MO-28858_48068_CA_LTRRPT_20230222

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC
www.excelengr.com

LIST OF TABLES

TABLE 1 – LIQUID LEVEL DATA

TABLE 2A – SOIL SUMMARY DATA (LSA)

TABLE 2B – SOIL SUMMARY DATA (RAR)

TABLE 3 – GROUNDWATER SUMMARY DATA

TABLE 4 – FIELD MEASUREMENTS OF GROUNDWATER SAMPLES

Table 1 - Liquid Level DataSam's Mart 749810 University City Boulevard, Charlotte, North CarolinaNCDEQ Incident 48068Excel Project No. 2021126WELL NUMBERDATE INSTALLEDWELL DEPTH (ft)SCREEN INTERVAL (ft)TOC (ft)DATE MEASUREDDTW (ft) WTE (ft)MW-130-Nov-21 15 5-15 100.00 -- NM --MW-230-Jun-22 19 9-19 102.38 -- NM --MW-325-Jul-22 24 14-24 99.74 -- NM --MW-45-Aug-22 22 12-22 99.83 -- NM --MW-530-Jan-23 22 17-22 97.53 31-Jan-23 7.45 90.08VW-130-Jun-22 35 30-35 99.93 -- NM --NOTES:Data provided in feet unless otherwise notedDTW - Depth to WaterWTE - Water Table Elevation TOC elevation for MW-1 set to datum of 100'
Table 2A - Soil Summary Data - LSASam's Mart 749810 University City Boulevard, Charlotte, North CarolinaNCDEQ Incident 48068Excel Project No. 20211265 ft10 ftDATE SAMPLEDPID READING7921,957------EPH C9 - C18 Aliphatics< 2.61 3.14 J -- -- --EPH C19 - C36 Aliphatics2.74 B J 2.83 B J -- 31,000810,000EPH C11 - C22 Aromatics3.2 B J 2.97 B J -- -- --VPH C5 - C8 Aliphatics3.52 J 6.19 B J68 93924,528VPH C9 - C12 Aliphatics< 2.36 < 3.09 -- -- --VPH C9 - C10 Aromatics2.78 J 4.55 J -- -- --TOTAL C9 - C18 AliphaticsBDL 3.14 J540 1,50040,000TOTAL C9 - C22 Aromatics5.98 J 7.52 J31 46912,264BENZENE0.00569 J0.0013 J0.005618164TOLUENE< 0.0147 < 0.002424.31,20032,000ETHYLBENZENE0.00841 J 0.00274 J4.91,56040,000XYLENES0.0394 J 0.01444.63,12981,760MTBE< 0.00396 0.0510.0913503,100NAPHTHALENE< 0.0551 0.0145 J0.163138,176ISOPROPYLBENZENE0.01 B J 0.00218 B J1.71,56440,880n-PROPYLBENZENE0.0117 J 0.00576 J1.762616,3501,2,4-TRIMETHYLBENZENE0.0931 0.03988.578220,4401,3,5-TRIMETHYLBENZENE0.028 J 0.01428.578220,440NAPHTHALENE< 0.0101 < 0.01060.163138,176PYRENE< 0.0079 < 0.0081927046912,2642-METHYLNAPHTHALENE0.00641 J < 0.005463.6631,635NOTES:Data in mg/kgMADEP - Massachussetts Dept. of Environmental ProtectionFBGL - Feet Below Grade LevelEPH - Extractable Petroleum HydrocarbonsVOC - Volatile Organic CompoundVPH - Volatile Petroleum HydrocarbonsSVOC - Semi-Volatile Organic CompoundBold data represents constituents above Soil-to-Water MSCCs (Maximum Soil Contaminant Concentrations)Highlighted data represent constituents above Residential Soil Cleanup Levels Italicized data represent constituents above Industrial / Commercial Soil Cleanup LevelsJ - Reported value is an estimateB - The same analyte was found in the associated blankResidential Soil Cleanup LevelsIndustrial / Commercial Soil Cleanup Levels30-Nov-21SVOCsMADEPVOCsSAMPLE LOCATIONSoil-to-Water MSCCsMW-1
5 ft10 ft5 ft10 ft5 ft10 ft5 ft10 ft5 ft10 ftDATE SAMPLEDPID READING456.0 1,8900.00.00.00.30.00.01,211 1,418--TPH GRO2.24 B J816 Q< 0.854 < 0.788 < 0.821 < 0.952 < 0.746 < 0.773 4.8629350TPH DRO< 0.873104< 0.983 < 0.932 < 0.960 < 1.04 < 0.9 < 0.927 < 8.815.6100NOTES:Data in mg/kg Bold data represents constituents above NCDEQ Action LevelsFBGL - Feet Below Grade Level B- Same analyte is found in associated blankTPH - Total Petroleum Hydrocarbons J- ID of analyte is acceptable, reported value is estimateGRO - Gasoline Range Organics Q - Sample analyzed past holding timeDRO - Diesel Range OrganicsSAMPLE LOCATIONNCDEQ Action LevelsTable 2B - Soil Summary Data - TPH GRO & DRO9810 University City Boulevard, Charlotte, North CarolinaNCDEQ Incident 48068 Excel Project 2021126Sam's Mart 7428-Jun-2230-Jun-225-Aug-22VW-1MW-2MW-3MW-4MW-530-Jan-23
Table 3 - Groundwater Summary DataSam's Mart 749810 University City Boulevard, Charlotte, North CarolinaNCDEQ Incident 48068 Excel Project No. 2021126SAMPLE LOCATIONMW-2 MW-3 MW-4 MW-5 VW-1DATE SAMPLED2-Dec-21 9-Aug-22 9-Aug-22 9-Aug-22 9-Aug-22 31-Jan-23 25-Jul-22EPH C9 - C18 Aliphatics58.7 J < 33.3 < 33.3 < 33.3 < 33.3 157 < 33.3 -- --EPH C19 - C36 Aliphatics110 B J 86.8 J < 33.3 < 33.3 33.8 J 252 118 B10,000 --EPH C11 - C22 Aromatics611 406 < 33.3 34.5 J < 33.3 674 35.0 BJ -- --VPH C5 - C8 Aliphatics44,600 46,400< 33.315,500< 33.33,020262 B400 --VPH C9 - C12 Aliphatics35,300 21,500 < 33.3 < 833 < 33.3 9,320 33.9 BJ -- --VPH C9 - C10 Aromatics6,920 6,800 < 33.3 < 833 < 33.3 8,480 <33.3 -- --TOTAL C9 - C18 Aliphatics35,358.7 21,500BDL BDL BDL9,47733.9700 --TOTAL C9 - C22 Aromatics7,531 7,206BDL 34.5 J BDL9,15435200 --BENZENE 10,300 12,700< 0.094113.6 J< 0.094110.7 19.4 1 5,000TOLUENE 8,330 5,400< 0.278 < 6.95 < 0.278 <13.9 1.17600 260,000ETHYLBENZENE 3,870 3,050< 0.137 < 3.43 < 0.1377050.174 J600 84,500TOTAL XYLENES 13,670 11,900< 0.604 < 15.05 < 0.6042,2811.257 J500 85,500MTBE 14,500 23,3000.332 J30,200< 0.1011,230 331 20 20,000NAPHTHALENE 525 512 J< 1 < 25 < 1175 J< 16 6,000N-PROPYLBENZENE556302< 0.0993 < 2.48 < 0.0993433< 0.099370 30,0001,2,4-TRIMETHYLBENZENE2,870 2,330< 0.322 < 8.05 < 0.3222,720< 0.322400 28,5001,3,5-TRIMETHYLBENZENE795605< 0.104 < 2.60 < 0.104740< 0.104400 25,000DI-ISOPROPYL ETHER236472< 0.105827< 0.10572.711.370 70,000sec-BUTYLBENZENE21.3 < 25.0 < 0.125 < 3.13 < 0.125 29.8 J < 0.12570 8,500n-BUTYLBENZENE20.1 < 31.4 < 0.157 < 3.93 < 0.157 43.1 J < 0.15770 6,9002-BUTANONE (MEK)54.7 J < 238 < 1.19 < 29.8 < 1.19 < 59.5 < 1.194,000 4,000,000STYRENE44.8 51.3 J < 0.118 < 2.95 < 0.118 < 5.9 < 0.11870 70,000ISOPROPYLBENZENE199122 J< 0.105 7.66 J < 0.1051040.147 J70 25,000p-ISOPROPYLTOLUENE9.0 J32.1 J< 0.120 < 3 < 0.120 13.6 J < 0.12025 11,700ETHYLENE DIBROMIDE (EDB) by 504.1< 0.00547 J4 NA < 0.00547 < 0.00547 < 0.00547 <0.00541 < 0.00547 J40.02 50t-AMYL ALCOHOL (TAA)NA5,440 J< 4.904,270< 4.90 < 245 33.8 J40 40,000TERT-BUTYL ALCOHOL (TBA)NA< 812 < 4.0629,200< 4.06 < 203 58.6 10 10,000TERT-AMYL METHYL ETHER (TAME)NA1,400< 0.195698< 0.195 37.6 J17128 128,000NAPHTHALENE2542140.906 J < 0.159 < 0.1591080.267 J66,000PHENOL3735.2< 4.33 < 4.33 < 4.33<4.33< 4.3330 30,0002,4-DIMETHYLPHENOL121< 0.0636 < 0.0636 < 0.0636 < 0.0636 <0.0636 < 0.0636100 100,000DIETHYL PHTHALATE2.26 J 0.411 J < 0.287 < 0.287 0.376 J <0.287 < 0.2876,000 --PHENANTHRENE0.165 J < 0.112 < 0.112 0.117 J < 0.112 0.457 J 0.143 J200 550DI-N-BUTYL PHTHALATE< 0.453 < 0.453 < 0.453 < 0.453 < 0.453 <0.453 0.729 J700 --MetalsLEAD95.13.12 J 3.41 J27.7 J< 2.9921.27.8915 15,000NOTES:Data in ug/lMTBE - Methyl Tert Butyl EtherMADEP - Massachusetts Dept. of Environmental Protection J - Reported value is an estimateEPH - Extractable Petroleum Hydrocarbons J4- batch QC outside established QC range for accuracyVPH - Volatile Petroleum Hydrocarbons B - The same analyte was found in the associated blankVOC - Volatile Organic Compound NA - Not AnalyzedSVOC - Semi-Volatile Organic Compound BDL - Below Detect Level Bold data represents constituents above NCAC 2L Standards Add'tl Results 8/9/22 Sampling: MW-3 - ETBE 6.72 J ug/l Highlighted data represent constituents above GCL Standards VOCsMADEPSVOCsNCAC 2L GCLMW-1
Electrical
Conductivity ORP
(µS/cm)
MW-1
MW-2
MW-3
MW-4
MW-5 5.78 0.556 226 12.08 18.57
VW-1
Notes:SU Standard units
µS/cm Microsiemens per centimeter
ppm Parts per million
0C Degrees Celsius
NS Not sampled, (Dry, Not Located, Destroyed, etc…)
MW Monitoring Well
1/31/23
Not Sampled
Not Sampled
Not Sampled
Not Sampled
Not Sampled
TABLE 4
FIELD MEASUREMENTS OF THE GROUNDWATER SAMPLES
Sam's Mart No. 74
9810 University City Blvd, Charlotte, North Carolina
Excel Project No. 2021126
Well
Identification
Sampling
Date
pH
(su)
Temperature
(0C)
Disolved
Oxygen
(ppm)

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC
www.excelengr.com

LIST OF FIGURES

FIGURE 1 – SITE VICINITY MAP

FIGURE 2 – SITE PLAN

FIGURE 3 – GROUNDWATER CONTOUR MAP

FIGURE 4 – GROUNDWATER CONSTITUENTS MAP

FIGURE 5 – BENZENE GW CONSTITUENTS MAP

FIGURE 6 – MTBE GW CONSTITUENTS MAP

FIGURE 7 – SOIL CONSTITUENTS MAP

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC 625 HUNTSMAN COURT GASTONIA, NC 28054 Figure 1 - Topographic Map Excel No. 2021126  N Source: USGS Harrisburg 2016
--
40 0 ---40
GRAPHIC BAR SCALE 1" = 40'
--
0
80 120
II 11 II 11 II 11 ii ii II ii II 11 1u1 s
LEGEND
Property Line (Approximate)
Roadway Centerline (Approximate)
Approximate UST Locations
Dispenser Pump Locations
Monitor Well Location
fi Hart & Hickman Temp Monitoring Well
'tl&HTMW-#
"@... Light Pole LP
+-
NOTES
Product Lines
Landscaping / Vegetation
Structure
Direction Arrow
Map not exact for sampling location
references only
Map adapted from Hart & Hickman Site Plan dated 7-9-2021., titled NCDOT Parcel 25.
Structure locations are approximate
UST -Underground Storage Tank
Excel CYv1l & Environmental Associates,, PLLC
625 HUNTSMAN COURT, GASTONIA, NC 28054
PREPARED FOR: SAM'S MART, INC
PHONE : [phone]
MAP TITLE:
PROJECT NO. :
2021126
SAM'S MART NO. 74 9810 & 9816 UNIVERSITY CITY BOULEVARD-CHARLOTTE NC
FIGURE 2 -- SITE PLAN LETTER REPORT
DRAWN BY : BJPJ APPROX. SCALE : DATE : 02/11/2022
REVSD BY : ACL 1" = 40' DATE: 2/21/2023
--
BWN VESTMENTS LLC
�PB24167PG611
87.4' &
40 0 ---40
GRAPHIC BAR SCALE 1" = 40'
80
---=--=--=--=--=---=---=---=---=---=--=-=---=---=---=-7----------"'
0
120
I '-
___ j ____ _)
--
II 11 II 11 II 11 II 11 II 11 II 11 1u1 s LEGEND
Property Line (Approximate)
Roadway Centerline (Approximate)
Approximate UST Locations
Dispenser Pump Locations
Monitor Well Location
Hart & Hickman Temp Monitoring Well
Approximate water table contour
[80.68'] Water Table Elevation
"@... Light Pole LP
NOTES
Product Lines
Landscaping / Vegetation
Structure
Direction Arrow
Map prepared from data collected on 8/9/22 MW-5 not used in creation of coutours Map not exact for sampling location
references only
Map adapted from Hart & Hickman
Site Plan dated 7-9-2021., titled NCDOT Parcel 25.
Structure locations are approximate
UST -Underground Storage Tank
Excel CYv1l & Environmental Associates,, PLLC
625 HUNTSMAN COURT, GASTONIA, NC 28054 PHONE : [phone]
PREPARED FOR: SAM'S MART, INC SAM'S MART NO. 74 9810 &9816 UNIVERSITY CITY BOULEVARD-CHARLOTTE NC
MAP TITLE: FIGURE 3 --GROUNDWATER COUNTOUR MAPLETTER REPORT
PROJECT NO. : DRAWN BY: BJPJ APPROX. SCALE : DATE: 02/11/2022
2021126 REVSD BY : ACL 1" = 40' DATE: 2/21/2023
< 0.137
< 0.604
< 0.101
< 1
/ BWN INVESTMEN
___ - � _,, PB 24167 PG 611
12,700
5,400
3,050
1.257 J
40 0 ---40
GRAPHIC BAR SCALE 1" = 40'
80
---=--=--=--=--=---=---=---=---=---=--=-=---=---=---=-7----------"'
0
0
120
I '-
___ j ____ _)
II 11 II 11 II 11 II 11 II 11 II 11 1u1
LEGEND
Property Line (Approximate)
Roadway Centerline (Approximate)
Approximate UST Locations
Dispenser Pump Locations
Monitor Well Location
fi Hart & Hickman Temp Monitoring Well
+l&HTMW-#
'@.. Light Pole LP
Product Lines
Landscaping / Vegetation
Structure
NOTES
Map not exact for sampling location
references only
Map adapted from Hart & Hickman Site Plan dated 7-9-2021., titled NCDOT Parcel 25.
Structure locations are approximate
UST -Underground Storage Tank
Data provided in ug/I
Data from samples collected on 7-25 & 8-9-2022.
Data from MW-5 from samples collected on 1-31-2023.
Data in orange exceeds NCDEQ GCLs
Benzene
Toluene
Ethyl benzene
Total Xylenes Constituents Shown MTBE
Napthalene
C9 -C18 Aliphatics
C9 -C22 Aromatics
Excel CYv1l & Environmental Associates,, PLLC
625 HUNTSMAN COURT, GASTONIA, NC 28054 PHONE : [phone]
PREPARED FOR: SAM'S MART, INC SAM'S MART NO. 74
MAP TITLE:
PROJECT NO. :
2021126
9810 &9816 UNIVERSITY CITY BOULEVARD-CHARLOTTE NC
FIGURE 4 --GROUNDWATER CONSITUENTS MAPLETTER REPORT
DRAWN BY : BJPJ APPROX. SCALE : DATE : 02/11/2022
REVSD BY : ACL 1" = 40' DATE: 2/21/2023
40 0 40
GRAPHIC BAR SCALE 1" = 40'
--=---=----=---=---=---=---=---=--=--=--=--=---=---=--=--=--=--=--=-=-7--------"---,
----
---=------
0
0
80 120
I ' ___ _j ____ _)
---
II 11 II 11 II 11 II 11 II 11 II 11 LJI
LEGEND
L__J
Property Line (Approximate)
Roadway Centerline (Approximate)
Approximate UST Locations
Dispenser Pump Locations
Monitor Well Location
_)B Hart & Hickman Temp Monitoring Well
+i&�TMW-#
'@... Light Pole LP
-
NOTES
Product Lines
Landscaping / Vegetation
Structure
Direction Arrow
Benzene Constituent of concern
Benzene lsoconcentration Line
Map not exact for sampling location & for reference only.
Map adapted from Hart & Hickman Site Plan Site Plan dated 7-9-2021., titled NCDOT Parcel 25. Data provided in ug/I
Data from samples collected on 7/25 & 8/9/2022. Data from MW-5 from samples collected on 1-31-2023.
Data in orange exceeds NCDEQ GCLs Structure locations are approximate UST -Underground Storage Tank
Excel Civil & Environmental Associate� PLLC
625 HUNTSMAN COURT, GASTONIA, NC 28054 PHONE: [phone]
PREPARED FOR: SAM'S MART, INC. SAM'S MART NO. 74 9810& 9816 UNIVERSITY CITY BOULEVARD-CHARLOTTE NC
MAP TITLE: FIGURE 5 --BENZENE CONSTITUENTS LETTER REPORT
PROJECT NO. : DRAWN BY: BJPJ APPROX. SCALE : DATE: 02/11/2022
2021126 REVSD BY : ACL 1" = 40' DATE: 2/21/2023
40 0 ---
--:;...------
40
GRAPHIC BAR SCALE 1" = 40'
--
80
---=--=--=--=--=---=---=---=---=---=--=-=---=---=---=-7----------"'
---------
0
120
I '-
___ j ____ _)
--
--
0
II 11 II 11 II 11 II 11 II 11 II 11 1u1 LEGEND
Property Line (Approximate) s
Roadway Centerline (Approximate)
Approximate UST Locations
Dispenser Pump Locations
Monitor Well Location
� Hart & Hickman Temp Monitoring Well
f'.i&HTMW-#
'@._ Light Pole LP
oO
�
20,000
NOTES
Product Lines
Landscaping / Vegetation
Structure
Direction Arrow
MTBE Constituent of concern
Map not exact for sampling location references only
Map adapted from Hart & Hickman Site Plan dated 7-9-2021., titled NCDOT Parcel 25.
Structure locations are approximate
UST - Underground Storage Tank
Data provided in ug/I
Data from samples collected on 7/25 & 8/9/2022.
Data from MW-5 from samples collected on 1/31/2023.
Data in orange exceeds NCDEQ GCLs
lsoconcentration Line Dashed where inferred
Excel CYv1l & Environmental Associates,, PLLC
625 HUNTSMAN COURT, GASTONIA, NC 28054 PHONE : [phone]
PREPARED FOR: SAM'S MART, INC SAM'S MART NO. 74 9810 &9816 UNIVERSITY CITY BOULEVARD-CHARLOTTE NC
MAP TITLE: FIGURE 6 -- MTBE CONSTITUENTS MAP LETTER REPORT
PROJECT NO. : DRAWN BY: BJPJ APPROX. SCALE : DATE: 02/11/2022
2021126 REVSD BY : ACL 1" = 40' DATE: 2/21/2023

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC
www.excelengr.com

LIST OF APPENDICES

APPENDIX A – MONITORING WELL CONSTRUCTION FORMS

APPENDIX B – LABORATORY REPORTS & CHAIN OF CUSTODY FORM(S)

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC
www.excelengr.com

APPENDIX A

MONITORING WELL CONSTRUCTION FORMS

EXCEL CIVIL & ENVIRONMENTAL ASSOCIATES, PLLC
www.excelengr.com

APPENDIX B

LABORATORY REPORTS & CHAIN OF CUSTODY FORM(S)
ANALYTICAL REPORT
February 13, 2023
Excel Civil & Environmental Associates
Sample Delivery Group:L1582427
Samples Received:02/04/2023
Project Number:2021126
Description:Sam's Mart 74
Report To:Aaron Long
625 Huntsman Court
Gastonia, NC 28054
Entire Report Reviewed By:
February 13, 2023
[Preliminary Report]
Heather J Wagner
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received.
Pace Analytical National
12065 Lebanon Rd Mount Juliet, TN 37122 615-758-5858 800-767-5859 www.pacenational.com
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
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February 13, 2023
Heather J Wagner
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 1 of 34
TABLE OF CONTENTS
Cp: Cover Page 1
Tc: Table of Contents 2
Ss: Sample Summary 3
Cn: Case Narrative 4
Sr: Sample Results 5
MW5 5FT L1582427-01 5
MW5 10FT L1582427-02 6
MW5 L1582427-03 7
TRIP BLANK L1582427-04 11
Qc: Quality Control Summary 13
Total Solids by Method 2540 G-2011 13
Metals (ICP) by Method 6010D 14
Volatile Petroleum Hydrocarbons by Method MADEPV 15
Volatile Organic Compounds (GC) by Method 8015C 16
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 18
EDB / DBCP by Method 504.1 23
Semi-Volatile Organic Compounds (GC) by Method 8015C 24
TPH by Method MADEPE 25
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 26
Gl: Glossary of Terms 31
Al: Accreditations & Locations 32
Sc: Sample Chain of Custody 33
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SAMPLE SUMMARY
Collected by Collected date/time Received date/time
MW5 5FT L1582427-01 Solid Justin Espana 01/30/23 13:50 02/04/23 10:20
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Total Solids by Method 2540 G-2011 WG2000904 1 02/08/23 09:48 02/08/23 09:54 CMK Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method 8015C WG2004757 25 02/06/23 11:58 02/13/23 02:10 ACG Mt. Juliet, TN
Semi-Volatile Organic Compounds (GC) by Method 8015C WG2001268 10 02/08/23 10:41 02/09/23 01:51 JAS Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW5 10FT L1582427-02 Solid Justin Espana 01/30/23 14:00 02/04/23 10:20
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Total Solids by Method 2540 G-2011 WG2000904 1 02/08/23 09:48 02/08/23 09:54 CMK Mt. Juliet, TN
Volatile Organic Compounds (GC) by Method 8015C WG2003118 1000 02/06/23 11:58 02/10/23 04:19 DWR Mt. Juliet, TN
Semi-Volatile Organic Compounds (GC) by Method 8015C WG2001268 1 02/08/23 10:41 02/08/23 21:43 JAS Mt. Juliet, TN
Collected by Collected date/time Received date/time
MW5 L1582427-03 GW Justin Espana 01/30/23 14:05 02/04/23 10:20
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Metals (ICP) by Method 6010D WG2001882 1 02/08/23 11:15 02/08/23 14:35 ZSA Mt. Juliet, TN
Volatile Petroleum Hydrocarbons by Method MADEPV WG2001163 50 02/07/23 12:43 02/07/23 12:43 ADM Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 WG2001664 50 02/07/23 21:00 02/07/23 21:00 ACG Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 WG2003348 50 02/09/23 15:35 02/09/23 15:35 JAH Mt. Juliet, TN
EDB / DBCP by Method 504.1 WG2002929 1.01 02/09/23 12:40 02/09/23 18:30 KKS Mt. Juliet, TN
TPH by Method MADEPE WG2002247 3 02/08/23 05:15 02/09/23 16:17 DMG Mt. Juliet, TN
TPH by Method MADEPE WG2002247 3 02/08/23 05:15 02/09/23 19:44 DMG Mt. Juliet, TN
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 WG2000359 1 02/06/23 06:31 02/07/23 10:40 DSH Mt. Juliet, TN
Collected by Collected date/time Received date/time
TRIP BLANK L1582427-04 GW Justin Espana 01/30/23 00:00 02/04/23 10:20
Method Batch Dilution Preparation Analysis Analyst Location
date/time date/time
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 WG2001664 1 02/07/23 17:14 02/07/23 17:14 ACG Mt. Juliet, TN
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 WG2003348 1 02/09/23 15:12 02/09/23 15:12 JAH Mt. Juliet, TN
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CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
[Preliminary Report]
Heather J Wagner
Project Manager
Sample Delivery Group (SDG) Narrative
pH outside of method requirement.
Lab Sample ID Project Sample ID Method
L1582427-03 MW5 MADEPV
1 Cp
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Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 11:42 4 of 34
Heather J Wagner
Project Manager
ACCOUNT:PROJECT:SDG:DATE/TIME:PAGE:
Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 4 of 34
SAMPLE RESULTS - 01
L1582427
MW5 5FT
Collected date/time: 01/30/23 13:50
Total Solids by Method 2540 G-2011
Result Qualifier Dilution Analysis Batch
Analyte %date / time
Total Solids 87.4 1 02/08/2023 09:54 WG2000904
Volatile Organic Compounds (GC) by Method 8015C
Result (dry)Qualifier MDL (dry)RDL (dry)Dilution Analysis Batch
Analyte ug/kg ug/kg ug/kg date / time
TPH (GC/FID) Low Fraction 4860 B 700 3220 25 02/13/2023 02:10 WG2004757
(S)
a,a,a-Trifluorotoluene(FID)96.9 77.0-120 02/13/2023 02:10 WG2004757
Semi-Volatile Organic Compounds (GC) by Method 8015C
Result (dry)Qualifier MDL (dry)RDL (dry)Dilution Analysis Batch
Analyte ug/kg ug/kg ug/kg date / time
TPH (GC/FID) High Fraction U J3 J5 8800 45800 10 02/09/2023 01:51 WG2001268
(S) o-Terphenyl 62.8 18.0-148 02/09/2023 01:51 WG2001268
Sample Narrative:
L1582427-01 WG2001268: Cannot run at lower dilution due to viscosity of extract
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 5 of 34
SAMPLE RESULTS - 02
L1582427
MW5 10FT
Collected date/time: 01/30/23 14:00
Total Solids by Method 2540 G-2011
Result Qualifier Dilution Analysis Batch
Analyte %date / time
Total Solids 80.1 1 02/08/2023 09:54 WG2000904
Volatile Organic Compounds (GC) by Method 8015C
Result (dry)Qualifier MDL (dry)RDL (dry)Dilution Analysis Batch
Analyte ug/kg ug/kg ug/kg date / time
TPH (GC/FID) Low Fraction 293000 B 32500 150000 1000 02/10/2023 04:19 WG2003118
(S)
a,a,a-Trifluorotoluene(FID)93.0 77.0-120 02/10/2023 04:19 WG2003118
Semi-Volatile Organic Compounds (GC) by Method 8015C
Result (dry)Qualifier MDL (dry)RDL (dry)Dilution Analysis Batch
Analyte ug/kg ug/kg ug/kg date / time
TPH (GC/FID) High Fraction 15600 960 4990 1 02/08/2023 21:43 WG2001268
(S) o-Terphenyl 58.7 18.0-148 02/08/2023 21:43 WG2001268
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 6 of 34
SAMPLE RESULTS - 03
L1582427
MW5
Collected date/time: 01/30/23 14:05
Metals (ICP) by Method 6010D
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Lead 21.2 2.99 6.00 1 02/08/2023 14:35 WG2001882
Volatile Petroleum Hydrocarbons by Method MADEPV
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Unadjusted C5-C8 Aliphatics 3020 J 1670 5000 50 02/07/2023 12:43 WG2001163
Unadjusted C9-C12 Aliphatics 9320 1670 5000 50 02/07/2023 12:43 WG2001163
Unadjusted C9-C10 Aromatics 8480 1670 5000 50 02/07/2023 12:43 WG2001163
Total VPH 20800 1670 5000 50 02/07/2023 12:43 WG2001163
(S) 2,5-Dibromotoluene(FID)93.3 70.0-130 02/07/2023 12:43 WG2001163
(S) 2,5-Dibromotoluene(PID)88.8 70.0-130 02/07/2023 12:43 WG2001163
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 565 2500 50 02/07/2023 21:00 WG2001664
Acrolein U C4 J3 127 2500 50 02/07/2023 21:00 WG2001664
Acrylonitrile U 33.6 500 50 02/07/2023 21:00 WG2001664
Benzene 10.7 J 4.71 50.0 50 02/07/2023 21:00 WG2001664
Bromobenzene U 5.90 50.0 50 02/07/2023 21:00 WG2001664
Bromodichloromethane U 6.80 50.0 50 02/07/2023 21:00 WG2001664
Bromoform U 6.45 50.0 50 02/07/2023 21:00 WG2001664
Bromomethane U 30.3 250 50 02/07/2023 21:00 WG2001664
n-Butylbenzene 43.1 J 7.85 50.0 50 02/07/2023 21:00 WG2001664
sec-Butylbenzene 29.8 J 6.25 50.0 50 02/07/2023 21:00 WG2001664
tert-Butylbenzene U 6.35 50.0 50 02/07/2023 21:00 WG2001664
Carbon tetrachloride U 6.40 50.0 50 02/07/2023 21:00 WG2001664
Chlorobenzene U 5.80 50.0 50 02/07/2023 21:00 WG2001664
Chlorodibromomethane U 7.00 50.0 50 02/07/2023 21:00 WG2001664
Chloroethane U 9.60 250 50 02/07/2023 21:00 WG2001664
Chloroform U 5.55 250 50 02/07/2023 21:00 WG2001664
Chloromethane U 48.0 125 50 02/07/2023 21:00 WG2001664
2-Chlorotoluene U 5.30 50.0 50 02/07/2023 21:00 WG2001664
4-Chlorotoluene U 5.70 50.0 50 02/07/2023 21:00 WG2001664
1,2-Dibromo-3-Chloropropane U 13.8 250 50 02/07/2023 21:00 WG2001664
1,2-Dibromoethane U 6.30 50.0 50 02/07/2023 21:00 WG2001664
Dibromomethane U 6.10 50.0 50 02/07/2023 21:00 WG2001664
1,2-Dichlorobenzene U 5.35 50.0 50 02/07/2023 21:00 WG2001664
1,3-Dichlorobenzene U 5.50 50.0 50 02/07/2023 21:00 WG2001664
1,4-Dichlorobenzene U 6.00 50.0 50 02/07/2023 21:00 WG2001664
Dichlorodifluoromethane U 18.7 250 50 02/07/2023 21:00 WG2001664
1,1-Dichloroethane U 5.00 50.0 50 02/07/2023 21:00 WG2001664
1,2-Dichloroethane U 4.09 50.0 50 02/07/2023 21:00 WG2001664
1,1-Dichloroethene U 9.40 50.0 50 02/07/2023 21:00 WG2001664
cis-1,2-Dichloroethene U 6.30 50.0 50 02/07/2023 21:00 WG2001664
trans-1,2-Dichloroethene U 7.45 50.0 50 02/07/2023 21:00 WG2001664
1,2-Dichloropropane U 7.45 50.0 50 02/07/2023 21:00 WG2001664
1,1-Dichloropropene U 7.10 50.0 50 02/07/2023 21:00 WG2001664
1,3-Dichloropropane U 5.50 50.0 50 02/07/2023 21:00 WG2001664
2,2-Dichloropropane U 8.05 50.0 50 02/07/2023 21:00 WG2001664
Di-isopropyl ether 72.7 5.25 50.0 50 02/07/2023 21:00 WG2001664
Ethylbenzene 705 6.85 50.0 50 02/07/2023 21:00 WG2001664
Hexachloro-1,3-butadiene U 16.9 50.0 50 02/07/2023 21:00 WG2001664
Isopropylbenzene 104 5.25 50.0 50 02/07/2023 21:00 WG2001664
p-Isopropyltoluene 13.6 J 6.00 50.0 50 02/07/2023 21:00 WG2001664
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 7 of 34
SAMPLE RESULTS - 03
L1582427
MW5
Collected date/time: 01/30/23 14:05
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
2-Butanone (MEK)U 59.5 500 50 02/07/2023 21:00 WG2001664
Methylene Chloride U 21.5 250 50 02/07/2023 21:00 WG2001664
4-Methyl-2-pentanone (MIBK)U 23.9 500 50 02/07/2023 21:00 WG2001664
Methyl tert-butyl ether 1230 5.05 50.0 50 02/07/2023 21:00 WG2001664
Naphthalene 175 J 50.0 250 50 02/07/2023 21:00 WG2001664
n-Propylbenzene 433 4.97 50.0 50 02/07/2023 21:00 WG2001664
Styrene U 5.90 50.0 50 02/07/2023 21:00 WG2001664
1,1,1,2-Tetrachloroethane U 7.35 50.0 50 02/07/2023 21:00 WG2001664
1,1,2,2-Tetrachloroethane U 6.65 50.0 50 02/07/2023 21:00 WG2001664
Tetrachloroethene U 15.0 50.0 50 02/07/2023 21:00 WG2001664
Toluene U 13.9 50.0 50 02/07/2023 21:00 WG2001664
1,2,3-Trichlorobenzene U 11.5 50.0 50 02/07/2023 21:00 WG2001664
1,2,4-Trichlorobenzene U 24.1 50.0 50 02/07/2023 21:00 WG2001664
1,1,1-Trichloroethane U 7.45 50.0 50 02/07/2023 21:00 WG2001664
1,1,2-Trichloroethane U 7.90 50.0 50 02/07/2023 21:00 WG2001664
Trichloroethene U 9.50 50.0 50 02/07/2023 21:00 WG2001664
Trichlorofluoromethane U 8.00 250 50 02/07/2023 21:00 WG2001664
1,2,3-Trichloropropane U 11.9 125 50 02/07/2023 21:00 WG2001664
1,2,4-Trimethylbenzene 2720 16.1 50.0 50 02/07/2023 21:00 WG2001664
1,3,5-Trimethylbenzene 740 5.20 50.0 50 02/07/2023 21:00 WG2001664
Vinyl chloride U 11.7 50.0 50 02/07/2023 21:00 WG2001664
o-Xylene 131 J4 8.70 50.0 50 02/07/2023 21:00 WG2001664
m&p-Xylenes 2150 21.5 100 50 02/07/2023 21:00 WG2001664
Ethanol U 2100 5000 50 02/09/2023 15:35 WG2003348
Ethyl tert-butyl ether U 5.05 50.0 50 02/07/2023 21:00 WG2001664
t-Amyl Alcohol U 245 2500 50 02/07/2023 21:00 WG2001664
tert-Butyl alcohol U 203 250 50 02/09/2023 15:35 WG2003348
tert-Amyl Methyl Ether 37.6 J 9.75 50.0 50 02/07/2023 21:00 WG2001664
(S) Toluene-d8 90.5 80.0-120 02/07/2023 21:00 WG2001664
(S) Toluene-d8 98.6 80.0-120 02/09/2023 15:35 WG2003348
(S) 4-Bromofluorobenzene 84.3 77.0-126 02/07/2023 21:00 WG2001664
(S) 4-Bromofluorobenzene 98.9 77.0-126 02/09/2023 15:35 WG2003348
(S) 1,2-Dichloroethane-d4 110 70.0-130 02/07/2023 21:00 WG2001664
(S) 1,2-Dichloroethane-d4 92.4 70.0-130 02/09/2023 15:35 WG2003348
EDB / DBCP by Method 504.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Ethylene Dibromide U 0.00541 0.0202 1.01 02/09/2023 18:30 WG2002929
TPH by Method MADEPE
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Unadjusted C9-C18 Aliphatics 157 J 99.9 300 3 02/09/2023 16:17 WG2002247
Unadjusted C19-C36 Aliphatics 252 B J 99.9 300 3 02/09/2023 16:17 WG2002247
Unadjusted C11-C22 Aromatics 674 99.9 300 3 02/09/2023 19:44 WG2002247
Unadjusted Total Petroleum
Hydrocarbons 1080 99.9 300 3 02/09/2023 19:44 WG2002247
(S) o-Terphenyl 67.0 40.0-140 02/09/2023 19:44 WG2002247
(S) 1-Chloro-octadecane 63.5 40.0-140 02/09/2023 16:17 WG2002247
(S) 2-Fluorobiphenyl 92.1 40.0-140 02/09/2023 19:44 WG2002247
(S) 2-Bromonaphthalene 89.5 40.0-140 02/09/2023 19:44 WG2002247
Sample Narrative:
L1582427-03 WG2002247: Dilution due to matrix impact during extraction procedure
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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Excel Civil & Environmental Associates 2021126 L1582427 02/13/23 12:36 8 of 34
SAMPLE RESULTS - 03
L1582427
MW5
Collected date/time: 01/30/23 14:05
Semi Volatile Organic Compounds (GC/MS) by Method 625.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acenaphthene 0.433 J 0.0886 1.00 1 02/07/2023 10:40 WG2000359
Acenaphthylene U 0.0921 1.00 1 02/07/2023 10:40 WG2000359
Anthracene 0.152 J 0.0804 1.00 1 02/07/2023 10:40 WG2000359
Benzidine U 3.74 10.0 1 02/07/2023 10:40 WG2000359
Benzo(a)anthracene U 0.199 1.00 1 02/07/2023 10:40 WG2000359
Benzo(b)fluoranthene U 0.130 1.00 1 02/07/2023 10:40 WG2000359
Benzo(k)fluoranthene U 0.120 1.00 1 02/07/2023 10:40 WG2000359
Benzo(g,h,i)perylene U 0.121 1.00 1 02/07/2023 10:40 WG2000359
Benzo(a)pyrene U 0.0381 1.00 1 02/07/2023 10:40 WG2000359
Bis(2-chlorethoxy)methane U 0.116 10.0 1 02/07/2023 10:40 WG2000359
Bis(2-chloroethyl)ether U 0.137 10.0 1 02/07/2023 10:40 WG2000359
2,2-Oxybis(1-Chloropropane)U 0.210 10.0 1 02/07/2023 10:40 WG2000359
4-Bromophenyl-phenylether U 0.0877 10.0 1 02/07/2023 10:40 WG2000359
2-Chloronaphthalene U 0.0648 1.00 1 02/07/2023 10:40 WG2000359
4-Chlorophenyl-phenylether U 0.0926 10.0 1 02/07/2023 10:40 WG2000359
Chrysene U 0.130 1.00 1 02/07/2023 10:40 WG2000359
Dibenz(a,h)anthracene U 0.0644 1.00 1 02/07/2023 10:40 WG2000359
3,3-Dichlorobenzidine U 0.212 10.0 1 02/07/2023 10:40 WG2000359
2,4-Dinitrotoluene U 0.0983 10.0 1 02/07/2023 10:40 WG2000359
2,6-Dinitrotoluene U 0.250 10.0 1 02/07/2023 10:40 WG2000359
Fluoranthene U 0.102 1.00 1 02/07/2023 10:40 WG2000359
Fluorene 0.768 J 0.0844 1.00 1 02/07/2023 10:40 WG2000359
Hexachlorobenzene U 0.0755 1.00 1 02/07/2023 10:40 WG2000359
Hexachloro-1,3-butadiene U 0.0968 10.0 1 02/07/2023 10:40 WG2000359
Hexachlorocyclopentadiene U 0.0598 10.0 1 02/07/2023 10:40 WG2000359
Hexachloroethane U 0.127 10.0 1 02/07/2023 10:40 WG2000359
Indeno(1,2,3-cd)pyrene U 0.279 1.00 1 02/07/2023 10:40 WG2000359
Isophorone U 0.143 10.0 1 02/07/2023 10:40 WG2000359
Naphthalene 108 0.159 1.00 1 02/07/2023 10:40 WG2000359
Nitrobenzene U 0.297 10.0 1 02/07/2023 10:40 WG2000359
n-Nitrosodimethylamine U 0.998 10.0 1 02/07/2023 10:40 WG2000359
n-Nitrosodiphenylamine U 2.37 10.0 1 02/07/2023 10:40 WG2000359
n-Nitrosodi-n-propylamine U 0.261 10.0 1 02/07/2023 10:40 WG2000359
Phenanthrene 0.457 J 0.112 1.00 1 02/07/2023 10:40 WG2000359
Benzylbutyl phthalate U 0.765 3.00 1 02/07/2023 10:40 WG2000359
Bis(2-ethylhexyl)phthalate U 0.895 3.00 1 02/07/2023 10:40 WG2000359
Di-n-butyl phthalate U 0.453 3.00 1 02/07/2023 10:40 WG2000359
Diethyl phthalate U 0.287 3.00 1 02/07/2023 10:40 WG2000359
Dimethyl phthalate U 0.260 3.00 1 02/07/2023 10:40 WG2000359
Di-n-octyl phthalate U 0.932 3.00 1 02/07/2023 10:40 WG2000359
Pyrene U 0.107 1.00 1 02/07/2023 10:40 WG2000359
1,2,4-Trichlorobenzene U 0.0698 10.0 1 02/07/2023 10:40 WG2000359
4-Chloro-3-methylphenol U 0.131 10.0 1 02/07/2023 10:40 WG2000359
2-Chlorophenol U 0.133 10.0 1 02/07/2023 10:40 WG2000359
2,4-Dichlorophenol U 0.102 10.0 1 02/07/2023 10:40 WG2000359
2,4-Dimethylphenol U 0.0636 10.0 1 02/07/2023 10:40 WG2000359
4,6-Dinitro-2-methylphenol U 1.12 10.0 1 02/07/2023 10:40 WG2000359
2,4-Dinitrophenol U 5.93 10.0 1 02/07/2023 10:40 WG2000359
2-Nitrophenol U 0.117 10.0 1 02/07/2023 10:40 WG2000359
4-Nitrophenol U 0.143 10.0 1 02/07/2023 10:40 WG2000359
Pentachlorophenol U 0.313 10.0 1 02/07/2023 10:40 WG2000359
Phenol U 4.33 10.0 1 02/07/2023 10:40 WG2000359
2,4,6-Trichlorophenol U 0.100 10.0 1 02/07/2023 10:40 WG2000359
(S) Nitrobenzene-d5 44.2 15.0-314 02/07/2023 10:40 WG2000359
(S) 2-Fluorobiphenyl 71.6 22.0-127 02/07/2023 10:40 WG2000359
(S) p-Terphenyl-d14 70.5 29.0-141 02/07/2023 10:40 WG2000359
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 03
L1582427
MW5
Collected date/time: 01/30/23 14:05
Semi Volatile Organic Compounds (GC/MS) by Method 625.1
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
(S) Phenol-d5 14.6 8.00-424 02/07/2023 10:40 WG2000359
(S) 2-Fluorophenol 14.5 10.0-120 02/07/2023 10:40 WG2000359
(S) 2,4,6-Tribromophenol 95.1 10.0-153 02/07/2023 10:40 WG2000359
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 04
L1582427
TRIP BLANK
Collected date/time: 01/30/23 00:00
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Acetone U 11.3 50.0 1 02/07/2023 17:14 WG2001664
Acrolein U C4 J3 2.54 50.0 1 02/07/2023 17:14 WG2001664
Acrylonitrile U 0.671 10.0 1 02/07/2023 17:14 WG2001664
Benzene U 0.0941 1.00 1 02/07/2023 17:14 WG2001664
Bromobenzene U 0.118 1.00 1 02/07/2023 17:14 WG2001664
Bromodichloromethane U 0.136 1.00 1 02/07/2023 17:14 WG2001664
Bromoform U 0.129 1.00 1 02/07/2023 17:14 WG2001664
Bromomethane U 0.605 5.00 1 02/07/2023 17:14 WG2001664
n-Butylbenzene U 0.157 1.00 1 02/07/2023 17:14 WG2001664
sec-Butylbenzene U 0.125 1.00 1 02/07/2023 17:14 WG2001664
tert-Butylbenzene U 0.127 1.00 1 02/07/2023 17:14 WG2001664
Carbon tetrachloride U 0.128 1.00 1 02/07/2023 17:14 WG2001664
Chlorobenzene U 0.116 1.00 1 02/07/2023 17:14 WG2001664
Chlorodibromomethane U 0.140 1.00 1 02/07/2023 17:14 WG2001664
Chloroethane U 0.192 5.00 1 02/07/2023 17:14 WG2001664
Chloroform U 0.111 5.00 1 02/07/2023 17:14 WG2001664
Chloromethane U 0.960 2.50 1 02/07/2023 17:14 WG2001664
2-Chlorotoluene U 0.106 1.00 1 02/07/2023 17:14 WG2001664
4-Chlorotoluene U 0.114 1.00 1 02/07/2023 17:14 WG2001664
1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 02/07/2023 17:14 WG2001664
1,2-Dibromoethane U 0.126 1.00 1 02/07/2023 17:14 WG2001664
Dibromomethane U 0.122 1.00 1 02/07/2023 17:14 WG2001664
1,2-Dichlorobenzene U 0.107 1.00 1 02/07/2023 17:14 WG2001664
1,3-Dichlorobenzene U 0.110 1.00 1 02/07/2023 17:14 WG2001664
1,4-Dichlorobenzene U 0.120 1.00 1 02/07/2023 17:14 WG2001664
Dichlorodifluoromethane U 0.374 5.00 1 02/07/2023 17:14 WG2001664
1,1-Dichloroethane U 0.100 1.00 1 02/07/2023 17:14 WG2001664
1,2-Dichloroethane U 0.0819 1.00 1 02/07/2023 17:14 WG2001664
1,1-Dichloroethene U 0.188 1.00 1 02/07/2023 17:14 WG2001664
cis-1,2-Dichloroethene U 0.126 1.00 1 02/07/2023 17:14 WG2001664
trans-1,2-Dichloroethene U 0.149 1.00 1 02/07/2023 17:14 WG2001664
1,2-Dichloropropane U 0.149 1.00 1 02/07/2023 17:14 WG2001664
1,1-Dichloropropene U 0.142 1.00 1 02/07/2023 17:14 WG2001664
1,3-Dichloropropane U 0.110 1.00 1 02/07/2023 17:14 WG2001664
2,2-Dichloropropane U 0.161 1.00 1 02/07/2023 17:14 WG2001664
Di-isopropyl ether U 0.105 1.00 1 02/07/2023 17:14 WG2001664
Ethylbenzene U 0.137 1.00 1 02/07/2023 17:14 WG2001664
Hexachloro-1,3-butadiene U 0.337 1.00 1 02/07/2023 17:14 WG2001664
Isopropylbenzene U 0.105 1.00 1 02/07/2023 17:14 WG2001664
p-Isopropyltoluene U 0.120 1.00 1 02/07/2023 17:14 WG2001664
2-Butanone (MEK)U 1.19 10.0 1 02/07/2023 17:14 WG2001664
Methylene Chloride U 0.430 5.00 1 02/07/2023 17:14 WG2001664
4-Methyl-2-pentanone (MIBK)U 0.478 10.0 1 02/07/2023 17:14 WG2001664
Methyl tert-butyl ether U 0.101 1.00 1 02/07/2023 17:14 WG2001664
Naphthalene U 1.00 5.00 1 02/07/2023 17:14 WG2001664
n-Propylbenzene U 0.0993 1.00 1 02/07/2023 17:14 WG2001664
Styrene U 0.118 1.00 1 02/07/2023 17:14 WG2001664
1,1,1,2-Tetrachloroethane U 0.147 1.00 1 02/07/2023 17:14 WG2001664
1,1,2,2-Tetrachloroethane U 0.133 1.00 1 02/07/2023 17:14 WG2001664
Tetrachloroethene U 0.300 1.00 1 02/07/2023 17:14 WG2001664
Toluene U 0.278 1.00 1 02/07/2023 17:14 WG2001664
1,2,3-Trichlorobenzene U 0.230 1.00 1 02/07/2023 17:14 WG2001664
1,2,4-Trichlorobenzene U 0.481 1.00 1 02/07/2023 17:14 WG2001664
1,1,1-Trichloroethane U 0.149 1.00 1 02/07/2023 17:14 WG2001664
1,1,2-Trichloroethane U 0.158 1.00 1 02/07/2023 17:14 WG2001664
Trichloroethene U 0.190 1.00 1 02/07/2023 17:14 WG2001664
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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SAMPLE RESULTS - 04
L1582427
TRIP BLANK
Collected date/time: 01/30/23 00:00
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011
Result Qualifier MDL RDL Dilution Analysis Batch
Analyte ug/l ug/l ug/l date / time
Trichlorofluoromethane U 0.160 5.00 1 02/07/2023 17:14 WG2001664
1,2,3-Trichloropropane U 0.237 2.50 1 02/07/2023 17:14 WG2001664
1,2,4-Trimethylbenzene U 0.322 1.00 1 02/07/2023 17:14 WG2001664
1,3,5-Trimethylbenzene U 0.104 1.00 1 02/07/2023 17:14 WG2001664
Vinyl chloride U 0.234 1.00 1 02/07/2023 17:14 WG2001664
o-Xylene U J4 0.174 1.00 1 02/07/2023 17:14 WG2001664
m&p-Xylenes U 0.430 2.00 1 02/07/2023 17:14 WG2001664
Ethanol U 42.0 100 1 02/09/2023 15:12 WG2003348
Ethyl tert-butyl ether U 0.101 1.00 1 02/07/2023 17:14 WG2001664
t-Amyl Alcohol U 4.90 50.0 1 02/07/2023 17:14 WG2001664
tert-Butyl alcohol U 4.06 5.00 1 02/09/2023 15:12 WG2003348
tert-Amyl Methyl Ether U 0.195 1.00 1 02/07/2023 17:14 WG2001664
(S) Toluene-d8 94.4 80.0-120 02/07/2023 17:14 WG2001664
(S) Toluene-d8 101 80.0-120 02/09/2023 15:12 WG2003348
(S) 4-Bromofluorobenzene 82.4 77.0-126 02/07/2023 17:14 WG2001664
(S) 4-Bromofluorobenzene 98.4 77.0-126 02/09/2023 15:12 WG2003348
(S) 1,2-Dichloroethane-d4 108 70.0-130 02/07/2023 17:14 WG2001664
(S) 1,2-Dichloroethane-d4 93.1 70.0-130 02/09/2023 15:12 WG2003348
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000904
Total Solids by Method 2540 G-2011 L1582427-01,02
Method Blank (MB)
(MB) R3888931-1 02/08/23 09:54
MB Result MB Qualifier MB MDL MB RDL
Analyte %%%
Total Solids 0.000
L1582425-04 Original Sample (OS) • Duplicate (DUP)
(OS) L1582425-04 02/08/23 09:54 • (DUP) R3888931-3 02/08/23 09:54
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte %%%%
Total Solids 82.2 82.1 1 0.116 10
Laboratory Control Sample (LCS)
(LCS) R3888931-2 02/08/23 09:54
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte %%%%
Total Solids 50.0 50.0 100 85.0-115
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001882
Metals (ICP) by Method 6010D L1582427-03
Method Blank (MB)
(MB) R3888770-1 02/08/23 13:59
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Lead U 2.99 6.00
Laboratory Control Sample (LCS)
(LCS) R3888770-2 02/08/23 14:02
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Lead 1000 1080 108 80.0-120
L1581227-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1581227-01 02/08/23 14:05 • (MS) R3888770-4 02/08/23 14:10 • (MSD) R3888770-5 02/08/23 14:13
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Lead 1000 U 1060 1100 106 110 1 75.0-125 3.31 20
L1583104-05 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1583104-05 02/08/23 14:15 • (MS) R3888770-6 02/08/23 14:18 • (MSD) R3888770-7 02/08/23 14:20
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Lead 1000 U 1100 1090 110 109 1 75.0-125 0.477 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001163
Volatile Petroleum Hydrocarbons by Method MADEPV L1582427-03
Method Blank (MB)
(MB) R3888438-3 02/07/23 09:59
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Unadjusted C5-C8 Aliphatics U 33.3 100
Unadjusted C9-C12 Aliphatics U 33.3 100
Unadjusted C9-C10 Aromatics U 33.3 100
Total VPH U 33.3 100
(S) 2,5-Dibromotoluene(FID)85.8 70.0-130
(S) 2,5-Dibromotoluene(PID)83.0 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3888438-1 02/07/23 07:48 • (LCSD) R3888438-2 02/07/23 08:21
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Unadjusted C5-C8 Aliphatics 1200 1100 1130 91.7 94.2 70.0-130 2.69 25
Unadjusted C9-C12 Aliphatics 1400 1430 1460 102 104 70.0-130 2.08 25
Unadjusted C9-C10 Aromatics 200 212 214 106 107 70.0-130 0.939 25
Total VPH 2800 2740 2800 97.9 100 70.0-130 2.17 25
(S) 2,5-Dibromotoluene(FID) 98.2 93.0 70.0-130
(S) 2,5-Dibromotoluene(PID) 96.1 90.0 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2003118
Volatile Organic Compounds (GC) by Method 8015C L1582427-02
Method Blank (MB)
(MB) R3889845-1 02/09/23 21:53
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/kg ug/kg ug/kg
TPH (GC/FID) Low Fraction 752 J 543 2500
(S)
a,a,a-Trifluorotoluene(FID)93.9 77.0-120
Laboratory Control Sample (LCS)
(LCS) R3889845-2 02/09/23 22:13
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/kg ug/kg %%
TPH (GC/FID) Low Fraction 5500 4830 87.8 72.0-127
(S)
a,a,a-Trifluorotoluene(FID) 103 77.0-120
L1582287-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582287-01 02/10/23 03:38 • (MS) R3889845-3 02/10/23 06:02 • (MSD) R3889845-4 02/10/23 06:22
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/kg ug/kg ug/kg ug/kg %%%%%
TPH (GC/FID) Low Fraction 550000 233000 838000 742000 110 92.5 100 10.0-151 12.2 28
(S)
a,a,a-Trifluorotoluene(FID) 98.6 96.9 77.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2004757
Volatile Organic Compounds (GC) by Method 8015C L1582427-01
Method Blank (MB)
(MB) R3890040-2 02/13/23 01:49
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/kg ug/kg ug/kg
TPH (GC/FID) Low Fraction 590 J 543 2500
(S)
a,a,a-Trifluorotoluene(FID)95.6 77.0-120
Laboratory Control Sample (LCS)
(LCS) R3890040-1 02/13/23 00:28
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/kg ug/kg %%
TPH (GC/FID) Low Fraction 5500 5220 94.9 72.0-127
(S)
a,a,a-Trifluorotoluene(FID) 110 77.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001664
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 L1582427-03,04
Method Blank (MB)
(MB) R3889132-5 02/07/23 12:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acetone U 11.3 50.0
Acrolein U 2.54 50.0
Acrylonitrile U 0.671 10.0
Benzene U 0.0941 1.00
Bromobenzene U 0.118 1.00
Bromodichloromethane U 0.136 1.00
Bromoform U 0.129 1.00
Bromomethane U 0.605 5.00
n-Butylbenzene U 0.157 1.00
sec-Butylbenzene U 0.125 1.00
tert-Butylbenzene U 0.127 1.00
Carbon tetrachloride U 0.128 1.00
Chlorobenzene U 0.116 1.00
Chlorodibromomethane U 0.140 1.00
Chloroethane U 0.192 5.00
Chloroform U 0.111 5.00
Chloromethane U 0.960 2.50
2-Chlorotoluene U 0.106 1.00
4-Chlorotoluene U 0.114 1.00
1,2-Dibromo-3-Chloropropane U 0.276 5.00
1,2-Dibromoethane U 0.126 1.00
Dibromomethane U 0.122 1.00
1,2-Dichlorobenzene U 0.107 1.00
1,3-Dichlorobenzene U 0.110 1.00
1,4-Dichlorobenzene U 0.120 1.00
Dichlorodifluoromethane U 0.374 5.00
1,1-Dichloroethane U 0.100 1.00
1,2-Dichloroethane U 0.0819 1.00
1,1-Dichloroethene U 0.188 1.00
cis-1,2-Dichloroethene U 0.126 1.00
trans-1,2-Dichloroethene U 0.149 1.00
1,2-Dichloropropane U 0.149 1.00
1,1-Dichloropropene U 0.142 1.00
1,3-Dichloropropane U 0.110 1.00
2,2-Dichloropropane U 0.161 1.00
Di-isopropyl ether U 0.105 1.00
Ethylbenzene U 0.137 1.00
Hexachloro-1,3-butadiene U 0.337 1.00
Isopropylbenzene U 0.105 1.00
p-Isopropyltoluene U 0.120 1.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001664
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 L1582427-03,04
Method Blank (MB)
(MB) R3889132-5 02/07/23 12:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
2-Butanone (MEK)U 1.19 10.0
Methylene Chloride U 0.430 5.00
4-Methyl-2-pentanone (MIBK)U 0.478 10.0
Methyl tert-butyl ether U 0.101 1.00
Naphthalene U 1.00 5.00
n-Propylbenzene U 0.0993 1.00
Styrene U 0.118 1.00
1,1,1,2-Tetrachloroethane U 0.147 1.00
1,1,2,2-Tetrachloroethane U 0.133 1.00
Tetrachloroethene U 0.300 1.00
Toluene U 0.278 1.00
1,2,3-Trichlorobenzene U 0.230 1.00
1,2,4-Trichlorobenzene U 0.481 1.00
1,1,1-Trichloroethane U 0.149 1.00
1,1,2-Trichloroethane U 0.158 1.00
Trichloroethene U 0.190 1.00
Trichlorofluoromethane U 0.160 5.00
1,2,3-Trichloropropane U 0.237 2.50
1,2,4-Trimethylbenzene U 0.322 1.00
1,3,5-Trimethylbenzene U 0.104 1.00
Vinyl chloride U 0.234 1.00
o-Xylene U 0.174 1.00
m&p-Xylenes U 0.430 2.00
Ethyl tert-butyl ether U 0.101 1.00
t-Amyl Alcohol U 4.90 50.0
tert-Amyl Methyl Ether U 0.195 1.00
(S) Toluene-d8 91.5 80.0-120
(S) 4-Bromofluorobenzene 86.8 77.0-126
(S) 1,2-Dichloroethane-d4 105 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889132-1 02/07/23 10:25 • (LCSD) R3889132-2 02/07/23 10:46
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Acetone 25.0 17.9 18.1 71.6 72.4 19.0-160 1.11 27
Acrolein 25.0 14.0 10.2 56.0 40.8 10.0-160 J3 31.4 26
Acrylonitrile 25.0 22.4 20.2 89.6 80.8 55.0-149 10.3 20
Benzene 5.00 5.08 4.93 102 98.6 70.0-123 3.00 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001664
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 L1582427-03,04
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889132-1 02/07/23 10:25 • (LCSD) R3889132-2 02/07/23 10:46
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Bromobenzene 5.00 5.52 4.95 110 99.0 73.0-121 10.9 20
Bromodichloromethane 5.00 5.68 5.66 114 113 75.0-120 0.353 20
Bromoform 5.00 4.63 4.36 92.6 87.2 68.0-132 6.01 20
Bromomethane 5.00 6.24 6.08 125 122 10.0-160 2.60 25
n-Butylbenzene 5.00 4.77 4.50 95.4 90.0 73.0-125 5.83 20
sec-Butylbenzene 5.00 5.09 4.65 102 93.0 75.0-125 9.03 20
tert-Butylbenzene 5.00 4.73 4.44 94.6 88.8 76.0-124 6.32 20
Carbon tetrachloride 5.00 5.43 5.32 109 106 68.0-126 2.05 20
Chlorobenzene 5.00 4.70 4.39 94.0 87.8 80.0-121 6.82 20
Chlorodibromomethane 5.00 4.86 4.50 97.2 90.0 77.0-125 7.69 20
Chloroethane 5.00 6.51 6.34 130 127 47.0-150 2.65 20
Chloroform 5.00 5.83 5.61 117 112 73.0-120 3.85 20
Chloromethane 5.00 5.39 5.19 108 104 41.0-142 3.78 20
2-Chlorotoluene 5.00 5.23 4.78 105 95.6 76.0-123 8.99 20
4-Chlorotoluene 5.00 4.96 4.56 99.2 91.2 75.0-122 8.40 20
1,2-Dibromo-3-Chloropropane 5.00 4.23 3.92 84.6 78.4 58.0-134 7.61 20
1,2-Dibromoethane 5.00 4.75 4.73 95.0 94.6 80.0-122 0.422 20
Dibromomethane 5.00 5.21 5.09 104 102 80.0-120 2.33 20
1,2-Dichlorobenzene 5.00 5.05 4.58 101 91.6 79.0-121 9.76 20
1,3-Dichlorobenzene 5.00 5.28 4.88 106 97.6 79.0-120 7.87 20
1,4-Dichlorobenzene 5.00 5.29 4.87 106 97.4 79.0-120 8.27 20
Dichlorodifluoromethane 5.00 6.36 6.81 127 136 51.0-149 6.83 20
1,1-Dichloroethane 5.00 4.92 4.77 98.4 95.4 70.0-126 3.10 20
1,2-Dichloroethane 5.00 5.74 5.34 115 107 70.0-128 7.22 20
1,1-Dichloroethene 5.00 5.15 4.95 103 99.0 71.0-124 3.96 20
cis-1,2-Dichloroethene 5.00 4.97 4.81 99.4 96.2 73.0-120 3.27 20
trans-1,2-Dichloroethene 5.00 5.12 5.12 102 102 73.0-120 0.000 20
1,2-Dichloropropane 5.00 4.81 4.62 96.2 92.4 77.0-125 4.03 20
1,1-Dichloropropene 5.00 5.01 4.97 100 99.4 74.0-126 0.802 20
1,3-Dichloropropane 5.00 4.78 4.55 95.6 91.0 80.0-120 4.93 20
2,2-Dichloropropane 5.00 6.38 6.30 128 126 58.0-130 1.26 20
Di-isopropyl ether 5.00 4.47 4.33 89.4 86.6 58.0-138 3.18 20
Ethylbenzene 5.00 4.39 4.26 87.8 85.2 79.0-123 3.01 20
Hexachloro-1,3-butadiene 5.00 5.71 5.72 114 114 54.0-138 0.175 20
Isopropylbenzene 5.00 4.14 3.96 82.8 79.2 76.0-127 4.44 20
p-Isopropyltoluene 5.00 4.72 4.45 94.4 89.0 76.0-125 5.89 20
2-Butanone (MEK)25.0 24.8 23.4 99.2 93.6 44.0-160 5.81 20
Methylene Chloride 5.00 5.05 5.24 101 105 67.0-120 3.69 20
4-Methyl-2-pentanone (MIBK)25.0 23.3 21.9 93.2 87.6 68.0-142 6.19 20
Methyl tert-butyl ether 5.00 4.93 4.80 98.6 96.0 68.0-125 2.67 20
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001664
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 L1582427-03,04
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889132-1 02/07/23 10:25 • (LCSD) R3889132-2 02/07/23 10:46
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Naphthalene 5.00 3.58 3.55 71.6 71.0 54.0-135 0.842 20
n-Propylbenzene 5.00 4.78 4.56 95.6 91.2 77.0-124 4.71 20
Styrene 5.00 3.95 3.79 79.0 75.8 73.0-130 4.13 20
1,1,1,2-Tetrachloroethane 5.00 4.64 4.29 92.8 85.8 75.0-125 7.84 20
1,1,2,2-Tetrachloroethane 5.00 5.76 5.38 115 108 65.0-130 6.82 20
Tetrachloroethene 5.00 5.10 4.70 102 94.0 72.0-132 8.16 20
Toluene 5.00 4.63 4.43 92.6 88.6 79.0-120 4.42 20
1,2,3-Trichlorobenzene 5.00 4.40 4.23 88.0 84.6 50.0-138 3.94 20
1,2,4-Trichlorobenzene 5.00 4.28 4.07 85.6 81.4 57.0-137 5.03 20
1,1,1-Trichloroethane 5.00 5.93 5.91 119 118 73.0-124 0.338 20
1,1,2-Trichloroethane 5.00 4.85 4.67 97.0 93.4 80.0-120 3.78 20
Trichloroethene 5.00 4.87 4.58 97.4 91.6 78.0-124 6.14 20
Trichlorofluoromethane 5.00 6.33 6.54 127 131 59.0-147 3.26 20
1,2,3-Trichloropropane 5.00 6.01 5.32 120 106 73.0-130 12.2 20
1,2,4-Trimethylbenzene 5.00 4.76 4.43 95.2 88.6 76.0-121 7.18 20
1,3,5-Trimethylbenzene 5.00 4.93 4.54 98.6 90.8 76.0-122 8.24 20
Vinyl chloride 5.00 5.51 5.68 110 114 67.0-131 3.04 20
o-Xylene 5.00 3.96 3.88 79.2 77.6 80.0-122 J4 J4 2.04 20
m&p-Xylenes 10.0 8.99 8.49 89.9 84.9 80.0-122 5.72 20
Ethyl tert-butyl ether 5.00 4.39 4.27 87.8 85.4 63.0-138 2.77 20
tert-Amyl Methyl Ether 5.00 4.44 4.36 88.8 87.2 66.0-125 1.82 20
(S) Toluene-d8 91.4 90.2 80.0-120
(S) 4-Bromofluorobenzene 82.1 81.8 77.0-126
(S) 1,2-Dichloroethane-d4 112 111 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2003348
Volatile Organic Compounds (GC/MS) by Method 6200B-1997/6200B-2011 L1582427-03,04
Method Blank (MB)
(MB) R3889577-3 02/09/23 12:44
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ethanol U 42.0 100
tert-Butyl alcohol U 4.06 5.00
(S) Toluene-d8 102 80.0-120
(S) 4-Bromofluorobenzene 98.8 77.0-126
(S) 1,2-Dichloroethane-d4 91.2 70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889577-1 02/09/23 11:37 • (LCSD) R3889577-2 02/09/23 11:59
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
ethanol 250 259 266 104 106 10.0-160 2.67 30
tert-Butyl alcohol 25.0 24.2 24.2 96.8 96.8 27.0-160 0.000 30
(S) Toluene-d8 99.4 104 80.0-120
(S) 4-Bromofluorobenzene 98.6 99.2 77.0-126
(S) 1,2-Dichloroethane-d4 89.6 91.2 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2002929
EDB / DBCP by Method 504.1 L1582427-03
Method Blank (MB)
(MB) R3889601-1 02/09/23 17:32
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Ethylene Dibromide U 0.00536 0.0200
L1582429-09 Original Sample (OS) • Duplicate (DUP)
(OS) L1582429-09 02/09/23 18:19 • (DUP) R3889601-3 02/09/23 18:07
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte ug/l ug/l %%
Ethylene Dibromide U U 1.06 0.000 20
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889601-4 02/09/23 20:15 • (LCSD) R3889601-5 02/09/23 22:47
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Ethylene Dibromide 0.250 0.233 0.234 93.2 93.6 70.0-130 0.428 20
L1582429-10 Original Sample (OS) • Matrix Spike (MS)
(OS) L1582429-10 02/09/23 17:55 • (MS) R3889601-2 02/09/23 17:44
Spike Amount Original Result MS Result MS Rec.Dilution Rec. Limits MS Qualifier
Analyte ug/l ug/l ug/l %%
Ethylene Dibromide 0.101 U 0.108 107 1.01 70.0-130
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2001268
Semi-Volatile Organic Compounds (GC) by Method 8015C L1582427-01,02
Method Blank (MB)
(MB) R3888979-2 02/08/23 18:51
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/kg ug/kg ug/kg
TPH (GC/FID) High Fraction U 769 4000
(S) o-Terphenyl 55.7 18.0-148
Laboratory Control Sample (LCS)
(LCS) R3888979-1 02/08/23 18:38
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/kg ug/kg %%
TPH (GC/FID) High Fraction 50000 33000 66.0 50.0-150
(S) o-Terphenyl 75.2 18.0-148
L1582427-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582427-01 02/09/23 01:51 • (MS) R3888979-3 02/09/23 02:04 • (MSD) R3888979-4 02/09/23 02:17
Spike Amount
(dry)
Original Result
(dry)MS Result (dry)MSD Result
(dry)MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/kg ug/kg ug/kg ug/kg %%%%%
TPH (GC/FID) High Fraction 56700 U 409000 46600 721 82.2 10 50.0-150 J5 J3 159 20
(S) o-Terphenyl 63.6 44.5 18.0-148
Sample Narrative:
OS: Cannot run at lower dilution due to viscosity of extract
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2002247
TPH by Method MADEPE L1582427-03
Method Blank (MB)
(MB) R3889367-1 02/09/23 12:35
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Unadjusted C9-C18 Aliphatics U 33.3 100
Unadjusted C19-C36 Aliphatics 35.2 J 33.3 100
Unadjusted Total Petroleum
Hydrocarbons 35.2 J 33.3 100
(S) 1-Chloro-octadecane 55.3 40.0-140
Method Blank (MB)
(MB) R3889367-2 02/09/23 12:57
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Unadjusted C11-C22 Aromatics 36.0 J 33.3 100
Unadjusted Total Petroleum
Hydrocarbons 36.0 J 33.3 100
(S) o-Terphenyl 62.1 40.0-140
(S) 2-Fluorobiphenyl 86.3 40.0-140
(S) 2-Bromonaphthalene 84.0 40.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889367-3 02/09/23 13:20 • (LCSD) R3889367-4 02/09/23 13:42
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Unadjusted C9-C18 Aliphatics 600 408 421 68.0 70.2 40.0-140 3.14 25
Unadjusted C19-C36 Aliphatics 800 750 766 93.8 95.8 40.0-140 2.11 25
(S) 1-Chloro-octadecane 75.0 73.0 40.0-140
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3889367-5 02/09/23 14:04 • (LCSD) R3889367-6 02/09/23 14:26
Spike Amount LCS Result LCSD Result LCS Rec.LCSD Rec.Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l %%%%%
Unadjusted C11-C22 Aromatics 1700 1370 1430 80.6 84.1 40.0-140 4.29 25
(S) o-Terphenyl 74.9 74.1 40.0-140
(S) 2-Fluorobiphenyl 87.9 91.0 40.0-140
(S) 2-Bromonaphthalene 83.6 86.6 40.0-140
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000359
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1582427-03
Method Blank (MB)
(MB) R3888265-3 02/07/23 11:13
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Acenaphthene U 0.0886 1.00
Acenaphthylene U 0.0921 1.00
Anthracene U 0.0804 1.00
Benzidine U 3.74 10.0
Benzo(a)anthracene U 0.199 1.00
Benzo(b)fluoranthene U 0.130 1.00
Benzo(k)fluoranthene U 0.120 1.00
Benzo(g,h,i)perylene U 0.121 1.00
Benzo(a)pyrene U 0.0381 1.00
Bis(2-chlorethoxy)methane U 0.116 10.0
Bis(2-chloroethyl)ether U 0.137 10.0
2,2-oxybis(1-chloropropane)U 0.210 10.0
4-Bromophenyl-phenylether U 0.0877 10.0
2-Chloronaphthalene U 0.0648 1.00
4-Chlorophenyl-phenylether U 0.0926 10.0
Chrysene U 0.130 1.00
Dibenz(a,h)anthracene U 0.0644 1.00
3,3-Dichlorobenzidine U 0.212 10.0
2,4-Dinitrotoluene U 0.0983 10.0
2,6-Dinitrotoluene U 0.250 10.0
Fluoranthene U 0.102 1.00
Fluorene U 0.0844 1.00
Hexachlorobenzene U 0.0755 1.00
Hexachloro-1,3-butadiene U 0.0968 10.0
Hexachlorocyclopentadiene U 0.0598 10.0
Hexachloroethane U 0.127 10.0
Indeno(1,2,3-cd)pyrene U 0.279 1.00
Isophorone U 0.143 10.0
Naphthalene U 0.159 1.00
Nitrobenzene U 0.297 10.0
n-Nitrosodimethylamine U 0.998 10.0
n-Nitrosodiphenylamine U 2.37 10.0
n-Nitrosodi-n-propylamine U 0.261 10.0
Phenanthrene U 0.112 1.00
Benzylbutyl phthalate U 0.765 3.00
Bis(2-ethylhexyl)phthalate U 0.895 3.00
Di-n-butyl phthalate U 0.453 3.00
Diethyl phthalate U 0.287 3.00
Dimethyl phthalate U 0.260 3.00
Di-n-octyl phthalate U 0.932 3.00
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000359
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1582427-03
Method Blank (MB)
(MB) R3888265-3 02/07/23 11:13
MB Result MB Qualifier MB MDL MB RDL
Analyte ug/l ug/l ug/l
Pyrene U 0.107 1.00
1,2,4-Trichlorobenzene U 0.0698 10.0
4-Chloro-3-methylphenol U 0.131 10.0
2-Chlorophenol U 0.133 10.0
2,4-Dichlorophenol U 0.102 10.0
2,4-Dimethylphenol U 0.0636 10.0
4,6-Dinitro-2-methylphenol U 1.12 10.0
2,4-Dinitrophenol U 5.93 10.0
2-Nitrophenol U 0.117 10.0
4-Nitrophenol U 0.143 10.0
Pentachlorophenol U 0.313 10.0
Phenol U 4.33 10.0
2,4,6-Trichlorophenol U 0.100 10.0
(S) Nitrobenzene-d5 71.4 15.0-314
(S) 2-Fluorobiphenyl 77.6 22.0-127
(S) p-Terphenyl-d14 81.2 29.0-141
(S) Phenol-d5 20.7 8.00-424
(S) 2-Fluorophenol 32.7 10.0-120
(S) 2,4,6-Tribromophenol 62.0 10.0-153
Laboratory Control Sample (LCS)
(LCS) R3888265-1 02/07/23 10:30
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
Acenaphthene 50.0 37.9 75.8 47.0-145
Acenaphthylene 50.0 40.5 81.0 33.0-145
Anthracene 50.0 37.2 74.4 27.0-133
Benzidine 100 4.81 4.81 1.00-120
Benzo(a)anthracene 50.0 39.2 78.4 33.0-143
Benzo(b)fluoranthene 50.0 39.5 79.0 24.0-159
Benzo(k)fluoranthene 50.0 39.1 78.2 11.0-162
Benzo(g,h,i)perylene 50.0 38.8 77.6 1.00-219
Benzo(a)pyrene 50.0 41.9 83.8 17.0-163
Bis(2-chlorethoxy)methane 50.0 33.9 67.8 1.00-219
Bis(2-chloroethyl)ether 50.0 35.0 70.0 33.0-185
2,2-oxybis(1-chloropropane)50.0 34.9 69.8 36.0-166
4-Bromophenyl-phenylether 50.0 40.5 81.0 53.0-127
2-Chloronaphthalene 50.0 37.9 75.8 60.0-120
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000359
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1582427-03
Laboratory Control Sample (LCS)
(LCS) R3888265-1 02/07/23 10:30
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
4-Chlorophenyl-phenylether 50.0 39.4 78.8 25.0-158
Chrysene 50.0 39.9 79.8 17.0-168
Dibenz(a,h)anthracene 50.0 38.9 77.8 1.00-227
3,3-Dichlorobenzidine 100 67.4 67.4 1.00-262
2,4-Dinitrotoluene 50.0 40.6 81.2 39.0-139
2,6-Dinitrotoluene 50.0 40.4 80.8 50.0-158
Fluoranthene 50.0 40.1 80.2 26.0-137
Fluorene 50.0 39.5 79.0 59.0-121
Hexachlorobenzene 50.0 39.0 78.0 1.00-152
Hexachloro-1,3-butadiene 50.0 33.3 66.6 24.0-120
Hexachlorocyclopentadiene 50.0 32.0 64.0 10.0-120
Hexachloroethane 50.0 34.3 68.6 40.0-120
Indeno(1,2,3-cd)pyrene 50.0 36.1 72.2 1.00-171
Isophorone 50.0 32.1 64.2 21.0-196
Naphthalene 50.0 32.6 65.2 21.0-133
Nitrobenzene 50.0 32.6 65.2 35.0-180
n-Nitrosodimethylamine 50.0 16.4 32.8 10.0-120
n-Nitrosodiphenylamine 50.0 32.3 64.6 44.0-120
n-Nitrosodi-n-propylamine 50.0 36.4 72.8 1.00-230
Phenanthrene 50.0 38.8 77.6 54.0-120
Benzylbutyl phthalate 50.0 40.1 80.2 1.00-152
Bis(2-ethylhexyl)phthalate 50.0 41.5 83.0 8.00-158
Di-n-butyl phthalate 50.0 40.6 81.2 1.00-120
Diethyl phthalate 50.0 39.8 79.6 1.00-120
Dimethyl phthalate 50.0 39.8 79.6 1.00-120
Di-n-octyl phthalate 50.0 35.9 71.8 4.00-146
Pyrene 50.0 39.3 78.6 52.0-120
1,2,4-Trichlorobenzene 50.0 32.6 65.2 44.0-142
4-Chloro-3-methylphenol 50.0 30.3 60.6 22.0-147
2-Chlorophenol 50.0 28.6 57.2 23.0-134
2,4-Dichlorophenol 50.0 32.3 64.6 39.0-135
2,4-Dimethylphenol 50.0 27.1 54.2 32.0-120
4,6-Dinitro-2-methylphenol 50.0 37.3 74.6 1.00-181
2,4-Dinitrophenol 50.0 31.8 63.6 1.00-191
2-Nitrophenol 50.0 33.4 66.8 29.0-182
4-Nitrophenol 50.0 12.5 25.0 1.00-132
Pentachlorophenol 50.0 37.2 74.4 14.0-176
Phenol 50.0 11.0 22.0 5.00-120
2,4,6-Trichlorophenol 50.0 39.0 78.0 37.0-144
(S) Nitrobenzene-d5 51.8 15.0-314
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000359
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1582427-03
Laboratory Control Sample (LCS)
(LCS) R3888265-1 02/07/23 10:30
Spike Amount LCS Result LCS Rec.Rec. Limits LCS Qualifier
Analyte ug/l ug/l %%
(S) 2-Fluorobiphenyl 74.2 22.0-127
(S) p-Terphenyl-d14 75.2 29.0-141
(S) Phenol-d5 20.3 8.00-424
(S) 2-Fluorophenol 34.1 10.0-120
(S) 2,4,6-Tribromophenol 75.5 10.0-153
L1582316-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582316-01 02/07/23 12:16 • (MS) R3888265-4 02/07/23 12:37 • (MSD) R3888265-5 02/07/23 12:58
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Acenaphthene 50.0 U 30.9 31.4 61.8 62.8 1 47.0-145 1.61 48
Acenaphthylene 50.0 U 32.2 33.1 64.4 66.2 1 33.0-145 2.76 74
Anthracene 50.0 U 33.4 31.1 66.8 62.2 1 27.0-133 7.13 66
Benzidine 100 U U 3.80 0.000 3.80 1 1.00-120 J6 J3 200 40
Benzo(a)anthracene 50.0 U 36.3 32.3 72.6 64.6 1 33.0-143 11.7 53
Benzo(b)fluoranthene 50.0 U 37.0 32.9 74.0 65.8 1 24.0-159 11.7 71
Benzo(k)fluoranthene 50.0 U 36.4 32.7 72.8 65.4 1 11.0-162 10.7 63
Benzo(g,h,i)perylene 50.0 U 37.8 32.1 75.6 64.2 1 1.00-219 16.3 97
Benzo(a)pyrene 50.0 U 40.2 35.1 80.4 70.2 1 17.0-163 13.5 72
Bis(2-chlorethoxy)methane 50.0 U 25.6 28.7 51.2 57.4 1 33.0-184 11.4 54
Bis(2-chloroethyl)ether 50.0 U 25.1 25.0 50.2 50.0 1 12.0-158 0.399 108
2,2-oxybis(1-chloropropane)50.0 U 24.9 27.7 49.8 55.4 1 36.0-166 10.6 76
4-Bromophenyl-phenylether 50.0 U 34.3 34.7 68.6 69.4 1 53.0-127 1.16 43
2-Chloronaphthalene 50.0 U 28.4 30.8 56.8 61.6 1 60.0-120 J6 8.11 24
4-Chlorophenyl-phenylether 50.0 U 34.5 32.6 69.0 65.2 1 25.0-158 5.66 61
Chrysene 50.0 U 37.9 33.2 75.8 66.4 1 17.0-168 13.2 87
Dibenz(a,h)anthracene 50.0 U 37.0 32.1 74.0 64.2 1 1.00-227 14.2 126
3,3-Dichlorobenzidine 100 U 38.4 48.6 38.4 48.6 1 1.00-262 23.4 108
2,4-Dinitrotoluene 50.0 U 38.8 34.1 77.6 68.2 1 39.0-139 12.9 42
2,6-Dinitrotoluene 50.0 U 34.6 33.4 69.2 66.8 1 50.0-158 3.53 48
Fluoranthene 50.0 U 40.4 33.9 80.8 67.8 1 26.0-137 17.5 66
Fluorene 50.0 U 34.5 33.0 69.0 66.0 1 59.0-121 4.44 38
Hexachlorobenzene 50.0 U 33.7 33.3 67.4 66.6 1 1.00-152 1.19 55
Hexachloro-1,3-butadiene 50.0 U 23.3 26.5 46.6 53.0 1 24.0-120 12.9 62
Hexachlorocyclopentadiene 50.0 U 23.0 27.5 46.0 55.0 1 10.0-146 17.8 34
Hexachloroethane 50.0 U 21.9 24.8 43.8 49.6 1 40.0-120 12.4 52
Indeno(1,2,3-cd)pyrene 50.0 U 35.4 30.3 70.8 60.6 1 1.00-171 15.5 99
Isophorone 50.0 U 24.8 26.8 49.6 53.6 1 21.0-196 7.75 93
1 Cp
2Tc
3Ss
4Cn
5Sr
6Qc
7Gl
8Al
9Sc
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QUALITY CONTROL SUMMARYWG2000359
Semi Volatile Organic Compounds (GC/MS) by Method 625.1 L1582427-03
L1582316-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1582316-01 02/07/23 12:16 • (MS) R3888265-4 02/07/23 12:37 • (MSD) R3888265-5 02/07/23 12:58
Spike Amount Original Result MS Result MSD Result MS Rec.MSD Rec.Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte ug/l ug/l ug/l ug/l %%%%%
Naphthalene 50.0 U 24.3 26.2 48.6 52.4 1 21.0-133 7.52 65
Nitrobenzene 50.0 U 24.0 26.8 48.0 53.6 1 35.0-180 11.0 62
n-Nitrosodimethylamine 50.0 U 12.7 14.2 25.4 28.4 1 10.0-120 11.2 40
n-Nitrosodiphenylamine 50.0 U 28.2 27.7 56.4 55.4 1 16.0-160 1.79 28
n-Nitrosodi-n-propylamine 50.0 U 27.6 28.6 55.2 57.2 1 1.00-230 3.56 87
Phenanthrene 50.0 U 34.7 32.5 69.4 65.0 1 54.0-120 6.55 39
Benzylbutyl phthalate 50.0 U 39.2 34.2 78.4 68.4 1 1.00-152 13.6 60
Bis(2-ethylhexyl)phthalate 50.0 U 39.3 35.1 78.6 70.2 1 8.00-158 11.3 82
Di-n-butyl phthalate 50.0 U 39.6 34.0 79.2 68.0 1 1.00-120 15.2 47
Diethyl phthalate 50.0 U 36.9 32.4 73.8 64.8 1 1.00-120 13.0 100
Dimethyl phthalate 50.0 U 33.8 32.8 67.6 65.6 1 1.00-120 3.00 183
Di-n-octyl phthalate 50.0 U 36.4 31.6 72.8 63.2 1 4.00-146 14.1 69
Pyrene 50.0 U 35.6 32.6 71.2 65.2 1 52.0-120 8.80 49
1,2,4-Trichlorobenzene 50.0 U 23.0 26.0 46.0 52.0 1 44.0-142 12.2 50
4-Chloro-3-methylphenol 50.0 U 28.4 26.8 56.8 53.6 1 22.0-147 5.80 73
2-Chlorophenol 50.0 U 21.0 23.3 42.0 46.6 1 23.0-134 10.4 61
2,4-Dichlorophenol 50.0 U 25.1 26.9 50.2 53.8 1 39.0-135 6.92 50
2,4-Dimethylphenol 50.0 U 22.3 24.4 44.6 48.8 1 32.0-120 8.99 58
4,6-Dinitro-2-methylphenol 50.0 U 33.8 31.8 67.6 63.6 1 1.00-181 6.10 203
2,4-Dinitrophenol 50.0 U 34.8 31.5 69.6 63.0 1 1.00-191 9.95 132
2-Nitrophenol 50.0 U 24.2 27.3 48.4 54.6 1 29.0-182 12.0 55
4-Nitrophenol 50.0 U 13.7 10.9 27.4 21.8 1 1.00-132 22.8 131
Pentachlorophenol 50.0 U 38.6 34.1 77.2 68.2 1 14.0-176 12.4 86
Phenol 50.0 U 8.67 9.12 17.3 18.2 1 5.00-120 5.06 64
2,4,6-Trichlorophenol 50.0 0.678 31.0 32.2 60.6 63.0 1 37.0-144 3.80 58
(S) Nitrobenzene-d5 43.4 44.8 15.0-314
(S) 2-Fluorobiphenyl 55.4 61.7 22.0-127
(S) p-Terphenyl-d14 69.3 62.5 29.0-141
(S) Phenol-d5 16.4 17.1 8.00-424
(S) 2-Fluorophenol 25.1 28.4 10.0-120
(S) 2,4,6-Tribromophenol 68.5 66.5 10.0-153
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GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On-Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
(dry)Results are reported based on the dry weight of the sample. [this will only be present on a dry report basis for soils].
MDL Method Detection Limit.
MDL (dry)Method Detection Limit.
RDL Reported Detection Limit.
RDL (dry)Reported Detection Limit.
Rec.Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
(S)
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Dilution
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Limits
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non-spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
Qualifier
This column provides a letter and/or number designation that corresponds to additional information concerning the result
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
Result
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state “ND” (Not Detected) or “BDL”
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)Confidence level of 2 sigma.
Case Narrative (Cn)
A brief discussion about the included sample results, including a discussion of any non-conformances to protocol
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
Summary (Qc)
This section of the report includes the results of the laboratory quality control analyses required by procedure or
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
Sample Chain of
Custody (Sc)
This is the document created in the field when your samples were initially collected. This is used to verify the time and
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
Sample Results (Sr)
This section of your report will provide the results of all testing performed on your samples. These results are provided
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier Description
B The same analyte is found in the associated blank.
C4 The reported concentration is an estimate. The continuing calibration standard associated with this data responded low.
Data is likely to show a low bias concerning the result.
J The identification of the analyte is acceptable; the reported value is an estimate.
J3 The associated batch QC was outside the established quality control range for precision.
J4 The associated batch QC was outside the established quality control range for accuracy.
J5 The sample matrix interfered with the ability to make any accurate determination; spike value is high.
J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low.
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Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN000032021-1
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey–NELAP TN002
California 2932 New Mexico ¹TN00003
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North Carolina ¹DW21704
Georgia NELAP North Carolina ³41
Georgia ¹923 North Dakota R-140
Idaho TN00003 Ohio–VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LAO00356
Kentucky ¹ ⁶KY90010 South Carolina 84004002
Kentucky ²16 South Dakota n/a
Louisiana AI30792 Tennessee ¹ ⁴2006
Louisiana LA018 Texas T104704245-20-18
Maine TN00003 Texas ⁵LAB0152
Maryland 324 Utah TN000032021-11
Massachusetts M-TN003 Vermont VT2006
Michigan 9958 Virginia 110033
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 998093910
Montana CERT0086 Wyoming A2LA
A2LA – ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA – ISO 17025 ⁵1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA–Crypto TN00003
ACCREDITATIONS & LOCATIONS

¹ Drinking Water ² Underground Storage Tanks ³ Aquatic Toxicity ⁴ Chemical/Microbiological ⁵ Mold ⁶ Wastewater n/a Accreditation not applicable
* Not all certifications held by the laboratory are applicable to the results reported in the attached report.
* Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
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