WS-3667_11700_CA_TCR_19980717

~Duke r-Power ...
A Duk< Energy Company
July 15, 1998
Ms. Sherry Knight
North Carolina Department of Environment
and Natural Resources
Winston Salem Regional Office
585 Waughtown St.
Winston-Salem, NC 27107-2241
Re: Duke Power Company
Burlington Operations Center
UST Closure Report
File: ENV-0309
Dear Ms. Knight:
Duke Power
526 South Church Street
P.O. Box 1006
Charlotte, NC 28201-1006
t"r 't:t'"" ,... " r f''\, . .. {--·:: ~ .. r -r~ "-, I r, ;· . . ···-
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Attached is the closure report for the removal of two underground storage tanks located at Duke
Power's Burlington Operations Center. These tanks were removed on June 15 and 16, 1998.
Please note that this facility is the location of a former Manufactured Gas Plant (MGP). Regulatory
oversite for the MGP sites is provided by the NCDENR, Superfund Section (Burce Nicholson). Duke
has scheduled to investigate the MGP site in the fall of 1998.
Please call me at (704 )3 73-7891 if you have questions or require additional information.
Sincerely,
Ta ara Carpenter, Engineer
Environmental Engineering
Environment, Health, and Safety
xc: RC Roberts
WA Carter
WA Hefner
Central Records
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DUKE POWER COMPANY
BURLINGTON OPERA TIO NS CENTER
UNDERGROUND STORAGE TANK
CLOSURE REPORT
r) -;'' ... : ' J ; ' ....
!.... .• .I '··-; "t ' .. :
~~ Tamara Carpenter
July 15, 1998
Duke Power Company
526 S. Church Street
Charlotte, NC 28202-1802
Ralph C. Roberts
July 15, 1998
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UNDERGROUNDSTORAGETANKCLOSUREREPORT
The closure report should contain, at a minimum, the following information. Any other information that
is pertinent to the site should be included.
11. General Information
A Ownership of UST(s)
B.
C.
D.
1. Name of UST owner.
Duke Power Company
2. Owner address and telephone number.
526 S. Church St, Charlotte, NC 28202-1802 [phone]
Operator of UST(s)
1. Name of UST operator.
Duke Power Company
2. Operator address and telephone number.
526 S. Church St, Charlotte, NC 28202-1802 [phone]
Facility Information
1. Facility name.
Burlington Operations Center
2. Facility ID#.
0-023474
3. Facility address, telephone number, and county.
1205 N. Church St., Burlington, NC 27215, Alamance County
Contacts
1. Name, address, telephone number, and job title of primary contact person.
Tamara Carpenter, Engineer,
526 S. Church St, Charlotte, NC 28202-1802 [phone]
2. Name, address, and telephone number of closure contractor.
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Tank
no.
1
2
E.
F.
SEI Environmental, 130 Penmarc Dr, Suite 108, Raleigh, NC 27603, Attn:
John Peters [phone]
3. Name, address, and telephone number of primary consultant.
Ralph C. Robert, 526 S. Church St, Charlotte, NC 28202-1802 (704)373-
7888
4. Name, address, telephone number, and State certification number of laboratory.
Duke Power -Environment, Health, and Safety Department,
Laboratory Services
13339 Hagers Ferry Road, Huntersville, NC 28078
[phone]
NC Certificate #248
UST Information
Installation Size in Gallons Tank Dimensions Last Contents
dates
5/10/68 10,000 18' long x 10.5' diesel
dia
5/9/75 15,000 23.5' long x 10.5' gasoline
dia
Site Characteristics
1. Describe any past releases at this site.
Previous Contents
(if any)
none
none
The gasoline tank was overfilled in 1996 which resulted in a release. The soil
around the fill port was removed and properly disposed of. Clean soil and
gravel was replaced. An overfill also occured on 12/15/92 at the gas tank.
2. Is the facility active or inactive at this time? If the facility is inactive, note the last
time the USTs were in operation.
Active.
3. Describe surrounding property use (for example, residential, commercial, farming,
etc.).
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The property surrounding the Burlington Operations Center is primarily
industrial and commercial.
4. Describe site geology/hydrogeology.
Site soils are primarily silty clay. Site drainage in the area is southeast The
depth to groundwater is unknown but expected to be greater than 13 feet. No
groundwater was encountered during the excavation and removal. Other
samplings at the site have found the groundwater at less than 13 feet.
5. Describe results of receptor survey (water wells, basements, etc., within 1500 feet of
the facility). To be performed if a release has occurred.
The receptors within 1500 feet of the site include a small creek approximately
200 feet southeast of the gasoline tank, and the basement of the operations
center (see Figure 3). The drinking water wells have not been surveyed but
the area is supplied by a public water supply. The surrounding receptors will
be better determined during the MGP site investigation.
Closure Procedures
A.
B.
C.
D.
Describe preparations for closure including the steps taken to notify authorities, permits
obtained, and the steps taken to clean and purge the tanks.
The GW/UST3-Form (see Appendix A) was submitted to the NCDEHNR Winston-
Salem Regional Office on May 26, 1998. The local fire marshal! was notified and
was present at the time of the UST removal. Vapors were expelled from the tank
using dry ice. The remaining product and sludge in the tanks was removed by
Haz-Mat Transportation and Disposal on June 12, 1998 (see appendix D).
Note the amount of residual material pumped from the tank(s).
Approximately 3100 gallons of gasoline and diesel fuel were pumped from the tanks
(see Appendix D).
Describe the storage, sampling, and disposal of the residual material.
The residual material was removed by Haz-Mat Transportation and Disposal
on June 12, 1998. The disposal manifest for the handling of the residual
material is included in Appendix D.
Excavation
1. Describe excavation procedures noting the condition of the soil encountered and the
dimensions of the excavation in relation to the tanks, piping, and/or pumps.
The gasoline and diesel tanks were excavated using a trackhoe. Groundwater
was not encountered during the removal. As shown on Figure 4, an
excavation with dimension 14' x 30' x 12' deep was made for the removal of
the diesel tank. As shown on Figure 5, an excavation with dimensions 25' x
32' x 13' deep was made for the removal of the gasoline tank. An excavation
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E.
with the dimension of 6' x 1 0' x 4' deep was made for the removal of the
dispensers. Approximately 78 cubic yards of contaminated soil was removed
during the removal of the diesel tank and dispenser. No gasoline
contaminated soil was found during the removal of the gasoline tank.
2. Note the depth of tank burial(s) (from land surface to top of tank).
The diesel tank had approximately 2 feet of cover. The surface above the
tanks was asphalt. The gasoline tank had approximately 3 feet of soil cover.
The surface above the tank was gravel.
3. Note volume of soil excavated .
Approximately 450 cubic yards of soil was excavated for the removal of the
tanks, piping, and dispensers.
4. Describe soil type(s) encountered.
The soil type was silty clay.
5. Describe type and source of backfill used .
The soil removed during the excavation of the gasoline tank was reused as
backfill. The soil removed during the excavation of the diesel tank and the
gasoline and diesel dispensers was contaminated and was disposed of with
Soil Solutions (see Appendix D). Soil samples were obtained around the
piping with the Geoprobe Direct Push Technology. The remainder of the
excavation was filled with clean soil and topped with gravel.
6. Describe condition of UST system(s) (i.e ., pitting, holes, etc.)
The UST, piping, and dispensers were in good condition. There was
some minor pitting on the tanks but no holes were present.
Note: Refer to the "Groundwater Section Guidelines for the Investigation and Remediation
of Soil and Groundwater" on limiting excavations. The Trust Fund will not pay for
excessive excavation. Potentially uncontaminated soil may be separated from potentially
contaminated soil based on field screening readings; however, laboratory confirmation is
required to document the presence or absence of contamination for disposal purposes.
Contaminated Soil
1. Describe how it was determined to what extent to excavate the soil.
Minimal excavation was performed to facilitate the UST system removal. Soil
samples were collected at the required sampling locations and field screened
using a Photovac Microtip 2000 photoionization detector (PID) to determine
the existence of any soil contamination. Field screening indicated
contamination due to product overfills around the diesel tank and under both
dispensers.
2. Describe method of temporary storage, sampling, and treatment/disposal of soil.
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The contaminated soil removed during the excavation was disposed of with
Soil Solutions, Inc. (see Appendix 0). The clean soil was returned to the
excavation and used as backfill. No temporary storage of soil was required.
Note: Suspected contaminated soil should be segregated from soil that appears to be
uncontaminated and should be treated as contaminated until proven otherwise It should
not be used as backfill.
1111 . Site investigation
A.
8 .
Provide information on field screening and physical observations, as well as methods
used to calibrate field screening instrument(s).
Soil initially removed from the excavation was screened using a Photovac Microtip
2000 photoionization detector (PIO). The field screening was done periodically
during the excavation to determine the condition of the soil removed.
Contamination was encountered under the dispensers and around the diesel tank.
Collected samples were also screened using the PIO. The PIO was calibrated in
accordance with manufacturer's recommendations.
Describe soil sampling points and sampling procedures used, including:
Location of samples;
Type of samples (from excavation, stockpiled soil, etc. );
Sample collection procedures (grab, split spoon, hand auger, etc.);
Depth of soil samples (below land surface);
Whether samples were taken from side or floor of an excavation;
Sample identification;
Sample analyses.
A total of 8 soil samples (all grab samples) were collected from the excavation
of the diesel tank. Note: There was a concrete pad under the tank which
required samples to be taken on each side of the pad. These samples were
collected around the pad at a depth of 12 feet below the surface. Sample 05 was
collected beneath the dispensers at a depth of 4 feet and samples 03 and 04
were collected beneath the product line at a depth of 4 feet. These samples
were analyzed per EPA methods 8260, 8270, and MAOEP VPH and EPH. The
location of these samples is shown on Figure 4.
A total of 3 samples were collected from the excavation of the gasoline tank.
Note: There was not a concrete pad beneath this tank. These samples were
collected on the floor of the excavation at a depth of 13 feet. Samples 13, and
14 were collected beneath the gasoline product line at a depth of 4 feet and
sample 12 was collected beneath the dispenser at a depth of 4 feet. The samples
under the product line were collected using the Geoprobe direct push
technology. These samples were analyzed per EPA methods 8260 and MAOEP-
VPH.
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C.
The sample analyses results summary is provided in Tables 1 and 2. The chain
of custody sheet and the analytical results are provided in Appendices E and F,
respectively.
The soil samples were placed in glass jars with teflon seals and screw caps
leaving zero headspace and placed on ice for temporary storage and transport
to the analytical laboratory. The MADEP-VPH samples were preserved in
methanol and placed on ice for temporary storage. Sample containers were
labeled in the field and consecutively numbered at the time of sample
collection.
Laboratories: Duke Power Company, Laboratory Services,
13339 Hagers Ferry Rd
Huntersivlle, NC 28078
MADEP Method
Paradigm Analytical Laboratories, Inc
Willmington, NC
Describe groundwater or surface water sampling procedures used, including:
Location of samples;
Sample collection procedures (grab, bailer, etc.);
Sample identification;
Sample analyses.
Note. Refer to the "Groundwater Section Guidelines for the Investigation and Remediation
of Soil and Groundwater" for information about sampling requirements.
Not Applicable. No groundwater was encountered during the removal of the
tanks.
D. Describe quality control measures, including :
Sample handling procedures including sample preservation and transportation;
Decontamination procedures used;
Time and date samples were collected and date submitted to lab;
Samples collected for quality control purposes (e.g. duplicates, field blanks, trip
blanks, etc.), including methods used to obtain these samples and analytical
parameters;
How results of quality control samples may have affected your interpretation of
soil, groundwater, or surface water sample results.
Samples were preserved for temporary storage and transport to the laboratory by
placing on ice in a cooler. The MADEP-VPH samples were preserved in methanol and
placed on ice for temporary storage. Sample containers were received from the
laboratory clean.
The soil samples were collected on June 15, 1998 for the removal of the diesel tank
and on June 16, 1998 for the removal of the gasoline tank and delivered to the
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laboratory on June 17, 1998. Soil was placed in jars by hand using latex gloves. New
gloves were used for each sample collected. A trip blank was only collected for the
MADEP method. No other field or trip blanks were collected.
E. Describe investigation results, including:
Results of Site Sensitivity Evaluation (SSE), (if SSE was not conducted,
explain why not);
Methods of analyses used (include U. S. EPA method number);
Analytical results for samples; discuss in relation to site specific cleanup level
or action level, as appropriate
The samples collected during the removal of the diesel tank system were anaylzed per EPA
Methods 8260, 8270, and MADEP -VPH and MADEP-EPH. The location of these samples is
shown on Figure 4. The samples collected during the removal of the gasoline tank system were
analyzed per EPA Methods 8260 and MADEP-VPH. The location of these samples is shown on
Figure 5. The results of the analyses are provided in Table 1 and Table 2.
The contaminated soil removed during the excavation of the diesel tank and the dispensers
most likely resulted from product overfills and in the dispensers leaking. The analyses results
presented in Tables 1 and 2 showed contamination remaining in both excavations. Analytical
results indicate a limited volume of diesel fuel contaminated soil and additional polycyclic
aromatic hydrocarbon (PAH) from a manufactured gas plant (MGP) formerly located at the site.
The levels of contaminants present did not exceed the Maximum Soil Contaminant
Concentrations (MSCC) for the industrial/commercial classification. However, the several of
the contaminants exceeded the MSCC soil-to-groundwater levels.
An SSE was not performed for this tank closure because the soil has been impacted with MGP
residues and the site will be investigated and remediated under the Hazardous Waste site
program.
J IV. Conclusions and Recommendations
Include probable sources of contamination, further investigation or remediation tasks, or whether
no further action is required.
The Burlington Operations Center is the location of a former Manufactured Gas Plant
(MGP) Site. The MGP operated from 1925 until the early 1950's. Regulatory oversite
for the MGP sites is provided by the NCDENR Sperfund Section (Bruce Nicholson).
Duke has scheduled to investigate the MGP site in the fall of 1998.
Duke recommends no additional investigation be performed as part of the tank
closure. Any contamination remaining from the UST systems is minor when
compared to the impacts of the MGP and will be handled as part of the MGP
investigation and remediation.
V. Signature and Seal of Professional Engineer or Licensed Geologist
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Professional Engineer Registration # 10354
Licensed Geologist License#. ~_£ C ~di avt}
Note. Required if a release or discharge of product from the tank(s) has occurred. If a release or
discharge has not occurred, the signature or seal of a P. E. or L. G. is not required.
I VI . Enclosures
A Figures
1. Area map(s) (can be USGS Topographic Quadrangle) showing:
Adjacent streets, roads, highways with names and numbers;
Buildings;
Surface water bodies;
Groundwater flow direction (if available);
North arrow;
Scale;
If a release has occurred show:
Public and private water supply well(s) within 1,500 feet of the site -
See Figures 1 and 2.
2. Site map of UST excavation area drawn to scale, showing.
Buildings;
Underground utilities such as sewer lines and other conduits; NA
Orientation of UST(s), pumps, and product lines (current and former);
Length, diameter and volume of USTs (current and former);
Type of material(s) stored in USTs (current and former);
Sample locations (identified by letter or number);
Groundwater well locations; NA
Groundwater flow direction (if available); NA
Final limits of excavation ;
North arrow;
Scale.
See Figures 3, 4, and 5.
3. Maps depicting analytical results, to include.
Orientation of UST(s), pumps, and product lines;
Sample locations, depths, and identifications;
Analytical results ;
Final limits of excavation(s).
See Tables 1 and 2, Figures 4 and 5.
B. Tables
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1. Field screening results. NA
2. Sample identifications, depths and analyses.
3. Sample identifications with results and dates that samples were taken.
See Tables 1 and 2.
C. Appendices
Appendix A. Notification of intent to close (GW/UST-3)
Appendix B. Site Investigation Report for Permanent Closure or Change-in-
Service UST (GW/UST-2)
Appendix C. Certificate of UST disposal
Appendix D. Soil , water, sludge disposal manifests
Appendix E. Complete chain-of-custody records
Appendix F. Copy of all laboratory analytical records
Appendix G. Site Sensitivity Evaluation (SSE) (if applicable) NA
Appendix H. Photographs of Closure Activities (optional) NA
Appendix I. Geologic logs for excavation(s)/borings NA
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ENCLOSURES
USGS Topo Map
Location Maps
Site Map of UST Excavation Area
Map of Sample Locations
Tables of Analytical Results
Appendices A thru F
TRANSFORMER SHOP
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,/.....___ AIR & WATER LINES TO DISPENSER
rro1-~ ~ - - -7 J 10,000 GALLON DIESEL FUEL UST
GASOLINE AND DIESEL I ,/
DISPENSERS I ,/
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//~ GASOLINE PRODUCT LINE
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15,000 GALLON GASOLINE UST J 0
c:\cfgn'i;bur lops . dgn
7
BURLINGTON GARAGE
BLDG. 7102
,,--, VfJ\\ \\\ ~
BURLINGTON OPERATION CENTER #0303
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30 0 30
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SCALE 1" = 30'
DUKE POWER
BURLINGTON OPERATION CENTER
PARTIAL SITE PLAN
FIGURE: 3
~ Burlington Operations Center
I UST Closure Report
Analytical Results -Table 1
Sample ID Depth (ft) Analytical Method Results ug/kg
I BOC 01 12 8260 ND
8270 bis(2-Ethylhexyl)phalate 630
I BOC 02 12 8260 Napthalene 4900
8270 Napthalene 330
2-Methylnapthalene 3300
I Acenaphthene 3300
Phenathrene 2500
Anthracene 1100
I Fluoranthene 780
Pyrene 340
Chrysene 5200
I BOC 03 4 8260 n-Butylbenzene 39
Napthalene 87
8270 ND I BOC 04 4 8260 Benzene 230
Ethyl benzene 450
I m-p-Xylene 1100
o-Xylene 240
n-Propyl benzene 94
I 1,3,5-trimethylbenzene 140
1,2,4-trimethylbenzene 560
Napthalene 70
I 8270 Napthalene 480
2-Methylnapthalene 360
Phenathrene 1200
I Fluoranthene 1100
Benzo(a)anthracene 990
Chrysene 1000
I Benzo(k)fluorathene 1600
Benzo(a)pyrene 680
lndeno(1 ,2,3-c,d)pyrene 850
I Dibenzo(a,h)anthracene 470
Benzo(g,h, l)perylene 820
I BOC 05 4 8260 ND
8270 bis(2-Ethylhexyl)phalate 600
I BOC 06 12 8260 Napthalene 310
8270 Phenanthrene 460
BOC 07 12 8260 Napthalene 12000 I 8270 Phenanthrene 430
bis(2-Ethylhexyl)phalate 750
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I Burlington Operations Center
I UST Closure Report
Analytical Results -Table 1
Sample ID Depth (ft) Analytical Method Results ug/kg
I BOC 08 12 8260 ND
8270 ND
I BOC 09 12 8260 ND
8270 ND
I BOC10 12 8260 Napthalene 15000
8270 Napthalene 24000
2-Methylnapthalene 51000
I Acenaphthene 25000
Dibenzofuran 4500
Fluorene 13000
I Phenanthrene 32000
Anthracene 10000
Fluoranthene 9000
I Pyrene 5100
Benzo(a)anthracene 5000
Chrysene 6700
Benzo(k)fluorathene 4100 I Benzo(a)pyrene 3400
BOC 11 12 8260 ND
I 8270 Phenanthrene 650
Fluoranthene 1100
Benzo( a )a nth racene 1200
I Chrysene 1300
bis(2-Ethylhexyl)phalate 570
Benzo(k)fluorathene 1800
I Benzo(a)pyrene 840
lndeno(1,2,3-c,d)pyrene 870
Dibenzo( a, h )anthracene 480
I Benzo(g , h, l)perylene 830
BOC12 4 8260 ND
I BOC13 4 8260 n-Propyl benzene 96
1,3,5-trimethylbenzene 360
I 1,2,4-trimethylbenzene 1100
sec-Butyl benzene 230
p-lsopropyltoluene 260
I Napthalene 430
BOC14 4 8260 Napthalene 190
I BOC15 13 8260 ND
8270 Napthalene 610
I 2-Methylnapthalene 780
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Sample ID
BOC16
BOC17
Depth (ft)
13
13
Burlington Operations Center
UST Closure Report
Analytical Results -Table 1
Analytical Method Results
Phenanthrene
Fluoranthene
Benzo( a)anthracene
Chrysene
bis(2-Ethylhexyl)phalate
Benzo(k)fluorathene
Benzo(a)pyrene
lndeno(1 ,2,3-c,d)pyrene
Dibenzo( a, h )anthracene
Benzo(g, h, I )perylene
8260 Ethyl benzene
m-p-Xylene
o-Xylene
n-Propyl benzene
1,3,5-trimethylbenzene
1,2,4-trimethylbenzene
Napthalene
8260 ND
Page 3
ug/kg
610
1100
1100
1200
640
1700
770
820
470
780
13
31
15
9.9
23
60
12
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Appendix A
Notification of Intent to Close (GW/UST-3)
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~Duke r-Power ...
A Duke Energy Company
May 26, 1998
Ms. Sherry Knight
North Carolina Department of Environment
and Natural Resources
Winston Salem Regional Office
585 Waughtown St.
Winston-Salem, NC 27107-2241
Re: Duke Power Company
Burlington Operations Center
GW/UST-3 Notification oflntent
File: ENV-0309
Dear Ms. Knight:
Duke Power Company
A Duke Energy Company
Energy Center
P.O. Box 1006
Charlotte, NC 28201-1006
Please find attached the GW/UST-3 Form for the removal of two underground storage
tanks located at Duke Power's Burlington Operations Center. These tanks are currently
scheduled to be removed beginning June 16, 1998.
Please call me at (704 )3 73-7891 if you have questions or require additional information.
Sincerely,
~
Tamara Carpente , Engineer
Environmental Engineering
Environment, Health, and Safety
xc: DEM Sullivan
WA Carter
WA Hefner
Central Records
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Appendix B
Site Investigation Report for Permanent Closure or Change in
Service of UST (GW /UST-2)
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Appendix C
Certificate of Disposal
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Appendix D
Disposal Manifest
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Appendix E
Complete Chain-of-Custody Records
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Appendix F
Copy of All Laboratory Analytical Records
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0,1 )09 /98 07 : 59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYI'JCAL LABORATORIES, INC.
VPH (Aliphatics/Aromatles) Laboratory Reporting Form
cnent Name: Duke Power AnalyticaI Laboratories
Project Name: Burtington OP Center
Sample Information and Analytical Results
Sample Identification BOC-01-061598
Sample Matrix Soil
Collection Option (for Soilt 3
Date Collected 06/15/98
Date Received 06/18/98
Date Extracted 06/15/98
Date Analyzed 06/23/98
Dry Weight 84
Dilution Factor 1
Cs-Ca Aliphatics .. 17000 (µg/Kg)
~-C12 Aliphatics" 23000 (µg/Kg)
Ca-C,o Aromatics-13000 (µg~)
Surrogate % Recovery -PIO 130
Surrogate % Recovery -FID 98
• = Option 1 : Established fill line 0n vial, Option 2 = Sampling OeviC8/Brand, or Option 3 = Field weight of soil.
.... = Excludes any surrogates or intemal standards.
-
Lab Info: G243-3-43145 Revleved By: !::::?::-Ir:'
~002
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07/09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
VPH (Aliphatics/Aromatics) Laboratory Reporting Fonn
Client Name: Duke Power Analytical Laboratories
Project Name: Burlington OP Center
Sample Information and Analytical Results
Sample Identification 80~1598
Sample Matrix Soil
Collection Option (for Soilt 3
Date Collected 06/15/96
Date Received 06/18/98
Date Extracted 06/15/98
Date Analyzed 06/23/98
Dry Weight 84
Dilution Factor 1
Cs-(:11 Aliphatics-2800 {µg/Kg)
C1-C12 Aliphatics .. 2000 (µg/Kg)
C.-C10 Aromatics-1100 (µg/Kg)
Surrogate % Recovery -PIO 92
Surrogate % Recovery -FID 87
• = Option 1 = E5tablished 111 llne on vial, Oplian 2 "" Sampling Devlee/Brand, or Option 3 "' Field weight of soil
" = Excludes any surrogates or Internal standards.
Lab Info: G243-343146 Revieved By: fZ-N'
~003
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07/09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name: Dulce Power Analytical Laboratpries
Project Name: Burlington OP Center
Sample Information and Analytical Results
Sample Identification BOC-OS.061598
Sample Matrix Soll
Collection Option (fer Soil}* 3
Date Collected 06/15/98
Date Received 06/18/98
Date Extracted 06/15/98
Date Analyzed 06123/98
Ory Weight 81
Dilution Factor 1
c~, Aliphatics .. 3800 (µg/Kg)
C9-C12 Aliphatics" 3600 (µg/Kg)
Ca-C,0 Aromatics-3200 (µg/Kg)
Surrogate % Recovery -PIO 100
Surrogate % Recovery -FID 80
• = Option 1 "' Established fill line on vial, Option 2 "' Sampling Device/8rand. or Option 3 "' Field weight of soH.
.. = Excludes any aurn,gates or internal standards.
Lab Info: G24~3-43147 Revieved By: b-v'."'
~004
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07/09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
VPH (Aliphatlcs/Aromatics) Laboratory Reporting Form
Client Name: Duke Power Analytical Laboratories I Project Name:.;;B;..;;u;.;..rl;.;.;in~gt;;..;;.o;;..;;.n..;.0.;..P_Ce;...;..;.n_te_r _____________ _
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Sample lnfonnatJon and Analytical Results
Sample Identification BOC-12-061598
Sample Matrix son
Collection Option (for Soil)· 3
Date Collected 06/15/98
Date Received 06/18/98
Date Extracted 06/15/98
Date Anal~ed 06/23/98
Dry Weight 73
Dilution Factor 1
Cs-Ca Aliphatics-7600 (µg/Kg)
Cg-C12 Aliphatics .. 32000 (µg/Kg)
~-C10 Aromatics-24000 (µg/Kg)
Surrogate % Recovery -PIO 100
surro ate % Recover J -FID
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• = Option 1 :: Estabflshed fiD llne on vial, Option 2 = Sampling Device/Brand, or Option 3 =-F"teld weight of soil.
•• = Excludes any surrogates or Internal standards.
~005
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Q//09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name; Duke Power Analytical Laboratories
Project Name: Burlington OP Center
Sample Information and Analytical Results
Sample Identification BOC-15--061598
Sample Mabix Soil
Collection Option {for Soil>-3
Date Collected 06/16/98
Date Received 06/18/98
Date Extracted 06/15/98
Date Analyzed 06/23/98
Dry Weight 82
Dilution Factor 1
Cs-Ca Aliphatics .. < 1000 (µg/Kg)
C,-C,2 Aliphatics .... < 1000 (µg/JSg)
C,,C1o Aromatics ... < 1000 (µg/Kg)
Surrogate % Recovery -PIO 79
Surrogate % Recovery -FID 78
• = Option 1 = Established fin line on viaL Option 2 "' Sampring Device/Brand, or Option 3 .. F'ield weight of soil.
... :;; ExcllJdes any surrogates or lntamal standards.
Lab Info: G243-3-43150 Revieved By: ??:v
~006
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07/09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
VPH (Aliphatics/Aromatics) Laboratory Reporting Form
Client Name: Duke Power Analytical Laboratories
Project Name: Burlington OP Center
Sample Information and Analytical Results
Sample Identification BOC-14...()61598
Sample Matrix Soil
Collection Option (for Son)* 3
Date Collected 06/16/98
Date Received 06/18/98
Date Extracted 06/15/98
Date Analyzed 06/23/98
Dry Weight 84
Dilution Factor 1 cs-e. Aliphatics-< 1000 (µg/Kg)
Ca-C,2 Aliphatics-1100 (µg/Kg)
C9-C,o Aromatics·· < 1000 (µg/Kg)
Surrogate % Recovery -PID 60
surrogate % Recovery -FID 78
• = Option 1 "' Established fin line on vial. Option 2 = SampDng Device/Brand, or Option 3 -Field weight of soil.
-= Exdudff any sul'TDgates or Internal standards.
Lab Info: G243-3-43149 Revleved By: '!:?:::V'
~007
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07:59 FAX [phone] PARADIGM_LAB __ ~008
PARADIGM ANAL\TICAL LABORATORIES, TNC.
Results for Extractable Petroleum
Hydrocarbons
by MADEP-EPH-98-1
Client Sample ID: BOC..01-061598 Date Collected: 6/15/98"
Client Project ID: Burlington OP Center Date Received: 6/18/98
Lab Sample ID: 43145 Analyzed By: JPW
Lab Project ID: G243-3 %Solids: 84.3
Mabix: Soil
Compound Result Quantitatlon Dilution Date
(MG/KG) Limit Factor Analyzed
C11-C22 Aromatics BQL 25 1.0 7/8/98
C9-C18 Aliphatic Hydrocarbons (Alkanes} BQL 25 1.0 7/8/98
C19-C36 Aliphatic Hydrocarbons (Alkanes) BQL 25 1.0 7/8/98
Comments:
Quantitatlon Limits are fully calculated using dRution factors and % solids.
BQL = Undetected or below quantitation limit
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0!/09 /98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID:
Client Project ID:
Lab Sample ID:
Lab Project ID:
Matrix:
Compound
C11-C22 Aromatics
Results for Extractable Petroleum
Hydrocarbons
by MAOEP-EPH-98-1
BOC-04-061598 Date Collected:
Bur1ington OP Center Date Received:
43146 Analyzed By:
G243-3 %Solids:
Soil
Result Quantitation
(MG/KG) Limit
120 25
C9-C18 Aliphatic Hydrocarbons (Alkanes) 51 25
C19-C36 Aliphatic Hydrocarbons (Alkanes) 34 25
Comments:
6/15/98
6/18/98
JPW
83.6
Dilution
Factor
1.0
1.0
1.0
~009
Date
Analyzed
7/3/98
7/8/98
7/8/98
Quantitation Limits are fully calculated using dilution factors and % solids.
BQL = Undetected or below quantitation limit
Reviewed By: kif
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07/09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYilCAL LABORATORIES, INC.
Client Sample ID:
cnent Project ID:
Lab Sample ID:
Lab Project 10:
Matrix:
Compound
C11-C22 Aromatics
Results for Extractable Petroleum
Hydrocarbons
by MADEP-EPH-98-1
BOC-05-061598 Date Collected:
Burtington OP Center Date Received:
43147 Analyzed By:
G243.J ¾Solids:
Soil
Result Quantitation
(MG/KG) Limit
120 25
C9-C18 Aliphatic Hydrocarbons (Alkanes) 25 25
C19-C35 Aliphatic Hydrocarbons (Alkanes) 47 25
Comments:
6/15/98
6/18/98
JPW
80.9
DilutJon
Factor
1.0
1.0
1.0
Date
Analyzed
7/3/98
7/8/98
7/8/98
Quantitation Limits are fully calculated using dilution factors and % solids ..
BQL = Undetected or below quantltafion limit
~010
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07/09/98 07 :59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID:
Client Project ID:
Lab Sample ID:
Lab Project ID:
Matrix:
Compound
C11-C22 Aromatics
Results for Extractable Petroleum
Hydrocarbons
by MADEP-EPH-98-1
BOC-12-061598 Date Collected:
Burtington OP Center Date ReceiVed:
43148 Analyzed By:
G243-3 %Solids:
Soil
Result Quantltatlon
(MG/KG) Limit
190 25
C9-C18 Aliphatic Hydrocarbons (Alkanes) 110 25
C19-C36 Aliphatic Hydrocarbons (Alkanes) 43 25
Comments:
6/15/98
6/18/98
JPW
72.7
Dilution
Factor
1.0
1.0
1.0
Date
Analyzed
7/3/98
7/3/98
7/3/98
Quantitation limits are fully calculated using dilution factors and % solids.
BQL = Undetected or below quantitation limil
~011
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07./09/98 07:59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID:
Client Project ID:
Lab Sample ID:
Lab Project ID:
Matrix:
Compound
C 11-C22 Aromatics
Results for Extractable Petroleum
Hydrocarbons
by MADEP-EPH-96-1
BOC-14-061598 Date Collected:
Burlington OP Center Date Received:
43149 Analyzed By:
G243-3 %Solids:
Soll
ijesult Quantltatlon
(MG/KG) Limit
84 25
C9-C1 a AJlphatlc Hydrocarbons (Alkanes) 28 25
C1S-C36 Aliphatic Hydrocarbons (Alkanes) BQL 25
Comments:
6/16/98 ·
6/18/98
JPW
83.6
Dilution
Factor
1.0
1.0
1.0
~012
Date
Analyzed
7/3/98
7/3/98
7/3/98
Quantitation Limits are fully calculated using dilution factors and % solids.
BQL ;;; Undetected or below quantitation limit
RRVl8Wed Bv: Lo.."
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·07/09/98 07 : 59 FAX [phone] PARADIGM_LAB __
PARADIGM ANALYTICAL LABORATORIES, INC.
Client Sample ID;
Client Project ID:
Lab Sample ID:
Lab Project ID:
Matrix:
Compound
C11-C22 Aromatics
Results for Extractable Petroleum
Hydrocarbons
by MADEP-EPH.98-1
BOC-15-061598
Burlington OP Center
43150
G243-3
Soil
Result
(MG/KG)
BOL
Date Collected:
Date Received:
Analyzed By:
%Solids:
Quantitation
Umlt
25
C9-C18 Aliphatic Hydrocarbons (Alkanes) BQL 25
C19-C36 Aliphatic Hydrocarbons (All<anes) BQL 25
Comments:
6/16/96 ·
6/18/98
JPW
81 .6
Dllutlon
Factor
1.0
1.0
1.0
Date
Anatyzed
7/8/98
7/8/98
7/8/98
Quantltation Limits are fully calculated using dilution factors and % sorrds.
BQL = Undetected or below quantitation limit
~013
1.
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-07 /09 /98 07 :59 FAX [phone] PARADIGM_LAB __
PARADIGM ANAL'YfICAL LABORATORIES, INC.
AH2chment2
VPH Laboratory Reporting Form
Calibration and QA/QC Information
FID Initial Calibration Date: 05/28/98
Callbration Ranges and Limits
Range MOL
(µg/L) (µg/K.g)
C,.C1 Aliphatics 2.4 120
C9-C12 Aliphatics 1.3 65
C9-C10 Aromatics 0.5 25
Calibration Concentration Levals
Range Levels
(µg/L) (µg/Kg)
40 2000
Cs-Ca 160 tjUUU
AJlphatics 400 20000
1600 80000
4000 200000
30 1500
C,-C12 120 bUUU
AliphaUcs 300 15000
1200 60000
3000 150000
65 3250
Ce-C,o 260 1;jUUU
Aromatics 650 32500
2600 130000
6500 325000
Calibration Cheek Dale: 06/22/98
Calibration Cheek
Range Levels
(µg/L) (µg/Kg)
CgC:8 AJiphatics 400 20000
C.-C,2 Aliphatics 300 15000
Ce-C10 Aromatics 650 32500
MDL = Method Detection Linlt
Ml "' Minimum Limit
RL "' Reportable Limit
PIO Initial Calibration Date: 05/28/98
ML RL
(µg/L) (µg/Kg) (µg/L) (µg/Kg)
7.5 380 200 1000
4.0 210 200 1000
1.6 80 200 1000
%RSDorCCC Method of Quantitation
9.7 Cafibratlon Factor
18.6 Calibration Factor
21.6 Calibration Factor
RPO
13.8
-12.9
1.5
RPO ., Relatlve Percent Differanc:e
%RSD :: Percent Relative Standard Deviation
CCC "' Correlation Coefficient of Cuive
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Revteved By: Ehl
~014
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Lab Info: G243-3-43148 Revieved By: b,e
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DATA FILE:: 23U05.D FIELD ID:: BOC-01-061598 LAB ID:: 98-JUN-0217
, ................ , ................................................................ , ... :::::.:,,.-.-.-.-.-.-.-............ _.._._._.,._._._._._._._._._._._._._._._._._._._._. ........................ _._._._._._.,.,•.:,, .......................................................................... .-............... · ..........•...••........ ···:.-.-................... ·.······· .-.-.-.-.-.-.-.... _._._._._._. .-.-.-.-.-.-.-.-.-.-.-.-.-.-.-.. _._._._._._. .. _.,._._._._._._._._._._._._._._._. .................. _._._._._._._._._._._._._._. .................. .-.-.-.-.-.-.-.-.-.-.. .-.-.-.-.-.-.-.1
Tentatively Identified Compound Report
i::•\•i·······i·····/:-:, ···i···i·············i····•:•:•··············i················ :;::•:•:•:•:•\{•: ·············i}•, ·······················•·········· ·······i···i·i········ ·····i·i·i···i :;:;:::::::::;:;:;:;:::::: :::::·::::::::
NO TICS
Internal Standard
Pentafluorobenzene
D4-1 ,4-Difluorobenzene
Chlorobenzene D-5
D-4 1,4-Dichlorobenzene
Probable ·
Molecular ,
RT
17.77
21.38
32.06
40.70
Estimated
Concentration
Library Match Retention
Probability Rime (RT)
Surrogates
% Recovery
Dibromofluoromethane 95%
~oluene D-8 103%
1,4-Bromofluorobenze 96%
:::::::::::::::::::·:::::::::::::::;:: ::::::;:;:;:;:;:::::::;:;:::::: :;:; .. ·.:.:.···:::·····:··::·············-.. :.:.::: ... ·.·•·•
Library
Identification
Manual Scan
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 ml/min, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 Clmin, hold 5 min
El
Page 1 -------------------
[I DATA FILE:: 25U02.D FIELD ID :: BOC-02-061598 LAB ID:: 98-JUN-0217 ~
I ........ ·.·.·.·.·.·.·.·.·.·.·.·.·.·.·:.·.·.·.:.·.·.·.·. ·.·.:.·.·.·.·.·.·.·,,., .·.·.·.·.·.·.·.·.·.· . .-.·.·.·.·.·.·.·.·.·.·.·=·.·.·.·.·.·::: ................... ·:.·.·.·.· ....................... -.·.·.,:.•.·.·.·.•.:.:.·.·.:.:.:.·.:.·.·.·.·:.·.· ....... -.·.·.· .·.·.·.·:.·.·.·.·:.·.· .-.-.·.·.·.·.·.-.-............. ·.·.·.·.·.·.·.·.·:: ........... ·:.-,·.·:::: ·::::.·.·.·.·.·.·.-••.• , ............. .-.·.·.·.·.·.·.•.•.•.•:,·.·.-............... -... ·.-:.·.·.·.·.·.·.·.·.·: ::.·.,.·.• .·.• .. ·., .•.•. , ... · .. , .•. •.•.•.•.•.• .•.•.•.•.•.•.•. , ... · .. .: .. •.•.•.•.•.· .. , .......... ·., .•.• ·•·•·•·•·• .•.•.•.•.•.•.· .. , ......... 1
Tentatively Identified Compound Report
Probable · Estimated Library Match Retention Identification
Molecular, Concentration Probability Rime (RT) Library Manual ~ Compound
unknown
methyl naphthalene
methyl naphthalene
ethyl naphthalene
Internal Standard
Pentafluorobenzene
D4-1 ,4-Difluorobenzene
1
Chlorobenzene D-5
D-4 1,4-Dichlorobenz~ne
Wei ht
RT
17.79
21.41
32.08
40.72
(u /k )
1400
8000
4800
2800
(%) (Minutes)
43.78
94 51 .96
94 52.7
95 54.92
Surrogates
% Recovery
Dibromofluoromethane 93%
~oluene D-8 104%
1 ,4-Bromofluorobenze 99%
Page 1 ------------
Match
X
X
X
Interpretation RT N
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 C/min, 180 to 200 C@ 10 C/min, hold 5 min
-------
II DATA FILE:: 23U06.D FIELD ID:: BOC-04-061598 LAB ID:: 98-JUN-0217
Tentatively Identified Compound Report
ethyl toluene
Internal Standard
Pentafluorobenzene
D4-1,4-Difluorobenzene
Chlorobenzene D-5
I D-4 1,4-Dichlorobenzene_
Probable ·
Molecular,
RT
17.77
21.38
32.06
40.70
Estimated
Concentration
284
Library Match Retention
Probability Rime (RT)
95 37 .35
Surrogates
% Recovery
Dibromofluoromethane 98%
h-01uene D-8 108%
1,4-Bromofluorobenze 97%
Library
X
Identification
Manual Scan
mber
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 C/min, hold 5 min
II
Page 1 -------------------
DATA FILE:: 23U08.D FIELD ID:: BOC-08-061598 LAB ID:: 98-JUN-0217
1.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·:·.·.:.:.·.·.·.:.:.•.·.·.·.·.·.·.· .·.·.·.·.·.· ..... ·.:.:.:.·,.,',' ... ·.·.·.·.·.·.·:.::. ·.·:.:.·.·.·.·.·:: ........... :::.·.·.·:::.::.:,:.·.· ... •.•,•,•.·.·::·, .. •,•.'.'.·.·:.·.·.· ... ·.•.•.·.·.· ... ·.·.·.·.·.·.·.·.·.·.·::::.·.·.·.· .·.·.:.·.·.·.·.·.·.·.·.·.·.·.·.·.:.:.:.·.:.·.:.·.:.:,:,:.:.·,:.·.:.·.:,•.:,•:•:·.·:.•:•:.•.:.·.·.·,·::•:•:•.•,•:.•:.·:.·.·.·.· ::::.·.·.·.·.·.·::: .·:.·.·.·.·.·.·.·.·.·.·:.·:.·:.·:::.·.·:.·.·.·.·.· ·:.·::.:,·.:.·.·.·.·.·. ·:::::.·.·.·.·.·:: .. : •. :.·.·.·, ·.·.:.·.: •. ·.:... ·'···'·'·'·'·'·········· ·············· ·····•
Tentatively Identified Compound Report
l=i:::/:::::::/:::::::\:::::;:::~:::::: :;:;:::::;:;:;:;:; :;:;:::/
Probable ·
Molecular ,
~t
e
de
·-
cahydro pentamethyl naphthalene
I
Internal Standard
Pentafluorobenzene
04-1 ,4-0ifluorobenzene
Chlorobenzene 0-5
0-4 1,4-0ichlorobenzene
-- -
RT
17.77
21.38
32.05
40.70
- -
Estimated Library Match Retention Identification
Concentration Probability Rime (RT) Library Manual Scan
(ug/kg) (%) (Minutes) Match Interpretation RT Number
37
39
--
89 52 .67
70 54.29
Surrogates
% Recovery
Oibromofluoromethane 102%
lroluene 0-8 103%
1,4-Bromofluorobenze 97%
-Page 1 - --
X
X
-
-
USEPA-8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 C/min, 180 to 200 C@ 10 C/min, hold 5 min
- - --- -
DATA FILE:: 23U09.D FIELD ID:: BOC-09-061598 LAB ID:: 98-JUN-0217
Tentatively Identified Compound Report
Probable · Estimated
Molecular, Concentration
Compound Weight (ug/kg)
dihydro methyl lndene
Internal Standard
Pentafluorobenzene
D4-1,4-Difluorobenzene
Chlorobenzene D-5
D-4 1,4-Dichloro~enzene
RT
17.77
21.39
32.06
40.70
15
Library Match Retention Identification
Probability ~ (%) -r
94 46.75
Surrogates
% Recovery
Dibromofluoromethane 102%
~oluene D-8 107%
1,4-Bromofluorobenze 100%
X
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 ml/min, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 Clmin, hold 5 min
Page 1 -------------------
[I DATA FILE:: 23U14.D FIELD ID:: BOC-10-061598 LAB ID:: 98-JUN-0217 II
1.·.:.:.:.:.:.·.·.:, ·.·.·.·.·.·.·:::::.·.·.·.·::.·.·.·.·:·.·:::·.:.·.·.·.·.:.:.·.·.:.·.:,:::.·.·.· ·.·.·.·.:.:.:.·.·.·.· ... :.· ... ·.· .·.·.•.•,•,•,•,•,•,'.','.·,· ..... ,,,,.,·.·.·,:,:,:;:;·:·:•.:.•.·.·.·.·.·:,·.::.·.:.·.·.·.·.·.·:.·.·::.·. ·.·.·.·:: ·:.·.· .·.·.·.·.·.·.· :.·:.·::·:.·.· .·.·.·.·.·.·.·.·.·.·.·.·.· .·:::.·:.·,·.·.:.·.·.:.·.·.·,·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.:.::;:.:,:.·.·.·.·.·::.·.:.·.:. ·.·.·.·.·.·.·.·.·.·.· .-.·.·.· .·.·.·.·.·.·.·.·.·.·.·.:.·.·.·.·.·.·.· .-.-.•.• ..... -:.·.·... ·::.·.·.· .·.·.·.·:.:.·.·:.:.·.· .·.·.·.·.·.·.:.:.:,:,:,:,:,·.·.· .. :.·.:.:.:.·. ·:::.·:::.· :.·:::.·.·.·.·.·.···
Tentatively Identified Compound Report
}}'}:}\. ....... ~
methyl naphthalene
Internal Standard
Pentafluorobenzene
D4-1 ,4-Difluorobenzene
Chlorobenzene D-5 I D-4 1,4-Dichlorobenzen~
Probable ·
Molecular,
RT
17.75
21 .36
32.04
40.69
Estimated
Concentration
12000
Library Match Retention
Probability Rime (RT)
94 51 .93
Surrogates
% Recovery
Dibromofluoromethane 103%
~oluene D-8 107%
1,4-Bromofluorobenze 96%
Page 1 ------------
Library
X
Identification
Manual Scan
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 C/min, 180 to 200 C@ 10 C/min, hold 5 min
-------
~ DATA FILE:: 25U07.D FIELD ID:: BOC-13-061598 LAB ID:: 98-JUN-0217
Tentatively Identified Compound Report
undecane
propyl toluene
isopropyl toluene
unknown
methyl lndan
unknown
dihydro methyl lndene
tetrahydro naphthalene
dihydro dimethyl lndene
dodecane
tetrahydro methyl naphthalene
tetrahydro methyl naphthalene
dihydro dimethyl lndene
tetrahydro methyl naphthalene
tetradecane
tetrahydro methyl naphthalene
tetrahydro dimethyl naphthalene
methyl naphthalene
methyl naphthalene
pentadecane
Internal Standard
Pentanuorobenzene
D4-1 ,4-Difiuorobenzene
Chlorobenzene D-5
D-4 1,4-Dichlorobenzene
Probable ·
Molecular ,
;
RT
17.79
21.40
32.09
40.72
Estimated
Concentration
870
500
440
540
810
670
610
I · 1900
540
1100
630
730
570
1400
870
660
540
610
1100
440
Library Match Retention Identification
Probability Rime (RT) Library Manual Scan
(Minutes) Match Interpretation RT Number
87 41.01
93 41.34
95 43.07
43.52
70 43.84
45.52
93 46.77
93 47.54
91 48.25
87 48.56
90 49.08
94 49.49
96 49.88
93 50.58
96 51.17
95 51.58
93 51 .81
90 51.97
83 52.69
82 53.82
Surrogates
% Recovery
Dibromofiuoromethane 97%
~oluene D-8 104%
1,4-Bromofiuorobenze 93%
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 Clmin, hold 5 min
~
Page 1 -------------------
[I DATA FILE:: 25U08.D FIELD ID:: BOC-14-061598 LAB ID:: 98-JUN-0217 ~
.:::::::::::]
Tentatively Identified Compound Report
unknown
tetradecane
meth I na hthalene
unknown
Internal Standard
Pentafluorobenzene
D4-1 ,4-Difluorobenzene
Chlorobenzene D-5
D-4 1,4-Dichlorobenzene
- ---
Probable ·
RT
17.77
21 .39
32.08
40.73
- -
Estimated
Concentration
140
68
120
130
81
--
Library Match Retention
Probability Rime (RT)
(%)
40.89
98 51.17
93 52.71
93 53.81
54.74
Surrogates
% Recovery
Dibromofluoromethane 94%
h-01uene D-8 108%
1,4-Bromofluorobenze 97%
Page 1 - - --
X
X
X
-
Identification
Manual
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 C/min, hold 5 min
- - --- -
~ DATA FILE:: 22U12.D FIELD ID:: BOC-15-061598 LAB ID:: 98-JUN-0217 II
•... ·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.·.:.:.·.·.: ::.·.·.·.·.·.·.·.·:.·.·.·.·.·.· ·.·.·.·.·.·.·.·.•.•::•:.:.•.:.:;:;:;:;:,::.·.::,::·.: .... · ... ::::::.:.···· .·.·.·.·.·.·:::::::.·.·.·.·.·.·.·.·.·.·.·.·:·.:,·:::: :·::.:.:::::.· :.·:.·.·.·.·.:.·.·.····::•.·.·.·.· .·.·.::•:•.•.·.·.·.·.·.·.·.·.·:•.·.·.·.·.·.·.·.·. ·.·.·.·.·.·.·.·.·.·.·.·.·.·. ·.·.·.·.·.•::.:.•:·.:,:,:,:,:::,:.:;:,:,·.·.·.·.·.·.·.·.·,::.·:.·.·.·.·.·.·.·.·;. ·.·.·:::.•::::.·.·.·::.·.·.·::: ::·:.·.·.·.·.·.·.·.·.·.·.:.·.·.·.·.·.·.·.·.· .·.·.·.·.·.:.·.·.·.:.·:::.·:.·.·.·.·.·.·::·:.:.·.·.·.·.·.·.·.,
Tentatively Identified Compound Report
··········•····················+················· ·····················································•·········\···········:·.·········•·········· ·.·.·········· .... ; ..... ;.; ........................... ; .•• ; .•......... ; ..... ; .... ·.·······•········ ···················· ·············•················ ······················ .....•... ; ... ; .... ·.······ ... ;.: .. ;:::::::,:;:.:,:,., •••••••••••••••••• ::::,:,:•:•:•,•i===: ::::::•===:i:,,,., •• :,:,:,:,:::,,;,,,,.,,,,;,,,, •• :::, ••• , •• :,,,., ···=·=·······i····•·:, ,,:,, .. ; ................ :,:,,,.,:,•::/:,:;:·=··· :.:,., •• :,:,, ••• :::,:,:,=,=·=i·=··········}·····=················:·:1
Probable · Estimated Library Match Retention Identification
Molecular, Concentration Probability Rime (RT) Library Manual Scan
Weight (ug/kg) (%) (Minutes) Match Interpretation RT Number
NO TICS
Internal Standard
Pentafluorobenzene
D4-1 ,4-Difluorobenzene
Chlorobenzene D-5
D-4 1,4-Dichlorobenzene
RT
17.76
21 .38
32.06
40.70
Surrogates
% Recovery
Dibromofluoromethane 93%
~oluene D-8 102%
1,4-Bromofluorobenze 99%
Page 1 ------------
USEPA -8260 G.C. Conditions
105 m x 0.53 mm x 1.0 um I Restek 502.2
He, 0.5 mVmin, 35 C hold 10 mins, 35 C to 180 C@
4 Clmin, 180 to 200 C@ 10 C/min, hold 5 min
-------
I Page # 2 of 3
30U0I.D 98JUN0217 I 98015589 BURLINGTON-BOC-01-061598 (Continued)
I Compound Name Concentration (ug I Kg)
Quantitative
Limit (ug I Kg)
I He.xachlorobutadiene Not Detected
4-Chloro-3-methylphenol Not Detected
330
330
2-M ethylnaphthalene Not Detected 330
I He.xachlorocyclopentadiene Not Detected
2, 4, 6-Trichlorophenol Not Detected
330
330
2, 4, 5-Trichlorophenol Not Detected 330
I 2-Chloronaphthalene Not Detected
2-Nitroaniline Not Detected
330
330
Dimethylphthalate Not Detected 330
I Acenaphthylene Not Detected
2, 6-Dinitrotoluene Not Detected
3-Nitroaniline Not Detected
330
330
330
I Acenaphthene Not Detected
2, 4-Dinitrophenol Not Detected
4-Nitrophenol Not Detected
330
330
330
Dibenzojuran Not Detected I 2, 4-Dinitrotoluene Not Detected
Diethylphthalate Not Detected
330
330
330
Fluorene Not Detected 330
I 4-Chlorophenylphenylether Not Detected
4-Nitroaniline Not Detected
330
330
2-Methyl-4, 6-dinitrophenol Not Detected 330
I n-Nitrosodiphenylan1ine Not Detected
1, 2-Diphenylhydrazine Not Detected
330
330
4-Bromophenylphenylether Not Detected 330
I He.xachlorobenzene Not Detected
Pentachlorophenol Not Detected
330
330
Phenanthrene Not Detected 330
I Anthracene Not Detected
di-n-Butylphthalate Not Detected
330
330
Fluoranthene Not Detected 330
I Pyrene Not Detected
Butylbenzylphthalate Not Detected
330
330
3, 3-Dichlorobenzidine Not Detected 330
I Benzo(a)anthracene Not Detected
Chrysene Not Detected
330
330
bis(2-Ethylhexyl)phthalate 630 330
I di-n-Octylphthalate Not Detected
Ben zo (b )fiuoranthene Not Detected
Benzo (k)fiuoranthene Not Detected
330
330
330
I Benzo(a)pyrene Not Detected
lndeno( 1, 2, 3-c,d)pyrene Not Detected
Dibenzo(a, h)anthracene Not Detected
330
330
330
I Benzo(g, h, i)perylene Not Detected 330
(Flags are described on page # 3)
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Page # 2 of 3
30U02.D .98JUN02 17 I .980155.90 B URLINGTON -BOC-02-0615.98
Co ,npound Name
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dirnethylphthnlate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzojuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
I, 2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3-Dichlorobenzidine
Benzo(a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di -n-Octy lphthalate
Benzo (b )jluoranthene
Benzo (k)fluoranthene
Benzo(a)pyrene
lndeno(l, 2, 3-c,d)pyrene
Dibenzo(a,h)anthracene
Benzo (g, h, i)perylene
Concentration (ug I Kg)
Not Detected
Not Detected
3,300
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
3,300
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
2,500
1,100
Not Detected
780
340
Not Detected
Not Detected
Not Detected
Not Detected
5,200
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued)
Quantitative
Li,nit (ug I Kg)
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
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Page # 2 of 3
30U01.D 98-JUN-0217 I I 98015591BURLINGTON-BOC-03-061598
Compound Narne
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
1,2-Diphenylhydrazine
4-Bromophenylphenylether
H exac h lorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3 '-Dichlorobenzidine
Benzo( a)anthracene
Chrysene
bis(2-Ethylhexyl)phtha/ate
di-n-Octylphthalate
Benzo(b)jluoranthene
Benzo(k)jluoranthene
Benzo( a) pyrene
lndeno(/,2, 3-c,d)pyrene
Dibenzo(a,h)anthracene
Benzo(g, h, i) perylene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
No t Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued )
Quantitative
Limit (uglKg)
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
390
I Page # 2 of 3
30U15.D 98JUN0217 I 98015592 BURLINGTON-BOC-04-061598 (Cont,inued )
I Quantitative
Compound Name Concentration (ug I Kg) Limit (ug I Kg)
I H e.x.achlorobutad i ene Not Detected 340
4-Chloro-3-methylphenol Not Detected 340
2-Methylnaphthalene 360 340
I He.x.achlorocyclopentadiene Not Detected 340
2, 4, 6-Trichlorophenol Not Detected 340
2, 4, 5-Trichlorophenol Not Detected 340
I 2-Chloronaphthalene Not Detected 340
2-Nitroaniline Not Detected 340
Dimethylphthalate Not Detected 340
I Acenaphthylene Not Detected 340
2, 6-Dinitrotoluene Not Detected 340
3-Nitroaniline Not Detected 340
I Acenaphthene Not Detected 340
2, 4-Dinitrophenol Not Detected 340
4-Nitrophenol Not Detected 340
I Dibenzofuran Not Detected 340
2, 4-Dinitrotoluene Not Detected 340
Diethylphthalate Not Detected 340
Fluorene Not Detected 340
I 4-Chlorophenylphenylether Not Detected 340
4-Ni troaniline Not Detected 340
2-Methyl-4, 6-dinitrophenol Not Detected 340
I n-Nitrosodiphenylamine Not Detected 340
1, 2-Diphenylhydrazine Not Detected 340
4-Bromophenylphenylether Not Detected 340
I He.x.achlorobenzene Not Detected 340
Pentachlorophenol Not Detected 340
Phenanthrene 1,200 340
I Anthracene Not Detected 340
di-n-Butylphthalate Not Detected 340
Fluoranthene 1,100 340
I Pyrene Not Detected 340
Buty lbenzy lphthalate Not Detected 340
3, 3-Dichlorobenzidine Not Detected 340
I Benzo (a)anthracene 990 340
Chrysene 1,000 340
bis(2-Ethylhexyl)phthalate Not Detected 340
I di-n-Octylphthalate Not Detected 340
Benzo (b )fluoranthene Not Detected 340
Benzo (k)fluoranthene 1,600 340
I Benzo(a)pyrene 680 340
lndeno(J, 2, 3-c,d)pyrene 850 340
Dibenzo (a, h)anthracene 470 340
I Benzo(g, h, i)perylene 820 340
I
(Flags are described on page # 3)
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Page # 2 of 3
30U02.D 98-JUN-0217 I I 98015593BURLINGTON-BOC-05-061598
Compound Na,ne
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
I, 2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3 '-Dichlorobenzidine
Benzo( a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo(b)fluoranthene
Benzo(k)jluoranthene
Benzo( a) pyrene
lndeno( 1,2, 3-c,d)pyrene
Dibenzo( a, h)anthracene
Benzo( g, h, i) perylene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
600
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued )
Quantitative
Limit (ug/Kg)
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
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Page # 2 of 3
30U03.D 98-JUN-0217 I I 98015594BURLINGTON-BOC-06-061598
Compound Nanie
Hexachlorobutadiene
4-Chloro-3-methylpheno/
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichloropheno/
2, 4, 5-Trichlorophenol
2-Chloronaphtha/ene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methy/-4, 6-dinitrophenol
n-Nitrosodiphenylamine
1,2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3 '-Dichlorobenzidine
Benzo( a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo(b )jluoranthene
Benzo(k)jluoranthene
Benzo( a) pyrene
I ndeno( I, 2, 3-c, d) pyrene
Dibenzo( a, h)anthracene
Benzo( g, h, i) perylene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
460
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued )
Quantitative
Limit (ug I Kg)
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
I Page # 1 of 3
( ___________ ____
USEPA Sv\--'84l5 fy1ethocf 82]01/ Soil Sample
laouke
1lt1Power ..
A Duke Energy Company
organic chemistry Grouy
Environmental Center, Mcguire Nuclear Complex, [phone]
North Carolina Department of Environment, Health and Natural Resources (DEHNR) Certification # 248
, _____________________ C_l_Je_n ... .f_R_~_P_9_rf_F_o_ri_nJ_, _________ _..._.__... ______ ..,.
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1 Field ID# BLJRL/NGTON-BOC-07-061598 : L ___________________________________________________________________ J
Date Collected::
L.I.M.S. Number::
Compound Name
n-Nitrosodimethylamine
Aniline
Phenol
bis(2-Chloroethyl)ether
2-Chlorophenol
/,3-Dichlorobenzene
1,4-Dichlorobenzene
Benzyl alcohol
1,2-Dichlorobenzene
2-Methylphenol
bis(2-Chloroisopropyl)ether
4-Methylphenol_
Hexachloroethane
n-Nitrosodi-n-propyl amine
Nitrobenzene
Jsophorone
2-Nitrophenol
2, 4-Dimethylphenol
bis(2-Chloroethoxy) methane
2, 4-Dichlorophenol
Benzoic acid
I, 2, 4-Trichlorobenzene
Naphthalene
4-Chloroaniline
06/15/98 Reviewed by::
98-JUN-0217 II 98015595 Lab ID#
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
***
***
30U04.D
Quantitative
Limit (ug I Kg)
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
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Page # 2 of 3
30U04.D 98-JUN-0217 I I 98015595BURLINGTON-BOC-07-061598
Compound Name
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
1,2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 31-Dichlorobenzidine
Benzo( a)anthracene
Chrysene
b is(2-Ethylhexy l) phthalate
di-n-Octylphthalate
Benzo(b)jluoranthene
Benzo(k)jluoranthene
Benzo( a) pyrene
I ndeno( I, 2, 3-c, d) pyrene
Dibenzo( a, h)anthracene
Benzo(g, h, i) perylene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
430
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
750
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued)
Quantitative
Limit (ug/Kg)
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
320
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Page # 2 of 3
30UIO.D 98JUN0217 I .98015596' BURLINGTON-BOC-08-06'1598
Compound Nanie
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
1, 2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3-Dichlorobenzidine
Benzo ( a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo (b )fluoranthene
Benzo (k)fluoranthene
Benzo(a)pyrene
lndeno( 1, 2, 3-c, d)pyrene
Dibenzo(a,h)anthracene
Benzo (g, h, i) pery Lene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued)
Quantitative
Limit (ug I Kg)
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
410
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Page # 2 of 3
30U05.D 98-JUN-0217 I I 98015597BURLINGTON-BOC-09-061598
Compound Narne
Hexachlorobutadiene
4-Chloro-3-methylphenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
I, 2-Diphenylhydrazine
4-Bromophenylphenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Butylbenzylphthalate
3, 3 '-Dichlorobenzidine
Benzo( a)anthracene
Crysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo(b)jluoranthene
Benzo(k)jluoranthene
Benzo( a) pyrene
I ndeno( I, 2, 3-c, d) pyrene
Dibenzo( a, h)anthracene
Benzo( g, h, i) perylene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
(Continued)
Quantitative
Limit (ug/Kg)
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
340
I Page # 2 of 3
30U12.D 98JUN0217 I 98015598 BURLINGTON-BOC-10-061598 (Continued)
I Quantitative
Compound Name Concentration (ug I Kg) Limit (ug/Kg)
I Hexachlorobutadiene Not Detected 3200
4-Chloro-3-methylphenol Not Detected 3200
2-M ethy !naphthalene 51,000 3200
I Hexachlorocyclopentadiene Not Detected 3200
2, 4, 6-Trichlorophenol Not Detected 3200
2, 4, 5-Trichlorophenol Not Detected 3200
I 2-Chloronaphthalene Not Detected 3200
2-Nitroaniline Not Detected 3200
Dimethylphthalate Not Detected 3200
I Acenaphthylene Not Detected 3200
2, 6-Dinitrotoluene Not Detected 3200
3-Nitroaniline Not Detected 3200
I Acenaphthene 25,000 3200
2, 4-Dinitrophenol Not Detected 3200
4-Nitrophenol Not Detected 3200
I Dibenzofuran 4,500 3200
2, 4-Dinitrotoluene Not Detected 3200
Diethylphthalate Not Detected 3200
Fluorene 13,000 3200 I 4-Chlorophenylphenylether Not Detected 3200
4-Nitroaniline Not Detected 3200
2-Methyl-4, 6-dinitrophenol Not Detected 3200
I n-Nitrosodiphenylamine Not Detected 3200
I, 2-Diphenylhydrazine Not Detected 3200
4-Rromophenylphenylether Not Detected 3200
I Hexachlorobenzene Not Detected 3200
Pentachlorophenol Not Detected 3200
Phenanthrene 32,000 3200
I Anthracene 10,000 3200
di-n-Rutylphthalate Not Detected 3200
Fluoranthene 9,000 3200
I Pyrene 5,100 3200
Rutylbenzylphthalate Not Detected 3200
3, 3-Dichlorobenzidine Not Detected 3200
I Renzo(a)anthracene 5,000 3200
Chrysene 4,200 3200
bis(2-Ethylhexyl)phthalate 6,700 3200
I di-n-Octy lphthalate Not Detected 3200
Renzo (b )fluoranthene Not Detected 3200
Renzo (k)fluoranthene 4,100 3200
I Renzo(a)pyrene 3,400 3200
Indeno(I, 2, 3-c, d)pyrene Not Detected 3200
Dibenzo (a, h)anthracene Not Detected 3200
I Benzo(g, h, i)perylene Not Detected 3200
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(Flags are described on page # 3)
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Page # 1 of 3
USEPA SW 846 Method 8270 // SoDSample
1ADuke
1r#PowersM
Organic Cfiemistry (jrouy
ENVIRONMENTAL CENTER, MCCVIRE A/VCI.EAR COMPUK. f704J 87S-S32S
9'/s,rtfi Carofina 1Jepartment of 'Environment, ?{ea{tf, aruf 9{at11.ral 1{_e.<ource.< (1J'E'Jb./JIJ Certificatinn. # 248 A Duke Energy Company
, ________________ c_'li_·en_ ... _t_CR_e_p_o_rl_R_o_nn _____________ ... __ .. __ .,. __
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: Field ID-#-------BURL/NGTiiiv~iioc--i1~061-5!iB _____ _ ! ___________________________________________________________________ I
Date Collected:: 06/15/98 Reviewed by:: yc:Ar7 JC::/<jQ
L.I.M.S. Number::
Compound Name
n-Nitrosodimethylamine
Phenol
Aniline
2-Chlorophenol
bis(2-Chloroethyl)ether
1, 3-Dichlorobenzene
1, 4-Dichlorobenzene
Benzyl alcohol
1, 2-Dichlorobenzene
2-Methylphenol
bis(2-Chloroisopropyl)ether
4-Methylphenol
Hexachloro.ethane
n-Nitrosodi-n-propylamine
Nitrobenzene
Lwphorone
2-Nitrophenol
2, 4-Dimethylphenol
bis (2-Chloroethoxy )methane
2, 4-Dichlorophenol
Benzoic acid
1, 2, 4-Trichlorobenzene
Naphthalene
4-Chloroaniline
98JUN0217/98015599 Lab ID#
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
(Flags are described on page # 3)
30U17.D
Quantitative
Limit (ug I Kg)
330
330
*** 330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
*** 330
330
330
330
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Page # 2 of 3
30U17.D 98JUN0217 I 98015599 BURLINGTON-BOC-11-06'1598
Compound Name
He.xachlorobutadiene
4-Chloro-3-methylphenol
2-M ethylnaphthalene
He.xachlorocyclopentadiene
2, 4, 6-Trichlorophenol
2, 4, 5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2, 6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2, 4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2, 4-Dinitrotoluene
Diethylphthalate
Fluorene
4-Chlorophenylphenylether
4-Nitroaniline
2-Methyl-4, 6-dinitrophenol
n-Nitrosodiphenylamine
I, 2-Diphenylhydrazine
4-Bromophenylphenylether
He.xachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
di-n-Butylphthalate
Fluoranthene
Pyrene
Buty lbenzy lphthalate
3, 3-Dichlorobenzidine
Benzo ( a)anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octy lphthalate
Benzo (b )fluoranthene
Benzo (k)fluoranthene
Benzo(a)pyrene
lndeno(J,2,3-c,d)pyrene
Dibenzo (a, h)anthracene
Benzo (g, h, i) pery Lene
Concentration (ug I Kg)
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
Not Detected
650
Not Detected
Not Detected
1,100
Not Detected
Not Detected
Not Detected
1,200
1,300
570
Not Detected
Not Detected
1,800
840
870
480
830
(Flags are described on page # 3)
(Continued)
Quantitative
Limit (ug I Kg)
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
330
I Page # 2 of 3
30U18.D .98JUN0217 I 980156'03 BURLINGTON-BOC-15-061598 (Continued )
I Compound Name Concentration (ug I Kg)
Quantitative
Limit (ug I Kg)
I Hex.achlorobutadiene Not Detected
4-Chloro-3-methylphenol Not Detected
330
330
2-Methylnaphthalene 780 330
I Hexachlorocyclopentadiene Not Detected
2, 4, 6-Trichlorophenol Not Detected
330
330
2, 4, 5-Trichlorophenol Not Detected 330
I 2-Chloronaphthalene Not Detected
2-Nitroaniline Not Detected
Dimethylphthalate Not Detected
330
330
330
I Acenaphthylene Not Detected
2, 6-Dinitrotoluene Not Detected
3-Nitroaniline Not Detected
330
330
330
Acenaphthene Not Detected I 2, 4-Dinitrophenol Not Detected
4-Nitrophenol Not Detected
330
330
330
Dibenzojuran Not Detected
I 2, 4-Dinitrotoluene Not Detected
Diethylphthnlate Not Detected
330
330
330
Fluorene Not Detected 330
I 4-Chlorophenylphenylether Not Detected
4-Nitroaniline Not Detected
330
330
2-Methyl-4, 6-dinitrophenol Not Detected 330
I n-Nitrosodiphenylamine Not Detected
I, 2-Diphenylhydrazine Not Detected
330
330
4-Bromophenylphenylether Not Detected 330
I Hexachlorobenzene Not Detected
Pentachlorophenol Not Detected
330
330
Phenanthrene 610 330
I Anthracene Not Detected
di-n-Butylphthalate Not Detected
330
330
Fluoranthene 1,100 330
I Pyrene Not Detected
Butylbenzylphthalate Not Detected
330
330
3, 3-Dichlorobenzidine Not Detected 330
I Benzo (a)anthracene 1,100
Chrysene 1,200
bis(2-Ethylhexyl)phthalate 640
330
330
330
I di-n-Octy lphthalate Not Detected
Benzo (b )fluoranthene Not Detected
Benzo (k)fluoranthene I, 700
330
330
330
I Benzo(a)pyrene 770
lndeno(J, 2,3-c,d)pyrene 820
Dibenzo(a,h)anthracene 470
330
330
330
Benzo(g, h, i)perylene 780
I 330
(Flags are described on page # 3)
I