WS-9385_44606_CA_IAR_20180417

#=CL#
April 09, 2018
LIMS USE: FR - MIKE JONES
LIMS OBJECT ID: 92378852
92378852
Project:
Pace Project No.:
RE:
Mr. Mike Jones
Pyramid Environmental
P.O. Box 16265
503 Industrial Avenue
Greensboro, NC 27416
Alamance Oil
Dear Mr. Jones:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92378852
Alamance Oil
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92378852
Alamance Oil
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92378852001 ORD-2 MADEP EPH 7 PASI-CNU1
MADEP VPH 5 PASI-CCAH
EPA 8270 74 PASI-CRES
EPA 8260 70 PASI-CDLK
ASTM D2974-87 1 PASI-CKDF
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92378852
Alamance Oil
Sample: ORD-2 Lab ID: 92378852001 Collected: 03/28/18 16:00 Received: 03/29/18 09:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPHMADEP EPH NC Soil
Aliphatic (C09-C18)31.4 mg/kg 04/05/18 12:37 N204/04/18 12:0012.8 1
Aliphatic (C19-C36)ND mg/kg 04/05/18 12:37 N204/04/18 12:0012.8 1
Aromatic (C11-C22)45.2 mg/kg 04/05/18 12:37 N204/04/18 12:0012.8 1
Surrogates
Nonatriacontane (S)48 %04/05/18 12:37 7194-86-704/04/18 12:0040-140 1
o-Terphenyl (S)104 %04/05/18 12:37 84-15-104/04/18 12:0040-140 1
2-Fluorobiphenyl (S)125 %04/05/18 12:37 321-60-804/04/18 12:0040-140 1
2-Bromonaphthalene (S)60 %04/05/18 12:37 580-13-204/04/18 12:0040-140 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPHVPH NC Soil
Aliphatic (C05-C08)ND mg/kg 04/02/18 15:07 N203/30/18 14:072.6 1
Aliphatic (C09-C12)15.2 mg/kg 04/02/18 15:07 N203/30/18 14:072.6 1
Aromatic (C09-C10)2.9 mg/kg 04/02/18 15:07 N203/30/18 14:072.6 1
Surrogates
4-Bromofluorobenzene (FID) (S)137 %04/02/18 15:07 460-00-4 S203/30/18 14:0770-130 1
4-Bromofluorobenzene (PID) (S)115 %04/02/18 15:07 460-00-403/30/18 14:0770-130 1
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Acenaphthene ND ug/kg 04/08/18 19:27 83-32-903/29/18 15:30427 1
Acenaphthylene ND ug/kg 04/08/18 19:27 208-96-803/29/18 15:30427 1
Aniline ND ug/kg 04/08/18 19:27 62-53-303/29/18 15:30427 1
Anthracene ND ug/kg 04/08/18 19:27 120-12-703/29/18 15:30427 1
Benzo(a)anthracene ND ug/kg 04/08/18 19:27 56-55-303/29/18 15:30427 1
Benzo(a)pyrene ND ug/kg 04/08/18 19:27 50-32-803/29/18 15:30427 1
Benzo(b)fluoranthene ND ug/kg 04/08/18 19:27 205-99-203/29/18 15:30427 1
Benzo(g,h,i)perylene ND ug/kg 04/08/18 19:27 191-24-203/29/18 15:30427 1
Benzo(k)fluoranthene ND ug/kg 04/08/18 19:27 207-08-903/29/18 15:30427 1
Benzoic Acid ND ug/kg 04/08/18 19:27 65-85-003/29/18 15:302130 1
Benzyl alcohol ND ug/kg 04/08/18 19:27 100-51-603/29/18 15:30853 1
4-Bromophenylphenyl ether ND ug/kg 04/08/18 19:27 101-55-303/29/18 15:30427 1
Butylbenzylphthalate ND ug/kg 04/08/18 19:27 85-68-703/29/18 15:30427 1
4-Chloro-3-methylphenol ND ug/kg 04/08/18 19:27 59-50-703/29/18 15:30853 1
4-Chloroaniline ND ug/kg 04/08/18 19:27 106-47-803/29/18 15:302130 1
bis(2-Chloroethoxy)methane ND ug/kg 04/08/18 19:27 111-91-103/29/18 15:30427 1
bis(2-Chloroethyl) ether ND ug/kg 04/08/18 19:27 111-44-403/29/18 15:30427 1
2-Chloronaphthalene ND ug/kg 04/08/18 19:27 91-58-703/29/18 15:30427 1
2-Chlorophenol ND ug/kg 04/08/18 19:27 95-57-803/29/18 15:30427 1
4-Chlorophenylphenyl ether ND ug/kg 04/08/18 19:27 7005-72-303/29/18 15:30427 1
Chrysene ND ug/kg 04/08/18 19:27 218-01-903/29/18 15:30427 1
Dibenz(a,h)anthracene ND ug/kg 04/08/18 19:27 53-70-303/29/18 15:30427 1
Dibenzofuran ND ug/kg 04/08/18 19:27 132-64-903/29/18 15:30427 1
1,2-Dichlorobenzene ND ug/kg 04/08/18 19:27 95-50-103/29/18 15:30427 1
1,3-Dichlorobenzene ND ug/kg 04/08/18 19:27 541-73-103/29/18 15:30427 1
1,4-Dichlorobenzene ND ug/kg 04/08/18 19:27 106-46-703/29/18 15:30427 1
3,3'-Dichlorobenzidine ND ug/kg 04/08/18 19:27 91-94-103/29/18 15:302130 1
2,4-Dichlorophenol ND ug/kg 04/08/18 19:27 120-83-203/29/18 15:30427 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92378852
Alamance Oil
Sample: ORD-2 Lab ID: 92378852001 Collected: 03/28/18 16:00 Received: 03/29/18 09:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Diethylphthalate ND ug/kg 04/08/18 19:27 84-66-203/29/18 15:30427 1
2,4-Dimethylphenol ND ug/kg 04/08/18 19:27 105-67-903/29/18 15:30427 1
Dimethylphthalate ND ug/kg 04/08/18 19:27 131-11-303/29/18 15:30427 1
Di-n-butylphthalate ND ug/kg 04/08/18 19:27 84-74-203/29/18 15:30427 1
4,6-Dinitro-2-methylphenol ND ug/kg 04/08/18 19:27 534-52-103/29/18 15:30853 1
2,4-Dinitrophenol ND ug/kg 04/08/18 19:27 51-28-503/29/18 15:302130 1
2,4-Dinitrotoluene ND ug/kg 04/08/18 19:27 121-14-203/29/18 15:30427 1
2,6-Dinitrotoluene ND ug/kg 04/08/18 19:27 606-20-203/29/18 15:30427 1
Di-n-octylphthalate ND ug/kg 04/08/18 19:27 117-84-003/29/18 15:30427 1
bis(2-Ethylhexyl)phthalate ND ug/kg 04/08/18 19:27 117-81-703/29/18 15:30427 1
Fluoranthene ND ug/kg 04/08/18 19:27 206-44-003/29/18 15:30427 1
Fluorene ND ug/kg 04/08/18 19:27 86-73-703/29/18 15:30427 1
Hexachloro-1,3-butadiene ND ug/kg 04/08/18 19:27 87-68-303/29/18 15:30427 1
Hexachlorobenzene ND ug/kg 04/08/18 19:27 118-74-103/29/18 15:30427 1
Hexachlorocyclopentadiene ND ug/kg 04/08/18 19:27 77-47-403/29/18 15:30427 1
Hexachloroethane ND ug/kg 04/08/18 19:27 67-72-103/29/18 15:30427 1
Indeno(1,2,3-cd)pyrene ND ug/kg 04/08/18 19:27 193-39-503/29/18 15:30427 1
Isophorone ND ug/kg 04/08/18 19:27 78-59-103/29/18 15:30427 1
1-Methylnaphthalene ND ug/kg 04/08/18 19:27 90-12-003/29/18 15:30427 1
2-Methylnaphthalene ND ug/kg 04/08/18 19:27 91-57-603/29/18 15:30427 1
2-Methylphenol(o-Cresol)ND ug/kg 04/08/18 19:27 95-48-703/29/18 15:30427 1
3&4-Methylphenol(m&p Cresol)ND ug/kg 04/08/18 19:27 15831-10-403/29/18 15:30427 1
Naphthalene ND ug/kg 04/08/18 19:27 91-20-303/29/18 15:30427 1
2-Nitroaniline ND ug/kg 04/08/18 19:27 88-74-403/29/18 15:302130 1
3-Nitroaniline ND ug/kg 04/08/18 19:27 99-09-203/29/18 15:302130 1
4-Nitroaniline ND ug/kg 04/08/18 19:27 100-01-603/29/18 15:30853 1
Nitrobenzene ND ug/kg 04/08/18 19:27 98-95-303/29/18 15:30427 1
2-Nitrophenol ND ug/kg 04/08/18 19:27 88-75-503/29/18 15:30427 1
4-Nitrophenol ND ug/kg 04/08/18 19:27 100-02-703/29/18 15:302130 1
N-Nitrosodimethylamine ND ug/kg 04/08/18 19:27 62-75-903/29/18 15:30427 1
N-Nitroso-di-n-propylamine ND ug/kg 04/08/18 19:27 621-64-703/29/18 15:30427 1
N-Nitrosodiphenylamine ND ug/kg 04/08/18 19:27 86-30-603/29/18 15:30427 1
2,2'-Oxybis(1-chloropropane)ND ug/kg 04/08/18 19:27 108-60-103/29/18 15:30427 1
Pentachlorophenol ND ug/kg 04/08/18 19:27 87-86-503/29/18 15:302130 1
Phenanthrene ND ug/kg 04/08/18 19:27 85-01-803/29/18 15:30427 1
Phenol ND ug/kg 04/08/18 19:27 108-95-203/29/18 15:30427 1
Pyrene ND ug/kg 04/08/18 19:27 129-00-003/29/18 15:30427 1
1,2,4-Trichlorobenzene ND ug/kg 04/08/18 19:27 120-82-103/29/18 15:30427 1
2,4,5-Trichlorophenol ND ug/kg 04/08/18 19:27 95-95-403/29/18 15:30427 1
2,4,6-Trichlorophenol ND ug/kg 04/08/18 19:27 88-06-203/29/18 15:30427 1
Surrogates
Nitrobenzene-d5 (S)52 %04/08/18 19:27 4165-60-003/29/18 15:3023-110 1
2-Fluorobiphenyl (S)46 %04/08/18 19:27 321-60-803/29/18 15:3030-110 1
Terphenyl-d14 (S)51 %04/08/18 19:27 1718-51-003/29/18 15:3028-110 1
Phenol-d6 (S)43 %04/08/18 19:27 13127-88-303/29/18 15:3022-110 1
2-Fluorophenol (S)48 %04/08/18 19:27 367-12-403/29/18 15:3013-110 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92378852
Alamance Oil
Sample: ORD-2 Lab ID: 92378852001 Collected: 03/28/18 16:00 Received: 03/29/18 09:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 8270 Preparation Method: EPA 35468270 MSSV Microwave
Surrogates
2,4,6-Tribromophenol (S)61 %04/08/18 19:27 118-79-603/29/18 15:3027-110 1
Analytical Method: EPA 82608260/5035A Volatile Organics
Acetone ND ug/kg 04/02/18 22:18 67-64-12450 25
Benzene ND ug/kg 04/02/18 22:18 71-43-2122 25
Bromobenzene ND ug/kg 04/02/18 22:18 108-86-1122 25
Bromochloromethane ND ug/kg 04/02/18 22:18 74-97-5122 25
Bromodichloromethane ND ug/kg 04/02/18 22:18 75-27-4122 25
Bromoform ND ug/kg 04/02/18 22:18 75-25-2122 25
Bromomethane ND ug/kg 04/02/18 22:18 74-83-9245 25
2-Butanone (MEK)ND ug/kg 04/02/18 22:18 78-93-32450 25
n-Butylbenzene ND ug/kg 04/02/18 22:18 104-51-8122 25
sec-Butylbenzene ND ug/kg 04/02/18 22:18 135-98-8122 25
tert-Butylbenzene ND ug/kg 04/02/18 22:18 98-06-6122 25
Carbon tetrachloride ND ug/kg 04/02/18 22:18 56-23-5122 25
Chlorobenzene ND ug/kg 04/02/18 22:18 108-90-7122 25
Chloroethane ND ug/kg 04/02/18 22:18 75-00-3245 25
Chloroform ND ug/kg 04/02/18 22:18 67-66-3122 25
Chloromethane ND ug/kg 04/02/18 22:18 74-87-3245 25
2-Chlorotoluene ND ug/kg 04/02/18 22:18 95-49-8122 25
4-Chlorotoluene ND ug/kg 04/02/18 22:18 106-43-4122 25
1,2-Dibromo-3-chloropropane ND ug/kg 04/02/18 22:18 96-12-8122 25
Dibromochloromethane ND ug/kg 04/02/18 22:18 124-48-1122 25
1,2-Dibromoethane (EDB)ND ug/kg 04/02/18 22:18 106-93-4122 25
Dibromomethane ND ug/kg 04/02/18 22:18 74-95-3122 25
1,2-Dichlorobenzene ND ug/kg 04/02/18 22:18 95-50-1122 25
1,3-Dichlorobenzene ND ug/kg 04/02/18 22:18 541-73-1122 25
1,4-Dichlorobenzene ND ug/kg 04/02/18 22:18 106-46-7122 25
Dichlorodifluoromethane ND ug/kg 04/02/18 22:18 75-71-8245 25
1,1-Dichloroethane ND ug/kg 04/02/18 22:18 75-34-3122 25
1,2-Dichloroethane ND ug/kg 04/02/18 22:18 107-06-2122 25
1,1-Dichloroethene ND ug/kg 04/02/18 22:18 75-35-4122 25
cis-1,2-Dichloroethene ND ug/kg 04/02/18 22:18 156-59-2122 25
trans-1,2-Dichloroethene ND ug/kg 04/02/18 22:18 156-60-5122 25
1,2-Dichloropropane ND ug/kg 04/02/18 22:18 78-87-5122 25
1,3-Dichloropropane ND ug/kg 04/02/18 22:18 142-28-9122 25
2,2-Dichloropropane ND ug/kg 04/02/18 22:18 594-20-7122 25
1,1-Dichloropropene ND ug/kg 04/02/18 22:18 563-58-6122 25
cis-1,3-Dichloropropene ND ug/kg 04/02/18 22:18 10061-01-5122 25
trans-1,3-Dichloropropene ND ug/kg 04/02/18 22:18 10061-02-6122 25
Diisopropyl ether ND ug/kg 04/02/18 22:18 108-20-3122 25
Ethylbenzene ND ug/kg 04/02/18 22:18 100-41-4122 25
Hexachloro-1,3-butadiene ND ug/kg 04/02/18 22:18 87-68-3122 25
2-Hexanone ND ug/kg 04/02/18 22:18 591-78-61220 25
Isopropylbenzene (Cumene)ND ug/kg 04/02/18 22:18 98-82-8122 25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92378852
Alamance Oil
Sample: ORD-2 Lab ID: 92378852001 Collected: 03/28/18 16:00 Received: 03/29/18 09:54 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No. QualReport Limit
Analytical Method: EPA 82608260/5035A Volatile Organics
p-Isopropyltoluene ND ug/kg 04/02/18 22:18 99-87-6122 25
Methylene Chloride ND ug/kg 04/02/18 22:18 75-09-2490 25
4-Methyl-2-pentanone (MIBK)ND ug/kg 04/02/18 22:18 108-10-11220 25
Methyl-tert-butyl ether ND ug/kg 04/02/18 22:18 1634-04-4122 25
Naphthalene ND ug/kg 04/02/18 22:18 91-20-3122 25
n-Propylbenzene ND ug/kg 04/02/18 22:18 103-65-1122 25
Styrene ND ug/kg 04/02/18 22:18 100-42-5122 25
1,1,1,2-Tetrachloroethane ND ug/kg 04/02/18 22:18 630-20-6122 25
1,1,2,2-Tetrachloroethane ND ug/kg 04/02/18 22:18 79-34-5122 25
Tetrachloroethene ND ug/kg 04/02/18 22:18 127-18-4122 25
Toluene ND ug/kg 04/02/18 22:18 108-88-3122 25
1,2,3-Trichlorobenzene ND ug/kg 04/02/18 22:18 87-61-6122 25
1,2,4-Trichlorobenzene ND ug/kg 04/02/18 22:18 120-82-1122 25
1,1,1-Trichloroethane ND ug/kg 04/02/18 22:18 71-55-6122 25
1,1,2-Trichloroethane ND ug/kg 04/02/18 22:18 79-00-5122 25
Trichloroethene ND ug/kg 04/02/18 22:18 79-01-6122 25
Trichlorofluoromethane ND ug/kg 04/02/18 22:18 75-69-4122 25
1,2,3-Trichloropropane ND ug/kg 04/02/18 22:18 96-18-4122 25
1,2,4-Trimethylbenzene ND ug/kg 04/02/18 22:18 95-63-6122 25
1,3,5-Trimethylbenzene ND ug/kg 04/02/18 22:18 108-67-8122 25
Vinyl acetate ND ug/kg 04/02/18 22:18 108-05-41220 25
Vinyl chloride ND ug/kg 04/02/18 22:18 75-01-4245 25
Xylene (Total)ND ug/kg 04/02/18 22:18 1330-20-7245 25
m&p-Xylene ND ug/kg 04/02/18 22:18 179601-23-1245 25
o-Xylene ND ug/kg 04/02/18 22:18 95-47-6122 25
Surrogates
Toluene-d8 (S)102 %04/02/18 22:18 2037-26-5 D370-130 25
4-Bromofluorobenzene (S)105 %04/02/18 22:18 460-00-470-130 25
1,2-Dichloroethane-d4 (S)105 %04/02/18 22:18 17060-07-070-132 25
Analytical Method: ASTM D2974-87Percent Moisture
Percent Moisture 21.3 %03/30/18 12:040.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
404268
MADEP VPH
MADEP VPH
VPH NC Soil
Associated Lab Samples: 92378852001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2242830
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 2.5 N203/30/18 16:26
Aliphatic (C09-C12)mg/kg ND 2.5 N203/30/18 16:26
Aromatic (C09-C10)mg/kg ND 2.5 N203/30/18 16:26
4-Bromofluorobenzene (FID) (S)%102 70-130 03/30/18 16:26
4-Bromofluorobenzene (PID) (S)%97 70-130 03/30/18 16:26
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2242831LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2242832
Aliphatic (C05-C08)mg/kg 14.9 N215.1 99 70-1309714.7 2 25
Aliphatic (C09-C12)mg/kg 14.6 N215.1 97 30-1309514.3 2 25
Aromatic (C09-C10)mg/kg 4.8 N259570-130934.7 2 25
4-Bromofluorobenzene (FID) (S)%109 70-130104
4-Bromofluorobenzene (PID) (S)%106 70-130101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
404494
EPA 8260
EPA 8260
8260 MSV 5035A Volatile Organics
Associated Lab Samples: 92378852001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2244039
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
1,1,1,2-Tetrachloroethane ug/kg ND 5.9 04/02/18 15:03
1,1,1-Trichloroethane ug/kg ND 5.9 04/02/18 15:03
1,1,2,2-Tetrachloroethane ug/kg ND 5.9 04/02/18 15:03
1,1,2-Trichloroethane ug/kg ND 5.9 04/02/18 15:03
1,1-Dichloroethane ug/kg ND 5.9 04/02/18 15:03
1,1-Dichloroethene ug/kg ND 5.9 04/02/18 15:03
1,1-Dichloropropene ug/kg ND 5.9 04/02/18 15:03
1,2,3-Trichlorobenzene ug/kg ND 5.9 04/02/18 15:03
1,2,3-Trichloropropane ug/kg ND 5.9 04/02/18 15:03
1,2,4-Trichlorobenzene ug/kg ND 5.9 04/02/18 15:03
1,2,4-Trimethylbenzene ug/kg ND 5.9 04/02/18 15:03
1,2-Dibromo-3-chloropropane ug/kg ND 5.9 04/02/18 15:03
1,2-Dibromoethane (EDB)ug/kg ND 5.9 04/02/18 15:03
1,2-Dichlorobenzene ug/kg ND 5.9 04/02/18 15:03
1,2-Dichloroethane ug/kg ND 5.9 04/02/18 15:03
1,2-Dichloropropane ug/kg ND 5.9 04/02/18 15:03
1,3,5-Trimethylbenzene ug/kg ND 5.9 04/02/18 15:03
1,3-Dichlorobenzene ug/kg ND 5.9 04/02/18 15:03
1,3-Dichloropropane ug/kg ND 5.9 04/02/18 15:03
1,4-Dichlorobenzene ug/kg ND 5.9 04/02/18 15:03
2,2-Dichloropropane ug/kg ND 5.9 04/02/18 15:03
2-Butanone (MEK)ug/kg ND 119 04/02/18 15:03
2-Chlorotoluene ug/kg ND 5.9 04/02/18 15:03
2-Hexanone ug/kg ND 59.4 04/02/18 15:03
4-Chlorotoluene ug/kg ND 5.9 04/02/18 15:03
4-Methyl-2-pentanone (MIBK)ug/kg ND 59.4 04/02/18 15:03
Acetone ug/kg ND 119 04/02/18 15:03
Benzene ug/kg ND 5.9 04/02/18 15:03
Bromobenzene ug/kg ND 5.9 04/02/18 15:03
Bromochloromethane ug/kg ND 5.9 04/02/18 15:03
Bromodichloromethane ug/kg ND 5.9 04/02/18 15:03
Bromoform ug/kg ND 5.9 04/02/18 15:03
Bromomethane ug/kg ND 11.9 04/02/18 15:03
Carbon tetrachloride ug/kg ND 5.9 04/02/18 15:03
Chlorobenzene ug/kg ND 5.9 04/02/18 15:03
Chloroethane ug/kg ND 11.9 04/02/18 15:03
Chloroform ug/kg ND 5.9 04/02/18 15:03
Chloromethane ug/kg ND 11.9 04/02/18 15:03
cis-1,2-Dichloroethene ug/kg ND 5.9 04/02/18 15:03
cis-1,3-Dichloropropene ug/kg ND 5.9 04/02/18 15:03
Dibromochloromethane ug/kg ND 5.9 04/02/18 15:03
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
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[phone]
Page 9 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2244039
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
Dibromomethane ug/kg ND 5.9 04/02/18 15:03
Dichlorodifluoromethane ug/kg ND 11.9 04/02/18 15:03
Diisopropyl ether ug/kg ND 5.9 04/02/18 15:03
Ethylbenzene ug/kg ND 5.9 04/02/18 15:03
Hexachloro-1,3-butadiene ug/kg ND 5.9 04/02/18 15:03
Isopropylbenzene (Cumene)ug/kg ND 5.9 04/02/18 15:03
m&p-Xylene ug/kg ND 11.9 04/02/18 15:03
Methyl-tert-butyl ether ug/kg ND 5.9 04/02/18 15:03
Methylene Chloride ug/kg ND 23.8 04/02/18 15:03
n-Butylbenzene ug/kg ND 5.9 04/02/18 15:03
n-Propylbenzene ug/kg ND 5.9 04/02/18 15:03
Naphthalene ug/kg ND 5.9 04/02/18 15:03
o-Xylene ug/kg ND 5.9 04/02/18 15:03
p-Isopropyltoluene ug/kg ND 5.9 04/02/18 15:03
sec-Butylbenzene ug/kg ND 5.9 04/02/18 15:03
Styrene ug/kg ND 5.9 04/02/18 15:03
tert-Butylbenzene ug/kg ND 5.9 04/02/18 15:03
Tetrachloroethene ug/kg ND 5.9 04/02/18 15:03
Toluene ug/kg ND 5.9 04/02/18 15:03
trans-1,2-Dichloroethene ug/kg ND 5.9 04/02/18 15:03
trans-1,3-Dichloropropene ug/kg ND 5.9 04/02/18 15:03
Trichloroethene ug/kg ND 5.9 04/02/18 15:03
Trichlorofluoromethane ug/kg ND 5.9 04/02/18 15:03
Vinyl acetate ug/kg ND 59.4 04/02/18 15:03
Vinyl chloride ug/kg ND 11.9 04/02/18 15:03
Xylene (Total)ug/kg ND 11.9 04/02/18 15:03
1,2-Dichloroethane-d4 (S)%107 70-132 04/02/18 15:03
4-Bromofluorobenzene (S)%99 70-130 04/02/18 15:03
Toluene-d8 (S)%100 70-130 04/02/18 15:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2244040LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 58.555.4 106 74-137
1,1,1-Trichloroethane ug/kg 59.655.4 108 67-140
1,1,2,2-Tetrachloroethane ug/kg 50.655.4 91 72-141
1,1,2-Trichloroethane ug/kg 58.855.4 106 78-138
1,1-Dichloroethane ug/kg 57.255.4 103 69-134
1,1-Dichloroethene ug/kg 63.455.4 114 67-138
1,1-Dichloropropene ug/kg 59.955.4 108 69-139
1,2,3-Trichlorobenzene ug/kg 57.555.4 104 70-146
1,2,3-Trichloropropane ug/kg 57.455.4 104 69-144
1,2,4-Trichlorobenzene ug/kg 57.355.4 103 68-148
1,2,4-Trimethylbenzene ug/kg 57.255.4 103 74-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
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Huntersville, NC 28078
[phone]
Page 10 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2244040LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dibromo-3-chloropropane ug/kg 58.755.4 106 65-140
1,2-Dibromoethane (EDB)ug/kg 58.255.4 105 77-135
1,2-Dichlorobenzene ug/kg 57.055.4 103 77-141
1,2-Dichloroethane ug/kg 59.655.4 108 65-137
1,2-Dichloropropane ug/kg 59.355.4 107 72-136
1,3,5-Trimethylbenzene ug/kg 57.655.4 104 76-133
1,3-Dichlorobenzene ug/kg 55.855.4 101 74-138
1,3-Dichloropropane ug/kg 59.555.4 107 71-139
1,4-Dichlorobenzene ug/kg 55.955.4 101 76-138
2,2-Dichloropropane ug/kg 59.455.4 107 68-137
2-Butanone (MEK)ug/kg 140111 126 58-147
2-Chlorotoluene ug/kg 58.155.4 105 73-139
2-Hexanone ug/kg 130111 117 62-145
4-Chlorotoluene ug/kg 57.655.4 104 76-141
4-Methyl-2-pentanone (MIBK)ug/kg 122111 110 64-149
Acetone ug/kg 116111 105 53-153
Benzene ug/kg 59.155.4 107 73-135
Bromobenzene ug/kg 56.255.4 101 75-133
Bromochloromethane ug/kg 58.655.4 106 73-134
Bromodichloromethane ug/kg 60.455.4 109 71-135
Bromoform ug/kg 62.455.4 113 66-141
Bromomethane ug/kg 50.855.4 92 53-160
Carbon tetrachloride ug/kg 60.355.4 109 60-145
Chlorobenzene ug/kg 57.555.4 104 78-130
Chloroethane ug/kg 58.155.4 105 64-149
Chloroform ug/kg 58.355.4 105 70-134
Chloromethane ug/kg 53.155.4 96 52-150
cis-1,2-Dichloroethene ug/kg 61.655.4 111 70-133
cis-1,3-Dichloropropene ug/kg 59.855.4 108 68-134
Dibromochloromethane ug/kg 59.255.4 107 71-138
Dibromomethane ug/kg 58.255.4 105 74-130
Dichlorodifluoromethane ug/kg 48.555.4 87 40-160
Diisopropyl ether ug/kg 59.155.4 107 69-141
Ethylbenzene ug/kg 58.455.4 105 75-133
Hexachloro-1,3-butadiene ug/kg 55.955.4 101 68-143
Isopropylbenzene (Cumene)ug/kg 59.455.4 107 76-143
m&p-Xylene ug/kg 117111 105 75-136
Methyl-tert-butyl ether ug/kg 56.255.4 101 68-144
Methylene Chloride ug/kg 59.355.4 107 45-154
n-Butylbenzene ug/kg 58.455.4 105 72-137
n-Propylbenzene ug/kg 59.055.4 106 76-136
Naphthalene ug/kg 62.355.4 112 68-151
o-Xylene ug/kg 59.355.4 107 76-141
p-Isopropyltoluene ug/kg 57.055.4 103 76-140
sec-Butylbenzene ug/kg 58.555.4 106 79-139
Styrene ug/kg 57.155.4 103 79-137
tert-Butylbenzene ug/kg 53.855.4 97 74-143
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2244040LABORATORY CONTROL SAMPLE:
LCSSpike
Tetrachloroethene ug/kg 46.055.4 83 71-138
Toluene ug/kg 57.655.4 104 74-131
trans-1,2-Dichloroethene ug/kg 61.255.4 110 67-135
trans-1,3-Dichloropropene ug/kg 60.855.4 110 65-146
Trichloroethene ug/kg 63.055.4 114 67-135
Trichlorofluoromethane ug/kg 60.055.4 108 59-144
Vinyl acetate ug/kg 49.3J111 44 40-160
Vinyl chloride ug/kg 63.255.4 114 56-141
Xylene (Total)ug/kg 176166 106 76-137
1,2-Dichloroethane-d4 (S)%102 70-132
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2244404MATRIX SPIKE SAMPLE:
MSSpike
Result
30247736005
1,1,1,2-Tetrachloroethane ug/kg 16.916.7 102 70-130ND
1,1,1-Trichloroethane ug/kg 17.316.7 104 70-130ND
1,1,2,2-Tetrachloroethane ug/kg 22.2 M116.7 134 70-130ND
1,1,2-Trichloroethane ug/kg 20.416.7 122 70-130ND
1,1-Dichloroethane ug/kg 16.716.7 100 70-130ND
1,1-Dichloroethene ug/kg 18.716.7 113 49-180ND
1,1-Dichloropropene ug/kg 17.916.7 107 70-130ND
1,2,3-Trichlorobenzene ug/kg 14.616.7 88 70-130ND
1,2,3-Trichloropropane ug/kg 21.116.7 127 70-130ND
1,2,4-Trichlorobenzene ug/kg 14.016.7 84 70-130ND
1,2,4-Trimethylbenzene ug/kg 16.416.7 98 70-130ND
1,2-Dibromo-3-chloropropane ug/kg 24.1 M116.7 145 70-130ND
1,2-Dibromoethane (EDB)ug/kg 19.716.7 119 70-130ND
1,2-Dichlorobenzene ug/kg 16.416.7 98 70-130ND
1,2-Dichloroethane ug/kg 19.616.7 118 70-130ND
1,2-Dichloropropane ug/kg 17.816.7 107 70-130ND
1,3,5-Trimethylbenzene ug/kg 17.516.7 105 70-130ND
1,3-Dichlorobenzene ug/kg 15.816.7 95 70-130ND
1,3-Dichloropropane ug/kg 19.916.7 120 70-130ND
1,4-Dichlorobenzene ug/kg 15.816.7 95 70-130ND
2,2-Dichloropropane ug/kg 17.016.7 102 70-130ND
2-Butanone (MEK)ug/kg 50.9J M133.3 153 70-130ND
2-Chlorotoluene ug/kg 16.416.7 99 70-130ND
2-Hexanone ug/kg 55.2 M133.3 166 70-130ND
4-Chlorotoluene ug/kg 16.216.7 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/kg 52.1 M133.3 156 70-130ND
Acetone ug/kg 59.7J33.3 126 70-130ND
Benzene ug/kg 22.316.7 103 50-1665.1
Bromobenzene ug/kg 17.116.7 103 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
2244404MATRIX SPIKE SAMPLE:
MSSpike
Result
30247736005
Bromochloromethane ug/kg 19.916.7 119 70-130ND
Bromodichloromethane ug/kg 18.016.7 108 70-130ND
Bromoform ug/kg 20.216.7 121 70-130ND
Bromomethane ug/kg 16.116.7 97 70-130ND
Carbon tetrachloride ug/kg 16.616.7 100 70-130ND
Chlorobenzene ug/kg 16.816.7 101 43-169ND
Chloroethane ug/kg 17.116.7 103 70-130ND
Chloroform ug/kg 17.916.7 108 70-130ND
Chloromethane ug/kg 14.916.7 89 70-130ND
cis-1,2-Dichloroethene ug/kg 17.916.7 107 70-130ND
cis-1,3-Dichloropropene ug/kg 17.716.7 107 70-130ND
Dibromochloromethane ug/kg 18.316.7 110 70-130ND
Dibromomethane ug/kg 19.016.7 114 70-130ND
Dichlorodifluoromethane ug/kg 14.316.7 86 70-130ND
Diisopropyl ether ug/kg 18.616.7 112 70-130ND
Ethylbenzene ug/kg 16.516.7 99 70-130ND
Hexachloro-1,3-butadiene ug/kg 13.016.7 78 70-130ND
Isopropylbenzene (Cumene)ug/kg 16.616.7 100 70-130ND
m&p-Xylene ug/kg 33.533.3 101 70-130ND
Methyl-tert-butyl ether ug/kg 20.016.7 120 70-130ND
Methylene Chloride ug/kg 13.5J16.7 81 70-130ND
n-Butylbenzene ug/kg 15.816.7 95 70-130ND
n-Propylbenzene ug/kg 16.516.7 99 70-130ND
Naphthalene ug/kg 20.316.7 122 70-130ND
o-Xylene ug/kg 18.816.7 113 70-130ND
p-Isopropyltoluene ug/kg 16.716.7 100 70-130ND
sec-Butylbenzene ug/kg 16.516.7 99 70-130ND
Styrene ug/kg 16.516.7 99 70-130ND
tert-Butylbenzene ug/kg 15.116.7 91 70-130ND
Tetrachloroethene ug/kg 16.216.7 76 70-130ND
Toluene ug/kg 16.716.7 101 52-163ND
trans-1,2-Dichloroethene ug/kg 17.916.7 107 70-130ND
trans-1,3-Dichloropropene ug/kg 18.416.7 110 70-130ND
Trichloroethene ug/kg 16.216.7 97 49-167ND
Trichlorofluoromethane ug/kg 17.416.7 104 70-130ND
Vinyl acetate ug/kg 53.6 M133.3 161 70-130ND
Vinyl chloride ug/kg 18.516.7 111 70-130ND
Xylene (Total)ug/kg 52.349.9 105 70-130ND
1,2-Dichloroethane-d4 (S)%114 70-132
4-Bromofluorobenzene (S)%105 70-130
Toluene-d8 (S)%101 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92378984001
2244403SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg NDND
1,1,1-Trichloroethane ug/kg NDND
1,1,2,2-Tetrachloroethane ug/kg NDND
1,1,2-Trichloroethane ug/kg NDND
1,1-Dichloroethane ug/kg NDND
1,1-Dichloroethene ug/kg NDND
1,1-Dichloropropene ug/kg NDND
1,2,3-Trichlorobenzene ug/kg NDND
1,2,3-Trichloropropane ug/kg NDND
1,2,4-Trichlorobenzene ug/kg NDND
1,2,4-Trimethylbenzene ug/kg NDND
1,2-Dibromo-3-chloropropane ug/kg NDND
1,2-Dibromoethane (EDB)ug/kg NDND
1,2-Dichlorobenzene ug/kg NDND
1,2-Dichloroethane ug/kg NDND
1,2-Dichloropropane ug/kg NDND
1,3,5-Trimethylbenzene ug/kg NDND
1,3-Dichlorobenzene ug/kg NDND
1,3-Dichloropropane ug/kg NDND
1,4-Dichlorobenzene ug/kg NDND
2,2-Dichloropropane ug/kg NDND
2-Butanone (MEK)ug/kg NDND
2-Chlorotoluene ug/kg NDND
2-Hexanone ug/kg NDND
4-Chlorotoluene ug/kg NDND
4-Methyl-2-pentanone (MIBK)ug/kg NDND
Acetone ug/kg 11JND
Benzene ug/kg NDND
Bromobenzene ug/kg NDND
Bromochloromethane ug/kg NDND
Bromodichloromethane ug/kg NDND
Bromoform ug/kg NDND
Bromomethane ug/kg NDND
Carbon tetrachloride ug/kg NDND
Chlorobenzene ug/kg NDND
Chloroethane ug/kg NDND
Chloroform ug/kg NDND
Chloromethane ug/kg NDND
cis-1,2-Dichloroethene ug/kg NDND
cis-1,3-Dichloropropene ug/kg NDND
Dibromochloromethane ug/kg NDND
Dibromomethane ug/kg NDND
Dichlorodifluoromethane ug/kg NDND
Diisopropyl ether ug/kg NDND
Ethylbenzene ug/kg NDND
Hexachloro-1,3-butadiene ug/kg NDND
Isopropylbenzene (Cumene)ug/kg NDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result QualifiersRPDResult
92378984001
2244403SAMPLE DUPLICATE:
m&p-Xylene ug/kg NDND
Methyl-tert-butyl ether ug/kg NDND
Methylene Chloride ug/kg NDND
n-Butylbenzene ug/kg NDND
n-Propylbenzene ug/kg NDND
Naphthalene ug/kg NDND
o-Xylene ug/kg NDND
p-Isopropyltoluene ug/kg NDND
sec-Butylbenzene ug/kg NDND
Styrene ug/kg NDND
tert-Butylbenzene ug/kg NDND
Tetrachloroethene ug/kg NDND
Toluene ug/kg NDND
trans-1,2-Dichloroethene ug/kg NDND
trans-1,3-Dichloropropene ug/kg NDND
Trichloroethene ug/kg NDND
Trichlorofluoromethane ug/kg NDND
Vinyl acetate ug/kg NDND
Vinyl chloride ug/kg NDND
Xylene (Total)ug/kg NDND
1,2-Dichloroethane-d4 (S)%99 7104
4-Bromofluorobenzene (S)%100 12100
Toluene-d8 (S)%100 10102
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
404113
EPA 3546
EPA 8270
8270 Solid MSSV Microwave
Associated Lab Samples: 92378852001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2242051
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
1,2,4-Trichlorobenzene ug/kg ND 331 04/04/18 18:53
1,2-Dichlorobenzene ug/kg ND 331 04/04/18 18:53
1,3-Dichlorobenzene ug/kg ND 331 04/04/18 18:53
1,4-Dichlorobenzene ug/kg ND 331 04/04/18 18:53
1-Methylnaphthalene ug/kg ND 331 04/04/18 18:53
2,2'-Oxybis(1-chloropropane)ug/kg ND 331 04/04/18 18:53
2,4,5-Trichlorophenol ug/kg ND 331 04/04/18 18:53
2,4,6-Trichlorophenol ug/kg ND 331 04/04/18 18:53
2,4-Dichlorophenol ug/kg ND 331 04/04/18 18:53
2,4-Dimethylphenol ug/kg ND 331 04/04/18 18:53
2,4-Dinitrophenol ug/kg ND 1660 04/04/18 18:53
2,4-Dinitrotoluene ug/kg ND 331 04/04/18 18:53
2,6-Dinitrotoluene ug/kg ND 331 04/04/18 18:53
2-Chloronaphthalene ug/kg ND 331 04/04/18 18:53
2-Chlorophenol ug/kg ND 331 04/04/18 18:53
2-Methylnaphthalene ug/kg ND 331 04/04/18 18:53
2-Methylphenol(o-Cresol)ug/kg ND 331 04/04/18 18:53
2-Nitroaniline ug/kg ND 1660 04/04/18 18:53
2-Nitrophenol ug/kg ND 331 04/04/18 18:53
3&4-Methylphenol(m&p Cresol)ug/kg ND 331 04/04/18 18:53
3,3'-Dichlorobenzidine ug/kg ND 1660 04/04/18 18:53
3-Nitroaniline ug/kg ND 1660 04/04/18 18:53
4,6-Dinitro-2-methylphenol ug/kg ND 662 04/04/18 18:53
4-Bromophenylphenyl ether ug/kg ND 331 04/04/18 18:53
4-Chloro-3-methylphenol ug/kg ND 662 04/04/18 18:53
4-Chloroaniline ug/kg ND 1660 04/04/18 18:53
4-Chlorophenylphenyl ether ug/kg ND 331 04/04/18 18:53
4-Nitroaniline ug/kg ND 662 04/04/18 18:53
4-Nitrophenol ug/kg ND 1660 04/04/18 18:53
Acenaphthene ug/kg ND 331 04/04/18 18:53
Acenaphthylene ug/kg ND 331 04/04/18 18:53
Aniline ug/kg ND 331 04/04/18 18:53
Anthracene ug/kg ND 331 04/04/18 18:53
Benzo(a)anthracene ug/kg ND 331 04/04/18 18:53
Benzo(a)pyrene ug/kg ND 331 04/04/18 18:53
Benzo(b)fluoranthene ug/kg ND 331 04/04/18 18:53
Benzo(g,h,i)perylene ug/kg ND 331 04/04/18 18:53
Benzo(k)fluoranthene ug/kg ND 331 04/04/18 18:53
Benzoic Acid ug/kg ND 1660 04/04/18 18:53
Benzyl alcohol ug/kg ND 662 04/04/18 18:53
bis(2-Chloroethoxy)methane ug/kg ND 331 04/04/18 18:53
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
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[phone]
Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2242051
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
bis(2-Chloroethyl) ether ug/kg ND 331 04/04/18 18:53
bis(2-Ethylhexyl)phthalate ug/kg ND 331 04/04/18 18:53
Butylbenzylphthalate ug/kg ND 331 04/04/18 18:53
Chrysene ug/kg ND 331 04/04/18 18:53
Di-n-butylphthalate ug/kg ND 331 04/04/18 18:53
Di-n-octylphthalate ug/kg ND 331 04/04/18 18:53
Dibenz(a,h)anthracene ug/kg ND 331 04/04/18 18:53
Dibenzofuran ug/kg ND 331 04/04/18 18:53
Diethylphthalate ug/kg ND 331 04/04/18 18:53
Dimethylphthalate ug/kg ND 331 04/04/18 18:53
Fluoranthene ug/kg ND 331 04/04/18 18:53
Fluorene ug/kg ND 331 04/04/18 18:53
Hexachloro-1,3-butadiene ug/kg ND 331 04/04/18 18:53
Hexachlorobenzene ug/kg ND 331 04/04/18 18:53
Hexachlorocyclopentadiene ug/kg ND 331 04/04/18 18:53
Hexachloroethane ug/kg ND 331 04/04/18 18:53
Indeno(1,2,3-cd)pyrene ug/kg ND 331 04/04/18 18:53
Isophorone ug/kg ND 331 04/04/18 18:53
N-Nitroso-di-n-propylamine ug/kg ND 331 04/04/18 18:53
N-Nitrosodimethylamine ug/kg ND 331 04/04/18 18:53
N-Nitrosodiphenylamine ug/kg ND 331 04/04/18 18:53
Naphthalene ug/kg ND 331 04/04/18 18:53
Nitrobenzene ug/kg ND 331 04/04/18 18:53
Pentachlorophenol ug/kg ND 1660 04/04/18 18:53
Phenanthrene ug/kg ND 331 04/04/18 18:53
Phenol ug/kg ND 331 04/04/18 18:53
Pyrene ug/kg ND 331 04/04/18 18:53
2,4,6-Tribromophenol (S)%87 27-110 04/04/18 18:53
2-Fluorobiphenyl (S)%69 30-110 04/04/18 18:53
2-Fluorophenol (S)%68 13-110 04/04/18 18:53
Nitrobenzene-d5 (S)%68 23-110 04/04/18 18:53
Phenol-d6 (S)%73 22-110 04/04/18 18:53
Terphenyl-d14 (S)%82 28-110 04/04/18 18:53
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2242052LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 11901680 71 36-120
1,2-Dichlorobenzene ug/kg 11401680 68 41-120
1,3-Dichlorobenzene ug/kg 11301680 67 66-120
1,4-Dichlorobenzene ug/kg 11101680 66 42-120
1-Methylnaphthalene ug/kg 13401680 80 40-120
2,2'-Oxybis(1-chloropropane)ug/kg 9981680 59 17-120
2,4,5-Trichlorophenol ug/kg 13601680 81 37-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2242052LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,6-Trichlorophenol ug/kg 13801680 82 40-120
2,4-Dichlorophenol ug/kg 13901680 83 33-120
2,4-Dimethylphenol ug/kg 14201680 84 36-120
2,4-Dinitrophenol ug/kg 55508390 66 22-121
2,4-Dinitrotoluene ug/kg 14201680 85 60-120
2,6-Dinitrotoluene ug/kg 14101680 84 54-120
2-Chloronaphthalene ug/kg 11801680 70 41-120
2-Chlorophenol ug/kg 12601680 75 39-120
2-Methylnaphthalene ug/kg 13201680 79 26-120
2-Methylphenol(o-Cresol)ug/kg 12601680 75 41-120
2-Nitroaniline ug/kg 26203360 78 45-120
2-Nitrophenol ug/kg 13901680 83 35-120
3&4-Methylphenol(m&p Cresol)ug/kg 13201680 79 35-120
3,3'-Dichlorobenzidine ug/kg 28503360 85 16-125
3-Nitroaniline ug/kg 27903360 83 45-120
4,6-Dinitro-2-methylphenol ug/kg 24703360 73 46-120
4-Bromophenylphenyl ether ug/kg 13001680 77 36-120
4-Chloro-3-methylphenol ug/kg 28903360 86 37-120
4-Chloroaniline ug/kg 25503360 76 35-120
4-Chlorophenylphenyl ether ug/kg 13601680 81 30-120
4-Nitroaniline ug/kg 29003360 86 48-120
4-Nitrophenol ug/kg 71908390 86 43-120
Acenaphthene ug/kg 13001680 77 46-120
Acenaphthylene ug/kg 13401680 80 46-120
Aniline ug/kg 11101680 66 33-120
Anthracene ug/kg 13201680 79 63-120
Benzo(a)anthracene ug/kg 13801680 82 61-120
Benzo(a)pyrene ug/kg 13701680 82 59-120
Benzo(b)fluoranthene ug/kg 14201680 84 55-120
Benzo(g,h,i)perylene ug/kg 13001680 78 57-120
Benzo(k)fluoranthene ug/kg 12701680 75 56-120
Benzoic Acid ug/kg 69208390 83 13-120
Benzyl alcohol ug/kg 25603360 76 34-120
bis(2-Chloroethoxy)methane ug/kg 13301680 79 21-120
bis(2-Chloroethyl) ether ug/kg 12101680 72 25-120
bis(2-Ethylhexyl)phthalate ug/kg 13701680 81 56-123
Butylbenzylphthalate ug/kg 13701680 82 57-120
Chrysene ug/kg 13101680 78 64-120
Di-n-butylphthalate ug/kg 13301680 80 58-120
Di-n-octylphthalate ug/kg 15901680 95 47-121
Dibenz(a,h)anthracene ug/kg 14001680 83 56-120
Dibenzofuran ug/kg 13101680 78 43-120
Diethylphthalate ug/kg 13901680 83 55-120
Dimethylphthalate ug/kg 13501680 80 54-120
Fluoranthene ug/kg 14801680 88 61-120
Fluorene ug/kg 13801680 82 51-120
Hexachloro-1,3-butadiene ug/kg 12201680 73 22-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2242052LABORATORY CONTROL SAMPLE:
LCSSpike
Hexachlorobenzene ug/kg 12301680 73 53-120
Hexachlorocyclopentadiene ug/kg 9491680 57 18-150
Hexachloroethane ug/kg 11201680 67 39-120
Indeno(1,2,3-cd)pyrene ug/kg 13801680 82 58-120
Isophorone ug/kg 12901680 77 38-120
N-Nitroso-di-n-propylamine ug/kg 13801680 83 30-120
N-Nitrosodimethylamine ug/kg 12801680 76 32-120
N-Nitrosodiphenylamine ug/kg 12701680 75 50-120
Naphthalene ug/kg 12401680 74 38-120
Nitrobenzene ug/kg 11801680 70 37-120
Pentachlorophenol ug/kg 29003360 87 10-120
Phenanthrene ug/kg 12701680 76 62-120
Phenol ug/kg 12501680 74 37-120
Pyrene ug/kg 12401680 74 63-120
2,4,6-Tribromophenol (S)%85 27-110
2-Fluorobiphenyl (S)%71 30-110
2-Fluorophenol (S)%71 13-110
Nitrobenzene-d5 (S)%70 23-110
Phenol-d6 (S)%76 22-110
Terphenyl-d14 (S)%74 28-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
404798
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Associated Lab Samples: 92378852001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2245553
Associated Lab Samples:92378852001
Matrix: Solid
Analyzed
Aliphatic (C09-C18)mg/kg ND 9.9 N204/05/18 10:14
Aliphatic (C19-C36)mg/kg ND 9.9 N204/05/18 10:14
Aromatic (C11-C22)mg/kg ND 9.9 N204/05/18 10:14
2-Bromonaphthalene (S)%94 40-140 04/05/18 10:14
2-Fluorobiphenyl (S)%94 40-140 04/05/18 10:14
Nonatriacontane (S)%63 40-140 04/05/18 10:14
o-Terphenyl (S)%81 40-140 04/05/18 10:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2245554LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2245555
Aliphatic (C09-C18)mg/kg ND N210.1 59 40-14044ND 50
Aliphatic (C19-C36)mg/kg ND N213.4 60 40-14045ND 50
Aromatic (C11-C22)mg/kg 21.0 N228.5 74 40-1406418.2 14 50
2-Bromonaphthalene (S)%84 40-14080
2-Fluorobiphenyl (S)%86 40-14082
Nonatriacontane (S)%65 40-14051
o-Terphenyl (S)%81 40-14074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92378852
Alamance Oil
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
404107
ASTM D2974-87
ASTM D2974-87
Dry Weight/Percent Moisture
Associated Lab Samples: 92378852001
Parameter Units
Dup
Result QualifiersRPDResult
92378740001
2242030SAMPLE DUPLICATE:
Percent Moisture %20.4 020.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92378852
Alamance Oil
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92378852
Alamance Oil
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92378852001 404798 405002ORD-2 MADEP EPH MADEP EPH
92378852001 404268 404403ORD-2 MADEP VPH MADEP VPH
92378852001 404113 404840ORD-2 EPA 3546 EPA 8270
92378852001 404494ORD-2 EPA 8260
92378852001 404107ORD-2 ASTM D2974-87
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/09/2018 11:03 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
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