WS-7744_7744_CA_RMR_20141229

13109 Overlook Pass, Roswell, GA 30075 [phone]
www.envirotrac.com

December 19, 2014

Mr. Gene Mao
Guilford County Health Department
1203 Maple Street
Greensboro, NC 27405

Re: Annual Groundwater Monitoring Report
Former Sunoco Greensboro Bulk Terminal
6900 West Market Street
Greensboro, Guilford County, NC 27409
NCDENR Incident No. 7744
NCDENR Priority Ranking: Intermediate

Dear Mr. Mao:

EnviroTrac Ltd is pleased to present the Annual Groundwater Monitoring Report for 2014 for the
above-referenced terminal. This report summarizes groundwater monitoring activities
conducted during June 2014 and November 2014. If you have any questions or require
additional information, please contact me.

Sincerely,

EnviroTrac Ltd.

John Coyne
Project Manager

cc: Ms. Devon Watts – Sunoco, Inc. (R&M)

Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

TABLE OF CONTENTS

1.0 INTRODUCTION................................................................................................... 1
1.1 Background .......................................................................................... 1
2.0 GROUNDWATER MONITORING ACTIVITIES ..................................................... 2
2.1 Groundwater Elevation Monitoring Activities ........................................ 2
2.2 Groundwater Sampling Activities ......................................................... 2
3.0 CONCLUSION AND RECOMMENDATIONS ....................................................... 3
3.1 Conclusions ......................................................................................... 3
3.2 Recommendations ............................................................................... 4
Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

TABLES

Table 1 Well Construction Summary
Table 2 Well Gauging Summary
Table 3 Summary of Current Groundwater Analytical Data
Table 4 Historical Groundwater Analytical Data

FIGURES

Figure 1 Site Topographic Map
Figure 2 Site Map
Figure 3A Groundwater Elevation Contour Map June 12, 2014
Figure 3B Groundwater Elevation Contour Map November 24, 2014
Figure 4A Chemicals of Concern in Groundwater Map June 12, 2014
Figure 4B Chemicals of Concern in Groundwater Map November 24, 2014

APPENDICES

Appendix A Laboratory Analytical Reports

Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

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1.0 INTRODUCTION

EnviroTrac Ltd. (EnviroTrac), on behalf of Sunoco, Inc. (Sunoco), is pleased to present this report
documenting monitoring activities performed at the Former Sunoco Bulk Terminal facility, located
at 6900 West Market Street in Greensboro, Guilford County, North Carolina. In April 2010 Sunoco
awarded an environmental services contract to EnviroTrac for continuing environmental services at
this site. A USGS Topographic map is presented in Figure 1.

This report presents the results of the semi-annual groundwater sampling activities conducted on
June 12, 2014 and November 24, 2014. The approximate locations of the site groundwater
monitoring wells are indicated in Figure 2.

1.1 Background

According to NCDENR, petroleum hydrocarbons were detected in the subsurface at the
Astroline and Sunoco properties in 1986. At the time of the release, Sunoco owned the bulk
storage terminal facility. Between 1986 and 1990, a groundwater quality investigation was
performed at the site. In 1990, an Environmental Audit Agreement Report was submitted by
ATEC Associates, Inc. (ATEC) to evaluate the site property. A Comprehensive Site
Assessment was submitted by Matrix Environmental Technologies (Matrix) in April 1994.

On May 16, 1994, Matrix submitted a CAP proposing a remediation system to address the
absorbed phase and dissolved phase petroleum hydrocarbon contaminants at the subject site.
On February 15, 1996, IT Corporation of North Carolina, Inc. (IT) submitted a CAP Addendum
proposing the installation of a dual phase vapor extraction system (DPVE), in response to
NCDENR correspondence dated November 13, 1995. The DPVE system was installed from
September to November 1996. The soil vapor extraction system was activated on January 10,
1997. The groundwater recovery and treatment system was activated on July 10, 1997, after
the issuance of an NPDES permit.

The system has remained off since August 1999 and a monitored natural attenuation program
was implemented. An Annual Monitoring Report was submitted by IT on March 28, 2001.
Sunoco has submitted Annual Monitoring Reports to NCDENR for each year since 2002.
Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

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2.0 GROUNDWATER MONITORING ACTIVITIES

Groundwater monitoring activities were conducted on June 12, 2014 and November 24, 2014.
Static groundwater levels were obtained from monitoring wells AW-1, AW-3, AW-4, AW-5, AW-
6, VEW-2, and VEW-4 prior to sample collection using an electronic oil/water interface probe to
gauge water levels and measure the thickness of free product, if encountered, in site monitoring
wells. A summary of well construction data is presented in Table 1.

2.1 Groundwater Elevation Monitoring Activities

Liquid level readings were collected during the June 2014 and November 2014 sampling events
using an electronic oil/water interface probe. The current and selected historical results of the
gauging events are presented in Table 2. Free product was not detected during either sampling
event. Groundwater elevation data obtained from the June 2014 sampling event and November
2014 sampling event was used to create groundwater elevation maps identified in Figure 3A
and Figure 3B, respectively. The inferred shallow groundwater flow direction across the site is
generally to the north.

2.2 Groundwater Sampling Activities

June 2014
Groundwater samples were collected on June 12, 2014, from monitoring wells AW-1, AW-3,
AW-4, AW-5, AW-6, VEW-2, and VEW-4. Prior to sample collection, a minimum of three well
casing volumes were purged from each well using a polyethylene disposable bailer. A
groundwater sample was decanted from the bailer into laboratory supplied containers and
placed on ice in a sample cooler. Groundwater samples from the June 2014 sampling event
were shipped via overnight courier to Accutest Laboratories in Scott, Louisiana for laboratory
analysis by EPA Method 624 including MTBE, IPE, and EDB.

A summary of the laboratory analytical results for the June 2014 sampling event is presented in
Table 3 and historical groundwater results are included in Table 4. A map showing the
chemicals of concern in groundwater from the June 2014 sampling event is included in Figure
4A.

Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

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November 2014
Groundwater samples were collected on November 24, 2014, from monitoring wells AW-1, AW-
3, AW-4, AW-5, AW-6, VEW-2, and VEW-4. Prior to sample collection, a minimum of three well
casing volumes were purged from each well using a polyethylene disposable bailer. A
groundwater sample was decanted from the bailer into laboratory supplied containers and
placed on ice in a sample cooler. Groundwater samples from the November 2014 sampling
event were shipped via overnight courier to Accutest in Scott, Louisiana for laboratory analysis
by EPA Method 624 including MTBE, IPE, and EDB.

A summary of the laboratory analytical results for the November 2014 sampling event is
presented in Table 3 and historical groundwater results are included in Table 4. A map
showing the chemicals of concern in groundwater from the November 2014 sampling event is
included in Figure 4B. Copies of the laboratory analytical reports for the June 12, 2014, and
November 24, 2014 sampling events are included in Appendix A.

In June 2014 benzene and naphthalene were detected above the NCDENR Groundwater
Quality 2L Standard (2L Standard) in monitoring well AW-4. MTBE was detected above the 2L
Standard in monitoring well VEW-2. In November 2014, benzene was detected above the 2L
Standard in monitoring well AW-4, AW-5, and VEW-2. Naphthalene was detected above the 2L
Standard in monitoring wells AW-4 and VEW-2, and MTBE was detected above the 2L
Standard in monitoring well VEW-2.
3.0 CONCLUSION AND RECOMMENDATIONS

3.1 Conclusions

Based on information collected during the June 2014 and November 2014 sampling events, the
following conclusions were made:
• Free product was not detected during the June 2014 and November 2014 sampling events
• Benzene was detected above the 2L Standard in monitoring well AW-4 in June 2014
• MTBE was detected above the 2L Standard in monitoring well VEW-2 in June 2014
• Naphthalene was detected above the 2L Standard in AW-4 in June 2014
• Benzene was detected above the 2L Standard in well AW-4, AW-5, and VEW-2 in November
2014
• MTBE was detected above the 2L Standard in well VEW-2 in November 2014
Annual Groundwater Monitoring Report November 2014
Former Sunoco Bulk Terminal, Market Street, Greensboro, NC

4

• Naphthalene was detected above the 2L Standard in wells AW-4 and VEW-2 in November 2014

3.2 Recommendations

Based on the above results, semi-annual groundwater sampling events will continue in May and
November 2015 and an annual remediation monitoring report including the results from both
events will be submitted to NCDENR by January 31, 2016, as identified in the Corrective Action
Plan.

TABLES

TABLE 1
Well Construction Summary
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
Well
Designation
Approximate Total Depth
(ft)
Screened Interval
(ft)
Inside Diameter
(inches)
AW-1 50 15-50 2
AW-2 40 15-40 2
AW-3 35 10-35 2
AW-4 25 5-25 2
AW-5 25 5-25 2
AW-6 46 Unknown 2
VEW-2 45 40-45 2
VEW-4 80 77.5-80 2
VEW-5 98 88-98 2
TABLE 2
Well Gauging Summary
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
Date
05/24/2005 15.24 683.41
11/30/2005 18.45 680.20
05/16/2006 18.44 680.21
11/17/2006 12.70 685.95
04/04/2007 14.50 684.15
11/30/2007 20.95 677.70
04/15/2008 15.90 682.75
11/12/2008 18.40 680.25
04/30/2009 14.70 683.95
11/03/2009 15.78 682.87
04/12/2010 11.80 686.85
11/30/2010 17.06 681.59
04/26/2011 14.10 684.55
11/28/2011 15.33 683.32
04/17/2012 16.43 682.22
11/14/2012 17.23 681.42
06/13/2013 12.24 686.41
11/07/2013 16.58 682.07
06/12/2014 13.27 685.38
11/24/2014 18.53 680.12
05/24/2005 28.43 673.75
11/30/2005 30.74 671.44
05/16/2006 30.73 671.45
11/17/2006 25.45 676.73
04/04/2007 26.84 675.34
11/30/2007 32.99 669.19
04/15/2008 28.24 673.94
11/12/2008 29.70 672.48
04/30/2009 26.10 676.08
11/03/2009 16.68 685.50
04/12/2010 13.55 688.63
11/30/2010 27.61 674.57
04/26/2011 24.26 677.92
11/28/2011 20.98 681.20
04/17/2012 25.01 677.17
11/14/2012 25.56 676.62
06/13/2013 22.19 679.99
11/07/2013 28.94 673.24
06/12/2014 22.70 679.48
11/24/2014 25.30 676.88
05/24/2005 18.86 679.59
11/30/2005 23.67 674.78
05/16/2006 23.24 675.21
11/17/2006 19.56 678.89
04/04/2007 19.88 678.57
11/30/2007 25.41 25.44 0.03 673.03
04/15/2008 22.20 676.25
08/07/2008 24.80 673.65
11/12/2008 24.87 673.58
04/30/2009 20.80 677.65
11/03/2009 23.66 674.79
04/12/2010 16.45 682.00
11/30/2010 22.38 676.07
04/26/2011 20.13 678.32
11/28/2011 22.55 675.90
04/17/2012 21.22 677.23
11/14/2012 23.80 674.65
06/13/2013 19.79 678.66
11/07/2013 21.91 676.54
06/12/2014 18.00 680.45
11/24/2014 24.12 674.33
AW-1 698.65
AW-3 702.18
AW-4 698.45
Product Thickness
(ft)
Groundwater Elevation
(ft)
Well
Identification
Top of Casing
Elevation (ft)Depth to Product Depth to Water
TABLE 2
Well Gauging Summary
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
Date Product Thickness
(ft)
Groundwater Elevation
(ft)
Well
Identification
Top of Casing
Elevation (ft)Depth to Product Depth to Water
05/24/2005 20.42 681.56
11/30/2005 25.30 676.68
05/16/2006 24.20 677.78
11/17/2006 20.13 681.85
04/04/2007 20.34 681.64
11/30/2007 NM/DRY NM/DRY
04/15/2008 23.80 678.18
11/12/2008 25.48 676.50
04/30/2009 21.63 680.35
11/03/2009 24.77 677.21
04/12/2010 18.08 683.90
11/30/2010 24.23 677.75
04/26/2011 21.46 680.52
11/28/2011 24.42 677.56
04/17/2012 22.75 679.23
11/14/2012 25.54 676.44
06/13/2013 20.58 681.40
11/07/2013 22.96 679.02
06/12/2014 19.07 682.91
11/24/2014 25.49 676.49
05/24/2005 23.10 676.96
11/30/2005 27.46 672.60
05/16/2006 25.38 674.68
11/17/2006 22.80 677.26
04/04/2007 22.11 677.95
11/30/2007 29.35 670.71
04/15/2008 26.15 673.91
11/12/2008 24.52 675.54
04/30/2009 21.62 678.44
11/03/2009 23.25 676.81
04/12/2010 17.12 682.94
11/30/2010 22.34 677.72
04/26/2011 20.26 679.80
11/28/2011 21.23 678.83
04/17/2012 20.74 679.32
11/14/2012 22.69 677.37
06/13/2013 19.75 680.31
11/07/2013 22.37 677.69
06/12/2014 19.09 680.97
11/24/2014 24.05 676.01
05/24/2005 20.75 680.23
11/30/2005 25.79 675.19
05/16/2006 25.15 675.83
11/17/2006 21.28 679.70
04/04/2007 20.73 680.25
11/30/2007 27.58 673.40
04/15/2008 24.03 676.95
11/12/2008 26.68 674.30
04/30/2009 22.50 678.48
11/03/2009 25.60 675.38
04/12/2010 18.75 682.23
11/30/2010 24.28 676.70
04/26/2011 21.84 679.14
11/28/2011 24.56 676.42
04/17/2012 23.00 677.98
11/14/2012 25.69 675.29
06/13/2013 21.31 679.67
11/07/2013 23.44 677.54
06/12/2014 19.57 681.41
11/24/2014 25.67 675.31
AW-5 701.98
AW-6 700.06
VEW-2 700.98
TABLE 2
Well Gauging Summary
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
Date Product Thickness
(ft)
Groundwater Elevation
(ft)
Well
Identification
Top of Casing
Elevation (ft)Depth to Product Depth to Water
05/24/2005 20.38 NS
11/30/2005 24.12 NS
05/16/2006 23.58 NS
11/17/2006 19.95 NS
04/04/2007 20.05 NS
11/30/2007 25.66 NS
04/15/2008 23.00 NS
11/12/2008 25.99 NS
04/03/2009 22.45 NS
11/03/2009 24.81 NS
04/12/2010 18.04 NS
11/30/2010 23.79 NS
04/26/2011 21.33 NS
11/28/2011 23.25 NS
04/17/2012 22.63 NS
11/14/2012 24.74 NS
06/13/2013 21.28 NS
11/07/2013 23.84 NS
06/12/2014 20.11 NS
11/24/2014 25.63 NS
Notes:
1. NS- Well elevation not surveyed.
2. NM - Depth to groundwater measurements were not measured.
3. NM/DRY - Depth to groundwater measurements were not measured due to lack of water.
4. Groundwater elevation calculated using the following formula for wells with free product:
(Top of Casing Elevation-Depth to Water) + (Product Thickness x 0.76)
VEW-4 NS
TABLE 3Summary of Current Groundwater Analytical DataSunoco, Inc. 6900 West Market Street, Greensboro, North Carolina DUNS #0000-0107AW-1 <1 <1 <1 <2 ND <1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-3 <1 <1 <1 <2 ND <1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-41801.3 48 142 371.3 <1 <1340NA NA NA NA NA NA NA NA NA NA NAAW-5 <1 <1 <1 <2 ND <1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-6 <1 <1 <1 <2 ND 1.9 <1 <5 NA NA NA NA NA NA NA NA NA NA NAVEW-2 <1 <1 <1 <2 ND58<1 <5 NA NA NA NA NA NA NA NA NA NA NAVEW-4 <1 <1 <1 <2 ND 15 <1 <5 NA NA NA NA NA NA NA NA NA NA NA1 600 600 500 NE 20 70 6 0.4 400 400 70 70 70 70 70 25 70 35,000 260,000 84,500 85,500 NE 20,000 70,000 6,000 400 28,500 25,000 15,000 8,500 6,900 30,000 25,000 11,700 70,000 3,000Notes:1. "<" or ND = Not Detected at or above the laboratory detection limit.2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.4. NE = Not Established5. NA = Not Analyzed6. GCL = Gross Contamination Level7. 1,2-DCA = 1,2-Dichloroethane8. 1,1-DCA = 1,1-Dichloroethane1,3,5-Trimethyl benzenep-Isopropyl toluenen-Butyl benzeneIsopropyl benzenen-Propyl benzenesec-Butyl benzenetert-Butyl benzeneNorth Carolina 2L North Carolina GCLEthylbenzene Total Xylenes Well IDSampling Date6/12/2014ChloroformChloromethaneBenzene Toluene 1,2-DCAIPE Naphthalene Total BTEXMTBE 1,2,4-Trimethyl benzene
TABLE 3 (cont'd)Summary of Current Groundwater Analytical DataSunoco, Inc. 6900 West Market Street, Greensboro, North Carolina DUNS #0000-0107AW-1 <1 <1 <1 <2 ND <1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-3 <1 <1 <1 <2 ND <1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-4170<20 85 159 414.0 <20 <20600NA NA NA NA NA NA NA NA NA NA NAAW-52.8<1 <1 <2 2.80 8.6 <1 <5 NA NA NA NA NA NA NA NA NA NA NAAW-6 <1 <1 <1 <2 ND 2.1 <1 <5 NA NA NA NA NA NA NA NA NA NA NAVEW-231<1 <1 <2 3148<113NA NA NA NA NA NA NA NA NA NA NAVEW-4 <1 <1 <1 <2 ND 14 <1 <5 NA NA NA NA NA NA NA NA NA NA NA1 600 600 500 NE 20 70 6 0.4 400 400 70 70 70 70 70 25 70 35,000 260,000 84,500 85,500 NE 20,000 70,000 6,000 400 28,500 25,000 15,000 8,500 6,900 30,000 25,000 11,700 70,000 3,000Notes:1. "<" or ND = Not Detected at or above the laboratory detection limit.2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.4. NE = Not Established5. NA = Not Analyzed6. GCL = Gross Contamination Level7. 1,2-DCA = 1,2-Dichloroethane8. 1,1-DCA = 1,1-DichloroethaneWell IDSampling DateBenzene Toluene Ethylbenzene Total Xylenes n-Propyl benzeneIsopropyl benzeneTotal BTEXMTBE IPE Naphthalene 1,2-DCA1,2,4-Trimethyl benzenep-Isopropyl tolueneChloroformChloromethaneNorth Carolina 2L North Carolina GCL11/24/20141,3,5-Trimethyl benzenetert-Butyl benzenesec-Butyl benzenen-Butyl benzene
TABLE 4
Historical Groundwater Analytical Data
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
02/17/94 7.1 2.1 BDL BDL 9.2 BDL BDL
01/28/99 BDL BDL BDL BDL BDL BDL BDL
08/10/99 BDL BDL BDL BDL BDL 1.5 BDL
08/10/99 BDL BDL BDL BDL BDL 1.5 BDL
02/28/00 ND ND ND ND ND 1.1 ND
08/18/00 ND ND ND ND ND 1.2 ND
02/26/01 BDL BDL BDL BDL BDL BDL BDL
10/31/01 2.4 BDL BDL BDL 2.4 BDL BDL
05/14/02 BDL BDL BDL BDL ND BDL BDL
10/10/02 <0.5 <1 <1 <1 ND <5 <5
05/28/03 <0.5 <1 <1 <1 ND <5 <5
11/17/03 <0.5 <1 <1 <1 ND <5 <5
05/25/04 <0.5 <5 <1 <1 ND <5 <5
11/30/04 <0.5 <1 <1 <1 ND <5 <5
05/24/05 <1 <1 <1 <1 ND 3.4 NA
11/30/05 <1 <1 <1 <1 ND 5.4 <1
05/16/06 1.6 <5 <5 <5 1.6 6.9 <5
11/17/06 <5 <5 <5 <5 ND <5 <5
04/04/07 <5 <5 <5 <5 ND <5 <5
11/30/07 <5 <5 <5 <5 ND 5.1 <5
04/15/08 <1 <1 <1 <1 ND <1 <1
11/12/08 <1 <1 <1 <1 ND <5 <1
04/30/09 <0.1 <0.1 <0.1 <0.3 ND 2.3 <0.1
11/03/09 0.19 <0.1 <0.1 <0.2 0.19 1.5 <0.1
04/12/10 <0.1 <0.1 <0.1 <0.2 ND 0.49 <0.1
11/30/10 <0.1 <0.1 <0.1 <0.2 ND 0.38 <0.1
04/26/11 <0.1 <0.1 <0.1 <0.2 ND 0.66 <0.1
11/28/11 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
04/17/12 <0.1 <0.1 <50 <0.2 ND 0.64 <0.2
11/14/12 <0.1 <0.1 <0.1 <0.6 ND 0.45 <0.1
06/13/13 <0.2 <0.1 <0.1 <0.6 ND 0.78 <0.2
11/07/13 <0.1 <0.1 <0.1 <0.3 ND 0.64 <0.1
06/12/14 <1 <1 <1 <2 ND <1 <1
11/24/14 <1 <1 <1 <2 ND <1 <1
02/17/94 14.7 BDL 2.8 3.5 21 253 BDL
08/02/95 4.47 BDL BDL BDL 4.47 114 106
12/06/96 BDL BDL BDL BDL BDL BDL BDL
12/13/96 BDL BDL BDL BDL BDL NA NA
12/19/96 0.9 BDL BDL BDL 0.9 NA NA
04/30/97 BDL BDL BDL BDL BDL NA NA
07/30/97 0.6 BDL BDL BDL 0.6 NA NA
10/10/97 1.6 BDL BDL BDL 1.6 NA NA
02/06/98 BDL BDL BDL BDL BDL BDL BDL
05/07/98 BDL BDL BDL BDL BDL BDL BDL
08/06/98 BDL BDL BDL BDL BDL BDL NA
01/28/99 BDL BDL BDL BDL BDL BDL BDL
08/10/99 BDL BDL BDL BDL BDL 2.4 BDL
02/28/00
05/28/03
11/17/03 NS NS NS NS NS NS NS
05/25/04 NS NS NS NS NS NS NS
11/30/04 NS NS NS NS NS NS NS
05/24/05 NS NS NS NS NS NS NS
11/30/05 NS NS NS NS NS NS NS
05/16/06 NS NS NS NS NS NS NS
11/17/06 NS NS NS NS NS NS NS
04/04/07 NS NS NS NS NS NS NS
11/30/07 NS NS NS NS NS NS NS
04/15/08 NS NS NS NS NS NS NS
11/12/08 NS NS NS NS NS NS NS
04/30/09 NS NS NS NS NS NS NS
11/03/09 NS NS NS NS NS NS NS
04/12/10 NS NS NS NS NS NS NS
11/30/10 NS NS NS NS NS NS NS
04/26/11 NS NS NS NS NS NS NS
11/28/11 NS NS NS NS NS NS NS
04/17/12 NS NS NS NS NS NS NS
11/14/12 NS NS NS NS NS NS NS
06/13/13 NS NS NS NS NS NS NS
11/07/13 NS NS NS NS NS NS NS
06/12/14 NS NS NS NS NS NS NS
11/24/14 NS NS NS NS NS NS NS
1 600 600 500 NE 20 70
5,000 260,000 84,500 85,500 NE 20,000 70,000
Notes:
1. "<", BDL, ND = Not Detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.
4. NE = Not Established
5. GCL = Gross Contamination Level
North Carolina GCL
IPE
WELL NOT LOCATED
WELL NOT LOCATED
North Carolina 2L
Ethyl-
Benzene
Total
Xylenes
AW-1
AW-2
Total BTEX MTBE Well ID Sampling Date Benzene Toluene
TABLE 4
Historical Groundwater Analytical Data
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
IPE Ethyl-
Benzene
Total
Xylenes Total BTEX MTBE Well ID Sampling Date Benzene Toluene
02/17/94 11.5 4.6 BDL 3.6 19.7 30.4 BDL
07/28/95 16.7 BDL 1.55 4.47 22.72 7.37 BDL
12/06/96 16 BDL 5.9 5.6 27.5 BDL BDL
12/13/96 16 BDL 6.5 7.7 30.2 NA NA
12/19/96 15 BDL 5.2 3.0 23.2 NA NA
04/30/97 12 BDL 6.8 2.1 20.9 NA NA
07/30/97 13 BDL 5.4 3.9 22.3 NA NA
10/10/97 9.4 BDL 6.1 15 30.5 NA NA
02/06/98 6 BDL 5 3 14 4 BDL
05/07/98 5.8 BDL 1.6 1.3 8.7 1.7 BDL
08/06/98 3 BDL BDL 2 5 BDL NA
01/28/99 5.8 BDL BDL BDL 5.8 1.8 BDL
08/10/99 BDL BDL BDL BDL BDL 1.5 BDL
02/28/00 ND ND ND ND ND ND ND
08/18/00 5.6 1 1.6 ND 8.2 1.1 ND
02/26/01 4.7 BDL BDL BDL BDL BDL BDL
10/31/01 NS NS NS NS NS NS NS
05/14/02 8.7 BDL BDL BDL 8.7 BDL BDL
10/10/02 6.3 <1 <1 2 8.3 <5 <5
05/28/03 3.5 1 <1 <1 4.5 6 <5
11/17/03 5.4 <1 <1 <1 5.4 <5 <5
05/25/04 5.4 <5 2 4 10.4 <5 <5
11/30/04 4.3 <1 <1 6 10.3 <5 <5
05/24/05 4.2 <1 1.1 2.8 8.1 1.2 NA
11/30/05 <1 <1 <1 <1 ND <1 <1
05/16/06 4.8 <5 <5 <5 4.8 <5 <5
11/17/06 <5 <5 <5 <5 ND <5 <5
04/04/07 <5 <5 <5 <5 ND <5 <5
11/30/07 <5 <5 <5 <5 ND <5 <5
04/15/08 2 <1 <1 <1 2 <1 <1
11/12/08 1.4 <1 <1 <1 1.4 <5 <1
04/30/09 0.63 0.23 0.12 0.53 1.51 0.3 <0.1
11/03/09 0.14 <0.1 0.2 <0.2 0.34 <0.2 <0.1
04/12/10 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
11/30/10 <0.1 0.11 0.36 0.71 1.18 <0.2 <0.1
04/26/11 <0.1 <0.1 <0.1 0.3 0.3 <0.2 <0.1
11/28/11 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
04/17/12 <0.1 <0.1 <50 0.25 0.25 <0.2 <0.2
11/14/12 <0.1 <0.1 0.23 <0.6 0.23 <0.2 <0.1
06/13/13 <0.2 <0.1 <0.1 <0.6 ND <0.2 <0.2
11/07/13 <0.1 <0.1 0.17 0.17 0.34 <0.2 <0.1
06/12/14 <1 <1 <1 <2 ND <1 <1
11/24/14 <1 <1 <1 <2 ND <1 <1
02/17/94 1,190 BDL BDL 242 1432 BDL BDL
07/28/95 3,640 174 806 3,705 8325 BDL BDL
12/06/96 2,700 BDL 1,000 4,200 7900 BDL BDL
12/13/96 4,300 99 660 2,600 7659 NA NA
12/19/96 3,100 64 490 2,200 5854 NA NA
04/30/97 4,500 86 570 2,500 7656 NA NA
07/31/97 3,200 63 520 1,600 5383 NA NA
10/10/97 3,300 100 650 2,100 6150 NA NA
02/06/98 3,150 99 603 2,980 6832 BDL BDL
05/07/98 2,210 99 464 2,116 4889 BDL BDL
08/06/98 2,320 84 481 2,410 5295 BDL NA
02/28/00 1.5 ND ND ND 1.5 ND ND
08/18/00 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
02/26/01 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
10/31/01 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
05/14/02 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
10/10/02 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
05/28/03 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
11/17/03 1,000 <20 300 1,040 2,340 <100 <100
05/25/04 1,500 <500 790 3,510 5,800 <500 <500
11/30/04 1,530 <200 1750 9,220 12,500 <1000 <1000
05/24/05 1,300 <50 330 1,270 2,900 <50 NA
11/30/05 1,500 <200 450 1,210 3,160 <200 <200
05/16/06 800 <100 400 2,000 3,200 <100 <100
11/17/06 930 <5 200 1,330 2,460 <5 <5
04/04/07 1,100 6.1 280 2,500 3,886 <5 <5
11/30/07 NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP NS/FP
04/15/08 760 <10 170 660 1,590 <10 <10
11/12/08 560 1.9 240 460 1,261.9 <5 <1
4/30/09 280 <0.5 270 520 1,070 <1 <0.5
11/3/09 480 46 330 680 1,536 <4 <2
4/12/10 400 2.7 130 400 933 1.8 <0.5
11/30/10 940 72 170 490 1,672 <2 <1
4/26/11 270 <1 120 290 680 <2 <1
11/28/11 230 0.94 140 350 721 1.6 0.31
4/17/12 190 <1 91 220 501 1.5 0.28
11/14/12 360 3.1 130 470 963 1.3 <0.5
6/13/13 210 0.45 59 86 355 <0.2 0.22
11/7/13 250 3.6 96 280 629.6 <2 <1
6/12/14 180 1.3 48 142 371.3 <1 <1
11/24/14 170 <20 85 159 414.0 <20 <20
1 600 600 500 NE 20 70
5,000 260,000 84,500 85,500 NE 20,000 70,000
Notes:
1. "<", BDL, ND = Not Detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.
4. NE = Not Established
5. NS/FP = Not Sampled/Free Product
6. GCL = Gross Contamination Level
AW-3
AW-4
North Carolina GCL
North Carolina 2L
TABLE 4
Historical Groundwater Analytical Data
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
IPE Ethyl-
Benzene
Total
Xylenes Total BTEX MTBE Well ID Sampling Date Benzene Toluene
12/06/96 130 1.6 27 54 212.6 230 21
12/13/96 100 BDL 21 61 182 NA NA
12/19/96 93 BDL 19 65 177 NA NA
04/30/97 30 BDL 5.8 12 47.8 NA NA
07/30/97 58 BDL 7.5 7.5 73 NA NA
10/10/97 31 BDL 7 12 50 NA NA
02/06/98 23 BDL 46 28 97 248 20
05/07/98 52 BDL 21 53 126 285 B
08/06/98 34 BDL 10 23 67 352 NA
01/28/99 6.9 BDL BDL 1.7 8.6 143 19.9
08/10/99 37.5 BDL BDL BDL 37.5 494 68
02/28/00 10.0 ND ND ND 10.0 105 ND
08/18/00 ND ND ND ND ND ND ND
02/26/01 BDL BDL BDL BDL BDL 19 BDL
10/31/01 36 BDL BDL BDL 36 330 58
05/14/02 5.1 BDL BDL BDL 5.1 180 BDL
10/10/02 NS NS NS NS NS NS NS
05/28/03 7.7 1 <1 1 9.7 <5 <5
11/17/03 16.9 <1 <1 <1 16.9 7 <5
05/25/04 35 <5 9 14 58 32 <5
11/17/03 46.4 <1 <1 <1 46.4 9 <5
05/24/05 26 <1 7 4 37 17 NA
11/30/05 21 <1 <1 2.3 23.3 34 5.3
05/16/06 21 <5 <5 <5 21 25 <5
11/17/06 43 <5 <5 <5 43 <5 <5
04/04/07 24 <5 <5 <5 24 17 <5
11/30/07 NS/DRY NS/DRY NS/DRY NS/DRY NS/DRY NS/DRY NS/DRY
04/15/08 <1 <1 <1 <1 ND <1 <1
11/12/08 5.3 <1 <1 <1 5.3 <5 <1
04/30/09 <0.1 <0.1 <0.1 <0.3 ND <0.2 <0.1
11/03/09 0.46 <0.1 <0.1 0.14 0.60 <0.2 <0.1
04/12/10 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
11/30/10 3.2 <0.1 0.53 0.46 4.19 3.4 0.55
04/26/11 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
11/28/11 <0.1 <0.1 <0.1 <0.2 ND <0.2 <0.1
04/17/12 <0.1 <0.1 <50 <0.2 ND <0.2 <0.2
11/14/12 1.8 <0.1 <0.1 <0.6 1.80 <0.2 0.21
06/13/13 <0.2 <0.1 <0.1 <0.6 ND <0.2 <0.2
11/07/13 3.8 <0.1 <0.1 0.17 3.97 1.3 0.19
06/12/14 <1 <1 <1 <2 ND <1 <1
11/24/14 2.8 <1 <1 <2 2.80 8.6 <1
02/17/94 BDL BDL BDL BDL BDL BDL BDL
07/28/95 4.17 BDL BDL BDL 4.17 BDL BDL
12/06/96 17 BDL BDL BDL 17 BDL BDL
12/13/96 14 BDL BDL BDL 14 NA NA
12/19/96 35 BDL BDL BDL 35 NA NA
04/30/97 34 BDL BDL BDL 34 NA NA
07/31/97 68 BDL BDL 3.7 71.7 NA NA
10/10/97 88 BDL BDL BDL 88 NA NA
02/06/98 17 BDL BDL BDL 17 BDL BDL
05/07/98 76 1 BDL 11.6 88.6 BDL BDL
08/06/98 56 BDL BDL BDL 56 BDL NA
01/28/99 BDL BDL BDL BDL BDL BDL BDL
08/10/99 1.4 BDL BDL BDL 1.4 BDL 1
02/28/00 13.2 ND ND ND 13.2 ND ND
08/18/00 3.0 ND ND ND 3.0 ND ND
02/26/01 BDL BDL BDL BDL BDL BDL BDL
10/31/01 BDL BDL BDL BDL BDL BDL BDL
05/14/02 BDL BDL BDL BDL BDL BDL BDL
10/10/02 <0.5 <1 <1 <1 ND <5 <5
05/28/03 <0.5 <1 <1 <1 ND <5 <5
11/17/03 <0.5 <1 <1 <1 ND <5 <5
05/25/04 <0.5 <1 <1 <1 ND <5 <5
11/30/04 <0.5 <1 <1 <1 ND <5 <5
05/24/05 <1 <1 <1 <1 ND <1 NA
11/30/05 <1 <1 <1 <1 ND <1 <1
05/16/06 2.4 7.2 <5 5.8 15.4 <5 <5
11/17/06 <5 <5 <5 <5 ND <5 <5
04/04/07 <5 <5 <5 <5 ND <5 <5
11/30/07 <5 <5 <5 <5 ND <5 <5
04/15/08 <1 <1 <1 <1 ND <1 <1
11/12/08 <1 <1 <1 <1 ND <5 <1
4/30/09 <0.1 <0.1 <0.1 <0.3 ND 0.26 0.12
11/3/09 <0.1 <0.1 <0.1 <0.2 ND 0.43 0.14
4/12/10 <0.1 <0.1 <0.1 <0.2 ND 0.32 <0.1
11/30/10 <0.1 <0.1 <0.1 <0.2 ND 0.56 0.11
4/26/11 0.18 <0.1 <0.1 <0.2 0.18 0.65 <0.1
11/28/11 <0.1 <0.1 <0.1 <0.2 ND 0.73 <0.1
4/17/12 <0.1 <0.1 <50 <0.2 ND 0.88 <0.2
11/14/12 0.56 <0.1 <0.1 <0.6 0.56 0.72 <0.1
6/13/13 <0.2 <0.1 <0.1 <0.6 ND 0.87 <0.2
11/7/13 <0.1 <0.1 <0.1 <0.3 ND 1.4 <0.1
6/12/14 <1 <1 <1 <2 ND 1.9 <1
11/24/14 <1 <1 <1 <2 ND 2.1 <1
1 600 600 500 NE 20 70
5,000 260,000 84,500 85,500 NE 20,000 70,000
Notes:
1. "<", BDL, ND = Not Detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.
4. NE = Not Established
5. NS/FP = Not Sampled/Dry
6. GCL = Gross Contamination Level
AW-5
AW-6
North Carolina 2L
North Carolina GCL
TABLE 4
Historical Groundwater Analytical Data
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
IPE Ethyl-
Benzene
Total
Xylenes Total BTEX MTBE Well ID Sampling Date Benzene Toluene
02/17/94 198 5.2 BDL 152 355.2 BDL BDL
07/28/95 811 BDL 498 BDL 1309 BDL BDL
12/06/96 470 3.1 2.5 410 885.6 18 1.9
12/13/96 780 BDL BDL 760 1540 NA NA
12/19/96 810 BDL BDL 830 1640 NA NA
04/30/97 930 5.4 5.3 920 1860.7 NA NA
07/31/97 860 14 BDL 810 1684 NA NA
10/10/97 730 BDL BDL 500 1230 NA NA
02/06/98 941 2 2 539 1484 19 BDL
05/07/98 346 BDL BDL 116 462 14 BDL
08/06/98 670 BDL BDL 515 1185 14 NA
01/28/99 752 1 3.2 372 1128.2 12.6 BDL
08/10/99 300 BDL BDL BDL 300 20 BDL
08/10/99 BDL BDL BDL BDL BDL 1.5 BDL
02/28/00 960 ND ND 410 1370 ND ND
08/18/00 530 ND ND 603 1133 10 ND
02/26/01 730 BDL BDL 440 1170 BDL BDL
10/31/01 600 BDL BDL 200 800 BDL BDL
05/14/02 980 BDL BDL 320 1300 BDL BDL
10/10/02 1,420 <10 <10 542 1962 <50 <50
05/28/03 714 7 <1 89 810 30 <5
11/17/03 915 <1 1 332 1247 30 11
05/25/04 996 <50 <10 258 1,254 <50 <50
11/30/04 874 <5 1 225 1100 <50 <50
05/24/05 650 <1 2.1 1.1 653 30 NA
11/30/05 960 <1 2.2 260 1,222 35 19
05/16/06 990 19 6.1 295 1,310 26 <5
11/17/06 890E <5 <5 310 1,200 32 <5
04/04/07 720 <5 <5 200 920 33 <5
11/30/07 <5 <5 <5 <5 ND 30 <5
04/15/08 540 <1 2.3 141.2 683.5 48 <1
11/12/08 330 <1 <1 45 375 41 <1
4/30/09 290 <0.1 1.4 25 316 36 14
11/3/09 480 0.21 2.1 160.13 642.44 59 38
4/12/10 12 <0.1 <0.1 0.46 12.46 40 25
11/30/10 180 <0.1 1 14 195 62 41
4/26/11 120 <0.1 <0.1 3 123 <0.2 38
11/28/11 NA NA NA NA NA NA NA
4/17/12 5.2 <0.1 <50 0.78 5.98 35 25
11/14/12 470 <0.1 2.4 90.7 563.1 <0.2 42
6/13/13 0.76 <0.1 0.33 <0.6 1.09 52 27
11/7/13 270 <0.1 0.78 15.34 286.12 76 35
6/12/14 <1 <1 <1 <2 ND 58 <1
11/24/14 31 <1 <1 <2 31 48 <1
07/28/95 2.8 BDL 6.46 BDL 9.26 BDL BDL
12/19/96 24 BDL BDL 46 70 NA NA
08/10/99 BDL BDL BDL BDL BDL BDL BDL
08/10/99 BDL BDL BDL BDL BDL 1.5 BDL
08/18/00 1 ND ND ND ND ND ND
02/26/01 5 BDL BDL 3.4 8.4 BDL BDL
10/31/01 9.1 BDL BDL 1.1 10.2 BDL BDL
05/14/02 48 BDL BDL 13 61 BDL BDL
10/10/02 46.6 <1 <1 16 62.6 <5 <5
05/28/03 3.6 <1 <1 <1 3.6 <5 <5
11/17/03 6.4 <1 <1 <1 6.4 <5 <5
05/25/04 1.7 <5 <1 <1 1.7 <5 <5
11/30/04 <0.5 <1 <1 <1 ND <5 <5
05/24/05 <1 <1 <1 <1 ND <1 NA
11/30/05 <1 <1 <1 <1 ND <1 <1
05/16/06 17.0 26 <5 27 70.0 <5 <5
11/17/06 7.2 12 <5 <5 19.2 <5 <5
04/04/07 <5 <5 <5 <5 ND <5 <5
11/30/07 <5 <5 <5 <5 ND <5 <5
04/15/08 2.2 1.8 <1 2.2 6.2 <1 <1
11/12/08 <1 <1 <1 <1 ND <5 <1
4/30/09 0.6 <0.1 <0.1 0.15 0.75 0.59 <0.1
11/3/09 3.3 <0.1 0.18 0.56 4.04 0.86 0.23
4/12/10 0.29 <0.1 <0.1 0.13 0.42 0.58 0.18
11/30/10 0.26 <0.1 <0.1 0.19 0.45 0.63 0.23
4/26/11 0.14 <0.1 <0.1 <0.2 0.14 0.49 0.12
11/28/11 0.11 <0.1 <0.1 <0.2 0.11 0.58 0.21
4/17/12 <0.1 <0.1 <50 0.18 0.18 <0.2 0.44
11/14/12 0.1 <0.1 <0.1 <0.6 0.1 3.1 0.25
6/13/13 <0.2 <0.1 <0.1 <0.6 ND 3.4 0.22
11/7/13 0.26 <0.1 <0.1 <0.3 0.26 5.2 0.3
6/12/14 <1 <1 <1 <2 ND 15 <1
11/24/14 <1 <1 <1 <2 ND 14 <1
1 600 600 500 NE 20 70
5,000 260,000 84,500 85,500 NE 20,000 70,000
Notes:
1. "<", BDL, ND = Not Detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.
4. NE = Not Established
5. GCL = Gross Contamination Level
6. E = Laboratory estimated value
VEW-2
VEW-4
North Carolina 2L
North Carolina GCL
TABLE 4
Historical Groundwater Analytical Data
Sunoco, Inc.
6900 West Market Street, Greensboro, North Carolina
DUNS #0000-0107
IPE Ethyl-
Benzene
Total
Xylenes Total BTEX MTBE Well ID Sampling Date Benzene Toluene
09/02/95 BDL BDL BDL BDL BDL BDL BDL
12/06/96 15 BDL BDL 3.8 18.8 BDL BDL
12/13/96 50 BDL BDL 11 61 NA NA
12/19/96 79 BDL BDL 16 95 NA NA
04/30/97 690 BDL 1.6 130 821.6 NA NA
07/31/97 470 BDL BDL 76 546 NA NA
10/10/97 130 BDL BDL 14 144 NA NA
02/06/98 3 BDL BDL BDL 3 BDL BDL
05/07/98 BDL BDL BDL BDL BDL BDL BDL
01/28/99 2 BDL BDL BDL 2 BDL BDL
08/10/99 BDL BDL BDL BDL BDL BDL BDL
03/27/00 NS NS NS NS NS NS NS
08/18/00 NS NS NS NS NS NS NS
02/26/01 NS NS NS NS NS NS NS
10/31/01 NS NS NS NS NS NS NS
05/14/02 NS NS NS NS NS NS NS
10/10/02 NS NS NS NS NS NS NS
05/28/03 NS NS NS NS NS NS NS
11/17/03 NS NS NS NS NS NS NS
05/25/04 NS NS NS NS NS NS NS
11/30/04 NS NS NS NS NS NS NS
05/24/05 NS NS NS NS NS NS NS
11/30/05 NS NS NS NS NS NS NS
05/16/06 NS NS NS NS NS NS NS
11/17/06 NS NS NS NS NS NS NS
04/04/07 NS NS NS NS NS NS NS
11/30/07 NS NS NS NS NS NS NS
04/15/08 NS NS NS NS NS NS NS
11/12/08 NS NS NS NS NS NS NS
04/30/09 NS NS NS NS NS NS NS
11/03/09 NS NS NS NS NS NS NS
04/12/10 NS NS NS NS NS NS NS
11/30/10 NS NS NS NS NS NS NS
04/26/11 NS NS NS NS NS NS NS
11/28/11 NS NS NS NS NS NS NS
04/17/12 NS NS NS NS NS NS NS
11/14/12 NS NS NS NS NS NS NS
1 600 600 500 NE 20 70
5,000 260,000 84,500 85,500 NE 20,000 70,000
Notes:
1. "<", BDL, ND = Not Detected at or above the laboratory detection limit.
2. Concentrations are reported in micrograms per liter (ug/l) = parts per billion (ppb).
3. Concentrations in bold print equal or exceed the corresponding NCDENR Groundwater Quality 2L Standard.
4. NE = Not Established
5. GCL = Gross Contamination Level
6. NS = Not Sampled
North Carolina GCL
North Carolina 2L
VEW-5

FIGURES

FIGURE 1 Site Topographic Map
Former Sun Company Bulk Terminal
6900 West Market Street
Greensboro, North Carolina 27409

SOURCE: USGS Topographic Quadrangle for Guilford, NC.

APPENDIX A

LABORATORY ANALYTICAL REPORTS

Case Narrative for:
L0044181
Certificate of Analysis Number:
SUNOCO, INC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ENVIROTRAC
13109 OVERLOOK PASS
ROSWELL
GA
30075-
JOHN COYNE
Date Reported:6/24/2014
Project Name:GREENSBORO, NC
PO Number:
Site:SUNOCO DUNS #0000-0107 GREENSB
State:North Carolina
State Cert. No.:487
Report To:
Site Address:6900 WEST MARKET ST
NCGREENSBORO
[phone] [phone]ph:fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and
the MS/MSD to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
Accutest Gulf Coast Laboratory is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateChristina Larriviere
6/24/2014
Project Manager
Test results meet all requirements of NELAC, unless specified in the narrative.
Version 2.2 - Modified May 16, 2012
Ron Benjamin
Accutest Gulf Coast Lafayette Laboratory Manager
Karen Rodrigue-Varnado
Accutest Gulf Coast Lafayette QA Officer
Page 1 of 19
L0044181
Certificate of Analysis Number:
SUNOCO, INC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ENVIROTRAC
13109 OVERLOOK PASS
ROSWELL
GA
30075-
[phone]
JOHN COYNE
Date Reported:6/24/2014
Project Name:GREENSBORO, NC
PO Number:
Site:SUNOCO DUNS #0000-0107 GREENSB
State:North Carolina
State Cert. No.:487
Report To:
Site Address:6900 WEST MARKET ST
NCGREENSBORO
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
L0044181-01 6/13/2014 9:50:00 AMAW-1 06/12/2014 7:30Water
L0044181-02 6/13/2014 9:50:00 AMAW-3 06/12/2014 8:30Water
L0044181-03 6/13/2014 9:50:00 AMAW-4 06/12/2014 10:00Water
L0044181-04 6/13/2014 9:50:00 AMAW-5 06/12/2014 9:00Water
L0044181-05 6/13/2014 9:50:00 AMAW-6 06/12/2014 8:00Water
L0044181-06 6/13/2014 9:50:00 AMVEW-2 06/12/2014 10:30Water
L0044181-07 6/13/2014 9:50:00 AMVEW-4 06/12/2014 9:30Water
DateChristina Larriviere
6/24/2014
6/24/2014 1:39:53 PM
Project Manager
Version 2.2 - Modified May 16, 2012
Ron Benjamin
Accutest Gulf Coast Lafayette Laboratory Manager
Karen Rodrigue-Varnado
Accutest Gulf Coast Lafayette QA Officer
Page 2 of 19
Client Sample ID AW-1
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-01
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 7:30
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/19/14 22:4711ND RPJ 5601947
Benzene 06/19/14 22:4711ND RPJ 5601947
Diisopropyl ether 06/19/14 22:4711ND RPJ 5601947
Ethylbenzene 06/19/14 22:4711ND RPJ 5601947
Methyl tert-butyl ether 06/19/14 22:4711ND RPJ 5601947
Naphthalene 06/19/14 22:4751ND RPJ 5601947
Toluene 06/19/14 22:4711ND RPJ 5601947
m,p-Xylene 06/19/14 22:4721ND RPJ 5601947
o-Xylene 06/19/14 22:4711ND RPJ 5601947
Xylenes,Total 06/19/14 22:4721ND RPJ 5601947
Surr: 1,2-Dichloroethane-d4 06/19/14 22:47% 81-120 195.8 RPJ 5601947
Surr: 4-Bromofluorobenzene 06/19/14 22:47% 86-110 1102 RPJ 5601947
Surr: Toluene-d8 06/19/14 22:47% 89-110 197.1 RPJ 5601947
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:30 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 3 of 19
Client Sample ID AW-3
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-02
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 8:30
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/19/14 23:1711ND RPJ 5601948
Benzene 06/19/14 23:1711ND RPJ 5601948
Diisopropyl ether 06/19/14 23:1711ND RPJ 5601948
Ethylbenzene 06/19/14 23:1711ND RPJ 5601948
Methyl tert-butyl ether 06/19/14 23:1711ND RPJ 5601948
Naphthalene 06/19/14 23:1751ND RPJ 5601948
Toluene 06/19/14 23:1711ND RPJ 5601948
m,p-Xylene 06/19/14 23:1721ND RPJ 5601948
o-Xylene 06/19/14 23:1711ND RPJ 5601948
Xylenes,Total 06/19/14 23:1721ND RPJ 5601948
Surr: 1,2-Dichloroethane-d4 06/19/14 23:17% 81-120 195.2 RPJ 5601948
Surr: 4-Bromofluorobenzene 06/19/14 23:17% 86-110 1102 RPJ 5601948
Surr: Toluene-d8 06/19/14 23:17% 89-110 197.3 RPJ 5601948
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:37 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 4 of 19
Client Sample ID AW-4
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-03
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 10:00
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/22/14 3:4111ND SNV 5605396
Benzene 06/22/14 3:4111180 SNV 5605396
Diisopropyl ether 06/22/14 3:4111ND SNV 5605396
Ethylbenzene 06/22/14 3:411148 SNV 5605396
Methyl tert-butyl ether 06/22/14 3:4111ND SNV 5605396
Naphthalene 06/22/14 3:4151340 SNV 5605396
Toluene 06/22/14 3:41111.3 SNV 5605396
m,p-Xylene 06/22/14 3:412157 SNV 5605396
o-Xylene 06/22/14 3:411185 SNV 5605396
Xylenes,Total 06/22/14 3:4121142 SNV 5605396
Surr: 1,2-Dichloroethane-d4 06/22/14 3:41% 81-120 1105 SNV 5605396
Surr: 4-Bromofluorobenzene 06/22/14 3:41% 86-110 1103 SNV 5605396
Surr: Toluene-d8 06/22/14 3:41% 89-110 1101 SNV 5605396
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:44 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 5 of 19
Client Sample ID AW-5
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-04
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 9:00
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/20/14 0:1611ND RPJ 5601950
Benzene 06/20/14 0:1611ND RPJ 5601950
Diisopropyl ether 06/20/14 0:1611ND RPJ 5601950
Ethylbenzene 06/20/14 0:1611ND RPJ 5601950
Methyl tert-butyl ether 06/20/14 0:1611ND RPJ 5601950
Naphthalene 06/20/14 0:1651ND RPJ 5601950
Toluene 06/20/14 0:1611ND RPJ 5601950
m,p-Xylene 06/20/14 0:1621ND RPJ 5601950
o-Xylene 06/20/14 0:1611ND RPJ 5601950
Xylenes,Total 06/20/14 0:1621ND RPJ 5601950
Surr: 1,2-Dichloroethane-d4 06/20/14 0:16% 81-120 197.8 RPJ 5601950
Surr: 4-Bromofluorobenzene 06/20/14 0:16% 86-110 1103 RPJ 5601950
Surr: Toluene-d8 06/20/14 0:16% 89-110 197.7 RPJ 5601950
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:50 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 6 of 19
Client Sample ID AW-6
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-05
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 8:00
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/20/14 0:4511ND RPJ 5601951
Benzene 06/20/14 0:4511ND RPJ 5601951
Diisopropyl ether 06/20/14 0:4511ND RPJ 5601951
Ethylbenzene 06/20/14 0:4511ND RPJ 5601951
Methyl tert-butyl ether 06/20/14 0:45111.9 RPJ 5601951
Naphthalene 06/20/14 0:4551ND RPJ 5601951
Toluene 06/20/14 0:4511ND RPJ 5601951
m,p-Xylene 06/20/14 0:4521ND RPJ 5601951
o-Xylene 06/20/14 0:4511ND RPJ 5601951
Xylenes,Total 06/20/14 0:4521ND RPJ 5601951
Surr: 1,2-Dichloroethane-d4 06/20/14 0:45% 81-120 196.0 RPJ 5601951
Surr: 4-Bromofluorobenzene 06/20/14 0:45% 86-110 1102 RPJ 5601951
Surr: Toluene-d8 06/20/14 0:45% 89-110 196.4 RPJ 5601951
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:53 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 7 of 19
Client Sample ID VEW-2
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-06
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 10:30
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/20/14 1:1411ND RPJ 5601952
Benzene 06/20/14 1:1411ND RPJ 5601952
Diisopropyl ether 06/20/14 1:1411ND RPJ 5601952
Ethylbenzene 06/20/14 1:1411ND RPJ 5601952
Methyl tert-butyl ether 06/20/14 1:141158 RPJ 5601952
Naphthalene 06/20/14 1:1451ND RPJ 5601952
Toluene 06/20/14 1:1411ND RPJ 5601952
m,p-Xylene 06/20/14 1:1421ND RPJ 5601952
o-Xylene 06/20/14 1:1411ND RPJ 5601952
Xylenes,Total 06/20/14 1:1421ND RPJ 5601952
Surr: 1,2-Dichloroethane-d4 06/20/14 1:14% 81-120 1101 RPJ 5601952
Surr: 4-Bromofluorobenzene 06/20/14 1:14% 86-110 1103 RPJ 5601952
Surr: Toluene-d8 06/20/14 1:14% 89-110 196.2 RPJ 5601952
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:56 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 8 of 19
Client Sample ID VEW-4
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0044181-07
Dil. Factor AnalystQUAL Seq. #
Collected:06/12/2014 9:30
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 06/20/14 1:4411ND RPJ 5601953
Benzene 06/20/14 1:4411ND RPJ 5601953
Diisopropyl ether 06/20/14 1:4411ND RPJ 5601953
Ethylbenzene 06/20/14 1:4411ND RPJ 5601953
Methyl tert-butyl ether 06/20/14 1:441115 RPJ 5601953
Naphthalene 06/20/14 1:4451ND RPJ 5601953
Toluene 06/20/14 1:4411ND RPJ 5601953
m,p-Xylene 06/20/14 1:4421ND RPJ 5601953
o-Xylene 06/20/14 1:4411ND RPJ 5601953
Xylenes,Total 06/20/14 1:4421ND RPJ 5601953
Surr: 1,2-Dichloroethane-d4 06/20/14 1:44% 81-120 199.4 RPJ 5601953
Surr: 4-Bromofluorobenzene 06/20/14 1:44% 86-110 1101 RPJ 5601953
Surr: Toluene-d8 06/20/14 1:44% 89-110 194.7 RPJ 5601953
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
6/24/2014 1:40:58 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 9 of 19
Quality Control Documentation
6/24/2014 1:41:00 PM
Version 2.1 - Modified February 11, 2011
Page 10 of 19
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID: R336502
WorkOrder: L0044181
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date:06/19/2014 15:59 Analyst:RPJ
RunID:GCMS1H_140619A-560193 Units:ug/L
1,2-Dibromoethane 20.0 21.5 108 50 15020.0 19.6 97.9 9.5 20
Benzene 20.0 18.3 91.4 37 15120.0 17.8 88.9 2.8 20
Diisopropyl ether 20.0 17.4 87.1 80 12020.0 16.2 81.1 7.1 20
Ethylbenzene 20.0 19.1 95.5 37 16220.0 18.8 94.0 1.6 20
Methyl tert-butyl ether 20.0 19.3 96.6 50 15020.0 16.8 84.2 13.7 20
Naphthalene 20.0 21.6 108 50 15020.0 21.5 108 0.2 20
Toluene 20.0 18.9 94.7 47 15020.0 18.2 91.2 3.8 20
m,p-Xylene 40.0 38.9 97.3 50 15040.0 38.2 95.6 1.8 20
o-Xylene 20.0 19.6 98.0 50 15020.0 19.2 96.1 2.0 20
Xylenes,Total 60.0 58.5 97.6 50 15060.0 57.4 95.8 1.9 20
Analyte Result Rep Limit
Method Blank
Analysis Date:06/19/2014 16:57 Analyst:RPJ
RunID:GCMS1H_140619A-5601935 Units:ug/L
1,2-Dibromoethane 1.0ND
Benzene 1.0ND
Diisopropyl ether 1.0ND
Ethylbenzene 1.0ND
Methyl tert-butyl ether 1.0ND
Naphthalene 5.0ND
Toluene 1.0ND
m,p-Xylene 2.0ND
o-Xylene 1.0ND
Xylenes,Total 2.0ND
Surr: 1,2-Dichloroethane-d4 81-12091.6
Surr: 4-Bromofluorobenzene 86-110100.6
Surr: Toluene-d8 89-11097.4
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
L0044181-01A AW-1
L0044181-02A AW-3
L0044181-04A AW-5
L0044181-05A AW-6
L0044181-06A VEW-2
L0044181-07A VEW-4
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
6/24/2014 1:41:07 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 11 of 19
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID: R336502
WorkOrder: L0044181
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date:06/19/2014 15:59 Analyst:RPJ
RunID:GCMS1H_140619A-560193 Units:ug/L
Surr: 1,2-Dichloroethane-d4 50.0 46.2 92.4 81 12050.0 41.2 82.3 11.5 20
Surr: 4-Bromofluorobenzene 50.0 51.0 102 86 11050.0 51.3 103 0.6 20
Surr: Toluene-d8 50.0 48.6 97.2 89 11050.0 49.5 99.1 1.9 20
Analyte MS Spike
Added
MSDResult MSD % Recovery RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult Low Limit High LimitMSResultMS % Recovery
Sample Spiked: L0044181-02
MSD Spike
Added
Analysis Date: 06/20/2014 3:12 Analyst:RPJ
RunID:GCMS1H_140619A-560195 Units:ug/L
1,2-Dibromoethane 100 103 103 50 150ND202.58106106100
Benzene 100 89.3 89.3 37 151ND201.5390.7 90.7 100
Diisopropyl ether 100 85.2 85.2 80 120ND201.1486.2 86.2 100
Ethylbenzene 100 93.1 93.1 37 162ND202.6795.7 95.7 100
Methyl tert-butyl ether 100 92.5 92.5 50 150ND203.6396.0 96.0 100
Naphthalene 100 110 110 50 150ND202.54107107100
Toluene 100 89.7 89.7 47 150ND202.1791.7 91.7 100
m,p-Xylene 200 192 96.0 50 150ND201.7519597.7 200
o-Xylene 100 93.4 93.4 50 150ND203.8397.0 97.0 100
Xylenes,Total 300 285 95.1 50 150ND202.4429297.5 300
Surr: 1,2-Dichloroethane-d4 250 240 96.2 81 120ND200.58924296.7 250
Surr: 4-Bromofluorobenzene 250 260 104 86 110ND201.22257103250
Surr: Toluene-d8 250 240 95.9 89 110ND202.2324598.1 250
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
6/24/2014 1:41:08 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 12 of 19
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID: R336678
WorkOrder: L0044181
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date:06/22/2014 2:13 Analyst:SNV
RunID:GCMS1G_140621I-560539 Units:ug/L
1,2-Dibromoethane 20.0 19.4 97.0 50 15020.0 18.7 93.3 3.9 20
Benzene 20.0 20.9 105 37 15120.0 19.7 98.7 5.7 20
Diisopropyl ether 20.0 20.0 100 80 12020.0 19.3 96.4 3.9 20
Ethylbenzene 20.0 20.0 100 37 16220.0 19.0 95.0 5.1 20
Methyl tert-butyl ether 20.0 20.4 102 50 15020.0 20.3 102 0.4 20
Naphthalene 20.0 17.7 88.6 50 15020.0 16.2 81.0 9.0 20
Toluene 20.0 20.0 100 47 15020.0 19.0 94.8 5.4 20
m,p-Xylene 40.0 40.1 100 50 15040.0 38.1 95.3 5.0 20
o-Xylene 20.0 19.7 98.5 50 15020.0 18.6 92.9 5.9 20
Xylenes,Total 60.0 59.8 99.7 50 15060.0 56.7 94.5 5.3 20
Analyte Result Rep Limit
Method Blank
Analysis Date:06/22/2014 3:12 Analyst: SNV
RunID:GCMS1G_140621I-5605395 Units:ug/L
1,2-Dibromoethane 1.0ND
Benzene 1.0ND
Diisopropyl ether 1.0ND
Ethylbenzene 1.0ND
Methyl tert-butyl ether 1.0ND
Naphthalene 5.0ND
Toluene 1.0ND
m,p-Xylene 2.0ND
o-Xylene 1.0ND
Xylenes,Total 2.0ND
Surr: 1,2-Dichloroethane-d4 81-120102.5
Surr: 4-Bromofluorobenzene 86-110102.2
Surr: Toluene-d8 89-11098.3
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
L0044181-03A AW-4
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
6/24/2014 1:41:10 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 13 of 19
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID: R336678
WorkOrder: L0044181
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike Added
LCS Result LCS Percent Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike Added
LCSD Result LCSD Percent Recovery
RPD RPD Limit
Analysis Date:06/22/2014 2:13 Analyst:SNV
RunID:GCMS1G_140621I-560539 Units:ug/L
Surr: 1,2-Dichloroethane-d4 50.0 48.4 96.9 81 12050.0 50.8 102 4.8 20
Surr: 4-Bromofluorobenzene 50.0 50.9 102 86 11050.0 51.1 102 0.4 20
Surr: Toluene-d8 50.0 50.0 100 89 11050.0 50.0 100 0.1 20
Analyte MS Spike
Added
MSDResult MSD % Recovery RPD RPD Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
SampleResult Low Limit High LimitMSResultMS % Recovery
Sample Spiked: L0044388-10
MSD Spike
Added
Analysis Date: 06/22/2014 12:32 Analyst:SNV
RunID:GCMS1G_140621I-560540 Units:ug/L
1,2-Dibromoethane 100 86.6 86.6 50 150ND204.6690.7 90.7 100
Benzene 100 96.4 96.4 37 151ND203.0499.4 99.4 100
Diisopropyl ether 100 92.1 92.1 80 120ND204.1196.0 96.0 100
Ethylbenzene 100 90.4 90.4 37 162ND204.0294.1 94.1 100
Methyl tert-butyl ether 100 97.3 97.3 50 150ND201.2298.5 98.5 100
Naphthalene 100 73.6 73.6 50 150ND2012.883.7 83.7 100
Toluene 100 90.6 90.6 47 150ND203.6293.9 93.9 100
m,p-Xylene 200 184 92.2 50 150ND203.3819195.3 200
o-Xylene 100 89.9 89.9 50 150ND203.4793.0 93.0 100
Xylenes,Total 300 274 91.4 50 150ND203.4128494.6 300
Surr: 1,2-Dichloroethane-d4 250 253 101 81 120ND202.18258103250
Surr: 4-Bromofluorobenzene 250 253 101 86 110ND201.77258103250
Surr: Toluene-d8 250 253 101 89 110ND200.649251100250
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
6/24/2014 1:41:10 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 14 of 19
Chain of Custody
Acronym Report And
Sample Receipt Checklist,
6/24/2014 1:41:11 PM
Version 2.1 - Modified February 11, 2011
Page 15 of 19
Sample Receipt Checklist
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:L0044181
Date and Time Received:6/13/2014 9:50:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:4.0°C
Received By:EMB
Accutest Representative:
Non Conformance
Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
6/24/2014 1:41:12 PM
Version 2.1 - Modified February 11, 2011
Page 16 of 19
Report Acronyms For WorkOrder L0044181
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Usage: Report Header Or Footer
Abbreviation Description
%Percent
% Rcvry Percent Recovery
COC Chain Of Custody
COC ID Chain Of Custody Identifier Or Number
Dil. Factor Dilution Factor
MCL Maximum Contaminant Limit
MDL Method Detection Limit
MS Matrix Spike
MSD Matrix Spike Duplicate
PDS Post Digestion Spike
PDSD Post Digestion Spike Duplicate
Prep Preparation
Qual Data Qualifier
Rep. Limit Reporting Limit
RPD Relative Percent Difference
Smp Sample
Usage: Units
Abbreviation Description
ug/l micrograms per liter
6/24/2014 1:41:13 PM
L0044181 Page 17Version 2.2 - Modified May 16, 2012
Page 17 of 19
Page 18 of 19
Page 19 of 19
Case Narrative for:
L0051046
Certificate of Analysis Number:
SUNOCO, INC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ENVIROTRAC
13109 OVERLOOK PASS
ROSWELL
GA
30075-
JOHN COYNE
Date Reported:12/4/2014
Project Name:GREENSBORO, NC
PO Number:
Site:SUNOCO DUNS #0000-0107 GREENSB
State:North Carolina
State Cert. No.:487
Report To:
Site Address:6900 WEST MARKET ST
NCGREENSBORO
[phone] [phone]ph:fax:
Matrix spike (MS) and matrix spike duplicate (MSD) samples are chosen and tested at random from an analytical batch of "like" matrix to check for possible matrix effect. The MS and MSD will provide site specific matrix data for those samples spiked by the laboratory and may be applicable to
other samples of similar matrix from the site. Since the MS and MSD are chosen at random from an analytical batch, the sample chosen for spike purposes may or may not have been a sample submitted in this sample delivery group.
The validity of the analytical procedures for which data is reported in this analytical report is determined by the Laboratory Control Sample (LCS) and the Method Blank (MB). The Laboratory Control Sample (LCS) and the Method Blank (MB) are processed with the samples and the MS/MSD
to ensure method criteria are achieved throughout the entire analytical process. If insufficient sample is supplied for MS/MSD, a Laboratory Control Sample (LCS) and a Laboratory Control Sample Duplicate (LCSD) are reported with the analytical batch and serve as the batch quality
control (QC).
Results are reported on a Wet Weight Basis unless otherwise noted in the sample unit field as -dry.
The collection of samples using encores, terracores or other field collection devices may result in inconsistent initial sample weights for the parent
sample and MS/MSD samples.
The MS/MSD recovery and precision data are calculated based on detected spike concentrations that are adjusted for initial sample weights. As a result of the variability between initial sample weights, the calculated RPD may have increased bias.
Any other exceptions associated with this report will be footnoted in the analytical result page(s) or the quality control summary page(s).
Please do not hesitate to contact us if you have any questions or comments pertaining to this data report. Please reference the above Certificate of Analysis Number.
This report shall not be reproduced except in full, without the written approval of the laboratory. The reported results are only representative of the samples submitted for testing.
Accutest Gulf Coast Laboratory is pleased to be of service to you. We anticipate working with you in fulfilling all your current and future analytical needs.
DateChristina Larriviere
12/4/2014
Project Manager
Test results meet all requirements of NELAC, unless specified in the narrative.
Version 2.2 - Modified May 16, 2012
Ron Benjamin
Accutest Gulf Coast Lafayette Laboratory Manager
Karen Rodrigue-Varnado
Accutest Gulf Coast Lafayette QA Officer
Page 1 of 17
L0051046
Certificate of Analysis Number:
SUNOCO, INC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
ENVIROTRAC
13109 OVERLOOK PASS
ROSWELL
GA
30075-
[phone]
JOHN COYNE
Date Reported:12/4/2014
Project Name:GREENSBORO, NC
PO Number:
Site:SUNOCO DUNS #0000-0107 GREENSB
State:North Carolina
State Cert. No.:487
Report To:
Site Address:6900 WEST MARKET ST
NCGREENSBORO
[phone]ph:fax:
Fax To:
Client Sample ID Lab Sample ID Date Collected Date Received COC IDMatrix HOLD
L0051046-01 11/25/2014 9:40:00 AMAW-1 11/24/2014 14:20Water
L0051046-02 11/25/2014 9:40:00 AMAW-3 11/24/2014 15:00Water
L0051046-03 11/25/2014 9:40:00 AMAW-4 11/24/2014 16:00Water
L0051046-04 11/25/2014 9:40:00 AMAW-5 11/24/2014 15:40Water
L0051046-05 11/25/2014 9:40:00 AMAW-6 11/24/2014 14:40Water
L0051046-06 11/25/2014 9:40:00 AMVEW-2 11/24/2014 16:30Water
L0051046-07 11/25/2014 9:40:00 AMVEW-4 11/24/2014 15:20Water
DateChristina Larriviere
12/4/2014
12/4/2014 2:29:02 PM
Project Manager
Version 2.2 - Modified May 16, 2012
Ron Benjamin
Accutest Gulf Coast Lafayette Laboratory Manager
Karen Rodrigue-Varnado
Accutest Gulf Coast Lafayette QA Officer
Page 2 of 17
Client Sample ID:AW-1
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-01
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 14:20
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 14:3611ND RPJ 5791555
Benzene 11/26/14 14:3611ND RPJ 5791555
Diisopropyl ether 11/26/14 14:3611ND RPJ 5791555
Ethylbenzene 11/26/14 14:3611ND RPJ 5791555
Methyl tert-butyl ether 11/26/14 14:3611ND RPJ 5791555
Naphthalene 11/26/14 14:3651ND RPJ 5791555
Toluene 11/26/14 14:3611ND RPJ 5791555
m,p-Xylene 11/26/14 14:3621ND RPJ 5791555
o-Xylene 11/26/14 14:3611ND RPJ 5791555
Xylenes,Total 11/26/14 14:3621ND RPJ 5791555
Surr: 1,2-Dichloroethane-d4 11/26/14 14:36% 81-120 1107 RPJ 5791555
Surr: 4-Bromofluorobenzene 11/26/14 14:36% 86-110 197.8 RPJ 5791555
Surr: Toluene-d8 11/26/14 14:36% 89-110 191.7 RPJ 5791555
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:15 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 3 of 17
Client Sample ID:AW-3
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-02
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 15:00
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 15:0411ND RPJ 5791556
Benzene 11/26/14 15:0411ND RPJ 5791556
Diisopropyl ether 11/26/14 15:0411ND RPJ 5791556
Ethylbenzene 11/26/14 15:0411ND RPJ 5791556
Methyl tert-butyl ether 11/26/14 15:0411ND RPJ 5791556
Naphthalene 11/26/14 15:0451ND RPJ 5791556
Toluene 11/26/14 15:0411ND RPJ 5791556
m,p-Xylene 11/26/14 15:0421ND RPJ 5791556
o-Xylene 11/26/14 15:0411ND RPJ 5791556
Xylenes,Total 11/26/14 15:0421ND RPJ 5791556
Surr: 1,2-Dichloroethane-d4 11/26/14 15:04% 81-120 197.4 RPJ 5791556
Surr: 4-Bromofluorobenzene 11/26/14 15:04% 86-110 199.3 RPJ 5791556
Surr: Toluene-d8 11/26/14 15:04% 89-110 192.4 RPJ 5791556
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:20 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 4 of 17
Client Sample ID:AW-4
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-03
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 16:00
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 17:272020ND RPJ 5791561
Benzene 11/26/14 17:272020170 RPJ 5791561
Diisopropyl ether 11/26/14 17:272020ND RPJ 5791561
Ethylbenzene 11/26/14 17:27202085 RPJ 5791561
Methyl tert-butyl ether 11/26/14 17:272020ND RPJ 5791561
Naphthalene 11/26/14 17:2710020600 RPJ 5791561
Toluene 11/26/14 17:272020ND RPJ 5791561
m,p-Xylene 11/26/14 17:27402099 RPJ 5791561
o-Xylene 11/26/14 17:27202060 RPJ 5791561
Xylenes,Total 11/26/14 17:274020159 RPJ 5791561
Surr: 1,2-Dichloroethane-d4 11/26/14 17:27% 81-120 2090.1 RPJ 5791561
Surr: 4-Bromofluorobenzene 11/26/14 17:27% 86-110 2098.5 RPJ 5791561
Surr: Toluene-d8 11/26/14 17:27% 89-110 2091.9 RPJ 5791561
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:25 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 5 of 17
Client Sample ID:AW-5
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-04
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 15:40
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 15:3311ND RPJ 5791557
Benzene 11/26/14 15:33112.8 RPJ 5791557
Diisopropyl ether 11/26/14 15:3311ND RPJ 5791557
Ethylbenzene 11/26/14 15:3311ND RPJ 5791557
Methyl tert-butyl ether 11/26/14 15:33118.6 RPJ 5791557
Naphthalene 11/26/14 15:3351ND RPJ 5791557
Toluene 11/26/14 15:3311ND RPJ 5791557
m,p-Xylene 11/26/14 15:3321ND RPJ 5791557
o-Xylene 11/26/14 15:3311ND RPJ 5791557
Xylenes,Total 11/26/14 15:3321ND RPJ 5791557
Surr: 1,2-Dichloroethane-d4 11/26/14 15:33% 81-120 196.6 RPJ 5791557
Surr: 4-Bromofluorobenzene 11/26/14 15:33% 86-110 194.9 RPJ 5791557
Surr: Toluene-d8 11/26/14 15:33% 89-110 192.7 RPJ 5791557
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:27 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 6 of 17
Client Sample ID:AW-6
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-05
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 14:40
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 16:0111ND RPJ 5791558
Benzene 11/26/14 16:0111ND RPJ 5791558
Diisopropyl ether 11/26/14 16:0111ND RPJ 5791558
Ethylbenzene 11/26/14 16:0111ND RPJ 5791558
Methyl tert-butyl ether 11/26/14 16:01112.1 RPJ 5791558
Naphthalene 11/26/14 16:0151ND RPJ 5791558
Toluene 11/26/14 16:0111ND RPJ 5791558
m,p-Xylene 11/26/14 16:0121ND RPJ 5791558
o-Xylene 11/26/14 16:0111ND RPJ 5791558
Xylenes,Total 11/26/14 16:0121ND RPJ 5791558
Surr: 1,2-Dichloroethane-d4 11/26/14 16:01% 81-120 199.9 RPJ 5791558
Surr: 4-Bromofluorobenzene 11/26/14 16:01% 86-110 197.3 RPJ 5791558
Surr: Toluene-d8 11/26/14 16:01% 89-110 188.6 RPJ*5791558
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:29 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 7 of 17
Client Sample ID:VEW-2
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-06
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 16:30
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 16:3011ND RPJ 5791559
Benzene 11/26/14 16:301131 RPJ 5791559
Diisopropyl ether 11/26/14 16:3011ND RPJ 5791559
Ethylbenzene 11/26/14 16:3011ND RPJ 5791559
Methyl tert-butyl ether 11/26/14 16:301148 RPJ 5791559
Naphthalene 11/26/14 16:305113 RPJ 5791559
Toluene 11/26/14 16:3011ND RPJ 5791559
m,p-Xylene 11/26/14 16:3021ND RPJ 5791559
o-Xylene 11/26/14 16:3011ND RPJ 5791559
Xylenes,Total 11/26/14 16:3021ND RPJ 5791559
Surr: 1,2-Dichloroethane-d4 11/26/14 16:30% 81-120 1103 RPJ 5791559
Surr: 4-Bromofluorobenzene 11/26/14 16:30% 86-110 197.8 RPJ 5791559
Surr: Toluene-d8 11/26/14 16:30% 89-110 193.7 RPJ 5791559
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:30 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 8 of 17
Client Sample ID:VEW-4
Analyses/Method Result Date AnalyzedRep.Limit
Lab Sample ID:L0051046-07
Dil. Factor AnalystQUAL Seq. #
Collected:11/24/2014 15:20
Site:SUNOCO DUNS #0000-0107 GREENSBRO, NC
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
VOLATILE ORGANICS BY METHOD 624 E624 ug/LUnits:MCL
1,2-Dibromoethane 11/26/14 16:5811ND RPJ 5791560
Benzene 11/26/14 16:5811ND RPJ 5791560
Diisopropyl ether 11/26/14 16:5811ND RPJ 5791560
Ethylbenzene 11/26/14 16:5811ND RPJ 5791560
Methyl tert-butyl ether 11/26/14 16:581114 RPJ 5791560
Naphthalene 11/26/14 16:5851ND RPJ 5791560
Toluene 11/26/14 16:5811ND RPJ 5791560
m,p-Xylene 11/26/14 16:5821ND RPJ 5791560
o-Xylene 11/26/14 16:5811ND RPJ 5791560
Xylenes,Total 11/26/14 16:5821ND RPJ 5791560
Surr: 1,2-Dichloroethane-d4 11/26/14 16:58% 81-120 1101 RPJ 5791560
Surr: 4-Bromofluorobenzene 11/26/14 16:58% 86-110 198.9 RPJ 5791560
Surr: Toluene-d8 11/26/14 16:58% 89-110 191.5 RPJ 5791560
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Surrogate Recovery Outside Advisable QC Limits
>MCL - Result Over Maximum Contamination Limit(MCL)
D - Surrogate Recovery Unreportable due to Dilution
12/4/2014 2:29:32 PM
J - Estimated value between MDL and PQL
MI - Matrix Interference
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.2 - Modified January 16, 2012
Page 9 of 17
Quality Control Documentation
12/4/2014 2:29:32 PM
Version 2.1 - Modified February 11, 2011
Page 10 of 17
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID:R346144
WorkOrder:L0051046
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS
Spike Added
LCS
Result
LCS
Percent Recovery
Lower
Limit
Upper
Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD
Spike Added
LCSD
Result
LCSD
Percent Recovery
RPD RPD
Limit
Analysis Date:11/26/2014 12:41 Analyst:RPJ
RunID:GCMS1X_141126D-579155 Units:ug/L
1,2-Dibromoethane 20.0 20.8 104 50 15020.0 20.4 102 2.0 20
Benzene 20.0 18.8 94.0 37 15120.0 17.6 88.1 6.5 20
Diisopropyl ether 20.0 16.2 81.2 80 12020.0 16.1 80.3 1.1 20
Ethylbenzene 20.0 19.1 95.7 37 16220.0 18.6 92.9 3.0 20
Methyl tert-butyl ether 20.0 18.4 91.9 50 15020.0 20.0 100 8.6 20
Naphthalene 20.0 20.2 101 50 15020.0 20.6 103 1.9 20
Toluene 20.0 18.9 94.6 47 15020.0 18.1 90.3 4.6 20
m,p-Xylene 40.0 39.7 99.4 50 15040.0 38.5 96.2 3.2 20
o-Xylene 20.0 19.0 95.1 50 15020.0 18.8 94.2 0.9 20
Xylenes,Total 60.0 58.7 97.9 50 15060.0 57.3 95.6 2.4 20
Analyte Result Rep Limit
Method Blank
Analysis Date:11/26/2014 12:13 Analyst:RPJ
RunID:GCMS1X_141126D-5791572 Units:ug/L
1,2-Dibromoethane 1.0ND
Benzene 1.0ND
Diisopropyl ether 1.0ND
Ethylbenzene 1.0ND
Methyl tert-butyl ether 1.0ND
Naphthalene 5.0ND
Toluene 1.0ND
m,p-Xylene 2.0ND
o-Xylene 1.0ND
Xylenes,Total 2.0ND
Surr: 1,2-Dichloroethane-d4 81-12091.9
Surr: 4-Bromofluorobenzene 86-11096.5
Surr: Toluene-d8 89-11091.0
Samples in Analytical Batch:
Lab Sample ID Client Sample ID
L0051046-01A AW-1
L0051046-02A AW-3
L0051046-03A AW-4
L0051046-04A AW-5
L0051046-05A AW-6
L0051046-06A VEW-2
L0051046-07A VEW-4
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/4/2014 2:29:33 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 11 of 17
Quality Control Report
SUNOCO, INC
GREENSBORO, NC
Lab Batch ID:R346144
WorkOrder:L0051046
Method:E624
Analysis:Volatile Organics by Method 624
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Analyte LCS Spike
Added
LCS Result LCS Percent
Recovery
Lower Limit Upper Limit
Laboratory Control Sample/Laboratory Control Sample Duplicate (LCS/LCSD)
LCSD Spike
Added
LCSD Result LCSD Percent
Recovery
RPD RPD Limit
Analysis Date:11/26/2014 12:41 Analyst:RPJ
RunID:GCMS1X_141126D-579155 Units:ug/L
Surr: 1,2-Dichloroethane-d4 50.0 47.1 94.3 81 12050.0 49.7 99.5 5.4 20
Surr: 4-Bromofluorobenzene 50.0 48.2 96.4 86 11050.0 48.3 96.5 0.1 20
Surr: Toluene-d8 50.0 46.5 93.1 89 11050.0 46.5 92.9 0.2 20
Analyte MS
Spike Added
MSD
Result
MSD %
Recovery
RPD RPD
Limit
Matrix Spike (MS) / Matrix Spike Duplicate (MSD)
Sample
Result
Low
Limit
High
Limit
MS
Result
MS %
Recovery
Sample Spiked: L0051046-07
MSD
Spike Added
Analysis Date:11/26/2014 17:56 Analyst:RPJ
RunID:GCMS1X_141126D-579156 Units:ug/L
1,2-Dibromoethane 100 99.9 99.9 50 150ND205.5894.5 94.5 100
Benzene 100 77.9 77.9 37 151ND204.2981.3 81.3 100
Diisopropyl ether 100 71.8 71.8 * 80 120ND204.3368.8 68.8 * 100
Ethylbenzene 100 85.0 85.0 37 162ND204.0988.5 88.5 100
Methyl tert-butyl ether 100 107 92.9 50 15013.6 2012.793.8 80.2 100
Naphthalene 100 96.7 95.3 50 150ND204.8392.1 90.8 100
Toluene 100 83.5 83.5 47 150ND203.9386.9 86.9 100
m,p-Xylene 200 179 89.4 50 150ND203.4618592.5 200
o-Xylene 100 85.7 85.7 50 150ND207.0092.0 92.0 100
Xylenes,Total 300 265 88.2 50 150ND204.6227792.3 300
Surr: 1,2-Dichloroethane-d4 250 265 106 81 120ND2011.223794.7 250
Surr: 4-Bromofluorobenzene 250 243 97.0 86 110ND201.2823995.8 250
Surr: Toluene-d8 250 238 95.1 89 110ND203.3123092.0 250
Qualifiers:
B - Analyte Detected In The Associated Method Blank
ND/U - Not Detected at the Reporting Limit
* - Recovery Outside Advisable QC Limits
D - Recovery Unreportable due to Dilution
12/4/2014 2:29:33 PM
J - Estimated Value Between MDL And PQL
MI - Matrix Interference
QC results presented on the QC Summary Report have been rounded. RPD and percent recovery values
calculated by the SPL LIMS system are derived from QC data prior to the application of rounding rules.
N/C - Not Calculated - Sample concentration is greater than 4 times the amount of spike added. Control limits do not apply.
TNTC - Too numerous to count
E - Estimated Value exceeds calibration curve
Version 2.1 - Modified February 11, 2011
Page 12 of 17
Chain of Custody
Acronym Report And
Sample Receipt Checklist,
12/4/2014 2:29:33 PM
Version 2.1 - Modified February 11, 2011
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Sample Receipt Checklist
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Workorder:L0051046
Date and Time Received:11/25/2014 9:40:00 AM Carrier name:FedEx-Std 1 Day PM
Shipping container/cooler in good condition?Yes No Not Present
Custody seals intact on shippping container/cooler?Yes No Not Present
Custody seals intact on sample bottles?Yes No Not Present
Chain of custody present?Yes No
Chain of custody signed when relinquished and received?Yes No
Chain of custody agrees with sample labels?Yes No
Samples in proper container/bottle?Yes No
Sample containers intact?Yes No
Sufficient sample volume for indicated test?Yes No
All samples received within holding time?Yes No
Container/Temp Blank temperature in compliance?Yes No
Water - VOA vials have zero headspace?Yes No VOA Vials Not Present
Temperature:4.1°C
Received By:HJC
Accutest Representative:
Non Conformance
Issues:
Client Name Contacted:
Contact Date & Time:
Client Instructions:
Water IceChilled by:
Yes No Not ApplicableWater - Preservation checked upon receipt (except VOA*)?
1.
3.
4.
5.
2.
7.
8.
9.
6.
10.
11.
12.
13.
*VOA Preservation Checked After Sample Analysis
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Report Acronyms For WorkOrder L0051046
ACCUTEST GULF COAST
500 AMBASSADOR CAFFERY PARKWAY
SCOTT, LA 70583
[phone]
Usage: Report Header Or Footer
Abbreviation Description
%Percent
% Rcvry Percent Recovery
COC Chain Of Custody
COC ID Chain Of Custody Identifier Or Number
Dil. Factor Dilution Factor
MCL Maximum Contaminant Limit
MDL Method Detection Limit
MS Matrix Spike
MSD Matrix Spike Duplicate
PDS Post Digestion Spike
PDSD Post Digestion Spike Duplicate
Prep Preparation
Qual Data Qualifier
Rep. Limit Reporting Limit
RPD Relative Percent Difference
Smp Sample
Usage: Units
Abbreviation Description
ug/l micrograms per liter
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