6002_Mecklenburg_HolbrooksRoad_MSWLF_March2023GW_FID1792209_20230503

kR USE ONLY []Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Mecklenburg County Solid Waste Services
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Amber R. Grzymski, P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006)
Holbrooks Road Landfill 15401 Holbrooks Road 60-02 .0500 March 29-30, 2022
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Amber R. Grzymski, P.G. Project Manager
Facility Re esent ti!, . M*(P ' Title
2145 Suttle Ave, Charlotte, NC 28208
Facility Representative Address
980-314-3855
(Area Code) Telephone Number
05/03/2023 Affix NC Licensed/
401
Date d 4b0
1877
Geologist Seal
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

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MECKLENBURG COUNTY
Land Use and Environmental Services Agency
Solid Waste Services
May 3, 2023
Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70
Swannanoa, IBC 28778
Subject: Holbrooks Road Landfill Permit 60-02
Semi-annual WQ Monitoring
Dear Ms. Drummond:
Mecklenburg County conducted semi-annual water quality monitoring at the closed
Holbrooks Road Landfill March 29-30, 2023 in accordance with the approved sample
and analysis plan dated March 27, 2003. This report details the results of that monitoring
event. Laboratory analytical data, field -measured data table of values exceeding 2L
standards is contained on the electronic data deliverable submittal.
Samples were collected from eleven (11) monitoring wells (HRW-7, HRW-8, HRW-9R,
HRW-10, HRW-11 R, HRW-13, HRW-16, HRW- 18. HRW-19, HRW-20 and HRW-21)
and three (3) surface -water sampling locations (HRSW-2, HRSW-3 and HRSW-4).
Samples were analyzed for metals and volatile organic compounds ("VOCs") listed in
Appendix I of 40 CFR Part 258.54 "Detection monitoring program". Samples were also
analyzed for 1,4-Dioxane as required as of July 1, 2018. Field measurements of
temperature, pH, and specific conductivity were made at each sampling location using a
calibrated instrument. Additionally, measurements of dissolved oxygen were made at
each surface -water sampling location.
The electronic data deliverable package containing the monitoring data is labeled to
reflect the units used for reporting. Surface water standards listed are the water quality
standards established for freshwater classification for aquatic life as outlined in 15A
NCAC 213 "Classification and Water Quality Standards Applicable to Surface Waters of
North Carolina". Groundwater standards listed are the standards outlined in 15A NCAC
2L "Classification of Water Quality Standards applicable to the Groundwaters of North
Carolina". If the sample is reported in parts per billion, then the standard is also reported
in parts per billion.
PEOPLE - PRIDE - PROGRESS - PARTNERSHIP
2145 Suttle Ave - Charlotte, North Carolina 28208 - [phone] Fax [phone]
www.wipeoutwaste.com

Page 2
Surface -water samples:
Barium was detected in all 3 stream sampling locations. The following table summarizes
the metals detections for the surface water sampling locations. Beaver activity has created
an area of standing / slow moving water near sampling location HRSW-4.
Sample Location
Barium
u /1
HRSW-2 upstream
31.3
HRSW-4 mid -stream
44.4
HRSW-3 downstream
35.0
No VOCs were detected in any of the samples collected from the three surface -water
sampling locations (HRSW-2, HRSW-4 and HRSW-3). All field -measured parameters
were within the established regulatory limits. The following table summarizes field -
measured parameters for surface water samples.
Sample Location
Temp.
°C
pH
S.U.
Specific Conductivity
ms/cm
Dissolved Oxygen
mg/1
HRSW-2 upstream
15.8
7.2
0.207
10.52
HRSW-4 mid -stream
15.2
7.2
0.208
10.61
HRSW-3 downstream
15.0
7.3
0.225
11.57
Groundwater samples:
Vanadium and cobalt were detected in various wells above the 21 standard. The
following table summarizes metals detection for groundwater samples.
Well ID
As
ug/1
Ba
ug/1
Be
ug/1
Cd
ug/1
Cr
ug/1
Co
ug/1
Cu
ug/1
Pb
ug/1
Ni
ug/1
Se
ug/1
Vn
ug/1
Zn
ug/1
HRW-7
-----
111
-----
4.8
-----
10.5
-----
-----
-----
-----
-----
46.1
HRW-8
-----
72.7
-----
-----
-----
-----
6.0
-----
-----
-----
10.5
-----
HRW-9R
-----
349
-----
-----
-----
17.6
6.0
-----
5.5
-----
-----
-----
HRW-10
-----
94.0
-----
-----
-----
-----
-----
-----
7.7
-----
-----
-----
HRW-11R
-----
134
-----
-----
-----
5.3
----
-----
15.5
-----
-----
-----
HRW-13
------
41.6
-----
-----
-----
-----
104
-----
9.9
-----
5.7
-----
HRW-16
-----
76.8
-----
-----
-----
-----
-----
-----
-----
-----
-----
-----
HRW-18
-----
280
-----
-----
-----
6.0
-----
-----
9.7
-----
-----
-----
HRW-19
-----
94.1
-----
-----
-----
-----
-----
-----
-----
-----
-----
-----
HRW-20
-----
138
-----
-----
-----
-----
-----
-----
-----
-----
6.6
-----
HRW-21
-----
58.6
-----
-----
-----
-----
-----
----
-----
-----
6.7
-----
2L Std.
10
700
4
2
10
1
1,000
15
100
20
0.3
1,000
Note: Results shown in bold exceed the 2L standard.

Page 3
VOCs were detected in six monitoring wells; HRW-7, HRW-9R, HRW-10, HRW-11R,
HRW-18 and HRW-20. The following table summarizes VOC detections.
Well ID
Volatile Constituent
Concentration
2L Standard
u /1
(u /1)
HRW-7
Cis-1,2-Dichloroethene
1.4
70
Trichloroethane
1.9
3
HRW-9R
Chlorobenzene
2.2
50
Chloroethane
1.4
3000
1,2-Dichlorobenzene
4.1
20
1,4-Dichlorobenzene
5.5
6
1,1-Dichloroethane
25.8
6
1,2-Dichloroethane
1.9
0.4
cis-1,2-Dichloroethane
64.6
70
1,2-Dichloropropane
2.5
0.6
Vinyl Chloride
6.0
0.03
1,4-Dioxane
13.1
3
HRW-10
1,4-Dioxane
4.6
3
HRW-11R
Chlorobenzene
1.5
50
1,4-Dioxane
73.7
3
HRW-18
Benzene
1.9
1
Chlorobenzene
5.0
50
Chloroethane
4.0
3000
1,1-Dichloroethane
23.4
6
cis-1,2-Dichloroethane
1.3
70
1,2-Dichloropropane
29
0.6
1,4-Dichlorobenzene
5.6
6
1,4-Dioxane
19.8
3
Trichlorofluoromethane
3.1
2000
Vinyl Chloride
6.4
0.03
HRW-20
1,1-Dichloroethane
10.0
6
Chloroethane
1.0
3 000
cis-1,2-Dichloroethane
1.3
70
Note: Results shown in bold exceed the 2L standard.
Measurements of pH were more acidic than the 2L standard range of 6.5 to 8.5 standard
units at HRW-7, HRW-8, HRW-9R, HRW-11R, HRW-13, HRW-16, HRW-19, HRW-20
and HRW-21. Field- measured parameters for groundwater samples are summarized in
the following table.

Page 4
Sample Location
Temp. °C
PH
Specific Conductivity ms/cm
HRW-7
17.0
5.9
0.324
HRW-8
12.3
5.6
0.077
HRW-9R
14.7
6.1
1.042
HRW-10
13.2
6.6
0.615
HRW-11R
13.9
5.9
1.688
HRW-13
12.2
5.5
0.085
HRW-16
13.6
5.1
0.073
HRW-18
15.4
6.5
1.076
HRW-19
13.9
6.1
0.367
HRW-20
14.8
5.8
0.409
HRW-21
15.6
6.0
0.472
Note: Results shown in bold are outside of the 2L standard range of 6.5 - 8.5 S.U.
Please call me at [phone] if you have any questions regarding this report.
,u000u9o� Sincerely,
o SEA
o 18�+RI Amber R. Grzymski, P.G.
�t 1% Project Manager
��;�� Solid Waste Services

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-.......I APPROXIMATE PIPELINE EASEMENT
-••—••- STREAM LOCATION (SEE REFERENCE 1)
APPROXIMATE POTENTIOMETRIC SURFACE CONTOUR (SPRING 2014)
GROUNDWATER DIVIDE
® MONITORING WELL (SEE REFERENCE 1)
DIRECTION OF GROUNDWATER FLOW
REFERENCES
1. PROPERTY LINES, MONITORING WELLS, STREAM AND WATER BODY
LOCATIONS, AND STRUCTURE LOCATIONS FROM MECKLENBURG
COUNTY GIS DEPARTMENT. EXISTING TOPOGRAPHY FROM NCDOT
LIDAR DATA.
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 10, 2023
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni for
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92659513001 6002-HRSW2
EPA 601OD
D13131
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659513002 6002-HRSW3
EPA 601 OD
D661
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659513003 6002-HRSW4
EPA 601 OD
D661
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW2 Lab ID: 92659513001 Collected: 03/29/23 14:08 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:01
7440-38-2
Barium
31.3
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:01
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:01
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:01
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:01
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:01
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:01
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 02:36
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 01:53
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 01:53
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 01:53
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 01:53
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 01:53
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 01:53
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 01:53
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 01:53
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 01:53
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 01:53
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 01:53
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 01:53
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 01:53
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 01:53
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 01:53
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 01:53
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 01:53
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 01:53
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 01:53
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 01:53
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 01:53
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 01:53
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 01:53
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW2 Lab ID: 92659513001 Collected: 03/29/23 14:08 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:09 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
97
%
108
%
110
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
87 %
93 %
1.0
1
03/31/23 01:53
75-35-4
1.0
1
03/31/23 01:53
156-59-2
1.0
1
03/31/23 01:53
156-60-5
1.0
1
03/31/23 01:53
78-87-5
1.0
1
03/31/23 01:53
10061-01-5
1.0
1
03/31/23 01:53
10061-02-6
1.0
1
03/31/23 01:53
100-41-4
5.0
1
03/31/23 01:53
591-78-6
20.0
1
03/31/23 01:53
74-88-4
5.0
1
03/31/23 01:53
75-09-2
5.0
1
03/31/23 01:53
108-10-1
1.0
1
03/31/23 01:53
100-42-5
1.0
1
03/31/23 01:53
630-20-6
1.0
1
03/31/23 01:53
79-34-5
1.0
1
03/31/23 01:53
127-18-4
1.0
1
03/31/23 01:53
108-88-3
1.0
1
03/31/23 01:53
71-55-6
1.0
1
03/31/23 01:53
79-00-5
1.0
1
03/31/23 01:53
79-01-6
1.0
1
03/31/23 01:53
75-69-4
1.0
1
03/31/23 01:53
96-18-4
2.0
1
03/31/23 01:53
108-05-4
1.0
1
03/31/23 01:53
75-01-4
1.0
1
03/31/23 01:53
1330-20-7
2.0
1
03/31/23 01:53
179601-23-1
1.0
1
03/31/23 01:53
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 01:53 460-00-4
03/31/23 01:53 17060-07-0
03/31/23 01:53 2037-26-5
[et01197f asF11fifi=if aS4Qi 1I
04/03/23 19:11 17060-07-0
04/03/23 19:11 2037-26-5
Page 5 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW3 Lab ID: 92659513002 Collected: 03/29/23 13:15 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:04
7440-38-2
Barium
35.0
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:04
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:04
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:04
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:04
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:04
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:04
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 02:55
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 02:11
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 02:11
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 02:11
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 02:11
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 02:11
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 02:11
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 02:11
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 02:11
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 02:11
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 02:11
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 02:11
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 02:11
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 02:11
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 02:11
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 02:11
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 02:11
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 02:11
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 02:11
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:11
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:11
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 02:11
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:11
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:11
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW3 Lab ID: 92659513002 Collected: 03/29/23 13:15 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:09 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
97
%
106
%
104
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
95 %
96 %
1.0
1
03/31/23 02:11
75-35-4
1.0
1
03/31/23 02:11
156-59-2
1.0
1
03/31/23 02:11
156-60-5
1.0
1
03/31/23 02:11
78-87-5
1.0
1
03/31/23 02:11
10061-01-5
1.0
1
03/31/23 02:11
10061-02-6
1.0
1
03/31/23 02:11
100-41-4
5.0
1
03/31/23 02:11
591-78-6
20.0
1
03/31/23 02:11
74-88-4
5.0
1
03/31/23 02:11
75-09-2
5.0
1
03/31/23 02:11
108-10-1
1.0
1
03/31/23 02:11
100-42-5
1.0
1
03/31/23 02:11
630-20-6
1.0
1
03/31/23 02:11
79-34-5
1.0
1
03/31/23 02:11
127-18-4
1.0
1
03/31/23 02:11
108-88-3
1.0
1
03/31/23 02:11
71-55-6
1.0
1
03/31/23 02:11
79-00-5
1.0
1
03/31/23 02:11
79-01-6
1.0
1
03/31/23 02:11
75-69-4
1.0
1
03/31/23 02:11
96-18-4
2.0
1
03/31/23 02:11
108-05-4
1.0
1
03/31/23 02:11
75-01-4
1.0
1
03/31/23 02:11
1330-20-7
2.0
1
03/31/23 02:11
179601-23-1
1.0
1
03/31/23 02:11
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 02:11 460-00-4
03/31/23 02:11 17060-07-0
03/31/23 02:11 2037-26-5
[et01197f asF11Blom f aS4Qi1I
04/03/23 19:30 17060-07-0
04/03/2319:30 2037-26-5
Page 7 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW4 Lab ID: 92659513003 Collected: 03/29/23 13:45 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:07
7440-38-2
Barium
44.4
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:07
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:07
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:07
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:07
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:07
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:07
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 02:59
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 02:29
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 02:29
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 02:29
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 02:29
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 02:29
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 02:29
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 02:29
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 02:29
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 02:29
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 02:29
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 02:29
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 02:29
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 02:29
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 02:29
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 02:29
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 02:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 02:29
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 02:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:29
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:29
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 02:29
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:29
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:29
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
Sample: 6002-HRSW4 Lab ID: 92659513003 Collected: 03/29/23 13:45 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:09 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
105
%
104
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
84 %
94 %
1.0
1
03/31/23 02:29
75-35-4
1.0
1
03/31/23 02:29
156-59-2
1.0
1
03/31/23 02:29
156-60-5
1.0
1
03/31/23 02:29
78-87-5
1.0
1
03/31/23 02:29
10061-01-5
1.0
1
03/31/23 02:29
10061-02-6
1.0
1
03/31/23 02:29
100-41-4
5.0
1
03/31/23 02:29
591-78-6
20.0
1
03/31/23 02:29
74-88-4
5.0
1
03/31/23 02:29
75-09-2
5.0
1
03/31/23 02:29
108-10-1
1.0
1
03/31/23 02:29
100-42-5
1.0
1
03/31/23 02:29
630-20-6
1.0
1
03/31/23 02:29
79-34-5
1.0
1
03/31/23 02:29
127-18-4
1.0
1
03/31/23 02:29
108-88-3
1.0
1
03/31/23 02:29
71-55-6
1.0
1
03/31/23 02:29
79-00-5
1.0
1
03/31/23 02:29
79-01-6
1.0
1
03/31/23 02:29
75-69-4
1.0
1
03/31/23 02:29
96-18-4
2.0
1
03/31/23 02:29
108-05-4
1.0
1
03/31/23 02:29
75-01-4
1.0
1
03/31/23 02:29
1330-20-7
2.0
1
03/31/23 02:29
179601-23-1
1.0
1
03/31/23 02:29
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 02:29 460-00-4
03/31/23 02:29 17060-07-0
03/31/23 02:29 2037-26-5
[et01197fasF11CRZifaS4Qi 1I
04/03/23 19:49 17060-07-0
04/03/2319:49 2037-26-5
Page 9 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
QC Batch: 766032 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659513001, 92659513002, 92659513003
METHOD BLANK: 3977273 Matrix: Water
Associated Lab Samples: 92659513001, 92659513002, 92659513003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
1.0
04/07/2312:32
1.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3977274
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
501
100
80-120
Arsenic
ug/L
500
499
100
80-120
Barium
ug/L
500
511
102
80-120
Beryllium
ug/L
500
504
101
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
506
101
80-120
Lead
ug/L
500
507
101
80-120
Nickel
ug/L
500
508
102
80-120
Selenium
ug/L
500
498
100
80-120
Silver
ug/L
250
249
99
80-120
Thallium
ug/L
500
505
101
80-120
Vanadium
ug/L
500
510
102
80-120
Zinc
ug/L
500
504
101
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
6002 HOLBROOKS RD LANDFILL
92659513
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
3977275
3977276
MS
MSD
92659004001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
522
106
104
75-125
1
Arsenic
ug/L
ND
500
500
528
523
105
104
75-125
1
Barium
ug/L
583
500
500
1120
1100
107
103
75-125
2
Beryllium
ug/L
ND
500
500
522
522
104
104
75-125
0
Cadmium
ug/L
ND
500
500
513
509
103
102
75-125
1
Chromium
ug/L
ND
500
500
520
515
104
103
75-125
1
Cobalt
ug/L
16.0
500
500
536
530
104
103
75-125
1
Copper
ug/L
ND
500
500
537
529
107
106
75-125
1
Lead
ug/L
ND
500
500
518
512
103
102
75-125
1
Nickel
ug/L
ND
500
500
518
512
103
102
75-125
1
Selenium
ug/L
ND
500
500
545
537
109
107
75-125
1
Silver
ug/L
ND
250
250
263
258
105
103
75-125
2
Thallium
ug/L
ND
500
500
517
510
103
102
75-125
1
Vanadium
ug/L
ND
500
500
536
530
107
106
75-125
1
Zinc
ug/L
ND
500
500
516
512
103
102
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
QC Batch: 766335 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659513001, 92659513002, 92659513003
METHOD BLANK: 3979049
Matrix:
Water
Associated Lab Samples: 92659513001, 92659513002, 92659513003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Thallium
ug/L
ND
0.20
04/07/23 02:28
LABORATORY CONTROL SAMPLE:
3979050
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
26.5
106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979051 3979052
MS MSD
92659513001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Thallium ug/L ND 25 25 27.2 26.5 109 106 75-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
QC Batch: 764931 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659513001, 92659513002, 92659513003
METHOD BLANK: 3971910 Matrix:
Associated Lab Samples: 92659513001, 92659513002, 92659513003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,1-Trichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,2-Trichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1-Dichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
1,2,3-Trichloropropane
ug/L
ND
1.0
03/31/23 00:40
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
03/31/23 00:40
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichlorobenzene
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloropropane
ug/L
ND
1.0
03/31/23 00:40
1,4-Dichlorobenzene
ug/L
ND
1.0
03/31/23 00:40
2-Butanone (MEK)
ug/L
ND
5.0
03/31/23 00:40
2-Hexanone
ug/L
ND
5.0
03/31/23 00:40
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/31/23 00:40
Acetone
ug/L
ND
25.0
03/31/23 00:40
Acrylonitrile
ug/L
ND
10.0
03/31/23 00:40
Benzene
ug/L
ND
1.0
03/31/23 00:40
Bromochloromethane
ug/L
ND
1.0
03/31/23 00:40
Bromodichloromethane
ug/L
ND
1.0
03/31/23 00:40
Bromoform
ug/L
ND
1.0
03/31/23 00:40
Bromomethane
ug/L
ND
2.0
03/31/23 00:40
Carbon disulfide
ug/L
ND
2.0
03/31/23 00:40
Carbon tetrachloride
ug/L
ND
1.0
03/31/23 00:40
Chlorobenzene
ug/L
ND
1.0
03/31/23 00:40
Chloroethane
ug/L
ND
1.0
03/31/23 00:40
Chloroform
ug/L
ND
1.0
03/31/23 00:40
Chloromethane
ug/L
ND
1.0
03/31/23 00:40
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/31/23 00:40
Dibromochloromethane
ug/L
ND
1.0
03/31/23 00:40
Dibromomethane
ug/L
ND
1.0
03/31/23 00:40
Ethylbenzene
ug/L
ND
1.0
03/31/23 00:40
lodomethane
ug/L
ND
20.0
03/31/23 00:40
m&p-Xylene
ug/L
ND
2.0
03/31/23 00:40
Methylene Chloride
ug/L
ND
5.0
03/31/23 00:40
o-Xylene
ug/L
ND
1.0
03/31/23 00:40
Styrene
ug/L
ND
1.0
03/31/23 00:40
Tetrachloroethene
ug/L
ND
1.0
03/31/23 00:40
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
METHOD BLANK: 3971910 Matrix:
Associated Lab Samples: 92659513001, 92659513002, 92659513003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed Qualifiers
Toluene
ug/L
ND
1.0
03/31/23 00:40
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/31/23 00:40
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/31/23 00:40
Trichloroethene
ug/L
ND
1.0
03/31/23 00:40
Trichlorofluoromethane
ug/L
ND
1.0
03/31/23 00:40
Vinyl acetate
ug/L
ND
2.0
03/31/23 00:40
Vinyl chloride
ug/L
ND
1.0
03/31/23 00:40
Xylene (Total)
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloroethane-d4 (S)
%
108
70-130
03/31/23 00:40
4-Bromofluorobenzene (S)
%
97
70-130
03/31/23 00:40
Toluene-d8 (S)
%
101
70-130
03/31/23 00:40
LABORATORY CONTROL SAMPLE:
Parameter
3971911
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
21.5
107
70-130
1,1,1-Trichloroethane
ug/L
20
21.5
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.6
103
70-130
1,1,2-Trichloroethane
ug/L
20
20.5
103
70-130
1,1-Dichloroethane
ug/L
20
21.6
108
70-130
1,1-Dichloroethene
ug/L
20
21.3
106
70-130
1,2,3-Trichloropropane
ug/L
20
20.3
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.4
97
70-131
1,2-Dibromoethane (EDB)
ug/L
20
20.9
105
70-130
1,2-Dichlorobenzene
ug/L
20
20.6
103
70-130
1,2-Dichloroethane
ug/L
20
20.9
104
70-130
1,2-Dichloropropane
ug/L
20
20.8
104
70-130
1,4-Dichlorobenzene
ug/L
20
20.3
102
70-130
2-Butanone (MEK)
ug/L
40
39.6
99
70-134
2-Hexanone
ug/L
40
42.8
107
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
41.0
102
70-130
Acetone
ug/L
40
37.9
95
70-133
Acrylonitrile
ug/L
100
107
107
70-130
Benzene
ug/L
20
20.6
103
70-130
Bromochloromethane
ug/L
20
21.2
106
70-130
Bromodichloromethane
ug/L
20
20.0
100
70-130
Bromoform
ug/L
20
19.4
97
70-130
Bromomethane
ug/L
20
14.8
74
45-151 v3
Carbon disulfide
ug/L
20
21.1
105
70-130
Carbon tetrachloride
ug/L
20
20.2
101
70-130
Chlorobenzene
ug/L
20
20.5
102
70-130
Chloroethane
ug/L
20
20.6
103
39-152
Chloroform
ug/L
20
21.6
108
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
LABORATORY CONTROL SAMPLE:
Parameter
3971911
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
20
21.2
106
58-130
cis-1,2-Dichloroethene
ug/L
20
21.1
105
70-130
cis-1,3-Dichloropropene
ug/L
20
20.7
103
70-130
Dibromochloromethane
ug/L
20
20.5
103
70-130
Dibromomethane
ug/L
20
19.8
99
70-130
Ethylbenzene
ug/L
20
20.0
100
70-130
lodomethane
ug/L
40
35.5
89
53-141
m&p-Xylene
ug/L
40
41.6
104
70-130
Methylene Chloride
ug/L
20
19.2
96
66-130
o-Xylene
ug/L
20
20.8
104
70-130
Styrene
ug/L
20
20.7
104
70-130
Tetrachloroethene
ug/L
20
20.1
100
70-130
Toluene
ug/L
20
20.0
100
70-130
trans-1,2-Dichloroethene
ug/L
20
20.5
102
70-130
trans- 1,3-Dichloropropene
ug/L
20
20.5
102
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
22.6
113
57-185
Trichloroethene
ug/L
20
20.2
101
70-130
Trichlorofluoromethane
ug/L
20
19.5
98
62-130
Vinyl acetate
ug/L
40
42.4
106
70-144
Vinyl chloride
ug/L
20
17.7
88
62-130
Xylene (Total)
ug/L
60
62.4
104
70-130
1,2-Dichloroethane-d4 (S)
%
105
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971912
MS
92659513001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3971913
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.7
22.5
113
112
70-141
1
1,1,1-Trichloroethane
ug/L
ND
20
20
21.7
21.7
109
109
70-150
0
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.5
19.8
103
99
69-142
4
1,1,2-Trichloroethane
ug/L
ND
20
20
22.0
20.8
110
104
70-138
6
1,1-Dichloroethane
ug/L
ND
20
20
19.3
19.8
97
99
70-150
2
1,1-Dichloroethene
ug/L
ND
20
20
21.9
21.2
109
106
70-156
3
1,2,3-Trichloropropane
ug/L
ND
20
20
20.8
19.6
104
98
70-140
6
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.6
22.2
108
111
68-146
3
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.6
20.3
108
101
70-138
6
1,2-Dichlorobenzene
ug/L
ND
20
20
22.1
21.7
110
109
70-141
2
1,2-Dichloroethane
ug/L
ND
20
20
20.8
19.6
104
98
69-143
6
1,2-Dichloropropane
ug/L
ND
20
20
20.5
19.9
103
99
68-156
3
1,4-Dichlorobenzene
ug/L
ND
20
20
21.8
20.9
109
105
70-142
4
2-Butanone (MEK)
ug/L
ND
40
40
39.3
36.4
98
91
60-157
8
2-Hexanone
ug/L
ND
40
40
42.0
39.3
105
98
68-146
7
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
40.0
37.3
100
93
70-141
7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971912
MS
92659513001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3971913
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Acetone
ug/L
ND
40
40
37.7
35.0
91
84
58-157
7
Acrylonitrile
ug/L
ND
100
100
97.2
90.5
97
91
69-147
7
Benzene
ug/L
ND
20
20
22.1
21.4
111
107
70-142
3
Bromochloromethane
ug/L
ND
20
20
22.6
21.7
113
108
70-146
4
Bromodichloromethane
ug/L
ND
20
20
21.1
20.5
105
102
70-139
3
Bromoform
ug/L
ND
20
20
22.4
21.5
112
108
64-140
4
Bromomethane
ug/L
ND
20
20
17.4
17.0
87
84
28-192
3
Carbon disulfide
ug/L
ND
20
20
21.0
20.4
105
102
70-151
3
Carbon tetrachloride
ug/L
ND
20
20
23.5
23.0
117
115
70-148
2
Chlorobenzene
ug/L
ND
20
20
22.2
21.8
111
109
70-141
2
Chloroethane
ug/L
ND
20
20
20.7
19.4
104
97
58-191
7
Chloroform
ug/L
ND
20
20
22.7
21.3
113
107
70-148
6
Chloromethane
ug/L
ND
20
20
20.1
19.4
101
97
43-162
4
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.5
19.7
102
99
68-151
4
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.5
20.4
108
102
70-139
5
Dibromochloromethane
ug/L
ND
20
20
21.5
21.3
108
106
70-144
1
Dibromomethane
ug/L
ND
20
20
22.5
22.0
113
110
70-139
2
Ethylbenzene
ug/L
ND
20
20
21.3
21.1
106
106
70-143
1
lodomethane
ug/L
ND
40
40
46.6
43.6
116
109
35-171
7
m&p-Xylene
ug/L
ND
40
40
43.9
43.0
110
107
70-144
2
Methylene Chloride
ug/L
ND
20
20
18.3
17.3
91
86
62-149
6
o-Xylene
ug/L
ND
20
20
22.3
21.9
112
109
70-145
2
Styrene
ug/L
ND
20
20
22.7
22.7
114
114
70-143
0
Tetrachloroethene
ug/L
ND
20
20
24.1
23.0
120
115
70-145
5
Toluene
ug/L
ND
20
20
21.5
20.7
108
103
70-142
4
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.6
19.6
103
98
70-151
5
trans- 1,3-Dichloropropene
ug/L
ND
20
20
21.9
20.9
109
105
70-139
4
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
23.1
21.7
115
109
51-159
6
Trichloroethene
ug/L
ND
20
20
23.4
22.9
117
114
62-146
2
Trichlorofluoromethane
ug/L
ND
20
20
22.4
21.8
112
109
63-153
3
Vinyl acetate
ug/L
ND
40
40
39.5
36.7
99
92
61-162
7
Vinyl chloride
ug/L
ND
20
20
17.5
16.8
88
84
61-163
4
Xylene (Total)
ug/L
ND
60
60
66.3
64.9
110
108
70-143
2
1,2-Dichloroethane-d4 (S)
%
95
93
70-130
4-Bromofluorobenzene (S)
%
97
98
70-130
Toluene-d8(S)
%
96
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
QC Batch: 765583 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659513001, 92659513002, 92659513003
METHOD BLANK: 3975244
Matrix:
Water
Associated Lab Samples:
92659513001, 92659513002, 92659513003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
04/03/23 17:55
1,2-Dichloroethane-d4 (S)
%
86
67-130
04/03/23 17:55
Toluene-d8 (S)
%
92
70-130
04/03/23 17:55
LABORATORY CONTROL SAMPLE: 3975245
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.3 92 70-130
1,2-Dichloroethane-d4 (S) % 92 67-130
Toluene-d8(S) % 94 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975246
3975247
MS
MSD
92659539007 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L 0.88J 20
20 19.4
18.1 92
86
55-137 7
1,2-Dichloroethane-d4 (S)
%
79
82
67-130
Toluene-d8(S)
%
87
88
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: 6002 HOLBROOKS RD LANDFILL
Pace Project No.: 92659513
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:09 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
6002 HOLBROOKS RD LANDFILL
92659513
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659513001
6002-HRSW2
EPA 3010A
766032
EPA 6010D
766125
92659513002
6002-HRSW3
EPA 3010A
766032
EPA 6010D
766125
92659513003
6002-HRSW4
EPA 3010A
766032
EPA 6010D
766125
92659513001
6002-HRSW2
EPA 3010A
766335
EPA 6020B
766457
92659513002
6002-HRSW3
EPA 3010A
766335
EPA 6020B
766457
92659513003
6002-HRSW4
EPA 3010A
766335
EPA 6020B
766457
92659513001
6002-HRSW2
EPA 8260D
764931
92659513002
6002-HRSW3
EPA 8260D
764931
92659513003
6002-HRSW4
EPA 8260D
764931
92659513001
6002-HRSW2
EPA 8260D Mod.
765583
92659513002
6002-HRSW3
EPA 8260D Mod.
765583
92659513003
6002-HRSW4
EPA 8260D Mod.
765583
Date: 04/10/2023 09:09 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 22

DC#:Title. ENVmFRM,.HUN14Q83,VO am
2,S... PJ6 Coqdlfloa lJpon t cei.pt
z?
ace
Effict 'Oote; 11 .2022 /141
Laboratory receivinas samples-.:
Asheville 0. Ed no Gr6e hW,06d.[] Huntersvilley RalelghEl Mechanicsville
Ej Atlas taFl; Kernetsvillon,
Sample Candition dient Name:
UpDn Rereipt /V\ M WO#:92659513'
client
Courier: E1QPS DO psII I Nl f ff Ilf f II II II i!f
-
Eltommercw
92659513
Custody Seal Present? nyeri O1N,*C*_1 Seals intaica, Yes NO
El
Data/ e<
packin
g Matertat EIR4bbleWrap, lda"U�bble B.05 ONOne: OthOr Biological Time Ftmzen? 7/'j
ThermomqpK - Dye$ E]Nq FFN/A,
. C . orrecti . on Factor:: Type,Ot, ke, EJ'W�i ORItle Elmone:
Cooler Temp. Add./Subtract (X) Tempshould be.aljo.ve0 freezing &ng to &T
11S8MODS'OutoftemP c4feha. Sarnplds on ke,'Coaliff9 pripcess
:Cdowrtemp. Cofreddq: ("rl, '3 has
OSDA Regulated S.011 ( ZN;Awater sample)
Did .5 1 a . mples , briginat . e in a q . darati. W1,e jane withimfhe United Statisl. CA, NY ar SC
Did samples:669inate fr6m a nNo Forei
(theck maps}? go Source Oht.er.natiormfly,
rig Hawaii and Puerto :Oyes: 00 No)?
Chain of Custody, Ptesent
Correct Cdntaln&s Ukid?
�iI......
Yos
I
.­_
J N JA
�.
3.
Yes
N/A
4,
[21yes
ONb
Q N/A
5.
eY 5
[].N.G.
ONIA
6.
E114o:
EIN/A
i]issoived analysis: Samples -Reid FIItQred7 Mato! cov. Cly'' ON &
Sample Labels
ONG. EIN/
LHeaftace its VOA Via
10,
Field bata Aeqelred?.
Person contacted,
Date/.Time:
Project Manager sc URF:Review-
Date*
FFOjeO Manager W Review,
Page 20 of 22
Oualtrax ID: 696.14
Page 1 of 2

DC#_Title: ENV-;FRM-HUN1.0083 v02
;.Sample Condition Won:'Receipt
Ce,
are;x� r�ti xtxt� �s
Effective Date 11114/2022'
*
W4#:92659513
mark ark top half of bcrx'if pHand/or de`chlorinatfoh
is'uerified'and
Project
withr"n"the weptan,+ee rangy for preservation satrtp)es.
PM: ASF
Due
Date: 04/13/23
Estceptions V0A, eolifrsrmi TQCj Oil andcease DR0 8015 {."ter) DCiC, Clhig
CLIENT: 92—NECK
CO
**B.64om.half of box is -to list number ofbottles
** Check all ttopresetved Nltrates fir chlod e
u
z
u
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N
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PH Adjustment Log for Preserved samples
sample, 1 Type of preservative pH. upon► receipt date greservattvn;adjusted Time preservation Amour t`of 1?teservative: Lot #
adjusted added
Note: Whenever there k a discrepancy affecting: Carolina �o:mpiianco samples; a copy o€ this form will he seat`to the North Carnllrsa t?EtJR Cer#ificatiorr Df€'tee{i,e,
n.EP r�..i.
...a......v.•,w....�+r.�.;s..a 11+— LI, 4pi, f4 ILU11 Ut L UJII wT1kvb.
Qualtrax ID, 69614.
Page 2 of 2
Page 21 of 22

CAN
°
V
TEMP in C
Received on
Ice
(Y/N)
use NTy
Sealed
Cooler
YIN
Samples
Intact
(Y/N)
ITEM #
N
N
N V/
C.
N
ro s
°• IV
N
3 0 T
Cr
3
xv
It lei !4
0RAF
• C4
g2���adm�n
b �
i m
MATRIX COdE (see valid codes to left)
SAMPLETYPE (G=GRAB C-COMP)
O
Y
m
�1
�
r
m
m
z
�
O
m
m
SAMPLE TEMP AT COLLECTfON
# CF CONTAINERS
unpreserved
H2SO4
HNO3
]
n
HCI
°
n
NaOH
n
Na2S203
a
ff
Methanol
Other
Metals by 200.7
VOC 8260
VOC 8260 SIM
Residual Chlorine (Y/N)
7 3 n
o a 9
m m
O
3 n
5.
u�
n 3 Z-
,e n
c a n
i IN
t`
cn
A 0
+paI4d
(A� � ♦ ]I
w
�a
c
A
c c c
M a Cr
3
0
o
izto
x s
'n
3
3
a
a
v
u
M
d m m N 7
v v a
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c o c
3 o n
ac m m
a o n N
o
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a S
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Page 22 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 10, 2023
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni for
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92659516001 6002-HRW7
EPA 601OD
DBB1
15
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659516002 6002-HRW18
EPA 601OD
DBB1
15
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659516003 6002-HRW19
EPA 601OD
DBB1
15
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659516004 6002-HRW20
EPA 601OD
DBB1
15
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659516005 6002-HRW21
EPA 601OD
DBB1
15
PASI-A
EPA 6020E
CRW
1
PASI-A
EPA 8260D
JJK
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659516006 TRIP BLANK
EPA 8260D
JJK
52
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 28

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW7 Lab ID: 92659516001 Collected: 03/29/23 11:35 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:10
7440-38-2
Barium
111
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:10
7440-41-7
Cadmium
4.8
ug/L
1.0
1
04/05/2310:56
04/07/2313:10
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-48-4
Copper
10.5
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:10
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:10
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:10
7440-62-2
Zinc
46.1
ug/L
10.0
1
04/05/2310:56
04/07/2313:10
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/05/23 10:45
04/05/23 22:54
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 02:47
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 02:47
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 02:47
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 02:47
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 02:47
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 02:47
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 02:47
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 02:47
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 02:47
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 02:47
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 02:47
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 02:47
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 02:47
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 02:47
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 02:47
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 02:47
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 02:47
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 02:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:47
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 02:47
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 02:47
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:47
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 02:47
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW7 Lab ID: 92659516001 Collected: 03/29/23 11:35 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
1.4
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
1.9
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
108
%
101
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
93 %
97 %
1.0
1
03/31/23 02:47
75-35-4
1.0
1
03/31/23 02:47
156-59-2
1.0
1
03/31/23 02:47
156-60-5
1.0
1
03/31/23 02:47
78-87-5
1.0
1
03/31/23 02:47
10061-01-5
1.0
1
03/31/23 02:47
10061-02-6
1.0
1
03/31/23 02:47
100-41-4
5.0
1
03/31/23 02:47
591-78-6
20.0
1
03/31/23 02:47
74-88-4
5.0
1
03/31/23 02:47
75-09-2
5.0
1
03/31/23 02:47
108-10-1
1.0
1
03/31/23 02:47
100-42-5
1.0
1
03/31/23 02:47
630-20-6
1.0
1
03/31/23 02:47
79-34-5
1.0
1
03/31/23 02:47
127-18-4
1.0
1
03/31/23 02:47
108-88-3
1.0
1
03/31/23 02:47
71-55-6
1.0
1
03/31/23 02:47
79-00-5
1.0
1
03/31/23 02:47
79-01-6
1.0
1
03/31/23 02:47
75-69-4
1.0
1
03/31/23 02:47
96-18-4
2.0
1
03/31/23 02:47
108-05-4
1.0
1
03/31/23 02:47
75-01-4
1.0
1
03/31/23 02:47
1330-20-7
2.0
1
03/31/23 02:47
179601-23-1
1.0
1
03/31/23 02:47
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 02:47 460-00-4
03/31/23 02:47 17060-07-0
03/31/23 02:47 2037-26-5
[it, lLeX7f gal W17 [e%3111111 f �XS*1 Qi l l
04/03/23 20:08 17060-07-0
04/03/23 20:08 2037-26-5
Page 5 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW18 Lab ID: 92659516002 Collected: 03/29/23 11:20 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:13
7440-38-2
Barium
280
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:13
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:13
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-47-3
Cobalt
6.0
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7439-92-1
Nickel
9.7
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:13
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:13
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:13
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:13
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/05/23 10:45
04/05/23 22:58
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 03:05
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 03:05
107-13-1
Benzene
1.9
ug/L
1.0
1
03/31/23 03:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 03:05
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 03:05
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 03:05
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 03:05
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 03:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 03:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 03:05
56-23-5
Chlorobenzene
5.0
ug/L
1.0
1
03/31/23 03:05
108-90-7
Chloroethane
4.0
ug/L
1.0
1
03/31/23 03:05
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 03:05
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 03:05
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 03:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 03:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 03:05
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 03:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 03:05
95-50-1
1,4-Dichlorobenzene
5.6
ug/L
1.0
1
03/31/23 03:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 03:05
110-57-6
1,1-Dichloroethane
23.4
ug/L
1.0
1
03/31/23 03:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 03:05
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW18 Lab ID: 92659516002 Collected: 03/29/23 11:20 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
1.3
ug/L
ND
ug/L
2.9
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
3.1
ug/L
ND
ug/L
ND
ug/L
6.4
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
110
%
103
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
19.8 ug/L
101 %
97 %
1.0
1
03/31/23 03:05
75-35-4
1.0
1
03/31/23 03:05
156-59-2
1.0
1
03/31/23 03:05
156-60-5
1.0
1
03/31/23 03:05
78-87-5
1.0
1
03/31/23 03:05
10061-01-5
1.0
1
03/31/23 03:05
10061-02-6
1.0
1
03/31/23 03:05
100-41-4
5.0
1
03/31/23 03:05
591-78-6
20.0
1
03/31/23 03:05
74-88-4
5.0
1
03/31/23 03:05
75-09-2
5.0
1
03/31/23 03:05
108-10-1
1.0
1
03/31/23 03:05
100-42-5
1.0
1
03/31/23 03:05
630-20-6
1.0
1
03/31/23 03:05
79-34-5
1.0
1
03/31/23 03:05
127-18-4
1.0
1
03/31/23 03:05
108-88-3
1.0
1
03/31/23 03:05
71-55-6
1.0
1
03/31/23 03:05
79-00-5
1.0
1
03/31/23 03:05
79-01-6
1.0
1
03/31/23 03:05
75-69-4
1.0
1
03/31/23 03:05
96-18-4
2.0
1
03/31/23 03:05
108-05-4
1.0
1
03/31/23 03:05
75-01-4
1.0
1
03/31/23 03:05
1330-20-7
2.0
1
03/31/23 03:05
179601-23-1
1.0
1
03/31/23 03:05
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 03:05 460-00-4
03/31/23 03:05 17060-07-0
03/31/23 03:05 2037-26-5
[eLlLeXlf��c3��e7Y�tif��c?�;SQi�l!
04/03/23 20:27 17060-07-0
04/03/23 20:27 2037-26-5
Page 7 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW19 Lab ID: 92659516003 Collected: 03/29/23 10:45 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:16
7440-38-2
Barium
94.1
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:16
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:16
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:16
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:16
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:16
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:16
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/05/23 10:45
04/05/23 23:02
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 03:23
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 03:23
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 03:23
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 03:23
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 03:23
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 03:23
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 03:23
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 03:23
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 03:23
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 03:23
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 03:23
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 03:23
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 03:23
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 03:23
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 03:23
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 03:23
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 03:23
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 03:23
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 03:23
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 03:23
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 03:23
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 03:23
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 03:23
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW19 Lab ID: 92659516003 Collected: 03/29/23 10:45 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
97
%
108
%
102
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
87 %
94 %
1.0
1
03/31/23 03:23
75-35-4
1.0
1
03/31/23 03:23
156-59-2
1.0
1
03/31/23 03:23
156-60-5
1.0
1
03/31/23 03:23
78-87-5
1.0
1
03/31/23 03:23
10061-01-5
1.0
1
03/31/23 03:23
10061-02-6
1.0
1
03/31/23 03:23
100-41-4
5.0
1
03/31/23 03:23
591-78-6
20.0
1
03/31/23 03:23
74-88-4
5.0
1
03/31/23 03:23
75-09-2
5.0
1
03/31/23 03:23
108-10-1
1.0
1
03/31/23 03:23
100-42-5
1.0
1
03/31/23 03:23
630-20-6
1.0
1
03/31/23 03:23
79-34-5
1.0
1
03/31/23 03:23
127-18-4
1.0
1
03/31/23 03:23
108-88-3
1.0
1
03/31/23 03:23
71-55-6
1.0
1
03/31/23 03:23
79-00-5
1.0
1
03/31/23 03:23
79-01-6
1.0
1
03/31/23 03:23
75-69-4
1.0
1
03/31/23 03:23
96-18-4
2.0
1
03/31/23 03:23
108-05-4
1.0
1
03/31/23 03:23
75-01-4
1.0
1
03/31/23 03:23
1330-20-7
2.0
1
03/31/23 03:23
179601-23-1
1.0
1
03/31/23 03:23
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 03:23 460-00-4
03/31/23 03:23 17060-07-0
03/31/23 03:23 2037-26-5
[eLlLeXlf��c3��e7C['1<if��c?�;SQi�l!
04/03/23 20:46 17060-07-0
04/03/23 20:46 2037-26-5
Page 9 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW20 Lab ID: 92659516004 Collected: 03/29/23 11:05 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:19
7440-38-2
Barium
138
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:19
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:19
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:19
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:19
7440-28-0
Vanadium
6.6
ug/L
5.0
1
04/05/2310:56
04/07/2313:19
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:19
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/05/23 10:45
04/05/23 23:06
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 03:42
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 03:42
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 03:42
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 03:42
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 03:42
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 03:42
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 03:42
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 03:42
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 03:42
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 03:42
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 03:42
108-90-7
Chloroethane
1.0
ug/L
1.0
1
03/31/23 03:42
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 03:42
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 03:42
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 03:42
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 03:42
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 03:42
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 03:42
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 03:42
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 03:42
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 03:42
110-57-6
1,1-Dichloroethane
10.0
ug/L
1.0
1
03/31/23 03:42
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 03:42
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW20 Lab ID: 92659516004 Collected: 03/29/23 11:05 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
1.3
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
97
%
109
%
102
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
93 %
97 %
1.0
1
03/31/23 03:42
75-35-4
1.0
1
03/31/23 03:42
156-59-2
1.0
1
03/31/23 03:42
156-60-5
1.0
1
03/31/23 03:42
78-87-5
1.0
1
03/31/23 03:42
10061-01-5
1.0
1
03/31/23 03:42
10061-02-6
1.0
1
03/31/23 03:42
100-41-4
5.0
1
03/31/23 03:42
591-78-6
20.0
1
03/31/23 03:42
74-88-4
5.0
1
03/31/23 03:42
75-09-2
5.0
1
03/31/23 03:42
108-10-1
1.0
1
03/31/23 03:42
100-42-5
1.0
1
03/31/23 03:42
630-20-6
1.0
1
03/31/23 03:42
79-34-5
1.0
1
03/31/23 03:42
127-18-4
1.0
1
03/31/23 03:42
108-88-3
1.0
1
03/31/23 03:42
71-55-6
1.0
1
03/31/23 03:42
79-00-5
1.0
1
03/31/23 03:42
79-01-6
1.0
1
03/31/23 03:42
75-69-4
1.0
1
03/31/23 03:42
96-18-4
2.0
1
03/31/23 03:42
108-05-4
1.0
1
03/31/23 03:42
75-01-4
1.0
1
03/31/23 03:42
1330-20-7
2.0
1
03/31/23 03:42
179601-23-1
1.0
1
03/31/23 03:42
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 03:42 460-00-4
03/31/23 03:42 17060-07-0
03/31/23 03:42 2037-26-5
[it, 0e197pal PA Kim Ei f �XS*1 Qi l l
04/03/23 21:05 17060-07-0
04/03/23 21:05 2037-26-5
Page 11 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW21 Lab ID: 92659516005 Collected: 03/29/23 10:18 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:22
7440-38-2
Barium
58.6
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:22
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:22
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:22
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:22
7440-28-0
Vanadium
6.7
ug/L
5.0
1
04/05/2310:56
04/07/2313:22
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:22
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/05/23 10:45
04/05/23 23:10
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 04:00
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 04:00
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 04:00
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 04:00
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 04:00
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 04:00
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 04:00
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 04:00
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 04:00
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 04:00
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 04:00
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 04:00
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 04:00
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 04:00
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 04:00
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 04:00
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 04:00
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 04:00
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 04:00
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 04:00
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 04:00
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 04:00
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 04:00
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: 6002-HRW21 Lab ID: 92659516005 Collected: 03/29/23 10:18 Received: 03/29/23 15:03 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
107
%
102
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
107 %
106 %
1.0
1
03/31/23 04:00
75-35-4
1.0
1
03/31/23 04:00
156-59-2
1.0
1
03/31/23 04:00
156-60-5
1.0
1
03/31/23 04:00
78-87-5
1.0
1
03/31/23 04:00
10061-01-5
1.0
1
03/31/23 04:00
10061-02-6
1.0
1
03/31/23 04:00
100-41-4
5.0
1
03/31/23 04:00
591-78-6
20.0
1
03/31/23 04:00
74-88-4
5.0
1
03/31/23 04:00
75-09-2
5.0
1
03/31/23 04:00
108-10-1
1.0
1
03/31/23 04:00
100-42-5
1.0
1
03/31/23 04:00
630-20-6
1.0
1
03/31/23 04:00
79-34-5
1.0
1
03/31/23 04:00
127-18-4
1.0
1
03/31/23 04:00
108-88-3
1.0
1
03/31/23 04:00
71-55-6
1.0
1
03/31/23 04:00
79-00-5
1.0
1
03/31/23 04:00
79-01-6
1.0
1
03/31/23 04:00
75-69-4
1.0
1
03/31/23 04:00
96-18-4
2.0
1
03/31/23 04:00
108-05-4
1.0
1
03/31/23 04:00
75-01-4
1.0
1
03/31/23 04:00
1330-20-7
2.0
1
03/31/23 04:00
179601-23-1
1.0
1
03/31/23 04:00
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/31/23 04:00 460-00-4
03/31/23 04:00 17060-07-0
03/31/23 04:00 2037-26-5
[iDLelt7palPAiWZ=iPXS*1Qi 11
04/03/23 21:24 17060-07-0
04/03/23 21:24 2037-26-5
Page 13 of 28

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ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: TRIP BLANK
Lab ID: 92659516006
Collected:
03/29/23
10:02
Received: 03/29/23 15:03 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
1
03/31/23 01:16
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/31/23 01:16
107-13-1
Benzene
ND
ug/L
1.0
1
03/31/23 01:16
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/31/23 01:16
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
03/31/23 01:16
75-27-4
Bromoform
ND
ug/L
1.0
1
03/31/23 01:16
75-25-2
Bromomethane
ND
ug/L
2.0
1
03/31/23 01:16
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
1
03/31/23 01:16
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/31/23 01:16
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/31/23 01:16
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/31/23 01:16
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/31/23 01:16
75-00-3
Chloroform
ND
ug/L
1.0
1
03/31/23 01:16
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/31/23 01:16
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
03/31/23 01:16
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/31/23 01:16
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/31/23 01:16
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/31/23 01:16
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 01:16
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/31/23 01:16
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/31/23 01:16
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/31/23 01:16
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/31/23 01:16
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/31/23 01:16
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/31/23 01:16
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/31/23 01:16
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
03/31/23 01:16
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/31/23 01:16
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/31/23 01:16
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/31/23 01:16
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/31/23 01:16
591-78-6
lodomethane
ND
ug/L
20.0
1
03/31/23 01:16
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/31/23 01:16
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/31/23 01:16
108-10-1
Styrene
ND
ug/L
1.0
1
03/31/23 01:16
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/31/23 01:16
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/31/23 01:16
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/31/23 01:16
127-18-4
Toluene
ND
ug/L
1.0
1
03/31/23 01:16
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/31/23 01:16
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/31/23 01:16
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/31/23 01:16
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/31/23 01:16
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/31/23 01:16
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/31/23 01:16
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/31/23 01:16
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
Sample: TRIP BLANK
Parameters
Lab ID: 92659516006 Collected: 03/29/23 10:02
Results Units Report Limit DF
Received: 03/29/23 15:03 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Xylene (Total)
ND ug/L
1.0
1
03/31/23 01:16
1330-20-7
m&p-Xylene
ND ug/L
2.0
1
03/31/23 01:16
179601-23-1
o-Xylene
ND ug/L
1.0
1
03/31/23 01:16
95-47-6
Surrogates
4-Bromofluorobenzene (S)
97 %
70-130
1
03/31/23 01:16
460-00-4
1,2-Dichloroethane-d4 (S)
108 %
70-130
1
03/31/23 01:16
17060-07-0
Toluene-d8 (S)
100 %
70-130
1
03/31/23 01:16
2037-26-5
Date: 04/10/2023 09:08 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
QC Batch: 766032 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005
METHOD BLANK: 3977273 Matrix: Water
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony
ug/L
ND
5.0
04/07/2312:32
Arsenic
ug/L
ND
10.0
04/07/2312:32
Barium
ug/L
ND
5.0
04/07/2312:32
Beryllium
ug/L
ND
1.0
04/07/2312:32
Cadmium
ug/L
ND
1.0
04/07/2312:32
Chromium
ug/L
ND
5.0
04/07/2312:32
Cobalt
ug/L
ND
5.0
04/07/2312:32
Copper
ug/L
ND
5.0
04/07/2312:32
Lead
ug/L
ND
5.0
04/07/2312:32
Nickel
ug/L
ND
5.0
04/07/2312:32
Selenium
ug/L
ND
10.0
04/07/2312:32
Silver
ug/L
ND
5.0
04/07/2312:32
Thallium
ug/L
ND
10.0
04/07/2312:32
Vanadium
ug/L
ND
5.0
04/07/2312:32
Zinc
ug/L
ND
10.0
04/07/2312:32
LABORATORY CONTROL SAMPLE:
Parameter
3977274
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
500
501
100
80-120
Arsenic
ug/L
500
499
100
80-120
Barium
ug/L
500
511
102
80-120
Beryllium
ug/L
500
504
101
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
506
101
80-120
Lead
ug/L
500
507
101
80-120
Nickel
ug/L
500
508
102
80-120
Selenium
ug/L
500
498
100
80-120
Silver
ug/L
250
249
99
80-120
Thallium
ug/L
500
505
101
80-120
Vanadium
ug/L
500
510
102
80-120
Zinc
ug/L
500
504
101
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
6002-HOLBROOKS RD LANDFILL
92659516
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
3977275
3977276
MS
MSD
92659004001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
522
106
104
75-125
1
Arsenic
ug/L
ND
500
500
528
523
105
104
75-125
1
Barium
ug/L
583
500
500
1120
1100
107
103
75-125
2
Beryllium
ug/L
ND
500
500
522
522
104
104
75-125
0
Cadmium
ug/L
ND
500
500
513
509
103
102
75-125
1
Chromium
ug/L
ND
500
500
520
515
104
103
75-125
1
Cobalt
ug/L
16.0
500
500
536
530
104
103
75-125
1
Copper
ug/L
ND
500
500
537
529
107
106
75-125
1
Lead
ug/L
ND
500
500
518
512
103
102
75-125
1
Nickel
ug/L
ND
500
500
518
512
103
102
75-125
1
Selenium
ug/L
ND
500
500
545
537
109
107
75-125
1
Silver
ug/L
ND
250
250
263
258
105
103
75-125
2
Thallium
ug/L
ND
500
500
517
510
103
102
75-125
1
Vanadium
ug/L
ND
500
500
536
530
107
106
75-125
1
Zinc
ug/L
ND
500
500
516
512
103
102
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
QC Batch: 766048 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005
METHOD BLANK: 3977338
Matrix:
Water
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Thallium
ug/L
ND
0.20
04/05/23 21:48
LABORATORY CONTROL SAMPLE:
3977339
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
25.8
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3977340 3977341
MS MSD
92658990001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Thallium ug/L 0.66J 25 25 26.7 26.9 104 105 75-125 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
QC Batch: 764931 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005, 92659516006
METHOD BLANK: 3971910 Matrix: Water
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005, 92659516006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,1-Trichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1,2-Trichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1-Dichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,1-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
1,2,3-Trichloropropane
ug/L
ND
1.0
03/31/23 00:40
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
03/31/23 00:40
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichlorobenzene
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloroethane
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloropropane
ug/L
ND
1.0
03/31/23 00:40
1,4-Dichlorobenzene
ug/L
ND
1.0
03/31/23 00:40
2-Butanone (MEK)
ug/L
ND
5.0
03/31/23 00:40
2-Hexanone
ug/L
ND
5.0
03/31/23 00:40
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/31/23 00:40
Acetone
ug/L
ND
25.0
03/31/23 00:40
Acrylonitrile
ug/L
ND
10.0
03/31/23 00:40
Benzene
ug/L
ND
1.0
03/31/23 00:40
Bromochloromethane
ug/L
ND
1.0
03/31/23 00:40
Bromodichloromethane
ug/L
ND
1.0
03/31/23 00:40
Bromoform
ug/L
ND
1.0
03/31/23 00:40
Bromomethane
ug/L
ND
2.0
03/31/23 00:40
Carbon disulfide
ug/L
ND
2.0
03/31/23 00:40
Carbon tetrachloride
ug/L
ND
1.0
03/31/23 00:40
Chlorobenzene
ug/L
ND
1.0
03/31/23 00:40
Chloroethane
ug/L
ND
1.0
03/31/23 00:40
Chloroform
ug/L
ND
1.0
03/31/23 00:40
Chloromethane
ug/L
ND
1.0
03/31/23 00:40
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/31/23 00:40
Dibromochloromethane
ug/L
ND
1.0
03/31/23 00:40
Dibromomethane
ug/L
ND
1.0
03/31/23 00:40
Ethylbenzene
ug/L
ND
1.0
03/31/23 00:40
lodomethane
ug/L
ND
20.0
03/31/23 00:40
m&p-Xylene
ug/L
ND
2.0
03/31/23 00:40
Methylene Chloride
ug/L
ND
5.0
03/31/23 00:40
o-Xylene
ug/L
ND
1.0
03/31/23 00:40
Styrene
ug/L
ND
1.0
03/31/23 00:40
Tetrachloroethene
ug/L
ND
1.0
03/31/23 00:40
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
METHOD BLANK: 3971910 Matrix: Water
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005, 92659516006
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Toluene
ug/L
ND
1.0
03/31/23 00:40
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/31/23 00:40
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/31/23 00:40
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/31/23 00:40
Trichloroethene
ug/L
ND
1.0
03/31/23 00:40
Trichlorofluoromethane
ug/L
ND
1.0
03/31/23 00:40
Vinyl acetate
ug/L
ND
2.0
03/31/23 00:40
Vinyl chloride
ug/L
ND
1.0
03/31/23 00:40
Xylene (Total)
ug/L
ND
1.0
03/31/23 00:40
1,2-Dichloroethane-d4 (S)
%
108
70-130
03/31/23 00:40
4-Bromofluorobenzene (S)
%
97
70-130
03/31/23 00:40
Toluene-d8 (S)
%
101
70-130
03/31/23 00:40
LABORATORY CONTROL SAMPLE:
Parameter
3971911
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
20
21.5
107
70-130
1,1,1-Trichloroethane
ug/L
20
21.5
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
20.6
103
70-130
1,1,2-Trichloroethane
ug/L
20
20.5
103
70-130
1,1-Dichloroethane
ug/L
20
21.6
108
70-130
1,1-Dichloroethene
ug/L
20
21.3
106
70-130
1,2,3-Trichloropropane
ug/L
20
20.3
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
19.4
97
70-131
1,2-Dibromoethane (EDB)
ug/L
20
20.9
105
70-130
1,2-Dichlorobenzene
ug/L
20
20.6
103
70-130
1,2-Dichloroethane
ug/L
20
20.9
104
70-130
1,2-Dichloropropane
ug/L
20
20.8
104
70-130
1,4-Dichlorobenzene
ug/L
20
20.3
102
70-130
2-Butanone (MEK)
ug/L
40
39.6
99
70-134
2-Hexanone
ug/L
40
42.8
107
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
41.0
102
70-130
Acetone
ug/L
40
37.9
95
70-133
Acrylonitrile
ug/L
100
107
107
70-130
Benzene
ug/L
20
20.6
103
70-130
Bromochloromethane
ug/L
20
21.2
106
70-130
Bromodichloromethane
ug/L
20
20.0
100
70-130
Bromoform
ug/L
20
19.4
97
70-130
Bromomethane
ug/L
20
14.8
74
45-151 v3
Carbon disulfide
ug/L
20
21.1
105
70-130
Carbon tetrachloride
ug/L
20
20.2
101
70-130
Chlorobenzene
ug/L
20
20.5
102
70-130
Chloroethane
ug/L
20
20.6
103
39-152
Chloroform
ug/L
20
21.6
108
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 28

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QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
LABORATORY CONTROL SAMPLE:
Parameter
3971911
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
20
21.2
106
58-130
cis-1,2-Dichloroethene
ug/L
20
21.1
105
70-130
cis-1,3-Dichloropropene
ug/L
20
20.7
103
70-130
Dibromochloromethane
ug/L
20
20.5
103
70-130
Dibromomethane
ug/L
20
19.8
99
70-130
Ethylbenzene
ug/L
20
20.0
100
70-130
lodomethane
ug/L
40
35.5
89
53-141
m&p-Xylene
ug/L
40
41.6
104
70-130
Methylene Chloride
ug/L
20
19.2
96
66-130
o-Xylene
ug/L
20
20.8
104
70-130
Styrene
ug/L
20
20.7
104
70-130
Tetrachloroethene
ug/L
20
20.1
100
70-130
Toluene
ug/L
20
20.0
100
70-130
trans-1,2-Dichloroethene
ug/L
20
20.5
102
70-130
trans- 1,3-Dichloropropene
ug/L
20
20.5
102
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
22.6
113
57-185
Trichloroethene
ug/L
20
20.2
101
70-130
Trichlorofluoromethane
ug/L
20
19.5
98
62-130
Vinyl acetate
ug/L
40
42.4
106
70-144
Vinyl chloride
ug/L
20
17.7
88
62-130
Xylene (Total)
ug/L
60
62.4
104
70-130
1,2-Dichloroethane-d4 (S)
%
105
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971912
MS
92659513001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3971913
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.7
22.5
113
112
70-141
1
1,1,1-Trichloroethane
ug/L
ND
20
20
21.7
21.7
109
109
70-150
0
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.5
19.8
103
99
69-142
4
1,1,2-Trichloroethane
ug/L
ND
20
20
22.0
20.8
110
104
70-138
6
1,1-Dichloroethane
ug/L
ND
20
20
19.3
19.8
97
99
70-150
2
1,1-Dichloroethene
ug/L
ND
20
20
21.9
21.2
109
106
70-156
3
1,2,3-Trichloropropane
ug/L
ND
20
20
20.8
19.6
104
98
70-140
6
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.6
22.2
108
111
68-146
3
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.6
20.3
108
101
70-138
6
1,2-Dichlorobenzene
ug/L
ND
20
20
22.1
21.7
110
109
70-141
2
1,2-Dichloroethane
ug/L
ND
20
20
20.8
19.6
104
98
69-143
6
1,2-Dichloropropane
ug/L
ND
20
20
20.5
19.9
103
99
68-156
3
1,4-Dichlorobenzene
ug/L
ND
20
20
21.8
20.9
109
105
70-142
4
2-Butanone (MEK)
ug/L
ND
40
40
39.3
36.4
98
91
60-157
8
2-Hexanone
ug/L
ND
40
40
42.0
39.3
105
98
68-146
7
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
40.0
37.3
100
93
70-141
7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 28

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QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3971912
MS
92659513001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3971913
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Acetone
ug/L
ND
40
40
37.7
35.0
91
84
58-157
7
Acrylonitrile
ug/L
ND
100
100
97.2
90.5
97
91
69-147
7
Benzene
ug/L
ND
20
20
22.1
21.4
111
107
70-142
3
Bromochloromethane
ug/L
ND
20
20
22.6
21.7
113
108
70-146
4
Bromodichloromethane
ug/L
ND
20
20
21.1
20.5
105
102
70-139
3
Bromoform
ug/L
ND
20
20
22.4
21.5
112
108
64-140
4
Bromomethane
ug/L
ND
20
20
17.4
17.0
87
84
28-192
3
Carbon disulfide
ug/L
ND
20
20
21.0
20.4
105
102
70-151
3
Carbon tetrachloride
ug/L
ND
20
20
23.5
23.0
117
115
70-148
2
Chlorobenzene
ug/L
ND
20
20
22.2
21.8
111
109
70-141
2
Chloroethane
ug/L
ND
20
20
20.7
19.4
104
97
58-191
7
Chloroform
ug/L
ND
20
20
22.7
21.3
113
107
70-148
6
Chloromethane
ug/L
ND
20
20
20.1
19.4
101
97
43-162
4
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.5
19.7
102
99
68-151
4
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.5
20.4
108
102
70-139
5
Dibromochloromethane
ug/L
ND
20
20
21.5
21.3
108
106
70-144
1
Dibromomethane
ug/L
ND
20
20
22.5
22.0
113
110
70-139
2
Ethylbenzene
ug/L
ND
20
20
21.3
21.1
106
106
70-143
1
lodomethane
ug/L
ND
40
40
46.6
43.6
116
109
35-171
7
m&p-Xylene
ug/L
ND
40
40
43.9
43.0
110
107
70-144
2
Methylene Chloride
ug/L
ND
20
20
18.3
17.3
91
86
62-149
6
o-Xylene
ug/L
ND
20
20
22.3
21.9
112
109
70-145
2
Styrene
ug/L
ND
20
20
22.7
22.7
114
114
70-143
0
Tetrachloroethene
ug/L
ND
20
20
24.1
23.0
120
115
70-145
5
Toluene
ug/L
ND
20
20
21.5
20.7
108
103
70-142
4
trans-1,2-Dichloroethene
ug/L
ND
20
20
20.6
19.6
103
98
70-151
5
trans- 1,3-Dichloropropene
ug/L
ND
20
20
21.9
20.9
109
105
70-139
4
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
23.1
21.7
115
109
51-159
6
Trichloroethene
ug/L
ND
20
20
23.4
22.9
117
114
62-146
2
Trichlorofluoromethane
ug/L
ND
20
20
22.4
21.8
112
109
63-153
3
Vinyl acetate
ug/L
ND
40
40
39.5
36.7
99
92
61-162
7
Vinyl chloride
ug/L
ND
20
20
17.5
16.8
88
84
61-163
4
Xylene (Total)
ug/L
ND
60
60
66.3
64.9
110
108
70-143
2
1,2-Dichloroethane-d4 (S)
%
95
93
70-130
4-Bromofluorobenzene (S)
%
97
98
70-130
Toluene-d8(S)
%
96
96
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 28

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
QC Batch: 765583 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659516001, 92659516002, 92659516003, 92659516004, 92659516005
METHOD BLANK: 3975244
Matrix:
Water
Associated Lab Samples:
92659516001, 92659516002, 92659516003, 92659516004, 92659516005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
04/03/23 17:55
1,2-Dichloroethane-d4 (S)
%
86
67-130
04/03/23 17:55
Toluene-d8 (S)
%
92
70-130
04/03/23 17:55
LABORATORY CONTROL SAMPLE: 3975245
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.3 92 70-130
1,2-Dichloroethane-d4 (S) % 92 67-130
Toluene-d8(S) % 94 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3975246
3975247
MS
MSD
92659539007 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L 0.88J 20
20 19.4
18.1 92
86
55-137 7
1,2-Dichloroethane-d4 (S)
%
79
82
67-130
Toluene-d8(S)
%
87
88
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 28

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QUALIFIERS
Project: 6002-HOLBROOKS RD LANDFILL
Pace Project No.: 92659516
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 28

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
6002-HOLBROOKS RD LANDFILL
92659516
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659516001
6002-HRW7
EPA 3010A
766032
EPA6010D
766125
92659516002
6002-HRW18
EPA 3010A
766032
EPA6010D
766125
92659516003
6002-HRW19
EPA 3010A
766032
EPA6010D
766125
92659516004
6002-HRW20
EPA 3010A
766032
EPA6010D
766125
92659516005
6002-HRW21
EPA 3010A
766032
EPA6010D
766125
92659516001
6002-HRW7
EPA 3010A
766048
EPA 6020B
766136
92659516002
6002-HRW18
EPA 3010A
766048
EPA 6020B
766136
92659516003
6002-HRW19
EPA 3010A
766048
EPA 6020B
766136
92659516004
6002-HRW20
EPA 3010A
766048
EPA 6020B
766136
92659516005
6002-HRW21
EPA 3010A
766048
EPA 6020B
766136
92659516001
6002-HRW7
EPA 8260D
764931
92659516002
6002-HRW18
EPA 8260D
764931
92659516003
6002-HRW19
EPA 8260D
764931
92659516004
6002-HRW20
EPA 8260D
764931
92659516005
6002-HRW21
EPA 8260D
764931
92659516006
TRIP BLANK
EPA 8260D
764931
92659516001
6002-HRW7
EPA 8260D Mod.
765583
92659516002
6002-HRW18
EPA 8260D Mod.
765583
92659516003
6002-HRW19
EPA 8260D Mod.
765583
92659516004
6002-HRW20
EPA 8260D Mod.
765583
92659516005
6002-HRW21
EPA 8260D Mod.
765583
Date: 04/10/2023 09:08 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 28

tide DC#_Title: ENV-FRM-HUN1-0083 02 Sample Condition Upon Receipt
Effective Date: 11/14/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Z Raleigh❑
ConditionMechanicsville❑ Atlanta❑ Kernersville❑
Client Name: WO# ; 92659516
" Project i�:
Courier: [-]Fed Ex ❑UPS ❑USPS Client II I II' III III II II II III
❑ Commercial ❑Pace ❑Other: 82858516
Custody Seal Present? ❑YesjNo Seals Intact? ❑Yes Eallo
Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other
Therrnome F
[I IR Gun ID: -7 V
Type of Ice: [ Wet ❑clue
Correction Factor:
Cooler Temp: Add/Subtract ('Q
Cooler Temp Corrected (° I. . 5
USDA Regulated Soil ([N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
(check mans)? FIYr I1Nn
Date/Initials Person Examining Contents:` r
Biological Tissue Frozen?
❑Yes [:]No �1/A
❑none
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, codling process
has begun
Did samples originate from a foreign source (in€ernalionally,
Comments/Discrepancy: u
Chain of Custody Present?
Yes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
es
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
Ff N
❑N/A
3.
Rush Turn Around Time Requested?
©Yes
No
❑N/A
4.
Sufficient Volume?
Z /Ye.
[]No
❑N/A
S.
Correct Containers Used?
's
❑No
❑N/A
6.
-Pace Containers Used?
H~ y s
❑No
[]N/A
Containers Intact?
Yes
❑No
❑N A
7,
Dissolved analysis: Samples Field Filtered?
❑Y
[]No
N/A
8.
Sample Labels Match COC7
Ofes
❑No
[_-]N/A
9,
V��
Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5.6mm)?
❑ s
No
❑N/A
10.
Trip Blank Present?
ZYes
❑No
❑N/A
11.
Trip Blank Custody Seals Present?
❑Yes
UNa
❑N/A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager 5RF Review:
Lot I of split containers;
Date/Time:
Date:
Date:
Field Data Required? (JYes IIINo
Qualtrax ID: 69614 Page 1 of 2 Page 26 of 28

DC# —Title: ENV-FRM-HUN1-0083 v02 -Sample Condition Upon Receipt
ace
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination is verified and Project # WO# : 92659516
within the acceptance range for preservation samples, PM, ASF Due Date: 04/13/23
Exceptions: VOA, Coliform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLHg CLIENT: 92—MECK CO
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
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Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be senl to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 27 of 28

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Page 28 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 10, 2023
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni for
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92659670001 6002-HRW8
EPA 6010D
D13131
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659670002 6002-HRW9R
EPA 6010D
DBB1
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659670003 6002-HRW16
EPA 6010D
DBB1
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW8 Lab ID: 92659670001 Collected: 03/30/23 11:23 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:24
7440-38-2
Barium
72.7
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:24
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:24
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-48-4
Copper
6.0
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:24
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:24
7440-28-0
Vanadium
10.5
ug/L
5.0
1
04/05/2310:56
04/07/2313:24
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:24
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:11
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 02:51
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 02:51
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 02:51
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 02:51
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 02:51
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 02:51
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 02:51
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 02:51
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 02:51
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 02:51
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
04/07/23 02:51
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 02:51
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 02:51
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 02:51
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 02:51
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 02:51
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 02:51
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 02:51
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 02:51
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 02:51
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 02:51
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 02:51
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 02:51
107-06-2
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW8 Lab ID: 92659670001 Collected: 03/30/23 11:23 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
98
%
99
%
97
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
81 %
87 %
1.0
1
04/07/23 02:51
75-35-4
1.0
1
04/07/23 02:51
156-59-2
1.0
1
04/07/23 02:51
156-60-5
1.0
1
04/07/23 02:51
78-87-5
1.0
1
04/07/23 02:51
10061-01-5
1.0
1
04/07/23 02:51
10061-02-6
1.0
1
04/07/23 02:51
100-41-4
5.0
1
04/07/23 02:51
591-78-6
20.0
1
04/07/23 02:51
74-88-4
5.0
1
04/07/23 02:51
75-09-2 v2
5.0
1
04/07/23 02:51
108-10-1
1.0
1
04/07/23 02:51
100-42-5
1.0
1
04/07/23 02:51
630-20-6
1.0
1
04/07/23 02:51
79-34-5
1.0
1
04/07/23 02:51
127-18-4
1.0
1
04/07/23 02:51
108-88-3
1.0
1
04/07/23 02:51
71-55-6
1.0
1
04/07/23 02:51
79-00-5
1.0
1
04/07/23 02:51
79-01-6
1.0
1
04/07/23 02:51
75-69-4
1.0
1
04/07/23 02:51
96-18-4
2.0
1
04/07/23 02:51
108-05-4
1.0
1
04/07/23 02:51
75-01-4
1.0
1
04/07/23 02:51
1330-20-7
2.0
1
04/07/23 02:51
179601-23-1
1.0
1
04/07/23 02:51
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
04/07/23 02:51 460-00-4
04/07/23 02:51 17060-07-0
04/07/23 02:51 2037-26-5
[it, PXS*lm a,I
04/05/23 20:21 17060-07-0
04/05/23 20:21 2037-26-5
Page 5 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW9R Lab ID: 92659670002 Collected: 03/30/23 11:12 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:39
7440-38-2
Barium
349
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:39
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:39
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-47-3
Cobalt
17.6
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-48-4
Copper
6.0
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7439-92-1
Nickel
5.5
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:39
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:39
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:39
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:39
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:15
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 03:09
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 03:09
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 03:09
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 03:09
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 03:09
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 03:09
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 03:09
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 03:09
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 03:09
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 03:09
56-23-5
Chlorobenzene
2.2
ug/L
1.0
1
04/07/23 03:09
108-90-7
Chloroethane
1.4
ug/L
1.0
1
04/07/23 03:09
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 03:09
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 03:09
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 03:09
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 03:09
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 03:09
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 03:09
74-95-3
1,2-Dichlorobenzene
4.1
ug/L
1.0
1
04/07/23 03:09
95-50-1
1,4-Dichlorobenzene
5.5
ug/L
1.0
1
04/07/23 03:09
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 03:09
110-57-6
1,1-Dichloroethane
25.8
ug/L
1.0
1
04/07/23 03:09
75-34-3
1,2-Dichloroethane
1.9
ug/L
1.0
1
04/07/23 03:09
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW9R Lab ID: 92659670002 Collected: 03/30/23 11:12 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
64.6
ug/L
ND
ug/L
2.5
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
6.0
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
99
%
100
%
98
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
13.1 ug/L
80 %
86 %
1.0
1
04/07/23 03:09
75-35-4
1.0
1
04/07/23 03:09
156-59-2
1.0
1
04/07/23 03:09
156-60-5
1.0
1
04/07/23 03:09
78-87-5
1.0
1
04/07/23 03:09
10061-01-5
1.0
1
04/07/23 03:09
10061-02-6
1.0
1
04/07/23 03:09
100-41-4
5.0
1
04/07/23 03:09
591-78-6
20.0
1
04/07/23 03:09
74-88-4
5.0
1
04/07/23 03:09
75-09-2
5.0
1
04/07/23 03:09
108-10-1
1.0
1
04/07/23 03:09
100-42-5
1.0
1
04/07/23 03:09
630-20-6
1.0
1
04/07/23 03:09
79-34-5
1.0
1
04/07/23 03:09
127-18-4
1.0
1
04/07/23 03:09
108-88-3
1.0
1
04/07/23 03:09
71-55-6
1.0
1
04/07/23 03:09
79-00-5
1.0
1
04/07/23 03:09
79-01-6
1.0
1
04/07/23 03:09
75-69-4
1.0
1
04/07/23 03:09
96-18-4
2.0
1
04/07/23 03:09
108-05-4
1.0
1
04/07/23 03:09
75-01-4
1.0
1
04/07/23 03:09
1330-20-7
2.0
1
04/07/23 03:09
179601-23-1
1.0
1
04/07/23 03:09
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
04/07/23 03:09 460-00-4
04/07/23 03:09 17060-07-0
04/07/23 03:09 2037-26-5
[etILeI.'7palW11E,11MPXS*1N a,I
04/05/23 20:40 17060-07-0
04/05/23 20:40 2037-26-5
Page 7 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW16 Lab ID: 92659670003 Collected: 03/30/23 10:50 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:42
7440-38-2
Barium
76.8
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:42
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:42
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7439-92-1
Nickel
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:42
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:42
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:42
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:42
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:19
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 03:27
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 03:27
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 03:27
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 03:27
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 03:27
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 03:27
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 03:27
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 03:27
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 03:27
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 03:27
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
04/07/23 03:27
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 03:27
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 03:27
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 03:27
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 03:27
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 03:27
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 03:27
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 03:27
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 03:27
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 03:27
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 03:27
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 03:27
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 03:27
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
Sample: 6002-HRW16 Lab ID: 92659670003 Collected: 03/30/23 10:50 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 04/10/2023 09:08 PM
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
98
%
100
%
97
%
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
ND ug/L
83 %
88 %
1.0
1
04/07/23 03:27
75-35-4
1.0
1
04/07/23 03:27
156-59-2
1.0
1
04/07/23 03:27
156-60-5
1.0
1
04/07/23 03:27
78-87-5
1.0
1
04/07/23 03:27
10061-01-5
1.0
1
04/07/23 03:27
10061-02-6
1.0
1
04/07/23 03:27
100-41-4
5.0
1
04/07/23 03:27
591-78-6
20.0
1
04/07/23 03:27
74-88-4
5.0
1
04/07/23 03:27
75-09-2
5.0
1
04/07/23 03:27
108-10-1
1.0
1
04/07/23 03:27
100-42-5
1.0
1
04/07/23 03:27
630-20-6
1.0
1
04/07/23 03:27
79-34-5
1.0
1
04/07/23 03:27
127-18-4
1.0
1
04/07/23 03:27
108-88-3
1.0
1
04/07/23 03:27
71-55-6
1.0
1
04/07/23 03:27
79-00-5
1.0
1
04/07/23 03:27
79-01-6
1.0
1
04/07/23 03:27
75-69-4
1.0
1
04/07/23 03:27
96-18-4
2.0
1
04/07/23 03:27
108-05-4
1.0
1
04/07/23 03:27
75-01-4
1.0
1
04/07/23 03:27
1330-20-7
2.0
1
04/07/23 03:27
179601-23-1
1.0
1
04/07/23 03:27
95-47-6
70-130 1
70-130 1
70-130 1
67-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
04/07/23 03:27 460-00-4
04/07/23 03:27 17060-07-0
04/07/23 03:27 2037-26-5
[etILeI.'7pa3PZe71.' ZiPXS*1N a,I
04/05/23 20:59 17060-07-0
04/05/23 20:59 2037-26-5
Page 9 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
QC Batch: 766032 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659670001, 92659670002, 92659670003
METHOD BLANK: 3977273 Matrix: Water
Associated Lab Samples: 92659670001, 92659670002, 92659670003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
1.0
04/07/2312:32
1.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3977274
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
501
100
80-120
Arsenic
ug/L
500
499
100
80-120
Barium
ug/L
500
511
102
80-120
Beryllium
ug/L
500
504
101
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
506
101
80-120
Lead
ug/L
500
507
101
80-120
Nickel
ug/L
500
508
102
80-120
Selenium
ug/L
500
498
100
80-120
Silver
ug/L
250
249
99
80-120
Thallium
ug/L
500
505
101
80-120
Vanadium
ug/L
500
510
102
80-120
Zinc
ug/L
500
504
101
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
6002- Holbrooks Rd Landfill
92659670
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
3977275
3977276
MS
MSD
92659004001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
522
106
104
75-125
1
Arsenic
ug/L
ND
500
500
528
523
105
104
75-125
1
Barium
ug/L
583
500
500
1120
1100
107
103
75-125
2
Beryllium
ug/L
ND
500
500
522
522
104
104
75-125
0
Cadmium
ug/L
ND
500
500
513
509
103
102
75-125
1
Chromium
ug/L
ND
500
500
520
515
104
103
75-125
1
Cobalt
ug/L
16.0
500
500
536
530
104
103
75-125
1
Copper
ug/L
ND
500
500
537
529
107
106
75-125
1
Lead
ug/L
ND
500
500
518
512
103
102
75-125
1
Nickel
ug/L
ND
500
500
518
512
103
102
75-125
1
Selenium
ug/L
ND
500
500
545
537
109
107
75-125
1
Silver
ug/L
ND
250
250
263
258
105
103
75-125
2
Thallium
ug/L
ND
500
500
517
510
103
102
75-125
1
Vanadium
ug/L
ND
500
500
536
530
107
106
75-125
1
Zinc
ug/L
ND
500
500
516
512
103
102
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
QC Batch: 766335 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659670001, 92659670002, 92659670003
METHOD BLANK: 3979049
Matrix:
Water
Associated Lab Samples: 92659670001, 92659670002, 92659670003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Thallium
ug/L
ND
0.20
04/07/23 02:28
LABORATORY CONTROL SAMPLE:
3979050
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
26.5
106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979051 3979052
MS MSD
92659513001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Thallium ug/L ND 25 25 27.2 26.5 109 106 75-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
QC Batch: 765937 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659670001, 92659670002, 92659670003
METHOD BLANK: 3976888 Matrix:
Associated Lab Samples: 92659670001, 92659670002, 92659670003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,1-Trichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,2-Trichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1-Dichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
1,2,3-Trichloropropane
ug/L
ND
1.0
04/07/23 00:43
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
04/07/23 00:43
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichlorobenzene
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloropropane
ug/L
ND
1.0
04/07/23 00:43
1,4-Dichlorobenzene
ug/L
ND
1.0
04/07/23 00:43
2-Butanone (MEK)
ug/L
ND
5.0
04/07/23 00:43
2-Hexanone
ug/L
ND
5.0
04/07/23 00:43
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
04/07/23 00:43
Acetone
ug/L
ND
25.0
04/07/23 00:43
Acrylonitrile
ug/L
ND
10.0
04/07/23 00:43
Benzene
ug/L
ND
1.0
04/07/23 00:43
Bromochloromethane
ug/L
ND
1.0
04/07/23 00:43
Bromodichloromethane
ug/L
ND
1.0
04/07/23 00:43
Bromoform
ug/L
ND
1.0
04/07/23 00:43
Bromomethane
ug/L
ND
2.0
04/07/23 00:43
Carbon disulfide
ug/L
ND
2.0
04/07/23 00:43
Carbon tetrachloride
ug/L
ND
1.0
04/07/23 00:43
Chlorobenzene
ug/L
ND
1.0
04/07/23 00:43
Chloroethane
ug/L
ND
1.0
04/07/23 00:43
Chloroform
ug/L
ND
1.0
04/07/23 00:43
Chloromethane
ug/L
ND
1.0
04/07/23 00:43
cis-1,2-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
cis-1,3-Dichloropropene
ug/L
ND
1.0
04/07/23 00:43
Dibromochloromethane
ug/L
ND
1.0
04/07/23 00:43
Dibromomethane
ug/L
ND
1.0
04/07/23 00:43
Ethylbenzene
ug/L
ND
1.0
04/07/23 00:43
lodomethane
ug/L
ND
20.0
04/07/23 00:43
m&p-Xylene
ug/L
ND
2.0
04/07/23 00:43
Methylene Chloride
ug/L
ND
5.0
04/07/23 00:43
o-Xylene
ug/L
ND
1.0
04/07/23 00:43
Styrene
ug/L
ND
1.0
04/07/23 00:43
Tetrachloroethene
ug/L
ND
1.0
04/07/23 00:43
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
METHOD BLANK: 3976888 Matrix:
Associated Lab Samples: 92659670001, 92659670002, 92659670003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Toluene
ug/L
ND
1.0
04/07/23 00:43
trans-1,2-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
trans- 1,3-Dichloropropene
ug/L
ND
1.0
04/07/23 00:43
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
04/07/23 00:43
Trichloroethene
ug/L
ND
1.0
04/07/23 00:43
Trichlorofluoromethane
ug/L
ND
1.0
04/07/23 00:43
Vinyl acetate
ug/L
ND
2.0
04/07/23 00:43
Vinyl chloride
ug/L
ND
1.0
04/07/23 00:43
Xylene (Total)
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloroethane-d4 (S)
%
98
70-130
04/07/23 00:43
4-Bromofluorobenzene (S)
%
100
70-130
04/07/23 00:43
Toluene-d8 (S)
%
97
70-130
04/07/23 00:43
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3976889
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
21.2
106
70-130
1,1,1-Trichloroethane
ug/L
20
19.0
95
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.2
106
70-130
1,1,2-Trichloroethane
ug/L
20
20.5
102
70-130
1,1-Dichloroethane
ug/L
20
18.4
92
70-130
1,1-Dichloroethene
ug/L
20
18.2
91
70-130
1,2,3-Trichloropropane
ug/L
20
20.5
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.8
104
70-131
1,2-Dibromoethane (EDB)
ug/L
20
20.7
104
70-130
1,2-Dichlorobenzene
ug/L
20
21.3
107
70-130
1,2-Dichloroethane
ug/L
20
19.5
97
70-130
1,2-Dichloropropane
ug/L
20
19.9
100
70-130
1,4-Dichlorobenzene
ug/L
20
21.4
107
70-130
2-Butanone (MEK)
ug/L
40
37.1
93
70-134
2-Hexanone
ug/L
40
40.2
100
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
39.2
98
70-130
Acetone
ug/L
40
31.1
78
70-133
Acrylonitrile
ug/L
100
90.6
91
70-130
Benzene
ug/L
20
19.5
98
70-130
Bromochloromethane
ug/L
20
19.1
96
70-130
Bromodichloromethane
ug/L
20
19.7
98
70-130
Bromoform
ug/L
20
20.5
103
70-130
Bromomethane
ug/L
20
15.2
76
45-151
Carbon disulfide
ug/L
20
16.8
84
70-130
Carbon tetrachloride
ug/L
20
19.7
99
70-130
Chlorobenzene
ug/L
20
20.9
105
70-130
Chloroethane
ug/L
20
17.9
90
39-152
Chloroform
ug/L
20
19.2
96
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
LABORATORY CONTROL SAMPLE:
Parameter
3976889
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Chloromethane
ug/L
20
17.0
85
58-130
cis-1,2-Dichloroethene
ug/L
20
18.6
93
70-130
cis-1,3-Dichloropropene
ug/L
20
19.8
99
70-130
Dibromochloromethane
ug/L
20
20.6
103
70-130
Dibromomethane
ug/L
20
20.6
103
70-130
Ethylbenzene
ug/L
20
20.4
102
70-130
lodomethane
ug/L
40
36.3
91
53-141
m&p-Xylene
ug/L
40
41.0
103
70-130
Methylene Chloride
ug/L
20
15.6
78
66-130
o-Xylene
ug/L
20
20.3
101
70-130
Styrene
ug/L
20
21.0
105
70-130
Tetrachloroethene
ug/L
20
20.1
100
70-130
Toluene
ug/L
20
19.6
98
70-130
trans-1,2-Dichloroethene
ug/L
20
18.4
92
70-130
trans- 1,3-Dichloropropene
ug/L
20
19.8
99
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
22.5
113
57-185
Trichloroethene
ug/L
20
20.2
101
70-130
Trichlorofluoromethane
ug/L
20
18.2
91
62-130
Vinyl acetate
ug/L
40
38.7
97
70-144
Vinyl chloride
ug/L
20
14.9
74
62-130
Xylene (Total)
ug/L
60
61.3
102
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE SAMPLE:
Parameter
3976891
Units
92659923009
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
25.7
129
70-141
1,1,1-Trichloroethane
ug/L
ND
20
20.6
103
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
24.5
122
69-142
1,1,2-Trichloroethane
ug/L
ND
20
22.3
111
70-138
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-150
1,1-Dichloroethene
ug/L
ND
20
21.5
107
70-156
1,2,3-Trichloropropane
ug/L
ND
20
23.9
120
70-140
1,2-Dibromo-3-chloropropane
ug/L
ND
20
25.2
126
68-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
25.2
126
70-138
1,2-Dichlorobenzene
ug/L
ND
20
26.2
131
70-141
1,2-Dichloroethane
ug/L
ND
20
21.3
106
69-143
1,2-Dichloropropane
ug/L
ND
20
22.2
111
68-156
1,4-Dichlorobenzene
ug/L
ND
20
25.7
128
70-142
2-Butanone (MEK)
ug/L
ND
40
42.4
106
60-157
2-Hexanone
ug/L
ND
40
48.5
121
68-146
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
43.7
109
70-141
Acetone
ug/L
ND
40
37.5
94
58-157
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
MATRIX SPIKE SAMPLE:
Parameter
3976891
Units
92659923009
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Acrylonitrile
ug/L
ND
100
104
104
69-147
Benzene
ug/L
ND
20
22.3
112
70-142
Bromochloromethane
ug/L
ND
20
21.7
108
70-146
Bromodichloromethane
ug/L
ND
20
22.0
110
70-139
Bromoform
ug/L
ND
20
26.4
132
64-140
Bromomethane
ug/L
ND
20
19.0
95
28-192
Carbon disulfide
ug/L
ND
20
20.4
102
70-151
Carbon tetrachloride
ug/L
ND
20
22.5
112
70-148
Chlorobenzene
ug/L
ND
20
24.9
124
70-141
Chloroethane
ug/L
ND
20
24.2
121
58-191
Chloroform
ug/L
ND
20
20.5
103
70-148
Chloromethane
ug/L
ND
20
22.8
114
43-162
cis-1,2-Dichloroethene
ug/L
ND
20
20.5
102
68-151
cis-1,3-Dichloropropene
ug/L
ND
20
22.7
113
70-139
Dibromochloromethane
ug/L
ND
20
25.7
128
70-144
Dibromomethane
ug/L
ND
20
22.9
114
70-139
Ethylbenzene
ug/L
ND
20
23.9
119
70-143
lodomethane
ug/L
ND
40
45.1
113
35-171
m&p-Xylene
ug/L
ND
40
47.8
120
70-144
Methylene Chloride
ug/L
ND
20
8.9
45
62-149 IK,M1,v3
o-Xylene
ug/L
ND
20
24.5
122
70-145
Styrene
ug/L
ND
20
24.6
123
70-143
Tetrachloroethene
ug/L
ND
20
23.5
117
70-145
Toluene
ug/L
ND
20
21.5
107
70-142
trans-1,2-Dichloroethene
ug/L
ND
20
20.7
103
70-151
trans- 1,3-Dichloropropene
ug/L
ND
20
22.6
113
70-139
trans-1,4-Dichloro-2-butene
ug/L
ND
20
25.1
125
51-159
Trichloroethene
ug/L
ND
20
22.3
112
62-146
Trichlorofluoromethane
ug/L
ND
20
23.0
115
63-153
Vinyl acetate
ug/L
ND
40
39.9
100
61-162
Vinyl chloride
ug/L
ND
20
18.4
92
61-163
Xylene (Total)
ug/L
ND
60
72.3
121
70-143
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 3976890
Parameter
Units
92659670001
Result
Dup
Result
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
ND
ND
1,1-Dichloroethene
ug/L
ND
ND
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
SAMPLE DUPLICATE: 3976890
Parameter
Units
92659670001
Result
Dup
Result
1,2,3-Trichloropropane
ug/L
ND
ND
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,2-Dichloropropane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
ND
ND
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
ND
ND
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
99
102
4-Bromofluorobenzene (S)
%
98
99
Toluene-d8 (S)
%
97
96
RPD Qualifiers
v2
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
QC Batch: 766177 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659670001, 92659670002, 92659670003
METHOD BLANK: 3978071
Matrix:
Water
Associated Lab Samples:
92659670001, 92659670002, 92659670003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
04/05/23 17:11
1,2-Dichloroethane-d4 (S)
%
83
67-130
04/05/23 17:11
Toluene-d8 (S)
%
87
70-130
04/05/23 17:11
LABORATORY CONTROL SAMPLE: 3978072
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.3 92 70-130
1,2-Dichloroethane-d4 (S) % 84 67-130
Toluene-d8 (S) % 88 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978073
3978074
MS
MSD
92659945007 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 17.8
18.0 88
89
55-137 1 H1
1,2-Dichloroethane-d4 (S)
%
79
83
67-130
Toluene-d8(S)
%
89
88
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659670
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
H1 Analysis conducted outside the EPA method holding time.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2023 09:08 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
6002- Holbrooks Rd Landfill
92659670
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659670001
6002-HRW8
EPA 3010A
766032
EPA 6010D
766125
92659670002
6002-HRW9R
EPA 3010A
766032
EPA 6010D
766125
92659670003
6002-HRW16
EPA 3010A
766032
EPA6010D
766125
92659670001
6002-HRW8
EPA 3010A
766335
EPA 6020B
766457
92659670002
6002-HRW9R
EPA 3010A
766335
EPA 6020B
766457
92659670003
6002-HRW16
EPA 3010A
766335
EPA 6020B
766457
92659670001
6002-HRW8
EPA 8260D
765937
92659670002
6002-HRW9R
EPA 8260D
765937
92659670003
6002-HRW16
EPA 8260D
765937
92659670001
6002-HRW8
EPA 8260D Mod.
766177
92659670002
6002-HRW9R
EPA 8260D Mod.
766177
92659670003
6002-HRW16
EPA 8260D Mod.
766177
Date: 04/10/2023 09:08 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 23

-ace "om—i me: tNV-t-KM-t1Unf1-OOt33 v02 Sample Condition Upon Receipt
Effective Date: 11/14/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville[,--(Raleigh(--] MechanicsvilleFl AtlantaFl Karnprcvillal-1
Sample Condition
CI' nt Narpe• r } ■
ReceiptUpon eQ of �I roi t WO# : 9 6596
70
r��r��
Courier: Fed Ex ElUiPS ❑LISPS Client 1111111111111111111111
ElCommercial ❑Pace ❑ other:
92659570
Custody Seal Present? ❑Yes OKo Seals Intact? ❑Yes �lo
Date/initials Person Examining Contents
Packing Material: ❑Bubble Wrap Bubble Bags [—]None ❑ other Biological Tissu F zen?
Thermo m t : Dyes ❑No N/A
R Gun ID: '' �
Type of ice:
YN EJWCt ❑clue []None
Correction Factor:
Cooler
Temp: � Add/Subtract (*Q
Temp should be above freezing to 6"C
Cooler
Temp Corrected (� i
❑SMIJI soul of temp criteria. Samples on ice, cooling process
has begun
USDA
Regulated Soil ( N/A, water sample)
Did samples originate in a quarantine zone within the United States:
CA, NY, or
SC
Didsamples originate from a Foreign source {internationally,
(check maps)? Dyes ❑No
including Hawaii and Puerto RicoJ? ❑Yes []No
Comments/Discrepancy:
Chain of Custody Present? es
❑No
[I N/A
1.
Samples Arrived within Hold Time? es
❑Na
❑N/A
2.
Short Hold Time Analysis 1<72 hr.)? Dyes
o
❑N/A
3
Rush Turn Around Time Requested? E,lYes
&go
❑N/A
4.
Sufficient Volume? LlYes
[:]Nu
❑N/A
5.
Correct Containers Used? Yes
❑No
❑N/A
6.
-Pace Containers Used? W(Y
❑No
❑N/A
Containers Intact? Yes
❑Nv
❑N
7.
Dissolved analysis: Samples Field Filtered? Y
❑No
N/A
8,
Sample Labels Match COC? oEryes
❑No
❑N/A
9.
—
-Includes Date/Time/D/Analysis Matrix: `A
Headspace in VOA Vials (>5.Gmm)? ]Yes
/NNcccoyyy
❑N/A
10.
Trip Blank Present?
❑N
❑N/A
11,
Trip Blank Custody Seals Present? Yes
Na
❑N/A
COMMENTS/SAMPLE
DISCREPANCY
''i , C `�i
J i I
Fleld Data Required? Dyes ❑No
►
i�
CLIENT NOTIFICATION/RESOLUTION
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Qualtrax ID:69614
Page 1 of 2 Page 21 of 23

v%.*" t ttM: r-tiv-rrctvt nurvi-uuuj vuz Sample Condition Upon Receipt
ace
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination is verified and proje, l,I �+ 265�� 1 O
within the acceptance range for preservation samples, 0 04�13/23
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, t.LNg pM , ASF Due bate
**Bottom half of box is to list number of bottles CLIENT: 92-MECK CO
***Check all unpreserved Nitrates for chlorine
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pH Adjustment Log for Preserved Samples
Sample ip Type of PreservativeFpH upon receipt Date preservatloII adjusted Time preservation Amount of Preservative Lat d
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will besenttco the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 22 of 23

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Page 23 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 13, 2023
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ariel S Fitzgerald
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 30

lacmnalyfica('
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92659681001 6002-HRW10
EPA 6010D
D13131
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659681002 6002-HRW11R
EPA 6010D
DBB1
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659681003 6002-HRW13
EPA 6010D
DBB1
15
PASI-A
EPA 6020E
KRL
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
TEG
3
PASI-C
92659681004 TRIP BLANK
EPA 8260D
SAS
52
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW10 Lab ID: 92659681001 Collected: 03/30/23 10:25 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:45
7440-38-2
Barium
94.0
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:45
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:45
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7439-92-1
Nickel
7.7
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:45
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:45
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:45
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:45
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:22
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 03:45
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 03:45
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 03:45
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 03:45
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 03:45
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 03:45
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 03:45
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 03:45
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 03:45
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 03:45
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
04/07/23 03:45
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 03:45
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 03:45
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 03:45
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 03:45
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 03:45
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 03:45
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 03:45
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 03:45
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 03:45
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 03:45
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 03:45
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 03:45
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW10 Lab ID: 92659681001 Collected: 03/30/23 10:25 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1-Dichloroethene
ND
ug/L
1.0
1
04/07/23 03:45
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 03:45
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 03:45
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
04/07/23 03:45
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 03:45
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 03:45
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
04/07/23 03:45
100-41-4
2-Hexanone
ND
ug/L
5.0
1
04/07/23 03:45
591-78-6
lodomethane
ND
ug/L
20.0
1
04/07/23 03:45
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
04/07/23 03:45
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
04/07/23 03:45
108-10-1
Styrene
ND
ug/L
1.0
1
04/07/23 03:45
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 03:45
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 03:45
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
04/07/23 03:45
127-18-4
Toluene
ND
ug/L
1.0
1
04/07/23 03:45
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
04/07/23 03:45
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
04/07/23 03:45
79-00-5
Trichloroethene
ND
ug/L
1.0
1
04/07/23 03:45
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
04/07/23 03:45
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
04/07/23 03:45
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
04/07/23 03:45
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
04/07/23 03:45
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
04/07/23 03:45
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
04/07/23 03:45
179601-23-1
o-Xylene
ND
ug/L
1.0
1
04/07/23 03:45
95-47-6
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
04/07/23 03:45
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
04/07/23 03:45
17060-07-0
Toluene-d8(S)
98
%
70-130
1
04/07/23 03:45
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
4.6
ug/L
2.0
1
04/06/23 22:52
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
99
%
67-130
1
04/06/23 22:52
17060-07-0
Toluene-d8(S)
101
%
70-130
1
04/06/23 22:52
2037-26-5
Date: 04/13/2023 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW11R Lab ID: 92659681002 Collected: 03/30/23 09:40 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:48
7440-38-2
Barium
134
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:48
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:48
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-47-3
Cobalt
5.3
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-48-4
Copper
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7439-92-1
Nickel
15.5
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:48
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:48
7440-28-0
Vanadium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:48
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:48
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:26
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 04:04
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 04:04
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 04:04
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 04:04
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 04:04
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 04:04
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 04:04
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 04:04
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 04:04
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 04:04
56-23-5
Chlorobenzene
1.5
ug/L
1.0
1
04/07/23 04:04
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 04:04
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 04:04
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 04:04
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 04:04
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 04:04
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 04:04
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 04:04
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:04
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:04
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 04:04
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:04
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:04
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW11R Lab ID: 92659681002 Collected: 03/30/23 09:40 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:04
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:04
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:04
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:04
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:04
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:04
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
04/07/23 04:04
100-41-4
2-Hexanone
ND
ug/L
5.0
1
04/07/23 04:04
591-78-6
lodomethane
ND
ug/L
20.0
1
04/07/23 04:04
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
04/07/23 04:04
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
04/07/23 04:04
108-10-1
Styrene
ND
ug/L
1.0
1
04/07/23 04:04
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:04
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:04
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
04/07/23 04:04
127-18-4
Toluene
ND
ug/L
1.0
1
04/07/23 04:04
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:04
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:04
79-00-5
Trichloroethene
ND
ug/L
1.0
1
04/07/23 04:04
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
04/07/23 04:04
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
04/07/23 04:04
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
04/07/23 04:04
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
04/07/23 04:04
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
04/07/23 04:04
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
04/07/23 04:04
179601-23-1
o-Xylene
ND
ug/L
1.0
1
04/07/23 04:04
95-47-6
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
04/07/23 04:04
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
04/07/23 04:04
17060-07-0
Toluene-d8(S)
99
%
70-130
1
04/07/23 04:04
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
73.7
ug/L
2.0
1
04/12/23 16:21
123-91-1 H1,H5,
P4
Surrogates
1,2-Dichloroethane-d4 (S)
102
%
67-130
1
04/12/23 16:21
17060-07-0
Toluene-d8 (S)
129
%
70-130
1
04/12/23 16:21
2037-26-5
Date: 04/13/2023 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW13 Lab ID: 92659681003 Collected: 03/30/23 09:57 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Antimony
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-36-0
Arsenic
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:51
7440-38-2
Barium
41.6
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-39-3
Beryllium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:51
7440-41-7
Cadmium
ND
ug/L
1.0
1
04/05/2310:56
04/07/2313:51
7440-43-9
Chromium
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-47-3
Cobalt
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-48-4
Copper
104
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-50-8
Lead
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7439-92-1
Nickel
9.9
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-02-0
Selenium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:51
7782-49-2
Silver
ND
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-22-4
Thallium
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:51
7440-28-0
Vanadium
5.7
ug/L
5.0
1
04/05/2310:56
04/07/2313:51
7440-62-2
Zinc
ND
ug/L
10.0
1
04/05/2310:56
04/07/2313:51
7440-66-6
6020 MET ICPMS
Analytical Method:
EPA 6020E Preparation Method: EPA 3010A
Pace Analytical
Services -Asheville
Thallium
ND
ug/L
0.20
1
04/06/23 11:20
04/07/23 03:30
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 04:22
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 04:22
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 04:22
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 04:22
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 04:22
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 04:22
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 04:22
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 04:22
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 04:22
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 04:22
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
04/07/23 04:22
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 04:22
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 04:22
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 04:22
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 04:22
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 04:22
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 04:22
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 04:22
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:22
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:22
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 04:22
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:22
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:22
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: 6002-HRW13 Lab ID: 92659681003 Collected: 03/30/23 09:57 Received: 03/30/23 12:07 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,1-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:22
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:22
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:22
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:22
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:22
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:22
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
04/07/23 04:22
100-41-4
2-Hexanone
ND
ug/L
5.0
1
04/07/23 04:22
591-78-6
lodomethane
ND
ug/L
20.0
1
04/07/23 04:22
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
04/07/23 04:22
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
04/07/23 04:22
108-10-1
Styrene
ND
ug/L
1.0
1
04/07/23 04:22
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:22
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:22
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
04/07/23 04:22
127-18-4
Toluene
ND
ug/L
1.0
1
04/07/23 04:22
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:22
79-00-5
Trichloroethene
ND
ug/L
1.0
1
04/07/23 04:22
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
04/07/23 04:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
04/07/23 04:22
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
04/07/23 04:22
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
04/07/23 04:22
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
04/07/23 04:22
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
04/07/23 04:22
179601-23-1
o-Xylene
ND
ug/L
1.0
1
04/07/23 04:22
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
04/07/23 04:22
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
04/07/23 04:22
17060-07-0
Toluene-d8(S)
97
%
70-130
1
04/07/23 04:22
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
04/06/23 23:11
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
101
%
67-130
1
04/06/23 23:11
17060-07-0
Toluene-d8(S)
94
%
70-130
1
04/06/23 23:11
2037-26-5
Date: 04/13/2023 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: TRIP BLANK
Lab ID: 92659681004 Collected:
03/30/23
11:45
Received: 03/30/23 12:07 Matrix: Water
Parameters
Results
Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Pace Analytical
Services - Charlotte
Acetone
ND
ug/L
25.0
1
04/07/23 04:23
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
04/07/23 04:23
107-13-1
Benzene
ND
ug/L
1.0
1
04/07/23 04:23
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
04/07/23 04:23
74-97-5
Bromodichloromethane
ND
ug/L
1.0
1
04/07/23 04:23
75-27-4
Bromoform
ND
ug/L
1.0
1
04/07/23 04:23
75-25-2
Bromomethane
ND
ug/L
2.0
1
04/07/23 04:23
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
1
04/07/23 04:23
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
04/07/23 04:23
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
04/07/23 04:23
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
04/07/23 04:23
108-90-7
Chloroethane
ND
ug/L
1.0
1
04/07/23 04:23
75-00-3
Chloroform
ND
ug/L
1.0
1
04/07/23 04:23
67-66-3
Chloromethane
ND
ug/L
1.0
1
04/07/23 04:23
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
1
04/07/23 04:23
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
04/07/23 04:23
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
04/07/23 04:23
106-93-4
Dibromomethane
ND
ug/L
1.0
1
04/07/23 04:23
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:23
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
04/07/23 04:23
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
04/07/23 04:23
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:23
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
04/07/23 04:23
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:23
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:23
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
04/07/23 04:23
156-60-5
1,2-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:23
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:23
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
04/07/23 04:23
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
04/07/23 04:23
100-41-4
2-Hexanone
ND
ug/L
5.0
1
04/07/23 04:23
591-78-6
lodomethane
ND
ug/L
20.0
1
04/07/23 04:23
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
04/07/23 04:23
75-09-2 L1,v1
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
04/07/23 04:23
108-10-1
Styrene
ND
ug/L
1.0
1
04/07/23 04:23
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:23
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
04/07/23 04:23
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
04/07/23 04:23
127-18-4
Toluene
ND
ug/L
1.0
1
04/07/23 04:23
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:23
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
04/07/23 04:23
79-00-5
Trichloroethene
ND
ug/L
1.0
1
04/07/23 04:23
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
04/07/23 04:23
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
04/07/23 04:23
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
04/07/23 04:23
108-05-4 IK
Vinyl chloride
ND
ug/L
1.0
1
04/07/23 04:23
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
Sample: TRIP BLANK
Parameters
Lab ID: 92659681004 Collected: 03/30/23 11:45
Results Units Report Limit DF
Received: 03/30/23 12:07 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Xylene (Total)
ND ug/L
1.0
1
04/07/23 04:23
1330-20-7
m&p-Xylene
ND ug/L
2.0
1
04/07/23 04:23
179601-23-1
o-Xylene
ND ug/L
1.0
1
04/07/23 04:23
95-47-6
Surrogates
4-Bromofluorobenzene (S)
90 %
70-130
1
04/07/23 04:23
460-00-4
1,2-Dichloroethane-d4 (S)
94 %
70-130
1
04/07/23 04:23
17060-07-0
Toluene-d8(S)
105 %
70-130
1
04/07/23 04:23
2037-26-5
Date: 04/13/2023 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 766032 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659681001, 92659681002, 92659681003
METHOD BLANK: 3977273 Matrix: Water
Associated Lab Samples: 92659681001, 92659681002, 92659681003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
1.0
04/07/2312:32
1.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
5.0
04/07/2312:32
10.0
04/07/2312:32
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3977274
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
501
100
80-120
Arsenic
ug/L
500
499
100
80-120
Barium
ug/L
500
511
102
80-120
Beryllium
ug/L
500
504
101
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
506
101
80-120
Lead
ug/L
500
507
101
80-120
Nickel
ug/L
500
508
102
80-120
Selenium
ug/L
500
498
100
80-120
Silver
ug/L
250
249
99
80-120
Thallium
ug/L
500
505
101
80-120
Vanadium
ug/L
500
510
102
80-120
Zinc
ug/L
500
504
101
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
6002- Holbrooks Rd Landfill
92659681
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
3977275
3977276
MS
MSD
92659004001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
522
106
104
75-125
1
Arsenic
ug/L
ND
500
500
528
523
105
104
75-125
1
Barium
ug/L
583
500
500
1120
1100
107
103
75-125
2
Beryllium
ug/L
ND
500
500
522
522
104
104
75-125
0
Cadmium
ug/L
ND
500
500
513
509
103
102
75-125
1
Chromium
ug/L
ND
500
500
520
515
104
103
75-125
1
Cobalt
ug/L
16.0
500
500
536
530
104
103
75-125
1
Copper
ug/L
ND
500
500
537
529
107
106
75-125
1
Lead
ug/L
ND
500
500
518
512
103
102
75-125
1
Nickel
ug/L
ND
500
500
518
512
103
102
75-125
1
Selenium
ug/L
ND
500
500
545
537
109
107
75-125
1
Silver
ug/L
ND
250
250
263
258
105
103
75-125
2
Thallium
ug/L
ND
500
500
517
510
103
102
75-125
1
Vanadium
ug/L
ND
500
500
536
530
107
106
75-125
1
Zinc
ug/L
ND
500
500
516
512
103
102
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 766335 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92659681001, 92659681002, 92659681003
METHOD BLANK: 3979049
Matrix:
Water
Associated Lab Samples: 92659681001, 92659681002, 92659681003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Thallium
ug/L
ND
0.20
04/07/23 02:28
LABORATORY CONTROL SAMPLE:
3979050
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
26.5
106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979051 3979052
MS MSD
92659513001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Thallium ug/L ND 25 25 27.2 26.5 109 106 75-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 765937 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659681001, 92659681002, 92659681003
METHOD BLANK: 3976888 Matrix:
Associated Lab Samples: 92659681001, 92659681002, 92659681003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,1-Trichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1,2-Trichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1-Dichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,1-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
1,2,3-Trichloropropane
ug/L
ND
1.0
04/07/23 00:43
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
04/07/23 00:43
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichlorobenzene
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloroethane
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloropropane
ug/L
ND
1.0
04/07/23 00:43
1,4-Dichlorobenzene
ug/L
ND
1.0
04/07/23 00:43
2-Butanone (MEK)
ug/L
ND
5.0
04/07/23 00:43
2-Hexanone
ug/L
ND
5.0
04/07/23 00:43
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
04/07/23 00:43
Acetone
ug/L
ND
25.0
04/07/23 00:43
Acrylonitrile
ug/L
ND
10.0
04/07/23 00:43
Benzene
ug/L
ND
1.0
04/07/23 00:43
Bromochloromethane
ug/L
ND
1.0
04/07/23 00:43
Bromodichloromethane
ug/L
ND
1.0
04/07/23 00:43
Bromoform
ug/L
ND
1.0
04/07/23 00:43
Bromomethane
ug/L
ND
2.0
04/07/23 00:43
Carbon disulfide
ug/L
ND
2.0
04/07/23 00:43
Carbon tetrachloride
ug/L
ND
1.0
04/07/23 00:43
Chlorobenzene
ug/L
ND
1.0
04/07/23 00:43
Chloroethane
ug/L
ND
1.0
04/07/23 00:43
Chloroform
ug/L
ND
1.0
04/07/23 00:43
Chloromethane
ug/L
ND
1.0
04/07/23 00:43
cis-1,2-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
cis-1,3-Dichloropropene
ug/L
ND
1.0
04/07/23 00:43
Dibromochloromethane
ug/L
ND
1.0
04/07/23 00:43
Dibromomethane
ug/L
ND
1.0
04/07/23 00:43
Ethylbenzene
ug/L
ND
1.0
04/07/23 00:43
lodomethane
ug/L
ND
20.0
04/07/23 00:43
m&p-Xylene
ug/L
ND
2.0
04/07/23 00:43
Methylene Chloride
ug/L
ND
5.0
04/07/23 00:43
o-Xylene
ug/L
ND
1.0
04/07/23 00:43
Styrene
ug/L
ND
1.0
04/07/23 00:43
Tetrachloroethene
ug/L
ND
1.0
04/07/23 00:43
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
METHOD BLANK: 3976888 Matrix:
Associated Lab Samples: 92659681001, 92659681002, 92659681003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Toluene
ug/L
ND
1.0
04/07/23 00:43
trans-1,2-Dichloroethene
ug/L
ND
1.0
04/07/23 00:43
trans- 1,3-Dichloropropene
ug/L
ND
1.0
04/07/23 00:43
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
04/07/23 00:43
Trichloroethene
ug/L
ND
1.0
04/07/23 00:43
Trichlorofluoromethane
ug/L
ND
1.0
04/07/23 00:43
Vinyl acetate
ug/L
ND
2.0
04/07/23 00:43
Vinyl chloride
ug/L
ND
1.0
04/07/23 00:43
Xylene (Total)
ug/L
ND
1.0
04/07/23 00:43
1,2-Dichloroethane-d4 (S)
%
98
70-130
04/07/23 00:43
4-Bromofluorobenzene (S)
%
100
70-130
04/07/23 00:43
Toluene-d8 (S)
%
97
70-130
04/07/23 00:43
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3976889
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
21.2
106
70-130
1,1,1-Trichloroethane
ug/L
20
19.0
95
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
21.2
106
70-130
1,1,2-Trichloroethane
ug/L
20
20.5
102
70-130
1,1-Dichloroethane
ug/L
20
18.4
92
70-130
1,1-Dichloroethene
ug/L
20
18.2
91
70-130
1,2,3-Trichloropropane
ug/L
20
20.5
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
20.8
104
70-131
1,2-Dibromoethane (EDB)
ug/L
20
20.7
104
70-130
1,2-Dichlorobenzene
ug/L
20
21.3
107
70-130
1,2-Dichloroethane
ug/L
20
19.5
97
70-130
1,2-Dichloropropane
ug/L
20
19.9
100
70-130
1,4-Dichlorobenzene
ug/L
20
21.4
107
70-130
2-Butanone (MEK)
ug/L
40
37.1
93
70-134
2-Hexanone
ug/L
40
40.2
100
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
39.2
98
70-130
Acetone
ug/L
40
31.1
78
70-133
Acrylonitrile
ug/L
100
90.6
91
70-130
Benzene
ug/L
20
19.5
98
70-130
Bromochloromethane
ug/L
20
19.1
96
70-130
Bromodichloromethane
ug/L
20
19.7
98
70-130
Bromoform
ug/L
20
20.5
103
70-130
Bromomethane
ug/L
20
15.2
76
45-151
Carbon disulfide
ug/L
20
16.8
84
70-130
Carbon tetrachloride
ug/L
20
19.7
99
70-130
Chlorobenzene
ug/L
20
20.9
105
70-130
Chloroethane
ug/L
20
17.9
90
39-152
Chloroform
ug/L
20
19.2
96
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 30

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
LABORATORY CONTROL SAMPLE:
Parameter
3976889
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Chloromethane
ug/L
20
17.0
85
58-130
cis-1,2-Dichloroethene
ug/L
20
18.6
93
70-130
cis-1,3-Dichloropropene
ug/L
20
19.8
99
70-130
Dibromochloromethane
ug/L
20
20.6
103
70-130
Dibromomethane
ug/L
20
20.6
103
70-130
Ethylbenzene
ug/L
20
20.4
102
70-130
lodomethane
ug/L
40
36.3
91
53-141
m&p-Xylene
ug/L
40
41.0
103
70-130
Methylene Chloride
ug/L
20
15.6
78
66-130
o-Xylene
ug/L
20
20.3
101
70-130
Styrene
ug/L
20
21.0
105
70-130
Tetrachloroethene
ug/L
20
20.1
100
70-130
Toluene
ug/L
20
19.6
98
70-130
trans-1,2-Dichloroethene
ug/L
20
18.4
92
70-130
trans- 1,3-Dichloropropene
ug/L
20
19.8
99
70-130
trans-1,4-Dichloro-2-butene
ug/L
20
22.5
113
57-185
Trichloroethene
ug/L
20
20.2
101
70-130
Trichlorofluoromethane
ug/L
20
18.2
91
62-130
Vinyl acetate
ug/L
40
38.7
97
70-144
Vinyl chloride
ug/L
20
14.9
74
62-130
Xylene (Total)
ug/L
60
61.3
102
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE SAMPLE:
Parameter
3976891
Units
92659923009
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
25.7
129
70-141
1,1,1-Trichloroethane
ug/L
ND
20
20.6
103
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
24.5
122
69-142
1,1,2-Trichloroethane
ug/L
ND
20
22.3
111
70-138
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-150
1,1-Dichloroethene
ug/L
ND
20
21.5
107
70-156
1,2,3-Trichloropropane
ug/L
ND
20
23.9
120
70-140
1,2-Dibromo-3-chloropropane
ug/L
ND
20
25.2
126
68-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
25.2
126
70-138
1,2-Dichlorobenzene
ug/L
ND
20
26.2
131
70-141
1,2-Dichloroethane
ug/L
ND
20
21.3
106
69-143
1,2-Dichloropropane
ug/L
ND
20
22.2
111
68-156
1,4-Dichlorobenzene
ug/L
ND
20
25.7
128
70-142
2-Butanone (MEK)
ug/L
ND
40
42.4
106
60-157
2-Hexanone
ug/L
ND
40
48.5
121
68-146
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
43.7
109
70-141
Acetone
ug/L
ND
40
37.5
94
58-157
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
MATRIX SPIKE SAMPLE:
Parameter
3976891
Units
92659923009
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Acrylonitrile
ug/L
ND
100
104
104
69-147
Benzene
ug/L
ND
20
22.3
112
70-142
Bromochloromethane
ug/L
ND
20
21.7
108
70-146
Bromodichloromethane
ug/L
ND
20
22.0
110
70-139
Bromoform
ug/L
ND
20
26.4
132
64-140
Bromomethane
ug/L
ND
20
19.0
95
28-192
Carbon disulfide
ug/L
ND
20
20.4
102
70-151
Carbon tetrachloride
ug/L
ND
20
22.5
112
70-148
Chlorobenzene
ug/L
ND
20
24.9
124
70-141
Chloroethane
ug/L
ND
20
24.2
121
58-191
Chloroform
ug/L
ND
20
20.5
103
70-148
Chloromethane
ug/L
ND
20
22.8
114
43-162
cis-1,2-Dichloroethene
ug/L
ND
20
20.5
102
68-151
cis-1,3-Dichloropropene
ug/L
ND
20
22.7
113
70-139
Dibromochloromethane
ug/L
ND
20
25.7
128
70-144
Dibromomethane
ug/L
ND
20
22.9
114
70-139
Ethylbenzene
ug/L
ND
20
23.9
119
70-143
lodomethane
ug/L
ND
40
45.1
113
35-171
m&p-Xylene
ug/L
ND
40
47.8
120
70-144
Methylene Chloride
ug/L
ND
20
8.9
45
62-149 IK,M1,v3
o-Xylene
ug/L
ND
20
24.5
122
70-145
Styrene
ug/L
ND
20
24.6
123
70-143
Tetrachloroethene
ug/L
ND
20
23.5
117
70-145
Toluene
ug/L
ND
20
21.5
107
70-142
trans-1,2-Dichloroethene
ug/L
ND
20
20.7
103
70-151
trans- 1,3-Dichloropropene
ug/L
ND
20
22.6
113
70-139
trans-1,4-Dichloro-2-butene
ug/L
ND
20
25.1
125
51-159
Trichloroethene
ug/L
ND
20
22.3
112
62-146
Trichlorofluoromethane
ug/L
ND
20
23.0
115
63-153
Vinyl acetate
ug/L
ND
40
39.9
100
61-162
Vinyl chloride
ug/L
ND
20
18.4
92
61-163
Xylene (Total)
ug/L
ND
60
72.3
121
70-143
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 3976890
Parameter
Units
92659670001
Result
Dup
Result
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
ND
ND
1,1-Dichloroethene
ug/L
ND
ND
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
SAMPLE DUPLICATE: 3976890
Parameter
Units
92659670001
Result
Dup
Result
1,2,3-Trichloropropane
ug/L
ND
ND
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,2-Dichloropropane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
ND
ND
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
ND
ND
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
99
102
4-Bromofluorobenzene (S)
%
98
99
Toluene-d8 (S)
%
97
96
RPD Qualifiers
v2
v2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 766318 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659681004
METHOD BLANK: 3978973
Associated Lab Samples: 92659681004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 02:34
1,1,1-Trichloroethane
ug/L
ND
1.0
04/07/23 02:34
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
04/07/23 02:34
1,1,2-Trichloroethane
ug/L
ND
1.0
04/07/23 02:34
1,1-Dichloroethane
ug/L
ND
1.0
04/07/23 02:34
1,1-Dichloroethene
ug/L
ND
1.0
04/07/23 02:34
1,2,3-Trichloropropane
ug/L
ND
1.0
04/07/23 02:34
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
04/07/23 02:34
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
04/07/23 02:34
1,2-Dichlorobenzene
ug/L
ND
1.0
04/07/23 02:34
1,2-Dichloroethane
ug/L
ND
1.0
04/07/23 02:34
1,2-Dichloropropane
ug/L
ND
1.0
04/07/23 02:34
1,4-Dichlorobenzene
ug/L
ND
1.0
04/07/23 02:34
2-Butanone (MEK)
ug/L
ND
5.0
04/07/23 02:34
2-Hexanone
ug/L
ND
5.0
04/07/23 02:34
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
04/07/23 02:34
Acetone
ug/L
ND
25.0
04/07/23 02:34
Acrylonitrile
ug/L
ND
10.0
04/07/23 02:34
Benzene
ug/L
ND
1.0
04/07/23 02:34
Bromochloromethane
ug/L
ND
1.0
04/07/23 02:34
Bromodichloromethane
ug/L
ND
1.0
04/07/23 02:34
Bromoform
ug/L
ND
1.0
04/07/23 02:34
Bromomethane
ug/L
ND
2.0
04/07/23 02:34
Carbon disulfide
ug/L
ND
2.0
04/07/23 02:34
Carbon tetrachloride
ug/L
ND
1.0
04/07/23 02:34
Chlorobenzene
ug/L
ND
1.0
04/07/23 02:34
Chloroethane
ug/L
ND
1.0
04/07/23 02:34
Chloroform
ug/L
ND
1.0
04/07/23 02:34
Chloromethane
ug/L
ND
1.0
04/07/23 02:34
cis-1,2-Dichloroethene
ug/L
ND
1.0
04/07/23 02:34
cis-1,3-Dichloropropene
ug/L
ND
1.0
04/07/23 02:34
Dibromochloromethane
ug/L
ND
1.0
04/07/23 02:34
Dibromomethane
ug/L
ND
1.0
04/07/23 02:34
Ethylbenzene
ug/L
ND
1.0
04/07/23 02:34
lodomethane
ug/L
ND
20.0
04/07/23 02:34
m&p-Xylene
ug/L
ND
2.0
04/07/23 02:34
Methylene Chloride
ug/L
ND
5.0
04/07/23 02:34 C9,v1
o-Xylene
ug/L
ND
1.0
04/07/23 02:34
Styrene
ug/L
ND
1.0
04/07/23 02:34
Tetrachloroethene
ug/L
ND
1.0
04/07/23 02:34
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
METHOD BLANK: 3978973
Associated Lab Samples: 92659681004
Parameter
Units
Toluene
ug/L
trans-1,2-Dichloroethene
ug/L
trans- 1,3-Dichloropropene
ug/L
trans-1,4-Dichloro-2-butene
ug/L
Trichloroethene
ug/L
Trichlorofluoromethane
ug/L
Vinyl acetate
ug/L
Vinyl chloride
ug/L
Xylene (Total)
ug/L
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
QUALITY CONTROL DATA
Matrix: Water
Blank
Result
Reporting
Limit
Analyzed
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
2.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
ND
1.0
04/07/23 02:34
95
70-130
04/07/23 02:34
95
70-130
04/07/23 02:34
108
70-130
04/07/23 02:34
IK
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3978974
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
20
18.9
95
70-130
1,1,1-Trichloroethane
ug/L
20
18.5
93
70-130
1,1,2,2-Tetrachloroethane
ug/L
20
19.8
99
70-130
1,1,2-Trichloroethane
ug/L
20
19.5
97
70-130
1,1-Dichloroethane
ug/L
20
17.4
87
70-130
1,1-Dichloroethene
ug/L
20
17.8
89
70-130
1,2,3-Trichloropropane
ug/L
20
19.2
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
20
18.9
95
70-131
1,2-Dibromoethane (EDB)
ug/L
20
19.7
99
70-130
1,2-Dichlorobenzene
ug/L
20
19.5
98
70-130
1,2-Dichloroethane
ug/L
20
18.2
91
70-130
1,2-Dichloropropane
ug/L
20
20.2
101
70-130
1,4-Dichlorobenzene
ug/L
20
19.4
97
70-130
2-Butanone (MEK)
ug/L
40
40.6
102
70-134
2-Hexanone
ug/L
40
44.0
110
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
40
42.1
105
70-130
Acetone
ug/L
40
35.3
88
70-133
Acrylonitrile
ug/L
100
96.7
97
70-130
Benzene
ug/L
20
18.5
93
70-130
Bromochloromethane
ug/L
20
17.3
87
70-130
Bromodichloromethane
ug/L
20
18.0
90
70-130
Bromoform
ug/L
20
18.2
91
70-130
Bromomethane
ug/L
20
17.2
86
45-151
Carbon disulfide
ug/L
20
15.6
78
70-130
Carbon tetrachloride
ug/L
20
19.3
96
70-130
Chlorobenzene
ug/L
20
18.8
94
70-130
Chloroethane
ug/L
20
19.8
99
39-152
Chloroform
ug/L
20
16.8
84
70-130
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 30

leAnalyiical
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[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
LABORATORY CONTROL SAMPLE:
Parameter
3978974
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
20
18.7
cis-1,2-Dichloroethene
ug/L
20
17.6
cis-1,3-Dichloropropene
ug/L
20
20.2
Dibromochloromethane
ug/L
20
18.1
Dibromomethane
ug/L
20
18.5
Ethylbenzene
ug/L
20
18.6
lodomethane
ug/L
40
40.9
m&p-Xylene
ug/L
40
37.2
Methylene Chloride
ug/L
20
39.2
o-Xylene
ug/L
20
18.2
Styrene
ug/L
20
18.6
Tetrachloroethene
ug/L
20
17.6
Toluene
ug/L
20
18.8
trans-1,2-Dichloroethene
ug/L
20
17.6
trans- 1,3-Dichloropropene
ug/L
20
19.1
trans-1,4-Dichloro-2-butene
ug/L
20
24.5
Trichloroethene
ug/L
20
19.0
Trichlorofluoromethane
ug/L
20
18.9
Vinyl acetate
ug/L
40
34.3
Vinyl chloride
ug/L
20
16.6
Xylene (Total)
ug/L
60
55.4
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
94
58-130
88
70-130
101
70-130
90
70-130
93
70-130
93
70-130
102
53-141
93
70-130
196
66-130 L1,v1
91
70-130
93
70-130
88
70-130
94
70-130
88
70-130
95
70-130
123
57-185
95
70-130
94
62-130
86
70-1441K
83
62-130
92
70-130
103
70-130
98
70-130
102
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978975
MS
92659909002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3978976
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
24.0
27.3
120
136
70-141
13
1,1,1-Trichloroethane
ug/L
ND
20
20
21.7
24.2
108
121
70-150
11
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
22.3
25.6
112
128
69-142
14
1,1,2-Trichloroethane
ug/L
ND
20
20
22.5
25.7
113
129
70-138
13
1,1-Dichloroethane
ug/L
ND
20
20
20.5
22.8
102
114
70-150
10
1,1-Dichloroethene
ug/L
ND
20
20
20.9
23.2
105
116
70-156
10
1,2,3-Trichloropropane
ug/L
ND
20
20
21.9
25.4
110
127
70-140
15
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
21.8
24.4
109
122
68-146
11
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
23.0
26.7
115
133
70-138
15
1,2-Dichlorobenzene
ug/L
ND
20
20
23.7
25.9
119
129
70-141
9
1,2-Dichloroethane
ug/L
ND
20
20
20.9
23.7
104
118
69-143
13
1,2-Dichloropropane
ug/L
ND
20
20
22.0
24.9
110
124
68-156
12
1,4-Dichlorobenzene
ug/L
ND
20
20
23.4
25.3
117
126
70-142
8
2-Butanone (MEK)
ug/L
ND
40
40
42.6
49.2
106
123
60-157
14
2-Hexanone
ug/L
ND
40
40
50.6
59.5
127
149
68-146
16 M1
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40
45.6
53.0
114
133
70-141
15
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3978975
MS
92659909002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3978976
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD Qual
Acetone
ug/L
ND
40
40
38.5
45.1
96
113
58-157
16
Acrylonitrile
ug/L
ND
100
100
103
117
103
117
69-147
13
Benzene
ug/L
ND
20
20
21.3
23.9
107
120
70-142
12
Bromochloromethane
ug/L
ND
20
20
21.4
24.0
107
120
70-146
11
Bromodichloromethane
ug/L
ND
20
20
21.8
24.6
109
123
70-139
12
Bromoform
ug/L
ND
20
20
23.5
26.5
118
133
64-140
12
Bromomethane
ug/L
ND
20
20
11.8
12.5
59
63
28-192
6 v3
Carbon disulfide
ug/L
ND
20
20
20.1
22.1
100
110
70-151
10
Carbon tetrachloride
ug/L
ND
20
20
21.8
24.8
109
124
70-148
13
Chlorobenzene
ug/L
ND
20
20
23.1
25.8
116
129
70-141
11
Chloroethane
ug/L
ND
20
20
17.6
19.5
88
97
58-191
10
Chloroform
ug/L
ND
20
20
20.9
23.1
105
116
70-148
10
Chloromethane
ug/L
ND
20
20
17.7
19.7
89
98
43-162
10
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.6
23.2
103
116
68-151
12
cis-1,3-Dichloropropene
ug/L
ND
20
20
22.1
25.4
111
127
70-139
14
Dibromochloromethane
ug/L
ND
20
20
23.3
26.4
116
132
70-144
12
Dibromomethane
ug/L
ND
20
20
22.8
25.8
114
129
70-139
12
Ethylbenzene
ug/L
ND
20
20
22.6
25.3
113
126
70-143
11
lodomethane
ug/L
ND
40
40
37.4
40.1
93
100
35-171
7
m&p-Xylene
ug/L
ND
40
40
45.7
51.4
114
129
70-144
12
Methylene Chloride
ug/L
ND
20
20
23.4
26.4
111
127
62-149
12 v1
o-Xylene
ug/L
ND
20
20
22.8
25.7
114
128
70-145
12
Styrene
ug/L
ND
20
20
23.6
26.5
118
132
70-143
11
Tetrachloroethene
ug/L
ND
20
20
21.7
24.4
109
122
70-145
12
Toluene
ug/L
ND
20
20
21.0
23.6
105
118
70-142
11
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.2
23.5
106
118
70-151
10
trans- 1,3-Dichloropropene
ug/L
ND
20
20
23.3
26.4
117
132
70-139
12
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
28.4
33.9
142
170
51-159
181H,M1
Trichloroethene
ug/L
ND
20
20
22.7
25.5
113
128
62-146
12
Trichlorofluoromethane
ug/L
ND
20
20
18.2
20.4
91
102
63-153
12
Vinyl acetate
ug/L
ND
40
40
41.4
47.5
103
119
61-162
14
Vinyl chloride
ug/L
ND
20
20
15.1
16.8
76
84
61-163
11 v1
Xylene (Total)
ug/L
ND
60
60
68.5
77.1
114
128
70-143
12
1,2-Dichloroethane-d4 (S)
%
98
97
70-130
4-Bromofluorobenzene (S)
%
101
100
70-130
Toluene-d8(S)
%
97
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 766432 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659681001, 92659681003
METHOD BLANK: 3979517
Associated Lab Samples: 92659681001, 92659681003
Parameter Units
1,4-Dioxane (p-Dioxane) ug/L
1,2-Dichloroethane-d4 (S) %
Toluene-d8 (S) %
Matrix: Water
Blank Reporting
Result Limit
Analyzed
ND 2.0
04/06/23 18:46
103 67-130
04/06/2318:46
101 70-130
04/06/2318:46
Qualifiers
LABORATORY CONTROL SAMPLE: 3979518
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 19.6 98 70-130
1,2-Dichloroethane-d4 (S) % 103 67-130
Toluene-d8 (S) % 102 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3979519
3979520
MS
MSD
92659681001 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L 4.6 20
20 21.1
20.8 82
81
55-137 2 H1
1,2-Dichloroethane-d4 (S)
%
103
103
67-130
Toluene-d8(S)
%
121
120
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 30

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
QC Batch: 767422 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92659681002
METHOD BLANK: 3984624
Matrix:
Water
Associated Lab Samples: 92659681002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
04/12/23 15:43
1,2-Dichloroethane-d4 (S)
%
113
67-130
04/12/23 15:43
Toluene-d8 (S)
%
97
70-130
04/12/23 15:43
LABORATORY CONTROL SAMPLE: 3984625
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 17.6 88 70-130
1,2-Dichloroethane-d4 (S) % 96 67-130
Toluene-d8 (S) % 103 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3984626
3984627
MS
MSD
92659681002 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 73.7 20
20 92.7
96.5 95
114
55-137 4 H1,H5,P4
1,2-Dichloroethane-d4 (S)
%
108
102
67-130
Toluene-d8(S)
%
94
113
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: 6002- Holbrooks Rd Landfill
Pace Project No.: 92659681
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
C9 Common Laboratory Contaminant.
H1 Analysis conducted outside the EPA method holding time
H5 Reanalysis conducted in excess of EPA method holding time. Results confirm original analysis performed in hold time.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/13/2023 06:04 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 30

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
6002- Holbrooks Rd Landfill
92659681
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92659681001
6002-HRW10
EPA 3010A
766032
EPA6010D
766125
92659681002
6002-HRW11 R
EPA 3010A
766032
EPA6010D
766125
92659681003
6002-HRW13
EPA 3010A
766032
EPA6010D
766125
92659681001
6002-HRW10
EPA 3010A
766335
EPA6020B
766457
92659681002
6002-HRW11 R
EPA 3010A
766335
EPA 6020B
766457
92659681003
6002-HRW13
EPA 3010A
766335
EPA6020B
766457
92659681001
6002-HRW10
EPA 8260D
765937
92659681002
6002-HRW11R
EPA 8260D
765937
92659681003
6002-HRW13
EPA 8260D
765937
92659681004
TRIP BLANK
EPA 8260D
766318
92659681001
6002-HRW10
EPA 8260D Mod.
766432
92659681002
6002-HRW11R
EPA 8260D Mod.
767422
92659681003
6002-HRW13
EPA 8260D Mod.
766432
Date: 04/13/2023 06:04 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 30

ace DC# Title: ENV-FRM-HUN�1-0083 v02 Sample Condition Upon Receipt
Effective Date: 11/14/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client N1Name:Upon eceipt r �,,
��� �{���a♦ �ti��` L t��iIj� "f1i } }Li0I Project4:
Courier: ❑Fed Ex ❑ S ENSPS Client
❑ Commercial ❑pace ❑Other:
Custody Seal Present? Dyes E Na Seals lntact? ❑Yes ti o
Packing Material: ❑Bubble Wrap Bubble Bags ❑None ❑ Other
Thermonp�e'r:
IRGun ID: I �/ Type Ice: [ Wet 013lue
Correction Factor:
Cooler Temp: ° Add/Subtract (°C)
Cooler Temp CorrecteeN;A,,,ter
USDA Regulated Soil ( sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or 5C
(check maps)? llYes F— No
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Reauested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix
Headspace in VDA Vials (>5.6m
Trip Blank Present?
w
Yz
IJNo
LJN/A
1.
es
❑NO
❑N/A
2.
Yes
o
❑N/A
3.
Yes
o
El N/A
4.
es
❑No
(_1 N/A
5,
7 Y s
[:]No❑N/A
6.
es
[]No
❑N/A
res
❑No
❑N A
?,
PS
❑No
/A
8.
Yes
❑No
❑N/A
41
ONO ❑N/A 10.
❑No/ ❑N/A 11,
W00:92659681
92659581 II II II II I I I I I
f - �
Date/Initials Person Examining Contents:
Biological Tiss F zen?
❑Yes ❑eNo N/A fff
❑,None
Temp should be above freezing to 6'C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a Foreign source (internationally,
including Hawaii and Puerto Rico)? ❑Yes ❑No
Trip Blank Custody Seals Present? No ❑N/A
COMMENTS/SAMPLE DISCREPANCY Fleld Data Required? ❑Yes [:]No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Date:
Date:
Qualtrax ID: 69614 Page 1 of 2 Page 28 of 30

DC#_Title: ENV-FRM-HUN1-0083 02_Sample Condition Upon Receipt
ace
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project A
WO#:92659681
PM: ASF Due Date: 04/13/23
CLIENT: 92—HECK CO
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pH Adjustment Log for Preserved Samples
sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Arnountof Preservative Lot #
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina Compliance samples, a copy of this form will W sent to the North Carolina DEN RCertification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 29 of 30

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Page 30 of 30