5802_Madison_MSWLF_Oct22GW_FID1786953_20230413

DENRUSEONLY.J ❑Paper Report ❑Electronic Data-EmailCD(data loaded: Yes/No) Doc/Event#:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reaortina Form
Notice: Th isform and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC2Lgroundwater standards or NC213surface water standards. Then otification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, p re -existing
condition, etc.).
Attach a notification table of any groundwater orsurface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas l evel s. This includes any structures on or nearby the
facility (NCAC13B.1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Chuck Pippin Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual samplingdates(e.g.,
Facilityname: Faci I ityAd dress: Facility Permit# (.0500or.1600) 0 cto ber 20-24, 2006)
Madison County Closed Solid 389 Long Branch Road 58-02 .0500 October 10 & 12, 2022
Waste Facility Marshall, NC 28753
Environmental Status: (Check all that apply)
Initial/Background Monitoring Q Detecti o n Mo nitori ng Assessment Monitoring Corrective Action
T e of data submitted: (Check all that apply)
X Groundwater monitoringdatafrommonitoring wells Methane gas monitoringdata
Groundwater monitoring datafrom private water supplywells ❑ Corrective action data (specify)
Leach ate monitoringdata Other(specifv
X Surface water mo n itoring d ata
Notification attached?
No. No groundwater o rsurface water standards were exceeded.
X Yes, a notification of values exceeding a g roundwateror surface water standard isattached. Itincludes a listof groundwaterand surfacewater
monitoring points, dates, analytical values, NC 21-groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis ofth a cause and significance of any concentration.
El Yes, a notification of values exceeding an explosive methanegas limit is attached. It includesthe methane monitoring points, dates, sample
values and explosive methanegas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, orcertification includingthe possibility of a fine and imprisonment.
Chuck Pippin, P.G. Project Manager
Fad Iity Represen Title
Signature
231 Haywood Street Asheville, North Carolina 28801
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
828-281-3350
(Area
04/07/2023
Date
) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
Revised 6/2009

,i . r �- .,.k■sue. IddF
/
a _
March 2023
Madison County Closed Solid Waste Management Facility, Permit No. S8-02
Fall 2022
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

March 2023
Madison County Closed Solid Waste Management Facility, Permit No. 58-02
Fall 2022
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
Chuck Pippi
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Mayers, Staff Scientist
Project Number: C01500-01.01
\\WCL-FS1\Asheville\Projects\Madison County\-Reports\2022\02_Fall 2022\58-02_Closed\Deliverables\b_DEQ Submittal\5802_Madison
Closed -October 2022 Semiannual Water Quality Report.docx

TABLE OF CONTENTS
1 Introduction
2 Methods
1
2
2.1 Monitoring Well Sampling Methods...........................................................................................................2
2.1.1 Monitoring Well BG SPRING OLD.................................................................................................2
2.1.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD ........... 2
2.2 Surface Water Sampling Methods................................................................................................................3
2.3 Sample Handling, Documentation, and Analysis....................................................................................3
3 Findings........................................................................................................................................5
3.1 Groundwater.........................................................................................................................................................5
3.1.1 Field Parameters..................................................................................................................................6
3.1.2 RCRA Metals..........................................................................................................................................6
3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................6
3.2 Surface Water.......................................................................................................................................................7
3.2.1 Field Parameters..................................................................................................................................7
3.2.2 RCRA Metals..........................................................................................................................................8
3.2.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................8
3.3 Site Hydrogeology..............................................................................................................................................8
4 Summary......................................................................................................................................9
4.1 Future Activities...................................................................................................................................................9
5 References
TABLES
Table 1
Table 2
FIGURES
Figure 1
Figure 2
Summary of Laboratory Analyses Performed on Samples
Summary of Detected Constituents
Site Location Map
Sample Location Map
10
Fall 2022 Semiannual
Water Quality Monitoring Report i March 2023

APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data
Sheets
Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation
Fall 2022 Semiannual
Water Quality Monitoring Report ii March 2023

ABBREVIATIONS
µg/L
micrograms per liter
µmhos/cm
micromhos per centimeter
Closed Landfill
closed municipal solid waste landfill
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
DWM
Division of Waste Management
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentration
MDL
method detection limit
mg/L
milligrams per liter
MRL
method reporting limit
mV
millivolt
NCAC
North Carolina Administrative Code
NTU
nephelometric turbidity unit
ORP
oxidation-reduction potential
PVC
polyvinyl chloride
RCRA
Resource Conservation and Recovery Act
SC
specific conductivity
SU
standard unit
SWS
Solid Waste Section
TOC
top of well casing
VOC
volatile organic compound
Waypoint
Waypoint
Laboratories, Inc.
Fall 2022 Semiannual
Water Quality Monitoring Report iii March 2023

1 Introduction
The Madison County Solid Waste Department maintains a closed municipal solid waste landfill
(Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road
(State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1.
The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ)
Division of Waste Management (DWM), under Permit No. 58-02 (the permit), which requires
semiannual monitoring of groundwater and surface water quality. This report, prepared by
Anchor QEA of North Carolina, PLLC (Anchor QEA), is being submitted in accordance with monitoring
requirements for the Closed Landfill as stipulated in the permit, with regulations codified in the DEQ
Solid Waste Management Rules, Title 15A, Subchapter 13B, Section.1600 of the North Carolina
Administrative Code (15A North Carolina Administrative Code [NCAC] 1313.1600).
This report describes the second semiannual groundwater and surface water quality monitoring
event performed in 2022. The water quality monitoring network for the Closed Landfill consists of
four monitoring wells (MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background
groundwater quality sampling location (BG SPRING OLD), and two surface water sampling locations
(SW-01 OLD [upstream] and SW-02 OLD [downstream]) located along Profitt Branch (Figure 2).
Monitoring wells MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the
western part of the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower
elevations within topographic drainages in the southern part of the landfill parcel and are screened
in the upper saturated zone.
The water sample collected from background sampling location BG SPRING OLD is treated as a
groundwater sample for the following reasons:
• Groundwater does not discharge to the ground surface at the sampling point.
• Construction of the sampling point is similar to that of a temporary monitoring well and is
located upslope and upgradient of a springhead.
• The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground
surface with a screened interval from which groundwater is collected and recharges.
Attempts to contact Mrs. J.V. Edwards (99 Long Branch Road, Marshall, North Carolina) have been
unsuccessful, resulting in Anchor QEA personnel not collecting a sample from the residential well
(DW-01 OLD) during the fall 2022 sampling event. Anchor QEA will coordinate with Madison County
to ensure contact with the Edwards family for the spring 2023 sampling event; however, assistance
from the DEQ may be required to collect a groundwater sample from DW-01 OLD. The last time it
was sample was in 2018.
Fall 2022 Semiannual
Water Quality Monitoring Report 1 March 2023

2 Methods
On October 10 and 12, 2022, Anchor QEA collected five groundwater samples from the monitoring
wells (including background well BG SPRING OLD) and two surface water samples from the
established surface water locations. Sampling locations are shown in Figure 2. Water level
measurements, field parameters, and observations pertaining to water quality are included in the
sampling logs in Appendix A.
2.1 Monitoring Well Sampling Methods
Prior to groundwater sample collection from the monitoring wells, the static water level was
measured and recorded to calculate the volume of water within the well.
At each sample location, an initial round of field parameters (consisting of pH, specific conductivity
[SC], dissolved oxygen [DO], oxidation-reduction potential [ORP], turbidity, and temperature) were
measured and recorded. Water level measurements, field parameters, and observations pertaining to
water quality are included in the sampling logs in Appendix A.
2. 7.7 Monitoring Well BG SPRING OLD
Due to poor well access, which inhibited the use of pump, controller, and associated tubing for
purging the well, sampling point BG SPRING OLD was purged using a new disposable polyethylene
bailer. Following initial field parameter collection, as each consecutive well volume was removed with
the bailer, a round of groundwater field parameters was recorded.
The well was purged until a minimum of three well volumes had been removed and field parameters
had stabilized, or until the well had been bailed dry. All groundwater samples were collected by a
technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into
laboratory -supplied sample containers.
2. 7.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and
MW-04 OLD
Monitoring wells MW-01 OLD and MW-02 OLD were purged and sampled with a peristaltic pump.
Monitoring wells MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump.
These wells were purged using low -flow techniques in accordance with the procedures described in
Low -Flow (Minimal Drowdown) Ground -Water Sampling Procedures (Pull and Barcelona 1996).
During purging, pH, SC, DO, ORP, turbidity, and temperature were measured and recorded
approximately every 3 minutes. Well purging continued until these parameters had stabilized for
three consecutive readings. The following required stabilization criteria have been established by the
Fall 2022 Semiannual
Water Quality Monitoring Report 2 March 2023

U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division
Operating Procedure: Groundwater Sampling (EPA SESD 2017):
• pH values within ± 0.1 unit
• SC values within ± 5%
• Temperature, DO, and turbidity values within ± 10%
Following stabilization of these parameters, a groundwater sample was collected by a technician
wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into
laboratory -supplied sample containers.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 OLD and SW-02 OLD are collected semiannually at designated
locations along Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a
westerly direction (Figure 2). The surface water sample collected at the SW-01 OLD location is
interpreted to represent surface water quality upstream of the Closed Landfill, and the surface water
sample collected at the SW-02 OLD location is interpreted to represent surface water quality
downstream of the Closed Landfill.
For the samples SW-01 OLD and SW-02 OLD, field parameters, including temperature, pH, SC, DO,
ORP, and turbidity were measured and recorded at the surface water sampling location prior to
sample collection (Appendix A). One surface water sample was collected and transferred into
laboratory -supplied sample containers by a technician wearing a new pair of non -reactive nitrile gloves.
2.3 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to water quality sampling at the
Closed Landfill sampling locations are provided in the sampling logs in Appendix A.
Following sample collection, groundwater and surface water samples were immediately placed on ice
in sample coolers for transport to Waypoint Laboratories, Inc. (Waypoint), a laboratory certified in
North Carolina and located in Charlotte, North Carolina.
Anchor QEA submitted all collected groundwater and surface water samples to Waypoint for the
following analyses:
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260D
- Appendix I parameters are identified in Appendix I of the Code of Federal Regulations,
Title 40, Part 258 (40 Code of Federal Regulations 258).
• 1,4-dioxane, using EPA Method 8260DSIM
Fall 2022 Semiannual
Water Quality Monitoring Report 3 March 2023

• Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6020B
and 7470A
— In addition to this "totals" metal analysis, if the associated turbidity was measured at a
value that exceeded 10 nephelometric turbidity units (NTU), the laboratory was
requested to filter the associated sample, run the metals analysis, and report the
dissolved metal concentrations (in addition to the total metals analysis)
• Hardness, using EPA method SM2340C-2011; surface water samples only
A summary of laboratory analyses performed on the samples is provided in Table 1. Two trip blanks
for groundwater and two trip blanks for surface water, provided by the laboratory and stored in the
sample cooler, were analyzed for Appendix I VOCs. Proper chain -of -custody documentation
procedures were followed during collection and transport of each sample. The laboratory analytical
reports and chain -of -custody documentation are included in Appendix B.
Fall 2022 Semiannual
Water Quality Monitoring Report 4 March 2023

3 Findings
The field parameter data and laboratory analytical results for the groundwater, surface water, and
trip blank samples collected at the Closed Landfill are included in Appendices A and B. Results are
also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable format (DEQ 2020).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections are values reported by the laboratory as "below method
detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The MDL is the
minimum concentration of a substance that can be measured and reported by a laboratory
with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "J" Qualified: A "J" qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that
can be accurately determined by the referenced method.
• Groundwater Quality Standards: Detected concentrations of constituents in groundwater
samples were compared to applicable North Carolina groundwater quality standards. For
most constituents, this standard is the 2L standard, defined in 15A NCAC 02L. 0202. Detected
concentrations of analytes in groundwater with no established 2L standard were compared to
the interim maximum allowable concentrations (IMAC) for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L.0202).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 2 summarizes the field parameter results and laboratory analytical results for detected
constituents. The following discussion outlines constituents detected at concentrations that
exceeded their respective groundwater quality standards or 2B standards.
3.1 Groundwater
The following sections summarize the results of field parameter and laboratory analyses of
groundwater samples collected on October 10 and 12, 2022.
Fall 2022 Semiannual
Water Quality Monitoring Report 5 March 2023

3.1.7 Field Parameters
A summary of the field parameter measurements follows (Table 2):
• pH: The pH readings obtained from monitoring wells MW-01 OLD (6.1 standard units [SUs]),
MW-02 OLD (6.4 SU), MW-03 OLD (6.3 SU), MW-04 OLD (6.3 SU), and BG SPRING OLD
(6.0 SU) were lower than the range for pH (6.5 to 8.5 SU) specified in the 2L standard (Table 2).
• Turbidity: Turbidity in the monitoring wells ranged from 11.6 NTU in monitoring well
MW-03 OLD to 37.0 NTU in MW-01 OLD.
• DO: Measured DO values ranged from 0.35 milligrams per liter (mg/L) in MW-01 OLD to
7.41 mg/L in MW-04 OLD.
• SC: SC values ranged from 164.5 micromhos per centimeter (pmhos/cm) in BG SPRING OLD to
939 pmhos/cm in MW-03 OLD.
• ORP: ORP values in the monitoring wells ranged from -53.1 millivolts (mV) in MW-03 OLD to
83.0 mV in MW-04 OLD. These parameters do not have established groundwater quality
standards.
The field parameters measured for this sampling event are generally consistent with historical data.
3. 7.2 RCRA Metals
Five metals (arsenic, barium, cadmium, chromium, and lead) were detected in groundwater samples
collected from one or more monitoring wells (Table 2). Only one of these metals, barium, was
detected at concentrations that exceeded its associated groundwater protection standard of
700 micrograms per liter (pg/L).
The exceedance occurred in the sample collected from MW-03 OLD (785 pg/L). Laboratory findings
indicate concentrations of barium have decreased since the spring 2022 sampling event. In spring
2022, barium exceedances were reported at a concentration of 869 pg/L in MW-03 OLD. In fall 2021,
a barium exceedance was reported in MW-03 OLD at a concentration of 830 pg/L.
Samples collected from MW-01 OLD, MW-02 OLD, MW-03 OLD, MW-04 OLD, and BG SPRING OLD
were analyzed for laboratory -filtered metals due to turbidity readings of greater than 10 NTU. In the
samples collected and analyzed for dissolved metals, concentrations were generally less than the
total metal concentration, and no detections were reported at concentrations that exceeded their
associated 2L standard.
3.1.3 Appendix 1 VOCs and 1,4-Dioxane
Eleven VOCs (1,1-dichloroethane, cis-1,2-dichloroethene, trans-1,2-dichloroethene,
1,2-dichloropropane, 1,4-dioxane, benzene, chlorobenzene, chloroethane, vinyl chloride,
1,2-dichlorobenzene, and 1,4-dichlorobenzene) were detected in groundwater samples collected
Fall 2022 Semiannual
Water Quality Monitoring Report 6 March 2023

from one or more of the Site monitoring wells (Table 2). Of the detected compounds, two
(1,4-dioxane and vinyl chloride) were detected at concentrations that exceeded their associated
groundwater quality standard. 1,4-dioxane was detected in monitoring well MW-01 OLD at a
concentration of 3.43 pg/L, above its 2L standard of 3 pg/L. Vinyl chloride was detected in
monitoring well MW-01 OLD at a concentration of 0.769 pg/L, which exceeded its 2L standard of
0.03 pg/L.
The VOC detections in MW-01 OLD are generally consistent with recent historical data:
• Spring 2022 sampling event
- Vinyl chloride was detected at a concentration of 0.307 pg/L.
- 1,4-Dioxane was detected at a concentration of 2.70 pg/L.
• Fall 2021 sampling event
- Vinyl chloride was detected at a concentration of 1.05 pg/L.
- 1,4-Dioxane was detected at a concentration of 6.47 pg/L.
• Spring 2021 sampling event
- Vinyl chloride was detected at a concentration of 0.717 pg/L.
- 1,4-Dioxane was detected at a concentration of 2.16 pg/L.
3.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 OLD and SW-02 OLD.
3.2.7 Field Parameters
A summary of the field parameter measurements follows:
• pH: The pH readings collected from SW-01 OLD and SW-02 OLD were 6.9 and 7.3 SU,
respectively. The readings were within the 2B standard range established at 6 to 9 SU.
• Turbidity: The turbidity readings collected from SW-01 OLD and SW-02 OLD were 3.29 and
1.71 NTU, respectively. The readings were within the 2B standard established at less than
50 NTU.
• DO: DO readings collected from SW-01 OLD and SW-02 OLD were 5.81 and 8.87 mg/L,
respectively. The values are within the 2B standard for Class C waters (greater than or equal to
5 mg/L).
• SC: The SC measurements in SW-01 OLD and SW-02 OLD were recorded at 221.8 and
202.5 pmhos/cm, respectively. These parameters do not have established surface water
quality standards.
• ORP: The ORP values for SW-01 OLD and SW-02 OLD samples were recorded at 68.6 and
82.7 mV (Table 2), respectively. These parameters do not have established surface water
quality standards.
Fall 2022 Semiannual
Water Quality Monitoring Report 7 March 2023

3.2.2 RCRA Metals
Three metals (barium, chromium, and lead) were detected in the surface water samples. The only
detection that exceeded 2B standards in either of the surface water samples was reported in
SW-01 OLD. Lead was detected at a concentration of 2.27 pg/L in SW-01 OLD, which exceeded the
calculated hardness -dependent 2B standard (1.25 pg/L). SW-01 OLD is in the upstream location.
Lead has been detected in previous sampling events for the SW-01 OLD location:
• Spring 2022 sampling event
— Lead was estimated at a concentration of 0.572 J pg/L
• Fall 2021 sampling event
— Lead was not detected above detection limit, 0.260 U pg/L
• Spring 2021 sampling event
— Lead was estimated at a concentration of 0.467 J pg/L
3.2.3 Appendix 1 VOCs and 1,4-Dioxane
The samples collected from both surface water locations and analyzed for Appendix I VOCs and
1,4-dioxane reported no analytes were detected at concentrations greater than the MDLs or
applicable surface water protection standards.
3.3 Site Hydrogeology
Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD,
MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 6.31, 7.99, 45.52, and 46.69 feet
below the top of the well casing (TOC), respectively (Appendix A).
The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit
an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the
shallow groundwater is interpreted to generally mimic topography, flowing primarily southward
toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an
elevation of approximately 2,100 feet above mean sea level and slopes downward toward
Profitt Branch.
Fall 2022 Semiannual
Water Quality Monitoring Report 8 March 2023

4 Summary
Anchor QEA completed the second semiannual water quality monitoring event of 2022 at the
Closed Landfill on October 10 and 12, 2022. Table 1 summarizes the sampling and analyses that were
performed. Table 2, the field sampling logs (Appendix A), and the Waypoint Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and
surface water quality at the Closed Landfill. The following is a summary of the results from the
sampling event:
• Groundwater
- The detected concentration of barium (785 pg/L) exceeded the associated 2L standard
of 700 pg/L in the sample collected from MW-03 OLD. No other sample locations
exceeded 2L standards for metals.
- VOCs that exceeded 2L groundwater standards include the following:
• 1,4-dioxane (3.43 pg/L) was detected in the sample collected from MW-01 OLD
at a concentration exceeding its associated groundwater quality standard
(2L standards) of 3 pg/L.
• Vinyl chloride (0.769 pg/L) was detected in the sample collected from
MW-01 OLD at a concentration exceeding its associated groundwater quality
standard (2L standards) of 0.03 pg/L.
- The measured depths to groundwater in the upper saturated zone within the
topographic drainages at the landfill ranged from 6.31 to 7.99 feet below TOC. The
groundwater depths in the bedrock monitoring wells at the top of the ridge ranged
from 45.52 to 46.69 feet below TOC. The shallow groundwater is interpreted to
generally mimic topography, flowing primarily southward toward Profitt Branch.
• Surface Water
- The detected concentration of lead (2.27 pg/L) exceeded the calculated hardness -
dependent 2B standard of 1.25 pg/L in the sample collected from upstream location
SW-01 OLD. No VOCs were detected in the surface water samples.
4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater and surface water monitoring points associated with the Closed Landfill. Water quality
samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and
Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled
for March 2023.
Fall 2022 Semiannual
Water Quality Monitoring Report 9 March 2023

5 References
Anchor QEA (Anchor QEA of North Carolina, PLLC), 2021 a. Fall 2027 Semiannual Water Quality
Monitoring Report. Prepared for Madison County, North Carolina. February 2022.
Anchor QEA, 2021 b. Spring 2027 Semiannual Water Quality Monitoring Report. Prepared for Madison
County, North Carolina. May 2021.
Anchor QEA, 2022. Spring 2022 Semiannual Water Quality Monitoring Report. Prepared for Madison
County, North Carolina. June 2022.
DEQ (North Carolina Department of Environmental Quality), 2020. Memorandum to Solid Waste
Facility Owners and Operators/SW Directors/County Managers/Consultants/Laboratories.
Regarding: New Electronic Data Deliverable (EDD) Format. July 20, 2020.
EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017.
Operating Procedure: Groundwater Sampling. April 26, 2017.
Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling
Procedures. Prepared for the U.S. Environmental Protection Agency Office of Solid Waste and
Emergency Response. EPA/540/5-95/504. April 1996.
Fall 2022 Semiannual
Water Quality Monitoring Report 10 March 2023

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Facility Permit
Well ID
Collection Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
58-02
MW-01OLD
1011012022
MW-01-OLD-20221010
X
X
X1
58-02
MW-02 OLD
10/10/2022
MW-02-OLD-20221010
X
X
X'
58-02
MW-03 OLD
10/12/2022
MW-03-OLD-20221012
X
X
X1
58-02
MW-04 OLD
10/12/2022
MW-04-OLD-20221012
X
X
X'
58-02
BG SPRING OLD
10/10/2022
BG-Spring-OLD-20221010
X
X
X1
Surface Water Samples
Facility Permit
Location ID
Collection Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
Total Hardness
EPA 8260D
EPA 8260D SIM
EPA 6020B
EPA 7470A
EPA SM 2340C-
2011
58-02
SW-01 OLD
10/10/2022
SW-01-OLD-20221010
X
X
X
X
58-02
SW-02 OLD
10/10/2022
SW-02-OLD-20221010
X
X
X
X
Quality Control
Samples
Facility Permit
ID
Collection Date
Sample ID
Appendix I VOCs
EPA 8260D
58-02
TRIP BLANK
10/10/2022
TB-MW-OLD-20221010-1
X
58-02
TRIP BLANK
10/10/2022
TB-SW-OLD-20221010-1
X
58-02
TRIP BLANK
10/10/2022
TB-SW-OLD-20221010-2
X
58-02
TRIP BLANK
10/12/2022
TB-MW-OLD-20221012
X
Notes:
Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258).
A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event.
1. Additional sample for lab -filtered metals analysis was collected due to turbidity.
EPA: U.S. Environmental Protection Agency
RCRA: Resource Conservation and Recovery Act
SM: standard method
SIM: selective ion monitoring
VOC: volatile organic compound
Fall 2022 Semiannual Water Quality Monitoring Report Page 1 of 1
Madison County Closed Solid Waste Management Facility, Permit No. 58-02 March 2023

Table 2
Summary of Detected Constituents
Location ID
Sample ID
Sample Date
Sample Type
Matrix
X
Y
NC2L
Method NC21- IMAC NC213
Groundwater
Samples
Surface Water
Samples
QC Sample
QC Sample
BG SPRING OLD
MW-01 OLD
MW-02 OLD
MW-03 OLD
MW-04 OLD
SW-01 OLD
SW-02 OLD
Field QC - Groundwater
Field QC - Surface Water
BG-Spring-OLD-
20221010
MW-01-OLD-
20221010
MW-02-OLD-
20221010
MW-03-OLD-
20221012
MW-04-OLD-
20221012
SW-01-OLD-
20221010
SW-02-OLD-
20221010
TB-MW-OLD-
20221010-1
TB-MW-
20221012
TB -SW -OLD-
20221010-1
TB -SW -OLD -
20221010-2
10/10/2022
10/10/2022
10/10/2022
10/12/2022
10/12/2022
10/10/2022
10/10/2022
10/10/2022
10/12/2022
10/10/2022
10/10/2022
N
N
N
N
N
N
N
TB
TB
TB
TB
WG
WG
WG
WG
WG
WS
WS
WQ
WQ
WQ
WQ
917884.7
917267.7
917989.3
917134.3
917135.2
918644.2
916592.4
--
--
--
--
768038.1
766244.6
765984.1
766754.9
766695.2
766458.9
766226.2
--
--
--
--
Field
Parameters
Water level depth (feet TOC)
Field measure
--
--
--
9.79
6.31
7.99
45.52
46.69
--
--
--
--
--
--
Temperature (°C)
Field measure
--
--
--
17
15.2
15.2
15.5
15.5
10.9
12.8
--
--
--
--
Dissolved oxygen (mg/L)
Field measure
--
--
<5.0
1.1
0.35
2.04
7.25
7.41
5.81
8.87
--
--
--
--
ORP (mV)
Field measure
--
--
--
73.3
-32.1
71.6
-53.1
83.0
68.6
82.7
--
--
--
--
Turbidity (NTU)
Field measure
--
--
<50
27.0
37.0
13.8
11.6
12.7
3.29
1.71
--
--
--
--
pH (SU)
Field measure
6.5-8.5
--
6.0-9.0
6.0
6.1
6.4
6.3
6.3
6.9
7.3
--
--
--
--
Specific conductivity (µmhos/cm)
Field measure
--
--
--
164.5
931
240
939
891
221.8
202.5
--
--
--
--
Other
(Ng/L)
Hardness as CaCO3 SM2340C-2011 -- -- 100 -- -- -- - -- 66 66 -- -- -- --
Metals (Ng/L)
Arsenic
SW6020B
10
--
10
0.490 U
0.671 J
0.490 U
0.297 U
0.297 U
0.490 U
0.490 U
--
--
--
--
Barium
SW6020B
700
--
21000
141
573
61.8
785
669
134
45.2
--
--
--
--
Cadmium
SW6020B
2
--
*0.26
0.150 U
0.150 U
0.150 U
0.350 U
0.559 J
0.150 U
0.150 U
--
--
--
--
Chromium
SW6020B
10
--
*44.06
4.82
1.00 U
1.00 U
1.73 U
1.73 U
4.16
1.00 U
--
--
--
--
Lead
SW6020B
15
--
*1.25
0.808 J
0.500 U
0.500 U
0.264 U
0.728 J
2.27
0.500 U
--
--
--
--
Metals, Dissolved (Ng/L)
Arsenic
SW6020B
10
--
10
0.490 U
0.490 U
0.490 U
0.297 U
0.297 U
0.17 U
0.17 U
--
--
--
--
Barium
SW6020B
700
--
21000
109
359
58.9
414
633
--
--
--
--
--
--
Cadmium
SW6020B
2
--
*0.26
0.150 U
0.150 U
0.150 U
0.350 U
0.529 J
--
--
--
--
--
--
Chromium
SW6020B
10
--
*44.06
1.00 U
1.00 U
1.00 U
0.346 U
0.346 U
--
--
--
--
--
--
Lead
SW6020B
15
--
* 1.25
0.500 U
0.500 U
0.500 U
0.264 U
0.264 U
--
--
--
--
--
--
Volatile
Organics (Ng/L)
1,1-dichloroethane
SW8260D
6
--
6
0.240 U
0.665
0.471 J
0.240 U
0.240 U
0.240 U
0.240 U
0.240 U
0.240 U
0.240 U
0.240 U
1,2-dichloroethene, cis-
SW8260D
70
--
60
0.200 U
3.27
0.200 U
0.200 U
0.200 U
0.200 U
0.200 U
0.200 U
0.200 U
0.200 U
0.200 U
1,2-dichloroethene, trans-
SW8260D
100
--
100
0.180 U
0.426 J
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
1,2-dichloropropane
SW8260D
0.6
--
0.9
0.190 U
0.486 J
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
1,4-dioxane
SW8260D
3
--
0.35
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
16.0 U
1,4-dioxane
SW8260DSIM
3
--
0.35
0.139 U
3.43
0.139 U
0.139 U
0.139 U
0.139 U
0.139 U
--
--
--
--
Benzene
SW8260D
1
--
1.19
0.180 U
0.73
0.180 U
0.636
0.208 J
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
0.180 U
Chlorobenzene
SW8260D
50
--
140
0.190 U
4.04
0.190 U
3.07
3.08
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
0.190 U
Chloroethane
SW8260D
3000
--
--
0.430 U
1.09
0.430 U
0.430 U
0.430 U
0.430 U
0.430 U
0.430 U
0.430 U
0.430 U
0.430 U
Dichloromethane (Methylene
chloride)
SW8260D
5
--
20
0.330 U
0.330 U
0.330 U
0.330 U
0.330 U
0.330 U
0.330 U
0.674 J
0.803 J
0.330 U
0.330 U
m,p-xylene
SW8260D
500
--
420
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
0.420 U
o-xylene
SW8260D
500
--
600
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
0.210 U
Toluene
SW8260D
600
--
0.36
1 0.220 U
0.239 J
0.220 U
1 0.837
0.288 J
0.220 U
0.220 U
0.220 U
0.220 U
0.220 U
0.220 U
Total xylene
I SW8260D
500
1
1 670
1 0.21 U
1 0.21 U
1 0.21 U
1 0.21 U
0.21 U
0.21 U
0.21 U
0.21 U
0.21 U
0.21 U
0.21 U
Vinyl chloride
I SW8260D
0.03
1
1 0.025
1 0.170 U
1 0.769
1 0.170 U
1 0.170 U
0.170 U
0.170 U
0.170 U
0.170 U
0.170 U
0.170 U
0.170 U
Fall 2022 Semiannual Water Quality Monitoring Report Page 1 of 2
Madison County Closed Solid Waste Mangaement Facility, Permit No. 58-02 March 2023

Table 2
Summary of Detected Constituents
Notes:
indicates detected concentration is greater than the NC2L (2022) or IMAC (2022) screening level.
indicates detected concentration is greater than the NC26 screening level.
All nondetect results are reported at the method detection limit.
Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (U.S. Survey Feet).
Bold indicates a detected result.
Italics indicate non -detected concentration is above one or more identified screening levels.
*: NC213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation per North Carolina Administrative Code, Title 15A: Department of Environmental Quality,
Subchapter 213 - Surface Water and Wetland Standards (last amended September 2022).
--: not sampled or not analyzed
pg/L: micrograms per liter
pmhos/cm: micromhos per centimeter
Appendix I: volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
CaCO3: calcium carbonate
IMAC: interim maximum allowable concentration (listed in 2L Appendix 1)
J: laboratory qualifier used to indicate a detection at estimated concentrations greater than the minimum detection limit but less than the laboratory's method reporting limit
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NC26: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 213 — Surface Water and Wetland Standards (last amended in September 2022) or the standard obtained from the U.S. Environmental Protection Agency Nationally
Recommended Water Quality Criteria for Aquatic Life and Human Health
NC2L: subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (amended April 1, 2022); groundwater standard from North Carolina Administrative Code, Title 15A
NTU: nephelometric turbidity unit
ORP: oxidation-reduction potential
SU: standard unit
TB: trip blank
TOC: top of casing
U: compound analyzed for but not detected above detection limit
WG: groundwater
WQ: water quality
WS: surface water
Fall 2022 Semiannual Water Quality Monitoring Report Page 2 of 2
Madison County Closed Solid Waste Management Facility, Permit No. 58-02 March 2023

Figures

s 1��� �-U, v/ p•� � a°i , (j! ��,iv
o a+I
D
-�� .r % ; 1, / (i_7\k
LI
21
i
s
• � od � O _ d
LEGEND: SOURCES:
Basemap: USGS 1:24,000 Scale Topo Maps,
Landfill Parcel Marshall Quadrangle, 1990
Parcels: Madison County GIS 0 2,000
Feet
Publish Date: 2023/01/18, 8:55 AM I User: alesueur
Filepath: \\orcas\gis\Jobs\MadisonCounty_NC_1500\Maps\MadisonCo_SemiannualWQFigures\MadisonCo_SemiannualWQFigures.aprx
kzANCHOR Figure 1
QEA—`'�`-' Site Location Map
Anchor QEA of North Carolina, PLLC
Semiannual Water Quality Monitoring Report
Madison County Closed Solid Waste Management Facility, Permit No. 58-02

n
7 ��
�.
Feet
LEGEND:
NOTE:
Monitoring Well Location
Landfill Parcel Boundary
y
Monitoring well and surface water sample locations are
approximate.
Residential Well Location (Not
Sampled in Fall 2022 because
Elevation Contours (10-Foot Interval)
SOURCES:
Roads
Owner Could Not be Contacted)
2018
Ooads:
- Surface Water Sample Location
Streams
n CIDO
Contours and Roads: NCDOT
Contours
Streams: INC OneMap
Parcel Boundary: Madison County GIS
Publish Date: 2023/02/01, 8:04 AM I User: alesueur
Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1500\Maps\MadisonCo_SemiannualWQFigures\MadisonCo_SemiannualWQFigures.aprx
j� ANCHOR Figure 2
1z QEA`'`'`% Sample Location Map
Anchor QEA of North Carolina, PLLC
Semiannual Water Quality Monitoring Report
Madison County Closed Solid Waste Management Facility, Permit No. 58-02

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

ANCHOR
..�► QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Equipment Documentation and Instrument Calibration Data Sheet
Project Name: Madison County Closed Landfill Analyst Conducting Calibration:
Project Number:CJJ 500-01.01 Task 02 Date of Calibration: (O ( 10 I Z 2.
Project Location: Marshall, NC Date of Field Measurements: (01101 Z2
Facility ID or Permit # (if applicable): 58-02
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Equipment Tvpe Brand Serial Number Date of Use Rental Company
Select Turbidimeter. Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Asheville, North Carolina 28801
Instrument Readings
Instrument Readings
(Hach 2100Q)
(HF Scientific MicroTPW)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
1, TU
10.0 NTU
TU
Lot #:
Expiration Date:
Cal (NTU): 20. O
Cal (NTU)ga-(v
Cal (NTU): ej U
O
Cal (NTU):
Cal
Cal (NTU):
Time:
Time:
Time: 9
Time:
Time
Time:
Calibration
*Pre -Analysis
Result (NTU):
Q(.
Time:
*Pre -Analysis
Result (NTU):
Time:
Verification•
Check (10 NTU):
1
0
�' �O
Check (1 U):
*Post -Analysis
Result (NTU):
7j
Time: i /�
'r 3
HISS
*Po - nalysis
Result (NTU):
Time:
Check (10 NTU):
{
Check (10 NTU):
YSI Professional Plus Multiparameter Meter (s/n 18B101802)
-
Cal St1i Information
Instrument Readings
Date
Lot #
Opened
Exp. ate
Dissolved Oxygen
Initial (%):
Cal (%):
mmHg:
Temperatu .(°C):
Time:
(% saturation)
Q
DO (Site #2,
Initial (%):
Cal (%):
mmHg:
Temperature (*C):
Time:
if applicall
QC** Check: DO
Time:
Result (%):
Time:
Result (%):
Time:
Result (%):
PH 7 S.U.
Initial:( Q
pHmV:
Cal (S.U.): n
pHmV: !`--
`2tD•
Time:
I
it 1
report to0.7S.U.
+• I
.)
v
0(rJ•Z
PH 4 S.U.
Initial: {{��
Li
pHmV:
��J�D•O
Cal (S.U.):
LA-0
pHmV: f
(o.
Time:
+C54
!GI
0$fn
report to0.7S.U.
( f
0q -q
01tZ5
PH 10 S.U.
Initial:
pHin!1�
Cal (S.UJ:
pHmV:
Time: Q'ZOG
t
LGZ
�2
report to 0.1 S.U.
l o
-�
c
r
�V
J
QC** pH 7 S.U.
Time:
I
Result S.U.):
Time:
Result (S.UIB m .):-J
l
t
3Al
o2 Pt2
bltZS
report to0.1S.U.
Q',.�`",
"I •®
�
O(3
Spec. Cond.
Initial:
1102.0
Cal (pmhos/cm):
1000
Time:
'�.�}
[�
C1
�q /�
V 0v
®
/7_2
I 01't l
1,000mhos/cm
t7'�
% Recove =
QC** Spec. Cond.
Time: U •2C.
Result (pmhos/cm):
Time:
2
Result (pmhos/cm):
Time:
Result (pmhos/cm):
ZGD
t/12-
011 rZ3
11
[
i t
t ®�
1,000 mhos/cm
% Recov =
OAP 200 mV
Initial;
Cal:
Temperature °C):
Time;
'LCT(
�10
c 3 z?_
03(2
Analyst Signature: Analyst Name: Date: ](3/IO1
Notes:
Revision 6, 12/20/20, MAK
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows : Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. *When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site prior to analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the
instrument needs to be recalibrated.
6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be
performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm . True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members
initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pm ho/cm = 1 pS/cm
Abbreviations:
Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units
Temperature: SM 2550 B-2010
°C: degrees Celsius ORP: oxidation reduction potential
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number
DO: SM 4500 O G-2011
mg/L: milligrams per liter S.U.: standard units
pH: SM 4500-H' B-2011
mV: millivolt Spec. Cond.: Specific Conductivity
Turbidity SM 2130 B-2011
ONM
lid'aM
Page 1 of 1

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Anchor QEA of North Carolina, PLLC
ANCHOR
QEA
231 Haywood Street
Asheville, North Carolina 28801
v-Flow Sampling Log
Well ID: MW-01 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
00-01.01 Task02
Marshall, NC
-:VI v `
2
N/A
20.8
; 3
TOC
17
Peristaltic Bladder
w at F oy i I 'ko'yQ
Date: a
Weather: tAl VJ
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): MW--01 OLD- a 0 Z Zit) Ib
in Arrive at Well: , V
ft bgs Start Time: 11,04
ft bgs Sample Time: �L
ft Leave Well: 114b
Well Type: KStick Up ❑Flush Mount
ft Tagged Bottom: j ft at (time):
Other (describe): Purge Rate: ZOO th L y'wt
o vv l u( ( e fir ,((, Total Volume Purged:
ntot t, Pump Speed: 2- .0. rk
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
(o
2
0
2
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1r
®
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`54
Sample Analyst Signature:
j
Sample Analyst
Name:
Date: \O' (OI ZZ
Notes: v
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit,' +/- 10 mV (or ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
..�, QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
v-Flow Sampling Log
Well ID: MW-02 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
QV500-01.01 Task 02
Marshall, NC
TM
2
N/A
43.4
,
TOC
40
Peristaltic Bladder
.PU-xy\p ©,.1 Q2- 8a : 101
i-- Ih riS a Oct 7J G
1
Date: '
Weather:
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): MW-02 OLD -
in Arrive at Well: bCJ IS
ft bgs Start Time: 09L41
ft bgs Sample Time: 1 ® 5
ft Leave Well:
Well Type: NStick Up ❑Flush Mount —1
ft Tagged Bottom: �) ft at (time):
Other (describe): Purge Rate: 1 5*5 +h� Mnr1
1 Total Volume Purged:
'" u.+rc,,e. 1�PXL& '° i SC)'W�.l. � rN.rv1 Pump Speed: '2 epivi
Time
DTW (feet)
Temperature ('C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(kmhos/cm)
pH (S.U.)
reportto 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
61 LfI
7D5,2
(0, a
1C
--s
,)qN
T
• ©
I y •
2 i 1
2-L40 2-
,2_
102 , 01
Z - Co
As
f%_1
1 e q
2_Lji_o
3
Ck1.5
to. 2
oq
2'B5
2L4©. q
15.+
Oq SCD
1 .3
t5-
Z
2-Lt.i
L]
e
tS....
n
Sq
l 5• 1
2.02.
-L40 .q
�
°.o 05
I. i o
t S. 2
Oq
21-10 . fl
i
t 3
Sample Analyst Signature:
Sample Analyst
Name:
Date:
r
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,' +/- 3% Conductivity' +/- 0.7 pH unit, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
NA, 9�-ls ('s,q SL1
e�D`bv 4- \?`AvAp s `26°1 y?,n
'A e (I e-A obi' S,s01 v e SOf°L/T (e Page 1 of 1

ZANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
v-Flow Sar+npling Log
Well ID: MW-03 OLD
Prof ct Name:
Project` Number:
Project Location:
Sample.Collector(s).
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
4 500-01.01 Task 02
Marshall, NC
S
2
44 - 49
49
e4 13
TOC
45
Peristaltic Bladder
vi ov`
Date:
Weather:
Facility ID or Permit # (if applicable):
Sample ID (on COC):
in Arrive at Well:
ft bgs Start Time:
ft bgs Sample Time:
ft Leave Well:
Well Type:
ft Tagged Bottom:
Other (describe):
o 3
58-02
MW-03 OLD- c�
11913
W' kv
KStick Up eFlush Mount
�y ft at (time): i
Purge Rate: -� ('`
Total Volume Purged:
Pump Speed:
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (m1)
Turbidity (NTU)
ID
L
�} . 0Cl
t CA Z "
t
`t 4
r
Q
,Q
I
l
` a
C
—4.
Uo LL19
,D
53
4`
t o \
i
i
Y(42
Sample Analyst Signature:
Sample Analyst
Name:
Date: 1 `� j j 2- j2_2.
d i
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,' +/- 3% Conductivity, +/- 0.7 pH unit, +/- 70 ml/for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
...71 QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
v-Flow Sampling Log
Well ID- MW-04 OLD
I O j Z.
Project Name:
Madison County Closed Landfill
Date:
�iolZ
Project Number:
00-01.01 Task02
Weather:
� . 0 ��n4
Project Location:
Marshall, NC
Facility ID or. Permit # (if applicable):
-02
_
Sample Collector(s):�b
Sample ID (on COC):
MW-04 OLD-Z�O
)
Well Diameter:
2
in
Arrive at Well:
Screen Interval:
70 - 90
ft bgs
Start Time:
Well Depth (as constructed):
90
Lpj
ft bgs
Sample Time:
r`� f'
Depth to Water:
,
Z
ft
Leave Well:
Measuring Point:
TOC
Well Type:
XStick Up
❑Flush Mount
Depth of Pump Intake:
80
ft
Tagged Bottom:
C'43, i�3 ft
at (time):
I.-)
Pump Used (circle):
Peristaltic
Bladder
Other (describe):
Purge Rate:
1Zv"L rh
Comments
CM
P - rj '
Total Volume Purged:
'Ivl
)ZOYV
F?�t 1;, 'Ot
Pump Speed:
. 2- .
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTW (feet)
Temperature (°C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (mV)
Turbidity (NTU)
®a
s
y2 Q
I I >J
1 713
90
e,.
ESH.
a 09
"-62
q 0
1.
a v�
09 ; Z-1
yF.. So
i5 .q
y y
- 2
--i°3
0 Cl IL LJ
4 6.1
I S. b
`3
�3 Ctt 5
G3 io
1 Ig - 2
o
�bqq
1
®
1-6, 4
mot- S5
ls. e>
b
L
�S
1y.
Gliq " -3
L9 "TO
L S. C
5 . q i
13
e2
0 11 1.
SD.Q 23
15. '
6"
169 S
29..-�>
�S.(-
)
zq.
z.0
°.4 LA
t"�-5
Z4
`�3afi
2 0
13..
©q' ti
. i
)5-5
L41
tAl
(13-3-o
I2.q
Sample Analyst
Sample Analyst Signature:
Name:
1 i 1
Date:
Notes: V
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity,, +/- 0.7 pH unit,' +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
°C: degrees Celsius
S.U.: standard units
pmhos/cm: micromhos per centimeter
ft: feet
mg/L: milligrams per liter
in: inches
mV: millivolt
bgs: below ground surface
NTU: nephelometric turbidity units
TOC: top of casing
� C I () / [0/ 2'2 -- �p OY--, Q i'3 ". 2.4 (np"'A1.'
`Q h
(� s ��-
Page
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
D0: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Turbidity: SM 2130 B-2011
1 of 1

ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well Sampling Log
Well ID: BG SPRING OLD
Project Name:
Madison County Closed Landfill Date:
4 110 a 4
Project Number:
C21500-01.01 Task 02 Weather:
'lo(�,((� L�
Project Location:
Marshall, NC Facility ID or Permit # (if applicable):
58-02
Sample Collector(s)
1 � Sample ID (on COC):
BG SPRING OLD- ao 0 l n f C�
Well Diameter:
2 in Sample Time:
: l.[ ii 0
Screen Interval:
N/A ft bgs
Measuring Point:
TOC Well Depth (WD):
14.3 ft TOC
Well Type:
AStick Up ❑Flush Mount Water Level in Feet (WL):
% ft TOC
Comments:
+— Length of Water Column (LWQ: 4 ft; (WD - WL)
viciJ
--wa
One Casing Volume:
0, �, �� gallons; (LWC x WCV)
Three Casing Volumes: gallons
J
Actual Volume Purged:
gallons
Tagged Bottom:
ft at (time): Three Casing Volumes:
gallons
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Maw., 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft
8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft
Purge Method:
I-Sailer-Dispi
Bailer-Disp Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Other:
Sample Method:
Bailer -Teflon Dedicated Pump Whale Pump Grundfos
Other:
Oxidation
Dissolved
Specific
pH (S.U.)
Reduction
Gallons
Temperature
Oxygen
Conductivity
reportto 0.1
Potential'
Turbidity
Reading
Time
Purged
CQ
(mg/L)
(pmhos/cm)
S.U.
(mv
(NTU)
Comments
1
IS
S
s 2
qC-1
Ll
IS0.11
t-
1 3
i
4
r
f
it 5
!
1
t 7r
6
7
8
9
10
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
_
}}
I
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing
Pad: Lock: Vegetation: Acces
Sample Analysts Sample
Analysts
Signature:
Name:
Date:
(Votes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,
+/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996
(Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still
legible, followed by the staff members initials and date
l
3. Samples are analyzed immediately upon collection.
j .f
4. NC Field Laboratory Certificate Number 5445 � tt e d
�l
�' I
Abbreviations:
Method Reference: uj,po
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
C
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
J
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
.�► QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-01 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Comments:
Madison County Closed Landfill
CV 500-01.01 Task 02
Marshall, INC
,
Upstream of landfill
Date:
Weather:
Facility ID or Permit # (if applicable):
Sample ID (on COQ
101 1 -R O A A
0��
58-02
SW-01 OLD- 2 0 2 -2
Sample Method (circle
one):
Grab Syringe
Pump
Bailer-Disp.
Other:
Time
Temperature
VC)
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
3.�9
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
2
RCRA Metals, Hardness
125 mL Plastic
40 mL Glass
6
App I VOCs, 1,4-Dioxane
1 L Glass
Other
!� c ,om t k d o ugh &v caw 0
Vegetation: "� lJ�` J Access: yt) IL k
Sample Analyst Sample Analyst Signatu �� _na 0 Name: -f "} 1' f � Vj�/ /�
' � i i�.,r Date:
Notes: �r�
1. Documentation errors are to be crossed out with a sinale line, so the oriainal text is still legible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
4lJ c I, I q U VI
Page 1 of 1

kZANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-02 OLD
Project Name:
Project Number:
Project Location:
Sample Collector(s):
Comments:
Madison County Closed Landfill
C11500-01.01 Task 02
Marshall, NC
S"
Downstream of landfill
Date: i0/ 10 (-12
Weather: '�-O "it i Ib e Sl<i e S
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): SW-02 OLD- 2012 IDi 0
0 v GtG;�
�+�'C� I k I I +-a nu (oVIA
Sample Method (circle
one):
Grab Syringe
Pump Bailer-Disp. Other:
Time
Temperature
CQ
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
i5"Zi5
2-,
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
2
6
250 mL Plastic
RCRA Metals, Hardness
125 mL Plastic
40 mL Glass
App I VOCs, 1,4-Dioxane
1 L Glass
Other
Vegetation: Access: V-)5kIk-eA 'I'IYt k u,�q � f g(l -}j
v 'OerA - ►lu acy`Psi—
Sample Analyst
Sample Analyst Signature: I Name: J i Date: 101 hf -ZZ
1. Documentation errors are to be crossed out with a single line, so the original text is still leoible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter
DO: SM 4500 O G-2011
mv: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

Appendix B
Report of Laboratory Analysis and
Chain -of -Custody Documentation

Waypointo
ANALYTICAL
11 /3/2022
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville, NC, 28801
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 22-286-0101
Client Project Description: Madison County Closed Landfill
C21500-01.01, WA-1
Site: 58-02
Project Number: 58-02
Dear Chuck Pippin:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 10/13/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a,j
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 30

0
Waypoint.
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2022
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00016/22-286-0101
Page 2 of 30

Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Sample Summary Table
Report Number: 22-286-0101
Client Project Description: Madison County Closed Landfill
C215OO-01.01, WA-1
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
90649
MW-03-OLD-20221012
Aqueous
10/12/2022
10:51
10/13/2022
11:35
90649
MW-03-OLD-20221012
Aqueous
10/12/2022
10:51
10/13/2022
11:35 6020B WP MTN
90650
MW-04-OLD-20221012
Aqueous
10/12/2022
09:47
10/13/2022
11:35
90650
MW-04-OLD-20221012
Aqueous
10/12/2022
09:47
10/13/2022
11:35 6020E WP MTN
90651
Trip Blank-MW-20221012
Aqueous
10/12/2022
10/13/2022
11:35
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 30

Waypoint.(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Summary of Detected
Project: Madison County Closed Landfill
Report Number: 22-286-0101
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
MW-03-OLD-20221
V 90649
6020B
Barium
6020B
Dissolved Barium
8260D
Benzene
8260D
Chlorobenzene
8260D
1,4-Dichlorobenzene
MW-04-OLD-20221
V 90650
6020B
Barium
6020B
Dissolved Barium
6020B
Cadmium
6020B
Dissolved Cadmium
6020B
Lead
8260D
Benzene
8260D
Chlorobenzene
8260D
1,4-Dichlorobenzene
Trip
V 90651
131ank-MW-2022101
8260D
Methylene Chloride
785
pq/L
0.453
10/29/202215:52
414
Ng/L
0.453
10/29/202214:39
0.636
uq/L
0.180
10/19/2022 02:49
3.07
Ng/L
0.190
10/19/2022 02:49
1.42
pq/L
0.210
10/19/2022 02:49
669
Ng/L
0.453
10/29/202215:57
633
uq/L
0.453
10/29/202214:44
0.559
Ng/L
0.350
10/29/202215:57 J
0.529
uq/L
0.350
10/29/202214:44 J
0.728
Ng/L
0.264
10/29/202215:57 J
0.208
uq/L
0.180
10/19/2022 03:12 J
3.08
Ng/L
0.190
10/19/2022 03:12
1.26
pq/L
0.210
10/19/2022 03:12
0.803
Ng/L 0.330 10/19/2022 00:29 J
Page 4 of 30

Waypointo
ANALYTICAL
Client: Anchor QEA of North Carolina, PLLC
Project: Madison County Closed Landfill
Lab Report Number: 22-286-0101
Date: 11 /2/2022
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
Metals Analyses Method 6020B
Sample 90649 (MW-03-OLD-20221012)
Analyte: Chromium
QC Batch No: L646083/L645354/L645353
One or more Internal Standards are outside method acceptance criteria. Re -analysis and/or sample dilutions are
required.
Sample 90650 (MW-04-OLD-20221012)
Analyte: Chromium
QC Batch No: L646083/L645354/L645353
One or more Internal Standards are outside method acceptance criteria. Re -analysis and/or sample dilutions are
required.
Volatile Organic Compounds - GUMS Method 8260D
Analyte: 2-Butanone
QC Batch No: V25309/V25308
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Acetone
QC Batch No: V25309/V25308
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Bromoform
QC Batch No: V25309/V25308
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Carbon Disulfide
QC Batch No: V25309/V25308
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Carbon Tetrachloride
QC Batch No: V25309/V25308
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: trans-1,4-Dichloro-2-butene
QC Batch No: V25309/V25308
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Page 5 of 30

Waypointo
ANALYTICAL
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Analyte: trans-1,4-Dichloro-2-butene
QC Batch No: V25309/V25308
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 6 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101
REPOR T OF A NA L YSIS
Lab No : 90649
Matrix:
Aqueous
Sample ID: MW-03-OLD-20221012
Sampled: 10/12/2022 10:51
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
10/14/22 15:01
TBL
8260D SIM
Arsenic
<0.297
ug/L
0.297
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Arsenic
<0.297
Ng/L
0.297
1.00
1
10/29/22 14:39
BKN
6020E
Barium
785
ug/L
0.453
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Barium
414
Ng/L
0.453
1.00
1
10/29/22 14:39
BKN
6020E
Cadmium
<0.350
ug/L
0.350
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Cadmium
<0.350
Ng/L
0.350
1.00
1
10/29/22 14:39
BKN
6020E
Chromium
<1.73
ug/L
1.73
5.00
5
11/02/22 01:43
CPW
6020B
Dissolved Chromium
<0.346
Ng/L
0.346
1.00
1
10/29/22 14:39
BKN
6020E
Lead
<0.264
ug/L
0.264
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Lead
<0.264
Ng/L
0.264
1.00
1
10/29/22 14:39
BKN
6020E
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
10/20/22 18:00
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
10/24/22 16:09
EDV
7470A
Selenium
<0.703
ug/L
0.703
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Selenium
<0.703
Ng/L
0.703
1.00
1
10/29/22 14:39
BKN
6020E
Silver
<0.0570
ug/L
0.0570
1.00
1
10/29/22 15:52
BKN
6020B
Dissolved Silver
<0.0570
Ng/L
0.0570
1.00
1
10/29/22 14:39
BKN
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90649
Matrix: Aqueous
Sample ID: MW-03-OLD-20221012
Sampled:
10/12/2022 10:51
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
10/19/22 02:49
MSA
V25309
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
10/19/22 02:49
MSA
V25309
Benzene
0.636
N9/L
0.180
0.500
1
10/19/22 02:49
MSA
V25309
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
10/19/22 02:49
MSA
V25309
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
10/19/22 02:49
MSA
V25309
Bromoform
<1.50
u9/L
1.50
5.00
1
10/19/22 02:49
MSA
V25309
Bromomethane
<0.280
N9/L
0.280
1.00
1
10/19/22 02:49
MSA
V25309
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
10/19/22 02:49
MSA
V25309
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
10/19/22 02:49
MSA
V25309
Chlorobenzene
3.07
u9/L
0.190
0.500
1
10/19/22 02:49
MSA
V25309
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
10/19/22 02:49
MSA
V25309
Chloroethane
<0.430
u9/L
0.430
1.00
1
10/19/22 02:49
MSA
V25309
Chloroform
<0.220
N9/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
Chloromethane
<0.220
u9/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
10/19/22 02:49
MSA
V25309
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
10/19/22 02:49
MSA
V25309
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
10/19/22 02:49
MSA
V25309
Dibromomethane
<0.230
u9/L
0.230
0.500
1
10/19/22 02:49
MSA
V25309
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
10/19/22 02:49
MSA
V25309
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
1,4-Dichlorobenzene
1.42
N9/L
0.210
0.500
1
10/19/22 02:49
MSA
V25309
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
10/19/22 02:49
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 8 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90649
Matrix: Aqueous
Sample ID: MW-03-OLD-20221012
Sampled:
10/12/2022 10:51
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/19/22 02:49
MSA
V25309
1,2-Dichloroethane
<0.150
pg/L
0.150
0.500
1
10/19/22 02:49
MSA
V25309
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/19/22 02:49
MSA
V25309
cis- 1,2-Dich loroethene
<0.200
pg/L
0.200
0.500
1
10/19/22 02:49
MSA
V25309
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/19/22 02:49
MSA
V25309
1,2-Dichloropropane
<0.190
pg/L
0.190
0.500
1
10/19/22 02:49
MSA
V25309
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/19/22 02:49
MSA
V25309
trans-1,3-Dichloropropene
<0.150
pg/L
0.150
0.500
1
10/19/22 02:49
MSA
V25309
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/19/22 02:49
MSA
V25309
Ethylbenzene
<0.170
pg/L
0.170
0.500
1
10/19/22 02:49
MSA
V25309
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/19/22 02:49
MSA
V25309
Methyl Ethyl Ketone (MEK)
<0.710
pg/L
0.710
5.00
1
10/19/22 02:49
MSA
V25309
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/19/22 02:49
MSA
V25309
Methylene Chloride
<0.330
pg/L
0.330
1.00
1
10/19/22 02:49
MSA
V25309
Styrene
<0.220
Ng/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
1,1,1,2-Tetrachloroethane
<0.160
pg/L
0.160
0.500
1
10/19/22 02:49
MSA
V25309
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 02:49
MSA
V25309
Tetrachloroethene
<0.220
pg/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/19/22 02:49
MSA
V25309
Toluene
<0.220
pg/L
0.220
0.500
1
10/19/22 02:49
MSA
V25309
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 02:49
MSA
V25309
1,1,2-Trichloroethane
<0.096
pg/L
0.096
0.500
1
10/19/22 02:49
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 9 of 30

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/13/2022
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90649 Matrix: Aqueous
Sample ID: MW-03-OLD-20221012 Sampled: 10/12/2022 10:51
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25308 10/18/22 14:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
101
Limits: 80-124%
108
Limits: 75-129%
92.8
Limits: 63-136%
97.4
Limits: 77-123%
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
1 10/19/22 02:49 MSA V25309
J Estimated value
Page 10 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101
REPOR T OF A NA L YSIS
Lab No : 90650
Matrix:
Aqueous
Sample ID: MW-04-OLD-20221012
Sampled: 10/12/2022 9:47
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
10/14/22 15:26
TBL
8260D SIM
Arsenic
<0.297
ug/L
0.297
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Arsenic
<0.297
Ng/L
0.297
1.00
1
10/29/22 14:44
BKN
6020E
Barium
669
ug/L
0.453
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Barium
633
Ng/L
0.453
1.00
1
10/29/22 14:44
BKN
6020E
Cadmium
0.5593
ug/L
0.350
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Cadmium
0.5293
Ng/L
0.350
1.00
1
10/29/22 14:44
BKN
6020E
Chromium
<1.73
ug/L
1.73
5.00
5
11/02/22 01:56
CPW
6020B
Dissolved Chromium
<0.346
Ng/L
0.346
1.00
1
10/29/22 14:44
BKN
6020E
Lead
0.728 J
ug/L
0.264
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Lead
<0.264
Ng/L
0.264
1.00
1
10/29/22 14:44
BKN
6020E
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
10/20/22 18:02
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
10/24/22 16:12
EDV
7470A
Selenium
<0.703
ug/L
0.703
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Selenium
<0.703
Ng/L
0.703
1.00
1
10/29/22 14:44
BKN
6020E
Silver
<0.0570
ug/L
0.0570
1.00
1
10/29/22 15:57
BKN
6020B
Dissolved Silver
<0.0570
Ng/L
0.0570
1.00
1
10/29/22 14:44
BKN
6020E
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 11 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90650
Matrix: Aqueous
Sample ID: MW-04-OLD-20221012
Sampled:
10/12/2022 9:47
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/19/22 03:12
MSA
V25309
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
10/19/22 03:12
MSA
V25309
Benzene
0.2083
N9/L
0.180
0.500
1
10/19/22 03:12
MSA
V25309
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
10/19/22 03:12
MSA
V25309
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
10/19/22 03:12
MSA
V25309
Bromoform
<1.50
u9/L
1.50
5.00
1
10/19/22 03:12
MSA
V25309
Bromomethane
<0.280
N9/L
0.280
1.00
1
10/19/22 03:12
MSA
V25309
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
10/19/22 03:12
MSA
V25309
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
10/19/22 03:12
MSA
V25309
Chlorobenzene
3.08
u9/L
0.190
0.500
1
10/19/22 03:12
MSA
V25309
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
10/19/22 03:12
MSA
V25309
Chloroethane
<0.430
u9/L
0.430
1.00
1
10/19/22 03:12
MSA
V25309
Chloroform
<0.220
N9/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
Chloromethane
<0.220
u9/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
10/19/22 03:12
MSA
V25309
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
10/19/22 03:12
MSA
V25309
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
10/19/22 03:12
MSA
V25309
Dibromomethane
<0.230
u9/L
0.230
0.500
1
10/19/22 03:12
MSA
V25309
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
10/19/22 03:12
MSA
V25309
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
1,4-Dichlorobenzene
1.26
N9/L
0.210
0.500
1
10/19/22 03:12
MSA
V25309
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
10/19/22 03:12
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 12 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90650
Matrix: Aqueous
Sample ID: MW-04-OLD-20221012
Sampled:
10/12/2022 9:47
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/19/22 03:12
MSA
V25309
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/19/22 03:12
MSA
V25309
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/19/22 03:12
MSA
V25309
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/19/22 03:12
MSA
V25309
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/19/22 03:12
MSA
V25309
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/19/22 03:12
MSA
V25309
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/19/22 03:12
MSA
V25309
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/19/22 03:12
MSA
V25309
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/19/22 03:12
MSA
V25309
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/19/22 03:12
MSA
V25309
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/19/22 03:12
MSA
V25309
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/19/22 03:12
MSA
V25309
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/19/22 03:12
MSA
V25309
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/19/22 03:12
MSA
V25309
Styrene
<0.220
Ng/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/19/22 03:12
MSA
V25309
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 03:12
MSA
V25309
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/19/22 03:12
MSA
V25309
Toluene
<0.220
ug/L
0.220
0.500
1
10/19/22 03:12
MSA
V25309
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 03:12
MSA
V25309
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/19/22 03:12
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 13 of 30

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/13/2022
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90650 Matrix: Aqueous
Sample ID: MW-04-OLD-20221012 Sampled: 10/12/2022 9:47
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25308 10/18/22 14:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
101
Limits: 80-124%
107
Limits: 75-129%
93.6
Limits: 63-136%
95.6
Limits: 77-123%
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
1 10/19/22 03:12 MSA V25309
J Estimated value
Page 14 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90651
Matrix: Aqueous
Sample ID: Trip Blank-MW-20221012
Sampled:
10/12/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
10/19/22 00:29
MSA
V25309
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
10/19/22 00:29
MSA
V25309
Benzene
<0.180
N9/L
0.180
0.500
1
10/19/22 00:29
MSA
V25309
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
10/19/22 00:29
MSA
V25309
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
10/19/22 00:29
MSA
V25309
Bromoform
<1.50
u9/L
1.50
5.00
1
10/19/22 00:29
MSA
V25309
Bromomethane
<0.280
N9/L
0.280
1.00
1
10/19/22 00:29
MSA
V25309
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
10/19/22 00:29
MSA
V25309
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
10/19/22 00:29
MSA
V25309
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
10/19/22 00:29
MSA
V25309
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
10/19/22 00:29
MSA
V25309
Chloroethane
<0.430
u9/L
0.430
1.00
1
10/19/22 00:29
MSA
V25309
Chloroform
<0.220
N9/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
Chloromethane
<0.220
u9/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
10/19/22 00:29
MSA
V25309
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
10/19/22 00:29
MSA
V25309
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
10/19/22 00:29
MSA
V25309
Dibromomethane
<0.230
u9/L
0.230
0.500
1
10/19/22 00:29
MSA
V25309
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
10/19/22 00:29
MSA
V25309
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
10/19/22 00:29
MSA
V25309
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
10/19/22 00:29
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 15 of 30

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/13/2022
Asheville , NC 28801
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90651
Matrix: Aqueous
Sample ID: Trip Blank-MW-20221012
Sampled:
10/12/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/19/22 00:29
MSA
V25309
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/19/22 00:29
MSA
V25309
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/19/22 00:29
MSA
V25309
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/19/22 00:29
MSA
V25309
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/19/22 00:29
MSA
V25309
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/19/22 00:29
MSA
V25309
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/19/22 00:29
MSA
V25309
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/19/22 00:29
MSA
V25309
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/19/22 00:29
MSA
V25309
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/19/22 00:29
MSA
V25309
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/19/22 00:29
MSA
V25309
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/19/22 00:29
MSA
V25309
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/19/22 00:29
MSA
V25309
Methylene Chloride
0.8033
ug/L
0.330
1.00
1
10/19/22 00:29
MSA
V25309
Styrene
<0.220
Ng/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/19/22 00:29
MSA
V25309
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 00:29
MSA
V25309
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/19/22 00:29
MSA
V25309
Toluene
<0.220
ug/L
0.220
0.500
1
10/19/22 00:29
MSA
V25309
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 00:29
MSA
V25309
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/19/22 00:29
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 16 of 30

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/13/2022
Report Number : 22-286-0101 REPOR T OF A NA L YSIS
Lab No : 90651 Matrix: Aqueous
Sample ID: Trip Blank-MW-20221012 Sampled: 10/12/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25308 10/18/22 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
100
Limits: 80-124%
107
Limits: 75-129%
94.2
Limits: 63-136%
96.4
Limits: 77-123%
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
1 10/19/22 00:29 MSA V25309
J Estimated value
Page 17 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-286-0101
QC Prep:
L645238
QC Analytical Batch(es): L646083
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-1-645238
Matrix: AQU
Associated Lab Samples:
90649, 90650
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
pg/L
<0.297
0.297
1.00
10/29/2215:25
Barium
pg/L
0.711
0.453
1.00
10/29/2215:25
Cadmium
pg/L
<0.350
0.350
1.00
10/29/2215:25
Chromium
pg/L
<0.346
0.346
1.00
10/29/2215:25
Lead
pg/L
<0.264
0.264
1.00
10/29/22 15:25
Selenium
pg/L
<0.703
0.703
1.00
10/29/2215:25
Silver
pg/L
<0.0570
0.0570
1.00
10/29/2215:25
Laboratory Control Sample
LCS-L645238
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
pg/L
50.0
47.5
95.0
80-120
Barium
pg/L
100
92.8
93.0
80-120
Cadmium
pg/L
10.0
10.0
100
80-120
Chromium
pg/L
100
98.1
98.0
80-120
Lead
pg/L
50.0
48.4
97.0
80-120
Selenium
pg/L
100
92.3
92.0
80-120
Silver
pg/L
10.0
9.38
94.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 90968-MS-1-645238 V 90968-MSD-L645238
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result
Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Arsenic
pg/L
< 0.297
50.0
50.0 48.0
47.9 96.0
96.0
75-125 0.2 20.0
Barium
pg/L
132
100
100 225
222 93.0
90.0
75-125 1.3 20.0
Cadmium
pg/L
< 0.350
10.0
10.0 10.1
10.6 101
106
75-125 4.8 20.0
Chromium
pg/L
1.15
100
100 101
99.8 100
99.0
75-125 1.1 20.0
Date:
11/03/2022 12:51 PM
Page 1 of 11
Page 18 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-286-0101
QC Prep:
L645238
QC Analytical Batch(es): L646083
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 90968-MS-1-645238 V 90968-MSD-L645238
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
pg/L
< 0.264 50.0
50.0 50.2
49.9 100
100 75-125 0.5 20.0
Selenium
pg/L
< 0.703 100
100 93.7
92.3 94.0
92.0 75-125 1.5 20.0
Silver
pg/L
< 0.0570 10.0
10.0 9.37
9.28 94.0
93.0 75-125 0.9 20.0
Post Digestion Spike
V 90968-PDS-L645238
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Arsenic
pg/L
24.7
99.0
10/29/22 17:34
Barium
pg/L
114
98.0
10/29/22 17:34
Cadmium
pg/L
5.17
103
10/29/22 17:34
Chromium
pg/L
51.4
102
10/29/22 17:34
Lead
pg/L
25.1
100
10/29/22 17:34
Selenium
pg/L
48.0
96.0
10/29/22 17:34
Silver
pg/L
4.80
96.0
10/29/22 17:34
Date: 11/03/2022 12:51 PM Page 2 of 11
Page 19 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-286-0101
QC Prep: L645354 QC Analytical Batch(es): L646083
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Lab Reagent Blank LRB-1-645354 Matrix: AQU
Associated Lab Samples: 90649, 90650
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Dissolved Arsenic
pg/L
<0.297
0.297
1.00
10/29/22 13:55
Dissolved Barium
pg/L
<0.453
0.453
1.00
10/29/22 13:55
Dissolved Cadmium
pg/L
<0.350
0.350
1.00
10/29/22 13:55
Dissolved Chromium
pg/L
<0.346
0.346
1.00
10/29/22 13:55
Dissolved Lead
pg/L
<0.264
0.264
1.00
10/29/22 13:55
Dissolved Selenium
pg/L
<0.703
0.703
1.00
10/29/22 13:55
Dissolved Silver
pg/L
<0.0570
0.0570
1.00
10/29/22 13:55
Laboratory Control Sample & LCSD
LCS-L645354
LCSD-L645354
Spike
LCS
LCSD
LCS LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec % Rec
Limits
RPD
Max
RPD
Dissolved Arsenic
pg/L
50.0
48.1
48.3
96.0 97.0
80-120
0.4
20.0
Dissolved Barium
pg/L
100
94.7
93.8
95.0 94.0
80-120
0.9
20.0
Dissolved Cadmium
pg/L
10.0
9.72
9.55
97.0 96.0
80-120
1.7
20.0
Dissolved Chromium
pg/L
100
98.2
97.5
98.0 98.0
80-120
0.7
20.0
Dissolved Lead
pg/L
50.0
48.9
48.2
98.0 96.0
80-120
1.4
20.0
Dissolved Selenium
pg/L
100
89.4
93.2
89.0 93.0
80-120
4.1
20.0
Dissolved Silver
pg/L
10.0
9.33
9.07
93.0 91.0
80-120
2.8
20.0
Date: 11/03/2022 12:51 PM Page 3 of 11
Page 20 of 30

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill
Report No: 22-286-0101
QC Prep: V25341
QC Analytical Batch(es): V25386
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V25341
Matrix: AQU
Associated Lab Samples: 90649, 90650
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) mg/L <0.00007 0.00007
0.00020
10/20/22 17:19
Laboratory Control Sample
LCS-V25341
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) mg/L
0.00937
0.00922
98.0 80-120
Matrix Spike & Matrix Spike Duplicate
V 90638-MS-V25341
V 90638-MSD-V25341
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) mg/L < 0.00007 0.00937
0.00937 0.00878
0.00910 94.0 97.0 80-120 3.5 20.0
Post Digestion Spike
V 90638-PDS-V25341
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) mg/L
0.00435
93.0
10/20/22 17:52
Date: 11/03/2022 12:51 PM Page 4 of 11
Page 21 of 30

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill
Report No: 22-286-0101
QC Prep: V25422
QC Analytical Batch(es): V25487
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V25422
Matrix: AQU
Associated Lab Samples: 90649, 90650
Blank MDL
MQL
Analyzed
Parameter Units
Result
Dissolved Mercury mg/L
0.000 0.000
0.00020
10/24/22 15:17
Laboratory Control Sample
LCS-V25422
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Dissolved Mercury mg/L
0.00937
0.00950
101 80-120
Matrix Spike & Matrix Spike Duplicate
V 90496-V25365-MS-V25422 V 90496-V25365-MSD-V25422
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Dissolved Mercury mg/L < 0.00007 0.00937
0.00937 0.00917
0.00913 98.0 97.0 80-120 0.4 20.0
Post Digestion Spike
V 90496-V25365-PDS-V25422
PDS
%
Analyzed
Parameter Units
Result
Recovery
Dissolved Mercury mg/L
0.00455
97.0
10/24/22 15:53
Date: 11/03/2022 12:51 PM Page 5 of 11
Page 22 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-286-0101
QC Prep:
V25158
QC Analytical Batch(es): V25159
QC Prep Batch Method:
5030B
Analysis Method:
8260D SIM
Analysis Description:
Volatile Organic Compounds -
GC/MS
Lab Reagent Blank
LRB-V25158
Matrix: AQU
Associated Lab Samples:
90649, 90650
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
1,4-Dioxane
pg/L
<0.139 0.139
2.00
10/14/2210:17
4-Bromofluorobenzene (S)
10/14/22 10:17
105
70-130
Laboratory Control Sample
LCS-V25158
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
1,4-Dioxane
pg/L
50.0
43.9
87.8
70-130
4-Bromofluorobenzene (S)
116
70-130
Matrix Spike & Matrix Spike Duplicate
V 90658-MS-V25158
V 90658-MSD-V25158
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec
Limits RPD
Conc.
1,4-Dioxane
pg/L
< 0.139 50.0
50.0 50.7
45.2 101
90.4
70-130
4-Bromofluorobenzene (S)
107
115
70-130
Date: 11/03/2022 12:51 PM Page 6 of 11
Page 23 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-286-0101
QC Prep: V25308
QC Prep Batch Method: 5030B
Lab Reagent Blank LRB-V25308
Associated Lab Samples: 90649, 90650, 90651
QC Analytical Batch(es): V25309
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Matrix: AQU
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
10/18/22 23:19
Acrylonitrile
pg/L
<0.230
0.230
5.00
10/18/22 23:19
Benzene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Bromochloromethane
pg/L
<0.420
0.420
1.00
10/18/22 23:19
Bromodichloromethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
Bromoform
pg/L
<1.50
1.50
5.00
10/18/22 23:19
Bromomethane
pg/L
<0.280
0.280
1.00
10/18/22 23:19
Carbon Disulfide
pg/L
<0.150
0.150
5.00
10/18/22 23:19
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Chlorobenzene
pg/L
<0.190
0.190
0.500
10/18/22 23:19
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
10/18/22 23:19
Chloroethane
pg/L
<0.430
0.430
1.00
10/18/22 23:19
Chloroform
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Chloromethane
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
10/18/22 23:19
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
10/18/22 23:19
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
10/18/22 23:19
Dibromomethane
pg/L
<0.230
0.230
0.500
10/18/22 23:19
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
10/18/22 23:19
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
10/18/22 23:19
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
10/18/22 23:19
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
10/18/22 23:19
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
10/18/22 23:19
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
10/18/22 23:19
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Date:
11/03/2022 12:51 PM
Page 7 of 11
Page 24 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-286-0101
QC Prep: V25308
QC Prep Batch Method: 5030B
Lab Reagent Blank LRB-V25308
Associated Lab Samples: 90649, 90650, 90651
QC Analytical Batch(es): V25309
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Matrix: AQU
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
1,2-Dichloropropane
pg/L
<0.190
0.190
0.500
10/18/22 23:19
cis-1,3-Dichloropropene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
trans-1,3-Dichloropropene
pg/L
<0.150
0.150
0.500
10/18/22 23:19
1,4-Dioxane
pg/L
<16.0
16.0
150
10/18/22 23:19
Ethylbenzene
pg/L
<0.170
0.170
0.500
10/18/22 23:19
2-Hexanone
pg/L
<0.380
0.380
5.00
10/18/22 23:19
Methyl Ethyl Ketone (MEK)
pg/L
<0.710
0.710
5.00
10/18/22 23:19
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
10/18/22 23:19
Methylene Chloride
pg/L
<0.330
0.330
1.00
10/18/22 23:19
Styrene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,1,1,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
1,1,2,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
Tetrachloroethene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Tetrahydrofuran
pg/L
<1.50
1.50
10.0
10/18/22 23:19
Toluene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,1,1-Trichloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
1,1,2-Trichloroethane
pg/L
<0.096
0.096
0.500
10/18/22 23:19
Trichloroethene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Trichlorofluoromethane
pg/L
<0.180
0.180
0.500
10/18/22 23:19
1,2,3-Trichloropropane
pg/L
<0.270
0.270
1.00
10/18/22 23:19
Vinyl Acetate
pg/L
<1.00
1.00
2.00
10/18/22 23:19
Vinyl Chloride
pg/L
<0.170
0.170
0.500
10/18/22 23:19
o-Xylene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
m,p-Xylene
pg/L
<0.420
0.420
1.00
10/18/22 23:19
4-Bromofluorobenzene (S)
10/18/22 23:19
98.2 80-124
Dibromofluoromethane (S)
10/18/22 23:19
111 75-129
1,2-Dichloroethane - d4 (S)
10/18/22 23:19
93.4 63-136
Date:
11/03/2022 12:51 PM
Page 8 of 11
Page 25 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-286-0101
QC Prep:
V25308
QC Analytical Batch(es): V25309
QC Prep Batch Method:
5030B
Analysis
Method:
8260D
Analysis
Description:
Volatile Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V25308
Matrix: AQU
Associated Lab Samples:
90649, 90650, 90651
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8 (S)
10/18/22 23:19
98.8
77-123
Laboratory Control Sample & LCSD
LCS-V25308 LCSD-V25308
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
59.0
43.6
148
109
40-166
30.0*
20.0
Acrylonitrile
pg/L
40.0
47.9
42.8
120
107
81-127
11.2
20.0
Benzene
pg/L
20.0
21.2
21.0
106
105
77-128
0.9
20.0
Bromochloromethane
pg/L
20.0
20.5
20.3
103
102
78-135
0.9
20.0
Bromodichloromethane
pg/L
20.0
26.9
27.0
135
135
76-138
0.3
20.0
Bromoform
pg/L
20.0
26.3
27.9
132
140*
71-135
5.9
20.0
Bromomethane
pg/L
20.0
18.4
18.2
92.0
91.0
41-168
1.0
20.0
Chlorobenzene
pg/L
20.0
21.6
20.7
108
104
78-119
4.2
20.0
Chlorodibromomethane
pg/L
20.0
24.1
23.4
121
117
75-134
2.9
20.0
Chloroethane
pg/L
20.0
20.5
20.5
103
103
57-142
0.0
20.0
Chloroform
pg/L
20.0
22.4
21.9
112
110
77-130
2.2
20.0
Chloromethane
pg/L
20.0
20.2
19.9
101
99.5
47-145
1.4
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
21.1
21.5
106
108
60-154
1.8
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
23.5
21.4
118
107
63-134
9.3
20.0
1,2-Dibromoethane
pg/L
20.0
25.5
24.9
128
125
77-135
2.3
20.0
Dibromomethane
pg/L
20.0
23.6
23.5
118
118
76-138
0.4
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
29.5
22.7
148*
114
70-130
26.0*
20.0
1,2-Dichlorobenzene
pg/L
20.0
20.0
20.2
100
101
78-128
0.9
20.0
1,4-Dichlorobenzene
pg/L
20.0
19.9
20.3
99.5
102
75-126
1.9
20.0
Dichlorodifluoromethane
pg/L
20.0
20.2
19.7
101
98.5
28-163
2.5
20.0
1,1-Dichloroethane
pg/L
20.0
22.4
21.8
112
109
70-130
2.7
20.0
* QC Fail
Date:
11/03/2022
12:51 PM
Page 9 of 11
Page 26
of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-286-0101
QC Prep: V25308 QC Analytical Batch(es): V25309
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V25308 LCSD-V25308
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,2-Dichloroethane
pg/L
20.0
20.9
19.6
105
98.0
68-131
6.4
20.0
1,1-Dichloroethene
pg/L
20.0
20.8
21.3
104
107
70-154
2.3
20.0
cis-1,2-Dichloroethene
pg/L
20.0
21.5
21.8
108
109
76-141
1.3
20.0
trans-1,2-Dichloroethene
pg/L
20.0
20.3
20.6
102
103
76-135
1.4
20.0
1,2-Dichloropropane
pg/L
20.0
21.3
21.5
107
108
77-130
0.9
20.0
cis-1,3-Dichloropropene
pg/L
20.0
21.4
21.2
107
106
65-140
0.9
20.0
trans-1,3-Dichloropropene
pg/L
20.0
27.8
27.6
139
138
67-140
0.7
20.0
1,4-Dioxane
pg/L
200
168
169
84.0
84.5
70-130
0.5
20.0
Ethylbenzene
pg/L
20.0
21.3
20.8
107
104
80-127
2.3
20.0
2-Hexanone
pg/L
20.0
24.0
20.4
120
102
64-137
16.2
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
18.3
14.2
91.5
71.0
71-134
25.2*
20.0
4-Methyl-2-Pentanone
pg/L
20.0
22.7
20.5
114
103
69-134
10.1
20.0
Methylene Chloride
pg/L
20.0
22.0
20.6
110
103
73-131
6.5
20.0
Styrene
pg/L
20.0
20.4
20.9
102
105
78-129
2.4
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
26.8
26.1
134
131
79-134
2.6
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
25.4
24.4
127
122
62-127
4.0
20.0
Tetrachloroethene
pg/L
20.0
21.3
20.8
107
104
80-129
2.3
20.0
Tetrahydrofuran
pg/L
20.0
22.9
22.2
115
111
70-130
3.1
20.0
Toluene
pg/L
20.0
21.8
21.3
109
107
76-131
2.3
20.0
1,1,1-Trichloroethane
pg/L
20.0
25.7
26.2
129
131
75-135
1.9
20.0
1,1,2-Trichloroethane
pg/L
20.0
23.5
22.5
118
113
70-140
4.3
20.0
Trichloroethene
pg/L
20.0
21.9
22.1
110
111
77-133
0.9
20.0
Trichlorofluoromethane
pg/L
20.0
21.6
20.9
108
105
62-148
3.2
20.0
1,2,3-Trichloropropane
pg/L
20.0
23.0
20.6
115
103
71-127
11.0
20.0
Vinyl Acetate
pg/L
20.0
23.1
20.0
116
100
34-167
14.3
20.0
Vinyl Chloride
pg/L
20.0
19.7
19.6
98.5
98.0
57-141
0.5
20.0
* QC Fail Date: 11/03/2022 12:51 PM Page 10 of 11
Page 27 of 30

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-286-0101
QC Prep: V25308
QC Analytical Batch(es): V25309
QC Prep Batch Method: 5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD
LCS-V25308
LCSD-V25308
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter Units
Conc.
Result Result
%Rec
% Rec
Limits RPD
Max
RPD
o-Xylene pg/L
20.0
20.8 20.4
104
102
78-128 1.9
20.0
m,p-Xylene pg/L
40.0
43.1 42.8
108
107
77-133 0.6
20.0
4-Bromofluorobenzene (S)
100
102
80-124
Dibromofluoromethane (S)
118
119
75-129
1,2-Dichloroethane - d4 (S)
97.4
93.6
63-136
Toluene-d8 (S)
97.0
98.4
77-123
Date: 11/03/2022 12:51 PM Page 11 of 11
Page 28 of 30

WayPAoint.
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01015
Customer Name: Anchor QEA of North Carolina, PLLC
Report Number: 22-286-0101
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client # Courier
0 Other:
Thermometer ID:
IRT-15 1.1 C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
# Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
# Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample Iabel(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
U Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
U Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
Special precautions or instructions included?
Comments:
0 Yes 0 No U N/A
F Low concentration EnCore samplers (48 hr)
Low conc pre -weighed vials (Sod Bis -14 d)
0Yes ONo
Signature: Angela D Overcash
Date & Time: 10/13/2022 12:27:47
Page 29 of 30

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Page 30 of 30 J

Waypointo
ANALYTICAL
11 /3/2022
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville, NC, 28801
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 22-285-0100
Client Project Description: Madison County Closed Landfill
C21500-01.01, WA-1
Site: 58-02
Project Number: 58-02
Dear Chuck Pippin:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 10/12/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a,j
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 60

Waypoint.0
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2022
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Page 1 of 1 00016/22-285-0100
Page 2 of 60

Waypoint.(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Sample Summary Table
Report Number: 22-285-0100
Client Project Description: Madison County Closed Landfill
C215OO-01.01, WA-1
Lab No Client Sample ID Matrix Date Collected Date Received
90494
MW-01-OLD-20221010
Aqueous
10/10/2022
11:25
10/12/2022
12:00
90495
MW-02-OLD-20221010
Aqueous
10/10/2022
10:05
10/12/2022
12:00
90496
BG Spring-OLD-20221010
Aqueous
10/10/2022
16:00
10/12/2022
12:00
90497
Trip Blank-SW-OLD-20221010-1
Aqueous
10/10/2022
10/12/2022
12:00
90498
Trip Blank-SW-OLD-20221010-2
Aqueous
10/10/2022
10/12/2022
12:00
90499
Trip Blank-MW-OLD-20221010-1
Aqueous
10/10/2022
10/12/2022
12:00
90500
SW-01-OLD-20221010
Aqueous
10/10/2022
14:30
10/12/2022
12:00
90501
SW-02-OLD-20221010
Aqueous
10/10/2022
15:09
10/12/2022
12:00
Page 3 of 60

(2)
Waypoint. 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Summary of Detected Analytes
Project: Madison County Closed Landfill
Report Number: 22-285-0100
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-01-OLD-20221
V 90494
6020B
Arsenic
0.671
pq/L
0.490
10/31/2022 20:37
J
6020B
Barium
573
Ng/L
17.0
10/31/2022 20:30
6020B
Dissolved Barium
359
pq/L
17.0
10/31/2022 18:23
8260D
Benzene
0.730
pg/L
0.180
10/15/202213:19
8260D
Chlorobenzene
4.04
pq/L
0.190
10/15/202213:19
8260D
Chloroethane
1.09
pg/L
0.430
10/15/202213:19
8260D
1,2-Dichlorobenzene
0.714
pq/L
0.220
10/15/202213:19
8260D
1,4-Dichlorobenzene
5.93
pg/L
0.210
10/15/202213:19
8260D
1,1-Dichloroethane
0.665
pq/L
0.240
10/15/202213:19
8260D
cis- 1,2-Dichloroethene
3.27
pg/L
0.200
10/15/202213:19
8260D
trans-1,2-Dichloroethene
0.426
pq/L
0.180
10/15/202213:19
J
8260D
1,2-Dichloropropane
0.486
pg/L
0.190
10/15/202213:19
J
8260D
Vinyl Chloride
0.769
pq/L
0.170
10/15/2022 13:19
8260D SIM
1,4-Dioxane
3.43
Ng/L
0.139
10/13/2022 18:46
MW-02-OLD-20221
V 90495
6020B
Barium
61.8
pq/L
3.40
10/31/2022 21:17
6020B
Dissolved Barium
58.9
Ng/L
3.40
10/31/2022 18:43
8260D
1,1-Dichloroethane
0.471
pq/L
0.240
10/15/202213:46
J
BG
V 90496
Spring-OLD-20221(
6020B
Barium
141
Ng/L
3.40
10/31/2022 21:23
6020B
Dissolved Barium
109
pq/L
3.40
10/31/2022 19:03
6020B
Chromium
4.82
pg/L
1.00
10/31/2022 21:23
6020B
Lead
0.808
pg/L
0.500
10/31/2022 21:23
J
Trip
V 90499
Blank-MW-OLD-20;
8260D
Methylene Chloride
0.674
pg/L
0.330
10/15/2022 12:25
J
SW-0I-OLD-20221(
V 90500
2340C-2011
Hardness
66000
pq/L
1140
101201202211:50
6020B
Barium
134
Ng/L
3.40
10/31/2022 21:44
6020B
Chromium
4.16
pq/L
1.00
10/31/2022 21:44
6020B
Lead
2.27
Ng/L
0.500
10/31/2022 21:44
SW-02-OLD-20221(
V 90501
2340C-2011
Hardness
66000
pg/L
1140
10/20/202211:50
6020B
Barium
45.2
Ng/L
3.40
10/31/2022 21:50
Page 4 of 60

Waypointo
ANALYTICAL
Client: Anchor QEA of North Carolina, PLLC
Project: Madison County Closed Landfill
Lab Report Number: 22-285-0100
Date: 11 /2/2022
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
CASE NARRATIVE
Metals Analyses Method 6020B
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Silver
QC Batch No: V25780/V25778/V25776
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Silver
QC Batch No: V25780N25778N25776
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Barium
QC Batch No: V25780N25778/V25776
Dilution Test result used for both sample and DT.
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Barium
QC Batch No: V25780/V25778/V25776
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Barium
QC Batch No: V25811/V25778/V25776
Dilution Test result was used for both sample and DT.
Total Aqueous Mercury Analysis - CVAA Method 7470A
Sample 90494 (MW-01 -OLD-20221 010)
Analyte: Mercury
QC Batch No: V25177/V25422/V25365
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Volatile Organic Compounds - GUMS Method 8260D
Analyte: 2-Butanone
QC Batch No: V25309/V25192
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Acetone
QC Batch No: V25309/V25192
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 5 of 60

Waypointo
ANALYTICAL
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Analyte: Bromoform
QC Batch No: V25309/V25192
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Carbon Disulfide
QC Batch No: V25309/V25192
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Carbon Tetrachloride
QC Batch No: V25309/V25192
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: trans-1,4-Dichloro-2-butene
QC Batch No: V25309/V25192
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the
batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: trans-1,4-Dichloro-2-butene
QC Batch No: V25309/V25192
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 6 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100
REPOR T OF A NA L YSIS
Lab No : 90494
Matrix:
Aqueous
Sample ID: MW-01-OLD-20221010
Sampled: 10/10/2022 11:25
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
3.43
Ng/L
0.139
2.00
1
10/13/22 18:46
TBL
8260D SIM
Arsenic
0.671 J
ug/L
0.490
1.00
1
10/31/22 20:37
EDV
6020B
Dissolved Arsenic
<0.490
Ng/L
0.490
1.00
1
10/31/22 17:56
EDV
6020B
Barium
573
ug/L
17.0
50.0
5
10/31/22 20:30
EDV
6020B
Dissolved Barium
359
Ng/L
17.0
50.0
5
10/31/22 18:23
EDV
6020B
Cadmium
<0.150
ug/L
0.150
1.00
1
10/31/22 20:37
EDV
6020B
Dissolved Cadmium
<0.150
Ng/L
0.150
1.00
1
10/31/22 17:56
EDV
6020B
Chromium
<1.00
ug/L
1.00
2.00
1
10/31/22 20:37
EDV
6020B
Dissolved Chromium
<1.00
Ng/L
1.00
2.00
1
10/31/22 17:56
EDV
6020B
Lead
<0.500
ug/L
0.500
1.00
1
10/31/22 20:37
EDV
6020B
Dissolved Lead
<0.500
Ng/L
0.500
1.00
1
10/31/22 17:56
EDV
6020B
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
10/14/22 16:08
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
10/24/22 15:37
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
10/31/22 20:37
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
10/31/22 17:56
EDV
6020B
Silver
<0.130
ug/L
0.130
1.00
1
10/31/22 20:37
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
10/31/22 17:56
EDV
6020B
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90494
Matrix: Aqueous
Sample ID: MW-01-OLD-20221010
Sampled:
10/10/2022 11:25
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 13:19
MSA
V25193
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
10/15/22 13:19
MSA
V25193
Benzene
0.730
N9/L
0.180
0.500
1
10/15/22 13:19
MSA
V25193
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
10/15/22 13:19
MSA
V25193
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
10/15/22 13:19
MSA
V25193
Bromoform
<1.50
u9/L
1.50
5.00
1
10/15/22 13:19
MSA
V25193
Bromomethane
<0.280
N9/L
0.280
1.00
1
10/15/22 13:19
MSA
V25193
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
10/15/22 13:19
MSA
V25193
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
10/15/22 13:19
MSA
V25193
Chlorobenzene
4.04
u9/L
0.190
0.500
1
10/15/22 13:19
MSA
V25193
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
10/15/22 13:19
MSA
V25193
Chloroethane
1.09
u9/L
0.430
1.00
1
10/15/22 13:19
MSA
V25193
Chloroform
<0.220
N9/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
Chloromethane
<0.220
u9/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
10/15/22 13:19
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
10/15/22 13:19
MSA
V25193
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
10/15/22 13:19
MSA
V25193
Dibromomethane
<0.230
u9/L
0.230
0.500
1
10/15/22 13:19
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
10/15/22 13:19
MSA
V25193
1,2-Dichlorobenzene
0.714
u9/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
1,4-Dichlorobenzene
5.93
N9/L
0.210
0.500
1
10/15/22 13:19
MSA
V25193
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
10/15/22 13:19
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 8 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90494
Matrix: Aqueous
Sample ID: MW-01-OLD-20221010
Sampled:
10/10/2022 11:25
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.665
Ng/L
0.240
0.500
1
10/15/22 13:19
MSA
V25193
1,2-Dichloroethane
<0.150
pg/L
0.150
0.500
1
10/15/22 13:19
MSA
V25193
1,1-Dichloroethene
<0.150
N9/L
0.150
0.500
1
10/15/22 13:19
MSA
V25193
cis- 1,2-Dich loroethene
3.27
p9/L
0.200
0.500
1
10/15/22 13:19
MSA
V25193
trans-1,2-Dichloroethene
0.4263
N9/L
0.180
0.500
1
10/15/22 13:19
MSA
V25193
1,2-Dichloropropane
0.4863
pg/L
0.190
0.500
1
10/15/22 13:19
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
N9/L
0.210
0.500
1
10/15/22 13:19
MSA
V25193
trans-1,3-Dichloropropene
<0.150
pg/L
0.150
0.500
1
10/15/22 13:19
MSA
V25193
1,4-Dioxane
<16.0
N9/L
16.0
150
1
10/15/22 13:19
MSA
V25193
Ethylbenzene
<0.170
pg/L
0.170
0.500
1
10/15/22 13:19
MSA
V25193
2-Hexanone
<0.380
N9/L
0.380
5.00
1
10/15/22 13:19
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
pg/L
0.710
5.00
1
10/15/22 13:19
MSA
V25193
4-Methyl-2-Pentanone
<1.00
N9/L
1.00
5.00
1
10/15/22 13:19
MSA
V25193
Methylene Chloride
<0.330
pg/L
0.330
1.00
1
10/15/22 13:19
MSA
V25193
Styrene
<0.220
N9/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
pg/L
0.160
0.500
1
10/15/22 13:19
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
N9/L
0.160
0.500
1
10/15/22 13:19
MSA
V25193
Tetrachloroethene
<0.220
pg/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
Tetrahydrofuran
<1.50
N9/L
1.50
10.0
1
10/15/22 13:19
MSA
V25193
Toluene
<0.220
pg/L
0.220
0.500
1
10/15/22 13:19
MSA
V25193
1,1,1-Trichloroethane
<0.160
N9/L
0.160
0.500
1
10/15/22 13:19
MSA
V25193
1,1,2-Trichloroethane
<0.096
pg/L
0.096
0.500
1
10/15/22 13:19
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 9 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90494 Matrix: Aqueous
Sample ID: MW-01-OLD-20221010 Sampled: 10/10/2022 11:25
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
0.769
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
99.6
Limits: 80-124%
96.6
Limits: 75-129%
97.6
Limits: 63-136%
101
Limits: 77-123%
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
1 10/15/22 13:19 MSA V25193
J Estimated value
Page 10 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100
REPOR T OF A NA L YSIS
Lab No : 90495
Matrix:
Aqueous
Sample ID: MW-02-OLD-20221010
Sampled: 10/10/2022 10:05
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
10/13/22 19:11
TBL
8260D SIM
Arsenic
<0.490
ug/L
0.490
1.00
1
10/31/22 21:17
EDV
6020B
Dissolved Arsenic
<0.490
Ng/L
0.490
1.00
1
10/31/22 18:43
EDV
6020E
Barium
61.8
ug/L
3.40
10.0
1
10/31/22 21:17
EDV
6020B
Dissolved Barium
58.9
Ng/L
3.40
10.0
1
10/31/22 18:43
EDV
6020E
Cadmium
<0.150
ug/L
0.150
1.00
1
10/31/22 21:17
EDV
6020B
Dissolved Cadmium
<0.150
Ng/L
0.150
1.00
1
10/31/22 18:43
EDV
6020E
Chromium
<1.00
ug/L
1.00
2.00
1
10/31/22 21:17
EDV
6020B
Dissolved Chromium
<1.00
Ng/L
1.00
2.00
1
10/31/22 18:43
EDV
6020E
Lead
<0.500
ug/L
0.500
1.00
1
10/31/22 21:17
EDV
6020B
Dissolved Lead
<0.500
Ng/L
0.500
1.00
1
10/31/22 18:43
EDV
6020E
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
10/14/22 16:20
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
10/24/22 15:40
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
10/31/22 21:17
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
10/31/22 18:43
EDV
6020E
Silver
<0.130
ug/L
0.130
1.00
1
10/31/22 21:17
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
10/31/22 18:43
EDV
6020E
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 11 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90495
Matrix: Aqueous
Sample ID: MW-02-OLD-20221010
Sampled:
10/10/2022 10:05
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 13:46
MSA
V25193
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/15/22 13:46
MSA
V25193
Benzene
<0.180
Ng/L
0.180
0.500
1
10/15/22 13:46
MSA
V25193
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/15/22 13:46
MSA
V25193
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 13:46
MSA
V25193
Bromoform
<1.50
ug/L
1.50
5.00
1
10/15/22 13:46
MSA
V25193
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/15/22 13:46
MSA
V25193
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/15/22 13:46
MSA
V25193
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/15/22 13:46
MSA
V25193
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/15/22 13:46
MSA
V25193
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/15/22 13:46
MSA
V25193
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/15/22 13:46
MSA
V25193
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/15/22 13:46
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/15/22 13:46
MSA
V25193
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/15/22 13:46
MSA
V25193
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/15/22 13:46
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/15/22 13:46
MSA
V25193
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/15/22 13:46
MSA
V25193
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/15/22 13:46
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 12 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90495
Matrix: Aqueous
Sample ID: MW-02-OLD-20221010
Sampled:
10/10/2022 10:05
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.4713
Ng/L
0.240
0.500
1
10/15/22 13:46
MSA
V25193
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/15/22 13:46
MSA
V25193
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/15/22 13:46
MSA
V25193
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/15/22 13:46
MSA
V25193
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/15/22 13:46
MSA
V25193
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/15/22 13:46
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/15/22 13:46
MSA
V25193
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/15/22 13:46
MSA
V25193
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/15/22 13:46
MSA
V25193
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/15/22 13:46
MSA
V25193
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/15/22 13:46
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/15/22 13:46
MSA
V25193
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/15/22 13:46
MSA
V25193
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/15/22 13:46
MSA
V25193
Styrene
<0.220
Ng/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/15/22 13:46
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 13:46
MSA
V25193
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/15/22 13:46
MSA
V25193
Toluene
<0.220
ug/L
0.220
0.500
1
10/15/22 13:46
MSA
V25193
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 13:46
MSA
V25193
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/15/22 13:46
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 13 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90495 Matrix: Aqueous
Sample ID: MW-02-OLD-20221010 Sampled: 10/10/2022 10:05
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.6
Limits: 80-124%
95.2
Limits: 75-129%
98.0
Limits: 63-136%
99.8
Limits: 77-123%
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
1 10/15/22 13:46 MSA V25193
J Estimated value
Page 14 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100
REPOR T OF A NA L YSIS
Lab No : 90496
Matrix:
Aqueous
Sample ID: BG Spring-OLD-20221010
Sampled: 10/10/2022 16:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
10/13/22 19:36
TBL
8260D SIM
Arsenic
<0.490
ug/L
0.490
1.00
1
10/31/22 21:23
EDV
6020B
Dissolved Arsenic
<0.490
Ng/L
0.490
1.00
1
10/31/22 19:03
EDV
6020E
Barium
141
ug/L
3.40
10.0
1
10/31/22 21:23
EDV
6020B
Dissolved Barium
109
Ng/L
3.40
10.0
1
10/31/22 19:03
EDV
6020E
Cadmium
<0.150
ug/L
0.150
1.00
1
10/31/22 21:23
EDV
6020B
Dissolved Cadmium
<0.150
Ng/L
0.150
1.00
1
10/31/22 19:03
EDV
6020E
Chromium
4.82
ug/L
1.00
2.00
1
10/31/22 21:23
EDV
6020B
Dissolved Chromium
<1.00
Ng/L
1.00
2.00
1
10/31/22 19:03
EDV
6020E
Lead
0.8083
ug/L
0.500
1.00
1
10/31/22 21:23
EDV
6020B
Dissolved Lead
<0.500
Ng/L
0.500
1.00
1
10/31/22 19:03
EDV
6020E
Mercury (Total)
<0.00007
mg/L
0.00007
0.00020
1
10/14/22 16:22
EDV
7470A
Dissolved Mercury
<0.00007
mg/L
0.00007
0.00020
1
10/24/22 15:42
EDV
7470A
Selenium
<2.30
ug/L
2.30
5.00
1
10/31/22 21:23
EDV
6020B
Dissolved Selenium
<2.30
Ng/L
2.30
5.00
1
10/31/22 19:03
EDV
6020E
Silver
<0.130
ug/L
0.130
1.00
1
10/31/22 21:23
EDV
6020B
Dissolved Silver
<0.130
Ng/L
0.130
1.00
1
10/31/22 19:03
EDV
6020E
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 15 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90496
Matrix: Aqueous
Sample ID: BG Spring-OLD-20221010
Sampled:
10/10/2022 16:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 14:13
MSA
V25193
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/15/22 14:13
MSA
V25193
Benzene
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:13
MSA
V25193
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/15/22 14:13
MSA
V25193
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:13
MSA
V25193
Bromoform
<1.50
ug/L
1.50
5.00
1
10/15/22 14:13
MSA
V25193
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/15/22 14:13
MSA
V25193
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/15/22 14:13
MSA
V25193
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:13
MSA
V25193
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/15/22 14:13
MSA
V25193
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/15/22 14:13
MSA
V25193
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/15/22 14:13
MSA
V25193
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/15/22 14:13
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/15/22 14:13
MSA
V25193
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/15/22 14:13
MSA
V25193
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/15/22 14:13
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/15/22 14:13
MSA
V25193
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/15/22 14:13
MSA
V25193
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/15/22 14:13
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 16 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90496
Matrix: Aqueous
Sample ID: BG Spring-OLD-20221010
Sampled:
10/10/2022 16:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/15/22 14:13
MSA
V25193
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/15/22 14:13
MSA
V25193
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/15/22 14:13
MSA
V25193
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/15/22 14:13
MSA
V25193
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:13
MSA
V25193
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/15/22 14:13
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/15/22 14:13
MSA
V25193
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/15/22 14:13
MSA
V25193
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/15/22 14:13
MSA
V25193
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/15/22 14:13
MSA
V25193
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/15/22 14:13
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/15/22 14:13
MSA
V25193
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/15/22 14:13
MSA
V25193
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/15/22 14:13
MSA
V25193
Styrene
<0.220
Ng/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/15/22 14:13
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:13
MSA
V25193
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/15/22 14:13
MSA
V25193
Toluene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:13
MSA
V25193
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:13
MSA
V25193
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/15/22 14:13
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 17 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90496 Matrix: Aqueous
Sample ID: BG Spring-OLD-20221010 Sampled: 10/10/2022 16:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.2
Limits: 80-124%
96.4
Limits: 75-129%
98.6
Limits: 63-136%
101
Limits: 77-123%
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
1 10/15/22 14:13 MSA V25193
J Estimated value
Page 18 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90497
Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-1
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25332
10/19/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/19/22 13:33
MSA
V25333
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/19/22 13:33
MSA
V25333
Benzene
<0.180
Ng/L
0.180
0.500
1
10/19/22 13:33
MSA
V25333
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/19/22 13:33
MSA
V25333
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 13:33
MSA
V25333
Bromoform
<1.50
ug/L
1.50
5.00
1
10/19/22 13:33
MSA
V25333
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/19/22 13:33
MSA
V25333
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/19/22 13:33
MSA
V25333
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/19/22 13:33
MSA
V25333
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/19/22 13:33
MSA
V25333
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/19/22 13:33
MSA
V25333
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/19/22 13:33
MSA
V25333
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/19/22 13:33
MSA
V25333
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/19/22 13:33
MSA
V25333
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/19/22 13:33
MSA
V25333
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/19/22 13:33
MSA
V25333
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/19/22 13:33
MSA
V25333
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/19/22 13:33
MSA
V25333
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/19/22 13:33
MSA
V25333
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 19 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90497
Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-1
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25332
10/19/22 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/19/22 13:33
MSA
V25333
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/19/22 13:33
MSA
V25333
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/19/22 13:33
MSA
V25333
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/19/22 13:33
MSA
V25333
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/19/22 13:33
MSA
V25333
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/19/22 13:33
MSA
V25333
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/19/22 13:33
MSA
V25333
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/19/22 13:33
MSA
V25333
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/19/22 13:33
MSA
V25333
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/19/22 13:33
MSA
V25333
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/19/22 13:33
MSA
V25333
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/19/22 13:33
MSA
V25333
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/19/22 13:33
MSA
V25333
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/19/22 13:33
MSA
V25333
Styrene
<0.220
Ng/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/19/22 13:33
MSA
V25333
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 13:33
MSA
V25333
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/19/22 13:33
MSA
V25333
Toluene
<0.220
ug/L
0.220
0.500
1
10/19/22 13:33
MSA
V25333
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 13:33
MSA
V25333
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/19/22 13:33
MSA
V25333
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 20 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90497 Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-1 Sampled: 10/10/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25332 10/19/22 09:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.4
Limits: 80-124%
98.6
Limits: 75-129%
99.2
Limits: 63-136%
100
Limits: 77-123%
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
1 10/19/22 13:33 MSA V25333
J Estimated value
Page 21 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90498
Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-2
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 11:57
MSA
V25193
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/15/22 11:57
MSA
V25193
Benzene
<0.180
Ng/L
0.180
0.500
1
10/15/22 11:57
MSA
V25193
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/15/22 11:57
MSA
V25193
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 11:57
MSA
V25193
Bromoform
<1.50
ug/L
1.50
5.00
1
10/15/22 11:57
MSA
V25193
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/15/22 11:57
MSA
V25193
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/15/22 11:57
MSA
V25193
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/15/22 11:57
MSA
V25193
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/15/22 11:57
MSA
V25193
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/15/22 11:57
MSA
V25193
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/15/22 11:57
MSA
V25193
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/15/22 11:57
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/15/22 11:57
MSA
V25193
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/15/22 11:57
MSA
V25193
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/15/22 11:57
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/15/22 11:57
MSA
V25193
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/15/22 11:57
MSA
V25193
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/15/22 11:57
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 22 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90498
Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-2
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/15/22 11:57
MSA
V25193
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/15/22 11:57
MSA
V25193
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/15/22 11:57
MSA
V25193
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/15/22 11:57
MSA
V25193
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/15/22 11:57
MSA
V25193
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/15/22 11:57
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/15/22 11:57
MSA
V25193
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/15/22 11:57
MSA
V25193
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/15/22 11:57
MSA
V25193
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/15/22 11:57
MSA
V25193
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/15/22 11:57
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/15/22 11:57
MSA
V25193
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/15/22 11:57
MSA
V25193
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/15/22 11:57
MSA
V25193
Styrene
<0.220
Ng/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/15/22 11:57
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 11:57
MSA
V25193
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/15/22 11:57
MSA
V25193
Toluene
<0.220
ug/L
0.220
0.500
1
10/15/22 11:57
MSA
V25193
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 11:57
MSA
V25193
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/15/22 11:57
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 23 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90498 Matrix: Aqueous
Sample ID: Trip Blank-SW-OLD-20221010-2 Sampled: 10/10/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
98.6
Limits: 80-124%
96.4
Limits: 75-129%
98.0
Limits: 63-136%
101
Limits: 77-123%
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
1 10/15/22 11:57 MSA V25193
J Estimated value
Page 24 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90499
Matrix: Aqueous
Sample ID: Trip Blank-MW-OLD-20221010-1
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 12:25
MSA
V25193
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/15/22 12:25
MSA
V25193
Benzene
<0.180
Ng/L
0.180
0.500
1
10/15/22 12:25
MSA
V25193
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/15/22 12:25
MSA
V25193
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 12:25
MSA
V25193
Bromoform
<1.50
ug/L
1.50
5.00
1
10/15/22 12:25
MSA
V25193
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/15/22 12:25
MSA
V25193
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/15/22 12:25
MSA
V25193
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/15/22 12:25
MSA
V25193
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/15/22 12:25
MSA
V25193
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/15/22 12:25
MSA
V25193
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/15/22 12:25
MSA
V25193
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/15/22 12:25
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/15/22 12:25
MSA
V25193
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/15/22 12:25
MSA
V25193
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/15/22 12:25
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/15/22 12:25
MSA
V25193
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/15/22 12:25
MSA
V25193
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/15/22 12:25
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 25 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90499
Matrix: Aqueous
Sample ID: Trip Blank-MW-OLD-20221010-1
Sampled:
10/10/2022 0:00
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MOL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/15/22 12:25
MSA
V25193
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/15/22 12:25
MSA
V25193
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/15/22 12:25
MSA
V25193
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/15/22 12:25
MSA
V25193
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/15/22 12:25
MSA
V25193
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/15/22 12:25
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/15/22 12:25
MSA
V25193
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/15/22 12:25
MSA
V25193
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/15/22 12:25
MSA
V25193
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/15/22 12:25
MSA
V25193
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/15/22 12:25
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/15/22 12:25
MSA
V25193
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/15/22 12:25
MSA
V25193
Methylene Chloride
0.6743
ug/L
0.330
1.00
1
10/15/22 12:25
MSA
V25193
Styrene
<0.220
Ng/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/15/22 12:25
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 12:25
MSA
V25193
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/15/22 12:25
MSA
V25193
Toluene
<0.220
ug/L
0.220
0.500
1
10/15/22 12:25
MSA
V25193
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 12:25
MSA
V25193
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/15/22 12:25
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 26 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90499 Matrix: Aqueous
Sample ID: Trip Blank-MW-OLD-20221010-1 Sampled: 10/10/2022 0:00
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MOL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
100
Limits: 80-124%
96.4
Limits: 75-129%
98.2
Limits: 63-136%
101
Limits: 77-123%
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
1 10/15/22 12:25 MSA V25193
J Estimated value
Page 27 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90500 Matrix: Aqueous
Sample ID: SW-01-OLD-20221010 Sampled: 10/10/2022 14:30
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Hardness
1,4-Dioxane
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury (Total)
Selenium
Silver
66000
<0.139
<0.490
134
<0.150
4.16
2.27
<0.00007
<2.30
<0.130
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
N9/L
1140
10000
P9/L
0.139
2.00
N9/L
0.490
1.00
P9/L
3.40
10.0
N9/L
0.150
1.00
P9/L
1.00
2.00
N9/L
0.500
1.00
mg/L
0.00007
0.00020
N9/L
2.30
5.00
P9/L
0.130
1.00
1 10/20/22 11:50
CLB
2340C-2011
1 10/13/22 20:01
TBL
8260D SIM
1 10/31/22 21:44
EDV
6020E
1 10/31/22 21:44
EDV
6020B
1 10/31/22 21:44
EDV
6020E
1 10/31/22 21:44
EDV
6020B
1 10/31/22 21:44
EDV
6020E
1 10/14/22 16:25
EDV
7470A
1 10/31/22 21:44
EDV
6020E
1 10/31/22 21:44
EDV
6020B
J Estimated value
Page 28 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90500
Matrix: Aqueous
Sample ID: SW-01-OLD-20221010
Sampled:
10/10/2022 14:30
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
Ng/L
1.80
5.00
1
10/15/22 14:40
MSA
V25193
Acrylonitrile
<0.230
ug/L
0.230
5.00
1
10/15/22 14:40
MSA
V25193
Benzene
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:40
MSA
V25193
Bromochloromethane
<0.420
ug/L
0.420
1.00
1
10/15/22 14:40
MSA
V25193
Bromodichloromethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:40
MSA
V25193
Bromoform
<1.50
ug/L
1.50
5.00
1
10/15/22 14:40
MSA
V25193
Bromomethane
<0.280
Ng/L
0.280
1.00
1
10/15/22 14:40
MSA
V25193
Carbon Disulfide
<0.150
ug/L
0.150
5.00
1
10/15/22 14:40
MSA
V25193
Carbon Tetrachloride
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:40
MSA
V25193
Chlorobenzene
<0.190
ug/L
0.190
0.500
1
10/15/22 14:40
MSA
V25193
Chlorodibromomethane
<0.190
Ng/L
0.190
0.500
1
10/15/22 14:40
MSA
V25193
Chloroethane
<0.430
ug/L
0.430
1.00
1
10/15/22 14:40
MSA
V25193
Chloroform
<0.220
Ng/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
Chloromethane
<0.220
ug/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
10/15/22 14:40
MSA
V25193
1,2-Dibromo-3-Chloropropane
<1.10
ug/L
1.10
2.00
1
10/15/22 14:40
MSA
V25193
1,2-Dibromoethane
<0.200
Ng/L
0.200
0.500
1
10/15/22 14:40
MSA
V25193
Dibromomethane
<0.230
ug/L
0.230
0.500
1
10/15/22 14:40
MSA
V25193
trans-1,4-Dichloro-2-butene
<1.30
Ng/L
1.30
10.0
1
10/15/22 14:40
MSA
V25193
1,2-Dichlorobenzene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
1,4-Dichlorobenzene
<0.210
Ng/L
0.210
0.500
1
10/15/22 14:40
MSA
V25193
Dichlorodifluoromethane
<1.20
ug/L
1.20
5.00
1
10/15/22 14:40
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 29 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90500
Matrix: Aqueous
Sample ID: SW-01-OLD-20221010
Sampled:
10/10/2022 14:30
Analytical Method: 8260D
Prep Batch(es):
V25192
10/14/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/15/22 14:40
MSA
V25193
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/15/22 14:40
MSA
V25193
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/15/22 14:40
MSA
V25193
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/15/22 14:40
MSA
V25193
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/15/22 14:40
MSA
V25193
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/15/22 14:40
MSA
V25193
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/15/22 14:40
MSA
V25193
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/15/22 14:40
MSA
V25193
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/15/22 14:40
MSA
V25193
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/15/22 14:40
MSA
V25193
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/15/22 14:40
MSA
V25193
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/15/22 14:40
MSA
V25193
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/15/22 14:40
MSA
V25193
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/15/22 14:40
MSA
V25193
Styrene
<0.220
Ng/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/15/22 14:40
MSA
V25193
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:40
MSA
V25193
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/15/22 14:40
MSA
V25193
Toluene
<0.220
ug/L
0.220
0.500
1
10/15/22 14:40
MSA
V25193
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/15/22 14:40
MSA
V25193
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/15/22 14:40
MSA
V25193
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 30 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90500 Matrix: Aqueous
Sample ID: SW-01-OLD-20221010 Sampled: 10/10/2022 14:30
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25192 10/14/22 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
99.8
Limits: 80-124%
97.6
Limits: 75-129%
98.0
Limits: 63-136%
102
Limits: 77-123%
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
1 10/15/22 14:40 MSA V25193
J Estimated value
Page 31 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90501 Matrix: Aqueous
Sample ID: SW-02-OLD-20221010 Sampled: 10/10/2022 15:09
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Method
Hardness
1,4-Dioxane
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury (Total)
Selenium
Silver
66000
<0.139
<0.490
45.2
<0.150
<1.00
<0.500
<0.00007
<2.30
<0.130
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
N9/L
1140
10000
P9/L
0.139
2.00
N9/L
0.490
1.00
P9/L
3.40
10.0
N9/L
0.150
1.00
P9/L
1.00
2.00
N9/L
0.500
1.00
mg/L
0.00007
0.00020
N9/L
2.30
5.00
P9/L
0.130
1.00
1 10/20/22 11:50
CLB
2340C-2011
1 10/13/22 20:26
TBL
8260D SIM
1 10/31/22 21:50
EDV
6020E
1 10/31/22 21:50
EDV
6020B
1 10/31/22 21:50
EDV
6020E
1 10/31/22 21:50
EDV
6020B
1 10/31/22 21:50
EDV
6020E
1 10/14/22 16:27
EDV
7470A
1 10/31/22 21:50
EDV
6020B
1 10/31/22 21:50
EDV
6020B
J Estimated value
Page 32 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90501
Matrix: Aqueous
Sample ID: SW-02-OLD-20221010
Sampled:
10/10/2022 15:09
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<1.80
N9/L
1.80
5.00
1
10/19/22 02:25
MSA
V25309
Acrylonitrile
<0.230
u9/L
0.230
5.00
1
10/19/22 02:25
MSA
V25309
Benzene
<0.180
N9/L
0.180
0.500
1
10/19/22 02:25
MSA
V25309
Bromochloromethane
<0.420
u9/L
0.420
1.00
1
10/19/22 02:25
MSA
V25309
Bromodichloromethane
<0.160
N9/L
0.160
0.500
1
10/19/22 02:25
MSA
V25309
Bromoform
<1.50
u9/L
1.50
5.00
1
10/19/22 02:25
MSA
V25309
Bromomethane
<0.280
N9/L
0.280
1.00
1
10/19/22 02:25
MSA
V25309
Carbon Disulfide
<0.150
u9/L
0.150
5.00
1
10/19/22 02:25
MSA
V25309
Carbon Tetrachloride
<0.180
N9/L
0.180
0.500
1
10/19/22 02:25
MSA
V25309
Chlorobenzene
<0.190
u9/L
0.190
0.500
1
10/19/22 02:25
MSA
V25309
Chlorodibromomethane
<0.190
N9/L
0.190
0.500
1
10/19/22 02:25
MSA
V25309
Chloroethane
<0.430
u9/L
0.430
1.00
1
10/19/22 02:25
MSA
V25309
Chloroform
<0.220
N9/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
Chloromethane
<0.220
u9/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
Di -Isopropyl Ether (DIPE)
<0.960
N9/L
0.960
5.00
1
10/19/22 02:25
MSA
V25309
1,2-Dibromo-3-Chloropropane
<1.10
u9/L
1.10
2.00
1
10/19/22 02:25
MSA
V25309
1,2-Dibromoethane
<0.200
N9/L
0.200
0.500
1
10/19/22 02:25
MSA
V25309
Dibromomethane
<0.230
u9/L
0.230
0.500
1
10/19/22 02:25
MSA
V25309
trans-1,4-Dichloro-2-butene
<1.30
N9/L
1.30
10.0
1
10/19/22 02:25
MSA
V25309
1,2-Dichlorobenzene
<0.220
u9/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
1,4-Dichlorobenzene
<0.210
N9/L
0.210
0.500
1
10/19/22 02:25
MSA
V25309
Dichlorodifluoromethane
<1.20
u9/L
1.20
5.00
1
10/19/22 02:25
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 33 of 60

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed Landfill
Chuck Pippin Report Date : 11/03/2022
231 Haywood Street Information : C21500-01.01, WA-1 Received : 10/12/2022
Asheville , NC 28801
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90501
Matrix: Aqueous
Sample ID: SW-02-OLD-20221010
Sampled:
10/10/2022 15:09
Analytical Method: 8260D
Prep Batch(es):
V25308
10/18/22 14:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.240
Ng/L
0.240
0.500
1
10/19/22 02:25
MSA
V25309
1,2-Dichloroethane
<0.150
ug/L
0.150
0.500
1
10/19/22 02:25
MSA
V25309
1,1-Dichloroethene
<0.150
Ng/L
0.150
0.500
1
10/19/22 02:25
MSA
V25309
cis- 1,2-Dich loroethene
<0.200
ug/L
0.200
0.500
1
10/19/22 02:25
MSA
V25309
trans-1,2-Dichloroethene
<0.180
Ng/L
0.180
0.500
1
10/19/22 02:25
MSA
V25309
1,2-Dichloropropane
<0.190
ug/L
0.190
0.500
1
10/19/22 02:25
MSA
V25309
cis- 1,3-Dich loropropene
<0.210
Ng/L
0.210
0.500
1
10/19/22 02:25
MSA
V25309
trans-1,3-Dichloropropene
<0.150
ug/L
0.150
0.500
1
10/19/22 02:25
MSA
V25309
1,4-Dioxane
<16.0
Ng/L
16.0
150
1
10/19/22 02:25
MSA
V25309
Ethylbenzene
<0.170
ug/L
0.170
0.500
1
10/19/22 02:25
MSA
V25309
2-Hexanone
<0.380
Ng/L
0.380
5.00
1
10/19/22 02:25
MSA
V25309
Methyl Ethyl Ketone (MEK)
<0.710
ug/L
0.710
5.00
1
10/19/22 02:25
MSA
V25309
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
10/19/22 02:25
MSA
V25309
Methylene Chloride
<0.330
ug/L
0.330
1.00
1
10/19/22 02:25
MSA
V25309
Styrene
<0.220
Ng/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
1,1,1,2-Tetrachloroethane
<0.160
ug/L
0.160
0.500
1
10/19/22 02:25
MSA
V25309
1,1,2,2-Tetrachloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 02:25
MSA
V25309
Tetrachloroethene
<0.220
ug/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
Tetrahydrofuran
<1.50
Ng/L
1.50
10.0
1
10/19/22 02:25
MSA
V25309
Toluene
<0.220
ug/L
0.220
0.500
1
10/19/22 02:25
MSA
V25309
1,1,1-Trichloroethane
<0.160
Ng/L
0.160
0.500
1
10/19/22 02:25
MSA
V25309
1,1,2-Trichloroethane
<0.096
ug/L
0.096
0.500
1
10/19/22 02:25
MSA
V25309
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 34 of 60

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed Landfill
Report Date : 11/03/2022
Information : C21500-01.01, WA-1 Received : 10/12/2022
Report Number : 22-285-0100 REPOR T OF A NA L YSIS
Lab No : 90501 Matrix: Aqueous
Sample ID: SW-02-OLD-20221010 Sampled: 10/10/2022 15:09
Analytical Method: 8260D
Prep Method: 5030E
Test Results
Trichloroethene
<0.180
Trichlorofluoromethane
<0.180
1,2,3-Trichloropropane
<0.270
Vinyl Acetate
<1.00
Vinyl Chloride
<0.170
o-Xylene
<0.210
m,p-Xylene
<0.420
Xylene (Total)
<0.21
Surrogate: 4-Bromofluorobenzene
Surrogate: Dibromofluoromethane
Surrogate: 1,2-Dichloroethane - d4
Surrogate: Toluene-d8
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
Prep Batch(es): V25308 10/18/22 14:00
Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Ng/L
0.180 0.500
Pg/L
0.180 0.500
Ng/L
0.270 1.00
Pg/L
1.00 2.00
Ng/L
0.170 0.500
Pg/L
0.210 0.500
Ng/L
0.420 1.00
Pg/L
0.210 0.500
99.8
Limits: 80-124%
109
Limits: 75-129%
94.2
Limits: 63-136%
97.6
Limits: 77-123%
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
1 10/19/22 02:25 MSA V25309
J Estimated value
Page 35 of 60

•
Waypoint,
449 Springbrook
Charlotte, NC 28217
Rd, Ch
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill
Report No: 22-285-0100
QC Analytical Batch: V25345
Analysis Method: 2340C-2011
Analysis Description: Total Hardness
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples: 90500, 90501
Blank MDL
MQL
Analyzed
Parameter Units
Result
Hardness pg/L
<570 570
5000
10/20/22 11:50
Laboratory Control Sample
LCS
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Hardness pg/L
50000
50500
101 90-110
Duplicate
V 90500-DUP
Result DUP
RPD Max RPD
Analyzed
Parameter Units
Result
Hardness pg/L
66000 64000
3.0 20
10/20/22 11:50
Matrix Spike & Matrix Spike Duplicate
V 90501-MS V 90501-MSD
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Hardness pg/L
66000 20000
20000 88000
86000 110 100 80-120 2.2 20
Date: 11/03/2022 12:49 PM Page 1 of 23
Page 36 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25778
QC Analytical Batch(es): V25780
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V25778
Matrix: AQU
Associated Lab Samples:
90494, 90495, 90496
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Dissolved Arsenic
pg/L
<0.490
0.490
1.00
10/31/22 17:43
Dissolved Barium
pg/L
<3.40
3.40
10.0
10/31/22 17:43
Dissolved Cadmium
pg/L
<0.150
0.150
1.00
10/31/22 17:43
Dissolved Chromium
pg/L
<1.00
1.00
2.00
10/31/22 17:43
Dissolved Lead
pg/L
<0.500
0.500
1.00
10/31/22 17:43
Dissolved Selenium
pg/L
<2.30
2.30
5.00
10/31/22 17:43
Dissolved Silver
pg/L
<0.130
0.130
1.00
10/31/22 17:43
Laboratory Control Sample
LCS-V25778
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Dissolved Arsenic
pg/L
100
86.7
87.0
80-120
Dissolved Barium
pg/L
100
92.2
92.0
80-120
Dissolved Cadmium
pg/L
100
92.2
92.0
80-120
Dissolved Chromium
pg/L
100
89.8
90.0
80-120
Dissolved Lead
pg/L
100
89.3
89.0
80-120
Dissolved Selenium
pg/L
100
87.5
88.0
80-120
Dissolved Silver
pg/L
100
89.5
90.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 90494-V25776-MS-V25778 V 90494-V25776-MSD-V25778
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result
Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Dissolved Arsenic
pg/L
< 0.490
100
100 95.5
91.9 96.0
92.0
75-125 3.8 20.0
Dissolved Barium
pg/L
359
100
100 471
539 112
180*
75-125 13.4 20.0
Dissolved Cadmium
pg/L
< 0.150
100
100 97.9
94.2 98.0
94.0
75-125 3.8 20.0
Dissolved Chromium
pg/L
< 1.00
100
100 85.8
84.1 86.0
84.0
75-125 2.0 20.0
* QC Fail Date: 11/03/2022 12:49 PM Page 2 of 23
Page 37 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25778 QC Analytical Batch(es): V25780
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Matrix Spike & Matrix Spike Duplicate V 90494-V25776-MS-V25778 V 90494-V25776-MSD-V25778
MS Spike MSD MS Result MSD MS MSD %Rec Max
Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD
Conc.
Dissolved Lead
ug/L
< 0.500 100 100 90.6 88.4 91.0 88.0 75-125 2.4 20.0
Dissolved Selenium
ug/L
< 2.30 100 100 110 103 110 103 75-125 6.5 20.0
Dissolved Silver
ug/L
< 0.130 100 100 51.7 19.3 52.0* 19.0* 75-125 91.2* 20.0
Post Digestion Spike
V 90494-V25776-PDS-V25778
Parameter
PDS 0/0
Units Result Recovery
Analyzed
Dissolved Arsenic
ug/L
52.9
106
10/31/22 18:16
Dissolved Barium
ug/L
236
275*
10/31/22 18:16
Dissolved Cadmium
ug/L
53.8
108
10/31/22 18:16
Dissolved Chromium
ug/L
49.6
99.0
10/31/22 18:16
Dissolved Lead
ug/L
51.0
102
10/31/22 18:16
Dissolved Selenium
ug/L
53.8
108
10/31/22 18:16
Dissolved Silver
ug/L
41.7
83.0
10/31/22 18:16
* QC Fail Date: 11/03/2022 12:49 PM Page 3 of 23
Page 38 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25794
QC Analytical Batch(es): V25811
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V25794
Matrix: AQU
Associated Lab Samples:
90494, 90495, 90496, 90500, 90501
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
pg/L
<0.490 0.490
1.00
10/31/22 20:03
Barium
pg/L
<3.40 3.40
10.0
10/31/22 20:03
Cadmium
pg/L
<0.150 0.150
1.00
10/31/22 20:03
Chromium
pg/L
<1.00 1.00
2.00
10/31/22 20:03
Lead
pg/L
<0.500 0.500
1.00
10/31/22 20:03
Selenium
pg/L
<2.30 2.30
5.00
10/31/22 20:03
Silver
pg/L
<0.130 0.130
1.00
10/31/22 20:03
Laboratory Control Sample
LCS-V25794
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
pg/L
100
87.8
88.0
80-120
Barium
pg/L
100
98.4
98.0
80-120
Cadmium
pg/L
100
96.5
97.0
80-120
Chromium
pg/L
100
91.1
91.0
80-120
Lead
pg/L
100
93.8
94.0
80-120
Selenium
pg/L
100
91.5
92.0
80-120
Silver
pg/L
100
93.1
93.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 90494-MS-V25794
V 90494-MSD-V25794
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Arsenic
pg/L
0.671 100
100 89.1
89.7 88.0
89.0
75-125 0.6 20.0
Barium
pg/L
573 100
100 684
679 111
106
75-125 0.7 20.0
Cadmium
pg/L
< 0.150 100
100 98.3
98.9 98.0
99.0
75-125 0.6 20.0
Chromium
pg/L
< 1.00 100
100 88.7
88.8 89.0
89.0
75-125 0.1 20.0
Date: 11/03/2022
12:49 PM
Page 4 of 23
Page 39 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25794
QC Analytical Batch(es): V25811
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 90494-MS-V25794
V 90494-MSD-V25794
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
ug/L
< 0.500 100
100 94.9
94.1 95.0
94.0 75-125 0.8 20.0
Selenium
ug/L
< 2.30 100
100 88.2
91.2 88.0
91.0 75-125 3.3 20.0
Silver
ug/L
< 0.130 100
100 92.5
92.2 93.0
92.0 75-125 0.3 20.0
Post Digestion Spike
V 90494-PDS-V25794
PDS
%
Analyzed
Parameter
Units
Result Recovery
Arsenic
ug/L
50.0
99.0
10/31/22 21:10
Barium
ug/L
345
321*
10/31/22 21:10
Cadmium
ug/L
54.2
108
10/31/22 21:10
Chromium
ug/L
49.1
98.0
10/31/22 21:10
Lead
ug/L
50.9
102
10/31/22 21:10
Selenium
ug/L
49.5
99.0
10/31/22 21:10
Silver
ug/L
50.4
101
10/31/22 21:10
* QC Fail Date: 11/03/2022 12:49 PM Page 5 of 23
Page 40 of 60

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill
Report No: 22-285-0100
QC Prep: V25142
QC Analytical Batch(es): V25177
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V25142
Matrix: AQU
Associated Lab Samples: 90494, 90495, 90496, 90500, 90501
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) mg/L <0.00007 0.00007
0.00020
10/14/22 16:02
Laboratory Control Sample
LCS-V25142
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) mg/L
0.00937
0.00957
102 80-120
Matrix Spike & Matrix Spike Duplicate
V 90494-MS-V25142
V 90494-MSD-V25142
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) mg/L < 0.00007 0.00937
0.00937 0.00706
0.00675 75.0* 72.0* 80-120 4.4 20.0
Post Digestion Spike
V 90494-PDS-V25142
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) mg/L
0.00422
90.0
10/14/22 17:38
* QC Fail Date: 11/03/2022 12:49 PM Page 6 of 23
Page 41 of 60

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
Landfill
Report No: 22-285-0100
QC Prep: V25422
QC Analytical Batch(es): V25487
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V25422
Matrix: AQU
Associated Lab Samples: 90494, 90495, 90496
Blank MDL
MQL
Analyzed
Parameter Units
Result
Dissolved Mercury mg/L
0.000 0.000
0.00020
10/24/22 15:17
Laboratory Control Sample
LCS-V25422
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Dissolved Mercury mg/L
0.00937
0.00950
101 80-120
Matrix Spike & Matrix Spike Duplicate
V 90496-V25365-MS-V25422 V 90496-V25365-MSD-V25422
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Dissolved Mercury mg/L < 0.00007 0.00937
0.00937 0.00917
0.00913 98.0 97.0 80-120 0.4 20.0
Post Digestion Spike
V 90496-V25365-PDS-V25422
PDS
%
Analyzed
Parameter Units
Result
Recovery
Dissolved Mercury mg/L
0.00455
97.0
10/24/22 15:53
Date: 11/03/2022 12:49 PM Page 7 of 23
Page 42 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25081
QC Analytical Batch(es): V25082
QC Prep Batch Method:
5030B
Analysis Method:
8260D SIM
Analysis Description:
Volatile Organic Compounds -
GC/MS
Lab Reagent Blank
LRB-V25081
Matrix: AQU
Associated Lab Samples:
90494, 90495, 90496, 90500, 90501
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
1,4-Dioxane
pg/L
<0.139 0.139
2.00
10/13/2217:56
4-Bromofluorobenzene (S)
10/13/22 17:56
103
70-130
Laboratory Control Sample
LCS-V25081
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
1,4-Dioxane
pg/L
50.0
45.5
91.0
70-130
4-Bromofluorobenzene (S)
102
70-130
Matrix Spike & Matrix Spike Duplicate
V 90501-MS-V25081
V 90501-MSD-V25081
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec
Limits RPD
Conc.
1,4-Dioxane
pg/L
< 0.139 50.0
50.0 49.6
47.3 99.2
94.6
70-130
4-Bromofluorobenzene (S)
105
114
70-130
Date: 11/03/2022 12:49 PM Page 8 of 23
Page 43 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25192
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V25193
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25192 Matrix: AQU
Associated Lab Samples: 90494, 90495, 90496, 90498, 90499, 90500
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
10/15/22 11:30
Acrylonitrile
pg/L
<0.230
0.230
5.00
10/15/22 11:30
Benzene
pg/L
<0.180
0.180
0.500
10/15/22 11:30
Bromochloromethane
pg/L
<0.420
0.420
1.00
10/15/22 11:30
Bromodichloromethane
pg/L
<0.160
0.160
0.500
10/15/22 11:30
Bromoform
pg/L
<1.50
1.50
5.00
10/15/22 11:30
Bromomethane
pg/L
<0.280
0.280
1.00
10/15/22 11:30
Carbon Disulfide
pg/L
<0.150
0.150
5.00
10/15/22 11:30
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
10/15/22 11:30
Chlorobenzene
pg/L
<0.190
0.190
0.500
10/15/22 11:30
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
10/15/22 11:30
Chloroethane
pg/L
<0.430
0.430
1.00
10/15/22 11:30
Chloroform
pg/L
<0.220
0.220
0.500
10/15/22 11:30
Chloromethane
pg/L
<0.220
0.220
0.500
10/15/22 11:30
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
10/15/22 11:30
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
10/15/22 11:30
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
10/15/22 11:30
Dibromomethane
pg/L
<0.230
0.230
0.500
10/15/22 11:30
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
10/15/22 11:30
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
10/15/22 11:30
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
10/15/22 11:30
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
10/15/22 11:30
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
10/15/22 11:30
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
10/15/22 11:30
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
10/15/22 11:30
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
10/15/22 11:30
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
10/15/22 11:30
Date:
11/03/2022 12:49 PM
Page 9 of 23
Page 44 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25192
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V25193
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25192 Matrix: AQU
Associated Lab Samples: 90494, 90495, 90496, 90498, 90499, 90500
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
1,4-Dioxane
Ethylbenzene
2-Hexanone
Methyl Ethyl Ketone (MEK)
4-M ethyl-2-Penta none
Methylene Chloride
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Tetrahydrofuran
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl Acetate
Vinyl Chloride
o-Xylene
m,p-Xylene
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
1,2-Dichloroethane - d4 (S)
pg/L
<0.190
0.190
0.500
pg/L
<0.210
0.210
0.500
pg/L
<0.150
0.150
0.500
pg/L
<16.0
16.0
150
pg/L
<0.170
0.170
0.500
pg/L
<0.380
0.380
5.00
pg/L
<0.710
0.710
5.00
pg/L
<1.00
1.00
5.00
pg/L
<0.330
0.330
1.00
pg/L
<0.220
0.220
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.220
0.220
0.500
pg/L
<1.50
1.50
10.0
pg/L
<0.220
0.220
0.500
pg/L
<0.160
0.160
0.500
pg/L
<0.096
0.096
0.500
pg/L
<0.180
0.180
0.500
pg/L
<0.180
0.180
0.500
pg/L
<0.270
0.270
1.00
pg/L
<1.00
1.00
2.00
pg/L
<0.170
0.170
0.500
pg/L
<0.210
0.210
0.500
pg/L
<0.420
0.420
1.00
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
10/15/22 11:30
101
97.8
98.0
80-124
75-129
63-136
Date: 11/03/2022 12:49 PM Page 10 of 23
Page 45 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25192
QC Analytical Batch(es): V25193
QC Prep Batch Method:
5030B
Analysis
Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V25192
Matrix: AQU
Associated Lab Samples:
90494, 90495, 90496, 90498, 90499, 90500
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8(S)
10/15/22 11:30
100
77-123
Laboratory Control Sample
& LCSD
LCS-V25192 LCSD-V25192
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
37.8
40.3
94.5
101
40-166
6.4
20.0
Acrylonitrile
pg/L
40.0
42.5
42.1
106
105
81-127
0.9
20.0
Benzene
pg/L
20.0
19.6
19.4
98.0
97.0
77-128
1.0
20.0
Bromochloromethane
pg/L
20.0
20.8
20.2
104
101
78-135
2.9
20.0
Bromodichloromethane
pg/L
20.0
17.9
18.1
89.5
90.5
76-138
1.1
20.0
Bromoform
pg/L
20.0
20.5
19.5
103
97.5
71-135
5.0
20.0
Bromomethane
pg/L
20.0
20.1
19.2
101
96.0
41-168
4.5
20.0
Carbon Disulfide
pg/L
20.0
20.2
19.7
101
98.5
59-135
2.5
20.0
Carbon Tetrachloride
pg/L
20.0
18.9
19.3
94.5
96.5
72-142
2.0
20.0
Chlorobenzene
pg/L
20.0
20.1
19.6
101
98.0
78-119
2.5
20.0
Chlorodibromomethane
pg/L
20.0
19.1
19.0
95.5
95.0
75-134
0.5
20.0
Chloroethane
pg/L
20.0
20.2
19.5
101
97.5
57-142
3.5
20.0
Chloroform
pg/L
20.0
19.5
19.0
97.5
95.0
77-130
2.5
20.0
Chloromethane
pg/L
20.0
20.0
19.2
100
96.0
47-145
4.0
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
19.8
19.2
99.0
96.0
60-154
3.0
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
21.6
20.1
108
101
63-134
7.1
20.0
1,2-Dibromoethane
pg/L
20.0
19.5
19.4
97.5
97.0
77-135
0.5
20.0
Dibromomethane
pg/L
20.0
19.3
18.5
96.5
92.5
76-138
4.2
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
19.9
19.2
99.5
96.0
70-130
3.5
20.0
1,2-Dichlorobenzene
pg/L
20.0
21.1
20.1
106
101
78-128
4.8
20.0
1,4-Dichlorobenzene
pg/L
20.0
20.2
19.5
101
97.5
75-126
3.5
20.0
Date: 11/03/2022 12:49 PM Page 11 of 23
Page 46 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25192 QC Analytical Batch(es): V25193
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V25192 LCSD-V25192
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Dichlorodifluoromethane
pg/L
20.0
23.9
22.4
120
112
28-163
6.4
20.0
1,1-Dichloroethane
pg/L
20.0
19.2
19.4
96.0
97.0
70-130
1.0
20.0
1,2-Dichloroethane
pg/L
20.0
18.2
17.7
91.0
88.5
68-131
2.7
20.0
1,1-Dichloroethene
pg/L
20.0
19.8
19.1
99.0
95.5
70-154
3.5
20.0
cis-1,2-Dichloroethene
pg/L
20.0
19.3
18.6
96.5
93.0
76-141
3.6
20.0
trans-1,2-Dichloroethene
pg/L
20.0
19.3
19.1
96.5
95.5
76-135
1.0
20.0
1,2-Dichloropropane
pg/L
20.0
20.6
19.2
103
96.0
77-130
7.0
20.0
cis-1,3-Dichloropropene
pg/L
20.0
18.6
17.7
93.0
88.5
65-140
4.9
20.0
trans-1,3-Dichloropropene
pg/L
20.0
18.6
17.7
93.0
88.5
67-140
4.9
20.0
1,4-Dioxane
pg/L
200
180
179
90.0
89.5
70-130
0.5
20.0
Ethylbenzene
pg/L
20.0
19.2
18.5
96.0
92.5
80-127
3.7
20.0
2-Hexanone
pg/L
20.0
17.7
17.8
88.5
89.0
64-137
0.5
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
20.2
19.4
101
97.0
71-134
4.0
20.0
4-Methyl-2-Pentanone
pg/L
20.0
18.9
18.2
94.5
91.0
69-134
3.7
20.0
Methylene Chloride
pg/L
20.0
18.2
17.8
91.0
89.0
73-131
2.2
20.0
Styrene
pg/L
20.0
19.3
19.3
96.5
96.5
78-129
0.0
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
20.2
19.8
101
99.0
79-134
2.0
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
17.8
17.1
89.0
85.5
62-127
4.0
20.0
Tetrachloroethene
pg/L
20.0
20.4
19.5
102
97.5
80-129
4.5
20.0
Tetrahydrofuran
pg/L
20.0
19.8
20.9
99.0
105
70-130
5.4
20.0
Toluene
pg/L
20.0
19.2
18.9
96.0
94.5
76-131
1.5
20.0
1,1,1-Trichloroethane
pg/L
20.0
19.7
18.9
98.5
94.5
75-135
4.1
20.0
1,1,2-Trichloroethane
pg/L
20.0
19.6
19.4
98.0
97.0
70-140
1.0
20.0
Trichloroethene
pg/L
20.0
21.5
20.7
108
104
77-133
3.7
20.0
Trichlorofluoromethane
pg/L
20.0
20.6
19.0
103
95.0
62-148
8.0
20.0
1,2,3-Trichloropropane
pg/L
20.0
18.6
18.7
93.0
93.5
71-127
0.5
20.0
Date: 11/03/2022 12:49 PM Page 12 of 23
Page 47 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25192
QC Analytical Batch(es): V25193
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V25192 LCSD-V25192
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec
% Rec
Limits
RPD
Max
RPD
Vinyl Acetate
pg/L
20.0
10.5 10.3
52.5
51.5
34-167
1.9
20.0
Vinyl Chloride
pg/L
20.0
21.9 21.0
110
105
57-141
4.1
20.0
o-Xylene
pg/L
20.0
19.1 18.5
95.5
92.5
78-128
3.1
20.0
m,p-Xylene
pg/L
40.0
39.8 38.4
99.5
96.0
77-133
3.5
20.0
4-Bromofluorobenzene (S)
100
100
80-124
Dibromofluoromethane (S)
101
100
75-129
1,2-Dichloroethane - d4 (S)
98.6
99.2
63-136
Toluene-d8(S)
101
101
77-123
Date: 11/03/2022 12:49 PM Page 13 of 23
Page 48 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25308
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V25309
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25308 Matrix: AQU
Associated Lab Samples: 90501
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
10/18/22 23:19
Acrylonitrile
pg/L
<0.230
0.230
5.00
10/18/22 23:19
Benzene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Bromochloromethane
pg/L
<0.420
0.420
1.00
10/18/22 23:19
Bromodichloromethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
Bromoform
pg/L
<1.50
1.50
5.00
10/18/22 23:19
Bromomethane
pg/L
<0.280
0.280
1.00
10/18/22 23:19
Carbon Disulfide
pg/L
<0.150
0.150
5.00
10/18/22 23:19
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Chlorobenzene
pg/L
<0.190
0.190
0.500
10/18/22 23:19
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
10/18/22 23:19
Chloroethane
pg/L
<0.430
0.430
1.00
10/18/22 23:19
Chloroform
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Chloromethane
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
10/18/22 23:19
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
10/18/22 23:19
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
10/18/22 23:19
Dibromomethane
pg/L
<0.230
0.230
0.500
10/18/22 23:19
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
10/18/22 23:19
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
10/18/22 23:19
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
10/18/22 23:19
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
10/18/22 23:19
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
10/18/22 23:19
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
10/18/22 23:19
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Date:
11/03/2022 12:49 PM
Page 14 of 23
Page 49 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25308 QC Analytical Batch(es): V25309
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25308 Matrix: AQU
Associated Lab Samples: 90501
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
1,2-Dichloropropane
pg/L
<0.190
0.190
0.500
10/18/22 23:19
cis-1,3-Dichloropropene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
trans-1,3-Dichloropropene
pg/L
<0.150
0.150
0.500
10/18/22 23:19
1,4-Dioxane
pg/L
<16.0
16.0
150
10/18/22 23:19
Ethylbenzene
pg/L
<0.170
0.170
0.500
10/18/22 23:19
2-Hexanone
pg/L
<0.380
0.380
5.00
10/18/22 23:19
Methyl Ethyl Ketone (MEK)
pg/L
<0.710
0.710
5.00
10/18/22 23:19
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
10/18/22 23:19
Methylene Chloride
pg/L
<0.330
0.330
1.00
10/18/22 23:19
Styrene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,1,1,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
1,1,2,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
Tetrachloroethene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
Tetrahydrofuran
pg/L
<1.50
1.50
10.0
10/18/22 23:19
Toluene
pg/L
<0.220
0.220
0.500
10/18/22 23:19
1,1,1-Trichloroethane
pg/L
<0.160
0.160
0.500
10/18/22 23:19
1,1,2-Trichloroethane
pg/L
<0.096
0.096
0.500
10/18/22 23:19
Trichloroethene
pg/L
<0.180
0.180
0.500
10/18/22 23:19
Trichlorofluoromethane
pg/L
<0.180
0.180
0.500
10/18/22 23:19
1,2,3-Trichloropropane
pg/L
<0.270
0.270
1.00
10/18/22 23:19
Vinyl Acetate
pg/L
<1.00
1.00
2.00
10/18/22 23:19
Vinyl Chloride
pg/L
<0.170
0.170
0.500
10/18/22 23:19
o-Xylene
pg/L
<0.210
0.210
0.500
10/18/22 23:19
m,p-Xylene
pg/L
<0.420
0.420
1.00
10/18/22 23:19
4-Bromofluorobenzene (S)
10/18/22 23:19
98.2 80-124
Dibromofluoromethane (S)
10/18/22 23:19
111 75-129
1,2-Dichloroethane - d4 (S)
10/18/22 23:19
93.4 63-136
Date:
11/03/2022 12:49 PM
Page 15 of 23
Page 50 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25308
QC Analytical Batch(es): V25309
QC Prep Batch Method:
5030B
Analysis
Method:
8260D
Analysis
Description:
Volatile Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V25308
Matrix: AQU
Associated Lab Samples:
90501
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8 (S)
10/18/22 23:19
98.8
77-123
Laboratory Control Sample & LCSD
LCS-V25308 LCSD-V25308
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
59.0
43.6
148
109
40-166
30.0*
20.0
Acrylonitrile
pg/L
40.0
47.9
42.8
120
107
81-127
11.2
20.0
Benzene
pg/L
20.0
21.2
21.0
106
105
77-128
0.9
20.0
Bromochloromethane
pg/L
20.0
20.5
20.3
103
102
78-135
0.9
20.0
Bromodichloromethane
pg/L
20.0
26.9
27.0
135
135
76-138
0.3
20.0
Bromoform
pg/L
20.0
26.3
27.9
132
140*
71-135
5.9
20.0
Bromomethane
pg/L
20.0
18.4
18.2
92.0
91.0
41-168
1.0
20.0
Chlorobenzene
pg/L
20.0
21.6
20.7
108
104
78-119
4.2
20.0
Chlorodibromomethane
pg/L
20.0
24.1
23.4
121
117
75-134
2.9
20.0
Chloroethane
pg/L
20.0
20.5
20.5
103
103
57-142
0.0
20.0
Chloroform
pg/L
20.0
22.4
21.9
112
110
77-130
2.2
20.0
Chloromethane
pg/L
20.0
20.2
19.9
101
99.5
47-145
1.4
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
21.1
21.5
106
108
60-154
1.8
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
23.5
21.4
118
107
63-134
9.3
20.0
1,2-Dibromoethane
pg/L
20.0
25.5
24.9
128
125
77-135
2.3
20.0
Dibromomethane
pg/L
20.0
23.6
23.5
118
118
76-138
0.4
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
29.5
22.7
148*
114
70-130
26.0*
20.0
1,2-Dichlorobenzene
pg/L
20.0
20.0
20.2
100
101
78-128
0.9
20.0
1,4-Dichlorobenzene
pg/L
20.0
19.9
20.3
99.5
102
75-126
1.9
20.0
Dichlorodifluoromethane
pg/L
20.0
20.2
19.7
101
98.5
28-163
2.5
20.0
1,1-Dichloroethane
pg/L
20.0
22.4
21.8
112
109
70-130
2.7
20.0
* QC Fail
Date:
11/03/2022
12:49 PM
Page 16 of 23
Page 51
of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25308 QC Analytical Batch(es): V25309
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V25308 LCSD-V25308
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
1,2-Dichloroethane
pg/L
20.0
20.9
19.6
105
98.0
68-131
6.4
20.0
1,1-Dichloroethene
pg/L
20.0
20.8
21.3
104
107
70-154
2.3
20.0
cis-1,2-Dichloroethene
pg/L
20.0
21.5
21.8
108
109
76-141
1.3
20.0
trans-1,2-Dichloroethene
pg/L
20.0
20.3
20.6
102
103
76-135
1.4
20.0
1,2-Dichloropropane
pg/L
20.0
21.3
21.5
107
108
77-130
0.9
20.0
cis-1,3-Dichloropropene
pg/L
20.0
21.4
21.2
107
106
65-140
0.9
20.0
trans-1,3-Dichloropropene
pg/L
20.0
27.8
27.6
139
138
67-140
0.7
20.0
1,4-Dioxane
pg/L
200
168
169
84.0
84.5
70-130
0.5
20.0
Ethylbenzene
pg/L
20.0
21.3
20.8
107
104
80-127
2.3
20.0
2-Hexanone
pg/L
20.0
24.0
20.4
120
102
64-137
16.2
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
18.3
14.2
91.5
71.0
71-134
25.2*
20.0
4-Methyl-2-Pentanone
pg/L
20.0
22.7
20.5
114
103
69-134
10.1
20.0
Methylene Chloride
pg/L
20.0
22.0
20.6
110
103
73-131
6.5
20.0
Styrene
pg/L
20.0
20.4
20.9
102
105
78-129
2.4
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
26.8
26.1
134
131
79-134
2.6
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
25.4
24.4
127
122
62-127
4.0
20.0
Tetrachloroethene
pg/L
20.0
21.3
20.8
107
104
80-129
2.3
20.0
Tetrahydrofuran
pg/L
20.0
22.9
22.2
115
111
70-130
3.1
20.0
Toluene
pg/L
20.0
21.8
21.3
109
107
76-131
2.3
20.0
1,1,1-Trichloroethane
pg/L
20.0
25.7
26.2
129
131
75-135
1.9
20.0
1,1,2-Trichloroethane
pg/L
20.0
23.5
22.5
118
113
70-140
4.3
20.0
Trichloroethene
pg/L
20.0
21.9
22.1
110
111
77-133
0.9
20.0
Trichlorofluoromethane
pg/L
20.0
21.6
20.9
108
105
62-148
3.2
20.0
1,2,3-Trichloropropane
pg/L
20.0
23.0
20.6
115
103
71-127
11.0
20.0
Vinyl Acetate
pg/L
20.0
23.1
20.0
116
100
34-167
14.3
20.0
Vinyl Chloride
pg/L
20.0
19.7
19.6
98.5
98.0
57-141
0.5
20.0
* QC Fail Date: 11/03/2022 12:49 PM Page 17 of 23
Page 52 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25308
QC Analytical Batch(es): V25309
QC Prep Batch Method: 5030B
Analysis Method:
8260D
Analysis Description:
Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD
LCS-V25308
LCSD-V25308
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter Units
Conc.
Result Result
%Rec
% Rec
Limits RPD
Max
RPD
o-Xylene pg/L
20.0
20.8 20.4
104
102
78-128 1.9
20.0
m,p-Xylene pg/L
40.0
43.1 42.8
108
107
77-133 0.6
20.0
4-Bromofluorobenzene (S)
100
102
80-124
Dibromofluoromethane (S)
118
119
75-129
1,2-Dichloroethane - d4 (S)
97.4
93.6
63-136
Toluene-d8 (S)
97.0
98.4
77-123
Date: 11/03/2022 12:49 PM Page 18 of 23
Page 53 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25332
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V25333
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25332 Matrix: AQU
Associated Lab Samples: 90497
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<1.80
1.80
5.00
10/19/22 12:12
Acrylonitrile
pg/L
<0.230
0.230
5.00
10/19/22 12:12
Benzene
pg/L
<0.180
0.180
0.500
10/19/22 12:12
Bromochloromethane
pg/L
<0.420
0.420
1.00
10/19/22 12:12
Bromodichloromethane
pg/L
<0.160
0.160
0.500
10/19/22 12:12
Bromoform
pg/L
<1.50
1.50
5.00
10/19/22 12:12
Bromomethane
pg/L
<0.280
0.280
1.00
10/19/22 12:12
Carbon Disulfide
pg/L
<0.150
0.150
5.00
10/19/22 12:12
Carbon Tetrachloride
pg/L
<0.180
0.180
0.500
10/19/22 12:12
Chlorobenzene
pg/L
<0.190
0.190
0.500
10/19/22 12:12
Chlorodibromomethane
pg/L
<0.190
0.190
0.500
10/19/22 12:12
Chloroethane
pg/L
<0.430
0.430
1.00
10/19/22 12:12
Chloroform
pg/L
<0.220
0.220
0.500
10/19/22 12:12
Chloromethane
pg/L
<0.220
0.220
0.500
10/19/22 12:12
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
10/19/22 12:12
1,2-Dibromo-3-Chloropropane
pg/L
<1.10
1.10
2.00
10/19/22 12:12
1,2-Dibromoethane
pg/L
<0.200
0.200
0.500
10/19/22 12:12
Dibromomethane
pg/L
<0.230
0.230
0.500
10/19/22 12:12
trans-1,4-Dichloro-2-butene
pg/L
< 1.30
1.30
10.0
10/19/22 12:12
1,2-Dichlorobenzene
pg/L
<0.220
0.220
0.500
10/19/22 12:12
1,4-Dichlorobenzene
pg/L
<0.210
0.210
0.500
10/19/22 12:12
Dichlorodifluoromethane
pg/L
<1.20
1.20
5.00
10/19/22 12:12
1,1-Dichloroethane
pg/L
<0.240
0.240
0.500
10/19/22 12:12
1,2-Dichloroethane
pg/L
<0.150
0.150
0.500
10/19/22 12:12
1,1-Dichloroethene
pg/L
<0.150
0.150
0.500
10/19/22 12:12
cis-1,2-Dichloroethene
pg/L
<0.200
0.200
0.500
10/19/22 12:12
trans-1,2-Dichloroethene
pg/L
<0.180
0.180
0.500
10/19/22 12:12
Date:
11/03/2022 12:49 PM
Page 19 of 23
Page 54 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25332 QC Analytical Batch(es): V25333
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V25332 Matrix: AQU
Associated Lab Samples: 90497
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
1,2-Dichloropropane
pg/L
<0.190
0.190
0.500
10/19/22 12:12
cis-1,3-Dichloropropene
pg/L
<0.210
0.210
0.500
10/19/22 12:12
trans-1,3-Dichloropropene
pg/L
<0.150
0.150
0.500
10/19/22 12:12
1,4-Dioxane
pg/L
<16.0
16.0
150
10/19/22 12:12
Ethylbenzene
pg/L
<0.170
0.170
0.500
10/19/22 12:12
2-Hexanone
pg/L
<0.380
0.380
5.00
10/19/22 12:12
Methyl Ethyl Ketone (MEK)
pg/L
<0.710
0.710
5.00
10/19/22 12:12
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
10/19/22 12:12
Methylene Chloride
pg/L
<0.330
0.330
1.00
10/19/22 12:12
Styrene
pg/L
<0.220
0.220
0.500
10/19/22 12:12
1,1,1,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/19/22 12:12
1,1,2,2-Tetrachloroethane
pg/L
<0.160
0.160
0.500
10/19/22 12:12
Tetrachloroethene
pg/L
<0.220
0.220
0.500
10/19/22 12:12
Tetrahydrofuran
pg/L
<1.50
1.50
10.0
10/19/22 12:12
Toluene
pg/L
<0.220
0.220
0.500
10/19/22 12:12
1,1,1-Trichloroethane
pg/L
<0.160
0.160
0.500
10/19/22 12:12
1,1,2-Trichloroethane
pg/L
<0.096
0.096
0.500
10/19/22 12:12
Trichloroethene
pg/L
<0.180
0.180
0.500
10/19/22 12:12
Trichlorofluoromethane
pg/L
<0.180
0.180
0.500
10/19/22 12:12
1,2,3-Trichloropropane
pg/L
<0.270
0.270
1.00
10/19/22 12:12
Vinyl Acetate
pg/L
<1.00
1.00
2.00
10/19/22 12:12
Vinyl Chloride
pg/L
<0.170
0.170
0.500
10/19/22 12:12
o-Xylene
pg/L
<0.210
0.210
0.500
10/19/22 12:12
m,p-Xylene
pg/L
<0.420
0.420
1.00
10/19/22 12:12
4-Bromofluorobenzene (S)
10/19/22 12:12
99.2 80-124
Dibromofluoromethane (S)
10/19/22 12:12
98.2 75-129
1,2-Dichloroethane - d4 (S)
10/19/22 12:12
97.8 63-136
Date:
11/03/2022 12:49 PM
Page 20 of 23
Page 55 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25332
QC Analytical Batch(es): V25333
QC Prep Batch Method:
5030B
Analysis
Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V25332
Matrix: AQU
Associated Lab Samples:
90497
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8 (S)
10/19/22 12:12
101
77-123
Laboratory Control Sample
& LCSD
LCS-V25332 LCSD-V25332
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
38.6
41.2
96.5
103
40-166
6.5
20.0
Acrylonitrile
pg/L
40.0
43.8
43.4
110
109
81-127
0.9
20.0
Benzene
pg/L
20.0
20.4
20.1
102
101
77-128
1.4
20.0
Bromochloromethane
pg/L
20.0
21.4
21.5
107
108
78-135
0.4
20.0
Bromodichloromethane
pg/L
20.0
20.0
20.2
100
101
76-138
0.9
20.0
Bromoform
pg/L
20.0
22.2
21.7
111
109
71-135
2.2
20.0
Bromomethane
pg/L
20.0
19.9
20.6
99.5
103
41-168
3.4
20.0
Carbon Disulfide
pg/L
20.0
20.2
19.9
101
99.5
59-135
1.4
20.0
Carbon Tetrachloride
pg/L
20.0
20.2
19.9
101
99.5
72-142
1.4
20.0
Chlorobenzene
pg/L
20.0
20.7
20.5
104
103
78-119
0.9
20.0
Chlorodibromomethane
pg/L
20.0
20.9
20.9
105
105
75-134
0.0
20.0
Chloroethane
pg/L
20.0
20.3
19.9
102
99.5
57-142
1.9
20.0
Chloroform
pg/L
20.0
20.2
20.0
101
100
77-130
0.9
20.0
Chloromethane
pg/L
20.0
18.7
19.3
93.5
96.5
47-145
3.1
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
21.0
20.6
105
103
60-154
1.9
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
20.6
20.7
103
104
63-134
0.4
20.0
1,2-Dibromoethane
pg/L
20.0
20.4
19.9
102
99.5
77-135
2.4
20.0
Dibromomethane
pg/L
20.0
20.8
19.2
104
96.0
76-138
8.0
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
20.4
21.1
102
106
70-130
3.3
20.0
1,2-Dichlorobenzene
pg/L
20.0
20.2
20.0
101
100
78-128
0.9
20.0
1,4-Dichlorobenzene
pg/L
20.0
20.2
19.8
101
99.0
75-126
2.0
20.0
Date: 11/03/2022 12:49 PM Page 21 of 23
Page 56 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed Landfill
Report No: 22-285-0100
QC Prep: V25332 QC Analytical Batch(es): V25333
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V25332 LCSD-V25332
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Dichlorodifluoromethane
pg/L
20.0
19.3
19.4
96.5
97.0
28-163
0.5
20.0
1,1-Dichloroethane
pg/L
20.0
20.0
19.8
100
99.0
70-130
1.0
20.0
1,2-Dichloroethane
pg/L
20.0
18.6
18.3
93.0
91.5
68-131
1.6
20.0
1,1-Dichloroethene
pg/L
20.0
20.7
20.6
104
103
70-154
0.4
20.0
cis-1,2-Dichloroethene
pg/L
20.0
20.8
20.1
104
101
76-141
3.4
20.0
trans-1,2-Dichloroethene
pg/L
20.0
20.9
20.5
105
103
76-135
1.9
20.0
1,2-Dichloropropane
pg/L
20.0
20.2
20.3
101
102
77-130
0.4
20.0
cis-1,3-Dichloropropene
pg/L
20.0
20.4
20.0
102
100
65-140
1.9
20.0
trans-1,3-Dichloropropene
pg/L
20.0
20.4
20.0
102
100
67-140
1.9
20.0
1,4-Dioxane
pg/L
200
170
175
85.0
87.5
70-130
2.8
20.0
Ethylbenzene
pg/L
20.0
19.8
19.5
99.0
97.5
80-127
1.5
20.0
2-Hexanone
pg/L
20.0
19.2
19.7
96.0
98.5
64-137
2.5
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
22.3
21.3
112
107
71-134
4.5
20.0
4-Methyl-2-Pentanone
pg/L
20.0
19.8
20.4
99.0
102
69-134
2.9
20.0
Methylene Chloride
pg/L
20.0
18.6
18.5
93.0
92.5
73-131
0.5
20.0
Styrene
pg/L
20.0
20.6
20.0
103
100
78-129
2.9
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
20.9
20.5
105
103
79-134
1.9
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
20.2
19.3
101
96.5
62-127
4.5
20.0
Tetrachloroethene
pg/L
20.0
21.3
20.9
107
105
80-129
1.8
20.0
Tetrahydrofuran
pg/L
20.0
19.2
21.5
96.0
108
70-130
11.3
20.0
Toluene
pg/L
20.0
19.9
19.6
99.5
98.0
76-131
1.5
20.0
1,1,1-Trichloroethane
pg/L
20.0
20.9
20.1
105
101
75-135
3.9
20.0
1,1,2-Trichloroethane
pg/L
20.0
20.2
19.7
101
98.5
70-140
2.5
20.0
Trichloroethene
pg/L
20.0
21.0
20.9
105
105
77-133
0.4
20.0
Trichlorofluoromethane
pg/L
20.0
19.3
19.7
96.5
98.5
62-148
2.0
20.0
1,2,3-Trichloropropane
pg/L
20.0
20.3
20.3
102
102
71-127
0.0
20.0
Date: 11/03/2022 12:49 PM Page 22 of 23
Page 57 of 60

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed Landfill
Report No:
22-285-0100
QC Prep:
V25332
QC Analytical Batch(es): V25333
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V25332 LCSD-V25332
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec
% Rec
Limits
RPD
Max
RPD
Vinyl Acetate
pg/L
20.0
24.2 22.9
121
115
34-167
5.5
20.0
Vinyl Chloride
pg/L
20.0
19.6 19.4
98.0
97.0
57-141
1.0
20.0
o-Xylene
pg/L
20.0
20.0 19.5
100
97.5
78-128
2.5
20.0
m,p-Xylene
pg/L
40.0
41.4 40.4
104
101
77-133
2.4
20.0
4-Bromofluorobenzene (S)
99.6
99.6
80-124
Dibromofluoromethane (S)
101
103
75-129
1,2-Dichloroethane - d4 (S)
98.4
98.2
63-136
Toluene-d8(S)
101
101
77-123
Date: 11/03/2022 12:49 PM Page 23 of 23
Page 58 of 60

WayPAoint.
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01015
Customer Name: Anchor QEA of North Carolina, PLLC
Report Number: 22-285-0100
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client # Courier
0 Other:
Thermometer ID:
IRT-15 2.0 C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
# Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
# Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample Iabel(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
U Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
U Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
Special precautions or instructions included?
Comments:
0 Yes 0 No U N/A
F Low concentration EnCore samplers (48 hr)
Low conc pre -weighed vials (Sod Bis -14 d)
0Yes ONo
Signature: Angela D Overcash
Date & Time: 10/12/2022 15:33:38
Page 59 of 60

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Page 60 of 60