WS-96246_0_CA_IAR_20221215

Initial Assessment RePort
Recovered Used Oil and Wastewater Release
Shamrock Environmental
6106 Corporate Park Drive
Browns Summit, North Carolina 27214
Latitude 36.167 6lLon gitude 7 9.7 3538
December 15"2022
Preparedfor
Shamrock Environmentalo Inc.
Browns Summit" North Carolina 27214
Submitted to
Guilford County Department of Environmental Health
109 Maple Street
Greensboro, North Carolina
North Carolina Department of Environmental Quality
Winston-Salem Regional Office
Winston-Salem, North Carolina
Prepared by
Mr. Phillip Rahn PG RSM
Waters Edge Environmental, LLC
1434 Chester Road
Raleigh, North Carolina 27608
WATERS EDGE ENVIRONMENTAL, LLC
1434 CHESTER ROAD•RALEIGH, NC27608• PHONE [phone]
December 15, 2022

Mr. Steve Davis Shamrock Environmental 6106 Corporate Park Drive
Browns Summit, North Carolina 27214
Reference: Initial Assessment Report Recovered Used Oil and Wastewater Release
Shamrock Environmental
6106 Corporate Park Drive Browns Summit, North Carolina 27214 Waters Edge Job No. R22-62
Dear Mr. Davis:
Waters Edge Environmental, LLC (Waters Edge) is pleased to present the attached Initial Assessment Report (IAR) for the October 18, 2022 recovered used oil and wastewater release at the Shamrock operation located at 6106 Corporate Park Drive in Browns Summit, North Carolina
(see Figure 1). After remedial activities were completed, two confirmatory soil samples were
below both TPH-GRO and TPH-DRO thresholds of 50 mg/kg and 100 mg/kg respectively. Since the release was in excess of 25 gallons, this was reported to the NRC in Atlanta, Georgia. We have included a UST-62 form and Initial Site Assessment form which are all documented in Appendix A.

If you require additional information concerning the attached IAR, please contact us at 919.859.9987. Sincerely,

WATERS EDGE ENVIRONMENTAL, LLC
Phillip L. Rahn P.G. President
22-100/PLR/aht

ii

Table of Contents

1 Introduction 5
2 Initial Assessment Report 5
2.1 Site History and Characterization 5
3 Conclusions and Recommendations 6

iii
Figures

Figure No. Title 1 Project Location Map 2 Spill/Soil Sample Location Map

Tables
Table No. Title
1 Soil Analytical Results
Appendices
Appendix Title A Site Information Summary Sheet and 24-Hour Notification of Discharge
Release Form
B Soil Disposal Manifests C Soil Analytical Results

iv
Acronym List

bgs below ground surface mg/kg milligrams per kilograms or parts per million
ND Non-Detect
NCDEQ North Carolina Department of Environmental Quality PID Photoionization Detector

Shamrock Shamrock Environmental UST underground storage tank
Waters Edge Waters Edge Environmental, LLC

Initial Assessment Report Shamrock Environmental Used Oil and Wastewater Release 6106 Corporate Park Drive Browns Summit, North Carolina 27214
December 15, 2022
1 Introduction
Waters Edge has prepared this Initial Assessment Report (IAR) for the October 18, 2022 recovered
used oil and wastewater release at the Shamrock operation located at 6106 Corporate Park Drive in Browns Summit, North Carolina (see Figure 1). This IAM Report follows the NCDEQ UST Section Guidelines for Investigation and Remediation of Contamination from Non-UST Petroleum Releases-with the site information cover sheet. We have also included UST-62 24-hour
Notification of Discharge Release Form. Since the release was in excess of 25 gallons, Shamrock
also reported the incident to the NRC in Atlanta, Georgia. All of this is documented in Appendix A. Herein, are the remaining sections of the report.
2 Initial Assessment Report
2.1 Site History and Characterization 1. List, describe, and indicated location of AST systems and of all spill or other non-UST
releases-
On October 18, 2022, at approximately 16:45 hours, Shamrock Environmental Corporation experienced a release of oil water mixture containing approximately 50 gallons of heavy used oil recovered from oily wastewater. The release was reported as an equipment failure due to fouled pump transferring oil from the 500-gallon flow through tank to the storage
tank. Some preliminary information is summarized below:
• Type facility: Industrial Wastewater Pre-treatment (Discharge to Greensboro POTW). • Facility address: 6106 Corporate Park Dr Browns Summit (Greensboro), NC 27214 • City of Greensboro Significant Industrial User Permit P065. • SW General Permit: NCG110000 COI NCG110157

2. Describe initial abatement activities, assessment activities and corrective action performed to date and list all reports previously submitted- There were no previous reports. The oil was released to a gravel area adjacent to the transfer tank servicing the wastewater
clarifier at the Company’s industrial wastewater treatment facility located at 6106
Corporate Park Drive Browns Summit, Guilford County, NC. The release was determined to be an RQ release (> 25 gallons oil released, no sheen migration off site, no RQ release for other contaminants). Immediately following discovery, recovery and cleanup operations were undertaken and the release reported to the USCG National Response
Center and call verified as received by NC Emergency Management. USCG NRC Report
NRC#1350274 (see Appendix A). A spill location map is shown in Figure 2. The release was reported as an equipment failure due to fouled pump transferring oil from the 500-gallon flow through tank to the storage tank. Mitigation efforts began immediately
on discovery and included stopping of the release and dispatching vacuum trucks to recover

used oil and impacted gravel. Mixed wastewater, oil and gravel were collected from the impacted area using vacuum trucks. On a subsequent additional visual inspection, it was determined that a small but visible
portion of the oil had migrated through the gravel and under an adjacent containment liner.
Portable tanks were cleaned and moved, the liner pulled back and an additional area approximately 4 feet by 10 feet and 18 inches in depth was excavated using vacuum trucks (see Figure 2 and disposal manifest in Appendix B). In summary, approximately 4,000 gallons and 34 tons of used oil, wastewater, gravel and soil were removed and disposed as
industrial solid waste (see manifest in Appendix B).
The regional area would be considered residential. The immediate are would be considered commercial/light industrial.
Shamrock subsequently contracted with Waters Edge to perform confirmatory sampling.
On November 23, 2022, Water Edge mobilized to the site. We collected two (2) samples with a hand auger (SS-1 and SS-2-see Figure 2). The samples were collected at 0.5’ bgs with a hand auger and submitted to the laboratory according to EPA-accepted procedures. Based on Shamrock guidance, this sample was analyzed for both gasoline-ranged and
diesel-ranged total petroleum hydrocarbons (TPH-GRO/DRO) according to SW-846
Method 8015 (results summarized in Table 1 and documented in Appendix C). 3 Conclusions and Recommendations

Based upon the soil assessment findings, we would conclude the following:
• Both samples were below the TPH-GRO and TPH-DRO thresholds of 50 mg/kg and
100 mg/kg respectively. As such, we would conclude that no further remediation is
required. With submittal of the UST-62 Form, we would conclude that the release has been reported to NCDEQ.

Figures
Job No.Topo Quad Date Title
R22-62 Lake Br/Browns Sum 12/7/2022
File Name Figure Scale Project
22-100.xls 1 bar scale Browns Summit, North Carolina
Project Location Map
6106 Corporate Park DriveWATERS EDGE ENVIRONMENTAL, LLC
LEGEND
Spill Location
1,500 ft. Radius
Job No.Image/Photo Date Title
R22-62 Google Earth 12.6.22
File Name Figure Scale Project
22-100.xls 2 bar scale Browns Summit, North Carolina
Spill & Sampling Location Map
2106 Corporate Park DriveWATERS EDGE ENVIRONMENTAL, LLC
Spill Area LimitsA1 (South Quadrant)-26'(L) x 6'(W) x 0.5'(D)A2 (West Quadrant)-15'(L) x 3'(W) x 0.5'(D)
SS-1
SS-2
LEGEND
Soil Boring Location
Spill Area

Tables
Samp ID Samp ID
SS-1 SS-2
11/23/2022 11/23/2022
0.5'0.5'
TPH-GRO ND ND 50
TPH-DRO 9.1 ND 100
Total TPH 9.1 ND NS
Note:
ND - Not Detected
NS - No Standard
Bold Numbers Exceed NCDEQ TPH-GRO/DRO Threshold
TPH Threshold
Total Petroleum Hydrocarbons (TPH)(mg/kg)- Method 8015M
Table 1
Soil Analytical Results
6016 Corporate Park Drive
Browns Summit, North Carolina 27214
ANALYTE
Shamrock Environmenta

Appendix A
From:[e-mail]
To:Jim Hollingsworth
Subject:[EXTERNAL]NRC#1350274
Date:Tuesday, October 18, 2022 5:22:42 PM
CAUTION: The e-mail below is from an external source. Please exercise caution before opening attachments,
clicking links, or following guidance.
NATIONAL RESPONSE CENTER 1-800-424-8802
*** For Public Use ***
Information released to a third party shall comply with any
applicable federal and/or state Freedom of Information and Privacy Laws
Incident Report # 1350274
INCIDENT DESCRIPTION
*Report taken by NRC on 18-OCT-22 at 17:17 ET.
Incident Type: STORAGE TANK
Incident Cause: EQUIPMENT FAILURE
Affected Area:
Incident occurred on 18-OCT-22 at 16:45 local incident time.
Affected Medium: LAND / GRAVEL AREA
_______________________________________________________________________
SUSPECTED RESPONSIBLE PARTY
Organization: SHAMROCK ENVIRONMENTAL
GREENSBORO, NC 27415
Type of Organization: PRIVATE ENTERPRISE
_______________________________________________________________________
INCIDENT LOCATION
6106 CORPORATE PARK DR County: GUILFORD
City: BROWN SUMMIT State: NC
_______________________________________________________________________
RELEASED MATERIAL(S)
CHRIS Code: OTH Official Material Name: OTHER OIL
Also Known As: OTHER OIL - RECOVERED USED OIL
Qty Released: 50 GALLON(S)
_______________________________________________________________________
DESCRIPTION OF INCIDENT
RECOVERED USED OIL DISCHARGED FROM A FLOW-THROUGH TANK DUE TO A PUMP
FAILURE.
_______________________________________________________________________
INCIDENT DETAILS
Description of Tank: FLOW-THROUGH TANK
Tank Above/Below Ground: ABOVE
Transportable Container: NO
Tank Regulated: UNKNOWN
Tank Regulated By:
Tank ID: N/A
Capacity of Tank: 500 GALLON(S)
Actual Amount:
_______________________________________________________________________ IMPACT Fire Involved: NO Fire Extinguished: UNKNOWN
INJURIES: NO Sent to Hospital: Empl/Crew: Passenger: FATALITIES: NO Empl/Crew: Passenger: Occupant: EVACUATIONS:NO Who Evacuated: Radius/Area:
Damages: NO Hours Direction of Closure Type Description of Closure Closed Closure
Air: NO Major Road: NO Artery:NO
Waterway:NO
Track: NO
Passengers Transferred: NO Environmental Impact: UNKNOWN Media Interest: NONE ______________________________________________________________________ REMEDIAL ACTIONS OIL HAS BEEN CONTAINED AND AFFECTED AREA IS BEING REMOVED. Release Secured: YES Release Rate: Estimated Release Duration:
______________________________________________________________________ WEATHER
______________________________________________________________________ ADDITIONAL AGENCIES NOTIFIED Federal: State/Local: State/Local On Scene: State Agency Number: _______________________________________________________________________ NOTIFICATIONS BY NRC CENTERS FOR DISEASE CONTROL (GRASP) 18-OCT-22 17:21 CITY OF GREENSBORO EMERG MGMT (COMMAND CENTER) 18-OCT-22 17:21 CHEM SAFETY AND HAZARD INVEST BOARD (MAIN OFFICE) 18-OCT-22 17:21 CBP TRADE PTNRSHP AGAINST TERRORISM (CTPAT PROGRAM MIAMI) 18-OCT-22 17:21 DEPT OF HEALTH AND HUMAN SERVICES (SECRETARY OPERATION CENTER (SOC)) 18-OCT-22 17:21 DHS CISA (CISA CENTRAL) 18-OCT-22 17:21 DHS I&A STATE AND LOCAL PRGM OFFICE (RALEIGH, NC FUSION CENTER)
18-OCT-22 17:21
DHS SOUTH CAROLINA FUSION CENTER (LE SENSITIVE ADVISORS & LIASON PROGRAM)
18-OCT-22 17:21 DOT CRISIS MANAGEMENT CENTER (MAIN OFFICE) 18-OCT-22 17:21 U.S. EPA IV (MAIN OFFICE)
U.S. EPA IV (NC/SC INCIDENTS) 18-OCT-22 17:21 U.S. EPA IV (ENFORCEMENT AND COMPLIANCE ASSURANCE DIVISION (ECAD)) 18-OCT-22 17:21 GUILFORD COUNTY EMERGENCY MGMT (COMMAND CENTER) 18-OCT-22 17:21 NC DEPT OF EMERGENCY MGMT (MAIN OFFICE) 18-OCT-22 17:21 NC DEPT OF ENVIRONMENTAL QUALITY (DIVISION OF AIR QUALITY) 18-OCT-22 17:21 NC DEPT OF ENVIRONMENTAL QUALITY (DIVISION OF WASTE MANAGEMENT) 18-OCT-22 17:21 NC OCCUPATIONAL ENVMTL EPIDEMIOLOGY (COMMAND CENTER) 18-OCT-22 17:21 NC PUBLIC HEALTH PREPARE AND RESPNS (PHPR COMMAND CENTER) 18-OCT-22 17:21 NOAA RPTS FOR NC (MAIN OFFICE) 18-OCT-22 17:21 PIPELINE & HAZMAT SAFETY ADMIN (HAZARDOUS MATERIAL ACCIDENT INVESTIGATION) 18-OCT-22 17:21 DOI FOR REGION 4 (MAIN OFFICE) 18-OCT-22 17:21 REPORTING PARTY (RP SUBMITTER) 18-OCT-22 17:21 STATE OF NORTH CAROLINA DENR (MAIN OFFICE) 18-OCT-22 17:21 TENNESSEE VALLEY AUTHORITY (POLICE AND EMERGENCY MANAGEMENT) 18-OCT-22 17:21 USCG DISTRICT 5 (D5 DRAT) 18-OCT-22 17:21 _______________________________________________________________________ ADDITIONAL INFORMATION
_______________________________________________________________________ *** END INCIDENT REPORT #1350274 *** Report any problems by calling 1-800-424-8802 PLEASE VISIT OUR WEB SITE AT http://nrc.uscg.mil
Initial Site Assessment Report Appendix A
Report Formats
4. Initial Site Assessment Report(For non-UST petroleum releases onli)
Site RiskArlon-gg1 pun1. LowDt[e Klslvt\on_us.t Rank. rJuwESiteName: shamrock Environmental TTscrl rrir .Y_vr+ vseq vr! qrtd Wast.ewater ReIeESite Street Address: 510 6 corporate park orive
Release
ECity/Town: Browns Summit.zip Code: 272I4County: Guilf ord
to"n: aEI nnafin- I\,{^+L^l /nDo ---- -ELocationMethod(GPS,topographicalmap,othe.;:Goo
E)T qfifrrrla (A^^i^^t J^^-^^-\- a E 1 .n.
Syst.em
@Latitude (decimal degrees): 3 6 . 767 6 Longitude (decimal degrees): 7 g . 7 3 53 g
Information about contacts Associated with the Release (Addresses must include street, city, state, zip codeand mailing address, if dffirent)
EUST/AST Owner: SAA
Address:
Minimum elements of the report:
A. Site Information
l. Site Identification
@Date of Report: 12 . L 22
EFacilityl.D.: N7E--- InciclentNurnber: None
EUST/AST Operator:
Address:
EOther Person Associated with Release:
Address:
EProperty Owner: SAA
Address:
Tel:
Tel:EProperty Occupant:SAA
Address:
3.
both) in
4' certification (The .title page must display the seal and signature of the certping p,E. or L,G, qnd the name andcertification number of the company or corporation [sie t sA NCAC zL .tiiosiq.D
(Please ffix Seal and Signature)
or corporation) is licensed to p one ornumber ofthe company or cor
Tal.r gt.EConsultant/Contractor: Waters Edge Environmerrtal
Address: 1 3a ChAddress:
EAnalytical Laboratorv: Pace
Address: 9800 Kincevl"t300"5""t{{' statecertifiqaliqn Nt-Ttlu*: rel: rro. o?j^.,d"gzT_qJ. VJALHunLersvi1le, N-a-2 B O 78I nformation about Release
EDate Discovered: 10 .
EEstimated Quantity of Release: 50 Gal . Used Oil and Wast.ewaLerECause of Release: Equipment. Fai lureESource of Release: WW Flow Through TankESizes and contents of Tank or other containment from which the Release eesullsi; 5 o 0 Gal .
ofcompany
ceftification
7
71
For Non.UST
Releases of
Petroleum in NG
This form rhorld b
petroleum from a source other than.an underground storage tank. This form is required to be submitted within 24 hours ofdiscovery of a known or suspected petroleum release
(DWM USE ONLY)IncrqenlT._ priority Rank (H,l,L,U) _Received (time/date)
KeCelVe0 DV Roninn.- -J--Keponeo oy lcircte one): phone, Fax or Report
Suspected Contamination? (y/N)
Confirmed GW. Contamination? (VN)
Confirmed Soil Contamination ?(y/Ni -
9?f plg. taken?(Y/N)_ Free prooudi?-1vtrrrl _lf Yes(free product), state greatest thickness: '
feel
Release discovered
(time/date):
shamrock Envi ronm."S9lDuEtE %19.
Address (street number/name):qlqS Corporale park Drive county: Guilford
City/Town: Browns Summit.Zip Code: 27 2I4 ?1i97 t"yae.91.e): As@
Latitude (oecimaldesrees): 39, 767 6 Longitude (decimatdesrees) : j g . 7 353g d bv:
E Electronic topographic map
E Ots Address matching
E otner
iQ unrnown
ftscribe location:
r suspected or confirmed release (nat
10'18.22- Equipment. failure from ww flow t.hrouqh t.ank
releases 50 galrons of used oil and ww on the gravel baseDescribe initial response/abatement ft ^soil removed, confirmation samplino) :
Vac. t.rucks removed 4, OO0 qal_and 34 Lons of impact.ed me
Describe inrpacted receptors:Confirmalory sampling Joelow NCDEe t.hreho
Water Supply Well Contamination
Surface Water Contamination
HOWRELEASEWAS DISCffi
servation of Release at Occurrence
I Visual or Olfactory Evidence
fl Soit Contamination
fl Groundwater Contamination
fl spirr (Accidentat)
E spill (tntentionat)
D corrosion
Q Rnysicat or Mechanical
amage
ipment Failure
E AST overfitl
fl nSf Instailation problem
fl unknown
fl otner
Definitions presented on reverse
0teum
fl eotn petroteum
& Non-Petroleum
fl Gasotine/ Dieset/
Kerosene
D rrr -ezo
O eer - re+
D ees - ess
I Ethanot 100%
SOURCE OF CONTAMINATION
Source of Release(Check one to indicate primary
source)
(tank)
fl nsr piping/ Dispenser
D nSr Delivery problem
O orn vehicte Tank
fl orn Bulk Transport Tank
D RR ault Transport Tank
E Transformer
E unknown
fl otter
l Publicservice 2. Agricultural 3. Residential 4. Education/Rerig.eTfi;iQ6. commerciat 7. MiningGuidance presented on reverse " \* ---
Ownership
1. Municipal 2. Miritarv o. unrnown/frEiGi? 5. Federar 6. county 7, stare
Page
IMPACTONDR@
Water Supply Wells Affected?r. ves (TTD 3 unknown Number of Water Supply Wells Affected 0
(lnclude rtru
r'::::o r n "' u t u u' " i " n o t u''q s r' v ulAY'I tnF
"J
Name of Person Shamrock Environment.al 6106 Corporate park nriveBrowns Summit Codg -n^1 ^z /z!1
AST SYST'' O
AST owner/compunv SaA-
USTOperator/Cornpany SAA
LANDOWNE
Draw Sketch of Area or PfOVidg Map lstrowrn g incidentsite, Iocation,
etturn ,[u'tlipo'ftrl]p n ro,^ see Figure in Reporr.
Give Directions t
Refer to Google EarLh
coryav waters
FsfFr lf^a
UST Form 62 (04tj
Definitions ofsources
AST (Tank):
AST Piping:
AST Dispenser
Page 2
means the tank is used to store productmeans the i,'ijJl,i:ll.:.j,::::1,^1r:Tlllq frorn rhe tank to rhe dispenser or ortrer end_Lrse equipmenr
Transformer:Ineans electrical transfornrer
AST Delrvery Problenr l[lli:::i: :::T lil: ltl ll_: :tip*",f u,J io.,,;ffi;;il;#iilil ;:';,ii;'-r -
i9:1if'.r releases that occurred during product delivery to the rank3I* J:|l]."i.:lll,::" ln.:* rhe rank is ,,ro to ,1o,, pioJ;;i'ffii;iJ;ffi; ffi";iirfi;R[-*ll]llllSn,l::ll ::T:1rlt,l;; l,;;;";;;;,;il'ilil;ftTilll,l.lln.,".o (by rruck)ffiilffiiliililiil;;::iliTransformcr ha.h. ^r^^+-:^^r r-^ --.
other: serves as the option to use when the release soLrrce is l(nown but does not fit into one of the preceding categoriesUnknown: identifies rereases for wrricrr irr. r"rr.. has not been deter'rinedDefinitions of Causes
:n the delivery hose is disconnected frorn a fill pipe)entional dumping or breakage)
r release due to corrostotl
:chanical danrage, except corr osion
)r than corrosion or physical or mechanical damase:m the filr pipe at the tank or wrren the nozzre fail-s to shut offat the dispenser)occurred specifically because the AST system was not installed pr.p*fy
-' ,'the preceding categories
,stem, bulk transport tank, or other release source:h owner Lrses the AST systern, bulk transport tank, or other release source

Appendix B

Appendix C
#=CL#
November 30, 2022
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92638383
92638383
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
1434 Chester Road
Raleigh, NC 27606
R22-62
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on November 23, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 11
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92638383
R22-62
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 11
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92638383
R22-62
Lab ID Sample ID Matrix Date Collected Date Received
92638383001 SS-1 Solid 11/23/22 09:45 11/23/22 12:55
92638383002 SS-2 Solid 11/23/22 10:00 11/23/22 12:55
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 11
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92638383
R22-62
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92638383001 SS-1 EPA 8015C 2 PASI-CBAJ
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92638383002 SS-2 EPA 8015C 2 PASI-CBAJ
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 11
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92638383
R22-62
Sample:SS-1 Lab ID:92638383001 Collected:11/23/22 09:45 Received:11/23/22 12:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)9.1 mg/kg 11/30/22 10:2511/29/22 17:026.7 4.8 1
Surrogates
n-Pentacosane (S)78 %11/30/22 10:25 629-99-211/29/22 17:0210-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/29/22 20:1611/29/22 11:2210.2 2.8 1
Surrogates
4-Bromofluorobenzene (S)97 %11/29/22 20:16 460-00-411/29/22 11:2266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 26.1 %11/29/22 13:55 N20.10 0.10 1
Sample:SS-2 Lab ID:92638383002 Collected:11/23/22 10:00 Received:11/23/22 12:55 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-
C28)ND mg/kg 11/30/22 10:2511/29/22 17:026.6 4.7 1
Surrogates
n-Pentacosane (S)65 %11/30/22 10:25 629-99-211/29/22 17:0210-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/30/22 10:2911/29/22 11:229.8 2.7 1
Surrogates
4-Bromofluorobenzene (S)94 %11/30/22 10:29 460-00-411/29/22 11:2266-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 24.0 %11/29/22 13:55 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 11
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638383
R22-62
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739756
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638383001, 92638383002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3848892
Associated Lab Samples:92638383001, 92638383002
Matrix:Solid
AnalyzedMDL
Gas Range Organics (C6-C10)mg/kg ND 6.0 11/29/22 13:501.7
4-Bromofluorobenzene (S)%96 66-130 11/29/22 13:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3848893LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 61.350.1 122 70-130
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3848895MATRIX SPIKE SAMPLE:
MSSpike
Result
92638465004
Gas Range Organics (C6-C10)mg/kg 91.380.9 112 65-146ND
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638465003
3848894SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg ND 30ND
4-Bromofluorobenzene (S)%9897
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 11
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638383
R22-62
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739931
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638383001, 92638383002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3849997
Associated Lab Samples:92638383001, 92638383002
Matrix:Solid
AnalyzedMDL
Diesel Range Organics(C10-C28)mg/kg ND 5.0 11/30/22 10:093.6
n-Pentacosane (S)%80 10-130 11/30/22 10:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3849998LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 47.065.6 72 44-130
n-Pentacosane (S)%75 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3849999MATRIX SPIKE SAMPLE:
MSSpike
Result
92637874001
Diesel Range Organics(C10-C28)mg/kg 82.4111 70 10-130ND
n-Pentacosane (S)%69 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92637874002
3850000SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg ND 30ND
n-Pentacosane (S)%6078
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 11
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92638383
R22-62
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739841
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92638383001, 92638383002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92637772001
3849453SAMPLE DUPLICATE:
Percent Moisture %18.7 N242519.5
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638444001
3849454SAMPLE DUPLICATE:
Percent Moisture %68.7 N222569.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 11
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92638383
R22-62
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 11
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92638383
R22-62
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92638383001 739931 740056SS-1 EPA 3546 EPA 8015C
92638383002 739931 740056SS-2 EPA 3546 EPA 8015C
92638383001 739756 739813SS-1 EPA 5030B EPA 8015C
92638383002 739756 739813SS-2 EPA 5030B EPA 8015C
92638383001 739841SS-1 SW-846
92638383002 739841SS-2 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 04:31 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 11
Page 11 of 11