WS-6345_23973_CA_LAB_20221130

#=CL#
November 30, 2022
LIMS USE: FR - ROBERT PAYNE
LIMS OBJECT ID: 92637630
92637630
Project:
Pace Project No.:
RE:
Robert Payne
Cedar Rock Environmental
107 Pioneer Trail
Graham, NC 27253
FREDERICK JONES PROPERTY
Dear Robert Payne:
Enclosed are the analytical results for sample(s) received by the laboratory on November 18, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Stephanie Knott
[e-mail]
Project Manager
704-977-0981
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 1 of 35
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 2 of 35
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Lab ID Sample ID Matrix Date Collected Date Received
92637630001 MW-1 Water 11/17/22 12:30 11/18/22 09:33
92637630002 OL-1 Solid 11/17/22 13:00 11/18/22 09:33
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 3 of 35
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92637630001 MW-1 MADEP EPH 7 PASI-CBAJ
EPA 625.1 62 PASI-CPKS
SM 6200B 16 PASI-CSAS
92637630002 OL-1 EPA 8015C 2 PASI-CHH
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 4 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Sample:MW-1 Lab ID:92637630001 Collected:11/17/22 12:30 Received:11/18/22 09:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 11/23/22 01:48 N211/21/22 11:5097.1 1
Aliphatic (C19-C36)ND ug/L 11/23/22 01:48 N211/21/22 11:5097.1 1
Aromatic (C11-C22)ND ug/L 11/23/22 01:48 N211/21/22 11:5097.1 1
Surrogates
1-Chlorooctadecane (S)49 %11/23/22 01:48 3386-33-211/21/22 11:5040-140 1
o-Terphenyl (S)84 %11/23/22 01:48 84-15-111/21/22 11:5040-140 1
2-Fluorobiphenyl (S)114 %11/23/22 01:48 321-60-811/21/22 11:5040-140 1
2-Bromonaphthalene (S)121 %11/23/22 01:48 580-13-211/21/22 11:5040-140 1
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 11/24/22 04:21 83-32-911/23/22 11:065.0 1
Acenaphthylene ND ug/L 11/24/22 04:21 208-96-811/23/22 11:065.0 1
Anthracene ND ug/L 11/24/22 04:21 120-12-711/23/22 11:065.0 1
Benzo(a)anthracene ND ug/L 11/24/22 04:21 56-55-311/23/22 11:065.0 1
Benzo(a)pyrene ND ug/L 11/24/22 04:21 50-32-811/23/22 11:065.0 1
Benzo(b)fluoranthene ND ug/L 11/24/22 04:21 205-99-211/23/22 11:065.0 1
Benzo(g,h,i)perylene ND ug/L 11/24/22 04:21 191-24-211/23/22 11:065.0 1
Benzo(k)fluoranthene ND ug/L 11/24/22 04:21 207-08-911/23/22 11:065.0 1
4-Bromophenylphenyl ether ND ug/L 11/24/22 04:21 101-55-311/23/22 11:065.0 1
Butylbenzylphthalate ND ug/L 11/24/22 04:21 85-68-711/23/22 11:065.0 1
4-Chloro-3-methylphenol ND ug/L 11/24/22 04:21 59-50-711/23/22 11:065.0 1
bis(2-Chloroethoxy)methane ND ug/L 11/24/22 04:21 111-91-111/23/22 11:0610.0 1
bis(2-Chloroethyl) ether ND ug/L 11/24/22 04:21 111-44-411/23/22 11:065.0 1
2-Chloronaphthalene ND ug/L 11/24/22 04:21 91-58-711/23/22 11:065.0 1
2-Chlorophenol ND ug/L 11/24/22 04:21 95-57-811/23/22 11:065.0 1
4-Chlorophenylphenyl ether ND ug/L 11/24/22 04:21 7005-72-311/23/22 11:065.0 1
Chrysene ND ug/L 11/24/22 04:21 218-01-911/23/22 11:065.0 1
Dibenz(a,h)anthracene ND ug/L 11/24/22 04:21 53-70-311/23/22 11:065.0 1
3,3'-Dichlorobenzidine ND ug/L 11/24/22 04:21 91-94-111/23/22 11:0610.0 1
2,4-Dichlorophenol ND ug/L 11/24/22 04:21 120-83-211/23/22 11:065.0 1
Diethylphthalate ND ug/L 11/24/22 04:21 84-66-2 L111/23/22 11:065.0 1
2,4-Dimethylphenol ND ug/L 11/24/22 04:21 105-67-9 L111/23/22 11:0610.0 1
Dimethylphthalate ND ug/L 11/24/22 04:21 131-11-3 L111/23/22 11:065.0 1
Di-n-butylphthalate ND ug/L 11/24/22 04:21 84-74-2 L111/23/22 11:065.0 1
4,6-Dinitro-2-methylphenol ND ug/L 11/24/22 04:21 534-52-111/23/22 11:0610.0 1
2,4-Dinitrophenol ND ug/L 11/24/22 04:21 51-28-511/23/22 11:0650.0 1
2,4-Dinitrotoluene ND ug/L 11/24/22 04:21 121-14-2 L111/23/22 11:065.0 1
2,6-Dinitrotoluene ND ug/L 11/24/22 04:21 606-20-211/23/22 11:065.0 1
Di-n-octylphthalate ND ug/L 11/24/22 04:21 117-84-011/23/22 11:065.0 1
bis(2-Ethylhexyl)phthalate ND ug/L 11/24/22 04:21 117-81-711/23/22 11:065.0 1
Fluoranthene ND ug/L 11/24/22 04:21 206-44-011/23/22 11:065.0 1
Fluorene ND ug/L 11/24/22 04:21 86-73-711/23/22 11:065.0 1
Hexachloro-1,3-butadiene ND ug/L 11/24/22 04:21 87-68-311/23/22 11:065.0 1
Hexachlorobenzene ND ug/L 11/24/22 04:21 118-74-111/23/22 11:065.0 1
Hexachlorocyclopentadiene ND ug/L 11/24/22 04:21 77-47-411/23/22 11:0610.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 5 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Sample:MW-1 Lab ID:92637630001 Collected:11/17/22 12:30 Received:11/18/22 09:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Hexachloroethane ND ug/L 11/24/22 04:21 67-72-111/23/22 11:065.0 1
Indeno(1,2,3-cd)pyrene ND ug/L 11/24/22 04:21 193-39-511/23/22 11:065.0 1
Isophorone ND ug/L 11/24/22 04:21 78-59-111/23/22 11:0610.0 1
Naphthalene ND ug/L 11/24/22 04:21 91-20-311/23/22 11:065.0 1
Nitrobenzene ND ug/L 11/24/22 04:21 98-95-311/23/22 11:065.0 1
2-Nitrophenol ND ug/L 11/24/22 04:21 88-75-511/23/22 11:065.0 1
4-Nitrophenol ND ug/L 11/24/22 04:21 100-02-711/23/22 11:0610.0 1
N-Nitrosodimethylamine ND ug/L 11/24/22 04:21 62-75-911/23/22 11:065.0 1
N-Nitroso-di-n-propylamine ND ug/L 11/24/22 04:21 621-64-711/23/22 11:065.0 1
N-Nitrosodiphenylamine ND ug/L 11/24/22 04:21 86-30-611/23/22 11:0610.0 1
2,2'-Oxybis(1-chloropropane)ND ug/L 11/24/22 04:21 108-60-111/23/22 11:065.0 1
Pentachlorophenol ND ug/L 11/24/22 04:21 87-86-511/23/22 11:0610.0 1
Phenanthrene ND ug/L 11/24/22 04:21 85-01-811/23/22 11:065.0 1
Phenol ND ug/L 11/24/22 04:21 108-95-211/23/22 11:065.0 1
Pyrene ND ug/L 11/24/22 04:21 129-00-011/23/22 11:065.0 1
1,2,4-Trichlorobenzene ND ug/L 11/24/22 04:21 120-82-111/23/22 11:065.0 1
2,4,6-Trichlorophenol ND ug/L 11/24/22 04:21 88-06-211/23/22 11:0610.0 1
Surrogates
Nitrobenzene-d5 (S)89 %11/24/22 04:21 4165-60-011/23/22 11:0610-120 1
2-Fluorobiphenyl (S)74 %11/24/22 04:21 321-60-811/23/22 11:0615-120 1
Terphenyl-d14 (S)112 %11/24/22 04:21 1718-51-011/23/22 11:0611-131 1
Phenol-d6 (S)43 %11/24/22 04:21 13127-88-311/23/22 11:0610-120 1
2-Fluorophenol (S)37 %11/24/22 04:21 367-12-411/23/22 11:0610-120 1
2,4,6-Tribromophenol (S)68 %11/24/22 04:21 118-79-611/23/22 11:0610-137 1
Tentatively Identified Compounds
Unknown 28.3J ug/L 11/24/22 04:2111/23/22 11:061
Unknown 9.4J ug/L 11/24/22 04:2111/23/22 11:061
Unknown 5.9J ug/L 11/24/22 04:2111/23/22 11:061
Unknown 6.5J ug/L 11/24/22 04:2111/23/22 11:061
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
602 Volatiles by Method 6200
Benzene ND ug/L 11/21/22 14:46 71-43-21.0 1
Chlorobenzene ND ug/L 11/21/22 14:46 108-90-71.0 1
1,2-Dichlorobenzene ND ug/L 11/21/22 14:46 95-50-11.0 1
1,3-Dichlorobenzene ND ug/L 11/21/22 14:46 541-73-11.0 1
1,4-Dichlorobenzene ND ug/L 11/21/22 14:46 106-46-71.0 1
Diisopropyl ether ND ug/L 11/21/22 14:46 108-20-31.0 1
Ethylbenzene ND ug/L 11/21/22 14:46 100-41-41.0 1
Isopropylbenzene (Cumene)ND ug/L 11/21/22 14:46 98-82-81.0 1
Methyl-tert-butyl ether ND ug/L 11/21/22 14:46 1634-04-41.0 1
Naphthalene ND ug/L 11/21/22 14:46 91-20-32.0 1
Toluene ND ug/L 11/21/22 14:46 108-88-31.0 1
m&p-Xylene ND ug/L 11/21/22 14:46 179601-23-12.0 1
o-Xylene ND ug/L 11/21/22 14:46 95-47-61.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 6 of 35
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Sample:MW-1 Lab ID:92637630001 Collected:11/17/22 12:30 Received:11/18/22 09:33 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
602 Volatiles by Method 6200
Surrogates
4-Bromofluorobenzene (S)98 %11/21/22 14:46 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %11/21/22 14:46 17060-07-070-130 1
Toluene-d8 (S)101 %11/21/22 14:46 2037-26-570-130 1
Sample:OL-1 Lab ID:92637630002 Collected:11/17/22 13:00 Received:11/18/22 09:33 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8015 GCS THC-Diesel
Diesel Range Organics(C10-C28)751 mg/kg 11/29/22 11:1511/27/22 19:0616.5 2.5
Surrogates
n-Pentacosane (S)99 %11/29/22 11:15 629-99-211/27/22 19:0610-130 2.5
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 24.6 %11/18/22 17:54 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 7 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
738493
SM 6200B
SM 6200B
602 by 6200B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92637630001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3843052
Associated Lab Samples:92637630001
Matrix:Water
Analyzed
1,2-Dichlorobenzene ug/L ND 1.0 11/21/22 13:16
1,3-Dichlorobenzene ug/L ND 1.0 11/21/22 13:16
1,4-Dichlorobenzene ug/L ND 1.0 11/21/22 13:16
Benzene ug/L ND 1.0 11/21/22 13:16
Chlorobenzene ug/L ND 1.0 11/21/22 13:16
Diisopropyl ether ug/L ND 1.0 11/21/22 13:16
Ethylbenzene ug/L ND 1.0 11/21/22 13:16
Isopropylbenzene (Cumene)ug/L ND 1.0 11/21/22 13:16
m&p-Xylene ug/L ND 2.0 11/21/22 13:16
Methyl-tert-butyl ether ug/L ND 1.0 11/21/22 13:16
Naphthalene ug/L ND 2.0 11/21/22 13:16
o-Xylene ug/L ND 1.0 11/21/22 13:16
Toluene ug/L ND 1.0 11/21/22 13:16
1,2-Dichloroethane-d4 (S)%99 70-130 11/21/22 13:16
4-Bromofluorobenzene (S)%100 70-130 11/21/22 13:16
Toluene-d8 (S)%101 70-130 11/21/22 13:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3843053LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichlorobenzene ug/L 50.250 100 60-140
1,3-Dichlorobenzene ug/L 50.650 101 60-140
1,4-Dichlorobenzene ug/L 48.050 96 60-140
Benzene ug/L 45.350 91 60-140
Chlorobenzene ug/L 48.350 97 60-140
Diisopropyl ether ug/L 47.850 96 60-140
Ethylbenzene ug/L 47.650 95 60-140
Isopropylbenzene (Cumene)ug/L 47.450 95 60-140
m&p-Xylene ug/L 95.2100 95 60-140
Methyl-tert-butyl ether ug/L 50.450 101 60-140
Naphthalene ug/L 50.450 101 60-140
o-Xylene ug/L 48.750 97 60-140
Toluene ug/L 47.450 95 60-140
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%95 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 8 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3843054MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92637630001
3843055
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2-Dichlorobenzene ug/L 20 105 60-140106 2 3020ND20.9 21.3
1,3-Dichlorobenzene ug/L 20 108 60-140110 1 3020ND21.7 22.0
1,4-Dichlorobenzene ug/L 20 102 60-140105 2 3020ND20.4 20.9
Benzene ug/L 20 104 60-140107 3 3020ND20.8 21.5
Chlorobenzene ug/L 20 106 60-140112 5 3020ND21.2 22.3
Diisopropyl ether ug/L 20 95 60-14098 3 3020ND19.1 19.6
Ethylbenzene ug/L 20 106 60-140111 5 3020ND21.3 22.3
Isopropylbenzene
(Cumene)ug/L 20 108 60-140111 3 3020ND21.6 22.2
m&p-Xylene ug/L 40 107 60-140111 4 3040ND42.9 44.5
Methyl-tert-butyl ether ug/L 20 102 60-140108 6 3020ND20.3 21.6
Naphthalene ug/L 20 106 60-140102 4 3020ND21.3 20.5
o-Xylene ug/L 20 109 60-140111 2 3020ND21.7 22.3
Toluene ug/L 20 107 60-140108 1 3020ND21.3 21.5
1,2-Dichloroethane-d4 (S)%96 70-13096
4-Bromofluorobenzene (S)%100 70-130101
Toluene-d8 (S)%99 70-13096
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 9 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
738908
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92637630001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3845480
Associated Lab Samples:92637630001
Matrix:Water
Analyzed
1,2,4-Trichlorobenzene ug/L ND 5.0 11/23/22 10:39
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 11/23/22 10:39
2,4,6-Trichlorophenol ug/L ND 10.0 11/23/22 10:39
2,4-Dichlorophenol ug/L ND 5.0 11/23/22 10:39
2,4-Dimethylphenol ug/L ND 10.0 11/23/22 10:39
2,4-Dinitrophenol ug/L ND 50.0 11/23/22 10:39
2,4-Dinitrotoluene ug/L ND 5.0 11/23/22 10:39
2,6-Dinitrotoluene ug/L ND 5.0 11/23/22 10:39
2-Chloronaphthalene ug/L ND 5.0 11/23/22 10:39
2-Chlorophenol ug/L ND 5.0 11/23/22 10:39
2-Nitrophenol ug/L ND 5.0 11/23/22 10:39
3,3'-Dichlorobenzidine ug/L ND 10.0 11/23/22 10:39
4,6-Dinitro-2-methylphenol ug/L ND 10.0 11/23/22 10:39
4-Bromophenylphenyl ether ug/L ND 5.0 11/23/22 10:39
4-Chloro-3-methylphenol ug/L ND 5.0 11/23/22 10:39
4-Chlorophenylphenyl ether ug/L ND 5.0 11/23/22 10:39
4-Nitrophenol ug/L ND 10.0 11/23/22 10:39
Acenaphthene ug/L ND 5.0 11/23/22 10:39
Acenaphthylene ug/L ND 5.0 11/23/22 10:39
Anthracene ug/L ND 5.0 11/23/22 10:39
Benzo(a)anthracene ug/L ND 5.0 11/23/22 10:39
Benzo(a)pyrene ug/L ND 5.0 11/23/22 10:39
Benzo(b)fluoranthene ug/L ND 5.0 11/23/22 10:39
Benzo(g,h,i)perylene ug/L ND 5.0 11/23/22 10:39
Benzo(k)fluoranthene ug/L ND 5.0 11/23/22 10:39
bis(2-Chloroethoxy)methane ug/L ND 10.0 11/23/22 10:39
bis(2-Chloroethyl) ether ug/L ND 5.0 11/23/22 10:39
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 11/23/22 10:39
Butylbenzylphthalate ug/L ND 5.0 11/23/22 10:39
Chrysene ug/L ND 5.0 11/23/22 10:39
Di-n-butylphthalate ug/L ND 5.0 11/23/22 10:39
Di-n-octylphthalate ug/L ND 5.0 11/23/22 10:39
Dibenz(a,h)anthracene ug/L ND 5.0 11/23/22 10:39
Diethylphthalate ug/L ND 5.0 11/23/22 10:39
Dimethylphthalate ug/L ND 5.0 11/23/22 10:39
Fluoranthene ug/L ND 5.0 11/23/22 10:39
Fluorene ug/L ND 5.0 11/23/22 10:39
Hexachloro-1,3-butadiene ug/L ND 5.0 11/23/22 10:39
Hexachlorobenzene ug/L ND 5.0 11/23/22 10:39
Hexachlorocyclopentadiene ug/L ND 10.0 11/23/22 10:39
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 10 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3845480
Associated Lab Samples:92637630001
Matrix:Water
Analyzed
Hexachloroethane ug/L ND 5.0 11/23/22 10:39
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 11/23/22 10:39
Isophorone ug/L ND 10.0 11/23/22 10:39
N-Nitroso-di-n-propylamine ug/L ND 5.0 11/23/22 10:39
N-Nitrosodimethylamine ug/L ND 5.0 11/23/22 10:39
N-Nitrosodiphenylamine ug/L ND 10.0 11/23/22 10:39
Naphthalene ug/L ND 5.0 11/23/22 10:39
Nitrobenzene ug/L ND 5.0 11/23/22 10:39
Pentachlorophenol ug/L ND 10.0 11/23/22 10:39
Phenanthrene ug/L ND 5.0 11/23/22 10:39
Phenol ug/L ND 5.0 11/23/22 10:39
Pyrene ug/L ND 5.0 11/23/22 10:39
2,4,6-Tribromophenol (S)%92 10-137 11/23/22 10:39
2-Fluorobiphenyl (S)%28 15-120 11/23/22 10:39
2-Fluorophenol (S)%35 10-120 11/23/22 10:39
Nitrobenzene-d5 (S)%43 10-120 11/23/22 10:39
Phenol-d6 (S)%30 10-120 11/23/22 10:39
Terphenyl-d14 (S)%92 11-131 11/23/22 10:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3845481LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 47.050 94 44-142
2,2'-Oxybis(1-chloropropane)ug/L 40.950 82 36-166
2,4,6-Trichlorophenol ug/L 54.350 109 37-144
2,4-Dichlorophenol ug/L 50.150 100 1-191
2,4-Dimethylphenol ug/L 60.0 L15012032-119
2,4-Dinitrophenol ug/L 353250 141 1-181
2,4-Dinitrotoluene ug/L 74.8 L15015039-139
2,6-Dinitrotoluene ug/L 67.250 134 50-158
2-Chloronaphthalene ug/L 49.450 99 60-118
2-Chlorophenol ug/L 41.150 82 23-134
2-Nitrophenol ug/L 53.850 108 29-182
3,3'-Dichlorobenzidine ug/L 122100 122 1-262
4,6-Dinitro-2-methylphenol ug/L 134100 134 1-181
4-Bromophenylphenyl ether ug/L 48.350 97 53-127
4-Chloro-3-methylphenol ug/L 104100 104 22-147
4-Chlorophenylphenyl ether ug/L 56.250 112 25-158
4-Nitrophenol ug/L 164250 65 1-132
Acenaphthene ug/L 51.350 103 47-145
Acenaphthylene ug/L 50.650 101 33-145
Anthracene ug/L 49.150 98 1-166
Benzo(a)anthracene ug/L 55.850 112 33-143
Benzo(a)pyrene ug/L 54.650 109 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 11 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3845481LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 55.050 110 24-159
Benzo(g,h,i)perylene ug/L 57.650 115 1-219
Benzo(k)fluoranthene ug/L 50.650 101 11-162
bis(2-Chloroethoxy)methane ug/L 44.450 89 33-184
bis(2-Chloroethyl) ether ug/L 43.650 87 12-158
bis(2-Ethylhexyl)phthalate ug/L 59.250 118 8-158
Butylbenzylphthalate ug/L 62.950 126 1-152
Chrysene ug/L 54.550 109 17-168
Di-n-butylphthalate ug/L 61.7 L1501231-118
Di-n-octylphthalate ug/L 72.150 144 4-146
Dibenz(a,h)anthracene ug/L 59.450 119 1-227
Diethylphthalate ug/L 63.8 L1501281-114
Dimethylphthalate ug/L 59.7 L1501191-112
Fluoranthene ug/L 64.150 128 26-137
Fluorene ug/L 55.950 112 59-121
Hexachloro-1,3-butadiene ug/L 47.550 95 24-116
Hexachlorobenzene ug/L 52.150 104 1-152
Hexachlorocyclopentadiene ug/L 35.750 71 25-150
Hexachloroethane ug/L 38.250 76 40-113
Indeno(1,2,3-cd)pyrene ug/L 60.250 120 1-171
Isophorone ug/L 51.950 104 21-196
N-Nitroso-di-n-propylamine ug/L 52.750 105 1-230
N-Nitrosodimethylamine ug/L 41.950 84 25-150
N-Nitrosodiphenylamine ug/L 47.750 95 25-150
Naphthalene ug/L 43.350 87 21-133
Nitrobenzene ug/L 48.750 97 35-180
Pentachlorophenol ug/L 109100 109 14-176
Phenanthrene ug/L 52.350 105 54-120
Phenol ug/L 25.050 50 5-112
Pyrene ug/L 47.850 96 52-115
2,4,6-Tribromophenol (S)%109 10-137
2-Fluorobiphenyl (S)%86 15-120
2-Fluorophenol (S)%55 10-120
Nitrobenzene-d5 (S)%88 10-120
Phenol-d6 (S)%48 10-120
Terphenyl-d14 (S)%102 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3845482MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35760339002
3845483
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L M1502444-14230 23 30501.7U 12.0 15.1
2,2'-Oxybis(1-
chloropropane)ug/L M1,R1502836-16649 52 30501.2U 14.2 24.3
2,4,6-Trichlorophenol ug/L 50 78 37-14493 18 30501.6U 38.9 46.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 12 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3845482MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35760339002
3845483
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L 50 73 1-19193 23 30501.4U 36.6 46.3
2,4-Dimethylphenol ug/L 50 96 32-119116 19 30501.7U 48.2 58.2
2,4-Dinitrophenol ug/L 250 8 1-1819 3025026.0U ND ND
2,4-Dinitrotoluene ug/L 50 99 39-139124 22 30501.6U 49.6 62.2
2,6-Dinitrotoluene ug/L 50 96 50-158115 19 30501.7U 47.8 57.7
2-Chloronaphthalene ug/L M1505960-11868 14 30501.7U 29.4 33.9
2-Chlorophenol ug/L R1503723-13463 44 30503.9J 22.6 35.3
2-Nitrophenol ug/L 50 60 29-18280 28 30501.4U 30.1 40.1
3,3'-Dichlorobenzidine ug/L 100 87 1-26297 11 301008.1U 86.9 97.2
4,6-Dinitro-2-methylphenol ug/L R1100321-18146 36 301007.8U 32.1 46.3
4-Bromophenylphenyl ether ug/L 50 73 53-12786 16 30501.8U 36.5 43.0
4-Chloro-3-methylphenol ug/L 100 95 22-147121 25 301003.3U 94.5 121
4-Chlorophenylphenyl ether ug/L 50 76 25-15896 23 30502.0U 38.0 48.0
4-Nitrophenol ug/L 250 26 1-13233 24 302506.6U 65.9 83.5
Acenaphthene ug/L 50 69 47-14581 16 30502.0U 34.6 40.5
Acenaphthylene ug/L 50 70 33-14582 16 30502.0U 34.9 40.8
Anthracene ug/L 50 76 1-16689 16 30502.3U 38.1 44.7
Benzo(a)anthracene ug/L 50 86 33-143103 18 30502.7U 42.9 51.4
Benzo(a)pyrene ug/L 50 85 17-163102 19 30502.8U 42.4 51.2
Benzo(b)fluoranthene ug/L 50 84 24-159102 20 30502.6U 41.9 51.2
Benzo(g,h,i)perylene ug/L 50 89 1-219110 22 30502.8U 44.3 55.2
Benzo(k)fluoranthene ug/L 50 79 11-16297 20 30502.7U 39.7 48.5
bis(2-
Chloroethoxy)methane ug/L 50 56 33-18469 20 30501.8U 28.2 34.5
bis(2-Chloroethyl) ether ug/L R1503912-15867 53 30501.9U 19.5 33.7
bis(2-Ethylhexyl)phthalate ug/L 50 95 8-158114 18 30503.7U 47.6 57.1
Butylbenzylphthalate ug/L 50 100 1-152116 14 30503.1U 50.0 57.8
Chrysene ug/L 50 86 17-168102 16 30502.8U 43.2 50.8
Di-n-butylphthalate ug/L 50 103 1-118116 12 30502.2U 51.3 58.0
Di-n-octylphthalate ug/L 50 114 4-146133 15 30503.9U 57.0 66.3
Dibenz(a,h)anthracene ug/L 50 91 1-227112 21 30503.0U 45.7 56.2
Diethylphthalate ug/L 50 94 1-114113 19 30502.0U 46.8 56.5
Dimethylphthalate ug/L 50 87 1-112107 21 30502.1U 43.5 53.7
Fluoranthene ug/L 50 101 26-137114 13 30502.2U 50.5 57.2
Fluorene ug/L 50 80 59-12197 20 30502.1U 39.9 48.6
Hexachloro-1,3-butadiene ug/L M1,R1501624-11621 31 30501.8U 7.9 10.7
Hexachlorobenzene ug/L 50 78 1-15292 16 30502.2U 39.1 46.0
Hexachlorocyclopentadiene ug/L M1502125-15024 12 30501.6U 10.5 11.9
Hexachloroethane ug/L M150540-1139 30501.4U 2.7J 4.4J
Indeno(1,2,3-cd)pyrene ug/L 50 93 1-171116 22 30502.9U 46.3 57.9
Isophorone ug/L 50 76 21-19694 21 30501.7U 38.1 46.8
N-Nitroso-di-n-propylamine ug/L 50 73 1-23093 24 30501.3U 36.5 46.3
N-Nitrosodimethylamine ug/L R1504225-15063 41 30501.9U 20.8 31.7
N-Nitrosodiphenylamine ug/L 50 71 25-15084 17 30503.0U 35.7 42.2
Naphthalene ug/L 50 29 21-13336 21 30502.1U 14.6 18.0
Nitrobenzene ug/L R1504335-18065 40 30501.9U 21.5 32.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 13 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3845482MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35760339002
3845483
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L 100 71 14-17692 25 301003.8U 71.4 92.0
Phenanthrene ug/L 50 80 54-12094 16 30502.0U 40.1 46.8
Phenol ug/L M150225-112116 29 3050127138185
Pyrene ug/L 50 72 52-11597 29 30502.2U 36.2 48.6
2,4,6-Tribromophenol (S)%81 10-13797
2-Fluorobiphenyl (S)%46 15-12039
2-Fluorophenol (S)%25 10-12028
Nitrobenzene-d5 (S)%39 10-12040
Phenol-d6 (S)%35 10-12038
Terphenyl-d14 (S)%68 11-13189
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 14 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
739416
EPA 3546
EPA 8015C
8015 Solid GCSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92637630002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3847494
Associated Lab Samples:92637630002
Matrix:Solid
Analyzed
Diesel Range Organics(C10-C28)mg/kg ND 5.0 11/28/22 19:00
n-Pentacosane (S)%53 10-130 11/28/22 19:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3847495LABORATORY CONTROL SAMPLE:
LCSSpike
Diesel Range Organics(C10-C28)mg/kg 47.566.4 71 44-130
n-Pentacosane (S)%79 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92637399002
3847497SAMPLE DUPLICATE:
Diesel Range Organics(C10-C28)mg/kg 193 18 30232
n-Pentacosane (S)%10698
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 15 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
738442
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92637630001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3842856
Associated Lab Samples:92637630001
Matrix:Water
Analyzed
Aliphatic (C09-C18)ug/L ND 100 N211/22/22 20:47
Aliphatic (C19-C36)ug/L ND 100 N211/22/22 20:47
Aromatic (C11-C22)ug/L ND 100 N211/22/22 20:47
1-Chlorooctadecane (S)%70 40-140 11/22/22 20:47
2-Bromonaphthalene (S)%133 40-140 11/22/22 20:47
2-Fluorobiphenyl (S)%124 40-140 11/22/22 20:47
o-Terphenyl (S)%91 40-140 11/22/22 20:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3842857LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3842858
Aliphatic (C09-C18)ug/L 153 N23005140-14050151 1 50
Aliphatic (C19-C36)ug/L 358 N24008940-14086343 4 50
Aromatic (C11-C22)ug/L 761 N28509040-14080683 11 50
1-Chlorooctadecane (S)%67 40-14063
2-Bromonaphthalene (S)%119 40-140109
2-Fluorobiphenyl (S)%112 40-140103
o-Terphenyl (S)%86 40-14076
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 16 of 35
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
738239
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92637630002
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92637499004
3842207SAMPLE DUPLICATE:
Percent Moisture %20.2 N2132517.7
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92637590001
3842208SAMPLE DUPLICATE:
Percent Moisture %20.7 N222520.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 17 of 35
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 18 of 35
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92637630
FREDERICK JONES PROPERTY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92637630002 739416 739500OL-1 EPA 3546 EPA 8015C
92637630001 738442 738839MW-1 MADEP EPH MADEP EPH
92637630001 738908 739025MW-1 EPA 625.1 EPA 625.1
92637630001 738493MW-1 SM 6200B
92637630002 738239OL-1 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/30/2022 10:07 AM
Pace Analytical Services, LLC
1377 South Park Drive
Kernersville, NC 27284
[phone]
Page 19 of 35
Page 20 of 35
Page 21 of 35
Page 22 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
November 29, 2022
Stephanie Knott
Pace Analytical Services - NC
1377 South Park Dr.
Kernersville, NC 27284
Project Location: Frederick Jones Property
Client Job Number:
Project Number: 92637630
Laboratory Work Order Number: 22K3127
Enclosed are results of analyses for samples as received by the laboratory on November 22, 2022. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Rebecca Faust
Project Manager
Page 1 of 13
Table of Contents
Page 23 of 35
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
22K3127-01 5
Sample Preparation Information 6
QC Data 7
Petroleum Hydrocarbons Analyses - VPH 7
B323871 7
Flag/Qualifier Summary 9
Certifications 10
Chain of Custody/Sample Receipt 11
Page 2 of 13
Table of Contents
Page 24 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
11/29/2022
Pace Analytical Services - NC
1377 South Park Dr.
Kernersville, NC 27284
ATTN: Stephanie Knott
92637630
22K3127
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Frederick Jones Property
MW-1 22K3127-01 Water MADEP-VPH-Feb
2018 Rev 2.1
[TOC_1]Sample Summary[TOC]
Page 3 of 13
Table of Contents
Page 25 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA VPH only hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
MADEP-VPH-Feb 2018 Rev 2.1
No significant modifications were made to the method. All VPH samples were received preserved properly at pH <2 in the proper containers as specified on the chain-of-custody
form unless specified in this narrative.
Analytical column used for VPH analysis is Restek, Rtx-502.2, 105meter, 0.53mmID, 3um df. Trap used for VPH analysis is Carbopack B/CarboSieveS-III.
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Meghan E. Kelley
Reporting Specialist
Page 4 of 13
Table of Contents
Page 26 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 11/22/2022
Work Order: 22K3127Sample Description:Project Location: Frederick Jones Property
Sample ID: 22K3127-01
Field Sample #: MW-1
Sample Matrix: Water
Sampled: 11/17/2022 12:30
[TOC_2]22K3127-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Petroleum Hydrocarbons Analyses - VPH
ND 100 11/23/22 16:13 EEHg/L 11/23/22MADEP-VPH-Feb 2018
Rev 2.1
1Unadjusted C5-C8 Aliphatics
ND 100 11/23/22 16:13 EEHg/L 11/23/22MADEP-VPH-Feb 2018
Rev 2.1
1C5-C8 Aliphatics
ND 100 11/23/22 16:13 EEHg/L 11/23/22MADEP-VPH-Feb 2018
Rev 2.1
1Unadjusted C9-C12 Aliphatics
ND 100 11/23/22 16:13 EEHg/L 11/23/22MADEP-VPH-Feb 2018
Rev 2.1
1C9-C12 Aliphatics
ND 100 11/23/22 16:13 EEHg/L 11/23/22MADEP-VPH-Feb 2018
Rev 2.1
1C9-C10 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
2,5-Dibromotoluene (FID)85.0 11/23/22 16:1370-130
2,5-Dibromotoluene (PID)79.6 11/23/22 16:1370-130
[TOC_1]Sample Results[TOC]
Page 5 of 13
Table of Contents
Page 27 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: MA VPH Analytical Method: MADEP-VPH-Feb 2018 Rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B323871 11/23/225 5.0022K3127-01 [MW-1]
[TOC_1]Sample Preparation Information[TOC]
Page 6 of 13
Table of Contents
Page 28 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - VPH[TOC]
Batch B323871 - MA VPH
[TOC_3]B323871[TOC]
Blank (B323871-BLK1) Prepared & Analyzed: 11/23/22
Unadjusted C5-C8 Aliphatics g/L100ND
C5-C8 Aliphatics g/L100ND
Unadjusted C9-C12 Aliphatics g/L100ND
C9-C12 Aliphatics g/L100ND
C9-C10 Aromatics g/L100ND
Benzene g/L1.0ND
Butylcyclohexane g/L1.0ND
Decane g/L1.0ND
Ethylbenzene g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
2-Methylpentane g/L1.0ND
Naphthalene g/L5.0ND
Nonane g/L1.0ND
Pentane g/L1.0ND
Toluene g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
2,2,4-Trimethylpentane g/L1.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)87.134.8
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)84.733.9
LCS (B323871-BS1) Prepared & Analyzed: 11/23/22
Unadjusted C5-C8 Aliphatics g/L100 150 70-13095.7144
Unadjusted C9-C12 Aliphatics g/L100 150 70-130110165
C9-C10 Aromatics g/L100 50.0 70-13096.448.2
Benzene g/L1.0 50.0 70-13094.047.0
Butylcyclohexane g/L1.0 50.0 70-13012260.8
Decane g/L1.0 50.0 70-13087.243.6
Ethylbenzene g/L1.0 50.0 70-13089.844.9
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 70-13089.444.7
2-Methylpentane g/L1.0 50.0 70-13097.148.5
Naphthalene g/L5.0 50.0 70-13089.344.6
Nonane g/L1.0 50.0 70-13012260.8
Pentane g/L1.0 50.0 70-13089.844.9
Toluene g/L1.0 50.0 70-13092.246.1
1,2,4-Trimethylbenzene g/L1.0 50.0 70-13096.448.2
2,2,4-Trimethylpentane g/L1.0 50.0 70-13010050.1
m+p Xylene g/L2.0 100 70-13092.092.0
o-Xylene g/L1.0 50.0 70-13099.049.5
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10441.7
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)10642.2
[TOC_1]QC Data[TOC]
Page 7 of 13
Table of Contents
Page 29 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
Batch B323871 - MA VPH
LCS Dup (B323871-BSD1) Prepared & Analyzed: 11/23/22
Unadjusted C5-C8 Aliphatics g/L100 150 2570-13093.1 2.77140
Unadjusted C9-C12 Aliphatics g/L100 150 2570-130109 0.643164
C9-C10 Aromatics g/L100 50.0 2570-13096.7 0.25948.3
Benzene g/L1.0 50.0 2570-13094.6 0.70847.3
Butylcyclohexane g/L1.0 50.0 2570-130121 0.40960.5
Decane g/L1.0 50.0 2570-13086.7 0.47843.4
Ethylbenzene g/L1.0 50.0 2570-13090.1 0.28945.0
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 2570-13090.7 1.4645.4
2-Methylpentane g/L1.0 50.0 2570-13095.0 2.1947.5
Naphthalene g/L5.0 50.0 2570-13087.1 2.4643.5
Nonane g/L1.0 50.0 2570-130120 0.99460.2
Pentane g/L1.0 50.0 2570-13087.0 3.2243.5
Toluene g/L1.0 50.0 2570-13094.1 2.0647.1
1,2,4-Trimethylbenzene g/L1.0 50.0 2570-13096.7 0.25948.3
2,2,4-Trimethylpentane g/L1.0 50.0 2570-13097.3 2.9448.7
m+p Xylene g/L2.0 100 2570-13092.6 0.63492.6
o-Xylene g/L1.0 50.0 2570-13098.4 0.61649.2
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)10742.9
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)10541.8
Page 8 of 13
Table of Contents
Page 30 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
[TOC_1]Flag/Qualifier Summary[TOC]
Page 9 of 13
Table of Contents
Page 31 of 35
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP-VPH-Feb 2018 Rev 2.1 in Water
CT,NC,ME,NH-PUnadjusted C5-C8 Aliphatics
CT,NC,ME,NH-PC5-C8 Aliphatics
CT,NC,ME,NH-PUnadjusted C9-C12 Aliphatics
CT,NC,ME,NH-PC9-C12 Aliphatics
CT,NC,ME,NH-PC9-C10 Aromatics
[TOC_1]Certifications[TOC]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
PH-0165Connecticut Department of Public HealthCT 12/31/2022
652North Carolina Div. of Water QualityNC 12/31/2022
MA00100State of MaineME 06/9/2023
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
Page 10 of 13
Table of Contents
Page 32 of 35
Page 11 of 13
Table of Contents
Page 33 of 35
Page 12 of 13
Table of Contents
Page 34 of 35
Page 13 of 13
Table of Contents
Page 35 of 35