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HomeMy WebLinkAboutWS-96113_96490_CA_RPTS_20210809 January 29, 2021 Mr. Scott Wellborn SEGRA One Lumos Plaza Waynesboro, Virginia 22980 Reference: Soil and Groundwater Assessment Report (Revised) Northstate Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 Dear Mr. Wellborn: As authorized by your acceptance of ECS Proposal 49:19518-PR (revised) dated July 24, 2020 and authorized on August 10, 2020, ECS Southeast, LLP (ECS) has completed the Soil and Groundwater Assessment Report (Revised) for the above referenced site. Included in this report is a description of the field activities, the results obtained, and our conclusions and recommendations. ECS appreciates the opportunity to provide our services to you. If there are questions regarding this report, or a need for further information, please contact us. Respectfully submitted, ECS SOUTHEAST, LLP Randy H. Cavallier Assistant Staff Project Manager rcavallier@ecslimited.com Joseph P. Nestor, P.G., P.E. Environmental Principal jnestor@ecslimited.com SOIL AND GROUNDWATER ASSESSMENT REPORT (REVISED) NORTHSTATE TELEPHONE SERVICE GARAGE 1201 WEST FAIRFIELD ROAD HIGH POINT, GUILFORD COUNTY, NORTH CAROLINA ECS PROJECT NO. 49-12119 PREPARED FOR SEGRA WAYNESBORO, VIRGINIA JANUARY 29, 2021 Soil and Groundwater Assessment Report (Revised) NorthState Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 January 29, 2021 1 TABLE OF CONTENTS 1.0 PROJECT INFORMATION ................................................................................................. 1 2.0 SCOPE OF SERVICES ...................................................................................................... 1 3.0 RESULTS ............................................................................................................................ 3 4.0 CONCLUSIONS .................................................................................................................. 4 5.0 RECOMMENDATIONS ....................................................................................................... 4 6.0 QUALIFICATIONS OF REPORT ........................................................................................ 4 FIGURES Figure 1 Site Topographic Map Figure 2 Aerial Site Map Figure 3 Sample Location Map TABLES Table 1 Summary of Soil Analytical Results Table 2 Summary of Groundwater Analytical Results APPENDICES Appendix A Site Photograph Log Appendix B Boring Logs Appendix C Laboratory Data Sheets and Chain-of-Custody Records Soil and Groundwater Assessment Report (Revised) NorthState Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 January 29, 2021 1 1.0 PROJECT INFORMATION The site is the Northstate Telephone vehicle service garage located at 1201 West Fairfield Road in High Point, Guilford County, North Carolina (Figure 1 and Figure 2). Mr. Scott Wellborn with SEGRA contracted ECS to perform soil and groundwater assessment at the site in an effort to determine if the use of the site as a vehicle service garage has impacted the soil and groundwater beneath the site. 2.0 SCOPE OF SERVICES The environmental assessment consisted of collecting two (10) soil samples and three (3) groundwater samples at the site. Drilling activities were conducted using a Geoprobe® drill rig and hand auger. The subcontractor used for this project was 3D Environmental Investigations, LLC (3D). Drilling and sampling activities were conducted on August 19, 2020 and August 25, 2020. Additional hand auger soil sampling was completed on December 15, 2020 to further assess the utility pole storage area at the site. A photographic log documenting the field sampling activities is provided in Appendix A. 2.1 Public Utility Locate Prior to commencing with field activities, ECS contacted the North Carolina 811 service to locate/mark public utilities at the site. ECS also contracted with a private utility locating service to locate private underground utilities at the site. Required separation distances between subsurface activities and marked utilities (typically 30-inches) were maintained during the field activities. 2.2 Soil Sampling Activities On August 19, 2020, soil borings GP-1 through GP-8, HA-1 and HA-2 were drilled to collect soil samples. Soil borings GP-1 through GP-8 were drilled to a depth of approximately ten feet below ground surface (bgs). Soil borings HA-1 and HA-2 were drilled to a depth of one foot bgs. The approximate locations of the borings is shown on Figure 3. Soil samples GP-1 through GP-8 were collected by driving a macrocore sampler with the Geoprobe® drill rig in 5-foot intervals in each soil boring. Each 5-foot sample sleeve was divided in half and screened for volatile organic compounds in the field using a Thermo Scientific Toxic Vapor Analyzer 2020 flame ionization detector (FID). In each boring, the soil interval with the highest FID reading was collected for laboratory analysis. If no organic vapors were detected, the sample collected from the bottom of the boring was submitted for analysis. Soil samples HA-1 and HA-2 were collected using a decontaminated hand auger. Both soil samples HA-1 and HA-2 were collected over the interval of 0 to 1-foot bgs. The soil was characterized by an ECS professional. Boring logs can be found in Appendix B. Prior to the initial boring and after each subsequent boring the sampling equipment was decontaminated using a high-pressure steam cleaner. On December 15, 2020, based on the laboratory analytical results of soil samples HA-1 and HA-2 (See below), soil borings HA-3 through HA-10 (Figure 3) were drilled using a decontaminated hand auger in the utility pole storage area. Soil samples HA-3 through HA-10 were collected over the interval of 0 to 1-foot bgs. Soil and Groundwater Assessment Report (Revised) NorthState Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 January 29, 2021 2 Soil samples GP-1 through GP-8, HA-1 and HA-2 were placed into laboratory provided jars, labeled, and maintained on ice until delivered to Pace Analytical Services, LLC (Pace) to be analyzed for volatile and semi-volatile organic compounds (VOCs and SVOC) using EPA Methods 8260 and 8270, respectively. Soil samples HA-3 through HA-10 were analyzed for SVOCs using EPA Method 8270. The samples were maintained under chain-of-custody until delivered to the laboratory. Chain-of Custody Records are included in Appendix C. Soil sample results for soil samples T-1 and P-1 were collected as part of a Limited Site Assessment (LSA) for the on-site hydraulic lift closure and are reported on the same laboratory report but are not part of this assessment. 2.3 Groundwater Sampling Activities Soil borings GP-3 and GP-5 were advanced using direct push technology (DPT) to below the water table for the collection of groundwater samples GW-1 and GW-2. Groundwater boring GW-3 was advanced on the southern portion of the site using hollow stem augers because of drilling refusal using DPT. The locations of the groundwater borings are shown on Figure 3. The groundwater samples were collected from a depth of approximately 6-13 feet bgs. Groundwater samples GW-1 and GW-2 were collected by driving a 4-foot long, 1-inch diameter water-sampling probe into the soil to an approximate depth of 4 feet beneath the water table as estimated during drilling. The groundwater sampling probe is a 1-inch diameter stainless steel probe with a 19-inch screened interval inside of a perforated stainless-steel sleeve. The stainless steel screen has a pore size of 0.145 millimeter (mm). Connections are sealed with O-rings to prevent water from entering the sampler prior to achieving the desired depth. When the desired sampling depth is reached, the sampler is retracted approximately 4 to 5 feet, which disengages the expendable drive point and creates an open borehole from which to sample. The inner core, which consists of the stainless steel wire screen inside of a perforated stainless steel sleeve, is then pushed into the borehole space and water is allowed to enter the sampler. Groundwater sample GW-3 was collected from a 2-inch diameter temporary monitoring well installed using hollow stem augers on August 25, 2020. The temporary well was constructed with 2-inch I.D. schedule 40 PVC flushed-threaded casing and screen. The PVC screen and casing were lowered to the bottom of each borehole (15 feet bgs) . A 10-foot length of slotted well screen with machined 0.010-inch slot widths and threaded bottom plug were installed at the bottom of the well. A solid section of PVC casing was placed above the screened interval and extended to a point approximately 0.5 foot above the ground surface. The annular space around the well screen was filled with washed fine filter sand to approximately 2 feet above the top of the screen. A minimum 2-foot thick seal of bentonite pellets was placed immediately above the sand pack. The top of each well casing was equipped with a lockable, water-tight well plug. Prior to sampling, groundwater borings GW-1 and GW-2 were purged using a new length of disposable polyethylene tubing connected to a peristaltic pump. Temporary monitoring well GW-3 was purged and a sample was collected using a new disposable polyethylene bailer and new length of nylon cord. The groundwater sample points were developed/purged to remove sand, silt and other fine sediments which may have entered the drilling and to promote communication between the surrounding formation and the screened interval of the groundwater sampler. After the purging was completed, groundwater samples were collected and transferred into sample containers provided by the laboratory. Soil and Groundwater Assessment Report (Revised) NorthState Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 January 29, 2021 3 The groundwater sample containers were labeled and placed into a cooler with ice to maintain the samples at approximately 4° Celsius (C°). The samples were submitted to Pace to be analyzed for VOCs and SVOCs using Standard Method 8260 and 8270, respectively. ECS maintained chain-of-custody procedures throughout the sample collection and transportation process. Chain-of Custody Records are included in Appendix C. 3.0 RESULTS 3.1 Soil Sample Analytical Results Laboratory analysis of soil samples GP-1 through GP-5, GP-7, and GP-8 did not detect target VOCs and SVOCs above the laboratory detection limits. Laboratory analysis of soil sample GP-6 collected in the vicinity of the used oil above ground storage tank (AST) detected fluoranthene at a concentration above the laboratory detection limits but below its applicable NCDEQ Maximum Soil Contaminant Concentration (MSCC). Laboratory analysis of soil sample HA-1 collected in the vicinity of the utility pole storage area detected pentachlorophenol at a concentration (72.4 mg/kg) above its respective Residential and Industrial/Commercial MSCCs (5 milligrams per kilogram [mg/kg] and 48 mg/kg, respectively). Laboratory analysis of soil sample HA-2 collected in the vicinity of the utility pole storage area detected pentachlorophenol at a concentration (8.7 mg/kg) above its Residential MSCC (5 mg/kg). A summary of the laboratory analytical results is shown on Table 1 and the laboratory data sheets are included in Appendix C. Laboratory analysis of soil samples HA-3, HA-5, and HA-6 detected pentachlorophenol (the contaminant of concern from the August 2020 sampling) at concentrations of 3.5 mg/kg, 1.8 mg/kg, and 1.5 mg/kg, respectively above its Soil-to-Groundwater MSCC of 0.0065 mg/kg. Laboratory analysis of soil samples HA-4 and HA-7 through HA-10 did not detect pentachlorophenol above the laboratory reporting limit (RL) of 0.75 mg/kg; however, the RL is above the Soil-to-Groundwater MSCC. Laboratory analysis of soil sample HA-3 detected benzo(a)anthracene, and benzo(b)fluoranthene at concentrations of 0.99 mg/kg and 3.2 mg/kg, respectively, above their respective Residential MSCC (0.88 mg/kg). Laboratory analysis of soil sample HA-10 detected Indeno(1,2,3-cd)pyrene at a concentration of mg/kg above its Residential MSCC of 0.88 mg/kg. Laboratory analysis of soil sample HA-3 detected benzo(a)pyrene at the concentration of 3.2 mg/kg which is above its Industrial/Commercial MSCC of 0.78 mg/kg. 3.2 Groundwater Sample Analytical Results Laboratory analysis of groundwater sample GW-1 detected diisopropyl ether (DIPE), and methyl-tert-butyl ether (MTBE) above the laboratory detection limit but below their North Carolina 2L Groundwater Standard (NC2LGWQS). Laboratory analysis of groundwater sample GW-2 detected acetone, 2-Butanone (MEK), naphthalene, p-Isopropyltoluene, and total xylenes above the laboratory detection limit but below their NC2LGWQS. Laboratory analysis of groundwater sample GW-3 did not detect target VOCs or SVOCs above the laboratory RLs. A summary of the laboratory analytical results is shown on Table 2 and the laboratory data sheets are included in Appendix C. Soil and Groundwater Assessment Report (Revised) NorthState Telephone Service Garage 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 January 29, 2021 4 4.0 CONCLUSIONS Based on the laboratory analytical results; ECS concludes the following: • Fluoranthene was detected in soil sample GP-6 collected in the vicinity of the ASTs below its respective MSCCs. • Pentachlorophenol was detected in soil samples (HA-1 and HA-2) collected in the vicinity of the utility pole storage above their respective Residential and/or Industrial/Commercial MSCCs. • Pentachlorophenol was detected in soil samples HA-3, HA-5, and HA-6 collected in the vicinity of the utility pole storage above its Soil-to-Groundwater MSCC. • Benzo(a)anthracene, and benzo(b)fluoranthene were detected in soil sample HA-3 above their respective Residential MSCCs. • Indeno(1,2,3-cd)pyrene was detected in soil sample HA-10 at a concentration above its Residential MSCC. • Benzo(a)pyrene was detected in soil sample HA-3 above its Industrial/Commercial MSCC. • Petroleum-related compounds were detected in groundwater collected in the vicinity of the maintenance shop (GW-1) and ASTs (GW-2) below their respective NC2LGWQS. Targeted VOCs and SVOCs were not detected in groundwater sample GW-3 collected in the vicinity of the utility pole storage. • A regulatory (NCDEQ) reporting requirement may exist for the site. 5.0 RECOMMENDATIONS Based on the results of the environmental assessment, ECS recommends the following: • ECS recommends that soil in the vicinity of the utility pole storage in the vicinity of soil samples HA-1 and HA-3 (Figure 4) be removed for off-site disposal in an effort to remediate the soil to below the Industrial/Commercial MSCCs. ECS estimates that approximately 120 tons of soil will be removed for off-site disposal. Following excavation, ECS recommends that confirmatory soil samples be collected and analyzed for SVOCs. • ECS recommends seeking legal counsel concerning possible reporting requirements. 6.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in environmental assessment projects of this type. Our evaluation of site conditions has been based on our understanding of the site project information and the data obtained during our field activities. This report was prepared for the express use of SEGRA. Use of this report by other individuals or companies implies their acceptance of the General Conditions of Service of the original contract. FIGURES SOURCE: USGS TOPOGRAPHIC MAP 7.5 –MINUTE SERIES HIGH POINT WEST + HIGH POINT EAST, NC DATED: 2019 SCALE: 1 : 24,000 CONTOUR INVERVAL = 10’ FIGURE 1 SITE TOPOGRAPHIC MAP 1201 WEST FAIRFIELD ROAD HIGH POINT, GUILFORD COUNTY, NC ECS PROJECT NO. 49-12119 APPROXIMATE SITE LOCATION SOURCE: GUILFORD COUNTY GIS SCALE: 344 fEET LEGEND SAMPLE LOCATION APPROXIMATE UST LOCATION APPROXIMATE SITE BOUNDARY FIGURE 2 AERIALSITE MAP 1201 WEST FAIRFIELD ROAD HIGH POINT, GUILFORD COUNTY, NC ECS PROJECT NO. 49-12119 P-2 T-1 SOURCE GUILFORD COUNTY GIS SCALE: 75 fEET LEGEND SAMPLE LOCATION APPROXIMATE UST LOCATION APPROXIMATE SITE BOUNDARY FIGURE 3 SAMPLE LOCATION MAP 1201 WEST FAIRFIELD ROAD HIGH POINT, GUILFORD COUNTY, NC ECS PROJECT NO. 49-12119 GP-1 GP-2 GP-3/GW-1 GP-4 GP-5/GW-2 GP-6 GP-7GP-8 HA-1/GW-3 HA-2 SOURCE GUILFORD COUNTY GIS SCALE: NTS LEGEND SAMPLE LOCATION APPROXIMATE UST LOCATION APPROXIMATE SITE BOUNDARY FIGURE 4 SAMPLE LOCATION MAP (Pole Storage) 1201 WEST FAIRFIELD ROAD HIGH POINT, GUILFORD COUNTY, NC ECS PROJECT NO. 49-12119 GP-1 GP-2 GP-3/GW-1 GP-4 GP-5/GW-2 GP-6 GP-7GP-8 August 2020 Soil Sample Location December 2020Soil Sample Location Areas Impacted above Industrial/Commercial MSCCs HA-2HA-3 HA-1 Pole Storage Areas TABLES Northstate Telephone 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 Sample Identification GP-1 GP-2 GP-3 GP-4 GP-5 GP-6 GP-7 GP-8 HA-1 HA-2 Soil to Groundwater MSCC (mg/kg) Residential MSCC (mg/kg) Indusrtial/ Commercial MSCC (mg/kg) Sample Date FID Readings 12.4 64.7 57.1 36.6 67.8 19.5 44.1 55.1 6.5 6.4 AllTarget Compounds ND ND ND ND ND ND ND ND ND ND -- -- -- Fluoranthene <3.0 <3.0 <3.0 <3.0 <3.0 0.54 <3.0 <3.0 <3.0 <3.0 290 620 16,400 Pentachlorophenol <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 <3.0 72.4 8.7 0.0065 5 48 Sample Identification HA-3 HA-4 HA-5 HA-6 HA-7 HA-8 HA-9 HA-10 Soil to Groundwater MSCC (mg/kg) Residential MSCC (mg/kg) Indusrtial/ Commercial MSCC (mg/kg) Sample Date VOCs by EPA 8260 AllTarget Compounds NS NS NS NS NS NS NS NS -- -- -- SVOCs by EPA 8270 Anthracene 0.39 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.76 940 4,600 122,000 Acenaphthylene <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 0.51 11 469 12,264 Benzo(a)anthracene 0.99 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 2.2 0.35 0.88 8 Benzo(a)pyrene 3.2 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 1.7 0.096 0.088 0.78 Benzo(g,h,i)perylene 0.59 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 1.3 6,400 469 12,264 Benzo(b)fluoranthene 3.2 <0.38 0.80 <0.38 <0.38 <0.38 <0.38 5.6 1.2 0.88 8 Benzo(k)fluoranthene 1.2 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 1.5 12 9 78 Chrysene 2.2 <0.38 0.62 <0.38 <0.38 <0.38 <0.38 3.1 39 88 780 Fluoranthene 3.0 <0.38 0.89 <0.38 <0.38 <0.38 <0.38 3.3 290 620 16,400 Indeno(1,2,3-cd)pyrene 0.60 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 1.2 3.4 0.88 8 Pentachlorophenol 3.5 <0.75*1.8 1.5 <0.75*<0.75*<0.75*<0.75*0.0065 5 48 Phenanthrene 0.45 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 <0.38 56 469 12,264 Pyrene 2.6 <0.38 <0.80 <0.38 <0.38 <0.38 <0.38 5.1 270 469 12,264 NOTES: VOCs = Volatile Organic Compounds mg/kg = milligrams per kilogram = ppm (parts per million) SVOCs = Semi-volatile Organic Compounds BOLD = Concentration Exceeds Soil-to-Groundwater MSCC MSCC = Maximum Soil Contaminant Concentration UNDERLINE = Concentration Exceeds Residential MSCC ND = Not Detected Above Laboratory Reporting Limits NS = Parameter Not Sampled For SVOCs by EPA 8270 TABLE 1: SUMMARY OF SOIL ANALYTICAL RESULTS 8/13/2020 ITALICS = Concentration Exceeds Industrial/Commercial MSCC VOCs by EPA 8260 * = Reporting Limit Above Soil-to-Groundwater MSCC 12/15/2020 Northstate Telephone 1201 West Fairfield Road High Point, Guilford County, North Carolina ECS Project No. 49-12119 Sample Identification GW-1 GW-2 GW-3 Sample Date VOCs by EPA Method 8260 Acetone <25.0 39.4 <25.0 6,000 Diisopropyl Ether (DIPE)6.9 <1.0 <1.0 70 2-Butanone (MEK)<5.0 11.4 <5.0 4,000 Methyl-tert-butyl Ether (MTBE)9.9 <1.0 <1.0 20 Naphthalene <1.0 4.0 <1.0 6 p-Isopropyltoluene <1.0 2.0 <1.0 25 Xylenes (Total)<1.0 1.6 <1.0 500 All Targeted Compounds ND ND ND NA Notes: NA = Not Applicable NC2LGWQS = North Carolina 2L Groundwater Quality Standard All results reported in µg/l = micrograms per liter = ppb (parts per billion) BOLD = Concentration exceeds NC2LGWQS TABLE 2: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS NC2LGWQS6/5/2019 ND = Not Detected Above Laboratory Reporting Limits SVOCs by EPA Method 8270 VOCs = Volatile Orgnic Compounds SVOCs = Semi-Volatile Organic Compounds APPENDIX A (Photographic Log) PHOTOGRAPH LOG 1201 WEST FAIRFIELD ROADHIGH POINT, GUILFORD COUNTY, NORTH CAROLINAECS PROJECT NO. 49-12119 Photograph 1: Geoprobe Soil Boring in Vicinity of Fuel Dispensers Photograph 2: Collection of Groundwater Sample GW-1 PHOTOGRAPH LOG 1201 WEST FAIRFIELD ROADHIGH POINT, GUILFORD COUNTY, NORTH CAROLINAECS PROJECT NO. 49-12119 Photograph 3: Geporobe Soil Boring in Vicinity of Oil Change Pit Photograph 4: Geoprobe Soil Boring in Vicinity of ASTs PHOTOGRAPH LOG 1201 WEST FAIRFIELD ROADHIGH POINT, GUILFORD COUNTY, NORTH CAROLINAECS PROJECT NO. 49-12119 Photograph 5: Geoprobe Groundwater Boring In Vicinity of ASTs Photograph 6: Drilling Groundwater Sample GW-3 with Hollow-Stem Augers APPENDIX B (Boring Logs) 0 5 10 15 20 25 30 35 12.4 6.9 7.1 GP-1 ML-CL ML Brown clayey silt Water at 6' Brown silt End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-1 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 64.7 7.1 GP-2 CL ML-CL Gray brown clay Brown clayey silt Water at 6' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-2 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 57.1 41.2 GP-3 ML-CL Brown clayey silt Water at 7' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-3 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 32.6 7.4 GP-4 ML-CL ML Brown clayey silt Brown silt Water at 6' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-4 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 27.3 67.8 GP-5 ML Brown silt Water at 6' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-5 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 19.5 11.4 GP-6 ML Brown silt Water at 6' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-6 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 6.6 44.1 GP-7 SW ML Brown sand - wet Brown silt End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-7 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 55.1 44.2 GP-8 ML Brown silt Dark brown silt Water at 7' End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.GP-8 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 6.5 Ha-1 SW-SP Fill Brown sandrock End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.Ha-1 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 0 5 10 15 20 25 30 35 6.4 Ha-2 SW-SP Fill Brown sandrock End of boring PROJECT:NorthState Telephone Service GarageBORING NUM.Ha-2 CLIENT:SEGRA PROJECT NO.12119 LOCATION: 1201 West Fairfield Road, High Point, NC ELEVATION: DRILLER: 3D Environmental Investigations DATE DRILLED: 8/19/20 LOGGED BY: Randy Cavallier DRILL RIG: Geoprobe DEPTH TO WATER: Elevation/ Depth (Ft)PIDReadingSampleNumberSampleRecovery(in/in)Graphic LogSoilClassificationSOIL DESCRIPTION This information pertains only to this boring and should not be interpreted as being indicative ofthe site.Page 1 of 1 Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-10 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-10 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-3 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-3 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-4 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-4 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-5 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-5 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-6 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-6 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-7 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon HA-7 END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-7 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-8 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-8 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley Depth/ 5 10 15 20 25 30 ElevaƟon -5 -10 -15 -20 -25 PID ReadingSample NumberHA-9 Sample Recovery (in)Graphic LogSoil ClassiĮcaƟon SW-SP DescripƟon Brown Sandrock END OF DRILLING AT 1.0 FT Project Name:NorthState -West FairĮeld Road - Environmental Svcs Client:SEGRA Site LocaƟon:1201 West FairĮeld Road, High Point, North Carolina 27263 LaƟtude/Longitude: Sheet:1 of 1 Boring No:HA-9 Project No.:49:12119 Driller:Drill Rig:Hand Auger WL (First Encountered)Boring Started:Dec 15 2020 WL (CompleƟon)Boring Completed:Dec 15 2020 Remarks:Logged By: Principal Engineer/ Responsible PG: Randy H. Cavallier ScoƩ Werley APPENDIX C (Laboratory Data Sheets and Chain of Custody Record) #=CL# August 28, 2020 LIMS USE: FR - RANDY CAVALLIER LIMS OBJECT ID: 92492009 92492009 Project: Pace Project No.: RE: Mr. Randy Cavallier ECS Southeast, LLP 4811 Koger Blvd. Greensboro, NC 27407 Northstate Dear Mr. Cavallier: Enclosed are the analytical results for sample(s) received by the laboratory on August 21, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com Project Manager (704)875-9092 Enclosures cc:ECS Southeast Reporting, ECS Southeast REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 90 #=CP# CERTIFICATIONS Pace Project No.: Project: 92492009 Northstate Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 90 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92492009 Northstate Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92492009001 GP-1 (8270)EPA 8270E 75 PASI-CBPJ ASTM D2974-87 1 PASI-CCLW 92492009002 GP-1 (8260)EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009003 GP-2 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009004 GP-3 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009005 GP-4 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009006 GP-5 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009007 GP-6 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009008 GP-7 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009009 GP-8 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009010 HA-1 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009011 HA-2 EPA 8270E 75 PASI-CBPJ EPA 8260D 70 PASI-CSAS ASTM D2974-87 1 PASI-CCLW 92492009012 GW-1 EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CPM1 92492009013 GW-2 EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CPM1 92492009014 T-1 MADEP EPH 7 PASI-CBAJ EPA 8270E 75 PASI-CBPJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 90 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92492009 Northstate Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts ASTM D2974-87 1 PASI-CCLW 92492009015 P-1 MADEP EPH 7 PASI-CBAJ EPA 8270E 75 PASI-CBPJ ASTM D2974-87 1 PASI-CCLW PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-1 (8270)Lab ID:92492009001 Collected:08/19/20 09:35 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 11:19 83-32-908/27/20 12:350.39 1 Acenaphthylene ND mg/kg 08/28/20 11:19 208-96-808/27/20 12:350.39 1 Aniline ND mg/kg 08/28/20 11:19 62-53-308/27/20 12:350.39 1 Anthracene ND mg/kg 08/28/20 11:19 120-12-708/27/20 12:350.39 1 Benzo(a)anthracene ND mg/kg 08/28/20 11:19 56-55-308/27/20 12:350.39 1 Benzo(a)pyrene ND mg/kg 08/28/20 11:19 50-32-808/27/20 12:350.39 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 11:19 205-99-208/27/20 12:350.39 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 11:19 191-24-208/27/20 12:350.39 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 11:19 207-08-908/27/20 12:350.39 1 Benzoic Acid ND mg/kg 08/28/20 11:19 65-85-008/27/20 12:352.0 1 Benzyl alcohol ND mg/kg 08/28/20 11:19 100-51-608/27/20 12:350.78 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 11:19 101-55-308/27/20 12:350.39 1 Butylbenzylphthalate ND mg/kg 08/28/20 11:19 85-68-708/27/20 12:350.39 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 11:19 59-50-708/27/20 12:350.78 1 4-Chloroaniline ND mg/kg 08/28/20 11:19 106-47-808/27/20 12:350.78 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 11:19 111-91-108/27/20 12:350.39 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 11:19 111-44-408/27/20 12:350.39 1 2-Chloronaphthalene ND mg/kg 08/28/20 11:19 91-58-708/27/20 12:350.39 1 2-Chlorophenol ND mg/kg 08/28/20 11:19 95-57-808/27/20 12:350.39 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 11:19 7005-72-308/27/20 12:350.39 1 Chrysene ND mg/kg 08/28/20 11:19 218-01-908/27/20 12:350.39 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 11:19 53-70-308/27/20 12:350.39 1 Dibenzofuran ND mg/kg 08/28/20 11:19 132-64-908/27/20 12:350.39 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 11:19 95-50-108/27/20 12:350.39 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 11:19 541-73-108/27/20 12:350.39 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 11:19 106-46-708/27/20 12:350.39 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 11:19 91-94-108/27/20 12:350.78 1 2,4-Dichlorophenol ND mg/kg 08/28/20 11:19 120-83-208/27/20 12:350.39 1 Diethylphthalate ND mg/kg 08/28/20 11:19 84-66-208/27/20 12:350.39 1 2,4-Dimethylphenol ND mg/kg 08/28/20 11:19 105-67-908/27/20 12:350.39 1 Dimethylphthalate ND mg/kg 08/28/20 11:19 131-11-308/27/20 12:350.39 1 Di-n-butylphthalate ND mg/kg 08/28/20 11:19 84-74-208/27/20 12:350.39 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 11:19 534-52-108/27/20 12:350.78 1 2,4-Dinitrophenol ND mg/kg 08/28/20 11:19 51-28-5 v108/27/20 12:352.0 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 11:19 121-14-208/27/20 12:350.39 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 11:19 606-20-2 v208/27/20 12:350.39 1 Di-n-octylphthalate ND mg/kg 08/28/20 11:19 117-84-008/27/20 12:350.39 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 11:19 117-81-708/27/20 12:350.39 1 Fluoranthene ND mg/kg 08/28/20 11:19 206-44-008/27/20 12:350.39 1 Fluorene ND mg/kg 08/28/20 11:19 86-73-708/27/20 12:350.39 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 11:19 87-68-308/27/20 12:350.39 1 Hexachlorobenzene ND mg/kg 08/28/20 11:19 118-74-108/27/20 12:350.39 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 11:19 77-47-408/27/20 12:350.39 1 Hexachloroethane ND mg/kg 08/28/20 11:19 67-72-108/27/20 12:350.39 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 11:19 193-39-508/27/20 12:350.39 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-1 (8270)Lab ID:92492009001 Collected:08/19/20 09:35 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 08/28/20 11:19 78-59-108/27/20 12:350.39 1 1-Methylnaphthalene ND mg/kg 08/28/20 11:19 90-12-008/27/20 12:350.39 1 2-Methylnaphthalene ND mg/kg 08/28/20 11:19 91-57-608/27/20 12:350.39 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 11:19 95-48-708/27/20 12:350.39 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 11:19 15831-10-408/27/20 12:350.39 1 Naphthalene ND mg/kg 08/28/20 11:19 91-20-308/27/20 12:350.39 1 2-Nitroaniline ND mg/kg 08/28/20 11:19 88-74-408/27/20 12:352.0 1 3-Nitroaniline ND mg/kg 08/28/20 11:19 99-09-208/27/20 12:352.0 1 4-Nitroaniline ND mg/kg 08/28/20 11:19 100-01-608/27/20 12:350.78 1 Nitrobenzene ND mg/kg 08/28/20 11:19 98-95-308/27/20 12:350.39 1 2-Nitrophenol ND mg/kg 08/28/20 11:19 88-75-508/27/20 12:350.39 1 4-Nitrophenol ND mg/kg 08/28/20 11:19 100-02-7 v208/27/20 12:352.0 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 11:19 62-75-908/27/20 12:350.39 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 11:19 621-64-7 v208/27/20 12:350.39 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 11:19 86-30-608/27/20 12:350.39 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 11:19 108-60-108/27/20 12:350.39 1 Pentachlorophenol ND mg/kg 08/28/20 11:19 87-86-508/27/20 12:350.78 1 Phenanthrene ND mg/kg 08/28/20 11:19 85-01-808/27/20 12:350.39 1 Phenol ND mg/kg 08/28/20 11:19 108-95-208/27/20 12:350.39 1 Pyrene ND mg/kg 08/28/20 11:19 129-00-008/27/20 12:350.39 1 Pyridine ND mg/kg 08/28/20 11:19 110-86-108/27/20 12:350.39 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 11:19 120-82-108/27/20 12:350.39 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 11:19 95-95-408/27/20 12:350.39 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 11:19 88-06-208/27/20 12:350.39 1 Surrogates Nitrobenzene-d5 (S)43 %08/28/20 11:19 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)54 %08/28/20 11:19 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)67 %08/28/20 11:19 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)54 %08/28/20 11:19 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)57 %08/28/20 11:19 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)73 %08/28/20 11:19 118-79-608/27/20 12:3527-110 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 17.2 %08/25/20 10:140.10 1 Sample:GP-1 (8260)Lab ID:92492009002 Collected:08/19/20 09:35 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 15:21 67-64-108/25/20 10:360.12 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-1 (8260)Lab ID:92492009002 Collected:08/19/20 09:35 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Benzene ND mg/kg 08/25/20 15:21 71-43-208/25/20 10:360.0060 1 Bromobenzene ND mg/kg 08/25/20 15:21 108-86-108/25/20 10:360.0060 1 Bromochloromethane ND mg/kg 08/25/20 15:21 74-97-5 IK08/25/20 10:360.0060 1 Bromodichloromethane ND mg/kg 08/25/20 15:21 75-27-408/25/20 10:360.0060 1 Bromoform ND mg/kg 08/25/20 15:21 75-25-208/25/20 10:360.0060 1 Bromomethane ND mg/kg 08/25/20 15:21 74-83-9 v108/25/20 10:360.012 1 2-Butanone (MEK)ND mg/kg 08/25/20 15:21 78-93-308/25/20 10:360.12 1 n-Butylbenzene ND mg/kg 08/25/20 15:21 104-51-808/25/20 10:360.0060 1 sec-Butylbenzene ND mg/kg 08/25/20 15:21 135-98-808/25/20 10:360.0060 1 tert-Butylbenzene ND mg/kg 08/25/20 15:21 98-06-608/25/20 10:360.0060 1 Carbon tetrachloride ND mg/kg 08/25/20 15:21 56-23-508/25/20 10:360.0060 1 Chlorobenzene ND mg/kg 08/25/20 15:21 108-90-708/25/20 10:360.0060 1 Chloroethane ND mg/kg 08/25/20 15:21 75-00-308/25/20 10:360.012 1 Chloroform ND mg/kg 08/25/20 15:21 67-66-308/25/20 10:360.0060 1 Chloromethane ND mg/kg 08/25/20 15:21 74-87-3 v208/25/20 10:360.012 1 2-Chlorotoluene ND mg/kg 08/25/20 15:21 95-49-808/25/20 10:360.0060 1 4-Chlorotoluene ND mg/kg 08/25/20 15:21 106-43-408/25/20 10:360.0060 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 15:21 96-12-808/25/20 10:360.0060 1 Dibromochloromethane ND mg/kg 08/25/20 15:21 124-48-108/25/20 10:360.0060 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 15:21 106-93-408/25/20 10:360.0060 1 Dibromomethane ND mg/kg 08/25/20 15:21 74-95-308/25/20 10:360.0060 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 15:21 95-50-108/25/20 10:360.0060 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 15:21 541-73-108/25/20 10:360.0060 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 15:21 106-46-708/25/20 10:360.0060 1 Dichlorodifluoromethane ND mg/kg 08/25/20 15:21 75-71-808/25/20 10:360.012 1 1,1-Dichloroethane ND mg/kg 08/25/20 15:21 75-34-308/25/20 10:360.0060 1 1,2-Dichloroethane ND mg/kg 08/25/20 15:21 107-06-208/25/20 10:360.0060 1 1,1-Dichloroethene ND mg/kg 08/25/20 15:21 75-35-408/25/20 10:360.0060 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 15:21 156-59-208/25/20 10:360.0060 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 15:21 156-60-508/25/20 10:360.0060 1 1,2-Dichloropropane ND mg/kg 08/25/20 15:21 78-87-508/25/20 10:360.0060 1 1,3-Dichloropropane ND mg/kg 08/25/20 15:21 142-28-908/25/20 10:360.0060 1 2,2-Dichloropropane ND mg/kg 08/25/20 15:21 594-20-708/25/20 10:360.0060 1 1,1-Dichloropropene ND mg/kg 08/25/20 15:21 563-58-608/25/20 10:360.0060 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 15:21 10061-01-508/25/20 10:360.0060 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 15:21 10061-02-608/25/20 10:360.0060 1 Diisopropyl ether ND mg/kg 08/25/20 15:21 108-20-308/25/20 10:360.0060 1 Ethylbenzene ND mg/kg 08/25/20 15:21 100-41-408/25/20 10:360.0060 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 15:21 87-68-308/25/20 10:360.0060 1 2-Hexanone ND mg/kg 08/25/20 15:21 591-78-608/25/20 10:360.060 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 15:21 98-82-808/25/20 10:360.0060 1 p-Isopropyltoluene ND mg/kg 08/25/20 15:21 99-87-608/25/20 10:360.0060 1 Methylene Chloride ND mg/kg 08/25/20 15:21 75-09-208/25/20 10:360.024 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 15:21 108-10-108/25/20 10:360.060 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 15:21 1634-04-408/25/20 10:360.0060 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-1 (8260)Lab ID:92492009002 Collected:08/19/20 09:35 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Naphthalene ND mg/kg 08/25/20 15:21 91-20-308/25/20 10:360.0060 1 n-Propylbenzene ND mg/kg 08/25/20 15:21 103-65-108/25/20 10:360.0060 1 Styrene ND mg/kg 08/25/20 15:21 100-42-508/25/20 10:360.0060 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 15:21 630-20-608/25/20 10:360.0060 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 15:21 79-34-508/25/20 10:360.0060 1 Tetrachloroethene ND mg/kg 08/25/20 15:21 127-18-408/25/20 10:360.0060 1 Toluene ND mg/kg 08/25/20 15:21 108-88-308/25/20 10:360.0060 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 15:21 87-61-608/25/20 10:360.0060 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 15:21 120-82-108/25/20 10:360.0060 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 15:21 71-55-608/25/20 10:360.0060 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 15:21 79-00-508/25/20 10:360.0060 1 Trichloroethene ND mg/kg 08/25/20 15:21 79-01-608/25/20 10:360.0060 1 Trichlorofluoromethane ND mg/kg 08/25/20 15:21 75-69-408/25/20 10:360.0060 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 15:21 96-18-408/25/20 10:360.0060 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 15:21 95-63-608/25/20 10:360.0060 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 15:21 108-67-808/25/20 10:360.0060 1 Vinyl acetate ND mg/kg 08/25/20 15:21 108-05-408/25/20 10:360.060 1 Vinyl chloride ND mg/kg 08/25/20 15:21 75-01-408/25/20 10:360.012 1 Xylene (Total)ND mg/kg 08/25/20 15:21 1330-20-708/25/20 10:360.012 1 m&p-Xylene ND mg/kg 08/25/20 15:21 179601-23-108/25/20 10:360.012 1 o-Xylene ND mg/kg 08/25/20 15:21 95-47-608/25/20 10:360.0060 1 Surrogates Toluene-d8 (S)100 %08/25/20 15:21 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)102 %08/25/20 15:21 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)96 %08/25/20 15:21 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 20.0 %08/25/20 10:140.10 1 Sample:GP-2 Lab ID:92492009003 Collected:08/19/20 09:42 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 11:49 83-32-908/27/20 12:350.41 1 Acenaphthylene ND mg/kg 08/28/20 11:49 208-96-808/27/20 12:350.41 1 Aniline ND mg/kg 08/28/20 11:49 62-53-308/27/20 12:350.41 1 Anthracene ND mg/kg 08/28/20 11:49 120-12-708/27/20 12:350.41 1 Benzo(a)anthracene ND mg/kg 08/28/20 11:49 56-55-308/27/20 12:350.41 1 Benzo(a)pyrene ND mg/kg 08/28/20 11:49 50-32-808/27/20 12:350.41 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 11:49 205-99-208/27/20 12:350.41 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-2 Lab ID:92492009003 Collected:08/19/20 09:42 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Benzo(g,h,i)perylene ND mg/kg 08/28/20 11:49 191-24-208/27/20 12:350.41 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 11:49 207-08-908/27/20 12:350.41 1 Benzoic Acid ND mg/kg 08/28/20 11:49 65-85-008/27/20 12:352.0 1 Benzyl alcohol ND mg/kg 08/28/20 11:49 100-51-608/27/20 12:350.82 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 11:49 101-55-308/27/20 12:350.41 1 Butylbenzylphthalate ND mg/kg 08/28/20 11:49 85-68-708/27/20 12:350.41 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 11:49 59-50-708/27/20 12:350.82 1 4-Chloroaniline ND mg/kg 08/28/20 11:49 106-47-808/27/20 12:350.82 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 11:49 111-91-108/27/20 12:350.41 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 11:49 111-44-408/27/20 12:350.41 1 2-Chloronaphthalene ND mg/kg 08/28/20 11:49 91-58-708/27/20 12:350.41 1 2-Chlorophenol ND mg/kg 08/28/20 11:49 95-57-808/27/20 12:350.41 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 11:49 7005-72-308/27/20 12:350.41 1 Chrysene ND mg/kg 08/28/20 11:49 218-01-908/27/20 12:350.41 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 11:49 53-70-308/27/20 12:350.41 1 Dibenzofuran ND mg/kg 08/28/20 11:49 132-64-908/27/20 12:350.41 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 11:49 95-50-108/27/20 12:350.41 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 11:49 541-73-108/27/20 12:350.41 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 11:49 106-46-708/27/20 12:350.41 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 11:49 91-94-108/27/20 12:350.82 1 2,4-Dichlorophenol ND mg/kg 08/28/20 11:49 120-83-208/27/20 12:350.41 1 Diethylphthalate ND mg/kg 08/28/20 11:49 84-66-208/27/20 12:350.41 1 2,4-Dimethylphenol ND mg/kg 08/28/20 11:49 105-67-908/27/20 12:350.41 1 Dimethylphthalate ND mg/kg 08/28/20 11:49 131-11-308/27/20 12:350.41 1 Di-n-butylphthalate ND mg/kg 08/28/20 11:49 84-74-208/27/20 12:350.41 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 11:49 534-52-108/27/20 12:350.82 1 2,4-Dinitrophenol ND mg/kg 08/28/20 11:49 51-28-5 v108/27/20 12:352.0 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 11:49 121-14-208/27/20 12:350.41 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 11:49 606-20-2 v208/27/20 12:350.41 1 Di-n-octylphthalate ND mg/kg 08/28/20 11:49 117-84-008/27/20 12:350.41 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 11:49 117-81-708/27/20 12:350.41 1 Fluoranthene ND mg/kg 08/28/20 11:49 206-44-008/27/20 12:350.41 1 Fluorene ND mg/kg 08/28/20 11:49 86-73-708/27/20 12:350.41 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 11:49 87-68-308/27/20 12:350.41 1 Hexachlorobenzene ND mg/kg 08/28/20 11:49 118-74-108/27/20 12:350.41 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 11:49 77-47-408/27/20 12:350.41 1 Hexachloroethane ND mg/kg 08/28/20 11:49 67-72-108/27/20 12:350.41 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 11:49 193-39-508/27/20 12:350.41 1 Isophorone ND mg/kg 08/28/20 11:49 78-59-108/27/20 12:350.41 1 1-Methylnaphthalene ND mg/kg 08/28/20 11:49 90-12-008/27/20 12:350.41 1 2-Methylnaphthalene ND mg/kg 08/28/20 11:49 91-57-608/27/20 12:350.41 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 11:49 95-48-708/27/20 12:350.41 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 11:49 15831-10-408/27/20 12:350.41 1 Naphthalene ND mg/kg 08/28/20 11:49 91-20-308/27/20 12:350.41 1 2-Nitroaniline ND mg/kg 08/28/20 11:49 88-74-408/27/20 12:352.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-2 Lab ID:92492009003 Collected:08/19/20 09:42 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 3-Nitroaniline ND mg/kg 08/28/20 11:49 99-09-208/27/20 12:352.0 1 4-Nitroaniline ND mg/kg 08/28/20 11:49 100-01-608/27/20 12:350.82 1 Nitrobenzene ND mg/kg 08/28/20 11:49 98-95-308/27/20 12:350.41 1 2-Nitrophenol ND mg/kg 08/28/20 11:49 88-75-508/27/20 12:350.41 1 4-Nitrophenol ND mg/kg 08/28/20 11:49 100-02-7 v208/27/20 12:352.0 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 11:49 62-75-908/27/20 12:350.41 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 11:49 621-64-7 v208/27/20 12:350.41 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 11:49 86-30-608/27/20 12:350.41 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 11:49 108-60-108/27/20 12:350.41 1 Pentachlorophenol ND mg/kg 08/28/20 11:49 87-86-508/27/20 12:350.82 1 Phenanthrene ND mg/kg 08/28/20 11:49 85-01-808/27/20 12:350.41 1 Phenol ND mg/kg 08/28/20 11:49 108-95-208/27/20 12:350.41 1 Pyrene ND mg/kg 08/28/20 11:49 129-00-008/27/20 12:350.41 1 Pyridine ND mg/kg 08/28/20 11:49 110-86-108/27/20 12:350.41 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 11:49 120-82-108/27/20 12:350.41 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 11:49 95-95-408/27/20 12:350.41 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 11:49 88-06-208/27/20 12:350.41 1 Surrogates Nitrobenzene-d5 (S)42 %08/28/20 11:49 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)53 %08/28/20 11:49 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)72 %08/28/20 11:49 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)50 %08/28/20 11:49 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)54 %08/28/20 11:49 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)70 %08/28/20 11:49 118-79-608/27/20 12:3527-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 15:39 67-64-108/25/20 10:360.11 1 Benzene ND mg/kg 08/25/20 15:39 71-43-208/25/20 10:360.0057 1 Bromobenzene ND mg/kg 08/25/20 15:39 108-86-108/25/20 10:360.0057 1 Bromochloromethane ND mg/kg 08/25/20 15:39 74-97-5 IK08/25/20 10:360.0057 1 Bromodichloromethane ND mg/kg 08/25/20 15:39 75-27-408/25/20 10:360.0057 1 Bromoform ND mg/kg 08/25/20 15:39 75-25-208/25/20 10:360.0057 1 Bromomethane ND mg/kg 08/25/20 15:39 74-83-9 v108/25/20 10:360.011 1 2-Butanone (MEK)ND mg/kg 08/25/20 15:39 78-93-308/25/20 10:360.11 1 n-Butylbenzene ND mg/kg 08/25/20 15:39 104-51-808/25/20 10:360.0057 1 sec-Butylbenzene ND mg/kg 08/25/20 15:39 135-98-808/25/20 10:360.0057 1 tert-Butylbenzene ND mg/kg 08/25/20 15:39 98-06-608/25/20 10:360.0057 1 Carbon tetrachloride ND mg/kg 08/25/20 15:39 56-23-508/25/20 10:360.0057 1 Chlorobenzene ND mg/kg 08/25/20 15:39 108-90-708/25/20 10:360.0057 1 Chloroethane ND mg/kg 08/25/20 15:39 75-00-308/25/20 10:360.011 1 Chloroform ND mg/kg 08/25/20 15:39 67-66-308/25/20 10:360.0057 1 Chloromethane ND mg/kg 08/25/20 15:39 74-87-3 v208/25/20 10:360.011 1 2-Chlorotoluene ND mg/kg 08/25/20 15:39 95-49-808/25/20 10:360.0057 1 4-Chlorotoluene ND mg/kg 08/25/20 15:39 106-43-408/25/20 10:360.0057 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-2 Lab ID:92492009003 Collected:08/19/20 09:42 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 15:39 96-12-808/25/20 10:360.0057 1 Dibromochloromethane ND mg/kg 08/25/20 15:39 124-48-108/25/20 10:360.0057 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 15:39 106-93-408/25/20 10:360.0057 1 Dibromomethane ND mg/kg 08/25/20 15:39 74-95-308/25/20 10:360.0057 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 15:39 95-50-108/25/20 10:360.0057 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 15:39 541-73-108/25/20 10:360.0057 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 15:39 106-46-708/25/20 10:360.0057 1 Dichlorodifluoromethane ND mg/kg 08/25/20 15:39 75-71-808/25/20 10:360.011 1 1,1-Dichloroethane ND mg/kg 08/25/20 15:39 75-34-308/25/20 10:360.0057 1 1,2-Dichloroethane ND mg/kg 08/25/20 15:39 107-06-208/25/20 10:360.0057 1 1,1-Dichloroethene ND mg/kg 08/25/20 15:39 75-35-408/25/20 10:360.0057 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 15:39 156-59-208/25/20 10:360.0057 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 15:39 156-60-508/25/20 10:360.0057 1 1,2-Dichloropropane ND mg/kg 08/25/20 15:39 78-87-508/25/20 10:360.0057 1 1,3-Dichloropropane ND mg/kg 08/25/20 15:39 142-28-908/25/20 10:360.0057 1 2,2-Dichloropropane ND mg/kg 08/25/20 15:39 594-20-708/25/20 10:360.0057 1 1,1-Dichloropropene ND mg/kg 08/25/20 15:39 563-58-608/25/20 10:360.0057 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 15:39 10061-01-508/25/20 10:360.0057 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 15:39 10061-02-608/25/20 10:360.0057 1 Diisopropyl ether ND mg/kg 08/25/20 15:39 108-20-308/25/20 10:360.0057 1 Ethylbenzene ND mg/kg 08/25/20 15:39 100-41-408/25/20 10:360.0057 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 15:39 87-68-308/25/20 10:360.0057 1 2-Hexanone ND mg/kg 08/25/20 15:39 591-78-608/25/20 10:360.057 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 15:39 98-82-808/25/20 10:360.0057 1 p-Isopropyltoluene ND mg/kg 08/25/20 15:39 99-87-608/25/20 10:360.0057 1 Methylene Chloride ND mg/kg 08/25/20 15:39 75-09-208/25/20 10:360.023 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 15:39 108-10-108/25/20 10:360.057 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 15:39 1634-04-408/25/20 10:360.0057 1 Naphthalene ND mg/kg 08/25/20 15:39 91-20-308/25/20 10:360.0057 1 n-Propylbenzene ND mg/kg 08/25/20 15:39 103-65-108/25/20 10:360.0057 1 Styrene ND mg/kg 08/25/20 15:39 100-42-508/25/20 10:360.0057 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 15:39 630-20-608/25/20 10:360.0057 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 15:39 79-34-508/25/20 10:360.0057 1 Tetrachloroethene ND mg/kg 08/25/20 15:39 127-18-408/25/20 10:360.0057 1 Toluene ND mg/kg 08/25/20 15:39 108-88-308/25/20 10:360.0057 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 15:39 87-61-608/25/20 10:360.0057 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 15:39 120-82-108/25/20 10:360.0057 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 15:39 71-55-608/25/20 10:360.0057 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 15:39 79-00-508/25/20 10:360.0057 1 Trichloroethene ND mg/kg 08/25/20 15:39 79-01-608/25/20 10:360.0057 1 Trichlorofluoromethane ND mg/kg 08/25/20 15:39 75-69-408/25/20 10:360.0057 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 15:39 96-18-408/25/20 10:360.0057 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 15:39 95-63-608/25/20 10:360.0057 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 15:39 108-67-808/25/20 10:360.0057 1 Vinyl acetate ND mg/kg 08/25/20 15:39 108-05-408/25/20 10:360.057 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-2 Lab ID:92492009003 Collected:08/19/20 09:42 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Vinyl chloride ND mg/kg 08/25/20 15:39 75-01-408/25/20 10:360.011 1 Xylene (Total)ND mg/kg 08/25/20 15:39 1330-20-708/25/20 10:360.011 1 m&p-Xylene ND mg/kg 08/25/20 15:39 179601-23-108/25/20 10:360.011 1 o-Xylene ND mg/kg 08/25/20 15:39 95-47-608/25/20 10:360.0057 1 Surrogates Toluene-d8 (S)99 %08/25/20 15:39 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)101 %08/25/20 15:39 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)94 %08/25/20 15:39 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 17.7 %08/25/20 10:140.10 1 Sample:GP-3 Lab ID:92492009004 Collected:08/19/20 09:50 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 12:19 83-32-908/27/20 12:350.41 1 Acenaphthylene ND mg/kg 08/28/20 12:19 208-96-808/27/20 12:350.41 1 Aniline ND mg/kg 08/28/20 12:19 62-53-308/27/20 12:350.41 1 Anthracene ND mg/kg 08/28/20 12:19 120-12-708/27/20 12:350.41 1 Benzo(a)anthracene ND mg/kg 08/28/20 12:19 56-55-308/27/20 12:350.41 1 Benzo(a)pyrene ND mg/kg 08/28/20 12:19 50-32-808/27/20 12:350.41 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 12:19 205-99-208/27/20 12:350.41 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 12:19 191-24-208/27/20 12:350.41 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 12:19 207-08-908/27/20 12:350.41 1 Benzoic Acid ND mg/kg 08/28/20 12:19 65-85-008/27/20 12:352.1 1 Benzyl alcohol ND mg/kg 08/28/20 12:19 100-51-608/27/20 12:350.82 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 12:19 101-55-308/27/20 12:350.41 1 Butylbenzylphthalate ND mg/kg 08/28/20 12:19 85-68-708/27/20 12:350.41 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 12:19 59-50-708/27/20 12:350.82 1 4-Chloroaniline ND mg/kg 08/28/20 12:19 106-47-808/27/20 12:350.82 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 12:19 111-91-108/27/20 12:350.41 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 12:19 111-44-408/27/20 12:350.41 1 2-Chloronaphthalene ND mg/kg 08/28/20 12:19 91-58-708/27/20 12:350.41 1 2-Chlorophenol ND mg/kg 08/28/20 12:19 95-57-808/27/20 12:350.41 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 12:19 7005-72-308/27/20 12:350.41 1 Chrysene ND mg/kg 08/28/20 12:19 218-01-908/27/20 12:350.41 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 12:19 53-70-308/27/20 12:350.41 1 Dibenzofuran ND mg/kg 08/28/20 12:19 132-64-908/27/20 12:350.41 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 12:19 95-50-108/27/20 12:350.41 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-3 Lab ID:92492009004 Collected:08/19/20 09:50 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 1,3-Dichlorobenzene ND mg/kg 08/28/20 12:19 541-73-108/27/20 12:350.41 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 12:19 106-46-708/27/20 12:350.41 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 12:19 91-94-108/27/20 12:350.82 1 2,4-Dichlorophenol ND mg/kg 08/28/20 12:19 120-83-208/27/20 12:350.41 1 Diethylphthalate ND mg/kg 08/28/20 12:19 84-66-208/27/20 12:350.41 1 2,4-Dimethylphenol ND mg/kg 08/28/20 12:19 105-67-908/27/20 12:350.41 1 Dimethylphthalate ND mg/kg 08/28/20 12:19 131-11-308/27/20 12:350.41 1 Di-n-butylphthalate ND mg/kg 08/28/20 12:19 84-74-208/27/20 12:350.41 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 12:19 534-52-108/27/20 12:350.82 1 2,4-Dinitrophenol ND mg/kg 08/28/20 12:19 51-28-5 v108/27/20 12:352.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 12:19 121-14-208/27/20 12:350.41 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 12:19 606-20-2 v208/27/20 12:350.41 1 Di-n-octylphthalate ND mg/kg 08/28/20 12:19 117-84-008/27/20 12:350.41 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 12:19 117-81-708/27/20 12:350.41 1 Fluoranthene ND mg/kg 08/28/20 12:19 206-44-008/27/20 12:350.41 1 Fluorene ND mg/kg 08/28/20 12:19 86-73-708/27/20 12:350.41 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 12:19 87-68-308/27/20 12:350.41 1 Hexachlorobenzene ND mg/kg 08/28/20 12:19 118-74-108/27/20 12:350.41 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 12:19 77-47-408/27/20 12:350.41 1 Hexachloroethane ND mg/kg 08/28/20 12:19 67-72-108/27/20 12:350.41 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 12:19 193-39-508/27/20 12:350.41 1 Isophorone ND mg/kg 08/28/20 12:19 78-59-108/27/20 12:350.41 1 1-Methylnaphthalene ND mg/kg 08/28/20 12:19 90-12-008/27/20 12:350.41 1 2-Methylnaphthalene ND mg/kg 08/28/20 12:19 91-57-608/27/20 12:350.41 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 12:19 95-48-708/27/20 12:350.41 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 12:19 15831-10-408/27/20 12:350.41 1 Naphthalene ND mg/kg 08/28/20 12:19 91-20-308/27/20 12:350.41 1 2-Nitroaniline ND mg/kg 08/28/20 12:19 88-74-408/27/20 12:352.1 1 3-Nitroaniline ND mg/kg 08/28/20 12:19 99-09-208/27/20 12:352.1 1 4-Nitroaniline ND mg/kg 08/28/20 12:19 100-01-608/27/20 12:350.82 1 Nitrobenzene ND mg/kg 08/28/20 12:19 98-95-308/27/20 12:350.41 1 2-Nitrophenol ND mg/kg 08/28/20 12:19 88-75-508/27/20 12:350.41 1 4-Nitrophenol ND mg/kg 08/28/20 12:19 100-02-7 v208/27/20 12:352.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 12:19 62-75-908/27/20 12:350.41 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 12:19 621-64-7 v208/27/20 12:350.41 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 12:19 86-30-608/27/20 12:350.41 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 12:19 108-60-108/27/20 12:350.41 1 Pentachlorophenol ND mg/kg 08/28/20 12:19 87-86-508/27/20 12:350.82 1 Phenanthrene ND mg/kg 08/28/20 12:19 85-01-808/27/20 12:350.41 1 Phenol ND mg/kg 08/28/20 12:19 108-95-208/27/20 12:350.41 1 Pyrene ND mg/kg 08/28/20 12:19 129-00-008/27/20 12:350.41 1 Pyridine ND mg/kg 08/28/20 12:19 110-86-108/27/20 12:350.41 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 12:19 120-82-108/27/20 12:350.41 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 12:19 95-95-408/27/20 12:350.41 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 12:19 88-06-208/27/20 12:350.41 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-3 Lab ID:92492009004 Collected:08/19/20 09:50 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Surrogates Nitrobenzene-d5 (S)45 %08/28/20 12:19 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)58 %08/28/20 12:19 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)73 %08/28/20 12:19 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)58 %08/28/20 12:19 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)60 %08/28/20 12:19 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)76 %08/28/20 12:19 118-79-608/27/20 12:3527-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 15:58 67-64-108/25/20 10:360.10 1 Benzene ND mg/kg 08/25/20 15:58 71-43-208/25/20 10:360.0051 1 Bromobenzene ND mg/kg 08/25/20 15:58 108-86-108/25/20 10:360.0051 1 Bromochloromethane ND mg/kg 08/25/20 15:58 74-97-5 IK08/25/20 10:360.0051 1 Bromodichloromethane ND mg/kg 08/25/20 15:58 75-27-408/25/20 10:360.0051 1 Bromoform ND mg/kg 08/25/20 15:58 75-25-208/25/20 10:360.0051 1 Bromomethane ND mg/kg 08/25/20 15:58 74-83-9 v108/25/20 10:360.010 1 2-Butanone (MEK)ND mg/kg 08/25/20 15:58 78-93-308/25/20 10:360.10 1 n-Butylbenzene ND mg/kg 08/25/20 15:58 104-51-808/25/20 10:360.0051 1 sec-Butylbenzene ND mg/kg 08/25/20 15:58 135-98-808/25/20 10:360.0051 1 tert-Butylbenzene ND mg/kg 08/25/20 15:58 98-06-608/25/20 10:360.0051 1 Carbon tetrachloride ND mg/kg 08/25/20 15:58 56-23-508/25/20 10:360.0051 1 Chlorobenzene ND mg/kg 08/25/20 15:58 108-90-708/25/20 10:360.0051 1 Chloroethane ND mg/kg 08/25/20 15:58 75-00-308/25/20 10:360.010 1 Chloroform ND mg/kg 08/25/20 15:58 67-66-308/25/20 10:360.0051 1 Chloromethane ND mg/kg 08/25/20 15:58 74-87-3 v208/25/20 10:360.010 1 2-Chlorotoluene ND mg/kg 08/25/20 15:58 95-49-808/25/20 10:360.0051 1 4-Chlorotoluene ND mg/kg 08/25/20 15:58 106-43-408/25/20 10:360.0051 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 15:58 96-12-808/25/20 10:360.0051 1 Dibromochloromethane ND mg/kg 08/25/20 15:58 124-48-108/25/20 10:360.0051 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 15:58 106-93-408/25/20 10:360.0051 1 Dibromomethane ND mg/kg 08/25/20 15:58 74-95-308/25/20 10:360.0051 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 15:58 95-50-108/25/20 10:360.0051 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 15:58 541-73-108/25/20 10:360.0051 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 15:58 106-46-708/25/20 10:360.0051 1 Dichlorodifluoromethane ND mg/kg 08/25/20 15:58 75-71-808/25/20 10:360.010 1 1,1-Dichloroethane ND mg/kg 08/25/20 15:58 75-34-308/25/20 10:360.0051 1 1,2-Dichloroethane ND mg/kg 08/25/20 15:58 107-06-208/25/20 10:360.0051 1 1,1-Dichloroethene ND mg/kg 08/25/20 15:58 75-35-408/25/20 10:360.0051 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 15:58 156-59-208/25/20 10:360.0051 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 15:58 156-60-508/25/20 10:360.0051 1 1,2-Dichloropropane ND mg/kg 08/25/20 15:58 78-87-508/25/20 10:360.0051 1 1,3-Dichloropropane ND mg/kg 08/25/20 15:58 142-28-908/25/20 10:360.0051 1 2,2-Dichloropropane ND mg/kg 08/25/20 15:58 594-20-708/25/20 10:360.0051 1 1,1-Dichloropropene ND mg/kg 08/25/20 15:58 563-58-608/25/20 10:360.0051 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-3 Lab ID:92492009004 Collected:08/19/20 09:50 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles cis-1,3-Dichloropropene ND mg/kg 08/25/20 15:58 10061-01-508/25/20 10:360.0051 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 15:58 10061-02-608/25/20 10:360.0051 1 Diisopropyl ether ND mg/kg 08/25/20 15:58 108-20-308/25/20 10:360.0051 1 Ethylbenzene ND mg/kg 08/25/20 15:58 100-41-408/25/20 10:360.0051 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 15:58 87-68-308/25/20 10:360.0051 1 2-Hexanone ND mg/kg 08/25/20 15:58 591-78-608/25/20 10:360.051 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 15:58 98-82-808/25/20 10:360.0051 1 p-Isopropyltoluene ND mg/kg 08/25/20 15:58 99-87-608/25/20 10:360.0051 1 Methylene Chloride ND mg/kg 08/25/20 15:58 75-09-208/25/20 10:360.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 15:58 108-10-108/25/20 10:360.051 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 15:58 1634-04-408/25/20 10:360.0051 1 Naphthalene ND mg/kg 08/25/20 15:58 91-20-308/25/20 10:360.0051 1 n-Propylbenzene ND mg/kg 08/25/20 15:58 103-65-108/25/20 10:360.0051 1 Styrene ND mg/kg 08/25/20 15:58 100-42-508/25/20 10:360.0051 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 15:58 630-20-608/25/20 10:360.0051 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 15:58 79-34-508/25/20 10:360.0051 1 Tetrachloroethene ND mg/kg 08/25/20 15:58 127-18-408/25/20 10:360.0051 1 Toluene ND mg/kg 08/25/20 15:58 108-88-308/25/20 10:360.0051 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 15:58 87-61-608/25/20 10:360.0051 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 15:58 120-82-108/25/20 10:360.0051 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 15:58 71-55-608/25/20 10:360.0051 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 15:58 79-00-508/25/20 10:360.0051 1 Trichloroethene ND mg/kg 08/25/20 15:58 79-01-608/25/20 10:360.0051 1 Trichlorofluoromethane ND mg/kg 08/25/20 15:58 75-69-408/25/20 10:360.0051 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 15:58 96-18-408/25/20 10:360.0051 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 15:58 95-63-608/25/20 10:360.0051 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 15:58 108-67-808/25/20 10:360.0051 1 Vinyl acetate ND mg/kg 08/25/20 15:58 108-05-408/25/20 10:360.051 1 Vinyl chloride ND mg/kg 08/25/20 15:58 75-01-408/25/20 10:360.010 1 Xylene (Total)ND mg/kg 08/25/20 15:58 1330-20-708/25/20 10:360.010 1 m&p-Xylene ND mg/kg 08/25/20 15:58 179601-23-108/25/20 10:360.010 1 o-Xylene ND mg/kg 08/25/20 15:58 95-47-608/25/20 10:360.0051 1 Surrogates Toluene-d8 (S)99 %08/25/20 15:58 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)102 %08/25/20 15:58 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)97 %08/25/20 15:58 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 18.3 %08/25/20 10:150.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-4 Lab ID:92492009005 Collected:08/19/20 10:15 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 12:49 83-32-908/27/20 12:350.39 1 Acenaphthylene ND mg/kg 08/28/20 12:49 208-96-808/27/20 12:350.39 1 Aniline ND mg/kg 08/28/20 12:49 62-53-308/27/20 12:350.39 1 Anthracene ND mg/kg 08/28/20 12:49 120-12-708/27/20 12:350.39 1 Benzo(a)anthracene ND mg/kg 08/28/20 12:49 56-55-308/27/20 12:350.39 1 Benzo(a)pyrene ND mg/kg 08/28/20 12:49 50-32-808/27/20 12:350.39 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 12:49 205-99-208/27/20 12:350.39 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 12:49 191-24-208/27/20 12:350.39 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 12:49 207-08-908/27/20 12:350.39 1 Benzoic Acid ND mg/kg 08/28/20 12:49 65-85-008/27/20 12:351.9 1 Benzyl alcohol ND mg/kg 08/28/20 12:49 100-51-608/27/20 12:350.78 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 12:49 101-55-308/27/20 12:350.39 1 Butylbenzylphthalate ND mg/kg 08/28/20 12:49 85-68-708/27/20 12:350.39 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 12:49 59-50-708/27/20 12:350.78 1 4-Chloroaniline ND mg/kg 08/28/20 12:49 106-47-808/27/20 12:350.78 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 12:49 111-91-108/27/20 12:350.39 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 12:49 111-44-408/27/20 12:350.39 1 2-Chloronaphthalene ND mg/kg 08/28/20 12:49 91-58-708/27/20 12:350.39 1 2-Chlorophenol ND mg/kg 08/28/20 12:49 95-57-808/27/20 12:350.39 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 12:49 7005-72-308/27/20 12:350.39 1 Chrysene ND mg/kg 08/28/20 12:49 218-01-908/27/20 12:350.39 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 12:49 53-70-308/27/20 12:350.39 1 Dibenzofuran ND mg/kg 08/28/20 12:49 132-64-908/27/20 12:350.39 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 12:49 95-50-108/27/20 12:350.39 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 12:49 541-73-108/27/20 12:350.39 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 12:49 106-46-708/27/20 12:350.39 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 12:49 91-94-108/27/20 12:350.78 1 2,4-Dichlorophenol ND mg/kg 08/28/20 12:49 120-83-208/27/20 12:350.39 1 Diethylphthalate ND mg/kg 08/28/20 12:49 84-66-208/27/20 12:350.39 1 2,4-Dimethylphenol ND mg/kg 08/28/20 12:49 105-67-908/27/20 12:350.39 1 Dimethylphthalate ND mg/kg 08/28/20 12:49 131-11-308/27/20 12:350.39 1 Di-n-butylphthalate ND mg/kg 08/28/20 12:49 84-74-208/27/20 12:350.39 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 12:49 534-52-108/27/20 12:350.78 1 2,4-Dinitrophenol ND mg/kg 08/28/20 12:49 51-28-5 v108/27/20 12:351.9 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 12:49 121-14-208/27/20 12:350.39 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 12:49 606-20-2 v208/27/20 12:350.39 1 Di-n-octylphthalate ND mg/kg 08/28/20 12:49 117-84-008/27/20 12:350.39 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 12:49 117-81-708/27/20 12:350.39 1 Fluoranthene ND mg/kg 08/28/20 12:49 206-44-008/27/20 12:350.39 1 Fluorene ND mg/kg 08/28/20 12:49 86-73-708/27/20 12:350.39 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 12:49 87-68-308/27/20 12:350.39 1 Hexachlorobenzene ND mg/kg 08/28/20 12:49 118-74-108/27/20 12:350.39 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 12:49 77-47-408/27/20 12:350.39 1 Hexachloroethane ND mg/kg 08/28/20 12:49 67-72-108/27/20 12:350.39 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 12:49 193-39-508/27/20 12:350.39 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-4 Lab ID:92492009005 Collected:08/19/20 10:15 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 08/28/20 12:49 78-59-108/27/20 12:350.39 1 1-Methylnaphthalene ND mg/kg 08/28/20 12:49 90-12-008/27/20 12:350.39 1 2-Methylnaphthalene ND mg/kg 08/28/20 12:49 91-57-608/27/20 12:350.39 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 12:49 95-48-708/27/20 12:350.39 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 12:49 15831-10-408/27/20 12:350.39 1 Naphthalene ND mg/kg 08/28/20 12:49 91-20-308/27/20 12:350.39 1 2-Nitroaniline ND mg/kg 08/28/20 12:49 88-74-408/27/20 12:351.9 1 3-Nitroaniline ND mg/kg 08/28/20 12:49 99-09-208/27/20 12:351.9 1 4-Nitroaniline ND mg/kg 08/28/20 12:49 100-01-608/27/20 12:350.78 1 Nitrobenzene ND mg/kg 08/28/20 12:49 98-95-308/27/20 12:350.39 1 2-Nitrophenol ND mg/kg 08/28/20 12:49 88-75-508/27/20 12:350.39 1 4-Nitrophenol ND mg/kg 08/28/20 12:49 100-02-7 v208/27/20 12:351.9 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 12:49 62-75-908/27/20 12:350.39 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 12:49 621-64-7 v208/27/20 12:350.39 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 12:49 86-30-608/27/20 12:350.39 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 12:49 108-60-108/27/20 12:350.39 1 Pentachlorophenol ND mg/kg 08/28/20 12:49 87-86-508/27/20 12:350.78 1 Phenanthrene ND mg/kg 08/28/20 12:49 85-01-808/27/20 12:350.39 1 Phenol ND mg/kg 08/28/20 12:49 108-95-208/27/20 12:350.39 1 Pyrene ND mg/kg 08/28/20 12:49 129-00-008/27/20 12:350.39 1 Pyridine ND mg/kg 08/28/20 12:49 110-86-108/27/20 12:350.39 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 12:49 120-82-108/27/20 12:350.39 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 12:49 95-95-408/27/20 12:350.39 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 12:49 88-06-208/27/20 12:350.39 1 Surrogates Nitrobenzene-d5 (S)45 %08/28/20 12:49 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)57 %08/28/20 12:49 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)65 %08/28/20 12:49 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)56 %08/28/20 12:49 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)58 %08/28/20 12:49 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)79 %08/28/20 12:49 118-79-608/27/20 12:3527-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 16:16 67-64-108/25/20 10:360.11 1 Benzene ND mg/kg 08/25/20 16:16 71-43-208/25/20 10:360.0057 1 Bromobenzene ND mg/kg 08/25/20 16:16 108-86-108/25/20 10:360.0057 1 Bromochloromethane ND mg/kg 08/25/20 16:16 74-97-5 IK08/25/20 10:360.0057 1 Bromodichloromethane ND mg/kg 08/25/20 16:16 75-27-408/25/20 10:360.0057 1 Bromoform ND mg/kg 08/25/20 16:16 75-25-208/25/20 10:360.0057 1 Bromomethane ND mg/kg 08/25/20 16:16 74-83-9 v108/25/20 10:360.011 1 2-Butanone (MEK)ND mg/kg 08/25/20 16:16 78-93-308/25/20 10:360.11 1 n-Butylbenzene ND mg/kg 08/25/20 16:16 104-51-808/25/20 10:360.0057 1 sec-Butylbenzene ND mg/kg 08/25/20 16:16 135-98-808/25/20 10:360.0057 1 tert-Butylbenzene ND mg/kg 08/25/20 16:16 98-06-608/25/20 10:360.0057 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-4 Lab ID:92492009005 Collected:08/19/20 10:15 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Carbon tetrachloride ND mg/kg 08/25/20 16:16 56-23-508/25/20 10:360.0057 1 Chlorobenzene ND mg/kg 08/25/20 16:16 108-90-708/25/20 10:360.0057 1 Chloroethane ND mg/kg 08/25/20 16:16 75-00-308/25/20 10:360.011 1 Chloroform ND mg/kg 08/25/20 16:16 67-66-308/25/20 10:360.0057 1 Chloromethane ND mg/kg 08/25/20 16:16 74-87-3 v208/25/20 10:360.011 1 2-Chlorotoluene ND mg/kg 08/25/20 16:16 95-49-808/25/20 10:360.0057 1 4-Chlorotoluene ND mg/kg 08/25/20 16:16 106-43-408/25/20 10:360.0057 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 16:16 96-12-808/25/20 10:360.0057 1 Dibromochloromethane ND mg/kg 08/25/20 16:16 124-48-108/25/20 10:360.0057 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 16:16 106-93-408/25/20 10:360.0057 1 Dibromomethane ND mg/kg 08/25/20 16:16 74-95-308/25/20 10:360.0057 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 16:16 95-50-108/25/20 10:360.0057 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 16:16 541-73-108/25/20 10:360.0057 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 16:16 106-46-708/25/20 10:360.0057 1 Dichlorodifluoromethane ND mg/kg 08/25/20 16:16 75-71-808/25/20 10:360.011 1 1,1-Dichloroethane ND mg/kg 08/25/20 16:16 75-34-308/25/20 10:360.0057 1 1,2-Dichloroethane ND mg/kg 08/25/20 16:16 107-06-208/25/20 10:360.0057 1 1,1-Dichloroethene ND mg/kg 08/25/20 16:16 75-35-408/25/20 10:360.0057 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 16:16 156-59-208/25/20 10:360.0057 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 16:16 156-60-508/25/20 10:360.0057 1 1,2-Dichloropropane ND mg/kg 08/25/20 16:16 78-87-508/25/20 10:360.0057 1 1,3-Dichloropropane ND mg/kg 08/25/20 16:16 142-28-908/25/20 10:360.0057 1 2,2-Dichloropropane ND mg/kg 08/25/20 16:16 594-20-708/25/20 10:360.0057 1 1,1-Dichloropropene ND mg/kg 08/25/20 16:16 563-58-608/25/20 10:360.0057 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 16:16 10061-01-508/25/20 10:360.0057 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 16:16 10061-02-608/25/20 10:360.0057 1 Diisopropyl ether ND mg/kg 08/25/20 16:16 108-20-308/25/20 10:360.0057 1 Ethylbenzene ND mg/kg 08/25/20 16:16 100-41-408/25/20 10:360.0057 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 16:16 87-68-308/25/20 10:360.0057 1 2-Hexanone ND mg/kg 08/25/20 16:16 591-78-608/25/20 10:360.057 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 16:16 98-82-808/25/20 10:360.0057 1 p-Isopropyltoluene ND mg/kg 08/25/20 16:16 99-87-608/25/20 10:360.0057 1 Methylene Chloride ND mg/kg 08/25/20 16:16 75-09-208/25/20 10:360.023 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 16:16 108-10-108/25/20 10:360.057 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 16:16 1634-04-408/25/20 10:360.0057 1 Naphthalene ND mg/kg 08/25/20 16:16 91-20-308/25/20 10:360.0057 1 n-Propylbenzene ND mg/kg 08/25/20 16:16 103-65-108/25/20 10:360.0057 1 Styrene ND mg/kg 08/25/20 16:16 100-42-508/25/20 10:360.0057 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 16:16 630-20-608/25/20 10:360.0057 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 16:16 79-34-508/25/20 10:360.0057 1 Tetrachloroethene ND mg/kg 08/25/20 16:16 127-18-408/25/20 10:360.0057 1 Toluene ND mg/kg 08/25/20 16:16 108-88-308/25/20 10:360.0057 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 16:16 87-61-608/25/20 10:360.0057 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 16:16 120-82-108/25/20 10:360.0057 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 16:16 71-55-608/25/20 10:360.0057 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-4 Lab ID:92492009005 Collected:08/19/20 10:15 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,1,2-Trichloroethane ND mg/kg 08/25/20 16:16 79-00-508/25/20 10:360.0057 1 Trichloroethene ND mg/kg 08/25/20 16:16 79-01-608/25/20 10:360.0057 1 Trichlorofluoromethane ND mg/kg 08/25/20 16:16 75-69-408/25/20 10:360.0057 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 16:16 96-18-408/25/20 10:360.0057 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 16:16 95-63-608/25/20 10:360.0057 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 16:16 108-67-808/25/20 10:360.0057 1 Vinyl acetate ND mg/kg 08/25/20 16:16 108-05-408/25/20 10:360.057 1 Vinyl chloride ND mg/kg 08/25/20 16:16 75-01-408/25/20 10:360.011 1 Xylene (Total)ND mg/kg 08/25/20 16:16 1330-20-708/25/20 10:360.011 1 m&p-Xylene ND mg/kg 08/25/20 16:16 179601-23-108/25/20 10:360.011 1 o-Xylene ND mg/kg 08/25/20 16:16 95-47-608/25/20 10:360.0057 1 Surrogates Toluene-d8 (S)99 %08/25/20 16:16 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)100 %08/25/20 16:16 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)94 %08/25/20 16:16 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 15.6 %08/25/20 10:150.10 1 Sample:GP-5 Lab ID:92492009006 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 13:19 83-32-908/27/20 12:350.43 1 Acenaphthylene ND mg/kg 08/28/20 13:19 208-96-808/27/20 12:350.43 1 Aniline ND mg/kg 08/28/20 13:19 62-53-308/27/20 12:350.43 1 Anthracene ND mg/kg 08/28/20 13:19 120-12-708/27/20 12:350.43 1 Benzo(a)anthracene ND mg/kg 08/28/20 13:19 56-55-308/27/20 12:350.43 1 Benzo(a)pyrene ND mg/kg 08/28/20 13:19 50-32-808/27/20 12:350.43 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 13:19 205-99-208/27/20 12:350.43 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 13:19 191-24-208/27/20 12:350.43 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 13:19 207-08-908/27/20 12:350.43 1 Benzoic Acid ND mg/kg 08/28/20 13:19 65-85-008/27/20 12:352.1 1 Benzyl alcohol ND mg/kg 08/28/20 13:19 100-51-608/27/20 12:350.85 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 13:19 101-55-308/27/20 12:350.43 1 Butylbenzylphthalate ND mg/kg 08/28/20 13:19 85-68-708/27/20 12:350.43 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 13:19 59-50-708/27/20 12:350.85 1 4-Chloroaniline ND mg/kg 08/28/20 13:19 106-47-808/27/20 12:350.85 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 13:19 111-91-108/27/20 12:350.43 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 13:19 111-44-408/27/20 12:350.43 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-5 Lab ID:92492009006 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 2-Chloronaphthalene ND mg/kg 08/28/20 13:19 91-58-708/27/20 12:350.43 1 2-Chlorophenol ND mg/kg 08/28/20 13:19 95-57-808/27/20 12:350.43 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 13:19 7005-72-308/27/20 12:350.43 1 Chrysene ND mg/kg 08/28/20 13:19 218-01-908/27/20 12:350.43 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 13:19 53-70-308/27/20 12:350.43 1 Dibenzofuran ND mg/kg 08/28/20 13:19 132-64-908/27/20 12:350.43 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 13:19 95-50-108/27/20 12:350.43 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 13:19 541-73-108/27/20 12:350.43 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 13:19 106-46-708/27/20 12:350.43 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 13:19 91-94-108/27/20 12:350.85 1 2,4-Dichlorophenol ND mg/kg 08/28/20 13:19 120-83-208/27/20 12:350.43 1 Diethylphthalate ND mg/kg 08/28/20 13:19 84-66-208/27/20 12:350.43 1 2,4-Dimethylphenol ND mg/kg 08/28/20 13:19 105-67-908/27/20 12:350.43 1 Dimethylphthalate ND mg/kg 08/28/20 13:19 131-11-308/27/20 12:350.43 1 Di-n-butylphthalate ND mg/kg 08/28/20 13:19 84-74-208/27/20 12:350.43 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 13:19 534-52-108/27/20 12:350.85 1 2,4-Dinitrophenol ND mg/kg 08/28/20 13:19 51-28-5 v108/27/20 12:352.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 13:19 121-14-208/27/20 12:350.43 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 13:19 606-20-2 v108/27/20 12:350.43 1 Di-n-octylphthalate ND mg/kg 08/28/20 13:19 117-84-008/27/20 12:350.43 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 13:19 117-81-708/27/20 12:350.43 1 Fluoranthene ND mg/kg 08/28/20 13:19 206-44-008/27/20 12:350.43 1 Fluorene ND mg/kg 08/28/20 13:19 86-73-708/27/20 12:350.43 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 13:19 87-68-308/27/20 12:350.43 1 Hexachlorobenzene ND mg/kg 08/28/20 13:19 118-74-108/27/20 12:350.43 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 13:19 77-47-408/27/20 12:350.43 1 Hexachloroethane ND mg/kg 08/28/20 13:19 67-72-108/27/20 12:350.43 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 13:19 193-39-508/27/20 12:350.43 1 Isophorone ND mg/kg 08/28/20 13:19 78-59-108/27/20 12:350.43 1 1-Methylnaphthalene ND mg/kg 08/28/20 13:19 90-12-008/27/20 12:350.43 1 2-Methylnaphthalene ND mg/kg 08/28/20 13:19 91-57-608/27/20 12:350.43 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 13:19 95-48-708/27/20 12:350.43 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 13:19 15831-10-408/27/20 12:350.43 1 Naphthalene ND mg/kg 08/28/20 13:19 91-20-308/27/20 12:350.43 1 2-Nitroaniline ND mg/kg 08/28/20 13:19 88-74-408/27/20 12:352.1 1 3-Nitroaniline ND mg/kg 08/28/20 13:19 99-09-208/27/20 12:352.1 1 4-Nitroaniline ND mg/kg 08/28/20 13:19 100-01-608/27/20 12:350.85 1 Nitrobenzene ND mg/kg 08/28/20 13:19 98-95-308/27/20 12:350.43 1 2-Nitrophenol ND mg/kg 08/28/20 13:19 88-75-508/27/20 12:350.43 1 4-Nitrophenol ND mg/kg 08/28/20 13:19 100-02-7 v208/27/20 12:352.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 13:19 62-75-908/27/20 12:350.43 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 13:19 621-64-7 v208/27/20 12:350.43 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 13:19 86-30-608/27/20 12:350.43 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 13:19 108-60-108/27/20 12:350.43 1 Pentachlorophenol ND mg/kg 08/28/20 13:19 87-86-508/27/20 12:350.85 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-5 Lab ID:92492009006 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Phenanthrene ND mg/kg 08/28/20 13:19 85-01-808/27/20 12:350.43 1 Phenol ND mg/kg 08/28/20 13:19 108-95-208/27/20 12:350.43 1 Pyrene ND mg/kg 08/28/20 13:19 129-00-008/27/20 12:350.43 1 Pyridine ND mg/kg 08/28/20 13:19 110-86-108/27/20 12:350.43 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 13:19 120-82-108/27/20 12:350.43 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 13:19 95-95-408/27/20 12:350.43 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 13:19 88-06-208/27/20 12:350.43 1 Surrogates Nitrobenzene-d5 (S)43 %08/28/20 13:19 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)57 %08/28/20 13:19 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)67 %08/28/20 13:19 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)51 %08/28/20 13:19 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)52 %08/28/20 13:19 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)67 %08/28/20 13:19 118-79-608/27/20 12:3527-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 16:34 67-64-108/25/20 10:360.12 1 Benzene ND mg/kg 08/25/20 16:34 71-43-208/25/20 10:360.0060 1 Bromobenzene ND mg/kg 08/25/20 16:34 108-86-108/25/20 10:360.0060 1 Bromochloromethane ND mg/kg 08/25/20 16:34 74-97-5 IK08/25/20 10:360.0060 1 Bromodichloromethane ND mg/kg 08/25/20 16:34 75-27-408/25/20 10:360.0060 1 Bromoform ND mg/kg 08/25/20 16:34 75-25-208/25/20 10:360.0060 1 Bromomethane ND mg/kg 08/25/20 16:34 74-83-9 v108/25/20 10:360.012 1 2-Butanone (MEK)ND mg/kg 08/25/20 16:34 78-93-308/25/20 10:360.12 1 n-Butylbenzene ND mg/kg 08/25/20 16:34 104-51-808/25/20 10:360.0060 1 sec-Butylbenzene ND mg/kg 08/25/20 16:34 135-98-808/25/20 10:360.0060 1 tert-Butylbenzene ND mg/kg 08/25/20 16:34 98-06-608/25/20 10:360.0060 1 Carbon tetrachloride ND mg/kg 08/25/20 16:34 56-23-508/25/20 10:360.0060 1 Chlorobenzene ND mg/kg 08/25/20 16:34 108-90-708/25/20 10:360.0060 1 Chloroethane ND mg/kg 08/25/20 16:34 75-00-308/25/20 10:360.012 1 Chloroform ND mg/kg 08/25/20 16:34 67-66-308/25/20 10:360.0060 1 Chloromethane ND mg/kg 08/25/20 16:34 74-87-3 v208/25/20 10:360.012 1 2-Chlorotoluene ND mg/kg 08/25/20 16:34 95-49-808/25/20 10:360.0060 1 4-Chlorotoluene ND mg/kg 08/25/20 16:34 106-43-408/25/20 10:360.0060 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 16:34 96-12-808/25/20 10:360.0060 1 Dibromochloromethane ND mg/kg 08/25/20 16:34 124-48-108/25/20 10:360.0060 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 16:34 106-93-408/25/20 10:360.0060 1 Dibromomethane ND mg/kg 08/25/20 16:34 74-95-308/25/20 10:360.0060 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 16:34 95-50-108/25/20 10:360.0060 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 16:34 541-73-108/25/20 10:360.0060 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 16:34 106-46-708/25/20 10:360.0060 1 Dichlorodifluoromethane ND mg/kg 08/25/20 16:34 75-71-808/25/20 10:360.012 1 1,1-Dichloroethane ND mg/kg 08/25/20 16:34 75-34-308/25/20 10:360.0060 1 1,2-Dichloroethane ND mg/kg 08/25/20 16:34 107-06-208/25/20 10:360.0060 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-5 Lab ID:92492009006 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,1-Dichloroethene ND mg/kg 08/25/20 16:34 75-35-408/25/20 10:360.0060 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 16:34 156-59-208/25/20 10:360.0060 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 16:34 156-60-508/25/20 10:360.0060 1 1,2-Dichloropropane ND mg/kg 08/25/20 16:34 78-87-508/25/20 10:360.0060 1 1,3-Dichloropropane ND mg/kg 08/25/20 16:34 142-28-908/25/20 10:360.0060 1 2,2-Dichloropropane ND mg/kg 08/25/20 16:34 594-20-708/25/20 10:360.0060 1 1,1-Dichloropropene ND mg/kg 08/25/20 16:34 563-58-608/25/20 10:360.0060 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 16:34 10061-01-508/25/20 10:360.0060 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 16:34 10061-02-608/25/20 10:360.0060 1 Diisopropyl ether ND mg/kg 08/25/20 16:34 108-20-308/25/20 10:360.0060 1 Ethylbenzene ND mg/kg 08/25/20 16:34 100-41-408/25/20 10:360.0060 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 16:34 87-68-308/25/20 10:360.0060 1 2-Hexanone ND mg/kg 08/25/20 16:34 591-78-608/25/20 10:360.060 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 16:34 98-82-808/25/20 10:360.0060 1 p-Isopropyltoluene ND mg/kg 08/25/20 16:34 99-87-608/25/20 10:360.0060 1 Methylene Chloride ND mg/kg 08/25/20 16:34 75-09-208/25/20 10:360.024 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 16:34 108-10-108/25/20 10:360.060 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 16:34 1634-04-408/25/20 10:360.0060 1 Naphthalene ND mg/kg 08/25/20 16:34 91-20-308/25/20 10:360.0060 1 n-Propylbenzene ND mg/kg 08/25/20 16:34 103-65-108/25/20 10:360.0060 1 Styrene ND mg/kg 08/25/20 16:34 100-42-508/25/20 10:360.0060 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 16:34 630-20-608/25/20 10:360.0060 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 16:34 79-34-508/25/20 10:360.0060 1 Tetrachloroethene ND mg/kg 08/25/20 16:34 127-18-408/25/20 10:360.0060 1 Toluene ND mg/kg 08/25/20 16:34 108-88-308/25/20 10:360.0060 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 16:34 87-61-608/25/20 10:360.0060 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 16:34 120-82-108/25/20 10:360.0060 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 16:34 71-55-608/25/20 10:360.0060 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 16:34 79-00-508/25/20 10:360.0060 1 Trichloroethene ND mg/kg 08/25/20 16:34 79-01-608/25/20 10:360.0060 1 Trichlorofluoromethane ND mg/kg 08/25/20 16:34 75-69-408/25/20 10:360.0060 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 16:34 96-18-408/25/20 10:360.0060 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 16:34 95-63-608/25/20 10:360.0060 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 16:34 108-67-808/25/20 10:360.0060 1 Vinyl acetate ND mg/kg 08/25/20 16:34 108-05-408/25/20 10:360.060 1 Vinyl chloride ND mg/kg 08/25/20 16:34 75-01-408/25/20 10:360.012 1 Xylene (Total)ND mg/kg 08/25/20 16:34 1330-20-708/25/20 10:360.012 1 m&p-Xylene ND mg/kg 08/25/20 16:34 179601-23-108/25/20 10:360.012 1 o-Xylene ND mg/kg 08/25/20 16:34 95-47-608/25/20 10:360.0060 1 Surrogates Toluene-d8 (S)99 %08/25/20 16:34 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)99 %08/25/20 16:34 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)95 %08/25/20 16:34 17060-07-008/25/20 10:3670-132 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-5 Lab ID:92492009006 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 21.2 %08/25/20 10:160.10 1 Sample:GP-6 Lab ID:92492009007 Collected:08/19/20 11:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 13:50 83-32-908/27/20 12:350.42 1 Acenaphthylene ND mg/kg 08/28/20 13:50 208-96-808/27/20 12:350.42 1 Aniline ND mg/kg 08/28/20 13:50 62-53-308/27/20 12:350.42 1 Anthracene ND mg/kg 08/28/20 13:50 120-12-708/27/20 12:350.42 1 Benzo(a)anthracene ND mg/kg 08/28/20 13:50 56-55-308/27/20 12:350.42 1 Benzo(a)pyrene ND mg/kg 08/28/20 13:50 50-32-808/27/20 12:350.42 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 13:50 205-99-208/27/20 12:350.42 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 13:50 191-24-208/27/20 12:350.42 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 13:50 207-08-908/27/20 12:350.42 1 Benzoic Acid ND mg/kg 08/28/20 13:50 65-85-008/27/20 12:352.1 1 Benzyl alcohol ND mg/kg 08/28/20 13:50 100-51-608/27/20 12:350.83 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 13:50 101-55-308/27/20 12:350.42 1 Butylbenzylphthalate ND mg/kg 08/28/20 13:50 85-68-708/27/20 12:350.42 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 13:50 59-50-708/27/20 12:350.83 1 4-Chloroaniline ND mg/kg 08/28/20 13:50 106-47-808/27/20 12:350.83 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 13:50 111-91-108/27/20 12:350.42 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 13:50 111-44-408/27/20 12:350.42 1 2-Chloronaphthalene ND mg/kg 08/28/20 13:50 91-58-708/27/20 12:350.42 1 2-Chlorophenol ND mg/kg 08/28/20 13:50 95-57-808/27/20 12:350.42 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 13:50 7005-72-308/27/20 12:350.42 1 Chrysene ND mg/kg 08/28/20 13:50 218-01-908/27/20 12:350.42 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 13:50 53-70-308/27/20 12:350.42 1 Dibenzofuran ND mg/kg 08/28/20 13:50 132-64-908/27/20 12:350.42 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 13:50 95-50-108/27/20 12:350.42 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 13:50 541-73-108/27/20 12:350.42 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 13:50 106-46-708/27/20 12:350.42 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 13:50 91-94-108/27/20 12:350.83 1 2,4-Dichlorophenol ND mg/kg 08/28/20 13:50 120-83-208/27/20 12:350.42 1 Diethylphthalate ND mg/kg 08/28/20 13:50 84-66-208/27/20 12:350.42 1 2,4-Dimethylphenol ND mg/kg 08/28/20 13:50 105-67-908/27/20 12:350.42 1 Dimethylphthalate ND mg/kg 08/28/20 13:50 131-11-308/27/20 12:350.42 1 Di-n-butylphthalate ND mg/kg 08/28/20 13:50 84-74-208/27/20 12:350.42 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 13:50 534-52-108/27/20 12:350.83 1 2,4-Dinitrophenol ND mg/kg 08/28/20 13:50 51-28-5 v108/27/20 12:352.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 13:50 121-14-208/27/20 12:350.42 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-6 Lab ID:92492009007 Collected:08/19/20 11:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 2,6-Dinitrotoluene ND mg/kg 08/28/20 13:50 606-20-2 v208/27/20 12:350.42 1 Di-n-octylphthalate ND mg/kg 08/28/20 13:50 117-84-008/27/20 12:350.42 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 13:50 117-81-708/27/20 12:350.42 1 Fluoranthene 0.54 mg/kg 08/28/20 13:50 206-44-008/27/20 12:350.42 1 Fluorene ND mg/kg 08/28/20 13:50 86-73-708/27/20 12:350.42 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 13:50 87-68-308/27/20 12:350.42 1 Hexachlorobenzene ND mg/kg 08/28/20 13:50 118-74-108/27/20 12:350.42 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 13:50 77-47-408/27/20 12:350.42 1 Hexachloroethane ND mg/kg 08/28/20 13:50 67-72-108/27/20 12:350.42 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 13:50 193-39-508/27/20 12:350.42 1 Isophorone ND mg/kg 08/28/20 13:50 78-59-108/27/20 12:350.42 1 1-Methylnaphthalene ND mg/kg 08/28/20 13:50 90-12-008/27/20 12:350.42 1 2-Methylnaphthalene ND mg/kg 08/28/20 13:50 91-57-608/27/20 12:350.42 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 13:50 95-48-708/27/20 12:350.42 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 13:50 15831-10-408/27/20 12:350.42 1 Naphthalene ND mg/kg 08/28/20 13:50 91-20-308/27/20 12:350.42 1 2-Nitroaniline ND mg/kg 08/28/20 13:50 88-74-408/27/20 12:352.1 1 3-Nitroaniline ND mg/kg 08/28/20 13:50 99-09-208/27/20 12:352.1 1 4-Nitroaniline ND mg/kg 08/28/20 13:50 100-01-608/27/20 12:350.83 1 Nitrobenzene ND mg/kg 08/28/20 13:50 98-95-308/27/20 12:350.42 1 2-Nitrophenol ND mg/kg 08/28/20 13:50 88-75-508/27/20 12:350.42 1 4-Nitrophenol ND mg/kg 08/28/20 13:50 100-02-7 v208/27/20 12:352.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 13:50 62-75-908/27/20 12:350.42 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 13:50 621-64-7 v208/27/20 12:350.42 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 13:50 86-30-608/27/20 12:350.42 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 13:50 108-60-108/27/20 12:350.42 1 Pentachlorophenol ND mg/kg 08/28/20 13:50 87-86-508/27/20 12:350.83 1 Phenanthrene ND mg/kg 08/28/20 13:50 85-01-808/27/20 12:350.42 1 Phenol ND mg/kg 08/28/20 13:50 108-95-208/27/20 12:350.42 1 Pyrene ND mg/kg 08/28/20 13:50 129-00-008/27/20 12:350.42 1 Pyridine ND mg/kg 08/28/20 13:50 110-86-108/27/20 12:350.42 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 13:50 120-82-108/27/20 12:350.42 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 13:50 95-95-408/27/20 12:350.42 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 13:50 88-06-208/27/20 12:350.42 1 Surrogates Nitrobenzene-d5 (S)51 %08/28/20 13:50 4165-60-008/27/20 12:3523-110 1 2-Fluorobiphenyl (S)67 %08/28/20 13:50 321-60-808/27/20 12:3530-110 1 Terphenyl-d14 (S)76 %08/28/20 13:50 1718-51-008/27/20 12:3528-110 1 Phenol-d6 (S)65 %08/28/20 13:50 13127-88-308/27/20 12:3522-110 1 2-Fluorophenol (S)64 %08/28/20 13:50 367-12-408/27/20 12:3513-110 1 2,4,6-Tribromophenol (S)90 %08/28/20 13:50 118-79-608/27/20 12:3527-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 16:53 67-64-108/25/20 10:360.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-6 Lab ID:92492009007 Collected:08/19/20 11:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Benzene ND mg/kg 08/25/20 16:53 71-43-208/25/20 10:360.0052 1 Bromobenzene ND mg/kg 08/25/20 16:53 108-86-108/25/20 10:360.0052 1 Bromochloromethane ND mg/kg 08/25/20 16:53 74-97-5 IK08/25/20 10:360.0052 1 Bromodichloromethane ND mg/kg 08/25/20 16:53 75-27-408/25/20 10:360.0052 1 Bromoform ND mg/kg 08/25/20 16:53 75-25-208/25/20 10:360.0052 1 Bromomethane ND mg/kg 08/25/20 16:53 74-83-9 v108/25/20 10:360.010 1 2-Butanone (MEK)ND mg/kg 08/25/20 16:53 78-93-308/25/20 10:360.10 1 n-Butylbenzene ND mg/kg 08/25/20 16:53 104-51-808/25/20 10:360.0052 1 sec-Butylbenzene ND mg/kg 08/25/20 16:53 135-98-808/25/20 10:360.0052 1 tert-Butylbenzene ND mg/kg 08/25/20 16:53 98-06-608/25/20 10:360.0052 1 Carbon tetrachloride ND mg/kg 08/25/20 16:53 56-23-508/25/20 10:360.0052 1 Chlorobenzene ND mg/kg 08/25/20 16:53 108-90-708/25/20 10:360.0052 1 Chloroethane ND mg/kg 08/25/20 16:53 75-00-308/25/20 10:360.010 1 Chloroform ND mg/kg 08/25/20 16:53 67-66-308/25/20 10:360.0052 1 Chloromethane ND mg/kg 08/25/20 16:53 74-87-3 v208/25/20 10:360.010 1 2-Chlorotoluene ND mg/kg 08/25/20 16:53 95-49-808/25/20 10:360.0052 1 4-Chlorotoluene ND mg/kg 08/25/20 16:53 106-43-408/25/20 10:360.0052 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 16:53 96-12-808/25/20 10:360.0052 1 Dibromochloromethane ND mg/kg 08/25/20 16:53 124-48-108/25/20 10:360.0052 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 16:53 106-93-408/25/20 10:360.0052 1 Dibromomethane ND mg/kg 08/25/20 16:53 74-95-308/25/20 10:360.0052 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 16:53 95-50-108/25/20 10:360.0052 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 16:53 541-73-108/25/20 10:360.0052 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 16:53 106-46-708/25/20 10:360.0052 1 Dichlorodifluoromethane ND mg/kg 08/25/20 16:53 75-71-808/25/20 10:360.010 1 1,1-Dichloroethane ND mg/kg 08/25/20 16:53 75-34-308/25/20 10:360.0052 1 1,2-Dichloroethane ND mg/kg 08/25/20 16:53 107-06-208/25/20 10:360.0052 1 1,1-Dichloroethene ND mg/kg 08/25/20 16:53 75-35-408/25/20 10:360.0052 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 16:53 156-59-208/25/20 10:360.0052 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 16:53 156-60-508/25/20 10:360.0052 1 1,2-Dichloropropane ND mg/kg 08/25/20 16:53 78-87-508/25/20 10:360.0052 1 1,3-Dichloropropane ND mg/kg 08/25/20 16:53 142-28-908/25/20 10:360.0052 1 2,2-Dichloropropane ND mg/kg 08/25/20 16:53 594-20-708/25/20 10:360.0052 1 1,1-Dichloropropene ND mg/kg 08/25/20 16:53 563-58-608/25/20 10:360.0052 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 16:53 10061-01-508/25/20 10:360.0052 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 16:53 10061-02-608/25/20 10:360.0052 1 Diisopropyl ether ND mg/kg 08/25/20 16:53 108-20-308/25/20 10:360.0052 1 Ethylbenzene ND mg/kg 08/25/20 16:53 100-41-408/25/20 10:360.0052 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 16:53 87-68-308/25/20 10:360.0052 1 2-Hexanone ND mg/kg 08/25/20 16:53 591-78-608/25/20 10:360.052 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 16:53 98-82-808/25/20 10:360.0052 1 p-Isopropyltoluene ND mg/kg 08/25/20 16:53 99-87-608/25/20 10:360.0052 1 Methylene Chloride ND mg/kg 08/25/20 16:53 75-09-208/25/20 10:360.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 16:53 108-10-108/25/20 10:360.052 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 16:53 1634-04-408/25/20 10:360.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-6 Lab ID:92492009007 Collected:08/19/20 11:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Naphthalene ND mg/kg 08/25/20 16:53 91-20-308/25/20 10:360.0052 1 n-Propylbenzene ND mg/kg 08/25/20 16:53 103-65-108/25/20 10:360.0052 1 Styrene ND mg/kg 08/25/20 16:53 100-42-508/25/20 10:360.0052 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 16:53 630-20-608/25/20 10:360.0052 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 16:53 79-34-508/25/20 10:360.0052 1 Tetrachloroethene ND mg/kg 08/25/20 16:53 127-18-408/25/20 10:360.0052 1 Toluene ND mg/kg 08/25/20 16:53 108-88-308/25/20 10:360.0052 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 16:53 87-61-608/25/20 10:360.0052 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 16:53 120-82-108/25/20 10:360.0052 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 16:53 71-55-608/25/20 10:360.0052 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 16:53 79-00-508/25/20 10:360.0052 1 Trichloroethene ND mg/kg 08/25/20 16:53 79-01-608/25/20 10:360.0052 1 Trichlorofluoromethane ND mg/kg 08/25/20 16:53 75-69-408/25/20 10:360.0052 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 16:53 96-18-408/25/20 10:360.0052 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 16:53 95-63-608/25/20 10:360.0052 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 16:53 108-67-808/25/20 10:360.0052 1 Vinyl acetate ND mg/kg 08/25/20 16:53 108-05-408/25/20 10:360.052 1 Vinyl chloride ND mg/kg 08/25/20 16:53 75-01-408/25/20 10:360.010 1 Xylene (Total)ND mg/kg 08/25/20 16:53 1330-20-708/25/20 10:360.010 1 m&p-Xylene ND mg/kg 08/25/20 16:53 179601-23-108/25/20 10:360.010 1 o-Xylene ND mg/kg 08/25/20 16:53 95-47-608/25/20 10:360.0052 1 Surrogates Toluene-d8 (S)99 %08/25/20 16:53 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)102 %08/25/20 16:53 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)95 %08/25/20 16:53 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 20.3 %08/25/20 10:160.10 1 Sample:GP-7 Lab ID:92492009008 Collected:08/19/20 11:20 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 15:59 83-32-908/27/20 14:040.42 1 Acenaphthylene ND mg/kg 08/28/20 15:59 208-96-808/27/20 14:040.42 1 Aniline ND mg/kg 08/28/20 15:59 62-53-308/27/20 14:040.42 1 Anthracene ND mg/kg 08/28/20 15:59 120-12-708/27/20 14:040.42 1 Benzo(a)anthracene ND mg/kg 08/28/20 15:59 56-55-308/27/20 14:040.42 1 Benzo(a)pyrene ND mg/kg 08/28/20 15:59 50-32-808/27/20 14:040.42 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 15:59 205-99-208/27/20 14:040.42 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-7 Lab ID:92492009008 Collected:08/19/20 11:20 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Benzo(g,h,i)perylene ND mg/kg 08/28/20 15:59 191-24-208/27/20 14:040.42 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 15:59 207-08-908/27/20 14:040.42 1 Benzoic Acid ND mg/kg 08/28/20 15:59 65-85-008/27/20 14:042.1 1 Benzyl alcohol ND mg/kg 08/28/20 15:59 100-51-608/27/20 14:040.84 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 15:59 101-55-308/27/20 14:040.42 1 Butylbenzylphthalate ND mg/kg 08/28/20 15:59 85-68-708/27/20 14:040.42 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 15:59 59-50-708/27/20 14:040.84 1 4-Chloroaniline ND mg/kg 08/28/20 15:59 106-47-808/27/20 14:040.84 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 15:59 111-91-108/27/20 14:040.42 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 15:59 111-44-408/27/20 14:040.42 1 2-Chloronaphthalene ND mg/kg 08/28/20 15:59 91-58-708/27/20 14:040.42 1 2-Chlorophenol ND mg/kg 08/28/20 15:59 95-57-808/27/20 14:040.42 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 15:59 7005-72-308/27/20 14:040.42 1 Chrysene ND mg/kg 08/28/20 15:59 218-01-908/27/20 14:040.42 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 15:59 53-70-308/27/20 14:040.42 1 Dibenzofuran ND mg/kg 08/28/20 15:59 132-64-908/27/20 14:040.42 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 15:59 95-50-108/27/20 14:040.42 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 15:59 541-73-108/27/20 14:040.42 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 15:59 106-46-708/27/20 14:040.42 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 15:59 91-94-108/27/20 14:040.84 1 2,4-Dichlorophenol ND mg/kg 08/28/20 15:59 120-83-208/27/20 14:040.42 1 Diethylphthalate ND mg/kg 08/28/20 15:59 84-66-208/27/20 14:040.42 1 2,4-Dimethylphenol ND mg/kg 08/28/20 15:59 105-67-908/27/20 14:040.42 1 Dimethylphthalate ND mg/kg 08/28/20 15:59 131-11-308/27/20 14:040.42 1 Di-n-butylphthalate ND mg/kg 08/28/20 15:59 84-74-208/27/20 14:040.42 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 15:59 534-52-108/27/20 14:040.84 1 2,4-Dinitrophenol ND mg/kg 08/28/20 15:59 51-28-508/27/20 14:042.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 15:59 121-14-208/27/20 14:040.42 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 15:59 606-20-208/27/20 14:040.42 1 Di-n-octylphthalate ND mg/kg 08/28/20 15:59 117-84-008/27/20 14:040.42 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 15:59 117-81-708/27/20 14:040.42 1 Fluoranthene ND mg/kg 08/28/20 15:59 206-44-008/27/20 14:040.42 1 Fluorene ND mg/kg 08/28/20 15:59 86-73-708/27/20 14:040.42 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 15:59 87-68-308/27/20 14:040.42 1 Hexachlorobenzene ND mg/kg 08/28/20 15:59 118-74-108/27/20 14:040.42 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 15:59 77-47-408/27/20 14:040.42 1 Hexachloroethane ND mg/kg 08/28/20 15:59 67-72-108/27/20 14:040.42 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 15:59 193-39-508/27/20 14:040.42 1 Isophorone ND mg/kg 08/28/20 15:59 78-59-108/27/20 14:040.42 1 1-Methylnaphthalene ND mg/kg 08/28/20 15:59 90-12-008/27/20 14:040.42 1 2-Methylnaphthalene ND mg/kg 08/28/20 15:59 91-57-608/27/20 14:040.42 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 15:59 95-48-708/27/20 14:040.42 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 15:59 15831-10-408/27/20 14:040.42 1 Naphthalene ND mg/kg 08/28/20 15:59 91-20-308/27/20 14:040.42 1 2-Nitroaniline ND mg/kg 08/28/20 15:59 88-74-4 v208/27/20 14:042.1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-7 Lab ID:92492009008 Collected:08/19/20 11:20 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 3-Nitroaniline ND mg/kg 08/28/20 15:59 99-09-208/27/20 14:042.1 1 4-Nitroaniline ND mg/kg 08/28/20 15:59 100-01-608/27/20 14:040.84 1 Nitrobenzene ND mg/kg 08/28/20 15:59 98-95-308/27/20 14:040.42 1 2-Nitrophenol ND mg/kg 08/28/20 15:59 88-75-508/27/20 14:040.42 1 4-Nitrophenol ND mg/kg 08/28/20 15:59 100-02-708/27/20 14:042.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 15:59 62-75-908/27/20 14:040.42 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 15:59 621-64-7 v208/27/20 14:040.42 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 15:59 86-30-608/27/20 14:040.42 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 15:59 108-60-1 v208/27/20 14:040.42 1 Pentachlorophenol ND mg/kg 08/28/20 15:59 87-86-508/27/20 14:040.84 1 Phenanthrene ND mg/kg 08/28/20 15:59 85-01-808/27/20 14:040.42 1 Phenol ND mg/kg 08/28/20 15:59 108-95-208/27/20 14:040.42 1 Pyrene ND mg/kg 08/28/20 15:59 129-00-008/27/20 14:040.42 1 Pyridine ND mg/kg 08/28/20 15:59 110-86-108/27/20 14:040.42 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 15:59 120-82-108/27/20 14:040.42 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 15:59 95-95-408/27/20 14:040.42 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 15:59 88-06-208/27/20 14:040.42 1 Surrogates Nitrobenzene-d5 (S)47 %08/28/20 15:59 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)60 %08/28/20 15:59 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)72 %08/28/20 15:59 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)57 %08/28/20 15:59 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)60 %08/28/20 15:59 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)77 %08/28/20 15:59 118-79-608/27/20 14:0427-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 17:11 67-64-108/25/20 10:360.11 1 Benzene ND mg/kg 08/25/20 17:11 71-43-208/25/20 10:360.0054 1 Bromobenzene ND mg/kg 08/25/20 17:11 108-86-108/25/20 10:360.0054 1 Bromochloromethane ND mg/kg 08/25/20 17:11 74-97-5 IK08/25/20 10:360.0054 1 Bromodichloromethane ND mg/kg 08/25/20 17:11 75-27-408/25/20 10:360.0054 1 Bromoform ND mg/kg 08/25/20 17:11 75-25-208/25/20 10:360.0054 1 Bromomethane ND mg/kg 08/25/20 17:11 74-83-9 v108/25/20 10:360.011 1 2-Butanone (MEK)ND mg/kg 08/25/20 17:11 78-93-308/25/20 10:360.11 1 n-Butylbenzene ND mg/kg 08/25/20 17:11 104-51-808/25/20 10:360.0054 1 sec-Butylbenzene ND mg/kg 08/25/20 17:11 135-98-808/25/20 10:360.0054 1 tert-Butylbenzene ND mg/kg 08/25/20 17:11 98-06-608/25/20 10:360.0054 1 Carbon tetrachloride ND mg/kg 08/25/20 17:11 56-23-508/25/20 10:360.0054 1 Chlorobenzene ND mg/kg 08/25/20 17:11 108-90-708/25/20 10:360.0054 1 Chloroethane ND mg/kg 08/25/20 17:11 75-00-308/25/20 10:360.011 1 Chloroform ND mg/kg 08/25/20 17:11 67-66-308/25/20 10:360.0054 1 Chloromethane ND mg/kg 08/25/20 17:11 74-87-3 v208/25/20 10:360.011 1 2-Chlorotoluene ND mg/kg 08/25/20 17:11 95-49-808/25/20 10:360.0054 1 4-Chlorotoluene ND mg/kg 08/25/20 17:11 106-43-408/25/20 10:360.0054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-7 Lab ID:92492009008 Collected:08/19/20 11:20 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 17:11 96-12-808/25/20 10:360.0054 1 Dibromochloromethane ND mg/kg 08/25/20 17:11 124-48-108/25/20 10:360.0054 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 17:11 106-93-408/25/20 10:360.0054 1 Dibromomethane ND mg/kg 08/25/20 17:11 74-95-308/25/20 10:360.0054 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 17:11 95-50-108/25/20 10:360.0054 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 17:11 541-73-108/25/20 10:360.0054 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 17:11 106-46-708/25/20 10:360.0054 1 Dichlorodifluoromethane ND mg/kg 08/25/20 17:11 75-71-808/25/20 10:360.011 1 1,1-Dichloroethane ND mg/kg 08/25/20 17:11 75-34-308/25/20 10:360.0054 1 1,2-Dichloroethane ND mg/kg 08/25/20 17:11 107-06-208/25/20 10:360.0054 1 1,1-Dichloroethene ND mg/kg 08/25/20 17:11 75-35-408/25/20 10:360.0054 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 17:11 156-59-208/25/20 10:360.0054 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 17:11 156-60-508/25/20 10:360.0054 1 1,2-Dichloropropane ND mg/kg 08/25/20 17:11 78-87-508/25/20 10:360.0054 1 1,3-Dichloropropane ND mg/kg 08/25/20 17:11 142-28-908/25/20 10:360.0054 1 2,2-Dichloropropane ND mg/kg 08/25/20 17:11 594-20-708/25/20 10:360.0054 1 1,1-Dichloropropene ND mg/kg 08/25/20 17:11 563-58-608/25/20 10:360.0054 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 17:11 10061-01-508/25/20 10:360.0054 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 17:11 10061-02-608/25/20 10:360.0054 1 Diisopropyl ether ND mg/kg 08/25/20 17:11 108-20-308/25/20 10:360.0054 1 Ethylbenzene ND mg/kg 08/25/20 17:11 100-41-408/25/20 10:360.0054 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 17:11 87-68-308/25/20 10:360.0054 1 2-Hexanone ND mg/kg 08/25/20 17:11 591-78-608/25/20 10:360.054 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 17:11 98-82-808/25/20 10:360.0054 1 p-Isopropyltoluene ND mg/kg 08/25/20 17:11 99-87-608/25/20 10:360.0054 1 Methylene Chloride ND mg/kg 08/25/20 17:11 75-09-208/25/20 10:360.022 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 17:11 108-10-108/25/20 10:360.054 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 17:11 1634-04-408/25/20 10:360.0054 1 Naphthalene ND mg/kg 08/25/20 17:11 91-20-308/25/20 10:360.0054 1 n-Propylbenzene ND mg/kg 08/25/20 17:11 103-65-108/25/20 10:360.0054 1 Styrene ND mg/kg 08/25/20 17:11 100-42-508/25/20 10:360.0054 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 17:11 630-20-608/25/20 10:360.0054 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 17:11 79-34-508/25/20 10:360.0054 1 Tetrachloroethene ND mg/kg 08/25/20 17:11 127-18-408/25/20 10:360.0054 1 Toluene ND mg/kg 08/25/20 17:11 108-88-308/25/20 10:360.0054 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 17:11 87-61-608/25/20 10:360.0054 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 17:11 120-82-108/25/20 10:360.0054 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 17:11 71-55-608/25/20 10:360.0054 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 17:11 79-00-508/25/20 10:360.0054 1 Trichloroethene ND mg/kg 08/25/20 17:11 79-01-608/25/20 10:360.0054 1 Trichlorofluoromethane ND mg/kg 08/25/20 17:11 75-69-408/25/20 10:360.0054 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 17:11 96-18-408/25/20 10:360.0054 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 17:11 95-63-608/25/20 10:360.0054 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 17:11 108-67-808/25/20 10:360.0054 1 Vinyl acetate ND mg/kg 08/25/20 17:11 108-05-408/25/20 10:360.054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-7 Lab ID:92492009008 Collected:08/19/20 11:20 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Vinyl chloride ND mg/kg 08/25/20 17:11 75-01-408/25/20 10:360.011 1 Xylene (Total)ND mg/kg 08/25/20 17:11 1330-20-708/25/20 10:360.011 1 m&p-Xylene ND mg/kg 08/25/20 17:11 179601-23-108/25/20 10:360.011 1 o-Xylene ND mg/kg 08/25/20 17:11 95-47-608/25/20 10:360.0054 1 Surrogates Toluene-d8 (S)101 %08/25/20 17:11 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)142 %08/25/20 17:11 460-00-4 S308/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)99 %08/25/20 17:11 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 22.1 %08/25/20 10:160.10 1 Sample:GP-8 Lab ID:92492009009 Collected:08/19/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 14:32 83-32-908/27/20 14:040.39 1 Acenaphthylene ND mg/kg 08/28/20 14:32 208-96-808/27/20 14:040.39 1 Aniline ND mg/kg 08/28/20 14:32 62-53-308/27/20 14:040.39 1 Anthracene ND mg/kg 08/28/20 14:32 120-12-708/27/20 14:040.39 1 Benzo(a)anthracene ND mg/kg 08/28/20 14:32 56-55-308/27/20 14:040.39 1 Benzo(a)pyrene ND mg/kg 08/28/20 14:32 50-32-808/27/20 14:040.39 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 14:32 205-99-208/27/20 14:040.39 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 14:32 191-24-208/27/20 14:040.39 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 14:32 207-08-908/27/20 14:040.39 1 Benzoic Acid ND mg/kg 08/28/20 14:32 65-85-008/27/20 14:042.0 1 Benzyl alcohol ND mg/kg 08/28/20 14:32 100-51-608/27/20 14:040.79 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 14:32 101-55-308/27/20 14:040.39 1 Butylbenzylphthalate ND mg/kg 08/28/20 14:32 85-68-708/27/20 14:040.39 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 14:32 59-50-708/27/20 14:040.79 1 4-Chloroaniline ND mg/kg 08/28/20 14:32 106-47-808/27/20 14:040.79 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 14:32 111-91-108/27/20 14:040.39 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 14:32 111-44-408/27/20 14:040.39 1 2-Chloronaphthalene ND mg/kg 08/28/20 14:32 91-58-708/27/20 14:040.39 1 2-Chlorophenol ND mg/kg 08/28/20 14:32 95-57-808/27/20 14:040.39 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 14:32 7005-72-308/27/20 14:040.39 1 Chrysene ND mg/kg 08/28/20 14:32 218-01-908/27/20 14:040.39 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 14:32 53-70-308/27/20 14:040.39 1 Dibenzofuran ND mg/kg 08/28/20 14:32 132-64-908/27/20 14:040.39 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 14:32 95-50-108/27/20 14:040.39 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-8 Lab ID:92492009009 Collected:08/19/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 1,3-Dichlorobenzene ND mg/kg 08/28/20 14:32 541-73-108/27/20 14:040.39 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 14:32 106-46-708/27/20 14:040.39 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 14:32 91-94-108/27/20 14:040.79 1 2,4-Dichlorophenol ND mg/kg 08/28/20 14:32 120-83-208/27/20 14:040.39 1 Diethylphthalate ND mg/kg 08/28/20 14:32 84-66-208/27/20 14:040.39 1 2,4-Dimethylphenol ND mg/kg 08/28/20 14:32 105-67-908/27/20 14:040.39 1 Dimethylphthalate ND mg/kg 08/28/20 14:32 131-11-308/27/20 14:040.39 1 Di-n-butylphthalate ND mg/kg 08/28/20 14:32 84-74-208/27/20 14:040.39 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 14:32 534-52-108/27/20 14:040.79 1 2,4-Dinitrophenol ND mg/kg 08/28/20 14:32 51-28-508/27/20 14:042.0 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 14:32 121-14-208/27/20 14:040.39 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 14:32 606-20-208/27/20 14:040.39 1 Di-n-octylphthalate ND mg/kg 08/28/20 14:32 117-84-008/27/20 14:040.39 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 14:32 117-81-708/27/20 14:040.39 1 Fluoranthene ND mg/kg 08/28/20 14:32 206-44-008/27/20 14:040.39 1 Fluorene ND mg/kg 08/28/20 14:32 86-73-708/27/20 14:040.39 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 14:32 87-68-308/27/20 14:040.39 1 Hexachlorobenzene ND mg/kg 08/28/20 14:32 118-74-108/27/20 14:040.39 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 14:32 77-47-4 v208/27/20 14:040.39 1 Hexachloroethane ND mg/kg 08/28/20 14:32 67-72-108/27/20 14:040.39 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 14:32 193-39-508/27/20 14:040.39 1 Isophorone ND mg/kg 08/28/20 14:32 78-59-108/27/20 14:040.39 1 1-Methylnaphthalene ND mg/kg 08/28/20 14:32 90-12-008/27/20 14:040.39 1 2-Methylnaphthalene ND mg/kg 08/28/20 14:32 91-57-608/27/20 14:040.39 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 14:32 95-48-708/27/20 14:040.39 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 14:32 15831-10-408/27/20 14:040.39 1 Naphthalene ND mg/kg 08/28/20 14:32 91-20-308/27/20 14:040.39 1 2-Nitroaniline ND mg/kg 08/28/20 14:32 88-74-4 v208/27/20 14:042.0 1 3-Nitroaniline ND mg/kg 08/28/20 14:32 99-09-208/27/20 14:042.0 1 4-Nitroaniline ND mg/kg 08/28/20 14:32 100-01-608/27/20 14:040.79 1 Nitrobenzene ND mg/kg 08/28/20 14:32 98-95-308/27/20 14:040.39 1 2-Nitrophenol ND mg/kg 08/28/20 14:32 88-75-508/27/20 14:040.39 1 4-Nitrophenol ND mg/kg 08/28/20 14:32 100-02-708/27/20 14:042.0 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 14:32 62-75-908/27/20 14:040.39 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 14:32 621-64-708/27/20 14:040.39 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 14:32 86-30-608/27/20 14:040.39 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 14:32 108-60-1 v208/27/20 14:040.39 1 Pentachlorophenol ND mg/kg 08/28/20 14:32 87-86-508/27/20 14:040.79 1 Phenanthrene ND mg/kg 08/28/20 14:32 85-01-808/27/20 14:040.39 1 Phenol ND mg/kg 08/28/20 14:32 108-95-208/27/20 14:040.39 1 Pyrene ND mg/kg 08/28/20 14:32 129-00-008/27/20 14:040.39 1 Pyridine ND mg/kg 08/28/20 14:32 110-86-108/27/20 14:040.39 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 14:32 120-82-108/27/20 14:040.39 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 14:32 95-95-408/27/20 14:040.39 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 14:32 88-06-208/27/20 14:040.39 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-8 Lab ID:92492009009 Collected:08/19/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Surrogates Nitrobenzene-d5 (S)51 %08/28/20 14:32 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)64 %08/28/20 14:32 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)70 %08/28/20 14:32 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)58 %08/28/20 14:32 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)55 %08/28/20 14:32 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)81 %08/28/20 14:32 118-79-608/27/20 14:0427-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 17:30 67-64-108/25/20 10:360.094 1 Benzene ND mg/kg 08/25/20 17:30 71-43-208/25/20 10:360.0047 1 Bromobenzene ND mg/kg 08/25/20 17:30 108-86-108/25/20 10:360.0047 1 Bromochloromethane ND mg/kg 08/25/20 17:30 74-97-5 IK08/25/20 10:360.0047 1 Bromodichloromethane ND mg/kg 08/25/20 17:30 75-27-408/25/20 10:360.0047 1 Bromoform ND mg/kg 08/25/20 17:30 75-25-208/25/20 10:360.0047 1 Bromomethane ND mg/kg 08/25/20 17:30 74-83-9 v108/25/20 10:360.0094 1 2-Butanone (MEK)ND mg/kg 08/25/20 17:30 78-93-308/25/20 10:360.094 1 n-Butylbenzene ND mg/kg 08/25/20 17:30 104-51-808/25/20 10:360.0047 1 sec-Butylbenzene ND mg/kg 08/25/20 17:30 135-98-808/25/20 10:360.0047 1 tert-Butylbenzene ND mg/kg 08/25/20 17:30 98-06-608/25/20 10:360.0047 1 Carbon tetrachloride ND mg/kg 08/25/20 17:30 56-23-508/25/20 10:360.0047 1 Chlorobenzene ND mg/kg 08/25/20 17:30 108-90-708/25/20 10:360.0047 1 Chloroethane ND mg/kg 08/25/20 17:30 75-00-308/25/20 10:360.0094 1 Chloroform ND mg/kg 08/25/20 17:30 67-66-308/25/20 10:360.0047 1 Chloromethane ND mg/kg 08/25/20 17:30 74-87-3 v208/25/20 10:360.0094 1 2-Chlorotoluene ND mg/kg 08/25/20 17:30 95-49-808/25/20 10:360.0047 1 4-Chlorotoluene ND mg/kg 08/25/20 17:30 106-43-408/25/20 10:360.0047 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 17:30 96-12-808/25/20 10:360.0047 1 Dibromochloromethane ND mg/kg 08/25/20 17:30 124-48-108/25/20 10:360.0047 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 17:30 106-93-408/25/20 10:360.0047 1 Dibromomethane ND mg/kg 08/25/20 17:30 74-95-308/25/20 10:360.0047 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 17:30 95-50-108/25/20 10:360.0047 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 17:30 541-73-108/25/20 10:360.0047 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 17:30 106-46-708/25/20 10:360.0047 1 Dichlorodifluoromethane ND mg/kg 08/25/20 17:30 75-71-808/25/20 10:360.0094 1 1,1-Dichloroethane ND mg/kg 08/25/20 17:30 75-34-308/25/20 10:360.0047 1 1,2-Dichloroethane ND mg/kg 08/25/20 17:30 107-06-208/25/20 10:360.0047 1 1,1-Dichloroethene ND mg/kg 08/25/20 17:30 75-35-408/25/20 10:360.0047 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 17:30 156-59-208/25/20 10:360.0047 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 17:30 156-60-508/25/20 10:360.0047 1 1,2-Dichloropropane ND mg/kg 08/25/20 17:30 78-87-508/25/20 10:360.0047 1 1,3-Dichloropropane ND mg/kg 08/25/20 17:30 142-28-908/25/20 10:360.0047 1 2,2-Dichloropropane ND mg/kg 08/25/20 17:30 594-20-708/25/20 10:360.0047 1 1,1-Dichloropropene ND mg/kg 08/25/20 17:30 563-58-608/25/20 10:360.0047 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GP-8 Lab ID:92492009009 Collected:08/19/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles cis-1,3-Dichloropropene ND mg/kg 08/25/20 17:30 10061-01-508/25/20 10:360.0047 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 17:30 10061-02-608/25/20 10:360.0047 1 Diisopropyl ether ND mg/kg 08/25/20 17:30 108-20-308/25/20 10:360.0047 1 Ethylbenzene ND mg/kg 08/25/20 17:30 100-41-408/25/20 10:360.0047 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 17:30 87-68-308/25/20 10:360.0047 1 2-Hexanone ND mg/kg 08/25/20 17:30 591-78-608/25/20 10:360.047 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 17:30 98-82-808/25/20 10:360.0047 1 p-Isopropyltoluene ND mg/kg 08/25/20 17:30 99-87-608/25/20 10:360.0047 1 Methylene Chloride ND mg/kg 08/25/20 17:30 75-09-208/25/20 10:360.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 17:30 108-10-108/25/20 10:360.047 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 17:30 1634-04-408/25/20 10:360.0047 1 Naphthalene ND mg/kg 08/25/20 17:30 91-20-308/25/20 10:360.0047 1 n-Propylbenzene ND mg/kg 08/25/20 17:30 103-65-108/25/20 10:360.0047 1 Styrene ND mg/kg 08/25/20 17:30 100-42-508/25/20 10:360.0047 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 17:30 630-20-608/25/20 10:360.0047 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 17:30 79-34-508/25/20 10:360.0047 1 Tetrachloroethene ND mg/kg 08/25/20 17:30 127-18-408/25/20 10:360.0047 1 Toluene ND mg/kg 08/25/20 17:30 108-88-308/25/20 10:360.0047 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 17:30 87-61-608/25/20 10:360.0047 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 17:30 120-82-108/25/20 10:360.0047 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 17:30 71-55-608/25/20 10:360.0047 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 17:30 79-00-508/25/20 10:360.0047 1 Trichloroethene ND mg/kg 08/25/20 17:30 79-01-608/25/20 10:360.0047 1 Trichlorofluoromethane ND mg/kg 08/25/20 17:30 75-69-408/25/20 10:360.0047 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 17:30 96-18-408/25/20 10:360.0047 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 17:30 95-63-608/25/20 10:360.0047 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 17:30 108-67-808/25/20 10:360.0047 1 Vinyl acetate ND mg/kg 08/25/20 17:30 108-05-408/25/20 10:360.047 1 Vinyl chloride ND mg/kg 08/25/20 17:30 75-01-408/25/20 10:360.0094 1 Xylene (Total)ND mg/kg 08/25/20 17:30 1330-20-708/25/20 10:360.0094 1 m&p-Xylene ND mg/kg 08/25/20 17:30 179601-23-108/25/20 10:360.0094 1 o-Xylene ND mg/kg 08/25/20 17:30 95-47-608/25/20 10:360.0047 1 Surrogates Toluene-d8 (S)99 %08/25/20 17:30 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)103 %08/25/20 17:30 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)96 %08/25/20 17:30 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 16.1 %08/25/20 10:160.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-1 Lab ID:92492009010 Collected:08/19/20 12:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 15:29 83-32-908/27/20 14:043.0 1 Acenaphthylene ND mg/kg 08/28/20 15:29 208-96-808/27/20 14:043.0 1 Aniline ND mg/kg 08/28/20 15:29 62-53-308/27/20 14:043.0 1 Anthracene ND mg/kg 08/28/20 15:29 120-12-708/27/20 14:043.0 1 Benzo(a)anthracene ND mg/kg 08/28/20 15:29 56-55-308/27/20 14:043.0 1 Benzo(a)pyrene ND mg/kg 08/28/20 15:29 50-32-808/27/20 14:043.0 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 15:29 205-99-208/27/20 14:043.0 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 15:29 191-24-208/27/20 14:043.0 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 15:29 207-08-908/27/20 14:043.0 1 Benzoic Acid ND mg/kg 08/28/20 15:29 65-85-008/27/20 14:0415.1 1 Benzyl alcohol ND mg/kg 08/28/20 15:29 100-51-608/27/20 14:046.0 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 15:29 101-55-308/27/20 14:043.0 1 Butylbenzylphthalate ND mg/kg 08/28/20 15:29 85-68-708/27/20 14:043.0 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 15:29 59-50-708/27/20 14:046.0 1 4-Chloroaniline ND mg/kg 08/28/20 15:29 106-47-808/27/20 14:046.0 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 15:29 111-91-108/27/20 14:043.0 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 15:29 111-44-408/27/20 14:043.0 1 2-Chloronaphthalene ND mg/kg 08/28/20 15:29 91-58-708/27/20 14:043.0 1 2-Chlorophenol ND mg/kg 08/28/20 15:29 95-57-808/27/20 14:043.0 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 15:29 7005-72-308/27/20 14:043.0 1 Chrysene ND mg/kg 08/28/20 15:29 218-01-908/27/20 14:043.0 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 15:29 53-70-308/27/20 14:043.0 1 Dibenzofuran ND mg/kg 08/28/20 15:29 132-64-908/27/20 14:043.0 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 15:29 95-50-108/27/20 14:043.0 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 15:29 541-73-108/27/20 14:043.0 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 15:29 106-46-708/27/20 14:043.0 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 15:29 91-94-108/27/20 14:046.0 1 2,4-Dichlorophenol ND mg/kg 08/28/20 15:29 120-83-208/27/20 14:043.0 1 Diethylphthalate ND mg/kg 08/28/20 15:29 84-66-208/27/20 14:043.0 1 2,4-Dimethylphenol ND mg/kg 08/28/20 15:29 105-67-908/27/20 14:043.0 1 Dimethylphthalate ND mg/kg 08/28/20 15:29 131-11-308/27/20 14:043.0 1 Di-n-butylphthalate ND mg/kg 08/28/20 15:29 84-74-208/27/20 14:043.0 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 15:29 534-52-108/27/20 14:046.0 1 2,4-Dinitrophenol ND mg/kg 08/28/20 15:29 51-28-5 v108/27/20 14:0415.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 15:29 121-14-208/27/20 14:043.0 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 15:29 606-20-2 v208/27/20 14:043.0 1 Di-n-octylphthalate ND mg/kg 08/28/20 15:29 117-84-008/27/20 14:043.0 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 15:29 117-81-708/27/20 14:043.0 1 Fluoranthene ND mg/kg 08/28/20 15:29 206-44-008/27/20 14:043.0 1 Fluorene ND mg/kg 08/28/20 15:29 86-73-708/27/20 14:043.0 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 15:29 87-68-308/27/20 14:043.0 1 Hexachlorobenzene ND mg/kg 08/28/20 15:29 118-74-108/27/20 14:043.0 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 15:29 77-47-408/27/20 14:043.0 1 Hexachloroethane ND mg/kg 08/28/20 15:29 67-72-108/27/20 14:043.0 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 15:29 193-39-508/27/20 14:043.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-1 Lab ID:92492009010 Collected:08/19/20 12:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 08/28/20 15:29 78-59-108/27/20 14:043.0 1 1-Methylnaphthalene ND mg/kg 08/28/20 15:29 90-12-008/27/20 14:043.0 1 2-Methylnaphthalene ND mg/kg 08/28/20 15:29 91-57-608/27/20 14:043.0 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 15:29 95-48-708/27/20 14:043.0 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 15:29 15831-10-408/27/20 14:043.0 1 Naphthalene ND mg/kg 08/28/20 15:29 91-20-308/27/20 14:043.0 1 2-Nitroaniline ND mg/kg 08/28/20 15:29 88-74-408/27/20 14:0415.1 1 3-Nitroaniline ND mg/kg 08/28/20 15:29 99-09-208/27/20 14:0415.1 1 4-Nitroaniline ND mg/kg 08/28/20 15:29 100-01-608/27/20 14:046.0 1 Nitrobenzene ND mg/kg 08/28/20 15:29 98-95-308/27/20 14:043.0 1 2-Nitrophenol ND mg/kg 08/28/20 15:29 88-75-508/27/20 14:043.0 1 4-Nitrophenol ND mg/kg 08/28/20 15:29 100-02-7 v208/27/20 14:0415.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 15:29 62-75-908/27/20 14:043.0 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 15:29 621-64-7 v208/27/20 14:043.0 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 15:29 86-30-608/27/20 14:043.0 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 15:29 108-60-108/27/20 14:043.0 1 Pentachlorophenol 72.4 mg/kg 08/28/20 16:21 87-86-508/27/20 14:0460.4 10 Phenanthrene ND mg/kg 08/28/20 15:29 85-01-808/27/20 14:043.0 1 Phenol ND mg/kg 08/28/20 15:29 108-95-208/27/20 14:043.0 1 Pyrene ND mg/kg 08/28/20 15:29 129-00-008/27/20 14:043.0 1 Pyridine ND mg/kg 08/28/20 15:29 110-86-108/27/20 14:043.0 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 15:29 120-82-108/27/20 14:043.0 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 15:29 95-95-408/27/20 14:043.0 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 15:29 88-06-208/27/20 14:043.0 1 Surrogates Nitrobenzene-d5 (S)34 %08/28/20 15:29 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)46 %08/28/20 15:29 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)56 %08/28/20 15:29 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)42 %08/28/20 15:29 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)43 %08/28/20 15:29 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)67 %08/28/20 15:29 118-79-608/27/20 14:0427-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 17:48 67-64-108/25/20 10:360.091 1 Benzene ND mg/kg 08/25/20 17:48 71-43-208/25/20 10:360.0045 1 Bromobenzene ND mg/kg 08/25/20 17:48 108-86-108/25/20 10:360.0045 1 Bromochloromethane ND mg/kg 08/25/20 17:48 74-97-5 IK08/25/20 10:360.0045 1 Bromodichloromethane ND mg/kg 08/25/20 17:48 75-27-408/25/20 10:360.0045 1 Bromoform ND mg/kg 08/25/20 17:48 75-25-208/25/20 10:360.0045 1 Bromomethane ND mg/kg 08/25/20 17:48 74-83-9 v108/25/20 10:360.0091 1 2-Butanone (MEK)ND mg/kg 08/25/20 17:48 78-93-308/25/20 10:360.091 1 n-Butylbenzene ND mg/kg 08/25/20 17:48 104-51-808/25/20 10:360.0045 1 sec-Butylbenzene ND mg/kg 08/25/20 17:48 135-98-808/25/20 10:360.0045 1 tert-Butylbenzene ND mg/kg 08/25/20 17:48 98-06-608/25/20 10:360.0045 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-1 Lab ID:92492009010 Collected:08/19/20 12:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Carbon tetrachloride ND mg/kg 08/25/20 17:48 56-23-508/25/20 10:360.0045 1 Chlorobenzene ND mg/kg 08/25/20 17:48 108-90-708/25/20 10:360.0045 1 Chloroethane ND mg/kg 08/25/20 17:48 75-00-308/25/20 10:360.0091 1 Chloroform ND mg/kg 08/25/20 17:48 67-66-308/25/20 10:360.0045 1 Chloromethane ND mg/kg 08/25/20 17:48 74-87-3 v208/25/20 10:360.0091 1 2-Chlorotoluene ND mg/kg 08/25/20 17:48 95-49-808/25/20 10:360.0045 1 4-Chlorotoluene ND mg/kg 08/25/20 17:48 106-43-408/25/20 10:360.0045 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 17:48 96-12-808/25/20 10:360.0045 1 Dibromochloromethane ND mg/kg 08/25/20 17:48 124-48-108/25/20 10:360.0045 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 17:48 106-93-408/25/20 10:360.0045 1 Dibromomethane ND mg/kg 08/25/20 17:48 74-95-308/25/20 10:360.0045 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 17:48 95-50-108/25/20 10:360.0045 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 17:48 541-73-108/25/20 10:360.0045 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 17:48 106-46-708/25/20 10:360.0045 1 Dichlorodifluoromethane ND mg/kg 08/25/20 17:48 75-71-808/25/20 10:360.0091 1 1,1-Dichloroethane ND mg/kg 08/25/20 17:48 75-34-308/25/20 10:360.0045 1 1,2-Dichloroethane ND mg/kg 08/25/20 17:48 107-06-208/25/20 10:360.0045 1 1,1-Dichloroethene ND mg/kg 08/25/20 17:48 75-35-408/25/20 10:360.0045 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 17:48 156-59-208/25/20 10:360.0045 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 17:48 156-60-508/25/20 10:360.0045 1 1,2-Dichloropropane ND mg/kg 08/25/20 17:48 78-87-508/25/20 10:360.0045 1 1,3-Dichloropropane ND mg/kg 08/25/20 17:48 142-28-908/25/20 10:360.0045 1 2,2-Dichloropropane ND mg/kg 08/25/20 17:48 594-20-708/25/20 10:360.0045 1 1,1-Dichloropropene ND mg/kg 08/25/20 17:48 563-58-608/25/20 10:360.0045 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 17:48 10061-01-508/25/20 10:360.0045 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 17:48 10061-02-608/25/20 10:360.0045 1 Diisopropyl ether ND mg/kg 08/25/20 17:48 108-20-308/25/20 10:360.0045 1 Ethylbenzene ND mg/kg 08/25/20 17:48 100-41-408/25/20 10:360.0045 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 17:48 87-68-308/25/20 10:360.0045 1 2-Hexanone ND mg/kg 08/25/20 17:48 591-78-608/25/20 10:360.045 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 17:48 98-82-808/25/20 10:360.0045 1 p-Isopropyltoluene ND mg/kg 08/25/20 17:48 99-87-608/25/20 10:360.0045 1 Methylene Chloride ND mg/kg 08/25/20 17:48 75-09-208/25/20 10:360.018 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 17:48 108-10-108/25/20 10:360.045 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 17:48 1634-04-408/25/20 10:360.0045 1 Naphthalene ND mg/kg 08/25/20 17:48 91-20-308/25/20 10:360.0045 1 n-Propylbenzene ND mg/kg 08/25/20 17:48 103-65-108/25/20 10:360.0045 1 Styrene ND mg/kg 08/25/20 17:48 100-42-508/25/20 10:360.0045 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 17:48 630-20-608/25/20 10:360.0045 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 17:48 79-34-508/25/20 10:360.0045 1 Tetrachloroethene ND mg/kg 08/25/20 17:48 127-18-408/25/20 10:360.0045 1 Toluene ND mg/kg 08/25/20 17:48 108-88-308/25/20 10:360.0045 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 17:48 87-61-608/25/20 10:360.0045 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 17:48 120-82-108/25/20 10:360.0045 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 17:48 71-55-608/25/20 10:360.0045 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 36 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-1 Lab ID:92492009010 Collected:08/19/20 12:05 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,1,2-Trichloroethane ND mg/kg 08/25/20 17:48 79-00-508/25/20 10:360.0045 1 Trichloroethene ND mg/kg 08/25/20 17:48 79-01-608/25/20 10:360.0045 1 Trichlorofluoromethane ND mg/kg 08/25/20 17:48 75-69-408/25/20 10:360.0045 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 17:48 96-18-408/25/20 10:360.0045 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 17:48 95-63-608/25/20 10:360.0045 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 17:48 108-67-808/25/20 10:360.0045 1 Vinyl acetate ND mg/kg 08/25/20 17:48 108-05-408/25/20 10:360.045 1 Vinyl chloride ND mg/kg 08/25/20 17:48 75-01-408/25/20 10:360.0091 1 Xylene (Total)ND mg/kg 08/25/20 17:48 1330-20-708/25/20 10:360.0091 1 m&p-Xylene ND mg/kg 08/25/20 17:48 179601-23-108/25/20 10:360.0091 1 o-Xylene ND mg/kg 08/25/20 17:48 95-47-608/25/20 10:360.0045 1 Surrogates Toluene-d8 (S)99 %08/25/20 17:48 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)102 %08/25/20 17:48 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)93 %08/25/20 17:48 17060-07-008/25/20 10:3670-132 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 6.3 %08/25/20 10:160.10 1 Sample:HA-2 Lab ID:92492009011 Collected:08/19/20 12:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 15:55 83-32-908/27/20 14:040.35 1 Acenaphthylene ND mg/kg 08/28/20 15:55 208-96-808/27/20 14:040.35 1 Aniline ND mg/kg 08/28/20 15:55 62-53-308/27/20 14:040.35 1 Anthracene ND mg/kg 08/28/20 15:55 120-12-708/27/20 14:040.35 1 Benzo(a)anthracene ND mg/kg 08/28/20 15:55 56-55-308/27/20 14:040.35 1 Benzo(a)pyrene ND mg/kg 08/28/20 15:55 50-32-808/27/20 14:040.35 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 15:55 205-99-208/27/20 14:040.35 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 15:55 191-24-208/27/20 14:040.35 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 15:55 207-08-908/27/20 14:040.35 1 Benzoic Acid ND mg/kg 08/28/20 15:55 65-85-008/27/20 14:041.8 1 Benzyl alcohol ND mg/kg 08/28/20 15:55 100-51-608/27/20 14:040.71 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 15:55 101-55-308/27/20 14:040.35 1 Butylbenzylphthalate ND mg/kg 08/28/20 15:55 85-68-708/27/20 14:040.35 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 15:55 59-50-708/27/20 14:040.71 1 4-Chloroaniline ND mg/kg 08/28/20 15:55 106-47-808/27/20 14:040.71 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 15:55 111-91-108/27/20 14:040.35 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 15:55 111-44-408/27/20 14:040.35 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 37 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-2 Lab ID:92492009011 Collected:08/19/20 12:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 2-Chloronaphthalene ND mg/kg 08/28/20 15:55 91-58-708/27/20 14:040.35 1 2-Chlorophenol ND mg/kg 08/28/20 15:55 95-57-808/27/20 14:040.35 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 15:55 7005-72-308/27/20 14:040.35 1 Chrysene ND mg/kg 08/28/20 15:55 218-01-908/27/20 14:040.35 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 15:55 53-70-308/27/20 14:040.35 1 Dibenzofuran ND mg/kg 08/28/20 15:55 132-64-908/27/20 14:040.35 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 15:55 95-50-108/27/20 14:040.35 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 15:55 541-73-108/27/20 14:040.35 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 15:55 106-46-708/27/20 14:040.35 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 15:55 91-94-108/27/20 14:040.71 1 2,4-Dichlorophenol ND mg/kg 08/28/20 15:55 120-83-208/27/20 14:040.35 1 Diethylphthalate ND mg/kg 08/28/20 15:55 84-66-208/27/20 14:040.35 1 2,4-Dimethylphenol ND mg/kg 08/28/20 15:55 105-67-908/27/20 14:040.35 1 Dimethylphthalate ND mg/kg 08/28/20 15:55 131-11-308/27/20 14:040.35 1 Di-n-butylphthalate ND mg/kg 08/28/20 15:55 84-74-208/27/20 14:040.35 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 15:55 534-52-108/27/20 14:040.71 1 2,4-Dinitrophenol ND mg/kg 08/28/20 15:55 51-28-5 v108/27/20 14:041.8 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 15:55 121-14-208/27/20 14:040.35 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 15:55 606-20-2 v208/27/20 14:040.35 1 Di-n-octylphthalate ND mg/kg 08/28/20 15:55 117-84-008/27/20 14:040.35 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 15:55 117-81-708/27/20 14:040.35 1 Fluoranthene ND mg/kg 08/28/20 15:55 206-44-008/27/20 14:040.35 1 Fluorene ND mg/kg 08/28/20 15:55 86-73-708/27/20 14:040.35 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 15:55 87-68-308/27/20 14:040.35 1 Hexachlorobenzene ND mg/kg 08/28/20 15:55 118-74-108/27/20 14:040.35 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 15:55 77-47-4 v208/27/20 14:040.35 1 Hexachloroethane ND mg/kg 08/28/20 15:55 67-72-108/27/20 14:040.35 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 15:55 193-39-508/27/20 14:040.35 1 Isophorone ND mg/kg 08/28/20 15:55 78-59-108/27/20 14:040.35 1 1-Methylnaphthalene ND mg/kg 08/28/20 15:55 90-12-008/27/20 14:040.35 1 2-Methylnaphthalene ND mg/kg 08/28/20 15:55 91-57-608/27/20 14:040.35 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 15:55 95-48-708/27/20 14:040.35 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 15:55 15831-10-408/27/20 14:040.35 1 Naphthalene ND mg/kg 08/28/20 15:55 91-20-308/27/20 14:040.35 1 2-Nitroaniline ND mg/kg 08/28/20 15:55 88-74-408/27/20 14:041.8 1 3-Nitroaniline ND mg/kg 08/28/20 15:55 99-09-208/27/20 14:041.8 1 4-Nitroaniline ND mg/kg 08/28/20 15:55 100-01-608/27/20 14:040.71 1 Nitrobenzene ND mg/kg 08/28/20 15:55 98-95-308/27/20 14:040.35 1 2-Nitrophenol ND mg/kg 08/28/20 15:55 88-75-508/27/20 14:040.35 1 4-Nitrophenol ND mg/kg 08/28/20 15:55 100-02-7 v208/27/20 14:041.8 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 15:55 62-75-908/27/20 14:040.35 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 15:55 621-64-708/27/20 14:040.35 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 15:55 86-30-608/27/20 14:040.35 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 15:55 108-60-108/27/20 14:040.35 1 Pentachlorophenol 8.7 mg/kg 08/28/20 16:30 87-86-508/27/20 14:043.5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 38 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-2 Lab ID:92492009011 Collected:08/19/20 12:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Phenanthrene ND mg/kg 08/28/20 15:55 85-01-808/27/20 14:040.35 1 Phenol ND mg/kg 08/28/20 15:55 108-95-208/27/20 14:040.35 1 Pyrene ND mg/kg 08/28/20 15:55 129-00-008/27/20 14:040.35 1 Pyridine ND mg/kg 08/28/20 15:55 110-86-108/27/20 14:040.35 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 15:55 120-82-108/27/20 14:040.35 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 15:55 95-95-408/27/20 14:040.35 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 15:55 88-06-208/27/20 14:040.35 1 Surrogates Nitrobenzene-d5 (S)38 %08/28/20 15:55 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)45 %08/28/20 15:55 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)67 %08/28/20 15:55 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)47 %08/28/20 15:55 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)45 %08/28/20 15:55 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)62 %08/28/20 15:55 118-79-608/27/20 14:0427-110 1 Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles Acetone ND mg/kg 08/25/20 18:06 67-64-108/25/20 10:360.095 1 Benzene ND mg/kg 08/25/20 18:06 71-43-208/25/20 10:360.0047 1 Bromobenzene ND mg/kg 08/25/20 18:06 108-86-108/25/20 10:360.0047 1 Bromochloromethane ND mg/kg 08/25/20 18:06 74-97-5 IK08/25/20 10:360.0047 1 Bromodichloromethane ND mg/kg 08/25/20 18:06 75-27-408/25/20 10:360.0047 1 Bromoform ND mg/kg 08/25/20 18:06 75-25-208/25/20 10:360.0047 1 Bromomethane ND mg/kg 08/25/20 18:06 74-83-9 v108/25/20 10:360.0095 1 2-Butanone (MEK)ND mg/kg 08/25/20 18:06 78-93-308/25/20 10:360.095 1 n-Butylbenzene ND mg/kg 08/25/20 18:06 104-51-808/25/20 10:360.0047 1 sec-Butylbenzene ND mg/kg 08/25/20 18:06 135-98-808/25/20 10:360.0047 1 tert-Butylbenzene ND mg/kg 08/25/20 18:06 98-06-608/25/20 10:360.0047 1 Carbon tetrachloride ND mg/kg 08/25/20 18:06 56-23-508/25/20 10:360.0047 1 Chlorobenzene ND mg/kg 08/25/20 18:06 108-90-708/25/20 10:360.0047 1 Chloroethane ND mg/kg 08/25/20 18:06 75-00-308/25/20 10:360.0095 1 Chloroform ND mg/kg 08/25/20 18:06 67-66-308/25/20 10:360.0047 1 Chloromethane ND mg/kg 08/25/20 18:06 74-87-3 v208/25/20 10:360.0095 1 2-Chlorotoluene ND mg/kg 08/25/20 18:06 95-49-808/25/20 10:360.0047 1 4-Chlorotoluene ND mg/kg 08/25/20 18:06 106-43-408/25/20 10:360.0047 1 1,2-Dibromo-3-chloropropane ND mg/kg 08/25/20 18:06 96-12-808/25/20 10:360.0047 1 Dibromochloromethane ND mg/kg 08/25/20 18:06 124-48-108/25/20 10:360.0047 1 1,2-Dibromoethane (EDB)ND mg/kg 08/25/20 18:06 106-93-408/25/20 10:360.0047 1 Dibromomethane ND mg/kg 08/25/20 18:06 74-95-308/25/20 10:360.0047 1 1,2-Dichlorobenzene ND mg/kg 08/25/20 18:06 95-50-108/25/20 10:360.0047 1 1,3-Dichlorobenzene ND mg/kg 08/25/20 18:06 541-73-108/25/20 10:360.0047 1 1,4-Dichlorobenzene ND mg/kg 08/25/20 18:06 106-46-708/25/20 10:360.0047 1 Dichlorodifluoromethane ND mg/kg 08/25/20 18:06 75-71-808/25/20 10:360.0095 1 1,1-Dichloroethane ND mg/kg 08/25/20 18:06 75-34-308/25/20 10:360.0047 1 1,2-Dichloroethane ND mg/kg 08/25/20 18:06 107-06-208/25/20 10:360.0047 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 39 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-2 Lab ID:92492009011 Collected:08/19/20 12:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B Pace Analytical Services - Charlotte 8260D/5035A/5030B Volatiles 1,1-Dichloroethene ND mg/kg 08/25/20 18:06 75-35-408/25/20 10:360.0047 1 cis-1,2-Dichloroethene ND mg/kg 08/25/20 18:06 156-59-208/25/20 10:360.0047 1 trans-1,2-Dichloroethene ND mg/kg 08/25/20 18:06 156-60-508/25/20 10:360.0047 1 1,2-Dichloropropane ND mg/kg 08/25/20 18:06 78-87-508/25/20 10:360.0047 1 1,3-Dichloropropane ND mg/kg 08/25/20 18:06 142-28-908/25/20 10:360.0047 1 2,2-Dichloropropane ND mg/kg 08/25/20 18:06 594-20-708/25/20 10:360.0047 1 1,1-Dichloropropene ND mg/kg 08/25/20 18:06 563-58-608/25/20 10:360.0047 1 cis-1,3-Dichloropropene ND mg/kg 08/25/20 18:06 10061-01-508/25/20 10:360.0047 1 trans-1,3-Dichloropropene ND mg/kg 08/25/20 18:06 10061-02-608/25/20 10:360.0047 1 Diisopropyl ether ND mg/kg 08/25/20 18:06 108-20-308/25/20 10:360.0047 1 Ethylbenzene ND mg/kg 08/25/20 18:06 100-41-408/25/20 10:360.0047 1 Hexachloro-1,3-butadiene ND mg/kg 08/25/20 18:06 87-68-308/25/20 10:360.0047 1 2-Hexanone ND mg/kg 08/25/20 18:06 591-78-608/25/20 10:360.047 1 Isopropylbenzene (Cumene)ND mg/kg 08/25/20 18:06 98-82-808/25/20 10:360.0047 1 p-Isopropyltoluene ND mg/kg 08/25/20 18:06 99-87-608/25/20 10:360.0047 1 Methylene Chloride ND mg/kg 08/25/20 18:06 75-09-208/25/20 10:360.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/25/20 18:06 108-10-108/25/20 10:360.047 1 Methyl-tert-butyl ether ND mg/kg 08/25/20 18:06 1634-04-408/25/20 10:360.0047 1 Naphthalene ND mg/kg 08/25/20 18:06 91-20-308/25/20 10:360.0047 1 n-Propylbenzene ND mg/kg 08/25/20 18:06 103-65-108/25/20 10:360.0047 1 Styrene ND mg/kg 08/25/20 18:06 100-42-508/25/20 10:360.0047 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/25/20 18:06 630-20-608/25/20 10:360.0047 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/25/20 18:06 79-34-508/25/20 10:360.0047 1 Tetrachloroethene ND mg/kg 08/25/20 18:06 127-18-408/25/20 10:360.0047 1 Toluene ND mg/kg 08/25/20 18:06 108-88-308/25/20 10:360.0047 1 1,2,3-Trichlorobenzene ND mg/kg 08/25/20 18:06 87-61-608/25/20 10:360.0047 1 1,2,4-Trichlorobenzene ND mg/kg 08/25/20 18:06 120-82-108/25/20 10:360.0047 1 1,1,1-Trichloroethane ND mg/kg 08/25/20 18:06 71-55-608/25/20 10:360.0047 1 1,1,2-Trichloroethane ND mg/kg 08/25/20 18:06 79-00-508/25/20 10:360.0047 1 Trichloroethene ND mg/kg 08/25/20 18:06 79-01-608/25/20 10:360.0047 1 Trichlorofluoromethane ND mg/kg 08/25/20 18:06 75-69-408/25/20 10:360.0047 1 1,2,3-Trichloropropane ND mg/kg 08/25/20 18:06 96-18-408/25/20 10:360.0047 1 1,2,4-Trimethylbenzene ND mg/kg 08/25/20 18:06 95-63-608/25/20 10:360.0047 1 1,3,5-Trimethylbenzene ND mg/kg 08/25/20 18:06 108-67-808/25/20 10:360.0047 1 Vinyl acetate ND mg/kg 08/25/20 18:06 108-05-408/25/20 10:360.047 1 Vinyl chloride ND mg/kg 08/25/20 18:06 75-01-408/25/20 10:360.0095 1 Xylene (Total)ND mg/kg 08/25/20 18:06 1330-20-708/25/20 10:360.0095 1 m&p-Xylene ND mg/kg 08/25/20 18:06 179601-23-108/25/20 10:360.0095 1 o-Xylene ND mg/kg 08/25/20 18:06 95-47-608/25/20 10:360.0047 1 Surrogates Toluene-d8 (S)99 %08/25/20 18:06 2037-26-508/25/20 10:3670-130 1 4-Bromofluorobenzene (S)100 %08/25/20 18:06 460-00-408/25/20 10:3670-130 1 1,2-Dichloroethane-d4 (S)91 %08/25/20 18:06 17060-07-008/25/20 10:3670-132 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 40 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:HA-2 Lab ID:92492009011 Collected:08/19/20 12:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 5.4 %08/25/20 10:170.10 1 Sample:GW-1 Lab ID:92492009012 Collected:08/19/20 10:05 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 08/26/20 18:48 83-32-908/25/20 23:0610.0 1 Acenaphthylene ND ug/L 08/26/20 18:48 208-96-808/25/20 23:0610.0 1 Aniline ND ug/L 08/26/20 18:48 62-53-308/25/20 23:0610.0 1 Anthracene ND ug/L 08/26/20 18:48 120-12-708/25/20 23:0610.0 1 Benzo(a)anthracene ND ug/L 08/26/20 18:48 56-55-308/25/20 23:0610.0 1 Benzo(a)pyrene ND ug/L 08/26/20 18:48 50-32-808/25/20 23:0610.0 1 Benzo(b)fluoranthene ND ug/L 08/26/20 18:48 205-99-208/25/20 23:0610.0 1 Benzo(g,h,i)perylene ND ug/L 08/26/20 18:48 191-24-208/25/20 23:0610.0 1 Benzo(k)fluoranthene ND ug/L 08/26/20 18:48 207-08-908/25/20 23:0610.0 1 Benzoic Acid ND ug/L 08/26/20 18:48 65-85-008/25/20 23:0650.0 1 Benzyl alcohol ND ug/L 08/26/20 18:48 100-51-608/25/20 23:0620.0 1 4-Bromophenylphenyl ether ND ug/L 08/26/20 18:48 101-55-308/25/20 23:0610.0 1 Butylbenzylphthalate ND ug/L 08/26/20 18:48 85-68-708/25/20 23:0610.0 1 4-Chloro-3-methylphenol ND ug/L 08/26/20 18:48 59-50-708/25/20 23:0610.0 1 4-Chloroaniline ND ug/L 08/26/20 18:48 106-47-808/25/20 23:0620.0 1 bis(2-Chloroethoxy)methane ND ug/L 08/26/20 18:48 111-91-108/25/20 23:0610.0 1 bis(2-Chloroethyl) ether ND ug/L 08/26/20 18:48 111-44-408/25/20 23:0610.0 1 2-Chloronaphthalene ND ug/L 08/26/20 18:48 91-58-708/25/20 23:0610.0 1 2-Chlorophenol ND ug/L 08/26/20 18:48 95-57-808/25/20 23:0610.0 1 4-Chlorophenylphenyl ether ND ug/L 08/26/20 18:48 7005-72-308/25/20 23:0610.0 1 Chrysene ND ug/L 08/26/20 18:48 218-01-908/25/20 23:0610.0 1 Dibenz(a,h)anthracene ND ug/L 08/26/20 18:48 53-70-308/25/20 23:0610.0 1 Dibenzofuran ND ug/L 08/26/20 18:48 132-64-908/25/20 23:0610.0 1 1,2-Dichlorobenzene ND ug/L 08/26/20 18:48 95-50-108/25/20 23:0610.0 1 1,3-Dichlorobenzene ND ug/L 08/26/20 18:48 541-73-108/25/20 23:0610.0 1 1,4-Dichlorobenzene ND ug/L 08/26/20 18:48 106-46-708/25/20 23:0610.0 1 3,3'-Dichlorobenzidine ND ug/L 08/26/20 18:48 91-94-108/25/20 23:0620.0 1 2,4-Dichlorophenol ND ug/L 08/26/20 18:48 120-83-208/25/20 23:0610.0 1 Diethylphthalate ND ug/L 08/26/20 18:48 84-66-208/25/20 23:0610.0 1 2,4-Dimethylphenol ND ug/L 08/26/20 18:48 105-67-908/25/20 23:0610.0 1 Dimethylphthalate ND ug/L 08/26/20 18:48 131-11-308/25/20 23:0610.0 1 Di-n-butylphthalate ND ug/L 08/26/20 18:48 84-74-208/25/20 23:0610.0 1 4,6-Dinitro-2-methylphenol ND ug/L 08/26/20 18:48 534-52-108/25/20 23:0620.0 1 2,4-Dinitrophenol ND ug/L 08/26/20 18:48 51-28-508/25/20 23:0650.0 1 2,4-Dinitrotoluene ND ug/L 08/26/20 18:48 121-14-208/25/20 23:0610.0 1 2,6-Dinitrotoluene ND ug/L 08/26/20 18:48 606-20-208/25/20 23:0610.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 41 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-1 Lab ID:92492009012 Collected:08/19/20 10:05 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Di-n-octylphthalate ND ug/L 08/26/20 18:48 117-84-008/25/20 23:0610.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 08/26/20 18:48 117-81-708/25/20 23:066.0 1 Fluoranthene ND ug/L 08/26/20 18:48 206-44-008/25/20 23:0610.0 1 Fluorene ND ug/L 08/26/20 18:48 86-73-708/25/20 23:0610.0 1 Hexachloro-1,3-butadiene ND ug/L 08/26/20 18:48 87-68-308/25/20 23:0610.0 1 Hexachlorobenzene ND ug/L 08/26/20 18:48 118-74-108/25/20 23:0610.0 1 Hexachlorocyclopentadiene ND ug/L 08/26/20 18:48 77-47-408/25/20 23:0610.0 1 Hexachloroethane ND ug/L 08/26/20 18:48 67-72-108/25/20 23:0610.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 08/26/20 18:48 193-39-508/25/20 23:0610.0 1 Isophorone ND ug/L 08/26/20 18:48 78-59-108/25/20 23:0610.0 1 1-Methylnaphthalene ND ug/L 08/26/20 18:48 90-12-008/25/20 23:0610.0 1 2-Methylnaphthalene ND ug/L 08/26/20 18:48 91-57-608/25/20 23:0610.0 1 2-Methylphenol(o-Cresol)ND ug/L 08/26/20 18:48 95-48-708/25/20 23:0610.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 08/26/20 18:48 15831-10-408/25/20 23:0610.0 1 Naphthalene ND ug/L 08/26/20 18:48 91-20-308/25/20 23:0610.0 1 2-Nitroaniline ND ug/L 08/26/20 18:48 88-74-408/25/20 23:0620.0 1 3-Nitroaniline ND ug/L 08/26/20 18:48 99-09-208/25/20 23:0620.0 1 4-Nitroaniline ND ug/L 08/26/20 18:48 100-01-608/25/20 23:0620.0 1 Nitrobenzene ND ug/L 08/26/20 18:48 98-95-308/25/20 23:0610.0 1 2-Nitrophenol ND ug/L 08/26/20 18:48 88-75-508/25/20 23:0610.0 1 4-Nitrophenol ND ug/L 08/26/20 18:48 100-02-708/25/20 23:0650.0 1 N-Nitrosodimethylamine ND ug/L 08/26/20 18:48 62-75-908/25/20 23:0610.0 1 N-Nitroso-di-n-propylamine ND ug/L 08/26/20 18:48 621-64-708/25/20 23:0610.0 1 N-Nitrosodiphenylamine ND ug/L 08/26/20 18:48 86-30-608/25/20 23:0610.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 08/26/20 18:48 108-60-1 v108/25/20 23:0610.0 1 Pentachlorophenol ND ug/L 08/26/20 18:48 87-86-508/25/20 23:0620.0 1 Phenanthrene ND ug/L 08/26/20 18:48 85-01-808/25/20 23:0610.0 1 Phenol ND ug/L 08/26/20 18:48 108-95-208/25/20 23:0610.0 1 Pyrene ND ug/L 08/26/20 18:48 129-00-008/25/20 23:0610.0 1 1,2,4-Trichlorobenzene ND ug/L 08/26/20 18:48 120-82-108/25/20 23:0610.0 1 2,4,5-Trichlorophenol ND ug/L 08/26/20 18:48 95-95-408/25/20 23:0610.0 1 2,4,6-Trichlorophenol ND ug/L 08/26/20 18:48 88-06-208/25/20 23:0610.0 1 Surrogates Nitrobenzene-d5 (S)84 %08/26/20 18:48 4165-60-008/25/20 23:0613-130 1 2-Fluorobiphenyl (S)86 %08/26/20 18:48 321-60-808/25/20 23:0613-130 1 Terphenyl-d14 (S)132 %08/26/20 18:48 1718-51-0 S308/25/20 23:0625-130 1 Phenol-d6 (S)41 %08/26/20 18:48 13127-88-308/25/20 23:0610-130 1 2-Fluorophenol (S)37 %08/26/20 18:48 367-12-408/25/20 23:0610-130 1 2,4,6-Tribromophenol (S)55 %08/26/20 18:48 118-79-608/25/20 23:0610-137 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 08/25/20 23:35 67-64-125.0 1 Benzene ND ug/L 08/25/20 23:35 71-43-21.0 1 Bromobenzene ND ug/L 08/25/20 23:35 108-86-11.0 1 Bromochloromethane ND ug/L 08/25/20 23:35 74-97-51.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 42 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-1 Lab ID:92492009012 Collected:08/19/20 10:05 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Bromodichloromethane ND ug/L 08/25/20 23:35 75-27-41.0 1 Bromoform ND ug/L 08/25/20 23:35 75-25-21.0 1 Bromomethane ND ug/L 08/25/20 23:35 74-83-92.0 1 2-Butanone (MEK)ND ug/L 08/25/20 23:35 78-93-35.0 1 Carbon tetrachloride ND ug/L 08/25/20 23:35 56-23-51.0 1 Chlorobenzene ND ug/L 08/25/20 23:35 108-90-71.0 1 Chloroethane ND ug/L 08/25/20 23:35 75-00-31.0 1 Chloroform ND ug/L 08/25/20 23:35 67-66-35.0 1 Chloromethane ND ug/L 08/25/20 23:35 74-87-31.0 1 2-Chlorotoluene ND ug/L 08/25/20 23:35 95-49-81.0 1 4-Chlorotoluene ND ug/L 08/25/20 23:35 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 08/25/20 23:35 96-12-85.0 1 Dibromochloromethane ND ug/L 08/25/20 23:35 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/25/20 23:35 106-93-41.0 1 Dibromomethane ND ug/L 08/25/20 23:35 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 08/25/20 23:35 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 08/25/20 23:35 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 08/25/20 23:35 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 08/25/20 23:35 75-71-81.0 1 1,1-Dichloroethane ND ug/L 08/25/20 23:35 75-34-31.0 1 1,2-Dichloroethane ND ug/L 08/25/20 23:35 107-06-21.0 1 1,1-Dichloroethene ND ug/L 08/25/20 23:35 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 08/25/20 23:35 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 08/25/20 23:35 156-60-51.0 1 1,2-Dichloropropane ND ug/L 08/25/20 23:35 78-87-51.0 1 1,3-Dichloropropane ND ug/L 08/25/20 23:35 142-28-91.0 1 2,2-Dichloropropane ND ug/L 08/25/20 23:35 594-20-71.0 1 1,1-Dichloropropene ND ug/L 08/25/20 23:35 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 08/25/20 23:35 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 08/25/20 23:35 10061-02-61.0 1 Diisopropyl ether 6.9 ug/L 08/25/20 23:35 108-20-31.0 1 Ethylbenzene ND ug/L 08/25/20 23:35 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 08/25/20 23:35 87-68-31.0 1 2-Hexanone ND ug/L 08/25/20 23:35 591-78-65.0 1 p-Isopropyltoluene ND ug/L 08/25/20 23:35 99-87-61.0 1 Methylene Chloride ND ug/L 08/25/20 23:35 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/25/20 23:35 108-10-15.0 1 Methyl-tert-butyl ether 9.9 ug/L 08/25/20 23:35 1634-04-41.0 1 Naphthalene ND ug/L 08/25/20 23:35 91-20-31.0 1 Styrene ND ug/L 08/25/20 23:35 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/25/20 23:35 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/25/20 23:35 79-34-51.0 1 Tetrachloroethene ND ug/L 08/25/20 23:35 127-18-41.0 1 Toluene ND ug/L 08/25/20 23:35 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 08/25/20 23:35 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 08/25/20 23:35 120-82-11.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 43 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-1 Lab ID:92492009012 Collected:08/19/20 10:05 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level 1,1,1-Trichloroethane ND ug/L 08/25/20 23:35 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 08/25/20 23:35 79-00-51.0 1 Trichloroethene ND ug/L 08/25/20 23:35 79-01-61.0 1 Trichlorofluoromethane ND ug/L 08/25/20 23:35 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 08/25/20 23:35 96-18-41.0 1 Vinyl acetate ND ug/L 08/25/20 23:35 108-05-42.0 1 Vinyl chloride ND ug/L 08/25/20 23:35 75-01-41.0 1 Xylene (Total)ND ug/L 08/25/20 23:35 1330-20-71.0 1 m&p-Xylene ND ug/L 08/25/20 23:35 179601-23-12.0 1 o-Xylene ND ug/L 08/25/20 23:35 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)95 %08/25/20 23:35 460-00-470-130 1 1,2-Dichloroethane-d4 (S)108 %08/25/20 23:35 17060-07-070-130 1 Toluene-d8 (S)99 %08/25/20 23:35 2037-26-570-130 1 Sample:GW-2 Lab ID:92492009013 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 08/26/20 18:38 83-32-908/26/20 09:3910.0 1 Acenaphthylene ND ug/L 08/26/20 18:38 208-96-808/26/20 09:3910.0 1 Aniline ND ug/L 08/26/20 18:38 62-53-308/26/20 09:3910.0 1 Anthracene ND ug/L 08/26/20 18:38 120-12-708/26/20 09:3910.0 1 Benzo(a)anthracene ND ug/L 08/26/20 18:38 56-55-308/26/20 09:3910.0 1 Benzo(a)pyrene ND ug/L 08/26/20 18:38 50-32-808/26/20 09:3910.0 1 Benzo(b)fluoranthene ND ug/L 08/26/20 18:38 205-99-208/26/20 09:3910.0 1 Benzo(g,h,i)perylene ND ug/L 08/26/20 18:38 191-24-208/26/20 09:3910.0 1 Benzo(k)fluoranthene ND ug/L 08/26/20 18:38 207-08-908/26/20 09:3910.0 1 Benzoic Acid ND ug/L 08/26/20 18:38 65-85-008/26/20 09:3950.0 1 Benzyl alcohol ND ug/L 08/26/20 18:38 100-51-608/26/20 09:3920.0 1 4-Bromophenylphenyl ether ND ug/L 08/26/20 18:38 101-55-308/26/20 09:3910.0 1 Butylbenzylphthalate ND ug/L 08/26/20 18:38 85-68-708/26/20 09:3910.0 1 4-Chloro-3-methylphenol ND ug/L 08/26/20 18:38 59-50-708/26/20 09:3910.0 1 4-Chloroaniline ND ug/L 08/26/20 18:38 106-47-808/26/20 09:3920.0 1 bis(2-Chloroethoxy)methane ND ug/L 08/26/20 18:38 111-91-108/26/20 09:3910.0 1 bis(2-Chloroethyl) ether ND ug/L 08/26/20 18:38 111-44-408/26/20 09:3910.0 1 2-Chloronaphthalene ND ug/L 08/26/20 18:38 91-58-708/26/20 09:3910.0 1 2-Chlorophenol ND ug/L 08/26/20 18:38 95-57-808/26/20 09:3910.0 1 4-Chlorophenylphenyl ether ND ug/L 08/26/20 18:38 7005-72-308/26/20 09:3910.0 1 Chrysene ND ug/L 08/26/20 18:38 218-01-908/26/20 09:3910.0 1 Dibenz(a,h)anthracene ND ug/L 08/26/20 18:38 53-70-308/26/20 09:3910.0 1 Dibenzofuran ND ug/L 08/26/20 18:38 132-64-908/26/20 09:3910.0 1 1,2-Dichlorobenzene ND ug/L 08/26/20 18:38 95-50-108/26/20 09:3910.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 44 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-2 Lab ID:92492009013 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE 1,3-Dichlorobenzene ND ug/L 08/26/20 18:38 541-73-108/26/20 09:3910.0 1 1,4-Dichlorobenzene ND ug/L 08/26/20 18:38 106-46-708/26/20 09:3910.0 1 3,3'-Dichlorobenzidine ND ug/L 08/26/20 18:38 91-94-108/26/20 09:3920.0 1 2,4-Dichlorophenol ND ug/L 08/26/20 18:38 120-83-208/26/20 09:3910.0 1 Diethylphthalate ND ug/L 08/26/20 18:38 84-66-208/26/20 09:3910.0 1 2,4-Dimethylphenol ND ug/L 08/26/20 18:38 105-67-908/26/20 09:3910.0 1 Dimethylphthalate ND ug/L 08/26/20 18:38 131-11-308/26/20 09:3910.0 1 Di-n-butylphthalate ND ug/L 08/26/20 18:38 84-74-208/26/20 09:3910.0 1 4,6-Dinitro-2-methylphenol ND ug/L 08/26/20 18:38 534-52-108/26/20 09:3920.0 1 2,4-Dinitrophenol ND ug/L 08/26/20 18:38 51-28-508/26/20 09:3950.0 1 2,4-Dinitrotoluene ND ug/L 08/26/20 18:38 121-14-208/26/20 09:3910.0 1 2,6-Dinitrotoluene ND ug/L 08/26/20 18:38 606-20-208/26/20 09:3910.0 1 Di-n-octylphthalate ND ug/L 08/26/20 18:38 117-84-008/26/20 09:3910.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 08/26/20 18:38 117-81-708/26/20 09:396.0 1 Fluoranthene ND ug/L 08/26/20 18:38 206-44-008/26/20 09:3910.0 1 Fluorene ND ug/L 08/26/20 18:38 86-73-708/26/20 09:3910.0 1 Hexachloro-1,3-butadiene ND ug/L 08/26/20 18:38 87-68-308/26/20 09:3910.0 1 Hexachlorobenzene ND ug/L 08/26/20 18:38 118-74-108/26/20 09:3910.0 1 Hexachlorocyclopentadiene ND ug/L 08/26/20 18:38 77-47-408/26/20 09:3910.0 1 Hexachloroethane ND ug/L 08/26/20 18:38 67-72-108/26/20 09:3910.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 08/26/20 18:38 193-39-508/26/20 09:3910.0 1 Isophorone ND ug/L 08/26/20 18:38 78-59-108/26/20 09:3910.0 1 1-Methylnaphthalene ND ug/L 08/26/20 18:38 90-12-008/26/20 09:3910.0 1 2-Methylnaphthalene ND ug/L 08/26/20 18:38 91-57-608/26/20 09:3910.0 1 2-Methylphenol(o-Cresol)ND ug/L 08/26/20 18:38 95-48-708/26/20 09:3910.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 08/26/20 18:38 15831-10-408/26/20 09:3910.0 1 Naphthalene ND ug/L 08/26/20 18:38 91-20-308/26/20 09:3910.0 1 2-Nitroaniline ND ug/L 08/26/20 18:38 88-74-408/26/20 09:3920.0 1 3-Nitroaniline ND ug/L 08/26/20 18:38 99-09-208/26/20 09:3920.0 1 4-Nitroaniline ND ug/L 08/26/20 18:38 100-01-608/26/20 09:3920.0 1 Nitrobenzene ND ug/L 08/26/20 18:38 98-95-308/26/20 09:3910.0 1 2-Nitrophenol ND ug/L 08/26/20 18:38 88-75-508/26/20 09:3910.0 1 4-Nitrophenol ND ug/L 08/26/20 18:38 100-02-708/26/20 09:3950.0 1 N-Nitrosodimethylamine ND ug/L 08/26/20 18:38 62-75-908/26/20 09:3910.0 1 N-Nitroso-di-n-propylamine ND ug/L 08/26/20 18:38 621-64-708/26/20 09:3910.0 1 N-Nitrosodiphenylamine ND ug/L 08/26/20 18:38 86-30-608/26/20 09:3910.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 08/26/20 18:38 108-60-108/26/20 09:3910.0 1 Pentachlorophenol ND ug/L 08/26/20 18:38 87-86-508/26/20 09:3920.0 1 Phenanthrene ND ug/L 08/26/20 18:38 85-01-808/26/20 09:3910.0 1 Phenol ND ug/L 08/26/20 18:38 108-95-208/26/20 09:3910.0 1 Pyrene ND ug/L 08/26/20 18:38 129-00-008/26/20 09:3910.0 1 1,2,4-Trichlorobenzene ND ug/L 08/26/20 18:38 120-82-108/26/20 09:3910.0 1 2,4,5-Trichlorophenol ND ug/L 08/26/20 18:38 95-95-408/26/20 09:3910.0 1 2,4,6-Trichlorophenol ND ug/L 08/26/20 18:38 88-06-208/26/20 09:3910.0 1 Surrogates Nitrobenzene-d5 (S)34 %08/26/20 18:38 4165-60-008/26/20 09:3913-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 45 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-2 Lab ID:92492009013 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Surrogates 2-Fluorobiphenyl (S)20 %08/26/20 18:38 321-60-808/26/20 09:3913-130 1 Terphenyl-d14 (S)88 %08/26/20 18:38 1718-51-008/26/20 09:3925-130 1 Phenol-d6 (S)19 %08/26/20 18:38 13127-88-308/26/20 09:3910-130 1 2-Fluorophenol (S)24 %08/26/20 18:38 367-12-408/26/20 09:3910-130 1 2,4,6-Tribromophenol (S)59 %08/26/20 18:38 118-79-608/26/20 09:3910-137 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone 39.4 ug/L 08/25/20 23:17 67-64-125.0 1 Benzene ND ug/L 08/25/20 23:17 71-43-21.0 1 Bromobenzene ND ug/L 08/25/20 23:17 108-86-11.0 1 Bromochloromethane ND ug/L 08/25/20 23:17 74-97-51.0 1 Bromodichloromethane ND ug/L 08/25/20 23:17 75-27-41.0 1 Bromoform ND ug/L 08/25/20 23:17 75-25-21.0 1 Bromomethane ND ug/L 08/25/20 23:17 74-83-92.0 1 2-Butanone (MEK)11.4 ug/L 08/25/20 23:17 78-93-35.0 1 Carbon tetrachloride ND ug/L 08/25/20 23:17 56-23-51.0 1 Chlorobenzene ND ug/L 08/25/20 23:17 108-90-71.0 1 Chloroethane ND ug/L 08/25/20 23:17 75-00-31.0 1 Chloroform ND ug/L 08/25/20 23:17 67-66-35.0 1 Chloromethane ND ug/L 08/25/20 23:17 74-87-31.0 1 2-Chlorotoluene ND ug/L 08/25/20 23:17 95-49-81.0 1 4-Chlorotoluene ND ug/L 08/25/20 23:17 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 08/25/20 23:17 96-12-85.0 1 Dibromochloromethane ND ug/L 08/25/20 23:17 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/25/20 23:17 106-93-41.0 1 Dibromomethane ND ug/L 08/25/20 23:17 74-95-31.0 1 1,2-Dichlorobenzene ND ug/L 08/25/20 23:17 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 08/25/20 23:17 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 08/25/20 23:17 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 08/25/20 23:17 75-71-81.0 1 1,1-Dichloroethane ND ug/L 08/25/20 23:17 75-34-31.0 1 1,2-Dichloroethane ND ug/L 08/25/20 23:17 107-06-21.0 1 1,1-Dichloroethene ND ug/L 08/25/20 23:17 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 08/25/20 23:17 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 08/25/20 23:17 156-60-51.0 1 1,2-Dichloropropane ND ug/L 08/25/20 23:17 78-87-51.0 1 1,3-Dichloropropane ND ug/L 08/25/20 23:17 142-28-91.0 1 2,2-Dichloropropane ND ug/L 08/25/20 23:17 594-20-71.0 1 1,1-Dichloropropene ND ug/L 08/25/20 23:17 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 08/25/20 23:17 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 08/25/20 23:17 10061-02-61.0 1 Diisopropyl ether ND ug/L 08/25/20 23:17 108-20-31.0 1 Ethylbenzene ND ug/L 08/25/20 23:17 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 08/25/20 23:17 87-68-31.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 46 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:GW-2 Lab ID:92492009013 Collected:08/19/20 10:30 Received:08/21/20 10:00 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level 2-Hexanone ND ug/L 08/25/20 23:17 591-78-65.0 1 p-Isopropyltoluene 2.0 ug/L 08/25/20 23:17 99-87-61.0 1 Methylene Chloride ND ug/L 08/25/20 23:17 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/25/20 23:17 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 08/25/20 23:17 1634-04-41.0 1 Naphthalene 4.0 ug/L 08/25/20 23:17 91-20-31.0 1 Styrene ND ug/L 08/25/20 23:17 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/25/20 23:17 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/25/20 23:17 79-34-51.0 1 Tetrachloroethene ND ug/L 08/25/20 23:17 127-18-41.0 1 Toluene ND ug/L 08/25/20 23:17 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 08/25/20 23:17 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 08/25/20 23:17 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 08/25/20 23:17 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 08/25/20 23:17 79-00-51.0 1 Trichloroethene ND ug/L 08/25/20 23:17 79-01-61.0 1 Trichlorofluoromethane ND ug/L 08/25/20 23:17 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 08/25/20 23:17 96-18-41.0 1 Vinyl acetate ND ug/L 08/25/20 23:17 108-05-42.0 1 Vinyl chloride ND ug/L 08/25/20 23:17 75-01-41.0 1 Xylene (Total)1.6 ug/L 08/25/20 23:17 1330-20-71.0 1 m&p-Xylene ND ug/L 08/25/20 23:17 179601-23-12.0 1 o-Xylene 1.6 ug/L 08/25/20 23:17 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)96 %08/25/20 23:17 460-00-470-130 1 1,2-Dichloroethane-d4 (S)106 %08/25/20 23:17 17060-07-070-130 1 Toluene-d8 (S)96 %08/25/20 23:17 2037-26-570-130 1 Sample:T-1 Lab ID:92492009014 Collected:08/13/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: MADEP EPH Preparation Method: MADEP EPH Pace Analytical Services - Charlotte MADEP EPH NC Soil Aliphatic (C09-C18)ND mg/kg 08/27/20 09:16 N208/25/20 16:0935.7 2.5 Aliphatic (C19-C36)144 mg/kg 08/27/20 09:16 N208/25/20 16:0935.7 2.5 Aromatic (C11-C22)16.0 mg/kg 08/26/20 16:22 N208/25/20 16:0914.3 1 Surrogates 1-Chlorooctadecane (S)102 %08/27/20 09:16 3386-33-208/25/20 16:0940-140 2.5 o-Terphenyl (S)69 %08/26/20 16:22 84-15-108/25/20 16:0940-140 1 2-Fluorobiphenyl (S)94 %08/26/20 16:22 321-60-808/25/20 16:0940-140 1 2-Bromonaphthalene (S)95 %08/26/20 16:22 580-13-208/25/20 16:0940-140 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 47 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:T-1 Lab ID:92492009014 Collected:08/13/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 14:35 83-32-908/27/20 14:040.46 1 Acenaphthylene ND mg/kg 08/28/20 14:35 208-96-808/27/20 14:040.46 1 Aniline ND mg/kg 08/28/20 14:35 62-53-308/27/20 14:040.46 1 Anthracene ND mg/kg 08/28/20 14:35 120-12-708/27/20 14:040.46 1 Benzo(a)anthracene ND mg/kg 08/28/20 14:35 56-55-308/27/20 14:040.46 1 Benzo(a)pyrene ND mg/kg 08/28/20 14:35 50-32-808/27/20 14:040.46 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 14:35 205-99-208/27/20 14:040.46 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 14:35 191-24-208/27/20 14:040.46 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 14:35 207-08-908/27/20 14:040.46 1 Benzoic Acid ND mg/kg 08/28/20 14:35 65-85-008/27/20 14:042.3 1 Benzyl alcohol ND mg/kg 08/28/20 14:35 100-51-608/27/20 14:040.92 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 14:35 101-55-308/27/20 14:040.46 1 Butylbenzylphthalate ND mg/kg 08/28/20 14:35 85-68-708/27/20 14:040.46 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 14:35 59-50-708/27/20 14:040.92 1 4-Chloroaniline ND mg/kg 08/28/20 14:35 106-47-808/27/20 14:040.92 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 14:35 111-91-108/27/20 14:040.46 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 14:35 111-44-408/27/20 14:040.46 1 2-Chloronaphthalene ND mg/kg 08/28/20 14:35 91-58-708/27/20 14:040.46 1 2-Chlorophenol ND mg/kg 08/28/20 14:35 95-57-808/27/20 14:040.46 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 14:35 7005-72-308/27/20 14:040.46 1 Chrysene ND mg/kg 08/28/20 14:35 218-01-908/27/20 14:040.46 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 14:35 53-70-308/27/20 14:040.46 1 Dibenzofuran ND mg/kg 08/28/20 14:35 132-64-908/27/20 14:040.46 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 14:35 95-50-108/27/20 14:040.46 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 14:35 541-73-108/27/20 14:040.46 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 14:35 106-46-708/27/20 14:040.46 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 14:35 91-94-108/27/20 14:040.92 1 2,4-Dichlorophenol ND mg/kg 08/28/20 14:35 120-83-208/27/20 14:040.46 1 Diethylphthalate ND mg/kg 08/28/20 14:35 84-66-208/27/20 14:040.46 1 2,4-Dimethylphenol ND mg/kg 08/28/20 14:35 105-67-908/27/20 14:040.46 1 Dimethylphthalate ND mg/kg 08/28/20 14:35 131-11-308/27/20 14:040.46 1 Di-n-butylphthalate ND mg/kg 08/28/20 14:35 84-74-208/27/20 14:040.46 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 14:35 534-52-108/27/20 14:040.92 1 2,4-Dinitrophenol ND mg/kg 08/28/20 14:35 51-28-508/27/20 14:042.3 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 14:35 121-14-208/27/20 14:040.46 1 2,6-Dinitrotoluene ND mg/kg 08/28/20 14:35 606-20-208/27/20 14:040.46 1 Di-n-octylphthalate ND mg/kg 08/28/20 14:35 117-84-008/27/20 14:040.46 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 14:35 117-81-708/27/20 14:040.46 1 Fluoranthene ND mg/kg 08/28/20 14:35 206-44-008/27/20 14:040.46 1 Fluorene ND mg/kg 08/28/20 14:35 86-73-708/27/20 14:040.46 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 14:35 87-68-308/27/20 14:040.46 1 Hexachlorobenzene ND mg/kg 08/28/20 14:35 118-74-108/27/20 14:040.46 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 14:35 77-47-4 v208/27/20 14:040.46 1 Hexachloroethane ND mg/kg 08/28/20 14:35 67-72-108/27/20 14:040.46 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 14:35 193-39-508/27/20 14:040.46 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 48 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:T-1 Lab ID:92492009014 Collected:08/13/20 10:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 08/28/20 14:35 78-59-108/27/20 14:040.46 1 1-Methylnaphthalene ND mg/kg 08/28/20 14:35 90-12-008/27/20 14:040.46 1 2-Methylnaphthalene ND mg/kg 08/28/20 14:35 91-57-608/27/20 14:040.46 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 14:35 95-48-708/27/20 14:040.46 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 14:35 15831-10-408/27/20 14:040.46 1 Naphthalene ND mg/kg 08/28/20 14:35 91-20-308/27/20 14:040.46 1 2-Nitroaniline ND mg/kg 08/28/20 14:35 88-74-4 v208/27/20 14:042.3 1 3-Nitroaniline ND mg/kg 08/28/20 14:35 99-09-208/27/20 14:042.3 1 4-Nitroaniline ND mg/kg 08/28/20 14:35 100-01-608/27/20 14:040.92 1 Nitrobenzene ND mg/kg 08/28/20 14:35 98-95-308/27/20 14:040.46 1 2-Nitrophenol ND mg/kg 08/28/20 14:35 88-75-508/27/20 14:040.46 1 4-Nitrophenol ND mg/kg 08/28/20 14:35 100-02-708/27/20 14:042.3 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 14:35 62-75-908/27/20 14:040.46 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 14:35 621-64-708/27/20 14:040.46 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 14:35 86-30-608/27/20 14:040.46 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 14:35 108-60-1 v208/27/20 14:040.46 1 Pentachlorophenol ND mg/kg 08/28/20 14:35 87-86-508/27/20 14:040.92 1 Phenanthrene ND mg/kg 08/28/20 14:35 85-01-808/27/20 14:040.46 1 Phenol ND mg/kg 08/28/20 14:35 108-95-208/27/20 14:040.46 1 Pyrene ND mg/kg 08/28/20 14:35 129-00-008/27/20 14:040.46 1 Pyridine ND mg/kg 08/28/20 14:35 110-86-108/27/20 14:040.46 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 14:35 120-82-108/27/20 14:040.46 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 14:35 95-95-408/27/20 14:040.46 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 14:35 88-06-208/27/20 14:040.46 1 Surrogates Nitrobenzene-d5 (S)43 %08/28/20 14:35 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)50 %08/28/20 14:35 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)56 %08/28/20 14:35 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)54 %08/28/20 14:35 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)51 %08/28/20 14:35 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)66 %08/28/20 14:35 118-79-608/27/20 14:0427-110 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 28.8 %08/25/20 10:170.10 1 Sample:P-1 Lab ID:92492009015 Collected:08/13/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: MADEP EPH Preparation Method: MADEP EPH Pace Analytical Services - Charlotte MADEP EPH NC Soil Aliphatic (C09-C18)ND mg/kg 08/28/20 11:46 N208/27/20 08:3412.5 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 49 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:P-1 Lab ID:92492009015 Collected:08/13/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: MADEP EPH Preparation Method: MADEP EPH Pace Analytical Services - Charlotte MADEP EPH NC Soil Aliphatic (C19-C36)57.0 mg/kg 08/28/20 11:46 N208/27/20 08:3412.5 1 Aromatic (C11-C22)22.6 mg/kg 08/28/20 11:46 N208/27/20 08:3412.5 1 Surrogates o-Terphenyl (S)77 %08/28/20 11:46 84-15-108/27/20 08:3440-140 1 2-Fluorobiphenyl (S)103 %08/28/20 11:46 321-60-808/27/20 08:3440-140 1 2-Bromonaphthalene (S)106 %08/28/20 11:46 580-13-208/27/20 08:3440-140 1 Nonatriacontane (S)76 %08/28/20 11:46 7194-86-708/27/20 08:3440-140 1 Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 08/28/20 15:29 83-32-908/27/20 14:040.42 1 Acenaphthylene ND mg/kg 08/28/20 15:29 208-96-808/27/20 14:040.42 1 Aniline ND mg/kg 08/28/20 15:29 62-53-308/27/20 14:040.42 1 Anthracene ND mg/kg 08/28/20 15:29 120-12-708/27/20 14:040.42 1 Benzo(a)anthracene ND mg/kg 08/28/20 15:29 56-55-308/27/20 14:040.42 1 Benzo(a)pyrene ND mg/kg 08/28/20 15:29 50-32-808/27/20 14:040.42 1 Benzo(b)fluoranthene ND mg/kg 08/28/20 15:29 205-99-208/27/20 14:040.42 1 Benzo(g,h,i)perylene ND mg/kg 08/28/20 15:29 191-24-208/27/20 14:040.42 1 Benzo(k)fluoranthene ND mg/kg 08/28/20 15:29 207-08-908/27/20 14:040.42 1 Benzoic Acid ND mg/kg 08/28/20 15:29 65-85-008/27/20 14:042.1 1 Benzyl alcohol ND mg/kg 08/28/20 15:29 100-51-608/27/20 14:040.83 1 4-Bromophenylphenyl ether ND mg/kg 08/28/20 15:29 101-55-308/27/20 14:040.42 1 Butylbenzylphthalate ND mg/kg 08/28/20 15:29 85-68-708/27/20 14:040.42 1 4-Chloro-3-methylphenol ND mg/kg 08/28/20 15:29 59-50-708/27/20 14:040.83 1 4-Chloroaniline ND mg/kg 08/28/20 15:29 106-47-808/27/20 14:040.83 1 bis(2-Chloroethoxy)methane ND mg/kg 08/28/20 15:29 111-91-108/27/20 14:040.42 1 bis(2-Chloroethyl) ether ND mg/kg 08/28/20 15:29 111-44-408/27/20 14:040.42 1 2-Chloronaphthalene ND mg/kg 08/28/20 15:29 91-58-708/27/20 14:040.42 1 2-Chlorophenol ND mg/kg 08/28/20 15:29 95-57-808/27/20 14:040.42 1 4-Chlorophenylphenyl ether ND mg/kg 08/28/20 15:29 7005-72-308/27/20 14:040.42 1 Chrysene ND mg/kg 08/28/20 15:29 218-01-908/27/20 14:040.42 1 Dibenz(a,h)anthracene ND mg/kg 08/28/20 15:29 53-70-308/27/20 14:040.42 1 Dibenzofuran ND mg/kg 08/28/20 15:29 132-64-908/27/20 14:040.42 1 1,2-Dichlorobenzene ND mg/kg 08/28/20 15:29 95-50-108/27/20 14:040.42 1 1,3-Dichlorobenzene ND mg/kg 08/28/20 15:29 541-73-108/27/20 14:040.42 1 1,4-Dichlorobenzene ND mg/kg 08/28/20 15:29 106-46-708/27/20 14:040.42 1 3,3'-Dichlorobenzidine ND mg/kg 08/28/20 15:29 91-94-108/27/20 14:040.83 1 2,4-Dichlorophenol ND mg/kg 08/28/20 15:29 120-83-208/27/20 14:040.42 1 Diethylphthalate ND mg/kg 08/28/20 15:29 84-66-208/27/20 14:040.42 1 2,4-Dimethylphenol ND mg/kg 08/28/20 15:29 105-67-908/27/20 14:040.42 1 Dimethylphthalate ND mg/kg 08/28/20 15:29 131-11-308/27/20 14:040.42 1 Di-n-butylphthalate ND mg/kg 08/28/20 15:29 84-74-208/27/20 14:040.42 1 4,6-Dinitro-2-methylphenol ND mg/kg 08/28/20 15:29 534-52-108/27/20 14:040.83 1 2,4-Dinitrophenol ND mg/kg 08/28/20 15:29 51-28-508/27/20 14:042.1 1 2,4-Dinitrotoluene ND mg/kg 08/28/20 15:29 121-14-208/27/20 14:040.42 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 50 of 90 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492009 Northstate Sample:P-1 Lab ID:92492009015 Collected:08/13/20 11:30 Received:08/21/20 10:00 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave 2,6-Dinitrotoluene ND mg/kg 08/28/20 15:29 606-20-208/27/20 14:040.42 1 Di-n-octylphthalate ND mg/kg 08/28/20 15:29 117-84-008/27/20 14:040.42 1 bis(2-Ethylhexyl)phthalate ND mg/kg 08/28/20 15:29 117-81-708/27/20 14:040.42 1 Fluoranthene ND mg/kg 08/28/20 15:29 206-44-008/27/20 14:040.42 1 Fluorene ND mg/kg 08/28/20 15:29 86-73-708/27/20 14:040.42 1 Hexachloro-1,3-butadiene ND mg/kg 08/28/20 15:29 87-68-308/27/20 14:040.42 1 Hexachlorobenzene ND mg/kg 08/28/20 15:29 118-74-108/27/20 14:040.42 1 Hexachlorocyclopentadiene ND mg/kg 08/28/20 15:29 77-47-4 v208/27/20 14:040.42 1 Hexachloroethane ND mg/kg 08/28/20 15:29 67-72-108/27/20 14:040.42 1 Indeno(1,2,3-cd)pyrene ND mg/kg 08/28/20 15:29 193-39-508/27/20 14:040.42 1 Isophorone ND mg/kg 08/28/20 15:29 78-59-108/27/20 14:040.42 1 1-Methylnaphthalene ND mg/kg 08/28/20 15:29 90-12-008/27/20 14:040.42 1 2-Methylnaphthalene ND mg/kg 08/28/20 15:29 91-57-608/27/20 14:040.42 1 2-Methylphenol(o-Cresol)ND mg/kg 08/28/20 15:29 95-48-708/27/20 14:040.42 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 08/28/20 15:29 15831-10-408/27/20 14:040.42 1 Naphthalene ND mg/kg 08/28/20 15:29 91-20-308/27/20 14:040.42 1 2-Nitroaniline ND mg/kg 08/28/20 15:29 88-74-4 v208/27/20 14:042.1 1 3-Nitroaniline ND mg/kg 08/28/20 15:29 99-09-208/27/20 14:042.1 1 4-Nitroaniline ND mg/kg 08/28/20 15:29 100-01-608/27/20 14:040.83 1 Nitrobenzene ND mg/kg 08/28/20 15:29 98-95-308/27/20 14:040.42 1 2-Nitrophenol ND mg/kg 08/28/20 15:29 88-75-508/27/20 14:040.42 1 4-Nitrophenol ND mg/kg 08/28/20 15:29 100-02-708/27/20 14:042.1 1 N-Nitrosodimethylamine ND mg/kg 08/28/20 15:29 62-75-908/27/20 14:040.42 1 N-Nitroso-di-n-propylamine ND mg/kg 08/28/20 15:29 621-64-708/27/20 14:040.42 1 N-Nitrosodiphenylamine ND mg/kg 08/28/20 15:29 86-30-608/27/20 14:040.42 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 08/28/20 15:29 108-60-1 v208/27/20 14:040.42 1 Pentachlorophenol ND mg/kg 08/28/20 15:29 87-86-508/27/20 14:040.83 1 Phenanthrene ND mg/kg 08/28/20 15:29 85-01-808/27/20 14:040.42 1 Phenol ND mg/kg 08/28/20 15:29 108-95-208/27/20 14:040.42 1 Pyrene ND mg/kg 08/28/20 15:29 129-00-008/27/20 14:040.42 1 Pyridine ND mg/kg 08/28/20 15:29 110-86-108/27/20 14:040.42 1 1,2,4-Trichlorobenzene ND mg/kg 08/28/20 15:29 120-82-108/27/20 14:040.42 1 2,4,5-Trichlorophenol ND mg/kg 08/28/20 15:29 95-95-408/27/20 14:040.42 1 2,4,6-Trichlorophenol ND mg/kg 08/28/20 15:29 88-06-208/27/20 14:040.42 1 Surrogates Nitrobenzene-d5 (S)46 %08/28/20 15:29 4165-60-008/27/20 14:0423-110 1 2-Fluorobiphenyl (S)51 %08/28/20 15:29 321-60-808/27/20 14:0430-110 1 Terphenyl-d14 (S)53 %08/28/20 15:29 1718-51-008/27/20 14:0428-110 1 Phenol-d6 (S)55 %08/28/20 15:29 13127-88-308/27/20 14:0422-110 1 2-Fluorophenol (S)53 %08/28/20 15:29 367-12-408/27/20 14:0413-110 1 2,4,6-Tribromophenol (S)70 %08/28/20 15:29 118-79-608/27/20 14:0427-110 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 20.8 %08/25/20 10:170.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 51 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562180 EPA 5035A/5030B EPA 8260D 8260D 5035A 5030B Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009002, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007, 92492009008, 92492009009, 92492009010, 92492009011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2981638 Associated Lab Samples:92492009002, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007, 92492009008, 92492009009, 92492009010, 92492009011 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 08/25/20 11:03 1,1,1-Trichloroethane mg/kg ND 0.0050 08/25/20 11:03 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 08/25/20 11:03 1,1,2-Trichloroethane mg/kg ND 0.0050 08/25/20 11:03 1,1-Dichloroethane mg/kg ND 0.0050 08/25/20 11:03 1,1-Dichloroethene mg/kg ND 0.0050 08/25/20 11:03 1,1-Dichloropropene mg/kg ND 0.0050 08/25/20 11:03 1,2,3-Trichlorobenzene mg/kg ND 0.0050 08/25/20 11:03 1,2,3-Trichloropropane mg/kg ND 0.0050 08/25/20 11:03 1,2,4-Trichlorobenzene mg/kg ND 0.0050 08/25/20 11:03 1,2,4-Trimethylbenzene mg/kg ND 0.0050 08/25/20 11:03 1,2-Dibromo-3-chloropropane mg/kg ND 0.0050 08/25/20 11:03 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 08/25/20 11:03 1,2-Dichlorobenzene mg/kg ND 0.0050 08/25/20 11:03 1,2-Dichloroethane mg/kg ND 0.0050 08/25/20 11:03 1,2-Dichloropropane mg/kg ND 0.0050 08/25/20 11:03 1,3,5-Trimethylbenzene mg/kg ND 0.0050 08/25/20 11:03 1,3-Dichlorobenzene mg/kg ND 0.0050 08/25/20 11:03 1,3-Dichloropropane mg/kg ND 0.0050 08/25/20 11:03 1,4-Dichlorobenzene mg/kg ND 0.0050 08/25/20 11:03 2,2-Dichloropropane mg/kg ND 0.0050 08/25/20 11:03 2-Butanone (MEK)mg/kg ND 0.10 08/25/20 11:03 2-Chlorotoluene mg/kg ND 0.0050 08/25/20 11:03 2-Hexanone mg/kg ND 0.050 08/25/20 11:03 4-Chlorotoluene mg/kg ND 0.0050 08/25/20 11:03 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.050 08/25/20 11:03 Acetone mg/kg ND 0.10 08/25/20 11:03 Benzene mg/kg ND 0.0050 08/25/20 11:03 Bromobenzene mg/kg ND 0.0050 08/25/20 11:03 Bromochloromethane mg/kg ND 0.0050 IK08/25/20 11:03 Bromodichloromethane mg/kg ND 0.0050 08/25/20 11:03 Bromoform mg/kg ND 0.0050 08/25/20 11:03 Bromomethane mg/kg ND 0.010 v108/25/20 11:03 Carbon tetrachloride mg/kg ND 0.0050 08/25/20 11:03 Chlorobenzene mg/kg ND 0.0050 08/25/20 11:03 Chloroethane mg/kg ND 0.010 08/25/20 11:03 Chloroform mg/kg ND 0.0050 08/25/20 11:03 Chloromethane mg/kg ND 0.010 v208/25/20 11:03 cis-1,2-Dichloroethene mg/kg ND 0.0050 08/25/20 11:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 52 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2981638 Associated Lab Samples:92492009002, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007, 92492009008, 92492009009, 92492009010, 92492009011 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 08/25/20 11:03 Dibromochloromethane mg/kg ND 0.0050 08/25/20 11:03 Dibromomethane mg/kg ND 0.0050 08/25/20 11:03 Dichlorodifluoromethane mg/kg ND 0.010 08/25/20 11:03 Diisopropyl ether mg/kg ND 0.0050 08/25/20 11:03 Ethylbenzene mg/kg ND 0.0050 08/25/20 11:03 Hexachloro-1,3-butadiene mg/kg ND 0.0050 08/25/20 11:03 Isopropylbenzene (Cumene)mg/kg ND 0.0050 08/25/20 11:03 m&p-Xylene mg/kg ND 0.010 08/25/20 11:03 Methyl-tert-butyl ether mg/kg ND 0.0050 08/25/20 11:03 Methylene Chloride mg/kg ND 0.020 08/25/20 11:03 n-Butylbenzene mg/kg ND 0.0050 08/25/20 11:03 n-Propylbenzene mg/kg ND 0.0050 08/25/20 11:03 Naphthalene mg/kg ND 0.0050 08/25/20 11:03 o-Xylene mg/kg ND 0.0050 08/25/20 11:03 p-Isopropyltoluene mg/kg ND 0.0050 08/25/20 11:03 sec-Butylbenzene mg/kg ND 0.0050 08/25/20 11:03 Styrene mg/kg ND 0.0050 08/25/20 11:03 tert-Butylbenzene mg/kg ND 0.0050 08/25/20 11:03 Tetrachloroethene mg/kg ND 0.0050 08/25/20 11:03 Toluene mg/kg ND 0.0050 08/25/20 11:03 trans-1,2-Dichloroethene mg/kg ND 0.0050 08/25/20 11:03 trans-1,3-Dichloropropene mg/kg ND 0.0050 08/25/20 11:03 Trichloroethene mg/kg ND 0.0050 08/25/20 11:03 Trichlorofluoromethane mg/kg ND 0.0050 08/25/20 11:03 Vinyl acetate mg/kg ND 0.050 08/25/20 11:03 Vinyl chloride mg/kg ND 0.010 08/25/20 11:03 Xylene (Total)mg/kg ND 0.010 08/25/20 11:03 1,2-Dichloroethane-d4 (S)%100 70-132 08/25/20 11:03 4-Bromofluorobenzene (S)%101 70-130 08/25/20 11:03 Toluene-d8 (S)%99 70-130 08/25/20 11:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981639LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane mg/kg 1.41.2 108 70-130 1,1,1-Trichloroethane mg/kg 1.31.2 105 70-130 1,1,2,2-Tetrachloroethane mg/kg 1.11.2 92 55-130 1,1,2-Trichloroethane mg/kg 1.21.2 99 70-130 1,1-Dichloroethane mg/kg 1.21.2 95 68-130 1,1-Dichloroethene mg/kg 1.21.2 94 70-130 1,1-Dichloropropene mg/kg 1.21.2 94 70-130 1,2,3-Trichlorobenzene mg/kg 1.21.2 97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 53 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981639LABORATORY CONTROL SAMPLE: LCSSpike 1,2,3-Trichloropropane mg/kg 1.21.2 93 70-130 1,2,4-Trichlorobenzene mg/kg 1.21.2 94 70-130 1,2,4-Trimethylbenzene mg/kg 1.21.2 93 69-130 1,2-Dibromo-3-chloropropane mg/kg 1.31.2 101 57-141 1,2-Dibromoethane (EDB)mg/kg 1.21.2 99 70-130 1,2-Dichlorobenzene mg/kg 1.21.2 97 70-130 1,2-Dichloroethane mg/kg 1.11.2 90 70-130 1,2-Dichloropropane mg/kg 1.21.2 99 70-130 1,3,5-Trimethylbenzene mg/kg 1.21.2 96 70-130 1,3-Dichlorobenzene mg/kg 1.21.2 98 70-130 1,3-Dichloropropane mg/kg 1.21.2 98 70-130 1,4-Dichlorobenzene mg/kg 1.21.2 94 70-130 2,2-Dichloropropane mg/kg 1.21.2 98 70-130 2-Butanone (MEK)mg/kg 2.12.5 85 60-130 2-Chlorotoluene mg/kg 1.21.2 96 70-130 2-Hexanone mg/kg 2.32.5 92 70-132 4-Chlorotoluene mg/kg 1.21.2 92 70-130 4-Methyl-2-pentanone (MIBK)mg/kg 2.32.5 92 69-130 Acetone mg/kg 2.22.5 86 49-148 Benzene mg/kg 1.21.2 93 70-130 Bromobenzene mg/kg 1.21.2 99 70-130 Bromochloromethane mg/kg 1.2 IK1.2 97 70-130 Bromodichloromethane mg/kg 1.31.2 102 70-130 Bromoform mg/kg 1.41.2 114 68-136 Bromomethane mg/kg 1.6 v11.2 131 60-140 Carbon tetrachloride mg/kg 1.51.2 118 70-130 Chlorobenzene mg/kg 1.21.2 98 70-130 Chloroethane mg/kg 1.21.2 95 51-147 Chloroform mg/kg 1.21.2 97 70-130 Chloromethane mg/kg 0.86 v31.2 69 48-130 cis-1,2-Dichloroethene mg/kg 1.21.2 95 70-130 cis-1,3-Dichloropropene mg/kg 1.31.2 103 70-130 Dibromochloromethane mg/kg 1.41.2 110 70-130 Dibromomethane mg/kg 1.41.2 113 70-130 Dichlorodifluoromethane mg/kg 1.11.2 90 49-130 Diisopropyl ether mg/kg 1.11.2 86 66-130 Ethylbenzene mg/kg 1.21.2 93 70-130 Hexachloro-1,3-butadiene mg/kg 1.21.2 96 70-130 Isopropylbenzene (Cumene)mg/kg 1.31.2 100 70-130 m&p-Xylene mg/kg 2.52.5 100 70-130 Methyl-tert-butyl ether mg/kg 1.21.2 95 70-130 Methylene Chloride mg/kg 1.01.2 81 50-137 n-Butylbenzene mg/kg 1.11.2 90 70-130 n-Propylbenzene mg/kg 1.11.2 91 70-130 Naphthalene mg/kg 1.21.2 95 70-131 o-Xylene mg/kg 1.21.2 98 70-130 p-Isopropyltoluene mg/kg 1.21.2 93 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 54 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981639LABORATORY CONTROL SAMPLE: LCSSpike sec-Butylbenzene mg/kg 1.21.2 93 70-130 Styrene mg/kg 1.41.2 108 70-130 tert-Butylbenzene mg/kg 1.21.2 93 69-130 Tetrachloroethene mg/kg 1.31.2 105 56-130 Toluene mg/kg 1.21.2 95 70-130 trans-1,2-Dichloroethene mg/kg 1.21.2 96 70-130 trans-1,3-Dichloropropene mg/kg 1.31.2 102 70-130 Trichloroethene mg/kg 1.31.2 105 70-141 Trichlorofluoromethane mg/kg 1.41.2 112 67-130 Vinyl acetate mg/kg 2.32.5 91 10-136 Vinyl chloride mg/kg 1.01.2 82 67-130 Xylene (Total)mg/kg 3.73.8 99 70-130 1,2-Dichloroethane-d4 (S)%98 70-132 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%99 70-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2981640MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491900004 2981641 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane mg/kg 0.65 94 52-133108 130.65ND 0.61 0.70 1,1,1-Trichloroethane mg/kg 0.65 96 49-137108 120.65ND 0.62 0.70 1,1,2,2-Tetrachloroethane mg/kg 0.65 82 39-15094 130.65ND 0.53 0.61 1,1,2-Trichloroethane mg/kg 0.65 93 48-140101 90.65ND 0.60 0.66 1,1-Dichloroethane mg/kg 0.65 80 46-13591 130.65ND 0.52 0.59 1,1-Dichloroethene mg/kg 0.65 81 38-14988 90.65ND 0.52 0.57 1,1-Dichloropropene mg/kg 0.65 89 41-140102 140.65ND 0.58 0.66 1,2,3-Trichlorobenzene mg/kg 0.65 91 10-158106 150.65ND 0.59 0.69 1,2,3-Trichloropropane mg/kg 0.65 83 33-15793 120.65ND 0.54 0.60 1,2,4-Trichlorobenzene mg/kg 0.65 93 10-155106 120.65ND 0.61 0.68 1,2,4-Trimethylbenzene mg/kg 0.65 95 24-154108 120.65ND 0.62 0.70 1,2-Dibromo-3-chloropropane mg/kg 0.65 86 33-158100 150.65ND 0.56 0.65 1,2-Dibromoethane (EDB)mg/kg 0.65 86 40-13697 110.65ND 0.56 0.63 1,2-Dichlorobenzene mg/kg 0.65 94 27-146105 110.65ND 0.61 0.68 1,2-Dichloroethane mg/kg 0.65 88 49-14097 100.65ND 0.57 0.63 1,2-Dichloropropane mg/kg 0.65 92 44-143102 100.65ND 0.60 0.66 1,3,5-Trimethylbenzene mg/kg 0.65 95 40-144108 120.65ND 0.62 0.70 1,3-Dichlorobenzene mg/kg 0.65 94 33-140110 150.65ND 0.61 0.71 1,3-Dichloropropane mg/kg 0.65 87 47-14798 120.65ND 0.56 0.63 1,4-Dichlorobenzene mg/kg 0.65 90 35-139102 120.65ND 0.59 0.66 2,2-Dichloropropane mg/kg 0.65 75 41-14091 190.65ND 0.49 0.59 2-Butanone (MEK)mg/kg 1.3 66 10-18174 111.3ND 0.85 0.95 2-Chlorotoluene mg/kg 0.65 95 38-147108 130.65ND 0.61 0.70 2-Hexanone mg/kg 1.3 44 18-16952 171.3ND 0.57 0.68 4-Chlorotoluene mg/kg 0.65 90 36-145103 130.65ND 0.59 0.67 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 55 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2981640MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491900004 2981641 MSD Result MSD % Rec RPD MSDMS Spike Conc. 4-Methyl-2-pentanone (MIBK)mg/kg 1.3 78 16-17588 131.3ND 1.0 1.1 Acetone mg/kg 1.3 42 10-20044 41.3ND 0.55 0.57 Benzene mg/kg 0.65 89 46-136100 120.65ND 0.57 0.65 Bromobenzene mg/kg 0.65 92 38-149105 130.65ND 0.60 0.68 Bromochloromethane mg/kg IK0.65 88 44-14294 70.65ND 0.57 0.61 Bromodichloromethane mg/kg 0.65 89 41-14097 90.65ND 0.57 0.63 Bromoform mg/kg 0.65 90 34-145102 120.65ND 0.59 0.66 Bromomethane mg/kg M1,v10.65 180 14-162172 50.65ND 1.2 1.1 Carbon tetrachloride mg/kg 0.65 106 44-141120 120.65ND 0.68 0.77 Chlorobenzene mg/kg 0.65 90 39-141102 120.65ND 0.59 0.66 Chloroethane mg/kg 0.65 41 10-18246 100.65ND 0.27 0.30 Chloroform mg/kg 0.65 83 45-14090 80.65ND 0.54 0.58 Chloromethane mg/kg v30.65 78 19-14989 130.65ND 0.51 0.57 cis-1,2-Dichloroethene mg/kg 0.65 82 38-15095 150.65ND 0.53 0.62 cis-1,3-Dichloropropene mg/kg 0.65 92 30-14499 80.65ND 0.60 0.64 Dibromochloromethane mg/kg 0.65 91 36-145102 110.65ND 0.59 0.66 Dibromomethane mg/kg 0.65 92 41-145102 100.65ND 0.60 0.66 Dichlorodifluoromethane mg/kg 0.65 85 16-14698 150.65ND 0.55 0.63 Diisopropyl ether mg/kg 0.65 76 41-14385 110.65ND 0.49 0.55 Ethylbenzene mg/kg 0.65 87 35-14498 120.65ND 0.56 0.64 Hexachloro-1,3-butadiene mg/kg 0.65 95 10-160113 170.65ND 0.61 0.73 Isopropylbenzene (Cumene)mg/kg 0.65 95 30-152106 120.65ND 0.61 0.69 m&p-Xylene mg/kg 1.3 92 33-145106 131.3ND 1.2 1.4 Methyl-tert-butyl ether mg/kg 0.65 86 49-14097 120.65ND 0.56 0.63 Methylene Chloride mg/kg 0.65 71 10-17481 140.65ND 0.46 0.53 n-Butylbenzene mg/kg 0.65 91 10-160102 120.65ND 0.59 0.66 n-Propylbenzene mg/kg 0.65 93 24-159104 110.65ND 0.60 0.67 Naphthalene mg/kg 0.65 87 10-171100 130.65ND 0.57 0.65 o-Xylene mg/kg 0.65 91 31-150101 100.65ND 0.59 0.66 p-Isopropyltoluene mg/kg 0.65 92 21-154105 130.65ND 0.60 0.68 sec-Butylbenzene mg/kg 0.65 94 19-159109 140.65ND 0.61 0.71 Styrene mg/kg 0.65 96 15-152107 110.65ND 0.62 0.69 tert-Butylbenzene mg/kg 0.65 94 31-141107 130.65ND 0.61 0.69 Tetrachloroethene mg/kg 0.65 95 19-141110 150.65ND 0.62 0.71 Toluene mg/kg 0.65 91 31-146101 100.65ND 0.59 0.65 trans-1,2-Dichloroethene mg/kg 0.65 89 28-157100 120.65ND 0.57 0.65 trans-1,3-Dichloropropene mg/kg 0.65 86 25-14695 110.65ND 0.56 0.62 Trichloroethene mg/kg 0.65 99 34-149113 140.65ND 0.64 0.73 Trichlorofluoromethane mg/kg 0.65 38 10-16744 160.65ND 0.24 0.29 Vinyl acetate mg/kg 1.3 70 10-20080 141.3ND 0.91 1.0 Vinyl chloride mg/kg 0.65 79 36-15594 180.65ND 0.51 0.61 Xylene (Total)mg/kg 1.9 92 29-148104 121.9ND 1.8 2.0 1,2-Dichloroethane-d4 (S)%102 70-13298 4-Bromofluorobenzene (S)%98 70-13099 Toluene-d8 (S)%100 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 56 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562268 EPA 8260D EPA 8260D 8260D MSV Low Level Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009012, 92492009013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2982163 Associated Lab Samples:92492009012, 92492009013 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 08/25/20 15:29 1,1,1-Trichloroethane ug/L ND 1.0 08/25/20 15:29 1,1,2,2-Tetrachloroethane ug/L ND 1.0 08/25/20 15:29 1,1,2-Trichloroethane ug/L ND 1.0 08/25/20 15:29 1,1-Dichloroethane ug/L ND 1.0 08/25/20 15:29 1,1-Dichloroethene ug/L ND 1.0 08/25/20 15:29 1,1-Dichloropropene ug/L ND 1.0 08/25/20 15:29 1,2,3-Trichlorobenzene ug/L ND 1.0 08/25/20 15:29 1,2,3-Trichloropropane ug/L ND 1.0 08/25/20 15:29 1,2,4-Trichlorobenzene ug/L ND 1.0 08/25/20 15:29 1,2-Dibromo-3-chloropropane ug/L ND 5.0 08/25/20 15:29 1,2-Dibromoethane (EDB)ug/L ND 1.0 08/25/20 15:29 1,2-Dichlorobenzene ug/L ND 1.0 08/25/20 15:29 1,2-Dichloroethane ug/L ND 1.0 08/25/20 15:29 1,2-Dichloropropane ug/L ND 1.0 08/25/20 15:29 1,3-Dichlorobenzene ug/L ND 1.0 08/25/20 15:29 1,3-Dichloropropane ug/L ND 1.0 08/25/20 15:29 1,4-Dichlorobenzene ug/L ND 1.0 08/25/20 15:29 2,2-Dichloropropane ug/L ND 1.0 08/25/20 15:29 2-Butanone (MEK)ug/L ND 5.0 08/25/20 15:29 2-Chlorotoluene ug/L ND 1.0 08/25/20 15:29 2-Hexanone ug/L ND 5.0 08/25/20 15:29 4-Chlorotoluene ug/L ND 1.0 08/25/20 15:29 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 08/25/20 15:29 Acetone ug/L ND 25.0 08/25/20 15:29 Benzene ug/L ND 1.0 08/25/20 15:29 Bromobenzene ug/L ND 1.0 08/25/20 15:29 Bromochloromethane ug/L ND 1.0 08/25/20 15:29 Bromodichloromethane ug/L ND 1.0 08/25/20 15:29 Bromoform ug/L ND 1.0 08/25/20 15:29 Bromomethane ug/L ND 2.0 08/25/20 15:29 Carbon tetrachloride ug/L ND 1.0 08/25/20 15:29 Chlorobenzene ug/L ND 1.0 08/25/20 15:29 Chloroethane ug/L ND 1.0 08/25/20 15:29 Chloroform ug/L ND 5.0 08/25/20 15:29 Chloromethane ug/L ND 1.0 08/25/20 15:29 cis-1,2-Dichloroethene ug/L ND 1.0 08/25/20 15:29 cis-1,3-Dichloropropene ug/L ND 1.0 08/25/20 15:29 Dibromochloromethane ug/L ND 1.0 08/25/20 15:29 Dibromomethane ug/L ND 1.0 08/25/20 15:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 57 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2982163 Associated Lab Samples:92492009012, 92492009013 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 08/25/20 15:29 Diisopropyl ether ug/L ND 1.0 08/25/20 15:29 Ethylbenzene ug/L ND 1.0 08/25/20 15:29 Hexachloro-1,3-butadiene ug/L ND 1.0 08/25/20 15:29 m&p-Xylene ug/L ND 2.0 08/25/20 15:29 Methyl-tert-butyl ether ug/L ND 1.0 08/25/20 15:29 Methylene Chloride ug/L ND 5.0 08/25/20 15:29 Naphthalene ug/L ND 1.0 08/25/20 15:29 o-Xylene ug/L ND 1.0 08/25/20 15:29 p-Isopropyltoluene ug/L ND 1.0 08/25/20 15:29 Styrene ug/L ND 1.0 08/25/20 15:29 Tetrachloroethene ug/L ND 1.0 08/25/20 15:29 Toluene ug/L ND 1.0 08/25/20 15:29 trans-1,2-Dichloroethene ug/L ND 1.0 08/25/20 15:29 trans-1,3-Dichloropropene ug/L ND 1.0 08/25/20 15:29 Trichloroethene ug/L ND 1.0 08/25/20 15:29 Trichlorofluoromethane ug/L ND 1.0 08/25/20 15:29 Vinyl acetate ug/L ND 2.0 08/25/20 15:29 Vinyl chloride ug/L ND 1.0 08/25/20 15:29 Xylene (Total)ug/L ND 1.0 08/25/20 15:29 1,2-Dichloroethane-d4 (S)%105 70-130 08/25/20 15:29 4-Bromofluorobenzene (S)%98 70-130 08/25/20 15:29 Toluene-d8 (S)%99 70-130 08/25/20 15:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2982164LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 49.450 99 70-130 1,1,1-Trichloroethane ug/L 47.150 94 70-130 1,1,2,2-Tetrachloroethane ug/L 53.150 106 70-130 1,1,2-Trichloroethane ug/L 47.450 95 70-130 1,1-Dichloroethane ug/L 52.550 105 70-130 1,1-Dichloroethene ug/L 57.050 114 70-130 1,1-Dichloropropene ug/L 48.850 98 70-130 1,2,3-Trichlorobenzene ug/L 51.850 104 70-130 1,2,3-Trichloropropane ug/L 55.550 111 70-130 1,2,4-Trichlorobenzene ug/L 52.750 105 70-130 1,2-Dibromo-3-chloropropane ug/L 49.050 98 70-130 1,2-Dibromoethane (EDB)ug/L 48.850 98 70-130 1,2-Dichlorobenzene ug/L 54.150 108 70-130 1,2-Dichloroethane ug/L 48.950 98 70-130 1,2-Dichloropropane ug/L 51.750 103 70-130 1,3-Dichlorobenzene ug/L 53.350 107 70-130 1,3-Dichloropropane ug/L 52.850 106 70-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 58 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2982164LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 53.050 106 70-130 2,2-Dichloropropane ug/L 50.050 100 69-130 2-Butanone (MEK)ug/L 92.4100 92 64-135 2-Chlorotoluene ug/L 53.750 107 70-130 2-Hexanone ug/L 103100 103 66-135 4-Chlorotoluene ug/L 54.250 108 70-130 4-Methyl-2-pentanone (MIBK)ug/L 102100 102 70-130 Acetone ug/L 103100 103 61-157 Benzene ug/L 54.050 108 70-130 Bromobenzene ug/L 52.350 105 70-130 Bromochloromethane ug/L 50.050 100 70-130 Bromodichloromethane ug/L 46.950 94 70-130 Bromoform ug/L 48.450 97 70-130 Bromomethane ug/L 53.650 107 38-130 Carbon tetrachloride ug/L 47.450 95 70-130 Chlorobenzene ug/L 52.750 105 70-130 Chloroethane ug/L 42.750 85 37-142 Chloroform ug/L 51.050 102 70-130 Chloromethane ug/L 42.250 84 48-130 cis-1,2-Dichloroethene ug/L 52.450 105 70-130 cis-1,3-Dichloropropene ug/L 51.150 102 70-130 Dibromochloromethane ug/L 46.950 94 70-130 Dibromomethane ug/L 52.250 104 70-130 Dichlorodifluoromethane ug/L 47.950 96 53-134 Diisopropyl ether ug/L 48.250 96 70-135 Ethylbenzene ug/L 54.150 108 70-130 Hexachloro-1,3-butadiene ug/L 57.850 116 68-132 m&p-Xylene ug/L 108100 108 70-130 Methyl-tert-butyl ether ug/L 49.850 100 70-130 Methylene Chloride ug/L 51.050 102 67-132 Naphthalene ug/L 48.350 97 70-130 o-Xylene ug/L 53.350 107 70-131 p-Isopropyltoluene ug/L 51.550 103 70-130 Styrene ug/L 54.450 109 70-130 Tetrachloroethene ug/L 52.250 104 69-130 Toluene ug/L 52.550 105 70-130 trans-1,2-Dichloroethene ug/L 53.350 107 70-130 trans-1,3-Dichloropropene ug/L 50.250 100 70-130 Trichloroethene ug/L 47.450 95 70-130 Trichlorofluoromethane ug/L 52.750 105 63-130 Vinyl acetate ug/L 108100 108 55-143 Vinyl chloride ug/L 46.550 93 70-131 Xylene (Total)ug/L 161150 108 70-130 1,2-Dichloroethane-d4 (S)%94 70-130 4-Bromofluorobenzene (S)%102 70-130 Toluene-d8 (S)%101 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 59 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2982165MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491985011 2982166 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 800 107 73-134107 0800ND855854 1,1,1-Trichloroethane ug/L 800 109 82-143108 1800ND871865 1,1,2,2-Tetrachloroethane ug/L 800 108 70-136107 2800ND865852 1,1,2-Trichloroethane ug/L 800 101 70-135100 1800ND805798 1,1-Dichloroethane ug/L 800 118 70-139116 1800ND943930 1,1-Dichloroethene ug/L 800 129 70-154127 2800ND10301020 1,1-Dichloropropene ug/L 800 115 70-149110 4800ND918883 1,2,3-Trichlorobenzene ug/L 800 111 70-135108 3800ND889866 1,2,3-Trichloropropane ug/L 800 110 71-137106 4800ND878845 1,2,4-Trichlorobenzene ug/L 800 112 73-140110 1800ND894881 1,2-Dibromo-3-chloropropane ug/L 800 103 65-134102 1800ND823816 1,2-Dibromoethane (EDB)ug/L 800 112 70-137107 4800ND894858 1,2-Dichlorobenzene ug/L 800 111 70-133111 0800ND884888 1,2-Dichloroethane ug/L 800 107 70-137105 2800ND874857 1,2-Dichloropropane ug/L 800 114 70-140116 2800ND913927 1,3-Dichlorobenzene ug/L 800 109 70-135109 0800ND872874 1,3-Dichloropropane ug/L 800 120 70-143117 2800ND962940 1,4-Dichlorobenzene ug/L 800 111 70-133112 1800ND888899 2,2-Dichloropropane ug/L 800 75 61-14877 2800ND601614 2-Butanone (MEK)ug/L 1600 108 60-139104 41600ND17301660 2-Chlorotoluene ug/L 800 119 70-144118 1800ND956942 2-Hexanone ug/L 1600 106 65-138105 11600ND16901670 4-Chlorotoluene ug/L 800 118 70-137117 1800ND943934 4-Methyl-2-pentanone (MIBK)ug/L 1600 106 65-135106 01600ND16901690 Acetone ug/L 1600 125 60-148120 41600ND20101920 Benzene ug/L 800 112 70-151130 3800469055805720 Bromobenzene ug/L 800 111 70-136110 1800ND890882 Bromochloromethane ug/L 800 103 70-141102 1800ND823813 Bromodichloromethane ug/L 800 99 70-13898 1800ND791784 Bromoform ug/L 800 91 63-13090 1800ND731723 Bromomethane ug/L 800 131 15-152125 5800ND1050998 Carbon tetrachloride ug/L 800 105 70-143107 2800ND839856 Chlorobenzene ug/L 800 114 70-138113 1800ND909903 Chloroethane ug/L 800 120 52-163117 3800ND963939 Chloroform ug/L 800 112 70-139108 4800ND894862 Chloromethane ug/L 800 98 41-13995 3800ND784759 cis-1,2-Dichloroethene ug/L 800 114 70-141112 2800ND914896 cis-1,3-Dichloropropene ug/L 800 101 70-137103 2800ND809827 Dibromochloromethane ug/L 800 101 70-13499 2800ND807790 Dibromomethane ug/L 800 109 70-138107 2800ND869853 Dichlorodifluoromethane ug/L 800 105 47-155103 2800ND841828 Diisopropyl ether ug/L 800 110 63-144110 0800ND881878 Ethylbenzene ug/L 800 121 66-153118 180075617201700 Hexachloro-1,3-butadiene ug/L 800 119 65-149112 6800ND952895 m&p-Xylene ug/L 1600 117 69-152115 21600ND19301900 Methyl-tert-butyl ether ug/L 800 114 54-156112 1800ND909898 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 60 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2982165MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491985011 2982166 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 800 108 42-159105 3800ND862840 Naphthalene ug/L 800 112 61-148111 180049513901390 o-Xylene ug/L 800 114 70-148112 2800ND928913 p-Isopropyltoluene ug/L 800 114 70-146111 3800ND912888 Styrene ug/L 800 116 70-135111 4800ND957920 Tetrachloroethene ug/L 800 122 59-143120 2800ND973956 Toluene ug/L 800 110 59-148112 280017710601080 trans-1,2-Dichloroethene ug/L 800 120 70-146119 1800ND960955 trans-1,3-Dichloropropene ug/L 800 97 70-13599 2800ND778794 Trichloroethene ug/L 800 105 70-147108 3800ND842868 Trichlorofluoromethane ug/L 800 126 70-148117 7800ND1000932 Vinyl acetate ug/L 1600 121 49-151119 11600ND19301910 Vinyl chloride ug/L 800 103 70-156101 2800ND821807 Xylene (Total)ug/L 2400 119 63-158117 22400ND28502810 1,2-Dichloroethane-d4 (S)%108 70-130106 4-Bromofluorobenzene (S)%99 70-13098 Toluene-d8 (S)%98 70-13098 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 61 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562199 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009013 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2981725 Associated Lab Samples:92492009013 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 08/25/20 10:26 1,2-Dichlorobenzene ug/L ND 10.0 08/25/20 10:26 1,3-Dichlorobenzene ug/L ND 10.0 08/25/20 10:26 1,4-Dichlorobenzene ug/L ND 10.0 08/25/20 10:26 1-Methylnaphthalene ug/L ND 10.0 08/25/20 10:26 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 08/25/20 10:26 2,4,5-Trichlorophenol ug/L ND 10.0 08/25/20 10:26 2,4,6-Trichlorophenol ug/L ND 10.0 08/25/20 10:26 2,4-Dichlorophenol ug/L ND 10.0 08/25/20 10:26 2,4-Dimethylphenol ug/L ND 10.0 08/25/20 10:26 2,4-Dinitrophenol ug/L ND 50.0 08/25/20 10:26 2,4-Dinitrotoluene ug/L ND 10.0 08/25/20 10:26 2,6-Dinitrotoluene ug/L ND 10.0 08/25/20 10:26 2-Chloronaphthalene ug/L ND 10.0 08/25/20 10:26 2-Chlorophenol ug/L ND 10.0 08/25/20 10:26 2-Methylnaphthalene ug/L ND 10.0 08/25/20 10:26 2-Methylphenol(o-Cresol)ug/L ND 10.0 08/25/20 10:26 2-Nitroaniline ug/L ND 20.0 08/25/20 10:26 2-Nitrophenol ug/L ND 10.0 08/25/20 10:26 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 08/25/20 10:26 3,3'-Dichlorobenzidine ug/L ND 20.0 08/25/20 10:26 3-Nitroaniline ug/L ND 20.0 08/25/20 10:26 4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/25/20 10:26 4-Bromophenylphenyl ether ug/L ND 10.0 08/25/20 10:26 4-Chloro-3-methylphenol ug/L ND 10.0 08/25/20 10:26 4-Chloroaniline ug/L ND 20.0 08/25/20 10:26 4-Chlorophenylphenyl ether ug/L ND 10.0 08/25/20 10:26 4-Nitroaniline ug/L ND 20.0 08/25/20 10:26 4-Nitrophenol ug/L ND 50.0 08/25/20 10:26 Acenaphthene ug/L ND 10.0 08/25/20 10:26 Acenaphthylene ug/L ND 10.0 08/25/20 10:26 Aniline ug/L ND 10.0 08/25/20 10:26 Anthracene ug/L ND 10.0 08/25/20 10:26 Benzo(a)anthracene ug/L ND 10.0 08/25/20 10:26 Benzo(a)pyrene ug/L ND 10.0 08/25/20 10:26 Benzo(b)fluoranthene ug/L ND 10.0 08/25/20 10:26 Benzo(g,h,i)perylene ug/L ND 10.0 08/25/20 10:26 Benzo(k)fluoranthene ug/L ND 10.0 08/25/20 10:26 Benzoic Acid ug/L ND 50.0 08/25/20 10:26 Benzyl alcohol ug/L ND 20.0 08/25/20 10:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 62 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2981725 Associated Lab Samples:92492009013 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 08/25/20 10:26 bis(2-Chloroethyl) ether ug/L ND 10.0 08/25/20 10:26 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 08/25/20 10:26 Butylbenzylphthalate ug/L ND 10.0 08/25/20 10:26 Chrysene ug/L ND 10.0 08/25/20 10:26 Di-n-butylphthalate ug/L ND 10.0 08/25/20 10:26 Di-n-octylphthalate ug/L ND 10.0 08/25/20 10:26 Dibenz(a,h)anthracene ug/L ND 10.0 08/25/20 10:26 Dibenzofuran ug/L ND 10.0 08/25/20 10:26 Diethylphthalate ug/L ND 10.0 08/25/20 10:26 Dimethylphthalate ug/L ND 10.0 08/25/20 10:26 Fluoranthene ug/L ND 10.0 08/25/20 10:26 Fluorene ug/L ND 10.0 08/25/20 10:26 Hexachloro-1,3-butadiene ug/L ND 10.0 08/25/20 10:26 Hexachlorobenzene ug/L ND 10.0 08/25/20 10:26 Hexachlorocyclopentadiene ug/L ND 10.0 08/25/20 10:26 Hexachloroethane ug/L ND 10.0 08/25/20 10:26 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 08/25/20 10:26 Isophorone ug/L ND 10.0 08/25/20 10:26 N-Nitroso-di-n-propylamine ug/L ND 10.0 08/25/20 10:26 N-Nitrosodimethylamine ug/L ND 10.0 08/25/20 10:26 N-Nitrosodiphenylamine ug/L ND 10.0 08/25/20 10:26 Naphthalene ug/L ND 10.0 08/25/20 10:26 Nitrobenzene ug/L ND 10.0 08/25/20 10:26 Pentachlorophenol ug/L ND 20.0 08/25/20 10:26 Phenanthrene ug/L ND 10.0 08/25/20 10:26 Phenol ug/L ND 10.0 08/25/20 10:26 Pyrene ug/L ND 10.0 08/25/20 10:26 2,4,6-Tribromophenol (S)%78 10-137 08/25/20 10:26 2-Fluorobiphenyl (S)%80 13-130 08/25/20 10:26 2-Fluorophenol (S)%56 10-130 08/25/20 10:26 Nitrobenzene-d5 (S)%82 13-130 08/25/20 10:26 Phenol-d6 (S)%41 10-130 08/25/20 10:26 Terphenyl-d14 (S)%119 25-130 08/25/20 10:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981726LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 42.350 85 30-130 1,2-Dichlorobenzene ug/L 43.850 88 30-130 1,3-Dichlorobenzene ug/L 41.850 84 20-130 1,4-Dichlorobenzene ug/L 45.050 90 30-130 1-Methylnaphthalene ug/L 43.150 86 30-130 2,2'-Oxybis(1-chloropropane)ug/L 55.850 112 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 63 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981726LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 53.250 106 40-130 2,4,6-Trichlorophenol ug/L 49.950 100 40-130 2,4-Dichlorophenol ug/L 48.850 98 31-130 2,4-Dimethylphenol ug/L 52.750 105 30-130 2,4-Dinitrophenol ug/L 261250 104 30-130 2,4-Dinitrotoluene ug/L 55.150 110 49-130 2,6-Dinitrotoluene ug/L 57.350 115 50-130 2-Chloronaphthalene ug/L 47.850 96 30-130 2-Chlorophenol ug/L 46.650 93 30-130 2-Methylnaphthalene ug/L 45.750 91 30-130 2-Methylphenol(o-Cresol)ug/L 47.250 94 30-130 2-Nitroaniline ug/L 115100 115 40-130 2-Nitrophenol ug/L 47.350 95 20-130 3&4-Methylphenol(m&p Cresol)ug/L 46.250 92 20-130 3,3'-Dichlorobenzidine ug/L 105100 105 10-150 3-Nitroaniline ug/L 111100 111 40-130 4,6-Dinitro-2-methylphenol ug/L 98.7100 99 40-130 4-Bromophenylphenyl ether ug/L 48.950 98 30-130 4-Chloro-3-methylphenol ug/L 102100 102 30-130 4-Chloroaniline ug/L 94.2100 94 20-130 4-Chlorophenylphenyl ether ug/L 49.050 98 20-130 4-Nitroaniline ug/L 118100 118 40-130 4-Nitrophenol ug/L 198250 79 10-130 Acenaphthene ug/L 47.850 96 30-130 Acenaphthylene ug/L 48.550 97 30-130 Aniline ug/L 41.150 82 20-130 Anthracene ug/L 44.050 88 50-130 Benzo(a)anthracene ug/L 51.550 103 50-130 Benzo(a)pyrene ug/L 53.250 106 50-130 Benzo(b)fluoranthene ug/L 58.850 118 50-130 Benzo(g,h,i)perylene ug/L 50.750 101 50-130 Benzo(k)fluoranthene ug/L 56.850 114 50-130 Benzoic Acid ug/L 147250 59 10-130 Benzyl alcohol ug/L 92.3100 92 20-130 bis(2-Chloroethoxy)methane ug/L 48.250 96 30-130 bis(2-Chloroethyl) ether ug/L 49.750 99 30-130 bis(2-Ethylhexyl)phthalate ug/L 57.250 114 50-130 Butylbenzylphthalate ug/L 60.950 122 50-150 Chrysene ug/L 51.250 102 50-130 Di-n-butylphthalate ug/L 53.350 107 50-130 Di-n-octylphthalate ug/L 54.950 110 50-130 Dibenz(a,h)anthracene ug/L 51.350 103 40-130 Dibenzofuran ug/L 49.250 98 40-130 Diethylphthalate ug/L 54.050 108 40-130 Dimethylphthalate ug/L 50.850 102 40-130 Fluoranthene ug/L 49.150 98 30-130 Fluorene ug/L 50.950 102 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 64 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981726LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 38.250 76 10-130 Hexachlorobenzene ug/L 47.650 95 30-130 Hexachlorocyclopentadiene ug/L 41.350 83 10-150 Hexachloroethane ug/L 44.550 89 10-130 Indeno(1,2,3-cd)pyrene ug/L 51.350 103 40-130 Isophorone ug/L 46.350 93 30-130 N-Nitroso-di-n-propylamine ug/L 50.950 102 30-130 N-Nitrosodimethylamine ug/L 42.450 85 10-130 N-Nitrosodiphenylamine ug/L 49.150 98 30-130 Naphthalene ug/L 44.650 89 20-130 Nitrobenzene ug/L 48.450 97 20-130 Pentachlorophenol ug/L 101100 101 10-140 Phenanthrene ug/L 47.650 95 50-130 Phenol ug/L 30.950 62 10-130 Pyrene ug/L 51.050 102 50-130 2,4,6-Tribromophenol (S)%105 10-137 2-Fluorobiphenyl (S)%94 13-130 2-Fluorophenol (S)%72 10-130 Nitrobenzene-d5 (S)%98 13-130 Phenol-d6 (S)%57 10-130 Terphenyl-d14 (S)%124 25-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 65 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562342 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2982551 Associated Lab Samples:92492009012 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 08/26/20 10:46 1,2-Dichlorobenzene ug/L ND 10.0 08/26/20 10:46 1,3-Dichlorobenzene ug/L ND 10.0 08/26/20 10:46 1,4-Dichlorobenzene ug/L ND 10.0 08/26/20 10:46 1-Methylnaphthalene ug/L ND 10.0 08/26/20 10:46 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 v108/26/20 10:46 2,4,5-Trichlorophenol ug/L ND 10.0 08/26/20 10:46 2,4,6-Trichlorophenol ug/L ND 10.0 08/26/20 10:46 2,4-Dichlorophenol ug/L ND 10.0 08/26/20 10:46 2,4-Dimethylphenol ug/L ND 10.0 08/26/20 10:46 2,4-Dinitrophenol ug/L ND 50.0 08/26/20 10:46 2,4-Dinitrotoluene ug/L ND 10.0 08/26/20 10:46 2,6-Dinitrotoluene ug/L ND 10.0 08/26/20 10:46 2-Chloronaphthalene ug/L ND 10.0 08/26/20 10:46 2-Chlorophenol ug/L ND 10.0 08/26/20 10:46 2-Methylnaphthalene ug/L ND 10.0 08/26/20 10:46 2-Methylphenol(o-Cresol)ug/L ND 10.0 08/26/20 10:46 2-Nitroaniline ug/L ND 20.0 08/26/20 10:46 2-Nitrophenol ug/L ND 10.0 08/26/20 10:46 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 08/26/20 10:46 3,3'-Dichlorobenzidine ug/L ND 20.0 08/26/20 10:46 3-Nitroaniline ug/L ND 20.0 08/26/20 10:46 4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/26/20 10:46 4-Bromophenylphenyl ether ug/L ND 10.0 08/26/20 10:46 4-Chloro-3-methylphenol ug/L ND 10.0 08/26/20 10:46 4-Chloroaniline ug/L ND 20.0 08/26/20 10:46 4-Chlorophenylphenyl ether ug/L ND 10.0 08/26/20 10:46 4-Nitroaniline ug/L ND 20.0 08/26/20 10:46 4-Nitrophenol ug/L ND 50.0 08/26/20 10:46 Acenaphthene ug/L ND 10.0 08/26/20 10:46 Acenaphthylene ug/L ND 10.0 08/26/20 10:46 Aniline ug/L ND 10.0 08/26/20 10:46 Anthracene ug/L ND 10.0 08/26/20 10:46 Benzo(a)anthracene ug/L ND 10.0 08/26/20 10:46 Benzo(a)pyrene ug/L ND 10.0 08/26/20 10:46 Benzo(b)fluoranthene ug/L ND 10.0 08/26/20 10:46 Benzo(g,h,i)perylene ug/L ND 10.0 08/26/20 10:46 Benzo(k)fluoranthene ug/L ND 10.0 08/26/20 10:46 Benzoic Acid ug/L ND 50.0 08/26/20 10:46 Benzyl alcohol ug/L ND 20.0 08/26/20 10:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 66 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2982551 Associated Lab Samples:92492009012 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 08/26/20 10:46 bis(2-Chloroethyl) ether ug/L ND 10.0 08/26/20 10:46 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 08/26/20 10:46 Butylbenzylphthalate ug/L ND 10.0 08/26/20 10:46 Chrysene ug/L ND 10.0 08/26/20 10:46 Di-n-butylphthalate ug/L ND 10.0 08/26/20 10:46 Di-n-octylphthalate ug/L ND 10.0 08/26/20 10:46 Dibenz(a,h)anthracene ug/L ND 10.0 08/26/20 10:46 Dibenzofuran ug/L ND 10.0 08/26/20 10:46 Diethylphthalate ug/L ND 10.0 08/26/20 10:46 Dimethylphthalate ug/L ND 10.0 08/26/20 10:46 Fluoranthene ug/L ND 10.0 08/26/20 10:46 Fluorene ug/L ND 10.0 08/26/20 10:46 Hexachloro-1,3-butadiene ug/L ND 10.0 08/26/20 10:46 Hexachlorobenzene ug/L ND 10.0 08/26/20 10:46 Hexachlorocyclopentadiene ug/L ND 10.0 08/26/20 10:46 Hexachloroethane ug/L ND 10.0 08/26/20 10:46 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 08/26/20 10:46 Isophorone ug/L ND 10.0 08/26/20 10:46 N-Nitroso-di-n-propylamine ug/L ND 10.0 08/26/20 10:46 N-Nitrosodimethylamine ug/L ND 10.0 08/26/20 10:46 N-Nitrosodiphenylamine ug/L ND 10.0 08/26/20 10:46 Naphthalene ug/L ND 10.0 08/26/20 10:46 Nitrobenzene ug/L ND 10.0 08/26/20 10:46 Pentachlorophenol ug/L ND 20.0 08/26/20 10:46 Phenanthrene ug/L ND 10.0 08/26/20 10:46 Phenol ug/L ND 10.0 08/26/20 10:46 Pyrene ug/L ND 10.0 08/26/20 10:46 2,4,6-Tribromophenol (S)%73 10-137 08/26/20 10:46 2-Fluorobiphenyl (S)%68 13-130 08/26/20 10:46 2-Fluorophenol (S)%56 10-130 08/26/20 10:46 Nitrobenzene-d5 (S)%79 13-130 08/26/20 10:46 Phenol-d6 (S)%43 10-130 08/26/20 10:46 Terphenyl-d14 (S)%101 25-130 08/26/20 10:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2982552LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 31.750 63 30-130 1,2-Dichlorobenzene ug/L 31.350 63 30-130 1,3-Dichlorobenzene ug/L 30.150 60 20-130 1,4-Dichlorobenzene ug/L 32.050 64 30-130 1-Methylnaphthalene ug/L 37.350 75 30-130 2,2'-Oxybis(1-chloropropane)ug/L 61.1 v15012220-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 67 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2982552LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 44.650 89 40-130 2,4,6-Trichlorophenol ug/L 42.350 85 40-130 2,4-Dichlorophenol ug/L 42.750 85 31-130 2,4-Dimethylphenol ug/L 48.550 97 30-130 2,4-Dinitrophenol ug/L 194250 78 30-130 2,4-Dinitrotoluene ug/L 47.050 94 49-130 2,6-Dinitrotoluene ug/L 48.250 96 50-130 2-Chloronaphthalene ug/L 42.050 84 30-130 2-Chlorophenol ug/L 42.650 85 30-130 2-Methylnaphthalene ug/L 38.650 77 30-130 2-Methylphenol(o-Cresol)ug/L 38.850 78 30-130 2-Nitroaniline ug/L 105100 105 40-130 2-Nitrophenol ug/L 45.950 92 20-130 3&4-Methylphenol(m&p Cresol)ug/L 35.950 72 20-130 3,3'-Dichlorobenzidine ug/L 83.2100 83 10-150 3-Nitroaniline ug/L 92.4100 92 40-130 4,6-Dinitro-2-methylphenol ug/L 90.0100 90 40-130 4-Bromophenylphenyl ether ug/L 43.150 86 30-130 4-Chloro-3-methylphenol ug/L 85.5100 86 30-130 4-Chloroaniline ug/L 86.0100 86 20-130 4-Chlorophenylphenyl ether ug/L 39.950 80 20-130 4-Nitroaniline ug/L 95.2100 95 40-130 4-Nitrophenol ug/L 127250 51 10-130 Acenaphthene ug/L 43.250 86 30-130 Acenaphthylene ug/L 44.650 89 30-130 Aniline ug/L 36.950 74 20-130 Anthracene ug/L 41.350 83 50-130 Benzo(a)anthracene ug/L 43.150 86 50-130 Benzo(a)pyrene ug/L 45.150 90 50-130 Benzo(b)fluoranthene ug/L 43.550 87 50-130 Benzo(g,h,i)perylene ug/L 46.250 92 50-130 Benzo(k)fluoranthene ug/L 45.350 91 50-130 Benzoic Acid ug/L 88.5250 35 10-130 Benzyl alcohol ug/L 77.2100 77 20-130 bis(2-Chloroethoxy)methane ug/L 44.350 89 30-130 bis(2-Chloroethyl) ether ug/L 44.550 89 30-130 bis(2-Ethylhexyl)phthalate ug/L 46.650 93 50-130 Butylbenzylphthalate ug/L 50.050 100 50-150 Chrysene ug/L 44.850 90 50-130 Di-n-butylphthalate ug/L 45.950 92 50-130 Di-n-octylphthalate ug/L 49.850 100 50-130 Dibenz(a,h)anthracene ug/L 45.450 91 40-130 Dibenzofuran ug/L 44.050 88 40-130 Diethylphthalate ug/L 44.950 90 40-130 Dimethylphthalate ug/L 43.950 88 40-130 Fluoranthene ug/L 44.250 88 30-130 Fluorene ug/L 42.850 86 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 68 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2982552LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 25.850 52 10-130 Hexachlorobenzene ug/L 41.450 83 30-130 Hexachlorocyclopentadiene ug/L 30.950 62 10-150 Hexachloroethane ug/L 26.950 54 10-130 Indeno(1,2,3-cd)pyrene ug/L 45.950 92 40-130 Isophorone ug/L 44.050 88 30-130 N-Nitroso-di-n-propylamine ug/L 45.850 92 30-130 N-Nitrosodimethylamine ug/L 36.450 73 10-130 N-Nitrosodiphenylamine ug/L 46.750 93 30-130 Naphthalene ug/L 37.650 75 20-130 Nitrobenzene ug/L 44.650 89 20-130 Pentachlorophenol ug/L 81.4100 81 10-140 Phenanthrene ug/L 44.950 90 50-130 Phenol ug/L 25.550 51 10-130 Pyrene ug/L 44.950 90 50-130 2,4,6-Tribromophenol (S)%91 10-137 2-Fluorobiphenyl (S)%83 13-130 2-Fluorophenol (S)%64 10-130 Nitrobenzene-d5 (S)%93 13-130 Phenol-d6 (S)%52 10-130 Terphenyl-d14 (S)%104 25-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 69 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562804 EPA 3546 EPA 8270E 8270E Solid MSSV Microwave Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009001, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2984509 Associated Lab Samples:92492009001, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007 Matrix:Solid Analyzed 1,2,4-Trichlorobenzene mg/kg ND 0.32 08/28/20 12:31 1,2-Dichlorobenzene mg/kg ND 0.32 08/28/20 12:31 1,3-Dichlorobenzene mg/kg ND 0.32 08/28/20 12:31 1,4-Dichlorobenzene mg/kg ND 0.32 08/28/20 12:31 1-Methylnaphthalene mg/kg ND 0.32 08/28/20 12:31 2,2'-Oxybis(1-chloropropane)mg/kg ND 0.32 08/28/20 12:31 2,4,5-Trichlorophenol mg/kg ND 0.32 08/28/20 12:31 2,4,6-Trichlorophenol mg/kg ND 0.32 08/28/20 12:31 2,4-Dichlorophenol mg/kg ND 0.32 08/28/20 12:31 2,4-Dimethylphenol mg/kg ND 0.32 08/28/20 12:31 2,4-Dinitrophenol mg/kg ND 1.6 08/28/20 12:31 2,4-Dinitrotoluene mg/kg ND 0.32 08/28/20 12:31 2,6-Dinitrotoluene mg/kg ND 0.32 08/28/20 12:31 2-Chloronaphthalene mg/kg ND 0.32 08/28/20 12:31 2-Chlorophenol mg/kg ND 0.32 08/28/20 12:31 2-Methylnaphthalene mg/kg ND 0.32 08/28/20 12:31 2-Methylphenol(o-Cresol)mg/kg ND 0.32 08/28/20 12:31 2-Nitroaniline mg/kg ND 1.6 08/28/20 12:31 2-Nitrophenol mg/kg ND 0.32 08/28/20 12:31 3&4-Methylphenol(m&p Cresol)mg/kg ND 0.32 08/28/20 12:31 3,3'-Dichlorobenzidine mg/kg ND 0.65 08/28/20 12:31 3-Nitroaniline mg/kg ND 1.6 08/28/20 12:31 4,6-Dinitro-2-methylphenol mg/kg ND 0.65 08/28/20 12:31 4-Bromophenylphenyl ether mg/kg ND 0.32 08/28/20 12:31 4-Chloro-3-methylphenol mg/kg ND 0.65 08/28/20 12:31 4-Chloroaniline mg/kg ND 0.65 08/28/20 12:31 4-Chlorophenylphenyl ether mg/kg ND 0.32 08/28/20 12:31 4-Nitroaniline mg/kg ND 0.65 08/28/20 12:31 4-Nitrophenol mg/kg ND 1.6 08/28/20 12:31 Acenaphthene mg/kg ND 0.32 08/28/20 12:31 Acenaphthylene mg/kg ND 0.32 08/28/20 12:31 Aniline mg/kg ND 0.32 08/28/20 12:31 Anthracene mg/kg ND 0.32 08/28/20 12:31 Benzo(a)anthracene mg/kg ND 0.32 08/28/20 12:31 Benzo(a)pyrene mg/kg ND 0.32 08/28/20 12:31 Benzo(b)fluoranthene mg/kg ND 0.32 08/28/20 12:31 Benzo(g,h,i)perylene mg/kg ND 0.32 08/28/20 12:31 Benzo(k)fluoranthene mg/kg ND 0.32 08/28/20 12:31 Benzoic Acid mg/kg ND 1.6 08/28/20 12:31 Benzyl alcohol mg/kg ND 0.65 08/28/20 12:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 70 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2984509 Associated Lab Samples:92492009001, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007 Matrix:Solid Analyzed bis(2-Chloroethoxy)methane mg/kg ND 0.32 08/28/20 12:31 bis(2-Chloroethyl) ether mg/kg ND 0.32 08/28/20 12:31 bis(2-Ethylhexyl)phthalate mg/kg ND 0.32 08/28/20 12:31 Butylbenzylphthalate mg/kg ND 0.32 08/28/20 12:31 Chrysene mg/kg ND 0.32 08/28/20 12:31 Di-n-butylphthalate mg/kg ND 0.32 08/28/20 12:31 Di-n-octylphthalate mg/kg ND 0.32 08/28/20 12:31 Dibenz(a,h)anthracene mg/kg ND 0.32 08/28/20 12:31 Dibenzofuran mg/kg ND 0.32 08/28/20 12:31 Diethylphthalate mg/kg ND 0.32 08/28/20 12:31 Dimethylphthalate mg/kg ND 0.32 08/28/20 12:31 Fluoranthene mg/kg ND 0.32 08/28/20 12:31 Fluorene mg/kg ND 0.32 08/28/20 12:31 Hexachloro-1,3-butadiene mg/kg ND 0.32 08/28/20 12:31 Hexachlorobenzene mg/kg ND 0.32 08/28/20 12:31 Hexachlorocyclopentadiene mg/kg ND 0.32 v208/28/20 12:31 Hexachloroethane mg/kg ND 0.32 08/28/20 12:31 Indeno(1,2,3-cd)pyrene mg/kg ND 0.32 08/28/20 12:31 Isophorone mg/kg ND 0.32 08/28/20 12:31 N-Nitroso-di-n-propylamine mg/kg ND 0.32 08/28/20 12:31 N-Nitrosodimethylamine mg/kg ND 0.32 08/28/20 12:31 N-Nitrosodiphenylamine mg/kg ND 0.32 08/28/20 12:31 Naphthalene mg/kg ND 0.32 08/28/20 12:31 Nitrobenzene mg/kg ND 0.32 08/28/20 12:31 Pentachlorophenol mg/kg ND 0.65 08/28/20 12:31 Phenanthrene mg/kg ND 0.32 08/28/20 12:31 Phenol mg/kg ND 0.32 08/28/20 12:31 Pyrene mg/kg ND 0.32 08/28/20 12:31 Pyridine mg/kg ND 0.32 08/28/20 12:31 2,4,6-Tribromophenol (S)%59 27-110 08/28/20 12:31 2-Fluorobiphenyl (S)%61 30-110 08/28/20 12:31 2-Fluorophenol (S)%64 13-110 08/28/20 12:31 Nitrobenzene-d5 (S)%62 23-110 08/28/20 12:31 Phenol-d6 (S)%66 22-110 08/28/20 12:31 Terphenyl-d14 (S)%74 28-110 08/28/20 12:31 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984510LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene mg/kg 1.21.6 72 52-130 1,2-Dichlorobenzene mg/kg 1.21.6 76 51-130 1,3-Dichlorobenzene mg/kg 1.21.6 75 50-130 1,4-Dichlorobenzene mg/kg 1.31.6 79 49-130 1-Methylnaphthalene mg/kg 1.11.6 70 55-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 71 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984510LABORATORY CONTROL SAMPLE: LCSSpike 2,2'-Oxybis(1-chloropropane)mg/kg 1.31.6 79 30-130 2,4,5-Trichlorophenol mg/kg 1.31.6 77 55-130 2,4,6-Trichlorophenol mg/kg 1.21.6 75 57-130 2,4-Dichlorophenol mg/kg 1.21.6 74 56-130 2,4-Dimethylphenol mg/kg 1.31.6 77 51-130 2,4-Dinitrophenol mg/kg 4.58.2 55 27-133 2,4-Dinitrotoluene mg/kg 1.31.6 78 61-130 2,6-Dinitrotoluene mg/kg 1.31.6 80 60-130 2-Chloronaphthalene mg/kg 1.21.6 74 52-130 2-Chlorophenol mg/kg 1.31.6 77 54-130 2-Methylnaphthalene mg/kg 1.21.6 74 54-130 2-Methylphenol(o-Cresol)mg/kg 1.31.6 79 51-130 2-Nitroaniline mg/kg 2.73.3 82 51-130 2-Nitrophenol mg/kg 1.21.6 74 49-130 3&4-Methylphenol(m&p Cresol)mg/kg 1.31.6 77 11-163 3,3'-Dichlorobenzidine mg/kg 2.43.3 72 10-132 3-Nitroaniline mg/kg 2.73.3 82 55-130 4,6-Dinitro-2-methylphenol mg/kg 2.03.3 60 47-142 4-Bromophenylphenyl ether mg/kg 1.21.6 75 59-130 4-Chloro-3-methylphenol mg/kg 2.63.3 78 55-130 4-Chloroaniline mg/kg 2.53.3 75 54-130 4-Chlorophenylphenyl ether mg/kg 1.21.6 76 58-130 4-Nitroaniline mg/kg 2.43.3 75 54-130 4-Nitrophenol mg/kg 6.58.2 79 48-130 Acenaphthene mg/kg 1.21.6 74 60-130 Acenaphthylene mg/kg 1.21.6 75 60-130 Aniline mg/kg 1.21.6 72 43-130 Anthracene mg/kg 1.11.6 68 63-130 Benzo(a)anthracene mg/kg 1.21.6 74 59-130 Benzo(a)pyrene mg/kg 1.21.6 75 57-130 Benzo(b)fluoranthene mg/kg 1.21.6 75 54-130 Benzo(g,h,i)perylene mg/kg 1.21.6 73 59-130 Benzo(k)fluoranthene mg/kg 1.21.6 75 54-130 Benzoic Acid mg/kg 4.88.2 58 19-130 Benzyl alcohol mg/kg 2.53.3 76 50-130 bis(2-Chloroethoxy)methane mg/kg 1.21.6 74 54-130 bis(2-Chloroethyl) ether mg/kg 1.31.6 76 48-130 bis(2-Ethylhexyl)phthalate mg/kg 1.31.6 78 45-134 Butylbenzylphthalate mg/kg 1.21.6 76 46-138 Chrysene mg/kg 1.21.6 76 58-130 Di-n-butylphthalate mg/kg 1.41.6 83 60-130 Di-n-octylphthalate mg/kg 1.31.6 81 53-130 Dibenz(a,h)anthracene mg/kg 1.21.6 74 59-130 Dibenzofuran mg/kg 1.31.6 77 60-130 Diethylphthalate mg/kg 1.31.6 81 60-130 Dimethylphthalate mg/kg 1.31.6 80 60-130 Fluoranthene mg/kg 1.31.6 78 65-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 72 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984510LABORATORY CONTROL SAMPLE: LCSSpike Fluorene mg/kg 1.21.6 76 63-130 Hexachloro-1,3-butadiene mg/kg 1.21.6 72 46-130 Hexachlorobenzene mg/kg 1.21.6 73 58-130 Hexachlorocyclopentadiene mg/kg 0.78 v31.6 48 23-130 Hexachloroethane mg/kg 1.21.6 73 47-130 Indeno(1,2,3-cd)pyrene mg/kg 1.21.6 72 60-130 Isophorone mg/kg 1.31.6 79 49-130 N-Nitroso-di-n-propylamine mg/kg 1.31.6 80 47-130 N-Nitrosodimethylamine mg/kg 1.31.6 78 45-130 N-Nitrosodiphenylamine mg/kg 1.21.6 76 59-130 Naphthalene mg/kg 1.21.6 73 55-130 Nitrobenzene mg/kg 1.21.6 76 49-130 Pentachlorophenol mg/kg 2.53.3 76 10-132 Phenanthrene mg/kg 1.21.6 76 62-130 Phenol mg/kg 1.21.6 76 46-130 Pyrene mg/kg 1.21.6 71 53-130 Pyridine mg/kg 1.11.6 67 37-130 2,4,6-Tribromophenol (S)%66 27-110 2-Fluorobiphenyl (S)%66 30-110 2-Fluorophenol (S)%69 13-110 Nitrobenzene-d5 (S)%68 23-110 Phenol-d6 (S)%70 22-110 Terphenyl-d14 (S)%71 28-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 2984511MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491985006 2984512 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene mg/kg 2.2 60 18-13052 132.2ND 1.3 1.1 1,2-Dichlorobenzene mg/kg 2.2 59 14-13052 112.2ND 1.3 1.1 1,3-Dichlorobenzene mg/kg 2.2 59 12-13052 112.2ND 1.3 1.1 1,4-Dichlorobenzene mg/kg 2.2 62 10-13054 112.2ND 1.3 1.2 1-Methylnaphthalene mg/kg 2.2 58 12-13049 142.2ND 1.2 1.1 2,2'-Oxybis(1-chloropropane)mg/kg v32.2 45 10-13040 102.2ND 0.96 0.87 2,4,5-Trichlorophenol mg/kg 2.2 64 13-13057 102.2ND 1.4 1.3 2,4,6-Trichlorophenol mg/kg 2.2 60 17-13053 112.2ND 1.3 1.2 2,4-Dichlorophenol mg/kg 2.2 66 10-13057 122.2ND 1.4 1.3 2,4-Dimethylphenol mg/kg 2.2 60 10-13052 132.2ND 1.3 1.1 2,4-Dinitrophenol mg/kg 10.8 18 10-130011ND1.9J ND 2,4-Dinitrotoluene mg/kg 2.2 64 24-13053 172.2ND 1.4 1.2 2,6-Dinitrotoluene mg/kg 2.2 64 23-13054 152.2ND 1.4 1.2 2-Chloronaphthalene mg/kg 2.2 58 19-13051 102.2ND 1.2 1.1 2-Chlorophenol mg/kg 2.2 66 10-13058 112.2ND 1.4 1.3 2-Methylnaphthalene mg/kg 2.2 60 18-13051 142.2ND 1.3 1.1 2-Methylphenol(o-Cresol)mg/kg 2.2 64 10-13055 132.2ND 1.4 1.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 73 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2984511MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491985006 2984512 MSD Result MSD % Rec RPD MSDMS Spike Conc. 2-Nitroaniline mg/kg v34.3 46 17-130394.4ND 2J 1.7J 2-Nitrophenol mg/kg 2.2 60 10-13045 272.2ND 1.3 0.98 3&4-Methylphenol(m&p Cresol)mg/kg 2.2 61 10-13053 102.2ND 1.3 1.2 3,3'-Dichlorobenzidine mg/kg 4.3 54 10-13046 154.4ND 2.3 2.0 3-Nitroaniline mg/kg 4.3 63 24-13051 204.4ND 2.7 2.2 4,6-Dinitro-2-methylphenol mg/kg 4.3 29 10-15204.4ND 1.3 ND 4-Bromophenylphenyl ether mg/kg 2.2 55 29-13049 112.2ND 1.2 1.1 4-Chloro-3-methylphenol mg/kg 4.3 62 17-13053 134.4ND 2.7 2.3 4-Chloroaniline mg/kg 4.3 61 14-13052 134.4ND 2.6 2.3 4-Chlorophenylphenyl ether mg/kg 2.2 56 25-13048 132.2ND 1.2 1.1 4-Nitroaniline mg/kg 4.3 66 22-13054 174.4ND 2.8 2.4 4-Nitrophenol mg/kg 10.8 53 10-13045 1511ND5.7 4.9 Acenaphthene mg/kg 2.2 56 20-13049 112.2ND 1.2 1.1 Acenaphthylene mg/kg 2.2 59 25-13051 112.2ND 1.3 1.1 Aniline mg/kg 2.2 55 10-13048 112.2ND 1.2 1.1 Anthracene mg/kg 2.2 53 29-13045 142.2ND 1.1 1.0 Benzo(a)anthracene mg/kg 2.2 55 19-13048 132.2ND 1.2 1.1 Benzo(a)pyrene mg/kg 2.2 55 12-13048 122.2ND 1.2 1.1 Benzo(b)fluoranthene mg/kg 2.2 53 14-13047 112.2ND 1.1 1.0 Benzo(g,h,i)perylene mg/kg 2.2 60 10-13051 152.2ND 1.3 1.1 Benzo(k)fluoranthene mg/kg 2.2 55 14-13049 102.2ND 1.2 1.1 Benzoic Acid mg/kg 10.8 27 10-1301611ND2.9 1.7J Benzyl alcohol mg/kg 4.3 60 13-13051 134.4ND 2.6 2.3 bis(2-Chloroethoxy)methane mg/kg 2.2 53 16-13046 132.2ND 1.2 1.0 bis(2-Chloroethyl) ether mg/kg 2.2 56 11-13049 112.2ND 1.2 1.1 bis(2-Ethylhexyl)phthalate mg/kg 2.2 49 21-13046 52.2ND 1.1 1.0 Butylbenzylphthalate mg/kg 2.2 48 23-13044 62.2ND 1.0 0.96 Chrysene mg/kg 2.2 56 22-13048 122.2ND 1.2 1.1 Di-n-butylphthalate mg/kg 2.2 58 30-13049 152.2ND 1.2 1.1 Di-n-octylphthalate mg/kg 2.2 61 23-14255 82.2ND 1.3 1.2 Dibenz(a,h)anthracene mg/kg 2.2 66 10-13056 152.2ND 1.4 1.2 Dibenzofuran mg/kg 2.2 60 24-13053 112.2ND 1.3 1.2 Diethylphthalate mg/kg 2.2 61 26-13052 132.2ND 1.3 1.2 Dimethylphthalate mg/kg 2.2 62 22-13053 132.2ND 1.3 1.2 Fluoranthene mg/kg 2.2 66 33-13054 182.2ND 1.4 1.2 Fluorene mg/kg 2.2 57 22-13049 132.2ND 1.2 1.1 Hexachloro-1,3-butadiene mg/kg 2.2 58 13-13050 132.2ND 1.3 1.1 Hexachlorobenzene mg/kg 2.2 57 29-13049 132.2ND 1.2 1.1 Hexachlorocyclopentadiene mg/kg v32.2 20 10-130162.2ND 0.44 .36J Hexachloroethane mg/kg 2.2 52 10-13046 102.2ND 1.1 1.0 Indeno(1,2,3-cd)pyrene mg/kg 2.2 60 10-13050 162.2ND 1.3 1.1 Isophorone mg/kg 2.2 53 13-13045 142.2ND 1.1 0.99 N-Nitroso-di-n-propylamine mg/kg 2.2 51 12-13044 132.2ND 1.1 0.96 N-Nitrosodimethylamine mg/kg 2.2 49 11-13042 142.2ND 1.1 0.92 N-Nitrosodiphenylamine mg/kg 2.2 51 15-13045 102.2ND 1.1 0.99 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 74 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2984511MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92491985006 2984512 MSD Result MSD % Rec RPD MSDMS Spike Conc. Naphthalene mg/kg 2.2 58 15-13050 132.2ND 1.2 1.1 Nitrobenzene mg/kg 2.2 48 12-13041 162.2ND 1.0 0.89 Pentachlorophenol mg/kg 4.3 53 10-13045 134.4ND 2.3 2.0 Phenanthrene mg/kg 2.2 58 27-13049 132.2ND 1.2 1.1 Phenol mg/kg 2.2 62 10-13053 132.2ND 1.3 1.2 Pyrene mg/kg 2.2 49 19-13045 72.2ND 1.1 0.99 Pyridine mg/kg 2.2 43 10-13037 132.2ND 0.92 0.81 2,4,6-Tribromophenol (S)%65 27-11055 2-Fluorobiphenyl (S)%52 30-11044 2-Fluorophenol (S)%56 13-11047 Nitrobenzene-d5 (S)%46 23-11038 Phenol-d6 (S)%59 22-11049 Terphenyl-d14 (S)%52 28-11044 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 75 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562839 EPA 3546 EPA 8270E 8270E Solid MSSV Microwave Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009008, 92492009009, 92492009010, 92492009011, 92492009014, 92492009015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2984727 Associated Lab Samples:92492009008, 92492009009, 92492009010, 92492009011, 92492009014, 92492009015 Matrix:Solid Analyzed 1,2,4-Trichlorobenzene mg/kg ND 0.33 08/28/20 15:13 1,2-Dichlorobenzene mg/kg ND 0.33 08/28/20 15:13 1,3-Dichlorobenzene mg/kg ND 0.33 08/28/20 15:13 1,4-Dichlorobenzene mg/kg ND 0.33 08/28/20 15:13 1-Methylnaphthalene mg/kg ND 0.33 08/28/20 15:13 2,2'-Oxybis(1-chloropropane)mg/kg ND 0.33 08/28/20 15:13 2,4,5-Trichlorophenol mg/kg ND 0.33 08/28/20 15:13 2,4,6-Trichlorophenol mg/kg ND 0.33 08/28/20 15:13 2,4-Dichlorophenol mg/kg ND 0.33 08/28/20 15:13 2,4-Dimethylphenol mg/kg ND 0.33 08/28/20 15:13 2,4-Dinitrophenol mg/kg ND 1.6 08/28/20 15:13 2,4-Dinitrotoluene mg/kg ND 0.33 08/28/20 15:13 2,6-Dinitrotoluene mg/kg ND 0.33 08/28/20 15:13 2-Chloronaphthalene mg/kg ND 0.33 08/28/20 15:13 2-Chlorophenol mg/kg ND 0.33 08/28/20 15:13 2-Methylnaphthalene mg/kg ND 0.33 08/28/20 15:13 2-Methylphenol(o-Cresol)mg/kg ND 0.33 08/28/20 15:13 2-Nitroaniline mg/kg ND 1.6 08/28/20 15:13 2-Nitrophenol mg/kg ND 0.33 08/28/20 15:13 3&4-Methylphenol(m&p Cresol)mg/kg ND 0.33 08/28/20 15:13 3,3'-Dichlorobenzidine mg/kg ND 0.65 08/28/20 15:13 3-Nitroaniline mg/kg ND 1.6 08/28/20 15:13 4,6-Dinitro-2-methylphenol mg/kg ND 0.65 08/28/20 15:13 4-Bromophenylphenyl ether mg/kg ND 0.33 08/28/20 15:13 4-Chloro-3-methylphenol mg/kg ND 0.65 08/28/20 15:13 4-Chloroaniline mg/kg ND 0.65 08/28/20 15:13 4-Chlorophenylphenyl ether mg/kg ND 0.33 08/28/20 15:13 4-Nitroaniline mg/kg ND 0.65 08/28/20 15:13 4-Nitrophenol mg/kg ND 1.6 08/28/20 15:13 Acenaphthene mg/kg ND 0.33 08/28/20 15:13 Acenaphthylene mg/kg ND 0.33 08/28/20 15:13 Aniline mg/kg ND 0.33 08/28/20 15:13 Anthracene mg/kg ND 0.33 08/28/20 15:13 Benzo(a)anthracene mg/kg ND 0.33 08/28/20 15:13 Benzo(a)pyrene mg/kg ND 0.33 08/28/20 15:13 Benzo(b)fluoranthene mg/kg ND 0.33 08/28/20 15:13 Benzo(g,h,i)perylene mg/kg ND 0.33 08/28/20 15:13 Benzo(k)fluoranthene mg/kg ND 0.33 08/28/20 15:13 Benzoic Acid mg/kg ND 1.6 08/28/20 15:13 Benzyl alcohol mg/kg ND 0.65 08/28/20 15:13 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 76 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2984727 Associated Lab Samples:92492009008, 92492009009, 92492009010, 92492009011, 92492009014, 92492009015 Matrix:Solid Analyzed bis(2-Chloroethoxy)methane mg/kg ND 0.33 08/28/20 15:13 bis(2-Chloroethyl) ether mg/kg ND 0.33 08/28/20 15:13 bis(2-Ethylhexyl)phthalate mg/kg ND 0.33 08/28/20 15:13 Butylbenzylphthalate mg/kg ND 0.33 08/28/20 15:13 Chrysene mg/kg ND 0.33 08/28/20 15:13 Di-n-butylphthalate mg/kg ND 0.33 08/28/20 15:13 Di-n-octylphthalate mg/kg ND 0.33 08/28/20 15:13 Dibenz(a,h)anthracene mg/kg ND 0.33 08/28/20 15:13 Dibenzofuran mg/kg ND 0.33 08/28/20 15:13 Diethylphthalate mg/kg ND 0.33 08/28/20 15:13 Dimethylphthalate mg/kg ND 0.33 08/28/20 15:13 Fluoranthene mg/kg ND 0.33 08/28/20 15:13 Fluorene mg/kg ND 0.33 08/28/20 15:13 Hexachloro-1,3-butadiene mg/kg ND 0.33 08/28/20 15:13 Hexachlorobenzene mg/kg ND 0.33 08/28/20 15:13 Hexachlorocyclopentadiene mg/kg ND 0.33 v208/28/20 15:13 Hexachloroethane mg/kg ND 0.33 08/28/20 15:13 Indeno(1,2,3-cd)pyrene mg/kg ND 0.33 08/28/20 15:13 Isophorone mg/kg ND 0.33 08/28/20 15:13 N-Nitroso-di-n-propylamine mg/kg ND 0.33 08/28/20 15:13 N-Nitrosodimethylamine mg/kg ND 0.33 08/28/20 15:13 N-Nitrosodiphenylamine mg/kg ND 0.33 08/28/20 15:13 Naphthalene mg/kg ND 0.33 08/28/20 15:13 Nitrobenzene mg/kg ND 0.33 08/28/20 15:13 Pentachlorophenol mg/kg ND 0.65 08/28/20 15:13 Phenanthrene mg/kg ND 0.33 08/28/20 15:13 Phenol mg/kg ND 0.33 08/28/20 15:13 Pyrene mg/kg ND 0.33 08/28/20 15:13 Pyridine mg/kg ND 0.33 08/28/20 15:13 2,4,6-Tribromophenol (S)%59 27-110 08/28/20 15:13 2-Fluorobiphenyl (S)%60 30-110 08/28/20 15:13 2-Fluorophenol (S)%63 13-110 08/28/20 15:13 Nitrobenzene-d5 (S)%64 23-110 08/28/20 15:13 Phenol-d6 (S)%66 22-110 08/28/20 15:13 Terphenyl-d14 (S)%76 28-110 08/28/20 15:13 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984728LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene mg/kg 1.11.6 70 52-130 1,2-Dichlorobenzene mg/kg 1.21.6 74 51-130 1,3-Dichlorobenzene mg/kg 1.21.6 73 50-130 1,4-Dichlorobenzene mg/kg 1.21.6 76 49-130 1-Methylnaphthalene mg/kg 1.11.6 68 55-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 77 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984728LABORATORY CONTROL SAMPLE: LCSSpike 2,2'-Oxybis(1-chloropropane)mg/kg 1.31.6 79 30-130 2,4,5-Trichlorophenol mg/kg 1.21.6 72 55-130 2,4,6-Trichlorophenol mg/kg 1.11.6 70 57-130 2,4-Dichlorophenol mg/kg 1.21.6 71 56-130 2,4-Dimethylphenol mg/kg 1.21.6 74 51-130 2,4-Dinitrophenol mg/kg 4.08.2 49 27-133 2,4-Dinitrotoluene mg/kg 1.21.6 76 61-130 2,6-Dinitrotoluene mg/kg 1.21.6 75 60-130 2-Chloronaphthalene mg/kg 1.21.6 71 52-130 2-Chlorophenol mg/kg 1.31.6 76 54-130 2-Methylnaphthalene mg/kg 1.21.6 72 54-130 2-Methylphenol(o-Cresol)mg/kg 1.31.6 78 51-130 2-Nitroaniline mg/kg 2.53.3 77 51-130 2-Nitrophenol mg/kg 1.21.6 73 49-130 3&4-Methylphenol(m&p Cresol)mg/kg 1.31.6 78 11-163 3,3'-Dichlorobenzidine mg/kg 2.23.3 66 10-132 3-Nitroaniline mg/kg 2.53.3 77 55-130 4,6-Dinitro-2-methylphenol mg/kg 1.73.3 52 47-142 4-Bromophenylphenyl ether mg/kg 1.11.6 70 59-130 4-Chloro-3-methylphenol mg/kg 2.53.3 75 55-130 4-Chloroaniline mg/kg 2.43.3 72 54-130 4-Chlorophenylphenyl ether mg/kg 1.21.6 71 58-130 4-Nitroaniline mg/kg 2.53.3 75 54-130 4-Nitrophenol mg/kg 6.28.2 76 48-130 Acenaphthene mg/kg 1.11.6 70 60-130 Acenaphthylene mg/kg 1.21.6 71 60-130 Aniline mg/kg 1.21.6 71 43-130 Anthracene mg/kg 1.01.6 63 63-130 Benzo(a)anthracene mg/kg 1.11.6 70 59-130 Benzo(a)pyrene mg/kg 1.21.6 71 57-130 Benzo(b)fluoranthene mg/kg 1.21.6 71 54-130 Benzo(g,h,i)perylene mg/kg 1.11.6 67 59-130 Benzo(k)fluoranthene mg/kg 1.21.6 74 54-130 Benzoic Acid mg/kg 3.98.2 48 19-130 Benzyl alcohol mg/kg 2.43.3 75 50-130 bis(2-Chloroethoxy)methane mg/kg 1.21.6 73 54-130 bis(2-Chloroethyl) ether mg/kg 1.21.6 76 48-130 bis(2-Ethylhexyl)phthalate mg/kg 1.31.6 76 45-134 Butylbenzylphthalate mg/kg 1.21.6 75 46-138 Chrysene mg/kg 1.21.6 71 58-130 Di-n-butylphthalate mg/kg 1.31.6 79 60-130 Di-n-octylphthalate mg/kg 1.31.6 78 53-130 Dibenz(a,h)anthracene mg/kg 1.11.6 68 59-130 Dibenzofuran mg/kg 1.21.6 72 60-130 Diethylphthalate mg/kg 1.31.6 78 60-130 Dimethylphthalate mg/kg 1.21.6 74 60-130 Fluoranthene mg/kg 1.21.6 73 65-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 78 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984728LABORATORY CONTROL SAMPLE: LCSSpike Fluorene mg/kg 1.21.6 72 63-130 Hexachloro-1,3-butadiene mg/kg 1.11.6 69 46-130 Hexachlorobenzene mg/kg 1.11.6 67 58-130 Hexachlorocyclopentadiene mg/kg 0.74 v21.6 45 23-130 Hexachloroethane mg/kg 1.21.6 74 47-130 Indeno(1,2,3-cd)pyrene mg/kg 1.11.6 67 60-130 Isophorone mg/kg 1.31.6 77 49-130 N-Nitroso-di-n-propylamine mg/kg 1.31.6 80 47-130 N-Nitrosodimethylamine mg/kg 1.21.6 75 45-130 N-Nitrosodiphenylamine mg/kg 1.21.6 72 59-130 Naphthalene mg/kg 1.21.6 70 55-130 Nitrobenzene mg/kg 1.21.6 74 49-130 Pentachlorophenol mg/kg 2.33.3 71 10-132 Phenanthrene mg/kg 1.21.6 70 62-130 Phenol mg/kg 1.21.6 76 46-130 Pyrene mg/kg 1.11.6 67 53-130 Pyridine mg/kg 1.11.6 66 37-130 2,4,6-Tribromophenol (S)%68 27-110 2-Fluorobiphenyl (S)%68 30-110 2-Fluorophenol (S)%74 13-110 Nitrobenzene-d5 (S)%71 23-110 Phenol-d6 (S)%75 22-110 Terphenyl-d14 (S)%74 28-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 2984729MATRIX SPIKE SAMPLE: MSSpike Result 92492009009 1,2,4-Trichlorobenzene mg/kg 1.22 62 18-130ND 1,2-Dichlorobenzene mg/kg 1.42 68 14-130ND 1,3-Dichlorobenzene mg/kg 1.32 67 12-130ND 1,4-Dichlorobenzene mg/kg 1.42 72 10-130ND 1-Methylnaphthalene mg/kg 1.12 56 12-130ND 2,2'-Oxybis(1-chloropropane)mg/kg 1.4 v226810-130ND 2,4,5-Trichlorophenol mg/kg 1.42 70 13-130ND 2,4,6-Trichlorophenol mg/kg 1.42 71 17-130ND 2,4-Dichlorophenol mg/kg 1.22 62 10-130ND 2,4-Dimethylphenol mg/kg 0.752 38 10-130ND 2,4-Dinitrophenol mg/kg 4.110 41 10-130ND 2,4-Dinitrotoluene mg/kg 1.22 62 24-130ND 2,6-Dinitrotoluene mg/kg 0.912 46 23-130ND 2-Chloronaphthalene mg/kg 1.32 63 19-130ND 2-Chlorophenol mg/kg 1.42 72 10-130ND 2-Methylnaphthalene mg/kg 1.22 60 18-130ND 2-Methylphenol(o-Cresol)mg/kg 1.02 51 10-130ND 2-Nitroaniline mg/kg 1.9J v24.1 47 17-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 79 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 2984729MATRIX SPIKE SAMPLE: MSSpike Result 92492009009 2-Nitrophenol mg/kg 1.32 64 10-130ND 3&4-Methylphenol(m&p Cresol)mg/kg 1.12 56 10-130ND 3,3'-Dichlorobenzidine mg/kg 1.74.1 43 10-130ND 3-Nitroaniline mg/kg 2.24.1 55 24-130ND 4,6-Dinitro-2-methylphenol mg/kg 2.74.1 66 10-152ND 4-Bromophenylphenyl ether mg/kg 1.32 65 29-130ND 4-Chloro-3-methylphenol mg/kg 2.24.1 54 17-130ND 4-Chloroaniline mg/kg 2.34.1 58 14-130ND 4-Chlorophenylphenyl ether mg/kg 1.32 64 25-130ND 4-Nitroaniline mg/kg 2.44.1 60 22-130ND 4-Nitrophenol mg/kg 4.510 45 10-130ND Acenaphthene mg/kg 1.22 58 20-130ND Acenaphthylene mg/kg 1.22 61 25-130ND Aniline mg/kg 0.752 37 10-130ND Anthracene mg/kg 0.972 49 29-130ND Benzo(a)anthracene mg/kg 1.12 53 19-130ND Benzo(a)pyrene mg/kg 1.02 50 12-130ND Benzo(b)fluoranthene mg/kg 0.992 50 14-130ND Benzo(g,h,i)perylene mg/kg 1.12 54 10-130ND Benzo(k)fluoranthene mg/kg 1.02 51 14-130ND Benzoic Acid mg/kg 1.2J10 12 10-130ND Benzyl alcohol mg/kg 2.64.1 65 13-130ND bis(2-Chloroethoxy)methane mg/kg 1.12 57 16-130ND bis(2-Chloroethyl) ether mg/kg 1.32 64 11-130ND bis(2-Ethylhexyl)phthalate mg/kg 0.952 47 21-130ND Butylbenzylphthalate mg/kg 0.952 48 23-130ND Chrysene mg/kg 1.12 54 22-130ND Di-n-butylphthalate mg/kg 1.02 52 30-130ND Di-n-octylphthalate mg/kg 0.972 48 23-142ND Dibenz(a,h)anthracene mg/kg 1.02 52 10-130ND Dibenzofuran mg/kg 1.22 61 24-130ND Diethylphthalate mg/kg 1.22 62 26-130ND Dimethylphthalate mg/kg 1.32 64 22-130ND Fluoranthene mg/kg 1.12 54 33-130ND Fluorene mg/kg 1.22 58 22-130ND Hexachloro-1,3-butadiene mg/kg 1.32 67 13-130ND Hexachlorobenzene mg/kg 1.32 64 29-130ND Hexachlorocyclopentadiene mg/kg 0.91 v224610-130ND Hexachloroethane mg/kg 1.32 65 10-130ND Indeno(1,2,3-cd)pyrene mg/kg 1.12 53 10-130ND Isophorone mg/kg 0.992 50 13-130ND N-Nitroso-di-n-propylamine mg/kg 1.02 52 12-130ND N-Nitrosodimethylamine mg/kg 1.02 50 11-130ND N-Nitrosodiphenylamine mg/kg 1.12 55 15-130ND Naphthalene mg/kg 1.22 62 15-130ND Nitrobenzene mg/kg 0.972 48 12-130ND Pentachlorophenol mg/kg 2.64.1 64 10-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 80 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 2984729MATRIX SPIKE SAMPLE: MSSpike Result 92492009009 Phenanthrene mg/kg 1.12 54 27-130ND Phenol mg/kg 1.32 64 10-130ND Pyrene mg/kg 1.02 52 19-130ND Pyridine mg/kg 0.842 42 10-130ND 2,4,6-Tribromophenol (S)%71 27-110 2-Fluorobiphenyl (S)%59 30-110 2-Fluorophenol (S)%59 13-110 Nitrobenzene-d5 (S)%48 23-110 Phenol-d6 (S)%60 22-110 Terphenyl-d14 (S)%55 28-110 Parameter Units Dup Result QualifiersRPDResult 92492009014 2984730SAMPLE DUPLICATE: 1,2,4-Trichlorobenzene mg/kg NDND 1,2-Dichlorobenzene mg/kg NDND 1,3-Dichlorobenzene mg/kg NDND 1,4-Dichlorobenzene mg/kg NDND 1-Methylnaphthalene mg/kg NDND 2,2'-Oxybis(1-chloropropane)mg/kg ND v2ND 2,4,5-Trichlorophenol mg/kg NDND 2,4,6-Trichlorophenol mg/kg NDND 2,4-Dichlorophenol mg/kg NDND 2,4-Dimethylphenol mg/kg NDND 2,4-Dinitrophenol mg/kg NDND 2,4-Dinitrotoluene mg/kg NDND 2,6-Dinitrotoluene mg/kg NDND 2-Chloronaphthalene mg/kg NDND 2-Chlorophenol mg/kg NDND 2-Methylnaphthalene mg/kg NDND 2-Methylphenol(o-Cresol)mg/kg NDND 2-Nitroaniline mg/kg ND v2ND 2-Nitrophenol mg/kg NDND 3&4-Methylphenol(m&p Cresol)mg/kg NDND 3,3'-Dichlorobenzidine mg/kg NDND 3-Nitroaniline mg/kg NDND 4,6-Dinitro-2-methylphenol mg/kg NDND 4-Bromophenylphenyl ether mg/kg NDND 4-Chloro-3-methylphenol mg/kg NDND 4-Chloroaniline mg/kg NDND 4-Chlorophenylphenyl ether mg/kg NDND 4-Nitroaniline mg/kg NDND 4-Nitrophenol mg/kg NDND Acenaphthene mg/kg NDND Acenaphthylene mg/kg NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 81 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92492009014 2984730SAMPLE DUPLICATE: Aniline mg/kg NDND Anthracene mg/kg NDND Benzo(a)anthracene mg/kg NDND Benzo(a)pyrene mg/kg NDND Benzo(b)fluoranthene mg/kg NDND Benzo(g,h,i)perylene mg/kg NDND Benzo(k)fluoranthene mg/kg NDND Benzoic Acid mg/kg NDND Benzyl alcohol mg/kg NDND bis(2-Chloroethoxy)methane mg/kg NDND bis(2-Chloroethyl) ether mg/kg NDND bis(2-Ethylhexyl)phthalate mg/kg NDND Butylbenzylphthalate mg/kg NDND Chrysene mg/kg NDND Di-n-butylphthalate mg/kg NDND Di-n-octylphthalate mg/kg NDND Dibenz(a,h)anthracene mg/kg NDND Dibenzofuran mg/kg NDND Diethylphthalate mg/kg NDND Dimethylphthalate mg/kg NDND Fluoranthene mg/kg NDND Fluorene mg/kg NDND Hexachloro-1,3-butadiene mg/kg NDND Hexachlorobenzene mg/kg NDND Hexachlorocyclopentadiene mg/kg ND v2ND Hexachloroethane mg/kg NDND Indeno(1,2,3-cd)pyrene mg/kg NDND Isophorone mg/kg NDND N-Nitroso-di-n-propylamine mg/kg NDND N-Nitrosodimethylamine mg/kg NDND N-Nitrosodiphenylamine mg/kg NDND Naphthalene mg/kg NDND Nitrobenzene mg/kg NDND Pentachlorophenol mg/kg NDND Phenanthrene mg/kg NDND Phenol mg/kg NDND Pyrene mg/kg NDND Pyridine mg/kg NDND 2,4,6-Tribromophenol (S)%5766 2-Fluorobiphenyl (S)%4450 2-Fluorophenol (S)%4651 Nitrobenzene-d5 (S)%3843 Phenol-d6 (S)%4754 Terphenyl-d14 (S)%5956 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 82 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562160 MADEP EPH MADEP EPH MADEP EPH NC Soil Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009014 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2981523 Associated Lab Samples:92492009014 Matrix:Solid Analyzed Aliphatic (C09-C18)mg/kg ND 10 N208/26/20 07:10 Aliphatic (C19-C36)mg/kg ND 10 N208/26/20 07:10 Aromatic (C11-C22)mg/kg ND 10 N208/26/20 07:10 1-Chlorooctadecane (S)%58 40-140 08/26/20 07:10 2-Bromonaphthalene (S)%95 40-140 08/26/20 07:10 2-Fluorobiphenyl (S)%94 40-140 08/26/20 07:10 o-Terphenyl (S)%68 40-140 08/26/20 07:10 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2981524LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 2981525 Aliphatic (C09-C18)mg/kg ND N210.1 48 40-14055ND 50 Aliphatic (C19-C36)mg/kg ND N213.4 70 40-1408010.9 50 Aromatic (C11-C22)mg/kg 17.8 N228.5 62 40-1407321.0 16 50 1-Chlorooctadecane (S)%67 40-14072 2-Bromonaphthalene (S)%87 40-14097 2-Fluorobiphenyl (S)%84 40-14095 o-Terphenyl (S)%65 40-14077 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 83 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562714 MADEP EPH MADEP EPH MADEP EPH NC Soil Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009015 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2984189 Associated Lab Samples:92492009015 Matrix:Solid Analyzed Aliphatic (C09-C18)mg/kg ND 10.1 N208/28/20 09:56 Aliphatic (C19-C36)mg/kg ND 10.1 N208/28/20 09:56 Aromatic (C11-C22)mg/kg ND 10.1 N208/28/20 09:56 2-Bromonaphthalene (S)%107 40-140 08/28/20 09:56 2-Fluorobiphenyl (S)%105 40-140 08/28/20 09:56 Nonatriacontane (S)%87 40-140 08/28/20 09:56 o-Terphenyl (S)%81 40-140 08/28/20 09:56 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2984190LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 2984191 Aliphatic (C09-C18)mg/kg ND N29.9 49 40-14064ND 50 Aliphatic (C19-C36)mg/kg ND N213.2 66 40-1408811.6 50 Aromatic (C11-C22)mg/kg 16.3 N228.1 58 40-1408222.8 33 50 2-Bromonaphthalene (S)%95 40-140113 2-Fluorobiphenyl (S)%93 40-140109 Nonatriacontane (S)%62 40-14089 o-Terphenyl (S)%61 40-14087 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 84 of 90 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492009 Northstate Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 562170 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492009001, 92492009002, 92492009003, 92492009004, 92492009005, 92492009006, 92492009007, 92492009008, 92492009009, 92492009010, 92492009011, 92492009014, 92492009015 Parameter Units Dup Result QualifiersRPDResult 92488411001 2981581SAMPLE DUPLICATE: Percent Moisture %26.8 425.9 Parameter Units Dup Result QualifiersRPDResult 92492009015 2981582SAMPLE DUPLICATE: Percent Moisture %21.7 420.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 85 of 90 #=QL# QUALIFIERS Pace Project No.: Project: 92492009 Northstate DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value.IK Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request.N2 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias.v1 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias.v3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 86 of 90 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92492009 Northstate Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92492009014 562160 562533T-1 MADEP EPH MADEP EPH 92492009015 562714 563152P-1 MADEP EPH MADEP EPH 92492009012 562342 562440GW-1 EPA 3510C EPA 8270E 92492009013 562199 562214GW-2 EPA 3510C EPA 8270E 92492009001 562804 563117GP-1 (8270)EPA 3546 EPA 8270E 92492009003 562804 563117GP-2 EPA 3546 EPA 8270E 92492009004 562804 563117GP-3 EPA 3546 EPA 8270E 92492009005 562804 563117GP-4 EPA 3546 EPA 8270E 92492009006 562804 563117GP-5 EPA 3546 EPA 8270E 92492009007 562804 563117GP-6 EPA 3546 EPA 8270E 92492009008 562839 563121GP-7 EPA 3546 EPA 8270E 92492009009 562839 563121GP-8 EPA 3546 EPA 8270E 92492009010 562839 563121HA-1 EPA 3546 EPA 8270E 92492009011 562839 563121HA-2 EPA 3546 EPA 8270E 92492009014 562839 563121T-1 EPA 3546 EPA 8270E 92492009015 562839 563121P-1 EPA 3546 EPA 8270E 92492009002 562180 562188GP-1 (8260)EPA 5035A/5030B EPA 8260D 92492009003 562180 562188GP-2 EPA 5035A/5030B EPA 8260D 92492009004 562180 562188GP-3 EPA 5035A/5030B EPA 8260D 92492009005 562180 562188GP-4 EPA 5035A/5030B EPA 8260D 92492009006 562180 562188GP-5 EPA 5035A/5030B EPA 8260D 92492009007 562180 562188GP-6 EPA 5035A/5030B EPA 8260D 92492009008 562180 562188GP-7 EPA 5035A/5030B EPA 8260D 92492009009 562180 562188GP-8 EPA 5035A/5030B EPA 8260D 92492009010 562180 562188HA-1 EPA 5035A/5030B EPA 8260D 92492009011 562180 562188HA-2 EPA 5035A/5030B EPA 8260D 92492009012 562268GW-1 EPA 8260D 92492009013 562268GW-2 EPA 8260D 92492009001 562170GP-1 (8270)ASTM D2974-87 92492009002 562170GP-1 (8260)ASTM D2974-87 92492009003 562170GP-2 ASTM D2974-87 92492009004 562170GP-3 ASTM D2974-87 92492009005 562170GP-4 ASTM D2974-87 92492009006 562170GP-5 ASTM D2974-87 92492009007 562170GP-6 ASTM D2974-87 92492009008 562170GP-7 ASTM D2974-87 92492009009 562170GP-8 ASTM D2974-87 92492009010 562170HA-1 ASTM D2974-87 92492009011 562170HA-2 ASTM D2974-87 92492009014 562170T-1 ASTM D2974-87 92492009015 562170P-1 ASTM D2974-87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 08/28/2020 05:43 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 87 of 90 Page 88 of 90 Page 89 of 90 Page 90 of 90 #=CL# January 04, 2021 LIMS USE: FR - RANDY CAVALLIER LIMS OBJECT ID: 92512363 92512363 Project: Pace Project No.: RE: Mr. Randy Cavallier ECS Southeast, LLP 4811 Koger Blvd. Greensboro, NC 27407 NorthState Dear Mr. Cavallier: Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte A revised laboratory report is being submitted on 1/4/2021 to revise all units to mg/kg, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com Project Manager (704)875-9092 Enclosures cc:ECS Southeast Reporting, ECS Southeast REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 31 #=CP# CERTIFICATIONS Pace Project No.: Project: 92512363 NorthState Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 31 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92512363 NorthState Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92512363001 HA-3 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363002 HA-4 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363003 HA-5 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363004 HA-6 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363005 HA-7 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363006 HA-8 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363007 HA-9 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF 92512363008 HA-10 EPA 8270E 74 PASI-CBPJ ASTM D2974-87 1 PASI-CKDF PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-3 Lab ID:92512363001 Collected:12/15/20 12:30 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 13:38 83-32-912/17/20 12:170.39 1 Acenaphthylene ND mg/kg 12/18/20 13:38 208-96-812/17/20 12:170.39 1 Aniline ND mg/kg 12/18/20 13:38 62-53-312/17/20 12:170.39 1 Anthracene 0.39 mg/kg 12/18/20 13:38 120-12-712/17/20 12:170.39 1 Benzo(a)anthracene 0.99 mg/kg 12/18/20 13:38 56-55-312/17/20 12:170.39 1 Benzo(a)pyrene 0.97 mg/kg 12/18/20 13:38 50-32-812/17/20 12:170.39 1 Benzo(b)fluoranthene 3.2 mg/kg 12/18/20 13:38 205-99-212/17/20 12:170.39 1 Benzo(g,h,i)perylene 0.59 mg/kg 12/18/20 13:38 191-24-212/17/20 12:170.39 1 Benzo(k)fluoranthene 1.2 mg/kg 12/18/20 13:38 207-08-912/17/20 12:170.39 1 Benzoic Acid ND mg/kg 12/18/20 13:38 65-85-012/17/20 12:171.9 1 Benzyl alcohol ND mg/kg 12/18/20 13:38 100-51-612/17/20 12:170.78 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 13:38 101-55-312/17/20 12:170.39 1 Butylbenzylphthalate ND mg/kg 12/18/20 13:38 85-68-712/17/20 12:170.39 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 13:38 59-50-712/17/20 12:170.78 1 4-Chloroaniline ND mg/kg 12/18/20 13:38 106-47-812/17/20 12:170.78 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 13:38 111-91-112/17/20 12:170.39 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 13:38 111-44-412/17/20 12:170.39 1 2-Chloronaphthalene ND mg/kg 12/18/20 13:38 91-58-712/17/20 12:170.39 1 2-Chlorophenol ND mg/kg 12/18/20 13:38 95-57-812/17/20 12:170.39 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 13:38 7005-72-312/17/20 12:170.39 1 Chrysene 2.2 mg/kg 12/18/20 13:38 218-01-912/17/20 12:170.39 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 13:38 53-70-312/17/20 12:170.39 1 Dibenzofuran ND mg/kg 12/18/20 13:38 132-64-912/17/20 12:170.39 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 13:38 95-50-112/17/20 12:170.39 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 13:38 541-73-112/17/20 12:170.39 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 13:38 106-46-712/17/20 12:170.39 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 13:38 91-94-112/17/20 12:170.78 1 2,4-Dichlorophenol ND mg/kg 12/18/20 13:38 120-83-212/17/20 12:170.39 1 Diethylphthalate ND mg/kg 12/18/20 13:38 84-66-212/17/20 12:170.39 1 2,4-Dimethylphenol ND mg/kg 12/18/20 13:38 105-67-912/17/20 12:170.39 1 Dimethylphthalate ND mg/kg 12/18/20 13:38 131-11-312/17/20 12:170.39 1 Di-n-butylphthalate ND mg/kg 12/18/20 13:38 84-74-212/17/20 12:170.39 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 13:38 534-52-1 v112/17/20 12:170.78 1 2,4-Dinitrophenol ND mg/kg 12/18/20 13:38 51-28-5 v112/17/20 12:171.9 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 13:38 121-14-212/17/20 12:170.39 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 13:38 606-20-212/17/20 12:170.39 1 Di-n-octylphthalate ND mg/kg 12/18/20 13:38 117-84-012/17/20 12:170.39 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 13:38 117-81-712/17/20 12:170.39 1 Fluoranthene 3.0 mg/kg 12/18/20 13:38 206-44-012/17/20 12:170.39 1 Fluorene ND mg/kg 12/18/20 13:38 86-73-712/17/20 12:170.39 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 13:38 87-68-312/17/20 12:170.39 1 Hexachlorobenzene ND mg/kg 12/18/20 13:38 118-74-112/17/20 12:170.39 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 13:38 77-47-412/17/20 12:170.39 1 Hexachloroethane ND mg/kg 12/18/20 13:38 67-72-112/17/20 12:170.39 1 Indeno(1,2,3-cd)pyrene 0.60 mg/kg 12/18/20 13:38 193-39-512/17/20 12:170.39 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-3 Lab ID:92512363001 Collected:12/15/20 12:30 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 13:38 78-59-112/17/20 12:170.39 1 1-Methylnaphthalene ND mg/kg 12/18/20 13:38 90-12-012/17/20 12:170.39 1 2-Methylnaphthalene ND mg/kg 12/18/20 13:38 91-57-612/17/20 12:170.39 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 13:38 95-48-712/17/20 12:170.39 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 13:38 15831-10-412/17/20 12:170.39 1 Naphthalene ND mg/kg 12/18/20 13:38 91-20-312/17/20 12:170.39 1 2-Nitroaniline ND mg/kg 12/18/20 13:38 88-74-412/17/20 12:171.9 1 3-Nitroaniline ND mg/kg 12/18/20 13:38 99-09-2 IL12/17/20 12:171.9 1 4-Nitroaniline ND mg/kg 12/18/20 13:38 100-01-612/17/20 12:170.78 1 Nitrobenzene ND mg/kg 12/18/20 13:38 98-95-312/17/20 12:170.39 1 2-Nitrophenol ND mg/kg 12/18/20 13:38 88-75-512/17/20 12:170.39 1 4-Nitrophenol ND mg/kg 12/18/20 13:38 100-02-712/17/20 12:171.9 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 13:38 62-75-912/17/20 12:170.39 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 13:38 621-64-712/17/20 12:170.39 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 13:38 86-30-612/17/20 12:170.39 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 13:38 108-60-112/17/20 12:170.39 1 Pentachlorophenol 3.5 mg/kg 12/18/20 13:38 87-86-512/17/20 12:170.78 1 Phenanthrene 0.45 mg/kg 12/18/20 13:38 85-01-812/17/20 12:170.39 1 Phenol ND mg/kg 12/18/20 13:38 108-95-212/17/20 12:170.39 1 Pyrene 2.6 mg/kg 12/18/20 13:38 129-00-012/17/20 12:170.39 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 13:38 120-82-112/17/20 12:170.39 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 13:38 95-95-412/17/20 12:170.39 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 13:38 88-06-212/17/20 12:170.39 1 Surrogates Nitrobenzene-d5 (S)92 %12/18/20 13:38 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)72 %12/18/20 13:38 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)84 %12/18/20 13:38 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)85 %12/18/20 13:38 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)81 %12/18/20 13:38 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)99 %12/18/20 13:38 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 15.0 %12/17/20 17:170.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-4 Lab ID:92512363002 Collected:12/15/20 12:40 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 14:09 83-32-912/17/20 12:170.38 1 Acenaphthylene ND mg/kg 12/18/20 14:09 208-96-812/17/20 12:170.38 1 Aniline ND mg/kg 12/18/20 14:09 62-53-312/17/20 12:170.38 1 Anthracene ND mg/kg 12/18/20 14:09 120-12-712/17/20 12:170.38 1 Benzo(a)anthracene ND mg/kg 12/18/20 14:09 56-55-312/17/20 12:170.38 1 Benzo(a)pyrene ND mg/kg 12/18/20 14:09 50-32-812/17/20 12:170.38 1 Benzo(b)fluoranthene ND mg/kg 12/18/20 14:09 205-99-212/17/20 12:170.38 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 14:09 191-24-212/17/20 12:170.38 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 14:09 207-08-912/17/20 12:170.38 1 Benzoic Acid ND mg/kg 12/18/20 14:09 65-85-012/17/20 12:171.9 1 Benzyl alcohol ND mg/kg 12/18/20 14:09 100-51-612/17/20 12:170.75 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 14:09 101-55-312/17/20 12:170.38 1 Butylbenzylphthalate ND mg/kg 12/18/20 14:09 85-68-712/17/20 12:170.38 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 14:09 59-50-712/17/20 12:170.75 1 4-Chloroaniline ND mg/kg 12/18/20 14:09 106-47-812/17/20 12:170.75 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 14:09 111-91-112/17/20 12:170.38 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 14:09 111-44-412/17/20 12:170.38 1 2-Chloronaphthalene ND mg/kg 12/18/20 14:09 91-58-712/17/20 12:170.38 1 2-Chlorophenol ND mg/kg 12/18/20 14:09 95-57-812/17/20 12:170.38 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 14:09 7005-72-312/17/20 12:170.38 1 Chrysene ND mg/kg 12/18/20 14:09 218-01-912/17/20 12:170.38 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 14:09 53-70-312/17/20 12:170.38 1 Dibenzofuran ND mg/kg 12/18/20 14:09 132-64-912/17/20 12:170.38 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 14:09 95-50-112/17/20 12:170.38 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 14:09 541-73-112/17/20 12:170.38 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 14:09 106-46-712/17/20 12:170.38 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 14:09 91-94-112/17/20 12:170.75 1 2,4-Dichlorophenol ND mg/kg 12/18/20 14:09 120-83-212/17/20 12:170.38 1 Diethylphthalate ND mg/kg 12/18/20 14:09 84-66-212/17/20 12:170.38 1 2,4-Dimethylphenol ND mg/kg 12/18/20 14:09 105-67-912/17/20 12:170.38 1 Dimethylphthalate ND mg/kg 12/18/20 14:09 131-11-312/17/20 12:170.38 1 Di-n-butylphthalate ND mg/kg 12/18/20 14:09 84-74-212/17/20 12:170.38 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 14:09 534-52-1 v112/17/20 12:170.75 1 2,4-Dinitrophenol ND mg/kg 12/18/20 14:09 51-28-5 v112/17/20 12:171.9 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 14:09 121-14-212/17/20 12:170.38 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 14:09 606-20-212/17/20 12:170.38 1 Di-n-octylphthalate ND mg/kg 12/18/20 14:09 117-84-012/17/20 12:170.38 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 14:09 117-81-712/17/20 12:170.38 1 Fluoranthene ND mg/kg 12/18/20 14:09 206-44-012/17/20 12:170.38 1 Fluorene ND mg/kg 12/18/20 14:09 86-73-712/17/20 12:170.38 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 14:09 87-68-312/17/20 12:170.38 1 Hexachlorobenzene ND mg/kg 12/18/20 14:09 118-74-112/17/20 12:170.38 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 14:09 77-47-412/17/20 12:170.38 1 Hexachloroethane ND mg/kg 12/18/20 14:09 67-72-112/17/20 12:170.38 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 14:09 193-39-512/17/20 12:170.38 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-4 Lab ID:92512363002 Collected:12/15/20 12:40 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 14:09 78-59-112/17/20 12:170.38 1 1-Methylnaphthalene ND mg/kg 12/18/20 14:09 90-12-012/17/20 12:170.38 1 2-Methylnaphthalene ND mg/kg 12/18/20 14:09 91-57-612/17/20 12:170.38 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 14:09 95-48-712/17/20 12:170.38 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 14:09 15831-10-412/17/20 12:170.38 1 Naphthalene ND mg/kg 12/18/20 14:09 91-20-312/17/20 12:170.38 1 2-Nitroaniline ND mg/kg 12/18/20 14:09 88-74-412/17/20 12:171.9 1 3-Nitroaniline ND mg/kg 12/18/20 14:09 99-09-2 IL12/17/20 12:171.9 1 4-Nitroaniline ND mg/kg 12/18/20 14:09 100-01-612/17/20 12:170.75 1 Nitrobenzene ND mg/kg 12/18/20 14:09 98-95-312/17/20 12:170.38 1 2-Nitrophenol ND mg/kg 12/18/20 14:09 88-75-512/17/20 12:170.38 1 4-Nitrophenol ND mg/kg 12/18/20 14:09 100-02-712/17/20 12:171.9 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 14:09 62-75-912/17/20 12:170.38 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 14:09 621-64-712/17/20 12:170.38 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 14:09 86-30-612/17/20 12:170.38 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 14:09 108-60-112/17/20 12:170.38 1 Pentachlorophenol ND mg/kg 12/18/20 14:09 87-86-512/17/20 12:170.75 1 Phenanthrene ND mg/kg 12/18/20 14:09 85-01-812/17/20 12:170.38 1 Phenol ND mg/kg 12/18/20 14:09 108-95-212/17/20 12:170.38 1 Pyrene ND mg/kg 12/18/20 14:09 129-00-012/17/20 12:170.38 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 14:09 120-82-112/17/20 12:170.38 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 14:09 95-95-412/17/20 12:170.38 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 14:09 88-06-212/17/20 12:170.38 1 Surrogates Nitrobenzene-d5 (S)70 %12/18/20 14:09 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)52 %12/18/20 14:09 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)86 %12/18/20 14:09 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)65 %12/18/20 14:09 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)64 %12/18/20 14:09 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)92 %12/18/20 14:09 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 12.9 %12/17/20 17:170.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-5 Lab ID:92512363003 Collected:12/15/20 12:50 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 14:39 83-32-912/17/20 12:170.40 1 Acenaphthylene ND mg/kg 12/18/20 14:39 208-96-812/17/20 12:170.40 1 Aniline ND mg/kg 12/18/20 14:39 62-53-312/17/20 12:170.40 1 Anthracene ND mg/kg 12/18/20 14:39 120-12-712/17/20 12:170.40 1 Benzo(a)anthracene ND mg/kg 12/18/20 14:39 56-55-312/17/20 12:170.40 1 Benzo(a)pyrene ND mg/kg 12/18/20 14:39 50-32-812/17/20 12:170.40 1 Benzo(b)fluoranthene 0.80 mg/kg 12/18/20 14:39 205-99-212/17/20 12:170.40 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 14:39 191-24-212/17/20 12:170.40 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 14:39 207-08-912/17/20 12:170.40 1 Benzoic Acid ND mg/kg 12/18/20 14:39 65-85-012/17/20 12:172.0 1 Benzyl alcohol ND mg/kg 12/18/20 14:39 100-51-612/17/20 12:170.80 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 14:39 101-55-312/17/20 12:170.40 1 Butylbenzylphthalate ND mg/kg 12/18/20 14:39 85-68-712/17/20 12:170.40 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 14:39 59-50-712/17/20 12:170.80 1 4-Chloroaniline ND mg/kg 12/18/20 14:39 106-47-812/17/20 12:170.80 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 14:39 111-91-112/17/20 12:170.40 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 14:39 111-44-412/17/20 12:170.40 1 2-Chloronaphthalene ND mg/kg 12/18/20 14:39 91-58-712/17/20 12:170.40 1 2-Chlorophenol ND mg/kg 12/18/20 14:39 95-57-812/17/20 12:170.40 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 14:39 7005-72-312/17/20 12:170.40 1 Chrysene 0.62 mg/kg 12/18/20 14:39 218-01-912/17/20 12:170.40 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 14:39 53-70-312/17/20 12:170.40 1 Dibenzofuran ND mg/kg 12/18/20 14:39 132-64-912/17/20 12:170.40 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 14:39 95-50-112/17/20 12:170.40 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 14:39 541-73-112/17/20 12:170.40 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 14:39 106-46-712/17/20 12:170.40 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 14:39 91-94-112/17/20 12:170.80 1 2,4-Dichlorophenol ND mg/kg 12/18/20 14:39 120-83-212/17/20 12:170.40 1 Diethylphthalate ND mg/kg 12/18/20 14:39 84-66-212/17/20 12:170.40 1 2,4-Dimethylphenol ND mg/kg 12/18/20 14:39 105-67-912/17/20 12:170.40 1 Dimethylphthalate ND mg/kg 12/18/20 14:39 131-11-312/17/20 12:170.40 1 Di-n-butylphthalate ND mg/kg 12/18/20 14:39 84-74-212/17/20 12:170.40 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 14:39 534-52-1 v112/17/20 12:170.80 1 2,4-Dinitrophenol ND mg/kg 12/18/20 14:39 51-28-5 v112/17/20 12:172.0 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 14:39 121-14-212/17/20 12:170.40 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 14:39 606-20-212/17/20 12:170.40 1 Di-n-octylphthalate ND mg/kg 12/18/20 14:39 117-84-012/17/20 12:170.40 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 14:39 117-81-712/17/20 12:170.40 1 Fluoranthene 0.89 mg/kg 12/18/20 14:39 206-44-012/17/20 12:170.40 1 Fluorene ND mg/kg 12/18/20 14:39 86-73-712/17/20 12:170.40 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 14:39 87-68-312/17/20 12:170.40 1 Hexachlorobenzene ND mg/kg 12/18/20 14:39 118-74-112/17/20 12:170.40 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 14:39 77-47-412/17/20 12:170.40 1 Hexachloroethane ND mg/kg 12/18/20 14:39 67-72-112/17/20 12:170.40 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 14:39 193-39-512/17/20 12:170.40 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-5 Lab ID:92512363003 Collected:12/15/20 12:50 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 14:39 78-59-112/17/20 12:170.40 1 1-Methylnaphthalene ND mg/kg 12/18/20 14:39 90-12-012/17/20 12:170.40 1 2-Methylnaphthalene ND mg/kg 12/18/20 14:39 91-57-612/17/20 12:170.40 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 14:39 95-48-712/17/20 12:170.40 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 14:39 15831-10-412/17/20 12:170.40 1 Naphthalene ND mg/kg 12/18/20 14:39 91-20-312/17/20 12:170.40 1 2-Nitroaniline ND mg/kg 12/18/20 14:39 88-74-412/17/20 12:172.0 1 3-Nitroaniline ND mg/kg 12/18/20 14:39 99-09-2 IL12/17/20 12:172.0 1 4-Nitroaniline ND mg/kg 12/18/20 14:39 100-01-612/17/20 12:170.80 1 Nitrobenzene ND mg/kg 12/18/20 14:39 98-95-312/17/20 12:170.40 1 2-Nitrophenol ND mg/kg 12/18/20 14:39 88-75-512/17/20 12:170.40 1 4-Nitrophenol ND mg/kg 12/18/20 14:39 100-02-712/17/20 12:172.0 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 14:39 62-75-912/17/20 12:170.40 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 14:39 621-64-712/17/20 12:170.40 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 14:39 86-30-612/17/20 12:170.40 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 14:39 108-60-112/17/20 12:170.40 1 Pentachlorophenol 1.8 mg/kg 12/18/20 14:39 87-86-512/17/20 12:170.80 1 Phenanthrene ND mg/kg 12/18/20 14:39 85-01-812/17/20 12:170.40 1 Phenol ND mg/kg 12/18/20 14:39 108-95-212/17/20 12:170.40 1 Pyrene 0.80 mg/kg 12/18/20 14:39 129-00-012/17/20 12:170.40 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 14:39 120-82-112/17/20 12:170.40 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 14:39 95-95-412/17/20 12:170.40 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 14:39 88-06-212/17/20 12:170.40 1 Surrogates Nitrobenzene-d5 (S)89 %12/18/20 14:39 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)56 %12/18/20 14:39 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)75 %12/18/20 14:39 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)91 %12/18/20 14:39 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)87 %12/18/20 14:39 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)84 %12/18/20 14:39 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 18.4 %12/17/20 17:170.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-6 Lab ID:92512363004 Collected:12/15/20 13:00 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 15:10 83-32-912/17/20 12:170.44 1 Acenaphthylene ND mg/kg 12/18/20 15:10 208-96-812/17/20 12:170.44 1 Aniline ND mg/kg 12/18/20 15:10 62-53-312/17/20 12:170.44 1 Anthracene ND mg/kg 12/18/20 15:10 120-12-712/17/20 12:170.44 1 Benzo(a)anthracene ND mg/kg 12/18/20 15:10 56-55-312/17/20 12:170.44 1 Benzo(a)pyrene ND mg/kg 12/18/20 15:10 50-32-812/17/20 12:170.44 1 Benzo(b)fluoranthene ND mg/kg 12/18/20 15:10 205-99-212/17/20 12:170.44 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 15:10 191-24-212/17/20 12:170.44 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 15:10 207-08-912/17/20 12:170.44 1 Benzoic Acid ND mg/kg 12/18/20 15:10 65-85-012/17/20 12:172.2 1 Benzyl alcohol ND mg/kg 12/18/20 15:10 100-51-612/17/20 12:170.88 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 15:10 101-55-312/17/20 12:170.44 1 Butylbenzylphthalate ND mg/kg 12/18/20 15:10 85-68-712/17/20 12:170.44 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 15:10 59-50-712/17/20 12:170.88 1 4-Chloroaniline ND mg/kg 12/18/20 15:10 106-47-812/17/20 12:170.88 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 15:10 111-91-112/17/20 12:170.44 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 15:10 111-44-412/17/20 12:170.44 1 2-Chloronaphthalene ND mg/kg 12/18/20 15:10 91-58-712/17/20 12:170.44 1 2-Chlorophenol ND mg/kg 12/18/20 15:10 95-57-812/17/20 12:170.44 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 15:10 7005-72-312/17/20 12:170.44 1 Chrysene ND mg/kg 12/18/20 15:10 218-01-912/17/20 12:170.44 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 15:10 53-70-312/17/20 12:170.44 1 Dibenzofuran ND mg/kg 12/18/20 15:10 132-64-912/17/20 12:170.44 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 15:10 95-50-112/17/20 12:170.44 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 15:10 541-73-112/17/20 12:170.44 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 15:10 106-46-712/17/20 12:170.44 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 15:10 91-94-112/17/20 12:170.88 1 2,4-Dichlorophenol ND mg/kg 12/18/20 15:10 120-83-212/17/20 12:170.44 1 Diethylphthalate ND mg/kg 12/18/20 15:10 84-66-212/17/20 12:170.44 1 2,4-Dimethylphenol ND mg/kg 12/18/20 15:10 105-67-912/17/20 12:170.44 1 Dimethylphthalate ND mg/kg 12/18/20 15:10 131-11-312/17/20 12:170.44 1 Di-n-butylphthalate ND mg/kg 12/18/20 15:10 84-74-212/17/20 12:170.44 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 15:10 534-52-1 v112/17/20 12:170.88 1 2,4-Dinitrophenol ND mg/kg 12/18/20 15:10 51-28-5 v112/17/20 12:172.2 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 15:10 121-14-212/17/20 12:170.44 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 15:10 606-20-212/17/20 12:170.44 1 Di-n-octylphthalate ND mg/kg 12/18/20 15:10 117-84-012/17/20 12:170.44 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 15:10 117-81-712/17/20 12:170.44 1 Fluoranthene ND mg/kg 12/18/20 15:10 206-44-012/17/20 12:170.44 1 Fluorene ND mg/kg 12/18/20 15:10 86-73-712/17/20 12:170.44 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 15:10 87-68-312/17/20 12:170.44 1 Hexachlorobenzene ND mg/kg 12/18/20 15:10 118-74-112/17/20 12:170.44 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 15:10 77-47-412/17/20 12:170.44 1 Hexachloroethane ND mg/kg 12/18/20 15:10 67-72-112/17/20 12:170.44 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 15:10 193-39-512/17/20 12:170.44 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-6 Lab ID:92512363004 Collected:12/15/20 13:00 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 15:10 78-59-112/17/20 12:170.44 1 1-Methylnaphthalene ND mg/kg 12/18/20 15:10 90-12-012/17/20 12:170.44 1 2-Methylnaphthalene ND mg/kg 12/18/20 15:10 91-57-612/17/20 12:170.44 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 15:10 95-48-712/17/20 12:170.44 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 15:10 15831-10-412/17/20 12:170.44 1 Naphthalene ND mg/kg 12/18/20 15:10 91-20-312/17/20 12:170.44 1 2-Nitroaniline ND mg/kg 12/18/20 15:10 88-74-412/17/20 12:172.2 1 3-Nitroaniline ND mg/kg 12/18/20 15:10 99-09-2 IL12/17/20 12:172.2 1 4-Nitroaniline ND mg/kg 12/18/20 15:10 100-01-612/17/20 12:170.88 1 Nitrobenzene ND mg/kg 12/18/20 15:10 98-95-312/17/20 12:170.44 1 2-Nitrophenol ND mg/kg 12/18/20 15:10 88-75-512/17/20 12:170.44 1 4-Nitrophenol ND mg/kg 12/18/20 15:10 100-02-712/17/20 12:172.2 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 15:10 62-75-912/17/20 12:170.44 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 15:10 621-64-712/17/20 12:170.44 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 15:10 86-30-612/17/20 12:170.44 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 15:10 108-60-112/17/20 12:170.44 1 Pentachlorophenol 1.5 mg/kg 12/18/20 15:10 87-86-512/17/20 12:170.88 1 Phenanthrene ND mg/kg 12/18/20 15:10 85-01-812/17/20 12:170.44 1 Phenol ND mg/kg 12/18/20 15:10 108-95-212/17/20 12:170.44 1 Pyrene ND mg/kg 12/18/20 15:10 129-00-012/17/20 12:170.44 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 15:10 120-82-112/17/20 12:170.44 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 15:10 95-95-412/17/20 12:170.44 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 15:10 88-06-212/17/20 12:170.44 1 Surrogates Nitrobenzene-d5 (S)63 %12/18/20 15:10 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)56 %12/18/20 15:10 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)71 %12/18/20 15:10 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)57 %12/18/20 15:10 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)53 %12/18/20 15:10 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)70 %12/18/20 15:10 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 25.4 %12/17/20 17:180.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-7 Lab ID:92512363005 Collected:12/15/20 13:10 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 15:41 83-32-912/17/20 12:170.41 1 Acenaphthylene ND mg/kg 12/18/20 15:41 208-96-812/17/20 12:170.41 1 Aniline ND mg/kg 12/18/20 15:41 62-53-312/17/20 12:170.41 1 Anthracene ND mg/kg 12/18/20 15:41 120-12-712/17/20 12:170.41 1 Benzo(a)anthracene ND mg/kg 12/18/20 15:41 56-55-312/17/20 12:170.41 1 Benzo(a)pyrene ND mg/kg 12/18/20 15:41 50-32-812/17/20 12:170.41 1 Benzo(b)fluoranthene ND mg/kg 12/18/20 15:41 205-99-212/17/20 12:170.41 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 15:41 191-24-212/17/20 12:170.41 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 15:41 207-08-912/17/20 12:170.41 1 Benzoic Acid ND mg/kg 12/18/20 15:41 65-85-012/17/20 12:172.1 1 Benzyl alcohol ND mg/kg 12/18/20 15:41 100-51-612/17/20 12:170.82 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 15:41 101-55-312/17/20 12:170.41 1 Butylbenzylphthalate ND mg/kg 12/18/20 15:41 85-68-712/17/20 12:170.41 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 15:41 59-50-712/17/20 12:170.82 1 4-Chloroaniline ND mg/kg 12/18/20 15:41 106-47-812/17/20 12:170.82 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 15:41 111-91-112/17/20 12:170.41 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 15:41 111-44-412/17/20 12:170.41 1 2-Chloronaphthalene ND mg/kg 12/18/20 15:41 91-58-712/17/20 12:170.41 1 2-Chlorophenol ND mg/kg 12/18/20 15:41 95-57-812/17/20 12:170.41 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 15:41 7005-72-312/17/20 12:170.41 1 Chrysene ND mg/kg 12/18/20 15:41 218-01-912/17/20 12:170.41 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 15:41 53-70-312/17/20 12:170.41 1 Dibenzofuran ND mg/kg 12/18/20 15:41 132-64-912/17/20 12:170.41 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 15:41 95-50-112/17/20 12:170.41 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 15:41 541-73-112/17/20 12:170.41 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 15:41 106-46-712/17/20 12:170.41 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 15:41 91-94-112/17/20 12:170.82 1 2,4-Dichlorophenol ND mg/kg 12/18/20 15:41 120-83-212/17/20 12:170.41 1 Diethylphthalate ND mg/kg 12/18/20 15:41 84-66-212/17/20 12:170.41 1 2,4-Dimethylphenol ND mg/kg 12/18/20 15:41 105-67-912/17/20 12:170.41 1 Dimethylphthalate ND mg/kg 12/18/20 15:41 131-11-312/17/20 12:170.41 1 Di-n-butylphthalate ND mg/kg 12/18/20 15:41 84-74-212/17/20 12:170.41 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 15:41 534-52-1 v112/17/20 12:170.82 1 2,4-Dinitrophenol ND mg/kg 12/18/20 15:41 51-28-5 v112/17/20 12:172.1 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 15:41 121-14-212/17/20 12:170.41 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 15:41 606-20-212/17/20 12:170.41 1 Di-n-octylphthalate ND mg/kg 12/18/20 15:41 117-84-012/17/20 12:170.41 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 15:41 117-81-712/17/20 12:170.41 1 Fluoranthene ND mg/kg 12/18/20 15:41 206-44-012/17/20 12:170.41 1 Fluorene ND mg/kg 12/18/20 15:41 86-73-712/17/20 12:170.41 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 15:41 87-68-312/17/20 12:170.41 1 Hexachlorobenzene ND mg/kg 12/18/20 15:41 118-74-112/17/20 12:170.41 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 15:41 77-47-412/17/20 12:170.41 1 Hexachloroethane ND mg/kg 12/18/20 15:41 67-72-112/17/20 12:170.41 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 15:41 193-39-512/17/20 12:170.41 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-7 Lab ID:92512363005 Collected:12/15/20 13:10 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 15:41 78-59-112/17/20 12:170.41 1 1-Methylnaphthalene ND mg/kg 12/18/20 15:41 90-12-012/17/20 12:170.41 1 2-Methylnaphthalene ND mg/kg 12/18/20 15:41 91-57-612/17/20 12:170.41 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 15:41 95-48-712/17/20 12:170.41 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 15:41 15831-10-412/17/20 12:170.41 1 Naphthalene ND mg/kg 12/18/20 15:41 91-20-312/17/20 12:170.41 1 2-Nitroaniline ND mg/kg 12/18/20 15:41 88-74-412/17/20 12:172.1 1 3-Nitroaniline ND mg/kg 12/18/20 15:41 99-09-2 IL12/17/20 12:172.1 1 4-Nitroaniline ND mg/kg 12/18/20 15:41 100-01-612/17/20 12:170.82 1 Nitrobenzene ND mg/kg 12/18/20 15:41 98-95-312/17/20 12:170.41 1 2-Nitrophenol ND mg/kg 12/18/20 15:41 88-75-512/17/20 12:170.41 1 4-Nitrophenol ND mg/kg 12/18/20 15:41 100-02-712/17/20 12:172.1 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 15:41 62-75-912/17/20 12:170.41 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 15:41 621-64-712/17/20 12:170.41 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 15:41 86-30-612/17/20 12:170.41 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 15:41 108-60-112/17/20 12:170.41 1 Pentachlorophenol ND mg/kg 12/18/20 15:41 87-86-512/17/20 12:170.82 1 Phenanthrene ND mg/kg 12/18/20 15:41 85-01-812/17/20 12:170.41 1 Phenol ND mg/kg 12/18/20 15:41 108-95-212/17/20 12:170.41 1 Pyrene ND mg/kg 12/18/20 15:41 129-00-012/17/20 12:170.41 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 15:41 120-82-112/17/20 12:170.41 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 15:41 95-95-412/17/20 12:170.41 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 15:41 88-06-212/17/20 12:170.41 1 Surrogates Nitrobenzene-d5 (S)82 %12/18/20 15:41 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)63 %12/18/20 15:41 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)90 %12/18/20 15:41 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)72 %12/18/20 15:41 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)68 %12/18/20 15:41 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)69 %12/18/20 15:41 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 18.2 %12/17/20 17:180.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-8 Lab ID:92512363006 Collected:12/15/20 13:20 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 16:12 83-32-912/17/20 12:170.38 1 Acenaphthylene ND mg/kg 12/18/20 16:12 208-96-812/17/20 12:170.38 1 Aniline ND mg/kg 12/18/20 16:12 62-53-312/17/20 12:170.38 1 Anthracene ND mg/kg 12/18/20 16:12 120-12-712/17/20 12:170.38 1 Benzo(a)anthracene ND mg/kg 12/18/20 16:12 56-55-312/17/20 12:170.38 1 Benzo(a)pyrene ND mg/kg 12/18/20 16:12 50-32-812/17/20 12:170.38 1 Benzo(b)fluoranthene ND mg/kg 12/18/20 16:12 205-99-212/17/20 12:170.38 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 16:12 191-24-212/17/20 12:170.38 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 16:12 207-08-912/17/20 12:170.38 1 Benzoic Acid ND mg/kg 12/18/20 16:12 65-85-012/17/20 12:171.9 1 Benzyl alcohol ND mg/kg 12/18/20 16:12 100-51-612/17/20 12:170.75 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 16:12 101-55-312/17/20 12:170.38 1 Butylbenzylphthalate ND mg/kg 12/18/20 16:12 85-68-712/17/20 12:170.38 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 16:12 59-50-712/17/20 12:170.75 1 4-Chloroaniline ND mg/kg 12/18/20 16:12 106-47-812/17/20 12:170.75 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 16:12 111-91-112/17/20 12:170.38 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 16:12 111-44-412/17/20 12:170.38 1 2-Chloronaphthalene ND mg/kg 12/18/20 16:12 91-58-712/17/20 12:170.38 1 2-Chlorophenol ND mg/kg 12/18/20 16:12 95-57-812/17/20 12:170.38 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 16:12 7005-72-312/17/20 12:170.38 1 Chrysene ND mg/kg 12/18/20 16:12 218-01-912/17/20 12:170.38 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 16:12 53-70-312/17/20 12:170.38 1 Dibenzofuran ND mg/kg 12/18/20 16:12 132-64-912/17/20 12:170.38 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 16:12 95-50-112/17/20 12:170.38 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 16:12 541-73-112/17/20 12:170.38 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 16:12 106-46-712/17/20 12:170.38 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 16:12 91-94-112/17/20 12:170.75 1 2,4-Dichlorophenol ND mg/kg 12/18/20 16:12 120-83-212/17/20 12:170.38 1 Diethylphthalate ND mg/kg 12/18/20 16:12 84-66-212/17/20 12:170.38 1 2,4-Dimethylphenol ND mg/kg 12/18/20 16:12 105-67-912/17/20 12:170.38 1 Dimethylphthalate ND mg/kg 12/18/20 16:12 131-11-312/17/20 12:170.38 1 Di-n-butylphthalate ND mg/kg 12/18/20 16:12 84-74-212/17/20 12:170.38 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 16:12 534-52-1 v112/17/20 12:170.75 1 2,4-Dinitrophenol ND mg/kg 12/18/20 16:12 51-28-5 v112/17/20 12:171.9 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 16:12 121-14-212/17/20 12:170.38 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 16:12 606-20-212/17/20 12:170.38 1 Di-n-octylphthalate ND mg/kg 12/18/20 16:12 117-84-012/17/20 12:170.38 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 16:12 117-81-712/17/20 12:170.38 1 Fluoranthene ND mg/kg 12/18/20 16:12 206-44-012/17/20 12:170.38 1 Fluorene ND mg/kg 12/18/20 16:12 86-73-712/17/20 12:170.38 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 16:12 87-68-312/17/20 12:170.38 1 Hexachlorobenzene ND mg/kg 12/18/20 16:12 118-74-112/17/20 12:170.38 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 16:12 77-47-412/17/20 12:170.38 1 Hexachloroethane ND mg/kg 12/18/20 16:12 67-72-112/17/20 12:170.38 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 16:12 193-39-512/17/20 12:170.38 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-8 Lab ID:92512363006 Collected:12/15/20 13:20 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 16:12 78-59-112/17/20 12:170.38 1 1-Methylnaphthalene ND mg/kg 12/18/20 16:12 90-12-012/17/20 12:170.38 1 2-Methylnaphthalene ND mg/kg 12/18/20 16:12 91-57-612/17/20 12:170.38 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 16:12 95-48-712/17/20 12:170.38 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 16:12 15831-10-412/17/20 12:170.38 1 Naphthalene ND mg/kg 12/18/20 16:12 91-20-312/17/20 12:170.38 1 2-Nitroaniline ND mg/kg 12/18/20 16:12 88-74-412/17/20 12:171.9 1 3-Nitroaniline ND mg/kg 12/18/20 16:12 99-09-2 IL12/17/20 12:171.9 1 4-Nitroaniline ND mg/kg 12/18/20 16:12 100-01-612/17/20 12:170.75 1 Nitrobenzene ND mg/kg 12/18/20 16:12 98-95-312/17/20 12:170.38 1 2-Nitrophenol ND mg/kg 12/18/20 16:12 88-75-512/17/20 12:170.38 1 4-Nitrophenol ND mg/kg 12/18/20 16:12 100-02-712/17/20 12:171.9 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 16:12 62-75-912/17/20 12:170.38 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 16:12 621-64-712/17/20 12:170.38 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 16:12 86-30-612/17/20 12:170.38 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 16:12 108-60-112/17/20 12:170.38 1 Pentachlorophenol ND mg/kg 12/18/20 16:12 87-86-512/17/20 12:170.75 1 Phenanthrene ND mg/kg 12/18/20 16:12 85-01-812/17/20 12:170.38 1 Phenol ND mg/kg 12/18/20 16:12 108-95-212/17/20 12:170.38 1 Pyrene ND mg/kg 12/18/20 16:12 129-00-012/17/20 12:170.38 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 16:12 120-82-112/17/20 12:170.38 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 16:12 95-95-412/17/20 12:170.38 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 16:12 88-06-212/17/20 12:170.38 1 Surrogates Nitrobenzene-d5 (S)87 %12/18/20 16:12 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)65 %12/18/20 16:12 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)82 %12/18/20 16:12 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)77 %12/18/20 16:12 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)78 %12/18/20 16:12 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)84 %12/18/20 16:12 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 11.5 %12/17/20 17:180.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-9 Lab ID:92512363007 Collected:12/15/20 13:30 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 16:43 83-32-912/17/20 12:170.41 1 Acenaphthylene ND mg/kg 12/18/20 16:43 208-96-812/17/20 12:170.41 1 Aniline ND mg/kg 12/18/20 16:43 62-53-312/17/20 12:170.41 1 Anthracene ND mg/kg 12/18/20 16:43 120-12-712/17/20 12:170.41 1 Benzo(a)anthracene ND mg/kg 12/18/20 16:43 56-55-312/17/20 12:170.41 1 Benzo(a)pyrene ND mg/kg 12/18/20 16:43 50-32-812/17/20 12:170.41 1 Benzo(b)fluoranthene ND mg/kg 12/18/20 16:43 205-99-212/17/20 12:170.41 1 Benzo(g,h,i)perylene ND mg/kg 12/18/20 16:43 191-24-212/17/20 12:170.41 1 Benzo(k)fluoranthene ND mg/kg 12/18/20 16:43 207-08-912/17/20 12:170.41 1 Benzoic Acid ND mg/kg 12/18/20 16:43 65-85-012/17/20 12:172.0 1 Benzyl alcohol ND mg/kg 12/18/20 16:43 100-51-612/17/20 12:170.82 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 16:43 101-55-312/17/20 12:170.41 1 Butylbenzylphthalate ND mg/kg 12/18/20 16:43 85-68-712/17/20 12:170.41 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 16:43 59-50-712/17/20 12:170.82 1 4-Chloroaniline ND mg/kg 12/18/20 16:43 106-47-812/17/20 12:170.82 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 16:43 111-91-112/17/20 12:170.41 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 16:43 111-44-412/17/20 12:170.41 1 2-Chloronaphthalene ND mg/kg 12/18/20 16:43 91-58-712/17/20 12:170.41 1 2-Chlorophenol ND mg/kg 12/18/20 16:43 95-57-812/17/20 12:170.41 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 16:43 7005-72-312/17/20 12:170.41 1 Chrysene ND mg/kg 12/18/20 16:43 218-01-912/17/20 12:170.41 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 16:43 53-70-312/17/20 12:170.41 1 Dibenzofuran ND mg/kg 12/18/20 16:43 132-64-912/17/20 12:170.41 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 16:43 95-50-112/17/20 12:170.41 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 16:43 541-73-112/17/20 12:170.41 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 16:43 106-46-712/17/20 12:170.41 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 16:43 91-94-112/17/20 12:170.82 1 2,4-Dichlorophenol ND mg/kg 12/18/20 16:43 120-83-212/17/20 12:170.41 1 Diethylphthalate ND mg/kg 12/18/20 16:43 84-66-212/17/20 12:170.41 1 2,4-Dimethylphenol ND mg/kg 12/18/20 16:43 105-67-912/17/20 12:170.41 1 Dimethylphthalate ND mg/kg 12/18/20 16:43 131-11-312/17/20 12:170.41 1 Di-n-butylphthalate ND mg/kg 12/18/20 16:43 84-74-212/17/20 12:170.41 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 16:43 534-52-1 v112/17/20 12:170.82 1 2,4-Dinitrophenol ND mg/kg 12/18/20 16:43 51-28-5 v112/17/20 12:172.0 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 16:43 121-14-212/17/20 12:170.41 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 16:43 606-20-212/17/20 12:170.41 1 Di-n-octylphthalate ND mg/kg 12/18/20 16:43 117-84-012/17/20 12:170.41 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 16:43 117-81-712/17/20 12:170.41 1 Fluoranthene ND mg/kg 12/18/20 16:43 206-44-012/17/20 12:170.41 1 Fluorene ND mg/kg 12/18/20 16:43 86-73-712/17/20 12:170.41 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 16:43 87-68-312/17/20 12:170.41 1 Hexachlorobenzene ND mg/kg 12/18/20 16:43 118-74-112/17/20 12:170.41 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 16:43 77-47-412/17/20 12:170.41 1 Hexachloroethane ND mg/kg 12/18/20 16:43 67-72-112/17/20 12:170.41 1 Indeno(1,2,3-cd)pyrene ND mg/kg 12/18/20 16:43 193-39-512/17/20 12:170.41 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-9 Lab ID:92512363007 Collected:12/15/20 13:30 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 16:43 78-59-112/17/20 12:170.41 1 1-Methylnaphthalene ND mg/kg 12/18/20 16:43 90-12-012/17/20 12:170.41 1 2-Methylnaphthalene ND mg/kg 12/18/20 16:43 91-57-612/17/20 12:170.41 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 16:43 95-48-712/17/20 12:170.41 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 16:43 15831-10-412/17/20 12:170.41 1 Naphthalene ND mg/kg 12/18/20 16:43 91-20-312/17/20 12:170.41 1 2-Nitroaniline ND mg/kg 12/18/20 16:43 88-74-412/17/20 12:172.0 1 3-Nitroaniline ND mg/kg 12/18/20 16:43 99-09-2 IL12/17/20 12:172.0 1 4-Nitroaniline ND mg/kg 12/18/20 16:43 100-01-612/17/20 12:170.82 1 Nitrobenzene ND mg/kg 12/18/20 16:43 98-95-312/17/20 12:170.41 1 2-Nitrophenol ND mg/kg 12/18/20 16:43 88-75-512/17/20 12:170.41 1 4-Nitrophenol ND mg/kg 12/18/20 16:43 100-02-712/17/20 12:172.0 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 16:43 62-75-912/17/20 12:170.41 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 16:43 621-64-712/17/20 12:170.41 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 16:43 86-30-612/17/20 12:170.41 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 16:43 108-60-112/17/20 12:170.41 1 Pentachlorophenol ND mg/kg 12/18/20 16:43 87-86-512/17/20 12:170.82 1 Phenanthrene ND mg/kg 12/18/20 16:43 85-01-812/17/20 12:170.41 1 Phenol ND mg/kg 12/18/20 16:43 108-95-212/17/20 12:170.41 1 Pyrene ND mg/kg 12/18/20 16:43 129-00-012/17/20 12:170.41 1 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 16:43 120-82-112/17/20 12:170.41 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 16:43 95-95-412/17/20 12:170.41 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 16:43 88-06-212/17/20 12:170.41 1 Surrogates Nitrobenzene-d5 (S)90 %12/18/20 16:43 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)67 %12/18/20 16:43 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)93 %12/18/20 16:43 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)79 %12/18/20 16:43 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)78 %12/18/20 16:43 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)81 %12/18/20 16:43 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 18.7 %12/17/20 17:180.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-10 Lab ID:92512363008 Collected:12/15/20 13:40 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Acenaphthene ND mg/kg 12/18/20 17:44 83-32-912/17/20 12:170.38 1 Acenaphthylene 0.51 mg/kg 12/18/20 17:44 208-96-812/17/20 12:170.38 1 Aniline ND mg/kg 12/18/20 17:44 62-53-312/17/20 12:170.38 1 Anthracene 0.76 mg/kg 12/18/20 17:44 120-12-712/17/20 12:170.38 1 Benzo(a)anthracene 2.2 mg/kg 12/18/20 17:44 56-55-3 D612/17/20 12:170.38 1 Benzo(a)pyrene 1.7 mg/kg 12/18/20 17:44 50-32-8 D612/17/20 12:170.38 1 Benzo(b)fluoranthene 5.6 mg/kg 12/21/20 09:38 205-99-2 D612/17/20 12:170.76 2 Benzo(g,h,i)perylene 1.3 mg/kg 12/18/20 17:44 191-24-2 D612/17/20 12:170.38 1 Benzo(k)fluoranthene 1.5 mg/kg 12/18/20 17:44 207-08-9 D612/17/20 12:170.38 1 Benzoic Acid ND mg/kg 12/18/20 17:44 65-85-012/17/20 12:171.9 1 Benzyl alcohol ND mg/kg 12/18/20 17:44 100-51-612/17/20 12:170.76 1 4-Bromophenylphenyl ether ND mg/kg 12/18/20 17:44 101-55-312/17/20 12:170.38 1 Butylbenzylphthalate ND mg/kg 12/18/20 17:44 85-68-712/17/20 12:170.38 1 4-Chloro-3-methylphenol ND mg/kg 12/18/20 17:44 59-50-712/17/20 12:170.76 1 4-Chloroaniline ND mg/kg 12/18/20 17:44 106-47-812/17/20 12:170.76 1 bis(2-Chloroethoxy)methane ND mg/kg 12/18/20 17:44 111-91-112/17/20 12:170.38 1 bis(2-Chloroethyl) ether ND mg/kg 12/18/20 17:44 111-44-412/17/20 12:170.38 1 2-Chloronaphthalene ND mg/kg 12/18/20 17:44 91-58-712/17/20 12:170.38 1 2-Chlorophenol ND mg/kg 12/18/20 17:44 95-57-812/17/20 12:170.38 1 4-Chlorophenylphenyl ether ND mg/kg 12/18/20 17:44 7005-72-312/17/20 12:170.38 1 Chrysene 3.1 mg/kg 12/18/20 17:44 218-01-9 D612/17/20 12:170.38 1 Dibenz(a,h)anthracene ND mg/kg 12/18/20 17:44 53-70-312/17/20 12:170.38 1 Dibenzofuran ND mg/kg 12/18/20 17:44 132-64-912/17/20 12:170.38 1 1,2-Dichlorobenzene ND mg/kg 12/18/20 17:44 95-50-112/17/20 12:170.38 1 1,3-Dichlorobenzene ND mg/kg 12/18/20 17:44 541-73-112/17/20 12:170.38 1 1,4-Dichlorobenzene ND mg/kg 12/18/20 17:44 106-46-712/17/20 12:170.38 1 3,3'-Dichlorobenzidine ND mg/kg 12/18/20 17:44 91-94-112/17/20 12:170.76 1 2,4-Dichlorophenol ND mg/kg 12/18/20 17:44 120-83-212/17/20 12:170.38 1 Diethylphthalate ND mg/kg 12/18/20 17:44 84-66-212/17/20 12:170.38 1 2,4-Dimethylphenol ND mg/kg 12/18/20 17:44 105-67-912/17/20 12:170.38 1 Dimethylphthalate ND mg/kg 12/18/20 17:44 131-11-312/17/20 12:170.38 1 Di-n-butylphthalate ND mg/kg 12/18/20 17:44 84-74-212/17/20 12:170.38 1 4,6-Dinitro-2-methylphenol ND mg/kg 12/18/20 17:44 534-52-1 v112/17/20 12:170.76 1 2,4-Dinitrophenol ND mg/kg 12/18/20 17:44 51-28-5 v112/17/20 12:171.9 1 2,4-Dinitrotoluene ND mg/kg 12/18/20 17:44 121-14-212/17/20 12:170.38 1 2,6-Dinitrotoluene ND mg/kg 12/18/20 17:44 606-20-212/17/20 12:170.38 1 Di-n-octylphthalate ND mg/kg 12/18/20 17:44 117-84-012/17/20 12:170.38 1 bis(2-Ethylhexyl)phthalate ND mg/kg 12/18/20 17:44 117-81-712/17/20 12:170.38 1 Fluoranthene 3.3 mg/kg 12/18/20 17:44 206-44-0 D612/17/20 12:170.38 1 Fluorene ND mg/kg 12/18/20 17:44 86-73-712/17/20 12:170.38 1 Hexachloro-1,3-butadiene ND mg/kg 12/18/20 17:44 87-68-312/17/20 12:170.38 1 Hexachlorobenzene ND mg/kg 12/18/20 17:44 118-74-112/17/20 12:170.38 1 Hexachlorocyclopentadiene ND mg/kg 12/18/20 17:44 77-47-412/17/20 12:170.38 1 Hexachloroethane ND mg/kg 12/18/20 17:44 67-72-112/17/20 12:170.38 1 Indeno(1,2,3-cd)pyrene 1.2 mg/kg 12/18/20 17:44 193-39-5 D612/17/20 12:170.38 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92512363 NorthState Sample:HA-10 Lab ID:92512363008 Collected:12/15/20 13:40 Received:12/16/20 17:03 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3546 Pace Analytical Services - Charlotte 8270E MSSV Microwave Isophorone ND mg/kg 12/18/20 17:44 78-59-112/17/20 12:170.38 1 1-Methylnaphthalene ND mg/kg 12/18/20 17:44 90-12-012/17/20 12:170.38 1 2-Methylnaphthalene ND mg/kg 12/18/20 17:44 91-57-612/17/20 12:170.38 1 2-Methylphenol(o-Cresol)ND mg/kg 12/18/20 17:44 95-48-712/17/20 12:170.38 1 3&4-Methylphenol(m&p Cresol)ND mg/kg 12/18/20 17:44 15831-10-412/17/20 12:170.38 1 Naphthalene ND mg/kg 12/18/20 17:44 91-20-312/17/20 12:170.38 1 2-Nitroaniline ND mg/kg 12/18/20 17:44 88-74-412/17/20 12:171.9 1 3-Nitroaniline ND mg/kg 12/18/20 17:44 99-09-2 IL12/17/20 12:171.9 1 4-Nitroaniline ND mg/kg 12/18/20 17:44 100-01-612/17/20 12:170.76 1 Nitrobenzene ND mg/kg 12/18/20 17:44 98-95-312/17/20 12:170.38 1 2-Nitrophenol ND mg/kg 12/18/20 17:44 88-75-512/17/20 12:170.38 1 4-Nitrophenol ND mg/kg 12/18/20 17:44 100-02-712/17/20 12:171.9 1 N-Nitrosodimethylamine ND mg/kg 12/18/20 17:44 62-75-912/17/20 12:170.38 1 N-Nitroso-di-n-propylamine ND mg/kg 12/18/20 17:44 621-64-712/17/20 12:170.38 1 N-Nitrosodiphenylamine ND mg/kg 12/18/20 17:44 86-30-612/17/20 12:170.38 1 2,2'-Oxybis(1-chloropropane)ND mg/kg 12/18/20 17:44 108-60-112/17/20 12:170.38 1 Pentachlorophenol ND mg/kg 12/18/20 17:44 87-86-512/17/20 12:170.76 1 Phenanthrene ND mg/kg 12/18/20 17:44 85-01-812/17/20 12:170.38 1 Phenol ND mg/kg 12/18/20 17:44 108-95-212/17/20 12:170.38 1 Pyrene 5.1 mg/kg 12/21/20 09:38 129-00-0 D612/17/20 12:170.76 2 1,2,4-Trichlorobenzene ND mg/kg 12/18/20 17:44 120-82-112/17/20 12:170.38 1 2,4,5-Trichlorophenol ND mg/kg 12/18/20 17:44 95-95-412/17/20 12:170.38 1 2,4,6-Trichlorophenol ND mg/kg 12/18/20 17:44 88-06-212/17/20 12:170.38 1 Surrogates Nitrobenzene-d5 (S)76 %12/18/20 17:44 4165-60-012/17/20 12:1721-130 1 2-Fluorobiphenyl (S)74 %12/18/20 17:44 321-60-812/17/20 12:1719-130 1 Terphenyl-d14 (S)68 %12/18/20 17:44 1718-51-012/17/20 12:1715-130 1 Phenol-d6 (S)71 %12/18/20 17:44 13127-88-312/17/20 12:1718-130 1 2-Fluorophenol (S)72 %12/18/20 17:44 367-12-412/17/20 12:1718-130 1 2,4,6-Tribromophenol (S)85 %12/18/20 17:44 118-79-612/17/20 12:1718-130 1 Analytical Method: ASTM D2974-87 Pace Analytical Services - Charlotte Percent Moisture Percent Moisture 13.1 %12/17/20 17:180.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 587823 EPA 3546 EPA 8270E 8270E Solid MSSV Microwave Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92512363001, 92512363002, 92512363003, 92512363004, 92512363005, 92512363006, 92512363007, 92512363008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3106299 Associated Lab Samples:92512363001, 92512363002, 92512363003, 92512363004, 92512363005, 92512363006, 92512363007, 92512363008 Matrix:Solid Analyzed 1,2,4-Trichlorobenzene mg/kg ND 0.33 12/18/20 08:34 1,2-Dichlorobenzene mg/kg ND 0.33 12/18/20 08:34 1,3-Dichlorobenzene mg/kg ND 0.33 12/18/20 08:34 1,4-Dichlorobenzene mg/kg ND 0.33 12/18/20 08:34 1-Methylnaphthalene mg/kg ND 0.33 12/18/20 08:34 2,2'-Oxybis(1-chloropropane)mg/kg ND 0.33 12/18/20 08:34 2,4,5-Trichlorophenol mg/kg ND 0.33 12/18/20 08:34 2,4,6-Trichlorophenol mg/kg ND 0.33 12/18/20 08:34 2,4-Dichlorophenol mg/kg ND 0.33 12/18/20 08:34 2,4-Dimethylphenol mg/kg ND 0.33 12/18/20 08:34 2,4-Dinitrophenol mg/kg ND 1.7 v112/18/20 08:34 2,4-Dinitrotoluene mg/kg ND 0.33 12/18/20 08:34 2,6-Dinitrotoluene mg/kg ND 0.33 12/18/20 08:34 2-Chloronaphthalene mg/kg ND 0.33 12/18/20 08:34 2-Chlorophenol mg/kg ND 0.33 12/18/20 08:34 2-Methylnaphthalene mg/kg ND 0.33 12/18/20 08:34 2-Methylphenol(o-Cresol)mg/kg ND 0.33 12/18/20 08:34 2-Nitroaniline mg/kg ND 1.7 12/18/20 08:34 2-Nitrophenol mg/kg ND 0.33 12/18/20 08:34 3&4-Methylphenol(m&p Cresol)mg/kg ND 0.33 12/18/20 08:34 3,3'-Dichlorobenzidine mg/kg ND 0.67 12/18/20 08:34 3-Nitroaniline mg/kg ND 1.7 IL12/18/20 08:34 4,6-Dinitro-2-methylphenol mg/kg ND 0.67 v112/18/20 08:34 4-Bromophenylphenyl ether mg/kg ND 0.33 12/18/20 08:34 4-Chloro-3-methylphenol mg/kg ND 0.67 12/18/20 08:34 4-Chloroaniline mg/kg ND 0.67 12/18/20 08:34 4-Chlorophenylphenyl ether mg/kg ND 0.33 12/18/20 08:34 4-Nitroaniline mg/kg ND 0.67 12/18/20 08:34 4-Nitrophenol mg/kg ND 1.7 12/18/20 08:34 Acenaphthene mg/kg ND 0.33 12/18/20 08:34 Acenaphthylene mg/kg ND 0.33 12/18/20 08:34 Aniline mg/kg ND 0.33 12/18/20 08:34 Anthracene mg/kg ND 0.33 12/18/20 08:34 Benzo(a)anthracene mg/kg ND 0.33 12/18/20 08:34 Benzo(a)pyrene mg/kg ND 0.33 12/18/20 08:34 Benzo(b)fluoranthene mg/kg ND 0.33 12/18/20 08:34 Benzo(g,h,i)perylene mg/kg ND 0.33 12/18/20 08:34 Benzo(k)fluoranthene mg/kg ND 0.33 12/18/20 08:34 Benzoic Acid mg/kg ND 1.7 12/18/20 08:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:3106299 Associated Lab Samples:92512363001, 92512363002, 92512363003, 92512363004, 92512363005, 92512363006, 92512363007, 92512363008 Matrix:Solid Analyzed Benzyl alcohol mg/kg ND 0.67 12/18/20 08:34 bis(2-Chloroethoxy)methane mg/kg ND 0.33 12/18/20 08:34 bis(2-Chloroethyl) ether mg/kg ND 0.33 12/18/20 08:34 bis(2-Ethylhexyl)phthalate mg/kg ND 0.33 12/18/20 08:34 Butylbenzylphthalate mg/kg ND 0.33 12/18/20 08:34 Chrysene mg/kg ND 0.33 12/18/20 08:34 Di-n-butylphthalate mg/kg ND 0.33 12/18/20 08:34 Di-n-octylphthalate mg/kg ND 0.33 12/18/20 08:34 Dibenz(a,h)anthracene mg/kg ND 0.33 12/18/20 08:34 Dibenzofuran mg/kg ND 0.33 12/18/20 08:34 Diethylphthalate mg/kg ND 0.33 12/18/20 08:34 Dimethylphthalate mg/kg ND 0.33 12/18/20 08:34 Fluoranthene mg/kg ND 0.33 12/18/20 08:34 Fluorene mg/kg ND 0.33 12/18/20 08:34 Hexachloro-1,3-butadiene mg/kg ND 0.33 12/18/20 08:34 Hexachlorobenzene mg/kg ND 0.33 12/18/20 08:34 Hexachlorocyclopentadiene mg/kg ND 0.33 12/18/20 08:34 Hexachloroethane mg/kg ND 0.33 12/18/20 08:34 Indeno(1,2,3-cd)pyrene mg/kg ND 0.33 12/18/20 08:34 Isophorone mg/kg ND 0.33 12/18/20 08:34 N-Nitroso-di-n-propylamine mg/kg ND 0.33 12/18/20 08:34 N-Nitrosodimethylamine mg/kg ND 0.33 12/18/20 08:34 N-Nitrosodiphenylamine mg/kg ND 0.33 12/18/20 08:34 Naphthalene mg/kg ND 0.33 12/18/20 08:34 Nitrobenzene mg/kg ND 0.33 12/18/20 08:34 Pentachlorophenol mg/kg ND 0.67 12/18/20 08:34 Phenanthrene mg/kg ND 0.33 12/18/20 08:34 Phenol mg/kg ND 0.33 12/18/20 08:34 Pyrene mg/kg ND 0.33 12/18/20 08:34 2,4,6-Tribromophenol (S)%92 18-130 12/18/20 08:34 2-Fluorobiphenyl (S)%83 19-130 12/18/20 08:34 2-Fluorophenol (S)%84 18-130 12/18/20 08:34 Nitrobenzene-d5 (S)%84 21-130 12/18/20 08:34 Phenol-d6 (S)%83 18-130 12/18/20 08:34 Terphenyl-d14 (S)%104 15-130 12/18/20 08:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3106300LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene mg/kg 1.41.7 81 47-130 1,2-Dichlorobenzene mg/kg 1.41.7 83 49-130 1,3-Dichlorobenzene mg/kg 1.31.7 80 48-130 1,4-Dichlorobenzene mg/kg 1.41.7 83 49-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3106300LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 1.31.7 75 54-130 2,2'-Oxybis(1-chloropropane)mg/kg 1.11.7 69 38-130 2,4,5-Trichlorophenol mg/kg 1.31.7 78 49-130 2,4,6-Trichlorophenol mg/kg 1.31.7 77 50-130 2,4-Dichlorophenol mg/kg 1.41.7 82 51-130 2,4-Dimethylphenol mg/kg 1.41.7 83 53-130 2,4-Dinitrophenol mg/kg 7.5 v18.4 90 39-130 2,4-Dinitrotoluene mg/kg 1.41.7 86 53-130 2,6-Dinitrotoluene mg/kg 1.51.7 87 55-130 2-Chloronaphthalene mg/kg 1.31.7 78 48-130 2-Chlorophenol mg/kg 1.41.7 83 54-130 2-Methylnaphthalene mg/kg 1.31.7 78 57-130 2-Methylphenol(o-Cresol)mg/kg 1.41.7 82 50-130 2-Nitroaniline mg/kg 2.63.3 77 49-130 2-Nitrophenol mg/kg 1.41.7 83 50-130 3&4-Methylphenol(m&p Cresol)mg/kg 1.31.7 79 50-130 3,3'-Dichlorobenzidine mg/kg 2.43.3 72 47-130 3-Nitroaniline mg/kg 2.4 IL3.3 70 45-130 4,6-Dinitro-2-methylphenol mg/kg 3.4 v13.3 103 50-142 4-Bromophenylphenyl ether mg/kg 1.41.7 84 55-130 4-Chloro-3-methylphenol mg/kg 2.73.3 82 52-130 4-Chloroaniline mg/kg 2.33.3 69 49-130 4-Chlorophenylphenyl ether mg/kg 1.31.7 78 53-130 4-Nitroaniline mg/kg 2.43.3 72 51-130 4-Nitrophenol mg/kg 7.18.4 85 40-130 Acenaphthene mg/kg 1.31.7 77 56-130 Acenaphthylene mg/kg 1.31.7 75 58-130 Aniline mg/kg 1.01.7 62 44-130 Anthracene mg/kg 1.21.7 73 60-130 Benzo(a)anthracene mg/kg 1.41.7 82 59-130 Benzo(a)pyrene mg/kg 1.41.7 83 57-130 Benzo(b)fluoranthene mg/kg 1.41.7 81 54-130 Benzo(g,h,i)perylene mg/kg 1.31.7 81 59-130 Benzo(k)fluoranthene mg/kg 1.41.7 86 54-130 Benzoic Acid mg/kg 4.18.4 49 19-130 Benzyl alcohol mg/kg 2.63.3 79 50-130 bis(2-Chloroethoxy)methane mg/kg 1.31.7 77 55-130 bis(2-Chloroethyl) ether mg/kg 1.41.7 82 53-130 bis(2-Ethylhexyl)phthalate mg/kg 1.31.7 80 58-130 Butylbenzylphthalate mg/kg 1.41.7 81 46-138 Chrysene mg/kg 1.41.7 83 57-130 Di-n-butylphthalate mg/kg 1.31.7 80 57-130 Di-n-octylphthalate mg/kg 1.31.7 79 57-130 Dibenz(a,h)anthracene mg/kg 1.31.7 78 60-130 Dibenzofuran mg/kg 1.31.7 80 54-130 Diethylphthalate mg/kg 1.41.7 82 55-130 Dimethylphthalate mg/kg 1.31.7 78 57-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 3106300LABORATORY CONTROL SAMPLE: LCSSpike Fluoranthene mg/kg 1.41.7 82 57-130 Fluorene mg/kg 1.31.7 78 56-130 Hexachloro-1,3-butadiene mg/kg 1.41.7 82 41-130 Hexachlorobenzene mg/kg 1.41.7 85 53-130 Hexachlorocyclopentadiene mg/kg 0.971.7 58 23-130 Hexachloroethane mg/kg 1.41.7 82 48-130 Indeno(1,2,3-cd)pyrene mg/kg 1.41.7 82 61-130 Isophorone mg/kg 1.31.7 77 49-130 N-Nitroso-di-n-propylamine mg/kg 1.21.7 73 52-130 N-Nitrosodimethylamine mg/kg 1.21.7 72 45-130 N-Nitrosodiphenylamine mg/kg 1.41.7 83 56-130 Naphthalene mg/kg 1.31.7 77 56-130 Nitrobenzene mg/kg 1.31.7 79 50-130 Pentachlorophenol mg/kg 2.73.3 82 33-130 Phenanthrene mg/kg 1.31.7 80 60-130 Phenol mg/kg 1.51.7 87 54-130 Pyrene mg/kg 1.41.7 83 61-130 2,4,6-Tribromophenol (S)%101 18-130 2-Fluorobiphenyl (S)%87 19-130 2-Fluorophenol (S)%88 18-130 Nitrobenzene-d5 (S)%89 21-130 Phenol-d6 (S)%92 18-130 Terphenyl-d14 (S)%98 15-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 3106301MATRIX SPIKE SAMPLE: MSSpike Result 92512363007 1,2,4-Trichlorobenzene mg/kg 1.72.1 81 22-130ND 1,2-Dichlorobenzene mg/kg 1.62.1 77 23-130ND 1,3-Dichlorobenzene mg/kg 1.62.1 78 26-130ND 1,4-Dichlorobenzene mg/kg 1.62.1 79 27-130ND 1-Methylnaphthalene mg/kg 1.52.1 74 30-130ND 2,2'-Oxybis(1-chloropropane)mg/kg 1.42.1 67 30-130ND 2,4,5-Trichlorophenol mg/kg 1.72.1 84 26-130ND 2,4,6-Trichlorophenol mg/kg 1.62.1 79 23-130ND 2,4-Dichlorophenol mg/kg 1.72.1 82 29-130ND 2,4-Dimethylphenol mg/kg 1.52.1 74 13-130ND 2,4-Dinitrophenol mg/kg 8.9 v110.3 86 10-131ND 2,4-Dinitrotoluene mg/kg 1.82.1 85 28-130ND 2,6-Dinitrotoluene mg/kg 1.82.1 88 36-130ND 2-Chloronaphthalene mg/kg 1.62.1 78 27-130ND 2-Chlorophenol mg/kg 1.72.1 81 29-130ND 2-Methylnaphthalene mg/kg 1.62.1 78 29-130ND 2-Methylphenol(o-Cresol)mg/kg 1.52.1 74 20-130ND 2-Nitroaniline mg/kg 3.04.2 73 29-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 3106301MATRIX SPIKE SAMPLE: MSSpike Result 92512363007 2-Nitrophenol mg/kg 1.82.1 89 26-130ND 3&4-Methylphenol(m&p Cresol)mg/kg 1.52.1 74 10-176ND 3,3'-Dichlorobenzidine mg/kg 2.74.2 64 15-130ND 3-Nitroaniline mg/kg 3.0 IL4.2 72 28-130ND 4,6-Dinitro-2-methylphenol mg/kg 4.0 v14.2 98 15-132ND 4-Bromophenylphenyl ether mg/kg 1.62.1 77 35-130ND 4-Chloro-3-methylphenol mg/kg 3.44.2 83 30-130ND 4-Chloroaniline mg/kg 2.84.2 67 28-130ND 4-Chlorophenylphenyl ether mg/kg 1.72.1 80 32-130ND 4-Nitroaniline mg/kg 2.94.2 71 30-130ND 4-Nitrophenol mg/kg 8.310.3 80 17-130ND Acenaphthene mg/kg 1.62.1 77 29-130ND Acenaphthylene mg/kg 1.62.1 76 31-130ND Aniline mg/kg 0.982.1 47 10-130ND Anthracene mg/kg 1.42.1 67 33-130ND Benzo(a)anthracene mg/kg 1.62.1 76 32-130ND Benzo(a)pyrene mg/kg 1.62.1 77 32-130ND Benzo(b)fluoranthene mg/kg 1.62.1 78 33-130ND Benzo(g,h,i)perylene mg/kg 1.62.1 77 28-130ND Benzo(k)fluoranthene mg/kg 1.72.1 81 31-130ND Benzoic Acid mg/kg 3.810.3 37 10-130ND Benzyl alcohol mg/kg 3.04.2 74 31-130ND bis(2-Chloroethoxy)methane mg/kg 1.72.1 81 30-130ND bis(2-Chloroethyl) ether mg/kg 1.72.1 83 68-130ND bis(2-Ethylhexyl)phthalate mg/kg 1.62.1 77 40-130ND Butylbenzylphthalate mg/kg 1.62.1 78 40-130ND Chrysene mg/kg 1.62.1 79 30-130ND Di-n-butylphthalate mg/kg 1.62.1 76 41-130ND Di-n-octylphthalate mg/kg 1.62.1 77 42-130ND Dibenz(a,h)anthracene mg/kg 1.62.1 77 27-130ND Dibenzofuran mg/kg 1.62.1 78 32-130ND Diethylphthalate mg/kg 1.62.1 79 40-130ND Dimethylphthalate mg/kg 1.72.1 80 37-130ND Fluoranthene mg/kg 1.62.1 74 26-130ND Fluorene mg/kg 1.62.1 76 31-130ND Hexachloro-1,3-butadiene mg/kg 1.72.1 80 20-130ND Hexachlorobenzene mg/kg 1.62.1 79 29-130ND Hexachlorocyclopentadiene mg/kg 1.12.1 52 10-130ND Hexachloroethane mg/kg 1.72.1 83 21-130ND Indeno(1,2,3-cd)pyrene mg/kg 1.72.1 81 28-130ND Isophorone mg/kg 1.62.1 76 32-130ND N-Nitroso-di-n-propylamine mg/kg 1.52.1 72 31-130ND N-Nitrosodimethylamine mg/kg 1.42.1 68 20-130ND N-Nitrosodiphenylamine mg/kg 1.62.1 79 32-130ND Naphthalene mg/kg 1.62.1 78 30-130ND Nitrobenzene mg/kg 1.62.1 80 25-130ND Pentachlorophenol mg/kg 3.24.2 72 10-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 3106301MATRIX SPIKE SAMPLE: MSSpike Result 92512363007 Phenanthrene mg/kg 1.62.1 76 34-130ND Phenol mg/kg 1.72.1 81 14-130ND Pyrene mg/kg 1.62.1 75 31-130ND 2,4,6-Tribromophenol (S)%82 18-130 2-Fluorobiphenyl (S)%73 19-130 2-Fluorophenol (S)%74 18-130 Nitrobenzene-d5 (S)%77 21-130 Phenol-d6 (S)%73 18-130 Terphenyl-d14 (S)%75 15-130 Parameter Units Dup Result QualifiersRPDResult 92512363008 3106302SAMPLE DUPLICATE: 1,2,4-Trichlorobenzene mg/kg NDND 1,2-Dichlorobenzene mg/kg NDND 1,3-Dichlorobenzene mg/kg NDND 1,4-Dichlorobenzene mg/kg NDND 1-Methylnaphthalene mg/kg NDND 2,2'-Oxybis(1-chloropropane)mg/kg NDND 2,4,5-Trichlorophenol mg/kg NDND 2,4,6-Trichlorophenol mg/kg NDND 2,4-Dichlorophenol mg/kg NDND 2,4-Dimethylphenol mg/kg NDND 2,4-Dinitrophenol mg/kg ND v1ND 2,4-Dinitrotoluene mg/kg NDND 2,6-Dinitrotoluene mg/kg NDND 2-Chloronaphthalene mg/kg NDND 2-Chlorophenol mg/kg NDND 2-Methylnaphthalene mg/kg NDND 2-Methylphenol(o-Cresol)mg/kg NDND 2-Nitroaniline mg/kg NDND 2-Nitrophenol mg/kg NDND 3&4-Methylphenol(m&p Cresol)mg/kg NDND 3,3'-Dichlorobenzidine mg/kg NDND 3-Nitroaniline mg/kg ND ILND 4,6-Dinitro-2-methylphenol mg/kg ND v1ND 4-Bromophenylphenyl ether mg/kg NDND 4-Chloro-3-methylphenol mg/kg NDND 4-Chloroaniline mg/kg NDND 4-Chlorophenylphenyl ether mg/kg NDND 4-Nitroaniline mg/kg NDND 4-Nitrophenol mg/kg NDND Acenaphthene mg/kg NDND Acenaphthylene mg/kg .16J0.51 Aniline mg/kg NDND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result QualifiersRPDResult 92512363008 3106302SAMPLE DUPLICATE: Anthracene mg/kg .24J0.76 Benzo(a)anthracene mg/kg 0.66 D61072.2 Benzo(a)pyrene mg/kg 0.56 D61021.7 Benzo(b)fluoranthene mg/kg 1.6 D61105.6 Benzo(g,h,i)perylene mg/kg 0.41 D61021.3 Benzo(k)fluoranthene mg/kg 0.53 D6941.5 Benzoic Acid mg/kg NDND Benzyl alcohol mg/kg NDND bis(2-Chloroethoxy)methane mg/kg NDND bis(2-Chloroethyl) ether mg/kg NDND bis(2-Ethylhexyl)phthalate mg/kg NDND Butylbenzylphthalate mg/kg NDND Chrysene mg/kg 1.0 D61003.1 Di-n-butylphthalate mg/kg NDND Di-n-octylphthalate mg/kg NDND Dibenz(a,h)anthracene mg/kg NDND Dibenzofuran mg/kg NDND Diethylphthalate mg/kg NDND Dimethylphthalate mg/kg NDND Fluoranthene mg/kg 1.0 D61063.3 Fluorene mg/kg NDND Hexachloro-1,3-butadiene mg/kg NDND Hexachlorobenzene mg/kg NDND Hexachlorocyclopentadiene mg/kg NDND Hexachloroethane mg/kg NDND Indeno(1,2,3-cd)pyrene mg/kg 0.39 D6991.2 Isophorone mg/kg NDND N-Nitroso-di-n-propylamine mg/kg NDND N-Nitrosodimethylamine mg/kg NDND N-Nitrosodiphenylamine mg/kg NDND Naphthalene mg/kg NDND Nitrobenzene mg/kg NDND Pentachlorophenol mg/kg NDND Phenanthrene mg/kg .13JND Phenol mg/kg NDND Pyrene mg/kg 1.5 D61085.1 2,4,6-Tribromophenol (S)%8385 2-Fluorobiphenyl (S)%7274 2-Fluorophenol (S)%6672 Nitrobenzene-d5 (S)%7476 Phenol-d6 (S)%6571 Terphenyl-d14 (S)%7168 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92512363 NorthState Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 587966 ASTM D2974-87 ASTM D2974-87 Dry Weight/Percent Moisture Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92512363001, 92512363002, 92512363003, 92512363004, 92512363005, 92512363006, 92512363007, 92512363008 Parameter Units Dup Result QualifiersRPDResult 92512346001 3107152SAMPLE DUPLICATE: Percent Moisture %11.0 011.0 Parameter Units Dup Result QualifiersRPDResult 92512687001 3107223SAMPLE DUPLICATE: Percent Moisture %8.5 79.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 31 #=QL# QUALIFIERS Pace Project No.: Project: 92512363 NorthState DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS The precision between the sample and sample duplicate exceeded laboratory control limits.D6 This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value.IL The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias.v1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 31 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92512363 NorthState Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92512363001 587823 588071HA-3 EPA 3546 EPA 8270E 92512363002 587823 588071HA-4 EPA 3546 EPA 8270E 92512363003 587823 588071HA-5 EPA 3546 EPA 8270E 92512363004 587823 588071HA-6 EPA 3546 EPA 8270E 92512363005 587823 588071HA-7 EPA 3546 EPA 8270E 92512363006 587823 588071HA-8 EPA 3546 EPA 8270E 92512363007 587823 588071HA-9 EPA 3546 EPA 8270E 92512363008 587823 588071HA-10 EPA 3546 EPA 8270E 92512363001 587966HA-3 ASTM D2974-87 92512363002 587966HA-4 ASTM D2974-87 92512363003 587966HA-5 ASTM D2974-87 92512363004 587966HA-6 ASTM D2974-87 92512363005 587966HA-7 ASTM D2974-87 92512363006 587966HA-8 ASTM D2974-87 92512363007 587966HA-9 ASTM D2974-87 92512363008 587966HA-10 ASTM D2974-87 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 01/04/2021 09:31 AM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 31 Page 30 of 31 Page 31 of 31 #=CL# September 02, 2020 LIMS USE: FR - RANDY CAVALLIER LIMS OBJECT ID: 92492681 92492681 Project: Pace Project No.: RE: Mr. Randy Cavallier ECS Southeast, LLP 4811 Koger Blvd. Greensboro, NC 27407 NorthState 12119 Dear Mr. Cavallier: Enclosed are the analytical results for sample(s) received by the laboratory on August 26, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com Project Manager (704)875-9092 Enclosures cc:ECS Southeast Reporting, ECS Southeast REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 31 #=CP# CERTIFICATIONS Pace Project No.: Project: 92492681 NorthState 12119 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 31 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92492681 NorthState 12119 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92492681001 TW-1 MADEP EPH 7 PASI-CBAJ EPA 8270E 68 PASI-CPKS 92492681002 GW-3 EPA 8270E 74 PASI-CPKS EPA 8260D 63 PASI-CCL PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492681 NorthState 12119 Sample:TW-1 Lab ID:92492681001 Collected:08/25/20 09:45 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: MADEP EPH Preparation Method: MADEP EPH Pace Analytical Services - Charlotte MADEP EPH NC Water Aliphatic (C09-C18)ND ug/L 09/02/20 10:50 N208/31/20 22:19200020 Aliphatic (C19-C36)15600 ug/L 09/02/20 10:50 N208/31/20 22:19200020 Aromatic (C11-C22)2920 ug/L 09/01/20 21:24 N208/31/20 22:191001 Surrogates o-Terphenyl (S)94 %09/01/20 21:24 84-15-108/31/20 22:1940-140 1 2-Fluorobiphenyl (S)93 %09/01/20 21:24 321-60-808/31/20 22:1940-140 1 2-Bromonaphthalene (S)94 %09/01/20 21:24 580-13-208/31/20 22:1940-140 1 Nonatriacontane (S)0 %09/02/20 10:50 7194-86-7 S408/31/20 22:1940-140 20 Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 09/01/20 09:47 83-32-908/31/20 22:1710.0 1 Acenaphthylene ND ug/L 09/01/20 09:47 208-96-8 R108/31/20 22:1710.0 1 Aniline ND ug/L 09/01/20 09:47 62-53-3 L2,R108/31/20 22:1710.0 1 Anthracene ND ug/L 09/01/20 09:47 120-12-708/31/20 22:1710.0 1 Benzo(a)anthracene ND ug/L 09/01/20 09:47 56-55-308/31/20 22:1710.0 1 Benzo(a)pyrene ND ug/L 09/01/20 09:47 50-32-808/31/20 22:1710.0 1 Benzo(b)fluoranthene ND ug/L 09/01/20 09:47 205-99-208/31/20 22:1710.0 1 Benzo(g,h,i)perylene ND ug/L 09/01/20 09:47 191-24-208/31/20 22:1710.0 1 Benzo(k)fluoranthene ND ug/L 09/01/20 09:47 207-08-908/31/20 22:1710.0 1 Benzoic Acid ND ug/L 09/01/20 09:47 65-85-008/31/20 22:1750.0 1 Benzyl alcohol ND ug/L 09/01/20 09:47 100-51-608/31/20 22:1720.0 1 4-Bromophenylphenyl ether ND ug/L 09/01/20 09:47 101-55-308/31/20 22:1710.0 1 Butylbenzylphthalate ND ug/L 09/01/20 09:47 85-68-708/31/20 22:1710.0 1 4-Chloro-3-methylphenol ND ug/L 09/01/20 09:47 59-50-708/31/20 22:1710.0 1 4-Chloroaniline ND ug/L 09/01/20 09:47 106-47-808/31/20 22:1720.0 1 bis(2-Chloroethoxy)methane ND ug/L 09/01/20 09:47 111-91-108/31/20 22:1710.0 1 bis(2-Chloroethyl) ether ND ug/L 09/01/20 09:47 111-44-408/31/20 22:1710.0 1 2-Chloronaphthalene ND ug/L 09/01/20 09:47 91-58-708/31/20 22:1710.0 1 2-Chlorophenol ND ug/L 09/01/20 09:47 95-57-808/31/20 22:1710.0 1 4-Chlorophenylphenyl ether ND ug/L 09/01/20 09:47 7005-72-308/31/20 22:1710.0 1 Chrysene ND ug/L 09/01/20 09:47 218-01-908/31/20 22:1710.0 1 Dibenz(a,h)anthracene ND ug/L 09/01/20 09:47 53-70-308/31/20 22:1710.0 1 Dibenzofuran ND ug/L 09/01/20 09:47 132-64-908/31/20 22:1710.0 1 1,2-Dichlorobenzene ND ug/L 09/01/20 09:47 95-50-108/31/20 22:1710.0 1 1,3-Dichlorobenzene ND ug/L 09/01/20 09:47 541-73-108/31/20 22:1710.0 1 1,4-Dichlorobenzene ND ug/L 09/01/20 09:47 106-46-708/31/20 22:1710.0 1 3,3'-Dichlorobenzidine ND ug/L 09/01/20 09:47 91-94-108/31/20 22:1720.0 1 2,4-Dichlorophenol ND ug/L 09/01/20 09:47 120-83-208/31/20 22:1710.0 1 Diethylphthalate ND ug/L 09/01/20 09:47 84-66-208/31/20 22:1710.0 1 2,4-Dimethylphenol ND ug/L 09/01/20 09:47 105-67-908/31/20 22:1710.0 1 Dimethylphthalate ND ug/L 09/01/20 09:47 131-11-308/31/20 22:1710.0 1 Di-n-butylphthalate ND ug/L 09/01/20 09:47 84-74-208/31/20 22:1710.0 1 4,6-Dinitro-2-methylphenol ND ug/L 09/01/20 09:47 534-52-108/31/20 22:1720.0 1 2,4-Dinitrophenol ND ug/L 09/01/20 09:47 51-28-508/31/20 22:1750.0 1 2,4-Dinitrotoluene ND ug/L 09/01/20 09:47 121-14-208/31/20 22:1710.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492681 NorthState 12119 Sample:TW-1 Lab ID:92492681001 Collected:08/25/20 09:45 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE 2,6-Dinitrotoluene ND ug/L 09/01/20 09:47 606-20-208/31/20 22:1710.0 1 Di-n-octylphthalate ND ug/L 09/01/20 09:47 117-84-008/31/20 22:1710.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 09/01/20 09:47 117-81-708/31/20 22:176.0 1 Fluoranthene ND ug/L 09/01/20 09:47 206-44-008/31/20 22:1710.0 1 Fluorene ND ug/L 09/01/20 09:47 86-73-708/31/20 22:1710.0 1 Hexachloro-1,3-butadiene ND ug/L 09/01/20 09:47 87-68-308/31/20 22:1710.0 1 Hexachlorobenzene ND ug/L 09/01/20 09:47 118-74-108/31/20 22:1710.0 1 Hexachlorocyclopentadiene ND ug/L 09/01/20 09:47 77-47-408/31/20 22:1710.0 1 Hexachloroethane ND ug/L 09/01/20 09:47 67-72-108/31/20 22:1710.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 09/01/20 09:47 193-39-508/31/20 22:1710.0 1 Isophorone ND ug/L 09/01/20 09:47 78-59-108/31/20 22:1710.0 1 1-Methylnaphthalene ND ug/L 09/01/20 09:47 90-12-008/31/20 22:1710.0 1 2-Methylnaphthalene ND ug/L 09/01/20 09:47 91-57-608/31/20 22:1710.0 1 2-Methylphenol(o-Cresol)ND ug/L 09/01/20 09:47 95-48-708/31/20 22:1710.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 09/01/20 09:47 15831-10-408/31/20 22:1710.0 1 Naphthalene ND ug/L 09/01/20 09:47 91-20-308/31/20 22:1710.0 1 2-Nitroaniline ND ug/L 09/01/20 09:47 88-74-408/31/20 22:1720.0 1 3-Nitroaniline ND ug/L 09/01/20 09:47 99-09-208/31/20 22:1720.0 1 4-Nitroaniline ND ug/L 09/01/20 09:47 100-01-608/31/20 22:1720.0 1 Nitrobenzene ND ug/L 09/01/20 09:47 98-95-308/31/20 22:1710.0 1 2-Nitrophenol ND ug/L 09/01/20 09:47 88-75-508/31/20 22:1710.0 1 4-Nitrophenol ND ug/L 09/01/20 09:47 100-02-708/31/20 22:1750.0 1 N-Nitrosodimethylamine ND ug/L 09/01/20 09:47 62-75-908/31/20 22:1710.0 1 N-Nitroso-di-n-propylamine ND ug/L 09/01/20 09:47 621-64-708/31/20 22:1710.0 1 N-Nitrosodiphenylamine ND ug/L 09/01/20 09:47 86-30-608/31/20 22:1710.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 09/01/20 09:47 108-60-1 v108/31/20 22:1710.0 1 Pentachlorophenol ND ug/L 09/01/20 09:47 87-86-508/31/20 22:1720.0 1 Phenanthrene ND ug/L 09/01/20 09:47 85-01-808/31/20 22:1710.0 1 Phenol ND ug/L 09/01/20 09:47 108-95-208/31/20 22:1710.0 1 Pyrene ND ug/L 09/01/20 09:47 129-00-008/31/20 22:1710.0 1 1,2,4-Trichlorobenzene ND ug/L 09/01/20 09:47 120-82-108/31/20 22:1710.0 1 2,4,5-Trichlorophenol ND ug/L 09/01/20 09:47 95-95-408/31/20 22:1710.0 1 2,4,6-Trichlorophenol ND ug/L 09/01/20 09:47 88-06-208/31/20 22:1710.0 1 Sample:GW-3 Lab ID:92492681002 Collected:08/25/20 10:30 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Acenaphthene ND ug/L 09/01/20 16:34 83-32-909/01/20 08:2310.0 1 Acenaphthylene ND ug/L 09/01/20 16:34 208-96-809/01/20 08:2310.0 1 Aniline ND ug/L 09/01/20 16:34 62-53-309/01/20 08:2310.0 1 Anthracene ND ug/L 09/01/20 16:34 120-12-709/01/20 08:2310.0 1 Benzo(a)anthracene ND ug/L 09/01/20 16:34 56-55-309/01/20 08:2310.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492681 NorthState 12119 Sample:GW-3 Lab ID:92492681002 Collected:08/25/20 10:30 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE Benzo(a)pyrene ND ug/L 09/01/20 16:34 50-32-809/01/20 08:2310.0 1 Benzo(b)fluoranthene ND ug/L 09/01/20 16:34 205-99-209/01/20 08:2310.0 1 Benzo(g,h,i)perylene ND ug/L 09/01/20 16:34 191-24-209/01/20 08:2310.0 1 Benzo(k)fluoranthene ND ug/L 09/01/20 16:34 207-08-909/01/20 08:2310.0 1 Benzoic Acid ND ug/L 09/01/20 16:34 65-85-009/01/20 08:2350.0 1 Benzyl alcohol ND ug/L 09/01/20 16:34 100-51-609/01/20 08:2320.0 1 4-Bromophenylphenyl ether ND ug/L 09/01/20 16:34 101-55-309/01/20 08:2310.0 1 Butylbenzylphthalate ND ug/L 09/01/20 16:34 85-68-709/01/20 08:2310.0 1 4-Chloro-3-methylphenol ND ug/L 09/01/20 16:34 59-50-709/01/20 08:2310.0 1 4-Chloroaniline ND ug/L 09/01/20 16:34 106-47-809/01/20 08:2320.0 1 bis(2-Chloroethoxy)methane ND ug/L 09/01/20 16:34 111-91-109/01/20 08:2310.0 1 bis(2-Chloroethyl) ether ND ug/L 09/01/20 16:34 111-44-409/01/20 08:2310.0 1 2-Chloronaphthalene ND ug/L 09/01/20 16:34 91-58-709/01/20 08:2310.0 1 2-Chlorophenol ND ug/L 09/01/20 16:34 95-57-809/01/20 08:2310.0 1 4-Chlorophenylphenyl ether ND ug/L 09/01/20 16:34 7005-72-309/01/20 08:2310.0 1 Chrysene ND ug/L 09/01/20 16:34 218-01-909/01/20 08:2310.0 1 Dibenz(a,h)anthracene ND ug/L 09/01/20 16:34 53-70-309/01/20 08:2310.0 1 Dibenzofuran ND ug/L 09/01/20 16:34 132-64-909/01/20 08:2310.0 1 1,2-Dichlorobenzene ND ug/L 09/01/20 16:34 95-50-109/01/20 08:2310.0 1 1,3-Dichlorobenzene ND ug/L 09/01/20 16:34 541-73-109/01/20 08:2310.0 1 1,4-Dichlorobenzene ND ug/L 09/01/20 16:34 106-46-709/01/20 08:2310.0 1 3,3'-Dichlorobenzidine ND ug/L 09/01/20 16:34 91-94-109/01/20 08:2320.0 1 2,4-Dichlorophenol ND ug/L 09/01/20 16:34 120-83-209/01/20 08:2310.0 1 Diethylphthalate ND ug/L 09/01/20 16:34 84-66-209/01/20 08:2310.0 1 2,4-Dimethylphenol ND ug/L 09/01/20 16:34 105-67-909/01/20 08:2310.0 1 Dimethylphthalate ND ug/L 09/01/20 16:34 131-11-309/01/20 08:2310.0 1 Di-n-butylphthalate ND ug/L 09/01/20 16:34 84-74-209/01/20 08:2310.0 1 4,6-Dinitro-2-methylphenol ND ug/L 09/01/20 16:34 534-52-109/01/20 08:2320.0 1 2,4-Dinitrophenol ND ug/L 09/01/20 16:34 51-28-509/01/20 08:2350.0 1 2,4-Dinitrotoluene ND ug/L 09/01/20 16:34 121-14-209/01/20 08:2310.0 1 2,6-Dinitrotoluene ND ug/L 09/01/20 16:34 606-20-209/01/20 08:2310.0 1 Di-n-octylphthalate ND ug/L 09/01/20 16:34 117-84-009/01/20 08:2310.0 1 bis(2-Ethylhexyl)phthalate ND ug/L 09/01/20 16:34 117-81-709/01/20 08:236.0 1 Fluoranthene ND ug/L 09/01/20 16:34 206-44-009/01/20 08:2310.0 1 Fluorene ND ug/L 09/01/20 16:34 86-73-709/01/20 08:2310.0 1 Hexachloro-1,3-butadiene ND ug/L 09/01/20 16:34 87-68-309/01/20 08:2310.0 1 Hexachlorobenzene ND ug/L 09/01/20 16:34 118-74-109/01/20 08:2310.0 1 Hexachlorocyclopentadiene ND ug/L 09/01/20 16:34 77-47-409/01/20 08:2310.0 1 Hexachloroethane ND ug/L 09/01/20 16:34 67-72-109/01/20 08:2310.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 09/01/20 16:34 193-39-509/01/20 08:2310.0 1 Isophorone ND ug/L 09/01/20 16:34 78-59-109/01/20 08:2310.0 1 1-Methylnaphthalene ND ug/L 09/01/20 16:34 90-12-009/01/20 08:2310.0 1 2-Methylnaphthalene ND ug/L 09/01/20 16:34 91-57-609/01/20 08:2310.0 1 2-Methylphenol(o-Cresol)ND ug/L 09/01/20 16:34 95-48-709/01/20 08:2310.0 1 3&4-Methylphenol(m&p Cresol)ND ug/L 09/01/20 16:34 15831-10-409/01/20 08:2310.0 1 Naphthalene ND ug/L 09/01/20 16:34 91-20-309/01/20 08:2310.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492681 NorthState 12119 Sample:GW-3 Lab ID:92492681002 Collected:08/25/20 10:30 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270E Preparation Method: EPA 3510C Pace Analytical Services - Charlotte 8270E RVE 2-Nitroaniline ND ug/L 09/01/20 16:34 88-74-409/01/20 08:2320.0 1 3-Nitroaniline ND ug/L 09/01/20 16:34 99-09-209/01/20 08:2320.0 1 4-Nitroaniline ND ug/L 09/01/20 16:34 100-01-609/01/20 08:2320.0 1 Nitrobenzene ND ug/L 09/01/20 16:34 98-95-309/01/20 08:2310.0 1 2-Nitrophenol ND ug/L 09/01/20 16:34 88-75-509/01/20 08:2310.0 1 4-Nitrophenol ND ug/L 09/01/20 16:34 100-02-709/01/20 08:2350.0 1 N-Nitrosodimethylamine ND ug/L 09/01/20 16:34 62-75-909/01/20 08:2310.0 1 N-Nitroso-di-n-propylamine ND ug/L 09/01/20 16:34 621-64-709/01/20 08:2310.0 1 N-Nitrosodiphenylamine ND ug/L 09/01/20 16:34 86-30-609/01/20 08:2310.0 1 2,2'-Oxybis(1-chloropropane)ND ug/L 09/01/20 16:34 108-60-109/01/20 08:2310.0 1 Pentachlorophenol ND ug/L 09/01/20 16:34 87-86-509/01/20 08:2320.0 1 Phenanthrene ND ug/L 09/01/20 16:34 85-01-809/01/20 08:2310.0 1 Phenol ND ug/L 09/01/20 16:34 108-95-209/01/20 08:2310.0 1 Pyrene ND ug/L 09/01/20 16:34 129-00-009/01/20 08:2310.0 1 1,2,4-Trichlorobenzene ND ug/L 09/01/20 16:34 120-82-109/01/20 08:2310.0 1 2,4,5-Trichlorophenol ND ug/L 09/01/20 16:34 95-95-409/01/20 08:2310.0 1 2,4,6-Trichlorophenol ND ug/L 09/01/20 16:34 88-06-209/01/20 08:2310.0 1 Surrogates Nitrobenzene-d5 (S)96 %09/01/20 16:34 4165-60-009/01/20 08:2313-130 1 2-Fluorobiphenyl (S)84 %09/01/20 16:34 321-60-809/01/20 08:2313-130 1 Terphenyl-d14 (S)136 %09/01/20 16:34 1718-51-0 S309/01/20 08:2325-130 1 Phenol-d6 (S)54 %09/01/20 16:34 13127-88-309/01/20 08:2310-130 1 2-Fluorophenol (S)70 %09/01/20 16:34 367-12-409/01/20 08:2310-130 1 2,4,6-Tribromophenol (S)102 %09/01/20 16:34 118-79-609/01/20 08:2310-137 1 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level Acetone ND ug/L 08/30/20 15:04 67-64-125.0 1 Benzene ND ug/L 08/30/20 15:04 71-43-21.0 1 Bromobenzene ND ug/L 08/30/20 15:04 108-86-11.0 1 Bromochloromethane ND ug/L 08/30/20 15:04 74-97-51.0 1 Bromodichloromethane ND ug/L 08/30/20 15:04 75-27-41.0 1 Bromoform ND ug/L 08/30/20 15:04 75-25-21.0 1 Bromomethane ND ug/L 08/30/20 15:04 74-83-92.0 1 2-Butanone (MEK)ND ug/L 08/30/20 15:04 78-93-35.0 1 Carbon tetrachloride ND ug/L 08/30/20 15:04 56-23-51.0 1 Chlorobenzene ND ug/L 08/30/20 15:04 108-90-71.0 1 Chloroethane ND ug/L 08/30/20 15:04 75-00-31.0 1 Chloroform ND ug/L 08/30/20 15:04 67-66-35.0 1 Chloromethane ND ug/L 08/30/20 15:04 74-87-31.0 1 2-Chlorotoluene ND ug/L 08/30/20 15:04 95-49-81.0 1 4-Chlorotoluene ND ug/L 08/30/20 15:04 106-43-41.0 1 1,2-Dibromo-3-chloropropane ND ug/L 08/30/20 15:04 96-12-85.0 1 Dibromochloromethane ND ug/L 08/30/20 15:04 124-48-11.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/30/20 15:04 106-93-41.0 1 Dibromomethane ND ug/L 08/30/20 15:04 74-95-31.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92492681 NorthState 12119 Sample:GW-3 Lab ID:92492681002 Collected:08/25/20 10:30 Received:08/26/20 16:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 8260D MSV Low Level 1,2-Dichlorobenzene ND ug/L 08/30/20 15:04 95-50-11.0 1 1,3-Dichlorobenzene ND ug/L 08/30/20 15:04 541-73-11.0 1 1,4-Dichlorobenzene ND ug/L 08/30/20 15:04 106-46-71.0 1 Dichlorodifluoromethane ND ug/L 08/30/20 15:04 75-71-81.0 1 1,1-Dichloroethane ND ug/L 08/30/20 15:04 75-34-31.0 1 1,2-Dichloroethane ND ug/L 08/30/20 15:04 107-06-21.0 1 1,1-Dichloroethene ND ug/L 08/30/20 15:04 75-35-41.0 1 cis-1,2-Dichloroethene ND ug/L 08/30/20 15:04 156-59-21.0 1 trans-1,2-Dichloroethene ND ug/L 08/30/20 15:04 156-60-51.0 1 1,2-Dichloropropane ND ug/L 08/30/20 15:04 78-87-51.0 1 1,3-Dichloropropane ND ug/L 08/30/20 15:04 142-28-91.0 1 2,2-Dichloropropane ND ug/L 08/30/20 15:04 594-20-71.0 1 1,1-Dichloropropene ND ug/L 08/30/20 15:04 563-58-61.0 1 cis-1,3-Dichloropropene ND ug/L 08/30/20 15:04 10061-01-51.0 1 trans-1,3-Dichloropropene ND ug/L 08/30/20 15:04 10061-02-6 v11.0 1 Diisopropyl ether ND ug/L 08/30/20 15:04 108-20-31.0 1 Ethylbenzene ND ug/L 08/30/20 15:04 100-41-41.0 1 Hexachloro-1,3-butadiene ND ug/L 08/30/20 15:04 87-68-31.0 1 2-Hexanone ND ug/L 08/30/20 15:04 591-78-65.0 1 p-Isopropyltoluene ND ug/L 08/30/20 15:04 99-87-61.0 1 Methylene Chloride ND ug/L 08/30/20 15:04 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/30/20 15:04 108-10-15.0 1 Methyl-tert-butyl ether ND ug/L 08/30/20 15:04 1634-04-41.0 1 Naphthalene ND ug/L 08/30/20 15:04 91-20-31.0 1 Styrene ND ug/L 08/30/20 15:04 100-42-51.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/30/20 15:04 630-20-61.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/30/20 15:04 79-34-51.0 1 Tetrachloroethene ND ug/L 08/30/20 15:04 127-18-41.0 1 Toluene ND ug/L 08/30/20 15:04 108-88-31.0 1 1,2,3-Trichlorobenzene ND ug/L 08/30/20 15:04 87-61-61.0 1 1,2,4-Trichlorobenzene ND ug/L 08/30/20 15:04 120-82-11.0 1 1,1,1-Trichloroethane ND ug/L 08/30/20 15:04 71-55-61.0 1 1,1,2-Trichloroethane ND ug/L 08/30/20 15:04 79-00-51.0 1 Trichloroethene ND ug/L 08/30/20 15:04 79-01-61.0 1 Trichlorofluoromethane ND ug/L 08/30/20 15:04 75-69-41.0 1 1,2,3-Trichloropropane ND ug/L 08/30/20 15:04 96-18-41.0 1 Vinyl acetate ND ug/L 08/30/20 15:04 108-05-42.0 1 Vinyl chloride ND ug/L 08/30/20 15:04 75-01-41.0 1 Xylene (Total)ND ug/L 08/30/20 15:04 1330-20-71.0 1 m&p-Xylene ND ug/L 08/30/20 15:04 179601-23-12.0 1 o-Xylene ND ug/L 08/30/20 15:04 95-47-61.0 1 Surrogates 4-Bromofluorobenzene (S)102 %08/30/20 15:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)98 %08/30/20 15:04 17060-07-070-130 1 Toluene-d8 (S)107 %08/30/20 15:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 563202 EPA 8260D EPA 8260D 8260D MSV Low Level Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492681002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2986356 Associated Lab Samples:92492681002 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 08/30/20 13:34 1,1,1-Trichloroethane ug/L ND 1.0 08/30/20 13:34 1,1,2,2-Tetrachloroethane ug/L ND 1.0 08/30/20 13:34 1,1,2-Trichloroethane ug/L ND 1.0 08/30/20 13:34 1,1-Dichloroethane ug/L ND 1.0 08/30/20 13:34 1,1-Dichloroethene ug/L ND 1.0 08/30/20 13:34 1,1-Dichloropropene ug/L ND 1.0 08/30/20 13:34 1,2,3-Trichlorobenzene ug/L ND 1.0 08/30/20 13:34 1,2,3-Trichloropropane ug/L ND 1.0 08/30/20 13:34 1,2,4-Trichlorobenzene ug/L ND 1.0 08/30/20 13:34 1,2-Dibromo-3-chloropropane ug/L ND 5.0 08/30/20 13:34 1,2-Dibromoethane (EDB)ug/L ND 1.0 08/30/20 13:34 1,2-Dichlorobenzene ug/L ND 1.0 08/30/20 13:34 1,2-Dichloroethane ug/L ND 1.0 08/30/20 13:34 1,2-Dichloropropane ug/L ND 1.0 08/30/20 13:34 1,3-Dichlorobenzene ug/L ND 1.0 08/30/20 13:34 1,3-Dichloropropane ug/L ND 1.0 08/30/20 13:34 1,4-Dichlorobenzene ug/L ND 1.0 08/30/20 13:34 2,2-Dichloropropane ug/L ND 1.0 08/30/20 13:34 2-Butanone (MEK)ug/L ND 5.0 08/30/20 13:34 2-Chlorotoluene ug/L ND 1.0 08/30/20 13:34 2-Hexanone ug/L ND 5.0 08/30/20 13:34 4-Chlorotoluene ug/L ND 1.0 08/30/20 13:34 4-Methyl-2-pentanone (MIBK)ug/L ND 5.0 08/30/20 13:34 Acetone ug/L ND 25.0 08/30/20 13:34 Benzene ug/L ND 1.0 08/30/20 13:34 Bromobenzene ug/L ND 1.0 08/30/20 13:34 Bromochloromethane ug/L ND 1.0 08/30/20 13:34 Bromodichloromethane ug/L ND 1.0 08/30/20 13:34 Bromoform ug/L ND 1.0 08/30/20 13:34 Bromomethane ug/L ND 2.0 08/30/20 13:34 Carbon tetrachloride ug/L ND 1.0 08/30/20 13:34 Chlorobenzene ug/L ND 1.0 08/30/20 13:34 Chloroethane ug/L ND 1.0 08/30/20 13:34 Chloroform ug/L ND 5.0 08/30/20 13:34 Chloromethane ug/L ND 1.0 08/30/20 13:34 cis-1,2-Dichloroethene ug/L ND 1.0 08/30/20 13:34 cis-1,3-Dichloropropene ug/L ND 1.0 08/30/20 13:34 Dibromochloromethane ug/L ND 1.0 08/30/20 13:34 Dibromomethane ug/L ND 1.0 08/30/20 13:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2986356 Associated Lab Samples:92492681002 Matrix:Water Analyzed Dichlorodifluoromethane ug/L ND 1.0 08/30/20 13:34 Diisopropyl ether ug/L ND 1.0 08/30/20 13:34 Ethylbenzene ug/L ND 1.0 08/30/20 13:34 Hexachloro-1,3-butadiene ug/L ND 1.0 08/30/20 13:34 m&p-Xylene ug/L ND 2.0 08/30/20 13:34 Methyl-tert-butyl ether ug/L ND 1.0 08/30/20 13:34 Methylene Chloride ug/L ND 5.0 08/30/20 13:34 Naphthalene ug/L ND 1.0 08/30/20 13:34 o-Xylene ug/L ND 1.0 08/30/20 13:34 p-Isopropyltoluene ug/L ND 1.0 08/30/20 13:34 Styrene ug/L ND 1.0 08/30/20 13:34 Tetrachloroethene ug/L ND 1.0 08/30/20 13:34 Toluene ug/L ND 1.0 08/30/20 13:34 trans-1,2-Dichloroethene ug/L ND 1.0 08/30/20 13:34 trans-1,3-Dichloropropene ug/L ND 1.0 v108/30/20 13:34 Trichloroethene ug/L ND 1.0 08/30/20 13:34 Trichlorofluoromethane ug/L ND 1.0 08/30/20 13:34 Vinyl acetate ug/L ND 2.0 08/30/20 13:34 Vinyl chloride ug/L ND 1.0 08/30/20 13:34 Xylene (Total)ug/L ND 1.0 08/30/20 13:34 1,2-Dichloroethane-d4 (S)%98 70-130 08/30/20 13:34 4-Bromofluorobenzene (S)%101 70-130 08/30/20 13:34 Toluene-d8 (S)%106 70-130 08/30/20 13:34 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2986357LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 56.050 112 70-130 1,1,1-Trichloroethane ug/L 55.750 111 70-130 1,1,2,2-Tetrachloroethane ug/L 51.450 103 70-130 1,1,2-Trichloroethane ug/L 51.750 103 70-130 1,1-Dichloroethane ug/L 50.950 102 70-130 1,1-Dichloroethene ug/L 53.850 108 70-130 1,1-Dichloropropene ug/L 55.550 111 70-130 1,2,3-Trichlorobenzene ug/L 52.250 104 70-130 1,2,3-Trichloropropane ug/L 49.450 99 70-130 1,2,4-Trichlorobenzene ug/L 53.350 107 70-130 1,2-Dibromo-3-chloropropane ug/L 55.750 111 70-130 1,2-Dibromoethane (EDB)ug/L 55.950 112 70-130 1,2-Dichlorobenzene ug/L 51.250 102 70-130 1,2-Dichloroethane ug/L 51.750 103 70-130 1,2-Dichloropropane ug/L 52.750 105 70-130 1,3-Dichlorobenzene ug/L 51.850 104 70-130 1,3-Dichloropropane ug/L 54.350 109 70-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2986357LABORATORY CONTROL SAMPLE: LCSSpike 1,4-Dichlorobenzene ug/L 51.750 103 70-130 2,2-Dichloropropane ug/L 58.750 117 69-130 2-Butanone (MEK)ug/L 97.8100 98 64-135 2-Chlorotoluene ug/L 51.950 104 70-130 2-Hexanone ug/L 109100 109 66-135 4-Chlorotoluene ug/L 50.250 100 70-130 4-Methyl-2-pentanone (MIBK)ug/L 105100 105 70-130 Acetone ug/L 101100 101 61-157 Benzene ug/L 50.950 102 70-130 Bromobenzene ug/L 50.050 100 70-130 Bromochloromethane ug/L 52.950 106 70-130 Bromodichloromethane ug/L 49.250 98 70-130 Bromoform ug/L 57.850 116 70-130 Bromomethane ug/L 55.050 110 38-130 Carbon tetrachloride ug/L 56.050 112 70-130 Chlorobenzene ug/L 50.350 101 70-130 Chloroethane ug/L 38.850 78 37-142 Chloroform ug/L 49.550 99 70-130 Chloromethane ug/L 41.150 82 48-130 cis-1,2-Dichloroethene ug/L 51.050 102 70-130 cis-1,3-Dichloropropene ug/L 57.950 116 70-130 Dibromochloromethane ug/L 57.350 115 70-130 Dibromomethane ug/L 51.750 103 70-130 Dichlorodifluoromethane ug/L 39.250 78 53-134 Diisopropyl ether ug/L 54.050 108 70-135 Ethylbenzene ug/L 49.850 100 70-130 Hexachloro-1,3-butadiene ug/L 54.450 109 68-132 m&p-Xylene ug/L 99.8100 100 70-130 Methyl-tert-butyl ether ug/L 58.250 116 70-130 Methylene Chloride ug/L 48.250 96 67-132 Naphthalene ug/L 51.150 102 70-130 o-Xylene ug/L 49.050 98 70-131 p-Isopropyltoluene ug/L 52.350 105 70-130 Styrene ug/L 52.350 105 70-130 Tetrachloroethene ug/L 54.550 109 69-130 Toluene ug/L 47.450 95 70-130 trans-1,2-Dichloroethene ug/L 54.450 109 70-130 trans-1,3-Dichloropropene ug/L 56.3 v15011370-130 Trichloroethene ug/L 55.450 111 70-130 Trichlorofluoromethane ug/L 40.950 82 63-130 Vinyl acetate ug/L 102100 102 55-143 Vinyl chloride ug/L 40.050 80 70-131 Xylene (Total)ug/L 149150 99 70-130 1,2-Dichloroethane-d4 (S)%106 70-130 4-Bromofluorobenzene (S)%99 70-130 Toluene-d8 (S)%97 70-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2986917MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92492679031 2986918 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 5000 116 73-134105 105000ND58105240 1,1,1-Trichloroethane ug/L 5000 125 82-143122 25000ND62606120 1,1,2,2-Tetrachloroethane ug/L 5000 103 70-13697 55000ND51404870 1,1,2-Trichloroethane ug/L 5000 109 70-135104 55000ND54705180 1,1-Dichloroethane ug/L 5000 115 70-139112 25000ND57405620 1,1-Dichloroethene ug/L 5000 121 70-154117 35000ND60505870 1,1-Dichloropropene ug/L 5000 122 70-149117 55000ND61205840 1,2,3-Trichlorobenzene ug/L 5000 111 70-135104 65000ND55305220 1,2,3-Trichloropropane ug/L 5000 103 71-13796 75000ND51504780 1,2,4-Trichlorobenzene ug/L 5000 110 73-140110 05000ND55205510 1,2-Dibromo-3-chloropropane ug/L 5000 111 65-134108 35000ND55705410 1,2-Dibromoethane (EDB)ug/L 5000 116 70-137108 85000ND58105380 1,2-Dichlorobenzene ug/L 5000 110 70-133107 35000ND55105330 1,2-Dichloroethane ug/L 5000 108 70-137106 25000ND55505410 1,2-Dichloropropane ug/L 5000 114 70-140111 35000ND56905530 1,3-Dichlorobenzene ug/L 5000 113 70-135108 45000ND56405410 1,3-Dichloropropane ug/L 5000 113 70-143106 75000ND56405280 1,4-Dichlorobenzene ug/L 5000 111 70-133108 25000ND55405420 2,2-Dichloropropane ug/L 5000 117 61-148111 55000ND58405530 2-Butanone (MEK)ug/L 10000 95 60-13994 110000ND94909410 2-Chlorotoluene ug/L 5000 114 70-144110 45000ND57005480 2-Hexanone ug/L 10000 111 65-138104 710000ND1110010400 4-Chlorotoluene ug/L 5000 111 70-137108 35000ND55705400 4-Methyl-2-pentanone (MIBK)ug/L 10000 104 65-135101 310000ND1040010100 Acetone ug/L 10000 112 60-148107 510000ND1120010700 Benzene ug/L 5000 112 70-151107 45000ND55905370 Bromobenzene ug/L 5000 108 70-136106 25000ND53805290 Bromochloromethane ug/L 5000 113 70-141114 05000ND56605680 Bromodichloromethane ug/L 5000 106 70-138102 35000ND52905110 Bromoform ug/L 5000 112 63-130106 65000ND55805280 Bromomethane ug/L v1500014815-152142 45000ND73807080 Carbon tetrachloride ug/L 5000 127 70-143123 35000ND63706160 Chlorobenzene ug/L 5000 112 70-138103 85000ND55805170 Chloroethane ug/L v350009252-16392 15000ND46104590 Chloroform ug/L 5000 117 70-139112 55000ND58505580 Chloromethane ug/L 5000 86 41-13984 25000ND42804210 cis-1,2-Dichloroethene ug/L 5000 113 70-141109 35000ND56505470 cis-1,3-Dichloropropene ug/L 5000 118 70-137113 45000ND58805630 Dibromochloromethane ug/L 5000 115 70-134109 55000ND57405450 Dibromomethane ug/L 5000 115 70-138107 75000ND57505370 Dichlorodifluoromethane ug/L v350008147-15579 35000ND40503950 Diisopropyl ether ug/L 5000 109 63-144107 2500037158305710 Ethylbenzene ug/L 5000 114 66-153109 55000ND56905430 Hexachloro-1,3-butadiene ug/L 5000 112 65-149116 35000ND56205810 m&p-Xylene ug/L 10000 116 69-152109 610000ND1160010900 Methyl-tert-butyl ether ug/L M1500026454-156256 15000244003760037200 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2986917MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92492679031 2986918 MSD Result MSD % Rec RPD MSDMS Spike Conc. Methylene Chloride ug/L 5000 107 42-159104 35000ND53705210 Naphthalene ug/L 5000 107 61-148104 35000ND53505210 o-Xylene ug/L 5000 112 70-148106 55000ND55905300 p-Isopropyltoluene ug/L 5000 112 70-146110 15000ND55805520 Styrene ug/L 5000 115 70-135111 45000ND57605550 Tetrachloroethene ug/L 5000 119 59-143111 75000ND59505530 Toluene ug/L 5000 108 59-148105 35000ND54005230 trans-1,2-Dichloroethene ug/L 5000 124 70-146118 55000ND61905900 trans-1,3-Dichloropropene ug/L 5000 113 70-135107 55000ND56605350 Trichloroethene ug/L 5000 118 70-147118 05000ND59005880 Trichlorofluoromethane ug/L 5000 100 70-14895 55000ND50104770 Vinyl acetate ug/L 10000 98 49-15195 210000ND97609530 Vinyl chloride ug/L 5000 86 70-15683 45000ND42804130 Xylene (Total)ug/L 15000 115 63-158108 615000ND1720016200 1,2-Dichloroethane-d4 (S)%103 70-130108 4-Bromofluorobenzene (S)%104 70-130101 Toluene-d8 (S)%98 70-13096 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 563579 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492681001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2988182 Associated Lab Samples:92492681001 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 09/01/20 08:50 1,2-Dichlorobenzene ug/L ND 10.0 09/01/20 08:50 1,3-Dichlorobenzene ug/L ND 10.0 09/01/20 08:50 1,4-Dichlorobenzene ug/L ND 10.0 09/01/20 08:50 1-Methylnaphthalene ug/L ND 10.0 09/01/20 08:50 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 09/01/20 08:50 2,4,5-Trichlorophenol ug/L ND 10.0 09/01/20 08:50 2,4,6-Trichlorophenol ug/L ND 10.0 09/01/20 08:50 2,4-Dichlorophenol ug/L ND 10.0 09/01/20 08:50 2,4-Dimethylphenol ug/L ND 10.0 09/01/20 08:50 2,4-Dinitrophenol ug/L ND 50.0 09/01/20 08:50 2,4-Dinitrotoluene ug/L ND 10.0 09/01/20 08:50 2,6-Dinitrotoluene ug/L ND 10.0 09/01/20 08:50 2-Chloronaphthalene ug/L ND 10.0 09/01/20 08:50 2-Chlorophenol ug/L ND 10.0 09/01/20 08:50 2-Methylnaphthalene ug/L ND 10.0 09/01/20 08:50 2-Methylphenol(o-Cresol)ug/L ND 10.0 09/01/20 08:50 2-Nitroaniline ug/L ND 20.0 09/01/20 08:50 2-Nitrophenol ug/L ND 10.0 09/01/20 08:50 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 09/01/20 08:50 3,3'-Dichlorobenzidine ug/L ND 20.0 09/01/20 08:50 3-Nitroaniline ug/L ND 20.0 09/01/20 08:50 4,6-Dinitro-2-methylphenol ug/L ND 20.0 09/01/20 08:50 4-Bromophenylphenyl ether ug/L ND 10.0 09/01/20 08:50 4-Chloro-3-methylphenol ug/L ND 10.0 09/01/20 08:50 4-Chloroaniline ug/L ND 20.0 09/01/20 08:50 4-Chlorophenylphenyl ether ug/L ND 10.0 09/01/20 08:50 4-Nitroaniline ug/L ND 20.0 09/01/20 08:50 4-Nitrophenol ug/L ND 50.0 09/01/20 08:50 Acenaphthene ug/L ND 10.0 09/01/20 08:50 Acenaphthylene ug/L ND 10.0 09/01/20 08:50 Aniline ug/L ND 10.0 09/01/20 08:50 Anthracene ug/L ND 10.0 09/01/20 08:50 Benzo(a)anthracene ug/L ND 10.0 09/01/20 08:50 Benzo(a)pyrene ug/L ND 10.0 09/01/20 08:50 Benzo(b)fluoranthene ug/L ND 10.0 09/01/20 08:50 Benzo(g,h,i)perylene ug/L ND 10.0 09/01/20 08:50 Benzo(k)fluoranthene ug/L ND 10.0 09/01/20 08:50 Benzoic Acid ug/L ND 50.0 09/01/20 08:50 Benzyl alcohol ug/L ND 20.0 09/01/20 08:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2988182 Associated Lab Samples:92492681001 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 09/01/20 08:50 bis(2-Chloroethyl) ether ug/L ND 10.0 09/01/20 08:50 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 09/01/20 08:50 Butylbenzylphthalate ug/L ND 10.0 09/01/20 08:50 Chrysene ug/L ND 10.0 09/01/20 08:50 Di-n-butylphthalate ug/L ND 10.0 09/01/20 08:50 Di-n-octylphthalate ug/L ND 10.0 09/01/20 08:50 Dibenz(a,h)anthracene ug/L ND 10.0 09/01/20 08:50 Dibenzofuran ug/L ND 10.0 09/01/20 08:50 Diethylphthalate ug/L ND 10.0 09/01/20 08:50 Dimethylphthalate ug/L ND 10.0 09/01/20 08:50 Fluoranthene ug/L ND 10.0 09/01/20 08:50 Fluorene ug/L ND 10.0 09/01/20 08:50 Hexachloro-1,3-butadiene ug/L ND 10.0 09/01/20 08:50 Hexachlorobenzene ug/L ND 10.0 09/01/20 08:50 Hexachlorocyclopentadiene ug/L ND 10.0 09/01/20 08:50 Hexachloroethane ug/L ND 10.0 09/01/20 08:50 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 09/01/20 08:50 Isophorone ug/L ND 10.0 09/01/20 08:50 N-Nitroso-di-n-propylamine ug/L ND 10.0 09/01/20 08:50 N-Nitrosodimethylamine ug/L ND 10.0 09/01/20 08:50 N-Nitrosodiphenylamine ug/L ND 10.0 09/01/20 08:50 Naphthalene ug/L ND 10.0 09/01/20 08:50 Nitrobenzene ug/L ND 10.0 09/01/20 08:50 Pentachlorophenol ug/L ND 20.0 09/01/20 08:50 Phenanthrene ug/L ND 10.0 09/01/20 08:50 Phenol ug/L ND 10.0 09/01/20 08:50 Pyrene ug/L ND 10.0 09/01/20 08:50 2,4,6-Tribromophenol (S)%111 10-137 09/01/20 08:50 2-Fluorobiphenyl (S)%86 13-130 09/01/20 08:50 2-Fluorophenol (S)%71 10-130 09/01/20 08:50 Nitrobenzene-d5 (S)%99 13-130 09/01/20 08:50 Phenol-d6 (S)%51 10-130 09/01/20 08:50 Terphenyl-d14 (S)%154 25-130 S309/01/20 08:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988183LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 27.350 55 30-130 1,2-Dichlorobenzene ug/L 22.950 46 30-130 1,3-Dichlorobenzene ug/L 21.350 43 20-130 1,4-Dichlorobenzene ug/L 23.050 46 30-130 1-Methylnaphthalene ug/L 34.350 69 30-130 2,2'-Oxybis(1-chloropropane)ug/L 47.850 96 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988183LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 47.350 95 40-130 2,4,6-Trichlorophenol ug/L 45.950 92 40-130 2,4-Dichlorophenol ug/L 43.750 87 31-130 2,4-Dimethylphenol ug/L 45.450 91 30-130 2,4-Dinitrophenol ug/L 211250 84 30-130 2,4-Dinitrotoluene ug/L 48.950 98 49-130 2,6-Dinitrotoluene ug/L 47.250 94 50-130 2-Chloronaphthalene ug/L 41.150 82 30-130 2-Chlorophenol ug/L 41.550 83 30-130 2-Methylnaphthalene ug/L 35.550 71 30-130 2-Methylphenol(o-Cresol)ug/L 38.750 77 30-130 2-Nitroaniline ug/L 90.9100 91 40-130 2-Nitrophenol ug/L 44.450 89 20-130 3&4-Methylphenol(m&p Cresol)ug/L 37.650 75 20-130 3,3'-Dichlorobenzidine ug/L 74.9100 75 10-150 3-Nitroaniline ug/L 88.1100 88 40-130 4,6-Dinitro-2-methylphenol ug/L 92.8100 93 40-130 4-Bromophenylphenyl ether ug/L 47.050 94 30-130 4-Chloro-3-methylphenol ug/L 84.8100 85 30-130 4-Chloroaniline ug/L 65.4100 65 20-130 4-Chlorophenylphenyl ether ug/L 43.550 87 20-130 4-Nitroaniline ug/L 93.3100 93 40-130 4-Nitrophenol ug/L 146250 59 10-130 Acenaphthene ug/L 43.250 86 30-130 Acenaphthylene ug/L 43.350 87 30-130 Aniline ug/L 9.3J L2501920-130 Anthracene ug/L 41.150 82 50-130 Benzo(a)anthracene ug/L 45.750 91 50-130 Benzo(a)pyrene ug/L 48.850 98 50-130 Benzo(b)fluoranthene ug/L 47.950 96 50-130 Benzo(g,h,i)perylene ug/L 47.750 95 50-130 Benzo(k)fluoranthene ug/L 50.750 101 50-130 Benzoic Acid ug/L 123250 49 10-130 Benzyl alcohol ug/L 78.5100 78 20-130 bis(2-Chloroethoxy)methane ug/L 43.250 86 30-130 bis(2-Chloroethyl) ether ug/L 43.650 87 30-130 bis(2-Ethylhexyl)phthalate ug/L 51.150 102 50-130 Butylbenzylphthalate ug/L 50.450 101 50-150 Chrysene ug/L 46.650 93 50-130 Di-n-butylphthalate ug/L 49.650 99 50-130 Di-n-octylphthalate ug/L 49.050 98 50-130 Dibenz(a,h)anthracene ug/L 47.250 94 40-130 Dibenzofuran ug/L 44.650 89 40-130 Diethylphthalate ug/L 46.550 93 40-130 Dimethylphthalate ug/L 45.150 90 40-130 Fluoranthene ug/L 45.650 91 30-130 Fluorene ug/L 44.750 89 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988183LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 20.850 42 10-130 Hexachlorobenzene ug/L 45.550 91 30-130 Hexachlorocyclopentadiene ug/L 30.050 60 10-150 Hexachloroethane ug/L 20.350 41 10-130 Indeno(1,2,3-cd)pyrene ug/L 47.950 96 40-130 Isophorone ug/L 41.750 83 30-130 N-Nitroso-di-n-propylamine ug/L 40.350 81 30-130 N-Nitrosodimethylamine ug/L 40.250 80 10-130 N-Nitrosodiphenylamine ug/L 44.150 88 30-130 Naphthalene ug/L 32.650 65 20-130 Nitrobenzene ug/L 44.450 89 20-130 Pentachlorophenol ug/L 83.2100 83 10-140 Phenanthrene ug/L 45.850 92 50-130 Phenol ug/L 25.550 51 10-130 Pyrene ug/L 45.550 91 50-130 2,4,6-Tribromophenol (S)%100 10-137 2-Fluorobiphenyl (S)%83 13-130 2-Fluorophenol (S)%62 10-130 Nitrobenzene-d5 (S)%88 13-130 Phenol-d6 (S)%47 10-130 Terphenyl-d14 (S)%113 25-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2988186MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92492681001 2988187 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/L 100 75 30-13071 5100ND75.0 71.1 1,2-Dichlorobenzene ug/L 100 66 30-13063 5100ND65.5 62.6 1,3-Dichlorobenzene ug/L 100 59 20-13058 3100ND59.2 57.7 1,4-Dichlorobenzene ug/L 100 63 30-13061 3100ND63.1 61.3 1-Methylnaphthalene ug/L 100 84 30-13085 0100ND84.4 84.8 2,2'-Oxybis(1-chloropropane)ug/L v110011820-130122 3100ND118122 2,4,5-Trichlorophenol ug/L 100 96 40-13093 3100ND95.8 93.4 2,4,6-Trichlorophenol ug/L 100 91 40-13087 5100ND91.4 87.1 2,4-Dichlorophenol ug/L 100 91 31-13085 6100ND90.6 85.3 2,4-Dimethylphenol ug/L 100 96 30-13090 7100ND95.8 89.7 2,4-Dinitrophenol ug/L 500 90 30-13090 0500ND448448 2,4-Dinitrotoluene ug/L 100 100 49-130104 3100ND100104 2,6-Dinitrotoluene ug/L 100 104 50-130108 4100ND104108 2-Chloronaphthalene ug/L 100 92 30-13092 0100ND91.9 91.8 2-Chlorophenol ug/L 100 90 30-13090 0100ND89.7 89.9 2-Methylnaphthalene ug/L 100 89 30-13088 1100ND88.8 88.2 2-Methylphenol(o-Cresol)ug/L 100 84 30-13088 4100ND84.0 87.8 2-Nitroaniline ug/L 200 97 40-13093 4200ND195187 2-Nitrophenol ug/L 100 96 20-13098 2100ND95.8 97.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2988186MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92492681001 2988187 MSD Result MSD % Rec RPD MSDMS Spike Conc. 3&4-Methylphenol(m&p Cresol)ug/L 100 83 20-13085 2100ND82.7 84.7 3,3'-Dichlorobenzidine ug/L 200 39 10-15046 17200ND77.3 91.7 3-Nitroaniline ug/L 200 82 40-13086 4200ND165172 4,6-Dinitro-2-methylphenol ug/L 200 101 40-130101 1200ND201202 4-Bromophenylphenyl ether ug/L 100 101 30-130101 1100ND101101 4-Chloro-3-methylphenol ug/L 200 92 30-13092 0200ND184183 4-Chloroaniline ug/L 200 52 20-13062 17200ND105124 4-Chlorophenylphenyl ether ug/L 100 88 20-13090 2100ND88.3 89.8 4-Nitroaniline ug/L 200 81 40-13085 4200ND163169 4-Nitrophenol ug/L 500 65 10-13070 8500ND324350 Acenaphthene ug/L 100 94 30-13092 2100ND94.2 92.0 Acenaphthylene ug/L R11005030-13082 49100ND49.7 81.8 Aniline ug/L R11002620-13042 46100ND26.5 42.3 Anthracene ug/L 100 91 50-13091 1100ND91.4 90.6 Benzo(a)anthracene ug/L 100 100 50-130100 1100ND10099.5 Benzo(a)pyrene ug/L 100 98 50-13095 3100ND97.6 95.1 Benzo(b)fluoranthene ug/L 100 98 50-13095 3100ND98.3 95.5 Benzo(g,h,i)perylene ug/L 100 102 50-13099 3100ND10299.1 Benzo(k)fluoranthene ug/L 100 100 50-13097 4100ND10096.7 Benzoic Acid ug/L 500 68 10-13070 2500ND342349 Benzyl alcohol ug/L 200 86 20-13094 8200ND173187 bis(2-Chloroethoxy)methane ug/L 100 88 30-13094 7100ND87.6 93.7 bis(2-Chloroethyl) ether ug/L 100 91 30-13094 3100ND90.5 93.5 bis(2-Ethylhexyl)phthalate ug/L 100 116 50-130110 5100ND120114 Butylbenzylphthalate ug/L 100 124 50-150125 1100ND124125 Chrysene ug/L 100 100 50-130102 2100ND100102 Di-n-butylphthalate ug/L 100 106 50-130107 0100ND106107 Di-n-octylphthalate ug/L 100 129 50-130123 4100ND129123 Dibenz(a,h)anthracene ug/L 100 101 40-13099 2100ND10199.2 Dibenzofuran ug/L 100 96 40-13097 1100ND95.7 96.7 Diethylphthalate ug/L 100 98 40-130101 2100ND98.4 101 Dimethylphthalate ug/L 100 94 40-13098 4100ND94.0 98.2 Fluoranthene ug/L 100 97 30-13096 0100ND96.5 96.1 Fluorene ug/L 100 94 20-13094 0100ND94.1 93.9 Hexachloro-1,3-butadiene ug/L 100 73 10-13064 14100ND73.0 63.6 Hexachlorobenzene ug/L 100 94 30-13096 2100ND93.9 95.7 Hexachlorocyclopentadiene ug/L 100 81 10-15078 4100ND80.7 77.5 Hexachloroethane ug/L 100 62 10-13054 13100ND61.7 54.0 Indeno(1,2,3-cd)pyrene ug/L 100 103 40-130100 3100ND103100 Isophorone ug/L 100 92 30-13097 5100ND91.9 96.8 N-Nitroso-di-n-propylamine ug/L 100 93 30-130101 8100ND93.0 101 N-Nitrosodimethylamine ug/L 100 77 10-13086 10100ND77.4 85.7 N-Nitrosodiphenylamine ug/L 100 102 30-13087 16100ND10286.9 Naphthalene ug/L 100 80 20-13079 2100ND80.3 79.0 Nitrobenzene ug/L 100 103 20-130112 9100ND103112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2988186MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92492681001 2988187 MSD Result MSD % Rec RPD MSDMS Spike Conc. Pentachlorophenol ug/L 200 100 10-14093 7200ND201187 Phenanthrene ug/L 100 99 50-130100 0100ND99.5 99.7 Phenol ug/L 100 68 10-13076 11100ND69.0 77.3 Pyrene ug/L 100 111 50-130112 1100ND111112 2,4,6-Tribromophenol (S)%106 10-13787 2-Fluorobiphenyl (S)%95 13-13089 2-Fluorophenol (S)%72 10-13072 Nitrobenzene-d5 (S)%91 13-13088 Phenol-d6 (S)%64 10-13071 Terphenyl-d14 (S)%122 25-130121 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 563626 EPA 3510C EPA 8270E 8270E Water MSSV RVE Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492681002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2988273 Associated Lab Samples:92492681002 Matrix:Water Analyzed 1,2,4-Trichlorobenzene ug/L ND 10.0 08/31/20 12:41 1,2-Dichlorobenzene ug/L ND 10.0 08/31/20 12:41 1,3-Dichlorobenzene ug/L ND 10.0 08/31/20 12:41 1,4-Dichlorobenzene ug/L ND 10.0 08/31/20 12:41 1-Methylnaphthalene ug/L ND 10.0 08/31/20 12:41 2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 08/31/20 12:41 2,4,5-Trichlorophenol ug/L ND 10.0 08/31/20 12:41 2,4,6-Trichlorophenol ug/L ND 10.0 08/31/20 12:41 2,4-Dichlorophenol ug/L ND 10.0 08/31/20 12:41 2,4-Dimethylphenol ug/L ND 10.0 08/31/20 12:41 2,4-Dinitrophenol ug/L ND 50.0 08/31/20 12:41 2,4-Dinitrotoluene ug/L ND 10.0 08/31/20 12:41 2,6-Dinitrotoluene ug/L ND 10.0 08/31/20 12:41 2-Chloronaphthalene ug/L ND 10.0 08/31/20 12:41 2-Chlorophenol ug/L ND 10.0 08/31/20 12:41 2-Methylnaphthalene ug/L ND 10.0 08/31/20 12:41 2-Methylphenol(o-Cresol)ug/L ND 10.0 08/31/20 12:41 2-Nitroaniline ug/L ND 20.0 08/31/20 12:41 2-Nitrophenol ug/L ND 10.0 08/31/20 12:41 3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 08/31/20 12:41 3,3'-Dichlorobenzidine ug/L ND 20.0 08/31/20 12:41 3-Nitroaniline ug/L ND 20.0 08/31/20 12:41 4,6-Dinitro-2-methylphenol ug/L ND 20.0 08/31/20 12:41 4-Bromophenylphenyl ether ug/L ND 10.0 08/31/20 12:41 4-Chloro-3-methylphenol ug/L ND 10.0 08/31/20 12:41 4-Chloroaniline ug/L ND 20.0 08/31/20 12:41 4-Chlorophenylphenyl ether ug/L ND 10.0 08/31/20 12:41 4-Nitroaniline ug/L ND 20.0 08/31/20 12:41 4-Nitrophenol ug/L ND 50.0 08/31/20 12:41 Acenaphthene ug/L ND 10.0 08/31/20 12:41 Acenaphthylene ug/L ND 10.0 08/31/20 12:41 Aniline ug/L ND 10.0 08/31/20 12:41 Anthracene ug/L ND 10.0 08/31/20 12:41 Benzo(a)anthracene ug/L ND 10.0 08/31/20 12:41 Benzo(a)pyrene ug/L ND 10.0 08/31/20 12:41 Benzo(b)fluoranthene ug/L ND 10.0 08/31/20 12:41 Benzo(g,h,i)perylene ug/L ND 10.0 08/31/20 12:41 Benzo(k)fluoranthene ug/L ND 10.0 08/31/20 12:41 Benzoic Acid ug/L ND 50.0 08/31/20 12:41 Benzyl alcohol ug/L ND 20.0 08/31/20 12:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2988273 Associated Lab Samples:92492681002 Matrix:Water Analyzed bis(2-Chloroethoxy)methane ug/L ND 10.0 08/31/20 12:41 bis(2-Chloroethyl) ether ug/L ND 10.0 08/31/20 12:41 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 08/31/20 12:41 Butylbenzylphthalate ug/L ND 10.0 08/31/20 12:41 Chrysene ug/L ND 10.0 08/31/20 12:41 Di-n-butylphthalate ug/L ND 10.0 08/31/20 12:41 Di-n-octylphthalate ug/L ND 10.0 08/31/20 12:41 Dibenz(a,h)anthracene ug/L ND 10.0 08/31/20 12:41 Dibenzofuran ug/L ND 10.0 08/31/20 12:41 Diethylphthalate ug/L ND 10.0 08/31/20 12:41 Dimethylphthalate ug/L ND 10.0 08/31/20 12:41 Fluoranthene ug/L ND 10.0 08/31/20 12:41 Fluorene ug/L ND 10.0 08/31/20 12:41 Hexachloro-1,3-butadiene ug/L ND 10.0 08/31/20 12:41 Hexachlorobenzene ug/L ND 10.0 08/31/20 12:41 Hexachlorocyclopentadiene ug/L ND 10.0 08/31/20 12:41 Hexachloroethane ug/L ND 10.0 08/31/20 12:41 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 08/31/20 12:41 Isophorone ug/L ND 10.0 08/31/20 12:41 N-Nitroso-di-n-propylamine ug/L ND 10.0 08/31/20 12:41 N-Nitrosodimethylamine ug/L ND 10.0 08/31/20 12:41 N-Nitrosodiphenylamine ug/L ND 10.0 08/31/20 12:41 Naphthalene ug/L ND 10.0 08/31/20 12:41 Nitrobenzene ug/L ND 10.0 08/31/20 12:41 Pentachlorophenol ug/L ND 20.0 08/31/20 12:41 Phenanthrene ug/L ND 10.0 08/31/20 12:41 Phenol ug/L ND 10.0 08/31/20 12:41 Pyrene ug/L ND 10.0 08/31/20 12:41 2,4,6-Tribromophenol (S)%77 10-137 08/31/20 12:41 2-Fluorobiphenyl (S)%70 13-130 08/31/20 12:41 2-Fluorophenol (S)%69 10-130 08/31/20 12:41 Nitrobenzene-d5 (S)%78 13-130 08/31/20 12:41 Phenol-d6 (S)%54 10-130 08/31/20 12:41 Terphenyl-d14 (S)%107 25-130 08/31/20 12:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988274LABORATORY CONTROL SAMPLE: LCSSpike 1,2,4-Trichlorobenzene ug/L 28.150 56 30-130 1,2-Dichlorobenzene ug/L 28.450 57 30-130 1,3-Dichlorobenzene ug/L 26.750 53 20-130 1,4-Dichlorobenzene ug/L 28.550 57 30-130 1-Methylnaphthalene ug/L 29.750 59 30-130 2,2'-Oxybis(1-chloropropane)ug/L 40.750 81 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988274LABORATORY CONTROL SAMPLE: LCSSpike 2,4,5-Trichlorophenol ug/L 36.450 73 40-130 2,4,6-Trichlorophenol ug/L 36.150 72 40-130 2,4-Dichlorophenol ug/L 35.450 71 31-130 2,4-Dimethylphenol ug/L 38.050 76 30-130 2,4-Dinitrophenol ug/L 161250 64 30-130 2,4-Dinitrotoluene ug/L 38.150 76 49-130 2,6-Dinitrotoluene ug/L 37.450 75 50-130 2-Chloronaphthalene ug/L 33.150 66 30-130 2-Chlorophenol ug/L 33.750 67 30-130 2-Methylnaphthalene ug/L 30.450 61 30-130 2-Methylphenol(o-Cresol)ug/L 32.150 64 30-130 2-Nitroaniline ug/L 70.4100 70 40-130 2-Nitrophenol ug/L 36.250 72 20-130 3&4-Methylphenol(m&p Cresol)ug/L 31.150 62 20-130 3,3'-Dichlorobenzidine ug/L 64.2100 64 10-150 3-Nitroaniline ug/L 69.5100 69 40-130 4,6-Dinitro-2-methylphenol ug/L 70.2100 70 40-130 4-Bromophenylphenyl ether ug/L 34.950 70 30-130 4-Chloro-3-methylphenol ug/L 68.2100 68 30-130 4-Chloroaniline ug/L 63.8100 64 20-130 4-Chlorophenylphenyl ether ug/L 33.950 68 20-130 4-Nitroaniline ug/L 73.1100 73 40-130 4-Nitrophenol ug/L 105250 42 10-130 Acenaphthene ug/L 33.550 67 30-130 Acenaphthylene ug/L 34.350 69 30-130 Aniline ug/L 28.050 56 20-130 Anthracene ug/L 31.450 63 50-130 Benzo(a)anthracene ug/L 34.850 70 50-130 Benzo(a)pyrene ug/L 36.050 72 50-130 Benzo(b)fluoranthene ug/L 36.150 72 50-130 Benzo(g,h,i)perylene ug/L 34.550 69 50-130 Benzo(k)fluoranthene ug/L 36.650 73 50-130 Benzoic Acid ug/L 83.0250 33 10-130 Benzyl alcohol ug/L 63.0100 63 20-130 bis(2-Chloroethoxy)methane ug/L 34.350 69 30-130 bis(2-Chloroethyl) ether ug/L 36.050 72 30-130 bis(2-Ethylhexyl)phthalate ug/L 38.150 76 50-130 Butylbenzylphthalate ug/L 37.950 76 50-150 Chrysene ug/L 35.350 71 50-130 Di-n-butylphthalate ug/L 37.850 76 50-130 Di-n-octylphthalate ug/L 36.650 73 50-130 Dibenz(a,h)anthracene ug/L 34.750 69 40-130 Dibenzofuran ug/L 34.550 69 40-130 Diethylphthalate ug/L 36.550 73 40-130 Dimethylphthalate ug/L 35.550 71 40-130 Fluoranthene ug/L 34.750 69 30-130 Fluorene ug/L 34.550 69 20-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2988274LABORATORY CONTROL SAMPLE: LCSSpike Hexachloro-1,3-butadiene ug/L 24.650 49 10-130 Hexachlorobenzene ug/L 33.950 68 30-130 Hexachlorocyclopentadiene ug/L 26.950 54 10-150 Hexachloroethane ug/L 27.450 55 10-130 Indeno(1,2,3-cd)pyrene ug/L 34.450 69 40-130 Isophorone ug/L 33.050 66 30-130 N-Nitroso-di-n-propylamine ug/L 33.050 66 30-130 N-Nitrosodimethylamine ug/L 31.050 62 10-130 N-Nitrosodiphenylamine ug/L 35.050 70 30-130 Naphthalene ug/L 31.350 63 20-130 Nitrobenzene ug/L 36.350 73 20-130 Pentachlorophenol ug/L 63.8100 64 10-140 Phenanthrene ug/L 34.250 68 50-130 Phenol ug/L 21.650 43 10-130 Pyrene ug/L 34.350 69 50-130 2,4,6-Tribromophenol (S)%79 10-137 2-Fluorobiphenyl (S)%71 13-130 2-Fluorophenol (S)%53 10-130 Nitrobenzene-d5 (S)%78 13-130 Phenol-d6 (S)%38 10-130 Terphenyl-d14 (S)%90 25-130 Parameter Units MS Result % Rec Limits Qual% RecConc. 2988275MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92484369018 2988276 MSD Result MSD % Rec RPD MSDMS Spike Conc. 1,2,4-Trichlorobenzene ug/L 50 68 30-13068 050ND34.2 34.2 1,2-Dichlorobenzene ug/L 50 66 30-13068 250ND33.1 33.9 1,3-Dichlorobenzene ug/L 50 62 20-13064 350ND31.1 32.1 1,4-Dichlorobenzene ug/L 50 68 30-13069 250ND33.8 34.5 1-Methylnaphthalene ug/L 50 75 30-13073 350ND37.4 36.4 2,2'-Oxybis(1-chloropropane)ug/L 50 99 20-13093 650ND49.5 46.4 2,4,5-Trichlorophenol ug/L 50 90 40-13091 150ND44.8 45.4 2,4,6-Trichlorophenol ug/L 50 89 40-13090 150ND44.3 44.9 2,4-Dichlorophenol ug/L 50 86 31-13088 250ND42.9 43.8 2,4-Dimethylphenol ug/L 50 91 30-13094 350ND45.5 47.0 2,4-Dinitrophenol ug/L 250 78 30-13085 8250ND195212 2,4-Dinitrotoluene ug/L 50 97 49-13094 350ND48.3 46.8 2,6-Dinitrotoluene ug/L 50 94 50-13092 350ND47.0 45.8 2-Chloronaphthalene ug/L 50 84 30-13081 350ND41.8 40.5 2-Chlorophenol ug/L 50 82 30-13089 850ND41.1 44.6 2-Methylnaphthalene ug/L 50 78 30-13075 450ND38.9 37.6 2-Methylphenol(o-Cresol)ug/L 50 74 30-13086 1550ND37.2 43.2 2-Nitroaniline ug/L 100 89 40-13085 4100ND88.9 85.5 2-Nitrophenol ug/L 50 90 20-13090 150ND44.8 45.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2988275MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92484369018 2988276 MSD Result MSD % Rec RPD MSDMS Spike Conc. 3&4-Methylphenol(m&p Cresol)ug/L 50 70 20-13087 2250ND35.1 43.6 3,3'-Dichlorobenzidine ug/L 100 80 10-15073 9100ND80.4 73.3 3-Nitroaniline ug/L 100 89 40-13084 5100ND88.7 84.2 4,6-Dinitro-2-methylphenol ug/L 100 88 40-13088 1100ND87.8 88.4 4-Bromophenylphenyl ether ug/L 50 85 30-13086 150ND42.6 43.0 4-Chloro-3-methylphenol ug/L 100 83 30-13087 5100ND83.0 87.5 4-Chloroaniline ug/L 100 80 20-13075 6100ND79.7 74.7 4-Chlorophenylphenyl ether ug/L 50 86 20-13082 550ND43.1 40.8 4-Nitroaniline ug/L 100 93 40-13087 6100ND92.6 87.4 4-Nitrophenol ug/L R12504510-13065 35250ND113162 Acenaphthene ug/L 50 84 30-13081 450ND42.0 40.5 Acenaphthylene ug/L 50 86 30-13083 450ND43.0 41.5 Aniline ug/L 50 70 20-13063 1150ND35.2 31.6 Anthracene ug/L 50 77 50-13074 350ND38.3 37.2 Benzo(a)anthracene ug/L 50 86 50-13083 350ND42.8 41.5 Benzo(a)pyrene ug/L 50 88 50-13086 350ND44.2 43.1 Benzo(b)fluoranthene ug/L 50 87 50-13087 050ND43.4 43.4 Benzo(g,h,i)perylene ug/L 50 83 50-13081 250ND41.5 40.6 Benzo(k)fluoranthene ug/L 50 92 50-13087 550ND45.9 43.5 Benzoic Acid ug/L M1250910-13042250ND23.4J 104 Benzyl alcohol ug/L 100 74 20-13076 3100ND74.0 75.9 bis(2-Chloroethoxy)methane ug/L 50 84 30-13081 350ND42.0 40.7 bis(2-Chloroethyl) ether ug/L 50 88 30-13086 350ND44.2 42.9 bis(2-Ethylhexyl)phthalate ug/L 50 93 50-13091 250ND46.4 45.7 Butylbenzylphthalate ug/L 50 94 50-15092 250ND46.8 46.1 Chrysene ug/L 50 85 50-13083 250ND42.4 41.6 Di-n-butylphthalate ug/L 50 93 50-13091 250ND46.3 45.5 Di-n-octylphthalate ug/L 50 90 50-13088 250ND44.9 44.0 Dibenz(a,h)anthracene ug/L 50 85 40-13082 350ND42.5 41.1 Dibenzofuran ug/L 50 86 40-13083 350ND42.8 41.5 Diethylphthalate ug/L 50 91 40-13088 350ND45.4 44.0 Dimethylphthalate ug/L 50 89 40-13086 450ND44.3 42.8 Fluoranthene ug/L 50 85 30-13083 250ND42.4 41.3 Fluorene ug/L 50 87 20-13083 550ND43.4 41.4 Hexachloro-1,3-butadiene ug/L 50 60 10-13063 450ND30.0 31.3 Hexachlorobenzene ug/L 50 84 30-13083 050ND41.9 41.7 Hexachlorocyclopentadiene ug/L 50 69 10-15070 150ND34.4 34.9 Hexachloroethane ug/L 50 63 10-13066 550ND31.6 33.1 Indeno(1,2,3-cd)pyrene ug/L 50 85 40-13083 250ND42.3 41.4 Isophorone ug/L 50 84 30-13081 450ND42.1 40.6 N-Nitroso-di-n-propylamine ug/L 50 83 30-13081 350ND41.4 40.3 N-Nitrosodimethylamine ug/L 50 69 10-13071 250ND34.5 35.3 N-Nitrosodiphenylamine ug/L 50 86 30-13085 150ND43.0 42.5 Naphthalene ug/L 50 75 20-13073 350ND37.6 36.6 Nitrobenzene ug/L 50 88 20-13086 350ND44.1 42.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 2988275MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92484369018 2988276 MSD Result MSD % Rec RPD MSDMS Spike Conc. Pentachlorophenol ug/L 100 80 10-14085 6100ND80.0 84.9 Phenanthrene ug/L 50 83 50-13082 250ND41.7 40.9 Phenol ug/L R1504610-13071 4350ND23.1 35.6 Pyrene ug/L 50 86 50-13084 350ND43.0 41.8 2,4,6-Tribromophenol (S)%96 10-13797 2-Fluorobiphenyl (S)%85 13-13078 2-Fluorophenol (S)%56 10-13076 Nitrobenzene-d5 (S)%90 13-13084 Phenol-d6 (S)%37 10-13062 Terphenyl-d14 (S)%108 25-130101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92492681 NorthState 12119 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 563349 MADEP EPH MADEP EPH MADEP EPH NC Water Laboratory:Pace Analytical Services - Charlotte Associated Lab Samples:92492681001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:2986951 Associated Lab Samples:92492681001 Matrix:Water Analyzed Aliphatic (C09-C18)ug/L ND 100 N208/31/20 21:28 Aliphatic (C19-C36)ug/L ND 100 N208/31/20 21:28 Aromatic (C11-C22)ug/L ND 100 N209/01/20 08:57 2-Bromonaphthalene (S)%96 40-140 09/01/20 08:57 2-Fluorobiphenyl (S)%97 40-140 09/01/20 08:57 Nonatriacontane (S)%88 40-140 08/31/20 21:28 o-Terphenyl (S)%74 40-140 09/01/20 08:57 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 2986952LABORATORY CONTROL SAMPLE & LCSD: LCSSpike LCSD % Rec RPD Max RPD LCSD Result 2986953 Aliphatic (C09-C18)ug/L 172 N23005740-14047141 20 50 Aliphatic (C19-C36)ug/L 321 N24008040-14071285 12 50 Aromatic (C11-C22)ug/L 590 N28506940-14078661 11 50 2-Bromonaphthalene (S)%89 40-14096 2-Fluorobiphenyl (S)%89 40-14095 Nonatriacontane (S)%91 40-14085 o-Terphenyl (S)%77 40-14085 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 31 #=QL# QUALIFIERS Pace Project No.: Project: 92492681 NorthState 12119 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low.L2 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request.N2 RPD value was outside control limits.R1 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3 Surrogate recovery not evaluated against control limits due to sample dilution.S4 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias.v1 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias.v3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 31 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92492681 NorthState 12119 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92492681001 563349 563631TW-1 MADEP EPH MADEP EPH 92492681001 563579 563634TW-1 EPA 3510C EPA 8270E 92492681002 563626 563823GW-3 EPA 3510C EPA 8270E 92492681002 563202GW-3 EPA 8260D REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 09/02/2020 01:49 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31