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HomeMy WebLinkAboutNCD000770487_20030429_Johnson Controls Battery Group_FRBCERCLA RA_Groundwater Sampling-OCRJuly 16, 2003 Mr. Luis Flores Remedial Project Manager USEP A Region IV 61 Forsyth Street, 1 1th Floor Atlanta, Georgia 30303 Re: Groundwater Sampling Results April 29, 2003 Winston-Salem Facility Dear Luis: MWH Americas, Inc. (MWH) completed the second round of groundwater monitoring at the JCBGI Winston-Salem facility on April 29, 2003. This letter presents the methods and results of the sampling. Also attached is a copy of the comments we received from Randy McElveen (NCDENR) on a draft copy of this same report, which he requested prior to sending the report final to US EPA. We responded to Specific Comment #1 in this final report to US EPA for clarification of the scope actually conducted during this sampling round with the inclusion of SVOC analysis at MW0I. However, we believe that Specific Comments #2 through #4, regarding future groundwater monitoring requirements for the site, should be addressed as a permitting issue between JCBGI and NCDENR outside of the EE/CA process. The EE/CA process is complete with respect to investigation for the purpose of designing an appropriate remedy, of which groundwater monitoring was a part. The completion of this second round of groundwater monitoring confirms that no remedial action for groundwater was appropriate, as presented in the EE/CA. Based on our review of this second round of data, we provide our recommendations for US EPA 's consideration at the close of this report. The groundwater sampling confirmation round 'includes analysis of metals, volatile organic compounds, and pesticides in groundwater. Semi-volatiles and PCBs were explicitly excluded from the list of analytes, based on the first round of sampling results reviewed from the EE/CA investigation. However, by agreement with NCDENR, SVOCs were included in the list of analytes for upgradient well MW0l, only, because this well had a previous detection of bis(2-ethylhexyl)phthalate, a common sampling contaminant, above it's MCL. The Quality Assurance Project Plan (QAPP) and Field Sampling Plan (FSP) previously developed for the EE/CA guided this second round of confirmation groundwater sampling and analysis. A. Groundwater Sampling Methods The field technicians sampled each of the 6 monitoring wells (MW-01 through MW-06) using low-flow purge sampling techniques to obtain representative groundwater samples. Prior to groundwater sampling, each monitoring well was purged. A clean plastic drop cloth was spread around the well prior to purging. Purging was accomplished by removing groundwater from the monitoring wells using a decontaminated, low-flow submersible pump with new dedicated polyethylene discharge tubing. Purging continued until water quality parameters, including pH, temperature, redox, conductivity, and turbidity, stabilized and a minimum of 3 and maximum of 5 well volumes were removed or the well was pumped dry. Purge water was containerized in 55-gallon drums. One Science Court P.O. Box 5385 Madison, Wisconsin 53705-0385 Tel: 608 231 4747 Fax: 608 231 4777 Oeliverinp innovative Projects and Solutions Worldwide • • Once the wells were properly purged, groundwater samples were collected. The groundwater samples for total metals analyses were collected directly from the polyethylene tubing. The groundwater sample for dissolved metals analyses were field filtered using a 0.45-micron inline filter with the polyethylene tubing and discharged into the sample containers. The groundwater samples for VOCs and organochlorine pesticides analyses were collected using a new, clean Teflon® bailer. Groundwater samples were placed in appropriate sample containers, preserved, properly labeled, and stored on ice. Chain of custody procedures were followed for collection and shipping the samples. Field quality control (QC) samples were collected to assess the quality of the analytical data and to evaluate sampling and analytical reproducibility (precision). Field quality control samples consisted of one each of a duplicate sample, field blank, matrix spike/ matrix spike duplicate, and trip blank. Each QC sample was analyzed for all scheduled parameters, except the trip blank, which was analyzed for VOCs, only. The groundwater level and total depth of each monitoring well were measured using an electronic water-level indicator to an accuracy of 0.01 feet prior to purging the well. The water-level indicator was rinsed with deionized water prior to each use. The depth to groundwater was recorded in the field logbook and the well volume was calculated. Liquids from the decontamination of sampling equipment and sample purge water were contained in 55-gal drums for later disposal or treatment by facility management. B. Water Quality Analyses Each of the six groundwater samples and QC samples were analyzed for the following parameters: Total TAL Metals Dissolved T AL Metals voes Organochlorine pesticides 3005A/6010B/7470A 3005A/6010B174 70A 5030B18260B 8081 In addition, the sample from well MW-01 was analyzed for SVOCs (Method 8270C). The samples that were field filtered (FF) represent the Dissolved T AL Metals results. CompuChem Laboratories of Research Triangle Park, NC conducted the analyses of the groundwater samples. C. Water Quality Results The groundwater analytical results are presented in the attached Tables 1 through 4. The April 29, 2003 data is presented adjacent to the January 29/30, 2001 data previously submitted. Data qualifiers presented with the results are summarized and presented following the tables. The following is a brief discussion of each class of parameters. 1. Metals The following two tables present the minimum, mean, and maximum concentrations of total and dissolved select metals, along with the number of detections from the six groundwater monitoring wells. Please note that, the minimum value is the minimum detected value (not non-detect, unless no detections were noted in any samples). The mean is calculated from samples with detected concentrations. Further, QA duplicate samples are not included within the number of detections. The tables below also identify the I SA Mr. Luis Flores July 16 2003 USEPA Region IV Page 2 • • NCA 2L groundwater standards and the monitoring well locations where standards are exceeded. Total Select T AL Metals in Groundwater Cadmium ND ND ND 0 1.8 Co er 4.3 4.3 4.3 I 1000 Iron 80.4 726.1 2320 4 300 MW0I MW06 Lead 4.9 4.9 4.9 I 15 Man anese 16.5 2 I 1.3 996 6 50 MW0I MW05 MW06 Nickel 3.5 5.6 7.1 3 100 Total ND ND ND 0 I.I Mercur Zinc 10.2 21.2 36.6 5 1050 *Sample locations: MW0I-MW06 Dissolved Select T AL Metals in Groundwater Cadmium ND ND ND 0 1.8 Co er ND ND ND 0 1000 Iron 52.9 312.0 571 2 300 MW06 Lead ND ND ND 0 15 Man anese 15.6 541.5 3060 6 50 MW0I MW05 MW06 Nickel 1.4 1.9 2.7 2 100 Total 0.13 0.13 0.13 I.I Mercur Zinc 19.1 21.9 27.1 3 1050 *Sample locations: MW0I-MW06 Based on the information presented in the tables above, only total manganese was detected in all 6 groundwater samples above the reporting limits. In contrast, total lead was detected in only one sample (MW-01, 4.9 ug/L). Total aluminum and total iron were detected in 5 and 4 samples, respectively. Concentration ranges and mean values of total metals from the April 2003 sampling are comparable to the January 2001 sampling, except that 5 samples had total aluminum above detection limits in the current sampling, as compared to only one in the previous sampling. As expected, the number of detections of dissolved metals from filtered samples is generally less than the total metals detections. The exception is at well MW06, where several metals were higher in the filtered sample than the total samples. The manganese concentration was high enough in the filtered sample for MW06, that it skews the mean value of the filtered samples. Similar to the total metals, only manganese was detected in all 6 filtered groundwater samples. Lead was not detected in any of the filtered samples. Aluminum was apparently filtered out of the samples, since none was detected. Maximum iron and manganese concentrations are higher in the April 2003 sampling than the January 2001 sampling. Groundwater standards were exceeded only for iron (in upgradient wells MW0\ and MW06) and manganese (in wells MW0I, MW05, and MW06) in the total metal analyses. Similarly, standards were exceeded in the dissolved metal analyses for iron (in well Mr. Luis Flores July I 6, 2003 Page 3 USEPA Region IV • • MW06) and manganese (in wells MW0I, MW0S, and MW06). Iron and manganese are generally ubiquitous in the environment and likely do not represent Site-derived contamination. No other total or dissolved metals analyzed beyond the select metals exceeded a groundwater standard. The data confirm the site is not an important source of metals to the groundwater. The iron and manganese concentrations are naturally occurring and are not considered Site-derived contamination. 2. SVOCs No SVOes were detected in the April 2003 groundwater sample from MW0I. 3. voes The table below presents the list of voes detected in groundwater monitoring at the site, the list of voes detected in April 2003 groundwater monitor, the I SA NeA 2L groundwater standards, and the wells which exceeded the standard: '"~wl!~:m;'?\\1/'iliB'y,,,i l~· , ~~ -.:t~~!'<!;i. ·1 .. ~,~ : *P.arameter1~~; .. ,,1. · , if~ ~- ~i,,m2003~~11! -oetffiii>iTslll ~ # of Samoles 6 (1) 1, 1,2.2 Tetrachloroethane 0 1,2 4 Trichlorobenzene 0 1,2,4 Trimethvlbenzene MW01,MW05 1,2-Dichlorobenzene 0 1,3,5-Trimethvlbenzene MW05 1,3-Dichlorobenzene 0 1 4-Dichlorobenzene 0 2-Butanone MW0I. MW05. MW06 2-Hexanone 0 Acetone MW0l, MW02, MW03, MW04, MW05, MW06 Benzene MW01,MW04, MW03 Duo Chlorobenzene MW04 MW05, MW06 Bromodichloromethane 0 Carbon Disulfide 0 Chloroform MW0l, MW02, MW03, MW04. MW05. MW06 Chloromethane 0 Cis-1,3-Dichloronronene 0 Dibromochloromethane 0 Methylene Chloride MW0l, MW02, MW03, MW04, MW05, MW06 m&o Xvlenes MW0l o-Xvlene 0 Stvrene 0 Tetrachloroethvlene 0 Toluene MW0l, MW02, MW03, MW04, MW05, MW06 Trans-1-3-Dichloronronene 0 Trichloroethylene MW0l, MW04, MW05, MW06 ( 1) Sampling Locations: MW0 1 through MW06. (2) Value is for total xylenes m, p & o til5l\'\NGA',2£'.¥ IWlC:wlst~~ 50 70 350 620 350 620 75 170 280 700 1 50 0.6 700 0.19 2.6 0.2 0.41 5 530 /2) 530 (2) NS 0.7 1000 0.2 2.8 Mr. Luis Flores July 16 2003 Page 4 ~-11~~~-'E""'"• if'tu/Stif wxceem ., .. MW02,MW03, MW04,MW05 USEPA Region IV • • Groundwater data indicates the presence of several voes detected at very low levels in site monitoring wells. Several of these additional voes are apparently petroleum related (benzenes, xylenes, toluene) and others are chlorinated or propenated compounds. The April 2003 monitoring detected very minor amounts of 2-butanone, chlorobenzene, and trichloroethylene, which were not detected in the January 2001 sampling. In contrast, several compounds detected in the January 2001 sampling were not detected in the April 2003 results from any of the wells. In particular, background well MW0I had nine compounds detected in the current sampling compared to 16 compounds in the previous sampling. Some compounds were detected in all 6 monitoring wells, including acetone, chloroform, methylene chloride, and toluene, and appear to be present in both up gradient wells (MW0I, MW04, MW06) and downgradient wells (MW02, MW03, and MW0S). Several VOCs (methylene chloride, toluene, xylenes, dichlorodifluoromethane) were detected at low levels in the laboratory blanks, and their results are qualified on the summary table. Most other compounds were detected in a combination of upgradient and downgradient wells. Acetone and methylene chloride was detected in other media from sampling conducted during the EE/CA, but these constituents are often considered laboratory contaminants. Neither toluene nor chloroform was detected in other media than groundwater from the EE/CA. Nearly all of the VOC values were reported as estimated, because the values were lower than the reporting limit but higher than the detection, with the exception of some acetone and chloroform results. Only chloroform exceeded a I SA NCA 2L groundwater standard of all_ the VOC detections. Chloroform concentrations barely exceeded the standard (0.19 ug/L) in 4 of the 6 groundwater samples in which it was detected, ranging from 0.2 ug/L to 0.3 ug/L. All 4 samples where exceedances occurred were qualified as estimated values by the - laboratory. Chloroform is a trihalomethane, often associated with drinking water treatment. These VOC data confirm previous results that the Site is not an important source of VOCs to the groundwater. 4. Pesticides The table below presents the list of pesticides detected in groundwater monitoring at the site, the list of pesticides detected in April 2003 groundwater monitor, the I SA NCA 2L groundwater standards, and the wells which exceeded the standard: ~}~earameterffic;c·_a_ .... ti-·a·[III &1fil'~f5:A!N6'A'i2L~1ttl i~wen~, ~1~tea1~~ -·, . lt",':~~ , r . i ~ rm ~-~,. . ..,.~ ;i:,.lk't i·v\,-wr:!f;' , i'~ .,';!~£bO,DS~,,:.:... i :.~-,ri ~ GW,Stils.~ . fl/ Jl).~_~eea.1.\!gl~!!,!.i , .... ""•"··""""'"' j_ . -~--J.. •. i,;;{-,-.,...c,,. .... :r. . # of Samples 6 Samnle Locations MW0l throu~h MW06 Aldrin 0 NS Alpha BHC 0 0.019 (I) Aloha Endosulfan 0 NS Aloha Chlordane 0 0.027 Beta BHC 0 0.019(1) DDD 0 0,14 Delta BHC MW06 0.019 /1) MW06 Endrin ketone 0 2,1 Gamma Chlordane 0 0.027 Hwtachlor MW06 0.008 MW06 Heptachlor Expoxide 0 0.004 (I) Value 1s for total BHC Mr. Luis Flores July I 6, 2003 USEPA Region IV Page 5 • • Two pesticide compounds were detected in the groundwater sample from well MW06 in the April 2003 groundwater monitoring compared to 10 compounds detected in up to 4 wells in the January 2001 monitoring. Only minor concentrations of delta BHC (0.078 ug/L) and Heptachlor (0. 13 ug/L) were detected, both in upgradient well MW06 in April 2003. Both of these compounds exceeded their respective I SA NCA 2L groundwater standard. Heptachlor had not been detected in the January 2001 results. Well MW06 is considered an upgradient well, so these compounds may not be Site-related. Further, no pesticides were detected in downgradient wells at the Site. Overall, these pesticide results present an improvement in water quality since the January 2001 monitoring. The data confirm that the Site is not an important source of pesticides to the groundwater. · D. Groundwater Flow I. Water Levels A summary of water level measurements from the monitoring wells and staff gages is presented in the attached table. The depth to groundwater on April 29, 2003 ranged from approximately 24 ft (MW04) to 37 ft (MW0S) below land surface. Groundwater elevations· on April 29, 2003 ranged from 882.15 ft ms! at well MW06, at the southeast comer of the Facility building, to 851.74 ft ms! at well MW02, located downgradient from the north end of the Facility building. The depths to water measured at each well are consistent with data collected in 2001. 2. Groundwater Flow Similar to the previous interpretation of groundwater elevations (EE/CA Figure 5), groundwater flows from the topographically high area around the Facility toward the west and northwest, in the direction of Lowery Mill Creek. The topographically high area around the Facility is likely a local groundwater recharge area, while the wetlands and Lowery Mill Creek are the groundwater discharge areas. E. Conclusions Based on the results of the April 2003 groundwater monitoring, the following conclusions are drawn: • Lead was only detected in one groundwater sample, and its concentration was below the I SA NCA 2L groundwater standard. Groundwater standards were exceeded only for iron and manganese in the total and dissolved metal analyses. Iron and manganese are generally ubiquitous in the environment and likely do not represent Site-derived contamination. • No SVOCs were detected in groundwater. • Groundwater data indicates the presence of several VOCs detected at very low levels, in site monitoring wells. Only chloroform exceeded a I SA NCA 2L groundwater standard of the VOC detections. The four samples where exceedances occurred were qualified as estimated values by the laboratory. Mr. Luis Flores July 16 2003 Page 6 USEPA Region IV • • • Only two pesticide compounds were detected in one upgradient well, but both exceeded groundwater standards. Ten compounds were detected in up to 4 wells in the January 2001 monitoring, so these current results present an improvement in water quality. Pesticides may not be Site related. These results groundwater. necessary. indicate that the Site is not an important source of contaminants to the Therefore, we recommend that no further groundwater monitoring is If you have any questions about this information, please contact the undersigned. Sincerely, MWH AMERICAS, INC. ~~iu_~ Daniel W. Hall, PG Project Manager Enclosure: Summary Tables of Groundwater Analytical Data Summary of Water Table Elevations NCDENR letter dated July 3, 2003 cc: Timothy J. Lafond, JCBGI Randy McElveen, NCDENR Dennis Reis, LLC DWH/vlr/LBL N :\lobs\208\2593\01 \wp\ltr\99 Flores.doc 2082593.01160101-MADI - Mr. Luis Flores July 16, 2003 Page 7 USEPA Region IV Location ldmtification MW-01 Field Sample Identification MW-01 Sample Type Nonna\ Date Collected 1/29/2001 Fixed Lab Metals (pg/I) Aluminum 299 * Antimony <3.5 u Arsenic <3.9 un Barium 44.4 eJ Bcryllium <0.2 u Cadmium <0.4 u Calcium 2340 * Chromium. Total 4.6 b Cobalt 4.9 b Copper 6.3 U ''°" 527 *nJ Lead 12.9 Magnesium 1180 Manganese 747 * Mercury <0.1 u Nickel 7.9 Potassium 2270 * Selenium <3.9 unR Silver <0.8 u Sodium 3570 eJ Thallium <5.1 un Vanadium 1.2 b Zinc 37.5 Notes: I. NS= No Standard established 2. (FF),. Field filtered. 3. Qualifiers summarized at end of section. ATF/vh-/LBL N:\Jobs\208\2593\GW Quality.ds (FIXED METALS IN WG) 2082593.0I 160101 MADI 7/16/2003 MW-OJ MW-01 Normal 4/29/2003 1550 <\Ou <JO u 68.4 e 0.16 b <5" 551 be 9.7 4b 4.3 b 2320 4.9 l040e 130 e <0.2 u 7.1 2410 <5" <5" 1220 b <!Ou 6.6 b 36.6 * MW-01 (FF) MW-01 Normal 1129noo1 <13.8 u <3.5 u <3.9 u 34 <0.2 u <0.4 u 2140 <0.9 u 4.0b 5.7 U <9.8 u 5.3 1050 653 <0.1 u 4.8bU 1960 <3.9 un <0.8 un 2500 eJ 7.0bU <0.5 u " SUMMARY OF FIXED METALS RESULTS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. WINSTON SALEM, NORTH CAROLINA PLANT AREA MW-01 (FF) MW-02 MW-02 MW-01 MW-02 MW-02 Nonna! Normal Normal 4129noo3 l/29/2001 4/30/2003 <\OOu 383" 23.2 b <!Ou <3.5 u <\Ou <\Ou <3.9 un <!Ou 41.9 e 46.5 eJ 52.3 e <5" <0.2 u 0.47 b <5" <0.4 u <5" 439 b 4320 * 2760 e <5" 11.6 1.3 b 2.3 b 2.6 b <5" <5" 4.5 bU <5" <\00 u 567 *nJ <IOOu <3" 4.o <3" 586 b 894 b 716 be 64.8 e 112 * 16.8 e <0.2 u <0.1 u <0.2 u 1.7 b 17.8 <5" 1830 1750 * 1600 2.6 un <3.9 unR <5" <5" <0.8 u <5, 776 b 6150 eJ 4110 <IOu <5.1 un <!Ou <20, 0.89 b <20 u <20, 40.1 U 17.7 b* I of 3 MW-02 (FF) MW-02 (FF) MW-03 MW-03 MW-02 MW-02 MW-03 MW-03 HH SSL Normal Nonna! Nonna! Normal Groundwater 1n912001 4/30/2003 113onoo1 4/30/2003 15A NCA 2L <13.8 u <IOOu 1160 * <IOOu NS • <3.5 u <!Ou <3.5 u 4.8 b NS <3.9 u <!Ou <3.9 un <\Ou 0.02 37.3 51 • 40.3 eJ 66.8 e 2,000 <0.2 u 0.41 b 0.21 bU, J <5" NS <0.4 u <5" <0.4 u <5" 1.8 4210 2490 28300" 11500 e NS <0.9 u <5" 7.8 3.3 b 50 L7bU <5" 2.9 bJ. <5, NS 4.8 bU <5" 3.1 bU.J <5" 1000 10.6 b <IOOu 1210 *nJ <I00u 300 <2.6u <3" <2.6u <3 " 15 818 b 726 b 4630 4520 e NS 96.5 16.3 e 268 * 16.5 e 50 <0.J u <0.2 u <0.1 u <0.2 u 1.1 6.6 <5" 6.8 U <5" 100 1700 1830 5990" 3520 NS <3.9 un 2.6 un <3.9 unR <5" 50 <0.8 un <5" <0.8 u 0.87 b 17.5 5120eJ 4100 8870 eJ 5890 NS 7.1 bU <!Ou <5.1 un <10 u NS <0.5 u <20, 4.0 bJ I.I b NS 30.4 <20, 15.6bU 19.6 b* 1050 • location Identification MW-03 Field Sample Identification MW•DUP-01 Sample Type Field Duplicate Date Collected 1/30/2001 Fixed Lab Metab (µg/1) Aluminum 884 * Antimony <3.5 u Arsenic <3.9 un Barium 30.2 eJ Beryllium <0.2 u Cadmium <0.4 u Calcium 23500 * Chromium, Total 124 Cobalt 4.2 b Copper 66 .,. 1840 *nJ L<,d <2.6u Magnesium 4450 Manganese 291 * M=nry <0.1 u Nickel 110 Potassium 5170 • Selenium <3.9 unR Silver <0.8 u Sodium 7510 eJ Thallium <5.1 un Vanadium 3.1 b Zinc 96.8 Notes: I. NS = No Standard established 2. (FF) = Field filtered. 3. Qualifiers summarized at end of sect ATF/vlr/LBL N:\Jobs\208\2593\GW Quality.xis (FIXED METALS IN WG) 2082593.0i 160101 MADI 7/1612003 MW-03 MW-03 (FF) MW.DUP-01 MW-03 Field Duplicate Nonna! 4/30/2003 l/30/2001 <100 u <13.8 u <10 u <3.5 u <JO u <3.9 u 68.1 e 40.7 <5 n <0.2 u <5 n <0.4 u 12000e 18300 3.2 b <0.9 u <5" 3.7 b <5" 25.6 31.1 b 24.8 b <3 n <2.6 u 4710e 4650 16.8 e 297 <0.2 u <0.1 u <5 n 4.8bU 3910 4860 <Sn <3.9 un <5 n <0.8 un 6250 6830 eJ <!Ou 6.3 bU 1.7 b 1.7 b 19.S b* 41.6 SUMMARY OF FIXED METALS RESULTS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. WINSTON SALEM, NORTH CAROLINA PLANT AREA MW-03 (FF) MW-03 (FF) MW-03 (FF) MW-03 MW•DUP-01 MW-DUP-01 Normal Field Duplic.ate Field Duplicate 4/30/2003 I/J0/'2001 4/30/2003 <JOOu 259U <IOOu <IO u <3.5 u <10 u <10u <3.9 u <!Ou 63' 21 63 e <5 n <0.2 u <5 n <5 n <0.4 u <5 n 10900 24100 11000 2.4 b 24.4 1.9 b <5 n 3.7 b <5" <5 n 70.6 <5 n <IOOu 967 <IOOu <3 n <2.6u <3 n 4250 4440 4320 15.6 e 287 16 e <0.2 u <0.1 u <0.2 u <5 n 52.5 <5 n 3720 5310 3950 2.6 un <3.9 IW 2.6 un <5 n <0.8 un <5 n 5580 6720 eJ 5590 <10 u 7.9bU <!Ou <20n 1.9b <20n 19.4 b 98.6 11.S b MW-04 MW•04 Normal 1/29/2001 60.5 b*U <3.5 u <3.9 un 74.6 eJ <0.2 u <0.4 u 2790 * <0.9 u <0.6 u <0.9u 72.1 b*nU, J <2.6 u 881 b 904 * <0.1 u 2.4 bU 3770 * <3.9 unR <0.8 u 4430 eJ <5.1 un <0.5 u 7.9bU 2 ofJ MW-04 MW-04 (FF) MW-04(FF) MW-04 MW--04 MW·04 HIISSL Normal Normal Normal Groundwater 4/29/2003 1/29/2001 4/29/2003 ISA NCA 2L 49.7 b <13.8 u <IOOu NS • <10 u <3.5 u <!Ou NS <10 u <3.9 u <I Ou 0.02 64.5 e 70.8 60.2 e 2,000 <5 n <0.2u <5 n NS <5 n <0.4 u <5 n 1.8 916 be 2780 885 b NS 1.9 b <0.9u I b 50 <5" <0.6 u <5 n NS <5" 2.3 bU <Sn 1000 80.4 b <9.8 u <lOOu 300 <3 n <2.6u <3 n 15 447 be 856b 413 b NS 38.1 e 826 31.Je 50 <0.2 u <0.1 u 0.13 b 1.1 <5 n 2.7bU <5 n 100 3460 3770 3460 NS <5 n <3.9 un 2.6 un 50 1.2b <0.8 un <5 n 17.5 1960 b 3520 eJ 1570 b NS <10 u 7.4 bU <I Ou NS <20n <0.5 u <20u NS 22. 6.0bU 19.1 b 1050 • location Identification Field Sample Jdt11tificatio11 Sarnplt Typt Datt Collected Fixed Lab Metals (pg/I) Aluminum Antimony Arsenic Bariun1 Beryllium Cadmium Calcium Chromium, Total Cobalt Copper Iron Lead Magnesium Manganese Mercury Nickel Potassium Selenium Silver Sodium Tha\lium Vanadium Zinc Notes: I. NS = No Standard established 2. (FF)._ Field filtered. 3. Qualifiers summarized at end of sect ATF/vlr/LBL N:\Jobs\208\2593\GW Quality.xis (FIXED METALS IN WG) 2082593.01160101 MADI 7/1612003 MW-OS MW-OS MW-05 MW-05 Normal Normal 1/30/2001 4129/2003 970 * 90 b <3.5 u <\Ou <3.9 un <\Ou 62.9 eJ 52.5 C <0.2 u <5" <0.4 u <5" 1580 * 559 be 20 8.9 u 5.0 1.4 b 7.7U <5" 1360 *nJ 184 5.5 <3" 936 b 583 be 404• 70.6e <0.1 u <0.2 u 18.S "' 3150 * 2670 <3.9 unR <5" <0.8 u <5" 4920 eJ 1680 b <5.1 un <\Ou 2.8 b <20 u 25.1 15.3 b" SUMMARY OF FIXED METALS RES.UL TS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. WINSTON SALEM, NORTH CAROLINA PLANT AREA MW-05(FF) MW-05 (FF) MW-06 MW-05 MW-05 MW-06 Normal Normal Normal 1!3012001 4/29/2003 1/3012001 273 <JOOu 168 •u <3.5 u <\Ou <3.5 u <3.9 u <\Ou <3.9 un 45.8 46. 43.S eJ <0.2 u 0.13 b <0.2 u <0.4u <5" <0.4u 1450 526 b 3660" <0.9 u 1.8 b 1.3 b l.7bU 1.2b <0.6u 4.5bU <5" 2.7bU 212 52.9 b 176 *nJ <2.6 u <3" 5.4 761 b 531 b 1190 326 60.8 e 1130* <0.1 u <0.2 u <O.J u 5.5 U 2.7 b 2.9bU 3030 2580 2900 * <3.9 un 2.6 un <3.9 unR <0.8 un • <5" <0.8 u 3740 eJ 1650 b 4580 eJ 6.4 bU <\Ou <5.1 un <0.5 u <20, <0.5 u 10.4 bU <20" 13.4bU 3 of3 MW-06 MW-06 (FF) MW-06 (FF) MW-06 MW-06 MW-06 HH SSL Normal Normal Normal Groundwater 4/29/2003 1!3012001 4/29/2003 ISA NCA 2L 133 <13.8 u <\OOu NS • <\Ou <3.Su <\Ou NS <10 u <3.9 u <\Ou 0.02 58.4 e 38.8 57.4 C 2,000 <5" <0.2 u <5, NS <5" <0.4 u <5" 1.8 2080e 3710 3470 NS 6.7 <0.9 u 0.89 b 50 <5" <0.6 u <5" NS <5" 3.5 bU <5" 1000 320 <9.8 u 571 300 <3" 4.7 <3" 15 996 be 1140 1250 NS 967 e l050 3060 e 50 <0.2 u <0.1 u <0.2 u 1.1 3.S b 4.2bU 1.4 b 100 3110 28IO 3090 NS <5" <3.9 un 2.6 un 50 <5" <0.8 un <5" 17.5 2560 3790 eJ 2360 NS <JO u 8.1 bU <!Ou NS <20" <0.5 u <20" NS 10.2 b* !2.3 bU 27.1 1050 • Location lden1ijkt1tion Field Sa,,.pfe ldenl/fittlfion Sa,,.ple TJ.pe Dt11t' Collected Vola!tle Ora:ank Compounds {µefl) ].I .1-TrichlorOf'lhane I , 1,2,2-Teirac:hloroeth.we 1.1.2-Trichloroethane I, 1-Dichloroethane I, 1-Dichloroethene I .2,4-Trich!orobcnune 1.2,4-Trimethyfbenzenc t .2-Dichlorobenzene 1.2-Dichloroethane 1,2-Dichloroprop:me 1.3.S•Trimethylbenzene (Mesitylrne) 1,3-Dich\orobenzene 1,4-Dich!orobenzene 2-B11tanone (Methyl ethyl ketone) 2-Hexanone 4-Melhy\-2-pentanone (Methyl isobutyl ketone) Acetone ·-· Bromodiehloromethane Bromofonn Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromclhane cis-1,2-Dichloroethylenc cis-1.l-Dichloropropene Dibromochloromelhane Dibmmomethane DichJorodinuoromethane Elhylbcnzene Hela,;hlorob11w:lirnc Xylcncs, o &. m Methylene chloride o-Xylrne (l .2·Dimethylbcnzene) s,,,.. Tetrachloroelhylcne(PCE) Toluene trarui-1,2-Dichloroethenc trans· l ,J-Dichloropropenc T richloroethylenc: (TCE) TrichloroOuoromethane Vinyl acetate Viffyl chloride Notes: I. NS-No Standard established 2 Qualifim summarized at end ofse,;tion ATF/vlrlLBL N:IJobs\20812593\GW Quality.ds (VOC JN WG) 2082593.0I 16010! MADI 711612003 SUM~1ARY Of \'OLA TILE ORGANIC COMPOUND RESULTS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. MW-01 MW-01 MW-01 MW..01 Normal Normal 1n9noo1 4/29nOOJ <0.5 II <0.5 u <0.5 u <0.5 II <0.5 u <0 5 II <O 5 u <0.5 u <O.Su <0.5 u o.s J <0.5 u 0.2 JJ O.o2Jh O.J JJ <O 5" <O.S u <0.5 u <0 5 II <0.5 u 0.2 JJ <0.5 u 0.2 JJ <O.S u 0.3 JJ <0.5 II <3.0 II IJ 2.0 JJ <3' <3.0 u <" 14 UJ 2 J <0.5 II 0.08 Jb 1.0 J <0.5 u <0 Su <0.5 II <O.S II <0.5 II <0.5 II <O.S 11 <O.S 11 <0.5 u <O 5" <0.5 II <0.5 u <0.5 II 9.0 J o.os J 0.7 J <0.5 II <O 5 u <O.S u <Q,5 II <0.5 11 0.2 JJ <0.5 II <O.S u <Q.5 II <0 5 II <0.5 II <0.5 u <0.5 II <O.S u <O Su 0.4 JJ 0.1 Jb <0.5 II 0.2 Jb 0.2 JJ <0.5 u 0.1 JJ <0.5 11 <0.5 II <0.5 u 0.3jUJ 0.4Jb <0.5 II <0.5 u <0.5 u <0.5 II <0.5 II 0.03 Jb <O.S 11 <0.5 II <1.0 II <!' <0.5u <0.5 u WINSTON SALEM, NORTH CAROLINA PLANT AREA MW..02 MW-02 MW-OJ MW.OZ MW-02 MW.OJ Normal Normal Normal Jn912001 4/JOnOOJ 11Jono01 <O.S u <O.S u <0.5 u <0.5 u <OS u 0.2 JJ <O 5 u <0.5 u <0.5 II <OS u <0.5 II <0.5 u <0.5 u <0.5 II <0.5 u <O.S u <O.S u <0 Su <0.S u <0.5 u <0.5 u <0.5 u <0.5 u 0.2 JJ <0.5 u <0.5 ll <0.5 u <0.5 11 <O.Su <0.5 u <0.5 U <OS u <0.5 u <0.5 U <0.5 u <0.5 u <0.5 u <0.5 u <0.5 II <3.0 u <3' <3.0 u <3 Ou <3' <3.0 u <3.0 u <3' <3.0 u 5.0 U IJ <3 0 II <O 5" <0.5 u <0.5 u 5.0 <0.5 II <0.5 u <0.5 u <0.5 u <O.S u <0.5 U <0 5 u <0.5 II <0.5 11 <0.5 II 0.9 J <O.S 11 <O.S u <0 5 11 <0.5 II <0.5 II <0.5 II <O.S u <0 5 11 <0.5 11 17 0.2 J 3.0 J <Q.5 11 <0.5 u <0.5 II <0.5 11 <0.S u <0.5 u <0.5 11 <0.5 II <Q.5 II 0.6 <0.5 II 0.2 JJ <0.5 11 <0.5 II <O 5" <0.5 11 <O.Su <0.5 u <0.5 II <0.5 u <0.S 11 <0 5 u <0.5 II <0.5 II <I.Ou <" <1.0 II <0.5 11 0.2 Jh <0.5 II <0.5 11 <0.S u <0.5 II <0.5 II <0 5 11 <O.S 11 <0 5 u <0.5 II 0.2jUJ 0.2JU 0.,4 jb <0.5 II <0.5 II <0.5 II <0.5 u <0.5 II <0.S u 0.2 JJ <0.5u <0.5 II <0.5 u <0 5 u <0.5 II <0.5 II <1.0u <!' <I.Ou <O.S II <0.5 u <0.5 II MW-OJ MW.OJ Normal 4/JMOOJ <0.5 u <0.5 u <0.5 u <0.5 u <O.S u <0.S u <0.5 u <0.5 u <0.5 II <0.5 u <O.S u <O.S u <0.5 II <J' <" <3" 2 J <0.5 u <0.5 II <O.S u <0.5 II <0.5 II <0.5 II <0.5 II <0.S u I <0.5 II <O.S u <0.5 II <O.S u <O.S u <0.5 II <0.5 II <0 5 II <!' 0.3 Jb <0.5 II <0.5 II <0 5 11 O.J Jb <0.5 II <0.5 II <0.5 II <0.5 II <,' <0.5 II I of2 MW-OJ MW-OJ MW-OUP-01 MW-DUP..01 HHSSL fleld Dupllcate field Duplkale Groundwater 1/JMOOI 4130/2003 !SA NCA lL <o Su <0.5 u ,oo <O.S u <0.5 u 0.17 <0.5 u <0.5 II NS <0.5 II <0.5 II 700 <0.5 II <0 5 II 7 <O 5 u <O.S u 70 <o.5 u <0.5 u 350 <0.5 u <0.5 u 6,0 <o.s u <O.S 11 0.38 • <o.s u <0.5 u 0.56 <0.5 II <0.5 u 350 <OS u <OS u "' <0.5 II <O.S 11 75 <3.0 II 'J ,10 <J,0 u <3' 2,0 <3.0 u <J' NS <3.0 II 3 700 <o.5 u 0.04 Jb ' <0,5 II <0.5 u 0.6 <o.s u <0.5 II 0.19 <0.5 II <0.5 11 NS "' <0.5 II 700 <o 5 u <0.5 u 03 <0.5 II <0.5 II 50 <0.5 u <0.5 u 2'00 3,0 J ' 0.19 <O 5' <0.5 u 2.6 <o.s 11 <0.5 II 70 <0.5 11 <O.S II 0.2 <o.5 u <0.5 II 0.41 <o s u <O.S 11 NS <O.S u <O.S u '400 <0.5 II <0.S 11 29 <o.s u <O.S u 0 .. • <I.Ou <,' 530 <0 5 II O.J Jb 5 <0.5 11 <0.5 II 530 <0.5 II <0.5 II NS <0.5 II <0.5 u 0.7 <0.5 u 0.3 Jb "''° <0.5 u <0.5 II 70 <Q.5 II <0.5 II 0.2 <0.5 II <0.5 II 2.8 <o.s 11 <0.5 u 2'00 <1 0 u <," NS <0.5 II <0.5 II 0.015 ATF!vlr/1.BL N:\Job!i\208\2593\GW Quality.xis {VOC IN WG) 2082593.0l 160101 MADI 7116/2003 SUMMARY OF VOLATILE ORGANIC COMPOUND RESULTS IN GROUNDWATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. lo,:atio11 lde11tijlc111io11 Fidd Sample fdc11tijie111io11 Sample T,-pe Date Col/med Volatllc Ore:i.nk Compounds (11£11) 1.1,1-T richlorocthanc I, l .2.2-Tc1rachlorocthanc I, l .2-Trichlorocthanc I. !-Dichloroctha:nc 1,l-Dichlorocthcnc 1.2.4-T rich!orobcnzenc 1,2.4-Trimethylbrnzrnc 1,2-Dichlorob=c l .2-Dichlorocthanc 1,2-Dichloropropane 1,3 ,5-Trimcthylbenzcne {Mcsitylcne) 1.3-Dichlorobcnzcnc I ,4-Dichlorobenzenc 2-B11tanonc (Methyl ethyl ketone) 2-Heunone 4-Mcthyl-2-pcntanone (Methyl isob11tyl ketone) Acetone -.. Bromodichloromcthanc Bromofonn Bromomethanc Carbon disulfide Carbon tetr:i.chloridc Chlorobcnzcnc Chlorocthanc Chloroform Chloromcthane cis-1.2-Dkhlorocthylcnc cis-1.3-Dichloropropcnc Dibromochloromcthane Dibromomethane Dich!orodi011oromcthane Ethylbcnzenc Hcxachlorobuiadicne Xylcncs. o &. m Methylene chloride o-X ylcne { 1,2-Dimethylbcnzcne) Styrene Tctrachlorocthylcne(PCE) Toluene lranS· \ ,1.-Diehlorocthcnc trans-1,.3-Dicbloropropcnc Trichlorocthylcnc (TCE) Trichlorofl11oromcthanc Vinyl acciatc Vinyl chloride Notes I. NS• No Standard established 2 Qu.alilieis s11mm.irixcd at end of5tttion MW-04 MW-04 Normal WINSTON SALEM, NORTH CAROLINA PLANT AREA MW--0-I MW-05 MW-04 MW-05 Normal Normal 11291200\ 4/29/2003 1/3012001 <o.s" <0 5 II <O.S 11 <0.5 II <0.S 11 <0.5 II <o.5 u <0.5 11 <0.Su <0.S u <0.5 II <0.S 11 <o s u <0.5 II <0 5 u <()'" <0 Su <0.5 II <0.5 II <OS u <0.5 II <0 5 II <0.5 II 0.3 jJ <0 5 II <0.5 II <0 5 u <0,5 u <0.5 II <0.5 II <0 5 u <0.S u <0.5 II <0.5 II <0 5 II 0.2 JJ <0.5 II <0.5 u 0.2 JJ <3.0 11 <3" <J.0 11 <3.0 II <3" <3.0 u <3,0 u <3" <3.0 II <3 0 u 3 10 UJ o.3 l 0.06Jb <0.5 II 1.0 <0.5 II 2.0 J <o.s u <0.5 II <OSu <0 5 II <0.5 II <0 5 u 3.0 <0.S u <0.5 II <o.s u <0.5 u <0.5 II <0.5 II · 0.04 J <0.5 II <0.5 II <0.5 II <0.5 II 12 0.2 J 10 J <o.s u <0 Su <0 5 u <0.5 II <0 5 11 <0.5 II <0.5 II <0.5 II 0.2 JJ <0 5 11 <0.5 II o.s J <o.s u <O'" <0 5 11 <0.5 II 0.06 j <0.5 u <0.5 II <0.5 II <0.S u <0.5 II <0.5 II <0.5 u <I.Ou <I" <1.0 u o., 0.J jb O.S UJ <0.5 II <0 S 11 0.2 JJ <o.s u <0.5 II <0.5 u <0.5 II <0.5 II <0.S u <0.5 II 0.3 Jb 0 2jUJ <0.5 u <O.S u <0.S u <0.5 II <0.S u 0.2 JJ <0.5 II 0.06Jb <0.5 u <o.s" <0.S 11 <0.5 u <LO u <I " <I.Ou <0 5 11 <0.5 II <0.S u MW-OS MW-06 MW-OS MW-06 Normal Normal 4/2912003 1/301200\ <0.5 11 <0.511 <0.5 II <0.S u <0.S u <0.5 II <0.5 11 <0,5 u <0.5 11 <0 5 II <0 5 11 <o.5 11 0.02 J <0.5 II <0.5 II <0.5 II <0.5 11 <0 5 II <0 Su <0.5 II 0.03 J <0.5 11 <0.5 II <o.s 11 <0.5 II <0.5 u I) <3.0 u <3" <3.0 II <3" <J.0u 3 8.0U <0.5 u <0.5 II <0.5 u 1.0 <OSu <0,5 u <0.S u <0.S 11 <0 5 II <0.5 II <0.5 II <0.5 II 0.Ollj <0.5 II <0 5 u <0,5 u 0.3 j " <0.5 II <0.5 II <0.5 II <0.5 II <0.5 II . <0.5 II <0.5 II <0 5 u <0.5 II <0.5 II 0.08 Jb <0.S u <0.S u <o.s u <0.5 u <0.5 II <'" <1,011 0.4Jb 0.SjU <0.5 II <0.5 II <0.S u <o.5 u <05 II 0.S U 0.2 Jb <OS u <0.S u <0.5 II <0.5 II <0.5 II 0.03 J <0.5 u <0.5 u <0.5u <I" <l.0 u <0.5 u <0,5 II 2 of2 MW-06 MW-06 HHSSL Normal Groundwater 4/2912003 JSA ~CA 2L <0.5 II 200 <0.5 II 0.17 <O'" NS <0.5 II 70-0 <0.5 u 7 <0 5 11 70 <0 5 11 350 <0.S 11 620 <0.5 II 0.38 • <0.S u 0.56 <0.5 II 350 <0.5 II "° <0.S 11 75 2 J 170 <3" 280 <3" NS 3 700 <0.5 u I <0.5 II 06 <0.5 II 0.19 <0.S 11 NS <0.5 u 700 <0.S u 0.3 0.06 J so <0.5 u 2800 0.1 J 0.19 <0.S u 2.6 <0.5 II 70 <0 5 II 02 <0.5 II O<I <0.5 II NS 0.07 Jb 1'00 <0.5 II 29 <0.5 II 0.44 • <I" 530 0.S jb ' <O.S u 530 <0.S 11 NS 0.8 0.7 0.l Jb 1000 <0.5 u 70 <0.5 11 0.2 0.03 J 28 <0.5 II 210-0 <I" NS <0.5 u 0.015 • • SUMMARY OF SEMI-VOLATILE ORGANIC COMPOUND RES UL TS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. IA<•tlon Utnfifk•rlon MW-01 Flt" Snmplt Utnrl/fcfflon MW-01 S11mplt Typt Non1>1,I Dalt C,ll«tU l/l91lOOI Srm&-Volatlle OrJ:111le Compouadl (Jit/1) 2.2'-<nybil( l..:hk:,rolf'i-op111e 2.4.3,T ricblomphniol 2.4,6• Ttid1lomphcnol 2,4-Dithlomphcnol l,4-T>in-..thyl ph<:nol ~-4-Dini1ropbtnol ?,4-Dinitrotoluaie 2,6-Dini1r0toluaoc 2-Chlo,onaphlhalcnc 2-ChlomphcDOl 2-Mt'lltylnaphlh.ale>c: 2-Mffll)'!phcnol 10-c, .. 01) 2-Nitroanilinc 2-Nill'OJlbcnol J , l ' -Dichlorobenzidinc 3-Nitro,u,ilinc 4,6-0initro-2-m:lhylphalol 4.Brurmpbcnyl phenyl dhcf 4-Chloro-)-melhylpheno! 4•Chloroani!ino 4-Chlo!01)hmyl phenyl el.her 4-Motbylphmol (p•Crosoll 4.Niuo111iH110 4•NiUOpbcnol Acmlpbllx:nc Acm•phlhyltno AllthrlCa,O Bfflzo(a)m,lb-lCfflC flr:ru:ol11pyrcne lk:nm(b)Ouor;,,lhmc BcmD(g.h.i~,rylcic flc,zo(\ )lluoranthtnc bis<2-<hLoo-o«hoxy)McUuuto bi$(2-0lloroelhyl) l!O,cr (2-Cbloroetlryl EIM> bls<l.cthyll=y\) Pbthala1c Bci:eyl butyl ph1hala1c C.ubazolc Dibmz<a, h )amhracmo Dib(ru:ofuran Diethyl Pblhalate Dimelhyl phlhalllo Di-n•blltyl phlhalal< Di-n«ty!phlhal110 Fluoranlhaic Fl110tcne Hn..chlorobcnzme Hnac.hlor~lopcn!adicn• Hcuchloroclhanc lnda,o( 1,2,l-c,d)l'yra,e llophorono Naphthalc,c Nil1'ob(ruenc n-Niiroso-di-n-prapylanin• 11•Nitrotodiphenyla,rint Pcntachlorophmol Phenan1hreno '"""' ,,,_ Notes 1. NS•N0Stmdardcs1abli1hcd 2. (!). lnlrlm "2L" Groonc:twater Standan:I. 3. Qualifiers are summMzed al end or secbon ATFMrlLBL N.\Jobsl20812S9JIGW Qwlity.dl (SVOC 1N WGJ 20SH93.01160101 MADI 7/161200) """ """ ""'" ""'" ""'" <140u ""'" ""'" ""'" ""'" ""'" """ "'" ""'" <>;. "'" "'" ""'. "''" "''" "''" "''. <>;. "'" II J MW-01 MW-01 Nonnal 4/29/lOOJ <10 II <I Ou <)Ou <10 u <10 II <SO 11 <10 u <\0 II <I Ou <10 II <10 u <10 u """ <10 u <10 u "'". "'". <10 u <10 u <10u <10 u <]0 II "'". "'"" <10 u <10 11 <10u <1011 <10 II <10 u <1011 <1011 <10 u <!Ou <10u <10 u <10 II <1011 "10u <10 11 <10 II <]Ou <10 II <!Ou <1011 <10 II <10 II <!0 II "20u <lOu <1011 <10u WINSTON SALEM, NORTH CAROLINA PLANT AREA MW-01 MW-DUP-01 Flrld Dap\leolr 4'19/1003 <10 u <]0 u <\011 <t0 u <10 u """ <LO u <10 u <JO u <\Ou <10 u <JO u "'". <I Ou <\0 11 "'"" <C20u <[Ou <JO u <]Q II <\Ou <10 u "'". "'"" <JO II <1011 <10 II <1011 <\0 11 <10 u <1011 <\0 11 <10 u <JO u <10u <IQ II <10 u <1011 <1011 <IO 11 <10u <1011 <10 u <JO u <]Ou <tO u <10 u <]Ou <\0 11 <LO II <)0 II <]Ou <\Q II "'". <LO 11 <1011 <10 u MW-02 MW-tlJ Normt.l 1/29/2001 <IOU <]Ou <10u <10 u <]Ou «•. <IOu <]Ou <10u <10u <10 u <]Ou <19u <I Ou <19 II <19u <19u <!Ou <I Ou <JOU <1011 <10 u <19u <C]9u <10u <lOu <[Ou <!Ou <IOU <I Ou <I Ou <JQ II <Cl Ou <10u <I Ou <]Ou <Cl Ou <I Du <10 u <10 u <I Ou <10 II <10 u <Cl Ou <lOu <10 II <lOu <10 II <10 u <[Ou <CIOu <19u <10 u <]Ou <!Ou MW..(13 MW-OJ Nonn•l IIJ0/2001 <10 II <10 u <10 u <10 u <10 u «h <10 u <10 u <10 II <LO 11 <10 11 <lOu <19 II <]Q II <19 u <19 II <19 u <10 II <10 II <10 II <\0 II <10u <[9 II <[9 II <lO u <1011 <10 u <I Ou <I Ou <10 II <10 II <JOu J.0J <10 u <!Ou <10u <10 u <I Ou <10u <10 II <I Ou <!Ou <10 u <!Ou <I Ou <\Ou <10 II <IOU <10u <10 u <10 II <]Ou <10u <19 II <10 u <JOu <10 u MW-OJ MW-DUP-01 Flold Dapllrur 1/J0/l00J <10 11 <!Ou <!Ou <I Ou <IO 11 """ <I Ou <]0 11 <10u <I Ou <]0 11 <I Ou "'"" <LOu "'"" "'"" "'"" <1011 <C10u <IOU <I Ou <]0 II "'"" """" <10 u <I Ou <lOu <IOU <\Ou <LOu <I Ou <10 u 2.0J <!Ou <]Ou <[Ou <IQ II <10 II <IOu <!Ou <JO u <I Ou <10 u <10 II <\Ou <10 u <10 u <lOu <10 u <10 u <10 u <I Ou "'"" <10 u <1011 <10 u MW-" MW_.. Normal 1129/J00I <9,0u <9.0 u <9,0 u <9.0u <9.0 II 4;, <9.0u "'"" "'". <9.0u tjO, <9.0 II <19u <9.0u <19 u <19u <19 u <9.0u tj0o tjO, <9.0u <9,0 u <19u <19u <9.0 II <9.0u tj0o tj". <9,011 tjO, tj". <9,0u tj0o tj". <9.0u <9.0u tjO, <9.0u <9,0u <90u <9,0 II <9.011 <9,0 u tj0. <9.0u <9.0 u <9.0 u tj "" tj0. MW-OS MW_,, Nonna! 1130/J00I <LO u <10 u <10u <10 u <10 u """ <\Q II <10 II <10u <\Ou <IOa <1011 "'"" <LO 11 "'"• "'"" """. ' <1011 <lOu <10 u <10 u <10u "'"" "'". <\Ou <10 11 <1011 <1011 <IOu <JO u <]Ou <\011 <I Ou <I Ou <10u <10 u <10u <10u <10 11 <1011 <10u <1011 <10u <1011 <!Ou <I Ou <lOu <10 u <!Ou <\Ou <10 11 <!Ou <1011 "'". <10 u <!Ou <10 11 MW_.. MW_.. Nonnll 1130/l00l <9.0u <9,0 11 tj". <9.0 II <9.0 II «;, <9.0u <9.0 II <90 u tj0o tj0. <9,0 u <1911 tj0o <19 u <l9u <19u tj0. tj0, <9.0u tj0• tj0o <1911 <L9u <9.0u <9,011 tj0. <9.011 <9.0u tj". <9.0u <9.0 u <9,0 u <9.0u tjO, <9.0 u tj". <9.0 u <9,0 u tj0o <9.0 u <9.0 u <9.0u tj". <9.0u <9.0 u <9,0 u <9.0u <9.0 u <9,0 u <9.0 u <9.0 II <9.0u <9.0u <]9 II tj". tj0. <9,0 u I of I HII SSL Groood,ntu lMNCAlL NS NS NS NS 140 NS NS NS NS NS 28 NS NS NS NS NS NS NS NS NS NS 3.5 NS NS 80(l) 210 (I) 210011) o.os<11 0.0047 (I) 0.047(I) 210 0,47 (I) NS 0.031 3 100 NS 5U1 0.0047 ilJ 28 5000 NS 700 140 280(I) 280 O.Q2 NS NS 0.047(1) 36.8 21 NS NS NS 0.3 210 300 2101!1 SUMMARY OF ORGANO CHLORINE PESflCIDE AND PCB RESULTS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. Location ldtntificat/on MW-01 Fitld Samplt ldtntification MW-OJ Samplt Typt Nonna! Datt Cofltcttd tn9/200I Pesticides (µg/1) Aldrin <0.047 11 alpha Bhc (alpha Hexachlorocyclohexane) <0.047 U alpha Endosulfan <0.094 u alpha-Chlordane <0.094 u beta BHC (beta Hexachlorocyclohexane) <0.094 11 beta Endosulfan <0.19 u ODD ( I, I-bis( chlorop heny 1)-2,2-Di ch loroethane) <0.19 u ODE ( I, I-bis( chlorophenyl)-2.2-Dichloroethenc) <0.094 u DDT ( I ,l-bis{chlorophcnyl)-2,2,2-TrichJorocthane) <0.28 u delta BHC (delta Hexachlorocyclohcxane) <0.047 u Dieldrin <0.094 u Endosulfan sulfate <O.J9u Endrin <0.19 u Endrin aldehyde <0.19 u Endrin ketone <0.47 u gamma BHC (Lindane) <0.047 U gamma-Chlordane 0.015jJ Heptachlor <0.047 11 Heptachlor epoxide <0.047 u Methoxych\or <0.47 u Toxaphene <4.7 II PCBs (µ.g/1) PCB-1016 (Arochlor 1016) <0.94 u PCB-1221 (Arochlor 1221) <1.9 u PCB-1232 (Arochlor 1232) <0.9411 PCB-1242 (Arochlor 1242) <0.94 u PCB-1248 (Arochlor 1248) <0.94 u PCB-1254 (Arochlor 1254) <0.94 u PCB-1260 (Arochlor 1260) <0.94 II Notes: I. NS= No Standard established 2. (b) Value is for total endrin (endrink endrin aldehyde, and endrin ketone). 3. (e) Interim (I) standard for hexachlorocyclohexane isomers. 4. Qualifiers summarized at end of section. ATF/vlr/LBL N:\Jobs\208\2593\GW Quality.xis (PST IN WO) 2082593.0J 160101 MADI 7/1612003 WINSfON SALEM, NORTH CAROLINA PLANT AREA MW-01 MW-02 !\IW-02 MW-0t MW-02 MW-02 Normal Normal Normal 4/29/2003 1/29/2001 4/30/2003 <0.05 u <0.047 U <0.05 u <0.05 U <0.047 11 <0.05 U <0.1 u <0.094 u <0.1 u <0.l u 0.027 jpU <0.J II <0.1 u <0.094 u <0.1 u <0.2 u <0.19 u <0.2 u <0.2 11 <0.19 u <0.2 u <0.1 u <0.094 u <0.1 u <0.3 u <0.28 11 <0.3 II <0.05 u <0.047 u <0.05 u <0.1 u <0.094 u <O.J 11 <0.2 u <0.19 11 <0.2 u <0.2 u <0.19 u <0.2 II <0.2u <0.19 II <0.2 II <0.5u <0.47 u <0.5 u <0.05 u <0.047 u <0.05 ll <0.05 u <0.047 II <0.05 11 <0.05 u <0.047 11 <0,05 II <0.05 11 <0.047 11 <0.05 u <0.5 11 <0.47 u <0.5 u <S, <4.7 u <S, NS <0.94 u NS NS <1.9 u NS NS <0.9411 NS NS <0.94 u NS NS <0.9411 NS NS <0.94 u NS NS <0.94 II NS MW-03 MW-03 MW-03 MW-03 Normal Normal 1/l0n00I 4/30/2003 <0.048 U <0.05 U <0.048 11 <0.05 U <0.095 u <0.1 u 0.043 jpU <0.1 u 0.058 jpJ <0.111 <0.19 u <0.2 II <0.19 u <0.2 u <0.095 u <0.1 u <0.28 11 <0.3 u <0.048 u <0.05 u <0.095 11 <0.1 u <0.19 u <0.2 II <0.19 u <0.2 II <0.19u <0.2 u <0.48u <0.S u <0.048 u <0.05 u 0.051 pJ <0.05 II <0.048 11 <0.05 u 0.032 jpJ <0.05 11 <0.4811 <0.5 u <4.8 u <S, <0.95 11 NS <J.9u NS <0,95 II NS <0.95 u NS <0.95 u NS <0.95 u NS <0.95 11 NS l of2 MW-03 MW-03 MW-DUP-01 MW-DUP-01 HH SSL Field Duplicate Fldd Duplicate Groundwater 1/30/2001 4/29/2003 15A NCA2L <0.046 u <0.05 U NS <0.046 U <0.05 U 0.OJ9(e) • <0.093 11 <0.1 u NS <0.093 u <0.1 u 0.027 <0.093 u <0.1 u 0.019 (e) <0.19 11 <0.2 u 42 <0.19 u <0.2 u 0.14 <0.093 u <0.1 u NS <0.28 u <0.3 u 0.1 <0.046 u <0.05 u 0.019 (e) <0.093 u <0.1 u 0.002 <0.19 u <0.2 u NS <0.19 II <0.2 II 2.1 (b) <0.19 u <0.2 u 2.1 (b) <0.46 u <0.5 u 2.1 (b) <0.046 11 <0.05 u 0.2 <0.046 II <0.05 u 0.027 <0.046 u <0.05 11 0.008 <0.046 11 <0.05 u 0.004 <0.46 u <O.S u JS <4.6u <S, 0.03 <0.93 11 NS NS <1.9 u NS NS • <0.93 II NS NS <0.93 u NS NS <0.93 u NS NS <0.93 II NS NS <0.93 II NS NS SUMMARY OF ORGANO CHLORINE PESTICIDE AND PCB RESULTS IN GROUND WATER SAMPLES JOHNSON CONTROLS BATTERY GROUP, INC. Location Identification Field Sample Identification Sample Type Date Collected Pesticides (pg/I) Aldrin alpha Bhc (alpha Hcxachlorocyclohe){ane) alpha Endos11lfan alpha-Chlordl.!le beta BHC (beta Hcxachlorocyclohe){ane) beta Endosulfan DDD (I, l-bis(chlorophenyl)-2,2-Dichloroethane) DOE (I, 1-bis(chlorophenyl)-2,2-Dichloroethene) DDT ( l , 1-bis( chlorophenyl)-2,2,2-Trichlorocthane) delta BHC (delta He){achlorocyclohexane) Dicldrin Endosu\fan sulfate Endrin Endrin aldehyde Endrin ketone gamma BHC (Lindane) gamma-Chlordane Heptachlor Heptachlor epo){ide Metho:xych\or Toxaphene PCBs (pg/I) PCB-1016(Arochlor 1016) PCB-1221 (Arochlor 1221) PCB-I 232 (Arochlor 1232) PCB-1242 (Arochlor 1242) PCB-1248 (Arochlor 1248) PCB-1254 (Aroch\or 1254) PCB-1260 (Arochlor 1260) Notes: I. NS= No Standard established 2. (b) Value is for total endrin (endrink endrin aldehyde, and endrin ke1 3. (e) Interim (I) standard for hexachlorocyclohexanc isomers. 4. Qualifiers summarized at end of section. ATF/vlr/LBL N:\Jobs\20812593\GW Quality.xis (PST [N WG) 2082593.0i !60101 MADI 7/16/2003 WINSTON SALEM, NORTH CAROLINA PLANT AREA l\lW-04 MW-04 MW-OS MW-04 MW-04 MW-05 Normal Normal Normal 1nw2001 4/29/2003 1/30/2001 0.0J8j <0.05 u 0.14 p <0.048 11 <0.05 II <0.051 II <0.095 II <0.J 11 0.036 jp <0.095 11 <0.! 11 0.056jpU <0.095 11 <0.I u <Q,[ II <0.\9u <0.2 u <0.2 u 0.19jpJ <0.2 11 <0.2 11 <0.095 u <0.\ II <0.\ II <0.28 II <0.3 u <0.31 II <0.048 II <0.05 II 0.03Ijp <0.095 II <0.J II <0.] II <0.19 11 <0.2 II <0.2 u <0.19 II <0.2 II <0.2 II <0.1911 <0.2 II <0.2 II <0.48 u <0.5 11 0.031 j <0.048 u <0.05 II <0.051 u <0.048 II <0.05 II <0.051 u <0.048 II <0.05 II <0,051 II O.OIJjp <0.05 u <0.051 11 <0.48 II <0.5 11 <0.5\ II <4.8 II <5" <5.J u <0.95 II NS <I.Ou <\.911 NS <2.0 II <0.95 II NS <I.Ou <0.95 II NS <I.Ou <0.95 U NS <\.Ou <0.95 II NS <1.0 II <0.95 II NS <I.Ou MW-OS MW-06 MW-OS MW-06 Normal Normal 4/29/2003 1/30/2001 <0.05 11 0.035 jp <0.05 11 <0.047 11 <0.\ 11 0.02Sj <0.J u 0.053 jpU <0.1 u <0.094 II <0.2 11 <0.1911 <0.2 u <0.!9 II <0.\ u <0.094 u <0.3 u <0.28 11 <0.05 u <0.047 II <Q.J II <0.094 II <0.2 u <0.\9 II <0.2 II <0.19 II <0.2 11 <0.1911 <0.5 u <0.47 II <0.05 II <0.047 II <0.05 11 <0.047 II <0.05 II <0.047 11 <0.05 11 <0.047 u <0.5 u <0.47 u <5" <4.7 u NS <0.94 u NS <1.9 II NS <0.94 u NS <0.94 II NS <0.94 II NS <0,94 II NS <0.94 U 2 of2 MW-06 MW-06 HHSSL Normal Groundwater 4/29/2003 ISA NCA 2L <0.05 11 NS <0.05 11 0.019(e) <0.111 NS <0.111 0.027 • <0.111 0.019 (e) <0.2 u 42 <0.2 11 0.14 <0.111 NS <0.3 II 0.1 0.078 p O.Ol9(c) <0.\ 11 0.002 <0.2 II NS <0.2 u 2.1 (b) <0.2 II 2.1 (b) <0.5 11 2.1 (b) <0,05 II 0.2 <0.05 II 0.027 0.13 0.008 <0,05 u 0.004 <0.5 u JS <5" 0.03 NS NS NS NS NS NS • NS NS NS NS NS NS NS NS • • INORGANIC DATA QUALIF1ERS u -laboratory qualifier indicates the analyte is not detected at the reporting limit n -laboratory qualifier indicates sample spike recovery is outside control limits b -laboratory qualifier indicates the reported value is less than the reporting limit but greater than the instrument detection limit e -laboratory qualifier indicates the serial dilution result was not within 10% of the undiluted result * .,. .laboratory: qualifier indicates -the sample and sample duplicate results are outside control limits . J .,.._ data validation qualifier indicates. the value is estimated due to spike recovery, serial dilution, and/or initial and/or continuing calibration outside quality control limits· -R -· data validation qualifier indicates the value was. not detected and is unusable due to spike and/or initial calibration criteria outside criiepa · ·· U -data validation qualifier indicates the value was not detected due to the analyte being .. detected at a similar concentration in an associated blank ---indicates the parameter was not analyzed ORGANIC DATA QUALIFlERS ··' .. . . ' . u -laboratory qualifier indicates the analytc is not detected at the reporting limit j ""' laboratory qualifier indicates the reported. value is less than the reporting limit but greater than the instrument detection limit p -laboratory qualifier i~dicates the_ value for the pcsucide or PCB c01ppound has greater·· . than 25% relative pel'CCnt difference between the values detected on the primary and confirmation columns < -laboratory qualifier indicates the analyte is not detected at the reporting limit J -data validation qualifier indicates the value is estimated due to spike recovery, surrogate recovery, laboratory control sample, and/or initial and/or continuing calibration outside quality control limits R -data validation qualifier indicates the value was not detected and is unusable due to spike, surrogate, laboratory control sample, and/or initial calibration criteria outside criteria U -data validation qualifier indicates the value was not detected due to the analytc being detected at a similar concentration in an associated blank MW-02 881.87 MW-03 889.97 MW-04 902.28 MW-05 914.06 MW-06 910.77 SG-01 865.45 SG-02 835.41 SG-03 818.77 SG-04 803.16 NM = Not measured A TF\atf\LBL N:Vobs\208\2593\01\Water Levels.:itls] 2082593.01160 IO I -MAD I 34.22 28.63 24.88 38.08 29.23 NM NM NM NM Summary of Water Level Elevations Johnson Controls Battery Group, Inc. Winston-Salem, North Carolina 847.65 34.22 847.65 861.34 27.78 862.19 877.40 24.49 877.79 875.98 37.66 876.40 881.54 29.27 881.50 34. 18 27.93 24.68 37.6 29.35 NM NM NM ~5'i,~•• :;{~,;:; 0-:/ r. 65 NM NM NM 0.62 NM NM NM 0.8 NM NM NM 1.16 Page I of I • 847.69 30.13 851.74 862.04 26.79 863.18 877.60 23.71 878.57 876.46 37 877.06 881.42 28.62 882. 15 ;E :::863~77~~; NM NM 832.70 NM NM 816.24 NM NM 800.99 NM NM • North Carolina A Department of Environment an"'atural Resources Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary Dexter R. Matthews, Interim Director Mr. Luis Flores Remedial Project Manager US EPA Region IV 61 Forsyth Street, I Ith Floor Atlanta, Georgia 3 03 03 July 3, 2003 RE: Comments on the Draft Groundwater Sampling Results Johnson Controls Battery Group, Inc. (JCBG) NCO 000 770 487 Winston Salem, Forsyth County, North Carolina Dear Mr. Flores: The State received an electronic letter of the Draft Groundwater Sampling Results, dated 17 June 2003, for the Johnson Controls Battery Facility, located in Walkertown near Winston-Salem, NC. The following comments by the North Carolina Superfund Section are submitted for your consideration. General Comment The NC Superfund Section would agree that the site is not an important source of metals or pesticides to the groundwater. The facility groundwater is not badly contaminated with any contaminants. However, those that exist above NC Groundwater Standards must be shown to be background or continued monitoring would be required to assure that they are decreasing in concentration and do not leave the facility property and especially that they do not impact other downgradient receptors. An upgradient monitoring well needs to be provided in a undisturbed location of the property or on an upgradient adjacent property in order to properly confirm background concentrations. Specific Comments: I. The First paragraph on page I of the Groundwater Sampling Results does not include SVOC's as agreed at monitoring well MW-I. Monitoring well MW-01 should include analysis for SVOCs since it contained bis(2-ethylhexyl)phthalate in the first round results. This was a comment the state made on the Draft Sampling Work Plan dated I 646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-733-4996 \ FAX: 919-715-3605 \ Internet: www.enr.state.nc.us AN EQUAL OPPORllJNITY \ AFFIRMATIVE ACTION EMPLOYER-50% RECYCLED/ 10% POST CONSUMER PAPER Mr. Luis Flores 4-22-2003 Page 2 of3 • • March 21, 2003. I had further discussions of this issue by telephone with Dan Hall with Montgomery Watson Harza. The States comment letter on the Work Plan was dated April 22, 2003. On Tuesday 29 April 2003, I witnessed Trevor Banister and Dale Lane with Montgomery Watson Harza complete groundwater sampling of monitoring well MW-I. I discussed the issue of SVOC samples with Mr. Banister who was aware of the different protocol for monitoring well MW-I and was prepared to sample for SVOCs at this well. During sampling overview the sampling included appropriate bottles and samples for SVOCs. The Paragraph under B. Water Quality Analyses on page 2 states that "the sample from well MW-01 was analyzed for SVOCs (Method 8270C)." This statement on page 2 should also be clarified with emphasis in the first paragraph on page I for consistency. This sample data is a critical part of the verification that monitoring well MW-I is not contaminated with SVOCs. 2. As noted in the Tables on page 2 and 3 the metals iron and manganese were detected in monitoring wells MW-I, MW-5, and MW-6 at concentrations significantly above the NCAC 2L Groundwater Standards. Proper monitoring of these wells will be required to confirm that these concentrations are decreasing and are contained on the property or are consistent with local background metals concentrations. Additional monitoring wells would be required in either up gradient and downgradient areas of the site to confirm that these metals are either background or are contained on site. 3. The third paragraph on page 3 states that "Iron and manganese are generally ubiquitous in the environment and likely do not represent Site-derived contamination." Facilities that use acids and Volatile Organic Compounds (VOCs) and have documented spills of these compounds commonly have high concentrations of metals such as iron and manganese resulting from leaching of the naturally occurring metals due to the changes in grondwater chemistry. Therefore, proper documentation of background metals will be required in order to confirm that they are naturally occurring in groundwater at these high concentrations. The presence of high levels of iron and manganese concentrations that exceed 2 times background, in an aquifer, should be considered at a minimum in the monitoring program for the site. In this manner we can assure that these high metals concentrations do not impact receptors. If the high metals concentrations are the result of the high VOC concentrations or spilled acids we expect that the metals concentrations will reduce to background as the pH neutralizes. If these metals concentrations are contained on the Johnson Controls Battery Group property, the simplest way to deal with the issue is to deed restrict the use of groundwater and set up an acceptable groundwater-monitoring schedule for the downgradient wells. In this way we can confirm that the metals contaminants are decreasing and that they do not leave the property. Mr. Luis Flores 4-22-2003 Page 3 of3 • • 4. As you stated in the report, the pesticides detected in monitoring well MW-06 may or may not be site related. Since heptachlor is much more toxic and at 2 orders of magnitude greater than the NC 2L Groundwater Standard it would worth the effort to resample this well for pesticides to confirm their presence or absence. The pesticides must be shown to be similar to background or additional monitoring for pesticides will be required in monitoring well MW-6. The Delta BHC compound is not very toxic and only slightly exceeds the standard but the heptachlor is very toxic to humans and it should be documented that the contaminant is not present above State groundwater Standards. The State appreciates the opportunity to comment on this document and we look forward to working with you on the project. If you have any questions or comments, please call me, at (9 I 9) 733-280 I, extension 341 or email at randy.mcelveen@ncmail._n.~!- cc: Dave Lown, N.C. Superfund Section Sincerely, Randy McElveen Environmental Engineer NC Superfund Section ({ID MWH June 17, 2003 Mr. Luis Flores • Remedial Project Manager USEPA Region IV 6 I Forsyth Street, I I th Floor Atlanta, Georgia 30303 Re: Groundwater Sampling Results April 29, 2003 Winston-Salem Facility Dear Luis: • DRAFT MWH Americas, Inc. (MWH) completed the second round of groundwater monitoring at the JCBGI Winston-Salem facility on April 29, 2003. The groundwater sampling confinnation round includes analysis of metals, volatile organic compounds, and pesticides in groundwater. Semi-volatiles and PCBs were explicitly excluded from the list of analytes, based on the first round of sampling results reviewed from the EE/CA investigation. The Quality Assurance Project Plan (QAPP) and Field Sampling Plan (FSP) previously developed for the EE/CA guided this second round of confinnation groundwater sampling and analysis. A. Groundwater Sampling Methods The field technicians sampled each of the 6 monitoring wells (MW-0 I through MW-06) using low-flow purge sampling techniques to obtain representative groundwater samples. Prior to groundwater sampling, each monitoring well was purged. A clean plastic drop cloth was spread around the well prior lo purging. Purging was accomplished by removing groundwater from the monitoring wells using a decontaminated, low-flow submersible pump with new dedicated polyethylene discharge tubing. Purging continued until water quality parameters, including pH, temperature, redox, conductivity, and turbidity, stabilized and a minimum of 3 and maximum of 5 well volumes were removed or the well was pumped dry. Purge water was containerized in 55-gallon drums. Once the wells were properly purged, groundwater samples were collected. The groundwater samples for total metals analyses were collected directly from the polyethylene tubing. The groundwater sample for dissolved metals analyses were field filtered using a 0.45-micron inline filter with the polyethylene tubing and discharged into the sample containers. The groundwater samples for VOCs and organochlorine pesticides analyses were collected using a new, clean Teflon® bailer. Groundwater samples were placed in appropriate sample containers, preserved, properly labeled, and stored on ice. Chain of custody procedures were followed for collection and shipping the samples. Field quality control (QC) samples were collected to assess the quality of the analytical data and to evaluate sampling and analytical reproducibility (precision). Field quality control samples consisted of one each of a duplicate sample, field blank, matrix spike/ matrix spike duplicate, and trip blank. Each QC sample was analyzed for all scheduled parameters, except the trip blank, which was analyzed for VOCs, only. One Science Cour1 PO Box 5385 Madison, Wisconsin <;'l7(\<;J\1Q<; Tel· 608 231 4747 Filx 608/.314777 Delivering lnnov,1/ive Projecls and S0/11/ions Worl!lwrde • • The groundwater level and total depth of each monitoring well were measured using an electronic water-level indicator to an accuracy of 0.0 I feet prior to purging the well. The water-level indicator was rinsed with deionized water prior to each use. The depth to groundwater was recorded in the field logbook and the well volume was calculated. Liquids from the decontamination of sampling equipment and sample purge water were contained in 55-gal drums for later disposal or treatment by facility management. B. Water Quality Analyses Each of the six groundwater samples and QC samples were analyzed for the following parameters: Total T AL Metals Dissolved TAL Metals voes Organochlorine pesticides 3005A/6010B/7470A 3005A/60 I 0B/7470A 5030B/8260B 8081 In addition, the sample from well MW-0 I was analyzed for SVOCs (Method 8270C). The samples that were field filtered (FF) represent the Dissolved T AL Metals results. CompuChem Laboratories of Research Triangle Park, NC conducted the analyses of the groundwater samples. C. Water Quality Results The groundwater analytical results are presented in the attached Tables I through 4. The April 29, 2003 data is presented adjacent to the January 29/30, 2001 data previously submitted. Data qualifiers presented with the results are summarized and presented following the tables. The following is a brief discussion of each class of parameters. I. Metals The following two tables present the minimum, mean, and maximum concentrations of total and dissolved select metals, along with the number of detections from the six groundwater monitoring wells. Please note that, the minimum value is the minimum detected value (not non-detect, unless no detections were noted in any samples). The mean is calculated from samples with detected concentrations. Further, QA duplicate samples are not included within the number of detections. The tables below also identify the 15A NCA 2L groundwater standards and the monitoring well locations where standards are exceeded. Total Select TAL Metals in Groundwater Parameter Minimum Mean /uo/L\ • luo/L\ Aluminum 49.7 369.2 Cadmium ND ND Conner 4.3 4.3 Iron 80.4 726.i Lead 4.9 4.9 Mane:ancse 16.5 211.3 Nickel 3.5 5.6 Total ND ND Mercurv Zinc 10.2 21.2 •sample locat1ons: MW0I-MW06 Mr Luis Flores No. of ISANCA Maximum Detections 2L luo/L\ • GW Stds . 1550 5 NS ND 0 1.8 4.3 I 1000 2320 4 300 4.9 I 15 996 6 50 7.1 3 100 ND 0 I.I 36.6 5 1050 June 17 2003 Wells Exceeding Std. MW0I MW06 MW0J. MW05. MW06 USEPA Regions IV • • Dissolved Select TAL Metals in Groundwater No. of ISANCA Wells Exceeding Std. Parameter Minimum, Mean Maximum Detections 2L 'lu•/1,l ful!/Ll (uon .\ • GW Stds . Aluminum ND ND ND 0 NS Cadmium ND ND ND 0 1.8 Conner ND ND ND 0 1000 Iron 52.9 312.0 571 2 300 MW06 Lead ND ND ND 0 15 Manl!ancse 15.6 541.5 3060 6 50 MW0I. MW05. MW06 Nickel 1.4 1.9 2.7 2 100 Total 0.13 0.13 0.13 I I.I Mcrcurv Zinc 19.1 21.9 27, I 3 1050 •sample locat1ons: MW0I-MW06 Based on the information presented in the tables above, only total manganese was detected in all 6 groundwater samples above the reporting limits. In contrast, total lead was detected in only one sample (MW-01, 4.9 ug/L). Total aluminum and total iron were detected in 5 and 4 samples, respectively. Concentration ranges and mean values of total metals from the April 2003 sampling are comparable to the January 2001 sampling, except that 5 samples had total aluminum above detection limits in the current sampling, as compared to only one in the previous sampling. As expected, the number of detections of dissolved metals from filtered samples is generally less than the total metals detections. The exception is at well MW06, where several metals were higher in the filtered sample than the total samples. The manganese concentration was high enough in the filtered sample for MW06, that it skews the mean value of the filtered' samples. Similar to the total metals, only manganese was detected in all 6 filtered groundwater samples. Lead was not detected in any of the filtered samples. Aluminum was apparently filtered out of the samples, since none was detected. Maximum iron and manganese concentrations are higher in the April 2003 sampling than the January 2001 sampling. Groundwater standards were exceeded only for iron (in upgradient wells MW0 I and MW06) and manganese (in wells MW0l, MW05, and MW06) in the total metal analyses. Similarly, standards were exceeded in the dissolved metal analyses for iron (in well MW06) and manganese (in wells MW0l, MW05, and MW06). Iron and manganese are generally ubiquitous in the environment and likely do not represent Site-derived contamination. No other total or dissolved metals analyzed beyond the select metals exceeded a groundwater standard. The data confirm the site is not an important source of metals to the groundwater. The iron and manganese concentrations are naturally occurring and are not considered Site-derived contamination. 2. SVOCs No SYOCs were detected in the April 2003 groundwater sample from MW0 1. Mr, Luis Flores June 17. 2003 USEPA Regions IV P.:iuP 1 • • 3. voes The table below presents the list of voes detected in groundwater monitoring at the site, the list of voes detected in April 2003 groundwater monitor, the I SA NeA 2L groundwater standards, and the wells which exceeded the standard: April 2003 Parameter Detections # of Samn\cs 6 I I l 1.1.2.2 Tetrachlorocthanc 0 1.2.4 Trichlorobenzenc 0 1,2,4 Trimcthvlbcnzene MW0I, MW05 I 2-Dichlorobenzcne 0 I 3 5-Trimcthvlbcnzenc MW05 I 3-Dichlorobenzene 0 I 4-Dichlorobenzene 0 2-Butanone MW0I MW05 MW06 2-Hcxanone 0 Acetone MW0\, MW02, MW03, MW04. MW05. MW06 Benzene MW0I, MW04, MW03 Dun Chlorobenzene MW04. MW05. MW06 Bromodichloromcth:ine 0 Carbon Disulfide 0 Chiorofonn MW0I, MW02, MW03, MW04 MW05 MW06 Chloromethane 0 Cis-1 3-Dichloroorooenc 0 Dibromochloromethane 0 Methylene Chloride MW0I, MW02, MW03, MW04. MW05. MW06 m&n Xvlcnes MW0\ o-Xvlene 0 Stvrenc 0 T etrachlorocthvicne 0 Toluene MW0I, MW02, MW03, MW04. MW05 MW06 Trans-1.3-Dichlorooroncnc 0 Trichioroethylene MW0I, MW04, MW05, MW06 (I) Sampling Locations: MW0I through MW06. (2) Value is for total xylenes m, p & o ISA NCA 2L Wells GW Stds. Exceedine Std. 50 70 350 620 350 620 75 170 280 700 I 50 0.6 700 0.19 MW02, MW03, MW04.MW05 2.6 0.2 0.41 5 530 (2) 530 /2) NS 0.7 1000 0.2 2.8 Groundwater data indicates the presence of several voes detected at very low levels in site monitoring wells. Several of these additional voes are apparently petroleum related (benzenes, xylenes, toluene) and others are chlorinated or propenated compounds. The April 2003 monitoring detected very minor amounts of 2-butanone, chlorobenzene, and trichloroethylene, which were not detected in the January 200 I sampling. In contrast, several compounds detected in the January 200 I sampling were not detected in the April 2003 results from any of the wells. In particular, background well MW0 I had nine compounds detected in the current sampling compared to 16 compounds in the previous sampling. Mr. Luis Flores June 17 2003 LJSEPA Regions IV p~.,,,. d • • 1,/J'L I\L~l Some compounds were detected in all 6 monitoring wells, including acetone, chloroform, 1_.,,,-c; ,.,.J methylene chloride, and toluene, and appear to be present in both upgradient wells (MW0I,~ b<~f.~"' MW04, MW06) and downgradient wells (MW02, MW03, and MW05). Several VOCs VJ<..,.'{,,( (methylene chloride, toluene, xylenes, dichlorodifluoromethane) were detected at low ' levels in the laboratory blanks, and their results are qualified on the summary table. Most other compounds were detected in a combination of upgradient and downgradient wells. Acetone and methylene chloride was detected in other media from sampling conducted during the EE/CA, but these constituents are often considered laboratory contaminants. Neither toluene nor chloroform was detected in other media than groundwater from the EE/CA. Nearly all of the VOC values were reported as estimated, because the values were lower than the reporting limit but higher than the detection, with the exception of some acetone and chloroform results. Only chloroform exceeded a 15A NCA 2L groundwater standard of all the VOC detections. Chloroform concentrations barely exceeded the standard (0.19 ug/L) in 4 of the 6 groundwater samples in which it was detected, ranging from 0.2 ug/L to 0.3 ug/L. All 4 samples where exceedances occurred were qualified as estimated values by the laboratory. Chloroform is a trihalomethane, often associated with drinking water treatment. These VOC data confirm previous results that the Site is not an important source of VOCs to the groundwater. 4. Pesticides The table below presents the list of pesticides detected in groundwater monitoring at the site, the list of pesticides detected in April 2003 groundwater monitor, the 15A NCA 2L groundwater standards, and the wells which exceeded the standard: Parameter/Location Pesticide ISANCA 2L Wells Exceeding Media Detections GW Stds. Std. # of Samoles 6 Sample Locations MW0 I through MW06 Aldrin 0 NS Alnha BHC 0 0.019 (I) Aloha Endosulfan 0 NS Aloha Chlordane 0 0.027 Beta BHC 0 0.019/ll DDD 0 0.14 Delta BHC MW06 0.01911) MW06 Endrin ketone 0 2.1 Gamma Chlordane 0 0.027 Heotachlor MW06 0,008 MW06 Heotachlor Exooxide 0 0.004 (I) Value 1s for total BHC Two pesticide compounds were detected in the groundwater sample from well MW06 in the April 2003 groundwater monitoring compared to IO compounds detected in up to 4 wells in the January 200 I monitoring. Only minor concentrations of delta BHC (0.078 ug/L) and Heptachlor (0.13 ug/L) were detected, both in upgradient well MW06 in April 2003. Both of these compounds exceeded their respective 15A NCA 2L groundwater standard. Heptachlor had not been detected in the January 200 I results. Well MW06 is considered an upgradient well, so these compounds may not be Site-related. Further, no pesticides were detected in downgradient wells at the Site. Mr. Luis Flores June 17 2003 USEPA Regions IV • • Overall, these pesticide results present an improvement in water quality since the January 2001 monitoring. The data confirm that the Site is not an important source of pesticides to the groundwater. D. Groundwater Flow I. Water Levels. A summary of water level measurements from the monitoring wells and staff gages is presented in the attached table. The depth to groundwater on April 29, 2003 ranged from approximately 24 ft (MW04) to 37 ft (MW05) below land surface. Groundwater elevations on April 29, 2003 ranged from 882.15 ft ms! at well MW06, at the southeast comer of the Facility building, to 851.74 ft ms! at well MW02, located downgradient from the north end of the Facility building. The depths to water measured at each well are consistent with data collected in 200 l. 2. Groundwater Flow Similar to the previous interpretation of groundwater elevations (EE/CA Figure 5), groundwater flows from the topographically high area around the Facility toward the west and northwest, in the direction of Lowery Mill Creek. The topographically high area around the Facility is likely a local groundwater recharge area, while the wetlands and Lowery Mill Creek are the groundwater discharge areas. E. Conclusions Based on the results of the April 2003 groundwater monitoring, the following conclusions are drawn: • Lead was only detected in one groundwater sample, and its concentration was below the 15A NCA 2L groundwater standard. Groundwater standards were exceeded only for iron and manganese in the total and dissolved metal analyses. Iron and manganese are generally ubiquitous in the environment and likely do not represent Site-derived contamination. · • No SVOes were detected in groundwater. • Groundwater data indicates the presence of several voes detected at very low levels, in site monitoring wells. Only chloroform exceeded a 15A NeA 2L groundwater standard of the voe detections. The four samples where exceedances occurred were qualified as estimated values by the laboratory. • Only two pesticide compounds were detected in one upgradient well, but both exceeded groundwater standards. Ten compounds were detected in up to 4 wells in the January 200 I monitoring, so these current results present an improvement in water quality. Pesticides may not be Site related. Mr, Luis Flores June 17, 2003 USEPA Regions IV • • These results groundwater. necessary. indicate that the Site is not an important source of contaminants to · the Therefore, we recommend that no further groundwater monitoring is If you have any questions about this infonnation, please contact the undersigned. Sincerely, MWH Americas, Inc. Daniel W. Hall, PG Project Manager Enclosure: Summary Tables of Groundwater Analytical Data Summary of Water Table Elevations cc: Timothy J. Lafond, JCBGI Randy McElveen, NCDENR DWH/pjs/LBL N:\Jobs\208\2593\WSGW Monitoringrcsuhs.doc 2082593.01160101-MADI Mr. Luis Flores June 17 2003 P<ltJP 7 LJSEPA Regions IV Loclllion ld,ntijfration MW-01 Fi,ld Sample Identification MW-01 Sampl, T;pe Normal Date Collected 1129nOOI Find Lab Metals (1,1-g/l) Aluminum 299" Antimony <3.S u Arsenic <3.9 un Barium 44,4 eJ Beryllium <0.2 u Cadmium <0.4 u Calcium 2340 * Chromium. Total 4.6 b Cobalt 4.9 b Copper 6.3 U lroo 527 *aJ L~d 12.9 Magnci;ium 1180 ManganeM: 747" Mercury <0.1 u Nickel 7.9 Potassium 2270 • Sclrnium <3.9 unR Silver <0.8 u Sodium 3570 eJ Thallium <5.1 un Vanadium 1.2 b Zinc JU Notes: I. NS= No Standard established 2. (FF)• Field filtcrcd. 3. Qualifier.; summ3rized at end of section. A TF/vlr/LBL N:\JobsU08U5931GW Quality.,h (FIXED METALS IN WG) 2082593.01160101 MADI 6/17n003 MW-01 MW-01 l"ormal 4/29/2003 1550 <10 u <10 u 68.4 e 0.16 b <5' 551 be 9.7 .. 4.3 b 2320 ,.9 1040 e 130 e <0.2 u 7.1 2410 <5' <5" 1220 b <!Ou 6.6 b 36.6 * MW-01 (FF) MW.OJ Normal 1/29/2001 <13.8 u <J.5 u <3.9u .l4 <0.2 u <0.4 u 2140 <0.9 u 4.0 b 5.7 U <9.8 u SJ 1050 653 <0.1 u 4.8 bU 1960 <3.9 un <0.8 un 2500 eJ 7.0bU <0.5 u 23 SU!'>l!\1ARY OF FIXED !\.IETALS RES UL TS l:'I,' GROU:-.'D WATER SA!'>IPLES JOH:-.'SON CO:-.'TROLS BATTERY GROUP, 1:-.'C. Wl:-.'STO:"i SALDI, !',ORTII CAROLl:-.'A PLA:,,;T AREA MW-01 (FF) MW-02 MW--02 MW-01 MW-02 MW-02 Normal Normal Normal 4/29/2003 1/29/2001 4/30/2003 <IOOu 383" 23.2 b <!Ou <3.5 u <!Ou <IO u <3.9 un <!Ou 41.9 e 46.5 eJ 52.3 e <5' <0.2 u 0.47 b <5' <0.4 u <5' 439 b 4320 * 2760 e <5' 11.6 1.3 b 2.3 b 2.6 b <5' <5" 4.5 bU <5" <100 u S67 "nJ <\OOu <3' ,., <3" 5116 b 894 b 716 be 64.8 e 112" 16.8 e <0.2 u <0.1 u <0.2 u 1.7 b 17.11 <5" 1830 1750" 1600 2.6 un <3.9 unR <5' <5" <0.8 u <5" 776 b 6150 eJ 4110 <LO u <5.1 un <JO u <20u 0.89 b <20 u <20u 40.1 U 17.7 b" I of3 MW-02 (FF) MW-02 (FF) MW-OJ MW-OJ MW-02 MW--02 MW-OJ MW-OJ HII SSL Normal Normal Normal !liormal GroundV1-ater 1129/2001 4/30/2003 1/30/2001 4/3onoo3 15A NCA 2L • <13.8 u <JOO u 1160" <\00 u NS <3.5 u <10 u <3.5 u 4.8 b NS <3.9 u <10 u <3.9 un <!Ou 0.02 37J SI • 40.3 eJ 66.11 e 2,000 <0.2 u 0.41 b 0.21 bU. J <5' NS <0.4 u <5' <0.4 u <5' 1.8 4210 ,.,, 211300" 11500 e NS <0.9 u <5' 7.8 3.3 b so 1.7 bU <5' 2.9 bJ <5' NS 4.8 bU <5" 3.1 bU. J <5" 1000 10.6b <100 u 1210 *oJ <lOOu 300 <2.6u <3" <2.6 u <3 " 1S 1118 b 726 b 4630 4520 e NS 96.5 16.3 e 2611 * 16.5 e so <0.1 u <0,2 u <0.1 u <0.2 u 1.1 6.6 <5" 6.8 U <5" 100 1700 1830 5990 * 3520 NS <3.9 un 2.6 un <3.9 unR <5' so <0.8 un <5' <0.8 u 0.87 b 17.5 5120 eJ "" 11870 eJ 5890 NS 7.1 bU <\Ou <5.1 un <10 u NS <0.5 u <20u 4.0 bJ I.I b NS 30.4 <20u 15.6bU 19.6 b* 1050 • Location Identification MW-OJ MW-OJ Fidd Sample Jdentlfu:ation MW-DUP-01 MW-DUP-01 Satnpk Type Fltld Duplicalt Fltld Duplinll' Date Collected I/J0/2001 Filed Lab Ml'tah (p.gfl) Aluminum 1184. Aniimony <J.5 u Arsenic <3.9 un Barium J0.2 tJ Beryllium <0.2 u Cadmium <0.4 u Calcium 23500 • Chromium. Total 124 Cobalt 4.2 b Coppn .. lro, 1840 *nJ L<-' <2.6 u Magnesium .. ,. Manga.no:se 291 • MeTCury <0.1 u Nickel 110 Potassium 5170 • Selenium <3.9 unR Silver <0.8 u Sodium 7510 eJ Thallium <5.1 un Vanadium J.1 b Zinc 96.8 Notes: I. NS = No St.,ndard established 2. (FF) = Field filtered. 3. Qua!ificn summarized at end of se<:t ATFMr/LBL N:\Jobs\1081.2593\GW Qulity.ds (FIXED METALS IN WG) 2082593.01160101 MADI 6/17/2003 4/J0/2003 <JOO u <10 u <10u 68.1 t <5' <5' 12000 t J.2 b <5' <S' JI.I b <)' 4710 l' 16.8 t <0.2 u <S' 3910 <5' <5' 6250 <!Ou 1.7 b 19.5 b* MW-OJ (FF) MW-OJ Normal I/J0/2001 <\J.8 u <3.5 u <J.9 u 40.7 <0.2 u <0.4 u 18300 <0.9 u J.7 b 25.6 24.8 b <2.6u 4650 m <0.1 u 4.8 bU 4860 <3.9 un <0.8 un '830 tJ 6.3 bU 1.7 b 41.6 SUMMARY OF FIXED METALS RESULTS IN GROUND WATER SAMPLES JOHNSOS CO:-OTROLS BATTERY GROUP, INC. WINSTON SALEM, NORTH CAROLINA PLA:",I AR[A MW-OJ (FF) MW-OJ(FF) MW-OJ (FF) MW-OJ MW-DUP-01 MW-DUP-01 Normal Fitld Duplinlt Held Duplieatt 4/30/2003 1/30/2001 4/30/2003 <100 u 259 U <100u <10u <J.5 u <\Ou <10 ll <3.9 u <10 u ., . l7 ., . <S' <0.2 u <5' <5' <0.4 u <5' !0900 24100 11000 2.4 b 24.4 1.9 b <5' J.7 b <5' <5' 70.6 <S' <100 u 967 <100 u <)' <2.6 u <)' 4250 4440 4320 15.6 e m 16. <0.2 u <0.1 u <0.2 u <S' 52.5 <5' 3720 5310 3950 2.6 uo <3.9 un 2.6 uo <5' <0.8 un <5' ""' 6720 ,J 5590 <10 u 7.9bU <10u <20u 1.9 b <20u 19.4 b 98.6 11.5 b MW-04 MW-04 r-:ormal 1/2912001 60.5 b0U <3.5 u <3.9 un 74.6 eJ <0.2 u <0.4 u 2790 • <0.9 u <0.6u <0.9u 72.1 b0nU.J <2.6 u 8'1 b 904 • <0.1 u 2.4 bU 3770 • <3.9 unR <0.8 u 4430 tJ <S.I un <0.5 u 7.9 bU 2 of3 MW-04 MW-04 (FF) MW-04 (FF) MW-04 MW-04 MW-04 HH SSL Normal :•formal Normal Ground .. altr 4/29/2003 1/29/2001 4/2912003 ISA NCA 2L • 49.7 b <13.8 u <!00 u NS <IOu <3.5 u <10u NS <10 u <3.9 u <IOu 0.02 64.S l' 70.8 60.2 l' 2,000 <S' <0.2 u <5' NS <5' <0.4 u <5' 1.8 916 bl' 278-0 885 b NS 1.9 b <0.9 u I b 50 <5' <0.6 u <5' NS <S' 2.3 bU <S' 1000 80.4 b <9.8 u <IOOu 300 <)' <2.6 u <)' 15 447 bl' 856 b 413 b NS 38.1 e "' 31.3 t 50 <0.2 u <0.1 u 0.13 b 1.1 <5' 2.7 bU <5' 100 3460 3770 3460 NS <5' <3.9 un 2.6 un 50 I.lb <0.8 un <5' 17.5 1960 b 3520 eJ 1570 b NS <!Ou 7.4 bU <10 u NS <20u <0.5 u <20 u NS 2l • 6.0bU 19.1 b 1050 • i,,xldion Identification Fkld Sample ldentifictUion Sample Type Date Collected Find Lab Mttals (µ.g/1) Aluminum Antimony Ar.enic Barium Beryllium Cadmium Calcium Chromium. Total Cobalt Copper lroa '-'"' Mag~siwn Manga~!.e M~ul)" Nickel Potassium Selenium Silver Sodium Thallium Vanadium Zinc No~s: I. NS = No Standard established 2. (FF)= Field Iii~ 3. Qualifier; summarized at end of sect A TF/vlr/LBL N:\Jobs\208\2593\GW Qua!i1y.,ds (FIXED METALS IN WGJ 2082593.01160101 MADI 6/17/2003 MW-05 MW-05 MW-05 MW-0, Normal Normal ll3MOOI 4/29/1003 970 • 90 b <3.S u <IO u <3.9 un <JO u 62.9 eJ 52.5 t <0.2 u <S' <0.4 II <S' 1580 • 559 bt 20 8.9 II ,., 1.4 b 7.7 U <S' 1360 °nJ 184 ,., <3' 936 b 583 .. '". 70.6 t <0.1 u <0.2 II 18.5 6.1 3150 * 2670 <3.9 unR <S" <0.8 u <S" ◄920 eJ , ... , <5.1 un <10 II 2.Sb <20 II 25.1 15.3 b* SUMMARY OF FIXED ~1ETALS RESULTS IN CROUl"iD WATER SA~1PLES JOH1'SOS COl"iTROLS BATTERY CROUP, INC. WISSTOS SALEM, 1'ORTH CAROLINA PLANT AREA MW-05(fF) MW-OS (FF) MW-06 MW-05 MW-05 MW-06 Normal Normal Normal 1/30/1001 ◄/29/1003 1(30/1001 m <100u 168 •u <3.5 u <\Ou <3.S II <3.9 u <10 u <J.9 un ◄5.8 ... 43.5 eJ <0.2 II 0.13 b <0.2 II <0.4 u <S' <0.4 II 1450 526 b 3660 • <0.9 u 1.8 b 13b 1.7 bU 1.2 b <0.6u 4.5 bU <5 II 2.7 bU m 52.9 b 176 •nJ <2.6 II <3' ,., 761 b 531 b "'' 326 60.8 t 1130 • <0.1 II <0.2 II <0.1 u 5.5 U 2.7 b 2.9bU 3030 2580 2900 • <3.9 1111 2.6 UD <3.9 unR <0.11 un <S" <0.8 u 3740 ,J 1650 b ◄580 ,J 6.4 bU <!Ou <5.1 un <0.5 u <2011 <0.5 II 10.4 bU <2011 13.4 bU 3 of 3 MW-06 MW-06(Ff) MW-06(FF) MW-06 MW-06 MW-06 HHSSL Normal Normal Normal Croundwatn ◄/l'J/2003 1130/1001 4/29/2003 15A l"iCA 2L • 133 <13.8 u <]00 u NS <10 II <3.S u <\Ou NS <]0 II <3.9 u <\Ou 0.02 58.4 t 38.8 57.4, 2,000 <S' <0.2 II <S' NS <S' <0.4 II <S' 1.8 2080 t 3710 3'70 NS 6.7 <0.9 u 0.89 b so <S' <0.6 u <S' NS <S' 3.5 bU <S' 1000 320 <9.8 u 571 300 <3' 4.7 <)" 15 996b< I 140 1250 NS 967 t IOSO 3060 t so <0.2 u <0.1 u <0.2 u 1.1 3.5 b 4.2 bU 1.4 b 100 3110 2810 "" NS <S" <3.9 un 2.6 un so <S' <0.8 un <S" 17.5 2560 3790 ,J 1360 NS <\Ou 8.1 bU <10 II NS <20u <0.5 II <20 II NS 10.2 b• 12.3 bU 27.1 1050 • S:10"0 n ,:·0> nnp SN ",, n O"I> """ n ,:·0> nnp n n ,:·0> n 5"0> '' n S:"O> nnr> " n S:"O> n i;·O> '"" qfro n •·O> " n S:'O> n •·IP SN n s:·O> n ,·n:, "' n S'O> n S:'O> ; qff"I n S:'O> "' ",, 00·1> tt·o n )'0> n s:·O> • " II >"0> n >"O> """ II S"O> n >"O> SN II S"O> .... 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INC. ,,,., ... "·••if"••··· 1 Fi,ri,J .S.-,,k 1,1~,.,if.,,•NI" S• .. pi~ TftK o.u c.11=~• \"olullr O<1:■-k Compoand, (ia~) L.l.l-Trichlonxthane 1.1.2.2-T cm,chloroethane 1.1.2-T rn,hlonxthanc l.1-Dichloroc:thane 1.J-Dx,bloroetl,rne 1.2.4-TrichJ<.>«>br:nttn<, 1.2.4-Trirocliy!bnucnc l.2-Dichl~ 1.2-Dichlorortluine l .2-Dichlorupr!JP'lne 1.3.5-T rimc:<hylbenzcnc (Mesitylenc f 1.3-0ichlorobenttne 1.4-Dich~ 2-8uraaone (Methyl ethyl ketone) 2-Hcunone •-Mefhyl-2-penta!IOIII< (Mnhyl isot,o.dyl kcione) A=~ -Bromodichloromethane Bromofonn •-~ Carbon disulfide Carbon 1nnchloridc Chl"""""=< c,,""'"""~ Chloroform °""""""'"~ cis-1.2-Di<h~ylene cis-1.3-Dichloroi,ropcne O,bmmochloromnbane O,bromomcthane Dichloroditluor=l,ane bbylbelizenc HcxachlorobutadiCM Xylcnes. a & m Mefhylcnc chloride a-Xylcnc ( l.2-Dimro,yJbmzcne) "-T Clnchlorocthylenc(PCE) Toluene 1n1ns--lJ-[};cbk,ro,;,htne lnlns-1.J•Dichl~ Trichlon,et:hylcne (TCE) T richlorofluaromnhane Vinyl a=oic Vinyl chlaridc --,-L NS~ No Sanobrd establi.i..d 2. Quahficn. surnmuized at end of ocction. MW-IM MW-IM Normal WINSTON SALEM. 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North Carolina • Department of Environment and Natural Resources Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary Dexter R. 11atthcws, Interim Director April 22, 2003 Mr. Luis Flores Remedial Project Manager US EPA Region IV 61 Forsyth Street, I Ith Floor Atlanta, Georgia 30303 RE: Comments on the Draft Work Plan/Proposal Johnson Controls Battery Group, Inc. (JCBG) NCO 000 770 487 Winston Salem, Forsyth County, North Carolina Dear Mr. Flores: • The Draft Groundwater Sampling Work Plan, dated March 21, 2003, for groundwater at the Johnson Controls Battery Facility, located in Winston-Salem, NC has been received and reviewed. The following comments by the North Carolina Superfund Section are submitted for your consideration. Please Provide a Final Groundwater San1pling Work Plan prior to mobilization next Tuesday April 29. Specific Comments: I. The second paragraph on page 1 of the report states that PCB and SYOCs were excluded from the list of groundwater analytes based on the first round of sampling results. Monitoring well MW-01 should include analysis for SVOCs since it contained bis(2- ethylhexyl)phthalate in the first round results. Phthalates are generally associated with field or lab contamination due to contact with the rubber gloves used. SYOCs should also be included in the parameters list under B. on page 2. Those doing the sampling should be instructed not to touch the water samples or the interior of the lids or san1ple bottles during sampling and analysis. Please make appropriate corrections. 2. The sample schedule should be in spring of 2003 rather than spring 2002. 1646 Mail Service Center, Raleigh, North Carolina 27699-_1646 Phone: 919-733-4996 \ FAX: 9 I 9-715-3605 \ Internet: www.enr.state.nc.us AN EQUAL OPPORTUNITY\ AFFIRMATIVE ACTION EMPLOYER-SO% RECYCLED/ 10% POST CONSUMER PAPER Mr. Luis Flores 4-22-2003 Page 2 of2 • • The State appreciates the opportunity to comment on this document and we look forward to working with you on.the project. If you have any questions or comments, please call me, at (919) 733-2801, extension 341 or email at ranclv.mcclvccn@nc111ail.nc1. Sincerely, ,-( 1 '9fe i ~. -t~1{,xUL01A Randy McE!veen · \ cc: Dave Lown, N.C. Superfund Section Environmental Engineer NC Superfund Section I O : I 9 am March 21, 2003 l'v1r. Timothy J. Lafond Johnson Controls Battery Group, Inc. 5757 N. Green Bay Avenue PO Box 0591 i\1ilwaukee, Wisconsin 53201-059! Re: Proposal for Groundwater Sampling Winston-Salem Facility Dear Tim: +404 561 ,. T-60i: P 001/005 f-5S6 RA M\VH Americas, Inc. (M\VH) is presenting this proposal for groundwater monitoring at the JCBGI Winston-Salem facility, in accordance with JCBGI's previous commitment to the USEPA for a second round of monitoring. As described in the design report submitted to USEPA, a confirmation round of groundwater sampling would be completed during removal action activities. The gro,indwater sampling confirmation round includes analysis of metals, volatile organic compounds, and pesticides in groundwater. Semi-volatiles and PCBs were explicitly excluded from the list of analytes, based on the first round of sampling results reviewed from the EE/CA investigation. The Quality Assurance Project Plan (QAPP) and Field Sampling Plan (FSP) previously developed for the EE/CA guide this second round of confirmation groundwater sampling and analysis. The sections below outline the scope of work, estimated costs, and schedule associated with this confirmation round sampling. SCOPE OF WORK A. Groundwater Sampling The field technicians will sample each of the 6 monitoring wells using low-flow purge sampling techniques to obtain representative groundwater samples. Prior to groundwater sampling, each monitoring well will be purged. A clean plastic drop cloth will be spread around the well prior to purging. Purging will be accomplished by removing groundwater from the monitoring wells using a decontaminated, low-flow submersible pump with new dedicated polyethylene discharge tubing. Purging will continue until water quality parameters, including pH, temperature, redox, conductivity, and turbidity, have stabilized and a minimum of 3 and maximum of 5 well-volumes will be removed or the well 1s pumped dry. Purge water will be containerized in 55-gallon drums. 1-509 P 003/005 f-596 Once the wells have been proper! y purged, groundwater samples will be collected. The groundwater samples for total metals analyses will be collected directly from the polyethylene tubing. The groundwater sample for dissolved metals analyses will be field filtered using a 0.45--rnicron inline filter with the polyethylene tubing and discharged into the sample containers. The groundwater samples for VOCs and organochlorine pesticides analyses will be collected using a clean closed top Teflon® bailer. Groundwater samples will be placed in appropriate sample containers, preserved, properly labeled, and stored on ice. Chain of custody procedures will be followed for collection and shipping the samples. Field quality control (QC) samples will be collected to assess the quality of the analytical data and to evaluate sampling and analytical reproducibility (precision). Field quality control samples will consist of one each of a duplicate sample, field blank, matrix spike/ matrix spike duplicate, and trip blank. Each QC sample will be analyzed for all scheduled parameters, except the trip blank, which will be analyzed for VOCs, only. The groundwater Jeye) and total depth of each monitonng well will be measured using an eiectronic water-level indicator to an accuracy of 0.01 feet prior to purging the well. The water-level indicator will be rinsed with deionized water prior to each use. The depth to groundwater will be recorded in the field logbook and the well volume will be calculated. Liquids from the decontamination of sampling equipment and sample purge water will be contained in 55-gal drums for later disposal or treatment by facility management. B. "'ater Quality Analyses Each of the six groundwater samples and QC samples will be analyzed for the following parameters: Toto! TAL Metnis Dissolved T.4L Metals voes Organochlarine pesticides 3005A/60l0B/7470A 3005N60 I 0B/7 4 70A 5030B18260B 8081 Compuchem Laboratories of Research Triangle Park, NC will conduct the analyses of the groundwater samples. C. Report Preparation After receipt from the laboratory, the groundwater quality results will be reviewed and a brief written report will be prepared for eventual submittal to the USEPA. The report will include a brief description of the methods, .report text, summary tables of analytical parameter detections compared to groundwater quality standards, appended analytical reports, and a table of groundwater level measurements. A dtaft copy of the report will be prepared for JCBGI and comment prior to submittal to USEPA. Mr. Timothv J _ Lafond . March 21. 2003 Johnson Controls Batter• Gro:.ip. T11c Page 2 Apr-1\-03 i0:10am P 00,100: D. Project Management/Meeting Project management will include routine co=umcation with JCBGI and project staff, scheduling, and cost management. A meeting has been budgeted to review results with JCBGI in .tvii!waukee. ESTIMATED COSTS Estimated costs for this project are presented in the table below: Task. Estimated Cost Groundwater Sampling \Vater Quality AnJlyscs Report Preparation Project Manngement/Mccting Total $ 7,800 3,600 1,200 2 100 $14,700 The work will be conducted on u time and materials basis in accordance with the attached fee schedule and the April 7, 1997 Master Services Agreement. The actual costs may be more or less than the estimate. Assumptions that affect the cost estimate include the following: The sampling crew will consist of 2 persons for 2 days. • Costs for disposal or u·eatment of purge water are not included in the estimate. • l\1\VH will make arrangements for delivery of the 55-gal drums to the facility. • Data verification will be performed on the sample results by inspection of QC sample results and normal laboratory QC procedure. The report will not include any drawings or figures depicting groundwater quality results. • No meetings with the agency or development of final monitoring plans are included within the budget. SCHEDULE The schedule for sampling will be established by JCBGI in Spring 2002. tv1\VH can mobilize to the site within 2 weeks of notification of sampling to proceed. Mr. Timothy J. Lafond March 2 I. 2003 Page 3 JohrL~nn Controls Battery Gronp1 Inc. A.cr:2i-03 iG:20am Frcm-North -fund i-606 P 005/005 F-555 AUTHORIZATION JCBGI' s authorization of ~{WH to conduct this work is signing and returning the attached Work Order. We appreciate the opportunity to continue services on this project for JCBGL Please call me with any questions or comments. Sincerely, MWB AMERICAS, )NC Daniel W Hall, PG Project Manager Enclosures: Work Order DWH/vlr/LDL \\Usmad I s02 \.\foi.n\Jobs\800\480 l \2003\501'Wp1Jt:\62__Lafoad_ WS S w Monitoring.doc EC0480l .D0500\0 i -MAD1 Mr. Timothy J. Lafond Morch 21, 2003 Page 4 Johnson Contrcils B;itterv Qroup 1 Inc. i ,J: \ 9 arr1 r-so; ?.0011oos F-sas . ft . ~, . ' ~ UNITED STATES ENVIRONMENTAL PROTECTION AGENCY REGION 4 Atlanta Federal Center 61 Forsyth Street, S.W. Atlanta, Georgia 30303-8960 FACSIMILE TRANSMITTAL COVER SHEET . -·---· TO: ~ .. _fl, itfc/7£.,,~. - J 1JcDEN R COMPANY/ORGANIZATION: DATE: ~@! /o3 I PHONE NUMBER: FAX NUMBER: 'f/'7 -733-C/J' // NUMBER OF PAGES SENT (Including this cover sheet): ;) Please contact the person sending this fax if it is received poorly or incomplete, FROM: LUIS E. FLORES NORTH SITE MANAGEMENT BRANCH WASTE MANAGEMENT DIVISION Phone Number: (404) 562-8807 Fax Number: (404) 562-8788 COMMENTS: ~;' u ~ ~ 6{,U i<V /' V r-u "llf) J 0--C ~ Ciz!.f-! r I , ( --I I, c/-,; #-L -//'A, i --, I/ /I_ -. ,/V. ~rJ-2 '1 f ".fO :]od.J / -• Cl J '