1117_Buncombe_GARAA_Water Quality Mon Rep_Q1 2023_FID1792112_20230421

DENR USE ONLY []Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition,
etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Craig Eady Phone: [phone]
E-mail: ceady(a)svnterracoro.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Progress Greater January 26, 2023
Asheville Regional Airport FFIethrer,
inal Drive #1 1117-STRUC-2020 .0500
Authority North Carolina
Structural Fills — Areas 1, 3, & 4
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
® No. No groundwater or surface water standards were exceeded.
Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on
this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting
or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady Project Manager
[phone]
Facility Representative Name (Print) Title
(Area Code) Telephone Number
4/21/2023
Affix NC Licensed/ Professional Geologist Seal
Signature Date
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148 River Street, Suite 220, Greenville, SC 29601
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Facility Representative Address
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C-1478 / North Carolina Geological Corporation Number C-387';�:�
NC PE Firm License Number (if applicable effective May 1, 2009)
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Revised 6/2009

REPORT VERIFICATION
PROJECT: QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILLS —AREAS 1, 3, & 4
PERMIT NO. 1117-STRUC-2020
TITLE: QUARTERLY WATER QUALITY MONITORING REPORT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by:
Approved by:
Project Manager: Craig Eady, NC LG
Date: 4/21/2022
Date: 4/21/2022
Licensed Geologist Seal:
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SynTerra
148 River Street, Suite 220
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North Carolina Geological Corporation Number C-387

Science & Engineering Consultants
synterracorp.com
QUARTERLY WATER QUALITY
MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
STRUCTURAL FILLS —AREAS 1, 3, AND 4
PERMIT NO. 1117-STRUC-2020
61 TERMINAL DRIVE #1
FLETCHER, NORTH CAROLINA
APRIL 2023
PREPARED FOR
DUKE
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DUKE ENERGY PROGRESS, LLC
Kathryn W. Webb
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Kelly Ferri
Senior Peer Review "%CAR ///// Project Manager
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Craig D. Eacly; NC L.G. 1599
Senior Geologist

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0 BACKGROUND............................................................................................................1-1
2.0 MONITORING NETWORK............................................................................................ 2-1
2.1 Groundwater..............................................................................................................2-1
2.2 Surface Water............................................................................................................2-2
2.3 Fill Material Pore Water.............................................................................................2-2
3.0 SAMPLING ANALYSIS AND METHODS......................................................................... 3-1
3.1 Groundwater..............................................................................................................3-1
3.2 Surface Water............................................................................................................3-1
4.0 STATEMENT OF WORK............................................................................................... 4-1
5.0 FILL AREA 1 RESULTS.................................................................................................. 5-1
5.1 Groundwater Flow.....................................................................................................5-1
5.2 Groundwater Analytical Results.................................................................................5-1
5.3 Surface Water Analytical Results................................................................................5-1
5.4 Piezometer Pore Water Levels...................................................................................5-2
6.0 FILL AREA 3 RESULTS.................................................................................................. 6-1
6.1 Groundwater Flow.....................................................................................................6-1
6.2 Groundwater Analytical Results.................................................................................6-1
7.0 FILL AREA 4 RESULTS.................................................................................................. 7-1
7.1 Groundwater Flow.....................................................................................................7-1
7.2 Groundwater Analytical Results.................................................................................7-1
8.0 REFERENCES...............................................................................................................8-1
ril 2023 Page i
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report —January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF FIGURES
Figure 1
USGS Site Location Map
Figure 2
Groundwater Sample Location Map (Structural Fills - Areas 1, 3, and 4)
Figure 3
Surface Water Sample Location Map (Structural Fill - Area 1)
Figure 4
Pore Water Piezometer Location Map (Structural Fill - Area 1)
LIST OF TABLES
Table 1
Monitoring Well Construction Information
Table 2
Surface Water Field and Analytical Results
Table 3
Field and Analytical Results that Equal Surface Water Quality Standards
Table 4
Pore Water Piezometer Water Levels
LIST OF APPENDICES
Appendix A Surface Water Sampling Logs
Appendix B Surface Water Laboratory Analytical Reports
ril 2023 Page ii
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report —January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
LIST OF ACRONYMS AND ABBREVIATIONS
02B
Title 15A NCAC 02B .0200, Surface Water and Wetland Standards
CCP
coal combustion products
DWM
Division of Waste Management
Duke Energy
Duke Energy Progress, LLC
EDD
Electronic Data Deliverable
GARAA
Greater Asheville Regional Airport Authority
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
NOAA
National Oceanic and Atmospheric Administration
NRWQC
USEPA National Recommended Water Quality Criteria
ORP
oxygen reduction potential
Site
Greater Asheville Regional Airport Authority
SWS
Solid Waste Section
TDS
total dissolved solids
TOC
total organic carbon
TSS
total suspended solids
WQMRP
Water Quality Monitoring and Reporting Plan
ril 2023 Page iii
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
1.0 BACKGROUND
This Quarterly Water Quality Monitoring Report, prepared to satisfy reporting requirements of
permit No. 1117-STRUC-2020, provides a summary of January 2023 Site surface water quality
sampling activities and results at the Greater Asheville Regional Airport Authority (GARAA or
Site). The Site is located in Fletcher, Buncombe County, North Carolina, approximately 13 miles
south of Asheville, North Carolina (Figure 1). Three separate structural fill areas (Areas 1, 3, and
4) were constructed at the Site from the beneficial reuse of coal combustion products (CCP)
material. That material was sourced from the nearby Asheville Steam Electric Plant, owned and
operated by Duke Energy Progress, LLC (Duke Energy).
A Water Quality Monitoring and Reporting Plan (WQMRP) (SynTerra, 2020) pertaining to the
structural fills was submitted to the North Carolina Department of Environmental Quality
(NCDEQ) Division of Waste Management (DWM) — Solid Waste Section (SWS) in December
2020. The WQMRP established procedures for monitoring groundwater in the surficial flow
zone (saprolite and partially weathered rock) beneath structural fill Areas 1, 3, and 4 and
surface waters adjacent to structural fill Area 1 during operational and post -closure periods.
Such procedures are established to satisfy requirements of Title 15A of the North Carolina
Administrative Code (NCAC) 13B .0504(1)(g)(iv). Subsequent to approval of the WQMRP,
NCDEQ SWS issued water quality monitoring and reporting permit number 1117-STRUC-2020
on December 14, 2020.
ril 2023 Page 1-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report —January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
2.0 MONITORING NETWORK
2.1 Groundwater
Monitoring well locations of the three structural fill areas are provided on Figure 2, and
monitoring well construction details are presented in Table 1. Boring logs and well
abandonment records are included in the WQMRP and have been provided to NCDEQ SWS.
A brief description of the monitoring network for each fill area is provided below:
Area 1
The existing groundwater -quality monitoring network for Area 1 consists of two background
wells and six review boundary wells (Figure 2). Four of the monitoring wells (MW-1A-A1, MW-
2A-A1, MW-4A-Al, and MW-5-Al) were installed in 2009. The remaining four monitoring wells
(MW-6-Al, MW-7-Al, MW-8-Al, and MW-9-Al) were installed in 2018. Wells MW-4A-A1 and
MW-9-Al, located upgradient of Area 1, serve as background wells. The remaining wells were
installed either side -gradient or downgradient from Area 1 at the approximate review boundary
(Figure 2). One additional well (MW-1-Al), located north and downgradient of Area 1 beyond
the review boundary, is designated to be used only for water -level measurements, as per the
WQMRP.
Construction to upgrade the Area 1 cover system with a geomembrane liner began in May
2022. In August 2022, monitoring well MW-2A-A1 was abandoned to support construction for
the Area 1 cover project; a replacement well (MW-2B-Al) was installed in October 2022. The
well abandonment record for MW-2A-A1 was included in the Quarter 3 WQMR, submitted in
October 2022. A well construction record for MW-2B-A1 was included in the Quarter 4 WQMR,
submitted in March 2023. A boring log for MW-2B-A1 will be included in the WQMRP update,
anticipated to be completed in 2023.
Area 3
The existing groundwater monitoring well network for Area 3 consists of seven downgradient
review boundary wells (MW-1-A3, MW-2-A3, MW-3-A3, MW-4-A3, MW-5-A3, MW-6-A3, and
MW-7-A3) (Figure 2). The monitoring wells were installed in December 2013.
Area 4
The existing groundwater monitoring well network for Area 4 consists of one background well
and six downgradient review boundary wells (Figure 2). Wells MW-2-A4 and MW-5-A4 were
installed in 2009, wells MW-6-A4 and MW-7-A4 were installed in 2010, and the remaining three
wells (MW-1A-A4, MW-5D-A4, and MW-9-A4) were installed in 2012. The top of casing for well
MW-9-A4 was extended vertically in September 2014 to accommodate final surface grade of
the GARAA taxiway project. Well MW-1A-A4 was initially installed upgradient of Area 4 as a
background well but was abandoned because of the taxiway project. Replacement background
April 2023 Page 2-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
well MW-IAR-A4 was installed in September 2015 (Figure 2). MW-1A-A4 was properly
abandoned in October 2015.
In June 2022, a new Area 4 background well (MW-IAR-A4R) was installed in preparation for a
new GARAA control tower project. MW-IAR-A4 was abandoned, and a new background well
(MW-IAR-A4R) was installed and screened within the same flow zone. Construction details for
background monitoring well MW-IAR-A4R are presented in Table 1, and the location of the
well is shown on Figure 2. The well abandonment record for MW-IAR-A4 and the well
construction record for MW-AIR-A4R were included in the Q3 WQMR, submitted in October
2022. A boring log for MW-IAR-A4R will be included in the WQMRP update, anticipated to be
completed in Q2 2023.
2.2 Surface Water
The eight surface water sample locations designated for Area 1 include SW-2-Al, SW-3-Al, SW-
413-A1, SW-4C-Al, SW-5-Al, SW-6-Al, SW-8-Al, and SW-9-Al (Figure 3). SW-2-Al, located near
the southern portion of Area 1, serves as a background surface water monitoring location. SW-
3-Al, located north of Area 1, is the farthest downgradient surface water sample location and
receives flow from the remaining Area 1 surface water locations.
Surface water sample location SW-4C-Al was not sampled during the January 2023 sampling
event because of dry conditions. Surface water sample locations SW-6-Al and SW-8-Al are
inactive because of construction activities for the Area 1 cover project and were not sampled
during the January 2023 sampling event. A Site walk with NCDEQ is planned after completion of
the Area 1 cover project to observe remaining surface water sample locations and to identify
new surface water areas that may result from changing Site conditions related to the Area 1
cover project.
2.3 Fill Material Pore Water
A total of nine piezometers installed within the Area 1 Structural Fill are used to monitor pore
water within the fill material (Figure 4). Six piezometers (PZ-1, PZ-2, PZ-3, PZ-4, PZ-5, and PZ-6)
were installed in November 2017, and three piezometers (PZ-2S, PZ-31D, and PZ-7) were
installed in August 2018. Those piezometers are designated to be used only for pore water -level
measurements, as per the WQM RP.
ril 2023 Page 2-2
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
3.0 SAMPLING ANALYSIS AND METHODS
3.1 Groundwater
Groundwater samples are collected semiannually, as per the WQMRP, and were not collected
during Q1 2023.
3.2 Surface Water
Surface water sampling of Area 1 was conducted in accordance with the Internal Technical
Guidance: Evaluating Impact to Surface Water from Discharging Groundwater Plumes (NCDEQ,
October 2017). Surface water samples were collected during Q12023 at locations where there
was sufficient flow to sample. Samples were collected as single -grab samples on January 26,
2023. Surface water downgradient of Area 1 flows northward toward the French Broad River
and is not classified. The French Broad River has a Class B surface water classification in the
vicinity of the airport. Therefore, analytical results for surface water collected at Area 1 are
compared with Title 15A NCAC 02B .0200, Surface Water and Wetland Standards (02B).
Surface water samples were collected at each location during low or base flow conditions.
According to review of the U.S. Department of Commerce National Oceanic and Atmospheric
Administration (NOAA) record of climatological observations for the Asheville Airport Weather
Station (USW00003812), the last recorded precipitation event prior to the January 26, 2023,
sampling event was recorded on January 25, 2023, at 1.24 inches. Surface water samples were
not collected from locations where dry or stagnant conditions, insufficient flow, or other
observed conditions that would preclude the ability to collect a valid, representative sample
were encountered. Field parameters [i.e., pH, temperature, dissolved oxygen, specific
conductance, oxidation reduction potential (ORP), and turbidity] were measured and recorded
prior to collection of surface water samples. Copies of surface water field sampling logs are
included in Appendix A.
Duke Energy Analytical Laboratory (North Carolina Laboratory Certification #248) analyzed
surface water samples for total and dissolved phase metals, alkalinity, chloride, sulfate, cations,
anions, and other parameters, including total dissolved solids (TDS), total organic carbon (TOC),
and total suspended solids (TSS). Surface water analytical laboratory reports, including
analytical methods and constituent detection limits, and chain -of -custody forms are provided in
Appendix B.
ril 2023 Page 3-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
4.0 STATEMENT OF WORK
The following tasks occurred during Q1 2023:
• Collected quarterly surface water samples from Area 1 on January 26, 2023. (Duke
Energy personnel performed this task.)
• Measured depth -to -pore water in each of the piezometers positioned within Area 1 on
March 28, 2023. (SynTerra personnel performed this task.)
• Conducted a review of laboratory surface water analytical results for samples listed
above.
• Reviewed the laboratory analytical results pertaining to the parameters listed in the
WQMRP. The Electronic Data Deliverable (EDD) provided by Duke Energy was adapted
to conform to the format requirements of the NCDEQ EQUIS EDD template.
• Prepared and submitted this quarterly Water Quality Monitoring Report to Duke Energy.
ril 2023 Page 4-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
5.0 FILL AREA 1 RESULTS
5.1 Groundwater Flow
Not applicable during this reporting period.
5.2 Groundwater Analytical Results
Not applicable during this reporting period.
5.3 Surface Water Analytical Results
A summary of the surface water field parameters and analytical results (total and dissolved)
from the January 2023 surface water sampling event is presented in Table 2. Surface water
analytical results are compared with applicable 02B Class B surface water standards.
Concentrations greater than 02B standards are noted in Table 2 in bold font. A summary of
surface water field and analytical results that are equal to or greater than the 02B standard and
a preliminary analysis of the cause and significance of the exceedances are presented in
Table 3.
Surface water samples were collected using the grab sample method and compared to
applicable (02B Standards), in -stream target values, and USEPA National Recommended Water
Quality Criteria (NRWQC) for Aquatic Life and Human Health. Duke Energy provides
comparisons against in -stream target values with the qualification that an exceedance of the
published value is not necessarily a violation of the water quality standard for toxicity. As stated
by the USEPA, NRWQC standards do not constitute regulations, nor do they impose a legally
binding requirement. Therefore, comparisons with those criteria are for information purposes
only. Several 02B standards require sampling methods specific to acute or chronic
concentrations and are not applicable to the grab sample method. Acute and chronic standards
are included for screening purposes only. Hardness -dependent standards require sampling
methods specific to acute or chronic concentrations and are not applicable to the grab sample
method. An in -stream hardness of 25 mg/L is assumed, and standards are provided for
screening purposes only.
Review of the January 2023 surface water sampling data indicates that the estimated mercury
concentrations equal to or greater than the method detection limit but less than the method
reporting limit at SW-2-Al (background), SW-3-Al, SW-5-Al, and SW-9-Al were greater than
the 02B criteria. However, the mercury concentrations are within the Site background
concentration range. The turbidity at SW-5-Al was slightly greater than the 02B criteria and
may be a result of the precipitation event that occurred the previous day. No other constituents
were detected at concentrations greater than (or less than for dissolved oxygen and pH)
applicable 02B criteria for Class B surface waters.
Surface water in the vicinity of Area 1 flows north and is conveyed downgradient to surface
water location SW-3-Al, beyond the compliance boundary and near the northern property
boundary (Figure 3). The combined surface water flow at SW-3-Al is conveyed toward the
ril 2023 Page 5-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
French Broad River. Because of the downgradient location of SW-3-Al and the combined flow
from Area 1 surface water, evaluation of SW-3-Al data is representative of the overall surface
water quality downgradient of Area 1 prior to migrating off -Site and potentially discharging into
a classified body of water (French Broad River). Review of January 2023 surface water sampling
data (Table 2) indicates that surface water concentrations at SW-3-Al are less than 02B values
for Class B surface waters or Site background concentrations.
5.4 Piezometer Pore Water Levels
Pore water -level data were collected from the eight piezometers (PZ-1, PZ-2/2S, PZ-3/31D, PZ-4,
PZ-5, and PZ-6) in the Area 1 Structural Fill (Figure 4) during Q1 on March 28, 2023. Depth -to -
water -level measurements are presented in Table 4.
ril 2023 Page 5-2
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report —January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
6.0 FILL AREA 3 RESULTS
6.1 Groundwater Flow
Not applicable during this reporting period.
6.2 Groundwater Analytical Results
Not applicable during this reporting period.
ril 2023 Page 6-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
7.0 FILL AREA 4 RESULTS
7.1 Groundwater Flow
Not applicable during this reporting period.
7.2 Groundwater Analytical Results
Not applicable during this reporting period.
ril 2023 Page 7-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
8.0 REFERENCES
NCDEQ. (2017). Internal Technical Guidance: Evaluating Impact to Surface Water from
Discharging Groundwater Plume. N.C. Division of Water Resources. Raleigh, N.C.: N.C.
Department of Environmental Quality. Retrieved March 4, 2021, from
https://files.nc.gov/ncdeq/Sampl ing%20of%20SW%20for%2002L%20171031%20FI NAL_
O.pdf
SynTerra. (2020). Water Quality Monitoring and Reporting Plan — Structural Fills Areas 1, 3, & 4
- Greater Asheville Regional Airport Authority. November 2020.
ril 2023 Page 8-1
Project: 00.0059.53.01.02

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
FIGURES
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QUARTERLY WATER QUALITY MONITORING REPORT
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CHARLOTTE
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3AND 4 BASED ON DRAWING BY FRANKLIN S. CRAIG, P.E. OF
p,
GASTONIA, NORTH CAROLINA ("AREA#4-ALL PHASES ENGINEERED FILL
a MW-9-A4
DESIGN", SHEET E-1, JUNE 30, 2011).
c+� ;
T"
DETENTION
6. AERIAL PHOTOGRAPH OBTAINED FROM NC ONE MAP GEOSPATIAL
y
POND
t.
PORTALAT http://data.nconemap.com/geofortal/catalog/rasterldownload.page
__.. �"
ON OCTOBER 7, 2020. AERIAL COLLECTED ON JANUARY 1, 2019.
µ'Y
*
7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA
"'P _
STATE PLANE COORDINATE SYSTEM RIPS 3200 (NAD83).
41P
GRAPHIC SCALE
650 0 650 1,300
FIGURE 2
GROUNDWATER SAMPLE LOCATION MAP
WnTerra
(IN FEET)
STRUCTURAL FILLS -AREAS 1, 3, AND 4
DRAWN BY: C. WYATT
DATE:06/08/2022
QUARTERLY WATER QUALITY MONITORING REPORT
'DUKE
REVISED BY E.ORDEMANN
CHECKED BY: K..
DATE:03/24/2023
DATE:03/24/2023
JANUARY2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FERI
APPROVED K. FERRI
DATE: 03/24/2023
ENERGY
PROJECT MMAN
MANAGER K. EERRI
FLETCHER, NORTH CAROLINA
PROGRESS

• SW-3-A1 � � �:.
EXISTING
pr lSW-4C-A1
SW-4B-A1
S
r15" RRCCP �
/ 1
• 1
1
1
1
CONCRETE HEADWALL
VV8A1
1 \
1 \
1 �
� FENCE \
• LOCKED GATE 1
\ ;1 1
1 60" RCP r
■ - 1 r �
1 ACCESS ROAD
1
■ � 1 rI 41.
\ 1
1
SW-2-A1
LEGEND
0 BACKGROUND SURFACE WATER SAMPLE LOCATION
0 INACTIVE SURFACE WATER SAMPLE LOCATION
0 SURFACE WATER SAMPLE LOCATION
REVIEW BOUNDARY
• • COMPLIANCE BOUNDARY
PROPERTY BOUNDARY
COAL COMBUSTION PRODUCT LIMITS
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. SURFACE WATER SAMPLE LOCATIONS SW-6-Al AND SW-8-Al ARE INACTIVE DUE TO
CONSTRUCTION ACTIVITIES FOR THE COVER PROJECT.3. p
data nRonemapIAL OToO PHOTOGRAPH OBTAINED FROM download page ON OCTOBIAL ER PORTAL 020. AERIAL
COLLECTED ON JANU RRY 1, 2019.
4. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
COORDINATE SYSTEM FIPS 3200 (NAD83).
1,
synTerra
tDUKE
EENERGY
PROGRESS
GRAPHIC SCALE
125 0 125 250
(IN FEET)
DRAWN BY. C. WYATT DATE: 06/08/2022
REVISED BY. E. ORDEMANN DATE: 03/24/2023
CHECKED BY: K. FERRI DATE: 03/24/2023
APPROVED BY. K. FERRI DATE: 03/24/2023
PROJECT MANAGER: K. FERRI
FIGURE 3
SURFACE WATER SAMPLE LOCATION MAP
STRUCTURAL FILL -AREA I
QUARTERLY WATER QUALITY MONITORING RERPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

PTING WETLANDS l�'�
U
*15" RCP/
I
1
♦ N �
PZ-6 ` 7 m
m N�
CONCRETE HEADWALL \
PZ 5 PZ-4 \
1
(AD PZ-3 ,\ ♦
PZ-7 `
1 \
FENCE : �\ ♦
; r
, 9, LOCKED GATE 1 ♦ •It
1 60" RCP
1 pCCES d
41
1
\ 1
LEGEND
■
C PIEZOMETER -PORE WATER LEVEL ONLY
REVIEW BOUNDARY
- • - COMPLIANCE BOUNDARY
- - - - COAL COMBUSTION PRODUCT LIMITS
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. COAL COMBUSTION PRODUCTS LIMITS, REVIEW BOUNDARYAND COMPLIANCE BOUNDARY
TAKEN FROM S&ME DRAWING ( "GROUNDWATER FLOW MAP STRUCTURAL FILL", DECEMBER 12,
)BTAINED FROM NC ONE MAP GEOSPATIAL PORTALAT http://
al/catalog/raster/download.page ON OCTOBER 7, 2020. AERIAL
1, 2019.
T WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
3 3200 (NAD83).
F-�
SCALE
AlpGRAPHIC
125 0
125 250
synTerra
(IN FEET
DRAWN BY: C. WYATT
REVISED BY E.NN
CHECKED BY: K..FERRI FERRI
APPROVED BY: K. FERRI
PROJECT MANAGER: K. FERRI
DATE: 06/08/2022
DATE: 03/24/2023
DATE: 03/24/2023
DATE: 03/24/2023
DUKE
ENERGY
PROGRESS
........._.._.________
____
FIGURE 4
PORE WATER PIEZOMETER LOCATION MAP
STRUCTURAL FILL -AREA I
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
FLETCHER, NORTH CAROLINA

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
TABLES
L7
symTerra
Science & Engineering Consultants

TABLE 1
MONITORING WELL CONSTRUCTION INFORMATION
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well Name
Date
Installed
CasingNorthingEastin
Diameter
(inches)
g
Ground
Elevation
Top Of Casing
Elevation
Total Depth
of Well (bgs)
Length
of Screen (feet)
Screened Interval
(NAND 88)
Lithology of
Screened Interval
(NAD 83)
(NAVD 88)
from
to
MW-1-Al
1/4/2008
6.5
636742.78
945061.99
21096.5
2098.94
23
15
2,089
2,074
Saprolite
MW-1A-A1
10/6/2009
2
636559.68
944943.83
2,097.7
2,100.4
20
15
2,093
2,078
Saprolite
MW-2A-Al�
10/6/2009
2
636617.12
945291.16
2,099.9
2,102.71
15
10
2,095
2,085
Saprolite
MW-4A-Al
10/7/2009
2
635188.59
944975.13
2,149.1
2,151.55
45
15
2,119
2,104
Saprolite/PWR
MW-5-Al
10/7/2009
2
636320.32
944677.45
2,152
2,153.86
57
15
2,110
2,095
Saprolite
MW-6-Al
8/14/2018
2
636581.93
945096.41
2,102.83
2,103.13
20
10
2,093
2,083
Saprolite
MW-7-Al
8/14/2018
2
636504.84
945718.42
2,123.33
2,123.62
20
10
2,113
2,103
Saprolite
MW-8-Al
8/14/2018
2
636237.93
945850.91
2,142.29
2,142.59
25
10
2,127
2,117
Saprolite
MW-9-Al
8/14/2018
2
635681.19
946058.68
2,163.2
2,163.53
31.5
10
2,142
2,132
Saprolite
MW-1-A3
11/25/2013
2
634037.84
943846.89
2,159.54
2,162.42
57.5
15
2,117
2,102
PWR
MW-2-A3
12/11/2013
2
634848.88
943520.52
2,144.6
2,147.13
62.9
15
2,097
2,082
Saprolite/PWR
MW-3-A3
12/2/2013
2
635548.38
943337.34
2,138
2,140.98
64.7
15
2,088
2,073
Saprolite/PWR
MW-4-A3
12/13/2013
2
636014.4
943105.17
2,115.4
2,117.64
33.7
10
2,092
2,082
Saprolite/PWR
MW-5-A3
12/3/2013
2
636531.67
943234.27
2,120.6
2,123.16
62.4
15
2,073
2,058
Saprolite/PWR
MW-6-A3
12/4/2013
2
636734.52
943257.5
2,127.8
2,130.44
66.7
15
2,076
2,061
Saprolite/PWR
MW-7-A3
12/2/2013
2
637022.38
943192.53
2,119
2,121.54
67.5
15
2,067
2,052
Saprolite/PWR
MW-1AR-A4A
9/18/2015
2
631447.90
944679.90
2,131.2
2,133.72
60.2
10
2,081
2,071
PWR
MW-1AR-A411
6/21/2022
2
631602.17
944673.98
2,136.65
2,136.59
33
10
2,114
2,104
PWR
MW-2-A4
12/8/2009
2
629920.28
944436.9
2,074.6
2,076.56
30
20
2,065
2,045
Saprolite
MW-5-A4
12/8/2009
2
629395.45
944832.59
2,066.3
2,068.31
25
15
2,056
2,041
Saprolite
MW-5D-A4
4/2/2012
2
629386.39
944842.05
2,067.1
2,071.47
71.5
10
2,006
1,996
PWR
MW-6-A4
7/2/2010
2
628967.08
945202.85
2,071
2,074.01
30
15
2,056
2,041
Saprolite
MW-7-A4
7/2/2010
2
628489.87
945512.01
2,068.4
2,071.37
30
15
2,053
2,038
Saprolite
MW-9-A4
1 3/29/2012
1 2
627830.32
945932.12
2,065
2,069.01
104.9
10
1,972
1,962
PWR
Notes:
* - Monitoring well used for water level measurements only.
A - Monitoring well abandoned August 2022 and replaced with MW-IAR-A4R.
NAD 83 - North American Datum of 1983
NAVD 88 - North American Vertical Datum of 1988
bgs - below ground surface
PWR - partially weathered rock
Information on this table provided by Duke Energy Progress, LLC.
Prepared by: KHF Checked by: TAH
Page 1 of 1

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B Standards,
ISTV, and USEPA Criteria for
Surface Water
SW-2-Al1
SW-3-Al
SW-46-A1
SW-4C-Al2
SW-5-Al
SW-6-Al3
SW-8-Al 3
SW-9-Al
pH
320
S.U.
6.6
6.5
6.1
NS
6.2
NS
NS
6.4
NE
6.0 - 9.0
Temperature
325
Deg C
11
7
10
NS
7
NS
NS
12
NE
<_ 29
Specific Conductance
323
µmhos/cm
218
193
202
NS
271
NS
NS
226
NE
NE
Dissolved Oxygen
-
mg/L
9.18
10.65
7.94
NS
7.40
NS
NS
9.54
NE
>_ 4
Oxidation Reduction Potential
336
mV
247
265
254
NS
238
NS
NS
291
NE
NE
Turbidity
330
NTUs
7.1
40.1
44.1
NS
57.2
NS
NS
20.4
NE
<_ 50
Alkalinity
337
mg/L
11.1
16.4
28
NS
48.3
NS
NS
16.5
1.7
NE
Aluminum
-
µg/L
80
1980
83
NS
1240
NS
NS
1180
0.003
NE
Aluminum (Dissolved)
-
µg/L
43
291
43
NS
62
NS
NS
342
0.003
NE
Antimony
13
µg/L
<0.104
<0.104
<0.104
NS
<0.104
NS
NS
<0.104
0.104
5,300#
Antimony (Dissolved)
-
µg/L
<0.104
<0.104
<0.104
NS
<0.104
NS
NS
0.15 J
0.104
NE
Arsenic
14
µg/L
< 0.111
0.272 J
0.264 J
NS
4.87
NS
NS
0.156 J
0.111
10
Arsenic (Dissolved)
-
µg/L
< 0.111
0.147 J
0.126 J
NS
1.91
NS
NS
< 0.111
0.111
340'
Barium
15
µg/L
55
40
25
NS
220
NS
NS
44
2
21,000$
Barium (Dissolved)
-
µg/L
54
35
25
NS
161
NS
NS
39
2
NE
Beryllium
23
µg/L
< 0.249
< 0.249
< 0.249
NS
< 0.249
NS
NS
< 0.249
0.249
NE
Beryllium (Dissolved)
-
µg/L
< 0.249
< 0.249
< 0.249
NS
< 0.249
NS
NS
< 0.249
0.249
65'
Bicarbonate Alkalinity
347
mg/L
11.1
16.4
28
NS
48.3
NS
NS
16.5
5.0
NE
Boron
428
µg/L
7 J
19 J
146
NS
20 J
NS
NS
10 J
5
34,000#
Boron (Dissolved)
-
µg/L
8 J
20 J
153
NS
22 J
NS
NS
14 J
5
NE
Cadmium
34
µg/L
0.098 J
0.036 J
< 0.032
NS
0.032 J
NS
NS
< 0.032
0.032
NE
Cadmium (Dissolved)
-
µg/L
0.042 J
< 0.032
< 0.032
NS
< 0.032
NS
NS
< 0.032
0.032
0.75^'t
Calcium
375
mg/L
7.09
7.9
8.76
NS
13.5
NS
NS
8.43
0.012
NE
Calcium (Dissolved)
348
mg/L
7.82
8.86
9.54
NS
14.3
NS
NS
9.08
0.012
NE
Carbonate Alkalinity
301
mg/L
<1.7
<1.7
<1.7
NS
<1.7
NS
NS
<1.7
1.7
NE
Chloride
51
mg/L
16
11
3.3
NS
6.4
NS
NS
12
0.0154
230
Chromium
53
µg/L
0.214 J
1.18
0.378 J
NS
0.76 J
NS
NS
0.782 J
0.185
NE
Chromium (Dissolved)
-
µg/L
0.27 J
0.363 J
0.354 J
NS
0.192 J
NS
NS
0.361 J
0.185
183'' x
Cobalt
54
µg/L
0.322 J
1.4
1.4
NS
23.7
NS
NS
1.31
0.077
4$
Page 1 of 3

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B Standards,
ISTV, and USEPA Criteria for
Surface Water
SW-2-Al1
SW-3-Al
SW-46-A1
SW-4C-Al2
SW-5-Al
SW-6-Al3
SW-8-Al 3
SW-9-Al
Cobalt (Dissolved)
µg/L
0.324 J
1.21
1.24
NS
15.9
NS
NS
1.04
0.077
NE
Copper
-
µg/L
<1
11
<1
NS
<1
NS
NS
11
1
NE
Copper (Dissolved)
µg/L
< 1
< 1
< 1
NS
< 1
NS
NS
< 1
1
3.6"t
Fluoride
-
mg/L
< 0.0479
< 0.0479
< 0.0479
NS
< 0.0479
NS
NS
< 0.0479
0.0479
1.8
Hardness (Total)
340
mg/L
29.7
31.4
39.5
NS
50.5
NS
NS
33.6
5
NE
Iron
131
µg/L
869
2090
4880
NS
18,000
NS
NS
1740
4
1,000*
Iron (Dissolved)
-
µg/L
827
684
2,110
NS
6,470
NS
NS
942
4
NE
Lead
376
µg/L
0.136 J
0.884 J
0.098 J
NS
0.616 J
NS
NS
0.634 J
0.037
NE
Lead (Dissolved)
-
µg/L
0.056 J
0.159 J
0.042 J
NS
0.092 J
NS
NS
0.207 J
0.037
13.9^'t
Magnesium
342
mg/L
2.90
2.83
4.27
NS
4.09
NS
NS
3.04
0.008
NE
Magnesium (Dissolved)
-
mg/L
3.19
3.09
4.66
NS
4.42
NS
NS
3.26
0.008
NE
Manganese
132
µg/L
162
242
601
NS
5,380
NS
NS
286
1
100*
Manganese (Dissolved)
335
µg/L
168
285
587
NS
4,130
NS
NS
296
1
NE
Mercury
397
µg/L
0.02 J
0.02 J
0.011
NS
0.02 J
NS
NS
0.02 J
0.01
0.012
Mercury (Dissolved)
-
µg/L
0.011
0.011
0.011
NS
0.02 J
NS
NS
0.02 J
0.01
NE
Molybdenum
152
µg/L
< 0.18
< 0.18
< 0.18
NS
1.28
NS
NS
<0.18
0.18
2,000$
Molybdenum (Dissolved)
-
µg/L
<0.18
<0.18
< 0.18
NS
0.286 J
NS
NS
< 0.18
0.18
NE
Nickel
377
µg/L
0.38 J
0.945 J
0.332 J
NS
1.54
NS
NS
0.92 J
0.256
NE
Nickel (Dissolved)
-
µg/L
0.478 J
0.671 J
0.397 J
NS
1.22
NS
NS
0.792 J
0.256
145^'t
Potassium
183
mg/L
1.51
1.61
1.34
NS
2.34
NS
NS
1.7
0.031
NE
Potassium (Dissolved)
-
mg/L
1.61
1.62
1.42
NS
2.38
NS
NS
1.68
0.031
NE
Selenium
322
µg/L
<0.193
0.384 J
1.57
NS
0.246 J
NS
NS
<0.193
0.193
NE
Selenium (Dissolved)
-
µg/L
< 0.193
0.261 J
1.56
NS
< 0.193
NS
NS
< 0.193
0.193
3.1&
Sodium
mg/L
6.95
5.08
2.69
NS
1.69
NS
NS
5.84
0.017
NE
Sodium (Dissolved)
-
mg/L
6.91
5.23
2.86
NS
1.85
NS
NS
5.81
0.017
NE
Strontium
315
µg/L
59
52
69
NS
181
NS
NS
48
1
40,000#
Strontium (Dissolved)
-
µg/L
62
57
74
NS
182
NS
NS
50
1
NE
Sulfate
194
mg/L
2.4
5.3
13
NS
3.3
NS
NS
5.5
0.0428
NE
Thallium
311
µg/L
0.135 J
0.166 J
0.147 J
NS
0.178 J
NS
NS
0.102 J
0.041
2$
Page 2 of 3

TABLE 2
SURFACE WATER FIELD AND ANALYTICAL RESULTS
STRUCTURAL FILL AREAS 1, 3, AND 4
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
SWS ID
Units
Area 1 Surface Water Sample Locations
MDL
15A NCAC 02B Standards,
ISTV, and USEPA Criteria for
Surface Water
SW-2-Al1
SW-3-Al
SW-46-Al
SW-4C-Al2
SW-5-Al
SW-6-Al 3
SW-8-Al 3
SW-9-Al
Thallium (Dissolved)
-
µg/L
0.09 J
0.144 J
0.109 J
NS
0.131 J
NS
NS
0.084 J
0.041
NE
Total Dissolved Solids
343
mg/L
62
62
58
NS
60
NS
NS
61
25
NE
Total Suspended Solids
209
mg/L
<2.5
22.8
11.4
NS
24
NS
NS
13.9
2.5
NE
Vanadium
213
µg/L
<0.144
2.11
0.13 J
NS
1.60
NS
NS
1.08
0.114
NE
Vanadium (Dissolved)
-
µg/L
< 0.114
0.285 J
< 0.114
NS
< 0.114
NS
NS
0.262 J
0.114
NE
Zinc
-
µg/L
6
8
4 J
NS
8
NS
NS
9
4
NE
Zinc (Dissolved)
-
µg/L
5
7
<4
NS
9
NS
NS
10
4
36.2^'t
Notes:
Samples collected January 26, 2023.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 03/16/2023.
January 2023 data represent a one-time, single sample; therefore, compliance with either the acute or chronic 02B standards for dissolved constituents presented in 15A NCAC 02B .0211 (11)(e) cannot be determined.
Bold concentrations are equal to or greater than the 15A NCAC 02B Standard (for pH bold indicates a measurement less than or greater than the indicated range).
The analytical method for mercury analysis has a reporting limit that is greater than the 02B criteria.
15A NCAC 02B Standards for Surface Water - 15A NCAC 02B Standards for Class C surface waters. North Carolina surface water and wetland standards (effective September 1, 2022).
ISTV for Surface Water - In -stream target values established per 15A NCAC 02B .0202 and .0208.
USEPA Criteria for Surface Water - U.S. Environmental Protection Agency National Recommended Water Quality Criteria
For 15A NCAC 02B Standards and ISTVs with acute and chronic criteria, the acute criteria are considered more applicable to grab sampling; therefore, those values are presented.
$ - An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity. Comparison value presented is the lesser of the Aquatic Life & Secondary Recreation or Fish Consumption value.
ISTV is based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method. An exceedance of a published ISTV is not automatically a violation of the water quality standard for toxicity.
USEPA National Recommended Water Quality Criteria are not a regulation, nor do they impose a legally -binding requirement. Therefore, comparisons with these criteria are for situational context.
Comparison criteria based on acute sampling method described in 15A NCAC 02B (11)(e). Compliance with acute instream standard is not applicable to sampling method and provided for screening purposes only.
t - Hardness -dependent standard calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
"- Hardness -dependent standard for chromium III calculated using 25 mg/L hardness and not actual in -stream hardness value. Provided for screening purposes only.
&- Selenium standard for lotic water based on a 30-day average. Not applicable to the sampling method and provided for screening purposes only.
Total Hardness calculation = 2.497 (calcium) +4.118 (magnesium)
' - Surface water sample location SW-2-Al is an approved background monitoring location.
Z - Surface water sample location SW-4C-A1 was not sampled due to dry conditions.
s - Surface water sample locations SW-6-Al and SW-8-Al are inactive and were not sampled.
J - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
MDL- Laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L- milligrams per liter
mV - millivolts
NCAC - North Carolina Administrative Code
NE - not established
NS - not sampled
NTU - Nephelometric turbidity unit
S.U. - standard units
Prepared by: EMH Checked by: DFC KHF
Page 3 of 3

TABLE 3
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED SURFACE WATER QUALITY STANDARDS
STRUCTURAL FILL AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Parameter
Sample ID
Result
Units
15A NCAC
026
Standard
Site
Background
Concentration
Cause and Significance
Range
SW-3-Al
0.02 J
Mercury
µg/l-
0.012
<0.02 - 0.276
Within Site background concentration ranges - naturally occurring.
SW-5-Al
0.02 J
SW-9-Al
0.02 J
Turbidity
SW-5-Al
57.2
NTUs
<_ 50
0.60 - 34.1
First identified turbidity exceedance at this location. Continue monitoring.
Notes:
The analytical method for mercury analysis has a reporting limit that is greater than the 02B criteria.
15A NCAC 02B Standards for Class B surface waters - North Carolina surface water and wetland standards (effective July 26, 2021).
Background ranges are based on data from approved background surface water monitoring location SW-2-Al through January 2023.
< - Concentration not detected at or greater than the adjusted reporting limit.
°C - degrees Celsius
J - Estimated concentrations equal to or greater than the method detection limits but less than the laboratory's method reporting limit.
µg/L - micrograms per liter
mg/L - milligrams per liter
NCAC - North Carolina Administrative Code
S.U. - standard units
Prepared by: EMH Checked by: DFC
Page 1 of 1

TABLE 4
PORE WATER PIEZOMETER WATER LEVELS
STRUCTURAL FILL - AREA 1
QUARTERLY WATER QUALITY MONITORING REPORT
JANUARY 2023 SAMPLING EVENT
GREATER ASHEVILLE REGIONAL AIRPORT AUTHORITY
DUKE ENERGY PROGRESS, LLC, FLETCHER, NC
Well ID
Associated Unit
Date
Depth to Water
(Ft-BTOC)
PZ-1
Area 1
3/28/2023
25.20
PZ-2
Area 1
3/28/2023
32.40
PZ-2S
Area 1
3/28/2023
29.79
PZ-3
Area 1
3/28/2023
28.68
PZ-3D
Area 1
3/28/2023
24.75
PZ-4
Area 1
3/28/2023
27.05
PZ-5
Area 1
3/28/2023
5.30
PZ-6
Area 1
3/28/2023
6.02
PZ-7
Area 1
3/28/2023
24.00
Notes:
Pore water -levels collected by SynTerra personnel.
Pore water -levels collected in March 2023 are intended to represent conditions during Q1 2023.
ft - feet
BTCC - below top of casing
NM - not measured
Prepared by: KHF Checked by: EMH
Page 1 of 1

Quarterly Water Quality Monitoring Report — January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX A
SURFACE WATER SAMPLING LOGS
L7
symTerra
Science & Engineering Consultants

FCAMA FCCRFLandfill FNPDES ❑ DGWF]ASW [—]LRB ❑ SPECIAL STUDY
Site: A1-4%cj4/&. %%moo Well/SW ID: SW-Z-A )
Date: I- Z6 - Z3
1mi
GROUNDWATER SAMPLE 2SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: C72- WEATHER: EISUNNY El PARTLY CLOUDY ❑OVERCAST []RAIN SNOW AIR TEMP: 30 °F'
COMPANY: DUKE ENERGY FIELD METER TYPE/ SERIAL #: K/T Sc
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 332M
START PURGE TIME: 8SKr6 SAMPLE COLLECTION TIME: 0$55
6
PUMPITUBING INTAKE DEPTH: ` (ft) DEPTH TO WATER: , 19. (ft) MULT FACTOR *: 0.163 [*(radius/12)2*3.14*7.481
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: "" (gal)
TYPE OF PUMP:.
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
/
f
SAMPLING METHOD:
i
PUMP SETTING:
P
R
°
pQyp 1/Vr0
oo� ttr�,v�
❑ Tubin /Pump Inspected (psi) (see) (sec) S
❑Good LjTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low How Sampling Stabilization Criteria
pH t 0.1 standard unit
• Specific Conductance t 5% in pS/cm
DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
{mUrnin)
(x)
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x
6$
2w
0.2v
l t
°t. 25
ZZ 2
G 2g
?tW
6.v2
0653
2w
0_uv
t t
`fi cST
2t8
4.60
2K 7
7.1
pm,rx yr 1 nla anCC 1 It- I nt UNAK I AbUVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES � NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? [:]YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?Q YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS: — —
DETECTED ODOR O�7e H2S Petroleum Earthy Musty Undetermined
IYof i
ODOR STRENGTH e Minor Strong
ADDITIONAL NOTES: APPEARANCE ear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
i
version 1.z Kevlsed 09/29/2022 HPB

F-] CAMAF—lCCR[—]Lond0 [-]NPDEGF—1 ASVVF-]LRB[—1SPECIAL STUDY,
Site: Well/SW ID: Date:
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
-(FT)
(mUmin)
(gallons OR mL)
VC)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
Version 1.0Revised uo/2n/2oouHPa

❑CAMA ❑CCRaLandfill ❑NPDES ❑ DGW❑ASW F—]LRB [:] SPECIAL STUDY
DUKE
EVERM
Site: Ashml�, ,rfwt Well/SW ID: Stu- 3 -q Date: 1-26-n
El GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: GiZ
COMPANY: n DUKE ENERGY
❑ OTHER:
WEATHER:
[—]SUNNY [�IPARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIRTEMP: `fb -F
FIELD METER TYPE/ SERIAL #: %JIM
TURBIDIMETER TYPE/ SERIALM 33241
START PURGE TIME: (USJ SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: - (ft) DEPTH TO WATER: (n) MULT FACTOR *: 0.163 ["(radius/12)2"3.14'7.48j
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
6MIS
❑ Tubing/Pump /Pump Inspected (Ps) (sec) (sec) Low Flow Sampling Stabilization Criteria
❑Good [Tubing Bad []Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
Additional Notes: Specific Conductance t 5% in [1S/cm
• DO f 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Ms
--
--
-
I
q•V(%
Zut
6•SZ
2Zv
`f2.5
to 5c
7
0•65
1 113
' 6
1ZGS
Yo. t
1'LLASt KtFtK. I U I Ht 5AGK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR �" 1-12S Petroleum aOr y Musty Undetermined
ODOR STRENGTH None in r Strong
ADDITIONAL NOTES: APPEARANCE Clear LJ Turbid Red/Iron Film on Surface Sheen as Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HP13

[:]CAMA F-]CCR [—]Landfill F-]NPDES ❑ DGW❑ASW [-]LRB ❑ SPECIAL STUDY
Site:
WATER
TIME LEVEL
(FT)
Well/SW ID:
FLOW
VOLUME
RATE
REMOVED
nL/min)
(gallons OR mL)
W
(x.xx)
TEMPERATURE DO
VC) (mg/L)
(x) (x.xx)
Date:
SPECIFIC
CONDUCTANCE PH
(PS/cm) (su)
III
ORP TURBIDITY
(mv) (NTU)
(x) (x.x)
Version 1.2 Revised 09/29/2022 HPB

CAMA CCR 0 Landfill NPDES ❑ DGW❑ ASW ❑ LRB ❑ SPECIAL STUDY,
Site: Ask ewlz AgLA
Well/SW ID: SW -Ng -Ai
Date: I-Z6-2?
o
m
GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑WELL DEVELOPMENT
FIELD STAFF: 07, WEATHER: []SUNNY QPARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIR TEMP: k0 °F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL M 9f/9g
❑ OTHER: TURBIDI METER TYPE/ SERIAL M 332'1
START PURGE TIME: Ogg? SAMPLE COLLECTION TIME: OqS
PUMPITUBING INTAKE DEPTH: _ (ft) DEPTH TO WATER: (ft) MULT FACTOR*: 0.163 [*(radius/12)2*3,14*7:a8i
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: - (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
i
SAMPLING METHOD:
PUMP SETTING:
°
R
D
03
❑ Tubin /Pump Inspected I (psi) I (sec) I (sec) I Low Flow Sampling Stabilization Criteria
❑Good Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
Additional Notes: • Specific Conductance t 5% in pS/cm
• DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/Cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
0951
-
-
-
to
?fir
Zlr"."1
6.t ?
Zr/
3g.
7cN
Zo2
6.tq
ty.(
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15"MINUTES? ❑ YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES' ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑ YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None H2S Petroleum X.rth Musty Undetermined
ODOR STRENGTH None ino Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid R d/I Film on Surface Sheen in Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

❑ CAMA CCR ❑ Landfill ❑ NPDES 7 DGW7 ASW ❑ LRB ❑ SPECIAL STUDY,
Site:
WATER FLOW
TIME LEVEL RATE
(FT) (mUmin)
Well/SW ID:
Date:
MR
VOLUME TEMPERATURE DO SPECIFIC pH ORP TURBIDITY
REMOVED CONDUCTANCE
(gallons OR mL) (°C) (mg/L) (PS/cm) (su) (mv) (NTU)
(x.xx) (x) (x.xx) (x) (x.xx) (x) (x.x)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR Landfill F—]NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: 049w& ArPak Well/SW ID: Sk)- VC - 41
Date: /-26-23
o
m
GROUNDWATER SAMPLEFX]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 0L WEATHER: []SUNNYPARTLY CLOUDY ❑OVERCAST ❑RAIN nSNOW AIR TEMP: aft °F
COMPANY: © DUKE ENERGY FIELD METER TYPE/ SERIAL #: ysl�$Ti
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3324
START PURGE TIME: 0(i ILI[5 SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR*: 0.163 ['(radius/12)2"3.14'7.481
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
i
PUMP SETTING:
P
R
LJ Tubin /Pump Inspected (psi)I (sec) I (sec) I Low Flow Sampling Stabilization Criteria
❑Good [Tubing Bad []Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
Additional Notes: Specific Conductance t 5%in pS1crn
�/J DO f 0.2 mg/L or 10% saturation
►` Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL /min)
(x)
(gallons OR mL)
(x.xx)
CC)
(x)
(mg/L)
(x.xx
(PS/CM)
(x)
(su)
(x.xx)
(mv )
(x)
(NTU)
(x.x)
r6CAJr KtYttc I U I Ht t$AUK UI- I His SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES [:]NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE'
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[]CAMA F]CCRF—]Landfiill F—]NPDES ❑ DGW❑ASW F�LRB ❑ SPECIAL STUDY
Site:
Well/SW ID:
DUKE
E �
Date:
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
TIME
LEVEL
RATE
REMOVED
CONDUCTANCE
(FT)
(mUmin)
(gallons OR mL)
(°C)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x:xx)
W
(x.xx)
W
(x.xx)
W
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCR FLandfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: Ash VAr Agcwl Well/SW ID: SG✓- 5-Ai
MM
Date: dl•Z6-23
UGROUNDWATER SAMPLE ❑X SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 672- WEATHER: []SUNNY ❑PARTLY CLOUDY ❑OVERCAST []RAIN []SNOW AIR TEMP: qO "F
COMPANY: Q DUKE ENERGY FIELD METER TYPE/ SERIAL #:
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3324
START PURGE TIME: IbSo
SAMPLE COLLECTION TIME: I n
PUMPITUBING INTAKE DEPTH: '" (ft) DEPTH TO WATER: R MULT FACTOR *: 0.163 [•(radius/12)2"3.14"7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (tt) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
❑ Tubin /Pump Inspected (Psi) (see) (see)
❑Good []Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event
Additional Notes:
Low Flow Sampling Stabilization Criteria
pH f 0.1 standard unit
Specific Conductance t 5% in pS/cm
DO 10.2 mg/L or 10% saturation
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
)o2S
-
-
to
�102
Zblr
b.�to
2a'L
(�.t
tolii
—
7.Nd
271
�.Zr
2 y
S ,Z
rLrA0M Kr1-r c IV I Ht bAGK OF I HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[:] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[-] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None H2S Petroleum ar Musty Undetermined
ODOR STRENGTH None in Strong
ADDITIONAL NOTES: APPEARANCE Clear g%-L)d) Turbid Red/iron Film on Surface Sheen tfi n'ts Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
I GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

F-]CAMA F-]CCRFjLandfiII F�NPDES ❑ DGW7ASW F-]LRB SPECIAL STUDY.
Site:
WATER
TIME LEVEL
(FT)
Well/SW ID:
FLOW
VOLUME
RATE
REMOVED
(mL/min)
(gallons OR mL)
TEMPERATURE DO
(°C) (mg/L)
Date:
SPECIFIC pH
CONDUCTANCE
(PS/cm) (su
N (x.x)
ORP TURBIDITY
(mv) (NTU)
Version 1.2 Revised 09/29/2022 HPB

❑CAMA ❑CCRLandfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG DUKE
" .' ENE
Site: Asia, i; As%rG Well/SW ID: Sk/- 6 - A l Date: 61- 26-Z3
GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 2. WEATHER: ❑SUNNY ❑PARTLY CLOUDY ❑ OVERCAST ❑ RAIN RSNOW AIR TEMP: kV °F
COMPANY: FTDUKE ENERGY FIELD METER TYPE/ SERIAL #: 9 lK
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 332m
START PURGE TIME: _ INS SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: -• (ft) DEPTH TO WATER: — (ft) MULT FACTOR *: 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: _ (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
RI
11
❑ Tubing/Pump Inspected I (Si) I (see) I (5n) I Low Flow. Sampling Stabilization Criteria
❑Good HTubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event PH t 0.1 standard unit
Additional Notes: G' Spec[fic Conductance f 5% in pS/cm
8e5TRoYt:d St)MPL(N6' SP 1 DO t 0.2 mg/L or 10% saturation
A!O SAIKPa Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/Cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
rLrAW: Ktrth( I U I Ht t$AL;K UI- I Hlb bHEE 1 IF THE CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[::]CAMA [—]CCR❑Landfill F]NPDES ❑ DGWFASW F�LRB ❑ SPECIAL STUDY,
Site: Well/SW ID:.
DUKE
ENERM
Date:
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mL/min)
(gallons OR mL)
VC)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
W
(x.xx)
W
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑ CAMA CCR F,] Landfill ❑ NPDES ❑ DGW ❑ ASW ❑ LRB ❑ SPECIAL STUDY.
Site: A56i, - 4rpgt
Well/SW ID: 5k/-6-A i
Date: ►-26-�3
MR
GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G)I- WEATHER
COMPANY: Q DUKE ENERGY
❑ OTHER:
❑SUNNY ❑PARTLY CLOUDY ❑OVERCAST El RAIN SNOW AIR TEMP: 0 `F
FIELD METER TYPE/ SERIAL #: SS &
TURBIDIMETER TYPE/ SERIAL M 331A
START PURGE TIME: l(40 SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: ' (ft) MULT FACTOR ": 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: — (ft) WELL VOLUME: — (gal)
WELL DEPTH: _ (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
a
a
o
U Tubing/Pump /Pump Inspected I (psi) I (see) I (see) I Low How Sampling Stabilization Criteria
❑Good [Tubing Bad ❑Pump Bad ❑Changed/Cleaned ❑Correct Next Event pH f 0.1 standard unit
Additional Notes: aE5-rg*%j6b SAM17WN6 510, Specific Conductance t 5%e in NS/cm
• DO t 0.2 mg/L or 10% saturation
NO SPA PU Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
(-C)
(x)
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
rLtASt. KtrtK I U I tit UAGK OF I H15 SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[-] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN; WITHIN 15%0? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLEOBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.2 Revised 09/29/2022 HPB

[—]CAMA [—]CCR❑Landfill F-]NPDES ❑ DGW❑ASW F-]LRB 7 SPECIAL STUDY.
itP
WATER
TIME LEVEL
(FT)
Well/SW ID:
FLOW
VOLUME
RATE
REMOVED
(mUmin)
(gallons OR mL)
W
(x.xx)
TEMPERATURE DO
(°C) (m9/L)
(x) (x.xx)
Date:
SPECIFIC H
CONDUCTANCE P
(PS/cm) (su)
W (x.xx)
ORP TURBIDITY
(mv) (NTU)
(x) (x.x)
Version 1.2 Revised 09/29/2022 HPB

[:]CAMA ❑CCRF_�Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
Site: AskcA Well/SW ID: Sw-q-Ai
Date: i-Zg-23
❑GROUNDWATER SAMPLE SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G72-
COMPANY: DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY 2PARTLYCLOUDY ❑OVERCAST ❑RAIN SNOW AIRTEMP: ff °F
FIELD METER TYPE/ SERIAL #: 0
TURBIDI METER TYPE/ SERIALM 33IR
START PURGE TIME: 036 SAMPLE COLLECTION TIME: bq t-t(b
PUMPITUBING INTAKE DEPTH: - (ft) DEPTH TO WATER: (ft) 0.163
MULT FACTOR *•
.. ["( adius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: - (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
GPAS
PUMP SETTING:
❑ Tubin /Pump Inspected (Psi)
❑Good []Tubing Bad []Pump Bad ❑Changed/Cleaned [-]Correct Next Event
Additional Notes:
LOW glow Sampling Stabilization Criteria
pH f 0.1 standard unit
• Specific Conductance f 5% in pS/cm
DO t 0.2 mg/L or 10% saturation
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
0 3
(FT)
(x.xx)
(mL/min)
(x)
—
(gallons OR mL)
(x.xx)
—
(°C)
W
�2
(mglL)
(x.xx)
9.Y3
(NS/cm)
W
Z2L
(su)
(x.xx)
GSz
(mv)
W
Z83
(NTU)
(x.x
cr;.�
L.Lcrcrl 1 v 1 nc Dm�,r% yr 1 rug arftt 1 Ir 1 Ht UHAH I ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? OYES NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ [:1NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE?[] ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1­12S Petroleum �Ta by Musty Undetermined
ODOR STRENGTH None Or Strong
ADDITIONAL NOTES: APPEARANCE le Cloudy Turbid Red/iron Film on Surface Sheen in Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
I NONE
GOOD
BAD
NONE
version 1.2 Revised 09/29/2022 HPB

[—]CAMA 7CCR Landfill [—]NPDES ❑ DGW❑ASW 7LRB ❑ SPECIAL STUDY.
Site:
Well/SW ID:
Date:
a
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mL/min)
(gallons OR mL)
VC)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
W
(x.xx)
W
(x.xx)
(x)
(x.x)
Version 1.2 Revised 09/29/2022 HPB

❑LAMA ❑CCRaLandfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
DAILY CALIBRATION LOG
Site: 454 Dater I-Z4-S3
FIELD PERSONNEL: C12_
WEATHER: ❑< SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW TEMPERATURE (APPROX):
INSITU SERIAL#: g5,198% 3S'F
21000 SERIAL M 33Z4
H
Time: 5Mv
Lot Number
Expiration
Buffer
Temperature
(°C)
Chart
pH
(su)
Meter
Reading
(su)
Within ±
0.1° su?
7.00 su
Z13013
oY-3ti-23
l3. do
7•65
70 ss
N
10,01 su
Z47370
03-31 -Z3
10.11
to. 11
f0,16
60 N
4.01 su
I 2I4220
o6-3o-Z3
(6•03
3etq
K.03
` N
Check of 7.00 su as Live Reading
g13t�13
oy-3o-23
l2,ffp
� o c)
N
/-ZG-23
Post Calibration- Date: Time: 11 ZS
Within ±
0.2 su?
7.00 su
Z13o13
0y-30-23
10•io
'7(,-7
10.01 su
207370
03-31-13
11.8o
to.IK
(0.2t
N
4.01 su
214Z2o
06-30-Z3
Specific Conductivity
Buffer
Meter
Within ±
Time: 6�535
Lot Number
Expiration
Temperature (°C)
Reading (Ns)
10%?
Standard Value: 72o Ns
E / 7Z 1 !3
oS • o I - Z3
7 (U
"�Z� , (
N
Calibration Check of
Z27 GIs as Live Reading
L 2321 C
it -ol -Z3
Zg
Z ZZ,
N
Post Calibration- Date: _ 1-2r- `23 Time: 11 t
710 Ns
' nZ16
$-1-23
q.aG
723.0
60 N
ORP
Buffer
Adjusted
Meter
Time: db'?'S
Lot Number
Expiration
Temperature
Value
Reading
Within ±
20%?
(QC)
(mV)
(mV)
42q mV
222L!
o z -30-z 3
6.JL
tit�4. 6
'.t '73.1
Of N
Post Calibration- Date: 1-ZG-23
Time: NHS
4-Zj mV
2Z2�i
o2-3o-23
fte 7[o
W6�.N
u 65•g
c41 N
Revised 12118/201'8 KKH

F-�CAMA F-]CCROLandfiII F-]NPDES ❑ DGW❑ASW F-ILRB ❑ SPECIAL STUDY
DU KE
ENERGY
DAILY CALIBRATION LOG
Site: ASA Date: Field Personnel 01
Barometric
Meter
Dissolved Oxygen
Temperature
Pressure
Chart DO
Reading.
%u Saturation
Within t 0.5?
Time:
(CC)
(mg/L)
(%Sat)
(mmHg)
(mg/L)
bb�t�
01
70Yo1
N
Calibration Check as Live
G .
O-L &
t �. $
t +• 6 K
t O Z•BF i;
N
Reading
Post Calibration -
Date: I-'X14
I1.a�
7uN.lZ
Io.3
10-U
CY N
Time: 03o
Acceptance
Meter Reading
Within �
Turbidity
Standard (NTU)
Range (NTU)
(NTU)
5%?
Time: 0 (sew
10.0
t 0.5
-
(6.0
Y N
Post Calibration -
Date: l.u'Z
10.0
0.5
10,0
N
Time: 050
Daily Turbidity Meter BLANK
DI Water (NTU)
Less than 0.10 NTU?
Date: I' u
N
D.oK
Time: 08uo
Revised 12/18/2018 KKH

Quarterly Water Quality Monitoring Report —January 2023 Sampling Event
Greater Asheville Regional Airport Authority - Duke Energy Progress, LLC
Fletcher, North Carolina
APPENDIX B
SURFACE WATER LABORATORY ANALYTICAL REPORTS
L7
synTerra
Science & Engineering Consultants

DUE Analytical Laboratory Page 1of58
ENERGY
Y
Order Number:
Project Name:
Task Code:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J23010300
ASHEVILLE AIRPORT - AIRPORT FILL AREA I SW - (IN-HOUSE)
STRFL
John Toepfer, B Moeller, Josh Stowe, C Zahora
Asheville Airport
Peggy Kendall
Phone: [phone]
Date:
Mdall
Please contact the Program Manager (Peggy Kendall) with any questions regarding this report.
Data Flags & Calculations:
2/13/2023
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions: Page 2 of 58
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2023001342
Asheville Airport
26-Jan-23
8:55 AM
Connor Zahora
ASA_SW-2-A1
2023001343
Asheville Airport
26-Jan-23
11:00 AM
Connor Zahora
ASA_SW-3-A1
2023001344
Asheville Airport
26-Jan-23
9:55 AM
Connor Zahora
ASA_SW-413-A1
2023001346
Asheville Airport
26-Jan-23
10:30 AM
Connor Zahora
ASA_SW-5-A1
2023001349
Asheville Airport
26-Jan-23
9:40 AM
Connor Zahora
ASA_SW-9-A1
2023001350
Asheville Airport
26-Jan-23
9:45 AM
Connor Zahora
ASA_FtB-20230126-0945
2023001351
Asheville Airport
26-Jan-23
9:50 AM
Connor Zahora
ASA_EB-20230126-0950
2023001352
Asheville Airport
26-Jan-23
9:55 AM
Connor Zahora
ASA_FB-20230126-0955
8 Total Samples

Page 3 of 58
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 2/13/2023

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-2-A1
Collection Date: 01/26/2023 08:55 AM Loc code: ASA SW-2-A1
Sample #: 2023001342
Matrix: GW RCRA
Page 4 of 58
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q23020073
Alkalinity, Bicarbonate
11.1
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:25
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:25
SNEGLIA
Total Alkalinity as CaCO3
11.1
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:25
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
16
mg/L
0.5
0.0154
5
EPA 9056A
01/31/2023 18:33
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 18:33
BGN9034
Sulfate
2.4
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 18:33
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 13:37
JAA5429
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:03
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.043
mg/L
0.01
0.003
1
SW 601OD
02/01/2023 11:15
CELL106
Barium (Ba)
0.054
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:15
CELL106
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:15
CELL106
Calcium (Ca)
7.82
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:15
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:15
CELL106
Iron (Fe)
0.827
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:15
CELL106
Magnesium (Mg)
3.19
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:15
CELL106
Manganese (Mn)
0.168
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:15
CELL106
Potassium (K)
1.61
mg/L
0.1
0.031
1
SW 601OD
02/01/2023 11:15
CELL106
Sodium (Na)
6.91
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:15
CELL106
Strontium (Sr)
0.062
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:15
CELL106
Zinc (Zn)
0.005
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:15
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-2-A1
Collection Date: 01/26/2023 08:55 AM Loc code: ASA SW-2-A1
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
0.080
mg/L
0.01
0.003
Barium (Ba)
0.055
mg/L
0.005
0.002
Boron (B)
0.007 J
mg/L
0.05
0.005
Calcium (Ca)
7.09
mg/L
0.05
0.012
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.869
mg/L
0.01
0.004
Magnesium (Mg)
2.90
mg/L
0.02
0.008
Manganese (Mn)
0.162
mg/L
0.005
0.001
Potassium (K)
1.51
mg/L
0.1
0.031
Sodium (Na)
6.95
mg/L
0.05
0.017
Strontium (Sr)
0.059
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
29.7
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.006
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.111 U
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.042 J
ug/L
1
0.032
Chromium (Cr)
0.27 J
ug/L
1
0.185
Cobalt (Co)
0.324 J
ug/L
1
0.077
Lead (Pb)
0.056 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.478 J
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.09 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Page 5 of 58
Sample #:
2023001342
Matrix:
GW RCRA
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 601OD
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1
SW 601OD
02/03/2023 10:26
MHALL3
1
SW 601OD
02/03/2023 10:26
MHALL3
1
SW 6010D
02/03/2023 10:26
MHALL3
1 SW 6010D
02/03/2023 10:26
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3
1 SW 6020B
01/31/2023 23:51
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-2-A1
Collection Date: 01/26/2023 08:55 AM Loc code: ASA SW-2-A1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.098 J
ug/L
1
0.032
1
Chromium (Cr)
0.214 J
ug/L
1
0.185
1
Cobalt (Co)
0.322 J
ug/L
1
0.077
1
Lead (Pb)
0.136 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.38 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.135 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL SUSPENDED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
Sample #: 2023001342
Matrix: GW RCRA
Page 6 of 58
Method Analysis Date/Time Analyst
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
SW 6020B
02/01/2023
02:32
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-3-A1
Collection Date: 01/26/2023 11:00 AM Loc code: ASA SW-3-A1
Sample #: 2023001343
Matrix: GW RCRA
Page 7 of 58
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q23020073
Alkalinity, Bicarbonate
16.4
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:32
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:32
SNEGLIA
Total Alkalinity as CaCO3
16.4
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:32
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
11
mg/L
0.5
0.0154
5
EPA 9056A
01/31/2023 19:51
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 19:51
BGN9034
Sulfate
5.3
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 19:51
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 13:39
JAA5429
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:10
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.291
mg/L
0.01
0.003
1
SW 601OD
02/01/2023 11:20
CELL106
Barium (Ba)
0.035
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:20
CELL106
Boron (B)
0.02 J
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:20
CELL106
Calcium (Ca)
8.86
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:20
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:20
CELL106
Iron (Fe)
0.684
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:20
CELL106
Magnesium (Mg)
3.09
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:20
CELL106
Manganese (Mn)
0.285
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:20
CELL106
Potassium (K)
1.62
mg/L
0.1
0.031
1
SW 601OD
02/01/2023 11:20
CELL106
Sodium (Na)
5.23
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:20
CELL106
Strontium (Sr)
0.057
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:20
CELL106
Zinc (Zn)
0.007
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:20
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-3-A1
Collection Date: 01/26/2023 11:00 AM Loc code: ASA SW-3-A1
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
1.98
mg/L
0.01
0.003
Barium (Ba)
0.040
mg/L
0.005
0.002
Boron (B)
0.019 J
mg/L
0.05
0.005
Calcium (Ca)
7.90
mg/L
0.05
0.012
Copper (Cu)
0.001 J
mg/L
0.005
0.001
Iron (Fe)
2.09
mg/L
0.01
0.004
Magnesium (Mg)
2.83
mg/L
0.02
0.008
Manganese (Mn)
0.242
mg/L
0.005
0.001
Potassium (K)
1.61
mg/L
0.1
0.031
Sodium (Na)
5.08
mg/L
0.05
0.017
Strontium (Sr)
0.052
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
31.4
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.008
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.147 J
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.363 J
ug/L
1
0.185
Cobalt (Co)
1.21
ug/L
1
0.077
Lead (Pb)
0.159 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.671 J
ug/L
1
0.256
Selenium (Se)
0.261 J
ug/L
1
0.193
Thallium (TI) Low Level
0.144 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.285 J
ug/L
0.3
0.114
Page 8 of 58
Sample #:
2023001343
Matrix:
GW RCRA
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 601OD
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1
SW 601OD
02/03/2023 10:11
MHALL3
1
SW 601OD
02/03/2023 10:11
MHALL3
1
SW 6010D
02/03/2023 10:11
MHALL3
1 SW 6010D
02/03/2023 10:11
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3
1 SW 6020B
02/01/2023 00:38
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-3-A1
Collection Date: 01/26/2023 11:00 AM Loc code: ASA SW-3-A1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.272 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.036 J
ug/L
1
0.032
1
Chromium (Cr)
1.18
ug/L
1
0.185
1
Cobalt (Co)
1.40
ug/L
1
0.077
1
Lead (Pb)
0.884 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.945 J
ug/L
1
0.256
1
Selenium (Se)
0.384 J
ug/L
1
0.193
1
Thallium (TI) Low Level
0.166 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
2.11
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL SUSPENDED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
Sample #: 2023001343
Matrix: GW RCRA
Page 9 of 58
Method Analysis Date/Time Analyst
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
SW 6020B
02/01/2023
03:19
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 10 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-4B-A1
Sample #: 2023001344
Collection Date: 01/26/2023 09:55 AM
Loc code: ASA SW-4B-A1
Matrix: GW
RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL ALKALINITY - Q23020024
Total Alkalinity as CaCO3
28.0
mg/L
5
1.7
1
SM 2320B-2011
02/01/2023 10:07
SNEGLIA
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B-2011
02/01/2023 10:07
SNEGLIA
Alkalinity, Bicarbonate
28.0
mg/L
5
1.7
1
SM 2320B-2011
02/01/2023 10:07
SNEGLIA
INORGANIC IONS BY IC - Q23010483
Chloride
3.3
mg/L
0.1
0.0154
1
EPA 9056A
01/31/2023 20:16
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 20:16
BGN9034
Sulfate
13
mg/L
0.5
0.0428
5
EPA 9056A
01/31/2023 20:16
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 13:50
JAA5429
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:12
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q23010448
Aluminum (AI)
0.043
mg/L
0.01
0.003
1
SW 601OD
02/01/2023 11:01
CELL106
Barium (Ba)
0.025
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:01
CELL106
Boron (B)
0.153
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:01
CELL106
Calcium (Ca)
9.54
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:01
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:01
CELL106
Iron (Fe)
2.11
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:01
CELL106
Magnesium (Mg)
4.66
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:01
CELL106
Manganese (Mn)
0.587
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:01
CELL106
Potassium (K)
1.42
mg/L
0.1
0.031
1
SW 601OD
02/01/2023 11:01
CELL106
Sodium (Na)
2.86
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:01
CELL106
Strontium (Sr)
0.074
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:01
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:01
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-4B-A1
Collection Date: 01/26/2023 09:55 AM Loc code: ASA SW-4B-A1
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
0.083
mg/L
0.01
0.003
Barium (Ba)
0.025
mg/L
0.005
0.002
Boron (B)
0.146
mg/L
0.05
0.005
Calcium (Ca)
8.76
mg/L
0.05
0.012
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
4.88
mg/L
0.01
0.004
Magnesium (Mg)
4.27
mg/L
0.02
0.008
Manganese (Mn)
0.601
mg/L
0.005
0.001
Potassium (K)
1.34
mg/L
0.1
0.031
Sodium (Na)
2.69
mg/L
0.05
0.017
Strontium (Sr)
0.069
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
39.5
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 J
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.126 J
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.354 J
ug/L
1
0.185
Cobalt (Co)
1.24
ug/L
1
0.077
Lead (Pb)
0.042 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.397 J
ug/L
1
0.256
Selenium (Se)
1.56
ug/L
1
0.193
Thallium (TI) Low Level
0.109 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Page 11 of 58
Sample #:
Matrix:
2023001344
GW RCRA
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 601OD
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1
SW 601OD
02/03/2023 10:31
MHALL3
1
SW 601OD
02/03/2023 10:31
MHALL3
1
SW 6010D
02/03/2023 10:31
MHALL3
1 SW 6010D
02/03/2023 10:31
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3
1 SW 6020B
02/01/2023 00:48
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-4B-A1
Collection Date: 01/26/2023 09:55 AM Loc code: ASA SW-4B-A1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.264 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.378 J
ug/L
1
0.185
1
Cobalt (Co)
1.40
ug/L
1
0.077
1
Lead (Pb)
0.098 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.332 J
ug/L
1
0.256
1
Selenium (Se)
1.57
ug/L
1
0.193
1
Thallium (TI) Low Level
0.147 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.13 J
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL SUSPENDED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
Sample #: 2023001344
Matrix: GW RCRA
Page 12 of 58
Method
Analysis Date/Time
Analyst
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
SW 6020B
02/01/2023 03:28
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-5-A1
Collection Date: 01/26/2023 10:30 AM Loc code: ASA SW-5-A1
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL ALKALINITY - Q23020024
Total Alkalinity as CaCO3
48.3
mg/L
5
1.7
1
(CaCO3)
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
Alkalinity, Bicarbonate
48.3
mg/L
5
1.7
1
INORGANIC IONS BY IC - Q23010483
Chloride
6.4
mg/L
0.1
0.0154
1
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
Sulfate
3.3
mg/L
0.1
0.0428
1
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.062
mg/L
0.01
0.003
1
Barium (Ba)
0.161
mg/L
0.005
0.002
1
Boron (B)
0.022 J
mg/L
0.05
0.005
1
Calcium (Ca)
14.3
mg/L
0.05
0.012
1
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
Iron (Fe)
6.47
mg/L
0.01
0.004
1
Magnesium (Mg)
4.42
mg/L
0.01
0.008
1
Manganese (Mn)
4.13
mg/L
0.005
0.001
1
Potassium (K)
2.38
mg/L
0.1
0.031
1
Sodium (Na)
1.85
mg/L
0.05
0.017
1
Strontium (Sr)
0.182
mg/L
0.005
0.001
1
Zinc (Zn)
0.009
mg/L
0.005
0.004
1
Sample #: 2023001346
Matrix: GW RCRA
Page 13 of 58
Method Analysis Date/Time Analyst
SM 2320B-2011
02/01/2023 10:11
SNEGLIA
SM 2320B-2011
02/01/2023 10:11
SNEGLIA
SM 2320B-2011
02/01/2023 10:11
SNEGLIA
EPA 9056A
01/31/2023 20:42
BGN9034
EPA 9056A
01/31/2023 20:42
BGN9034
EPA 9056A
01/31/2023 20:42
BGN9034
EPA 7470A
02/01/2023 13:57
JAA5429
EPA 7470A
02/01/2023 15:14
JAA5429
SW 601OD
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 601OD
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106
SW 601OD
02/01/2023 11:25
CELL106
SW 6010D
02/01/2023 11:25
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-5-A1
Collection Date: 01/26/2023 10:30 AM Loc code: ASA SW-5-A1
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
1.24
mg/L
0.01
0.003
Barium (Ba)
0.220
mg/L
0.005
0.002
Boron (B)
0.02 J
mg/L
0.05
0.005
Calcium (Ca)
13.5
mg/L
0.05
0.012
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
18.0
mg/L
0.01
0.004
Magnesium (Mg)
4.09
mg/L
0.02
0.008
Manganese (Mn)
5.38
mg/L
0.005
0.001
Potassium (K)
2.34
mg/L
0.1
0.031
Sodium (Na)
1.69
mg/L
0.05
0.017
Strontium (Sr)
0.181
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
50.5
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.008
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
1.91
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.192 J
ug/L
1
0.185
Cobalt (Co)
15.9
ug/L
1
0.077
Lead (Pb)
0.092 J
ug/L
1
0.037
Molybdenum (Mo)
0.286 J
ug/L
1
0.18
Nickel (Ni)
1.22
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.131 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
Page 14 of 58
Sample #:
2023001346
Matrix:
GW RCRA
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 601OD
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1
SW 601OD
02/03/2023 10:36
MHALL3
1
SW 601OD
02/03/2023 10:36
MHALL3
1
SW 6010D
02/03/2023 10:36
MHALL3
1 SW 6010D
02/03/2023 10:36
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3
1 SW 6020B
02/01/2023 00:57
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-5-A1
Collection Date: 01/26/2023 10:30 AM Loc code: ASA SW-5-A1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
4.87
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 J
ug/L
1
0.032
1
Chromium (Cr)
0.76 J
ug/L
1
0.185
1
Cobalt (Co)
23.7
ug/L
1
0.077
1
Lead (Pb)
0.616 J
ug/L
1
0.037
1
Molybdenum (Mo)
1.28
ug/L
1
0.18
1
Nickel (Ni)
1.54
ug/L
1
0.256
1
Selenium (Se)
0.246 J
ug/L
1
0.193
1
Thallium (TI) Low Level
0.178 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
1.60
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL SUSPENDED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
Sample #: 2023001346
Matrix: GW RCRA
Page 15 of 58
Method Analysis Date/Time Analyst
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
SW 6020B
02/01/2023
03:38
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-9-A1
Collection Date: 01/26/2023 09:40 AM Loc code: ASA SW-9-A1
Sample #: 2023001349
Matrix: GW RCRA
Page 16 of 58
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q23020073
Alkalinity, Bicarbonate
16.5
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:39
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:39
SNEGLIA
Total Alkalinity as CaCO3
16.5
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:39
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
12
mg/L
0.5
0.0154
5
EPA 9056A
01/31/2023 21:08
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 21:08
BGN9034
Sulfate
5.5
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 21:08
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 13:59
JAA5429
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:16
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.342
mg/L
0.01
0.003
1
SW 601OD
02/01/2023 11:30
CELL106
Barium (Ba)
0.039
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:30
CELL106
Boron (B)
0.014 J
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:30
CELL106
Calcium (Ca)
9.08
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:30
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:30
CELL106
Iron (Fe)
0.942
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:30
CELL106
Magnesium (Mg)
3.26
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:30
CELL106
Manganese (Mn)
0.296
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:30
CELL106
Potassium (K)
1.68
mg/L
0.1
0.031
1
SW 601OD
02/01/2023 11:30
CELL106
Sodium (Na)
5.81
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:30
CELL106
Strontium (Sr)
0.050
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:30
CELL106
Zinc (Zn)
0.010
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:30
CELL106

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-9-A1
Collection Date: 01/26/2023 09:40 AM Loc code: ASA SW-9-A1
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
1.18
mg/L
0.01
0.003
Barium (Ba)
0.044
mg/L
0.005
0.002
Boron (B)
0.01 J
mg/L
0.05
0.005
Calcium (Ca)
8.43
mg/L
0.05
0.012
Copper (Cu)
0.001 J
mg/L
0.005
0.001
Iron (Fe)
1.74
mg/L
0.01
0.004
Magnesium (Mg)
3.04
mg/L
0.02
0.008
Manganese (Mn)
0.286
mg/L
0.005
0.001
Potassium (K)
1.70
mg/L
0.1
0.031
Sodium (Na)
5.84
mg/L
0.05
0.017
Strontium (Sr)
0.048
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
33.6
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.009
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.15 J
ug/L
1
0.104
Arsenic (As)
0.111 U
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.361 J
ug/L
1
0.185
Cobalt (Co)
1.04
ug/L
1
0.077
Lead (Pb)
0.207 J
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.792 J
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.084 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.262 J
ug/L
0.3
0.114
Page 17 of 58
Sample #:
2023001349
Matrix:
GW RCRA
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 601OD
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1
SW 601OD
02/03/2023 10:40
MHALL3
1
SW 601OD
02/03/2023 10:40
MHALL3
1
SW 6010D
02/03/2023 10:40
MHALL3
1 SW 6010D
02/03/2023 10:40
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3
1 SW 6020B
02/01/2023 01:07
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA SW-9-A1
Collection Date: 01/26/2023 09:40 AM Loc code: ASA SW-9-A1
Analyte
Result
Units
Qualifiers RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.156 J
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.782 J
ug/L
1
0.185
1
Cobalt (Co)
1.31
ug/L
1
0.077
1
Lead (Pb)
0.634 J
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.92 J
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.102 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
1.08
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS - (Analysis Performed by
Pace Laboratories)
Vendor Parameter
Complete
TOTAL SUSPENDED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete
Sample #: 2023001349
Matrix: GW RCRA
Page 18 of 58
Method Analysis Date/Time Analyst
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
SW 6020B
02/01/2023
03:47
MHALL3
Vendor Method
V_PACE
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 19 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA FtB-20230126-0945
Filter Blank
Sample #: 2023001350
Collection Date: 01/26/2023 09:45 AM
Loc code: ASA FtB
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q23020073
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:46
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:46
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:46
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
0.03 J
mg/L
0.1
0.0154
1
EPA 9056A
01/31/2023 17:16
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 17:16
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 17:16
BGN9034
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:19
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.003 U
mg/L
0.01
0.003
1
SW 6010D
02/01/2023 11:35
CELL106
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:35
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:35
CELL106
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:35
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:35
CELL106
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:35
CELL106
Magnesium (Mg)
0.008 U
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:35
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:35
CELL106
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 6010D
02/01/2023 11:35
CELL106
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:35
CELL106
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:35
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:35
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
02/01/2023 01:16
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
02/01/2023 01:16
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
02/01/2023 01:16
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
02/01/2023 01:16
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
02/01/2023 01:16
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
02/01/2023 01:16
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
02/01/2023 01:16
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
02/01/2023 01:16
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
02/01/2023 01:16
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
02/01/2023 01:16
MHALL3
Thallium (TI) Low Level
0.058 J
ug/L
0.2
0.041
1
SW 6020B
02/01/2023 01:16
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
02/01/2023 01:16
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA_EB-20230126-0950 Equipment Blank
Collection Date: 01/26/2023 09:50 AM Loc code: ASA EB
Sample #: 2023001351
Matrix: GW RCRA
Page 20 of 58
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q23020073
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:52
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:52
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:52
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
0.03 J
mg/L
0.1
0.0154
1
EPA 9056A
01/31/2023 17:42
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 17:42
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 17:42
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 14:01
JAA5429
DISSOLVED MERCURY (COLD VAPOR) IN WATER - Q23020029
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 15:21
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED) - Q23010448
Aluminum (AI)
0.003 U
mg/L
0.01
0.003
1
SW 601OD
02/01/2023 11:39
CELL106
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
02/01/2023 11:39
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
02/01/2023 11:39
CELL106
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 6010D
02/01/2023 11:39
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:39
CELL106
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
02/01/2023 11:39
CELL106
Magnesium (Mg)
0.008 U
mg/L
0.01
0.008
1
SW 6010D
02/01/2023 11:39
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/01/2023 11:39
CELL106
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 601OD
02/01/2023 11:39
CELL106
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 6010D
02/01/2023 11:39
CELL106
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
1
SW 601OD
02/01/2023 11:39
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
02/01/2023 11:39
CELL106

Certificate of Laboratory Analysis Page 21 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA_EB-20230126-0950
Equipment Blank
Sample #:
2023001351
Collection Date: 01/26/2023 09:50 AM
Loc code: ASA EB
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
0.003 U
mg/L
0.01
0.003
Barium (Ba)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.005 J
mg/L
0.01
0.004
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
Potassium (K)
0.031 U
mg/L
0.1
0.031
Sodium (Na)
0.017 U
mg/L
0.05
0.017
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
Total Hardness (Ca and Mg)
< 0.190
mg/L
0.19
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q23010456
Antimony (Sb)
0.104 U
ug/L
1
0.104
Arsenic (As)
0.111 U
ug/L
1
0.111
Beryllium (Be)
0.249 U
ug/L
1
0.249
Cadmium (Cd)
0.032 U
ug/L
1
0.032
Chromium (Cr)
0.185 U
ug/L
1
0.185
Cobalt (Co)
0.077 U
ug/L
1
0.077
Lead (Pb)
0.037 U
ug/L
1
0.037
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
Nickel (Ni)
0.256 U
ug/L
1
0.256
Selenium (Se)
0.193 U
ug/L
1
0.193
Thallium (TI) Low Level
0.042 J
ug/L
0.2
0.041
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
DF
Method
Analysis Date/Time
Analyst
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 601OD
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 601OD
02/03/2023 10:45
MHALL3
1
SW 601OD
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6010D
02/03/2023 10:45
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3
1
SW 6020B
02/01/2023 01:26
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA_EB-20230126-0950 Equipment Blank
Collection Date: 01/26/2023 09:50 AM Loc code: ASA EB
Analyte
Result
Units Qualifiers
RDL
MDL
DF
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
Arsenic (As)
0.111 U
ug/L
1
0.111
1
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
Lead (Pb)
0.037 U
ug/L
1
0.037
1
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
Selenium (Se)
0.193 U
ug/L
1
0.193
1
Thallium (TI) Low Level
0.066 J
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
Sample #: 2023001351
Matrix: GW RCRA
Page 22 of 58
Method Analysis Date/Time Analyst
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3
SW 6020B
02/01/2023 03:57
MHALL3

Certificate of Laboratory Analysis Page 23 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA FB-20230126-0955 Field Blank
Sample #: 2023001352
Collection Date: 01/26/2023 09:55 AM
Loc code:
ASA FB
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q23020073
Alkalinity, Bicarbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:58
SNEGLIA
Alkalinity, Carbonate
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:58
SNEGLIA
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320B4d
02/03/2023 11:58
SNEGLIA
(CaCO3)
INORGANIC IONS BY IC - Q23010483
Chloride
0.0154 U
mg/L
0.1
0.0154
1
EPA 9056A
01/31/2023 18:08
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
01/31/2023 18:08
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
01/31/2023 18:08
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q23020028
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
02/01/2023 14:04
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q23010452
Aluminum (AI)
0.003 U
mg/L
0.01
0.003
1
SW 6010D
02/03/2023 10:50
MHALL3
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
02/03/2023 10:50
MHALL3
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
02/03/2023 10:50
MHALL3
Calcium (Ca)
0.018 J
mg/L
0.05
0.012
1
SW 6010D
02/03/2023 10:50
MHALL3
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 601 OD
02/03/2023 10:50
MHALL3
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
02/03/2023 10:50
MHALL3
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 6010D
02/03/2023 10:50
MHALL3
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/03/2023 10:50
MHALL3
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 6010D
02/03/2023 10:50
MHALL3
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 6010D
02/03/2023 10:50
MHALL3
Strontium (Sr)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
02/03/2023 10:50
MHALL3
Total Hardness (Ca and Mg)
< 0.190
mg/L
0.19
1
SW 6010D
02/03/2023 10:50
MHALL3
(CaCO3)
Zinc (Zn)
0.005 J
mg/L
0.005
0.004
1
SW 601 OD
02/03/2023 10:50
MHALL3
TOTAL RECOVERABLE METALS BY ICP-MS - Q23010459
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
02/01/2023 04:06
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
02/01/2023 04:06
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
02/01/2023 04:06
MHALL3
Cadmium (Cd)
0.037 J
ug/L
1
0.032
1
SW 6020B
02/01/2023 04:06
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
02/01/2023 04:06
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
02/01/2023 04:06
MHALL3
Lead (Pb)
0.044 J
ug/L
1
0.037
1
SW 6020B
02/01/2023 04:06
MHALL3
Molybdenum (Mo)
0.18 U
ug/L
1
0.18
1
SW 6020B
02/01/2023 04:06
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
02/01/2023 04:06
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
02/01/2023 04:06
MHALL3
Thallium (TI) Low Level
0.056 J
ug/L
0.2
0.041
1
SW 6020B
02/01/2023 04:06
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
02/01/2023 04:06
MHALL3

Certificate of Laboratory Analysis Page 24 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Site: ASA FB-20230126-0955 Field Blank Sample #: 2023001352
Collection Date: 01/26/2023 09:55 AM Loc code: ASA FB Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 25 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23020024 ALK_CarbBicarb TOTAL ALKALINITY
Duplicate # 1
Parent Sample:
J23010300 -- 2023001344
Parameter
Measured
Final
Units
Dil
MDL
RPD
Alkalinity, Bicarbonate
28.4
mg/L
1
1.7
1.6
Alkalinity, Carbonate
0
mg/L
1
1.7
0
Total Alkalinity as CaCO3
28.4
mg/L
1
1.7
1.6
Duplicate # 2
Parent Sample:
J23010300
-- 2023001346
Parameter
Measured
Final
Units
Dil
MDL
RPD
Alkalinity, Bicarbonate
47.3
mg/L
1
1.7
1.99
Alkalinity, Carbonate
0
mg/L
1
1.7
0
Total Alkalinity as CaCO3
47.3
mg/L
1
1.7
1.99
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Total Alkalinity as CaCO3
49.2
mg/L
1
1.7
52.2
94.2
85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Total Alkalinity as CaCO3
49.6
mg/L
1
1.7
52.2
95.1
85
115
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 26 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23020073 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parent Sample:
J23010397 -- 2023001763
Parameter Measured
Final
Units
Dil
MDL
RPD Qualifier
Alkalinity, Bicarbonate
0.02
mg/L
1
1.7
127
Alkalinity, Carbonate
0
mg/L
1
1.7
0
Total Alkalinity as CaCO3
0.02
mg/L
1
1.7
127
LCS # 1
Parameter Measured
Final
Units
Dil
MDL S ike % Recovery
LCL UCL Qualifier
Total Alkalinity as CaCO3
46.5
mg/L
1
1.7 52.2 89
85 115
(CaCO3)

Certificate of Laboratory Analysis Page 27 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010483 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Sulfate
0.001
0.001
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
1.99
1.99
mg/L
1
0.0154
2
99.3
80
120
Fluoride
2.01
2.01
mg/L
1
0.0479
2
100
80
120
Sulfate
2.12
2.12
mg/L
1
0.0428
2
106
80
120
MS # 1
Parent Sample:
J23010300 -- 2023001342
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Qualifier
Chloride
4.22
21.1
mg/L
5
0.0154
5
98.9
80
120
Fluoride
5.01
5.01
mg/L
1
0.0479
5
99.6
80
120
Sulfate
7.58
7.58
mg/L
1
0.0428
5
104
80
120
MSD # 1
Parent Sample:
J23010300 -- 2023001342
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
4.23
21.2
mg/L
5
0.0154
5
99.6
80
120
0.705
Fluoride
5.04
5.04
mg/L
1
0.0479
5
100
80
120
0.621
Sulfate
7.6
7.6
mg/L
1
0.0428
5
104
80
120
0.326

Certificate of Laboratory Analysis Page 28 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23020028 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.017
0.017
ug/L
1
0.01
0.05
> MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.023
0.023
ug/L
1
0.01
0.05
> MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.021
0.021
ug/L
1
0.01
0.05
> MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.015
0.015
ug/L
1
0.01
0.05
> MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.013
0.013
ug/L
1
0.01
0.05
> MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.012
0.012
ug/L
1
0.01
0.05
> MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.011
0.011
ug/L
1
0.01
0.05
> MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.91
1.91
ug/L
1
0.01
2
95.5 85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.9
1.9
ug/L
1
0.01
2
95.1 85
115
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.84
1.84
ug/L
1
0.01
2
92.2 85
115
MS # 1
Parent Sample: J23010074 -- 2023000291
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
103 75
125

Certificate of Laboratory Analysis Page 29 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23020028 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 1
Parent Sample:
J23010074 -- 2023000291
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
101
75 125 1.37
MS # 2
Parent Sample:
J23010074 -- 2023000301
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
100
75 125
MSD # 2
Parent Sample:
J23010074 -- 2023000301
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
99.5
75 125 0.701
MS # 3
Parent Sample:
J23010074 -- 2023000315
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
97.4
75 125
MSD # 3
Parent Sample:
J23010074 -- 2023000315
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
97.6
75 125 0.205
MS # 4
Parent Sample:
J23010276 -- 2023001221
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
99
75 125
MSD # 4
Parent Sample:
J23010276 -- 2023001221
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
97.1
75 125 1.94
MS # 5
Parent Sample:
J23010300 -- 2023001344
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.976
0.976
ug/L
1
0.01
1
96.3
75 125
MSD # 5
Parent Sample:
J23010300 -- 2023001344
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.953
0.953
ug/L
1
0.01
1
94
75 125 2.42
MS # 6
Parent Sample:
J23010318 -- 2023001434
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.977
0.977
ug/L
1
0.01
1
96.2
75 125
MSD # 6
Parent Sample:
J23010318 -- 2023001434
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.958
0.958
ug/L
1
0.01
1
94.3
75 125 1.99

Certificate of Laboratory Analysis Page 30 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23020029 HG 7470_Dissolved DISSOLVED MERCURY (COLD VAPOR) IN WATER
Blank # 1
Blank # 2
LCS # 1
MS # 1
MSD # 1
Parameter Measured Final
Mercury (Hg) 0.011 0.011
Parameter Measured Final
Mercury (Hg) 0.012 0.012
Parameter Measured Final
Mercury (Hg) 1.75 1.75
Parameter Measured Final
Mercury (Hg) 0.926 0.926
Parameter Measured Final
Mercury (Hg) 0.925 0.925
Units
Dil
MDL
RDL
Relative Concentration
ug/L
1
0.01
0.05
> MDL
Units
Dil
MDL
RDL
Relative Concentration
ug/L
1
0.01
0.05
> MDL
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
ug/L
1
0.01
2
87.6
85
115
Parent Sample:
J23010300 -- 2023001342
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
ug/L
1
0.01
1
91.4
75
125
Parent Sample:
J23010300 -- 2023001342
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
ug/L
1
0.01
1
91.3
75
125 0.109
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010448 ICP_DIS_TRM TOTAL RECOVERABLE METALS BV ICP (DISSOLVED)
Blank # 1
Page 31 of 58
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Aluminum (AI)
0.00149
0.00149
mg/L
1
0.003
0.01
< MDL
Barium (Ba)
-0.000406
-0.000406
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00186
0.00186
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00486
0.00486
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
-0.000246
-0.000246
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.000617
0.000617
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.00184
0.00184
mg/L
1
0.008
0.01
< MDL
Manganese (Mn)
0.000062
0.000062
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.00567
-0.00567
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.00333
-0.00333
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
-0.000025
-0.000025
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
-0.000819
-0.000819
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Aluminum (AI)
5.14
5.14
mg/L
1
0.003
5
103
80
120
Barium (Ba)
5.09
5.09
mg/L
1
0.002
5
102
80
120
Boron (B)
5.37
5.37
mg/L
1
0.005
5
107
80
120
Calcium (Ca)
5.39
5.39
mg/L
1
0.012
5
108
80
120
Copper (Cu)
5.36
5.36
mg/L
1
0.001
5
107
80
120
Iron (Fe)
5.38
5.38
mg/L
1
0.004
5
108
80
120
Magnesium (Mg)
5.42
5.42
mg/L
1
0.008
5
109
80
120
Manganese (Mn)
5.42
5.42
mg/L
1
0.001
5
108
80
120
Potassium (K)
5.27
5.27
mg/L
1
0.031
5
105
80
120
Sodium (Na)
5.09
5.09
mg/L
1
0.017
5
102
80
120
Strontium (Sr)
5.21
5.21
mg/L
1
0.001
5
104
80
120
Zinc (Zn)
5.4
5.4
mg/L
1
0.004
5
108
80
120
MS # 1
Parent Sample:
J23010300 -- 2023001344
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
5.08
5.08
mg/L
1
0.003
5
101
70
130
Barium (Ba)
5.01
5.01
mg/L
1
0.002
5
99.7
70
130
Boron (B)
5.17
5.17
mg/L
1
0.005
5
100
70
130
Calcium (Ca)
14.8
14.8
mg/L
1
0.012
5
104
70
130
Copper (Cu)
5.27
5.27
mg/L
1
0.001
5
105
70
130
Iron (Fe)
7.44
7.44
mg/L
1
0.004
5
107
70
130
Magnesium (Mg)
9.83
9.83
mg/L
1
0.008
5
103
70
130
Manganese (Mn)
5.94
5.94
mg/L
1
0.001
5
107
70
130
Potassium (K)
6.61
6.61
mg/L
1
0.031
5
104
70
130
Sodium (Na)
7.86
7.86
mg/L
1
0.017
5
100
70
130
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 32 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010448 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.25
5.25
Zinc (Zn)
5.32
5.32
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
5.09
5.09
Barium (Ba)
5.01
5.01
Boron (B)
5.52
5.52
Calcium (Ca)
14.9
14.9
Copper (Cu)
5.32
5.32
Iron (Fe)
7.52
7.52
Magnesium (Mg)
9.96
9.96
Manganese (Mn)
5.98
5.98
Potassium (K)
6.7
6.7
Sodium (Na)
7.93
7.93
Strontium (Sr)
5.31
5.31
Zinc (Zn)
5.36
5.36
Parent Sample:
J23010300 -- 2023001344
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
103
70
130
mg/L
1
0.004
5
106
70
130
Parent Sample:
J23010300
-- 2023001344
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
101
70
130
0.256
mg/L
1
0.002
5
99.8
70
130
0.0798
mg/L
1
0.005
5
107
70
130
6.43
mg/L
1
0.012
5
108
70
130
1.04
mg/L
1
0.001
5
106
70
130
0.963
mg/L
1
0.004
5
108
70
130
1.1
mg/L
1
0.008
5
106
70
130
1.38
mg/L
1
0.001
5
108
70
130
0.537
mg/L
1
0.031
5
106
70
130
1.32
mg/L
1
0.017
5
101
70
130
0.874
mg/L
1
0.001
5
105
70
130
1.17
mg/L
1
0.004
5
107
70
130
0.805
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010452 JCP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Page 33 of 58
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Aluminum (AI)
0.00188
0.00188
mg/L
1
0.003
0.01
< MDL
Barium (Ba)
-0.000798
-0.000798
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00134
0.00134
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00473
0.00473
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000039
0.000039
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00147
0.00147
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.00171
0.00171
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000136
0.000136
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.00429
-0.00429
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
-0.00153
-0.00153
mg/L
1
0.017
0.05
< MDL
Strontium (Sr)
-0.000052
-0.000052
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0
0
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Aluminum (AI)
4.82
4.82
mg/L
1
0.003
5
96.3
80
120
Barium (Ba)
5.09
5.09
mg/L
1
0.002
5
102
80
120
Boron (B)
5.13
5.13
mg/L
1
0.005
5
103
80
120
Calcium (Ca)
5.1
5.1
mg/L
1
0.012
5
102
80
120
Copper (Cu)
5.18
5.18
mg/L
1
0.001
5
104
80
120
Iron (Fe)
5.11
5.11
mg/L
1
0.004
5
102
80
120
Magnesium (Mg)
5
5
mg/L
1
0.008
5
100
80
120
Manganese (Mn)
5.1
5.1
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.04
5.04
mg/L
1
0.031
5
101
80
120
Sodium (Na)
5.06
5.06
mg/L
1
0.017
5
101
80
120
Strontium (Sr)
5.07
5.07
mg/L
1
0.001
5
101
80
120
Zinc (Zn)
5.08
5.08
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J23010300 -- 2023001343
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Aluminum (AI)
6.61
6.61
mg/L
1
0.003
5
92.6
75
125
Barium (Ba)
5.17
5.17
mg/L
1
0.002
5
103
75
125
Boron (B)
5.21
5.21
mg/L
1
0.005
5
104
75
125
Calcium (Ca)
12.9
12.9
mg/L
1
0.012
5
99.7
75
125
Copper (Cu)
5.22
5.22
mg/L
1
0.001
5
104
75
125
Iron (Fe)
7.1
7.1
mg/L
1
0.004
5
100
75
125
Magnesium (Mg)
7.72
7.72
mg/L
1
0.008
5
97.9
75
125
Manganese (Mn)
5.37
5.37
mg/L
1
0.001
5
103
75
125
Potassium (K)
6.66
6.66
mg/L
1
0.031
5
101
75
125
Sodium (Na)
10.2
10.2
mg/L
1
0.017
5
103
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 34 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010452 TCP_TRM TOTAL RECOVERABLE METALS BY ICP
MS # 1
Parameter
Measured
Final
Strontium (Sr)
5.15
5.15
Zinc (Zn)
5.11
5.11
MSD # 1
Parameter
Measured
Final
Aluminum (AI)
6.79
6.79
Barium (Ba)
5.23
5.23
Boron (B)
5.27
5.27
Calcium (Ca)
13.1
13.1
Copper (Cu)
5.31
5.31
Iron (Fe)
7.22
7.22
Magnesium (Mg)
7.85
7.85
Manganese (Mn)
5.44
5.44
Potassium (K)
6.79
6.79
Sodium (Na)
10.4
10.4
Strontium (Sr)
5.18
5.18
Zinc (Zn)
5.18
5.18
Parent Sample:
J23010300 -- 2023001343
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
mg/L
1
0.001
5
102
75
125
mg/L
1
0.004
5
102
75
125
Parent Sample:
J23010300
-- 2023001343
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
mg/L
1
0.003
5
96.2
75
125
2.7
mg/L
1
0.002
5
104
75
125
1.21
mg/L
1
0.005
5
105
75
125
1.13
mg/L
1
0.012
5
103
75
125
1.26
mg/L
1
0.001
5
106
75
125
1.61
mg/L
1
0.004
5
103
75
125
1.66
mg/L
1
0.008
5
100
75
125
1.62
mg/L
1
0.001
5
104
75
125
1.39
mg/L
1
0.031
5
104
75
125
2.07
mg/L
1
0.017
5
106
75
125
1.55
mg/L
1
0.001
5
103
75
125
0.697
mg/L
1
0.004
5
104
75
125
1.47
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 35 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010456 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.027
-0.027
ug/L
1
0.104
1
< MDL
Arsenic (As)
-0.022
-0.022
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.013
0.013
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.013
0.013
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.084
0.084
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.025
0.025
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.008
0.008
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.01
0.01
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.029
0.029
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.005
0.005
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
0.025
0.025
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.15
-0.15
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
51.9
51.9
ug/L
1
0.104
50
104
80
120
Arsenic (As)
52
52
ug/L
1
0.111
50
104
80
120
Beryllium (Be)
49.8
49.8
ug/L
1
0.249
50
99.5
80
120
Cadmium (Cd)
51.6
51.6
ug/L
1
0.032
50
103
80
120
Chromium (Cr)
53.4
53.4
ug/L
1
0.185
50
107
80
120
Cobalt (Co)
53.9
53.9
ug/L
1
0.077
50
108
80
120
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
80
120
Molybdenum (Mo)
54
54
ug/L
1
0.18
50
108
80
120
Nickel (Ni)
53.6
53.6
ug/L
1
0.256
50
107
80
120
Selenium (Se)
48
48
ug/L
1
0.193
50
96
80
120
Thallium (TI) Low Level
49.7
49.7
ug/L
1
0.041
50
99.4
80
120
Vanadium (V) Low Level
54.3
54.3
ug/L
1
0.114
50
109
80
120
MS # 1
Parent Sample:
J23010300 -- 2023001342
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
51.8
51.8
ug/L
1
0.104
50
104
75
125
Arsenic (As)
51
51
ug/L
1
0.111
50
102
75
125
Beryllium (Be)
48.1
48.1
ug/L
1
0.249
50
96.1
75
125
Cadmium (Cd)
51.6
51.6
ug/L
1
0.032
50
103
75
125
Chromium (Cr)
53.6
53.6
ug/L
1
0.185
50
107
75
125
Cobalt (Co)
52.4
52.4
ug/L
1
0.077
50
104
75
125
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
75
125
Molybdenum (Mo)
53.4
53.4
ug/L
1
0.18
50
107
75
125
Nickel (Ni)
52.7
52.7
ug/L
1
0.256
50
105
75
125
Selenium (Se)
47.4
47.4
ug/L
1
0.193
50
94.7
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010456 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
47.3
47.3
ug/L
Vanadium (V) Low Level
53.5
53.5
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
51.6
51.6
ug/L
Arsenic (As)
50.7
50.7
ug/L
Beryllium (Be)
47.2
47.2
ug/L
Cadmium (Cd)
51.4
51.4
ug/L
Chromium (Cr)
52.8
52.8
ug/L
Cobalt (Co)
51.6
51.6
ug/L
Lead (Pb)
51.7
51.7
ug/L
Molybdenum (Mo)
53
53
ug/L
Nickel (Ni)
51.2
51.2
ug/L
Selenium (Se)
46.8
46.8
ug/L
Thallium (TI) Low Level
47.8
47.8
ug/L
Vanadium (V) Low Level
53
53
ug/L
Parent Sample:
J23010300 -- 2023001342
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
94.4
75
125
1
0.114
50
107
75
125
Parent Sample:
J23010300
-- 2023001342
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
103
75
125
0.358
1
0.111
50
101
75
125
0.537
1
0.249
50
94.3
75
125
1.96
1
0.032
50
103
75
125
0.315
1
0.185
50
105
75
125
1.46
1
0.077
50
103
75
125
1.47
1
0.037
50
103
75
125
0.882
1
0.18
50
106
75
125
0.8
1
0.256
50
101
75
125
2.95
1
0.193
50
93.6
75
125
1.21
1
0.041
50
95.3
75
125
0.957
1
0.114
50
106
75
125
1.05
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 37 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010459 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
-0.006
-0.006
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.006
0.006
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.019
0.019
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.007
0.007
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.059
0.059
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.006
0.006
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.01
0.01
ug/L
1
0.037
1
< MDL
Molybdenum (Mo)
0.004
0.004
ug/L
1
0.18
1
< MDL
Nickel (Ni)
0.002
0.002
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.005
0.005
ug/L
1
0.193
1
< MDL
Thallium (TI) Low Level
0.035
0.035
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
-0.096
-0.096
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
51.3
51.3
ug/L
1
0.104
50
103
80
120
Arsenic (As)
48.9
48.9
ug/L
1
0.111
50
97.8
80
120
Beryllium (Be)
48.6
48.6
ug/L
1
0.249
50
97.3
80
120
Cadmium (Cd)
51
51
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
53.2
53.2
ug/L
1
0.185
50
106
80
120
Cobalt (Co)
50.6
50.6
ug/L
1
0.077
50
101
80
120
Lead (Pb)
51.7
51.7
ug/L
1
0.037
50
103
80
120
Molybdenum (Mo)
51.8
51.8
ug/L
1
0.18
50
104
80
120
Nickel (Ni)
50.4
50.4
ug/L
1
0.256
50
101
80
120
Selenium (Se)
46.9
46.9
ug/L
1
0.193
50
93.8
80
120
Thallium (TI) Low Level
47.7
47.7
ug/L
1
0.041
50
95.4
80
120
Vanadium (V) Low Level
53.2
53.2
ug/L
1
0.114
50
106
80
120
MS # 1
Parent Sample:
J23010300 -- 2023001342
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
51.8
51.8
ug/L
1
0.104
50
103
75
125
Arsenic (As)
49.3
49.3
ug/L
1
0.111
50
98.4
75
125
Beryllium (Be)
48.1
48.1
ug/L
1
0.249
50
96
75
125
Cadmium (Cd)
51.4
51.4
ug/L
1
0.032
50
103
75
125
Chromium (Cr)
53.4
53.4
ug/L
1
0.185
50
106
75
125
Cobalt (Co)
50.5
50.5
ug/L
1
0.077
50
100
75
125
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
75
125
Molybdenum (Mo)
52.8
52.8
ug/L
1
0.18
50
106
75
125
Nickel (Ni)
50.6
50.6
ug/L
1
0.256
50
100
75
125
Selenium (Se)
47.1
47.1
ug/L
1
0.193
50
94.1
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 58
This report shall not be reproduced, except in full.
Order # J23010300
Level II QC Summary
Q23010459 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
47.1
47.1
ug/L
Vanadium (V) Low Level
53.4
53.4
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
50.6
50.6
ug/L
Arsenic (As)
48.1
48.1
ug/L
Beryllium (Be)
46.4
46.4
ug/L
Cadmium (Cd)
50.1
50.1
ug/L
Chromium (Cr)
51.7
51.7
ug/L
Cobalt (Co)
49.3
49.3
ug/L
Lead (Pb)
50.9
50.9
ug/L
Molybdenum (Mo)
51.1
51.1
ug/L
Nickel (Ni)
48.9
48.9
ug/L
Selenium (Se)
46.2
46.2
ug/L
Thallium (TI) Low Level
46.5
46.5
ug/L
Vanadium (V) Low Level
52.3
52.3
ug/L
Parent Sample:
J23010300 -- 2023001342
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
94
75
125
1
0.114
50
107
75
125
Parent Sample:
J23010300
-- 2023001342
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
101
75
125
2.25
1
0.111
50
96
75
125
2.46
1
0.249
50
92.7
75
125
3.5
1
0.032
50
100
75
125
2.47
1
0.185
50
103
75
125
3.3
1
0.077
50
98
75
125
2.43
1
0.037
50
102
75
125
2.44
1
0.18
50
102
75
125
3.23
1
0.256
50
97
75
125
3.48
1
0.193
50
92.2
75
125
1.97
1
0.041
50
92.7
75
125
1.44
1
0.114
50
105
75
125
2.03
Qualifier
Qualifier

leAnalyiical
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Pace Analytical Services, LLC
og8� 6f,Pr e. Suite 100
�J Huntersville, NC 28078
[phone]
February 07, 2023
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J23010300-ASA
Pace Project No.: 92649187
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on January 27, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 19

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CERTIFICATIONS
Project: J23010300-ASA
Pace Project No.: 92649187
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 19

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[phone]
SAMPLE SUMMARY
Project: J23010300-ASA
Pace Project No.: 92649187
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92649187001
SW-2-Al
Water
01/26/23 08:55
01/27/2313:15
92649187002
SW-3-Al
Water
01/26/2311:00
01/27/2313:15
92649187003
SW-413-A7
Water
01/26/23 09:55
01/27/23 13:15
92649187004
SW-5-Al
Water
01/26/2310:30
01/27/2313:15
92649187005
SW-9-Al
Water
01/26/23 09:40
01 /27/23 13:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 19

leAnalyiical
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Pace Analytical Services, LLC
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[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J23010300-ASA
92649187
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92649187001
SW-2-Al
SM 2540C-2015
MJP
1
PASI-A
SM 2540D-2015
MJP
1
PASI-A
92649187002
SW-3-Al
SM 2540C-2015
MJP
1
PASI-A
SM 2540D-2015
MJP
1
PASI-A
92649187003
SW-413-A1
SM 2540C-2015
MJP
1
PASI-A
SM 2540D-2015
MJP
1
PASI-A
92649187004
SW-5-Al
SM 2540C-2015
MJP
1
PASI-A
SM 2540D-2015
MJP
1
PASI-A
92649187005
SW-9-Al
SM 2540C-2015
MJP
1
PASI-A
SM 2540D-2015
MJP
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 19

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SUMMARY OF DETECTION
Project:
Pace Project No.:
J23010300-ASA
92649187
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92649187001
SW-2-Al
SM 2540C-2015
Total Dissolved Solids
62.0
mg/L
25.0
02/01/23 11:08
92649187002
SW-3-Al
SM 2540C-2015
Total Dissolved Solids
62.0
mg/L
25.0
02/01/23 11:08
SM 2540D-2015
Total Suspended Solids
22.8
mg/L
5.0
02/01/23 10:48
92649187003
SW-46-Al
SM 2540C-2015
Total Dissolved Solids
58.0
mg/L
25.0
02/01/23 11:08
SM 2540D-2015
Total Suspended Solids
11.4
mg/L
2.5
02/01/23 10:48
92649187004
SW-5-Al
SM 2540C-2015
Total Dissolved Solids
60.0
mg/L
25.0
02/01/23 11:08
SM 2540D-2015
Total Suspended Solids
24.0
mg/L
5.0
02/01/23 10:48
92649187005
SW-9-Al
SM 2540C-2015
Total Dissolved Solids
61.0
mg/L
25.0
02/01/23 11:08
SM 2540D-2015
Total Suspended Solids
13.9
mg/L
2.5
02/01/23 10:48
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 19

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[phone]
PROJECT NARRATIVE
Project: J23010300-ASA
Pace Project No.: 92649187
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: February 07, 2023
General Information:
5 samples were analyzed for SM 2540C-2015 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 6 of 19

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[phone]
PROJECT NARRATIVE
Project: J23010300-ASA
Pace Project No.: 92649187
Method: SM 2540D-2015
Description: 2540D Total Suspended Solids
Client: Duke Energy
Date: February 07, 2023
General Information:
5 samples were analyzed for SM 2540D-2015 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 7 of 19

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ANALYTICAL RESULTS
Project: J23010300-ASA
Pace Project No.: 92649187
Sample: SW-2-Al
Lab ID: 92649187001 Collected:
01/26/23 08:55
Received: 01/27/23 13:15 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
62.0 mg/L 25.0
25.0 1
02/01/23 11:08
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services -Asheville
Total Suspended Solids
ND mg/L 2.5
2.5 1
02/01/23 10:48
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2023 11:06 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 19

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ANALYTICAL RESULTS
Project: J23010300-ASA
Pace Project No.: 92649187
Sample: SW-3-Al
Lab ID: 92649187002 Collected:
01/26/23 11:00
Received: 01/27/23 13:15 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
62.0 mg/L 25.0
25.0 1
02/01/23 11:08
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services -Asheville
Total Suspended Solids
22.8 mg/L 5.0
5.0 1
02/01/23 10:48
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2023 11:06 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 19

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ANALYTICAL RESULTS
Project: J23010300-ASA
Pace Project No.: 92649187
Sample: SW-413-A1
Lab ID: 92649187003 Collected:
01/26/23 09:55
Received: 01/27/23 13:15 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
58.0 mg/L 25.0
25.0 1
02/01/23 11:08
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services -Asheville
Total Suspended Solids
11.4 mg/L 2.5
2.5 1
02/01/23 10:48
Date: 02/07/2023 11:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 19

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[phone]
ANALYTICAL RESULTS
Project: J23010300-ASA
Pace Project No.: 92649187
Sample: SW-5-Al
Lab ID: 92649187004 Collected:
01/26/23 10:30
Received: 01/27/23 13:15 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
60.0 mg/L 25.0
25.0 1
02/01/23 11:08
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services -Asheville
Total Suspended Solids
24.0 mg/L 5.0
5.0 1
02/01/23 10:48
Date: 02/07/2023 11:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 19

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ANALYTICAL RESULTS
Project: J23010300-ASA
Pace Project No.: 92649187
Sample: SW-9-Al
Lab ID: 92649187005 Collected:
01/26/23 09:40
Received: 01/27/23 13:15 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids
61.0 mg/L 25.0
25.0 1
02/01/23 11:08
2540D Total Suspended Solids
Analytical Method: SM 254OD-2015
Pace Analytical Services -Asheville
Total Suspended Solids
13.9 mg/L 2.5
2.5 1
02/01/23 10:48
Date: 02/07/2023 11:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 19

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[phone]
QUALITY CONTROL DATA
Project: J23010300-ASA
Pace Project No.: 92649187
QC Batch: 752976 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92649187001, 92649187002, 92649187003, 92649187004, 92649187005
METHOD BLANK: 3912476 Matrix: Water
Associated Lab Samples: 92649187001, 92649187002, 92649187003, 92649187004, 92649187005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 02/01/23 11:05
LABORATORY CONTROL SAMPLE: 3912477
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 251 264 105 90-110
SAMPLE DUPLICATE: 3912478
92649127018 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 5780 5730 1 25
SAMPLE DUPLICATE: 3912479
92649187001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 62.0 64.0 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/07/2023 11:06 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 19

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[phone]
QUALITY CONTROL DATA
Project: J23010300-ASA
Pace Project No.: 92649187
QC Batch: 752978 Analysis Method: SM 2540D-2015
QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92649187001, 92649187002, 92649187003, 92649187004, 92649187005
METHOD BLANK: 3912484 Matrix: Water
Associated Lab Samples: 92649187001, 92649187002, 92649187003, 92649187004, 92649187005
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 2.5 02/01/23 10:46
LABORATORY CONTROL SAMPLE: 3912485
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Suspended Solids mg/L 250 240 96 90-110
SAMPLE DUPLICATE: 3912948
92649033001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Suspended Solids mg/L 238000 ug/L 259 8 25
SAMPLE DUPLICATE: 3912949
92649034001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Suspended Solids mg/L 188 198 5 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/07/2023 11:06 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 19

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QUALIFIERS
Project: J23010300-ASA
Pace Project No.: 92649187
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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Date: 02/07/2023 11:06 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 19

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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J23010300-ASA
Pace Project No.: 92649187
Lab ID Sample ID QC Batch Method QC Batch
92649187001
SW-2-Al
SM
2540C-2015
752976
92649187002
SW-3-Al
SM
2540C-2015
752976
92649187003
SW-4B-A1
SM
2540C-2015
752976
92649187004
SW-5-Al
SM
2540C-2015
752976
92649187005
SW-9-Al
SM
2540C-2015
752976
92649187001
SW-2-Al
SM
2540D-2015
752978
92649187002
SW-3-Al
SM
2540D-2015
752978
92649187003
SW-4B-A1
SM
2540D-2015
752978
92649187004
SW-5-Al
SM
2540D-2015
752978
92649187005
SW-9-Al
SM
2540D-2015
752978
Date: 02/07/2023 11:06 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 16 of 19

DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
ace Page 55 of 58
Effective Date: 11/14/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersvillej�f Raleigh❑ Mechanicsville❑ Atlanta[] Kernersvillel-1
Client Name:
Upon �- . Project �. W4# : 925491 S
Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client ❑ Commercialace ❑other. 11111111111111111111
Custody Seal Present? . Dyes ❑No Seals Intact? ❑Yes ❑No
Packing Material: ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other
Thermometer:
IR Gu in
9 21 9187 ,
Date/Initials Person Examining Contents:�tJ�� "d
Biological Tissue Frozen?
3
Dyes [:]No [ !J /A
n T() L? Type of Ice: k]Wet ❑slue ❑None
Correction Factor:
Copier Temp: ��__ Add/Subtract (°C) Temp should be above freezing to 6"C
Cooler Tern Corrected G : a, ! ❑Samplesoutof temp criteria. Samples on ice, cooling process
P (' I �a , � t i' has begun
USDA Regulated Soil ( Q-N/A, water sample}
Did samples originate inrraa� quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally, {
(check maosl? nYes r�IIVo inrludina Hawaii and Pnnrin Rirn1? MY— F-Im;'
Comments/Discrepancy:
Chain of Custody Present?
yes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
s
[]No
El N/A
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
❑No
_ON7A
3.
Rush Turn Around Time Requested?
❑Yes
❑No
OkIA
4.
Sufficient Votume?
Yes
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
_-QYes
J2Yes
❑No
[]No
[]N/A
❑N/A
6.
Containers Intact?
__DYes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
[-]No
A
8.
Sample Labels Match COC?
Includes Date/Time/ID/Analysis Matrix:
es
1'�'/ 4 ^T
❑No
❑N/A
9.
Headspace in VOA Vials (?5.6mm)?
❑Yes
❑No
N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
[]No
❑No
N/A
EIN/A
11.
COMMENTS/SAMPLE DISCREPANCY field Data Required? ❑Yes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Page 17 of 19
Qualtrax ID: 69614 Page 1 of 2

DC#_Title: ENV-FRM-HUN1-0083 v02_Sample Condition Upon Receipt
a�',{a, Page 56 of 58
Effective Date: 11/14/2022
*Check mark top half of box if pH and/or dechlorination (s verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
WO# : 92649187
Project # PM: LJP Due Date: 02/03/23
CLIENT: 82-Duke Ener
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PH Adjustment Log for Preserved Samples
Sample ID Type of Preservative I pH upon recelpt Date preservatlon adjusted Time preservatio-n Amount of Preservative Lot ft
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i,e,
out of hold, incorrect preservative, out of temp, incorrect containers.
Page 18 of 19
Qualtrax ID: 69614 Page 2 of 2

CHAIN OF CUSTODY R1=CORD AND ANAI YSIC P;=nl Ir!ST 1:nann
P.nc R7 of rR
Duke
nergy Malytical Latlorotory --I - -------------------^•------------ - - - - - - - - - - - - -•- Anel Ical LabOnla Use Only................................................_._._._._._._._._._._._._._._._._._._._._._._._ r-
;Orden J23010300
Matrix WATER
..�„,•.a,a�.l,.,r,a. NC`x_ Page_1_of_1 O
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Logged By pamaTl a i ORIGINAL to LAD. COPY to CLIENT N
pa.lars42�s SAMPLE PROGRAM
...................._._. _ _ _ _ _
- ._._._
_._. _._._._.�i I
rna:gwj arass2a _ Ground Waler X NPDES
ILL AREA Pamu Nc' !Vendor '— —
Project Name ASHEVILLE AIRFORT
SURFACE WA
Brinkkng Walar_ UST'
ER i V - RCRA Waste_
iPOd-_.._.._.._._.._..Cod,.r7amejCy,�,•.•_.._.._.._.._.._.._.._.._.
Client JOHN 7OEPFER, BRYAN MOEL
R
BEE O'BRIEN, JOSH SFOWE, CONNOR ZA
ORA PACE Filtration (0.45 um) 4 Unfiltered 4 Flit red
BENVWS Account: i
Operoting Urdu: AE00 Process
Preservative ICE ICE
�._.._..
D: FaciOty 10; ASA PO 10614879 Container Volume ImL) 300 1 500 200D 250
Sub-PmgmmRask Cede; ContalnerT ypa PET HOPE PET HOPE
in
j ¢ O ICP TRM (90100); Al. ea, 9, p,
Project: Activity
Program l EQvlS Tmk Coda:
COMPLIANCrrSTRFL
Customer to complete elf oppreprinte non-shnaod auras. u 4 Ca, C., F•. Mg, Mn,K, N.,
r0 rc Sr, Z.,,tatdn•..
------- - Sample
description or ID V IMS TRM (e020131: Sb, A., 0 v c
Collection Information w Bs. Cd. Cr. Co, Pb, Me, NI, u
i SAMPLE ID i
i NUMBER
_ d u z _
E x O Se n(LLj, vjI,41 Rg 7e70A to m A
Bate Tlme Printed Name SI nature roe u q a
i 2023001342 i
ASA SW-2-Al
1-26-Z3
Gb5S
C&,VAdb r, ZL1t-162A
x
1
1
1
1
4
2023001343 ;
ASA SW-3-Al
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x
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2023001344 ;
ASA-_SW-4B-A
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x
1
1
1
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a
2023001345 •.
_
x
i• 2023001346 l
ASA SW-5-Al
ro3o
x
1
1
1
1
4
2023001347 !
x
1
1
1
1
2023001348 i
672w
x
2023DO1349 ;
ASA SW-9-Al
614C,
x
1
1
i
1
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E 2023001350
ASA_FtB- Zo
-jal?G _ G995
i-u-Z3
61,45
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x
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1
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2023001351
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2023001352 i
ASA FB - 2ts
to t U 0 C1 55
09 SS
x
1
1
2
0
0
i
0
0
i
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0
0
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Customer to sign date
be Ow
TOTAL CONTAINERS
0
0
11
11
0
a
0
0
0
0
0
10
0
40
Reflnqulshed By
�Rellnqu
Daterfime
Aced d sy: Datenrime
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Total 40
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Comments
NOTE: NCDEQ EDD
Ind EOUIS REQUIRED
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'Other
'Add. Cost Will Apply
U

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
C Duke Energynal Aytical Laboratory i i
xE Ma1lCodeMGO]A2(Building 7405) ! 2 ,1
13339 Hegers Ferry Rd i Order#-J23O1O300
Analytical Lab ratory Use Only
Matrix WATER
-
Nc_x_
,«gh,ewy Frwn
I rdyt: 00 UI UO
Page 1 of 1_
UTIDAI
Do
e Hunlersville, N.C.N. C. 2307a ; , Logged B
ENERGY
pal 37s3245
Date TI
SAMPLE PROGRAM
LAB.
! ORIGINAL to LAB, COPY to CLIENT
;
Fu;jra)s�sso]a.-.-.---•--_'!
''Z
Ground
Water_X_ NPDES_
.--------_._•_._._.-•_._.-.---.--•- - - -'-'
s Project Name ASHEVILLE AIRPORT FILL AREA I Phone No: 'Vendor
Tt SURFACE WATER
uo Client JOHN TOEPFER, BRYAN MOELLER, :POD x
s DEE O'BRIEN, JOSH STOWE, CONNOR ZAHORA ;
_
PACE
.-.•-.----- 21CI.-__-_
i Filtration (0.45 um)
Drinking
_-- _.._.._..-..............
O
Water_ UST
RCRA Waste
...... _.._.._...... ..........................
Unfiltered
_
!1 Filtered
€ Operating Unit: AE00 Process: BENVWS Account: i
�r
! Preservative
ICE
ICE
-
_ `- -
Project: Activity ID: Facility ID: ASA
PO 10624878
Container Volume (ml.)
300
500
2000
250
Program / EQuiS Task Code: Sub-ProgremlTask Code:
Container Type
PET
HOPE
PET
HOPE
COMPLIANCE/STRFL
m
Q p
ICP TRM (6010D); AI, Be, B.
ut
_
v
Customer to complete all appropriate non -shaded areas. N �
O a?
to =
Ca, Cu, Fe, Mg, Mn,K, Na,
Sr, Zn, Hardness
2
c
-..-..-.._.._.._..- Sample Description or ID
�'?
IMS TRM (8020B): Sb, As,
G
w
V
I I
i SAMPLE ID i -
Collection Information
E
Q 0)
Y O
Be, CA, Or. Co, Pb, later, NI,
Se TI(LL), V(LL) Fig 7470A
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to
m
a
_
n
i NUMBER i Date
Time Printed Name
a
Signature u t7
¢ Q
O
~
2023001342
ASA SW-2-Al
144-�3
06SS
COIVivOQ Zgt.jaA
x
1
7
1
1
4
-I
2023001343 ;
ASA SW-3-Al
IWO
x
1
1
1
1
4
2023001344
ASA SW-4B-Al
0%55
x
1
t
1
1
a
20230013451
ASA_ p�-
x
1
1
t
1
2023001346 is
ASA SW-6-Al
tD30
x
1
1
1
1
4
2023001347 !
ASA evvw- t-
x
1
1
1
1
+-
12023001348
C72.
x
1
1
1
1
+
j 2023001349
_
ASA SW-9-Al
0940
x
1
1
1
1
a
-
0
! 2023001350 !
i
ASA FlIB- 202i 6126 - 0415
1-U-23
04S
[CrYW22AHORd1
x
t
1
3
2023001351 !
ASA EB- 2023012(e- 0150
oov
x
1
1
1
3
2023001352 i
ASA _FB- 2b'00IV, - 0"t55
01SS
X
1
1
2
o
0
i
0
o
0
I
0
r-i
i I
TOTAL #CONTAINERS
0
0
11
11
0
8
0
0
0
0
0
10
0
40
Customer o sign & date below
Relinquished By DateRlme
5o
Acce d By:
DatelTima
Requested Turnaround
Total
40
13
c
/. , j
5 .y o
21 Days
Refinqujilhed By DateRlme
Accepted By: Date/Time
c
aw
E
c E
14 Days s V •
2
l
Relinqutshe DatarTime,
Accepted y: Date/Time
0 d
'7 Days
y
Seal/Locked By DateRlme
SealedlLoek Opened By Date/Time
E 'm
v
Comments
o
Other
NOTE: NCDEQ EDD and EQUIS REQUIRED
a
U
' Add. Cost Will Apply