above, a few of these subsurface soils could not be collected due to subsurface obstructions preventing use of hand augering. Surface soils were also collected at fourteen locations on residential properties adjacent to the site. These samples were collected as a composite of five aliquots and were analyzed for the same constituents as onsite soils. Analysis of RI samples was performed by EPA' s contracted laboratories. Data validation of the RI analytical data was performed by Region IV SESD Office of Quality Assurance and Data Integration. 2.2.2 Removal Action Soil Sampling In general, five point aliquot composite samples were collected and the samples were analyzed for the same constituents as the RI data by a laboratory subcontracted by BBLES, Savannah Laboratories and Environmental Services, Inc. in Savannah Georgia. The RI data were compared to SSRALs and the following grids were planned for excavation at the depths given: • Grid 39 - 1 foot; CDM Fo:icral Programs Corporation $PIINB2/SEC2.WPD 2-3 I I I I I I I I I I I I I I I I I I I • • • • • • Grid 40 - 1 foot; Grid 41 -2.5 feet; Grid 44 -2.5 feet; Grid 46 - 4 feet; Grid 47 -1 foot; and Grid 49 -2.5 feet Section 2 Soil Sampling Investigation Following the excavation of the grids, one five-point composite sample was collected from the surface of each of the seven excavated grids and these samples were analyzed for the constituents of concern that originally exceeded the SSRAL. The USEP A also collected and analyzed split samples of these confirmation samples collected by BBLES. The BBLES results are presented below following the RI sampling results. 2.3 Summary The analytical results for surface and subsurface soil samples collected onsite and offsite in the residential neighborhood are summarized in Tables 2-1 through 2-4. Table 2-1 presents the volatile and extractable organic constituents detected. Table 2- 2 presents the pesticide and PCBs constituents detected. Table 2-3 presents the dioxins and furans detected. Table 2-4 presents the inorganic constituents detected. Note that for the purpose of summarizing, only chemicals detected at least once in each medium and their measured concentrations are presented in the summary tables. The complete data set of analytical results for the CLP laboratory analyses performed are provided in Appendix A. In the tables the following sample identifiers were used: • • • • • The SLA on the sample designation was a soil sample collected from 0 - 6 inches below land surface (bis); The SLB represents a soil sample collected from 18 -24 inches bis; The SLC represents a soil sample collected from 36 -42 inches bis; The numbers 00X in GP004SLA corresponds to the Grid number. The residential soil samples are represented by the 200 series designation, for example, GP204SLA COM Federnl Pn~nuns Corp,1rnti<1n SPIINB2/SEC2.WPD 2-4 ----- CHEMICAL VOLATILE ORGANICS EXTRACTABLE ORGANICS -- - - - - - -- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA - GP001SLA GP001SLB (Duplicate) GP002$LA GP002$LB GP003SLA GP003SLB GP004SLA Pat.a OualifJers· U = Material was analyzed but not detected. The number is the minimum quantitatlon limit NA= Not analyzed. J = Estimated value Concentrations presented in ug/kg Section 2 Soll Sampling Investigation GP004SLB 1 of 18 ----- - CHEMICAL VOLATILE ORGANICS -- - - - - --- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP005SLA GPOOSSLB GP006SLA GP006SLB GP007SLA GP007SLA (Duplicate) GP007SLB Section 2 Soll Sampf/ng Investigation GP007SLB (Dupllcate) 1,1-qlCHLOROETJ-{ENE (1, 1-QICH_LORQ_ETH~~~-NE), :·1 : :-i.l2 -. 1]'.:!J,·:··•,,2\ ~-.>~Ji-=_Q{~,?::?JJ~U:Qii~;~~ :.-~~;;i:f{f((!..'.t_~~~{~[Jt1P:~;;\;:?:~ :i:.f1Ji',\ ~-~t!;~f.;-~·j'i_ LJ:· -~,-. ~:-11 u 1,2-DICHLOROETHENE (TOTAL) 11 U 11 U 11 U 11 U 11 U 11 U 11 U 11 U CARBON DISULFIDE-~ . ·-·::-, ~'.:_ ;-~~ ~:;~,_1-.-.-:•;;_,.:. D .u :.,:::<.-:'?~•--' Jii9.~i?;~sr;·~~f ~t!.'~t:~~~ ·0iJ:JJl!::-lf.f!!Xf.,1}1Q/_>,:-={J~·\\tJj~-~.;.,::_::;r!::t:::;.:J1(Q:'"-J: _:-:._-;,.;:,~:-"\1: ·u METHYLETHYLKETONE 11 U 11 U 11 U 11 U 11 U 11 U 11 U 11 U TETRACHLoRoETHENE ctETRACl:i~oR0EtHv11t.f~i. ,.,: :' ·: 1 \:~~d.::;i, :\ '':'!'.'lfQJ;:i;"':::~:, I 11r.:;-: ;;;~;'3TI"1'"'i-i'~J.ZJ"-~'iF9 ,tr:,-.,? -:'1 fy· ??'·::-·.Ji p-__ : _':\ .. _1 r~ . TOLUENE 11UJ 11UJ 11U 11U 11U 11U 11U 11U TRICHLOROETHENE (TRIC.H~QRO~THYi..E!'Jg) ··(1• ~: ~_ .• 1: 1,:· r·:~ ::.:;,~~~::v=·{:-,.t· ·:~;Jj£Jt:;:~~~~-::_'"fFQ/:t;L<f#fifi}~k~"~1IJf_l){;f~bi~?•~:1~. 0'-~·:.,\?,·;~---._11 q•~ · ·. · y . ·. 11 Ll· EXTRACTABLE ORGANICS 2 of 18 ----- - CHEMICAL VOLATILE ORGANICS ---- - - --- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP008SLA GPOOSSLB GP009SLA GP009SLB GP010$LA GP010SLB GP011SLA Section 2 Soll Sampling Investigation GP012SLA 1, 1-0/CHLOROETHENE (1:1-DICHLOROETHYbE_NE); ;,:,, ._,·:(:'; '11 u . . ;•_;· .1fli'''.'. ;: ", . _j_)'QC;L •''•~t."':~fQI'f -i"l.1/':if\i'?-";:·-•:;::11 '[.r ,.,. 11· u. 11 u 1,2-DICHLOROETHENE (TOTAL) 11 U 12 U 11 U 59 UJ 11 U 11 U 11 U 11 U CARBON DISULFIDE .. ' ;-;:-, ·. ··,ifi.i,; .. ,'. ,· ~~ci'Q•.~••c?. Tiu.::-' ';'.-".'sT~1·:tJ<:;?}'iVO:S:•,··:;_,;:'JJ:_uc :,-Jiu.>· . 11 u METHYL ETHYL KETONE 11 U 12 U 11 U 59 UJ 11 U 11 U 11 U 11 U T~TRACljLOROETHEN~. (TET_RA_CH~Q89~t8Y}l~!'{E)'~~.~.;::;;_·.::: r·. 1-i. Q:":,:;:·•.-i,~ ·f ~1r1u:-'4:,:-t;:<j.f~.O~'lsf'~-? .?9. Q'"J~-:~~~-;~f~ffQ·. ~-i':-~;-f~~_:J} p .•' -,~.~-:_:·_::~·;:,j_Llf'_~· .' ~:~ : 11 u TOLUENE 11U 12U 11U 59UJ 11U 11U 11U 11U TRICHLOROETHENE (TRICHLORO$THYLEN_E) ,);;.:!,> --. ,, . ';_ fr u}:'_5 . :-rnc: :i:.: :: -.-. 'ii'1'1:E' . .''' ··;_'~t~J?~';;/ff\f'::,'.:.:.t( i (U, '. '.' . h U 11 U - EXTRACTABLE ORGANICS 3 of 18 --- -- --- - - -- - TABLE 2-1 ---Section 2 Soll Sampling Investigation SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP013SLA GP013SLB GP015SLA GP015SLB GP016SLA GP016SLB GP017SLA GP017SLA (Dupllcate) CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROEJHENE (1_, 1-DICHLORO~THYL~NE) . --· .. i -11 0 1,2-DICHLOROETHENE (TOT AL) 11 U CARBON DISULFIDE ., -- · ·. ·.-,;so 1J :, METHYL ETHYL KETONE 11 U TETRACHLOROETHENE(TETRAGHLOR()ETHYLEJ'!Ec) . .:":.... -·_. _,ff_((,:.: - TOLUENE 7 J TRICHLOROETHENE (TRICHLOROETHYLENE). . . ,· 1_1 jj'. _ _,;" EXTRACTABLE ORGANICS 1j Q?~. ·:~ ··:(!j',l_!-.:-~·.-r~~\>.;~·f~:;!i~:{",'-Sr°:·::-:t:\:1f~ji.-::(:';. ·,·~1 \I_. . 1_Q lt 11U 11U 12U 11U 11U 10U . 1,j .9·.~-::.,'. /i,(:. il Q.{~·rf~-::.: :·· J~1JJjf-;'.~c\•.;,,··, ''.,'.t::69,Q!';, ~};.:,. /?Ti !-!-. : :-. ,·,.•,;:_ ~-,:JO µ~ \·, 11U 11U 12U 11U 11U 10U . n--~:i. ~ ffQf:o,i,'.:._:,:·ir~u~trtr~~~.,rrP: -~:<r .... ,:: ";Ti-~-. --1Q ~ .. ~-. · 11U 11U 12U 11U 11U 10U ·~ 1.f!J.•~---_ ... : ·_,-._ 1r\r· ~:/~--?-·· jf~T ;~·t~r~~~/ d"f-D.--~--:···~ ~-·~-11 ·u -.10 Y~;:~ _ .. 10 U 10 U 10 U 10 U 10 U 10 U 10 U 4 of 18 ---- --- -- - ---- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA 111!!1 Section 2 Soll Sampling Investigation GP017SLB GP017SLB (Duplicate) GP018SLA GP018SLA (Duplicate) GP019SLA GP019SLB GP020SLA GP020SLB CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1,1,DICHLOROETHYL~Nl~f .r. . .. '''1 j LJ . ·:, : 1j Uf) ·.·'· .. · S:c11' iJ. ,·./'.' :''. f1:[:·:'.\J;C:: 1,(i,i,:',l'\{· ':r.11 .U:'>''· 1,2-DICHLOROETHENE (TOTAL) 11 U 11 U 11 U 11 U 11 U 11 U CARBON DISU.LFIQE ~ ·:,<;: ·~f1.·P-£ • · ·1f:Qr}:;'_•:;_!.~::·J1;_~0,:t~~,~(_",,JjJ{J\;_..:.\;f:, _ _.~ .If.Q~;/_/:;, ·.1j,._Qt'_:;•~. METHYL ETHYL KETONE 11 U 11 U 11 U 11 U 11 U 11 U TETRACHLoRoETHENE (TETRACHLORoErHff~f!~Y >,,,. :. , ::~H:i;i. ·: .. \' · 1 LQ,:t:'.:,,,,:\ffu· ";"'J~~t11r0_;.,,:·tr,':c-1-r1:i:.•· ""· c,ff il TOLUENE 11 U 11 U 11 U 11 U 11 U 11 U TRICHLOROETHENE (TRICHLQROETHYLENE)' '¥ '/: ': ·, , 1,f'.I],?/ '., ';•, ,ffjJ_;?,}".?}: ';f.ft,J,'',')',;::;:,'.: 11'lJj,:J,f2f;:)!'!,Ji ',1, ••, i' ;_ ii,itf;• c . EXTRACTABLE ORGANICS .,_ '!.~ LJ,'. ' 12 U :•12 Li_, ,i 12 U '12 IJ. > 12 U · '12u:> 5 of 18 12 U 12 U 12 U. 12 U 12 U 12 U 12 U == -------- --- ---- --Section 2 Soil Sampling lnvestJgaUon CHEMICAL VOLATILE ORGANICS TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP021SLA GP021SLB GP022SLA GP022SLB GP023$LA GP023SLB GP024SLA 1, 1-DICHLOROETHENE (1,1-CllCHLOROETHYLENE) ... >.• ·:,c-. ._, 12 LI ;l' ' _1 Hh, ::.:_ ::. Jiy:; :~ ..• i)i1,.u: 2,.'.;>· .1?:Ll : '\:-~. _:1i 1:r -)1.UJ 1,2-DICHLOROETHENE(TOTAL) 12U 11U 12U 11U 12U 13U 11UJ CARBON DISULflDE . . . . .: :~·•. ~ ·., f~ ~/; · ,' fj._q,; :.:i·.:~:\ <itQi;_:·,_. f~i-!:tJ.1 -~·'•,~::,.\:,:.;-: .·:_,, g;y;;;;f.::t/,.tftQ i:-:: ~. :. '~~i:·~; . METHYL ETHYL KETONE 12 U 11 U 12 U 11 U 12 U 13 U 11 UJ TETRACHLoRoETHENt /TET~<;HLoR9EfHYLE:~ei ', ,:',>·: :c12Ji• ;.,_, ·,· .. ·· 11:yc;-,:-,.,.,.,_,:-inf'.,', ,,-.,-;/H V.''''': ~· , : WJ!.'i\r::;;-·:1) _u_,.\,; .-... ... 11 _uJ_ TOLUENE 12 U 11 U 12 U 11 U 12 U 13 U 11 UJ GP024SLB rn1cHLOROETHENE crR1c;HLORoetHYLENE> -. , ,. · 12 u . ,. . ; .. 1 i'l.1 :~: :,,.:: w.:Q ·,-·::;;1;;: :::u:.Ji.-::.J1.·:";_ 1tQ:::.:L,·,_;:,i3 u.;.::,,-. _11 uJ .•• 12 U, 12 U 12 U 12 U 12_U 12 U 12 U EXTRACTABLE ORGANICS (3-ANo,oR 4-JMETHYLPHENQL'. . . , 3Jg li ,· : ·. 31q·i/· . ,:·>,, :i]!9.,u_.;,,,:; :_;:,tfo·I,!;:\ ... ;; -'@cf•Qd,~•\ ... ,.~49 u:;_·,·:: 1400 u . : .~oo u 2,4-DINITROTOLUENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U , 2500 J 2-METHYLNAPHTHALENE · 37.Q u , . :iiQ._l/' -. :•.:::.:,__3~_ci Q· " , ':ito u•· -~ '::·: :\iliiLO:; : · .. .'~Q u: ·:, • 1400 y. · , s6oo u ACENAPHTHENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U ACENAPHTHYLENE ·. ~t□i.i-, . :½o.u ·,: ')ii.11:t:i:::. 3t,qg',;.~;;"''''1@_u_,,'.1.1;:¥QT1 -·· ._Hq_qu ~6o_ou ANTHRACENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U BENZO(A)ANTHRACENE_ . . ··''.·~-":~tQ _Q,; :_ . ·:, 340 U "'' .. ·• '~:0 u._,.c[:"::7':·:,_:i]Q ld'·'.0~n••:_;~11_i:i:9._ ·-~·:J?,::..'¥.~.\J.-, ; , : . ;j~oil _l,i.-. , ,5600 U , BENZO(B AND/OR K)FLUORANTHENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U . · 1400 J BENZO(GHl)PERYLENE ' . . . . ;_ ' : . f ,· ,' . .-:~?,(i l,i ,. ·. ':: 34o;u >'. :-~SQ (p,;;;,',j'::·~10 :q;:~1;.'c·_ ~ ~()Q__l]'/•4·'' ,AfO 1.1,:,•, ~;i~OQ LL' >.:. ?600 u BENZO-A-PYRENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U GA~BAZOLE ' · · ~~-•. :;,:."~ · r,-·: ,:·c ~J.::)Iii?Q. ~r.·.··-·:; ,:.'. ~~:f!.i:f.Q· ;·:· '::--~ ~~lQ Y).:~~~·lliiI?Jt1I~~;f,.:;t/~QiL~~:-·.}/J~¥JfJt,~.-.t -~·-1400 u: : -~6qo I..! CHRYSENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U DIBENZO(A,H)ANTHRAl::l(NE . • • " ·,. . . ,· <, •\;0:;.-\~ZQ. u,.:: :': <,.3-19.LW' , . .,_,;:T:;' .~Q:)J iti::il::~·w!L\:J[£t~.'ili.q]F:')'l''-".i;i~~ Q;:/',:,.:~' 14o_Q W ·c:. :, !}60,0 lJ, DIBENZOFURAN 370 U 340 U 380 U 370 U. 400 U 440 U 1400 U 5600 U FLUORANTHENE : :··; · ,, ~<?~~;;::f11~~?.Q•Q~~:·,:~ .. --~; .. ;.J1.cF"Q ·::-:~~i}l:~:~I~EQ.7.=:J;:C1~?R J&1 :;:;~i! ]f&;Q:!~~~sf.J.;J~if.:Y)-~~:t X· 140Q_4:.'. /: ·! ::.~~Q.]; _ FLUORENE. 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U IND~NO (1,2,3-CD) .PYRENf_ •. '· :· ;.; .· ·. "'·. : ?ii jf.fi,ifO: U':' ': '.l4_Q'Q' ; _ t';';~fil[,jl;:/: ~~illQ. uli::}"-;ci''.':4o\FQ ;;1'·:c:J':t,¥]:_Q\, : ·;:,_1{<)Q u ~--·::· ~60,0 !,J, N-NITROSODIPHENYLAMINE/DIPHENYLAMINE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 5600 U ~APHTHALENE --, ·· .. · . ;, .... -_~::.···:··:f.'~· .. -_. {}370:_~ · _..:;~~i';:<M!f[ :; .. ~:\-:., )~lY]~f/~.~:-~~~711o'"Qff~t;\~~-~Q~i!J'-I/~-\:Dt~~44~iJ .. ;/:j:. _:·: '14Q.Qj.J_:-;.;• ,'-·.~··s~90 y_ PENTACHLOROPHENOL 920 U 860 U 970 U 930 U 1000 U 1100 U 3400 U 14000 U PHE~ANTHRENE .• · .• ·~ ,;• . .J-' .. '· •• X .. :/::~:,t-.~ ,3701!,lfti~-?}f. 34f\f.-_1~~w •:3s{);_UJ:f::~;;1:3·i9,y::;r~·41~:f!Q['·P;~?fi~[/~{:H.Q·1t-:s-Jt~Y/i~QQ:jl i;: .. < -~§0Q..Y.: PYRENE 370 U 340 U 380 U 370 U 400 U 440 U 1400 U 580 J 6 of 18 ------------ TABLE: 2-1 SOIL SAMPLING SUMMARY· VOLATILE: AND EXTRACTABLE: ORGANICS GEORGIA-PACIFIC SITE: PLYMOUTH, NORTH CAROLINA ---Section 2 Soll Sampling Investigation GP025SLA GP025SLB GP025SLC GP026SLA GP026SLB GP026SLC GP027SLA GP027SLB CHEMICAL VOLATILE ORGANICS 1,1-DICHLORQEJ"HENE {1_, ~-DICHLORQf[HY~~N~):,'. · -~'-.:.: .. ,. '- 1,2-DICHLOROETHENE (TOTAL) CARBON DISULFIDE METHYL ETHYL KETONE TETRACH_LOROETH~NE (TETRAC:HLORQ~TtJ'(l~NE) TOLUENE TRICHLOROETHENE (TRICHhOROETrlYL~N!c) .'· ' · EXTRACTABLE ORGANICS uli :::.:-r._.:11 l!: 1tu <.:/;~; 11.:i:iLJ'.:'.·,11-I/,, ·> 11 u• ·11 u, • 11 U 11 U 11 U 11 U 11 U 3 J 11 U 11U 11U 12U 12U 11U 11U 11U , ... :-. .u ~ .: .. .-:••-' · -~ u -~•_.,:;._:. --i~:::~Jf!-f ~-,-~f:J:?Jt~~:5k:::.z:Ji-Cf::-Z_-:.,< ~1-~ , ?.9 u,- 11 u 11U 12U 12U 11U 11U 11U 11 u_ ., .. :._:W• .,11.fi ';}:: ,, 7'12:u; ,;··.,<\ .fi'Q:,.;:4\,·.,, ffQ::·::c. ·. •. ·11 iY''·'·• .--11 u ·. · · 11U 11U 12U 12U 11U 11U 11U 11 ~ · -:'·: .: .. ~/~:Jf U---~-:.: :~ .L?_,ii_. ~-:._-;:;~ JfQIJ;Ti-.. ~-~,A i lJ -~• .... ~ ~ ~ -: 11_ ~-··• , __ :_.t :. _ f 1-!J, 350 U 350 U 350 U 350 U 3~0 lJ 350 U c4 J ,190 J •42 J·· 1'78 J · 3~\!_U . 73 J , :.350 U. 350 U J.E.ri J 350 U :~6§. ./ 350 U _ _350 U 870 U _58 J 130 J 7 of 18 - --- CHEMICAL VOLATILE ORGANICS --·---... _ - TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP027SLC GP028SLA GP028SLB GP028SLC GP029SLA GP029SL8 GP029SLC --Section 2 Soll Sampling Investigation GP030SLA 1,1-DICHLOROETHENE (1,1'DL~HLQROETHYL~g)_: .· •• ,-.:-~.:'...:'t1'.Y.1l',it'.;i.{f_LI:/'.', ~:~1,:.1g_-[;1~::i:gf;}It,ff{1L'SE tl½!tQ .. :,;·,,._:1I.\JJc11:1C :.:<' JL\J: ·_ ··. 11 u 1,2-DICHLOROETHENE (TOTAL) 11 U 11 U 12 U 11 U 10 U 12 U 11 U 11 U CARBON DISULFIDE : ~ . .,. . -."-. :~'· ~\~::<, >, -~•::'.,:;,. -: .-.. /~_:::;~•:.:}' .u-:JI~~;;:,;dt~?:~tQ""•P-;?i./-;\;,~/_:;~q_-.iu;-;lBi]2!TitQ;;~Jd'lflfo:iQ:Q;, .. r. ;:;:/-~1J~QE~~~~t? ·L·fi:._i.J_-)'.I~:. 20 u METHYL ETHYL KETONE 11 U 11 U 12 U 11 U 10 U 12 U 11 U 11 U TETRACHLORO!=T~E~.t (~T~GH~Q~OET!"iXh[N]) ~ .. :.-:.'!:t:l·; _ 11·~~fi£·~~di-Q)t~lrT~~:-:rr-!J}Jf1lt~\fU\1.i:f:~~:t~';_~~TQ:!J._:--_, ,:.:;r. •?._1f"Qil!i::-~~-( :·~ 'j 1 J1 .. ~<-1, u TOLUENE 11U 6J ,3J 11U -1J 12U 11U 2J TRICHLOROETHEN~ (TRl~ti(Q.R9ETHY~~_r-.r~>\•:-:_,i/~·0, -.-.::";.,t · __ -·-:n.~1L~::::.-:-:_-~_:·:.11·:1J1:.-·:.::·: --~:::1_r.~:-i~ it:J:fJ2JIJ!i·::,~l:.:;~,:~:1Q!_~.::-. // •::·-~::_::il-~T.--~;. ! .• -. '.) 1.-~:: _,,; ... ·[ -11 u EXTRACTABLE ORGANICS 8 of 18 - ---- CHEMICAL VOLATILE ORGANICS ------ TABLE 2-1 SOIL SAMPLING SUMMARY· VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP030SLB GP030SLC GP031SLA GP031SLB GP032SLA GP033SLA GP034SLA Section 2 Soil Sampling Investigation GP034SLB 1, 1-DICHLOROETHENE (1, 1,DICHLOR.QETHYh~NE) · ;·... 1}.L(:·/,;·. '. ,; 11 l,l : \~ :. :_.1.(1,J :~,;,,;;it"J.fJ'.fci~t,~,·,,;l.g,jJ'''. f'_. _ · ·11 Y,.,;! · . 10 li ·_' 11 U 1,2-DICHLOROETHENE(TOTAL) 11 U 11 U 11 U 11 U 12 U 11 U 10 U 11 U CARBON rnsuLFIDE -..... JI~~--~·,-'; ·'.:~~10 J! \ .. -·~ :.-·. :.1_1 .. Q-._ ., t:tf{~/f1•.I2;:;r;:::~~E.,1~tr: .:.:~~\ ._ .-JJ~_Q:,j~.1(t.~°!.-~ . ..1.~f~r.~:.~;~t_-: 11 u METHYL ETHYL KETONE 11 U 11 U 11 U 11 U 12 U 11 U 10 U 11 U TETRACHLOROETHENE (TET~CH~QR()_E'rHy~_r;je;/ fi i,: : ·/ '.'.:J j -l,i\:;,~, > ... 'fi. !JC ti;: , ' fr i} < :;i:,;~;ij 'jJ ':cfi.J.[:,;:Cq 2v~ ?\ -'{ '. '1ij)1'. r?: . ·: . i O Li :~; r, . . . i 1 Li TOLUENE 2J 2J 11U 11U 12U 11U 10U 11U TRICHLOROETHENE (TRICHLOROETHYLENE) '. /'.:·. JfQ,;:L ·< , ii.Q '•' · i}U\: 1;'.iC~if; Li,': ~;j,:;-j;?,Q :· ,:.•"· ;0,•.·11jL:'1\ /· ._ jO ·u. ,,.: ;:: : 11 U. EXTRACTABLE ORGANICS 9 of 18 - -- CHEMICAL VOLATILE ORGANICS --·-_, __ 1111,· -- TABLE 2-1 SOIL SAMPLING SUMMARY· VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP034$LC GP035SLA GP035SLB GP035SLC GP036SLA GP036SLB GP036SLC --Section 2 Soll Sampflng Investigation GP037SLA 1, 1-DICHLOROETHEN~ (1, 1,QiCHLOR.Qi;"ff-i_y4~NE): ·: ·~~": -. :':i i.EQ"t,.,,: . 1 : }J lJ-:i;::,:0 ,:1.?' g_:;_;;,i?;~j''fi ;ff· ;,i"J,f/'J j(lJ L'. ":.":S fUh'.{:;;,;/,';j;[ _LI· \ '.' .· . _ 1_20 U 1,2-DICHLOROETHENE (TOTAL) 11 U 11 UJ 12 U 11 U 11 U 11 U 11 U 120 U cARsoN D1suLF1DE · · ·· ;,, •. :. • · ·. , ,. · ·J1J£>_,::,~:; ' :n uI/I•:'.i; ~-~fs~·:::~ ,; 'i-~f;g,..:J:.i:.'?:j.f J:i.,. :;;:, , .20 J.F;tlf '..-1 i 1.1 -.~ -: ·1,. 120 u METHYL ETHYL KETONE 11 U 11 UJ 12 U 11 U 11 U 11 U 11 U 120 U TETRACHl-OROETHEf\!E_ tf~:r~~~·f!-.Q.R9~tH.Y~~N~>;~:; .. ✓:--,-:::·: ~':jfU~t-Ac:;:,,{ 3l 1lJ_ fl.?h: -~·jJ·Q~.r~~l\~;JJ.~f1:·t.i~\~iJ{Q~i:·f:,r~r:,_:~1f'PJt1~;i,.;.': 1 i ~ ~ ·? · ·:>:· 1:fo Li TOLUENE 11U 11UJ 12U 11UJ 11U 11U 11U 120U rnIcHLOROETHENE (TfllCHLOR<;l_ETHYLENE) _ .+ :/t . ~ 1.r;iJ.1t,":::· · _, · fi-P:EJ?~:,:··.ItlJr::,]sI,ffi1-L:'.t:.iJ:;-,,;JfJL',,;.:./ ::,.: 1iy,;E;;,-:,· 11 u ·_ .• ,·•~.: .120 u EXTRACTABLE ORGANICS (3-AND/OR 4-)METHYLPH~NQL .. 2.4-DINITROTOLUENE 2-METHYLNAPHTHALENE. · ACENAPHTHENE ACENAPHTHYLENE ANTHRACENE BENZO(A)ANTHRACENE. BENZO(B AND/OR K)FLUORANTH_ENE BENZO(GHl)P~f3YLENE. BENZO-A-PYRENE PYRENE . ··" .) '.•:..·. 10 of 18 - ------ -.. - TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP037SLB GP037SLC GPD38SLA GP038SLA (Duplicate) GP038SLB GP038SLC GP039SLA CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1, 1-DICHLQROETHYIJ'NE) · :- 1,2-DICHLOROETHENE (TOTAL) CARBON DISULFIDE METHYL ETHYL KETONE TETRACHLOROETHENE (TETRACHl,,9RQETJ-iXbtN~)('J :·: ·. • , TOLUENE TRICHLOROETHENE (TRICHLORO_ETl-jY~EN~) '. EXTRACTABLE ORGANICS Section 2 Soll Sampling Investigation GP040SLA 11 U • • .. 11 u (3-AND/OR 4-)METHYLPHE_NOL .. 780\J ,;•·; ~-6.~ \,I · -~: .,,,. ~fo·u ...... ,:,,j.j"ffu :;:-~.~' . _:35() \J ' • ,. ': jso;iL' .:1200 U 370 U . 2,4-DINITROTOLUENE 780 U 360 U 370 U 370 U 350 U 360 U 2200 U 370 U 2-METHYLNAPHTHALENE 78..Q Li: i .. ,: -~60 U · ._;. 0 ':iio_ 0J''',c\J31·o~ij,_ .. ·::., ,.: 3.~Q Q;.. :jii_Q lj,,,. ::' i~OO \J .... _370 U ACENAPHTHENE 780 U 360 U 370 U 370 U 350 U 360 U 2200 U 370 U ACENAPHTHYLENE -t~o·Q. ·c.'•. :j§Q Q :, ,., .: ~~Qi{;•,A]:~~)fii].:VC:.:c.,::; ,:i_5jj i:J_ :_.-·, ~&Q y_.;<,.:,·.· 2:?oii lJ 370 u ANTHRACENE 780 U 360 U . 100 J 370 U 350 U ( 41 J 2200 U 370 U B~NZO(A)ANTHRACENE • -. ' : :~iiii:,_: :::; ,/'j]~ u .=:: __ ; : ; 11§. J/,:,;;./';_i.90•.fi:-':'':·2-i, ":iS:cXR ;· '_; •.;~~E:i''::: :b??QO Li 370 u BENZO(B AND/OR K)FLUORANTHENE 1200 J 360 U 270 J : 320 J 350 U :830 2200 U 370 U BENZO(GHl)PERYLENE . . . . · ., •,; ,: 430· J:' '°' ·•· · .'":foo Li• ' • ..:'·' ,~'43 J · . ·;; ':)·140'\j; ic,,,•:,o •;: 350-U ..---:·,,,.',370'.fc' · . <' 2200 iJ _ ;, .37Q U BENZO-A-PYRENE '540 J"' ... 360 u -.. '140 J ... ~--1:;go-:i·· -" Jso'u. ,., . ';'550' . . ·2200 u 370 u CARBAZOLE . ;~:.~.~~/ '<•. I~~Q ~._;:;_:~ .. ;: ~SQ_U~ _~_t?-t~t:Q,Q ~.:;~~112:3101.rrr:~::;.--:,'"IS<f,_ij.~:-_t, ·:~j_s_Q:.Q:2~2.~;~JipQ. µ .L: .,,. ,379 U· CHRYSENE . 710 J 360 U 180 J -230 J 350 U f540 . 2200 U 370 U rnsENzo(A,H)ANrnRAcENE • sc • -z~g'iJ.;:,:.:-,Y~:~ll_Ji· :.,,"3j.9..Jf:..-t:,.'l.T?Q.iJli'.,t!:f;:jJq.\J-:,':~',,.s,_:i.® 1t:.i~~:;_:z-zoii J.J _ ~_70 u DIBENZOFURAN 780 U 360 U 370 U 370 U 350 U 360 U 2200 U 370 U F~UOJ3ANTHEN~ , . :.: .... ::.~. ·.· ·'/~70 .~J:·}f..'£7;:_~§J-!>~•.:-•~2:~:iff~:fafF~'.:[!~OO~t}1tI-\~35DJL~~~= S': .. fifC~~~~-.;~-~t2_~\:[9 i/. 379 u FLUORENE 780 U 360 U ·41 J . 370 U 350 U 360 U 2200 U 370 U iNoE:N_o (1,2,3_:CD} pvR~N~. : · __ ,_. •: .•-.. ::......:·_. >:;::~: :_); !/ · :~4@:~l:~;:,,::1~~P;_:~[Q_._Q;:-§$.-'-:•.~~~--~~~75 __ -Qe,.~~_{-~,:;:.~13o~~l]~I~E~tl§g_~!J :5 :~-i--:·@O·,j~i_~.-~~;~:'-T~Qq !X·· -·, ·. ~~-~??O L! N-NITROSODIPHENYLAMINE/DIPHENYLAMINE 780 U 360 U 370 U 370 U 350 U 360 U 2200 U 370 U NAPHTHALENE --,.. ,·f --~ _:· !;•· .. :·. ;~ __ '.? ... _~, ;:'.· ... _:z1sa~:u--::::y~!':L~F~36ofl[:;~~:~J/{ :~370~•□-<;?~·;.;~CT7oijff§~)·:;\~~:JS()';Q:r. ~' ~:·.~-360 u:.~b,1:T··::;;2200 lr.f' :·= . ·--~~7!) u PENTACHLOROPHENOL 2000 U 910 U 930 U 930 U 890 U 910 U 5600 U 12000' PHEt:4ANTHRE!'-J~ _.·:· :·::"· ✓-?/:f:'1,:·:;;;-:;~~;i~ ~; ~-._.,:~.:;~7i§lJI :t.'.~·; .. ·~~:iftEtf'-;J_~ :,:1&1s0:l1~{11:,!:Z35C5[~:.~-:-:.~:i.:it!!it1Jt?;~.::~£QQ (,~-~~~--:.// · 3?(> U PYRENE 850 360 U 270 J · 350 J' 350 U · 1000 2200 U 370 U 11 of18 - -.. ----- --- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA ---Section 2 Soll Sampling lnve.stigation GP040SLB GP041SLA GP041SLB GP041SLC GP042SLA GP042SLB GP042SLC GP043$LA CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1 ;i-DICHL,(JROEJHY,~NE)·.• "-,·. ·, _. 1,2-DICHLOROETHENE (TOTAL) CARBON DISULFIDE .. METHYL ETHYL KETONE 'f.- TETRACHLOROETHENE (TETRAGHlQROETHY\.ENE) .::~. '.;:".: TOLUENE TRICHLOROETHENE (TRICHLOflO_l;T_HYLENE) . EXTRACTABLE ORGANICS (3-AND/OR 4-)METHYLPHENOL 2,4-DINITROTOLUENE 2-METHYLNAPHTHALENE ACENAPHTHENE ACENAPHTHYLENE ANTHRACENE BENZO(A)ANTHRAC~NE . BENZO(B AND/OR K)FLUORANTHENE BENZO(GHl)PERYLENE BENZO-A-PYRENE 11 U 11 U 11 U 11 U 11 U 11 U 11 U 370 U 370 U _370 U 370 U 370 U 370 U . ... _370 U 370 U 370 U 370 U 370 U 370 U . 370 U 370 U 12 of 18 - ------· ---· --- TABLE 2-1 SOIL SAMPLING SUMMARY. VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA --Section 2 Soll Sampllng Investigation GP044SLA GP044SLB GP045SLA GP045SLB GP045SLC GP046SLA GP046SLB GP046SLC CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1, 1-DICHLOROETHY~E:NE) ;'·: :\ , 1,2-DICHLOROETHENE (TOTAL) CARBON DIS!JLFIDE METHYL ETHYL KETONE TETRACHLOROETHENE (TETRACHLQRCl!=THY\,ENE).', r, :,,. TOLUENE TRICHLOROETHENE (TRJCHLORQETHY~St-JE) \·~.::-.-.-::.~ EXTRACTABLE ORGANICS "1.7 JJ 17 U ~Qy··-., 17 U .j1Q_;· 17 U 11u:·-- :. 1_1 U 11 U 11 U 11 U 11 U 11 U 1i lJ (3-AND/OR 4-)METHYLPHENOL ·; -~90 Q 86_0:o LJ: •i,' , ''.' :i_ii:ii jJ ·: ".'\);'~§9 LJ,:,.c '><:i_SQ;ij 35[ !J:. '· . •~4 j _ 370 U 2,4-DINITROTOLUENE 390 U 8600 U 390 U 360 U 360 U 350 U 400 U 370 U 2-METHYLNAPHTHALENE Jfilj-Q'. '. 8690 jj, .. · -. ·~: ,l~.,/_c,j'.,E((J~§Q'.U_.: "_'.-;~ ':iti§jJ· ': '< ,· __ 35Q Q.:'? iio· J -_..,., · _37_0 U -'---·· ACENAPHTHENE 390 U 1300 J 390 U 360 U 360 U 350 U 310 J 370 U ACENAPHTHYLENE 3_9Q )d, , · . 860Q JJ s:->:jjj9 !J. ,_,,-;,;:j}6Q U_ ,,_:1'< . ;3~Q l]_,.}iJ.~ ·-~~O ti_'. ; ·. c; 20Qi/ : '_370. U ANTHRACENE 390 U 3200 J ,43 J 360 U 360 U 350 U ,2800 370 U BENZO(A)ANTHRACENE ,,. 4-'!.-! ." -jg_i/ijg' -. . ::, ;J~Q J --:~JJ:ij;o_ij '-i :t:,c'0:~gQf:.z:· · 3S_o'_ii-\. '_']@ii Y-' _ 370 u BENZO(B AND/OR K)FLUORANTHENE 48 J 14000 J 520 J 47 J _ 360 U 350 U _ _400 U . 55 J, BENZO(GHl)PERYLENE ,'<.i'·C• ._._. 390 lJ ---4~Qo·:t-.,f/F.!J4Q,l. <-:·.,;~Q'{J:\:i::t ... ~s_It);:_"(;": --~5_0_!J·.':-'. 100 u . .c'_.c-_)70 u BENZO-A-PYRENE 390 U 8000 J .180 J 360 U 360 U 350 U 400 U 370 U CARBAZOLE : . . :·;. • ~-3g'Q_ ~· . . . -~~Qk ./.:·.f;;}::½.iiQ.c.Q.·::;.:·::~~~;l§Q~1I.·~;,s~,~~(·Q"";!=~{·~•::~J$Q_~,:;} ~·,. i.l_s~~, ,,:_·, .::.;:_:.3?9 u_ CHRYSENE . 56 J 10000 .-260 J 37 J / 360 U 350 U 7300 J 370 U DIBENZO(A,H)ANTHRACENE _. ,' ::·:·::'-t'c.-''.~;_~:~q '.QJ,< :_8~_Q_Q·uc_,:.-_ i{r;)~!d; ··:'!.tL~i'Jl1Q: LJ,::';'.;'.t;:,!,\3_6__Q'll •?~:.'.·' : 3~Q:\J';;':':~·., --~40Q. u_'_,, .) 370 lJ _ DIBENZOFURAN 390 U 1200 J 390 U 360 U 360 U 350 U 560 370 U FLUORA_t--!T!-ll;NE . ~-,· -.'~: .... ;,;,:~:·~--:: · ..... ,_., ~tL~.,:!J~:· ':<·~tzifQ~~~i:i.~t' {~-~~~-.;~~ ... 11-~.:~;;ti·:-4t_;:µr.~:jJ;;fI~66l'Q i'.~,/~~;t~1~9_y}..il~:i·a.s_iJQ_Q;·.·-.:~l':>,j;;'CJi{li.✓ . FLUORENE 390 U 1700 J 390 U 360 U 360 U 350 U ,1100 370 U INDE_NO (1,2,3-CD)PYRENE ·---.· ,_::· ;,.;;c :;:;-, ,, c•.: -, :i9o·Q?:< ~~l-;c1::c.\:f1~:~~' ,¼'iJ,t:i_~fi'p,i;J:?'[,]'.?]§Q'.l.CV,;:•r'.~9:Yi:t','~ }~-9 i: .. JY. ;_370 u . N-NITROSODIPHENYLAMINE/DIPHENYLAMINE 390 U 8600 U 390 U 360 U 360 U 350 U 400 U 370 U NAPHTHALENE · · ··""°• ""' .• :: .-.::::J{ ~±;;<-~:. :-~~:. ~Q-.~::Ji.: -_~;:.J.iO<;~-1~-~ . ~~~½:i!£dt :. i~~J.!-}.§QJ~~~Cfif~~r~~~.2Q.:~0J~::~;z-2:.~j§~~Q} ~~:7;·1~· i'! 6~:J., _ .. _ .. ~-:--. ~_)?Q· u PENTACHLOROPHENOL 980 U 22000 U 990 U 900 U 890 U 890 U 1000 U 940 U PHENANTHRENE. . :·. :,.~?~~-!~~ ~-'.\ ~ _.5:t~~Q·TI -~-~-. ·~· :~~ f5~.Q_ ?~;.·.'tif*.,.}_3i["'l ± :~·;,~r~]:6Jj~:Ji~or~J60lQ~-I£;.;~;'\:: 35ft~V.::.t~t·;~faoo'q_~;: ~:1.;._-~'° ... ·. ~}70 ~ ,· PYRENE 70 J 18000 350 J '46 J 360 U 350 U 1400 U 63 J, 13 of 18 - ---- CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1, 1-QICHLOROETHYL(N~) '. 1,2-DICHLOROETHENE (TOTAL) CARBON DISULFIDE METHYL ETHYL KETONE TETRACHLOROETHENE (TETRACHLOROETHYL~NE) TOLUENE TRICHLOROETHENE (TRICHLOROETHYLENE) _ EXTRACTABLE ORGANICS - -- - --·- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA -- - Section 2 Soll Sampling Investigation GP047SLA GP047SLB GP048SLA GP048SLB GP048SLC GP049SLA GP049SLB GP049SLC <\ 1_? U 12 U 70 u, 12 U ... 12_U 2 J . . 12 U (3-AND/OR 4-)METHYLPHENOl '\.OQ U . ·,37.Q iJ . . :~~9(! LJ_:f_, ;,'.~~7.Q ·y. ,':;;j~'i::, ')§0,Q -,;)$9:lJ: ;✓• : 610 LI. 830 U 2,4-DINITROTOLUENE 400 U 370 U 1700 J 370 U 380 U 350 U 810 U 830 U 2-METl:lYLNAPHTHALENE ..... ·. ~69 U }· 37Q lJ . ','':i_gop\J. ,:,-:';' )ifo_iJ '"'':}1.--;~li_o·iJ., ; ','.")soy·::-:-8jO iJ_ -_·faoj ACENAPHTHENE 400 U 370 U 3900 U 370 U 380 U 350 U 810 U , .180 J ACENAPHTHYLENE :.4.oou :~t\1Q·. ,.-~'ifoQ:"~.::i:.::"i?P!J:''~J.i:'.'.'.3~01i • .'-: ":')sq __ u'::-c _li16iJ.·i;_:' --~30lJ ANTHRACENE 400 U 370 U 3900 U 370 U 380 U 350 U 810 U · 640 J BENZO(A)ANTHRACENI; . ; . ~ .. -4~(!tj ~ __ . 370)J. ~-,-.j@.Q Q .'-~~:-~\-;-jfQ_ 11_ • ;.i,~~~f~~~ }]. ;,:r{,~,.".:~~:J t: -:;;.: _ ·<J.~.Q /-.:·_.r '. , L 1_~~(! , BENZO(B AND/OR K)FLUORANTHENE 400 U 370 U 3900 U 370 U 380 U 110 J 310 J ,2200 BENZO(GHl)PERYLENE ·.;40_0 if'., -~ ·., ~19 i;!,, ... /)9_b_cjj.f :-'~: ))'.'°:ijti L)' ':};_\,}/;_:i~:o _i;i_: ;'·; '?13§i!]E,:/ · ·. · 160:J_ -·, /9!0, BENZO-A-PYRENE 400 U 370 U 3900 U 370 U 380 U 55 J -170 J 1300 CARBAZQLE ,.· .. :-~ ':¥ .:l:~fi.Q.Q.!L:.i:._:_·.~---.~jj~{Y_;J.~ ·'"~>~sQ91(:fa211~~~:[?lf P-=-~i~lt~-fQ:~~~:;~L~~Q11lit-tJ · L~10~u ~1~o-~ g~~~~~!.HJANTHRAcsNE ·, . , :if; _ :,,-·, ,J~t~~f -' · _: {t~:.ti-:_ ~-:~'-1~~flh~:cfitd~~t:;;:~221&,d!ttl;,;-;\:":'.:jfo_c_Q:;:',~.:: J~i:~-:~ .. _ !~~~ _u DIBENZOFURAN 400 U 370 U 3900 U 370 U 380 U 350 U 810 U -190 J FLU013ANTHENE -:./ ,;~~ .~~:, ,. ~·-~·:_.~;~~ .·-~~'./{,?f-:ifa:~i~·• -:·~~.~7.Q;__Q_~~I, ~~,-~i_;i.l~~~~~~:~~?_Q.i~: .. ;;~~![;}ij~-:Y,7:'~i~~i::7 ~t~5-:·::.ti~~--;!~ ·: .:;;. ··: ... '~:~~O~ ~~ _ FLUORENE 400 U 370 U _ 3900 U _370 U 380 U 350 U 81.0 U ;260 J INDE~O (1,2,3-C_D) ~y~~-~E •.. . -''---L .'':;;:,(-;. -~/~:;,. ·:12;::4@,:_uj :.j ·. 370.'l.1,.~:,:'., ·1-,;3900.o.'.r~ITT)~~~,.310":i.f f}}~~;'..f38o'U_~;;~~i~::!~~?350flf:-:~;·-:: . (14o'i~ :·:_ .· .. ,~qo ·. N-NITROSODIPHENYLAMINE/DIPHENYLAMINE 400 U 370 U 3900 U 370 U 380 U 350 U 810 U 830 U NAPHTHALENE · ... · · -_}-_;.·_,--__ -,,:.·-: .;.,~;~·-··.?.~_; ·;~'1,4.Q~fQ'.~.;''..· ·: .:~ _ .. :._~?.[.l:l_: :,::i:~:~~ItFJ1\~r::·:~t"}fffQJL-JI;1{.filfcf_p;/;{~i~/G!lf~IO-_Q~i:I:.;_~ .. _ ~f Q.Y~ _:~ .. : :·;~o,f.1- PENTACHLOROPHENOL 1000 U 940 U 9900 U 930 U 950 U 880 U 2000 U 2100 U PHENAl';HHR.EN~ . ~-~--': -~'.~r:;\~;;~43 ~i:~1: ~; i.\i;,3,;:9_::--~•~;.:2:~.~(~~~~~~;L£~TI1, ~~Mr~'.3~Q~JJ1}::;;~t: 350~ u~~~l:::., J}[<f ~ _} _~·:: .. 01<!9 PYRENE ,52 J 370 U 3900 U 370 U 380 U 53 J 380 J .3000 14 of 18 - ----- ---- ---_,_ --Section 2 Soll Sampling Investigation CHEMICAL VOLATILE ORGANICS TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP050SLA GP050SLB GP051SLA GP051SLB GP051SLC GP052SLA GP052SLB GP053SLA 1, 1-DICHLOROETl:IENE (1, 1-DICf-l~(JR(lgTHYLEN~i.,, """:i<. ·. j,1 I.! '< )._: , 1~ u.):·•:•;,;C;,J:{_1,J ·: '.:': };,..§ti:u:i;;:~:,;-;~;j_2_jJ~~;;.:c, _ ·.JflJ; :::,~ -~.17 UJ .. 13 UJ 13 UJ 13 UJ 13 UJ 1,2-DICHLOROETHENE (TOTAL) 11 U 14 U 14 U 11 UJ 12 U 12 U 17 UJ CARBON DISULFID!= '\~·, :.:\:~·t;_:·_-_ __{1 ~_ \J; -,f ."' 1_4 if_).:-·_ '~!l' J~fQ\: -y_;~~i~;'.J1Jff[f:_;~;; ·~:Yl-tf~.f~-.-_\":.t~j;!'(i~~::2:, ~ 1? U~ METHYL ETHYL KETONE 11 U 14 U 14 U 11 UJ 12 U 12 U 17 UJ TETRACHLORO_ETH~NE <t$rRACH~Q8Q~THY_L§Ng)?/t?:~·; .· ·.1;1:iJ. \:.-:.\:)· ·jif_Q~~:-,·:c\~")'f'.~T~~µ~~::·~;:.~.r".?:.ff-.Y.~Tt1'i,'.: s t~"\:I~t!ffJ~~ ;_ :-121r :~.1::-_r:~.:' iz.~·~: : , 1,3 UJ 13 UJ 13 UJ TOLUENE 11 U 14 U 14 UJ , 2 J 3 J 12 U 5 J TRICHLOROETHENE (TRl<::HLORO~TtiY!,ENE) i.1~.' .-_ij ~--. \4 '(i'_•·· .. '· '.;:_;J~,U< ~~:(,:.,Jfl,i,f,:i_'::;'.'f: 12 Tit;]:~'~-~~;'·'. i~!J-'.\:-~ ·.:.:. l°i iJ · EXTRACTABLE ORGANICS 15 of 18 - - - -... ------ ---- TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA - GP053SLB GP053$LC GP054SLA GP054SLB GP054SLC GP055SLA GP055SLB CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1,!:0.ICHLOROETHYLlcc_f'i~j_:·:,.J.';::\,., .. 14:)J,. , . 1,2-0ICHLOROETHENE (TOTAL) 14 U CARBON OISULf=:IDE .... -.:, _; .~;_,.;~-~:t•~. j~ l/:" , ~ METHYL ETHYL KETONE 14 U TETRACHLOROETHENE(TETRACJ-\LORQETHYLENE). ~:~.:•'/ .. j4 i.J:· TOLUENE 14 U TRICHLOROETHENE (T~ICHLOROE_THYLENE) · {,.;;:~•; ... : :j4 U - EXTRACTABLE ORGANICS - - Section 2 Soll Sampling Investigation GP056SLA . : NA NA N'i,: NA .: NA NA NA (3-ANDIOR 4-)METHYLPHENOL _;: < . 9500,lJ. ]?O_ lJ :,;''.: : -~ ;~s_Q,J!:~: ;..'.';~)§q::i:[~;: .. /t::jfo~_Li,, ,'._',!,: ;4.QQ u· • : ~ :i~Q U · 340 lJ 2,4-DINITROTOLUENE 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U 2-METHYLNAPHTHALENE. '.-i ., -; ;,9§,QO u ,: . -~-," ~?Q ~';,' :-.:':7-'ISQ\Li':: '. '.'i:~10JJ2\E'.'::·:rrJi,.U: ~~t:r·. ::;.-:c. 359 lJ i. ·,: . -:i<io LI ACENAPHTHENE 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U ACENAPHTHY~ENE ,,_ -. • ·,_.-, ,,." •· ·.9§o§Q :.~ . · .Eii J.! : :..;'(:· ~si&O;,:·: 1cf-.cJ!iii1!,,:,c-·:):J'?.!i .... i,ii.;.:\f-', ·;;o:i1J;·fifi~.=fs_o u· -...• , : ~o u ANTHRACENE 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U BENZO(A)ANTHRACE_N~ -_ . -~ ~ ·~ . r :--, . _.: · • ,~·.:--:<~~it,~:;_ .t~ '.9_~QP _y_ :· ·,/'.: f \: I?1f9:,.,· -'.-):'.: ;.:~s[~f t\'t:t~J)90 i!J\f';:rr::_~fcLQ.~¾~-/·. ~~Q. .-!.:.' ~J? .. :· ;·~~ti ·y _ _,, ·. :~ ::. ~46 1-:! BENZO(B AND/OR K)FLUORANTHENE 9500 U 370 U 350 U 390 U 370 U 480 J 350 U 340 U sENzocGH1JPERYLE.NE :,c· · · · ,, · :_:,::,' ;) ,~§QQ \i :,;.::;; ~ZQJi ,_., :::,:@fili.,Q',. ·.,::•"X@cFu:ff;i-djffQ .:;ti,;.,:.':'.1.§i_~_, ~-Si; .)s91.! .• ___ 340 u BENZO-A-PYRENE 9500 U 370 U 350 U 390 U 370 U 220 J 350 U 340 U GARBAZOLE -1.-,_ . ._ _ .• •::,: : -~· :t) .. ·:~J9_DjJ.-:.:/ht::~f!;EU/ :·:.,:j_:',~~~sci\f\ ... 1~•~::~~__9..Q1J%.t.;~.:;i.]icf·1F·· ;?;J -~::jb9Jt~_r:: • -:)~P:~· · :.~ ~, :-~Q !-J · CHRYSENE 9500 U 370 U 350 U 390 U 370 U 210 J 350 U 340 U Dli?ENZQ{A,H)f,N,:-H~Q!;~_E . . ;::•·~1 .. r-.::'•.~'.Li;::{:, ~::-9506~ u' :.:~.~·-:;-~ 0 '.• 370~u;;~-:·, ·:: c·1~J:35o"'TJ.J~..,,'.~}t1.396TP~;t:.~-:g;37·ou·.}i-''.:.:F::_:.~ ~oo·u-'~·_ . .-_·;:;,_ . :359. l!·• ~ "•\_ ;·_:·: ,. 349 l! DIBENZOFURAN 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U FL_U9~NTHEN~. ~-; :.:.~: :;-\·-~ :.,.\!-.fd~-~•:.:0'..:...:,:i, (;.iI~9.Q~i.L:· •. :~~¥,.f{37Q,'._~~j~\~:i!:{~,1.§Q~QlI~!-\~§39i:iitYJ1~a1.iJ.1t@ZQJ1:t.;w;t.t.0J90 J6_.-_::j:z;t::;.. i~ef=U: ::· ~~ ,:1·:...~D,. ~ FLUORENE 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U 1NoENo 0,2,~-¢~) PYR~J'~!;. , __ ., ::_~;~:_·. ~-~-di:.-:i,.'}t .. ~~:.;_-~ t:~:;950Q-1_Q·:.:· ::~:~~?~qy;~·f5[U;hl2.[Q~-;.-'J~~~39Q&~:~~~37Qff~~~:'lI_Z,.~fso ,~ .~{~S..: 3~~tf p ~, .. ~.: .~}4_0 .. u~- N-NITROSODIPHENYLAMINEIDIPHENYLAMINE 9500 U 370 U 350 U 390 U 370 U 400 U 350 U 340 U NAPHTHAL~~{E -·•-• , . • ~ ·i ~ __ •1• :· : • :;,?.;. ~;/~ :~:.: .1-f>...'.'~-~~t~J:th.t~§.9Q;j.L?"'~t:;:;t:_3j§_'!-!:: ._•;1·:f!11IsJ~1Tc::;>:J}:d:~_go·1o~~tf.'f~:f~Z9:~~}.'Jil':~~@Q I[C::_·Jrt'l.t~ -~~9.· IJ: ~ .. :-'\~-~-_ ~Q -~ -· PENTACHLOROPHENOL 24000 U 940 U 890 U 980 U 930 U 1000 U 870 U 860 U PHENANTHRENE --~~:~/ .. · .. :; .. ~:.. .;-•-:.:: . _.;-.·;~~~;:_~<< :·:_{ ~;J7ig5QO'LJY:.,:1 ... ":~-·}3iQ.Mr,;-;.\.~-~T350'.Ut°r"jp~39otUi~;,::_:;,~37jfU~~::-,.,;.G,,:a4~J.:FCr~i~r350:U · '. -"-:·-;340-·u PYRENE -. ·-... ·-... _._950ctu ___ ,,., 370 U -. -"3sou -· --390 IJ , --370 U , • .,."fro]--· ---•350U. ·--"34i5\j 16 of 18 - -- - ---- ---- -- - TABLE 2-1 SOIL SAMPLING SUMMARY· VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA ---Section 2 Soll Sampling Investigation GP201SLA GP201SLA (Duplicate) GP202$LA GP202SLA (Resample) GP203SLA GP204SLA GP205SLA GP206SLA CHEMICAL VOLATILE ORGANICS 1, 1-DICHLOROETHENE (1, 1-DICHLOROETHYLENE) , .. ;,, t. .1.D l,J·•'. 1,2-DICHLOROETHENE (TOTA.L) 10 U CARBON DISULFIDE _ ·;.:°PL ·_,:;i['c:, · METHYL ETHYL KETONE 10 U TETRACHLOROETHEN.E (TETRACHLOROETHYLENEj' ·,.,; ".'l; •,,•.. 10 iJ. TOLUENE 10 U TRICHLOROETHENE (TRICHLOROETfj'Y_~ENE) :-.:·-.:•;· . 19 ~ ;, EXTRACTABLE ORGANICS ·11 UJ. 11 UJ 11 UJ ;.~,: 11 UJ 11..y~-~: . 11 UJ •'' ·" 11 uJ , ·/_. ·. 11 UJ 11 UJ 11 UJ 11 UJ 11 UJ 11 UJ 11 UJ 17 of 18 - ------ CHEMICAL VOLATILE ORGANICS - ---- -- - TABLE 2-1 SOIL SAMPLING SUMMARY -VOLATILE AND EXTRACTABLE ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA - - - Section 2 Soll Sampling Investigation GP207SLA GP208SLA GP209SLA GP210SLA GP211SLA GP212SLA GP213SLA GP214SLA 1, 1-DICHLOROETH!cf-:JE (1, 1-DICHLOROET_HY!,E_NE)_ ., . ",:::{,, ·: 1Q u. <: ,•.·.'11 y . ,: '.:;: ,;fr'Q\ .. L.,:f..C:j]jJ,f-2:,,:::::ii.9 ,-i/.:L:J.-:1 i.Y·, ,, (.: . '10 u 11. Li 1,2-DICHLOROETHENE(TOTAL) 10 U 11 U 11 U 10 UJ 11 U 11 U 10 U 11 U cARsoN rn~uLFI0E · ._ --.. '; -/:,j;;~:-~i::.}.~;:;..sS.7: : --. ; . • . :.:·~.i 1. -~ _._--:: _;~ ~· .~t2:1~~~~:::6~~.'!':IQ;_iik~*f~r~t~fi5.iJ~:,. ·:~tifNt:~~£:-;':;_, . .; ... ~~-".1Q -~ ~ l· ~--~· ... ~. 1 LU METHYL ETHYL KETONE 10 U 11 U 11 U 10 UJ 11 U 11 U 10 U 11 U TETRACHLoRoETHENE (TETRACflL□RQETHY~gi.lEi {· ';·~·:'" 1:irw-:· • · · n.JJ/: .. t , 1'1.1 iJ.i'I:,i~\r!, 10.Plrr:f'trfff[it :,I:-Fi:c{'fiJ.[-,: ·>:-' 10 u 11 uJ TOLUENE '7 J 11 U 11 U 10 UJ 11 U 11 U 2 J 11 UJ TRICHLOROETHENE (TRIC_HLOROETHYl!cN\c) ,~; '' :/ • :.( . .' io Q _:., •:,': ;. 11 ·u::.; ·>HftJ:'.:t;?/l/flfiJ_Jj,:l('',,.::.:n]i:,,'.,j}t~-;;,h,Q,'_:•·'i'': :. iQ Li .. ~ .. , 11 U EXTRACTABLE ORGANICS (3-ANDIOR 4-)METHY~P~ENOL ."·,.-~-. .:.•i.<:iS;~JtcfQ:.W: .. ·'--. _3JO•.!i-·Jt·:;~ .. \-~~~9 -~U ~~~j;}i\~~tfJl{!\t:~:~j:·,~~~tu_'..~/.:Jti.1.Ycio .. ~:: -.'.:·.,~;;·J... 3_4_0 u ·_. :-' :·.:· . 340 ~- 2,4-DINITROTOLUENE . 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U 340 U 2-METHYLNAPHTHALENE ., '":: :, XtQQ~ [so u'',:: ~: t~§p Qt';} ;';:\:½9 jJ/;:i:i}/' :i~ctQ::,·' ~-:'.·;f.'i_iili:O:,·.\ .::J{o iJ :, ·=· '• . '340 U ACENAPHTHENE 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U 340 U ACENAPHTHYLENE '; ;:. , :· fiqg u., ' •; ':i~IQ , · ~;;:,•:; ~§Q!I :::; ·~•;,}1Q iJii'c:T:t. j~cfQ<D?'i:jfiJq jJ .. . .:'.)10 Li ; -::, • _<,77, :i ., ANTHRACENE 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U 150 J BENZO(A)ANTHRf'.CE~I; ~. ,. . __ r:.;:) -'··) :5-1iQO, V.. ~.: .. _~ .,:'i',~jf~---! .· ·:: ·_~\Z~rr:::::,~fit~]Xftr·:I,~'tir~M-:~c~: ~:t'./15~i?__;J_\ •;~:.;: \·~--:.:.~9,0. ~.~i.B~p_: . BENZO(B AND/OR K)FLUORANTHENE 1700 U 350 U '160 J 340 U 210 J 1200 J 340 U 14700. sENzocGH1>PERYLENE -. · · · • . .: , ::'.f flji> :\L ~ . ·:' )s_o' u .. .-:::;:,,,,,:~_'!J.;>;.:'<f~'. .. !::Ho..112.iZ.I t;.~i:J ;-,;_.'i/:~· ;,~ii,J : , '~ -· .. :::i4o iJ _ .··.i ,!~o_ BENzo-A-PYRENE 1700 UJ_ 350 UJ 78 J .. 340 UJ 100 J . ." 580 J 340 UJ ,1100 J cARsAZoLE ~ -.j.~i :i"-:-~ ... ·erAqjr .. . .. )~_cu.r-,.: ·_ :r-~~!1.?: .. ~r;;_;~~~o-t1i'l~T1f;~3s9 -~'-:f:~;2.110QJ1,~:·:. ,:•;:1 --~-;HQ y · ~!-~ : _:_33(! _J · CHRYSENE 1700 U 350 U 120 J 340 U 130 J 620 J 340 U ,3900 DiBENZO(A,H)ANTHRAC,ENE ' • • : ,-~~ "'.<:°', ·::/.1?00 "Q. ' :~.' .:!§.ii:1.1. :. '.,:: :,,35Q'Q'.ia·,,.t1{:ftQJ/;i~t3i,'.: 390 Li :'.'(;:~,;1700 Qt.: :· '}i.Q lj '<' .:. :Ro u DIBENZOFURAN 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U 340 U FL~oRAN~HENE -~":<{ ~~ -~j;,f,13{...-;i •.-<lZQQ·p ,::· .. ·./.·:~~-3so~~~~ "·:~:~~~?3o 1L{~f-~;;:_~ __ I1\i!lMPD'"l.,;tr:v~oo··:r.-. :_ -: ... --~MQ !.f :,. . :t. i91oo_~..:- FLuoRENE 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U . 34 J INDEr,JO (1,2,3--Gl?) P)'.RE~E __ . :_•·~ .. ', ·:J.~:,.·;,~ l'.-,(:t.(:; ·-;'. ·-:~-~:ffim.!i.T t•: i:,~-'i~Q_!)·~ -~:,:;_/~2,:.~---;1 ... f-sl-'fiL:g_fjJ\:1~~fil~~iJ_~i~1~;1f£'O r;;;--._-:/..:, -~-.::.}~O ~ ,. ·., .. ··-.. 790 .. -. ' N-NITROSODIPHENYLAMINE/DIPHENYLAMINE 1700 U 350 U 350 U 340 U 390 U 1700 U 340 U .. ·-340 °LJ NAPHTHALENE . ·. ·. "· ~-:·"-::;,;-::-;; ::._-..... ~~,;-;;-_:\J: :-;-; 1700 ir:-_:.:.· 7 : 350.iJ;. -.'-·~/ '._35i5·0~-,:·:;.•!~-r34o-iJ;@ff'?.~39Q1U~ .. ~i.Si\~Tf70Q1F·: ~;_; . '.,-34Q (J -~ :.,-:)40-U PENTACHLOROPH,ENOL ' .... ""··· ., ··-'"4300·u -· ··amu ,,,_87ou·•----sso~u -'99ou·· .,,,_4300U" _,,_840U 850U PHENANTHRENE _; -• . :: ~~:,<·--~·,:-:~'. _,: r{:;~; ~ -~:_;: ;~;;f :fl§Jl·.JJ.:"·:~ :::-'.'.: ·';~~•i!i i::~~,:i.;@0\J.~~;~t·~~.l:!;34o{ji1$~:: .. [J§~;'.; .. :~~;;;_}1-·46f~-:;~~~-~::..-':lr~p Q ~-:~ : -£1~!'9 , -.;.." PYRENE 1700 U 350 U 190 J 340 U 180 J 980 J 340 U '1300 18of18 - ------------------- CHEMICAL PESTICIPESIPCBS TABLE 2-2 Section 2 Soll Sampling Investigation SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP001SLA GP001SLB (Duplicate) @~itivl· 3.5 U 1.5 J GP002SLA H :S\0cJJ nwrn M%/l q: ihl 1.8U 1.9U GP002SLB GP00JSLA f,1),IJJ:l'T/ Vi2:fl1?i 4 UR 21 U :;::j!JJq;;J:q:q:.§Q}\)J:,:r 2.1 U 11 U GP00JSLB GP004SLA GP004SLB /Hurn .·.·.· .. · ; ~!]RE 4 U 4 UR 3.7 UR •.•. lJ!Hiii I rnnrnrn}!f!j)j i@HP:H'silt Q . 2.1 U 2.1 U 1.9 U BETA-BHC 1.8 U 1.9 U 1.8 U 2.1 U 11 U 2.1 U 2.1 U 1.9 U OEt[,%~1'\!;1$)ll@i%jili;irnmrnrn11rn iifflfffl n @ff It Mi~ .Ql /l&i!HMlllQ ; lfffl ffJ~J;/ E'.5%;1 1;ili[@btfaI1M'J;;!l; I}:g/~ q i;rn ;;g;xµ;;Gn ; ;}1'.g'.t/} DIELDRIN 3.5 U 3.7 U 3.6 U 4 U 21 U 4 U 4 U 3.7 U t!;&od~!iJtl\'AN,irlAtief.lA)l n;r@fa i t II ii Iliil!M;/Ji!i!I li wt@M!Ml!i!i.iitl!Hilli ~HliRBilil 1@1it!YRIH\ifoi: iJ~IW/HH@/ii@11I!!ilH IIII iLi De~ niiti:li YR ENDOSULFAN II (BETA) 3.5 U 3.7 U 3.6 UR 4 UR 6.7 U 4 U 4 UR 3.7 UR gfi!QRll\lF. mqg;;;n;;fl) H !iil!la;§lP!Hilli!}i(?'faiJ!Ji!I!t!!}l!~!!!lll illlI\tll!il!Jt!l!lg1i!J!lilHlill'lifjiiH ;4]':[ ' ;;;;$,%,Q,: ENDRIN ALDHYDE c.1 J 3.7 U 3.6 U 4 U 21 U 4 U 4 U 3.7 U §NQR!ti!ffi'C!iPt:!ElI T ll l!Jl§!aY'i ii!:l:1ii!~i~!il!i!'l r d\etua #!llW!!:llllrn::31:!!!.iilI il!IIli!~iiYlill :;;:4oa;:: ll~l!:!lJ GAMMA-BHC (LINDANE) 1.8 U 1.9 U 1.8 U 11 U 2.1 U 2.1 U 1.9 U ~M!&tWfiildROANEliiW 1!8 UH Fi1 'l\ijf§luH r. %1Wi!JY 'f ::Im~: @rn:l : H 2.·, ··u·.·· .•.. ······.2.1 ··4 ' . I / 1!9iU/ HEPTACHLOR 1.8 U 1.9 U 1.8 U 2.1 U 11 U 2.1 U 2.1 U 1.9 U !l!li4eltei@Bli9Bi§RQX]R§li!li'i 1l~ !ii !:::Hi: i:ll11~LWI!ll I fl~];! I i ! ii11 :wi li K 1(11\ki . l ~11 ;~ ;;; i ; ; ra;~ µ; ;;;; . t 1.'9.: l/ fa METHOXYCHLOR 18 U 19 U 18 U 21 U 110 U 21 U 21 U 19 U flQ§~~g§~l~~99§WQfil[ic%§rtX t T eaHl!inl!ll li !B.A!!JHfflHII Pi:\!f!Ii H~\!iHSE!Jff,~71.!;j;iili i!iiil~inl: lll' ; 1gl!;l;J!I!m1l!ll1~%!!;l PCB-1260 (AROCHLOR 1260) 35 U 37 u 36 U 40 U 210 U 40 U 40 U 37 U Data Qualifiers: U = Material was analyzed but not detected. The number is the minimum quantitation limit R = QC indicates that data is unusable. J = Estimated value. N = Presumptive evidence of presence of material Concentrations reported in ug/kg. 1 of 18 ------------------- TABLE 2-2 Section 2 Soll Sampling Investigation SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE GP005SLA GP005SLB CHEMICAL PESTICIDESIPCBS 3.7 §NQBIN !S§XTQff§ t m I i ~i't 9. IH GAMMA-BHC (LINDANE) 1.9 U 1.8 U G5MM..%GHPORPi\\!\!!i:l!l! r nn @;$ Q I 1!~ ill HEPTACHLOR 1.9 U 1.8 U e@iflg~/ifiR9§ttM@R1?$il'IIE PCB-1260 (AROCHLOR 1260) 37 U 34 U PLYMOUTH, NORTH CAROLINA GP006SLA GP006SLB 2U 2U 38 U 38 U GP007SLA GP007SLA (Duplicate) GP007SLB GP007SLB (Duplicate) 1.9 U 1.9 U 2.1 U 2 U i1!@!J> 'I#l$tl i\ g;ig S~tU/ 1.9 U 1.9 U 2.1 U 2 U 37 U 37 U 41 U 38 U 2 of 18 ---- --- ---- --------Sec:t/on 2 Son Sampling Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP00BSLA GP00BSLB GP009SLA GP009SLB GP010SLA GP010SLB GP011SLA GP012SLA CHEMICAL PESIICIDES/PCBS 4ll!l@RQ((RlRitRRRl li ,. l!itliiffi/ ' m ; l%Ri§ !i!BiffHH\liJJ41\:1BN rn na&MR} n;@H§i§tQa H}liS@§j wrnn rnl ;zj§f.!WFM ii!!Rl1 9.RHHtlIJ@;glQ " 4,4'-DDE (P,P'-DDE) 3.6 UR 4.4 UR 3.6 UR 6.3 UR ( 0.67 J 3.6 U 3.4 UR 3.5 UR 4ili8P9I(?i!filtRR®L r nrnrnwr ; ; nuafe;qrnrnrnh\!kl!lPlPll i llleI!i!? l ; {@$;\$\U@H' !!?~!$-P nrnlPl 'qillB!i@/lM ; ;~(4 Q ff iFH3l$. ow ALDRIN 2.3 U 1.6 U 3.2 U 1.6 U 1.6 U 1.6 U DIELDRIN 3.6 U 4.4 U 3.6 U 6.3 U 3.5 U 3.6 U 3.5 U §@RR§hl~#l!§i;t~lm!l!&il;ii!:ff •••< 1.a:qiii,, T!M?l~ll!R : ;;i~pg;; !1iI@1gil:!B11!lll1! 11~w. ::;n 1,g:14::n;t ataI:ua ENDOSULFAN II (BETA) 3.6 UR 4.4 UR 3.6 UR 6.3 UR 3.5 U 3.6 U 3.4 UR 3.5 UR §NPSlNl) !:i ' ; ;....... .. r;:;;;:;Uli:itn:Hrnit;:g Hi !l! ~'.!:lit.Jfi, ;;; W4l!ilj!jff ;;,;;; i~ley;µ ;rrn;@Jey;(J)iO\jj1!1}1Hls;l!ili) !Hi i ;::;@;fiof(f\lljh!FlH@iJ!i g HJ l~:$-QW ENDRIN ALDHYDE 3.6 U 4.4 U 3.6 U 6.3 U 3.5 U 3.6 U 3.4 U 3.5 U !;fjp}AfNIKl;'@lg&(';l!l!!i:@l!t!ii\!MH!@fa; " " --1;zy\gi!,,!iHWNlHL4i1!UUHMifa!l9J!f:!C!!PMWHFvi%W!tiHH #gl9,tQM!;lHMHt%\§JM;iMMhiH@i!lVµ1urmm;@igQJt GAMMA-BHC (LINDANE) 1.9 U 2.3 U 1.6 U 3.2 U 1.6 U 1.6 U 1.6 U 1.6 U %!%MM&llf!i!£9!tP~§ff.!lMilli! l!MHi: I$i~tiif1;J;ii~!~tl l Itf1HIUiHlll:}lsi2@<:, 1.s u,,, ,: , , 1.~p,':'.;'>: -, 1.~ u Hiliff1!~!Jff HEPTACHLOR 1.9 U 2.3 U 1.6 U 1.6 U 1.6 U 1.6 U 1.6 U Ht!Pjif>f!§fiµoR Ef!.9.X\95 gm M~ MT.! !! Fi2is UH j;JfQ'. t M~ V i ; nm:Ml!lU:t,rnrrn lMWP t k ("ta u METHOXYCHLOR 19 U 23 U 16 U 16 U 16 U 16 U 16 U e£l!¾Jl!~lt~B2§1\\W@®jg§fil'.li:!fl •·•••·•••·•-• •!K;P H@§Il!il H!lll:lil?$)'!l!Wl!l1·J :e.4rg L••••••• @§JJ; PCB-1260 (AROCHLOR 1260) 36 U 44 U 36 U 35 U 36 U 34 U 35 U 3 of 16 _____________ , _____ _ TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA Section 2 Soll Samp/fng Investigation GP013SLA GP013SLB GP015SLA GP015SLB GP016SLA GP016SLB GP017SLA GP017SLA (Duplicate) CHEMICAL PESTICIDES/PCB$ DIELDRIN 3.6 U 3.6 U 3.7 U 3.8 U 3.6 U 3.5 U 3.4 U 3.4 U 1.a(!H 3.4 U $!\!P2i1:!!filr&!\/Jif.t;!ifi!i!i'i!t 11~ua wauRw fad;$oo<···•·• Hl!Iii!B Mi§!!i!Hi l1l~!JR1 n t1a1J1 r ENDOSULFAN II (BETA) 3.6 UR 3.6 UR 3. 7 UR 3.8 UR 3.6 UR 3.5 UR 3.4 U siiibliiiii n tiJl\li I ij(e;UH 1$/tI!il t i;~l!!H@ I iiiIQ H l@;t!M l Iil'.#v IH i.i!fW ENDRIN ALDHYDE 3.6 U 3.6 U 3.7 U 3.8 U 3.6 U 3.4 U 3.4 U ltNPRIN KltYXQNi; .............. ........ ; ~',S 94 I i~il'l urn ll;t l!J 1i r t I at~ lil;f lfiifij a 4 u GAMMA-BHC (LINDANE) 1.9 U 1.8 U 1.9 U 2 U 1.8 U 1.8 U ·1.8 U 1.8 U GAtWvil!JoBl!otlJ>.w.llgt? ········•••·•·•·•·•·•·•·••··•·•·•·•••·•·•·• r$•t1 .. ·•·•·•·•·•·•·•···t·•·•·•·•·••1;ap .. •••·•·•·•·••··•·•···•••·•·•·••··1;~gJ gµ Lttn 11~:9 M!M!i I HI ll~M ii 1i8!Ji HEPTACHLOR 1.9 U 1.8 U 1.9 U 2U 1.8 U 1.8 U 1.8 U 1.2 JN METHOXYCHLOR i@l&!@~itill@Pft§@R1g§!!I ....... -.. :, PCB-1260 (AROCHLOR 1260) 36 U 36 U 37 U 38 U 36 U 34 U 4 of 18 ------------------- GP017SLB CHEMICAL PESTICIDES/PCBS TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE GP017SLB (Duplicate) PLYMOUTH, NORTH CAROLINA GP018SLA GP018SLA (Duplicate) GP019SLA GP019SLB GP020SLA Section 2 Soll Sampling Investigation GP020SLB !!i!!'f@Rtlte1e;:@12@r1@ + !W i Imm ti rn:t :rni@iBW!!! , i1;;1g !11!:ts I~/$. ll!R 1 i~l~ !i!Rt ;: w rnu§1µ11iw ;;;; #tt9 1rm1~ww~:§?P" : M w ~;7,µ 4,4'-DDE (P,P'-DDE) 3.7 U 19 U 3.5 UR 3.5 UR 18 U 3.7 U 3.6 UR 3.7 UR #t#HRPIBlIBlfiliP:Rflilff1l!lliil >> c :; ;,,,, £ >·vtvN,,v+:wu :l!!itU ·······1n;:g1prnj ?fF6gilJ)?rnMi1)R?iiii!h:}!l¢§f\:!RWP?e?i9 ALDRIN 9.2 U 1.9 U 1.9 U 1.9 U DIELDRIN 3.7U 19U 3.5U 3.5U 18U 3.7U 3.6U 3.7U §WR@§Wirf'.ittlii[e!lwii!:1 77'.T/ff{'.; Tir:90 ;2:; :neu; LAJ'VQ!lt··· ··mmHOR LZ f~@q trnrnrnJ{QJ!ilfd@i# ihliillR!@HMHiiFOR ENDOSULFAN II (BETA) 1¥N@R!NF ENDRIN ALDHYDE itNR!'!l!'l Kiiirn@!'i§l rn GAMMA-BHC (LINDANE) GAMMAfG!i!!\QRQ/:s;!)lpt2? ·• ··········· ·· METHOXYCHLOR RGaiiff~$4I!f,R,◊¢BlioRti~54H fi PCB-1260 (AROCHLOR 1260) 3.7 U 40 U 3.5 UR 3.5 UR 18 U 3.7 U 3.6 UR 3.7 UR ><><>< GTE ~r:11>>> '.'.'.iffi!it :z dsp ~;§u Jllc!'!n:;: ,at7Iui +•irai\lut ii@;1K1w 3.7 U 3.5 U 3.5 U 18 U 0.76 J 3.6 U 3.7 U ,: '.~;'tlii B;§Q4 ~l§!!JlL .t~V":'1:i!IE!~\1'.!lm;:;;;;::;:!&l!Q~': :;:g;z!ll4 1.9U 9.6U 1.8U 1.8U 9.2U 1.9U 1.9U 1.9U ·!lJiaW • i9i6•U ; :J~Q a;irm;;; ~i:?9.,FLTMfrs"U'.'ttn :J;Jl\g 1rntidF 1.9 U 9.6 U 9.2 U 1.9 U 1.9 U 1.9 U t't:r~v+ ::+i!4u rn~:z;o::; t:l!;g~;u;r1:;::x1:sru+rn;;;;1;~u: 19 U 96 U 18 U 18 U 92 U 19 U 19 U 19 U >··'i!F!'. ;9,;~z:tr ;;tt~gqe 351] @§;µ;; l1i\Ottl.@%}HF3'r\.UK:l:: 36UWIH 370T 37 U 190 U 35 U 35 U 180 U 37 U 36 U 37 U 5 of 18 -- -- -- - ----- - - - -- - Section 2 Soll Sampllng Investigation TABLE 2-2 SOIL SAMPLING SUMMARY· PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP021SLA GP021SLB GP022SLA GP022SLB GP023SLA GP023SLB GP024SLA GP024SLB CHEMICAL PESTICIPESIPCBS if;~*RPR(fl1fft!?ia!?lI @ey;§@BL. B!1LVRY a.au· · .. ·•i;'.'a·:z:u l ll ~!!!ll1lll~I4Ml llil1 ~l~YBlll IWlAH1I 4,4'-DDE (P,P'-DDE) 3.6UR 3.4UR 3.8U 3.7U 4U '...2J 6.8UR 3.2J 1\lf'.tRRTilfl\!ll)f!:IgT}!!Hl ..... , i ;;i~jeyg &;~;g fff@1!liU i;;;p;gs;) III 4iQff@iG lM(4!J; lNliffW;;JjQ rnrnr ill!t!!il ALDRIN 1.9 U 1.8 U 2U 1.9 U 2 U 2.3 U 3.5 U 2.9 U DIELDRIN 3.8 U 3.7 U 4 U 4.4 U 6.8 U 5.6 U §t'!@@i1W£Eeif!!l!&!&~&i t@IWi 'dliji!iffl ;; : g;urnr; 2aW.t ··.·.·.·.·a;s gR . @l~WR ENDOSULFAN II (BETA) 3.6 UR 3.4 UR 3.8 U 3.7 U 4 U 6.8 UR 5.6 UR ENDRii\:f ·.-;-:-.-:•,:·:·::;:❖:•;.·-·.;,·.·.·. fojg;§Y; }'. !ti#Q:li;::'.; I~l~lliil ;;ta)ttL I ft;Q;; Willi' §it!M: rn {Il$llMQHl ENDRIN ALDHYDE 3.6 U 3.4 U 3.8 U 3.7 U 4 U 4.4 U 6.8 U 5.6 U !:t:IRRIN !Slf'Nl1f@!i!,$Hil@i\ifl :&ifri I l ililtMF@:l,s uJ i ,3;4, o;fi,f@ i¾ itU i ?;{Hl~l!!Ml,W '\, ~;q:;72;;; ,¥¥9 ' illff F?ia;wnI;1rni!§l§l!!!U GAMMA-BHC (LINDANE) 1.8 U 2 U 1.9 U 2 U 2.3 U 3.5 U 2.9 U dAMMA.~C8tpfIDANEizdi ... . •·•·•·•·t llf]/1:/ \ [f g ; ;;;;;;;1%4'. <> JFU•D;E '.;@%H....... L.~.6 U· >A fgJ8t©I HEPTACHLOR 1.9 U 1.8 U 2 U 1.9 U 2 U 0.82 JN 3.5 U 2.9 U METHOXYCHLOR R@!Ri3§il~l2@HYRB@tl°ll li!l l PCB-1260 (AROCHLOR 1260) 19 U YL>•i•~eµ; 36 U 18 U •:; iJi! !Jrc; 34 U 20 U 23 U 35 U 29 U *9;g;r;;;;:;71;4;q;;c; Rl§!Jil!l!I@IIU ®UL 38 U ~u ~u 68U ~u 6 of 18 - -- --- CHEMICAL PESTICIPESIPCBS 1;1~Bi{e!ffll!l!RRlill tJ CS 4,4'-DDE (P,P'-DDE) li)!!iiR.BI {R;filfQRiiI@!lli!! rnr ALDRIN AtPi1l~aR& HI :-:-:,:-:-:«❖:❖:❖:❖:❖:❖:•:·:·:•:•:•:•:·:❖:•:❖:❖·--,. BETA-BHC -- --- - ------ - Section 2 Soll Sampl/ng Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP025SLA GP025SLB GP025SLC GP026SLA GP026SLB GP026SLC GP027SLA GP027SLB f@•l➔l!?!l!B f;il l~\#°MB! il W~!~!i!ft il!J;!J~l§\0$\l i§:t .VR!fftl:l!~l~;litBnffa l:~;s(iJ@H tiiif~i~P. : 3.6 UR 3.4 UR 3.9 UR 3.5 UR 5.1 UR 3.6 UR 3.5 UR 3.4 UR Hiil~l!!fli!Iil ll§l~Q ij:i!iu th d#@J@;i; %4,Mi.Uiii;i@$;ittUfriiil @l1l@1 · aAU 1.8 U 1.8 U 2 U 1.8 U 2.6 U 1.8 U 1.8 U 1.8 U n na&ll?IVll; lll !lIJl§lQ#li Eilt;;g·yl!];i;,;r;;:;1i*tYMiiil[i:i Iq\~Q~;/;~;I@iewi!ii I 1:tl§l!fig ;; rt ~Qg 4.6N 1.8U 2U 1.8U 2.6U 1.8U 1.8U 1.8U DIELDRIN 3.6 U 3.4 U 3.9 U 3.5 U 5.1 U 3.6 U 3.5 U 3.4 U gfilpfl§QµfiANllf~RRffl~! r f•~\!lWRl 1\~Q/31 :;: '.,?!JR/ 1i~YRi I] ~iR!i!Biirnrn1i§QfllE fH~iaIORM !HJlil~QB ENDOSULFAN II (BETA) 3.6 UR 3.4 UR 3.9 UR 3.5 UR 5.1 UR 3.6 UR 3.5 UR 3.4 UR i;NbRIN ;rrrnww I;rnrnt nnnnrnrn;;;rnR£1rumrw;raA1pn;rn 1;,,,3;sumff J?i!'Wt:1;n;;;;;91~t;1+rn;w1r3:et1I ;qquu; 1 ·rna:!ttli ENDRIN ALDHYDE 2.8 J 3.4 U 3.9 U 3.5 U 6.4 3.6 U 3.5 U 3.4 U §J'iRfl!Ni~§Ym§N§lI!l H I n ;;;n; m;; ;g w~t \;/ilJ@tliill %l41\;pjj lHh~i!li!il.iJ! M!idI ~;§ l:14/I ; l i!lf@g li wrnrn~i§!!il!!i%frt@I§!&•\:MF n Hl@4!W GAMMA-BHC (LINDANE) 1.8 U 1.8 U 2 U 1.8 U 2.6 U 1.8 U 1.8 U 1.8 U QAMMt#GFiii'dROANEiz H rnE1!!!t! Imii!l m§l\:IHH wm;gg;11im1i1;~;i(l,t!l I@i~l!i(l!Iililfil!!i!l!!!!li H\tH!l8</l!IIMli1i!~!JW HEPTACHLOR 1.8 U 1.8 U 2 U 1.8 U 2.6 U 1.8 U 1.8 U 1.8 U fflsRIA§filgQf§§RQX!PsWII rnrn;.; x 'S i;tiili*P .. ,;.I 1i~IH; I );;;;g;Ji)) .w\ ... J.,!i;,\\l,,i ,;.; ..... g,§,.Q ... ; ... , .. ; .. \1.,§.!)!;,",········J,§;Q .... ;;. Mih~R;; METHOXYCHLOR 18 U 20 U 18 U 26 U 18 U 18 U 18 U B@!¾!@§#!AB8P)ib9B1g§jfj W:m!i!! ~gJi! fili~EiJll!l!;'is1u iNi@§il!: ll i~~p t ii~iiu PCB-1260 (AROCHLOR 1260) 36 U 34 U 39 U 35 U 51 U 36 U 35 U 34 U 7 of 18 - --- - --- - - - ------- --Section 2 SoD Sampling Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP027SLC GP028SLA GP028SLB GP028SLC GP029SLA GP029SLB GP029SLC GP030SLA CHEMICAL PESTICIPES/PCBS 1;\!\4ppl)i(l?1Ri\PPPil &Fl% l M; lH @Ml!hd l it$ ORH@t!: J3i$ PB M;rn ?i~ Q.&n l t;I@ll!iP..RIIliH)/$;!!t!l¥!H\1i;' ~Jl ;IJ! Ib Mil~iZ U 1 ! ;rnihi ~;$ U.R 4,4'-DDE (P,P'-DDE) 3.5 UR 3.5 UR 3.9 UR 3.5 UR 3.4 U 3.8 U 1.7 J 3.5 UR l4li\'tl?l?rnl!elfltt!?B'9 n •·•·•·•·•·•·•·•·•·•·•·•·•·•·•·•·•···········•·•······ @!§!l!!i•g1w?:srui_ ppi9••-□ naisrnnmrnrn ~i~)g,IF. ~11l'P .. >e:, mrrn:nn@isrun ALDRIN 1.8U 1.8U 2U 1.8U 1.7U 2U 1.9U 1.8U e,µffRA!!lB.◊Mff ; ; '.jjJ@;il!l! lk+ !1;& !l/JlM!dli !;l!l!JJI Vi:il:';Z;iJJ I; ;!JJ})Ji!lii i i it\liW!JfNTlMI ;rn l\z Q ffff rn Il!llllim!l•ltl!JhJ!}I!li& BETA-BHC 1.8 U 1.8 U 2 U 1.8 U 1.7 U 2 U 1.9 U 1.8 U ENDOSULFAN II (BETA) 3.5 UR 3.5 UR 3.9 UR 3.5 UR 3.4 U 3.8 U 3.7 U 3.5 UR qi[lg13ii[I i rnrr ., .... ,. . ... CE' 1;.r~l!tti@ll!Wf~)$U n l:l~liJllMlJ l\~;gl;b l!~ilHf!HE ,; ;Hliy rn•:!f}jtl#l?)Ql: • ffl'.}~l~QH ENDRIN ALDHYDE 3.5 U 3.5 U 3.9 U 3.5 U 3.4 U 3.8 U 3.7 U 3.5 U ~M?fB!IHtlosti*NS!~;: !MfflH M/eyJ~H l!(\,jj~!tlil@I Ii!liiliFli( :2q z•i. 1lq~--?ii:~11••••· HEPTACHLOR 1.8 U 1.8 U 2 U 1.8 U 1.7 U 2 U 1.9 U 1.8 U §§J;'[ACH@::!BsRi219H§Hhl nw I!!!Wii ; ~glNffW!Hwll1)~I!i! n l IMIFMlgll!'! ::::d;.ey;rj}} 1/i!·/UY ii ; ;; ~ ~X;Y} %~•¥! ii '. a !;'8 g METHOXYCHLOR 18 U 18 U 20 U 18 U 17 U 20 U 19 U 18 U !il%§1%)@.p~\~~lt!i!!i9Bi1&~~m; H l!lW lliM?!!Jl !li!Wif@llp If! i H ;n l~~lO ' j;'35'U' " ;~ J!!;rnrnm ?~;q ;:: ;;; ;};JIU ;;;; ; ; 3!i U PCB-1260 (AROCHLOR 1260) 35 U 35 U 39 U 35 U 34 U 38 U 37 U 35 U 8 of 18 ---- ----- -- - ---- - - Section 2 Soll Sampling Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP0305LB GP030SLC GP031SLA GP031SLB GP032SLA GP033SL.A GP034SL.A GP034SLB CHEMICAL PESTICIDES/PCB$ ~l~liPRQfRiB'.fQR9ll!l[\i!'I rn#t L iftjj It\ ;; H~:$ g§ :: :;:&;y: gj§ ZFL l\l;glQRK W$i,t 01"{ rn k$\ffiQl'fiH@lll~;?!!MRW l!il ;}i§it/~ l !lI;lll)l~ l:L 4,4'-DDE (P,P'-DDE) 3.6 UR 3.7 UR 3.6 UR 3.7 UR 3.8 UR 3.5 UR 3.6 UR 3.7 UR !liii!ii!RBT(B!B!tRRIBl i I l tg/§I!! ! ; Jl}t;U : ais u I~lz !I! I !!I t!i@1l!I!l/I ::n ! l llg!§ !it ll i ! §]ll!QiiIII iiil~;f!!'!I! ALDRIN 1.9 U 1.9 U 1.9 U 1.9 U 2 U 1.8 U 1.8 U 1.9 U &\\BMet!:lfil§)iJ!H ;;!;:1;t;;; rnmil!WQl!!irn@ti\fJ:mrn@t Wl!lP.AH '. :){ij(lj • F\.i!JJF:i; jj\\Jjfr ?h;Ji l/4 ,4,;d(sqq, BETA-BHC 1.9 U 1.9 U 1.9 U 1.9 U 2 U 1.8 U 1.8 U 1.9 U DIELDRIN 3.6 U 3.7 U 3.6 U 3.7 U 3.8 U 3.5 U 3.6 U 3.7 U i::NDQSQLl1AN ji)l;(pflA·) It ilfll ltlli w tlfaiaiUR wrnHH#ii! IJs l rn l 'l:91QR1 {; i @tWluR ili faWHtz i:u,i;i;;H t#ii!t/RP.n }iiil!iUR ; Fil[) 1fa WR ......... ..: ..... :.: .......... c ... .:,. .. ,., .. dJJ, .•• , .•... ; ..• ,.,, .•.•••. :.n . .. . . .... .. . . ,.. .......... . . .. ............. . ......... . ... . .... .. . . .. .. ... .. . .. .. ENDOSULFAN II (BETA) 3.6 UR 7 UR 3.6 UR 3.7 UR 3.8 UR 3.5 UR 3.6 UR 3.7 UR E,N\tlRlf:llllEH ! nie l ~;!l;G li ! §;z;g ! !4i!!ill!\;; li~1?;lU ;n d@1l!,!l/ll ;•;; ;~;1mn ;;a;i\U if ;;~~?ti£ ENDRIN ALDHYDE 3.6 U 20 U 3.6 U 3.7 U :4.7 3.5 U 3.6 U 5 U €Nf?ffi!)!!S§MlllQ!l!§..IHI:m· ?t)il$/6i!llil fr; $llYQ! pa•s·••ulid I 3;7•pli···.•··••;:•::··s;s··uu· .: , .. :)PU!Jif';; j i~)!E!t~ii! i~i?!lW•• GAMMA-BHC (LINDANE) GAMMffi§.fillil'RRRAf:!J?i2i t HEPTACHLOR HElPTACRLOREP6Xi6!%H 1.9U 1.9U 1.9U 1.9U 2U 1.8U 1.8U 1.9U :; ;;; lii~I@llI!ii!Ii1ill'Mil!Mli@J!!I!Jll q1,gu; ;r:~Q 0:2 Ji§\Wii ::rn1:J!,U i!;iJ:lE!l/ 1.9 U 1.9 U 1.9 U 1.9 U 2 U · 1.8 U 1.8 U 1.9 U 11;~g IIifli1\~9['ii F1!llI!!!IlI fi:hllV ;;;·: @\f;;';;;; rr~r;e;: ;.; .. ,J,.~.\J : n;!!Qi METHOXYCHLOR 19 U 19 U 19 U 19 U 20 U 18 U 18 U 19 U PG§it9?&XARQ$.1il!'iPB1f?fr}Jl@WM!• ....... ·.fo iC••· ··•·•·•·•·um§IQL .... · '!'i~?P .. ····•;;+; -~§;Mnn .. Ei:~zq; .... p;$31VH;y ' asur. '.?,'.(},6!} jpi/y:f31tJf PCB-1260 (AROCHLOR 1260) 36 U . 210 36 U 37 U 38 U 35 U 36 U 100 U 9 of 18 - - --- CHEMICAL PESTICIDES/PCBS !i~:!Pfl'fi:IR1Rtf@R!?l 4.4'-DDE (P,P'-DDE) iflm!RPlliRBiiJJqg;QI; ALDRIN :4freiiUiU!illc BETA-BHC - --- - -- - - --- --Section 2 Soil Sampling lnvesUgation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP034SLC GP035SLA GP035SLB GP035SLC GP036SLA GP036SLB GP036SLC GP037SLA 411¥/B % q;;};ttj~J... IH~;~•••WB ·rn:I@;~gg t•ta1gg. nt WWURT F~isUt,HF tii§lWW•··· 4.1 UR 4 UR 5 UR 3.7 UR 3.4 UR 3.7 UR 3.5 UR 3.7 UR rnrnrn+ntil IIIHM@ifl)Qt:rnnnrn@wtlti!MVi!H@.l~lP:tUW!Ii!@.iZQIEMIH•~>!l!JiltlffHl;fiz:l!i.! ;19;gll\! ' ; ~YI:\!) 2.1 U 2 U 2 U 1.9 U 1.8 U 1.9 U 1.8 U 1.9 U ·g,!i:1a ·. ::,. 2 u:1 IR!l@liltI!l~il!Jirnll!l11§;t!!iiliF:t@t~Ii¥i!i.lrnI1i112, rn~wm 2.1 U 2 U 2 U 1.9 U 1.8 U 1.9 U 1.8 U 1.9 U DIELDRIN 4.1 U 4 U 3.8 U 3.7 U 3.4 U 3.7 U 3.5 U 3.7 U gNQQB\!1@;6!\iit(~!!RB&1III!ii!illiIHl : 1 M [Ji!llltl ,fi1i!i.tRH! ll I @!!flllirn! 1g;!!!f{ lllill!ii1i~li!!!Rilllil!WJ1.i.§1!i/BJliliilll1illi litR li jf;J!!ti~l!i.tfli · :1 ifDa ENDOSULFAN II (BETA) 4.1 UR 4 UR 3.8 UR 4 UR 3.4 UR 3.7 UR 3.5 UR 3.7 UR Eilibi'ii& r• ••········· •: ••-t•••••, •+&Au ••t•• • A•ti •· ··rn~;~•!iNI:rnn;•i?i@!l!•!HMMM•~;1:.u••••·· t\Wtr•iw•·••••••••••••••~;ey;u• ··••••·•·•·a·t·u• ENDRIN ALDHYDE 4.1 U 4 U 5 U 3.7 U 3.4 U 3.7 U 3.5 U 3.7 U !if!RR!rl !S@f@;Qfi/.§ t • m lffHW+rn l litnt;;;;4@\!!!!fri!foil /Ml#'.Wi!Mlt!Iiii~ ~ !lii!li)iljjl,~)J'iI!ll~Iifr•li)i[~\1ill!Afll; ; ;G&)zm!; ; : ;;~;:§ QJ . 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H ljjj~($Mf§l@ li!H:?lQR e.'.§:!\l!3d@@ia)pRIR . 4,4'-DDE (P,P'-DDE) .· 0.98 JN 6.2 J 3.6 UR 3.5 UR 4.2 UR 3.6 UR 3.6 UR ~l~]RRIBlRlRl@!'iiPlli •·•·•·•·•·•·•·•·•·•·•························································H!i!@?HP... t@iiI:9{'.•.•.'.~·.·, if&tl OH . '\iRi?'!l!i:iMrnl·m1fa?Hi!I •. t~)6UM\ }i·•~··ll·•·o•·•·•···•·c ALDRIN 1.8 U 2.2 U 1.8 U DIELDRIN 3.5 U 3.6 U 3.6 U 3.5 U 4.2 U 5 U 3.6 U 3.7 U 1;~o~sp1.JFAN/ilA¼PiilA!l Iil lt trn Iilli:l;Mf il fofaia)µ I Ii !%ll!;gqgtW/11!!Mfll' WFJ lil rnwa1ii1BH!@iil:H2t\!iJ{l)I ii~: ORt}n!@!i'JllilLIR ll fi;s;ua ENDOSULFAN II (BETA) 3.5 U 3.6 UR 3.6 UR . 3.5 UR 4.2 UR 3.6 UR 3.6 UR 3.7 UR €i!l!RB!NH ilMrnlHllL....... iIIMMitmrnmit~Ji!l@PM!ll~l§.@ff,MiMIH$\lKP l l llRi?!i!i!lli1llll!l6il\! lil H gg\QWMIHlllgJ§!i! H HH$!'1'Qf ENDRIN ALDHYDE 3.5 U 3.6 U 3.6 U 3.5 U 4.2 U 3.6 U 3.6 U 3.7 U §NfilB!NK§XffiQN§\il\ 'EH1l~lilr ll'l ll:~;;gq ll!l:::ll@l~Wf ii l~l§l!\!~J;;@rn::r4@:µ.g;;; I %\?)Q;JH lliiI~l~ ua i@;Z\!'W GAMMA-BHC (LINDANE) 1.8 U 40 U 1.8 U · 1.8 U 2.2 U 1.9 U 1.8 U 1.9 U §~f¢ffi!il'2BPAN$f?H Hiil!ti i?!~i\l,'.tHHJi?P 1i~!,lll')Tlill?1?lHilli I1!%!ii\ :;•MtP M!IP HEPTACHLOR 1.8 U 1.9 U 1.8 U 1.8 U 2.2 U 1.9 U 1.8 U 1.9 U ReefAi:;fli!i;iR!l;g,q~r&E!I n i;n@1:1mr~1;r: IH i1l§IPlFHJ 41~!!1! n mnurMrnnn;i~@n rnm;wo1nrni@wa;l}!Pn I:ii;g!JI METHOXYCHLOR 18 U . 28 18 U 18 U 22 U 19 U 18 U 19 U fiR!;l@4!'i!fXA89PH4!?BiJ?filffl l Il!JllHMitill@Ai!!ti ;;ug;~g(g;;rnf~IWE\!· 1 '. 3§U ;;wrn;ah!\ll )2'.tf$;pt:rn:t; ; '.allµ ;;ff~y::o: PCB-1260 (AROCHLOR 1260) 35 U 36 U 36 U 35 U 42 U 110 36 U 37 U 12 of 18 ---- - --- - - - - ----- - - Section 2 Soll Sampling Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP044SLA GP044SLB GP045SLA GP045SLB GP045SLC GP046SLA GP046SLB GP046SLC CHEMICAL PESTICIDES/PCB$ it#tJ©QPJRiRHPPPJUr 4,4'-DDE (P,P'-DDE) 1t4'.1!lllThm!e1RttPRT1 t:';•t?······ 1i@~l~;0a lii\l,!li§i!l!Biltlll ey;~jQ?;HiilNii@l§llMBHW:ill)@l@WBliiri l ~l$JVtl!illn @20/u;ti ll'@glii 3.9 UR 4.3 UR 3.9 UR 3.6 UR 3.6 UR 3.5 U 19 U Hl/!lQ aoun amun ~!!~vi @fJ!l!Hli t~:~llJl:I HlH1!!il'! ALDRIN 2U 2.2U 2U 1.8U 1.8U 1.8U 10U 9.7U DIELDRIN 3.9 U 4.3 U 3.9 U 3.6 U 3.6 U 3.5 U 20 U 19 U §N!llQ§!i!\\f.1£NlH(i%~B\M)J!l llW ;;}; il!MM!&!!!!B ': Ji?'tiUB :a!·t iti.B/i;b;:d:~ URI'Dfa'AiaDR#J{;ffi:a;ti: :'! ; \nl Otfa'; >;%wi@n ENDOSULFAN II (BETA) 3.9 UR 4.3 UR 2.9 J 3.6 UR 3.6 UR 3.5 U 31 U 160 U ENPWN H l ll~'-~l!l! Hil l#l~i!! :: ~l~D)i! l' ll~l§!ll 1·1.:rnrn@\l}pl ,I;;lH @!{(!Jlffl@l ll\?llQ • l!?W ENDRIN ALDHYDE 60 U 140 U 31 3.6 U 3.6 U 3.5 U 20 U 190 U €li!Rifilli!!S§Yffi9!l!§]l :: i!'.~im@! ;;;rn:~@IRJlill;: a;gµJ !HLl~l§@i i;%i~\§LQg;JlH::il~l%'YPf ;;; gii;r;r;:n; ; Higo GAMMA-BHC (LINDANE) 2 U 2.2 U 2 U 1.8 U 1.8 U 1.8 U 10 U 1.5 J §4MM!¥9HilPRt!A!llgg ii• H mmr· @:ti P i i::11~ ,Ni ll I l t g !iM l l!Hll~l~IQ i@tifi%11~ liWI ;li H !!~ Ui:tlll\ i19 !llii{{;' !N?}Yi HEPTACHLOR 2 U 2.2 U 2 U 1.8 U 1.8 U 1.8 U 10 U 9.7 U H~f1f4Qf!WRR gggx!R~ii! rn nrntML I :i:11 g1u I n :g;z o ;;: ;;;; ~ u ; urn: ;;1m:!ll: ;; ;n;Jrn;;p;;:rn:rnx ~ts v:;; ;; ;; l@'!iU: ; ; ; Jag,nn 20 U 60 U 20 U 18 U 18 U 18 U 170 97 U METHOXYCHLOR {;L:w 11 ll~,3l9 iH!l~gW-! lll Mi~!l!l!!'1 lll g~.\ii il iI~tl,!llM fllll~~!Mr!l l![i1~00~HlH 2800 160 U 49 36 U 35 U 200 U 190 U B9§11i~JiB!ll~filij@Bli@iil!I PCB-1260 (AROCHLOR 1260) 1100 13 of 18 ------ CHEMICAL PESJICIPES/PCBS :#M!.!fR!?RfB;R!Ii?PP~I 4,4'-DDE (P,P'-DDE) li'lli'fi!if@J\(B!BlfR!aNl: F ALDRIN DIELDRIN §!'!.P@§\;/gg.,«N.\!If\\$t111>1rnmirn ENDOSULFAN II (BETA) ENdRiN '. ENDRIN ALDHYDE €t'!RB1til!S€Ym2tl§ iii!! 1!!1 !itilI n ;;;u,r GAMMA-BHC (LINDANE) @AMM6f,9!;lijQBR&N§Igi rnm HEPTACHLOR !:J§iII6§t!ggg:§R~~\9§ i!miWH - - ---- -- - - --Seer/on 2 Soll Sampling InvestigaUon TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP047SLA GP047SLB GP048SLA GP048SLB GP048SLC GP049SLA GP049SLB GP049SLC 1111~1gI!llsf1l ;11~1z:2a: H :m~;~qg ,t,\$yt4aymif!a;1.uR.n , ,(!;s<µR iiiua;; 3.9 UR 3.7 UR 3.9 UR 3.7 UR 3.7 UR 3.5 UR 6 UR 4.2 :uiu $!irl9Wt unmtli!!P: 7?3at0:· .> ;~~§,Yi , "i't!i!;;; >>•·•;12 3.9 U ifo;I;lll!gfl!~iih 3.9 UR '\'\3-i9?ti:ffNJ 2.1 U 3.9 U 3.7 U 3.7 U 3.5 U 4 U 4.2 U ,· ;2,ua;,,, w,disua,niii;1,a.0Rii, 1,atiR,, ,, "'2ittlR ,,n,tzilu 3.9 UR 3.7 UR 3.7 UR 3.5 UR 5 UR 4.2 UR ; ~;g!!; ·+:i·3i1Q '. '. '. $;z q > ~l§t\Jl , WU '. gqp: 3.9 U 3.7 U 3.9 U 3.7 U 3.7 U 3.5 U 20 U 4.2 U %WM%igili/f!tEtliti ?lZMi!lil Wa\$£!®! 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EtR •fr'.397 ip,::: ;i,9fa;g:;;;; :i1PYi, 4:~!Ei 37 U 37 U 35 U . 320 42 U gg~jjg~('5R2QflH@Rig§4ili "" liHfjllJJ i,WiP-w-···· PCB-1260 (AROCHLOR 1260) 39 U 37 U 39 U 14 of 18 - ----- ----- ---- - --- - Section 2 Soll Sampling Investigation TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP0S0SLA GP0S0SLB GP051SLA GP051$LB GP051SLC GP052SLA GP052SLB GP053SLA CHEMICAL PEST!CIDES/PCBS !fi!fl!Rl?!?Rffli@l!RWRJ !3-!5\l! iii iii ~1;~:Qlli ii; hi)g!JR! ~;$iJRil'.t!!1& URlTft~;e:o tr:v;,S;\iU; kiksua 4,4'-DDE (P ,P'-DDE) 3.5 U 4.8 U 4.2 UR 3.9 UR 4.5 UR 3.9 U c:__ 10 frifr(fP.ilfti!'!lR:IRmlJf ··· •.· ... 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C2&ft , , g~·!.1.)• HEPTACHLOR 1.8 U 2.5 U 2.1 U 2 U 2.3 U 2 U 2.9 U 2.3 U H€BTeISfil£9B€BfilX!!¥§':;;;f!:;J ,c'., 0::x:.,1.a-:v:'',:\2;s;u :: :Lill \.'./'':2Qr\:;>2faui• , :2u< 1:z:g:::< ;,, ;vrv: METHOXYCHLOR 18 U 25 U 21 U 20 U 23 U 20 U 29 U 23 U R£§t~R§~feig99ftM9ff!1M§1i!ifi >,;+ hd?~!JWlH Kii!!lilti iMKlM~¥.IHL i@ggrn; ." 145:U! n }}l!t!!rnn ...... > !l't!Jf%i i45U PCB-1260 (AROCHLOR 1260) 35 U 48 U . 78 39 U 45 U 39 U 57 U 45 U 15 of 18 ------------------- GP053SLB CHEMICAL PESTICIDES/PC BS ./!11!~i?IP1Rlf@i?@l iii 4,4'-DDE TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP053SLC GP054SLA GP054SLB GP054SLC GP055SLA GP055SLB Section 2 Soll Sampling Investigation GP056SLA DIELDRIN 18 U 3.9 U 4 U 3.4 U 3.4 U 1Bili@@§\1!Rll~!flil{6~Jll61ll rnrn;;;:1 ............ w.1w. :;::.•: <?J:L••·•• ••.•··.··············•··1 ivgny +lHWP.R,rn11:Iw11~1p .. . 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GAMMA-BHC (LINDANE) 1.9 U 1.8 U 1.8 U • 15 J 1.9 U 1.8 U 1.9 U 2 U @AMMM@Hk9EQAN§/ii ;});; Jl!! UH E1% tti{:l] !!!H IJtrnrt!!lliMI ; 'H!-~Rf!lff 'EM~P ! i )'i;it8tHi :mmw; ; HEPTACHLOR 1.9 U 1.8 U 1.8 U 1.9 U 1.9 U 1.8 U 1.9 U 2 U METHOXYCHLOR eqiil:1i@~JARRGH~Q!:}hlg§~lJWWIW PCB-1260 (AROCHLOR 1260) 19 UJ 18 UJ ?~i!iiff lHMilil®JP.WIW 36 U 36 U 18 UJ 19 U 19 UJ 18 UJ 19 UJ 20 UJ naM!ll IiWHHg't 4rn@rnrn ;!$:p m Mtrnm J)~!i!!i/rntn i@@BlLY l I lli[E~ Pi 37 U 37 U 35 U 37 U 38 U 34 U 17 of 18 ------------------- GP207SLA CHEMICAL PESTICIPES/PCBS METHOXYCHLOR !:l@!'¾Jg~ l\'¥R@@li!W@R@?§if1 PCB-1260 (AROCHLOR 1260) 34 U TABLE 2-2 SOIL SAMPLING SUMMARY -PESTICIDES AND PCBs GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP20BSLA GP209SLA GP210SLA GP211SLA GP212SLA 18 UJ 17 UJ 20 UJ 18 UJ :'II\35:':IJ/:':':' {ttt/gj!HJ: t::':':':':'t':t\39iUt,:II'''''''''W·C··· 3!%U .-:-:-:❖:❖:-:,:-:-:-:-:-:-:-:❖:❖·-;-:,:-:-:-:-:-:.:-:-:-:-:-:-:-:-.•.·.·.·-·-·:" 35 U 35 U 34 U 39 U 34 U GP213SLA Section 2 Soll Sampling Investigation GP214SLA 18 UJ 17 UJ M.U•••Fi @EV 34 U 34 U 18 of 18 -------- ----S"'1on 2 son Sampling ttwfftigatJon CHEMICAL PIOXINS/EIJRANS 1di~i~M@&i!l!!Wfff,,QljJ;Q~@i~~lQX!EF; L ; . 1,2,3,4,6, 7,8-HEPTACHLORODIBENZOFURAN i~!~ii;i!i!i€Al!rif !q'.jtggjjj!!§~!lli/#.ij 1,2,3,4, 7 ,8-HEXACHLORODIBENZODIOXIN iwi,l!ltl~ii@&A%\t@l¢!\lij/oo.;;ilifm m GP001SLA TABLE 2-3 SOIL SAMPLING SUMMARY· DIOXINS AND FURANS GEORGIA-PACIFIC SITE GP001SLB (Duplicate) PLYMOUTH, NORTH CAROLINA GP002SLA GP002SLB GP003SLA GP003SLB GP004SLA GP004SLB ::}:~:;:::t2trtMt ··--.·-·-·-·--,.~r::::/:::~A ------:,,,,,L~,,,,,,,:::::,,,htfa. ----❖-·' ----~,=~d~r ;;;;;;:\:\:;:;;;_;:::::/:Nl(t::::.,:{,:LffEY?NAr:z::•:•~:r:=:=•Et::::m>:?t:?•<<= :::::;;;;<5}~ NA : j·· :dlii NA ,14 NA ?)iii¥ ••t•·,·, ··M,s@r:::w· WE!'!/\ NA NA 27 !:/,NI tiniil .·.·.·········;···:·m;;arnm ............. . NA NA 4.8 U NA NA NA 4.2 J NA w r··: trw;,: wa&+ .,. ; MA :rnmr.. t<< NA > '.~:•: 1¥x< r ;;gi; 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN NA NA 3.6 J NA NA NA· 12 NA :i@?l~iil®~PBt9l!!li\iijiiii~&iimm1nrn·nirnm ·.: :.• ::;:; .; . .zwc;;: ·•;:;; :1 :wii vi WihN@nnw:n#.if · • • >·m· +:++6w·m:"'A :··· ,·•·#u " ~'"''+-<+,/!<A 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN NA NA 4.8 U NA NA NA 6.8 NA :~q;~~!.A~~H.~D~9P!§~#:)~~1IiliMJVi@1IIF:l :::::;:::;:::0:;: :ijA}-:•:=ct+:::~=::z,::Nk=r=:::::,:;:=:::=:':':::::=:::,:=:::=:,:;fff'Oti('.=f=:w::~=•=~:=wnA:,:=:,:0:g:=:,=,,=,:::::;:::7:ffiAfF'F}H?tWI&g~:r:=:=:}'?\:X:~':-;,~~:j)'.~?F:':::97:(Nt?:t::.: 1,2,3,7,8-PENTACHLORODIBENZODIOXIN NA NA 4.8 U NA NA NA 4.8 U NA !i;~!ti;;~ffl;,i;q'.j(QRQp(il§ijjggm i!!i:i HMlt;!WJ!llMIV NA ii:.~ µ ' I itt1 11/,i;Yn·;p llji l!f4 '' '" '1E!!li~ll/:lI!H!1\iliji 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN NA NA 4.8 U NA. NA NA· 4.8 U NA 2,3,7,8-TETRACHLORODIBENZODIOXIN NA NA 1.9 U NA NA NA 1.9 U NA ifat%w,1eff~cfilU:\fiooiiliifgo/i-'gE@WfolMI .;.·.·.·c·····.•:; ":i:!iii Hfrdi~fo·#A ·•·•··•·•·••·•·•·•·••·••;•)ttA'il:;; ·>:.iik .···.··;;, .. ··:.);1.t;ZF:E;;;m> ............. -:o,:i)i·,1:,1 ......... NAi;) HEPTACHLORODIBENZODIOXIN (TOTAL) NA NA 240 J NA NA NA 510 J NA B$t\i19ilto/%&pi[~Nii:i~i)AAii#i:\f&;H!iliMIFMlH ; fl 'f"/{ '.'." ; :nxmt : ; < efii;t;, ;;~; m > ., ff A >ts:; Rli4t Yi ;E;Jt~itt!d;; ; [i,i/(f/ HEXACHLORODIBENZODIOXIN (TOTAL) NA NA . 31 J NA NA NA 110 J NA /li~gi!i@i&i&i~/wz§iffit.li!rr&f!(i\t )<.;;:;/ ;)ff . · : i'lfi ~ o "'~~., : ,Ii,,;; '.: .... '..: ·.:••;TJlM!. > ; /·. W5 i frifr1W'isin!mi:nlrn/'!5W TtffV~;;wng; n ii# OCTACHLORODIBENZODIOXIN 2200 J NA NA 2600 NA PENTACHLORODIBENZODIOXIN (TOTAL) NA NA 4UJ NA NA NA 28J· NA ' ' .... ~.. .•.•.•.•.•.•.•.•.•.•.;, ............... . il!Wf4¢@@llfilQi!'igig§@!¾&1!9;t~Ht , · ••··•·• :pt .. ·qg ;. •··•·1!1(···. ' ;NA]; l#iilii!:@ : ';w,\ :•: ~ ·J!A/k :\ /MA ....... . ioWJ:Tt;'·:w;;: TEO (TOXIC EQUIV. VALUE, FROM I-TEF/89) NA NA 3.9 J NA NA NA 7,7 NA r!tiM\@ji@Rqpiiji:f~6Jo\ilRrro'.t.M)M!iMl!)(ffH 3?%% l%l1iM;M#EMWUNffA ii!ifatiJi\h@il'iAd ··•?;p·•··•·;u;.:·c;7 :ti Wi Wbl/ii;i:lefc\t.)i#dffhiifA#, TETRACHLORODIBENZOFURAN (TOTAL) NA NA 0.16 J NA NA NA 0.3 J . NA Pata Qualifiers; U = Material was analyzed but not detected. The number is the minimum quantltatlon limit R = QC Indicates that data is unusable. J = Estimated value. N = Presumptive evidence of presence of material Concentrations reported in ng/kg. 1 of 18 - _, -_, --- CHEMICAL PIOXINS/EURANS .................... , .......................................... . ~l?A/f;~mw®etA9llt◊RQQl!l!;~!Ql\!J'l -_, --; -- GPOOSSLA TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GPOOSSLB GP006SLA GP006SLB GP007SLA GP007SLA (Oupllcate) GP007SLB -· -Section 2 Soll Samplfns, Investigation GP007SLB (Duplicate) ~f~=NN=iinM=rn:nnJi~:n:ttii,:ti:::::123i~~t,~,}=~= =:::=::::/::x:=rJX ,;,;;;:;t;;::);;;;At;taji;§,; :rrnn:nw;::1:11t.:;~::~~:~::r::n~~~:n~~•;::Jtx: iH@iH:@@itNAtnn 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN NA NA , 12 NA 10 ·9.5 NA NA 1~:~1~!Vi~i~lHg!ff¥!i1l!iqtii!i!l~W%l:il%\UI w >> .. •·•· .. •·><·•·•·•·•· .. •••·•·•·•·•··· .. NA · ..• · •••• ; N!l········•.·· · ,. ··········rn;¥Hiu··············· < f;~·••iii ::t'••·~ ··········•· ,.,NA •· 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN %ifaiMi:@ii€x4bflilooooiiilmzoe&i#til t ; 1,2,3,6, 7,8-HEXACHLORODIBENZODIOXIN .·.•.·.·.·.·.·.-.·.·.-❖:•·······❖:~;-:-·-·.·.-.·.·.·-·.-.·.·.·.·.·.·.·.·.·-·.·-:❖:❖:<❖:c❖:-:❖:❖: .......... ·-·· ••• ···············•:~ t~@!i'i?m±!EXAPl#~QRQP!~lilllQfQ!lf.\!'f:FKt• ' 1,2,3, 7 ,8.9-HEXACHLORODIBENZODIOXIN i~l?;tlaloiB~Ei#IQ'&/g&lt6#flwJ'l; filI 1,2,3, 7 ,8-PENT ACHLORODIBENZODIOXIN .,:-:=:-::::,:_::::: •. ,.; ••• :., •• ,;,,:w,,;;;.,.;::;,:,:_:;::=:=:=:::·:.=:=.=::;.=.--.·:>.=::<;_:_:_:_:_:_:,:_:_;::.:_;_:_: ... : .. :=·'·=······-•·w•• !)g\@Zi!W/§t·!J)'iQH\\QRQQ!@IM?QfQRA!f! 2,3,4,6, 7,8-HEXACHLORODIBENZOFURAN ?1~111@;iwi~m\@ffiiifill2i\lmiitl1!!mm NA 3 J NA 4. 7 U 4.8 U NA NA , u;;;; ••••••• ;; <•¥iu ···•'E ?tl«t 1il@i[JJlfit•rntnm~m;; Ml INAf ·······, ffAAPf NA NA .'6.7 . NA '-~6 :.'_7_2 NA NA ..• ::z;·w;;"· :;g;m; lilt\4\li:/\••··••D:•LNA'. :nrntiMWO :k\#!iftiPiH•MWi:i·'••··· ,fr)% I NA NA 8.8 NA 18 21 NA NA ;.. ,,·.·.·. , :w,vr .t:-)A; /i!W!f HiMNAHMM Wli:'iiIDTIWHi:!MliiiJ :tli:li®X ''' 'SM¥ NA NA 4.7 U NA 4.7 U 4.8 U NA NA .-.•-•.•-·-·.·-·-·f'@tN.At:~~~~:~:~._-:·:~::'.:~::::?:':~1~~3\uu:r:~fdt~:iNi:W:~::~U:!~:~:}\#~:411;:tl!:t~MH~::W~@}fi.ftfr:!fffitH!:t~Af::ttt:dt~::~:::}JA\trt' NA 4. 7 U NA 4. 7 U 4.8 U NA NA , HHHN&I·· : :'.litJil.. ..NN ,rn,:iu grnrnno············•um; •·::::Lll¼'t 2,3,7,8-TETRACHLORODIBENZODIOXIN NA NA 1.9 U NA 1.9 U 1.9 U NA NA 2;&iiMtli'lW@B®moifiiiejlgjjKljjwf,:HE(k.•···••.····· ····~····~•"<••··· t·AA+•tH ),{•····•·w1·•· ···•·.x··•xfriii~Xi.••· ,t,:dr)¼t:; ... -,,., .. HtJM~fo~tHJrnfH1#fa&l:#@ftfH%MH@&@WHMTN)@Mi&Wt@ NA NA 650 J 120 J NA NA HEXACHLORODIBENZODIOXIN (TOTAL) NA NA 98 J NA 140 J NA NA ii™i!iB®ifi66M@t{;jtj)\Wllrr¢1#,tfriii;i n;fa@in •·•·•·•·• i\L,i;,;> •·•·•·•·•·•·•·•·•·•Nk·•·•·•·•·•·•·····•·•· i{§!H4Jtfai i:!h(~i; lHWiih~w j/iJiil;th1A YJH@NifaA ii ll tliJWlil OCTACHLORODIBENZODIOXIN 6000 NA 9600 1100 NA NA PENTACHLORODIBENZODIOXIN (TOTAL) NA NA 12 UJ NA . 20 J . 19 J NA NA iliii'#@iNii;oRoPiilWU&iillRXiii\lffi'f,ffafWlH ;;.sw ....... ,,,...... t!AH? l}FAfAMW ;;;zii¥i:iiii , .. Jwl tL@Wllii\%MM{tffFK~W@iMV•Mii¾ tl i•Aiw'ii TEQ (TOXIC EQUIV. VALUE, FROM I-TEF/89) NA NA .10 NA 15 13 NA NA fgl@§flilooi!i~gq§@~Jiiiffqjggj l H l l l!\¼li :,Nil)D kks12 tD /j>';/t#iiL t :;t:J;;W ;; i t tM DJ'. ,M@~ /An t NA!% TETRACHLORODIBENZOFURAN (TOTAL) NA NA p.16 J NA p,26 J 0.21 J NA NA 2 of 18 - - - -- CHEMICAL QIOXINSIFLJRANS -· -·--· -_,_ - GP008SLA TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GPOOBSLB GP009SLA GP009SLB GP010SLA GP010SLB --- GP011SLA -· -Section 2 Soll Samp/11111 Investigation GP012SLA ••rm ·;;; ;;,if.IA'· i;jiim •ttt iiiiAN•·•······•·•·•·•·•· i N4l ~ h 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 36 NA NA . ... NA ....•... ,, ........ ~.8 U... ..~.'.",..... NA 4.7 U ¥WlJ•~q~ !l!HilflIAcfltoROOi!le/;lroiiuAAN t .. •.•·.•·.•·.•·.·••·4·•·.:.ll.····.•·.u .• ·.··. , .• ??+ i,wf •.•·•.•·.•··•.•··.•.•.·.·•.•·····•.•·•.•····••.•·.::.· .. ••.•··"'··.• .. :.:: ... ·• .. NA .. ·.·.· .. · .. ·· .. ·.•.·. · .. •·.•.•.•.•.•.·.•.·.•.·.• ... '.•.-.·•.•.·.·.· .. ·.··.·.•."'.·.·.·.•,'.· .. A ... \~ ... ··.•.·.· .. u.·.· .. · .. ··.·.·.·•.• .. ·• .. ·•.·.·.•. ;.:.;£NA:..... •·.l.••.•·················':'·•····•·., .•. •.•.····m· •. • .. •. ·.•:.t.··.•· ...... ····· ... AliWli:l j ··•"''-···•···"·"·•·i•.·• ....... ·.···•········•······'-············•·············-'·································•·············•····..:::•· ... . .. .... .... . . . . --.. ... ... . . . . .. . 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN . 4.8 J NA NA 4.8 U NA NA 4.7 U 'i4i~iiil%iii8iili'\¢l@liiRllPi~@:ii\l!&ii&llh@ Y -F ; :i;J;;;;;;;;;;; ; wii+ ··-· ·; im'i Hilll•lW-ii~iiiilff E l!iifli\HNW l Wl:IA@H ilfii ifriiu+ 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN 12 NA NA '6.6 J NA NA 4.7 U MiWi~#iii+l~il¼l.;Hif$R9p1iifill~g~!j n ti :: ' )L #&lt:n;: t!mi •·•·<•·•·•·r••·· i·•·•·Nili ......... ❖•❖.• ••• ❖ ••a~W;vB .. H&/H( .. I rnw;n ; ; ;;/foil 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN 1D NA NA NA (12 NA NA 4.7 U l@?i?!iil~B§El\9ilgiliiifill?Qfmrn; ....... ; ..... ;;.;. ;;;; wr ~ra1rn1rnm NA?·· ,, Nii•••••••• "•;;: ~ ;;;; ;; iiiiia uii: rn •·•· ;NA'r ;.. •Gf;IAmw ;: r 11~wu1; 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 4.8 U NA NA NA 4.8 U NA NA 4.7 U i=:=:ia=:z:a=¥ENTAGHtOROD\8£#ZOF.URtJi~=:{,:,:,~ t~t:?t::n:::::;1r:Gt:;;:?{:::r;:n~~intt:t4mrrn:r:&f;:~r~:~;::~}~:~::z:;::;:: ;::NA:;;:;::;;:;~~;~::;:;::~::~:~::~:~::::a@{;;::::::::~::;;rtf:r:::;:ti~faLUR:;:;::;: :/:/):NA:?/<-~ntn:rn:NArwfnw·~dhifadrti:i· : .. .i ... i •... i ...... , ..•••..•.... :. ···•·······'······~• .. ·. • ..... · .. · .. ·.·.·.·.·.·.·•. : .......... ·.·.·•·················•;::•:::: .. . . . . . . . . . . . . . . . . . . • •. . . . . ,. ' .• .• - -• . . .. . . • . . . . . . . . 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 4.8 U NA NA NA 4.8 U NA NA 4.7 U 2,3,7,8-TETRACHLORODIBENZODIOXIN 1.9 U NA NA NA 1.9 U NA NA 1.9 U ii~/itilU'iff/¼¢A[bifodiBE.NZPBlIBMIHWM rm l•m· w·vt ... i .. )isJui•iiifaL •·IJAw ;. <,C• t"Mi ·••j)c)ijl,{ ·"' v>·.y)¥·1t·>:X"'·'•N!\t }'.. ·••; • Ni'/faU mntkilillBH HEPTACHLORODIBENZODIOXIN (TOTAL) 72D J NA NA NA . 810 J NA NA '91 J figgf~9@iggl;ii'\@!j/;g95p84~l!QI-/wl! }Y :n: !AA' ·····•·fW ; '. : ; NA;C •rnw;w;~qJ .... ................ : :)fjl/7 HEXACHLORODIBENZODIOXIN , 76 J OCTACHLORODIBENZODIOXIN NA 17D0D J NA ¢§t.l\£B\i2@jj!iE@¢f~ Ji: + @t;E;;;;r· ..................... ,_. ••• iiA ')!§&A ii MW@#iii ii iN5fa% PENTACHLORODIBENZODIOXIN (TOTAL) 12 UJ NA NA NA 6.2 UJ NA NA 4.7 UJ ei!~r.?i.?iilffi.9gqgjijgjg§fil)fMHlmif.@lM!ff! •••••• •:iisiiiJLi••:·. :NA ..... , iiiA ·.·.·.·····'·pp(NK +,Hi•••w •• 3 JiA/3•3·' ·f:iAyF •. , ••Abililtil TEO (TOXIC EQUIV. VALUE, FROM I-TEF/89) 13 NA NA NA ,23 J NA NA ·1.6 rlifill\¢Rlioowi.1g2!li@Ni!'tt§i'AMl!lil c;;;x ;4foJ:P,nt NAFl • AfA YTIFW.:•· rninm;m~IW ; Jwrnni ••·••·•i!# ....... ,2n;n\ur TETRACHLORODIBENZOFURAN (TOTAL) 9.1 UJ NA NA NA 3 UJ NA NA 1.9 UJ 3 of 18 - ---- CHEMICAL PIOXINS/EURANS _, ---· --- GP013SLA TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP013SLB GP015SLA GP015SLB GP016SLA GP016SLB -- GP017SLA -· -Sactlon 2 Soil Sampllng lnve$tlgatlon GP017SLA (Duplicate) l,~:~;{@fiilifffi@'f;g!jg§R§pj~g~iRll!Nl ....••••.• NA•······. •< I!Mliii iiio~;j .·.·>•NAU<L,.·.·.•.·.·.·············•59b·••·····•·· ./·•······· !Mi ti ii it?ffeff ;j\ !@It 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN NA NA 230 NA <91 NA 310 J 280 J ~Jifa/,\jiiti'%~etXoJJtB.®Pi~f:iiqjjoAA# M!WiWli x xs~ fr w fNNini •·•·•·• ,15 :···........ .. <,NNw k'· r 1,;2 p:;n ;NArnfrmm t·····•····11U <t·····•· 2l! ::: 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN NA NA 12 NA 4.5 U NA ·14 J 16 J j;ji)~i~W)~!B~¢tilioi@ip!~lffiz9ifµ/½NH ··········;:; iNA \Ii¼' c+••·•·•·•·•·• iefi-i•+ Ni\hh ···•.··· ,K~'.\JEYWttNA) ··•·+ 1~Z'.Z;; T~li 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN NA NA •50 NA '31 J NA 52 J 62 J 1fa:~l~Hl~~&4l%t&ili;ilJ!i\eyjzqj~~& .................. , .. ,.,; 'l!IK2 illf:t\tL i~i;;;; Ni ;;; ... ; 1,JiJ:;;;; ,NA"v·v + , fa y·; '·' iii ~ 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN NA NA . 24 NA ,7.7 J NA •·30 40 i@!ili@illB~xA4!M9ilPP!i'lfillt§)Hifil;/HMi .. <:· ·;;+, ·,•.•, iid,w{ ;; ; ; &A:r;;;; w )faHDlF' 'NA'.'7? 2 ;mu;;,·.•·-;; H@ffH!!!!!HiflH\llil!B!Iiitl: ;~;~;iiiR 1,2,3,7,8-PENTACHLORODIBENZODIOXIN NA NA 4.9 NA . 4.5 U NA 9.7 '13 i:~i~ff·~ie~lliii/,:iw@iiglli~Rll~ :: l !ff x•·•·•·•·•·• ················ mu we; ;; •·•·•·?••····•·•·•·~ ilµfr < 1'4''. @li µ '. '. nM ;:;:::::;mmw;iiun w ; @iA!iin 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN NA NA _ 7.5 NA 4.5 U NA 120 J 19 J z~i4W$!PWW#&l@lil'9Piiiiffiio#tii{Nili •-.~·,;····· iH!/M/%j'@ • ii\ifa.)iff;i HiNifa;iiUHii!iiis'IJ@''HifaNNU@%Y ·••)tt;f/'.> << /£¥VF 2,3,7,8-TETRACHLORODIBENZODIOXIN NA NA 1.8 U NA 1.8 U NA 3.5 U '1.1 J !!4ltl4\i:l@!m¢.B~RRQQ!\i§'!t§R~!diWH ... '. ... ,'.> • :wvc . ]JikbW!t T/4,B~J/B•;aNAq;;;• ; 4:4t£::•:n. ;•&A•;•,;:;; :.::.:~¥ir.:.7.:-.::)i9: HEPTACHLORODIBENZODIOXIN (TOTAL) NA NA '2100 J NA J300 J NA :2700 J 2500 J ili!lil1A2i®lliii§&liig~ill½filr\$/i'Mllrn. tNA·+ i. i iFiAAiFi .:.·.:paJ x ; 1% ;;;;;; ;,f,1/i,Vii •~11v11wtl@!Wt•rnu tfoo:i+ HEXACHLORODIBENZODIOXIN (TOTAL) NA NA '.320 J NA '100 J NA ·410 J ·520 J f!gli&\;l(!Mj~gg\~W,#i~!T!?I.®!li ·•·•·· ::C:7i7n -... i,c;i'jA.;· ........... iiliiH!Kil l l!'#WiJWil i!Af'#.\1;:···'; !1imt~i!f:\i·•<·• •i:!.i#CJ;T; Bali;;@;>: sww; OCTACHLORODIBENZODIOXIN NA NA , 14000 NA (4400 NA ,17000 J 12000 §¢fe,gjggjjlw.\l!i:1!g§/@~l ·················•········· /NA ri +NA:,, HH~ii11 ; i Nfi ··························• ~mn id ~f@i¥ i¥41n ,; tml:t PENTACHLORODIBENZODIOXIN (TOTAL) NA NA 37 J NA 23 J NA '87 J 'B1 J WiffKcAfikiiioNBelUoJ®iiiifiirofAi¥ .·•····•·•·· ;: :;:.;••· ,,_ ;;rnJ#Arnrnr ii ;NA';; ;;;· HisiiiiiM+ :nNA,±+:J ,<32,oJ;w;s :riMir;22c;:;t¥M:X;; ~titJA TEQ (TOXIC EQUIV. VALUE, FROM 1-TEF/89) NA NA 41 J NA ·15 J NA 59 J :f50 J rirr/½¢figgsgp!~~QR\9XWITQT6MH @··•· iim·· M.il'Jf Nkil"_ ii1i~Li!iiiiiiii !f¾:3 ;,'.'. i~iiiiiiiiiifiN1iiM TETRACHLORODIBENZOFURAN (TOTAL) NA NA 49 J NA 0.47 J NA 260 J ?BO J 4 of 18 - ---------- - Section 2 Soll Sampling /nve$Ugation CHEMICAL PIOXINS/EURANS 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN i@iiitii:ll;l!liitit~!lil?@iiiigg~llR4&1iH 1,2,3,4,7,8-HEXACHLORODIBENZODl_oX.I.N. it@Miill±itM¢!:MW@itliillmt$l%ll½Nl GP017SLB TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE GP017SLB (Duplicate} PLYMOUTH, NORTH CAROLINA GP01BSLA GP018SLA (Duplicate) GP019SLA GP019SLB GP020SLA GP020SLB NA NA 15 15 72 J NA 11 4.7 U t•l4t;••·• ...... , ..... ~rn; 4WP;:L, )li5D •·•·•·•·•·•·•·•·•·•···•·•·•···•·•·M!Uc;;/'.i Nl\;(i;J;•d. 4't•••U<FVi ii~\i@i NA ~ 4.7U 4.5U 5.6U NA 4.8U 43U k !AA E'' ff\&g{: i!iiiQifai' AKO ~Ji\/;;; ?Ne/ #,~w.e: •w !ftVt 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN NA NA 6.9 ·7.3 ··30 J NA 15.4 4.7 U i!ill?l~M~ti~~@mqil//iil$J~9~ji@tH ····•%%{;mm; ·••wn >·•·•·•·•·•·• NAY/hr trn!iliM@fHjiH jiiifo .·.·.•.·.·.·.·.·.;·. ·&2iµJ;;;;;;;;;NP£;··· cF ;iiiiJL:;;: \4EciF 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN NA NA 4.7 U 4.5 U •.13 NA 4.8 J 4.7 U 1:~:~liili)~iti~~(;QflQJ;ii!l§j?Qf~i1llii ll!Mii@:;; i% /;iA; A,tQ;. . .. ;.u:+5:. i2itiiif NA ; ;;;i;au; ?Pti? 1,2,3,7,8-PENTACHLORODIBENZODIOXIN NA NA 4.7 U 4.5 U 5.2 U NA 4.8 U 4.7 U ti2iiiiiiaii?€1:rrf:cagQ!lop1~Nio1iiiJiNI ; ;;;j,/4;{; Hi%!>••;;;; HiAAt•tnn A;;lUWAM 4)5!0\kM/rn &;!UR nifr;NA ;;: 7 :uraux:• ·•·ii 4)fllirn 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN NA NA 4.7 U 4.5 U '.3.2 J NA 4.8 U 4.7 U ?i~i1lt;~;e~Hti\1™@m22,~~fi~§!!~Irn •·•···•••·••·••••tM n llti ;wrn ;;; rn;i liiiiiii 1;~ !JIH!idi ~gffilii ~r i//·)M••·o ···•·•·•·•·•·,!t)t, \. 2,3,7,8-TETRACHLORODIBENZODIOXIN NA NA 1.9 U 1.8 U 0.54 J NA 1.9 U 1.9 U ~@rl~if!rri!A!:\ti!l@@li:iillimiifi!f:gn • trnrnnn ff:@ ················•·NA U>•itilWJ l/fliAWii••H •ti iiiij!J}l \.•.••+•·•·JAA......... • '%FD @MJ: HEPTACHLORODIBENZODIOXIN [TOTAL) HgJifA§fliI5fil56m!&toli!Ji!Amn@f,m\E• •·•·•·•. •.· .. NA NA -J =J ~J NA :=J =J. i<iA F!WMH1 l®td!i@!t HY@hdb\ l# Jit;/Mi ii;!ii.;y •1\ fhli "¼)iljj;jhil l#i# cwn• i tli OJ HEXACHLORODIBENZODIOXIN NA 51 J '.240 J NA '59 J OCTACHLORODIBENZODIOXIN '.1600 1600 J 15300 NA • 11000 19000 §QfAciilloirooiii€!lib!l0@:iil¥ • ••+ifr n Jtii:ihii:i ii)® f/Ah••···· ;;;;p;c; ·: •• ;>; •2~{• <:Jc. ;: ~4. i,( PENTACHLORODIBENZODIOXIN [TOTAL) NA NA 7.6 UJ 7.5 UJ 18 UJ NA li:3 UJ 4.7 UJ Rfill.tA¢&1@i@Rm~Nt.§@~llilt9tA!ilMI@W•I , ,t+,nr•Wl•lMfl!I m;• w,, ,. +10J• J , H;it1r, '21u · ::z ww• :: •t~.u;i ·rnw•wwww TEO [TOXIC EQUIV. VALUE, FROM I-TEF/89) NA NA '.3.6 '3.8 J :17 J NA , 14 •20 !~!MMi®.#.~~g§.Q!PX!fitiAIAhl :::::::::,:,::.,:,::<??? r:f.m. ... :::::~:::::;d:tY=;~:;:_ f#\IDftlHf?ifii~j!j@tf ::i:rr:~:ifaJ@}{i\Ifa!i:;Ji~Af:~::~:qqg~~tfE@KiPfiJiHt\Ei ;~j~:;:fiii= :ntt@M@H TETRACHLORODIBENZOFURAN [TOTAL) NA NA 0.61 J ,_0.14 J .48 J NA 1.9 UJ 1.9 UJ 5 of 18 - ------ - ---·------·-Section 2 Soll Sampllng Investigation GP021SLA CHEMICAL QIOXINS/ElJRANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP021SLB GP022SLA GP022SLB GP023SLA GP023SLB GP024SLA GP024SLB 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN NA NA 10 U NA 160 J NA NA NA 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN 1@1i:ifrriih8~!;8~9®ili#~ziiii~r < A 1,2,3,6, 7,8-HEXACHLORODIBENZODIOXIN iiJi:1ttHiwffi™filltPBSRi~fqi(l)wJiH 1,2,3, 7,8,9-HEXACHLORODIBENZODIOXIN ·::::::::c,::::::::::::::::::,,,,,.,,,,,,,,-,.::,·:::::::::,r,:,,,=,r:::.:::::: ._.,... ... .,_,~,;_:::,;_:,:,;_ .......... . 1,J;3Y!Wi ~f!!"l½l';Hl@!:!QQt~l;9f!J!lAf!Ml ff 1,2,3, 7 ,8-PENT ACHLORODIBENZODIOXIN t@i~fr;~fe$Nfi!,JW®B9!llai:if~lrn NA NA 10 U NA 10 J NA NA NA ,tiA> ; ,l#:tm· II i1ii@rn wrn:;;;; \\Iinrn i iwi••••·····;!'.Min•• H!%H NA 8.9J NA jiJ NA NA NA :• •HMNkiiiiit I•••!fo(i•r :H•·Ml@trnrn: .•. 'iii'•+•<·.·.·.,·.·•········NAi·'><0••·•; .• •.••riAT;7 •·'·•···· IiAA ..• NA NA U NA ~ NA NA NA •mtili#;M;i •N&Iffi+ .:)o•.•ur§;•;; ?YN&ffl "•x:e.:uR:;;.x•hN?,\idiF•rTii;w; ;;;c;,iwv NA NA 10 U NA ·s.6 NA NA NA •tJA n ··u;;;:;;;'.' @Icil!if ·•·iNA fr;/ 1;~Ji;j;;i; ••i·•·•·••NM,•·•••:··••·•• ilAitl . ''liiA/' PENTACHLORODIBENZODIOXIN (TOTAL) NA NA 16 UJ NA '39 J NA NA NA w,;;;c; i t1irwsii tiAA:::::: ::,;:;,;::;;:;:;;: <riw' ;;:;;; w.tt•;t i\,IAAtt g€ITT4Gm%Rl:iPl~~~9fj)l~ltrrSr.Aiir!1 E t :ht i itk,'iM i~i;i11~i$Wttii~£iiili:l , ))'Vi +··•····;···~·: NA ro NA ~J NA NA NA )N,\' ;;··· >i!Hivw; ; •••·•rr:i,,.iii ;;,;•·•·•·• iii L ; HA A ;; ; ; iiA •••••·•••·r:.••·• :NA··· TETRACHLORODIBENZOFURAN (TOTAL) NA NA UW NA nJ NA NA NA 6 of 18 --· ---- -·-- ----.. --Sectlonz Soll Sampling Investigation CHEMICAL PIOXINS/EIJRANS 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN lf?(il:;w;ilitl~i!f!@!tf1R9fliw.im9RiMfiH 1,2,3,4, 7 ,8-HEXACHLORODIBENZODIOXIN i!i)~illHimti™§i!lMii'«\Piiji@!~llii!ffiHM 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN ii~iiiJ11i@il$i/A\:JAfaii.loRiij§§i§i!ffiH M BUI 1,2,3, 7 ,8,9-HEXACHLORODIBENZODIOXIN 1]iii'fililiilfl™1ltl~!l!li~f9flffil 1,2,3, 7,8-PENTACHLORODIBENZODIOXIN 1iii:ilii.il,1?emi\ci,Jrol:loBifumzo#i[iRAl,i 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN t~1tmliitiirlll:;tiiii:IR9i;lii!g1liP\i~ 2,3, 7,8-TETRACHLORODIBENZODIOXIN ?.li~?f.ik~I:MGHµmQQ/~iQEffilffH :::,::::>-·:·:· TABLE 2-3 SOIL SAMPLING SUMMARY • DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP025SL.A GP025SLB GP025SLC GP026SLA GP026SLB GP026SLC GP027SLA GP027SLB 590 NA NA 36 'C @ 11( · '· u:i!%lit ---,.,··-,·x-:ItNAtatttrntmn~:tmrtn@ 63 NA NA 15 U NA NA 6.7 NA ;;~~ ; ......... JMikW>,, &ii HilllfaGBtMl Mllimllrnrn ti:-¼i .... Ji li1)Kt\!1li ;;'!WSL 370 NA NA ~ NA NA ft NA ::zwr:•:•:· :e~t :>: ::.::;Nii> nui :n:::Mt1m::v1@1:ms:t·:nn:::rn:,rNAJn : ·+· ·••::•NP(:·••:•:•:•:•:•••: :.:u,:iHt:Q 130 NA NA 27 NA NA 13 NA :: l{I}lllljdiiiTill b/44 HM# H Nii iliW F~iliil@rnrnt ; &AL . . L.,,Ni'(\>:.:." ~.7)J'•· :_ Nii ) '. 96 NA NA . 8.6 NA NA 4.7 U NA n1~1· .. ) ...... ;!w.: ······'N&nii @)i)ijJuPm1rrni¼,t NM ............ Jtid? li/@:t ? 23 NA NA 4.8 U NA 4.7 U NA @HiiiiJk tNAH•: n• un·;;iA ii,J!Wi@ti iii&:: '%4',Ebh ·· , 9Mit:• 6.7 NA NA 1.9 U NA NA 1.9 U NA :rnmnrn @m1rn :> NA'1' ' ;NA { ::i Ni:s§ iiHfr i'i ?!W ·•·•·•·•·•·<·•·· •·:}ik : < :m Mii~i;;t&W .. .;.Ni ;; HEPTACHLORODIBENZODIOXIN (TOTAL) •8900 J NA NA '2600 J NA NA fagirrAfiw;gJl@wij~lggiw/¼~rr&r6lil '' l!!!!I\HMmiwHl ttiiw;i:fomn Twv:: ..... · :Y¥4 ;!M,'.; ; ; i'Yir:···· •· ··· NA ii:NAifo~ R~BAt6k66i~;i&WJW®ff$t4tiIMM%IMM i;; rn;rntttii;/Jjfi : :);)/ {;~:Ui n ;i:; ·•·•·•·•:•:•;'. H/4HJH\H mf;;;J;rn" IIrn;;n OCTACHLORODIBENZODIOXIN !$qf@l¥i.4PR®i$!!if##it!fu¾:JH PENTACHLORODIBENZODIOXIN (TOTAL) i#l'm'11GfitQRQraijijiJi®JW#Aif Hl#WiJJl TETRACHLORODIBENZOFURAN (TOTAL) · 63000 NA NA 15000 NA NA '130000 NA IfWW rnt"'@.!%K HHT&/H >i(@ffliff····· Ht.I-IA' W#ff ff Eif.i~!i n //iitK 290 J 43 J NA NA 13 UJ NA Hi&iUI f@;j irojwi ·iii LNA / i,·.•.·. Hw O iil~:~t~i iHW! t . 41 NA NA ', 140 ·· '.fti4i;,;:;;, ,NAf\::>.••i>>t•·•:NA.:f<•<r•:••••:•·A:iiiS n NA :tiro1n:::-:·:" ·.75 J NA NA 0.58 J NA NA 0.25 J NA 7 of 18 - --·--------- - ----Section 2 Soil Sampling Investigation GP027SLC CHEMICAL PIOXINS/EURANS TABLE 2-3 SOIL SAMPLING SUMMARY· DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP0285LA GP028SLB GP028SLC GP029SLA GP029SLB GP029SLC GP030SLA 1t?;~:~rn;rt~i~!itllilim!1,i&i~!!lg9!ll9~l~liii!Ml\\!rn "' . c;w-:v i ;+ wm+>c:<r····r·*K:•·•·•·•·•·•·••>••·•·•·•·•iiiik······; <>•···•·•·•'.100••··+> >>c?!lAt ; ••. ·.•.·.•.···········• :Rik , : : · ::Jwrr>· 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN NA 13 NA NA 4.9 U NA NA 4.9 U 1i~;~;~fa;~:~;~~IA¢ft~QRQP/~§~gg/W,ttf!II k!llll F ; !:IA:'! $;j{p• ... •.•·>i·•····••NAX .•. ·.·.·.•··························•· #K·•··········.·~ i·.············\f111•i;; .. ·•·······•·i·.·.·.·.·.iJ.ii .•. · /.·.·.···········•·i.·.·.JilA·. ·•·•·>·········•'·• )ttU• 1,2,3,4, 7 ,8-HEXACHLORODIBENZODIOXIN NA ~3U NA NA ~9U NA NA 4~U l~~J~'.~Wl&H.i~~Bt~:ilil#@;~~t.OE:mt ···········:····, •:>d••!<IA'l'•• •>1ni;v.• jiiA •••r1;c'•·•·J••w~rn•••?·NK 7 @:•:f!K't•:t'.Dl:f'tlt 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN NA 5.3 U NA NA 4.9 U NA NA 4.7 U )iiifa~lil1;if!i~tiiil~~gi~zoilmllMHll l )ii('. n•rn1!ifaloithffilff\:l)( lN w;;! WHHHi'.eULiliwilfoiid iiiAi hi £ifotui 1,2,3, 7 ,8,9-HEXACHLORODIBENZODIOXIN 1;g;J:1;~;1iiB~timD1l1li~i!,i!i&ii Jllil rn NA UU NA NA UU NA NA ~7U ....... :-: ···•···c'WW/iVWK''.fF!ic~'i.k·· •</pk/; /}NATT ·········•·:::;nitil'i ,.· .. ·•···· #A•L•kXIb!'!i!{ii•••L:1;n1t NA 5.3 U NA !ifi\1:liii Iil'6TI I!IlEWt~ivHi!Mli W.4!! 1.2,3, 7,8-PENT ACHLORODIBENZODIOXIN 1~;@;'1;j;#!!Nf6q/~ggp/~?@R!m@lff P' NA iffi'{-' .. 4.9 U NA NA 4. 7 U ii~:9uf1'···· · i!-fii / •·>>•••·•·•·:JiiX>>•>·>·•·•••·"rri•••·: 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN #M!m!!rn/lMM,liBt!®Q$i!ll/flu:l!Ml¼NM !HM!Jff NA 5~U NA NA 4SU NA NA 4~U .... NA .... , · .. :~.:!JI +NA /#A ;;; fr@~cii .;:#A :5 // #A ; ifrifr 2,3, 7,8-TETRACHLORODIBENZODIOXIN ?l~lfiijtftfl@,tiiilµm/.\Biij~fotmn NA 2.1 U NA NA 1.9 U NA NA 1.9 U •++ w;l\ i!itr4li •••••••••••i iiliiE N/4:i :;;:Vitte ff!!'lilA E!t7tw>i;31'.;AY Aiiiiii HEPTACHLORODIBENZODIOXIN (TOTAL) NA i'!ghlf,i,ct!tilgd/li~~Nib!iPRAiilrri#AtJ1n ········· # )NJ% ;Jw;irnu 530 J NA NA '230 J NA NA 170 J • ••••••••••• •'••,.•••H• ~ :-,. ' • •HJikm•,· v••···~·V·•·, ,·~··· :A!&ii•i•· A·•,;@gJ1t;•···••?s••t!l\.hfrii•ih•·•·ffA••·k•{· ·•·E•·••d~••;c;. HEXACHLORODIBENZODIOXIN (TOTAL) NA 63 J NA NA 24 J NA NA '. 23 J f.i~§il!K@!l9!'il~/lli?Qffi&WIIT9f#}!IW I ti / +• • • t:!&.; .... T> ··s~ w F> '. ;'NA)/ J;•;• ; NA iy; ... >r;; 8;$MJ; ;!}> /#A; \;/ ;•} <NA:ji>• +•>·• ~,;i:u. OCTACHLORODIBENZODIOXIN NA 22000 NA NA J NA NA 7200 PENTACHLORODIBENZODIOXIN (TOTAL) iitflfiGtfil.qs.!J~~N?f/.\iitfr4ijngf;;tirn NA UW NA NA ~9W NA NA ~7W :;rnp;;n ;; .:)t11c r ·•·•·••• ;'ii:ii:iL/: 5,;,r ;: nirn;w,;;;rn;rnrn;m;,;1;;mrn1mwi •·>•·•···•·····•···•••i<m<••·• :: .... ," ~imN NA ·24 NA NA •·7.8 J NA 8 l!M)MHH l'i.MMMf@@SfiJlli!;IIH #!!'.• ·•·<•·•:JUA .. ;,;; :; lf,em: ... q ... SMi H1M@J NA .0.17 J NA NA NA NA 1.9 UJ 8 of 18 - ----------- -----SO<t/on2 Soil Sampling lnvntlgation GP030SLB CHEMICAL PIOXINSIFURANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS ANO FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP030SLC GP031SLA GP031SLB GP032SLA GP033SLA GP034SLA GP034SLB •••••••••••••••••••••••••••••••••••••••••y.••• • ••• • •••••••••••••••,•••••"·•••••••••••••••••••••••• ••• ••••••••••••••• ,•,•,•,•,•,•• •••••••• S V , U -' , _.. , 1•••••ihi1i•tll.ii'tEi1tActltoRbbiBENZOOitiXiN%%••;••••M• •·•·•·•·•·•·•·• Nii•• :.:.:.:.:.:.211J..• .. •.:•:•:.: . .:.:.:.:cc::• . .:.:.:. .. •.NA.•.•.·.·.•.·.•• .. t.• .••.••.••.•.•.•.•·•.•.i.'.•.1.·.i!o.••.··•· .. a.·.••.••.••.••.•·;·•··•.•.••.••.••• ••\ •2100.·.·.\•L<h .. ••·•·•·t.:1.··.·.w.•.·•.••·.• .. wt.••••.t.\.••.J.t.t.•• .... Hs.oo.·•·.•.·.•.o.·•.'..••·.••.•• .. t.••.••.•· .&• ' '· ' . ... . . . .•. . .• . ....... ·.. ··• . . . . ....................... .,... ...... ,... . ..... " . . . . . • . . .. . . .. . .. NA NA ' 29 NA 250 '······ +NkII•it!:% .. t MiO·--·r•cNii•·· .. \ iii 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 1m1tl~t1ra:iliifffei~gi@iwJim&Jmw;ij 1,2,3,4, 7 ,8-HEXACHLORODIBENZODIOXIN NA NA 4.7 U NA 31 36 . 3.1 J 46 1#im;;fii!1Hm!A½B@i&@J'liij\wfa:\€l!!wl@H }iii; .·.·•••••NA /X;; $!£# ·• ::NA ;· j\::µ:XL ··•·~·•······ .•11..•.•••.·• •h Hli•l!iti!#iiffMlt•~•H 1,2,3,6, 7 ,8-HEXACHLORODIBENZODIOXIN NA NA 12 U NA 82 120 13 ' 300 i!iijltifl!f:Hili'AB8@i&ociiij~z pf;µw!!;l!ff n::N!t tt:::·::=• j~if#Hiiit··· -··=;J)f:NA!f''?Tff :::~fft)-f:\: ..................... , .. · •. ·,, ...................................... , ,. ~ ·e·•·•n·•·?·•·•·•·w1ax::·•·•·•··•·• ... •.•n•:'.?\11r:•+<• 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN NA 4.8 NA 49 68 . 11 120 1:1ii~l1i~i!i\B~XAB8~1'.1PlQ~;i9f'µw f }rn >>i t iii\@@ < :;~:iii ~,:,,~f ?i4fi:'.: -:-·.-.·.~-: ::~~;;;~:;;~:~~~;;~:&;~~L:;:;;:;i iii,i:i·: ;; :;mu•;J X:411@ 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 1!i#&i~re~Wi<.BiliiiPR6Bi•BiiAT 2,3,4,6, 7,8-HEXACHLORODIBENZOFURAN %1l\iifiiret&f#iw\!&i&1R'l\i!i@Wr&Ml 2,3,7,8-TETRACHLORODIBENZODIOXIN zfa\fiifiiW:,Bt9ffoPi~zl$gµw NA NA 4.7 U NA 13 18 4.7 U 30 :~;:NA6Ite-~ 101 ;:j,b¥;:\:;;:;:;:; ~:::ii ~rt~@~11v. it;~;i{%:NP./;;~;:;;;:it;i;:;; :):/~•~:il::fr:::;::::::::·: Ui&Mii••nrn;fi•tlnr · i'.Ft ;:::::::::::;: NA •'••'"•NAY•••••••• NA ····•·•·•··•••••••Nk,::.: 4.7 U NA :i;,9 '11 4.7U 0 24 •~•·••::ftQ • •frlli!!li \i~!Jii W#i/;Mu•; .i ":k.¥6%! IHHml@i NA NA 1.9U NA 1.9U 2.2 U 1.9 U 3.5 : :•i%L ::: iii;•> di #idiR6 y; TNA) < ,. %iN#P IIIFZ:HitH fI1ttOSHfHJ@#VilliHH%% 8@kfX&iW6lib@~~;;;;~ff&fxt1ff•HW;F t;;.; . .;.;;;;.;.: : rn ;r; . ;:. .,. 560 J i~~Mff NA iAA'F • 3900 J ;;iiii~DB 4300 J · 650 J 11000 J n~arn WA@ ;; !f{iiiilf ~~2~ .. ~8~881~';~38918;;:~\I(?I:H ·•.·•.·•·'.NA.·•.·.•• .. •.·•.·.·.·.•.••••.••.·•••.·• .. •.· •. • •. •.. . NA ?~ J ·················~·· •. 580 .. J ····· ·.· ... · .. IIBJ ......... , ...... 120J... • 16.oo. J H.~9%9R9Pl1\!ic'l~Qfl.l~IT9TAAf•· ·~ }NA • •1'~!!:•• ... ••••·•··•W>i•• . •• \S;(t1e:c2 •·•/·•·• 1.11.~•4HNi 1• •MtiW VW@1iiilW? OCTACHLORODIBENZODIOXIN NA NA 3000 J NA 22000 23000 17000 •11000 6bf¥cl!lto~OOla\'!i'd6ii~I@,.,. iik;;;;L;i•••iiiA ;;: /{j ·.·•···•·••h• , \}di'JJ,H, g;;;+:ia)KK,LGJY@,ji)T, ··•.•qwzr rnt~ii#H PENTACHLORODIBENZODIOXIN (TOTAL) ea!iiiitltl$i/l$~~Ni9!!u11Ai;iugf&&Hn ~~s . .rr.s~1s.~2H1~,x~~H::t.~?.~ .. 1.:T~ti~~1 J'!:IM1WliPBOQ.l!l!;i:gpp1.QX!!!fl'QTA!'clfff TETRACHLORODIBENZOFURAN (TOTAL) NA NA 9.5 UJ NA 58 J , 91 J 18 UJ '230 J •·•·•·· .; !fflimfi •;; ::;;;;;ii@i Hid •.•.• :111 •. w .•.•.•• t,!%,.t••·············••!iJ•A•L·•·· d tf\l•t•• ;. •·iitiiJ.!#nt WM~#t NA NA ~6J .... ,. .. .. . ......... , ...... ,..... "· k i®L . ;·• M iNii• •+•n ;za:•:uJ NA 70 .... · ..... : ··-~·~······❖•• HlK.,. , .............. ···•'t·}l:HiiXK········••i••·····"'••·······••flMil;;.. 23 200 •gSiuii+tt rtsli'Rnr NA NA .. 0.19 J NA 1.2 J 2 J 0.3 J ~160 J 9 of 18 - -... --- CHEMICAL PIOXINS/EURANS 1,2,3,4,6, 7,8-HEPTACHLORODIBENZOFURAN ll?l~:;;iiilli1/iiiti:A'9l@filRQQ!~~WJggµfiAij 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN i@~l,friiifB~i:itiiliii&itiii:il'aji¢~li \lid 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN 1fafa,~;'tii\tl™9fiiii:IB@Mij€fiiP.i!miH 1,2,3, 7 ,8,9-HEXACHLORODIBENZODIOXIN 1;g1~;2;i;itB™1:\fiiii:IB991i\'€fiz9rm:r"· 1,2,3, 7 ,8-PENTACHLORODIBENZODIOXIN i~#iiiiiWgN'fJAfil&l'i.99!~ij[4!lm· ..... 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN ti!iiili\i@i!#.4l$lfi;ii!iimiijgm/KiW!@I 2,3,7,8-TETRACHLORODIBENZODIOXIN tii\ritf~'tw(i:iiiiiQ\¾l:il?i~zi:?t~it HEPTACHLORODIB ENZODIOXI.N .(TOTAL) H!iilf&liffi§Ri:i@llf@ill!Wi!rr§.ff¥1 HEXA.CHLORODIBE.NZOrnO.XIN (TOT AL) i;ig%\.\:itllb'i16Mal~#Biiuru®rr&¥4lli OCTACHLORODIBENZODIOXIN &BfJicl'ltiiik6bl?MJiioiiiliWJ!i PENTACHLORODIBENZODIOXIN (TOTAL) .,.,.,.,.,.,.,.,.,.,-:-=-=c·=·=·=·=·=·=•:-:•·:::·.,❖,-:-:-:·:·:·=<•✓.:-:•=·=·=·=·····=·=•:-:-:-:-:-=-~=-=:=·:-:-:-.·->-··-·-·-·=···-·.,.,,,.,_,_,_, fil;NIAi;;tl\i.QRQP!El!;~Qf\:!fY\!'!flOIM} TEO (TOXIC.EQUIV .. VALUE,. FROM. t,.TEF/89). f~'ti¾P!'li;i@@pi~tPP!P&li!fi!i'.M,!W t ' TETRACHLORODIBENZOFURAN (TOTAL) ---- --- ---· --SO<tlon 2 Soll Sampling Investigation GP034SLC TABLE 2-3 SOIL SAMPLING SUMMARY • DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP035SLA GP035SLB 11 M\I~i;i ••••••••ix•••••• GP035SLC NA :,::·::,•::;:,:,,l\iASI GP036SLA . 11 ;;;;;ij;; GP036SLB 4.8 U 4.6 U NA NA 4.5 U NA •; l@llllif 1MMM'Jfol(ff ·• r:,·, 1'iA L /i ii!&; l@,@B, ;mm ]1,4 :X 4.8 U 7 NA NA 4.5 U NA ii llt~:1\P'i MMW¼foiiJHfiH ~iiti ' ' f&NIW hk~;\itii i llwifo; GP036SLC GP037SLA NA 830 iNK >•<WT'.? NA 210 ,,,,,,,,,,ii,,;.•/•'•'•:• •ttt::}•·••••·:«•'•'••nn NA -1300 itikirn :;;;:wi,ri•i 4.8 U 8.4 NA NA 4.5 U NA NA 790 .. i ifa!ii!fri:b iilil&lMlHiHlfiAffH\ htt!'ieirn \i;~~,F• ,,;/:' NA,,,.· .. Ni'.; i ::iiu 4.8 U 4.6 U NA NA 4.5 U NA NA 110 :;.:.·+'I%Mb1F I41\BlbfflfiffNA)f •••!lA'+m;· ··'@Ks&; )fol!"¼% ' NA ;,,¥)ii# 4.8 U 4.6 U NA NA 4.5 U NA NA 20 A¥o;i ;n,; ;iwomnw;n;wMrn , ii& :; \f)ij!J rnwmminrnrnrn NA • :i tii: 1.9 U 1.9 U NA NA 1.8 U NA NA 14 HP?tfiG?W mt1ii£;····· Nl\h. !Wfow t ;1;iiA w iwit _, ,. i&N ;7 3: ~ii i> 130 J 720 J NA NA '.260 J NA ,,,,,,,,,,.,,,,,,.,., ,,w,,,, ••... ".' .. '.••.'·'~.·.'.'',·.,.'·,'·y''.' .. '·· ... ' .. ' .. '·.·.-.·.·,,.·.,. ··. ··,v····· •.•.· ............. · .. ·.... ,. .·.··•······· "·"·' ....... •.• .. •,-.· .• .. •.· ... • ... ..· ... · .... · ...... . ,,, ,.,,; n ,.~ , •~.t\U,tt, :%:l'IAE??F '' ttNA ::::t:,.,<:<~.t'.l!XT!TTN>'( 47 J 82 J NA NA (34 J NA 6700 J lliEti;nTii!]tiJ rnrnn¥libi;l N¥U J i iNJ.•)i i \iifi: '/}NA';c ?F~AAVD 730 J 27000 NA NA , 4400 NA NA ,-170000 .; +wu·wtrn+#WH ti¾' ¥I !JlNkf!H ilMHluhHH)Tiffii<WHil! 7'Lfil,;F /F/l)mf 7 7.7 UJ 11 UJ NA NA 4.5 UJ NA NA 1400 J i~@Wl W!iff~IiWi lMFHi¾'H • H tt1'iA ••.•.•...... r:¥s•417+WN'A t; ;%:fiA'I ii7Jgrnlfr ' 640 ;taa@f 1.9 UJ 3.4 UJ NA NA 1.8 UJ NA NA <140 J ,_ 10 of 18 - ------ -- - ------- - - Section 2 Soll Sampling Investigation GP037SLB CHEMICAL DIOXINSIFURANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE GP037SLC PLYMOUTH, NORTH CAROLINA GP038SLA GP038SLA (Duplicate) GP038SLB GP038SLC GP039SLA GP040SLA ••••• ::::::-:::•:-:.;.:.:-:-:❖:❖:-:-:•:-:•:❖:-:-:❖»::.:,:-...... :;;-:cc:·.;:-:•:❖:❖:•:-:.;.:-:❖:❖:;•:❖:•:•:.;-;.•·· ::::·:· •• ::::::.: ·······•: · • ❖.•.❖ •• • •··•.,·.·.;· : •• :::'"·::::::. ::::: •• ,.;,.;;... • ·•.•·.•. .,, •••• w , :,:.:,:...,. ❖ ,.w , , , f..' , , -:° -:° '"':-,' ,', :-:.,-❖ ._., , . iiMHJiit,~i!l!!;r!A9Ht\:l!'©Plli1;@;qp\gi!!fi frfrt :nv@W'. ;>>51~• :k@i!~ 1?!/il;i;; · ·•~!! ..... ·o ~ • ••• soog.-·-,J:t@!t!WII 1,2,3,4,6, 7,8-HEPT ACHLORODIBENZOFURAN ifa;~:~\t;~;~l~ffi'.A~fiijqpjij$@&fµ~# H 64 4.7 U ·280 . 260 4.7 U 4.8 U 1700 110000 J •••••••· , ,;.,au t¥lfi!!M T~l!:··· ••••:: t,$.i;······ •• •• •,;;;7,;;p•• IiEJ~J;u @Wi ; •#t!;hi.1iiilifo 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN lliliMitiiB!l:m,¢Bl@li$Mijgfl@¢twwi ff 28 4.7 U 22 25 4.7 U 4.8 U 28 4000 J rn !fi;lµ# IffiK#!i!!HFF@ ··············•· di'. iiti!J.ri t'!IAiR ••t~~ MililWJH 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN 160 8.2 110 ! 100 4.7 U 4.8 U 280 · 47000 J ll~i~Wliiiffig:@,jjfl(gijqq(jjj§,ijit\iiirei®I h : • ·•·•· <: s:+·. :inrn Q. ?••·· rn,;M O r: rntFJii:f PH . i '.C•it.;L HJ} • 4/i#Hi i :: •%~ o . .;;,. ++w ••.•. : .•.•.•.•...•.• ( 160iir•·•·:••· 1,2,3, 7,8,9-HEXACHLORODIBENZODIOXIN i;ii~if;i@m~iiAPM!PBQQta£2if~!!M 85 4.7 U 48 d;teiVHPW ,;diQMI i (MJFW 54 )ii§@. 4.7 U 4.8 U 98 12000 l iJ ~friuii i!lP!\!IJJNiUMl@l~ll WlMilME@mlJi!B 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 13 4.7 U 14 , 13 4.7 U 4.8 U 24 1800 1MfaiiW!FimA\::liitooSBiii!iil£8i1&iwfm nrn IiI ;n; ;,;e.-uz;;; M\ilPiH w+ t,~li! fa; /¼$IL a;a ifiiui ::: iiii);t:;;i i11x+ir u,e1.wa 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 4.6 U 4.7 U : 8.9 -10 4.7 U 4.8 U . 35 1500 il~!li)i;~\Ril'iir4-mi~&BQPll/fj!iiliil~ll,rn TEWMUMHHlilWiiil,IIU ·•HJ¥lli L ;~iiiui trn !lM70JMMHW\ili/illH% ;iii :'i iffHQ#i 2,3,7,8-TETRACHLORODIBENZODIOXIN 1.9 U 1.9 U -1.7 J 1.7 J 1.9 U 1.9 U '3.9 \110 J tfai&i@ii\Aci!itdi'W6laaiiBR~ % :· ......... :.:.:.•-.:::.: .• :••··· Hff:fa:i,•nli>--···•·•--1 ll u --H,l!, ilWJllf Ifr l!}J;J,j 1nam~ru;rn1;;rnnm~Ml m rnrrnu"t,m fl!IH1W&l$E ·. n > ., ··.... . .·.· •· ... :••·•·•·•·•·• -....... .. .. . .. . .... . ..... ············ .. ... ..... ... ······· ................... . m~iiliaWB@igw!~Wh~~;ifdf ~~;;m; 1 me ;+ , n Th~ ii iii if ;;~~l~J x , ~~; ~ ;; ;~~; Jg ;;: f !¥t\Pff)l; ii#~~i,Jt; m ;,;: ~;;;;H;a~& &IE ffi;~i~@i@&l$iz&;m;i~t~ilrnmt;;;irrnh••·••%) +!::,~;.s,.;;J;;..;~i,0,fr. ,.rnZ:;ii wi ,::r~i ... ,.,i.;.. ~ij,iiifi,l;+•i••A;:,! ciJ•i•+tn!J: ii+ ,i;::.~:n OCTACHLORODIBENZODIOXIN .14000 750 .27000 22000 1600 700 · 51000 10000000 9.¢.f#¢BUgij§!;jj~ig@!Qlmi! j .,;;.+npqv: @ijj~,j •:MltHWrnl!Ji!W gy;pa;; .. :,.. ·.m:fx;;)bq,;trnn ;:;;:, ld\O /('.)700, ;, .. #SOil®{ " PENTACHLORODIBENZODIOXIN (TOTAL) -140 J 9.3 UJ J4 J 73 J 4.7 UJ 4.8 UJ 220 J .13000 J ggf#~¢Hiii¢fiqpj~~liii&ii\ii#ii&a&fk¥Wf··•· !HlW&wI ll i%mwl !Hff~## nu dtSObkiI W?lmF}fliNW@ilii e '.LW.if!P! mi~ii TEQ (TOXIC EQUIV. VALUE, FROM I-TEF/89) fgf&4Q1!!Q!#gpi§~oP.iti!@)fi'i\r¥t1f ···J Msili :2.3 ', 99 Niilii&WA rfitiit · 77 , ·2 · 1.3 200 · 27000 J :iii ii H Jt1\~®!ff t HEQ 22 tiiiJ ii Wiiiii6JH TETRACHLORODIBENZOFURAN (TOTAL) 1.1 J 1.9 UJ 41 J ,-53 J 16 UJ 1.9 UJ ·380 J 3300 J 11 of 18 - ------------ -- --Section 2 Soll Sampling lnve:;tigation CHEMICAL PIOXlNSIFURANS 1:i;:faiA:t:~rn1ei¾1;;~1;li!R9!!1iic§@@12½1fd. 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN GP040SLB TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP041SLA GP041SLB GP041SLC GPD42SLA GP042SLB GP042SLC GP043SLA L·•·· @!Mi!½nnt UifoliWMWH1il11illi\'blf:C inH:ziiliiiltn ii;i40Qiii +x;;y•w;;;;;;; HA;;x ;zSii&i'.n NA 110000 23000 570 130 NA NA '49 @i f!AEW HM£14~iHl1 i!i~Il:li WM•M'M <<>Hilt lli\'$.'t l! n ~! \.·.·.•m· ~,i.ibF IJg;~t~\tl~i~\iigl#:$,gii;gfi9!)!~!#'9!l!:iijNjil\H 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN NA 1300 1700 , 23 11 NA NA . 4 :i@ii)M1ifu8ij&iil';BU§llQQ!ijW'lf&!lmr Mi diUWffl ••?hliffn·tt XU} ;Li H~iii:@ NA .·.·.·.,, .... l@il : ifavQH 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN NA 50000 •4900 .150 '.53 NA NA •. 36 · ii:;i#;~Mi!ifill~&@ll!iwil@R!~~Q[Qi'wli Ml rn;w•;;nwrnnmrnnt,!iiHWU%UiW:l#iiU ! iFIMtlt NMMli®Mrnn .;;w;; 0•#(Jff 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN NA 4600 ,1400 27 '. 26 NA NA 13 iJJ~l\ilri~(gffii§½Plii!PRRQl~gpf'Vfl.Aflff iM • n@ifohl;;l;\ i Nkrtrnrn ;n;~ nnnrn;; NI~ µ•\HI i!J\ Qi iii rn~.~· ti ii !ll lii@ffl t ' ;; ; Ntii i jji~\!!Nit 1,2,3,7,8-PENTACHLORODIBENZODIOXIN NA 1300 J ' 520 14 .4.8 NA NA 4.9 U i~!iilifieiJfi\lii'iil3lfoB/liENt8iilJiwlF ....... ············•·.•••.•·.NA.·.·.:.1.••.•·····;:•n.••·······•··•··•·.~ .•.. ,.P:I.••· .. ···•·1·•········ t ;1 ... i :., •············ JW~itt.••··········'········•············ .. ··········k·:'·,·•·ii iii.r.t .• · .• ·.c: ·.·······:.•ilA .•...•..•. ·.·.f.i.\.I.i.i. NA ···• .. • M,~ u • .. ../ .. i •. •,.t .•.... ·.·•················•·············•··········•·······.·.·.·•······•·······•·•····················· .. . . . . .. . . 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN %~:Mt(liin!foifii'.l%\(9/'ii:lQ!!Jgl'!l@!iQll4fF NA 3300 85 , 5.7 4.6 U NA NA 4.9 U .... , ........... , Mi+ M #mi Ifr T1! fa +@i::¥ •vu i;i}ii\iiili U fa E)@ti·+uE Jii;igh i ii ii:iirii 2,3,7,8-TETRACHLORODIBENZODIOXIN NA 140 180 \ 4.2 1.9 U NA NA 1.9 U ifa'i@fofWI\BilE&a6Biii!miliil!ifil®k ·.•··•·•··•·•· •.··.·•.•·•.··., .......... ·••.••·•t•.••·•·••F•••·;••··•.•·•.•····•·•·•· INA Wm .•. 4JiflWM Hi£ ij# i#iS:Ji@rn Iii~iiiiikb tNi>i\i ;•rnw.ifab• '.iij;'t,;;; ...... , ................................... , .•..............................•...•. , ... . . ... ······ .... .. . . . .. . .... ........ ...... ..... ······ ..... . . HEPTACHLORODIBENZODIOXIN (TOTAL) NA 1600000 J 200000 J 5600 J '2900 J NA NA ( 1200 J. iiliiiff&ilil ··•·•·•·•&seNioifu/£Wfi¥6'fAil1······•·•• ............ ··••·Md••··••n•··••i••h Ir.·• .. t.fft&A d• l~.9.·o··· .. ·PD.·· .. ••.••· .. :.~•··%•.Il.• .. ·• e.,.'..10.·•·•·.ii/i# .. U)i., .••. _ .•..•. ME.F.il.J/!.\.·.l.I i.fi .. I ........... t.:::.••.··~.·• .. •.••.·••.i.i\.ffN.::. ..... f.•/ NA,.. : ::,:.;•::+•.••Nk. :+.·•· ............... 1.:••·t·••··ii·•·.~.1!.·.·.·· ........ J.•·.··.:.t.% ................... ·QBQ ...... , ....... ,., .. , ..•.... ,., •...... ,.:.· ,....... . . .. .. . .. . . . . ~.~S:.~fr?.~?.8!.~.~.~:?P.1?.*!~ \I?!tH... NA >.••.·.•~. •.: .• o.o .. •JJ••· .• ::;.; ••• •.•.;;.•.;t:{~.9.~~.o~.>.:.·:.::-.•.•·••••••>X••••.!~~ •. :.•·.;.; ... ;.:.; .. ;.,c;.•.•·<•;•.:!.o~. :,, ,+:.,:.-. ··• :••.•·:•••••••••••••••·i·:x;.;;.,;.;.•••7, .. A .•.. ,;; .• :::. ..................... •.••·.'.'•·•·•••:·2., .• !~ .. /ii,·.••••··· t!gX/\,§!ilP.QRRR!.@.!i!'!IQ.eJ~•.crQT@Y:m ·~-. . C ~-" •=, UM ~· '"'· •=· . .. ,n .. 8100000 J ;840000 34000 ··28000 NA NA I 6300 #6PiiWU••Wt~mHMl.UUW@ffHMH#ffeiPWMiP@R·MtiHiMW NkiL '.)if~tst OCTACHLORODIBENZODIOXIN oct!l&ik&a&Biffi€&26'#&¥ rn ;wrrn ; rn NA noo J'' i860 J 250 J 48 J NA NA ·21 J i ilfilim!EiM lFil@lt:H@Eii:iii@W! MlffMJli#ilWl!i '.X~~~?Jti. '.,NA:~ ; ; !IA, ; ,nAi PENTACHLORODIBENZODIOXIN (TOTAL) Wlitliii¢ii©Afiiii!ij~fg&f\J#AK/fi&f&U NA 28000 J :3400 . 100 >, 56 NA NA 19 ·•·•·•·•····· ,,,11rn @niii,\lJnrn+ • ioiihi ... 3\niio'il7 .. :r'.f;id;r iJ mwr,l'wrnw nM.1N;; •••••·••r ;:vil@&r:;;;: •tzJFiit ~~i;~i;;i~iti.iriii~±l[ii~1 ·· TETRACHLORODIBENZOFURAN (TOTAL) NA 2400 J ;200 J · 46 J p.52 J NA NA • 0.9 J 12 of 18 - ---------- - ----- --Section 2 So,1 Sampling Investigation GP044SLA CHEMICAL OIOXINS/EURANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP044SLB GP045SLA GP045SLB GP045SLC GP046SLA GP046SLB GP046SLC J;g;~i+;~iii\\1/iiif!li~Pilhii~ill~§~!l?xi~ijij <fr· .. ?Ff•., .. ,. •W1q~k':".c: TiiiiAii;; iiiiiiiiioiiii iitnN.ii #iii ;·ii½i > t !i~ tt it~i!ml! ; ;; !M~@H 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 210 NA 340 NA NA 35 J . '300 J 3300 J lJJW11!\¼llelH,W!Ail6ii.BilfBEi4ZBi1l:\l!i./&f .• •.:.••.••.·••·l·••·••.••·••.'.•·.•·.••.••·••·•••··1·••.i.I.S.}.••·•••·;·;·•••·••·•••·•·•••.••··••.•••·ir.·.:..•.•••·•,•••·;·t·••·••· H • •NA .. . 'Hdf~t . ' l l lN,it• .. ' iiNiii ·•••·••.•··••·•··••·•··•·••·;·i·••·•··••••·••·•~·\·~·•·••·••·ll·'.···.•··••··•.•••·••·I·••··••·•··•·•••·••••••·••·••·••·••·M·•·•·•··•···••·••·i··••· iMW n ·.· .. / ... ,.J.J ..... L•···•·•·······•••····'····•·····•··•·· ...... ·.'··········•·····•·•···•••··•··•······· . .. . . .. . . . . . . . .. .. 1,2,3,4,7,8·HEXACHLORODIBENZODIOXIN .12 NA 42 NA NA 4.6 U 25 J 290 U fi:i;i•.i'i .. lililliix)(oo(biidoial!NZOiiOW,i\i· .nlt••···· HHX••·••NA•'' .•.••.•. : ....................................... • •. J ... , .•. ·.•·.•··· ••+NA ,.... NA. . •.•.• >4~ 0 ·:."• ::/•i,;Jf •.·•.·••.•···•.·•.·•.•···•····.·•2 ..... ~ ... ·· ...••.••. 'il.·• •. •.·•.•·····• ••.·• . .< ..••. x.L •.•........... ••·····•·••····••··•···•·•············•·· ... ············•·•• . . ... . . .. . . .. ...... . ... . 1,2,3,6,7,8·HEXACHLORODIBENZODIOXIN 89 NA 190 NA NA . '21 J '140 J '2500 J ,&i~:~;f:J@)l~&i!M@9ii8i:iiEifflzqiiiffl½N ······'·'···•·····;;x;;;; DE ii fr•·•· • NA ·x t·c ;;13 . ; i-iA ••• w\ ;; '.i(4:efoifrij :2:iltl? , :tt®::: 1,2,3,7,8,9·HEXACHLORODIBENZODIOXIN 35 NA 110 NA NA 7.7 U .48 630 '1\~@i/\i9Jl&V~BHE6!i8BMl!Nz8/i/litiJ;f.· ... ·.·.·.·.·.·.·.·.·.·.· ······· .. . ..... ·•• .. nt.I.~.··.1s.··.··.·.·.ib.JH.!.·•·m·r·+· H,i.•·.·A·.·.·.··.••·I·I·n·I·f·••··•·!·i ······•·.A.·•.···.:a.·.· ... · ... •.••·u··.•.·.··.•·•. '.i./.••.•·.••·;·••.·•••'· NA.·.······. F.H+ll@H /iikfr rnmmrnntiifrlR. TV ·•1. %5111.. @fi.WifH.•• rn•1JW% .-i:f,~v;·,,w, .:m~·--: :._· ___ -·. .·.-·:.·•-_. ___ .:;:;:,:;~:,:,m:::::::,~:,:,~:::::::/:fa:fa:~•~=•-------...... --... -.. -'''"'··-·-·•v, , ....... -.-~ ,._ 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 9.8 NA .34 NA NA 4.6 U , 13 · 130. l2i'i•\JigJWJ.15l[6!l8oiBEht8l1&J'iJ@"· ., : :~. :·.~ za J ..•• , • •' -'wt ' ... • '. :· '.: # .. it; . ''T.I.••·'™·''•"·•·'Y• .. ····'·'··· •.••.••.•••. r.·•.e.·•····NA···.··.'.··.,.·•·1·•···•.I.f.i.t.••.I.H.•.•·'.i.l.I.f.i.u.···.··.r.'.JJ.'.· ... •··'·········•·i·••.1.r ..... l.t.••··•·I.:.·•·.· ... '.l.t.··.1.••·~········,..·'·••.l.!.·•.1.1.••.: .••.••.••..••.•. •.•·., .•. ,. 4. $t ,u ,.;., .. L .... ·•··•••·<·•· • ................... ...,.,..,. . ... . . . . ... . . . .. . .. . . . . . . . . . . . 2,3,4,6,7,8·HEXACHLORODIBENZOFURAN ·• 8.8 NA ff NA NA 4.6 U ·. 12 J '; 180 J :smiit#\&!;fl/JI\9.WQR9Plii~ff?Pf\!WiliMl! k M\~P i rn !iw T' ·•·····•~AW••·•·····•·· Ni\'. ,.··············••tmt ii ;l *!~id . iijit#lil. 'it••·······•fiiLv••····· 2,3,7,8-TETRACHLORODIBENZODIOXIN . f.4 J NA 20 NA NA 1.8 U • 3.6 . 16 !ii~@*\m§:@Q:!liQRQQ!l!§li;Q[~Kfa t•t ·················• ................................ ¥,i::: , .. :·:. '.. ··~ ··• •·•·•·•·•·•·• t.t • •·•·· ·•:·: .. : &,4;J·rr + '.HNA .................. +tit\·.·. .... faiViiiL • + ; • ·}t~••b HEPTACHLORODIBENZODIOXIN (TOTAL) 2200 J NA 5100 J NA NA 780 J ·4500 J .65000 J @#if~i:;ihlp~§Diijl/fi?PliiJJpifoiifii\r,iii;JMH@WlHHfl!I FFi~i!fPIW JI'® I if•X#B!PWH Wl/$ •·••••.•; •illl >s·•·>'\i!ioCJ\·<•·•·•·•·•·>ilgjipJ l!itf~lli HEXACHLORODIBENZODIOXIN (TOTAL) 450 J NA ·1200 J NA NA 140 J 740 J 10000 J iii~l:llii©lm~@:lcl~§filliwiR't§t#li!llll TS>••· : ; ; %1 ltf~@ii lWM •WM! iWIK\!W.WiilfH ll!HfNMi •·•· ;•·•···•·•·•·•· iw!fr@fr,@itP.!int; r ;n~l!ii!f i '-&~/&@ OCTACHLORODIBENZODIOXIN .9400 NA ,f6000 NA NA 3900 J -21000 400000 J Qi;t,i\qB¢6W:joi~~QfUfW';IKWM:nn·• •)ti L . 'Y :&@ihMM JMW;/.V/ ;HtP•il·••wFA••M• t• /N,\; •• •: •m:•;•.NA!• ••top•; )'i;b H Wt•iil9lHii ;; •• •Jim\/F PENTACHLORODIBENZODIOXIN (TOTAL) 58 J NA · 260 J NA NA 15 UJ 90 J 't300 J ~A¢M\PRQP@\;1@'§l¾Ji'§ftoof.4@i! t tt~ii! • Hill~ ii Wi4~ ii:•H Tiffi Ni¥ wk' i£ ;; ;w J; @ Diffeiiii + Xitiiii Jff TEO (TOXIC EQUIV. VALUE, FROM I-TEF/89) NA , 130 NA NA ff J :97 J 1300 J illrAA\';l@$iii$,9l!lgfgg.!ii§8!~aqf.~!1JW •; :NA FY' "*JHI .;; f,ieJ.;.•s;.t• .. W.J .uzm•~l\\WXI; '.@il • \t&if@t TETRACHLORODIBENZOFURAN (TOTAL) 59 J NA ;f30 J NA NA ,· 36 J .-300 J 1600 J 13 of 18 - ------- -- - - - ------Section 2 Soil Sampling Investigation GP047SLA CHEMICAL PIOXINS/E\JRANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP047SLB GP048SLA GP048SLB GP048SLC GP049SLA GP049SLB GP049SLC i@~@i!ir:~lti§!lf£gjl;q/ippj§§jggp\§x{~ rnn~~HMldliii!l~l h W&Wli ''311' <?/i><f6•.;.: ., . !AA F rl~F 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 3000 NA 66 1i?)~;~!ii~lWE@!lI£gjl;fi~PPl!t~~Pfl!Ri!Rt:li!Jlfi '.> tn htmlililllli ffNA{IH rn; rnswwr 4.6 U 4.6 U 12 n~;!lut ·•·•·•·•·•·•·; fij:iii\iii ii; HK%DJJ 42 6 li:i0; L; ii!ii~iiii 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN 170 NA 12 4.6 U 4.6 U 4.5 U 3.1 J 4.6 U li~fai4ii!ali1!¼¼<\i'it61:fol6iel!Ni6il'~@fr.·.·.·.·.·.•.c: ·Li n ¥Wit lrnMilX ••·•,• ¥ill ES? !OJDH•·•••••~••••••·••tkGiJtt:'T4:K\JX?§ iiiciiQi•••••;; N'¥Q@ 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN 1700 NA 37 4.6 U 4.6 U ' 8.8 14 j;gfa:~i?i&B™¢BMiBiiii;ii~~iPi!ww!i ;;;;·•,•;q;; 1t1nrn ;;; NX iinnn li\ill'i ·;+· it~PA ;;;; ~w;vt " wtmli:;· Ttn@WPt 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN 460 NA 24 4.6 U 4.6 U 4.5 U , 9.1 4.6 U i@~it;*lw8~§lll¼'IB¢Pilliifl~ilf'mW H!@Mii : 'NM ,, ;;;; AI?Q; Fl'l li;ailliU MiiiiilliDift!MiW¥ilUH@lNi%%iJ ;)iH.lll'.WU 4.6 U 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 130 NA 4.7 U 4.6 U 4.6 U 4.5 U 4.7 U 4.6 U 1daiafi~iWAB'it:oRaoiilliiNzi:Mi!irwr·'· ·"•····· itdlf )F)fui;•t •••Ni'i ,i:iuut• •··••·'·""·'·'·'···••·u·1•.~.·.a ... ·•.••.v.· .. ·••n.• ·.,.i.t.• ,.·••·••·•'·•·•·•••·••.w .. · .. ,e .... ·••·:t·.·••1 ... ••·!·•·!·••·•·••··&·'•·'·••·••.•'·•··"·"·••·'··;5·······•·••·v·····•·•••·!··•·····•···;••••·•q;1·dt'. ti~fo;0i •···•···'-i•.i•.·•'··••! ..........•.. •.·•···•···•··• ·••···•·•···••········• ·••·•··•'········•··'· ....... ~ ..... . . . .. ·~ -· ·· · · -· , ., · 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 150 NA 4,7 U 4.6 U 4.6 U 4.5 U 4.7 U ~~;4;f;~;#!l&l!~g:jgq#.!l\!illw~wl!iiiw! lH ; • • i+ ;:;U~WK rn ELNA+ £ ii •ifitiO f + We Uh ; ;; '. ;;;;~ ;s;;; ;: 4lci,) ;; @ffiii.it 4.6 U @:@lij@fi 2,3,7,8-TETRACHLORODIBENZODIOXIN 13 NA 1.9 U 1.8 U 1.9 U 1.8 U %~ifiwr~fi'¼¢l!i~RRi~§l~l:Ji!ww!i@i,iWJI: W Mg ff@l;@It·"'·····•• n~··••.<;••·•·•••· MfoM@ < fr~µ/\ j;~lcn.•• · · ·11.:u ;;; • ~;~ lHiiffii;if#~i•ii 1.9 U 1.9 U HEPTACHLORODIBENZODIOXIN (TOTAL) 54000 J. NA ' 2500 J 150 J 79 J 310 J 630 J 1 120 J •··•• •• •• •• •••• ,. • ••• . • ••• •••••• "•""<"" •¾•••-w.•,•••• ❖Y ., .. •· .... •· -•• ••••· -•• •••• ... • ·•· .-:❖:-::<>. •• :: ... :;,!;.'.;::::,<-:!:-;.:'.;::.., .• ,:..: •,•,•:•• .. ,, ..... , •· H~erMit!ii§JNP!!@\gR@!Mtltt9!MlI :,@ii&lib • HNAHR ·····:~@f:•: AAf!J~··· H•M/40~ ··.·.········Mvili,·· mrw r i,,@r.\JJi HEXACHLORODIBENZODIOXI.N (TOTAL) 6500 J NA -290 J 12 UJ 41 J ·51 J . 90 J 16 UJ i;/l\l!Ao\K~oilotiisfuiioil~lfi:i'fAtii tit1 :1d> UJNA+#lUt+ tl/4Jlirn %%\4& w.+ @ ]iiiji iiu....... •• tiiV>'. T• '.s1; J· @till.; OCTACHLORODIBENZODIOXIN 160000 NA '16000 460 650 '1500 · 4300 J 900 oiifr#cBtBiiooiat&za~• rnntm rnn m lL ,2rnmn1rnw.w ~rn;mm; wNww nn 1sitt< > MM' ; • a;,ru:~ ;; :; >n, :;; ;,;; 100; ;;; , ; @~~iww PENTACHLORODIBENZODIOXIN (TOTAL) 960 J NA 23 J 4.6 UJ 5.9 UJ 4.5 UJ 16 UJ 4.6 UJ l!gm'¼,qtJtpWli@l!\~/:giffeiPilA~rr~i'f&\rrnrn;n ·;;;;: iii rnm~wirnrnrn ;wirnw;rnw n~~Wl t ;i;.uiaJ}r i,;;;fkiiJ£ ; ; ziui xv;;pJ·;•· ii#@~ 860 NA 35 J 0.76 0.81 4.2 .11 J · 1.6. 281!lin • ,NA ,v, ;h wl!iJJ,' .;,r11cLc:t ilf!foivJfriAt#~iiiJi· r· Hbilt··· ;/iif!WM T~? IT?~'8I?~'Y.•Y~b~L~~8~};I:f(~?l., " , "' , JJ;:;IMm1.UOROR!.~9.P.!.O.xm.JtQJi!il1/f :,:,:,:::::: TETRACHLORODIBENZOFURAN (TOTAL) 860-!_, NA 2.2 UJ 1.8 UJ 1.9 UJ ·0.22 J ·38 J ~.95 J 14 of 18 - ---- -- ------- --- --Soction 2 Soll Sampling Investigation TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GPOSOSLA GP050SLB GP051SLA GP051SLB GP051SLC GP052SLA GP052SLB GP053SLA CHEMICAL PlOXINSIFURANS 1@~Al!iizi41t@er¾9l~QR9/;i\m;il?,®i2~@. v 1i 11iisot \ 11tni N% ; w tv~~mw :w+ 1~i/#Wlii itil:iiBt> >' >i~iiii;ii\> x : NAT >; , m\,.x 1:i:~:~;;:*tmi~1 x2AEB~i1i;l@.wiuwiw , , , , •j~i•ci > .~~ •• ;•. • • • • ::~ •• ; ••• ; •• ,. :.::.;,. ,+·< .:;i~n,.,v,,.:~: ~. . ........... :.;; .... ·+····· .;:;: ... / . 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN 4.4 U NA 48 11 4.7 U ·11 J NA 26 1!i#t¥Hl£1l~l/,@@tgl@ifii~i&i!&lMM +wittill•l t•t#lWi .>c:D.\ .•. ~~.,>, .. ·. ;,; .... ;,.,·fa~h, .. ;.·;. .. ,. , •. ,1,1;1.ir,, ;. .. ,.· !ti·v ......•.. : .. :;•f:¼ • • : : :.;M • 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN • 45 J NA 350 75 3.5 J 89 J NA 84 ~'ii\#t\kMiii'J~tfilCqilqp/i@i/)QffflI@F ( &~v.h ; jffe·,.·.· ... ·.·.·.·.·.·.yh ii;• %%st ;; J;i;i:i;i····· 'iiaiiJ[.·\V friii\ L··Ji;ij> 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN 10 NA 100 29 4.7 U 32 NA 21 j@s/tia;ii}BEU,c/:lilOl@iOIE!i;Ntol\)l:Wi!'li:il:Ei.•iW•• •: B:,.K::• ¥F%!4:4JlJ!l..#• nd•NA : rn::•.t:.:t: :1s:ui::•••Hkl••%nu:)h#:t:b:.il7i:JJ#:K.:?F :•;S!i>•Ull •hlW: ::•:fflfffff:% •••:l:ti!iiF.\IM 1,2,3,7,8·PENTACHLORODIBENZODIOXIN 4.4 U NA ·31 7.9 4.7 U ·6.7 J NA '5.6 i;g;&,,~\R!!NTAcat&lci6ial!!'lzo1,m;i tr ,•.•·· ···· ..... ·.·. di\iii.i Aililin;ibJ+ ~N ·:r ;:~?··:za:,; fr;; ii!~fa:ui,, lil !i~Im a; wi;ifoiin; :i;~i$11 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 3.8 J NA 17 '6.1 4.7 U 5.3 J NA -8 :b;;m:MM!mA®toRooiMNtoitiliRAfl rnu, n •7 •mrn1u11:rn ,•;ii'le; :;;;z :;;; ; #fiii : ;;¥tM<:.:;2;.:;ta;rn;::~:;;::::w;;;::;;;;: IIM¥Irn 2,3,7,8-TETRACHLORODIBENZODIOXIN 1.8 U NA '8.4 '2.1 1.9 U 11 U NA 4 U zi;}\)!lif~f/ll@iB~miJM~!®iPfffl)il!iH El : L ; g; l!l@iil :' ;'; HiiJi(l I PY if!•'.} ;;; :;;;s;;;;; 7 ; ;oiis;J ; ;; ii: ;;;; ;7;'.,NA : '. T '.,;;;;;s; HEPTACHLORODIBENZODIOXIN (TOTAL) '980 J NA 61000 J 1300 J 140 J 3800 J NA · 1900 J .•.•.•.,.;.:.;.:.,.;.•.;.:•:C❖:❖:-:-:❖):❖:-:-:-:-:❖:~❖C-:•:❖X•!•:•:❖:•!•:•!•!•:•:•:❖:•:•:-:❖:-:-:-:-:-:❖:❖>:❖:❖:❖:•:•:•:•:•:::,;-;.;.;.;.;.;.. .-...•.•,,,;-:;:❖!•'''•'•''•"~•' •'•'•!❖ ••••• _,. ••• .·.·.·.·.·.••.•.•.·.·.·.•.·.•.·.•.·.•.·.•.·.•.i, .. 9 ...• 0 ... ;.• .. •.=ti .. :: •. •.•.'.•.·.··.•.=:.::: '•'•"''•'❖"•>"·' ••• •··•• '❖'·"❖',,,-,.-;:;!;:;:;:;;:;:,:;:;:;:;!X!::::;: ,•,••:;~~;.;.• :;:;:;;:;:;:;:;:;:;:;:;:;:;:;:;:;:;: @er@fliiQ!'\QP.!!1!;!¢;Qfili!!i\i'!ITR!Af)l:t: ff#@iklt•i•••M:1!H•:Wt•?#i\. · v .,-· ·+fl!6@\h ::·14\°i:,e·::·:::::;:?~!Ut:; ·······NA. :·s6f/4• 7,~S~h.2~2P1.~~.~:2.Bisi.2.I~.rr. 2.r!~.1.,.. . ......................... 2.10J .... , NA H~~cHtoRol'Ji~ai?o8/8Af!ITQTAftt ........... ;.,. ;1ww w mm rnwv nm itHflAiH 1500 J r380 J 25 J 530 J NA 410 J rH1t~a11;1: i;H#d4 >·••:·:·>r1w>w:>·.·.···>.1i~·JF: Xiii\ :1 ~xm OCTACHLORODIBENZODIOXIN 3700 J NA :24000 6400 1100 55000 J NA 11000 ◊¢t@51i\$f:i.lmi~wQl(µiMft :-... , 1w r" : :wrnm' nniturn1n ;rn;mnn H:b1sl1!).n::;•••m.+t,Uiid ,:.-·••A2!i.L;•t:•:-:n2@\IP.:.::·:<·: i-lA·r:L .• '" ··:t~~At PENTACHLORODIBENZODIOXIN (TOTAL) 17 UJ NA '200 J ,62 J 4.8 U 60 J NA :30 J ~i'itl'i¢1it¾BPPm~N¥&!\i://¾ijrrg'fX\iltif"'·'·''":''"•······· :rn~WT:i@:t:mifoi@ :· ,iisoiiJ;· ·iiti"i<> :in.wwtiJ/dd:#J)ijk t• \l:lli#k .;;;~$;ii; I~?Q821S~9.~1YY!\#~:rn9M 1;I~E{I~I ......... w .w: ... !.1 .. / ................... ~.. . 160 . ·43 . ,·.2·2 . 95 J .NA. .. . .... 42J .. . I!;IRAG!:!~9BQPl~;':91'JIQ~!!mmwn Si ;;:;.: :,;;;.; d!!'~i!+w+ •• \NA; ;t;.·.»;;,;.:;··:.:L··:; •58 :r.·,:·;;;. :;+.4,~;(JJ;;:;;:;:;;.;;;tiCJZi•+:rx·•NAt:p ·•;;.;;: :;rnmfH# TETRACHLORODIBENZOFURAN (TOTAL) . 23 J NA 150 J ' 76 J 0.35 J .50 J NA 15 of 18 - -- ----- - - - - ---- --Section2 SoU Sampling Investigation CHEMICAL PIOXINS/FURANS 1,2,3,4,6, 7 ,8-HEPTACHLORODIBENZOFURAN 1fa;&~11;Wi#1f1€iir/4mit&RQ51sll~oiit.1~n / ; 1,2,3,4, 7,8-HEXACHLORODIBENZODIOXIN {;i@\tz;m!ll~xbitiilii®Pl$lmfli!mIHH 1,2,3,6, 7 ,8-HEXACHLORODIBENZODIOXIN iii~)~;~;i;fili!i~pjijgqijqqj~§'li&tm . • n GP053SLB TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP053SLC GP054SLA GP054SLB GP054SLC GP055SLA GP055SLB GP056SLA 55 4.6 U 80 J NA NA NA NA 4.8 U ffii{;@omtrntlks'.Wi \,c •~A:ur;rn:;;i%: \'.; £:Nkt N/4E o ;~; fifaip;; 4.9 U 4.6 U 11 J NA NA NA NA 4.8 U it~Ii!TF m~l~ilf··· Eii~;~;i;i ;,··•·••iiii&\i ;s JAAH i!H ; f.¼'Hi •·.·.·.,·.·.·.·.·.·.·.·•·••!'IA··•··•··•··•··•·•• ti!i@!P 7.1 4.6 U 63 J NA NA NA NA 7.9 :r··•·•·:••· I!iJillI i#iiiv········· IPK~fi! ?;HNXF?? T .·.··•NA·;·······.·· .•. · .•.• ~··;&k.••:r;;:;;M;;... Alim 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN 5,3 4.6 U 28 NA NA NA NA 4.8 U 1,1;~;1;~;!lwgl\e.l;8~@R!~~2ii&illl!!ilm!I }r· i , ;1rnu. rrn@WI'l!\ll@mrn ;· · .... :•:·i;·ukiH, MHfJA-W : I FY¥@? ;Iqq; i½ '.?'.{E '.;WC ..... <: nrnror 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 4.9 U 4.6 U ' 6.2 J NA NA NA NA 4.8 U jig:3(',j(~iREITTACH~OOli\!$HzoliililwiiMi)t ;:+ PP@'I)@iJHllM \iilJ;Unrnr;;c;;¥¥4 ·················••i&A)<<.i/ 'AA + ' wC; , vw;< 'a L -<c1l.JJ 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 4.9 U 4.6 U ,4,7 J NA NA NA NA 4.8 U ihlliiiiiiM!l/#4?i@$Rq¢\miiiPF~Vii!fii!\l@!I ,L ; t;M;Wrni'l il!ll@Mi rnni~&!Jtt· It@@ ·.·.·.•.· .. , JiKL: ··••N1L••··························•·········••Nk•• ,.......... UMDH 2 U 1.9 U • 0.65 J NA NA NA NA 1.9 U ;r:-0AiJ: +••nntFHi:M,XHi#trM;1wi,@:H,UHRWEV • ™'·••••::< •·NA••••7••• ....... NA.,••• •• •"•·•11ite1.•Jr• 2,3,7,8-TETRACHLORODIBENZODIOXIN %1:iit1i~ii!Ai:iBQ9!%i:ltiiij§'lt&ifQMN f " HEPTACHLORODIBENZODIOXIN (TOTAL) 640 J • 39 J 2100 J NA NA NA NA ·140 J ffi§!l[AQ®QRQQj~g/!g9B!!'½~ffQ!A!MMrn W:fft i@iliit@i'tiiiJ:iir ji,iiµii'.iii .. ~~MP ..•. ·.·.·•············•w,;•·•···>·· ii'.H@<i+· '\Jl,{ Y•·•··••':n•:Jlmi;;;';; J:MJi4 HH·.·.·.· .. ··.~.'.'.•.·.·.·.·.·.,.·.·.·.•.··.E.·.•.·.·.·.HH •..•. •.•.'.·.: ....... ·.·oo· .. ···•·.·.·aR.·.·.·.•.·.oo.· .. '.·.•.·.Do·.·.·.·.· .. 11 ••. BB •..•..•. ·.L.·.·.· .. N .... •.·.• .. zz··.•.·.oo·.·.·.•.·.·.·.E.•.·.••.·ul.·.o.·.·.".·.·.x·.·•.,·.•.·.: ..• ·.N·· .... •.••.• .... • .... ·.£.• •. ·.• .. ·.·.2 ...... •.· ... •.r .... ·.' .. •.t.•.· .. ···.L ... ·.·•.!.• •. ·,•.•.·.. . • .. • ..... ~1···J··········. 16 UJ ..... , ...... ,i:io.J .... .,., ........... , . ., ... NJ\ ..... ,.... NA ······~· .... ········'··········· ,t-11\ ........ ···•· ·····•·•···'Jt./ ... . =~ ~ = ~. ~• ,,u-~, :MH:tli!.lt· •'.H".$iJ®k :#:::tlmt:tfrKA•::fJ\liiiMW, ./\NA<. ••••N/\••:;x>:c•· \NA ,..,. ••••;JVtt/J OCTACHLORODIBENZODIOXIN 3900 340 J , 14000 NA NA PENTACHLORODIBENZODIOXIN (TOTAL) i!il"i'fiJZmmslilimlt&iai\01¥Aij&gfsiliM 6.4 UJ 4.6 UJ 30 J NA .·.·.·.·•·•••••••;>'.'..• i!.iiun iMi\li\xrn: , diiiiii " .•.... NN ..•.. ,.; 11 UJ %~~Ji NA NA NA fJfw; •;a•• :;);NA>•• •••·•·••••·•••••NAY i~ilt~ii1&~iiii~i!cii11% 7.9' •. ,.. tH:~;~:~tt~!:~;~~t~HMI 0.34 J iii;~§ .39 J it"i?' NA NA NA NA .2.1 Ht NA: :; ····· /!¾fr ;; W1ii,; t,N&, • ; @~atJJ TETRACHLORODIBENZOFURAN (TOTAL) 0.42 J 1.9 UJ 39 J NA NA NA NA '.0.16 J 16 of 18 - -.. - -- - -- - --·--- -- --Section 2 Soil Sampling lnvestlgatlon GP201SLA CHEMICAL PIOXINS/FURANS TABLE 2-3 SOIL SAMPLING SUMMARY -DIOXINS AND FURANS GEORGIA-PACIFIC SITE GP201SLA (Dupllcate) PLYMOUTH, NORTH CAROLINA GP202SLA GP202SLA (Resample) GP203SLA GP204SL.A GP205SLA GP206SL.A 1~:?l~Ji:z:i1ii.iii/2i1iPRQQ!?§tg@!Q*(llt !0 nmr IM!lflHi!il t;i/JGJ!!!ff 39!4iUl;; .. ,r ;;NR;7;;;;;;::1hf /\. lFIJiiiriltiti1!/fr51i@idHNfaiM) 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 11 J 4.6 U 6.4 U NA 8.9 U 9.9 U 17 J 4.6 U ti~i~:\i:1;~:~iii~ifri\iligf:iQQ\~gtggfgR,f\!:/ji ;;;)£ . : : Ilill jg)/! ili Ui!fi~ili ;/\! lfaj\~ !J • ' < &ii@ t lJ~ !'! ~\~'.µ ji , , %\i'H ;, 24'.KQ 12 U 4.8 U 4.9 U NA 4.6 U 4.9 U 6.2 U 4.8 U t l'HHiqn •,#iiiBn t:JMMH ihlHA /t:· !flf!)\ XA,lliiL : ... :.;;a.:.a.:. ii,Ml!ii 1,2,3.4, 7 ,8-HEXACHLORODIBENZODIOXIN 1fi)t#Wl/½Hii&itiBUQi\0RlilwMlt\U&W 6.6 J 4.8 U 4.9 U NA 4.8 U 4.9 U 13 J 6.3 U •• ff)~µ Hi\\®IU !Hi¼'·•· iiwki:!lditff,(@u:rn •n+~lliod '.<'§Tf/3 rn@!ilUid 1,2,3,6, 7 ,8-HEXACHLORODIBENZODIOXIN 1l~M;;fl&illi~Pti4®!6Riijaifi:iiiiJ@JlH 7.8 4.8 U 4.9 U NA 4.6 U 4.9 U 11 6.9 ••,•H,•o••«n••••••••••••••• ••••••-•.-.-,•.•.-••••••••••-••••• •, ... NNN,•,•••••':❖••• "❖'"'"" ••,v,••• •,••••••••• ••••••OoH••• •••• ••••• • •• • •••• •• • • W U#J2'UR• , ff!Wl•PRiT•t• Plf\illlk .......... •\NA+pib; •f;llJ\iR}F MT'iltii'.UR'F Hll,i!flJkf •rn~!!UJg 1,2,3, 7 ,8,9-HEXACHLORODIBENZODIOXIN i&:&¥.i~!!iiliiiBiABilliIB!lBB:ig~z&ii~ \tkk rnn f 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 12 U 4.8 U 4.9 U NA 10 4.9 U 4.7 U 4.8 U 'i##fiWi#Ei$-)(a:l/iBRaol~oifvlw! Lt ,frw,n; 7li%lllk@P,faifo(u!t l IV+:~llik NAii/ ;;;; AiiiPii; rntm~i#tii#&mfo~HHJiib;· Z;'Awelli~ 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 12 U 4.8 U 4.9 U NA 4.6 U 4.9 U 4.7 U 4.8 U g~~l~li\~\i:iiil0.%BRiw9Ql!Wfgpfm ········•··· ;;}•·•·····•·•· j;/Qff l#Ji)ll m wM@liMDi NA ;.; 'k~D F Hi!rn!JJl falilfoil#WllliHl, ll\ #;~µt 4.9 U 1.9 U 1.9 U NA 0.21 J . 0.21 J '0.58 J 1.9 U • 111,iwt t•I:/%4• • rn• H#;J/!Q •mm: : • Ni l ff •ttt)(~q;'. • •ji\!£ :'·fainw.tii!H ff :: · u.u B~xi@i§;~~~~~;;&i§t.il:1 nt~~+ ················'.tjj;t;Jt ~~~~ti •H ~t :::.~:~g;, t:~.;; ••ii(i;,;~;i.~ i i··i•~j••ili••: ~.~S~.\:8~8.9.1.~.7~.if.2819*:~ .. IT.8.I.tbL.. .. . . ....... ..... ..~t.r...... }H,_f p J . NA.......... 4.0 J . . • 53 J . .. 88 J He~§BLOROPIJlElolZQF\/RANIT◊TAtft nr ········ ··•····· HiltUJM. f\]i!HJJ +•rn•@l'm ::;; :nAAn:;:· :r::-::;atpJ\ .g1s:wx:; •trn tti$lQW 2,3,7,8-TETRACHLORODIBENZODIOXIN iii:iifiirriiA\:iill;®li:iiiii~iiii~n OCTACHLORODIBENZODIOXIN (3500 J ·4100 J 1400 NA 2000 J , 7600 J 27000 . 26000 6¢fA&lL&ll65ll!€/,iid/i/J@Jl nn@nn ff i-iiiii ;rn; l'I~$!0WWJrnnnrn~Rlfi NA ;; Zibi;i£DF iff!H!&HMH : @•: • ;; L ?.$9} PENTACHLORODIBENZODIOXIN (TOTAL) 12 UJ 5 UJ 4.9 UJ NA 87 J 4.9 UJ 19 UJ 8 UJ pgfgg~81(qfigpj~~&£®iiliri½NrrRT.M} H MtHlhiilF ·••.•·; Hjjg wmrrn HH~lli lim j@ i@jjQJ1 ;;;,'; ;&,, nm i!il~ wHlI ill li\i\l®iilMEIMI~J~;J kill ; ''··,1.11· W 6.8 J 5.2 J . 2.3 NA .. 8.3 J 12 J 36 30 ifk~Iwi .. ,, sicitiili ................ @J?I!® ·.,, .• ,•;m .... ,,khgf21!dii/ iiliii 7'\if?!I ' ,izii'iii~ TEQ (TOXIC EQUIV. VALUE, FROM I-TEF/89) fijfi¾mN6'ilPOil@g§p/§!wi/ff.&ii\M n:··· TETRACHLORODIBENZOFURAN (TOTAL) 9.2 J •9 J NA 5.9 J :·10 J 17 J 3.9 J 17 of 18 - --- - - -- - - --------Section 2 Soll Sampling Investigation GP207SLA CHEMICAL PIOXINS/FllRANS TABLE 2-3 SOIL SAMPLING SUMMARY • DIOXINS AND FURANS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP208SLA GP209SLA GP210SLA GP211SLA GP212SLA GP213SLA GP214SLA iF•a\fijiii iiEiii'iicll!MlROOiseNiooloxiN ·.······.··.··.".····.· ·······••m••·······•·"'·• l.·••.t.@:.·• .. t.400.··.··.·.··.··.\m.... ti. @~E.·• .· .. · .. · .. ·••·.·········· tfa.2.a.··.·· .. ••··;·rn .. •• .. t.t.i.l.• ii.ii.·. ;ii•··•·• >·•·••iao ....... . • .. 6 .... d, . .; .. ; .. ;, .......... i ............. .; .. , ..•............. ,.-.•···•···.;· ... .'. ..... .-. . . .. . .. . . . . . . . . . . • ... . . . . 1,2.3,4,6,7,8·HEPTACHLORODIBENZOFURAN 14 J :11 J 47 J 6.3 U 5.9 U '18 J 4.8 U 5.1 U !!~l%~\%~l%~m~&PR99!li.ig!iifQw/lH •· .. .. :iifa4 i;i .... =' ili0flr Rll II U\l& wnrn;rn; l:4\?Ii;JJ[I! lti :l~ll! w Hi >':4:1 •u ;. .. .. ; .. ; ... ;)q i;i;;. :'.t&¼h 5~U UU 4•U UU UU ~9U &@J!J .... "'· ;t:tQ ~ 1; Wi\.l >> ; AdY ; ;:;,¥\ii ..... · ;i;iiQH 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN ......................... •.•.·.·.·. 3.2 U 4.7 U il~l~~#ltlmBglih¢Bi@!i§Qlijl\Ht!@lmirnm .... . ....... ,.,, Ii•I~l@XE % ki/5Q!MHU 1.2,3,6,7,8-HEXACHLORODIBENZODIOXIN t;t~:~@tB~tBtooootll~i:difmm ..................... '······· ........... . 7.1 J 5.7 U 10 J 1 @All• ·.·,·mi M@i.in ·· Wil!t UU UU ~1U UU ~;1n;1 ibbit;1ii!Plhi.. iHWWffti Wi@\'.I.. . 4.9 U •ia¥Mi 1,2,3, 7 ,8,9-HEXACHLORODIBENZODIOXIN i'.[iillzli:i@~fltl@ilfilfill~ftl€ii'ilill!ll!i 12 7.6 9.4 4.7 U 4.9 U flit H@iI/1'§++ MMltlffi/EIH tiiWDfiTF iiidhih iiii iigiJifo 5.6 U 4.8 U 4.9 U @diufii i!P,+;~;iiR/... f/4(\jQ~ .. 1.2,3, 7,8-PENT ACHLORODIBENZODIOXIN i#lill?ill\R§ITTA½i'l!@B.99!&2€m;;rn 2AU UU 4~U UU ~9U UU 4~U t?:¾PRMill liiii':!18.H ..... @f'.!li!.iRlf foiwuiifrfrdlil~!Qf;JI niiifrtii;ii#Hii!i,uuR• 4.9 U ·•@iifoi 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 2A U 4.7 U 4.8 U 4.7 U 4.9 U 4.7 U 4.8 U 4.9 U tt~@l~\tlgiif~iwt&Rs:iillli\l,\1/¾jf\i/;Mifall! ·arn .... lHW ltiWBtMrnmmwwonm @%ti@; i iiijj(;'. :\ ti@4dii ,nw:vo .... ·.·} ... · '·•·'4,/l .. ·•U········• ... ·.·.:•······ <ii{yj\jff 2,3,7,8-TETRACHLORODIBENZODIOXIN 1 U 1.9 U 8.1 0.11 J •'0.13 J 0.69 J 1.9 U 1.9 U iiYMi~iiit@iilit61l6Bia€Ni6i!UiwF' ·.•••.• ... •····•·1·• ... i.h.• .......... !fu ................ , .••.••. l.l.l .••.••. ,.· ... •·•·'· .. ·•·t·••.\ ...... l.\i ........... b ............ l.l.•·.I.l.I.·•·'·'··•·;·•·· ... , .••. l.\ ... ·.• .• ~.·· .......... u.·· ........................................ ,.l.1 ..... \.!!.· ... •···•·u·•··· ........ ' · ·•.••.•••.•·.i.t.-... il.'.'.u.· ... :.··•·••.r .•. l ................ ; .• •.•······•·;··•·1.·.:.~.·.•··'·b·••.·. -:!ill u : ', • •.••.••.•. l.•.•·········;· ... · •. ·\i· .... · .. •·.f.b.'.".l .••..••.• ,.,.,. .................... · .. ··•·· .................................................... .,.... . .. " . ' .. HEPTACHLORODIBENZODIOXIN (TOTAL) 400 J 740 J 650 J :310 J 450 J 1200 J ( 89 J . 530 J lil~Ri:~i!fi@filrifilml\~fgqmR!i1lrrgf/4lil ;;;; ;;;; ...... +.. i;+~@i '''iii.ii$'. ii;/11Wiii t ii:lilwH rn~@m~ .. vt·t;r~;;; :?wflu· !@0ii HEXACHLORODiBENZODIOXIN(TOTAL) 87 J 83 J 99 J '32 J 53 J 88 J 14 UJ 59 J /:l~2illt6ii66l!HffizBtuAAllwBfMl" u •lmrn~@i.ilH.ll WH1¾l:@H.li +M9"Jt > <i'1·w• ............. ;w11umt I ;; ;i;0;;; Xdii,a;;;:;•;; ... • ... •.•• .... ·••.1.••.·•.r.·••.1•.•·.ll .... ·•··l·u·•·· .. · .. J.· ... ·••·••·· ..... . ' • . .. . .................... ..-,, .......... ,+ . . .. . . ....... .. . . . . ... .. ....... .,... ... ~ ......... ' ...................................... +.... .... .. . . . . . . . . .-..... . . . .. . OCTACHLORODIBENZODIOXIN , 11000 J C 15000 J ·9000 J ·12000 J . 13000 '.8200 (820 \11000 J se..t4®ii6JlBiile€fi&i\GlwHml ", .. , .. ,? •• •++n rn+®rcii•iWW ;r:aii1r: n .. t•SffiL.b• xz.... 1il)J;;.. ;,;;;nniu;x .... : .. 71wx .. , .. <,.,116·:tL ... t+i•••d~lfur PENTACHLORODIBENZODIOXIN (TOTAL) 11 UJ 14 UJ 19 UJ 4.7 UJ 6.9 UJ 9 UJ 4.8 UJ 4.9 UJ li#Hi~$i'it¾il'i~~igi%1Jw/Mrr&f&&m1m•• nm • Mffi&iH•m • •• sWJJ •@s~ iJii) • irn• (4\tUJ••rn w;wswmnm:i&fa\11\liadl g .. ifitiil~ Wl • l,ni!l)J ·11 J :19 J \23 J '{5 J ·. 15 .12 ,1.2 13 J fi1;@iii'fahfr@liiifrb:L l M@tmnrn ~ii#itfa mlP43iift #JJ;~l!fa;. '";{,iiq;i, • ti1iiiuµ••· ~14 J 8.5 J ' .5 J 1.9 UJ · 6.1 .J · 4.8 J 3.1 UJ _8 J 18 of 18 - --- CHEMICAL ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SELENIUM SILVER - SODIUM _ TOTAL MERCURY VANADIUM , 0" ZINC ---- - - ---- GP001SLA Data Qualifiers· GP001SLB (Duplicate) TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP002SLA GP002SLB GP003SLA GP003SLB U = Material was analyzed but not detected. The number is the minimum quantitation limit NA = Not analyzed. J = Estimated value Concentrations presented in mg/kg ---- GP004SLA Section 2 Soll Sampling Investigation GP004SLB 1 of 18 - ---- --- ---- --- ---- - Section 2 CHEMICAL ALUMINUM ANTIMONY ARSENIC · BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUrvl MANGANESE NICKEL POTASSIUM SELENIUM SILVER SODIUM TOTAL MERCURY VANADIUM ZINC GP00SSLA GP00SSLB TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP00BSLA GP00BSLB GP007SLA GP007SLA (Duplicate) GP007SLB Soil Sampling Investigation GP007SLB (Duplicate) ~!QQ:.~~--~tY::L:: {~?99.· }-.'.~ ~-:..~:-;: ~~q,r0:~:f::::~h:t1§Q§QS?:,J~;:;~~-~Q(>}?J~i~·??V:~so~.~·-~~~Y~'. :i1:[~:·11Q :: ;~:· ; '.". j~~ :,;)iOJ) :,, .. : 0.76 UR 1.1 U 1.1 U 1.1 U 1.1 U 1.1 U 1.2 U 1.2 U . ~:.! ~J~J~l.:.; __ :_, ·. ___ q~~9 q: -~-.-•,.':·. '.~.:-.. ~-JJ~~~~~~-=~ti:t:.-f~•i:-".!&t:·t/:-.. ~::1~~~~~'.; ~:L?.it/t_;t--..t? :,~•i<f -~-!1 ... ~t. ~ -7i_~-:.: ,:!l]4_ .W _: w u ~ n n ~ a2 14 · o,M .. :I. ::i:f ':: °Q.Ii u ::i , , · .□:'?.·t·!d.'9?t\ ::· :r,::Q<'f!:-t~', QifQc':·i:t ;Jf22;· o: t :::-: -~□--~4 IJ> . :'.:' J~ :u 0.18 U 0.21 U 0.22 U 0.22 U 0.22 U 0.22 U 0.24 U 0.23 U ---.;~pQ ~ . ·:; .. _·;::-~ f?:¢.O~.-~,; __ ~ ____ : . fiJPQ.< --~::-::~~i{~i{tQ9/it;.f;.;-iJ::-~'.1.~q-~~Ai1~:~:1~~~~~(~i?iQ.··'..t~~;::~.f:_.;j4~ _; .. :-;:~~:::.-. iBq .·f. · 2.6 7 3.4 8.5 5.1 4.5 1.5 J 1.8 J oJt_\:J ,_: : \ : 2 ·J.' -,:f,~;i::c~~' '/:'1_.J[.,{'{jJ/,:,:•JlfiJ.i:\tt?'.fd l · 3 Ji:.Q,4a D •; .. < .o.fii j 6.1 J 9.4 3.9 J 5.2 J 4.2 J 4.5 J 2.2 J 2.7 J . 36Q.O :f ". ·.' 4!JOQ : .; .: .. ' ifp.o.~1; i,:02 .. i§Q9; ':i ;~1;;iieJ'.J§91! j}S:l:!"?ZQQ ."::~'./·,;;;,';!.PO .. ~ :: .i'. /.tijp. :, •. 7 J 5.2 J 7 J 15 J 17 J 19 J 1.4 J 1.4 J 's"oo __ , , ._ tii@. :·:,: · .. 27-q .. ·';:·-~·;{ ')111 > \V;.;;;!;~}q~f:~"?i i:~l!;.•,.-:':'"_;,.'.if-',.:· · .. ":.· ·_-131_ 67 120 81 78 87 79 3.1 J 4.8 C!:~~--J-.-:-.~--~-, ·.:~ ~-:-.~./-.,._.~•::~;_?·/~ ·\)t~·,-·.:ij~--~-•:1t~'.t-~~/j~_F1/\!?:.!:~>:~;0'~ ~~~:.T)"~··'':"'·:•-; ·-,(_.t1.U .1 ~, 760 800 J 200 J 190 J 200 J 170 J 25 J 37 J o:t§ 11. ·: . ·· ·f.J Q <,~., . . · .. 1 jj,( :":·:;.•:.,,'-;:3 ;1;jf1:L1i:::'i;1J:.P11.t·/:, ,~J_) :~ .: , "-.~, C::1.t!! .. _ , · t:.1,2 fJ ; 0.31 U 0.43 U 0.45 U 0.45 U 0.43 U 0.44 U 0.48 U 0.47 U ::'BO ~.:· · ··. · 1QQ Y. . : ,fQ .l:!. >::\,XJ.§g g-., :7;t;}7J!l''.['r ,·;;_ :~·)]: q,;· , , .'.'?Cl lJ. : ·: '·. '"i;o u . 0.1 U 0.1 U 0.1 U 0.11 U 0.1 U 0.11 U 0.12 U 0.11 U ... ·. ~-l·i-LJ-~-~·;\=··: :,_ ~~,>.~)./I::, j ::;~~7 ~ -~r::0<~/f,Jf ::?~:t,tj!f/2.·;~-:i:-Q;~<iif•j.~•f.t~i~<-·~r ;~1:·,~::·1!·/:· .. J •• :: •• •• / -~~t .. J:_· 18 J 19 17 J 19 J 19 J 18 J 4.6 J 4.3 J 2 of 18 --- - CHEMICAL ALUMINUM. ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SlcLENIUM SILVER SODIUM TOTAL MERCURY VANADIUl\1 ZINC -- - - - - - - - - - TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA ~ - - - Section 2 Soll Sampling Investigation GP00BSLA GP00BSLB GP009SLA GP009SLB GP010SLA GP010SLB GP011SLA GP012SLA _;_.~~p_q/. ?J:it:~ ~ : ~§.QQ. ;.;-~-: .. ~.:}-i·.~:•l~'l9-~li~E.,]~:i 1.l!tff ~.j!' ~1: ·;:; ::~fl>~2r2I~3I! ~fQQiJll&J~iii7~1QQ;:f'f~.~~;{~ 3.~gq ~ · · . 1.1 U 1.3 U 1 U 1.6 U 0.67 UR 0.67 UR 1.1 U 1.1 U . :t::<·s!§•; ±/\.; .... -: / ···.: 'l!i :-~·.--: --~(-: t~I}J~; .. f:· :::<~f~{J/:f\t·1t~~:~]/;l~}~!.:.};/~, _,: ¾\:~:~~\\-. '-{~/\ -~t§1:JT: ~.:.r-~<-_ o:§? u u ~ a2 ~ a a 21 21 ;Jli21J.!d: ,,\ , : ii]~ ~ ,, . · . -sr_~1 Qi ,:. \._-,:,~~;Q:,.:·,};;c ;;"[If"}J;~,j-<-;;:·/~:If/Jf/(.' :. 021' 1.F,:,' / ~ 9..:H \,J • 0.22 U 0.26 U 0.21 U 0.33 U 0.16 U 0.16 U 0.21 U 0.21 U · 'ao_iio_;: . . : :{stiq ·· . Jig,j,.,,.,:a:; .: 34.0.!Jhi,,~= : · --·~}'ifgj:~tc,~,1,,,,,.--,.iioo , Jt2t;>1sgq•,,1 :\::::-: 1600 , . 5.4 3,3 2,3 2.4 J 13 3,6 3.4 4,2 · .f.f··J._ ~-·:-~ _ !:§ ~(;:.r::~ _cr2~ __ ;[:2 ~·•:· .•?J:~~;~('.~-;-::r· ·,~1g.s?~.tftl~~~J.:i'7i_.:-g}~--YJi<_~r-~ ~::J:~ ·ii-r1.·.-?:·· 2.? J. 6.7 8.2 2.8 J 5.6 J 5 J 2 UJ 7.5 5.3 . ~~!iil .: : J~tlo.. :: ' :'·. ~ i@Q: \,~ ·.:: .2p§g;.;k. ;t·t,:<-:@QIE;f'.t:.:::::f:2.1tlti. 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Q.i;i J GP017SLB (Duplicate) TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP018SLA GP018SLA (Duplicate) GP019SLA Sectlon 2 Soll Sampling Investigation GP019SLB GP020SLA GP020SLB .:1000)• :,:.: . : ~§.~!1.0:{;\,i''7X~YQ"!i!,L;; <~ '4]Jg_qf;tt" ;,(,.:'J1§iJ.•'!f-::;•_ ,:; -; ,:i3oo ·_·!!: "5300 . 1 UJ 1.1 U 1 U 0.74 UR 0.72 UR 1.1 U 1.2 U ?,3 _, . 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'fi!1,, -·•.<1!.,i:'<'.;;:{•·.,:i°jJ.'.;[·:,;~. ·. ji.JJ.•_,·,;~·J·?'l{· ,;,,,,, 2U 330 990 J 1100 J 940 80 U 250 J 170 J •. Q.~3u_ •. , :.::ttu.., . _ ... -.-Jl:!:--~:~.:_,EQ;f&JP-i/),.cfz1_Q~ .. :;_-/c:,::r1:i:rtL·· .-?· 1.2 u 0.33 U 0.42 U 0.42 U 0.3 U 0.29 U 0.44 U 0.47 U ·_ :'iig Li.,~-:· _:~.§Q:_(: -'.f1.q 9./f.J{f 'i~:ao Q:)i'.:, .\~Q _Q ~ ,; ·:;;:-;,;;tQ.Q~~ : ••.. _j10 iJ 0.2 U 0.1 U 0.11 U 0.05 U 0.06 U 0.11 U 0.11 U ~> >1!· ·;i-·' ·. -? t.1.iilJ.::.~. ·_,:· --·:} ~ ·\::~ 1i3? :·;[s!i&f Jf{ !t-_::-_:;;~~ ~-;Jl ·:-~:~;:.;.~-:.t~: (q-.1/.?J.Y ';~ :.: L ~ ... t I! . 13 J 28 27 32 J 2.7 J 13 13 7.7 5 of 18 - - - - CHEMICAL ALUMINUM. ANTIMONY ARSENIC BARIUM BERYLLIUM CAOMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESII.JM MANGANESE NICKEL POTASSIUM SELENIUM SILVER SODIUM TOTAL MERCURY VANADIUM ZINC - - - - ---- - - - GP021SLA GP021SLB TABLE 2-4 SOIL SAMPLING SUMMARY· INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP022SLA GP022SLB GP023SLA GP023SLB GP024SLA --- - Section 2 Soll Sampling Investigation GP024SLB 5400, . 2~0~ , ijog l : ·;r t~·~901fiH1f '{ 1Hi111l,h7,,_: '11f. :26q/i Jf/ : , . '47.00,.-. · · ·. ·. 3000 . 1.2 U 2 U 0.76 UR 0.65 UR 0.75 UR 0.77 UR 2 U 1.3 U 17. t1 •· · ~.Y :,',' •~rr-:r.1~2·.~:{{,,"J:~ji/.,·:~·.:;~A•::,:,:-/:' '. 7,2 ', '·.· .:1.2 57 33 31 38 200 130 230 39 ., ! y g.~1\!. ·o.s J ....... q.-iJ,1:'i:fJ:1:~:Q,Q§iiJ'~L'.L:c., . .9J>_a u<·.,~\:::Lsu .· .... Q.~6 u 0.23 U 0.21 U 0.18 U 0,16 U 0.18 U 0.19 U 0.27 U 0.26 U 2000 12{)g_ , . 2ioq J.'.,,:, ,. /3!Jth,-t';J,f:??OtJQ)"'''~:~'.:;Mo.P.ib:/;' ·,:j3000 ·< ·. •· 44000 .•· .· &3 11 S6 14 8 S6 6 ~6 1.6 J. (!,IJ J ·:· 1f,i_ _, '·',1!~J.f./'•J~i/: ·2.~ ,! :.·:/'J/1...:i_·:::~:,.-·,.2.9 J. ·'· .. 1.6 J 6.4 2.7 J 1 UJ 4 UJ 7.7 J 5.9 J 20 12 8200 .. f 2690. 52g9 J• ··Ei1oq,:T::':.:. 4ti9.o,).;/ '·'4?7JQ_J: ~.. ·:4909 . 5500 23 J 3.3 J 14 J 17 J 11 J 9 J 28 J 21 J 4Q. 1~0.-' 3~1) '.:,·, ·,37g_._',,,,-~;{•~~ft;,: ., •. :_1:j[ii'>c;'-·,:-" !fro· 880 92 39 21 21 410 250 370 96 3 u •. , 2 u • o.~'f ,1_ : .• •·, .• 1r~. ~' '''.·£::.~,;~~:_:.; -!. : 1·J,' ;,g)·,,,i, ·,'L: ~ u ' · · 3 u . 230 J 55 J 80 U 150 340 550 1300 J 250 J 1-'.~ .~·Jf? --,.~:) -µ :. ; •'.)· .-' .:Q;t§·:R. _,. :;,;~J-~~3f.£IT, ~::st~t~t-r~·.QJ7.~_(J}j\:I•t;~~Q:Z~·.1l.-::/~-.~::\._{J.~1.~ ~q: ... -~-:.-. ___ 1_} u 0.46 U 0.41 U 0.31 U 0.26 U 0.3 U 0.31 U 0.54 U 0.53 U · 1~fi.u -?>.: ; s.Q .1.1 • ~, .• • :~ !!Cl V;, .:;;;{,:,·::Ezl.\ P.ilt'.:,c,.i:i,;,: §Ql}o:,I 2fI1iQIQi,\:. : . ';:,~s_o 2;;< c': ·J!!9 y . 0.12 U 0.1 U 0.06 U 0.06 U 0.06 U 0.07 U 0.14 U 0.13 U -'if.::~_-.:;:: .-.,:}s."i:.~\:: -/:-:;-_.~::.-.tt)t:_~~~£.:~~;:f!I~:~;~2Jlt·r:·~~:-J)~;;:J/:~it?~r~:~~-t?\l:t~r~d 1~-)_ .-.:~ :.~; i:i ~ u ~9 a2J 12J aJ UJ ~J 47J 6 of 18 --- - --- - ----- TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA --- - - - Section 2 Soil Sampling Investigation GP025SLA GP025SLB GP025SLC GP026SLA GP026SLB GP026SLC GP027SLA GP027SLB CHEMICAL ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM. MANGANESE NICKEL POTASSIUM SELENIUM . SILVER SODIUM TOTAL MERCURY VANADIU.M-. ZINC 310§ •, 1.1 U 1J· . 66 1 \L 0.21 U 65(!0.- 6.1 '•1,8 J ·.~,--,~3°toQ;~:-~~.;,·-\··~)4Q<? ); t·~~i-: :·~9.Q~f~}i'~~i{?l§fi~~:.;~:r~\::}?Ji[ii __ 1?'.i•}:,':~--~~'I~"@ti•-\~~ : , T--_ -"2s6o 1.1U 1.2U 1.1U 3U 1U 1.1U 1U ·_ ~ u· ~-~\ ;<·,.~-:t.:~. -~'."tlr.·;f.f~~~tt:;f<tit·~~::i~'.-·1··-:t~r:q_:~t-u·.,~:-:\:?~::·.~;_:~ -t.Q -.. , 1.6 J: 60 34 45 1500 44 33 36 •' -. ,j g_:_-;:c • --~-I-Q.• ·· ",/LrLJ.':8TI\~'iJiC:,;,':,X/:/qJfy:·>;:0-'\:~~-.'.:1:\L · · · 1 u· 0.21 U 0.23 U 0.22 U 0.3 U 0.21 U 0.22 U 0.2 U i'ipo, ,,, ; , · . !150.·.i, .· -.-~1§9.::d"f,,.-;.\11tigg'Q ·" ;,_, .. 21gq_,f(-:Ijt,·:f2_oq ::;:·, 1000 ; · 3.3 9.1 4.7 8.8 3.7 5.1 2.3 ."-··-; j .:· ... ~<-, .',~}_·~,,_'. ::-_ < · ~ ~\~1(:i_;;~.:.:i-~:;.;= ::~~"1:"i-1~{/J ·.-.·o;~t~, ·~::{;~·::l·;_ :~'..f~ .l· .,;:· <~);-_ · 0.6~ J 16 3.3 J 3.2 J 8.3 64 3.3 J 7.1 2.3 J 520.§. -~ii_iio -; :·:.: 1_2qoo. , ,_ • s2-qo. >i;'};_, i~q·L-~J:., .. :: ~61/<f:'. · /::,r·~:iqq ;:_ . c . _26oq 22 J 8.8 J 5 J 18 J 43 J 3 J · 15 J 6.1 J 6q_q /: ·-'410 : .-·_.471J,(-;.;.i·, :'?~.f':tt·'.?,~.fiii_ii_ ,:::{iii~::. ~~!i,;•~•'··':et· ,t~iig :: , •/ jqo •·. 170 59 84 170 3400 100 150 120 .-;~2-u · : · . _;~-~-2-.tt '.-\··. ':i_; :··~:t·~iQ~~,:.::t .. -'! .···-C.t~-!~1;::~~~Jtt i§.l: .. ~~¥.:4~Fr:~--·:::7 Lfj/~f:TJ(~::~: __ )-·Q_·.: t:·-"'·-::< :!.~·-2 u· 350 J 350 J 360 J 610 J 3900 J 130 J 970 J 210 J ' ~:1·:-:1. !d;;: ~:-: :-_~-1·.j Q".1 ~~,, :: '-~·:i::1-~?. :Q:{·::~~;:_:::: ~----.. ~1j,a[l1!~~Jtfi).{F~:LJ"7::,i}!L;:(·f :?I:Q .. =E'fi['_L_:~./~t1·-~); .. 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Q ·::s'i ~-q _ld 0.11 U 0.11 U 0.12 U 0.11 U 0.05 U 0.1 U 0.1 U 0.11 U 8 of 18 --- - CHEMICAL ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD !'v1AGNESIUM. MANGANESE NICKEL. POTASSIUM SEL.ENIUM SILVER SODIUM TOTAL MERCURY VANADIUM ZINC ...,, -- GP030SLB GP030SLC - - ---- TABLE2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA - GP031SLA GP031SLB GP032SLA GP033SLA -- - - - Section 2 Soll Sampling Investigation GP034SLA GP034SLB 9 of 18 --.. CHEMICAL ALUMINUM. ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SELENIUM SILVER SODIUM - TOTAL MERCURY VANADIUM ZINC --, ~ --- ---) - - --- - Section 2 Soil Sampling Investigation TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP034SLC GP035SLA GP035SLB GP035SLC GP036SLA GP036SLB GP036SLC GP037SLA · 3~qq· ::: .)_:·-~, : ~3!'9~::~r£ ·::~ :;~ -~ .s4.qq ,,. ~ :~~i~~z_:~~:-~·1]~~;i.~<i!i~i6oq:3~~; ;r:::-·:~J~Q.-'/~~~;:2r·E~~~3-~~!2.~ ... rs:-~! ~ ,,_:. :-.~~if9-... L2 U 1.2 U 12 U 12 U 1 U U U 1.1 U 2 U a·. 94 LJ \ · ; ~ : ·<\~. ~t ·. __ ";_ ~j ,/:--~~~:J .. ,(:•3. ·:.~! ~:~:i~~f!J:{iJ'f :·_:: ~ §:·~·t:F~-;-t~; .f.f ·:• -_.'i i .1\-l,~-f-t.; t:\~~ /~;:· :~' l.f \:(.:_: -· ~: ·}: ~ J . 260 35 150 340 17 34 32 40 _ ·::1_ ~ <1:~~ ~?;:::-::, .-Q:~fY \~r ~:t:1_·cr~~---:tf::~~:x:-.~~~tfPE!)t-:~~{:}:::~:·:_-flt-:/':~~;~?t ::_) 1.r~:. 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ZINC - GP037SLB GP037SLC --- TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP038SLA GP038SLA (Duplicate) GP038SLB GP038SLC -- - - Sectlon 2 Soll Sampllng Investigation GP039SLA GP040SLA : 43fJQ . --.. < : _:4Bgef.i ½~~!{·,,,·: .:-~ ,.-~!tfQ '}!'\~_-,:~I: ~ ··:)~QQ;,·f~RiltPiQQt:~~~;~~rf ;~:~~q-~Jt:,~~·I:;;~::~ti~i(~·: -i-=. ·. ·• :t~Too J 1.1U 1.1U 2U 1.1U 1.1U 1.1U 4U 2UJ Q.?_g·:u~~,,:;:.: :-·.: ~ ·1:.tJfi{~<.··,~ ·: .. ::_f~ :~::1i;~~\:\,-t-~)!.t:}~;:~~f~!l~)'1:~~2,LJ2.t·'.·-.~-:o~~~-~!d{;.~ .. ;/lit.~ ~Qi-~~-\t; -~-~~-_: . -~~2 · · 83 35 76 82 33 23 290 110 ''.:1._lr~--~--:_,_. cL:r.t:g-_f(::•·. : ·j ·q,~,,:.u:_:·:;'_1 _N:\ .. 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TOTAL MERCURY VANADIUM ZINC -·-- GP040SLB GP041SLA --_,_ TABLE 2-4 SOIL SAMPLING SUMMARY • INORGANIC$ GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP041SLB GP041SLC GP042SLA GP042SLB ---·-Section 2 Soil Sampling Investigation GP042SLC GP043SLA ~~i!P.:'\J·:c:;;_ :; ~.': :/t4~Q JI?jtf::; e ~ \•::~fQQ,:;f;.:: f :~r.~ t;i~P{(~;;£~fl~~'!{~~[tf '.C~f~tii¾;~t~]~?f l!iift{:.:~~:!i§.OO;~: t~• • :~> •~B1JiO ~-. ·: • 0. 71 UR 1.1 U 1.1 U 1 U 1.3 U 2 U 1.1 U 1.1 U .,_ r ..... ::i-· ~-:,~:-\ ).;~:·~JfC~·· · .. ·_: r:~:__~~f~ }ff~.}. ~;o_j~::tJ.f~Yltt:J.i:?~t.it~t:?:J/: ... :'J!~;_.~;_1~Jfi~l: f.1.:~f:J_ ·>.: t· ::•~ ~-1.· :· 32 180 160 19 65 120 19 360 o:'1_~ d · ·: · ~_\Q.li.ht:·/:. ··::-:·-. 'l ~ ,:-,..: 5·. ·,"Qif'!.fft![J_;~Q:]?.:yJfil{:.}':?~J;,:uJ7_JiC~i ~iJ..!t-~ ~-·/; _-· _ 1 .u 0.17 U 0.22 U 0.22 U 0.21 U 0.27 U 0.22 U 0.21 U 0.23 U · . 811.Q!J'. 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CHEMICAL ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SELENIUM SILVER SODIUM - TOTAL MERCURY VANADIUM. ZINC _,, --- ---_, ---: ----Section 2 Soil Sampling Investigation TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP044SLA GP044SLB GP045SLA GP045SLB GP045SLC GP046SLA GP046SLB GP046SLC _:·6qq~r ·~:-:··: ->/~} .. 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MANGANESE NICKEL POTASSIUM SELENIUM SILVER - SODIUM : , , TOTAL MERCURY VANAD)U¥ · '" ZINC --- GP053SLB GP053SLC - - ---- -- - ---Section 2 Soll Sampling Investigation TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP054$LA GP054SLB GP054SLC GP055SLA GP055SLB GP056SLA 16 of 18 -- CHEMICAL ALUMINUM ANTIMONY ARSENIC. BARIUM BERYLLIUM CADMIUM CALCIUM ·'. CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SELEN.1~~ SILVER - SODIUM~ ..... TOTAL MERCURY VANADIUM ZINC - - GP201SLA GP201SLA (Duplicate) - -- - - TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA GP202SLA GP202SLA (Resample) GP203SLA GP204SLA -- - - - Section 2 Soil Sampling Investigation GP205SLA GP206SLA 17 of 18 --- CHEMICAL ALUMINUM ANTIMONY ARSENIC BARIUM BERYLLIUM. CADMIUM CALCIUM CHROMIUM COBALT COPPER IRON LEAD MAGNESIUM MANGANESE NICKEL POTASSIUM SELENIUM SILVER - SODIUM .· TOTAL MERCURY VANADIUM ZINC ----- -- --- TABLE 2-4 SOIL SAMPLING SUMMARY -INORGANIC$ GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA - - - - Section 2 Soll Sampling Investigation GP207SLA GP208SLA GP209SLA GP210SLA GP211SLA GP212SLA GP213SLA GP214SLA · 8§9.ifrtt~~-~~ ~:::':: .)·f Qir: ·: l t1~ \:.~ p1·oq~;;;~}~;.--fl%_J~f101!£l~lt~?10½'J~t;1:~./~{Zo.gQ:£ltit'lt:;J~pq_<··; :~-: -~ {·;.: .. 4.~~q ~· .' :. 2 UR 2 UR 2.1 UR 1.8 UR 2.3 UJ 2 UJ 1.9 UJ 1.9 UJ . ~.-J~:-i ~---~: f·: :: :~,)~> .:-b; :· ··f1 .. ;i_,:;~~~ -:?t?_~.,r1{~;(J~,t~ri1{:t:1·;QiiI•~t,~ :t·-~f2f~f J-t~r~:;,,i:/tt ~> ,'. -~-::_: ; .. 1.2 u-• 37 34 31 30 37 31 38 25 _. _.f ~(\~-•-•-~•.:_: ... ; ·J __ ~·:_.J~:> · <, J. g:./:.t~1{~.:;_._:d:1lt~sr:.:tf:1~~(·.1Ji.~{£H:2·:·~~~~;r~tf:!f·-\::.·ri:·~1 t.f'"_.;l ·::::·::-:_ -~.1 ~ 0.14 U 0.14 U 0.15 U 0.13 U 0.2 U 0.18 U 0.17 U 0.17 U 41oo·j T'·:Hbo_o_·_.·:1.· 1,ioa:i ... '"":fioo'J.·., .. :,:·~~·ssoa;i:;,;:,;,,,;·7soo·,'.:r:'",:·420 . .-'.·socio· -,-•-• "~ -~ -.-•. '1\,. "' •••~~•••.,,l, ' -••• .,. ~' "'••-" •-•• •- 12 13 15 7.1 26 14 4.6 6.8 · 1 i.i" .-{-·.:'. ·, .:_:··. ~-'1 .u ..... , .· . o:~t~Q ~-.i~~-/i ::~;~;Q:.ff.[tJ/(~:"~~Q;~li-.!-.L~[[~~l t9.?tf Jti:lJ::·:·9:1~ µ _-_'.-:~ o:1s -~ 5.7 7.1 6.2 5 U 5 U 4 U 3 U 2 U 1200g " , : .· : 1oqpg ,.\)) 1,~q!i: >.t: :.:: :.s1qt:.'~/~;;j:sj9.q,:_i:J,'.: :·:,:}·{l°Q.o,; .r::<_;:: ~'¥bi?' .. 2.100 :; 12 J 12 J 14 J 8.6 J 16 J 19 J 12 J 7.3 J 1!60 .,,;c ~-,. . 11~1? · • · :Gg_q_; f_: · /·~.:~~!!~ •~ ':;:}-_;:-j_iiJ .. ,; t6/~-' ;:~iQ:.''{:. . . .. '~gQ ·. ; .·., : 4~0 · .. ·. 100 85 58 69 81 79 97 54 1,ii / ,;.< \ 1,;; ,! , •. _,< !-.l_J;_ '· :·.:)t~I1/1I01E:{.'.fi ,:tf;ii': i.,ti~·d:-~\.'.:;-/;;jj _J. ,,j 2.1 J. 600 U 570 U 460 U 380 U 330 U 320 U 120 U 210 U a,~§ _95_,;;:· / ci:'7~. Q ,.-:\ 0~79 u, ,,:·1·:·:Yod;iJ,'-:.•::,i1;6's61J .·.· ·: :!7.'®5---;u,,;; ;., :;.:.0.12 u ~/ --\Q.7~.u. . 0.46 U 0.45 U 0.48 U 0.42 U 0.52 U 0.45 U 0.44 U 0.45 U · 1~lj il:;:·•~::.:·, )~9-lJ' : •:•: .· ·196 t:f; :,,."(t•<-,{fi:o:iJ:·J''.';l•1,~::2'fo u1:c: ,;:~,:,c•~w;tY'. :· .. )§~ lJ_ .Jso u 0.05 U 0.05 U 0.05 U 0.05 U 0.06 U 0.05 U 0.05 U 0.05 U ... :.2~; :h.~ ~ _ _.~\;ii~~;~'-·~~'.==:··· .l.if :~;;~~~t?1:·~~~1J~:rr.f;~ri~tlt:1:c~f~~~it1~~-ft1:_-:~~),.tt~::~ _LL .. · ·;·~~·--.-··-~ !~ /_. ~J UJ nJ 19J U ~ 12 18 18 of 18 - i i I I I I I I I I I I I I I I I I I I I Volatile Organic Contamination Section 2 Soil Sampling Investigation The RI investigation soil sampling results did not reveal significant contamination of volatile organic constituents in surface soils or to the sampled depth of 52 inches bis for both onsite and offsite soil samples. Seven volatile organic constituents were detected with toluene and carbon disulfide being the most prevalent. Toluene was detected only as an estimated value below the detection limit of the analytical method. Carbon disulfide detections ranged from estimated values of 2 to 810 µg/kg. The estimated concentration of 810 µg/kg was detected in GP009SLB. Other carbon disulfide concentrations were significantly lower. Chlorinated volatile organics were detected but were only an estimated concentration below the method detection limit. No areas of significant volatile organic contamination were identified either onsite or offsite based on this data. Extractable Organic Contamination The extractable organic compounds, predominantly the polynuclear aromatic hydrocarbons (PAHs), were extensively detected in surface and subsurface soils throughout onsite and off site soil. However, most of the detections highlighted in the tables were below the method detection limits and reported as estimated concentrations. Some of the soils contained concentrations of the carcinogenic PAHs ( cP AHs) near or an order of magnitude above the detection limits. The highest constituent detected was pyrene at 18,000 µg/kg in the soil sample collected from GP044SLB. Samples from GP044SLB, GP046SLB, and GP049SLC all contained PAHs. Offsite locations GP201SLA, GP202SLA, and GP214SLB contained P AHs just below the method detection limit. However, locations GP202SLA (resample) and GP214SLA both contained a signficant level of PAHs with the highest concentration of fluorene at 9100 µg/kg in GP214SLA. Figure 2-2 shows the depth intervals and concentrations of P AHs and cPAHs detected above the method detection limits for onsite soils. Figure 2-3 shows the concentrations of PAHs and cPAHs detected above the method detection limits for offsite surface soils. Figure 2-2 shows the areas of the site as potential areas of significant P AH contamination. These areas were typically located in former process areas centrally COM ·Federal Pmi:nuns Corpor.iclon SPIINB2/SEC2.WPD 2-77 I I I I I I I I I I I I I I I I I I I A A B C \ o B 14 B ,--;-:ra,-, .I 49 A A 0 300' ----- C 600' Georgia-Pacific Hardwoods i Pl mouth, North Carolina t:i---,;-==~----------1 N c:::::J C 0 [ LEGEND: AEl&E PAH & cPAH's IN ug/kg DEPTH INTERVAL A <, \ \ ) V GRID -···-RIVER ~ TREE LINE ~ RAILROAD PAH and cPAH Detected in 0nsite Soils Figure No. 2-2 ~ CDM Federal Pro2rams Corporation .__,., ____ .._ 7/00 ~L----------ii,,,.._ __________ _ -____ !ml, ___ _ I 111111 .. - 0 .1· I 1· .. /·· 250' Roanoke River .. /· ./· 500' ------• I i Georgia-Pacific Hardwoods ~ Pl outh, North Carolina ~ COM Federal ProJll'Olllll Corporation I A.....,..,Qiipa--~ ..... QP-21D-SI.A 210. BE/\ ■ ,~ ~210d .,,. .,,. OP-212 ~\.~:::::-, I LEGEND: . I . . . ~-T .• 2110 □ Em3 I PAH & cPk Detected in Off~ite Soils I .. -- --- N D D D D D D SURFACE SOIL SAMPLE LOCATION GRAB SURFACE SOIL SAMPLE LOCATION D D D D PAH & cPAH's IN ug/kg RIVER TREE LINE RAILROAD Figure No. 2-3 7/00 I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation located on the Georgia-Pacific property. The lateral extent of the PAH contamination was not significant beyond the site property. However, as Figure 2-3 shows, there were areas offsite which had low PAH contamination. These offsite areas were located adjacent to the site where airborne or surface runoff could have impacted the soils causing these areas of contamination. Downward migration of P AHs into the shallow groundwater could have occurred since some of the subsurface samples collected showed P AH contamination. See section 4 for the discussion of PAHs in groundwater. Prior to initiating the removal action, the P AH analytical data were compared to the SSRALs established for the site. Only Grid 44 exceeded the SSRALs for Total PAH. The SSRALs for cPAHs was also nearly exceeded in Grid 44. Pesticides and Polychlorinated biphenyls Trace levels of chlorinated pesticides were detected in the onsite and offsite soil. The most frequently detected pesticide was 4,4'-DDT with the highest concentration reported as 69 µg/kg in GP019SLA. However, PCBs mixtures were detected at significant levels in several samples collected onsite. None of the offsite soil contained PCBs. Aroclors 1254 and 1260 were the only PCBs detected with the highest concentration being 13,000 µg/kg of Aroclor 1254 in GP046SLC. Also noteworthy was that the level of Aroclor 1254 at this location increased as sample depth increased. (GP046SLA -410 µg/kg, GP046SLB -3300 µg/kg, and GP046SLC -13,000 µg/kg. Groundwater is just below the SLC sample depth. The next highest concentration of Aroclor 1254 was detected in GP017SLB. However the 3200 µg/kg of Aroclor 1254 was not detected in the duplicate from the same sample location and depth. The highest concentration of Aroclor 1260 was detected in GP044SLB at 2,800 µg/kg. Figure 2-4 shows the depths and concentrations of PCBs detected above the method detection limits for onsite soils. Contaminant levels of pesticides and/ or PCBs did not reveal any significant source areas on or off the site. However, Grid 46 PCB concentration did increase with depth COM Federal Proi;:mms Corporation SPIINB2tSEC2.WPD 2-80 I I I I I I I I I I I I I I I I I I I ')er 0\ \JRoonoke \) River A B B B N 0 300' 600' Georgia-Pacific Hardwoods t Pl mouth, North Carolina ~1-,.;,,;;~;.;... ........... _____ __, N I [ A 1~::~~ ~i~ PCB's IN ug/kg DEPTH INTERVAL ND NON DETECT A < 1 \ \ > GRID V --···--RIVER ~ TREE LINE ~ RAILROAD PCBs Detected in Onsite Soils Figure No. 2-4 ~ CDM Federal Pro£rams Corporation ,_., ____ .._ 7/00 ~a__ ______ ___,1,, _________ ,______, I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation which would indicate a downward migration into the shallow groundwater. See section 4 for discussion of groundwater sample analysis in or near Grid 46. Dioxin/Furan Chemical Contamination Varying concentrations of dioxins and furans were detected in all the samples collected both at the surface and in the subsurface soil. This was for both onsite and offsite sample locations. Octachlorodibenzodioxin (OCDD) was the most frequently detected dioxin and had the highest concentrations. The highest OCDD was detected in the sample collected from GP040SLA and reported as 10,000,000 ng/kg (equivalent to 10,000 µg/kg). Other dioxins and furans were also reported in the sample from GP040SLA and the toxic equivalent value (TEQ) was estimated at 27,000 ng/kg. The TEQ is calculated to normalize the toxicity of the detected dioxin-like compounds to the toxicity of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD), the most widely studied and most toxic of the dioxins. Each dioxin-like compound is assigned a toxic equivalence factor (TEF) as defined in Interim Procedures for Estimating Risks Associated with Exposures to Mixtures of Chlorinated Dibenzo-p-dioxins and Dibenzofurans (CDDs and CDFs) and 1989 Update (EPA, 1989). The TEQ is the sum of the concentrations of the dioxin-like compounds multiplied by their respective TEFs. The TEQ reported in GP041SLA was estimated as 28,000 ng/kg with OCDD detected at an estimated concentration of 8,100,000 ng/kg. The other grids which contained notable concentrations of dioxins and furans included: GP037, GP039, GP041, GP046, GP047, and GP051. Samples collected from GP046 showed TEQ increasing as samples were collected deeper from 11 ng/ kg in the GP046SLA, 97 ng/kg in the GP046SLB, and to 1300 ng/kg in the GP046SLC. These concentrations were estimated. However, the TEQ concentrations decreased with increasing depth in the three sample intervals from GP041, GP051, and GP053. Figure 2-5 shows the TEQ values for the surface soil locations where the TEQ was greater than 100 ng/kg. Figure 2-6 shows the TEQ values for the subsurface soil locations where the TEQ was greater than 10 ng/kg. The samples collected in the neighborhood contained dioxins and furans. The TEQ concentrations in the neighborhood ranged from non-detected (quantitation limit of CDM Federnl Pmi:rnms Corporation SPIINB2/SEC2.vVPD 2-82 I I I I I I I I I I I I I I I I I I I 0 - - Roanoke River 300' - - - 600' Georgia-Pacific Hardwoods Pl outh, North Carolina I c:::::i N LEGEND• SURFACE SOIL TEQ IN ng/kg ~-::-g 100-1,000 .. -~ JI_IJI:, 1,001-10,000 (NOT DETECTED IN THIS RANGE) 10,001-100,000 GRID RIVER TREE LINE RAILROAD Dioxins and Furans TEQs Detected in 0nsite Surface Soils Figure No. 2-5 ~ COM Federal Prol!l'IIDUI Corporation ._ ... .,_,_~--7/00 IL-______ ...L.. ________ ........__ I I I I I I I I I I I I I I I I I I I 0 'B Roanoke River C~I=□~ e5J□i-~r-----..._ 300' - --- - 600' Georgia-Pacific Hardwoods I 1-.:P.:l.:;;;;O;.;u;;;t.h=•-N;.;.;;o .. rt.h,;;;;;;..,;C;.;ar;;.;o;;;li;;;;"n;;;;a ... -l N c:::::i / [ ,~BfiB DIOXINS & FURANS IN ng/kg DEPTH INTERVAl.S NA NOT ANAL YlED GRID -----RIVER TREE LINE RAILROAD Dioxins and Furans TEQs Detected in Subsurface 0nsite Soils e No. 2-6 ~ COM Federal Pron-ams Corporation ,_.,.,._.......... '7/00 ~L.-_______ ..__ _____________ _ I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation · 1.9 ng/kg) to 36 ng/kg. The sample from GP205SLA contained the highest TEQ of 36 ng/kg and the highest concentration of OCDD of 27,000 ng/kg. The analytical data and Figures 2-5 and 2-6 show the general areas of dioxin and furan contamination potentially occurring from source areas on the site. Other dioxin and furan concentrations were below the site source area levels. In addition no significant downward migration is evident in the data collected. Grids 40 and 41 were selected for excavation during the removal action due to exceedance of the TEQ of 1 µg/kg (1,000 ng/kg) SSRAL. See the Post Removal Data discussion below for further discussion of the selection of grids requiring excavation. Inorganic Chemical Contamination The following table summarizes the ranges of concentrations in mg/ kg of metals detected in the surface and subsurface soils collected onsite and offsite. ONSITE OFFSITE Metal Minimum Maximum Minimum Maximum Aluminum 520 16,000 2,900 11,000 Antimony 0.55 600 1.6 260 Arsenic 0.82 83 1.1 18 Barium 2.6 2,200 25 120 Beryllium 0.07 2.5 0.22 1 Cadmium 0.13 3.3 0.13 0.22 Calcium 210 130,000 420 21,000 Chromium 1.3 270 2.8 26 Cobalt 0.44 24 0.72 2 Copper 0.43 260 2 17 Iron 300 48,000 2,400 13,000 Lead 1.4 3,300 7.3 2,300 Magnesium 54 9,500 200 890 Manganese 2.5 3,400 54 260 Nickel 0.65 310 0.77 4.3 Potassium 18 17,000 120 600 Selenium 0.59 1.6 0.7 1.1 Silver 0.22 270 0.34 0.55 Sodium 50 4,500 130 220 CDM FederJl Proi;n11ns Corporation SPIINB2/SEC2.WPO 2-85 I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation ONSITE OFFSITE Metal Minimum Maximum Minimum Maximum Total Mercury 0.05 4.4 0.05 0.11 Vanadium 1 110 4 25 Zinc 1.8 1.000 12 72 In general, the onsite soils showed higher concentrations of the nutrient metals; calcium, iron, potassium, and sodium, than offsite soils. Aluminum was the other metal detected at a significant concentration however was similar to offsite concentrations. Other metals were detected at higher concentrations at individual grid locations compared to the site average concentrations. Arsenic was detected in grid sample GP049SLA at a concentration of 59 mg/kg and at a concentration of 83 mg/kg in GP049SLB. The highest concentration of arsenic detected in an offsite location was an estimated concentration of 18 mg/kg at GP202SLA. Barium was detected in GP049SLC at a concentration of 2,200 mg/kg, whereas the highest concentration of barium detected off site was 120 mg/kg in GP206SLA. Chromium was detected at 270 mg/kg in GP039SLA whereas the average concentration of chromium including offsite was less than 15 mg/kg. The highest concentration of copper was also detected in GP039SLA at 260mg/kg. Lead was detected in GP046SLC at an estimated concentration of 3,300mg/kg and in GP202SLA (offsite) at an estimated concentration of 2,300 mg/kg. The lead concentration increased with depth for the samples collected in grid GP046. The majority of soil samples collected onsite and offsite contained lead concentrations less than about 50 mg/kg. The highest magnesium concentration was detected onsite in GP056SLA at 9,500 mg/kg. Another metal with a significant high concentration was zinc, which was detected in GP046SLC at an estimated concentration of 1,000 mg/kg. At this sample location the zinc concentration increased as the depth increased which is similar to the lead concentration also at this location. In addition, zinc was detected in GP049SLA, GP049SLB, and GP049SLC at concentrations of 900,840, and 900 mg/kg, respectively. Most of the other soil samples both onsite and off site contained zinc concentrations CDM Federal Pmi:rams Corporation SPIINB2/SEC2.W'PD 2-86 I I I I I I I I I I I I I I I I I I I Section 2 Soil Sampling Investigation less than 100 mg/kg. Figure 2-7 shows the onsite sampling grids with the highest detections of metals other than the nutrient metals. Post Removal Data Table 2-5 presents the detected contaminants of concern from the removal action confirmation samples collected by BBLES. EPA reviewed the RI data ·and selected grids for excavation. The method of selecting grids for excavation was based on elevated contaminant levels of various constituents as well as physical evidence of former site activities. Elevated concentrations of dioxins, furans, (expressed as TEQ), metals, or PAHs were compared to the SSRALs established by the EPA. Metals, dioxins, furans, or PAHs were evident as the primary contaminants in grids 39, 40, 41, 44, 46, 47, and 49. These grids were selected for excavation along with an area along -the southern portion of the site which was formerly the asphalt mixing plant. However, later focused sampling of the areas of the former asphalt mixing plant did not reveal any contamination exceeding the site specific removal action levels. A more detailed discussion of the reasoning and methods for resampling these grids was provided in the Removal Action Summary Report. Following the excavation and off site disposal of the soil, samples were collected from the bottom of the excavations to confirm the adequate removal of the contaminants. For grids 1, 2, and 3, only the arsenic concentration from the RI data slightly exceeded the SSRALs. Upon recommendation by Georgia-Pacific and concurrence by EPA these grids were resampled prior to the removal action. Table 2-5 above provides a confirmation that the targeted constituents were removed. COM Ftdernl Pnl):nnns Cnrpurmion SPIJNB2/SEC2.WPO 2-87 I I I I I I I I I I I I I I I I I I I A B C 0 As B N Roanoke River ,Pb Zn A ~~6>.:t(::+:~i;Jl,"JP BC tf1 ~O!QJill!.QO!Q!O!bJ d_ 00J 1000J A Cr Ba N N Cu Zn 300' ---600' Georgia-Pacific Hardwoods J ._...;,P.;l.,,;,;m;,;,o,,;,u=t;;,;h,:,., _N;,,;,,;;o,,;,r,,;,th ___ c_a_r_o_I_in_a_, I LEGEND: Cr A I 27□ I NA A <, \ \ ) V 0 0 [ METALS DEPTH INTERVAL NOT ANALYZED GRID RIVER TREE LINE RAILROAD N Metals Detected in Onsite Soils Figure No. 2-7 CDM Federal Proarams Corporation ,,_.,_,,_ .... "... 7/00 ~L.,_ _______ _.___ ___________ __, e 1/ - - -- CHEMICAL Pab'.1:bl2[illated Uilu:niodiolinsl'.Dibenio[ucaos (ne&e) HeptaCDD HeptaCDF OctaCDD OctaCDF 2,3, 7,8-TCDD TEQ (SSRAL = l µglkg) Polrnuclear A[orn~tk lil:'.dtos:atb:ons (uelke) Fluoranthene Pyrene Benzo(b)fluoranthene (cPAH) Total PAHs (SSRAL=l00,000 µglkg) Total cPAHs (SSRAL=50,000 µglkg) Pentachloroohenol (ne/kel Pentachlorophenol (SSRAL=25,000 µglkg) Jnoreanits (mg/kg) Arsenic (SSRAL=30 mg/kg) Chromium (SSRAL=200 mg/kg) Lead (SSRAL=400 mg/kg) Notes: cPAH = Carcinogenic polynuclear aromatic hydrocarbons PAH = Polynuclear aromatic hydrocarbons NA .. Not analyzed ND =-Not detected SSRAL • Site-specific removal action level ---- - - TABLE 2-5 REMOVAL ACTION CONFIRMATION ANALYSES GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA !irill..ll !irilUlt !iri.!!..il !irill.M -- ~ ----Section 2 Soil Sampling Investigation !iriU1 !i.rilU2 CONF-39-COMP CONF-40-COMP CONF-41-COMP CONF-44-COMP CONF-46-COMP CONF-47-COMP CONF-49-COMP NA I.I 1.2 u NA 1.3 U NA NA NA 0.55 1.2 u NA 1.3 U NA NA NA 0.7 J 1.6 UJ NA 1.7 UJ NA NA NA 1.6 UJ 1.7 UJ NA 1.8 UJ NA NA NA 0.017 ND NA ND NA NA NA NA NA 200 J NA NA NA NA NA NA 220 J NA NA NA NA NA NA 180 J NA NA NA NA NA NA 600 J NA NA NA NA NA NA 180 J NA NA NA NA 3040 UJ NA NA NA NA NA 16 NA NA NA NA 1.4 10 33 J NA NA NA NA NA NA NA NA NA NA 7.8 NA NA - I I I I I I I I I I I I I I I I I I I 3.0 Surface Water/Sediment Sampling Investigation 3.1 Purpose and Scope Surface water and sediment sampling were conducted in the intermittent drainage ditches located onsite to determine the nature and extent of contamination in these areas. Three surface water and seven sediment samples were collected from the drainage ditches. The locations of all the sur ace-water and sediment samples are shown on Figure 3-1. Note that it was intended for both a surface water and a sediment sample to be collected from each sampling location. In four locations, however, there was insufficient surface water to collect samples. 3.2 Methods All surface water and sediment samples collected were grab samples and were collected according to the procedures established in the Remedial Investigation Work Plan (EPA, 1998) for the Georgia Pacific Site, and Section 4 of EPA's Environmental Investigations Standard Operating Procedures and Quality Assurance Manual (EPA, 1996). The surface water samples were collected from several inches below the air-water interface and sent to a CLP laboratory for analysis of all TCL/TAL constituents. Sediment samples were collected from the zero-to three-inch interval below the water-sediment interface and sent to a CLP laboratory for analysis of all TCL/TAL constituents as well as for dioxin/furan analysis. 3.3 Summary The analytical results for the surface water and sediment samples collected at the site are summarized in Tables 3-1 (surface water), and Tables 3-2 through3-4 (sediment). Note that for the purpose of summarizing, only chemicals detected at least once in each medium and their measured concentrations are presented in the summary tables. The complete data set of analytical results for the CLP laboratory analyses performed are provided in Appendix A. CDM Federal Programs Corporation 3-1 I I I I I I I I I I I I I I I I I I I 0 - --- Roanoke River 300' 600' Georgia-Pacific Hardwoods ~ Pl mouth, North Carolina E ~"'----------.......... -----1 ~ COM Federal ProKrams Corporation ~ A subsidbry al ~ ,i,_. • Mi:i"N h:. LEGEND: SW-01. ,--..,....,, N SURFACE WATER SEDIMENT SAMPLE LOCATION 3 ~ SEDIMENT SAMPLE LOCATION RIVER EDGE TREE LINE ----PROPERlY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA Surface Water/Sediment Sampling Locations Figure No. 3-1 6/00 - ----------------- °P CHEMICAL VOLATILE ORGANICS INORGANICS Pata Qualifiers TABLE 3-1 SURFACE WATER SAMPLING SUMMARY GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA SW-3 SW-3 (Dup.) SW-4 U-Material was analyzed for but not detected. The number is the minimum quantitation limit. ---- SW-7 Section 3 Surface Water/Sediment Investigation Concentrations presented in ug/L. Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. I - -- --- CHEMICAL ----- --- TABLE 3-2 SEDIMENT SAMPLING SUMMARY -DIOXINS/FU RANS GEORGIA-PACIFIC SITE SD-1 PLYMOUTH, NORTH CAROLINA SD-2 SD-3 SD-3 (Dup.) SD-4 -- SD-5 - - - - Sectlon 3 Surface Water/Sediment Investigation SD-6 SD-7 jti;;i:;#;~;ri~;8ge;rA¢.$i;i:\(l.QR!l\!ili?9P!P&N j . . ~®urn mml!it1®f MtOO!li/htmM w \iadlt'' ' "' 'iJ®ll . ; ·.· >'. . '.190 WtQ ·······•·i!®ll·• 1,2,3,4,6,7,8-HEPTACHLORODIBENZOFURAN 2400 J 970 J 730 J 580 J 2400 J 9.4 U 9.3 U 470 J 1@@,l!i1Vkl!!Bgl'lfAWB@lRQi?i1}~¢lWM!\lT!I'H :?1-10; tlti! ••·<·•·:54; ·•·•·•·•·•;·•••·••·< Wr<•·••••; t•Mfi's/il ••·••··•······················· •4:itu ...•.... ·.·•·•·•·•·•·····•·• Dl7rn \~iii# 1,2,3,4,7,8-HEXACHLORODIBENZODIOXIN 94 J 40 J 63 J 44 J 290 J 4.8 U 4.7 U 34 J w~~A!r;jli!i/~BJ\9899i~l(j,jg,q/;Q!l§f:1El[;.ttJ#: •• iii';! ; ;;; ;;3o;tc;• ::;;:n;v;;r: Leng; '. ·;•;t4)KU ' 4'.'/FlJ.'.'.• >• ••11'/Y 1,2,3,6,7,8-HEXACHLORODIBENZODIOXIN 380 J 150 J 210 J 160 J 1000 J 6.9 J 4.7 U 160 J ti~ti&itili!B§iA¢Hli9RQ@l~.~j,jgtjj\QB#f:i is§)W t\C·•··•3a J' ····················•rn•i~tr::L············· :·~~!H•W •)Tr;ifE••·•w C Ai!F\l :: ;: i!?!l'.'.ZTL : ~§i!!A1 1,2,3,7,8,9-HEXACHLORODIBENZODIOXIN 200 94 120 82 460 8 4.7 U 92 J }@:~ltl4~B$/bCHAQRQJ:!lID.1!il\i'.QfQ@\@. : Wtm • M~J!!B j II~\!I9/£Il} i lt!Ll ;. @~\UR Tl i H~Q till' t ; !!(~ @l • l nn i\7 !#'{ irt @Q\l!B 1,2,3,7,8-PENTACHLORODIBENZODIOXIN 48 19 J 34 J 21 J 160 4.8 U 4.7 U 23 J g~j;i)ti!liR~HtM'i!f@lffl.QpJ~!;l>!tQi\QMl'/1 ...• ·•······ .. )9./!\t ••••·• ·;,::ra:7• ······•·•·••·'lliiif••···•·····•·•·····•·· •L.;5;4A}Lit O •js .• r;r;;;.(; W!k~KliFJNW:iU•Aiilmifff•i@hsoiui!j' 2,3,4,6,7,8-HEXACHLORODIBENZOFURAN 61 J 27 J 34 J 17 J 79 J 4.8 U 4.7 U 16 J ~1$)#;1i!¾efillIAQB~QRQQ!fl~NZ9iH!!!!§i.i . .,; ;: ;; :; 2'/J/ j I%¥HW1ff Wi G•&/Pil •· ... •' • a Ji ; . ;• : Jq:'J;;;; • . ;4;a;u, • ;; ;<• A%U•;•• •.;. . : 6;1;;( 2,3,7,8-TETRACHLORODIBENZODIOXIN 8.7 3 J 4.3 J 1.5 J 16 J 0.21 J 0.21 J 12 J kl~izilifm@&j@QA¢Rl@N?.RRllflAN1ffi,fff1 ,!!@::;m :r:n::•:::n~i,tl!tn:•:n •.• s,1; u · ·, ••• • ·••• •• ,,.,3u• • •·· • •r·;12Mz••· .-, •••• .;.,uuJ::··· •>•· • LVJ• •••.•• / •100.t c: HEPTACHLOROrnBENZODIOXIN (TOTAL) 15000 J 3300 J 8600 J 7700 J 23000 J 490 J 350 J 12000 J Hi:iP.li>,¢H4989P!i:Wil?9€Qi'!Afllh:PI.4!il ''" '7' :ij!l20l!;i tj dj/iM•;,•:U i i{pp/JU i/Fil#~ii/1 4 itj{))fiffei•#f}y+: '.g!i;#iiff' H )frW)L:+\:Jl()(liif:F HEXACHLORODIBENZODIOXIN (TOTAL) 2400 J 1000 J 1500 J 1200 J 7400 J 81 J 49 J 1400 J H~lV@Hiiol[ibolatFiidif#i¾N'.croi'i\GfrKF@N@ lHMl iM•ii26Qi¥1 % • n:1200;/Pffff H'i(l/il4IHiM •· ~241,qr•·. •~7®Dt!C ;::• . mtqJ•:;g •:; : AitfiJt•:x ; wo wq OCTACHLORODIBENZODIOXIN 52000 58000 67000 56000 270000 6200 J 4400 J 82000 <iv:r@H1;<1gqqii}gt,jt¢e1,1,~;•,;.k ; 1t:ii•ili '•ill ~$@iii• uSuiM!! ; ; ii ,i@P :ii iiii~~9l!ff ii •;• k~,; :0,!li ir?:u11ih;•d; ~iiu m t~ni PENTACHLORODIBENZODIOXIN (TOTAL) 350 J 150 J 200 J 140 J 1100 J 10 UJ 5 UJ 180 J Pl;J\IJACtlkOROP!l31lNZOfURAN,ftdt/\li}•·•···········•····· .... ,> .. •,·•·•·•···•f·•·<·n••·••!150 .. M••••o;••I•.•····;·•····••i;1~:;;;r.> •.•... ; •....•••• -;;•···A~o .••• µ; ••••••••••• .., ••••.•.• \ ....... 11Qt!)fr;?y'••n·•·•i:<~1//•Ai•··••'••······•···· .. .;:;·.Ai&.µJ ....... ,,y••···············""'·l/J ....... ;·.••···"·•.Jhniihl•C••,· TEO (TOXIC. EQUIV. VALUE, FROM I-TEF/89) 280 J 160 J 140 J 150 J 850 J 9.9 J 5.7 J 210 J Tl:STI:~,N;;H!iQRPQ!$!ilitPPi~!NlIQT$lil ; l; •;t l @;: ~@WI •l! ;;J ##it ilrnrn i?9itiii !WF~ifii/H Hillfai.11.i/J\li#fiiltQl~t;m rn;rnrnl!4fi1!@1MUUM1J{({t TETRACHLORODIBENZOFURAN (TOTAL) 470 J 150 J 180 J 140 J 450 J 3.3 UJ 2.9 UJ 250 J Data Qualifiers J-Estimated value. U-Material was analyzed for but not detected. The number is the minimum quantitation limit. R-QC indicates that data unusable. Compound may or may not be present. Resampling and analysis necessary for verification. Concentrations presented in ng/kg. Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. ------ CHEMICAL VOLATILE ORGANICS \' _ ... fJ } EXTRACTABLE ORGANICS ... - ----- SD-1 TABLE 3-3 SEDIMENT SAMPLING SUMMARY -ORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA SD-2 SD-3 SD-3 (Dup.) SD-4 - - SD-5 - - - - SecUon 3 Surface Water/Sediment Investigation SD-6 SD-7 ~~ ~i~~~~i;RENE rrnr ; ~:;@J;,· •t 1~&iinm;vm11w;M1n Fffji§ij~jd p]g;~~+wrn:~;~~j rn t\~@Mwi prn; a~~rqt:;i;;qi~ij@Q!F 1.N······:.r ..•. : .... ~ ... E'.:.¢.".'.: ... ~.' •..•. :.· •. :.·~ .••.. ~.-.. FU.1 ·~·,··.'.H.R.···.·~.;.••·.-.: ... c ... N .. ·.:.o.·· .. · .. · .. :.) .•. ·.· .. · .. :,i=~; ~.· .. :.·.,.· •. t.••.J·;····~.:.•····· .. !.· •. • ..•. :.i ... ··.,.::,.:.:.~.· .. 1.· •.. :.: ... : .•. •.··.:.!.·•·····;·:···:·:·:·:.·.:.·•·······.:.·.:.·.•·.·.l ... ·.! ... · ..... ;.: ... ;..! ... ·.•········;·· ···········.·.·:.:.·.•.· .. :. ·.· ... · •. :.:.·.· .. ·.:.· •. :.'.i.: .•. · .. ·.1 ...• ~.c .•.... 0 .:.·.•.•······.·.! ... :.; .•. '.;.· •. t.: .•. ·.··.~.: .•.... :.• .. ·.~o~. 0 .·.·.•.·.:.:.: .•...•. :.· •. :.:.· •. ·.•··•.:.·.: .•. • •. ~.: .•. -.i.:.· •.. go.~ .. : ... · •..•. ·.•······.! ....•... ·.:.;.:;.· .. :.· •. t.· ... · .. i.· .. •.:.:.······:.· •. • .. ~.·· .... =.·.:.· •. ·.:.·.:.· •. • .. • .. ··.:.:.:.• •. :.l.·•~.~.···o·o· 0 ·.··•.··•····.!.·•····.·•.:.·.· .. •.·.· ~YR;;-;E '' ~ .....• •~@~)!i~!_\iUj 4700. 1400 U . .. . 3;~ ~ . .. ;00 J ;;;O ~ •c •;~~ ~ iii'. ~; ~ •;;;;; ~· PESTICIPES/PCBS l'Mi'.iPA!il!!i!!fi;\QWJ i 1,1':[) I) E.(f',f'.';[)(:l,lc) • •• 4¥H?PJE!!li!l'.tPPnk ENDOSULFAN II (BETA) Pata Qualifiers J•Estimated value. @w,fWM Mtff::iHiff%Jffs,&Ot11iMMMl!!Ulff H4iJltllrn #ii!li! );;51lfD; 150 12U 3.SU 14U 4U 4.9U 18U Y~t I&1gy;··· UP§@\l· .. •,··pq; MAl!JUMHt t~li/k!iMM#l!!!-H frMiiFAlKVit 14U 12U 3.SU 14U 4U 4.9U 18U LI-Material was analyzed for but not detected. The number is the minimum quantitation limit. Concentrations presented in ug/kg. Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. ------ CHEMICAL Pata Qualifiers J-Estimated value. N-Presumptive evidence of presence of material. ---- - -- SD-1 TABLE 3-4 SEDIMENT SAMPLING SUMMARY -INORGANICS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA SD-2 SD-3 SD-3 (Dup.} SD-4 LI-Material was analyzed for but not detected. The number is the minimum quantitation limit. - --- - SD-5 Section 3 Surface Water/Sediment Investigation SD-6 SD-7 Concentrations presented in mg/kg. Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. - I I I I I I I I I I I I I I I I I I I Section 3 Surface Water/Sediment Sampllng Investigation In the summary tables, those concentrations considered to reflect a valid detection of unnatural contamination are printed in bold italicized text to distinguish them from the other measurements. Since organic chemicals are not believed to be naturally occurring in surface water, any detection of an organic chemical in surface water is considered to be unnatural contamination. The same is true for sediments. For the inorganics in both surface water and sediments, since no background surface water or sediment samples were collected at the site, the concentrations were compared to typical background concentrations at other North Carolina sites in an attempt to distinguish unnatural contamination from natural chemical concentrations. 3.3.1 Surface Water As indicated in Table 3-1, the number of chemicals detected in the surface water samples collected at the site was relatively small. The spectrum of chemicals detected in at least one surface water sample from this area included only one volatile organic and 11 inorganics. Volatile Organic Contamination Volatile organic chemical contamination in surface water appears to be relatively insignificant. The only VOC detected in surface water was acetone and it was detected in only one surface water sample (SW-7) at a concentration of 1§!l ug/1 SW 7 is located in the northeastern part of the perimeter drainage ditch near the Roanoke River. Inorganic Chemical Contamination As indicated in Table 3-1, of the 11 inorganic chemicals detected in surface water at the site, only two appear to be at concentrations which are clearly indicative of unnatural contamination. These two chemicals, arsenic and manganese, were detected at concentrations significantly above typical background concentrations in at least two of the three surface water samples collected. The areal distribution of the arsenic and manganese contamination found in surface water in this remedial ~ U I' ,.(\ rr-' U\, investigation is shown in Figure 3-2. i4'5~ CDM Federal Programs Corporation spinb2Jsec3.wpd 3-7 I I I I I I I I I I I I I I I I I I I Roanoke River 0 300' I _ _,_ 600' Georgia-Pacific Hardwoods ~ Pl mouth, North Carolina !~~;;..;.;_.....,_ __ _, ~ CDM Federal Pr011rams Corporation ~ A SUO:sidi:l'y o/ eo. D'ISw I: llcii. he. LEGEND: sw-01 e 00 -···- ~ ---- - - - - • • • SURFACE WATER SAMPLE LOCATION N ARSENIC CONCENTRATION (ug/L) MANGANESE CONCENTRATION (ug/L) RIVER EDGE TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA Inorganic Contaminant Distribution in Surface Water Figure No. 3-2 6/00 I I I I I I I I I I I I I I I I I 3.3.2 Sediment Section 3 Surface Water/Sediment Sampling Investigation As indicated in Tables 3-2 through 3-4, a wide variety of chemicals were detected in the sediment samples collected at the site. The spectrum of chemicals detected in at least one sediment sample from this area included 17 dioxins/furans, 2 volatile organics, 14 extractable organics, 4 pesticides, and 14 inorganics. Dioxin/Furan Chemical Contamination As indicated in Table 3-2, numerous dioxins/ furans were found at concentrations which appear to be significantly above typical background concentrations in all the sediment samples except SD-5 and SD-6. The TEQ for the dioxins/ furans measured in the sediments ranged from 9.9 ng/kg to 850 ng/kg. (See section 2.3 Dioxin/Furan Chemical Contamination for an explanation of TEQ.) The areal distribution of the dioxin/ furan contamination (as indicated by TEQ calculations) found in sediments in this remedial investigation is shown inFigure 3-3. Volatile Organic Chemical Contamination As indicated in Table 3-3, only two VOCs were detected in any of the sediment samples: acetone and methyl ethyl ketone. Acetone was found in 4 of the 7 sediment samples at concentrations ranging from 350 ug/kg to 2800 ug/kg. Methyl ethyl ketone was found in 3 of the 7 sediment samples at concentrations ranging from 84 ug/kg to 440 ug/kg. The areal distribution of the VOC contamination found in sediments in this remedial investigation is shown inFigure 3-4. Extractable Organic Chemical Contamination The extractable organic contt!· µon found in.the sediments appears to be significant at only one locati ~f the extractable organics detected in sediments are PAHs, and at S >~1~ PAHs were detected with concentrations ranging from 240 to 5600 ug/kg. The carcinogenic PAH concentrations in the SD-1 sediment sample range from 540 ug/kg to 4400 ug/kg. The total PAH concentration measured in sediment sample SD-1 is 31,500 ug/kg while the total carcinogenic PAH concentration measured is 13,840 ug/kg. A few PAHs were also detected in sediment CDM Federal Programs Corporation splnb2/Sec3.wpd 3-9 I I I I I I I I I I I I I I I I I I I 0 Roanoke River .300' ---600' Georgia-Pacific Hardwoods Pl mouth, North Carolina _/ / / LEGEND: N SO-I 18) SEDIMENT SAMPLE LOCATION DIOXIN/FURAN TEO CONCENTRATION (ng/kg) RIVER EDGE ~ TREE LINE ----PROPERTY BOUNDARY ----INTERMITTENT DRAINAGE DITCH MARSHY AREA Dioxin/Furan Contaminant Distribution in Sediment Figure No. 3-3 CDM Federal Prol!rams Corporation ,..._.,_,._........ 6/00 ~.___ _______ ......... _________ _,,,&,,. ___ _____. I I I I I I I I I I I I I I I I I I I 0 -- Roonoke River 300' 600' Georgia-Pacific Hardwoods ! Pl mouth, North Carolina ~ CDM Federal Pro11rams Corporation ~ AJ&llld:fo,y,IC..,,ths...tlti.k LEGEND: ND -···- ,....._ ,....,,.... ---- - - - - • • • N SEDIMENT SAMPLE LOCATION ACETONE CONCENTRATION {ug/kg) METHYL ETHYL KETONE CONCENTRATION {ug/kg) NON DETECT RIVER EDGE TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA VOC Contaminant Distribution in Sediment Figure No. 3-4 6/00 I I I I I I I I I I I I I I I I I I I Section 3 Surface Water/Sediment Sampling Investigation samples SD-3, SD-6, and SD-7, but at relatively low concentrations (ranging from 71 ug/kg to 350 ug/kg), and none of the PAHs detected in these samples are carcinogenic. The areal distribution of the extractable organic chemical contamination (as indicated by total PAH and total cPAH calculations) found in sediments in this remedial investigation is shown in Figure 3-5. Pesticide Chemical Contamination Pesticide chemical contamination in sediments at the site appears to be relatively insignificant. Three of the four pesticides detected are 4,4-DDX chemicals (4,4-DDD, 4,4-DDE, and 4,4-DDT), and they were found in only one sediment sample (SD-2) at concentrations ranging from 190 ug/kg to 540 ug/kg. Likewise, the fourth pesticide detected (Endosulfan II) was found in only one sediment sample (SD-1) at a· concentration of 6.1 ug/kg. SD-2 is located in the southwestern part of the perimeter drainage ditch near the entrance gate, while SD-1 is located in the northwestern part of the perimeter drainage ditch near the Roanoke River. Inorganic Chemical Contamination As indicated in Table 3-4, of the 14 inorganic chemicals detected in sediments at the site, only five appear to be at concentrations which are·clearly indicative of unnatural contamination. Three of these five chemicals (arsenic, lead, and zinc) were detected at concentrations significantly above typical background concentrations in several of the sediment samples. The other two chemicals (barium and iron) were detected at concentrations significantly above typical background concentrations in only one sediment sample (SD-2). The areal distribution of the arsenic, lead, and zinc contamination found in sediments in this remedial investigation is shown in Figure 3- 6. The arsenic and zinc contamination in sediments appears to be spread throughout most of the length of the intermittent drainage ditches, having been detected at elevated concentrations in SD-1, SD-2, SD-3, SD-4, and SD-7. The detected concentrations of arsenic ranged from 3.7 mg/kg to 300 mg/kg, while the detected concentrations of zinc ranged from 12 mg/kg to 340 mg/kg. The drainage ditch areas considered to be contaminated with arsenic and zinc include the western, southwestern, and northeastern segments of the perimeter drainage ditch. The lead CDM Federal Programs Corporation spinb2fsecJ.wpd 3-12 I I I I I I I I I I I I I I I I I I I 0 Roanoke River 300' 600' Georgia-Pacific Hardwoods J Pl mouth, North Carolina ~ COM Federal Pro11rams Corporation ~ A subifaiy o/ ~ a,_. • »;Ka tc. s0-1 ® ND -···- ~ ---- - - -- • • • N SEDIMENT SAMPLE LOCATION PAH CONCENTRATION (ug/kg) cPAH CONC£NTRATION (ug/kg) NONDETECT RIVER EDGE TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA PAH Contaminant Distribution in Sediment Figure No. 3-5 6/00 I I I I I I I I I I I I I I I I I I I 0 Roanoke River 300' --600' Georgia-Pacific Hardwoods f1-..;P:,.;l:...,::m=ou=th;:,,:...:,N,;.;o;.:r~t,;.;h;...;;C.;;a;:,r,;;,ol;.:i,;.;n.;;a~ ~ COM Federal Proirrams Corporation ~ A rumi6oty ol ea.. a,-~ Ati"• tic. 50-1 @ Eiffl ND -···- ~ ---- - - ---• - N SEDIMENT SAMPLE LOCATION ARSENIC CONCENTRATION (mg/kg) LEAD CONCENTRATION (mg/kg)- ZINC CONCENTRATION (mg/kg)'----'- NON DETECT RIVER EDGE TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA Inorganic Contaminant Distribution in Sediment Figure No. 3-6 6/00 I I I I I I I I I I I I I I I I I I I Section 3 Surface Water/Sediment Sampling Investigation contamination also appears to be spread throughout much of the length of the intermittent drainage ditches, having been detected at elevated concentrations in SD- 1, SD-2, SD-3, and SD-4. The detected concentrations of lead ranged from 5.7 mg/kg to 140 mg/kg. The drainage ditch areas considered to be contaminated with lead include the western and southwestern segments of the perimeter drainage ditch. COM Federal Programs Corporation splnb2/sec3.wpd 3-15 I I I I I I I I I I I I I I I I I I I 4.0 Groundwater Sampling Investigation 4.1 Purpose and Scope Groundwater sampling was conducted at the site in both new temporary well points and existing shallow monitor wells to fully assess the types and concentrations of contaminants present in the underlying shallow aquifer, and to determine the extent and magnitude of groundwater contamination in the shallow aquifer at the site. A total of five temporary well points were installed at the approximate locations shown in Figure 4-1 to supplement the nine existing monitor wells installed previously at the site (also shown in Figure 4-1) prior to this remedial investigation. Note that the nine existing monitor wells were all constructed with 2-inch diameter PVC. 4.2 Methods One groundwater sample was collected from each of the. five temporary well points and the nine existing monitor wells identified above. These samples were sent to a CLP laboratory for complete TCL/TAL analyses. Just prior to sampling of each monitor well, field measurements of the well depth, depth to water, groundwater temperature, pH, conductivity, and turbidity were taken, and the results are provided in Table 4-1. All groundwater samples collected were grab samples and were collected according to the procedures established in the Remedial Investigation Work Plan (EPA, 1998) for the Georgia Pacific Site, and Section 4 of EPA's Environmental Investigations Standard Operating Procedures and Quality Assurance Manual (EPA, 1996). 4.3 Summary The concentrations of chemicals detected in the groundwater samples collected at the site are summarized in Table 4-2. Note that for the purpose of summarizing, only chemicals detected at least once in groundwater and their measured concentrations are presented in the summary table. Complete analytical results for the CLP laboratory analyses performed are provided in Appendix A. In Table 4-2, those concentrations considered to reflect a valid detection of unnatural contamination are printed in bold italicized text to distinguish them from the other measurements. CDM Federal Programs Corporation SPlNB2/SEC4,\NPO 4-1 I I I I I I I I I I I I I I I I I I I 0 - - Roanoke River 300' - --600' Georgia-Pacific Hardwoods ii--P-l ..,m_o_u_t_h_,_N_o_r_t_h_C_a_r_o_li_n_a __ -1 ~ CDM Federal Pro11rams Corporation / I LEGEND: MW-I. TMW-1® ,..._,_.._.., N EXISTING MONITORING WELL LOCATION TEMPORARY MONITORING WELL LOCATION RIVER TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE Well Location Map Figure No. 4-1 A a.midio,y ol ~ ~ • M:i'• .he. ~------------------------__,ji....s..;./_o_o__, ---------------- ---Section 4 Groundwater Investigation TABLE 4-1 GROUNDWATER SAMPLING FIELD MEASUREMENTS GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA Well Total Depth Depth to Water Temperature Conductivity Turbidity Number (ft) (ft) (°C) pH (umhos) (NTUs) MW-1 19.3 7.6 18.9 6.5 717 5.3 MW-2 15.3 7.8 21.1 6.6 447 6.7 MW-3 17.4 8.4 18.4 6.2 1491 53.4 MW-4 18.2 5.9 20.0 6.5 1196 2.5 MW-5 42.3 8.6 17.5 6.8 488 3.0 MW-6 17.1 6.0 19.6 6.5 434 5.9 MW-7 17.3 5.8 20.6 6.3 807 5.5 MW-8 16.2 5.3 20.7 6.3 601 27.6 MW-9 15 8.1 19.7 6.7 1183 4.4 TW-24 9 19.2 7.5 1892 132 TW-29 9 22.0 6.2 736 12.3 TW-49 10 18.9 5.1 1169 394 TW-51 12.3 5.4 1085 408 TW-54 7.5 6.5 --.. ----- --- - ----- --Section 4 Groundwater Investigation TABLE 4-2 GROUNDWATER SAMPLING SUMMARY GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA MW-1 MW-2 MW-3 MW-4 MW-5 MW-6 MW-6 MW-7 CHEMICAL (□up.) VQLATILE QBGl\t,!IQS G;,v-,STO~IL. EXTAAQTABLE QRGANIQS INQBGI\NIQS --·-c:, u 140 SJ 140 990 4 U 4U 4U ••• IA !CALCIUM osnnn 58000 1snnnn 130000 .450()0 51000 45000 92000 COBALT 2U 2U 2 U 2U 2U 2 U 2 U 2 U , IRON :,,aO ·- 13000 1800 ssnnn 35000 1400 1snnn ,snnn ssnnn osnn 7~0(1 ?onnn 21non . 43()0 4700 4fo() 7Jg~H!I UM 22000 J 4700 J 24000 J -~~-000 J 2700 J S?MJ sonn J 12000 J ...... :.: 2U 2U 2 U 2U 2 U ? II ? II 2 II Pata Qualifiers J-Estimated value. U-Material was analyzed for but not detected. The number is the minimum quantitation limit. Concentrations presented in ug/L. Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. -.. ---- - MW-8 CHEMICAL VQLAIILE QBG/lt,IICS E~IB/ICT/l!;!LE QBQMICS -111_ .. '.-'L..l'IL.. tjr:~; 10 U IFLL,~ ,_ 10 U INQBG/ltllCS ijA~@M1 22 CALCIUM 67000 !COBALT 2U IIRON 30000 ;'.;,;~,~~~ 9200 '"Ju1 •11 ••• asnn J " .. sJ Pata Qualifiers J-Estimated value. - ---- TABLE 4-2 (cont.) GROUNDWATER SAMPLING SUMMARY GEORGIA-PACIFIC SITE PLYMOUTH, NORTH CAROLINA MW-9 TW-24 TW-29 10 U 10 U 10 lJ 10 U 10 U 10 U 28 26 an 110000 220000 7400() 2 U 5 J 8 J 8900 67000 ssnnn 33000 •snnn 1snnn 72000 J 30000 J 18000 J 2U 3 J 2 U U-Material was analyzed for but not detected. The number is the minimum quantitation limit. - - - TW-49 TW-51 10 U 10 II 10 U 10 U ~ 4 II unnnn J 1 rnnnn 4J 2 U tii! 1onnn i•nnn 49000 J sannn J "J 2U Concentrations presented in ug/L Concentrations printed in bold italicized text are considered to reflect a valid detection of unnatural contamination. -- - TW-54 ,j 2 J 1sn~ii •• J 46000 . 1snnn 30000 J S? Section 4 Groundwater Investigation - I I I I I I I I I I I I I I I I I I I Section 4 Groundwater Sampling Investigation Since organic chemicals are not believed to be naturally occurring in groundwater in this area, any detection of an organic chemical was considered to be unnatural contamination. For the inorganics, since no background groundwater samples were collected at the site, the concentrations were compared to typical background concentrations at other North Carolina sites in an attempt to distinguish unnatural contamination from natural chemical concentrations. As indicated in Table 4-2, a wide variety of chemicals were detected in the groundwater samples collected at the site. The spectrum of chemicals detected in at least one groundwater sample from this area included one volatile organic, five extractable organics, and 15 inorganics. Volatile Organic Chemical Contamination Volatile organic chemical contamination in groundwater at the site is relatively insignificant. The only VOC detected in groundwater was toluene and it was detected in only one monitor well (MW-1) at an estimated concentration of 1 ug/1. MW-1 is located in the Former Raw Timber Processing Area. Note that no VOCs were detected in any of the monitor wells located in or near the alleged TCE spill area. Extractable Organic Chemical Contamination Extractable organic chemical contamination in groundwater at the site is also relatively insignificant. The five extractable organics detected are all PAHs, and they were detected in only one well (TW-54) at concentrations ranging from only 1 ug/1 to 3 ug/1. TW-54 is located near the Roanoke River in the Former Raw Timber Receiving Area. It should be noted that when well point ~s installed, the drillers experienced an extremely strong creosote odor emanating from the hole and soils after drilling to a depth of 5 feet. Inorganic Chemical Contamination As indicated in Table 4-2, of the 15 inorganic chemicals detected in groundwater at the site, only two appear to be at concentrations which are clearly indicative of unnatural contamination. These two chemicals, arsenic and manganese, were detected at concentrations significantly above typical background concenh·ations in several wells. CDM Federal Programs Corporation $PINB2/SEC4,WPO 4-6 I I I I I I I I I I I I I I I I I I I Section 4 Groundwater Sampling Investigation The areal distribution of the arsenic and manganese contamination found in groundwater in this remedial investigation is shown in Figure 4-2. Some of the other inorganics detected (i.e., aluminum, chromium, cobalt, copper, lead, vanadium, and zinc) were found at slightly elevated concentrations in well points TW-49 and TW-54 when compared to the other wells onsite, but the concentrations measured in these samples are within the realm of possible background concentrations, particularly when considering the high turbidity of the TW-49 sample and the potential high turbidity of the TW-54 sample. The turbidity of the sample from TW-54 was not measured, but well point samples typically are very turbid due to the inability to develop a well point. The arsenic contamination in groundwater appears to be spread throughout much of the site, having been detected at elevated concentrations in MW-1, MW-3, MW-4, MW-7, MW-8, MW-9, TW-24, TW-29, TW-49, and TW-54. The detected concentrations of arsenic ranged from an estimated 5 ug/1 to 990 ug/1. The highest concentration of arsenic was found in the area of the alleged TCE spill, but other high concentrations of arsenic (above its 50 ug/1 MCL) were also found in the Former Raw Timber Processing Area (MW-1) and the eastern part of the Former Finished Wood Products Storage Area/Outerbanks Contractors Asphalt Mixing Plant Area (MW-3 and TW-29). The manganese contamination appears to be concentrated in the Former Finished Wood Products Storage Area/Outerbanks Contractors Asphalt Mixing Plant Area, having been detected at elevated concentrations in MW-3, MW-4, MW-7, and TW-29. The detected concentrations of manganese ranged from 62 ug/1 to 4700 ug/1. Note that no well had a concentration of manganese below its 50 ug/1 SMCL indicating that background concentrations of manganese in the surficial aquifer are likely above the SMCL. CDM Federal Prol!rnms Corporation SPINB2/SEC4.v\lPO 4-7 I I I I I I I I I I I I I I I I I I I 0 Roonoke River 300' 600' Georgia-Pacific Hardwoods fi-_P_l..._m __ o_u_t_h_, __ N_o_r_th ....... C .. a_r_o_li_n_a.....,. / LEGEND: .,._,. ND -···- ~ ---- - - -- • • • N / EXISTING MONITORING WELL LOCATION TEMPORARY MONITORING WELL LOCATION ARSENIC CONCENTRATION (ug/L) MANGANESE CONCENTRATION (ug/L) NONDETECT RIVER EDGE TREE LINE PROPERTY BOUNDARY INTERMITTENT DRAINAGE DITCH MARSHY AREA Figure No. Inorganic Contaminant Distribution in Groundwater 4-2 ~ COM Federal Programs Corporation ~ • ._.,_,,,_......... 6/00 ~--------------------------- I I I I I I I I I I I I I I I I I I I 5.0 Contaminant Fate and Transport Analysis An evaluation of the environmental fate and transport of site-related contaminants is important in determining the potential for exposure to the contaminants. There are several mechanisms by which contaminants may migrate at the Georgia Pacific Site. Migration into the air can occur via volatilization or dust generation. Migration into groundwater can occur by percolation of infiltrating rainwater or groundwater flow through waste materials or contaminated soils. Transport to surface waters can occur via surface water runoff, and/ or through groundwater discharge. The mechanisms of migration for the contaminants of concern detected at the site (see Section 6) are discussed in more detail below. Estimates of the physical and chemical properties of the contaminants of concern which may affect contaminant migration are presented in Table 5-1. Note that the properties for the dioxins/furans are represented by the properties of 2,3,7,8-TCDD (one particular dioxin) in Table 5-1. Some variation in properties is expected between each of the individual dioxins and furans, but the variations are not expected to be significant. The general persistence of the contaminants of concern is also discussed below. 5.1 Contaminant Migration 5.1.1 Air Migration Generally, volatilization from soil and/ or water into air may be an important transport mechanism for the organic chemicals with Henry's Law Constants greater than 10-5 atrn-m3 / mole and molecular weights less than 200 g/ mole. None of the organic contaminants of concern found at the site meet these criteria, and thus, volatilization of the contaminants of concern is not considered an important release mechanism at this site. Fugitive dust emissions from wind or mechanical disturbances may occur from unpaved or unvegetated areas of the site. The environmental factors that influence wind erosion are wind speed, moisture content, vegetative cover, and soil composition. Because the environmental factors at the Georgia Pacific Site are at times COM Fcd~ral Programs Corporation SPIN2B/SECT5 5-1 ---------· --- --- - - - - TABLES-I Section 5 Contaminant Fate and Transport ESTIMATED PHYSICAL AND CHEMICAL PROPERTIES OF THE CONTAMINANTS OF CONCERN GEORGIA-PACIFIC SITE Contaminant of Concern In organics Aluminum Arsenic Barium Chromium Iron Lead Manganese Vanadium Molecular Weight (g/mol) NA NA NA NA NA NA NA NA Extractable Organics Benzo(a)anthracene 2281 Benzo(b &/ or k)fluoranthene2521 Benzo-a-pyrene 2521 Dibenzo(a,h)anthracene 2781 Indeno(l,2,3-cd)pyrene 2761 Other Organics PCB-1254 PCB-1260 2,3,7,8-TCDD (Dioxin) 3271 3701 3221 PLYMOUTH, NORTH CAROLINA Solubility at25°C (mg/~ NA NA NA NA NA NA NA NA 0.0142 0.000552 0.00382 0.00052 0.622 0.0122 0.00272 0.21 Henry's Constant (atm-m3 /mo! x 10·5 ) I<.,., (ml/g) NA NA NA NA NA NA NA NA 0.0661 1.21 0.241 0.000731 3.0 X 10-15 1 2301 7101 5.4 X 10"18 1 NA NA NA NA NA NA NA NA 1,400,0001 550,0001 400,0001 1,700,0001 31,000,0001 400,0001 2,600,0001 4,600,0001 Kow (ml/g) NA NA NA NA NA NA NA NA 140,0002 3,700,0002 1,100,0002 930,0002 46,000,0002 1,100,0002 14,000,0002 2,000,0001 2004 o.s• 304 800• 16,000• 7504 5303 14,0003 42003 35003 170,0003 42003 53,0003 76003 ------------------- TABLE 5-1 (cont.) Section 5 Contaminant Fate and Transport ESTIMATED PHYSICAL AND CHEMICAL PROPERTIES OF THE CONT AMIN ANTS OF CONCERN GEORGIA PACIFIC SITE PLYMOUTH, NORTH CAROLINA Notes: Koc -Organic carbon partition coefficient K,w -Octanol/ water partition coefficient Kd -Soil/ water partition coefficient NA -Not Applicable -No Data Available Sources: 1) Montgomery and Welkom (1989) 2) Walton (1984) 3) Based on a typical fraction of organic carbon in soil and the following equation (Walton, 1984): foe = fraction of organic carbon in soil (0.006) 4) Based on data presented in Thibault, et al. (1990) I I I I I I I I I I I I I I I I I I I Section 5 Contaminant Fate and Transport and places conducive to wind erosion, each of the contaminants of concern detected in surface soil is susceptible to migration via fugitive dust generation. 5.1.2 Surface Water Migration Contaminant migration into the Roanoke River, a major surface water body at the Georgia Pacific Site, may occur through surface water runoff, and/ or through groundwater discharge. Upon reaching this surface water pathway, contaminants may remain in the water column, volatilize, or sorb to bottom or suspended sediments. Volatile organic contaminants tend to quickly volatilize into the atmosphere upon reaching surface waters and for this reason are rarely observed at detectable concentrations in surface water samples. Nevertheless, even though there are no volatile organic contaminants of concern at the site, it should be noted that during this RI, one volatile organic chemical (acetone) was detected in both surface water and sediment samples collected from the intermittent drainage ditches which lead to the Roanoke River. The dioxins/ furans and other organics with low water solubilities and high I<;., values such as PAHs, pesticides, and PCBs will tend to associate with sediments as opposed to volatile organics and extractable organics with high water solubilities and low Koc values, which tend to stay in the water column. All the organic contaminants of concern at this site have low water solubilities and high I<;,, values and based on the surface water and sediment sample results obtained in this remedial investigation, it appears that these contaminants are mostly sorbing to sediment particles, as expected. This does not preclude the migration of these contaminants to the Roanoke River, however, as the contaminated sediments may be conveyed to and within the Roanoke River via sediment transport mechanisms during storm events. The behavior of the inorganic contaminants of concern in surface water is affected by pH, temperature, and hardness. Inorganic compounds can occur in aquatic systems as dissolved ions, dissolved complexes with organic and inorganic chemicals, colloids, or particulates. The solubility and mobility of the metal inorganic contaminants is enhanced by their ability to form complexes with humic and fulvic acids, carbonates, CDM Federal Pmi:rnms Corporation SP!N2B/SECT5 5-4 I I I I I I I I I I I I I I I I I I I Section 5 Contaminant Fate and Transport hydroxides, and phosphates. Based on the surface water and sediment sample results obtained in this remedial investigation, it appears that several inorganic chemicals are migrating to surface waters at the site, and that the geochemical processes in the surface waters allow for some of these contaminants to both remain in the water column and sorb to sediments, while others are mostly sorbed to sediment particles. Again, however, the sorbing of contaminants to sediment particles does not preclude the migration of these contaminants to the Roanoke River, as the contaminated sediments may be still be conveyed to and within the Roanoke River via sediment transport mechanisms during storm events. 5.1.3 Soil Migration Contaminants present in surface and subsurface soils may leach to the underlying aquifer. Many factors influence the rate of contaminant movement through soils. These include the physical/ chemical properties of the contaminants (e.g., solubility, density, viscosity, K.,.,, ~w), and the physical/ chemical properties of the environment (e.g., rainfall percolation rate, soil permeability, porosity, particle size distribution, organic carbon content). Because all these factors can affect the rate of contaminant movement through soils, it is very difficult to predict such movement. However, based on the data collected in this remedial investigation some gross generalizations of this movement can be made. Sorption of a chemical to soil particles is the only significant hinderance of contaminant migration in soils at the Georgia Pacific Site. If it were not for sorption, rainfall recharge and soil permeability at this site are high enough such that all the contaminants of concern would readily move through the soils. Sorption of contaminants is generally described by their distribution coefficients (~). The distribution coefficient can be expressed as: mass of contaminant on the solid phase per mass of solid phase = concentration of solute in solution As indicated in Table 5-1, all the organic contaminants of concern at this site have very high Ki values and even though they have been observed in the soils and sediments at CDM Fe<lc:ral Pmi;:rams Corporation SPIN28/SECT5 5-5 I I I I I I I I I I I I I I I I I I I Section 5 Contaminant Fate and Transport significant concentrations, they have not been observed in groundwater. Sorption of these contaminants of concern to the soils at the site has apparently prevented significant migration into groundwater. Except for barium (and possibly aluminum and vanadium), the inorganic. contaminants of concern also have high l<;i values, and thus, these contaminants will also readily sorb to soil particles at the site. However, the observance of some of these inorganic contaminants (i.e., arsenic and manganese) in groundwater at significant concentrations indicates that the abundance of these contaminants in soil may be too high for complete sorption to occur. The concentrations of the inorganics in the soils is apparently high enough such that a significant amount of this inorganic contamination can still leach into groundwater. Nevertheless, except for barium (and possibly aluminum and vanadium), movement of the inorganic contaminants of concern in the soils at this site is expected to be very slow due to their high propensity for sorption. 5.1.4 Groundwater Migration Many factors influence the rate of contaminant movement in an aquifer system. These include the physical/ chemical properties of the contaminants (e.g., solubility, density, viscosity, etc.), and the physical/ chemical properties of the environment (e.g., soil permeability, porosity, bulk density, particle size distribution, extent and connectivity of fractures, etc.). Because all these factors can affect the rate of contaminant movement through aquifers, it is very difficult to predict such movement. However, based on the data collected in this RI, some gross approximations of this movement can be made. Once the contaminants of concern reach groundwater, they will generally move as groundwater moves, through the process of advection. However, the process of dispersion will also cause the contaminants to spread both horizontally and vertically. Dispersion generally causes contaminants to migrate (spread) 10 to 20 percent farther than migration created by advection alone. Counteractive to the advection and CDM Federal Programs Corporncion SPIN2B1SECT5 5-6 I I I I I I I I I I I I I I I I I I I Section 5 Contaminant Fate and Transport dispersion processes, however, is the process of sorption which will retard the movement of the contaminants. Estimates of the distribution coefficients for the contaminants of concern at the site are presented in Table 5-1. As indicated in this table, the majority of the inorganic contaminants of concern and all of the organic contaminants of concern have_relatively high I<., values, and thus, these contaminants will readily sorb to soil particles at the site and are essentially immobile. Barium and possibly a few other inorganic contaminants of concern, however, generally have lower ~ values, and thus will not sorb to soil particles as readily as the other contaminants of concern. These contaminants are therefore considered to be mobile, and will generally move as groundwater moves, only at reduced velocities. Furthermore, since groundwater most likely moves toward the Roanoke River, these mobile contaminants will also migrate toward the Roanoke River where, eventually, they will be discharged. 5.2 Contaminant Persistence Persistence is the measure of how long a chemical will exist in the environment before it degrades or transforms, either chemically or biologically, into some other chemical. Some of the factors which affect the persistence of a chemical include the state of the chemical, the availability of the chemical, exposure to sunlight, oxygen availability, the types and quantities of microorganisms present, availability of nutrients, temperature, pH, as well as the presence of other chemicals which may inhibit or enhance degradation. Usually, persistence is expressed in terms of a chemical half-life and can be on the order of days, weeks, or years. Because of the many complex factors which may affect persistence, the actual rate of chemical degradation is very difficult to predict for a given chemical at a given site, especially without the benefit of any degradation data collected from site-specific field studies. However, a qualitative evaluation of the potential for degradation of a chemical can be made based on the results of laboratory and/ or field studies conducted previously at other locations. Such a qualitative evaluation was conducted for the contaminants of concern detected at the Georgia Pacific Site, and the results are CDM Federal Pro1:r:uns Corporation SPIN2B/SECT5 5-7 I I I I I I I I I I I I I I I I I I I Section 5 Contaminant Fate and Transport summarized in Table 5-2. Again, note that the degradation potential for the dioxins/furans are represented by the degradation potential for 2,3,7,8-TCDD in Table 5-2. Some variation in the degradation potential is expected between each of the individual dioxins and furans, but the variations are not expected to be significant. In this table, the degradation potential for each of the contaminants of concern is indicated for the following three environmental media categories: • • • Atmospheric Degradation -A chemical released to the atmosphere may degrade by such processes as photolysis and/ or reactions with the hydroxyl radical, ozone, or other chemicals present. Aquatic Degradation -A chemical released to fresh, marine, or estuarine surface waters may degrade by such processes as photolysis, hydrolysis, oxidation, and/ or biodegradation. · • Terrestrial Degradation -A chemical released to soil or groundwater may degrade by such processes as hydrolysis, oxidation, and/ or biodegradation. As indicated in Table 5-2, of all the contaminants of concern at the Georgia Pacific Site, the metals have the least potential to degrade in all media and therefore will likely persist the longest at the site. In fact, these contaminants, under ordinary conditions, will likely persist indefinitely (for all practicable purposes). Other chemicals which also have low degradation potential include the PCBs. All the other contaminants of concern (i.e., the dioxins/ furans and the PAHs) generally have low to moderate potentials for degradation, unless released to the atmosphere, in which case all the P AHs generally have a high potential for degradation. CDM Fedem! Progrnms Curpnmtion SP!N2B!SECTS 5-8 ------------------- TABLES-2 Section 5 Contaminant Fate and Transport ESTIMATED DEGRADATION POTENTIAL OF THE CONTAMINANTS OF CONCERN' GEORGIA-PACIFIC SITE Contaminant of Concern Jnorganics Aluminum Arsenic Barium Chromium Iron Lead Manganese Vanadium Extractable Organics Benzo( a)anthracene Benzo(b &/ or k)fluoranthene Benzo-a-pyrene Dibenzo(a,h)anthracene Indeno(l,2,3-cd)pyrene Other Organics PCB-1254 PCB-1260 2,3,7,8-TCDD (Dioxin) PLYMOUTH NORTH CAROLINA Atmospheric Degradation Potential Low Low Low Low Low Low Low Low High High High High High Low/Moderate Low /Moderate Moderate Aquatic Degradation Potential Low Low Low Low Low Low Low Low Low /Moderate Low /Moderate Low/Moderate Low/Moderate Low /Moderate Low Low Low/Moderate Terrestrial Degradation Potential Low Low Low Low Low Low Low Low Low/Moderate Low/Moderate Low/Moderate Low/Moderate Low/Moderate Low Low Low/Moderate ------------------- TABLE 5-2 (cont.) Section 5 Contaminant Fate and Transport ESTIMATED DEGRADATION POTENTIAL OF THE CONTAMINANTS OF CONCERN' GEORGIA PACIFIC SITE PLYMOUTH, NORTH CAROLINA 10ualitative Evaluations Made Based on Information Obtained from the Following Sources: 1) U.S. Department of Health and Human Services Toxicological Profiles 2) Fate and Exposure Data For Organic Chemicals, (Howard, 1989) 3) Handbook of Environmental Degradation Rates, (Howard, 1991) 4) Hazardous Substance Data Bank maintained by the National Library of Medicine in Bethesda, Maryland I I I I I I I I I ,. I I I I I I'• I I 6.0 Quality Assurance Report 6.1 Controlling Documents The primary objective in instituting quality control procedures is to ensure that staff collect and record data in a uniform manner and that data are of consistently high quality. Data are thus more likely to be accurate and can be interpreted with a high degree of confidence. In order to collect and record data in a uniform manner, controlling documents that described and specified quality assurance/ quality control (QA/QC) procedures for the field investigation were prepared and/ or used. The documents used to guide and direct procedures throughout the investigation included: Environmental Investigations Standard Operating Procedures and Quality Assurance Manual, U.S. EPA Region IV, Science and Ecosystem Support Division, May 1996 and 1997 revisions U.S. EPA Region4 Remedial Investigation Work Plan Georgia-Pacific Hardwood Sawmill Plymouth. North Carolina, Science and Ecosystem Support Division, August 1998 Final Work Plan for Remedial Investigation Georgia-Pacific Hardwood Sawmill Site Plymouth. North Carolina, CDM Federal Programs Corporation, January, 1999 Guidance for the Data Quality Objectives process. EPA 600/R-96/055, September 1994 The U.S. EPA Work Plan specified and described all QA, QC, analytical, data management, auditing and reporting procedures for this investigation. In addition, the U.S. EPA Work Plan established the DQO levels for field and analytical data using the DQO levels defined in EPA 600 / R-96 / 055 September 1994. For this investigation, field measurements such as pH, temperature, NTUs, conductivity, water level, and ground survey measurements were considered DQO Level I data. The contaminant analysis data of surface water, sediment, soil, and groundwater provided by Contract Laboratory Program (CLP) laboratories and validated by Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) were considered DQO Level IV data. CDM Federnl Pmgraffill Corp:1r.uiun SPINB2/SEC1.I/JPO 6-1 I I I I ,I I I I I I 'I I I I I I I Section 6 Quality Assurance Report By providing a framework for sample collection, decontamination, field quality control, sample identification, chain-of-custody and sample handling procedures, the controlling documents help ensure that high quality data is collected and data comparability is enhanced. 6.2 Field Investigation 6.2.1 Groundwater Sampling The work plan had called for the installation of ten temporary monitoring wells and then collection of groundwater from the temporary well points and from five existing monitor wells. Temporary monitoring well installation and sampling was performed in accordance with the specifications in the Work Plan except that only five temporary monitor wells were completed due to conditions encountered at the site and actually nine of the permanent wells were sampled. As specified in the Work Plan, the samples were collected with a peristaltic pump. All groundwater samples collected were sent to CLP laboratories and analyzed according to DQO Level IV requirements. 6.2.1.1 Water Level Measurements Water level measurements followed the procedures specified in the work plan. Field measurements associated with this activity were conducted in accordance with DQO Level I requirements. 6.2.1.2 Field Parameter Measurements Field parameters (pH, specific conductivity, temperature, and turbidity) were measured on groundwater during well purging. Daily calibration of the monitoring instruments was performed and recorded in the field logbooks. In addition, post calibration checks were performed on the instruments following the days' activities. Instrument calibration and measurements performed appeared accurate and acceptable and no instrument malfunctions were reported. CDM Federal Pmi;r.uns Corpor.11ion SPINB2/SEC1.WPO 6-2 I I I I I I I I I I I I I I I I I I I 6.2.2 Surface Water/Sediment Sampling Section 6 Quality Assurance Report Surface water and sediment samples were collected according to procedures specified in the work plan. However instead of the six surface water and six sediment samples planned there were actually three surface waters and seven sediments samples collected. Surface water was not adequate enough to collect samples. All samples were sent to CLP laboratories and analyzed according to DQO Level IV requirements. 6.2.5 Soil Sampling USEP A divided the site into 54 grids and collected one five-aliquot composite surface sample from each grid. Samples were analyzed for volatile organic compounds (VOCs), semivolatile organic compounds(SVOCs), pesticides, polychlorinated biphenyls (PCBs), metals, and dioxin/ dibenzofuran (approximately 80% of the samples were analyzed for dioxin/ dibenzofuran). In addition, grab subsurface samples were collected at the center of each grid at a depth of 18" -24" bgs, and from grids 25 through 54 at a depth of 36" to 54" bgs. The grab samples were analyzed for VOCs, SVOCs, pesticides, PCBs, metals, and dioxin/ dibenzofuran (approximately 80% of the samples were analyzed for dioxin/ dibenzofuran). Two additional soil samples were collected onsite that were not associated with the 54 intially established grids. One sample was collected in an area just west of Grid 17, designated as sample GP055SLA, and another was collected of ash near the boiler house, designated as sample GP056SLA. Other minor sampling deviations occurred due to conditions encountered at the site. For example, some of the five point aliquots could not be collected due to buried obstructions. Twenty offsite locations were proposed for surface soil sample collection and some of these for subsurface soil sample collection. However, only 14 locations were identified and samples were collected for volatiles and extractable organics, metals, pesticides, PCBs, dioxins, and furans. 6.3 Field Quality Control Procedures All data was collected as specified in the work plan. Field measurements were performed in accordance with procedures specified in the work plan. All monitoring CDM F.,Jen1l Pm1:r.um Corpmation SPINB2/SEC1.WPO 6-3 I I I I I I I I I I I I I I I I I I I Section 6 Quality Assurance Report instruments were calibrated either before each use, at the beginning of each field day, or at the frequency specified for each instrument. All sampling equipment that came in contact with sample media was decontaminated as specified in the work plan before each sample was collected. All sample collection, chain-of-custody, and sample shipping procedures were carried out as specified in the work plan. As part of the sample collection and analysis effort, field quality control samples were prepared to monitor the performance of the CLP laboratories and the offsite laboratories, and to check the field sampling procedures. A description of each QC sample type and QC sample results are discussed in Section 6.5. 6.4 Data Validation 6.4.1 CLP Laboratory Analysis All DQO Level IV data collected under the Georgia-Pacific remedial investigation were validated by EPA Region IV SESD using EPA CLP data validation procedures. The validation process involves review for compliance with holding times, instrument calibration, method and laboratory blanks, instrument tuning and performance data, and constituent quantification. Results of duplicate, matrix spike and other QC samples are used to assess precision and accuracy of the analytical data and potential matrix effects. The following qualifier flags are typically used by SESD to qualify data. COM Fedeml Progr.ims Corpum1ion SPINB2/SEC1.\o\'PD A-Average Value NA-Not Analyzed NAI-Interferences J-Estimated Value N-Presumptive Evidence of Presence of Material K-Actual Value Is Known To Be Less Than Value Given L-Actual Value Is Known To Be Greater Than Value Given U-Material Was Analyzed For, But Not Detected, The Number Is The Minimum Quantitation Limit R-QC Indicates That Data Is Unusable, Compound May or May Not Be Present; Resampling and Reanalysis is Necessary For Verification 6-4 I I I I I I I I I I I I I I I I I I I Section 6 - Quality Assurance Report The purpose of validating the data is to allow the data user to interpret and use the data with varying degrees of confidence depending on how the data are qualified (e.g. unqualified, estimated, or rejected). For this investigation the data validation for both organic and inorganic analyses revealed that the overall data package can be accepted with confidence. However some data had to be rejected. Some results were rejected due to detection of analytes or compounds in blanks insufficient recovery of spiked samples. For organics in each media sampled, the "U" qualifier was applied on most data due to the contaminant being analyzed for but not detected at the minimum quantitation limit. The "J" qualifier was generally applied due to the sample containing those compounds less than the quantitation limits. Some extractable PAHs in samples were flagged with "J" due to low performance evaluation sample recovery for those P AHs. For the inorganics, the soils and sediment samples analyses resulted in actual levels of metals in most samples so no qualifiers were applied. For the aqueous samples analyzed much of the data was qualified "U" due to the those metals not detected at the minimum quantitation limit. For nonaqueous samples, the "U" was applied when the percent relative standard deviation %RSD greater than 20% for Inductively Coupled Plasma Emission Spectoscopy (ICP) multiple exposures and reported results were greater than instrument detection limit (IDL), but less than contract required detection limit (CRDL) or there was some baseline instability. The "J" qualifier was applied to some of the metals analyzed for a multitude of reasons which include matrix spike recovery and matrix duplicate out of control limits, and the Contract Laboratory Program Statement of Work (CLP SOW) requires analysis of two times CRDL standard for ICP analysis. 6.5 Data Evaluation As part of the overall data review, the results of field QC samples were examined so that effects of field procedures on data quality could be evaluated. Field QC samples included EPA blanks and spikes, duplicate samples, trip blanks, equipment rinsates, material blanks, and water blanks. In addition, sampling personnel collected CDM Feder.ii Proi:rnms Corporation SPINB2/SEC1.WPO 6-5 I I I I I I I I I I I I I I I I I I I -Section 6 Quality Assurance Report sufficient volume for the CLP laboratories to analyze matrix spike and matrix spike duplicate samples. 6.5.1 EPA Spikes Spike sample ampules were shipped from SESD to the CLP laboratories. The laboratory provided full CLP documentation for spike sample analyses. Spike samples were submitted for liquid environmental matrices during the subject week of sample collection. The spike samples submitted to the CLP laboratories were analyzed for TAL and TCL parameters. The sample results were used by EPA to check adherence to procedures by the CLP laboratories. These samples were submitted to the respective CLP laboratories on a blind basis. Fictitious station numbers were used on the traffic report forms; the CLP laboratories did not know which samples were blanks and spikes. These samples were identified as such only on the copy of the traffic report forms that were returned to SESD and Sample Management Office (SMO). 6.5.1 EPA Inorganic Blank In addition to the EPA Spike, SESD also prepared a blind inorganic blank which is sent to the field personnel to be shipped along with the field collected samples to the CLP inorganic laboratories. It is given a ficticious sample location and is reported by the CLP with the field sample data. SESD evaluated the CLP analytical results and did not report any false positives. 6.5.2 Trip Blanks Trip blanks (for VOCs only) accompanied the shipments of samples to the CLP laboratory whenever coolers contained samples for VOA analyses. Trip blanks were prepared for both aqueous and soil/ sediment type samples. Trip blanks are used to show contamination potentially having occurred during sample handling or storage. The trip blank was prepared by the field team prior to the sampling event and kept with the investigative samples throughout the sampling event. It was then packaged for shipment with the other samples and sent for analysis. Trip blank results are CDM Federal PmRr,uns C1irp(lmtion SPINBVSEC1.WPD 6-6 I I I I I I I I I I I I I I I I I I I Section 6 QualityAssurance Report presented in the Appendix A Quality Assurance Data. Only a few detections were noted in the trip blanks analytical results. All detections were qualified "U" or as a low "J" value. These detected constituents were generally corrunon laboratory contaminants or metal salts are not considered site contaminants of concern. · 6.5.3 Equipment Rinsates Rinsate blanks were obtained by running organic-free water over sampling equipment after it had been decontaminated. These samples were used to determine if cleaning procedures were adequate. Equipment rinsate samples were collected from decontaminated soil/ sediment sampling, groundwater sampling, and surface water sampling equipment. Rinsate blank results are presented in the Appendix A Quality Assurance Data. No constituents of organic or inorganic nature were detected in the equipment rinsates which would indicate inadequate decontamination of sampling equipment. 6.5.4 Field Blanks (Water Blanks) Field blanks are generally collected of the organic free water purification system which is connected to an onsite public water or well water supply. Water samples were sent for analysis of metals, volatile and extractable organics, pesticides and PCBs. No constituents of any significance were detected. 6.5.5 Duplicate Samples Field duplicates were collected as a means of quality control from the point of sample collection through all analytical processes. Duplicates were collected for all media sampled except sediment. The Relative Percent Difference (RPD) values calculated for field samples and their duplicates are calculated on positive results only. The RPD values calculated for inorganic analyses of the groundwater, surface water, sediment, and soil, sample/ duplicate pairs were: 15.3%, 2.3%, 10%, and 26%, respectively. This indicates that sample/ duplicate pairs for those media showed similar results and that the objectives of analyzing duplicate samples were achieved. The organic analytical results showed all non-detects for the sample/ duplicate pairs except for dioxins and furans in the sediments and soil which had RPDs of 34% and 22% respectively. COM Federal Pmgrdm! C1rpnrod11n SPINB2/SEC1.WPD 6-7 I I I I I I I I I I I I I I I I I I I Section 6 Quality Assurance Report A soil extractable organic analysis RPD was calculated as 26% and was based on detections in three sample/ duplicate pairs. 6.6 Precision, Accuracy, Representativeness, Comparability, Completeness 6.6.1 Precision Precision is the evaluation of the reproducibility of a measurement. Precision is estimated by the analysis of duplicate samples and the calculation of RPD or RSD. This project involved both the collection of field duplicates and the creation of laboratory duplicates. Field duplicate samples serve as an indicator of overall precision from sample collection through laboratory analysis. Laboratory duplicates focus on precision of the analytical method. Based on the %RPD results on the duplicate analyses provided above and the goals for soil duplicates of 20% and for aqueous duplicates of 35%, the data has met the criteria. 6.6.2 Accuracy Accuracy is a measure of the bias in a system. It is the degree of agreement of a measurement with an accepted reference or true value. Accuracy for this project was estimated from the analysis of QC samples whose true values are known (surrogate or matrix spikes) and was expressed as percent recovery. EPA provided performance evaluation samples to the CLP laboratories including spike samples. These were analyzed by the CLP along with the site samples and reported. EPA SESD evaluated and validated the data according to the results reported by the CLP. The reported analytical qualitative and quantitative results of the spike samples were within acceptable limits for accuracy in CLP contract. CDM Fe<lernl Proi;:rnms Curporntion SPIN82/SEC1.\\'PD 6-8 I I I I I I I I I I I I I I I I I I I 6.6.3 Representativeness, Comparability Section 6 Quality Assurance Report Representativeness expresses the degree to which data accurately and precisely represent a characteristic of a population at a sampling point, process condition or environmental condition. Comparability expresses the confidence with which one data set can be compared to another. Representativeness and comparability are qualitative objectives which were met by following standard operating procedures for sample collection and analysis. 6.6.4 Completeness Completeness is the measure of the amount of valid data obtained from a measurement system compared to the amount that was expected to be obtained under current normal conditions. The completeness of the data set for this investigation is based on the number of valid data points. Data validation and evaluation effects completeness of the data. Some data was rejected. Table 2 presents the completeness data. Table 1 Soils Data Completeness Analytical Fraction Total Data Valid Data Rejected Data Set Points Points Data Points Completeness Metals 3,151 3,120 31 99.1% Volatile OrR;anics 4,422 4,409 13 99.7% Semivolatile OrR;anics 8,694 8,602 92 99.0% Pesticides/PCBs 4,030 3,680 350 91.3% Totals 20,297 19,811 486 97.3% COM Fedem! Proi;rams Curpor.niun SPINS21SEC1.WPO 6-9 I I I I I I I I I I I I I I I I I I I Analytical Fraction Metals Volatile Orf{anics Semivolatile Orf{anics Pesticides/PCBs Dioxins/Furans Totals Analytical Fraction Metals Volatile Orf{anics Semivolatile Orf{anics Pesticides/PCBs Totals Analytical Fraction Metals Volatile Orf{anics Semivolatile Or~anics Pesticides/PCBs Totals CDM Fe<lernl Proi;n1ms Curpomtion SPINB2/SEC1.WPD Section 6 Quality Assurance Report Table2 Sediment Data Completeness Total Data Valid Data Rejected Points Points Data Points 299 292 7 231 224 7 819 819 0 364 364 0 286 274 12 1,999 1,973 26 Table 3 Surface Water Data Completeness Total Data Valid Data Rejected Points Points Data Points 69 69 0 99 96 3 189 189 0 84 84 0 441 438 3 Table 4 Groundwater Data Completeness Total Data Valid Data Rejected Points Points Data Points 322 322 0 462 462 0 882 868 14 392 336 56 2,058 1,988 70 Data Set Comoleteness 97.6% 97.0% 100.0% 100.0% 95.8% 98.1% Data Set Completeness 100.0% 97.0% 100.0% 100.0% 99.2% Data Set Completeness 100.0% 100.0% 98.4% 85.7 96.0% 6-10 I I I I I I I I I I I I I I I I I I I Section 6 Quality Assurance Report The EPA SESD Work Plan had established a completeness goal of 99% for this project for DQO level IV analytical results. This goal was not met except for the surface water samples. However, the remaining media and data set completeness was better than 96% which is generally acceptable for this type of sampling and analysis. 6.7 Audits 6.7 Audit Findings As part of CDM Federal' s Quality Assurance Program, various projects are selected quarterly for auditing. Auditing can be either system or performance audits. Performance audits are quantitative checks on different segments of project activity; they are most appropriate for field measurements and for laboratory analysis activities. System audits are qualitive reviews of project activity to check that the overall CDM Federal QA program is functioning and any project-specific QA and QC requirements are being met. System audits are generaIJy performed on a selected number of projects per calendar quarter. This project was not selected for audit of the field activities by CDM Federal Quality Assurance management since EPA performed the field work. However, an office audit will likely be performed to check office files. COM folml Pmi:rnms Corporatilln SPINB21SEC1.vVPD 6-11 I I I I I I I I I I I I I I I I I I I 7.0 RI Summary and Conclusions The Georgia Pacific Site was placed on the National Priorities List under the Comprehensive Environmental Response, Compensation, and Liability Act in October 1999, and therefore was designated for an RI/FS. In 1998, EPA initiated the RI/FS to address all contamination at the site. The primary objective of the RI was to provide the additional data needed to support a baseline risk assessment and provide a basis on which to recommend a subsequent remedial action for the site. The RI was divided into five parts: • • • • • A soil sampling investigation (Section 2.0) A surface water/ sediment sampling investigation (Section 3.0) A groundwater sampling investigation (Section 4.0) A contaminant transport and fate evaluation (Section 5.0) A baseline risk assessment (submitted separately) The details of each of these investigations are presented in their appropriate sections and should be consulted for a full understanding of the results of the RI. The major conclusions reached as a result of the RI include the following: • Analyses of soil samples collected indicate extensive contamination by dioxins/ furans, P AHs, PCBs, and inorganics. This contamination seemed to be focused in an area centrally located on the site property where most past operations were located. However, following the removal action, selected contaminated grids and other waste materials located onsite were removed from the site. There was indication of • off site contamination from site related constituents, however the concentrations were lower than onsite concentration. The results of the baseline risk assessment indicate that while the current human health risks associated with the levels of contamination found in the soils at the site are within EPA's acceptable target range, the potential future human health risks are slightly above EP A's acceptable target range, primarily due to the presence of dioxins/furans, carcinogenic PAHs, and arsenic. Surface waters at the site discharge into the Roanoke River. Analyses of surface water and sediment samples collected from the intermittent drainage ditches located onsite indicate significant contamination by arsenic and manganese in surface water, and by dioxins/ furans, acetone, methyl ethyl ketone, PAHs, arsenic, lead, and zinc in sediments. CDM Federal Programs Corporation SPIN2B1SECT7 7-1 I I I I I I I I I I I I I I I I I I I • Section 7 RI Summary and Conclusions The results of the baseline human health risk assessment indicate that both the current and potential future human health risks associated with the levels of contamination found in the intermittent drainage ditches are within EPA's acceptable target range. The site is underlain by a surficial unconfined aquifer. Groundwater flow at the site is likely toward the Roanoke River, where it discharges. Analyses of groundwater samples at the site indicate significant contamination by arsenic and manganese. The results of the baseline risk assessment indicate that the potential future human health risks associated with the levels of contamination found in the groundwater are significantly above EPA's acceptable target range, primarily due to the presence of arsenic. In addition, the concentrations of some of the contaminants found are above MCLs. Based on the results of the RI, the following actions are recommended: • • Remedial action objectives for soil and groundwater contamination at the site should be established based on human health exposure.risks, as well as the potential for future contaminant migration from one medium to another (e.g., soils to groundwater). Alternatives for reducing soil and groundwater contamination at the site to achieve the established remedial action objectives should be evaluated, and the most cost-effective alternative for each implemented. CDM Federal Programs Corporation SPIN28/SECTT 7-2