WS-5813_20918_CA_RPTS_20180727

S&ME, Inc. | 8646 W Market St, Ste 105 | Greensboro, NC 27409 | p 336.288.7180 | www.smeinc.com
July 27, 2018
High Falls Oil Company
PO Box 29
High Falls, NC 27259
Attention: Mr. Steven Majors
Reference: Report of Limited Groundwater Assessment
Eskimo Joes/Incident #20918/UST #WS-5813
1705 Cotton Grove Road, Lexington, Davidson County, North Carolina
S&ME Project No. 1584-02-045C
Dear Mr. Majors:
S&ME, Inc. (S&ME) submits this Letter Report for the above-referenced site in accordance with S&ME’s Proposal
No. 43-1700233, dated March 14, 2017 and subsequent authorizations. This work was performed at the request
of the North Carolina Department of Environmental Quality (NCDEQ) as pre-approved under Task Authorization
No. 20918-14 and signed by the Trust Fund Section of the Central Office on June 20, 2018.
The scope of services included the collection of groundwater samples from monitoring wells MW-1 and MW-2, for
analyses by Method 6200B and by Method 504.1. On July 3, 2018, the services were conducted as proposed.
Copies of the groundwater sampling forms are attached. The attached figure shows monitoring well locations and
the location of remediation wells used during corrective action activities performed during 2017.
Volatile organic compound (VOC) concentrations greater than the Gross Contamination Level (GCL), were
reported for monitor well sample MW-1, including Ethylene dibromide at a concentration of 111 micrograms per
liter (ug/L), and Benzene at a concentration of 5,580 ug/L. Eleven VOCs were reported in the sample collected
from monitor well MW-1 at concentrations less the corresponding GCLs but greater than the corresponding 15A
NCAC 02L Standards (2L Standards).
Six VOCs were reported for monitor well sample MW-2 at concentrations less than the corresponding GCLs but
greater than the corresponding 2L Standards. A copy of the laboratory report is attached.
Based on the analytical results described above, dissolved VOC impacts to groundwater near the source area
represented by monitor well MW-1 rebounded to concentrations greater than the GCLs. The VOCs detected at
monitoring well MW-2 remain at concentrations less than the corresponding GCLs. When compared with the
December 12, 2017, analytical results, the July 3, 2018 analytical results indicate that dissolved VOC concentrations
rebounded following the cessation of the hot-spot soil vapor extraction and air-sparge operations.
Report of Limited Groundwater Assessment
Eskimo Joes/Incident #20918/UST #WS-5813
1705 Cotton Grove Road, Lexington, Davidson County, North Carolina
S&ME Project No. 1584-02-045C
July 27, 2018 2
If you have any questions or comments regarding this report, please contact us at your convenience.
Sincerely,
S&ME, Inc.
Lyndal Butler Edmund Q.B. Henriques, L.G.
Environmental Scientist Senior Geologist
[e-mail] [e-mail]
CC. NCDEQ-UST Section, 450 W. Hanes Mill Road, Suite 300 Winston-Salem, NC 27105, Attention Karen Hall
Well I.D.
Installation Date
Total Depth1
Top of Casing Elevation
Casing Diameter
Consultant
Screen Interval Depth1
Date DTW GWE DTW GWE DTW GWE DTW GWE DTW GWE DTW GWE DTW GWE
06/25/02 23.35 77.26 23.68 77.07 23.43 77.19 22.91 76.59 NI -NI -NI -
09/27/02 25.11 75.50 25.17 75.58 24.96 75.66 23.43 76.07 25.55 76.06 23.08 76.41 24.86 74.92
08/21/07 21.01 79.60 20.95 79.80 21.16 79.46 19.98 79.52 20.97 80.64 20.41 79.08 22.04 77.74
07/20/12 17.67 82.94 17.73 83.02 17.72 12.48 17.92 11.88 17.97 12.03 15.70 14.30 15.90 54.10
05/05/14 12.82 87.79 12.82 87.93 NG NG NG NG NG NG NG NG 13.33 86.45
07/23/15 21.43 79.18 21.42 79.33 NG NG NG NG NG NG NG NG 22.46 77.32
06/30/17 14.79 85.82 15.01 85.74 NG NG NG NG NG NG NG NG NG NG
07/07/17 14.59 86.02 15.61 85.14 NG NG NG NG NG NG NG NG NG NG
10/07/17 24.91 75.70 28.58 72.17 NG NG NG NG NG NG NG NG NG NG
11/15/17 19.16 81.45 18.39 82.36 NG NG NG NG NG NG NG NG NG NG
12/12/17 23.72 76.89 22.32 78.43 NG NG NG NG NG NG NG NG NG NG
07/03/18 18.33 82.28 18.33 82.42 NG NG NG NG NG NG NG NG NG NG
Notes: All measurements are in feet
DTW = Depth to groundwater measured from the top of casing
GWE = Groundwater elevation
NI = Monitor well had not been installed at the time of data collection
NG = Not gauged
1 Depth below ground surface in feet
2-inch
9/10/2002
DW-1
7/3/2002
70.0
99.78
S&ME S&ME
30.0
2-inch
99.49
MW-2
28.8
100.75 100.62
6/26/2002
30.0
101.61
9/10/2002
MW-3
30.2
6/26/2002
99.50
6/25/2002
2-inch 2-inch 2-inch
6/25/2002
MW-1
27.1
100.61
S&ME S&ME S&ME
15.3 - 29.8 15 - 30
2-inch 2-inch
12.6 - 27.1 14.3 - 28.8 15.8 - 30.2 65 - 70
MW-4 MW-5 MW-6
S&ME S&ME
15 - 30
29.8
S&ME PROJECT NO. 1584-02-045C
TABLE 1
MONITOR WELL / GROUNDWATER ELEVATION DATA
ESKIMO JOE'S
LEXINGTON, NORTH CAROLINA
Updated January 17, 2018
Date
Collected BenzeneEthylbenzeneTolueneXylenes (total)Chloroform1,2 Dibromoethane (EDB)1,2-DichloroethaneIsopropyl Benzene (Cumene)n-PropylbenzeneDiisopropyl EtherMethyl tert-butyl etherNaphthalene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneMethylene ChlorideWell ID Method 602/6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B 6200B
MW-1 7/23/2015 14,000 1,510 26,600 12,660 541 67.0 125 <50.0 103 757 11,600 580 1,480 381 230
10/7/2017 12,700 1,210 26,000 16,280 NR NR NR NR NR 1,210 12,600 571 NR NR NR
11/15/2017 6,500 <500 7,400 18,500 NR NR NR NR NR <2500 15,400 NR NR NR NR
12/12/2017 3,650 590 6,420 18,100 <250 19.6 <250 <250 <250 1,080 19,700 640 3,420 1,900 <250
7/3/2018 5,580 1,890 19,000 18,080 <62.5 111*134 75.6 <62.5 582 9,300 522 2,920 <62.5 <250
MW-2 7/23/2015 9,700 2,650 29,900 18,960 274 <100 109 <100 227 382.00 3,330 458 2,190 668 <400
10/7/2017 dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well dry well
11/15/2017 1.9 1.0 2.0 2.8 NR NR NR NR NR 6.0 321 NR NR NR NR
12/12/2017 8.88 24.6 2.97 177 <0.5 0.50 <0.5 1.55 <0.5 3.08 186 12.3 73 49 <5
7/3/2018 26.4 146 518 2,490 <5.0 0.16 <5.0 11.6 <5.0 <5.0 115 75.1 478 <5.0 <20.0
1 600 600 500 70 0.02 0.4 70 70 70 20 6 400 400 5
5,000 84,500 260,000 85,500 70,000 50 400 25,000 30,000 70,000 20,000 6,000 28,500 25,000 5,000
Notes
Concentrations shown in microgram per liter (parts per billion).
Only compounds detected by analyses are shown.
Concentrations in bold exceed the corresponding 2L Groundwater Standard
Shaded cells indicate concentrations greater than the corresponding NCDEQ Gross Contamination Levels (GCLs)
< = Below the noted report limit
* Analyzed by Method 504.1
Gross Contamination
Levels (GCLs)
Table 2
Lexington, North Carolina
S&ME Project No. 1584-02-045C
2L Groundwater Quality
Standard (2L Standards)
Summary of Hot-Spot and Baseline Groundwater Analytical Results
Eskimo Joe's
Updated July 25, 2018
T:\Projects\2002\ENV\045C Eskimo Joes 2017 Hot Spot Sparging\Deliverables\July 2018 Monitoring Event\Tables 1-2_letter report_20180727.xls
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WLWLWLWLWLWLWLWLWLWLWLWLWLWLWLWLWLWLNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGx x x x x
xxxxxxxxxxxxxxxSVE-2
NC HIGHWAY 8 - COTTON GROVE ROADESKIMO JOE'SASPHALT
TEMPORARY FENCING
- MONITORING WELL LOCATION
- OVERHEAD UTILITY LINE
- VENT LINE (FORMER)
- CATHODIC PROTECTION (FORMER)
- CONDUITS (FORMER)
- WATER LINE
- LEXINGTON UTILITIES ELECTRICAL POLE
V
C
WL
OHL
CANOPYAPPROXIMATE PROPERTY BOUNDARY
MW-3
MW-2
MW-4
MW-1 RIGHT-OF-WAY- WATER SAMPLE LOCATION
NG - NATURAL GAS LINE
P1
DW-1
ALL LOCATIONS SHOWN ARE APPROXIMATE
NOTE
MW-5
MW-6 KEY
FORMER JIMMY'S BBQ
APPROXIMATE EXTENT OF NEW ISLAND
SVE-1
AS-1
AS-2
- SOIL VAPOR EXTRACTION WELL LOCATION
- AIR SPARGE WELL LOCATION
- 2" PVC AIR SPARGE CHASE PIPE
- 3" PVC SVE PIPE
APPROXIMATE
EQUIPMENT TRAILER
LOCATION
AS-3
FIGURE NO.Drawing path: Q:\1584\2002\02-045 - ESKIMO JOES\C\1-18\Eskimo Joes.dwgPROJECT NUMBER
DATE:
SCALE:
0 10 20
(IN FEET)GRAPHIC SCALE (IN FEET)GRAPHIC SCALE ESKIMO JOE'SLEXINGTON, NORTH CAROLINA1
JAN. 2018SITE MAPAS SHOWN
1584-02-045C
Attachment I – Groundwater Sampling Forms
° F
Date Time
7/3/18 07:30 4.0 10.0
7/3/18 07:30 µS/cm
18.33 ft-TOC inch
27.20 ft-TOC gal
8.87 feet gal
ft-GRD gal
ft-GRD
07:45 End Time:
gal
Time pH
Temp
Cond Turbidity

(s.u.)(°C) µS/cm (NTU)
07:50 5.7 21.8 69
07:55 5.6 21.8 67
08:00 5.6 21.8 67
08:05
Qty Container Pres.Qty Pres.
3 40mL VOAs HCl
3 40mL VOAs NaS2O3
(1)
Notes:
Form Revision Date:
Equipment Calibration Information:
Equipment Calibration Solution Calibration Check
pH 4.00, 7.00, 10.00
Air Temp:
July 3, 2018
80
08:05Sample Time:
Sample Date:
Weather:
Locked?:
Sampled By:
Yes
Gary Simcox
Sunny
Water Level & Well Data
Measuring Point:Top of Casing Well Volume
Depth to Water:Well Diameter
Conductivity 1,413 1,413
7.0
µS/cm
2
Stickup Height:
Well Purging Information
Purge Method:Bailer Purge Start Time:08:00
Total Well Depth:Well Volume
Height of Water Column:3 * Well Volume
Screen Length:5 * Well Volume
1.4
4.3
7.2
1.0 Petroleum Odors
Total Volume Purged:5.0 Well Purged Dry?:No
Field Parameters
Cumulative Volume Comments
Petroleum Odors
Petroleum Odors
3.0
5.0
(Gal)
Analytical Data
Method Method
9/13/17 8:00 AM
Name Signature Date
Container
Sample Method:Sample Time:Bailer
VOCs 6200
EDB 504.1
15Purge Time (Min.):
GROUNDWATER SAMPLING FORM
Project Name:
Project Location:
Project Number:
Source Well:
Eskimo Joe's
Lexington, NC
1584-02-045B
MW-1
Purge Date:July 3, 2018
7/3/18
° F
Date Time
7/3/18 07:30 4.0 10.0
7/3/18 07:30 µS/cm
18.33 ft-TOC inch
29.10 ft-TOC gal
10.77 feet gal
ft-GRD gal
ft-GRD
08:15 End Time:
gal
Time pH
Temp
Cond Turbidity

(s.u.)(°C) µS/cm (NTU)
08:20 5.9 22 227
08:25 5.9 22.1 225
08:30 5.9 22.2 222
08:35
Qty Container Pres.Qty Pres.
3 40mL VOAs HCl
3 40mL VOAs NaS2O3
(1)
Notes:
Form Revision Date:
Project Number:1584-02-045B Purge Date:July 3, 2018
Source Well:MW-2 Purge Time (Min.):15
GROUNDWATER SAMPLING FORM
Project Name:Eskimo Joe's
Project Location:Lexington, NC
Weather:Sunny Air Temp:80
Equipment Calibration Information:
Equipment Calibration Solution Calibration Check
Locked?:Yes Sample Date:July 3, 2018
Sampled By:Gary Simcox Sample Time:08:35
pH 4.00, 7.00, 10.00 7.0
Conductivity 1,413 1,413 µS/cm
Total Well Depth:Well Volume 1.8
Height of Water Column:3 * Well Volume 5.3
Water Level & Well Data
Measuring Point:Top of Casing Well Volume
Depth to Water:Well Diameter 2
Total Volume Purged:5.0 Well Purged Dry?:No
Field Parameters
Cumulative Volume Comments
Screen Length:5 * Well Volume 8.8
Stickup Height:
Well Purging Information
Purge Method:Bailer Purge Start Time:08:30
(Gal)
1.0 Petroleum Odors
3.0 Petroleum Odors
5.0 Petroleum Odors
Sample Method:Bailer Sample Time:
EDB 504.1
Analytical Data
Method Method Container
VOCs 6200
9/13/17 8:00 AM
Name Signature Date
7/3/18
Attachment II – Laboratory Report
#=CL#
July 12, 2018
LIMS USE: FR - ED HENRIQUES
LIMS OBJECT ID: 92390768
92390768
Project:
Pace Project No.:
RE:
Mr. Ed Henriques
S&ME, Inc.
8646 West Market Street
Suite 105
Greensboro, NC 27409
Eskimo Joe's
Dear Mr. Henriques:
Enclosed are the analytical results for sample(s) received by the laboratory on July 05, 2018. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
cc:Brian Wilson, S&ME Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 23
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92390768
Eskimo Joe's
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 23
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92390768
Eskimo Joe's
Lab ID Sample ID Matrix Date Collected Date Received
92390768001 MW-1 Water 07/03/18 08:05 07/05/18 09:54
92390768002 MW-2 Water 07/03/18 08:35 07/05/18 09:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92390768
Eskimo Joe's
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92390768001 MW-1 EPA 504.1 4 PASI-CSEM
SM 6200B 63 PASI-CCAH
92390768002 MW-2 EPA 504.1 4 PASI-CSEM
SM 6200B 63 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 23
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92390768
Eskimo Joe's
Method:
Client:S&ME - Greensboro
EPA 504.1
Date:July 12, 2018
Description:504 GCS EDB and DBCP
General Information:
2 samples were analyzed for EPA 504.1. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 504.1 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
QC Batch: 418528
S2: Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample re-
analysis).
• DUP (Lab ID: 2319951)
• 1-Chloro-2-bromopropane (S)
S4: Surrogate recovery not evaluated against control limits due to sample dilution.
• MW-1 (Lab ID: 92390768001)
• 1-Chloro-2-bromopropane (S)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 23
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92390768
Eskimo Joe's
Method:
Client:S&ME - Greensboro
SM 6200B
Date:July 12, 2018
Description:6200B MSV
General Information:
2 samples were analyzed for SM 6200B. All samples were received in acceptable condition with any exceptions noted below or on the
chain-of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: 418201
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92390233010
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 2318347)
• 1,1-Dichloroethene
• 1,2,3-Trichlorobenzene
• 2,2-Dichloropropane
• Carbon tetrachloride
• Dichlorodifluoromethane
• Hexachloro-1,3-butadiene
• Trichlorofluoromethane
• Vinyl chloride
• n-Butylbenzene
• sec-Butylbenzene
• MSD (Lab ID: 2318348)
• 1,1,1-Trichloroethane
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 23
#=NA#
PROJECT NARRATIVE
Pace Project No.:
Project:
92390768
Eskimo Joe's
Method:
Client:S&ME - Greensboro
SM 6200B
Date:July 12, 2018
Description:6200B MSV
QC Batch: 418201
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92390233010
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• 1,1-Dichloroethene
• 1,1-Dichloropropene
• 1,3,5-Trimethylbenzene
• 2,2-Dichloropropane
• Bromochloromethane
• Bromodichloromethane
• Carbon tetrachloride
• Dichlorodifluoromethane
• Hexachloro-1,3-butadiene
• Trichlorofluoromethane
• Vinyl chloride
• n-Butylbenzene
• n-Propylbenzene
• sec-Butylbenzene
• trans-1,3-Dichloropropene
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92390768
Eskimo Joe's
Sample:MW-1 Lab ID:92390768001 Collected:07/03/18 08:05 Received:07/05/18 09:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1504 GCS EDB and DBCP
1,2-Dibromo-3-chloropropane <9.8 ug/L 07/12/18 09:12 96-12-807/11/18 09:009.8 9.8 200
1,2-Dibromoethane (EDB)111 ug/L 07/12/18 09:12 106-93-407/11/18 09:003.9 3.9 200
1,2,3-Trichloropropane 38.1 ug/L 07/12/18 09:12 96-18-407/11/18 09:009.8 9.8 200
Surrogates
1-Chloro-2-bromopropane (S)0 %07/12/18 09:12 301-79-56 S407/11/18 09:0070-130 200
Analytical Method: SM 6200B6200B MSV
Benzene 5580 ug/L 07/09/18 15:41 71-43-262.5 31.2 125
Bromobenzene <62.5 ug/L 07/09/18 15:41 108-86-162.5 31.2 125
Bromochloromethane <62.5 ug/L 07/09/18 15:41 74-97-562.5 31.2 125
Bromodichloromethane <62.5 ug/L 07/09/18 15:41 75-27-462.5 31.2 125
Bromoform <62.5 ug/L 07/09/18 15:41 75-25-262.5 31.2 125
Bromomethane <625 ug/L 07/09/18 15:41 74-83-9625312125
n-Butylbenzene <62.5 ug/L 07/09/18 15:41 104-51-862.5 31.2 125
sec-Butylbenzene <62.5 ug/L 07/09/18 15:41 135-98-862.5 31.2 125
tert-Butylbenzene <62.5 ug/L 07/09/18 15:41 98-06-662.5 31.2 125
Carbon tetrachloride <62.5 ug/L 07/09/18 15:41 56-23-562.5 31.2 125
Chlorobenzene <62.5 ug/L 07/09/18 15:41 108-90-762.5 31.2 125
Chloroethane <125 ug/L 07/09/18 15:41 75-00-312562.5 125
Chloroform <62.5 ug/L 07/09/18 15:41 67-66-362.5 31.2 125
Chloromethane <125 ug/L 07/09/18 15:41 74-87-312562.5 125
2-Chlorotoluene <62.5 ug/L 07/09/18 15:41 95-49-862.5 31.2 125
4-Chlorotoluene <62.5 ug/L 07/09/18 15:41 106-43-462.5 31.2 125
1,2-Dibromo-3-chloropropane <125 ug/L 07/09/18 15:41 96-12-812562.5 125
Dibromochloromethane <62.5 ug/L 07/09/18 15:41 124-48-162.5 31.2 125
1,2-Dibromoethane (EDB)<62.5 ug/L 07/09/18 15:41 106-93-462.5 31.2 125
Dibromomethane <62.5 ug/L 07/09/18 15:41 74-95-362.5 31.2 125
1,2-Dichlorobenzene <62.5 ug/L 07/09/18 15:41 95-50-162.5 31.2 125
1,3-Dichlorobenzene <62.5 ug/L 07/09/18 15:41 541-73-162.5 31.2 125
1,4-Dichlorobenzene <62.5 ug/L 07/09/18 15:41 106-46-762.5 31.2 125
Dichlorodifluoromethane <62.5 ug/L 07/09/18 15:41 75-71-862.5 31.2 125
1,1-Dichloroethane <62.5 ug/L 07/09/18 15:41 75-34-362.5 31.2 125
1,2-Dichloroethane 134 ug/L 07/09/18 15:41 107-06-262.5 31.2 125
1,1-Dichloroethene <62.5 ug/L 07/09/18 15:41 75-35-462.5 31.2 125
cis-1,2-Dichloroethene <62.5 ug/L 07/09/18 15:41 156-59-262.5 31.2 125
trans-1,2-Dichloroethene <62.5 ug/L 07/09/18 15:41 156-60-562.5 31.2 125
1,2-Dichloropropane <62.5 ug/L 07/09/18 15:41 78-87-562.5 31.2 125
1,3-Dichloropropane <62.5 ug/L 07/09/18 15:41 142-28-962.5 31.2 125
2,2-Dichloropropane <62.5 ug/L 07/09/18 15:41 594-20-762.5 31.2 125
1,1-Dichloropropene <62.5 ug/L 07/09/18 15:41 563-58-662.5 31.2 125
cis-1,3-Dichloropropene <62.5 ug/L 07/09/18 15:41 10061-01-562.5 31.2 125
trans-1,3-Dichloropropene <62.5 ug/L 07/09/18 15:41 10061-02-662.5 31.2 125
Diisopropyl ether 582 ug/L 07/09/18 15:41 108-20-362.5 31.2 125
Ethylbenzene 1890 ug/L 07/09/18 15:41 100-41-462.5 31.2 125
Hexachloro-1,3-butadiene <250 ug/L 07/09/18 15:41 87-68-3250125125
Isopropylbenzene (Cumene)75.6 ug/L 07/09/18 15:41 98-82-862.5 31.2 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
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Page 8 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92390768
Eskimo Joe's
Sample:MW-1 Lab ID:92390768001 Collected:07/03/18 08:05 Received:07/05/18 09:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methylene Chloride <250 ug/L 07/09/18 15:41 75-09-2250125125
Methyl-tert-butyl ether 9300 ug/L 07/09/18 15:41 1634-04-462.5 31.2 125
Naphthalene 522 ug/L 07/09/18 15:41 91-20-3250125125
n-Propylbenzene <62.5 ug/L 07/09/18 15:41 103-65-162.5 31.2 125
Styrene <62.5 ug/L 07/09/18 15:41 100-42-562.5 31.2 125
1,1,1,2-Tetrachloroethane <62.5 ug/L 07/09/18 15:41 630-20-662.5 31.2 125
1,1,2,2-Tetrachloroethane <62.5 ug/L 07/09/18 15:41 79-34-562.5 31.2 125
Tetrachloroethene <62.5 ug/L 07/09/18 15:41 127-18-462.5 31.2 125
Toluene 19000 ug/L 07/09/18 15:41 108-88-362.5 31.2 125
1,2,3-Trichlorobenzene <250 ug/L 07/09/18 15:41 87-61-6250125125
1,2,4-Trichlorobenzene <250 ug/L 07/09/18 15:41 120-82-1250125125
1,1,1-Trichloroethane <62.5 ug/L 07/09/18 15:41 71-55-662.5 31.2 125
1,1,2-Trichloroethane <62.5 ug/L 07/09/18 15:41 79-00-562.5 31.2 125
Trichloroethene <62.5 ug/L 07/09/18 15:41 79-01-662.5 31.2 125
Trichlorofluoromethane <125 ug/L 07/09/18 15:41 75-69-412562.5 125
1,2,3-Trichloropropane <62.5 ug/L 07/09/18 15:41 96-18-462.5 31.2 125
1,2,4-Trimethylbenzene 2920 ug/L 07/09/18 15:41 95-63-662.5 31.2 125
1,3,5-Trimethylbenzene <62.5 ug/L 07/09/18 15:41 108-67-862.5 31.2 125
Vinyl chloride <125 ug/L 07/09/18 15:41 75-01-412562.5 125
m&p-Xylene 11200 ug/L 07/09/18 15:41 179601-23-112562.5 125
o-Xylene 6880 ug/L 07/09/18 15:41 95-47-662.5 31.2 125
Surrogates
1,2-Dichloroethane-d4 (S)105 %07/09/18 15:41 17060-07-070-130 125
4-Bromofluorobenzene (S)98 %07/09/18 15:41 460-00-470-130 125
Toluene-d8 (S)101 %07/09/18 15:41 2037-26-570-130 125
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
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Page 9 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92390768
Eskimo Joe's
Sample:MW-2 Lab ID:92390768002 Collected:07/03/18 08:35 Received:07/05/18 09:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 504.1 Preparation Method: EPA 504.1504 GCS EDB and DBCP
1,2-Dibromo-3-chloropropane 0.14 ug/L 07/06/18 15:50 96-12-807/06/18 09:000.049 0.049 1
1,2-Dibromoethane (EDB)0.16 ug/L 07/06/18 15:50 106-93-407/06/18 09:000.020 0.020 1
1,2,3-Trichloropropane 0.13 ug/L 07/06/18 15:50 96-18-407/06/18 09:000.049 0.049 1
Surrogates
1-Chloro-2-bromopropane (S)101 %07/06/18 15:50 301-79-5607/06/18 09:0070-130 1
Analytical Method: SM 6200B6200B MSV
Benzene 26.4 ug/L 07/09/18 15:25 71-43-25.0 2.5 10
Bromobenzene <5.0 ug/L 07/09/18 15:25 108-86-15.0 2.5 10
Bromochloromethane <5.0 ug/L 07/09/18 15:25 74-97-55.0 2.5 10
Bromodichloromethane <5.0 ug/L 07/09/18 15:25 75-27-45.0 2.5 10
Bromoform <5.0 ug/L 07/09/18 15:25 75-25-25.0 2.5 10
Bromomethane <50.0 ug/L 07/09/18 15:25 74-83-950.0 25.0 10
n-Butylbenzene <5.0 ug/L 07/09/18 15:25 104-51-85.0 2.5 10
sec-Butylbenzene <5.0 ug/L 07/09/18 15:25 135-98-85.0 2.5 10
tert-Butylbenzene <5.0 ug/L 07/09/18 15:25 98-06-65.0 2.5 10
Carbon tetrachloride <5.0 ug/L 07/09/18 15:25 56-23-55.0 2.5 10
Chlorobenzene <5.0 ug/L 07/09/18 15:25 108-90-75.0 2.5 10
Chloroethane <10.0 ug/L 07/09/18 15:25 75-00-310.0 5.0 10
Chloroform <5.0 ug/L 07/09/18 15:25 67-66-35.0 2.5 10
Chloromethane <10.0 ug/L 07/09/18 15:25 74-87-310.0 5.0 10
2-Chlorotoluene <5.0 ug/L 07/09/18 15:25 95-49-85.0 2.5 10
4-Chlorotoluene <5.0 ug/L 07/09/18 15:25 106-43-45.0 2.5 10
1,2-Dibromo-3-chloropropane <10.0 ug/L 07/09/18 15:25 96-12-810.0 5.0 10
Dibromochloromethane <5.0 ug/L 07/09/18 15:25 124-48-15.0 2.5 10
1,2-Dibromoethane (EDB)<5.0 ug/L 07/09/18 15:25 106-93-45.0 2.5 10
Dibromomethane <5.0 ug/L 07/09/18 15:25 74-95-35.0 2.5 10
1,2-Dichlorobenzene <5.0 ug/L 07/09/18 15:25 95-50-15.0 2.5 10
1,3-Dichlorobenzene <5.0 ug/L 07/09/18 15:25 541-73-15.0 2.5 10
1,4-Dichlorobenzene <5.0 ug/L 07/09/18 15:25 106-46-75.0 2.5 10
Dichlorodifluoromethane <5.0 ug/L 07/09/18 15:25 75-71-85.0 2.5 10
1,1-Dichloroethane <5.0 ug/L 07/09/18 15:25 75-34-35.0 2.5 10
1,2-Dichloroethane <5.0 ug/L 07/09/18 15:25 107-06-25.0 2.5 10
1,1-Dichloroethene <5.0 ug/L 07/09/18 15:25 75-35-45.0 2.5 10
cis-1,2-Dichloroethene <5.0 ug/L 07/09/18 15:25 156-59-25.0 2.5 10
trans-1,2-Dichloroethene <5.0 ug/L 07/09/18 15:25 156-60-55.0 2.5 10
1,2-Dichloropropane <5.0 ug/L 07/09/18 15:25 78-87-55.0 2.5 10
1,3-Dichloropropane <5.0 ug/L 07/09/18 15:25 142-28-95.0 2.5 10
2,2-Dichloropropane <5.0 ug/L 07/09/18 15:25 594-20-75.0 2.5 10
1,1-Dichloropropene <5.0 ug/L 07/09/18 15:25 563-58-65.0 2.5 10
cis-1,3-Dichloropropene <5.0 ug/L 07/09/18 15:25 10061-01-55.0 2.5 10
trans-1,3-Dichloropropene <5.0 ug/L 07/09/18 15:25 10061-02-65.0 2.5 10
Diisopropyl ether <5.0 ug/L 07/09/18 15:25 108-20-35.0 2.5 10
Ethylbenzene 146 ug/L 07/09/18 15:25 100-41-45.0 2.5 10
Hexachloro-1,3-butadiene <20.0 ug/L 07/09/18 15:25 87-68-320.0 10.0 10
Isopropylbenzene (Cumene)11.6 ug/L 07/09/18 15:25 98-82-85.0 2.5 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 23
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92390768
Eskimo Joe's
Sample:MW-2 Lab ID:92390768002 Collected:07/03/18 08:35 Received:07/05/18 09:54 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B6200B MSV
Methylene Chloride <20.0 ug/L 07/09/18 15:25 75-09-220.0 10.0 10
Methyl-tert-butyl ether 115 ug/L 07/09/18 15:25 1634-04-45.0 2.5 10
Naphthalene 75.1 ug/L 07/09/18 15:25 91-20-320.0 10.0 10
n-Propylbenzene <5.0 ug/L 07/09/18 15:25 103-65-15.0 2.5 10
Styrene <5.0 ug/L 07/09/18 15:25 100-42-55.0 2.5 10
1,1,1,2-Tetrachloroethane <5.0 ug/L 07/09/18 15:25 630-20-65.0 2.5 10
1,1,2,2-Tetrachloroethane <5.0 ug/L 07/09/18 15:25 79-34-55.0 2.5 10
Tetrachloroethene <5.0 ug/L 07/09/18 15:25 127-18-45.0 2.5 10
Toluene 518 ug/L 07/09/18 15:25 108-88-35.0 2.5 10
1,2,3-Trichlorobenzene <20.0 ug/L 07/09/18 15:25 87-61-620.0 10.0 10
1,2,4-Trichlorobenzene <20.0 ug/L 07/09/18 15:25 120-82-120.0 10.0 10
1,1,1-Trichloroethane <5.0 ug/L 07/09/18 15:25 71-55-65.0 2.5 10
1,1,2-Trichloroethane <5.0 ug/L 07/09/18 15:25 79-00-55.0 2.5 10
Trichloroethene <5.0 ug/L 07/09/18 15:25 79-01-65.0 2.5 10
Trichlorofluoromethane <10.0 ug/L 07/09/18 15:25 75-69-410.0 5.0 10
1,2,3-Trichloropropane <5.0 ug/L 07/09/18 15:25 96-18-45.0 2.5 10
1,2,4-Trimethylbenzene 478 ug/L 07/09/18 15:25 95-63-65.0 2.5 10
1,3,5-Trimethylbenzene <5.0 ug/L 07/09/18 15:25 108-67-85.0 2.5 10
Vinyl chloride <10.0 ug/L 07/09/18 15:25 75-01-410.0 5.0 10
m&p-Xylene 1480 ug/L 07/09/18 15:25 179601-23-110.0 5.0 10
o-Xylene 1010 ug/L 07/09/18 15:25 95-47-65.0 2.5 10
Surrogates
1,2-Dichloroethane-d4 (S)107 %07/09/18 15:25 17060-07-070-130 10
4-Bromofluorobenzene (S)99 %07/09/18 15:25 460-00-470-130 10
Toluene-d8 (S)101 %07/09/18 15:25 2037-26-570-130 10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
418201
SM 6200B
SM 6200B
6200B MSV
Associated Lab Samples:92390768001, 92390768002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2318345
Associated Lab Samples:92390768001, 92390768002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,1,1-Trichloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,1,2,2-Tetrachloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,1,2-Trichloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,1-Dichloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,1-Dichloroethene ug/L <0.50 0.50 07/09/18 11:360.25
1,1-Dichloropropene ug/L <0.50 0.50 07/09/18 11:360.25
1,2,3-Trichlorobenzene ug/L <2.0 2.0 07/09/18 11:361.0
1,2,3-Trichloropropane ug/L <0.50 0.50 07/09/18 11:360.25
1,2,4-Trichlorobenzene ug/L <2.0 2.0 07/09/18 11:361.0
1,2,4-Trimethylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
1,2-Dibromo-3-chloropropane ug/L <1.0 1.0 07/09/18 11:360.50
1,2-Dibromoethane (EDB)ug/L <0.50 0.50 07/09/18 11:360.25
1,2-Dichlorobenzene ug/L <0.50 0.50 07/09/18 11:360.25
1,2-Dichloroethane ug/L <0.50 0.50 07/09/18 11:360.25
1,2-Dichloropropane ug/L <0.50 0.50 07/09/18 11:360.25
1,3,5-Trimethylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
1,3-Dichlorobenzene ug/L <0.50 0.50 07/09/18 11:360.25
1,3-Dichloropropane ug/L <0.50 0.50 07/09/18 11:360.25
1,4-Dichlorobenzene ug/L <0.50 0.50 07/09/18 11:360.25
2,2-Dichloropropane ug/L <0.50 0.50 07/09/18 11:360.25
2-Chlorotoluene ug/L <0.50 0.50 07/09/18 11:360.25
4-Chlorotoluene ug/L <0.50 0.50 07/09/18 11:360.25
Benzene ug/L <0.50 0.50 07/09/18 11:360.25
Bromobenzene ug/L <0.50 0.50 07/09/18 11:360.25
Bromochloromethane ug/L <0.50 0.50 07/09/18 11:360.25
Bromodichloromethane ug/L <0.50 0.50 07/09/18 11:360.25
Bromoform ug/L <0.50 0.50 07/09/18 11:360.25
Bromomethane ug/L <5.0 5.0 07/09/18 11:362.5
Carbon tetrachloride ug/L <0.50 0.50 07/09/18 11:360.25
Chlorobenzene ug/L <0.50 0.50 07/09/18 11:360.25
Chloroethane ug/L <1.0 1.0 07/09/18 11:360.50
Chloroform ug/L <0.50 0.50 07/09/18 11:360.25
Chloromethane ug/L <1.0 1.0 07/09/18 11:360.50
cis-1,2-Dichloroethene ug/L <0.50 0.50 07/09/18 11:360.25
cis-1,3-Dichloropropene ug/L <0.50 0.50 07/09/18 11:360.25
Dibromochloromethane ug/L <0.50 0.50 07/09/18 11:360.25
Dibromomethane ug/L <0.50 0.50 07/09/18 11:360.25
Dichlorodifluoromethane ug/L <0.50 0.50 07/09/18 11:360.25
Diisopropyl ether ug/L <0.50 0.50 07/09/18 11:360.25
Ethylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2318345
Associated Lab Samples:92390768001, 92390768002
Matrix:Water
AnalyzedMDL
Hexachloro-1,3-butadiene ug/L <2.0 2.0 07/09/18 11:361.0
Isopropylbenzene (Cumene)ug/L <0.50 0.50 07/09/18 11:360.25
m&p-Xylene ug/L <1.0 1.0 07/09/18 11:360.50
Methyl-tert-butyl ether ug/L <0.50 0.50 07/09/18 11:360.25
Methylene Chloride ug/L <2.0 2.0 07/09/18 11:361.0
n-Butylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
n-Propylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
Naphthalene ug/L <2.0 2.0 07/09/18 11:361.0
o-Xylene ug/L <0.50 0.50 07/09/18 11:360.25
sec-Butylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
Styrene ug/L <0.50 0.50 07/09/18 11:360.25
tert-Butylbenzene ug/L <0.50 0.50 07/09/18 11:360.25
Tetrachloroethene ug/L <0.50 0.50 07/09/18 11:360.25
Toluene ug/L <0.50 0.50 07/09/18 11:360.25
trans-1,2-Dichloroethene ug/L <0.50 0.50 07/09/18 11:360.25
trans-1,3-Dichloropropene ug/L <0.50 0.50 07/09/18 11:360.25
Trichloroethene ug/L <0.50 0.50 07/09/18 11:360.25
Trichlorofluoromethane ug/L <1.0 1.0 07/09/18 11:360.50
Vinyl chloride ug/L <1.0 1.0 07/09/18 11:360.50
1,2-Dichloroethane-d4 (S)%103 70-130 07/09/18 11:36
4-Bromofluorobenzene (S)%95 70-130 07/09/18 11:36
Toluene-d8 (S)%102 70-130 07/09/18 11:36
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2318346LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 59.050 118 60-140
1,1,1-Trichloroethane ug/L 56.950 114 60-140
1,1,2,2-Tetrachloroethane ug/L 55.550 111 60-140
1,1,2-Trichloroethane ug/L 55.950 112 60-140
1,1-Dichloroethane ug/L 53.650 107 60-140
1,1-Dichloroethene ug/L 59.350 119 60-140
1,1-Dichloropropene ug/L 57.150 114 60-140
1,2,3-Trichlorobenzene ug/L 54.950 110 60-140
1,2,3-Trichloropropane ug/L 53.850 108 60-140
1,2,4-Trichlorobenzene ug/L 57.350 115 60-140
1,2,4-Trimethylbenzene ug/L 56.250 112 60-140
1,2-Dibromo-3-chloropropane ug/L 59.450 119 60-140
1,2-Dibromoethane (EDB)ug/L 55.850 112 60-140
1,2-Dichlorobenzene ug/L 55.550 111 60-140
1,2-Dichloroethane ug/L 50.450 101 60-140
1,2-Dichloropropane ug/L 56.750 113 60-140
1,3,5-Trimethylbenzene ug/L 55.750 111 60-140
1,3-Dichlorobenzene ug/L 54.650 109 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2318346LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichloropropane ug/L 55.650 111 60-140
1,4-Dichlorobenzene ug/L 54.650 109 60-140
2,2-Dichloropropane ug/L 61.350 123 60-140
2-Chlorotoluene ug/L 54.150 108 60-140
4-Chlorotoluene ug/L 54.550 109 60-140
Benzene ug/L 54.850 110 60-140
Bromobenzene ug/L 54.050 108 60-140
Bromochloromethane ug/L 58.950 118 60-140
Bromodichloromethane ug/L 59.950 120 60-140
Bromoform ug/L 51.050 102 60-140
Bromomethane ug/L 48.350 97 60-140
Carbon tetrachloride ug/L 60.650 121 60-140
Chlorobenzene ug/L 54.750 109 60-140
Chloroethane ug/L 52.250 104 60-140
Chloroform ug/L 51.450 103 60-140
Chloromethane ug/L 53.650 107 60-140
cis-1,2-Dichloroethene ug/L 55.050 110 60-140
cis-1,3-Dichloropropene ug/L 58.950 118 60-140
Dibromochloromethane ug/L 51.750 103 60-140
Dibromomethane ug/L 57.350 115 60-140
Dichlorodifluoromethane ug/L 68.350 137 60-140
Diisopropyl ether ug/L 54.150 108 60-140
Ethylbenzene ug/L 53.850 108 60-140
Hexachloro-1,3-butadiene ug/L 58.350 117 60-140
Isopropylbenzene (Cumene)ug/L 56.750 113 60-140
m&p-Xylene ug/L 110100 110 60-140
Methyl-tert-butyl ether ug/L 53.150 106 60-140
Methylene Chloride ug/L 53.150 106 60-140
n-Butylbenzene ug/L 58.450 117 60-140
n-Propylbenzene ug/L 55.550 111 60-140
Naphthalene ug/L 56.250 112 60-140
o-Xylene ug/L 56.850 114 60-140
sec-Butylbenzene ug/L 57.050 114 60-140
Styrene ug/L 56.850 114 60-140
tert-Butylbenzene ug/L 48.150 96 60-140
Tetrachloroethene ug/L 51.350 103 60-140
Toluene ug/L 54.450 109 60-140
trans-1,2-Dichloroethene ug/L 55.950 112 60-140
trans-1,3-Dichloropropene ug/L 60.550 121 60-140
Trichloroethene ug/L 57.450 115 60-140
Trichlorofluoromethane ug/L 59.850 120 60-140
Vinyl chloride ug/L 62.150 124 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2318347MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92390233010
2318348
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 1000 134 60-140136 2 301000ND13401360
1,1,1-Trichloroethane ug/L M1100013760-140141 2 301000ND13701410
1,1,2,2-Tetrachloroethane ug/L 1000 126 60-140133 5 301000ND12601330
1,1,2-Trichloroethane ug/L 1000 129 60-140133 3 301000ND12901330
1,1-Dichloroethane ug/L 1000 128 60-140130 2 301000ND12801300
1,1-Dichloroethene ug/L M1100014560-140148 2 301000ND14501480
1,1-Dichloropropene ug/L M1100013760-140141 3 301000ND13701410
1,2,3-Trichlorobenzene ug/L M1100014160-140138 3 301000ND14101380
1,2,3-Trichloropropane ug/L 1000 131 60-140127 3 301000ND13101270
1,2,4-Trichlorobenzene ug/L 1000 135 60-140137 1 301000ND13501370
1,2,4-Trimethylbenzene ug/L 1000 135 60-140136 0 301000ND13701380
1,2-Dibromo-3-
chloropropane ug/L 1000 133 60-140139 5 301000ND13301390
1,2-Dibromoethane (EDB)ug/L 1000 127 60-140135 6 301000ND12701350
1,2-Dichlorobenzene ug/L 1000 132 60-140132 0 301000ND13201320
1,2-Dichloroethane ug/L 1000 117 60-140123 5 301000ND11701230
1,2-Dichloropropane ug/L 1000 134 60-140138 3 301000ND13401380
1,3,5-Trimethylbenzene ug/L M1100013860-140141 2 301000ND13801410
1,3-Dichlorobenzene ug/L 1000 133 60-140131 1 301000ND13301310
1,3-Dichloropropane ug/L 1000 128 60-140133 3 301000ND12801330
1,4-Dichlorobenzene ug/L 1000 130 60-140130 0 301000ND13001300
2,2-Dichloropropane ug/L M1100014760-140152 3 301000ND14701520
2-Chlorotoluene ug/L 1000 132 60-140135 2 301000ND13201350
4-Chlorotoluene ug/L 1000 133 60-140135 2 301000ND13301350
Benzene ug/L 1000 131 60-140136 3 301000ND13101360
Bromobenzene ug/L 1000 133 60-140135 2 301000ND13301350
Bromochloromethane ug/L M1100013860-140146 6 301000ND13801460
Bromodichloromethane ug/L M1100013660-140142 4 301000ND13601420
Bromoform ug/L 1000 115 60-140121 6 301000ND11501210
Bromomethane ug/L 1000 126 60-140130 3 301000ND12601300
Carbon tetrachloride ug/L M1100014560-140150 3 301000ND14501500
Chlorobenzene ug/L 1000 127 60-140133 5 301000ND12701330
Chloroethane ug/L 1000 128 60-140133 4 301000ND12801330
Chloroform ug/L 1000 124 60-140126 2 301000ND12401260
Chloromethane ug/L 1000 126 60-140126 0 301000ND12601260
cis-1,2-Dichloroethene ug/L 1000 130 60-140136 5 301000ND13001360
cis-1,3-Dichloropropene ug/L 1000 137 60-140138 1 301000ND13701380
Dibromochloromethane ug/L 1000 119 60-140121 2 301000ND11901210
Dibromomethane ug/L 1000 128 60-140132 4 301000ND12801320
Dichlorodifluoromethane ug/L M1100015860-140162 3 301000ND15801620
Diisopropyl ether ug/L 1000 126 60-140131 4 301000ND12601310
Ethylbenzene ug/L 1000 128 60-140134 5 301000ND12801340
Hexachloro-1,3-butadiene ug/L M1100014760-140147 0 301000ND14701470
Isopropylbenzene (Cumene)ug/L 1000 136 60-140138 2 301000ND13601380
m&p-Xylene ug/L 2000 131 60-140135 3 302000ND26102690
Methyl-tert-butyl ether ug/L 1000 65 60-14077 2 301000561062606390
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2318347MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92390233010
2318348
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methylene Chloride ug/L 1000 128 60-140130 1 301000ND12801300
n-Butylbenzene ug/L M1100014460-140144 0 301000ND14401440
n-Propylbenzene ug/L M1100013860-140141 1 301000ND13801410
Naphthalene ug/L 1000 136 60-140139 2 301000ND13601390
o-Xylene ug/L 1000 131 60-140137 4 301000ND13101370
sec-Butylbenzene ug/L M1100014260-140142 0 301000ND14201420
Styrene ug/L 1000 130 60-140135 4 301000ND13001350
tert-Butylbenzene ug/L 1000 120 60-140120 0 301000ND12001200
Tetrachloroethene ug/L 1000 124 60-140125 1 301000ND12401250
Toluene ug/L 1000 128 60-140131 2 301000ND12901330
trans-1,2-Dichloroethene ug/L 1000 134 60-140139 3 301000ND13401390
trans-1,3-Dichloropropene ug/L M1100013860-140143 4 301000ND13801430
Trichloroethene ug/L 1000 136 60-140139 2 301000ND13601390
Trichlorofluoromethane ug/L M1100014660-140149 2 301000ND14601490
Vinyl chloride ug/L M1100014860-140149 0 301000ND14801490
1,2-Dichloroethane-d4 (S)%97 70-13099
4-Bromofluorobenzene (S)%98 70-13097
Toluene-d8 (S)%100 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
417967
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92390768002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2317143
Associated Lab Samples:92390768002
Matrix:Water
AnalyzedMDL
1,2,3-Trichloropropane ug/L <0.049 0.049 07/06/18 14:350.049
1,2-Dibromo-3-chloropropane ug/L <0.049 0.049 07/06/18 14:350.049
1,2-Dibromoethane (EDB)ug/L <0.020 0.020 07/06/18 14:350.020
1-Chloro-2-bromopropane (S)%108 70-130 07/06/18 14:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2317144LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2317145
1,2,3-Trichloropropane ug/L 0.27.25 107 70-1301050.26 2 20
1,2-Dibromo-3-chloropropane ug/L 0.24.25 96 70-130910.23 5 20
1,2-Dibromoethane (EDB)ug/L 0.24.25 96 70-130960.24 0 20
1-Chloro-2-bromopropane (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 23
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92390768
Eskimo Joe's
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
418528
EPA 504.1
EPA 504.1
GCS 504 EDB DBCP
Associated Lab Samples:92390768001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2319946
Associated Lab Samples:92390768001
Matrix:Water
AnalyzedMDL
1,2,3-Trichloropropane ug/L <0.049 0.049 07/11/18 16:000.049
1,2-Dibromo-3-chloropropane ug/L <0.049 0.049 07/11/18 16:000.049
1,2-Dibromoethane (EDB)ug/L <0.020 0.020 07/11/18 16:000.020
1-Chloro-2-bromopropane (S)%102 70-130 07/11/18 16:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2319947LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2319948
1,2,3-Trichloropropane ug/L 0.28.25 112 70-1301280.31 12 20
1,2-Dibromo-3-chloropropane ug/L 0.24.25 98 70-1301120.28 12 20
1,2-Dibromoethane (EDB)ug/L 0.24.25 98 70-1301120.28 12 20
1-Chloro-2-bromopropane (S)%110 70-130124
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2319949MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92390943001
2319950
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,3-Trichloropropane ug/L .25 123 65-135105 16 20.25ND 0.30 0.26
1,2-Dibromo-3-
chloropropane ug/L .25 103 65-13589 14 20.25ND 0.25 0.22
1,2-Dibromoethane (EDB)ug/L .25 101 65-13594 7 20.25ND 0.25 0.23
1-Chloro-2-bromopropane
(S)%109 70-13099
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92390949001
2319951SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L <0.049 20ND
1,2-Dibromo-3-chloropropane ug/L <0.049 20ND
1,2-Dibromoethane (EDB)ug/L 0.20 2 200.20
1-Chloro-2-bromopropane (S)%138 S25142
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 23
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92390768
Eskimo Joe's
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery not evaluated against control limits due to sample dilution.S4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 23
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92390768
Eskimo Joe's
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92390768001 418528 418636MW-1 EPA 504.1 EPA 504.1
92390768002 417967 417993MW-2 EPA 504.1 EPA 504.1
92390768001 418201MW-1 SM 6200B
92390768002 418201MW-2 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 07/12/2018 12:15 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 23
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