WS-4762_15503_CA_MRP_20140830

08/21/14
Technical Report for
GRI (Geological Resources Inc.)
Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
15543
Accutest Job Number: FA17353
Sampling Date: 08/11/14
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail];
ATTN: Angela Roach
Total number of pages in report:
Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001)
DoD ELAP (L-A-B L2229), CA (04226CA), TX (T104704404), PA (68-03573), VA (460177),
AK, AR, GA, KY, MA, NV, OK, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Southeast
08/21/14
e-Hardcopy 2.0
Automated Report
28
Accutest Laboratories is the sole authority for authorizing edits or modifications to this
document. Unauthorized modification of this report is strictly prohibited.
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FA17353
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA17353-1: MW-3 ........................................................................................................6
Section 4: Misc. Forms ............................................................................................................11
4.1: Chain of Custody ...........................................................................................................12
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................15
5.1: Method Blank Summary ................................................................................................16
5.2: Blank Spike Summary ...................................................................................................17
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................18
Section 6: GC Volatiles - QC Data Summaries .....................................................................19
6.1: Method Blank Summary ................................................................................................20
6.2: Blank Spike/Blank Spike Duplicate Summary ..............................................................21
6.3: Duplicate Summary .......................................................................................................22
Section 7: GC Semi-volatiles - QC Data Summaries ............................................................23
7.1: Method Blank Summary ................................................................................................24
7.2: Blank Spike Summary ...................................................................................................26
7.3: Blank Spike/Blank Spike Duplicate Summary ..............................................................27
7.4: Duplicate Summary .......................................................................................................28 12345672 of 28
FA17353
Accutest Laboratories
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA17353
Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Project No: 15543
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA17353-1 08/11/14 16:29 CB 08/13/14 AQ Ground Water MW-3
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FA17353 1
Summary of Hits Page 1 of 1
Job Number:FA17353
Account:GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Collected:08/11/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA17353-1 MW-3
Naphthalene a 218 50 30 ug/l MADEP VPH REV 1.1
C9- C12 Aliphatics (Unadj.) a 9020 E 1000 350 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics (Unadj.) a 10300 E 1000 350 ug/l MADEP VPH REV 1.1
C9- C12 Aliphatics a 9020 E 1000 350 ug/l MADEP VPH REV 1.1
C9- C10 Aromatics a 10300 E 1000 350 ug/l MADEP VPH REV 1.1
Acenaphthene 6.8 3.8 1.9 ug/l MADEP EPH REV 1.1
Acenaphthylene 5.9 3.8 1.9 ug/l MADEP EPH REV 1.1
Fluorene 8.4 3.8 1.9 ug/l MADEP EPH REV 1.1
2-Methylnaphthalene 7.4 3.8 1.9 ug/l MADEP EPH REV 1.1
Naphthalene 16.6 3.8 1.9 ug/l MADEP EPH REV 1.1
Phenanthrene 4.7 3.8 1.9 ug/l MADEP EPH REV 1.1
C11-C22 Aromatics (Unadj.)2930 190 140 ug/l MADEP EPH REV 1.1
C11-C22 Aromatics 2880 190 140 ug/l MADEP EPH REV 1.1
C9-C18 Aliphatics 9150 940 470 ug/l MADEP EPH REV 1.1
C19-C36 Aliphatics 2170 190 94 ug/l MADEP EPH REV 1.1
(a) Results from vial(s) are not consistent due to sample non-homogeneity; higher results were reported.
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FA17353 2
Accutest Laboratories
Sample Results
Report of Analysis
Southeast
Section 3
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FA17353 3
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FA17353-1 Date Sampled:08/11/14
Matrix:AQ - Ground Water Date Received:08/13/14
Method:SM 6200B Percent Solids:n/a
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E032620.D 1 08/19/14 EG n/a n/a VE1090
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
Purgeable Aromatics, Full List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.10 ug/l
108-90-7 Chlorobenzene ND 0.50 0.10 ug/l
108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l
100-41-4 Ethylbenzene ND 0.50 0.10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
108-88-3 Toluene ND 0.50 0.10 ug/l
1330-20-7 Xylene (total)ND 1.5 0.20 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 109%70-130%
17060-07-0 1,2-Dichloroethane-D4 118%70-130%
2037-26-5 Toluene-D8 79%70-130%
460-00-4 4-Bromofluorobenzene 132%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA17353 33.1
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FA17353-1 Date Sampled:08/11/14
Matrix:AQ - Ground Water Date Received:08/13/14
Method:MADEP VPH REV 1.1 Percent Solids:n/a
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a UV065482.D 10 08/19/14 AH n/a n/a GUV3474
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 10 10 ug/l
100-41-4 Ethylbenzene ND 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 20 10 ug/l
91-20-3 Naphthalene 218 50 30 ug/l
108-88-3 Toluene ND 20 10 ug/l
m,p-Xylene ND 40 20 ug/l
95-47-6 o-Xylene ND 20 10 ug/l
C5- C8 Aliphatics (Unadj.)ND 1000 350 ug/l
C9- C12 Aliphatics (Unadj.)9020 1000 350 ug/l E
C9- C10 Aromatics (Unadj.)10300 1000 350 ug/l E
C5- C8 Aliphatics ND 1000 350 ug/l
C9- C12 Aliphatics 9020 1000 350 ug/l E
C9- C10 Aromatics 10300 1000 350 ug/l E
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 99%70-130%
460-00-4 BFB 100%70-130%
(a) Results from vial(s) are not consistent due to sample non-homogeneity; higher results were reported.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA17353 33.1
Accutest Laboratories
Report of Analysis Page 1 of 1
Client Sample ID:MW-3
Lab Sample ID:FA17353-1 Date Sampled:08/11/14
Matrix:AQ - Ground Water Date Received:08/13/14
Method:EPA 610 EPA 610 Percent Solids:n/a
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a EE086208.D 20 08/19/14 NAF 08/18/14 OP52736 GEE3109
Run #2
Initial Volume Final Volume
Run #1 1050 ml 1.0 ml
Run #2
BN PAH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 38 15 ug/l
208-96-8 Acenaphthylene ND 38 15 ug/l
120-12-7 Anthracene ND 38 15 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 0.76 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 0.76 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 0.76 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 0.76 ug/l
218-01-9 Chrysene ND 38 7.6 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 0.76 ug/l
206-44-0 Fluoranthene b ND 76 76 ug/l
86-73-7 Fluorene ND 38 15 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 0.76 ug/l
91-20-3 Naphthalene ND 38 15 ug/l
90-12-0 1-Methylnaphthalene ND 38 7.6 ug/l
91-57-6 2-Methylnaphthalene ND 38 7.6 ug/l
85-01-8 Phenanthrene ND 38 15 ug/l
129-00-0 Pyrene ND 38 7.6 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 0% c 43-122%
92-94-4 p-Terphenyl 0% c 30-122%
(a) Dilution required due to matrix interference.
(b) Elevated MDL due to matrix interference.
(c) Outside control limits due to dilution.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA17353 33.1
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FA17353-1 Date Sampled:08/11/14
Matrix:AQ - Ground Water Date Received:08/13/14
Method:MADEP EPH REV 1.1 SW846 3510C Percent Solids:n/a
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN010193.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
Run #2 NN010215.D 5 08/20/14 NAF 08/14/14 OP52712 GNN440
Run #3 a NN010225.D 1 08/20/14 NAF 08/14/14 OP52712 GNN440
Run #4 a NN010223.D 5 08/20/14 NAF 08/14/14 OP52712 GNN440
Initial Volume Final Volume
Run #1 1060 ml 2.0 ml
Run #2 1060 ml 2.0 ml
Run #3 1060 ml 2.0 ml
Run #4 1060 ml 2.0 ml
MAEPH List
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene 6.8 3.8 1.9 ug/l
208-96-8 Acenaphthylene 5.9 3.8 1.9 ug/l
120-12-7 Anthracene ND 3.8 1.9 ug/l
56-55-3 Benzo(a)anthracene ND 3.8 1.9 ug/l
50-32-8 Benzo(a)pyrene ND 3.8 1.9 ug/l
205-99-2 Benzo(b)fluoranthene ND 3.8 1.9 ug/l
191-24-2 Benzo(g,h,i)perylene ND 3.8 1.9 ug/l
207-08-9 Benzo(k)fluoranthene ND 3.8 1.9 ug/l
218-01-9 Chrysene ND 3.8 1.9 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 3.8 1.9 ug/l
206-44-0 Fluoranthene ND 3.8 1.9 ug/l
86-73-7 Fluorene 8.4 3.8 1.9 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 3.8 1.9 ug/l
91-57-6 2-Methylnaphthalene 7.4 3.8 1.9 ug/l
91-20-3 Naphthalene 16.6 3.8 1.9 ug/l
85-01-8 Phenanthrene 4.7 3.8 1.9 ug/l
129-00-0 Pyrene ND 3.8 1.9 ug/l
C11-C22 Aromatics (Unadj.)2930 190 140 ug/l
C11-C22 Aromatics 2880 190 140 ug/l
C9-C18 Aliphatics 9150 b 940 470 ug/l
C19-C36 Aliphatics 2170 190 94 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Run# 3 Limits
3386-33-2 1-Chlorooctadecane 71%69%72%40-140%
580-13-2 2-Bromonaphthalene 97%97%64%40-140%
84-15-1 o-Terphenyl 74%74%49%40-140%
321-60-8 2-Fluorobiphenyl 91%88%52%40-140%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA17353 33.1
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FA17353-1 Date Sampled:08/11/14
Matrix:AQ - Ground Water Date Received:08/13/14
Method:MADEP EPH REV 1.1 SW846 3510C Percent Solids:n/a
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
MAEPH List
CAS No.Compound Result RL MDL Units Q
(a) Confirmation run.
(b) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA17353 33.1
Accutest Laboratories
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Southeast
Section 4
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FA17353 4
FA17353: Chain of Custody
Page 1 of 3
12 of 28
FA17353 44.1
FA17353: Chain of Custody
Page 2 of 3
13 of 28
FA17353 44.1
FA17353: Chain of Custody
Page 3 of 3
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FA17353 44.1
Accutest Laboratories
GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 5
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FA17353 5
Method Blank Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1090-MB E032613.D 1 08/19/14 EG n/a n/a VE1090
The QC reported here applies to the following samples:Method: SM 6200B
FA17353-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.10 ug/l
108-90-7 Chlorobenzene ND 0.50 0.10 ug/l
108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l
100-41-4 Ethylbenzene ND 0.50 0.10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
108-88-3 Toluene ND 0.50 0.10 ug/l
1330-20-7 Xylene (total)ND 1.5 0.20 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 105%70-130%
17060-07-0 1,2-Dichloroethane-D4 113%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
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FA17353 55.1.1
Blank Spike Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1090-BS E032611.D 1 08/19/14 EG n/a n/a VE1090
The QC reported here applies to the following samples:Method: SM 6200B
FA17353-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.4 104 70-130
108-90-7 Chlorobenzene 10 11.6 116 70-130
108-20-3 Di-Isopropyl ether 10 9.6 96 70-130
541-73-1 m-Dichlorobenzene 10 12.6 126 70-130
95-50-1 o-Dichlorobenzene 10 12.5 125 70-130
106-46-7 p-Dichlorobenzene 10 11.4 114 70-130
100-41-4 Ethylbenzene 10 10.9 109 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.4 94 70-130
91-20-3 Naphthalene 10 11.7 117 70-130
108-88-3 Toluene 10 10.2 102 70-130
1330-20-7 Xylene (total)30 35.6 119 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 110%70-130%
2037-26-5 Toluene-D8 93%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
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FA17353 55.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA17416-1MS E032623.D 1 08/19/14 EG n/a n/a VE1090
FA17416-1MSD E032624.D 1 08/19/14 EG n/a n/a VE1090
FA17416-1 a E032615.D 1 08/19/14 EG n/a n/a VE1090
The QC reported here applies to the following samples:Method: SM 6200B
FA17353-1
FA17416-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 3.0 10 12.9 99 10 11.1 81 15 70-130/20
108-90-7 Chlorobenzene ND 10 10.6 106 10 9.3 93 13 70-130/20
108-20-3 Di-Isopropyl ether ND 10 8.4 84 10 7.3 73 14 70-130/20
541-73-1 m-Dichlorobenzene ND 10 11.4 114 10 9.8 98 15 70-130/20
95-50-1 o-Dichlorobenzene ND 10 11.3 113 10 9.6 96 16 70-130/20
106-46-7 p-Dichlorobenzene ND 10 10.2 102 10 8.8 88 15 70-130/20
100-41-4 Ethylbenzene 13.9 10 24.8 109 10 21.4 75 15 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 10 8.1 81 10 7.0 70 15 70-130/20
91-20-3 Naphthalene 6.1 10 16.1 100 10 14.1 80 13 70-130/20
108-88-3 Toluene 0.33 J 10 9.4 91 10 8.2 79 14 70-130/20
1330-20-7 Xylene (total)2.1 30 28.9 89 30 24.8 76 15 70-130/20
CAS No.Surrogate Recoveries MS MSD FA17416-1 Limits
1868-53-7 Dibromofluoromethane 93%91%106%70-130%
17060-07-0 1,2-Dichloroethane-D4 90%88%116%70-130%
2037-26-5 Toluene-D8 94%95%87%70-130%
460-00-4 4-Bromofluorobenzene 104%104%105%70-130%
(a) Confirmation run.
* = Outside of Control Limits.
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FA17353 55.3.1
Accutest Laboratories
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 6
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FA17353 6
Method Blank Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUV3474-MB UV065480.D 1 08/19/14 AH n/a n/a GUV3474
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA17353-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 86%70-130%
460-00-4 BFB 87%70-130%
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FA17353 66.1.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
GUV3474-BS UV065477.D 1 08/19/14 AH n/a n/a GUV3474
GUV3474-BSD UV065478.D 1 08/19/14 AH n/a n/a GUV3474
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA17353-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene 80 73.6 92 79.1 99 7 70-130/25
100-41-4 Ethylbenzene 80 74.0 93 79.2 99 7 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 77.2 97 83.6 105 8 70-130/25
91-20-3 Naphthalene 80 75.7 95 80.3 100 6 70-130/25
108-88-3 Toluene 80 73.3 92 79.0 99 7 70-130/25
m,p-Xylene 160 150 94 161 101 7 70-130/25
95-47-6 o-Xylene 80 72.4 91 77.7 97 7 70-130/25
C5- C8 Aliphatics (Unadj.)240 273 114 291 121 6 70-130/25
C9- C12 Aliphatics (Unadj.)160 158 99 171 107 8 70-130/25
C9- C10 Aromatics (Unadj.)80 74.8 94 79.0 99 5 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 103%111%70-130%
460-00-4 BFB 100%101%70-130%
* = Outside of Control Limits.
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FA17353 66.2.1
Duplicate Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA17495-1DUP UV065485.D 1 08/19/14 AH n/a n/a GUV3474
FA17495-1 UV065481.D 1 08/19/14 AH n/a n/a GUV3474
The QC reported here applies to the following samples:Method: MADEP VPH REV 1.1
FA17353-1
FA17495-1 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA17495-1 Limits
460-00-4 BFB 98%94%70-130%
460-00-4 BFB 96%95%70-130%
* = Outside of Control Limits.
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FA17353 66.3.1
Accutest Laboratories
GC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 7
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FA17353 7
Method Blank Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP52736-MB a EE086171.D 1 08/18/14 NAF 08/18/14 OP52736 GEE3108
The QC reported here applies to the following samples:Method: EPA 610
FA17353-1
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 2.0 0.80 ug/l
208-96-8 Acenaphthylene ND 2.0 0.80 ug/l
120-12-7 Anthracene ND 2.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 0.20 0.040 ug/l
50-32-8 Benzo(a)pyrene ND 0.20 0.040 ug/l
205-99-2 Benzo(b)fluoranthene ND 0.20 0.040 ug/l
191-24-2 Benzo(g,h,i)perylene ND 0.20 0.040 ug/l
207-08-9 Benzo(k)fluoranthene ND 0.20 0.040 ug/l
218-01-9 Chrysene ND 2.0 0.40 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 0.20 0.040 ug/l
206-44-0 Fluoranthene ND 2.0 0.40 ug/l
86-73-7 Fluorene ND 2.0 0.80 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 0.20 0.040 ug/l
91-20-3 Naphthalene ND 2.0 0.80 ug/l
90-12-0 1-Methylnaphthalene ND 2.0 0.40 ug/l
91-57-6 2-Methylnaphthalene ND 2.0 0.40 ug/l
85-01-8 Phenanthrene ND 2.0 0.80 ug/l
129-00-0 Pyrene ND 2.0 0.40 ug/l
CAS No.Surrogate Recoveries Limits
84-15-1 o-Terphenyl 74%43-122%
92-94-4 p-Terphenyl 76%30-122%
(a) Insufficient sample for MS/MSD.
24 of 28
FA17353 77.1.1
Method Blank Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP52712-MB NN010186.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA17353-1
CAS No.Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)ND 200 150 ug/l
C11-C22 Aromatics ND 200 150 ug/l
C9-C18 Aliphatics ND 200 100 ug/l
C19-C36 Aliphatics ND 200 100 ug/l
CAS No.Surrogate Recoveries Limits
3386-33-2 1-Chlorooctadecane 72%40-140%
580-13-2 2-Bromonaphthalene 90%40-140%
84-15-1 o-Terphenyl 81%40-140%
321-60-8 2-Fluorobiphenyl 88%40-140%
25 of 28
FA17353 77.1.2
Blank Spike Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP52736-BS EE086172.D 1 08/18/14 NAF 08/18/14 OP52736 GEE3108
The QC reported here applies to the following samples:Method: EPA 610
FA17353-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
83-32-9 Acenaphthene 20 15.3 77 49-108
208-96-8 Acenaphthylene 20 16.5 83 54-110
120-12-7 Anthracene 10 8.3 83 58-112
56-55-3 Benzo(a)anthracene 10 8.5 85 63-107
50-32-8 Benzo(a)pyrene 10 8.3 83 62-111
205-99-2 Benzo(b)fluoranthene 10 8.6 86 62-109
191-24-2 Benzo(g,h,i)perylene 10 8.7 87 63-110
207-08-9 Benzo(k)fluoranthene 10 8.7 87 61-109
218-01-9 Chrysene 10 9.0 90 66-113
53-70-3 Dibenzo(a,h)anthracene 10 8.6 86 62-111
206-44-0 Fluoranthene 20 16.6 83 57-110
86-73-7 Fluorene 20 15.7 79 55-109
193-39-5 Indeno(1,2,3-cd)pyrene 10 8.5 85 62-109
91-20-3 Naphthalene 20 13.6 68 46-103
90-12-0 1-Methylnaphthalene 20 14.6 73 47-106
91-57-6 2-Methylnaphthalene 20 13.3 67 47-105
85-01-8 Phenanthrene 20 16.5 83 58-111
129-00-0 Pyrene 20 16.6 83 59-110
CAS No.Surrogate Recoveries BSP Limits
84-15-1 o-Terphenyl 81%43-122%
92-94-4 p-Terphenyl 86%30-122%
* = Outside of Control Limits.
26 of 28
FA17353 77.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP52712-BS NN010184.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
OP52712-BSD NN010185.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA17353-1
Spike BSP BSP BSD BSD Limits
CAS No.Compound ug/l ug/l %ug/l %RPD Rec/RPD
83-32-9 Acenaphthene 100 66.7 67 70.7 71 6 40-140/30
208-96-8 Acenaphthylene 100 66.4 66 72.8 73 9 40-140/30
120-12-7 Anthracene 100 77.0 77 81.7 82 6 40-140/30
56-55-3 Benzo(a)anthracene 100 84.2 84 88.8 89 5 40-140/30
50-32-8 Benzo(a)pyrene 100 84.4 84 89.0 89 5 40-140/30
205-99-2 Benzo(b)fluoranthene 100 85.0 85 88.6 89 4 40-140/30
191-24-2 Benzo(g,h,i)perylene 100 82.0 82 86.3 86 5 40-140/30
207-08-9 Benzo(k)fluoranthene 100 83.1 83 88.7 89 7 40-140/30
218-01-9 Chrysene 100 85.1 85 90.0 90 6 40-140/30
53-70-3 Dibenzo(a,h)anthracene 100 84.7 85 89.6 90 6 40-140/30
206-44-0 Fluoranthene 100 81.2 81 85.4 85 5 40-140/30
86-73-7 Fluorene 100 69.3 69 74.5 75 7 40-140/30
193-39-5 Indeno(1,2,3-cd)pyrene 100 84.3 84 88.6 89 5 40-140/30
91-57-6 2-Methylnaphthalene 100 42.2 42 65.9 66 44*40-140/30
91-20-3 Naphthalene 100 52.8 53 57.4 57 8 40-140/30
85-01-8 Phenanthrene 100 77.3 77 82.1 82 6 40-140/30
129-00-0 Pyrene 100 83.5 84 87.7 88 5 40-140/30
C11-C22 Aromatics (Unadj.)1700 1440 85 1560 92 8 40-140/30
C9-C18 Aliphatics 600 341 57 359 60 5 40-140/30
C19-C36 Aliphatics 800 493 62 532 67 8 40-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
3386-33-2 1-Chlorooctadecane 68%73%40-140%
580-13-2 2-Bromonaphthalene 92%90%40-140%
84-15-1 o-Terphenyl 73%78%40-140%
321-60-8 2-Fluorobiphenyl 87%85%40-140%
Sample Compound Col #1 Col #2 Breakthrough Limit
OP52712-BS 2-Methylnaphthalene 42.2 19.9 32.0%*5.0
OP52712-BS Naphthalene 52.8 4.8 8.3%*5.0
OP52712-BSD 2-Methylnaphthalene 65.9 ND 0.0%5.0
OP52712-BSD Naphthalene 57.4 ND 0.0%5.0
* = Outside of Control Limits.
27 of 28
FA17353 77.3.1
Duplicate Summary Page 1 of 1
Job Number:FA17353
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Doris McDonald; 5023 Woody Mill Rd, Julian, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP52712-DUP NN010192.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
FA17352-1 NN010191.D 1 08/18/14 NAF 08/14/14 OP52712 GNN439
The QC reported here applies to the following samples:Method: MADEP EPH REV 1.1
FA17353-1
FA17352-1 DUP
CAS No.Compound ug/l Q ug/l Q RPD Limits
83-32-9 Acenaphthene ND ND nc 30 a
208-96-8 Acenaphthylene ND ND nc 30 a
120-12-7 Anthracene ND ND nc 30 a
56-55-3 Benzo(a)anthracene ND ND nc 30 a
50-32-8 Benzo(a)pyrene ND ND nc 30 a
205-99-2 Benzo(b)fluoranthene ND ND nc 30 a
191-24-2 Benzo(g,h,i)perylene ND ND nc 30 a
207-08-9 Benzo(k)fluoranthene ND ND nc 30 a
218-01-9 Chrysene ND ND nc 30 a
53-70-3 Dibenzo(a,h)anthracene ND ND nc 30 a
206-44-0 Fluoranthene ND ND nc 30 a
86-73-7 Fluorene ND ND nc 30 a
193-39-5 Indeno(1,2,3-cd)pyrene ND ND nc 30 a
91-57-6 2-Methylnaphthalene ND ND nc 30 a
91-20-3 Naphthalene ND ND nc 30 a
85-01-8 Phenanthrene ND ND nc 30 a
129-00-0 Pyrene ND ND nc 30 a
C11-C22 Aromatics (Unadj.)ND ND nc 30 a
C11-C22 Aromatics ND ND nc 30 a
C9-C18 Aliphatics ND ND nc 30 a
C19-C36 Aliphatics ND ND nc 30 a
CAS No.Surrogate Recoveries DUP FA17352-1 Limits
3386-33-2 1-Chlorooctadecane 61%55%40-140%
580-13-2 2-Bromonaphthalene 86%88%40-140%
84-15-1 o-Terphenyl 68%69%40-140%
321-60-8 2-Fluorobiphenyl 84%84%40-140%
(a) Advisory control limits.
* = Outside of Control Limits.
28 of 28
FA17353 77.4.1