WS-9385_44606_CA_LAB_20151109

#=CL#
November 09, 2015
LIMS USE: FR - MIKE JONES
LIMS OBJECT ID: 92273833
92273833
Project:
Pace Project No.:
RE:
Mr. Mike Jones
Pyramid Environmental
P.O. Box 16265
503 Industrial Avenue
Greensboro, NC 27416
ALAMANCE
Dear Mr. Jones:
Enclosed are the analytical results for sample(s) received by the laboratory on October 28, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 25
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92273833
ALAMANCE
Charlotte Certification IDs9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84
West Virginia Certification #: 357Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 25
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92273833
ALAMANCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92273833001 ORD-1 2'EPA 8015 Modified 2 PASI-CBJL
EPA 8015 Modified 2 PASI-CZDO
ASTM D2974-87 1 PASI-CKDF
92273833002 ORD-1 5.5'MADEP EPH 7 PASI-CSWB
MADEP VPH 5 PASI-CZDO
EPA 8270 74 PASI-CBPJ
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273833
ALAMANCE
Sample:ORD-1 2'Lab ID:92273833001 Collected:10/26/15 12:45 Received:10/28/15 12:35 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015 Modified Preparation Method: EPA 35468015 GCS THC-Diesel
Diesel Range Organics(C10-C28)4050 mg/kg 10/30/15 15:2710/29/15 07:1011620
Surrogates
n-Pentacosane (S)0 %10/30/15 15:27 629-99-2 S410/29/15 07:1041-119 20
Analytical Method: EPA 8015 Modified Preparation Method: EPA 5035A/5030BGasoline Range Organics
Gas Range Organics (C6-C10)27.8 mg/kg 10/31/15 01:0510/29/15 10:035.4 1
Surrogates
4-Bromofluorobenzene (S)101 %10/31/15 01:05 460-00-410/29/15 10:0370-167 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 13.9 %10/30/15 07:200.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273833
ALAMANCE
Sample:ORD-1 5.5'Lab ID:92273833002 Collected:10/26/15 13:15 Received:10/28/15 12:35 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Soil
Aliphatic (C09-C18)23.6 mg/kg 11/05/15 00:35 N211/02/15 13:4511.8 1
Aliphatic (C19-C36)ND mg/kg 11/05/15 00:35 N211/02/15 13:4511.8 1
Aromatic (C11-C22)ND mg/kg 11/06/15 00:12 N211/02/15 13:4511.8 1
Surrogates
Nonatriacontane (S)79 %11/05/15 00:35 7194-86-711/02/15 13:4540-140 1
o-Terphenyl (S)87 %11/06/15 00:12 84-15-111/02/15 13:4540-140 1
2-Fluorobiphenyl (S)97 %11/06/15 00:12 321-60-811/02/15 13:4540-140 1
2-Bromonaphthalene (S)106 %11/06/15 00:12 580-13-211/02/15 13:4540-140 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPHVPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/29/15 18:43 N210/29/15 10:043.1 1
Aliphatic (C09-C12)ND mg/kg 10/29/15 18:43 N210/29/15 10:043.1 1
Aromatic (C09-C10)ND mg/kg 10/29/15 18:43 N210/29/15 10:043.1 1
Surrogates
4-Bromofluorobenzene (FID) (S)97 %10/29/15 18:43 460-00-410/29/15 10:0470-130 1
4-Bromofluorobenzene (PID) (S)97 %10/29/15 18:43 460-00-410/29/15 10:0470-130 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 11/02/15 17:38 83-32-910/30/15 08:003891
Acenaphthylene ND ug/kg 11/02/15 17:38 208-96-810/30/15 08:003891
Aniline ND ug/kg 11/02/15 17:38 62-53-310/30/15 08:003891
Anthracene ND ug/kg 11/02/15 17:38 120-12-710/30/15 08:003891
Benzo(a)anthracene ND ug/kg 11/02/15 17:38 56-55-310/30/15 08:003891
Benzo(a)pyrene ND ug/kg 11/02/15 17:38 50-32-810/30/15 08:003891
Benzo(b)fluoranthene ND ug/kg 11/02/15 17:38 205-99-210/30/15 08:003891
Benzo(g,h,i)perylene ND ug/kg 11/02/15 17:38 191-24-210/30/15 08:003891
Benzo(k)fluoranthene ND ug/kg 11/02/15 17:38 207-08-910/30/15 08:003891
Benzoic Acid ND ug/kg 11/02/15 17:38 65-85-010/30/15 08:0019501
Benzyl alcohol ND ug/kg 11/02/15 17:38 100-51-610/30/15 08:007791
4-Bromophenylphenyl ether ND ug/kg 11/02/15 17:38 101-55-310/30/15 08:003891
Butylbenzylphthalate ND ug/kg 11/02/15 17:38 85-68-710/30/15 08:003891
4-Chloro-3-methylphenol ND ug/kg 11/02/15 17:38 59-50-710/30/15 08:007791
4-Chloroaniline ND ug/kg 11/02/15 17:38 106-47-810/30/15 08:0019501
bis(2-Chloroethoxy)methane ND ug/kg 11/02/15 17:38 111-91-110/30/15 08:003891
bis(2-Chloroethyl) ether ND ug/kg 11/02/15 17:38 111-44-410/30/15 08:003891
bis(2-Chloroisopropyl) ether ND ug/kg 11/02/15 17:38 108-60-110/30/15 08:003891
2-Chloronaphthalene ND ug/kg 11/02/15 17:38 91-58-710/30/15 08:003891
2-Chlorophenol ND ug/kg 11/02/15 17:38 95-57-810/30/15 08:003891
4-Chlorophenylphenyl ether ND ug/kg 11/02/15 17:38 7005-72-310/30/15 08:003891
Chrysene ND ug/kg 11/02/15 17:38 218-01-910/30/15 08:003891
Dibenz(a,h)anthracene ND ug/kg 11/02/15 17:38 53-70-310/30/15 08:003891
Dibenzofuran ND ug/kg 11/02/15 17:38 132-64-910/30/15 08:003891
1,2-Dichlorobenzene ND ug/kg 11/02/15 17:38 95-50-110/30/15 08:003891
1,3-Dichlorobenzene ND ug/kg 11/02/15 17:38 541-73-110/30/15 08:003891
1,4-Dichlorobenzene ND ug/kg 11/02/15 17:38 106-46-710/30/15 08:003891
3,3'-Dichlorobenzidine ND ug/kg 11/02/15 17:38 91-94-110/30/15 08:0019501
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273833
ALAMANCE
Sample:ORD-1 5.5'Lab ID:92273833002 Collected:10/26/15 13:15 Received:10/28/15 12:35 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
2,4-Dichlorophenol ND ug/kg 11/02/15 17:38 120-83-210/30/15 08:003891
Diethylphthalate ND ug/kg 11/02/15 17:38 84-66-210/30/15 08:003891
2,4-Dimethylphenol ND ug/kg 11/02/15 17:38 105-67-910/30/15 08:003891
Dimethylphthalate ND ug/kg 11/02/15 17:38 131-11-310/30/15 08:003891
Di-n-butylphthalate ND ug/kg 11/02/15 17:38 84-74-210/30/15 08:003891
4,6-Dinitro-2-methylphenol ND ug/kg 11/02/15 17:38 534-52-110/30/15 08:007791
2,4-Dinitrophenol ND ug/kg 11/02/15 17:38 51-28-510/30/15 08:0019501
2,4-Dinitrotoluene ND ug/kg 11/02/15 17:38 121-14-210/30/15 08:003891
2,6-Dinitrotoluene ND ug/kg 11/02/15 17:38 606-20-210/30/15 08:003891
Di-n-octylphthalate ND ug/kg 11/02/15 17:38 117-84-010/30/15 08:003891
bis(2-Ethylhexyl)phthalate ND ug/kg 11/02/15 17:38 117-81-710/30/15 08:003891
Fluoranthene ND ug/kg 11/02/15 17:38 206-44-010/30/15 08:003891
Fluorene ND ug/kg 11/02/15 17:38 86-73-710/30/15 08:003891
Hexachloro-1,3-butadiene ND ug/kg 11/02/15 17:38 87-68-310/30/15 08:003891
Hexachlorobenzene ND ug/kg 11/02/15 17:38 118-74-110/30/15 08:003891
Hexachlorocyclopentadiene ND ug/kg 11/02/15 17:38 77-47-410/30/15 08:003891
Hexachloroethane ND ug/kg 11/02/15 17:38 67-72-110/30/15 08:003891
Indeno(1,2,3-cd)pyrene ND ug/kg 11/02/15 17:38 193-39-510/30/15 08:003891
Isophorone ND ug/kg 11/02/15 17:38 78-59-110/30/15 08:003891
1-Methylnaphthalene ND ug/kg 11/02/15 17:38 90-12-010/30/15 08:003891
2-Methylnaphthalene ND ug/kg 11/02/15 17:38 91-57-610/30/15 08:003891
2-Methylphenol(o-Cresol)ND ug/kg 11/02/15 17:38 95-48-710/30/15 08:003891
3&4-Methylphenol(m&p Cresol)ND ug/kg 11/02/15 17:3810/30/15 08:003891
Naphthalene ND ug/kg 11/02/15 17:38 91-20-310/30/15 08:003891
2-Nitroaniline ND ug/kg 11/02/15 17:38 88-74-410/30/15 08:0019501
3-Nitroaniline ND ug/kg 11/02/15 17:38 99-09-210/30/15 08:0019501
4-Nitroaniline ND ug/kg 11/02/15 17:38 100-01-610/30/15 08:007791
Nitrobenzene ND ug/kg 11/02/15 17:38 98-95-310/30/15 08:003891
2-Nitrophenol ND ug/kg 11/02/15 17:38 88-75-510/30/15 08:003891
4-Nitrophenol ND ug/kg 11/02/15 17:38 100-02-710/30/15 08:0019501
N-Nitrosodimethylamine ND ug/kg 11/02/15 17:38 62-75-910/30/15 08:003891
N-Nitroso-di-n-propylamine ND ug/kg 11/02/15 17:38 621-64-710/30/15 08:003891
N-Nitrosodiphenylamine ND ug/kg 11/02/15 17:38 86-30-610/30/15 08:003891
Pentachlorophenol ND ug/kg 11/02/15 17:38 87-86-510/30/15 08:0019501
Phenanthrene ND ug/kg 11/02/15 17:38 85-01-810/30/15 08:003891
Phenol ND ug/kg 11/02/15 17:38 108-95-210/30/15 08:003891
Pyrene ND ug/kg 11/02/15 17:38 129-00-010/30/15 08:003891
1,2,4-Trichlorobenzene ND ug/kg 11/02/15 17:38 120-82-110/30/15 08:003891
2,4,5-Trichlorophenol ND ug/kg 11/02/15 17:38 95-95-410/30/15 08:003891
2,4,6-Trichlorophenol ND ug/kg 11/02/15 17:38 88-06-210/30/15 08:003891
Surrogates
Nitrobenzene-d5 (S)41 %11/02/15 17:38 4165-60-010/30/15 08:0023-110 1
2-Fluorobiphenyl (S)40 %11/02/15 17:38 321-60-810/30/15 08:0030-110 1
Terphenyl-d14 (S)76 %11/02/15 17:38 1718-51-010/30/15 08:0028-110 1
Phenol-d6 (S)43 %11/02/15 17:38 13127-88-310/30/15 08:0022-110 1
2-Fluorophenol (S)42 %11/02/15 17:38 367-12-410/30/15 08:0013-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273833
ALAMANCE
Sample:ORD-1 5.5'Lab ID:92273833002 Collected:10/26/15 13:15 Received:10/28/15 12:35 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
2,4,6-Tribromophenol (S)53 %11/02/15 17:38 118-79-610/30/15 08:0027-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 10/29/15 22:16 67-64-198.7 1
Benzene ND ug/kg 10/29/15 22:16 71-43-24.9 1
Bromobenzene ND ug/kg 10/29/15 22:16 108-86-14.9 1
Bromochloromethane ND ug/kg 10/29/15 22:16 74-97-54.9 1
Bromodichloromethane ND ug/kg 10/29/15 22:16 75-27-44.9 1
Bromoform ND ug/kg 10/29/15 22:16 75-25-24.9 1
Bromomethane ND ug/kg 10/29/15 22:16 74-83-99.9 1
2-Butanone (MEK)ND ug/kg 10/29/15 22:16 78-93-398.7 1
n-Butylbenzene ND ug/kg 10/29/15 22:16 104-51-84.9 1
sec-Butylbenzene ND ug/kg 10/29/15 22:16 135-98-84.9 1
tert-Butylbenzene ND ug/kg 10/29/15 22:16 98-06-64.9 1
Carbon tetrachloride ND ug/kg 10/29/15 22:16 56-23-54.9 1
Chlorobenzene ND ug/kg 10/29/15 22:16 108-90-74.9 1
Chloroethane ND ug/kg 10/29/15 22:16 75-00-39.9 1
Chloroform ND ug/kg 10/29/15 22:16 67-66-34.9 1
Chloromethane ND ug/kg 10/29/15 22:16 74-87-39.9 1
2-Chlorotoluene ND ug/kg 10/29/15 22:16 95-49-84.9 1
4-Chlorotoluene ND ug/kg 10/29/15 22:16 106-43-44.9 1
1,2-Dibromo-3-chloropropane ND ug/kg 10/29/15 22:16 96-12-84.9 1
Dibromochloromethane ND ug/kg 10/29/15 22:16 124-48-14.9 1
1,2-Dibromoethane (EDB)ND ug/kg 10/29/15 22:16 106-93-44.9 1
Dibromomethane ND ug/kg 10/29/15 22:16 74-95-34.9 1
1,2-Dichlorobenzene ND ug/kg 10/29/15 22:16 95-50-14.9 1
1,3-Dichlorobenzene ND ug/kg 10/29/15 22:16 541-73-14.9 1
1,4-Dichlorobenzene ND ug/kg 10/29/15 22:16 106-46-74.9 1
Dichlorodifluoromethane ND ug/kg 10/29/15 22:16 75-71-89.9 1
1,1-Dichloroethane ND ug/kg 10/29/15 22:16 75-34-34.9 1
1,2-Dichloroethane ND ug/kg 10/29/15 22:16 107-06-24.9 1
1,1-Dichloroethene ND ug/kg 10/29/15 22:16 75-35-44.9 1
cis-1,2-Dichloroethene ND ug/kg 10/29/15 22:16 156-59-24.9 1
trans-1,2-Dichloroethene ND ug/kg 10/29/15 22:16 156-60-54.9 1
1,2-Dichloropropane ND ug/kg 10/29/15 22:16 78-87-54.9 1
1,3-Dichloropropane ND ug/kg 10/29/15 22:16 142-28-94.9 1
2,2-Dichloropropane ND ug/kg 10/29/15 22:16 594-20-74.9 1
1,1-Dichloropropene ND ug/kg 10/29/15 22:16 563-58-64.9 1
cis-1,3-Dichloropropene ND ug/kg 10/29/15 22:16 10061-01-54.9 1
trans-1,3-Dichloropropene ND ug/kg 10/29/15 22:16 10061-02-64.9 1
Diisopropyl ether ND ug/kg 10/29/15 22:16 108-20-34.9 1
Ethylbenzene ND ug/kg 10/29/15 22:16 100-41-44.9 1
Hexachloro-1,3-butadiene ND ug/kg 10/29/15 22:16 87-68-34.9 1
2-Hexanone ND ug/kg 10/29/15 22:16 591-78-649.3 1
Isopropylbenzene (Cumene)ND ug/kg 10/29/15 22:16 98-82-84.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 25
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92273833
ALAMANCE
Sample:ORD-1 5.5'Lab ID:92273833002 Collected:10/26/15 13:15 Received:10/28/15 12:35 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
p-Isopropyltoluene ND ug/kg 10/29/15 22:16 99-87-64.9 1
Methylene Chloride ND ug/kg 10/29/15 22:16 75-09-219.7 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 10/29/15 22:16 108-10-149.3 1
Methyl-tert-butyl ether ND ug/kg 10/29/15 22:16 1634-04-44.9 1
Naphthalene ND ug/kg 10/29/15 22:16 91-20-34.9 1
n-Propylbenzene ND ug/kg 10/29/15 22:16 103-65-14.9 1
Styrene ND ug/kg 10/29/15 22:16 100-42-54.9 1
1,1,1,2-Tetrachloroethane ND ug/kg 10/29/15 22:16 630-20-64.9 1
1,1,2,2-Tetrachloroethane ND ug/kg 10/29/15 22:16 79-34-54.9 1
Tetrachloroethene ND ug/kg 10/29/15 22:16 127-18-44.9 1
Toluene ND ug/kg 10/29/15 22:16 108-88-34.9 1
1,2,3-Trichlorobenzene ND ug/kg 10/29/15 22:16 87-61-64.9 1
1,2,4-Trichlorobenzene ND ug/kg 10/29/15 22:16 120-82-14.9 1
1,1,1-Trichloroethane ND ug/kg 10/29/15 22:16 71-55-64.9 1
1,1,2-Trichloroethane ND ug/kg 10/29/15 22:16 79-00-54.9 1
Trichloroethene ND ug/kg 10/29/15 22:16 79-01-64.9 1
Trichlorofluoromethane ND ug/kg 10/29/15 22:16 75-69-44.9 1
1,2,3-Trichloropropane ND ug/kg 10/29/15 22:16 96-18-44.9 1
1,2,4-Trimethylbenzene ND ug/kg 10/29/15 22:16 95-63-64.9 1
1,3,5-Trimethylbenzene ND ug/kg 10/29/15 22:16 108-67-84.9 1
Vinyl acetate ND ug/kg 10/29/15 22:16 108-05-449.3 1
Vinyl chloride ND ug/kg 10/29/15 22:16 75-01-49.9 1
Xylene (Total)ND ug/kg 10/29/15 22:16 1330-20-79.9 1
m&p-Xylene ND ug/kg 10/29/15 22:16 179601-23-19.9 1
o-Xylene ND ug/kg 10/29/15 22:16 95-47-64.9 1
Surrogates
Toluene-d8 (S)108 %10/29/15 22:16 2037-26-570-130 1
4-Bromofluorobenzene (S)96 %10/29/15 22:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)119 %10/29/15 22:16 17060-07-070-132 1
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 15.3 %10/30/15 07:210.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/10025
EPA 5035A/5030B
EPA 8015 Modified
Gasoline Range Organics
Associated Lab Samples:92273833001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594401
Associated Lab Samples:92273833001
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 10/30/15 21:42
4-Bromofluorobenzene (S)%94 70-167 10/30/15 21:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594402LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1594403
Gas Range Organics (C6-C10)mg/kg 53.250 106 70-16510251.0 4
4-Bromofluorobenzene (S)%94 70-16795
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
GCV/10026
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples:92273833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594414
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 2.5 N210/29/15 15:42
Aliphatic (C09-C12)mg/kg ND 2.5 N210/29/15 15:42
Aromatic (C09-C10)mg/kg ND 2.5 N210/29/15 15:42
4-Bromofluorobenzene (FID) (S)%99 70-130 10/29/15 15:42
4-Bromofluorobenzene (PID) (S)%99 70-130 10/29/15 15:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594415LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1594416
Aliphatic (C05-C08)mg/kg 16.0 N21510770-13010515.8 1 25
Aliphatic (C09-C12)mg/kg 17.3 N21511530-13011517.3 0 25
Aromatic (C09-C10)mg/kg 5.1 N2510270-1301015.0 1 25
4-Bromofluorobenzene (FID) (S)%103 70-130102
4-Bromofluorobenzene (PID) (S)%102 70-130102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/34050
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples:92273833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594780
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 4.7 10/29/15 14:02
1,1,1-Trichloroethane ug/kg ND 4.7 10/29/15 14:02
1,1,2,2-Tetrachloroethane ug/kg ND 4.7 10/29/15 14:02
1,1,2-Trichloroethane ug/kg ND 4.7 10/29/15 14:02
1,1-Dichloroethane ug/kg ND 4.7 10/29/15 14:02
1,1-Dichloroethene ug/kg ND 4.7 10/29/15 14:02
1,1-Dichloropropene ug/kg ND 4.7 10/29/15 14:02
1,2,3-Trichlorobenzene ug/kg ND 4.7 10/29/15 14:02
1,2,3-Trichloropropane ug/kg ND 4.7 10/29/15 14:02
1,2,4-Trichlorobenzene ug/kg ND 4.7 10/29/15 14:02
1,2,4-Trimethylbenzene ug/kg ND 4.7 10/29/15 14:02
1,2-Dibromo-3-chloropropane ug/kg ND 4.7 10/29/15 14:02
1,2-Dibromoethane (EDB)ug/kg ND 4.7 10/29/15 14:02
1,2-Dichlorobenzene ug/kg ND 4.7 10/29/15 14:02
1,2-Dichloroethane ug/kg ND 4.7 10/29/15 14:02
1,2-Dichloropropane ug/kg ND 4.7 10/29/15 14:02
1,3,5-Trimethylbenzene ug/kg ND 4.7 10/29/15 14:02
1,3-Dichlorobenzene ug/kg ND 4.7 10/29/15 14:02
1,3-Dichloropropane ug/kg ND 4.7 10/29/15 14:02
1,4-Dichlorobenzene ug/kg ND 4.7 10/29/15 14:02
2,2-Dichloropropane ug/kg ND 4.7 10/29/15 14:02
2-Butanone (MEK)ug/kg ND 94.7 10/29/15 14:02
2-Chlorotoluene ug/kg ND 4.7 10/29/15 14:02
2-Hexanone ug/kg ND 47.3 10/29/15 14:02
4-Chlorotoluene ug/kg ND 4.7 10/29/15 14:02
4-Methyl-2-pentanone (MIBK)ug/kg ND 47.3 10/29/15 14:02
Acetone ug/kg ND 94.7 10/29/15 14:02
Benzene ug/kg ND 4.7 10/29/15 14:02
Bromobenzene ug/kg ND 4.7 10/29/15 14:02
Bromochloromethane ug/kg ND 4.7 10/29/15 14:02
Bromodichloromethane ug/kg ND 4.7 10/29/15 14:02
Bromoform ug/kg ND 4.7 10/29/15 14:02
Bromomethane ug/kg ND 9.5 10/29/15 14:02
Carbon tetrachloride ug/kg ND 4.7 10/29/15 14:02
Chlorobenzene ug/kg ND 4.7 10/29/15 14:02
Chloroethane ug/kg ND 9.5 10/29/15 14:02
Chloroform ug/kg ND 4.7 10/29/15 14:02
Chloromethane ug/kg ND 9.5 10/29/15 14:02
cis-1,2-Dichloroethene ug/kg ND 4.7 10/29/15 14:02
cis-1,3-Dichloropropene ug/kg ND 4.7 10/29/15 14:02
Dibromochloromethane ug/kg ND 4.7 10/29/15 14:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1594780
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
Dibromomethane ug/kg ND 4.7 10/29/15 14:02
Dichlorodifluoromethane ug/kg ND 9.5 10/29/15 14:02
Diisopropyl ether ug/kg ND 4.7 10/29/15 14:02
Ethylbenzene ug/kg ND 4.7 10/29/15 14:02
Hexachloro-1,3-butadiene ug/kg ND 4.7 10/29/15 14:02
Isopropylbenzene (Cumene)ug/kg ND 4.7 10/29/15 14:02
m&p-Xylene ug/kg ND 9.5 10/29/15 14:02
Methyl-tert-butyl ether ug/kg ND 4.7 10/29/15 14:02
Methylene Chloride ug/kg ND 18.9 10/29/15 14:02
n-Butylbenzene ug/kg ND 4.7 10/29/15 14:02
n-Propylbenzene ug/kg ND 4.7 10/29/15 14:02
Naphthalene ug/kg ND 4.7 10/29/15 14:02
o-Xylene ug/kg ND 4.7 10/29/15 14:02
p-Isopropyltoluene ug/kg ND 4.7 10/29/15 14:02
sec-Butylbenzene ug/kg ND 4.7 10/29/15 14:02
Styrene ug/kg ND 4.7 10/29/15 14:02
tert-Butylbenzene ug/kg ND 4.7 10/29/15 14:02
Tetrachloroethene ug/kg ND 4.7 10/29/15 14:02
Toluene ug/kg ND 4.7 10/29/15 14:02
trans-1,2-Dichloroethene ug/kg ND 4.7 10/29/15 14:02
trans-1,3-Dichloropropene ug/kg ND 4.7 10/29/15 14:02
Trichloroethene ug/kg ND 4.7 10/29/15 14:02
Trichlorofluoromethane ug/kg ND 4.7 10/29/15 14:02
Vinyl acetate ug/kg ND 47.3 10/29/15 14:02
Vinyl chloride ug/kg ND 9.5 10/29/15 14:02
Xylene (Total)ug/kg ND 9.5 10/29/15 14:02
1,2-Dichloroethane-d4 (S)%84 70-132 10/29/15 14:02
4-Bromofluorobenzene (S)%101 70-130 10/29/15 14:02
Toluene-d8 (S)%109 70-130 10/29/15 14:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594781LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 55.653.3 104 74-137
1,1,1-Trichloroethane ug/kg 54.353.3 102 67-140
1,1,2,2-Tetrachloroethane ug/kg 55.653.3 104 72-141
1,1,2-Trichloroethane ug/kg 54.053.3 101 78-138
1,1-Dichloroethane ug/kg 56.553.3 106 69-134
1,1-Dichloroethene ug/kg 60.353.3 113 67-138
1,1-Dichloropropene ug/kg 65.653.3 123 69-139
1,2,3-Trichlorobenzene ug/kg 62.453.3 117 70-146
1,2,3-Trichloropropane ug/kg 54.753.3 103 69-144
1,2,4-Trichlorobenzene ug/kg 60.653.3 114 68-148
1,2,4-Trimethylbenzene ug/kg 57.553.3 108 74-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594781LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/kg 58.953.3 111 65-140
1,2-Dibromoethane (EDB)ug/kg 61.753.3 116 77-135
1,2-Dichlorobenzene ug/kg 60.353.3 113 77-141
1,2-Dichloroethane ug/kg 51.853.3 97 65-137
1,2-Dichloropropane ug/kg 58.953.3 111 72-136
1,3,5-Trimethylbenzene ug/kg 59.353.3 111 76-133
1,3-Dichlorobenzene ug/kg 60.453.3 113 74-138
1,3-Dichloropropane ug/kg 58.353.3 109 71-139
1,4-Dichlorobenzene ug/kg 59.853.3 112 76-138
2,2-Dichloropropane ug/kg 56.053.3 105 68-137
2-Butanone (MEK)ug/kg 116107 108 58-147
2-Chlorotoluene ug/kg 58.653.3 110 73-139
2-Hexanone ug/kg 128107 120 62-145
4-Chlorotoluene ug/kg 59.853.3 112 76-141
4-Methyl-2-pentanone (MIBK)ug/kg 118107 111 64-149
Acetone ug/kg 118107 111 53-153
Benzene ug/kg 59.653.3 112 73-135
Bromobenzene ug/kg 58.053.3 109 75-133
Bromochloromethane ug/kg 57.453.3 108 73-134
Bromodichloromethane ug/kg 55.253.3 103 71-135
Bromoform ug/kg 48.553.3 91 66-141
Bromomethane ug/kg 64.053.3 120 53-160
Carbon tetrachloride ug/kg 54.653.3 103 60-145
Chlorobenzene ug/kg 58.053.3 109 78-130
Chloroethane ug/kg 50.753.3 95 64-149
Chloroform ug/kg 56.653.3 106 70-134
Chloromethane ug/kg 57.753.3 108 52-150
cis-1,2-Dichloroethene ug/kg 60.353.3 113 70-133
cis-1,3-Dichloropropene ug/kg 58.753.3 110 68-134
Dibromochloromethane ug/kg 51.353.3 96 71-138
Dibromomethane ug/kg 56.853.3 107 74-130
Dichlorodifluoromethane ug/kg 50.253.3 94 40-160
Diisopropyl ether ug/kg 63.853.3 120 69-141
Ethylbenzene ug/kg 56.553.3 106 75-133
Hexachloro-1,3-butadiene ug/kg 58.853.3 110 68-143
Isopropylbenzene (Cumene)ug/kg 61.753.3 116 76-143
m&p-Xylene ug/kg 113107 106 75-136
Methyl-tert-butyl ether ug/kg 59.453.3 111 68-144
Methylene Chloride ug/kg 58.753.3 110 45-154
n-Butylbenzene ug/kg 61.853.3 116 72-137
n-Propylbenzene ug/kg 60.953.3 114 76-136
Naphthalene ug/kg 65.453.3 123 68-151
o-Xylene ug/kg 57.153.3 107 76-141
p-Isopropyltoluene ug/kg 60.453.3 113 76-140
sec-Butylbenzene ug/kg 61.953.3 116 79-139
Styrene ug/kg 59.253.3 111 79-137
tert-Butylbenzene ug/kg 51.653.3 97 74-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1594781LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 56.453.3 106 71-138
Toluene ug/kg 57.453.3 108 74-131
trans-1,2-Dichloroethene ug/kg 60.953.3 114 67-135
trans-1,3-Dichloropropene ug/kg 58.653.3 110 65-146
Trichloroethene ug/kg 55.453.3 104 67-135
Trichlorofluoromethane ug/kg 52.953.3 99 59-144
Vinyl acetate ug/kg 120 F310711240-160
Vinyl chloride ug/kg 61.153.3 115 56-141
Xylene (Total)ug/kg 170160 106 76-137
1,2-Dichloroethane-d4 (S)%88 70-132
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%97 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/38697
EPA 3546
EPA 8015 Modified
8015 Solid GCSV
Associated Lab Samples:92273833001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1593561
Associated Lab Samples:92273833001
Matrix:Solid
Analyzed
Diesel Range Organics(C10-C28)mg/kg ND 5.0 10/29/15 11:49
n-Pentacosane (S)%73 41-119 10/29/15 11:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1593562LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 54.166.7 81 49-113
n-Pentacosane (S)%71 41-119
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1593564MATRIX SPIKE SAMPLE:
MSSpike
Result
92273219002
Diesel Range Organics(C10-C28)mg/kg 8090 H3,M380.8 4300 10-1464610
n-Pentacosane (S)%P3,S527141-119
Parameter Units
Dup
Result QualifiersRPDResult
92273225002
1593563SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 3280 D6,H3565800
n-Pentacosane (S)%227 P3,S56214
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/38735
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples:92273833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595380
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 330 10/30/15 20:11
1,2-Dichlorobenzene ug/kg ND 330 10/30/15 20:11
1,3-Dichlorobenzene ug/kg ND 330 10/30/15 20:11
1,4-Dichlorobenzene ug/kg ND 330 10/30/15 20:11
1-Methylnaphthalene ug/kg ND 330 10/30/15 20:11
2,4,5-Trichlorophenol ug/kg ND 330 10/30/15 20:11
2,4,6-Trichlorophenol ug/kg ND 330 10/30/15 20:11
2,4-Dichlorophenol ug/kg ND 330 10/30/15 20:11
2,4-Dimethylphenol ug/kg ND 330 10/30/15 20:11
2,4-Dinitrophenol ug/kg ND 1650 10/30/15 20:11
2,4-Dinitrotoluene ug/kg ND 330 10/30/15 20:11
2,6-Dinitrotoluene ug/kg ND 330 10/30/15 20:11
2-Chloronaphthalene ug/kg ND 330 10/30/15 20:11
2-Chlorophenol ug/kg ND 330 10/30/15 20:11
2-Methylnaphthalene ug/kg ND 330 10/30/15 20:11
2-Methylphenol(o-Cresol)ug/kg ND 330 10/30/15 20:11
2-Nitroaniline ug/kg ND 1650 10/30/15 20:11
2-Nitrophenol ug/kg ND 330 10/30/15 20:11
3&4-Methylphenol(m&p Cresol)ug/kg ND 330 10/30/15 20:11
3,3'-Dichlorobenzidine ug/kg ND 1650 10/30/15 20:11
3-Nitroaniline ug/kg ND 1650 10/30/15 20:11
4,6-Dinitro-2-methylphenol ug/kg ND 660 10/30/15 20:11
4-Bromophenylphenyl ether ug/kg ND 330 10/30/15 20:11
4-Chloro-3-methylphenol ug/kg ND 660 10/30/15 20:11
4-Chloroaniline ug/kg ND 1650 10/30/15 20:11
4-Chlorophenylphenyl ether ug/kg ND 330 10/30/15 20:11
4-Nitroaniline ug/kg ND 660 10/30/15 20:11
4-Nitrophenol ug/kg ND 1650 10/30/15 20:11
Acenaphthene ug/kg ND 330 10/30/15 20:11
Acenaphthylene ug/kg ND 330 10/30/15 20:11
Aniline ug/kg ND 330 10/30/15 20:11
Anthracene ug/kg ND 330 10/30/15 20:11
Benzo(a)anthracene ug/kg ND 330 10/30/15 20:11
Benzo(a)pyrene ug/kg ND 330 10/30/15 20:11
Benzo(b)fluoranthene ug/kg ND 330 10/30/15 20:11
Benzo(g,h,i)perylene ug/kg ND 330 10/30/15 20:11
Benzo(k)fluoranthene ug/kg ND 330 10/30/15 20:11
Benzoic Acid ug/kg ND 1650 10/30/15 20:11
Benzyl alcohol ug/kg ND 660 10/30/15 20:11
bis(2-Chloroethoxy)methane ug/kg ND 330 10/30/15 20:11
bis(2-Chloroethyl) ether ug/kg ND 330 10/30/15 20:11
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1595380
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
bis(2-Chloroisopropyl) ether ug/kg ND 330 10/30/15 20:11
bis(2-Ethylhexyl)phthalate ug/kg ND 330 10/30/15 20:11
Butylbenzylphthalate ug/kg ND 330 10/30/15 20:11
Chrysene ug/kg ND 330 10/30/15 20:11
Di-n-butylphthalate ug/kg ND 330 10/30/15 20:11
Di-n-octylphthalate ug/kg ND 330 10/30/15 20:11
Dibenz(a,h)anthracene ug/kg ND 330 10/30/15 20:11
Dibenzofuran ug/kg ND 330 10/30/15 20:11
Diethylphthalate ug/kg ND 330 10/30/15 20:11
Dimethylphthalate ug/kg ND 330 10/30/15 20:11
Fluoranthene ug/kg ND 330 10/30/15 20:11
Fluorene ug/kg ND 330 10/30/15 20:11
Hexachloro-1,3-butadiene ug/kg ND 330 10/30/15 20:11
Hexachlorobenzene ug/kg ND 330 10/30/15 20:11
Hexachlorocyclopentadiene ug/kg ND 330 10/30/15 20:11
Hexachloroethane ug/kg ND 330 10/30/15 20:11
Indeno(1,2,3-cd)pyrene ug/kg ND 330 10/30/15 20:11
Isophorone ug/kg ND 330 10/30/15 20:11
N-Nitroso-di-n-propylamine ug/kg ND 330 10/30/15 20:11
N-Nitrosodimethylamine ug/kg ND 330 10/30/15 20:11
N-Nitrosodiphenylamine ug/kg ND 330 10/30/15 20:11
Naphthalene ug/kg ND 330 10/30/15 20:11
Nitrobenzene ug/kg ND 330 10/30/15 20:11
Pentachlorophenol ug/kg ND 1650 10/30/15 20:11
Phenanthrene ug/kg ND 330 10/30/15 20:11
Phenol ug/kg ND 330 10/30/15 20:11
Pyrene ug/kg ND 330 10/30/15 20:11
2,4,6-Tribromophenol (S)%47 27-110 10/30/15 20:11
2-Fluorobiphenyl (S)%44 30-110 10/30/15 20:11
2-Fluorophenol (S)%41 13-110 10/30/15 20:11
Nitrobenzene-d5 (S)%40 23-110 10/30/15 20:11
Phenol-d6 (S)%39 22-110 10/30/15 20:11
Terphenyl-d14 (S)%89 28-110 10/30/15 20:11
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595381LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595382
1,2,4-Trichlorobenzene ug/kg 14601670 87 36-120831390 5 30
1,2-Dichlorobenzene ug/kg 13701670 82 41-120751260 8 30
1,3-Dichlorobenzene ug/kg 12901670 77 66-120731210 6 30
1,4-Dichlorobenzene ug/kg 13101670 79 42-120741230 6 30
1-Methylnaphthalene ug/kg 15001670 90 40-120871440 4 30
2,4,5-Trichlorophenol ug/kg 16801670 101 37-120941570 6 30
2,4,6-Trichlorophenol ug/kg 15201670 91 40-120851420 7 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595381LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595382
2,4-Dichlorophenol ug/kg 16001670 96 33-120901500 6 30
2,4-Dimethylphenol ug/kg 14601670 87 36-120811350 7 30
2,4-Dinitrophenol ug/kg 65008330 78 22-121715930 9 30
2,4-Dinitrotoluene ug/kg 15501670 93 60-120921530 1 30
2,6-Dinitrotoluene ug/kg 15201670 91 54-120881470 3 30
2-Chloronaphthalene ug/kg 14101670 84 41-120791310 7 30
2-Chlorophenol ug/kg 14701670 88 39-120791320 11 30
2-Methylnaphthalene ug/kg 14001670 84 26-120801330 6 30
2-Methylphenol(o-Cresol)ug/kg 16401670 98 41-120881470 11 30
2-Nitroaniline ug/kg 24903330 75 45-120722410 3 30
2-Nitrophenol ug/kg 15401670 92 35-120901510 2 30
3&4-Methylphenol(m&p Cresol)ug/kg 15801670 95 35-120841400 12 30
3,3'-Dichlorobenzidine ug/kg 27803330 83 16-125842800 1 30
3-Nitroaniline ug/kg 25903330 78 45-120792640 2 30
4,6-Dinitro-2-methylphenol ug/kg 27203330 82 46-120802680 2 30
4-Bromophenylphenyl ether ug/kg 14201670 85 36-120851420 0 30
4-Chloro-3-methylphenol ug/kg 32403330 97 37-120933120 4 30
4-Chloroaniline ug/kg 24503330 74 35-120712360 4 30
4-Chlorophenylphenyl ether ug/kg 14001670 84 30-120811350 4 30
4-Nitroaniline ug/kg 29403330 88 48-120882930 0 30
4-Nitrophenol ug/kg 73408330 88 43-120877210 2 30
Acenaphthene ug/kg 14401670 86 46-120811350 6 30
Acenaphthylene ug/kg 15301670 92 46-120861430 7 30
Aniline ug/kg 11601670 69 33-120651080 7 30
Anthracene ug/kg 14901670 90 63-120911520 2 30
Benzo(a)anthracene ug/kg 15701670 94 61-120941570 0 30
Benzo(a)pyrene ug/kg 14501670 87 59-120891480 2 30
Benzo(b)fluoranthene ug/kg 13701670 82 55-120821370 0 30
Benzo(g,h,i)perylene ug/kg 11901670 72 57-120711180 1 30
Benzo(k)fluoranthene ug/kg 18301670 110 56-1201141900 4 30
Benzoic Acid ug/kg 64808330 78 13-120766340 2 30
Benzyl alcohol ug/kg 28403330 85 34-120772570 10 30
bis(2-Chloroethoxy)methane ug/kg 12901670 77 21-120731220 5 30
bis(2-Chloroethyl) ether ug/kg 12801670 77 25-120691140 11 30
bis(2-Chloroisopropyl) ether ug/kg 10201670 61 13-12055921 10 30
bis(2-Ethylhexyl)phthalate ug/kg 15901670 95 56-123941570 1 30
Butylbenzylphthalate ug/kg 16301670 98 57-120971620 1 30
Chrysene ug/kg 15601670 93 64-120961600 3 30
Di-n-butylphthalate ug/kg 15801670 95 58-120961590 1 30
Di-n-octylphthalate ug/kg 13201670 79 47-121781290 2 30
Dibenz(a,h)anthracene ug/kg 12601670 75 56-120751250 1 30
Dibenzofuran ug/kg 14401670 86 43-120821370 5 30
Diethylphthalate ug/kg 14401670 87 55-120861440 0 30
Dimethylphthalate ug/kg 14201670 85 54-120851410 1 30
Fluoranthene ug/kg 15701670 94 61-120971610 3 30
Fluorene ug/kg 15301670 92 51-120881460 4 30
Hexachloro-1,3-butadiene ug/kg 14601670 88 22-120861430 2 30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1595381LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1595382
Hexachlorobenzene ug/kg 16901670 102 53-1201011680 1 30
Hexachlorocyclopentadiene ug/kg 10501670 63 18-15054906 15 30
Hexachloroethane ug/kg 12501670 75 39-120701170 7 30
Indeno(1,2,3-cd)pyrene ug/kg 12501670 75 58-120741230 2 30
Isophorone ug/kg 13301670 80 38-120751240 7 30
N-Nitroso-di-n-propylamine ug/kg 13201670 79 30-120701170 12 30
N-Nitrosodimethylamine ug/kg 12501670 75 32-120681140 9 30
N-Nitrosodiphenylamine ug/kg 13601670 82 50-120811360 0 30
Naphthalene ug/kg 14201670 85 38-120811350 5 30
Nitrobenzene ug/kg 13101670 78 37-120741230 6 30
Pentachlorophenol ug/kg 30603330 92 10-120892980 3 30
Phenanthrene ug/kg 13601670 81 62-120821370 1 30
Phenol ug/kg 16601670 100 37-120891490 11 30
Pyrene ug/kg 17301670 104 63-1201051750 1 30
2,4,6-Tribromophenol (S)%102 27-11099
2-Fluorobiphenyl (S)%83 30-11077
2-Fluorophenol (S)%85 13-11076
Nitrobenzene-d5 (S)%80 23-11075
Phenol-d6 (S)%91 22-11081
Terphenyl-d14 (S)%98 28-11098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/38791
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples:92273833002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1596633
Associated Lab Samples:92273833002
Matrix:Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 10.0 N211/04/15 20:29
Aliphatic (C19-C36)mg/kg ND 10.0 N211/04/15 20:29
Aromatic (C11-C22)mg/kg ND 10.0 N211/05/15 20:07
2-Bromonaphthalene (S)%97 40-140 11/05/15 20:07
2-Fluorobiphenyl (S)%98 40-140 11/05/15 20:07
Nonatriacontane (S)%80 40-140 11/04/15 20:29
o-Terphenyl (S)%80 40-140 11/05/15 20:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1596634LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1596635
Aliphatic (C09-C18)mg/kg ND N2107840-14076ND 50
Aliphatic (C19-C36)mg/kg 11.0 N213.3 83 40-1408010.7 3 50
Aromatic (C11-C22)mg/kg 25.6 N228.3 90 40-1409125.7 1 50
2-Bromonaphthalene (S)%100 40-14095
2-Fluorobiphenyl (S)%101 40-14098
Nonatriacontane (S)%84 40-14086
o-Terphenyl (S)%92 40-14092
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 25
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92273833
ALAMANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
PMST/8516
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples:92273833001, 92273833002
Parameter Units
Dup
Result QualifiersRPDResult
92273654001
1595308SAMPLE DUPLICATE:
Percent Moisture %13.5 313.1
Parameter Units
Dup
Result QualifiersRPDResult
92273843001
1595309SAMPLE DUPLICATE:
Percent Moisture %51.3 151.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 25
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92273833
ALAMANCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.D6
The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.F3
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3
The lab does not hold TNI accreditation for this parameter.N2
Sample extract could not be concentrated to the routine final volume, resulting in elevated reporting limits.P3
Surrogate recovery not evaluated against control limits due to sample dilution.S4
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 25
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92273833
ALAMANCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92273833001 OEXT/38697 GCSV/23053ORD-1 2'EPA 3546 EPA 8015 Modified
92273833002 OEXT/38791 GCSV/23107ORD-1 5.5'MADEP EPH MADEP EPH
92273833001 GCV/10025 GCV/10031ORD-1 2'EPA 5035A/5030B EPA 8015 Modified
92273833002 GCV/10026 GCV/10029ORD-1 5.5'MADEP VPH MADEP VPH
92273833002 OEXT/38735 MSSV/11455ORD-1 5.5'EPA 3546 EPA 8270
92273833002 MSV/34050ORD-1 5.5'EPA 8260
92273833001 PMST/8516ORD-1 2'ASTM D2974-87
92273833002 PMST/8516ORD-1 5.5'ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 11/09/2015 09:16 AM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 25
Page 24 of 25
Page 25 of 25