WI-96022_96860_CA_IAR_20230210

ENVIRONMENTAL | CIVIL | GEOTECHNICAL
INITIAL ASSESSMENT AND ABATEMENT REPORT
QUALITY TURF FUEL SPILL 3698 NC HIGHWAY 53 EAST BURGAW, PENDER COUNTY, NC NCDEQ INCIDENT NO. 96860
RISK CLASSIFICATION: UNDETERMINED
FEBRUARY 10, 2023
WORK AUTHORIZATION NO. 02 CATLIN PROJECT NO. 222289
PREPARED FOR:
MR. ALFRED WOOTEN QUALITY TURF, INC.
1540 PINKEY ROAD BURGAW, NC 28425
PREPARED BY:
CATLIN ENGINEERS AND SCIENTISTS 220 OLD DAIRY ROAD WILMINGTON, NC 28405 [phone]
CORPORATE LICENSURE NO. FOR ENGINEERING SERVICES C-0585
CORPORATE LICENSURE NO. FOR GEOLOGY SERVICES C-118

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
TABLE OF CONTENTS
PAGE
1.0 SITE INFORMATION 1
2.0 EXECUTIVE SUMMARY 2
3.0 SITE HISTORY AND CHARACTERIZATION 3
3.1 OTR TANK OWNER AND OPERATOR INFORMATION 3 3.2 OTR TANK INFORMATION 3 3.3 CONTAMINANT SOURCE INVENTORY 3 3.4 SITE CHARACTERISTICS 3 3.5 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES 4
4.0 LNAPL INVESTIGATION AND FREE PRODUCT RECOVERY REPORT 4
5.0 INITIAL RESPONSE AND ABATEMENT ACTION 4
5.1 INITIAL RESPONSE ACTIONS 4 5.2 EXCAVATION OF CONTAMINATED SOIL 5
6.0 SITE INVESTIGATION INFORMATION 5
6.1 SOIL SAMPLING DATA 6 6.2 SUMMARY OF SOIL INFORMATION 6 6.3 MONITORING WELL INSTALLATION 7
6.4 GROUNDWATER GAUGING DATA 7 6.5 GROUNDWATER SAMPLING DATA 8 6.6 SUMMARY OF GROUNDWATER INFORMATION 8
7.0 CONCLUSIONS AND RECOMMENDATIONS 9
8.0 STATEMENTS AND CERTIFICATION 9
9.0 LIMITATIONS 9
10.0 REFERENCES 10

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
TABLES TABLE 1 SUMMARY OF SOIL LABORATORY RESULTS – ULTRA VIOLET FLUORESCENCE BY REDLAB QED™ ANALYZER
TABLE 2 SUMMARY OF SOIL LABORATORY RESULTS – EPA METHODS 8260D & 8270E
TABLE 3 SUMMARY OF SOIL LABORATORY RESULTS – MADEP EPH/VPH ANALYTICAL FRACTIONS
TABLE 4 WELL CONSTRUCTION AND WATER LEVEL GAUGING DATA – JANUARY 3, 2023
TABLE 5 SUMMARY OF GROUNDWATER LABORATORY RESULTS – STANDARD METHOD 6200B & EPA METHOD 625
TABLE 6 SUMMARY OF GROUNDWATER LABORATORY RESULTS – MADEP EPH/VPH
FIGURES FIGURE 1 SITE VICINITY MAP
FIGURE 2 SITE MAP
FIGURE 3 SUMMARIZED SOIL SAMPLE ANALYTICAL RESULTS – NOVEMBER 29, 2022
FIGURE 4 SUMMARIZED GROUNDWATER SAMPLE ANALYTICAL RESULTS – JANUARY 3, 2023
APPENDICES APPENDIX A SITE PHOTOGRAPHS
APPENDIX B SOIL DISPOSAL DOCUMENTATION
APPENDIX C WELL LOG AND WELL CONSTRUCTION RECORD
APPENDIX D DAILY ACTIVITIES LOGS AND GROUNDWATER SAMPLING SHEET
APPENDIX E LABORATORY ANALYTICAL REPORTS AND CHAIN OF CUSTODY DOCUMENTS

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 1 January 2023
1.0 SITE INFORMATION
Site Identification
Date: 02/10/2023
Site Name: Quality Turf Fuel Spill Site Risk/Priority Rank: Undetermined
Site Location: 3698 NC Highway 53 East Incident Number: 96860
Nearest City/Town: Burgaw County: Pender
Description of Geographical Data Point: Monitoring Well MW-1
Location Method: GPS Unit
Latitude (decimal degrees): 34.5917529° Longitude (decimal degrees): -77.885351°
Contacts Information
Responsible Party: Quality Turf, Inc. (c/o Alfred Wooten)
Address: PO Box 1548, Burgaw, NC 28425 Phone: [phone]
Property Owner: Daniel Edward Richards
Address: 3698 NC Hwy 53 E, Burgaw, NC 28425 Phone: [phone]
Property Occupant: Daniel Edward Richards
Address: 3698 NC Hwy 53 E, Burgaw, NC 28425 Phone: [phone]
Consultant: CATLIN Engineers and Scientists (CATLIN)
Address: 220 Old Dairy Rd., Wilmington, NC 28405 Phone: [phone]
Corporate Licensure No. For Engineering Services: C-0585
Corporate Geology License No.: C-118
Analytical Laboratory: RED Lab, LLC State Certification: UVF
Address: 105 Portwatch Way Phone: [phone]
Analytical Laboratory: Con-Test Analytical Laboratory State Certification: NC 652, NC-DW 25703
Address: 39 Spruce St., E. Longmeadow, MA 01028 Phone: [phone]
Release Information
Date Discovered: 11/07/2022
Estimated Quantity of Release: 30-50 gal
Cause of Release: Tractor trailer accident
Source of Release: Ruptured diesel tank
Sizes and contents of tank system(s) from which the release occurred:
• One ~100-gallon over the road (OTR) diesel fuel tank
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 2 February 2023
2.0 EXECUTIVE SUMMARY The Quality Turf Fuel Spill site is located at 3698 NC Highway 53, Burgaw, Pender
County, NC (site). The purpose of this report is to document the initial abatement
actions following a release caused by an automotive accident resulting in a ruptured fuel tank on November 7, 2022. Services for this report were performed in general accordance with North Carolina Department of Environmental Quality (NCDEQ) and Environmental Protection Agency (EPA) guidance documents.
According to a Notice of Regulatory Requirements (NORR) dated November 21,
2022, NCDEQ was notified on November 15, 2022 of a confirmed release at the site. On November 17, 2022, CATLIN Engineers and Scientists (CATLIN) was contacted to assist with the NORR. CATLIN personnel mobilized to the site on November 18, 2022. Grab soil samples were collected by hand from the sidewalls
(North, West, South, and East) and floor of the initial soil excavation. The sidewall
samples were collected at approximately two feet below land surface (BLS) and the floor of the excavation was approximately three feet BLS. These samples were submitted for total petroleum hydrocarbon (TPH) analysis via ultra-violet florescence (UVF) methods. Laboratory analytical results revealed TPH gasoline range organics
(GRO) and diesel range organics (DRO) at concentrations above the State Action
Levels (SALs) in the North 2’, South 2’, and Floor 3’ samples [up to 1,094 milligrams per kilogram (mg/kg) GRO and 2,614 mg/kg DRO]. TPH DRO was also above the SAL in the West 2’ sample. Detectable concentrations of TPH GRO and DRO were revealed in the East 2’ sample but were below the SALs. On November 22, 2022
CATLIN notified Quality Turf of the soil sample results and Quality Turf personnel
and equipment conducted additional soil excavation activities. CATLIN completed and submitted a UST-62 to NCDEQ via email on November 23, 2022 and returned to the site to inspect the excavation.
On November 23, 2022 CATLIN observed groundwater in the bottom of the
excavation (approximately six feet deep). Quality Turf was informed a groundwater sample would be required and additional (lateral) excavation activities were recommended.
On November 29, 2022, CATLIN contracted with Evo Corporation (Evo) to further
excavate and remove impacted soils. Approximately 18.42 tons of soil were transported off-site and accepted for disposal at a permitted disposal facility (Evo, Permit SRU400009). A soil sample was collected from each of the excavation sidewalls (East, North, South, and West) and submitted for analyses via EPA
Method 8260D, EPA Method 8270E, and Massachusetts Department of
Environmental Protection (MADEP) methods for extractable petroleum hydrocarbons (EPH) and volatile petroleum hydrocarbons (VPH). Several EPA 8260D analytes were detected, but all were below the lowest Maximum Soil Contaminant Concentration (MSCC). No EPA 8270E analytes were above the
laboratory method detection limits (MDLs). Estimated (“J”-value) concentrations of
MADEP VPH analytical fractions were detected in the East, South, and West samples, but all were below the lowest MSCC. One MADEP VPH fraction (C9-C10 Aromatics) was reported in the North sample at a concentration greater than its Soil-To-Groundwater (STGW) MSCC, but below the Residential MSCC.
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 3 February 2023
One shallow/Type II monitoring well (MW-01) was installed to 12 feet BLS on December 29, 2022. A groundwater sample was collected on January 3, 2023 and
submitted for analyses via Standard Method (SM) 6200B [plus ethylene dibromide
(EDB), methyl tert-butyl ether (MTBE) and diisopropyl ether (DIPE)], EPA Method 625, and MADEP EPH/VPH. All EPA 625 and MADEP EPH analytes were below the MDLs. One MADEP VPH fraction (C5-C8 Aliphatics) was above the MDL, but below the 2L GWQS. Multiple volatile organic compounds (VOCs) were reported in
the sample from MW-01. However, only benzene was reported at a concentration
greater than that established in Title 15A of the North Carolina Administrative Code, Subchapter 2L, Section .0202 Groundwater Quality Standards (2L GWQS), but below the Gross Contaminant Level (GCL).
CATLIN recommends resampling the monitoring well and the two water supply wells
on site.
3.0 SITE HISTORY AND CHARACTERIZATION The Quality Turf Fuel Spill site is located at 3698 NC Highway 53 East, Burgaw,
Pender County, NC (Figures 1 and 2). Site photographs are presented in
Appendix A. 3.1 OTR TANK OWNER AND OPERATOR INFORMATION
The tractor trailer was owned by Alfred Wooten of Quality Turf, Inc.
3.2 OTR TANK INFORMATION The release occurred from the road tractor’s ~100-gallon diesel fuel tank.
3.3 CONTAMINANT SOURCE INVENTORY On November 7, 2022, a road tractor and trailer belonging to Quality Turf suffered an accident that resulted in a ruptured diesel fuel tank. An estimated
30 to 50 gallons of light non-aqueous phase liquid (LNAPL; aka free product)
were released. Site photographs by CATLIN after the initial accident clean-up are included in Appendix A. Information regarding the petroleum release is provided on the
UST-62 24-Hour Notification of Discharge Form submitted to NCDEQ on
November 23, 2022. 3.4 SITE CHARACTERISTICS
The property is owned by Daniel Edward Richards and the property is
occupied by the David and Jennifer Edwards family. The property is bound by Highway 53 to the southeast and Murray Town Road (State Road 1504A) to the northeast. The site is comprised of a residential building, a garage in the northern portion of the parcel, a gravel driveway, several mature trees,
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 4 February 2023
and open grassy areas. According to the property owners/occupants, potable water is supplied by an on-site water supply well. The water supply well construction details are unknown. An additional water supply well (no pump,
old bored well, depth unknown) at the site is used for water plants/crops and
animals. Site photographs are presented in Appendix A. 3.5 PREVIOUS INVESTIGATIONS AND REMEDIAL ACTIVITIES
A historical release (Incident No. 19427) at the site was discovered in 1998
during site assessment activities in relation to a heating oil UST. Soil samples obtained during UST removal activities in 1999 indicated total petroleum hydrocarbons (TPH) above SALs. Approximately 15 tons of contaminated soils were removed from the site, and subsequent soil sampling indicated
that petroleum contamination was below Residential MSCCs. The site was
ranked Low Risk and a notice of No Further Action was issued in 2001. For further information, see the 2001 Site Closure Report by Clark Environmental Services, P.C.
4.0 LNAPL INVESTIGATION AND FREE PRODUCT RECOVERY REPORT Approximately 30 to 50 gallons of LNAPL (highway diesel fuel) were released from a ruptured fuel tank on November 7, 2022. During tractor trailer recovery, LNAPL was recovered using sorbent pads and subsequent soil removal. On November 18 and
22, 2022, the area around the diesel release was excavated by Quality Turf
personnel. The excavated soils were temporally stored on a trailer. Quality Turf completed a UST-72 Agreement for Land Application of Soils Containing Non-
Hazardous Substances on Private Land and submitted to NCDEQ on November 30, 2022. Approximately six cubic yards of soil were reportedly spread on Quality Turf’s
property at 1540 Pinkey Road, Burgaw, NC.
Additional excavation activities and soil sample results are discussed further below. No LNAPL associated with the November 2022 release remains on-site.
5.0 INITIAL RESPONSE AND ABATEMENT ACTION 5.1 INITIAL RESPONSE ACTIONS The release originated from a ruptured diesel fuel tank as a result of a
vehicular accident on the evening of November 7, 2022. The Quality Turf
tractor trailer was traveling northeast on Highway 53 when, in an attempt to avoid a vehicular accident, it jack-knifed and skidded into a tree on the property. An estimated 30 to 50 gallons of product were released. As discussed above, Quality Turf personnel and equipment performed initial
emergency response abatement actions. The incident was reported to the
NCDEQ Wilmington Regional Office on November 15, 2022 and via a UST-62 24-Hour Notification of Discharge Form emailed on November 23, 2022.
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 5 February 2023
The LNAPL was recovered using sorbent pads and subsequent soil removal. The tractor trailer was recovered via a towing service and removed from the site. No hazards due to fire, explosion, or vapor were identified after the
LNAPL was recovered and the vehicle was removed.
5.2 EXCAVATION OF CONTAMINATED SOIL
As described above, the November 2022 release occurred because of a
vehicular accident. Initial soil removal was performed by Quality Turf personnel on November 18 and 22, 2022. The resulting excavation was approximately seven feet by nine feet and six feet deep.
On November 29, 2022, CATLIN contracted with Evo to excavate petroleum
impacted soils from the release vicinity using a tracked excavator. The excavation pit measured approximately 10 feet on the north, south, and east sides, and six feet on the west side. The excavation extended to roughly 7.5 feet BLS. Based on field measurements, the excavation (shown on Figure 2)
was approximately 17.5 to 19 feet from the edge of Highway 53 and four to
six feet from the driveway. Sandy clay was encountered in the excavation. The excavation operation ceased approximately one to two feet into the water table and when obvious
field indications of impacted soils were removed from the sidewalls.
Petroleum impacted soil was disposed of as non-hazardous solid waste by Evo in Winston-Salem, NC (Permit SRU400009). According to the Certificate of Disposal and Non-Hazardous Materials Manifest (provided in Appendix B), 18.42 tons of soil were removed during the excavation.

The excavation was backfilled with clean sandy backfill from an off-site borrow source. The approximate excavation limits are shown on Figure 2. Photographs are provided in Appendix A. Disposal documents (including the Certificate of Disposal, materials manifest, and weight ticket) are included in
Appendix B.
6.0 SITE INVESTIGATION INFORMATION
CATLIN conducted field activities in general accordance with the approved Work
Authorization. Soil sampling and/or excavation activities were conducted on
November 18 and November 29, 2022. One monitoring well was installed on December 29, 2022 (See the well log and Well Construction Record in Appendix C) and sampled on January 3, 2023. Daily safety briefings detailing hazards identified in the Daily Activities Logs were conducted prior to initiating field work and are
included in Appendix D.

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 6 February 2023
6.1 SOIL SAMPLING DATA Five excavation confirmation soil samples were collected by CATLIN on
November 18, 2022 after excavation activities by Quality Turf. Grab samples
were obtained from the excavation walls (one from each sidewall at approximately two feet BLS) and one from the excavation floor (at approximately 3 feet BLS). These samples (North 2’, West 2’, South 2’, East 2’, and Floor 3’) were submitted for TPH analysis via UVF methods.

On November 29, 2022, four grab sidewall soil samples were collected by CATLIN after additional excavation activities by Evo. Samples were obtained from each excavation wall (East, North, South, and West) and submitted for analysis via EPA Methods 8260D & 8270E and MADEP EPH/VPH.

All soil samples were collected in general accordance with North Carolina Department of Environment and Natural Resources (NCDENR) and NCDEQ Guidelines and EPA Region 4 Operating Procedures. They were placed in appropriate glassware, labeled, and placed on ice in an insulated cooler.
6.2 SUMMARY OF SOIL INFORMATION Soil laboratory analytical results are summarized on Tables 1, 2, and 3. Excavation confirmation Risk-Based soil sample locations and summarized
results are illustrated on Figure 3. A copy of the complete laboratory report
and COC documentation are in Appendix E. TPH Analysis
The soil samples collected on November 18, 2022 from the initial excavation
activities by Quality Turf were analyzed for TPH via UVF methods. Analytical results revealed TPH GRO and DRO at concentrations above the SALs in the North 2’, South 2’, and Floor 3’ samples.
The sidewall sample with the highest TPH concentrations was South 2’
(1,094 mg/kg GRO and 2,176 mg/kg DRO). The Floor 3’ sample also contained high TPH concentrations (1,024 mg/kg GRO and 2,614 mg/kg DRO). TPH DRO was above the SAL in the West 2’ sample (101.2 mg/kg). Detectable concentrations of TPH GRO and DRO were revealed in the
East 2’ sample but were below the SALs.
EPA Method 8260D and EPA Method 8270E Analyses
The soil samples collected on November 29, 2022 (East, North, South, and
West) were analyzed for VOCs and semi-VOCs via EPA Methods 8260D and 8270E, respectively. No EPA 8270E analytes were above the MDLs in any of the samples. Laboratory analysis via EPA 8260D revealed low concentrations of multiple VOCs. However, none were above their lowest respective MSCCs.
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 7 February 2023
MADEP EPH/VPH Analyses The November 29, 2022 samples (East, North, South, and West) were also
analyzed for EPH and VPH via MADEP methods.
Estimated (“J”-value) concentrations of VPH analytical fractions were detected in the East, South, and West samples, but all were below the lowest MSCC. No EPH analytical fractions were above the MDLs in these samples.

The sample from the North sidewall contained the highest EPH and VPH concentrations. Only one VPH fraction (C9-C10 Aromatics) was reported in the North sample (76.4 mg/kg) at a concentration greater than its STGW MSCC; however, it was below the Residential MSCC.
6.3 MONITORING WELL INSTALLATION On December 29, 2022, a boring was advanced to 12 feet BLS for monitoring well construction by a North Carolina Certified Well Contractor, utilizing
hollow stem augers and a Diedrich D-50 drill rig. Cuttings generated during
drilling activities were spread in a grassy area on-site. The well (MW-01) was constructed of new, threaded PVC casing and screen. No glues or cements were used in joining PVC components. New nitrile
gloves were worn while handling all well materials. The monitoring well was
constructed with a pointed PVC sediment trap, 10 feet of 2-inch diameter, 0.010-inch slotted PVC well screen and approximately two feet of 2-inch diameter solid PVC riser to the surface. The annular space was filled with coarse sand pack to approximately one foot above the well screen and
bentonite chips to within one-half foot of the ground surface. The bentonite
chips were poured from the surface while simultaneously pouring water to facilitate hydration. The well was finished with a concrete pad and flush-mount steel wellhead and locking well cap. After installation, the monitoring well was developed by over-pumping.
Monitoring well construction information is summarized on Table 4 and a site map with the monitoring well location is illustrated on Figure 4. Site photographs are presented in Appendix A. The well log and Well Construction Record were submitted to NCDEQ on January 3, 2023; copies
are provided in Appendix C. 6.4 GROUNDWATER GAUGING DATA On January 3, 2023, depth to water was measured using an electronic probe.
Gauging data were recorded on an electronic groundwater sampling form using a tablet device (See Appendix D). Gauging procedures were performed in general accordance with NCDEQ Guidelines and EPA Region 4 Operating Procedures.
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 8 February 2023
Depth to water in MW-01 was 3.77 feet below top of casing. Gauging results are included on Table 4.
6.5 GROUNDWATER SAMPLING DATA Following gauging, monitoring well MW-01 was sampled in general accordance with NCDEQ Guidelines and EPA Region 4 Operating Procedures. Prior to obtaining a representative groundwater sample, the
monitoring well was purged by removing a minimum of three well volumes
using a new, disposable bailer. Groundwater field parameter data were measured at one-minute intervals using an In-Situ Aqua TROLL 600 Multiparameter Sonde (Aqua TROLL). Conductivity, pH, oxidation reduction potential (ORP), dissolved oxygen, and temperature measurements were
recorded utilizing the VuSitu mobile application (version 1.17.12).
Groundwater parameter data were transferred from the VuSitu mobile application to the electronic groundwater sampling form. A copy of the monitoring well sampling form is available in Appendix D.
After the well was purged a minimum of three well volumes, a groundwater
sample was collected from the well from a disposable bailer and poured directly into appropriate laboratory provided glassware, labeled, and placed on ice in an insulated cooler.
The groundwater sample was submitted to Con-Test Analytical Laboratory
(Certification NC 652 and NC-DW 25703) in East Longmeadow, Massachusetts, under proper chain of custody (COC) protocol and analyzed per SM 6200B (including EDB, MTBE, and DIPE), EPA Method 625, and MADEP EPH/VPH. The laboratory analytical data and COC are included in
Appendix E. 6.6 SUMMARY OF GROUNDWATER INFORMATION
One groundwater sample (MW-01) was submitted for analysis per SM 6200B
(including EDB, MTBE, and DIPE). Analytical results reported benzene at a
concentration of 3.2 micrograms per liter (µg/L), which is above the 2L GWQS (1 µg/L) but below the GCL (5,000 µg/L). Additionally, the following analyte concentrations were above the MDLs but below their respective 2L GWQS: ethylbenzene, isopropylbenzene, naphthalene, n-propylbenzene,
toluene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and total xylenes. Laboratory analyses via EPA Method 625 and MADEP EPH revealed no targeted analytes above the MDLs. One MADEP VPH analytical fraction (C5-C8 Aliphatics) was above the MDL but below the 2L GWQS.
The recent groundwater sampling laboratory results for SM 6200B and EPA 625 analyses are summarized in Table 5, and MADEP analyses are summarized in Table 6. Monitoring well sample analytical results are
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 9 February 2023
illustrated on Figure 4. A copy of the complete laboratory report and COC documentation are in Appendix E.
7.0 CONCLUSIONS AND RECOMMENDATIONS
The diesel released from the fuel tank, after being ruptured during a vehicular accident, was recovered via sorbent pads and excavated soils. Impacted materials were properly disposed at a permitted facility. Excavation confirmation soil samples
were collected and the excavation was backfilled. No petroleum impacted soils
remain in the area. CATLIN recommends resampling the monitoring well and sampling the two on site water supply wells.
8.0 STATEMENTS AND CERTIFICATION
1 Enter the date the report was due. February 16, 2023
Will this report be submitted after the established due date? NO
2 Was any required information from the above template missing from this report? YES
No cross sections are provided.
3 If applicable, will any of the proposed attenuation milestones under the schedule approved in the Corrective Action Plan not be met? NA
No CAP has been submitted for this site.
4 Does any known or suspected source zone soil contamination or free product remain outside of the assessed area that could be inhibiting natural attenuation? NO
5 Has there been an unexpected increase in contaminant mass sufficient to suggest a potential new release from a separate onsite or offsite source? NO
6 Certification:
I, Benjamin J. Ashba, a Licensed Geologist for CATLIN Engineers and Scientists, do certify that the information contained in this report is correct and accurate to the best of my knowledge.
CATLIN Engineers and Scientists is licensed to practice geology in North Carolina. The certification number of the company or corporation is C-118.
9.0 LIMITATIONS
The soil samples analyzed as part of this investigation only provide isolated data
points and may not represent conditions at every location in the project area. Analyses and conclusions of this report, being based on interpolation of data points at the project area, may not be completely representative of all site conditions.
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 10 February 2023
Conclusions and recommendations of this investigation and report are based on the best available data in an effort to comply with current regulatory requirements.
10.0 REFERENCES
Clark Environmental Services, P.C., Site Closure Report, Former Leedham Estate,
Highway 53 East, Burgaw, NC, GW Incident No. 19427, CES Project No. 98106, May 11, 2001.
NCDEQ, UST Section, North Carolina Department of Environmental Quality,
Division of Waste Management, Guidelines for Sampling, UST Section, North Carolina Department of Environment and Natural Resources, December 1, 2013.
NCDEQ, UST Section, North Carolina Department of Environment Quality, Division
of Waste Management, Guidelines for Site Checks, Tank Closure, and Initial
Response and Abatement for Petroleum and Hazardous Substance UST
Releases, Petroleum Non-UST Releases, January 19, 2021.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, UST Section Assessment Guidelines,
Petroleum and Hazardous Substance UST Releases, Petroleum Non-UST
Releases, January 19, 2021
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, UST Section Corrective Action Guidelines, Petroleum and Hazardous Substance UST Releases, Petroleum Non-UST
Releases, January 19, 2021.
NCDEQ, UST Section, North Carolina Department of Environmental Quality, Division of Waste Management, UST-62 Form, 24-Hour Notification of
Discharge Form, Submitted November 23, 2022(A).
NCDEQ, UST Section, North Carolina Department of Environmental Quality,
Division of Waste Management, UST-72 Form, Agreement For Land
Application or Contaminant and Treatment Of Soils Containing Non-
Hazardous Substances On Private Lands, Submitted November 30, 2022(B).
U.S. EPA, Region 4, U.S. Environmental Protection Agency, Science and Ecosystem Support Division, Athens Georgia, Operating Procedure – Field
Equipment Cleaning and Decontamination at the FEC, Striggow, B., U.S. EPA Report No. SESDPROC-206-R3, Effective Date December 18, 2015.

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

TABLES
Page 1 of 1
TABLE 1
Incident Name and No.: Quality Turf Fuel Spill - 96860
% light % mid % heavy
NORTH 2'11/18/22 <1.3 177.2 396.6 573.8 56.2 2.1 <0.051 98.7 1.3 0 Undeg. Diesel 91.8%, (FCM)
WEST 2'11/18/22 <1.3 29.2 101.2 130.4 8.2 <0.43 <0.053 98.2 1.7 0.1 Undeg. Diesel 92.3%, (FCM)
SOUTH 2'11/18/22 <25.9 1,094 2,176 3,270 185 <8.3 <1 99 1 0 Undeg. Diesel 92.4%, (FCM)
EAST 2'11/18/22 <1.2 43 99.1 142.1 8.4 <0.38 <0.047 98.8 1.1 0.1 Undeg. Diesel 93.5%, (FCM)
FLOOR 3'11/18/22 119.9 1,024 2,614 3,638 223.4 <8.1 <1 98.8 1.2 0 Undeg. Diesel 88.9%, (FCM)
NA 50 100
Sample depth provided in feet as part of the Sample ID.
All results in milligrams per kilogram (mg/Kg). Values are not corrected for moistore or stone content.
Bold Sample IDs and results indicate concentrations above State Action Levels.
SUMMARY OF SOIL LABORATORY RESULTS — ULTRA VIOLET FLUORESCENCE BY REDLAB QED™ ANALYZER
Sample
ID
Date
Collected
BTEX
(C6 - C9)
GRO
(C5 - C10)
DRO
(C10 - C35)
TPH
(C5 - C35)
Total
Aromatics
(C10-C35)
16 EPA
PAHs BaP
NA = Not Applicable
Ratios
HC Fingerprint
Match*
STATE ACTION LEVELS Not Applicable
< = Less than method detection limit
* = Fingerprints provide a tentative hydrocarbon identification. The abbreviations are:- FCM = Results calculated using Fundamental Calibration Mode :
% = confidence for sample fingerprint match to library (SBS) or (LBS) = Site Specific or Library Background Subtraction applied to result : (PFM) = Poor Fingerprint Match :
(T) = Turbid : (P) = Particulate present
Quality Turf; Hwy 53 Diesel Spill Inc. 96860; T1_Soil Results (UVF)
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023
Page 1 of 1
TABLE 2
Incident Name and No.: Quality Turf Fuel Spill - 96860
EPA
8270E
Date
Collected
11/29/22 <4.2 8.1 J <3.6 <5.2 <3.8 13.6 18.2 7.9 J 28.9 J BMDL BMDL
11/29/22 <2.2 31.6 16 77.6 <2.4 16.2 284 <2.3 168 BMDL BMDL
11/29/22 7.0 J 18.8 <4.2 <6.0 <4.4 32.7 8.9 J 7.3 J 60.1 BMDL BMDL
11/29/22 5.7 J 14.0 <3.4 <4.9 5.9 J 24.1 15.2 7.2 J 56.2 BMDL BMDL
All results in micrograms per kilogram (µg/kg).
EPA = Environmental Protection Agency
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
MSCC = Maximum Soil Contaminant Concentration
STGW = Soil-To-Groundwater
I/C = Industrial/Commercial
J = Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag).All EPA 8270E AnalytesVaries
Varies
Varies
EPA 8260DMethod
All Other EPA 8260D AnalytesSample ID
EAST p-Isopropyltoluene(p-Cymene)n-Propylbenzene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTotal XylenesContaminant of
Concern
BenzeneEthylbenzeneIsopropylbenzene (Cumene)SUMMARY OF SOIL LABORATORY RESULTS — EPA METHODS 8260D & 8270E
STGW MSCC (µg/kg)
Residential MSCC (µg/kg)
I/C MSCC (µg/kg)
6,600
156,000
2,330,000
6,600
156,000
2,330,000
NORTH
SOUTH
WEST Toluene 6,000
3,120,000
46,700,000
Varies
Varies
Varies
7.2
12,000
59,400
8,000
60,300
297,000
1,300
1,560,000
23,300,000
120
1,560,000
23,300,000
1,400
1,560,000
23,300,000
5,400
1,250,000
18,600,000
Quality Turf; Hwy 53 Diesel Spill Inc. 96860; T2_Soil Results (EPA 8260D)
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023
Page 1 of 1
TABLE 3
SUMMARY OF SOIL LABORATORY RESULTS — MADEP EPH/VPH ANALYTICAL FRACTIONS
Incident Name and No.: Quality Turf Fuel Spill - 96860
Date
Collected
11/29/22 <12.0 <12.0 <12.0 <2.25 2.36 J 3.19 J <2.25 <14.36 J*<12.0 <15.19 J*
11/29/22 70.0 23.9 23.3 9.10 93.2 76.4 9.10 163.2 23.9 99.7
11/29/22 <11.7 <11.7 <11.7 <2.23 5.98 J 3.77 J <2.23 <17.68 J*<11.7 <15.47 J*
11/29/22 <11.2 <11.2 <11.2 <2.26 3.12 J <2.26 <2.26 <14.32 J*<11.2 <13.46
All results in milligrams per kilogram (mg/kg).
Bold results indicate concentrations above the lowest MSCC.
MADEP = Massachusetts Department of Environmental Protection
EPH = Extractable Petroleum Hydrocarbon
VPH = Volatile Petroleum Hydrocarbon
MSCC = Maximum Soil Contaminant Concentration
# =Health based level > 100%
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
< = reporting limit
STGW = Soil-To-Groundwater
I/C = Industrial/Commercial
* = The value represents the sum of the reported practical quantitation limit of one analyte and the detected concentration of the other analyte.
J = Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag).
#
31,200
467,000
31
469
7,000
540
1,560
23,300
#
31,200
467,000
31
469
7,000
68
625
9,340
540
1,560
23,300
31
469
7,000
STGW MSCC (mg/kg)
Residential MSCC (mg/kg)
I/C MSCC (mg/kg)C9-C12 AliphaticC9-C10 AromaticC5-C8 AliphaticsC9-C18 AliphaticsSample ID
EAST
NORTH
SOUTH
WEST
68
625
9,340
540
1,560
23,300 C19-C36 AliphaticsC9-C22 AromaticsMethod EPH Analytical Fractions VPH Analytical Fractions Combined MADEP
EPH/VPH Fractions
Contaminant of
Concern
C9-C18 AliphaticC19-C36 AliphaticC11-C22 AromaticC5-C8 AliphaticQuality Turf; Hwy 53 Diesel Spill Inc. 96860; T3_Soil Results (MADEP)
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023
Page 1 of 1
TABLE 4
WELL CONSTRUCTION AND WATER LEVEL GAUGING DATA — JANUARY 3, 2023
Incident Name and No.: Quality Turf Fuel Spill - 96860
Well ID
Date
Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well
Diameter
(inches)
Well
Casing
Depth
(ft. BLS)
Screened
Interval
(x to y ft.
BLS)
Bottom
of Well
(ft. BLS)
Top of
Casing
Elevation
(ft.)
Free-Phase
Product
Thickness
Depth to
Groundwater
from Top of
Casing (ft.)
Groundwater
Elevation (ft.)
MW-01 12/29/22 01/03/23 2.0 2.0 2.0-12.0 12.0 NM NMT 3.77 Not requested
ft. BLS = feet Below Land Surface
NM = NM
NMT = No Measurable Thickness
Quality Turf; Hwy 53 Diesel Spill Inc. 96860; T4_Well Construction & Gauging
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023
Page 1 of 1
TABLE 5
Incident Name and No.: Quality Turf Fuel Spill - 96860
EPA 625
Date
Collected
(mm/dd/yy)
01/03/23 3.2 7.8 1.3 1.4 J 2.2 0.72 16 5.8 38.7 BMDL BMDL
All results in micrograms per liter (µg/L).
Bold results indicate concentrations above 2L GWQS.
EPA = Environmental Protection Agency
MADEP = Massachusetts Department of Environmental Protection
EPH = Extractable Petroleum Hydrocarbon
GCL = Gross Contaminant Level
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
J = Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag).
SUMMARY OF GROUNDWATER LABORATORY RESULTS — STANDARD METHOD 6200B & EPA METHOD 625
Method
All EPA 625 AnalytesIsopropylbenzene (Cumene)BenzeneVaries
Varies
Standard Method 6200B
30,500
70
5,000
1
Contaminant of
Concern
EthylbenzeneGCL (µg/L)
2L GWQS (µg/L) All Other SM 6200B AnalytesWell/
Sample
ID
MW-01 n-Propylbenzene80,000
600 Naphthalene Varies
Varies
6,000
6
26,100
70
260,000
600
28,500
400
24,100
400 Total Xylenes 50,000
500Toluene 1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneQuality Turf; Hwy 53 Diesel Spill Inc. 96860; T5_GW Results (SM & EPA)
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023
Page 1 of 1
TABLE 6
SUMMARY OF GROUNDWATER LABORATORY RESULTS — MADEP EPH/VPH
Incident Name and No.: Quality Turf Fuel Spill - 96860
Date
Collected
(mm/dd/yy)
01/03/23 <97.1 <97.1 <97.1 210 <200 <200 210 <297.1 <97.1 <297.1
All results in micrograms per liter (µg/L).
MADEP = Massachusetts Department of Environmental Protection
EPH = Extractable Petroleum Hydrocarbon
VPH = Volatile Petroleum Hydrocarbon
BMDL = Below Method Detection Limit (refer to analytical report for a complete list of analytes and detection limits)
GCL = Gross Contaminant Level
2L GWQS = NCAC T15A:02L Groundwater Quality Standards
< = Less than method detection limit
NE = Not Established
Well/
Sample
ID
Method EPH Analytical
Fractions
VPH Analytical
Fractions
Combined MADEP
EPH/VPH Fractions
Contaminant of
Concern
C9-C18 AliphaticC19-C36 AliphaticC11-C22 AromaticC5-C8 AliphaticC9-C12 AliphaticC9-C10 AromaticC5-C8 AliphaticsC9-C18 AliphaticsC19-C36 AliphaticsC9-C22 AromaticsMW-01
GCL (µg/L)
2L GWQS (µg/L)
NE
700
NE
10,000
NE
200
NE
200
NE
400
NE
700
NE
200
NE
400
NE
700
NE
10,000
Quality Turf; Hwy 53 Diesel Spill Inc. 96860; T6_GW Results (MADEP)
CATLIN Project No. 222289
CATLIN Engineers and Scientists
February 2023

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

FIGURES
Copyright:© 2013 National Geographic Society, i-cubed
2,000 0 2,000 4,0001,000
Feet
³
FIGUREPROJECTTITLE
1
QUALITY TURF
FUEL SPILL3698 NC HWY 53 EBURGAW, NC
SITE VICINITY MAP
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY96860222289FEB 2023 AS SHOWN GDH/BJA
SITE LOCATION
!>
!>
MW-01
Source: Esri, Maxar, Earthstar Geographics, and the GIS User Community
20 0 20 4010
Feet
³
Parcel Boundary
LEGEND
FIGUREPROJECTTITLEQUALITY TURFFUEL SPILL3698 NC HWY 53 EBURGAW, NC
SITE MAP
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY96860222289FEB 2023 AS SHOWN KMC/BJA
2
Excavation Limits
Monitoring Well(Type II)!>
##
##
!>
West North
EastSouth
S ource: Esri, Maxar, Earthstar Geographics, and the GIS User Community
20 0 20 4010
Feet
³
Parcel Boundary
LEGEND
FIGUREPROJECTTITLEQUALIT Y T UR FFUEL S PILL3698 NC HW Y 53 EBUR GAW , NC
S UMMAR IZ ED S OIL S AMPLEANALY T ICAL R ES ULT S —NOV EMBER 29, 2022
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY96860222289AS S HOW N GDH/BJA
3
Excavation Limits
S oil S ample#
SUMMARY OF SOIL LABORATORY RESULTS - VARIOUS METHODSIncident Name and No.: Quality Turf Fuel S pill - 96860 EPA 8260D EPA 8270E
DateCollected
11/29/22 BMS CC BMDL <15.19 J* BMS CC
11/29/22 BMS CC BMDL 99.7 BMS CC
11/29/22 BMS CC BMDL <15.47 J* BMS CC
11/29/22 BMS CC BMDL <13.46 BMS CC
All results in milligrams per kilogram (mg/kg).BMS CC = Below Maximum S oil Contaminant ConcentrationBMDL = Below Method Detection LimitBold results indicate concentrations above the lowest MS CC.R efer to Tables 2 & 3 for additional notes.
Method MADEP EPH/VPH
Contaminant of Concern
All EPA 8260D AnalytesC9-C22 AromaticsAll Other MADEP EPH/V PH AnalytesNOR TH
S OUTH
W ES T
EAS T All EPA 8270E AnalytesSample ID
314697,000
V ariesV ariesV aries
V ariesV ariesV aries
STGW MSCC (mg/kg)Residential MSCC (mg/kg) I/C MSCC (mg/kg)
V ariesV ariesV aries
FEB 2023
!>
!>
MW-01
Sourc e: Esri, Ma xa r, Ea rthsta r Geogra phic s, a nd the GIS User Com m unity
20 0 20 4010
Feet
³
Pa rc el Bound a ry
LEGEND
FIGUREPROJECTTITLEQUALITY TURFFUEL SPILL3698 N C HW Y 53 EBURGAW , N C
SUMMARIZED GROUN DW ATERSAMPLE AN ALYTICAL RESULTS —JAN UARY 3, 2023
INCIDENT NO.JOB NO.DATE SCALE DRAWN BY/CHECKED BY96860222289FEB 2023 AS SHOW N GDH/BJA
4
Exc a va tion Lim its
Monitoring W ell(Type II)!>
Inc id ent N a m e a nd N o.: Qua lity Turf Fuel Spill - 96860
EPA 625
DateCollected
01/03/23 3.2 B2L BMDL 210 BMDL
All results in m ic rogra m s per liter (µg/L).Bold results ind ic a te c onc entra tions a b ove 2L GW QS.B2L = Below 2L GW QSBMDL = Below Method Detec tion Lim itRefer to Ta b les 5 & 6 for a ll other results a nd notes.BenzeneAll Other MADEP EPH/ V PH Ana lytes
Well/SampleID
MADEP EPH/VPH
N E400C5-C8 Alipha tic
SUMMARY OF GROUNDWATER LABORATORY RESULTS - VARIOUS METHODS
V a riesV a ries
V a riesV a ries
V a riesV a ries
MW -01 All Other SM 6200B Ana lytesAll EPA 625 Ana lytes
GCL (µg/L)2L GWQS (µg/L) 5,000 1
Method SM 6200B
Contaminant of Concern

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDICES

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDIX A SITE PHOTOGRAPHS
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 18, 2022 INITIAL EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 7’ x 3’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking North-northwest from Hwy 53
Looking East-northeast from 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 18, 2022 INITIAL EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 7’ x 3’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking South-southeast from near 3698 Hwy 53 Driveway
(Note Stump in center of excavation)
Looking West-southwest from along Hwy 53 (Note Stump in center of excavation)

3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 23, 2022 SUBSEQUENT EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 9’ x 6’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking North-northwest from Hwy 53

Looking North-northwest into excavation from near Hwy 53 (Note water in bottom)
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 23, 2022 SUBSEQUENT EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 9’ x 6’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking East-northeast from 3698 Hwy 53 Driveway
Looking East-northeast into excavation from near 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 23, 2022 SUBSEQUENT EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 9’ x 6’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Looking South-southeast from near 3698 Hwy 53 Driveway
Looking South-southeast into excavation from near 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 23, 2022 SUBSEQUENT EXCAVATION BY QUALITY TURF PERSONNEL ~7’ x 9’ x 6’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking West from along Hwy 53
Looking West-southwest into excavation from along Hwy 53
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking North-northwest from Hwy 53

Looking East-northeast from 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking East-southeast from near 3698 Hwy 53 Driveway
Looking South-southwest from near Northeast end of excavation
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Looking into excavation from near Hwy 53
Looking South-southeast into excavation from near 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023
Excavator collecting sample from western sidewall (typical)
Backfill being dumped directly in excavation
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Loading out concrete (impacted with diesel fuel)
Looking North-northwest across backfilled excavation
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – NOVEMBER 29, 2022 SUBSEQUENT EXCAVATION BY Evo ~10’ x 8’ x 7.5’ DEEP
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Looking East-northeast across backfilled excavation from 3698 Hwy 53 Driveway
Looking North-northeast across backfilled excavation from 3698 Hwy 53 Driveway
3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – DECEMBER 29, 2022 MONITORING WELL INSTALLATION
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Installation of monitoring well looking East from near 3698 Hwy 53 Driveway.

3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – DECEMBER 29, 2022 MONITORING WELL INSTALLATION
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Purging newly installed monitoring well looking Northeast from near 3698 Hwy 53 Driveway.

3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – DECEMBER 29, 2022 MONITORING WELL INSTALLATION
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

Completed installation of monitoring well looking North-northeast from near 3698 Hwy 53 Driveway.

3698 HWY 53 BURGAW DIESEL SPILL SITE PHOTOGRAPHS – JANUARY 3, 2023 GROUNDWATER SAMPLING
Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

MW-01 facing Southeast.
MW-01 facing North-northwest.

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDIX B SOIL DISPOSAL DOCUMENTATION

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDIX C WELL LOG AND WELL CONSTRUCTION RECORD
12.0
0.0
10.0
1
2
Stem
2
Hollow
1
12.0
2.0
12.0
0.0 0.5
1.0
12.02" Sch. 40 PVC2" Slot .010Sch. 40 PVCM
W
6.0
10.0
6.0
10.0
12.0
(SP) - Gray, F. SAND (FILL)
Wet/Saturated at 4' BLS
Lithology obtained from drill cuttings
(SW) - Gray, F. to Med. SAND with tr. shell frags.
Saturated
Lithology obtained from drill cuttings
(CH) - Gray, Highly Plastic CLAY
BORING TERMINATED AT DEPTH 12.0 ft in highly
plastic CLAY
NM
NM
DRILL MACHINE:Diedrich D-50 METHOD:HSA
COUNTY:PENDER
2335461 308239
T.O.C. ELEV.:
TOTAL DEPTH:
WELL DEPTH:
NC
SHEET
2.7
NM
DEPTH
1
12.0
12.0
0 HOUR DTW:
24 HOUR DTW:END DATE:12/29/22
OF1
BORING LOCATION: Center of Excavation
BLOW COUNT
0.5ft
START DATE:12/29/22
0.5ft
WELL ID:
STATE:
MW-01NORTHING:
LOGGED BY:
DRILLER:
CREW:
0.5ft0.5ft
EASTING:
PROJECT NO.:222289
SYSTEM:NCSP NAD 83 (USft)
QUALITY TURF DIESEL FUEL SPILL
HWY 53
PROJECT:Corey Futral
Austin Fowler
LOCATION:BURGAW
ENVIRONMENTAL, CIVILGEOTECHNICAL
Wilmington, Raleigh, Washington,Charleston
CATLIN BORING LOG 222289-QUALITY TURF DIESEL FUEL SPILL HWY 53.GPJ CATLIN.GDT 12/30/22Concrete Bentonite Pellets #2 Medium Sand
0.0
WELL LOG
WELL
DETAIL
SOIL AND ROCK
DESCRIPTIONLAB.DEPTH
MOIS
0.0 LAND SURFACE
LOG
OVA
(ppm)
222289
NM
12/29/22
HSA
4366A
2.65
MW-01
-77.885351
Austin Fowler
34.5917529
PENDER
1
X
12/30/2022
8.25
Surface Pour
CATLIN Engineers and Scientists
X
2 Slot .010
3698 NC-53, BURGAW, NC 28425
Bent. Pellets1
2
N/A
1 12 #2 Medium Sand
12.0
X
Surface Pour
0.5
2 12 PVC
2
Sch. 40
0 Sch. 40 PVC
Well ID#:
Facility/Owner Name Facility ID# (if applicable)
Physical Address, City, and Zip
County Parcel Identification No. (PIN)
(if well field, one lat/long is sufficient)
N
6. Is (are) the well(s):
Yes
TemporaryPermanent or
or No7. Is this a repair to an existing well:
8. Number of wells constructed:
For multiple injection or non-water supply wells ONLY with the same construction, youcan submit one form.
9. Total well depth below land surface:
For multiple wells list all depths in different (example- 3@200' and 2@100')
W
(ft.)10. Static water level below top of casing:
If water level is above casing, use "+"
11. Borehole diameter:
MATERIAL
FROM
Residential Water Supply (shared)
Adapted from Form GW-1
ft.
ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.
ft.
(ft.)
(in.)
ft.
ft.ft.
ft.
ft.
ft.in.
in.
ft.
ft.
ft.ft.
ft.
ft.
13b. Disinfection type:
22. Certification:
Revised 2-22-2016
ft.QUALITY TURF
TO DIAMETER THICKNESS MATERIAL
FROM17. SCREEN DIAMETER SLOT SIZE MATERIALTHICKNESS
FROM TO MATERIAL
ft.ft.
ft.
ft.
FROM TO
18. GROUT
MATERIAL
19. SAND/GRAVEL PACK (if applicable)
1. Well Contractor Information:
This form can be used for single or multiple wells
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:List all applicable well permits (i.e. County, State, Variance, Injection, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural
Non-Water Supply Well:
Monitoring
Geothermal (Heating/Cooling Supply)
Industrial/Commercial
Irrigation
15. INNER CASING OR TUBING (geothermal closed-loop)
Municipal/Public
Residential Water Supply (single)
ft.
ft.ft.
ft.ft.
ft.
ft.ft.
ft.
TO
EMPLACEMENT METHOD & AMOUNT
in.
in.
in.
EMPLACEMENT METHOD
Recovery
Injection Well:
You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of
this record has been provided to the well owner.
If this is a repair, fill out known well construction information and explain the nature ofthe repair under #21 remarks section or on the back of this form.
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
13a. Yield (gpm)
FOR WATER SUPPLY WELLS ONLY:
Method of test:
Amount:
For Internal Use ONLY:
14. WATER ZONES
FROM TO DESCRIPTION
FROM TO
24c. For Water Sypply & Injection Wells:Also submit one copy of this form within 30 days of completion of wellconstruction to the county health department of the county where constructed.
DIAMETER THICKNESS
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
21. REMARKS
20. DRILLING LOG (attach additional sheets if necessary)
5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees:
Signature of Certified Well Contractor Date
24a. For All Wells: Submit this form within 30 days of completion of wellconstruction to the following:
SUBMITTAL INSTRUCTIONS
Division of Water Resources, Information Processing Unit,1617 Mail Service Center, Raleigh, NC 27699-1617
Division of Water Resources, Underground Injection Control Program,1636 Mail Service Center, Raleigh, NC 27699-1636
16. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
North Carolina Department of Environment and Natural Resources - Division of Water Resources
24b. For Injection Wells ONLY: In addition to sending the form to theaddress in 24a above, also submit a copy of this form within 30 days ofcompletion of well construction to the following:
WELL CONSTRUCTION RECORD
23. Site diagram or additional well details:
Aquifer Recharge Groundwater Remediation
Stormwater Drainage
Aquifer Storage and Recovery
Aquifer Test
Experimental Technology
Geothermal (Closed Loop)
Geothermal (Heating/Cooling Return)
Salinity Barrier
Subsidence Control
Tracer
Other (explain under #21 Remarks)
4. Date Well(s) Completed:
5a. Well Location:SEE
ATTAC
H
E
D
N/A
N/A
0.0 0.5 Concrete Surface Pour

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDIX D DAILY ACTIVITIES LOGS AND GROUNDWATER SAMPLING SHEET
CATLIN PROJECT:SAMPLED BY:
CATLIN PROJECT # :DATE SAMPLED:
CLIENT'S NAME:
MW-01 8.23
3.77 1.343
NMT 4.029
12 6.716
2
Method:Bailer Purge Start Time:11:59
Required Bails for 3 Well Volumes:17 Purge Stop Time:12:05
Required Bails for 5 Well Volumes:28 Was Well Purged Dry?no
Number of Bails Removed:17 Sample Time:12:05
Groundwater Removed (gal):4.1
Equipment Used:
Time
pH
(Standard Units)
ORP
(mV)
Specific
Cond.
(µS/cm)
Dissolved
Oxygen
(mg/L)
Temperature
(Co)
11:59 12.28 9.57 1966.94 6.29 26.58
12:00 12.33 12.33 1753.31 3.08 26.14
12:01 12.35 8.49 1919.59 3.01 26.11
12:02 12.33 3.79 1825.89 3.01 26.18
12:03 12.32 0.98 1536.76 2.97 26.21
12:04 12.32 -0.44 1491.99 3.01 26.31
12:05 12.31 -0.15 1494.65 3.03 26.35
Laboratory:Pace Analysis:
Quality Turf
Monitoring Well Information
T.Mizelle
1/3/2023
Diesel Spill - Hwy 53
222289
6200B/625/EPH/VPH
Laboratory Analysis Information
Geochemical Parameters
Depth to Water (ft below TOC)
High dark brown.
Aqua Troll 600
Turbidity and Additional
Sampling Notes
GROUNDWATER SAMPLING FORM
Water Column (ft below TOC)
One Well Volume (gal)
Three Well Volumes (gal)
Five Well Volumes (gal)
Well Data
Well ID
Depth to Product (ft below TOC)
Total Well Depth (ft)
Purging Information Information
Volume of Groundwater in Well
Well Diameter (inches)

Quality Turf; Hwy 53 Diesel Spill Inc. 96860 CATLIN Engineers and Scientists
CATLIN Project No. 222289 February 2023

APPENDIX E

LABORATORY ANALYTICAL REPORT
AND CHAIN OF CUSTODY DOCUMENT

Hydrocarbon Analysis Results
Client:CATLIN Samples taken Friday, November 18, 2022
Address:220 OLD DAIRY ROAD Samples extracted Monday, November 21, 2022
WILMINGTON NC 28405 Samples analysed Tuesday, November 22, 2022
Contact:BEN ASHBA Operator MAX MOYER
Project:HWY 53
5 F03640
Matrix Sample ID Dilution
used
BTEX
(C6 - C9)
GRO
(C5 - C10)
DRO
(C10 - C35)
TPH
(C5 - C35)
Total
Aromatics
(C10-C35)
16 EPA
PAHs BaP HC Fingerprint Match
% light % mid %
heavy
s NORTH 2'50.6 <1.3 177.2 396.6 573.8 56.2 2.1 <0.051 98.7 1.3 0 Undeg.Diesel 91.8%,(FCM)
s WEST 2'53.2 <1.3 29.2 101.2 130.4 8.2 <0.43 <0.053 98.2 1.7 0.1 Undeg.Diesel 92.3%,(FCM)
s SOUTH 2'1038.0 <25.9 1094 2176 3270 185 <8.3 <1 99 1 0 Undeg.Diesel 92.4%,(FCM)
s EAST 2'47.2 <1.2 43 99.1 142.1 8.4 <0.38 <0.047 98.8 1.1 0.1 Undeg.Diesel 93.5%,(FCM)
s FLOOR 3'1014.0 119.9 1024 2614 3638 223.4 <8.1 <1 98.8 1.2 0 Undeg.Diesel 88.9%,(FCM)
Initial Calibrator QC check OK Final FCM QC Check OK 90.7 %
Results generated by a QED HC-1 analyser. Concentration values in mg/kg for soil samples and mg/L for water samples. Soil values are not corrected for moisture or stone content
Fingerprints provide a tentative hydrocarbon identification. The abbreviations are:- FCM = Results calculated using Fundamental Calibration Mode : % = confidence for sample fingerprint match to library
(SBS) or (LBS) = Site Specific or Library Background Subtraction applied to result : (PFM) = Poor Fingerprint Match : (T) = Turbid : (P) = Particulate present
Ratios
QED Hydrocarbon FingerprintsProject:HWY 53 11/22/2022
23022
NORTH 2' : Undeg.Diesel 91.8%,(FCM)
5129
WEST 2' : Undeg.Diesel 92.3%,(FCM)
6021
SOUTH 2' : Undeg.Diesel 92.4%,(FCM)
5949
EAST 2' : Undeg.Diesel 93.5%,(FCM)
7436
FLOOR 3' : Undeg.Diesel 88.9%,(FCM)
#=CL#
December 08, 2022
LIMS USE: FR - BEN ASHBA
LIMS OBJECT ID: 92639042
92639042
Project:
Pace Project No.:
RE:
Ben Ashba
CATLIN Engineers & Scientists, Inc.
220 Old Dairy Road
Wilmington, NC 28405
WOOTEN DIESEL FUEL SPILL HWY53
Dear Ben Ashba:
Enclosed are the analytical results for sample(s) received by the laboratory on November 30, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
cc:Matthew Ginther, Catlin Engineers and Scientists
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 56
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 56
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Lab ID Sample ID Matrix Date Collected Date Received
92639042001 EAST Solid 11/29/22 11:45 11/30/22 10:50
92639042002 NORTH Solid 11/29/22 11:46 11/30/22 10:50
92639042003 SOUTH Solid 11/29/22 11:48 11/30/22 10:50
92639042004 WEST Solid 11/29/22 11:50 11/30/22 10:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 56
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92639042001 EAST MADEP EPH 7 PASI-CBAJ
MADEP VPH 6 PANAV
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
92639042002 NORTH MADEP EPH 7 PASI-CBAJ
MADEP VPH 6 PANAV
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
92639042003 SOUTH MADEP EPH 7 PASI-CBAJ
MADEP VPH 6 PANAV
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
92639042004 WEST MADEP EPH 7 PASI-CBAJ
MADEP VPH 6 PANAV
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CLMB
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 56
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92639042001 EAST
Aliphatic (C09-C12)2.36J mg/kg 12/07/22 02:49 J,ML6.74MADEP VPH
Aromatic (C09-C10),Unadjusted 3.19J mg/kg 12/07/22 02:49 J6.74MADEP VPH
Total VPH 5.55J mg/kg 12/07/22 02:49 J,ML6.74MADEP VPH
Ethylbenzene 8.1J ug/kg 12/02/22 00:2510.6EPA 8260D
Toluene 13.6 ug/kg 12/02/22 00:2510.6EPA 8260D
1,2,4-Trimethylbenzene 18.2 ug/kg 12/02/22 00:2510.6EPA 8260D
1,3,5-Trimethylbenzene 7.9J ug/kg 12/02/22 00:2510.6EPA 8260D
Xylene (Total)28.9 ug/kg 12/02/22 00:2521.2EPA 8260D
m&p-Xylene 17.6J ug/kg 12/02/22 00:2521.2EPA 8260D
o-Xylene 11.3 ug/kg 12/02/22 00:2510.6EPA 8260D
Percent Moisture 15.1 %12/01/22 15:19 N20.10SW-846
Total Solids 86.5 %12/05/22 15:43SM 2540G
92639042002 NORTH
Aliphatic (C09-C18)70.0 mg/kg 12/06/22 12:04 N211.6MADEP EPH
Aliphatic (C19-C36)23.9 mg/kg 12/06/22 12:04 N211.6MADEP EPH
Aromatic (C11-C22)23.3 mg/kg 12/06/22 12:04 N211.6MADEP EPH
Aliphatic (C05-C08)9.10 mg/kg 12/07/22 03:218.35MADEP VPH
Aliphatic (C09-C12)93.2 mg/kg 12/07/22 03:218.35MADEP VPH
Aromatic (C09-C10),Unadjusted 76.4 mg/kg 12/07/22 03:218.35MADEP VPH
Total VPH 179 mg/kg 12/07/22 03:218.35MADEP VPH
Ethylbenzene 31.6 ug/kg 12/02/22 19:086.7EPA 8260D
Isopropylbenzene (Cumene)16.0 ug/kg 12/02/22 19:086.7EPA 8260D
p-Isopropyltoluene 77.6 ug/kg 12/02/22 19:086.7EPA 8260D
Toluene 16.2 ug/kg 12/02/22 19:086.7EPA 8260D
1,2,4-Trimethylbenzene 284 ug/kg 12/02/22 19:086.7EPA 8260D
Xylene (Total)168 ug/kg 12/02/22 19:0813.4EPA 8260D
m&p-Xylene 102 ug/kg 12/02/22 19:0813.4EPA 8260D
o-Xylene 66.7 ug/kg 12/02/22 19:086.7EPA 8260D
Percent Moisture 14.6 %12/01/22 15:19 N20.10SW-846
Total Solids 85.0 %12/05/22 15:43SM 2540G
92639042003 SOUTH
Aliphatic (C09-C12)5.98J mg/kg 12/07/22 03:54 J6.68MADEP VPH
Aromatic (C09-C10),Unadjusted 3.77J mg/kg 12/07/22 03:54 J6.68MADEP VPH
Total VPH 9.75 mg/kg 12/07/22 03:546.68MADEP VPH
Benzene 7.0J ug/kg 12/02/22 00:4312.3EPA 8260D
Ethylbenzene 18.8 ug/kg 12/02/22 00:4312.3EPA 8260D
Toluene 32.7 ug/kg 12/02/22 00:4312.3EPA 8260D
1,2,4-Trimethylbenzene 8.9J ug/kg 12/02/22 00:4312.3EPA 8260D
1,3,5-Trimethylbenzene 7.3J ug/kg 12/02/22 00:4312.3EPA 8260D
Xylene (Total)60.1 ug/kg 12/02/22 00:4324.6EPA 8260D
m&p-Xylene 39.4 ug/kg 12/02/22 00:4324.6EPA 8260D
o-Xylene 20.7 ug/kg 12/02/22 00:4312.3EPA 8260D
Percent Moisture 15.3 %12/01/22 15:19 N20.10SW-846
Total Solids 86.0 %12/05/22 15:43SM 2540G
92639042004 WEST
Aliphatic (C09-C12)3.12J mg/kg 12/07/22 04:26 J6.78MADEP VPH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 56
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92639042004 WEST
Total VPH 3.12J mg/kg 12/07/22 04:26 J6.78MADEP VPH
Benzene 5.7J ug/kg 12/02/22 01:0010EPA 8260D
Ethylbenzene 14.0 ug/kg 12/02/22 01:0010EPA 8260D
n-Propylbenzene 5.9J ug/kg 12/02/22 01:0010EPA 8260D
Toluene 24.1 ug/kg 12/02/22 01:0010EPA 8260D
1,2,4-Trimethylbenzene 15.2 ug/kg 12/02/22 01:0010EPA 8260D
1,3,5-Trimethylbenzene 7.2J ug/kg 12/02/22 01:0010EPA 8260D
Xylene (Total)56.2 ug/kg 12/02/22 01:0019.9EPA 8260D
m&p-Xylene 32.5 ug/kg 12/02/22 01:0019.9EPA 8260D
o-Xylene 23.7 ug/kg 12/02/22 01:0010EPA 8260D
Percent Moisture 12.3 %12/01/22 15:19 N20.10SW-846
Total Solids 85.7 %12/05/22 15:43SM 2540G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:EAST Lab ID:92639042001 Collected:11/29/22 11:45 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)ND mg/kg 12/06/22 11:39 N212/05/22 09:5912.0 12.0 1
Aliphatic (C19-C36)ND mg/kg 12/06/22 11:39 N212/05/22 09:5912.0 12.0 1
Aromatic (C11-C22)ND mg/kg 12/06/22 11:39 N212/05/22 09:5912.0 12.0 1
Surrogates
1-Chlorooctadecane (S)63 %12/06/22 11:39 3386-33-212/05/22 09:5940-140 1
o-Terphenyl (S)56 %12/06/22 11:39 84-15-112/05/22 09:5940-140 1
2-Fluorobiphenyl (S)101 %12/06/22 11:39 321-60-812/05/22 09:5940-140 1
2-Bromonaphthalene (S)113 %12/06/22 11:39 580-13-212/05/22 09:5940-140 1
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 12/07/22 02:49 ML11/29/22 11:456.74 2.25 1
Aliphatic (C09-C12)2.36J mg/kg 12/07/22 02:49 J,ML11/29/22 11:456.74 2.25 1
Aromatic (C09-C10),Unadjusted 3.19J mg/kg 12/07/22 02:49 TPHC9C10A J11/29/22 11:456.74 2.25 1
Total VPH 5.55J mg/kg 12/07/22 02:49 VPH J,ML11/29/22 11:456.74 2.25 1
Surrogates
2,5-Dibromotoluene (FID)89.7 %12/07/22 02:49 615-59-8FID11/29/22 11:4570.0-130 1
2,5-Dibromotoluene (PID)88.7 %12/07/22 02:49 615-59-8PID11/29/22 11:4570.0-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 12/05/22 18:22 83-32-912/05/22 11:213871361
Acenaphthylene ND ug/kg 12/05/22 18:22 208-96-812/05/22 11:213871361
Aniline ND ug/kg 12/05/22 18:22 62-53-312/05/22 11:213871511
Anthracene ND ug/kg 12/05/22 18:22 120-12-712/05/22 11:213871271
Benzo(a)anthracene ND ug/kg 12/05/22 18:22 56-55-312/05/22 11:213871291
Benzo(a)pyrene ND ug/kg 12/05/22 18:22 50-32-812/05/22 11:213871341
Benzo(b)fluoranthene ND ug/kg 12/05/22 18:22 205-99-212/05/22 11:213871291
Benzo(g,h,i)perylene ND ug/kg 12/05/22 18:22 191-24-212/05/22 11:213871501
Benzo(k)fluoranthene ND ug/kg 12/05/22 18:22 207-08-912/05/22 11:213871361
Benzoic Acid ND ug/kg 12/05/22 18:22 65-85-012/05/22 11:2119408321
Benzyl alcohol ND ug/kg 12/05/22 18:22 100-51-612/05/22 11:217742931
4-Bromophenylphenyl ether ND ug/kg 12/05/22 18:22 101-55-312/05/22 11:213871491
Butylbenzylphthalate ND ug/kg 12/05/22 18:22 85-68-712/05/22 11:213871631
4-Chloro-3-methylphenol ND ug/kg 12/05/22 18:22 59-50-712/05/22 11:217742721
4-Chloroaniline ND ug/kg 12/05/22 18:22 106-47-812/05/22 11:217743041
bis(2-Chloroethoxy)methane ND ug/kg 12/05/22 18:22 111-91-112/05/22 11:213871611
bis(2-Chloroethyl) ether ND ug/kg 12/05/22 18:22 111-44-412/05/22 11:213871451
2-Chloronaphthalene ND ug/kg 12/05/22 18:22 91-58-712/05/22 11:213871541
2-Chlorophenol ND ug/kg 12/05/22 18:22 95-57-812/05/22 11:213871451
4-Chlorophenylphenyl ether ND ug/kg 12/05/22 18:22 7005-72-312/05/22 11:213871441
Chrysene ND ug/kg 12/05/22 18:22 218-01-9 v212/05/22 11:213871411
Dibenz(a,h)anthracene ND ug/kg 12/05/22 18:22 53-70-312/05/22 11:213871491
Dibenzofuran ND ug/kg 12/05/22 18:22 132-64-912/05/22 11:213871401
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:EAST Lab ID:92639042001 Collected:11/29/22 11:45 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
1,2-Dichlorobenzene ND ug/kg 12/05/22 18:22 95-50-112/05/22 11:213871401
1,3-Dichlorobenzene ND ug/kg 12/05/22 18:22 541-73-112/05/22 11:213871371
1,4-Dichlorobenzene ND ug/kg 12/05/22 18:22 106-46-712/05/22 11:213871481
3,3'-Dichlorobenzidine ND ug/kg 12/05/22 18:22 91-94-1 v212/05/22 11:217742621
2,4-Dichlorophenol ND ug/kg 12/05/22 18:22 120-83-212/05/22 11:213871511
Diethylphthalate ND ug/kg 12/05/22 18:22 84-66-212/05/22 11:213871421
2,4-Dimethylphenol ND ug/kg 12/05/22 18:22 105-67-912/05/22 11:213871611
Dimethylphthalate ND ug/kg 12/05/22 18:22 131-11-312/05/22 11:213871411
Di-n-butylphthalate ND ug/kg 12/05/22 18:22 84-74-212/05/22 11:213871301
4,6-Dinitro-2-methylphenol ND ug/kg 12/05/22 18:22 534-52-112/05/22 11:217743611
2,4-Dinitrophenol ND ug/kg 12/05/22 18:22 51-28-512/05/22 11:21194012001
2,4-Dinitrotoluene ND ug/kg 12/05/22 18:22 121-14-212/05/22 11:213871491
2,6-Dinitrotoluene ND ug/kg 12/05/22 18:22 606-20-212/05/22 11:213871421
Di-n-octylphthalate ND ug/kg 12/05/22 18:22 117-84-012/05/22 11:213871531
bis(2-Ethylhexyl)phthalate ND ug/kg 12/05/22 18:22 117-81-712/05/22 11:213871501
Fluoranthene ND ug/kg 12/05/22 18:22 206-44-012/05/22 11:213871331
Fluorene ND ug/kg 12/05/22 18:22 86-73-712/05/22 11:213871361
Hexachloro-1,3-butadiene ND ug/kg 12/05/22 18:22 87-68-312/05/22 11:213871681
Hexachlorobenzene ND ug/kg 12/05/22 18:22 118-74-112/05/22 11:213871511
Hexachlorocyclopentadiene ND ug/kg 12/05/22 18:22 77-47-412/05/22 11:213872221
Hexachloroethane ND ug/kg 12/05/22 18:22 67-72-112/05/22 11:213871481
Indeno(1,2,3-cd)pyrene ND ug/kg 12/05/22 18:22 193-39-512/05/22 11:213871531
Isophorone ND ug/kg 12/05/22 18:22 78-59-112/05/22 11:213871721
1-Methylnaphthalene ND ug/kg 12/05/22 18:22 90-12-012/05/22 11:213871361
2-Methylnaphthalene ND ug/kg 12/05/22 18:22 91-57-612/05/22 11:213871551
2-Methylphenol(o-Cresol)ND ug/kg 12/05/22 18:22 95-48-712/05/22 11:213871581
3&4-Methylphenol(m&p Cresol)ND ug/kg 12/05/22 18:22 15831-10-412/05/22 11:213871561
Naphthalene ND ug/kg 12/05/22 18:22 91-20-312/05/22 11:213871311
2-Nitroaniline ND ug/kg 12/05/22 18:22 88-74-412/05/22 11:2119403171
3-Nitroaniline ND ug/kg 12/05/22 18:22 99-09-212/05/22 11:2119403041
4-Nitroaniline ND ug/kg 12/05/22 18:22 100-01-612/05/22 11:217742941
Nitrobenzene ND ug/kg 12/05/22 18:22 98-95-312/05/22 11:213871801
2-Nitrophenol ND ug/kg 12/05/22 18:22 88-75-512/05/22 11:213871681
4-Nitrophenol ND ug/kg 12/05/22 18:22 100-02-712/05/22 11:2119407491
N-Nitrosodimethylamine ND ug/kg 12/05/22 18:22 62-75-912/05/22 11:213871301
N-Nitroso-di-n-propylamine ND ug/kg 12/05/22 18:22 621-64-712/05/22 11:213871451
N-Nitrosodiphenylamine ND ug/kg 12/05/22 18:22 86-30-612/05/22 11:213871371
2,2'-Oxybis(1-chloropropane)ND ug/kg 12/05/22 18:22 108-60-112/05/22 11:213871841
Pentachlorophenol ND ug/kg 12/05/22 18:22 87-86-512/05/22 11:217743791
Phenanthrene ND ug/kg 12/05/22 18:22 85-01-812/05/22 11:213871271
Phenol ND ug/kg 12/05/22 18:22 108-95-212/05/22 11:213871721
Pyrene ND ug/kg 12/05/22 18:22 129-00-012/05/22 11:213871571
Pyridine ND ug/kg 12/05/22 18:22 110-86-112/05/22 11:213871221
1,2,4-Trichlorobenzene ND ug/kg 12/05/22 18:22 120-82-112/05/22 11:213871531
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:EAST Lab ID:92639042001 Collected:11/29/22 11:45 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,4,5-Trichlorophenol ND ug/kg 12/05/22 18:22 95-95-412/05/22 11:213871771
2,4,6-Trichlorophenol ND ug/kg 12/05/22 18:22 88-06-212/05/22 11:213871601
Surrogates
Nitrobenzene-d5 (S)59 %12/05/22 18:22 4165-60-012/05/22 11:2110-130 1
2-Fluorobiphenyl (S)44 %12/05/22 18:22 321-60-812/05/22 11:2110-130 1
Terphenyl-d14 (S)61 %12/05/22 18:22 1718-51-012/05/22 11:2110-130 1
Phenol-d6 (S)65 %12/05/22 18:22 13127-88-312/05/22 11:2110-130 1
2-Fluorophenol (S)63 %12/05/22 18:22 367-12-412/05/22 11:2110-130 1
2,4,6-Tribromophenol (S)64 %12/05/22 18:22 118-79-612/05/22 11:2110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 12/02/22 00:25 67-64-111/30/22 18:4821268.0 1
Benzene ND ug/kg 12/02/22 00:25 71-43-211/30/22 18:4810.6 4.2 1
Bromobenzene ND ug/kg 12/02/22 00:25 108-86-111/30/22 18:4810.6 3.5 1
Bromochloromethane ND ug/kg 12/02/22 00:25 74-97-511/30/22 18:4810.6 3.1 1
Bromodichloromethane ND ug/kg 12/02/22 00:25 75-27-411/30/22 18:4810.6 4.1 1
Bromoform ND ug/kg 12/02/22 00:25 75-25-211/30/22 18:4810.6 3.7 1
Bromomethane ND ug/kg 12/02/22 00:25 74-83-9 IK11/30/22 18:4821.2 16.7 1
2-Butanone (MEK)ND ug/kg 12/02/22 00:25 78-93-311/30/22 18:4821250.9 1
n-Butylbenzene ND ug/kg 12/02/22 00:25 104-51-811/30/22 18:4810.6 5.0 1
sec-Butylbenzene ND ug/kg 12/02/22 00:25 135-98-811/30/22 18:4810.6 4.7 1
tert-Butylbenzene ND ug/kg 12/02/22 00:25 98-06-611/30/22 18:4810.6 3.8 1
Carbon tetrachloride ND ug/kg 12/02/22 00:25 56-23-511/30/22 18:4810.6 4.0 1
Chlorobenzene ND ug/kg 12/02/22 00:25 108-90-711/30/22 18:4810.6 2.0 1
Chloroethane ND ug/kg 12/02/22 00:25 75-00-311/30/22 18:4821.2 8.2 1
Chloroform ND ug/kg 12/02/22 00:25 67-66-311/30/22 18:4810.6 6.4 1
Chloromethane ND ug/kg 12/02/22 00:25 74-87-311/30/22 18:4821.2 8.9 1
2-Chlorotoluene ND ug/kg 12/02/22 00:25 95-49-811/30/22 18:4810.6 3.8 1
4-Chlorotoluene ND ug/kg 12/02/22 00:25 106-43-411/30/22 18:4810.6 1.9 1
1,2-Dibromo-3-chloropropane ND ug/kg 12/02/22 00:25 96-12-811/30/22 18:4810.6 4.1 1
Dibromochloromethane ND ug/kg 12/02/22 00:25 124-48-111/30/22 18:4810.6 6.0 1
1,2-Dibromoethane (EDB)ND ug/kg 12/02/22 00:25 106-93-411/30/22 18:4810.6 4.7 1
Dibromomethane ND ug/kg 12/02/22 00:25 74-95-311/30/22 18:4810.6 2.3 1
1,2-Dichlorobenzene ND ug/kg 12/02/22 00:25 95-50-111/30/22 18:4810.6 3.8 1
1,3-Dichlorobenzene ND ug/kg 12/02/22 00:25 541-73-111/30/22 18:4810.6 3.3 1
1,4-Dichlorobenzene ND ug/kg 12/02/22 00:25 106-46-711/30/22 18:4810.6 2.8 1
Dichlorodifluoromethane ND ug/kg 12/02/22 00:25 75-71-8 v111/30/22 18:4821.2 4.6 1
1,1-Dichloroethane ND ug/kg 12/02/22 00:25 75-34-311/30/22 18:4810.6 4.4 1
1,2-Dichloroethane ND ug/kg 12/02/22 00:25 107-06-211/30/22 18:4810.6 7.0 1
1,1-Dichloroethene ND ug/kg 12/02/22 00:25 75-35-411/30/22 18:4810.6 4.4 1
cis-1,2-Dichloroethene ND ug/kg 12/02/22 00:25 156-59-211/30/22 18:4810.6 3.6 1
trans-1,2-Dichloroethene ND ug/kg 12/02/22 00:25 156-60-511/30/22 18:4810.6 3.7 1
1,2-Dichloropropane ND ug/kg 12/02/22 00:25 78-87-511/30/22 18:4810.6 3.2 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:EAST Lab ID:92639042001 Collected:11/29/22 11:45 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,3-Dichloropropane ND ug/kg 12/02/22 00:25 142-28-911/30/22 18:4810.6 3.3 1
2,2-Dichloropropane ND ug/kg 12/02/22 00:25 594-20-7 IK11/30/22 18:4810.6 3.5 1
1,1-Dichloropropene ND ug/kg 12/02/22 00:25 563-58-611/30/22 18:4810.6 5.1 1
cis-1,3-Dichloropropene ND ug/kg 12/02/22 00:25 10061-01-511/30/22 18:4810.6 2.9 1
trans-1,3-Dichloropropene ND ug/kg 12/02/22 00:25 10061-02-611/30/22 18:4810.6 3.6 1
Diisopropyl ether ND ug/kg 12/02/22 00:25 108-20-311/30/22 18:4810.6 2.9 1
Ethylbenzene 8.1J ug/kg 12/02/22 00:25 100-41-411/30/22 18:4810.6 4.9 1
Hexachloro-1,3-butadiene ND ug/kg 12/02/22 00:25 87-68-311/30/22 18:4821.2 17.3 1
2-Hexanone ND ug/kg 12/02/22 00:25 591-78-611/30/22 18:4810610.2 1
Isopropylbenzene (Cumene)ND ug/kg 12/02/22 00:25 98-82-811/30/22 18:4810.6 3.6 1
p-Isopropyltoluene ND ug/kg 12/02/22 00:25 99-87-611/30/22 18:4810.6 5.2 1
Methylene Chloride ND ug/kg 12/02/22 00:25 75-09-2 IK11/30/22 18:4842.4 29.0 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 12/02/22 00:25 108-10-111/30/22 18:4810610.2 1
Methyl-tert-butyl ether ND ug/kg 12/02/22 00:25 1634-04-411/30/22 18:4810.6 4.0 1
Naphthalene ND ug/kg 12/02/22 00:25 91-20-311/30/22 18:4810.6 5.6 1
n-Propylbenzene ND ug/kg 12/02/22 00:25 103-65-111/30/22 18:4810.6 3.8 1
Styrene ND ug/kg 12/02/22 00:25 100-42-511/30/22 18:4810.6 2.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 12/02/22 00:25 630-20-611/30/22 18:4810.6 4.1 1
1,1,2,2-Tetrachloroethane ND ug/kg 12/02/22 00:25 79-34-511/30/22 18:4810.6 2.8 1
Tetrachloroethene ND ug/kg 12/02/22 00:25 127-18-411/30/22 18:4810.6 3.3 1
Toluene 13.6 ug/kg 12/02/22 00:25 108-88-311/30/22 18:4810.6 3.0 1
1,2,3-Trichlorobenzene ND ug/kg 12/02/22 00:25 87-61-611/30/22 18:4810.6 8.6 1
1,2,4-Trichlorobenzene ND ug/kg 12/02/22 00:25 120-82-111/30/22 18:4810.6 8.9 1
1,1,1-Trichloroethane ND ug/kg 12/02/22 00:25 71-55-611/30/22 18:4810.6 5.5 1
1,1,2-Trichloroethane ND ug/kg 12/02/22 00:25 79-00-511/30/22 18:4810.6 3.5 1
Trichloroethene ND ug/kg 12/02/22 00:25 79-01-611/30/22 18:4810.6 2.7 1
Trichlorofluoromethane ND ug/kg 12/02/22 00:25 75-69-411/30/22 18:4810.6 5.8 1
1,2,3-Trichloropropane ND ug/kg 12/02/22 00:25 96-18-411/30/22 18:4810.6 5.4 1
1,2,4-Trimethylbenzene 18.2 ug/kg 12/02/22 00:25 95-63-611/30/22 18:4810.6 2.9 1
1,3,5-Trimethylbenzene 7.9J ug/kg 12/02/22 00:25 108-67-811/30/22 18:4810.6 3.6 1
Vinyl acetate ND ug/kg 12/02/22 00:25 108-05-4 IK11/30/22 18:481067.7 1
Vinyl chloride ND ug/kg 12/02/22 00:25 75-01-411/30/22 18:4821.2 5.4 1
Xylene (Total)28.9 ug/kg 12/02/22 00:25 1330-20-711/30/22 18:4821.2 6.0 1
m&p-Xylene 17.6J ug/kg 12/02/22 00:25 179601-23-111/30/22 18:4821.2 7.2 1
o-Xylene 11.3 ug/kg 12/02/22 00:25 95-47-611/30/22 18:4810.6 4.7 1
Surrogates
Toluene-d8 (S)100 %12/02/22 00:25 2037-26-511/30/22 18:4870-130 1
4-Bromofluorobenzene (S)102 %12/02/22 00:25 460-00-411/30/22 18:4870-130 1
1,2-Dichloroethane-d4 (S)105 %12/02/22 00:25 17060-07-011/30/22 18:4870-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.1 %12/01/22 15:19 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:EAST Lab ID:92639042001 Collected:11/29/22 11:45 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 86.5 %12/05/22 15:4312/05/22 15:371
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:NORTH Lab ID:92639042002 Collected:11/29/22 11:46 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)70.0 mg/kg 12/06/22 12:04 N212/05/22 09:5911.6 11.6 1
Aliphatic (C19-C36)23.9 mg/kg 12/06/22 12:04 N212/05/22 09:5911.6 11.6 1
Aromatic (C11-C22)23.3 mg/kg 12/06/22 12:04 N212/05/22 09:5911.6 11.6 1
Surrogates
1-Chlorooctadecane (S)100 %12/06/22 12:04 3386-33-212/05/22 09:5940-140 1
o-Terphenyl (S)83 %12/06/22 12:04 84-15-112/05/22 09:5940-140 1
2-Fluorobiphenyl (S)125 %12/06/22 12:04 321-60-812/05/22 09:5940-140 1
2-Bromonaphthalene (S)149 %12/06/22 12:04 580-13-2 S512/05/22 09:5940-140 1
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)9.10 mg/kg 12/07/22 03:2111/29/22 11:468.35 2.77 1.27
Aliphatic (C09-C12)93.2 mg/kg 12/07/22 03:2111/29/22 11:468.35 2.77 1.27
Aromatic (C09-C10),Unadjusted 76.4 mg/kg 12/07/22 03:21 TPHC9C10A11/29/22 11:468.35 2.77 1.27
Total VPH 179 mg/kg 12/07/22 03:21 VPH11/29/22 11:468.35 2.77 1.27
Surrogates
2,5-Dibromotoluene (FID)122 %12/07/22 03:21 615-59-8FID11/29/22 11:4670.0-130 1.27
2,5-Dibromotoluene (PID)82.8 %12/07/22 03:21 615-59-8PID11/29/22 11:4670.0-130 1.27
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 12/05/22 19:08 83-32-912/05/22 11:213881361
Acenaphthylene ND ug/kg 12/05/22 19:08 208-96-812/05/22 11:213881361
Aniline ND ug/kg 12/05/22 19:08 62-53-312/05/22 11:213881521
Anthracene ND ug/kg 12/05/22 19:08 120-12-712/05/22 11:213881271
Benzo(a)anthracene ND ug/kg 12/05/22 19:08 56-55-312/05/22 11:213881291
Benzo(a)pyrene ND ug/kg 12/05/22 19:08 50-32-812/05/22 11:213881341
Benzo(b)fluoranthene ND ug/kg 12/05/22 19:08 205-99-212/05/22 11:213881291
Benzo(g,h,i)perylene ND ug/kg 12/05/22 19:08 191-24-212/05/22 11:213881501
Benzo(k)fluoranthene ND ug/kg 12/05/22 19:08 207-08-912/05/22 11:213881361
Benzoic Acid ND ug/kg 12/05/22 19:08 65-85-012/05/22 11:2119408331
Benzyl alcohol ND ug/kg 12/05/22 19:08 100-51-612/05/22 11:217752941
4-Bromophenylphenyl ether ND ug/kg 12/05/22 19:08 101-55-312/05/22 11:213881491
Butylbenzylphthalate ND ug/kg 12/05/22 19:08 85-68-712/05/22 11:213881631
4-Chloro-3-methylphenol ND ug/kg 12/05/22 19:08 59-50-712/05/22 11:217752731
4-Chloroaniline ND ug/kg 12/05/22 19:08 106-47-812/05/22 11:217753041
bis(2-Chloroethoxy)methane ND ug/kg 12/05/22 19:08 111-91-112/05/22 11:213881611
bis(2-Chloroethyl) ether ND ug/kg 12/05/22 19:08 111-44-412/05/22 11:213881461
2-Chloronaphthalene ND ug/kg 12/05/22 19:08 91-58-712/05/22 11:213881541
2-Chlorophenol ND ug/kg 12/05/22 19:08 95-57-812/05/22 11:213881461
4-Chlorophenylphenyl ether ND ug/kg 12/05/22 19:08 7005-72-312/05/22 11:213881441
Chrysene ND ug/kg 12/05/22 19:08 218-01-912/05/22 11:213881411
Dibenz(a,h)anthracene ND ug/kg 12/05/22 19:08 53-70-312/05/22 11:213881491
Dibenzofuran ND ug/kg 12/05/22 19:08 132-64-912/05/22 11:213881401
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:NORTH Lab ID:92639042002 Collected:11/29/22 11:46 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
1,2-Dichlorobenzene ND ug/kg 12/05/22 19:08 95-50-112/05/22 11:213881401
1,3-Dichlorobenzene ND ug/kg 12/05/22 19:08 541-73-112/05/22 11:213881371
1,4-Dichlorobenzene ND ug/kg 12/05/22 19:08 106-46-712/05/22 11:213881481
3,3'-Dichlorobenzidine ND ug/kg 12/05/22 19:08 91-94-112/05/22 11:217752621
2,4-Dichlorophenol ND ug/kg 12/05/22 19:08 120-83-212/05/22 11:213881521
Diethylphthalate ND ug/kg 12/05/22 19:08 84-66-212/05/22 11:213881421
2,4-Dimethylphenol ND ug/kg 12/05/22 19:08 105-67-912/05/22 11:213881611
Dimethylphthalate ND ug/kg 12/05/22 19:08 131-11-312/05/22 11:213881411
Di-n-butylphthalate ND ug/kg 12/05/22 19:08 84-74-212/05/22 11:213881301
4,6-Dinitro-2-methylphenol ND ug/kg 12/05/22 19:08 534-52-112/05/22 11:217753621
2,4-Dinitrophenol ND ug/kg 12/05/22 19:08 51-28-512/05/22 11:21194012001
2,4-Dinitrotoluene ND ug/kg 12/05/22 19:08 121-14-212/05/22 11:213881491
2,6-Dinitrotoluene ND ug/kg 12/05/22 19:08 606-20-212/05/22 11:213881421
Di-n-octylphthalate ND ug/kg 12/05/22 19:08 117-84-012/05/22 11:213881531
bis(2-Ethylhexyl)phthalate ND ug/kg 12/05/22 19:08 117-81-712/05/22 11:213881501
Fluoranthene ND ug/kg 12/05/22 19:08 206-44-012/05/22 11:213881331
Fluorene ND ug/kg 12/05/22 19:08 86-73-712/05/22 11:213881361
Hexachloro-1,3-butadiene ND ug/kg 12/05/22 19:08 87-68-312/05/22 11:213881681
Hexachlorobenzene ND ug/kg 12/05/22 19:08 118-74-112/05/22 11:213881521
Hexachlorocyclopentadiene ND ug/kg 12/05/22 19:08 77-47-412/05/22 11:213882221
Hexachloroethane ND ug/kg 12/05/22 19:08 67-72-112/05/22 11:213881481
Indeno(1,2,3-cd)pyrene ND ug/kg 12/05/22 19:08 193-39-512/05/22 11:213881531
Isophorone ND ug/kg 12/05/22 19:08 78-59-112/05/22 11:213881731
1-Methylnaphthalene ND ug/kg 12/05/22 19:08 90-12-012/05/22 11:213881361
2-Methylnaphthalene ND ug/kg 12/05/22 19:08 91-57-612/05/22 11:213881551
2-Methylphenol(o-Cresol)ND ug/kg 12/05/22 19:08 95-48-712/05/22 11:213881591
3&4-Methylphenol(m&p Cresol)ND ug/kg 12/05/22 19:08 15831-10-412/05/22 11:213881561
Naphthalene ND ug/kg 12/05/22 19:08 91-20-312/05/22 11:213881321
2-Nitroaniline ND ug/kg 12/05/22 19:08 88-74-412/05/22 11:2119403171
3-Nitroaniline ND ug/kg 12/05/22 19:08 99-09-212/05/22 11:2119403041
4-Nitroaniline ND ug/kg 12/05/22 19:08 100-01-612/05/22 11:217752951
Nitrobenzene ND ug/kg 12/05/22 19:08 98-95-312/05/22 11:213881801
2-Nitrophenol ND ug/kg 12/05/22 19:08 88-75-512/05/22 11:213881681
4-Nitrophenol ND ug/kg 12/05/22 19:08 100-02-712/05/22 11:2119407491
N-Nitrosodimethylamine ND ug/kg 12/05/22 19:08 62-75-912/05/22 11:213881301
N-Nitroso-di-n-propylamine ND ug/kg 12/05/22 19:08 621-64-712/05/22 11:213881461
N-Nitrosodiphenylamine ND ug/kg 12/05/22 19:08 86-30-612/05/22 11:213881371
2,2'-Oxybis(1-chloropropane)ND ug/kg 12/05/22 19:08 108-60-112/05/22 11:213881841
Pentachlorophenol ND ug/kg 12/05/22 19:08 87-86-512/05/22 11:217753791
Phenanthrene ND ug/kg 12/05/22 19:08 85-01-812/05/22 11:213881271
Phenol ND ug/kg 12/05/22 19:08 108-95-212/05/22 11:213881731
Pyrene ND ug/kg 12/05/22 19:08 129-00-012/05/22 11:213881571
Pyridine ND ug/kg 12/05/22 19:08 110-86-112/05/22 11:213881221
1,2,4-Trichlorobenzene ND ug/kg 12/05/22 19:08 120-82-112/05/22 11:213881531
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:NORTH Lab ID:92639042002 Collected:11/29/22 11:46 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,4,5-Trichlorophenol ND ug/kg 12/05/22 19:08 95-95-412/05/22 11:213881771
2,4,6-Trichlorophenol ND ug/kg 12/05/22 19:08 88-06-212/05/22 11:213881601
Surrogates
Nitrobenzene-d5 (S)70 %12/05/22 19:08 4165-60-012/05/22 11:2110-130 1
2-Fluorobiphenyl (S)51 %12/05/22 19:08 321-60-812/05/22 11:2110-130 1
Terphenyl-d14 (S)67 %12/05/22 19:08 1718-51-012/05/22 11:2110-130 1
Phenol-d6 (S)68 %12/05/22 19:08 13127-88-312/05/22 11:2110-130 1
2-Fluorophenol (S)67 %12/05/22 19:08 367-12-412/05/22 11:2110-130 1
2,4,6-Tribromophenol (S)74 %12/05/22 19:08 118-79-612/05/22 11:2110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 12/02/22 19:08 67-64-112/02/22 13:1813443.1 1
Benzene ND ug/kg 12/02/22 19:08 71-43-212/02/22 13:186.7 2.7 1
Bromobenzene ND ug/kg 12/02/22 19:08 108-86-112/02/22 13:186.7 2.2 1
Bromochloromethane ND ug/kg 12/02/22 19:08 74-97-512/02/22 13:186.7 2.0 1
Bromodichloromethane ND ug/kg 12/02/22 19:08 75-27-412/02/22 13:186.7 2.6 1
Bromoform ND ug/kg 12/02/22 19:08 75-25-212/02/22 13:186.7 2.4 1
Bromomethane ND ug/kg 12/02/22 19:08 74-83-9 IK12/02/22 13:1813.4 10.6 1
2-Butanone (MEK)ND ug/kg 12/02/22 19:08 78-93-312/02/22 13:1813432.2 1
n-Butylbenzene ND ug/kg 12/02/22 19:08 104-51-812/02/22 13:186.7 3.2 1
sec-Butylbenzene ND ug/kg 12/02/22 19:08 135-98-812/02/22 13:186.7 3.0 1
tert-Butylbenzene ND ug/kg 12/02/22 19:08 98-06-612/02/22 13:186.7 2.4 1
Carbon tetrachloride ND ug/kg 12/02/22 19:08 56-23-512/02/22 13:186.7 2.5 1
Chlorobenzene ND ug/kg 12/02/22 19:08 108-90-712/02/22 13:186.7 1.3 1
Chloroethane ND ug/kg 12/02/22 19:08 75-00-312/02/22 13:1813.4 5.2 1
Chloroform ND ug/kg 12/02/22 19:08 67-66-312/02/22 13:186.7 4.1 1
Chloromethane ND ug/kg 12/02/22 19:08 74-87-312/02/22 13:1813.4 5.6 1
2-Chlorotoluene ND ug/kg 12/02/22 19:08 95-49-812/02/22 13:186.7 2.4 1
4-Chlorotoluene ND ug/kg 12/02/22 19:08 106-43-412/02/22 13:186.7 1.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 12/02/22 19:08 96-12-812/02/22 13:186.7 2.6 1
Dibromochloromethane ND ug/kg 12/02/22 19:08 124-48-112/02/22 13:186.7 3.8 1
1,2-Dibromoethane (EDB)ND ug/kg 12/02/22 19:08 106-93-412/02/22 13:186.7 3.0 1
Dibromomethane ND ug/kg 12/02/22 19:08 74-95-312/02/22 13:186.7 1.4 1
1,2-Dichlorobenzene ND ug/kg 12/02/22 19:08 95-50-112/02/22 13:186.7 2.4 1
1,3-Dichlorobenzene ND ug/kg 12/02/22 19:08 541-73-112/02/22 13:186.7 2.1 1
1,4-Dichlorobenzene ND ug/kg 12/02/22 19:08 106-46-712/02/22 13:186.7 1.7 1
Dichlorodifluoromethane ND ug/kg 12/02/22 19:08 75-71-812/02/22 13:1813.4 2.9 1
1,1-Dichloroethane ND ug/kg 12/02/22 19:08 75-34-312/02/22 13:186.7 2.8 1
1,2-Dichloroethane ND ug/kg 12/02/22 19:08 107-06-212/02/22 13:186.7 4.4 1
1,1-Dichloroethene ND ug/kg 12/02/22 19:08 75-35-412/02/22 13:186.7 2.8 1
cis-1,2-Dichloroethene ND ug/kg 12/02/22 19:08 156-59-212/02/22 13:186.7 2.3 1
trans-1,2-Dichloroethene ND ug/kg 12/02/22 19:08 156-60-512/02/22 13:186.7 2.3 1
1,2-Dichloropropane ND ug/kg 12/02/22 19:08 78-87-512/02/22 13:186.7 2.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:NORTH Lab ID:92639042002 Collected:11/29/22 11:46 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,3-Dichloropropane ND ug/kg 12/02/22 19:08 142-28-912/02/22 13:186.7 2.1 1
2,2-Dichloropropane ND ug/kg 12/02/22 19:08 594-20-7 IK12/02/22 13:186.7 2.2 1
1,1-Dichloropropene ND ug/kg 12/02/22 19:08 563-58-612/02/22 13:186.7 3.2 1
cis-1,3-Dichloropropene ND ug/kg 12/02/22 19:08 10061-01-512/02/22 13:186.7 1.8 1
trans-1,3-Dichloropropene ND ug/kg 12/02/22 19:08 10061-02-612/02/22 13:186.7 2.3 1
Diisopropyl ether ND ug/kg 12/02/22 19:08 108-20-312/02/22 13:186.7 1.8 1
Ethylbenzene 31.6 ug/kg 12/02/22 19:08 100-41-412/02/22 13:186.7 3.1 1
Hexachloro-1,3-butadiene ND ug/kg 12/02/22 19:08 87-68-312/02/22 13:1813.4 11.0 1
2-Hexanone ND ug/kg 12/02/22 19:08 591-78-6 v112/02/22 13:1867.1 6.5 1
Isopropylbenzene (Cumene)16.0 ug/kg 12/02/22 19:08 98-82-812/02/22 13:186.7 2.3 1
p-Isopropyltoluene 77.6 ug/kg 12/02/22 19:08 99-87-612/02/22 13:186.7 3.3 1
Methylene Chloride ND ug/kg 12/02/22 19:08 75-09-2 IK12/02/22 13:1826.8 18.4 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 12/02/22 19:08 108-10-1 v112/02/22 13:1867.1 6.5 1
Methyl-tert-butyl ether ND ug/kg 12/02/22 19:08 1634-04-412/02/22 13:186.7 2.5 1
Naphthalene ND ug/kg 12/02/22 19:08 91-20-312/02/22 13:186.7 3.5 1
n-Propylbenzene ND ug/kg 12/02/22 19:08 103-65-112/02/22 13:186.7 2.4 1
Styrene ND ug/kg 12/02/22 19:08 100-42-512/02/22 13:186.7 1.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 12/02/22 19:08 630-20-612/02/22 13:186.7 2.6 1
1,1,2,2-Tetrachloroethane ND ug/kg 12/02/22 19:08 79-34-512/02/22 13:186.7 1.8 1
Tetrachloroethene ND ug/kg 12/02/22 19:08 127-18-412/02/22 13:186.7 2.1 1
Toluene 16.2 ug/kg 12/02/22 19:08 108-88-312/02/22 13:186.7 1.9 1
1,2,3-Trichlorobenzene ND ug/kg 12/02/22 19:08 87-61-612/02/22 13:186.7 5.4 1
1,2,4-Trichlorobenzene ND ug/kg 12/02/22 19:08 120-82-112/02/22 13:186.7 5.6 1
1,1,1-Trichloroethane ND ug/kg 12/02/22 19:08 71-55-612/02/22 13:186.7 3.5 1
1,1,2-Trichloroethane ND ug/kg 12/02/22 19:08 79-00-512/02/22 13:186.7 2.2 1
Trichloroethene ND ug/kg 12/02/22 19:08 79-01-612/02/22 13:186.7 1.7 1
Trichlorofluoromethane ND ug/kg 12/02/22 19:08 75-69-412/02/22 13:186.7 3.7 1
1,2,3-Trichloropropane ND ug/kg 12/02/22 19:08 96-18-412/02/22 13:186.7 3.4 1
1,2,4-Trimethylbenzene 284 ug/kg 12/02/22 19:08 95-63-612/02/22 13:186.7 1.8 1
1,3,5-Trimethylbenzene ND ug/kg 12/02/22 19:08 108-67-812/02/22 13:186.7 2.3 1
Vinyl acetate ND ug/kg 12/02/22 19:08 108-05-4 IK12/02/22 13:1867.1 4.9 1
Vinyl chloride ND ug/kg 12/02/22 19:08 75-01-412/02/22 13:1813.4 3.4 1
Xylene (Total)168 ug/kg 12/02/22 19:08 1330-20-712/02/22 13:1813.4 3.8 1
m&p-Xylene 102 ug/kg 12/02/22 19:08 179601-23-112/02/22 13:1813.4 4.6 1
o-Xylene 66.7 ug/kg 12/02/22 19:08 95-47-612/02/22 13:186.7 3.0 1
Surrogates
Toluene-d8 (S)100 %12/02/22 19:08 2037-26-5 u812/02/22 13:1870-130 1
4-Bromofluorobenzene (S)106 %12/02/22 19:08 460-00-412/02/22 13:1870-130 1
1,2-Dichloroethane-d4 (S)105 %12/02/22 19:08 17060-07-012/02/22 13:1870-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 14.6 %12/01/22 15:19 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:NORTH Lab ID:92639042002 Collected:11/29/22 11:46 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 85.0 %12/05/22 15:4312/05/22 15:371
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:SOUTH Lab ID:92639042003 Collected:11/29/22 11:48 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)ND mg/kg 12/06/22 12:29 N212/05/22 09:5911.7 11.7 1
Aliphatic (C19-C36)ND mg/kg 12/06/22 12:29 N212/05/22 09:5911.7 11.7 1
Aromatic (C11-C22)ND mg/kg 12/06/22 12:29 N212/05/22 09:5911.7 11.7 1
Surrogates
1-Chlorooctadecane (S)68 %12/06/22 12:29 3386-33-212/05/22 09:5940-140 1
o-Terphenyl (S)61 %12/06/22 12:29 84-15-112/05/22 09:5940-140 1
2-Fluorobiphenyl (S)110 %12/06/22 12:29 321-60-812/05/22 09:5940-140 1
2-Bromonaphthalene (S)120 %12/06/22 12:29 580-13-212/05/22 09:5940-140 1
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 12/07/22 03:5411/29/22 11:486.68 2.23 1
Aliphatic (C09-C12)5.98J mg/kg 12/07/22 03:54 J11/29/22 11:486.68 2.23 1
Aromatic (C09-C10),Unadjusted 3.77J mg/kg 12/07/22 03:54 TPHC9C10A J11/29/22 11:486.68 2.23 1
Total VPH 9.75 mg/kg 12/07/22 03:54 VPH11/29/22 11:486.68 2.23 1
Surrogates
2,5-Dibromotoluene (FID)86.1 %12/07/22 03:54 615-59-8FID11/29/22 11:4870.0-130 1
2,5-Dibromotoluene (PID)88.5 %12/07/22 03:54 615-59-8PID11/29/22 11:4870.0-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 12/05/22 19:16 83-32-912/05/22 11:213921381
Acenaphthylene ND ug/kg 12/05/22 19:16 208-96-812/05/22 11:213921381
Aniline ND ug/kg 12/05/22 19:16 62-53-312/05/22 11:213921531
Anthracene ND ug/kg 12/05/22 19:16 120-12-712/05/22 11:213921281
Benzo(a)anthracene ND ug/kg 12/05/22 19:16 56-55-312/05/22 11:213921311
Benzo(a)pyrene ND ug/kg 12/05/22 19:16 50-32-812/05/22 11:213921361
Benzo(b)fluoranthene ND ug/kg 12/05/22 19:16 205-99-212/05/22 11:213921311
Benzo(g,h,i)perylene ND ug/kg 12/05/22 19:16 191-24-212/05/22 11:213921521
Benzo(k)fluoranthene ND ug/kg 12/05/22 19:16 207-08-912/05/22 11:213921381
Benzoic Acid ND ug/kg 12/05/22 19:16 65-85-012/05/22 11:2119608431
Benzyl alcohol ND ug/kg 12/05/22 19:16 100-51-612/05/22 11:217852971
4-Bromophenylphenyl ether ND ug/kg 12/05/22 19:16 101-55-312/05/22 11:213921511
Butylbenzylphthalate ND ug/kg 12/05/22 19:16 85-68-712/05/22 11:213921651
4-Chloro-3-methylphenol ND ug/kg 12/05/22 19:16 59-50-712/05/22 11:217852761
4-Chloroaniline ND ug/kg 12/05/22 19:16 106-47-812/05/22 11:217853081
bis(2-Chloroethoxy)methane ND ug/kg 12/05/22 19:16 111-91-112/05/22 11:213921631
bis(2-Chloroethyl) ether ND ug/kg 12/05/22 19:16 111-44-412/05/22 11:213921471
2-Chloronaphthalene ND ug/kg 12/05/22 19:16 91-58-712/05/22 11:213921561
2-Chlorophenol ND ug/kg 12/05/22 19:16 95-57-812/05/22 11:213921471
4-Chlorophenylphenyl ether ND ug/kg 12/05/22 19:16 7005-72-312/05/22 11:213921461
Chrysene ND ug/kg 12/05/22 19:16 218-01-9 v212/05/22 11:213921431
Dibenz(a,h)anthracene ND ug/kg 12/05/22 19:16 53-70-312/05/22 11:213921511
Dibenzofuran ND ug/kg 12/05/22 19:16 132-64-912/05/22 11:213921411
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:SOUTH Lab ID:92639042003 Collected:11/29/22 11:48 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
1,2-Dichlorobenzene ND ug/kg 12/05/22 19:16 95-50-112/05/22 11:213921411
1,3-Dichlorobenzene ND ug/kg 12/05/22 19:16 541-73-112/05/22 11:213921391
1,4-Dichlorobenzene ND ug/kg 12/05/22 19:16 106-46-712/05/22 11:213921501
3,3'-Dichlorobenzidine ND ug/kg 12/05/22 19:16 91-94-1 v212/05/22 11:217852651
2,4-Dichlorophenol ND ug/kg 12/05/22 19:16 120-83-212/05/22 11:213921531
Diethylphthalate ND ug/kg 12/05/22 19:16 84-66-212/05/22 11:213921441
2,4-Dimethylphenol ND ug/kg 12/05/22 19:16 105-67-912/05/22 11:213921631
Dimethylphthalate ND ug/kg 12/05/22 19:16 131-11-312/05/22 11:213921431
Di-n-butylphthalate ND ug/kg 12/05/22 19:16 84-74-212/05/22 11:213921321
4,6-Dinitro-2-methylphenol ND ug/kg 12/05/22 19:16 534-52-112/05/22 11:217853661
2,4-Dinitrophenol ND ug/kg 12/05/22 19:16 51-28-512/05/22 11:21196012101
2,4-Dinitrotoluene ND ug/kg 12/05/22 19:16 121-14-212/05/22 11:213921511
2,6-Dinitrotoluene ND ug/kg 12/05/22 19:16 606-20-212/05/22 11:213921441
Di-n-octylphthalate ND ug/kg 12/05/22 19:16 117-84-012/05/22 11:213921551
bis(2-Ethylhexyl)phthalate ND ug/kg 12/05/22 19:16 117-81-712/05/22 11:213921521
Fluoranthene ND ug/kg 12/05/22 19:16 206-44-012/05/22 11:213921341
Fluorene ND ug/kg 12/05/22 19:16 86-73-712/05/22 11:213921381
Hexachloro-1,3-butadiene ND ug/kg 12/05/22 19:16 87-68-312/05/22 11:213921701
Hexachlorobenzene ND ug/kg 12/05/22 19:16 118-74-112/05/22 11:213921531
Hexachlorocyclopentadiene ND ug/kg 12/05/22 19:16 77-47-412/05/22 11:213922251
Hexachloroethane ND ug/kg 12/05/22 19:16 67-72-112/05/22 11:213921501
Indeno(1,2,3-cd)pyrene ND ug/kg 12/05/22 19:16 193-39-512/05/22 11:213921551
Isophorone ND ug/kg 12/05/22 19:16 78-59-112/05/22 11:213921751
1-Methylnaphthalene ND ug/kg 12/05/22 19:16 90-12-012/05/22 11:213921381
2-Methylnaphthalene ND ug/kg 12/05/22 19:16 91-57-612/05/22 11:213921571
2-Methylphenol(o-Cresol)ND ug/kg 12/05/22 19:16 95-48-712/05/22 11:213921611
3&4-Methylphenol(m&p Cresol)ND ug/kg 12/05/22 19:16 15831-10-412/05/22 11:213921581
Naphthalene ND ug/kg 12/05/22 19:16 91-20-312/05/22 11:213921331
2-Nitroaniline ND ug/kg 12/05/22 19:16 88-74-412/05/22 11:2119603211
3-Nitroaniline ND ug/kg 12/05/22 19:16 99-09-212/05/22 11:2119603081
4-Nitroaniline ND ug/kg 12/05/22 19:16 100-01-612/05/22 11:217852981
Nitrobenzene ND ug/kg 12/05/22 19:16 98-95-312/05/22 11:213921821
2-Nitrophenol ND ug/kg 12/05/22 19:16 88-75-512/05/22 11:213921701
4-Nitrophenol ND ug/kg 12/05/22 19:16 100-02-712/05/22 11:2119607591
N-Nitrosodimethylamine ND ug/kg 12/05/22 19:16 62-75-912/05/22 11:213921321
N-Nitroso-di-n-propylamine ND ug/kg 12/05/22 19:16 621-64-712/05/22 11:213921471
N-Nitrosodiphenylamine ND ug/kg 12/05/22 19:16 86-30-612/05/22 11:213921391
2,2'-Oxybis(1-chloropropane)ND ug/kg 12/05/22 19:16 108-60-112/05/22 11:213921871
Pentachlorophenol ND ug/kg 12/05/22 19:16 87-86-512/05/22 11:217853841
Phenanthrene ND ug/kg 12/05/22 19:16 85-01-812/05/22 11:213921281
Phenol ND ug/kg 12/05/22 19:16 108-95-212/05/22 11:213921751
Pyrene ND ug/kg 12/05/22 19:16 129-00-012/05/22 11:213921591
Pyridine ND ug/kg 12/05/22 19:16 110-86-112/05/22 11:213921241
1,2,4-Trichlorobenzene ND ug/kg 12/05/22 19:16 120-82-112/05/22 11:213921551
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:SOUTH Lab ID:92639042003 Collected:11/29/22 11:48 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,4,5-Trichlorophenol ND ug/kg 12/05/22 19:16 95-95-412/05/22 11:213921801
2,4,6-Trichlorophenol ND ug/kg 12/05/22 19:16 88-06-212/05/22 11:213921621
Surrogates
Nitrobenzene-d5 (S)62 %12/05/22 19:16 4165-60-012/05/22 11:2110-130 1
2-Fluorobiphenyl (S)42 %12/05/22 19:16 321-60-812/05/22 11:2110-130 1
Terphenyl-d14 (S)60 %12/05/22 19:16 1718-51-012/05/22 11:2110-130 1
Phenol-d6 (S)67 %12/05/22 19:16 13127-88-312/05/22 11:2110-130 1
2-Fluorophenol (S)66 %12/05/22 19:16 367-12-412/05/22 11:2110-130 1
2,4,6-Tribromophenol (S)59 %12/05/22 19:16 118-79-612/05/22 11:2110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 12/02/22 00:43 67-64-111/30/22 18:4824678.9 1
Benzene 7.0J ug/kg 12/02/22 00:43 71-43-211/30/22 18:4812.3 4.9 1
Bromobenzene ND ug/kg 12/02/22 00:43 108-86-111/30/22 18:4812.3 4.0 1
Bromochloromethane ND ug/kg 12/02/22 00:43 74-97-511/30/22 18:4812.3 3.6 1
Bromodichloromethane ND ug/kg 12/02/22 00:43 75-27-411/30/22 18:4812.3 4.7 1
Bromoform ND ug/kg 12/02/22 00:43 75-25-211/30/22 18:4812.3 4.3 1
Bromomethane ND ug/kg 12/02/22 00:43 74-83-9 IK11/30/22 18:4824.6 19.4 1
2-Butanone (MEK)ND ug/kg 12/02/22 00:43 78-93-311/30/22 18:4824659.0 1
n-Butylbenzene ND ug/kg 12/02/22 00:43 104-51-811/30/22 18:4812.3 5.8 1
sec-Butylbenzene ND ug/kg 12/02/22 00:43 135-98-811/30/22 18:4812.3 5.4 1
tert-Butylbenzene ND ug/kg 12/02/22 00:43 98-06-611/30/22 18:4812.3 4.4 1
Carbon tetrachloride ND ug/kg 12/02/22 00:43 56-23-511/30/22 18:4812.3 4.6 1
Chlorobenzene ND ug/kg 12/02/22 00:43 108-90-711/30/22 18:4812.3 2.4 1
Chloroethane ND ug/kg 12/02/22 00:43 75-00-311/30/22 18:4824.6 9.5 1
Chloroform ND ug/kg 12/02/22 00:43 67-66-311/30/22 18:4812.3 7.5 1
Chloromethane ND ug/kg 12/02/22 00:43 74-87-311/30/22 18:4824.6 10.3 1
2-Chlorotoluene ND ug/kg 12/02/22 00:43 95-49-811/30/22 18:4812.3 4.3 1
4-Chlorotoluene ND ug/kg 12/02/22 00:43 106-43-411/30/22 18:4812.3 2.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 12/02/22 00:43 96-12-811/30/22 18:4812.3 4.8 1
Dibromochloromethane ND ug/kg 12/02/22 00:43 124-48-111/30/22 18:4812.3 6.9 1
1,2-Dibromoethane (EDB)ND ug/kg 12/02/22 00:43 106-93-411/30/22 18:4812.3 5.4 1
Dibromomethane ND ug/kg 12/02/22 00:43 74-95-311/30/22 18:4812.3 2.6 1
1,2-Dichlorobenzene ND ug/kg 12/02/22 00:43 95-50-111/30/22 18:4812.3 4.4 1
1,3-Dichlorobenzene ND ug/kg 12/02/22 00:43 541-73-111/30/22 18:4812.3 3.8 1
1,4-Dichlorobenzene ND ug/kg 12/02/22 00:43 106-46-711/30/22 18:4812.3 3.2 1
Dichlorodifluoromethane ND ug/kg 12/02/22 00:43 75-71-8 v111/30/22 18:4824.6 5.3 1
1,1-Dichloroethane ND ug/kg 12/02/22 00:43 75-34-311/30/22 18:4812.3 5.1 1
1,2-Dichloroethane ND ug/kg 12/02/22 00:43 107-06-211/30/22 18:4812.3 8.1 1
1,1-Dichloroethene ND ug/kg 12/02/22 00:43 75-35-411/30/22 18:4812.3 5.1 1
cis-1,2-Dichloroethene ND ug/kg 12/02/22 00:43 156-59-211/30/22 18:4812.3 4.2 1
trans-1,2-Dichloroethene ND ug/kg 12/02/22 00:43 156-60-511/30/22 18:4812.3 4.3 1
1,2-Dichloropropane ND ug/kg 12/02/22 00:43 78-87-511/30/22 18:4812.3 3.7 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:SOUTH Lab ID:92639042003 Collected:11/29/22 11:48 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,3-Dichloropropane ND ug/kg 12/02/22 00:43 142-28-911/30/22 18:4812.3 3.8 1
2,2-Dichloropropane ND ug/kg 12/02/22 00:43 594-20-7 IK11/30/22 18:4812.3 4.0 1
1,1-Dichloropropene ND ug/kg 12/02/22 00:43 563-58-611/30/22 18:4812.3 5.9 1
cis-1,3-Dichloropropene ND ug/kg 12/02/22 00:43 10061-01-511/30/22 18:4812.3 3.3 1
trans-1,3-Dichloropropene ND ug/kg 12/02/22 00:43 10061-02-611/30/22 18:4812.3 4.2 1
Diisopropyl ether ND ug/kg 12/02/22 00:43 108-20-311/30/22 18:4812.3 3.3 1
Ethylbenzene 18.8 ug/kg 12/02/22 00:43 100-41-411/30/22 18:4812.3 5.7 1
Hexachloro-1,3-butadiene ND ug/kg 12/02/22 00:43 87-68-311/30/22 18:4824.6 20.1 1
2-Hexanone ND ug/kg 12/02/22 00:43 591-78-611/30/22 18:4812311.8 1
Isopropylbenzene (Cumene)ND ug/kg 12/02/22 00:43 98-82-811/30/22 18:4812.3 4.2 1
p-Isopropyltoluene ND ug/kg 12/02/22 00:43 99-87-611/30/22 18:4812.3 6.0 1
Methylene Chloride ND ug/kg 12/02/22 00:43 75-09-2 IK11/30/22 18:4849.1 33.7 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 12/02/22 00:43 108-10-111/30/22 18:4812311.8 1
Methyl-tert-butyl ether ND ug/kg 12/02/22 00:43 1634-04-411/30/22 18:4812.3 4.6 1
Naphthalene ND ug/kg 12/02/22 00:43 91-20-311/30/22 18:4812.3 6.5 1
n-Propylbenzene ND ug/kg 12/02/22 00:43 103-65-111/30/22 18:4812.3 4.4 1
Styrene ND ug/kg 12/02/22 00:43 100-42-511/30/22 18:4812.3 3.2 1
1,1,1,2-Tetrachloroethane ND ug/kg 12/02/22 00:43 630-20-611/30/22 18:4812.3 4.7 1
1,1,2,2-Tetrachloroethane ND ug/kg 12/02/22 00:43 79-34-511/30/22 18:4812.3 3.2 1
Tetrachloroethene ND ug/kg 12/02/22 00:43 127-18-411/30/22 18:4812.3 3.9 1
Toluene 32.7 ug/kg 12/02/22 00:43 108-88-311/30/22 18:4812.3 3.5 1
1,2,3-Trichlorobenzene ND ug/kg 12/02/22 00:43 87-61-611/30/22 18:4812.3 9.9 1
1,2,4-Trichlorobenzene ND ug/kg 12/02/22 00:43 120-82-111/30/22 18:4812.3 10.3 1
1,1,1-Trichloroethane ND ug/kg 12/02/22 00:43 71-55-611/30/22 18:4812.3 6.4 1
1,1,2-Trichloroethane ND ug/kg 12/02/22 00:43 79-00-511/30/22 18:4812.3 4.1 1
Trichloroethene ND ug/kg 12/02/22 00:43 79-01-611/30/22 18:4812.3 3.2 1
Trichlorofluoromethane ND ug/kg 12/02/22 00:43 75-69-411/30/22 18:4812.3 6.8 1
1,2,3-Trichloropropane ND ug/kg 12/02/22 00:43 96-18-411/30/22 18:4812.3 6.2 1
1,2,4-Trimethylbenzene 8.9J ug/kg 12/02/22 00:43 95-63-611/30/22 18:4812.3 3.4 1
1,3,5-Trimethylbenzene 7.3J ug/kg 12/02/22 00:43 108-67-811/30/22 18:4812.3 4.1 1
Vinyl acetate ND ug/kg 12/02/22 00:43 108-05-4 IK11/30/22 18:481238.9 1
Vinyl chloride ND ug/kg 12/02/22 00:43 75-01-411/30/22 18:4824.6 6.2 1
Xylene (Total)60.1 ug/kg 12/02/22 00:43 1330-20-711/30/22 18:4824.6 7.0 1
m&p-Xylene 39.4 ug/kg 12/02/22 00:43 179601-23-111/30/22 18:4824.6 8.4 1
o-Xylene 20.7 ug/kg 12/02/22 00:43 95-47-611/30/22 18:4812.3 5.4 1
Surrogates
Toluene-d8 (S)100 %12/02/22 00:43 2037-26-511/30/22 18:4870-130 1
4-Bromofluorobenzene (S)101 %12/02/22 00:43 460-00-411/30/22 18:4870-130 1
1,2-Dichloroethane-d4 (S)105 %12/02/22 00:43 17060-07-011/30/22 18:4870-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.3 %12/01/22 15:19 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:SOUTH Lab ID:92639042003 Collected:11/29/22 11:48 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 86.0 %12/05/22 15:4312/05/22 15:371
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:WEST Lab ID:92639042004 Collected:11/29/22 11:50 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)ND mg/kg 12/06/22 12:54 N212/05/22 09:5911.2 11.2 1
Aliphatic (C19-C36)ND mg/kg 12/06/22 12:54 N212/05/22 09:5911.2 11.2 1
Aromatic (C11-C22)ND mg/kg 12/06/22 12:54 N212/05/22 09:5911.2 11.2 1
Surrogates
1-Chlorooctadecane (S)54 %12/06/22 12:54 3386-33-212/05/22 09:5940-140 1
o-Terphenyl (S)67 %12/06/22 12:54 84-15-112/05/22 09:5940-140 1
2-Fluorobiphenyl (S)111 %12/06/22 12:54 321-60-812/05/22 09:5940-140 1
2-Bromonaphthalene (S)120 %12/06/22 12:54 580-13-212/05/22 09:5940-140 1
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 12/07/22 04:2611/29/22 11:506.78 2.26 1
Aliphatic (C09-C12)3.12J mg/kg 12/07/22 04:26 J11/29/22 11:506.78 2.26 1
Aromatic (C09-C10),Unadjusted ND mg/kg 12/07/22 04:26 TPHC9C10A11/29/22 11:506.78 2.26 1
Total VPH 3.12J mg/kg 12/07/22 04:26 VPH J11/29/22 11:506.78 2.26 1
Surrogates
2,5-Dibromotoluene (FID)90.7 %12/07/22 04:26 615-59-8FID11/29/22 11:5070.0-130 1
2,5-Dibromotoluene (PID)89.9 %12/07/22 04:26 615-59-8PID11/29/22 11:5070.0-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 12/06/22 08:51 83-32-912/05/22 11:213721311
Acenaphthylene ND ug/kg 12/06/22 08:51 208-96-812/05/22 11:213721311
Aniline ND ug/kg 12/06/22 08:51 62-53-312/05/22 11:213721461
Anthracene ND ug/kg 12/06/22 08:51 120-12-712/05/22 11:213721221
Benzo(a)anthracene ND ug/kg 12/06/22 08:51 56-55-312/05/22 11:213721241
Benzo(a)pyrene ND ug/kg 12/06/22 08:51 50-32-812/05/22 11:213721291
Benzo(b)fluoranthene ND ug/kg 12/06/22 08:51 205-99-212/05/22 11:213721241
Benzo(g,h,i)perylene ND ug/kg 12/06/22 08:51 191-24-212/05/22 11:213721441
Benzo(k)fluoranthene ND ug/kg 12/06/22 08:51 207-08-912/05/22 11:213721311
Benzoic Acid ND ug/kg 12/06/22 08:51 65-85-012/05/22 11:2118608001
Benzyl alcohol ND ug/kg 12/06/22 08:51 100-51-612/05/22 11:217452821
4-Bromophenylphenyl ether ND ug/kg 12/06/22 08:51 101-55-312/05/22 11:213721431
Butylbenzylphthalate ND ug/kg 12/06/22 08:51 85-68-712/05/22 11:213721571
4-Chloro-3-methylphenol ND ug/kg 12/06/22 08:51 59-50-712/05/22 11:217452621
4-Chloroaniline ND ug/kg 12/06/22 08:51 106-47-812/05/22 11:217452921
bis(2-Chloroethoxy)methane ND ug/kg 12/06/22 08:51 111-91-112/05/22 11:213721551
bis(2-Chloroethyl) ether ND ug/kg 12/06/22 08:51 111-44-412/05/22 11:213721401
2-Chloronaphthalene ND ug/kg 12/06/22 08:51 91-58-712/05/22 11:213721481
2-Chlorophenol ND ug/kg 12/06/22 08:51 95-57-812/05/22 11:213721401
4-Chlorophenylphenyl ether ND ug/kg 12/06/22 08:51 7005-72-312/05/22 11:213721391
Chrysene ND ug/kg 12/06/22 08:51 218-01-912/05/22 11:213721351
Dibenz(a,h)anthracene ND ug/kg 12/06/22 08:51 53-70-312/05/22 11:213721431
Dibenzofuran ND ug/kg 12/06/22 08:51 132-64-912/05/22 11:213721341
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:WEST Lab ID:92639042004 Collected:11/29/22 11:50 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
1,2-Dichlorobenzene ND ug/kg 12/06/22 08:51 95-50-112/05/22 11:213721341
1,3-Dichlorobenzene ND ug/kg 12/06/22 08:51 541-73-112/05/22 11:213721321
1,4-Dichlorobenzene ND ug/kg 12/06/22 08:51 106-46-712/05/22 11:213721421
3,3'-Dichlorobenzidine ND ug/kg 12/06/22 08:51 91-94-112/05/22 11:217452521
2,4-Dichlorophenol ND ug/kg 12/06/22 08:51 120-83-212/05/22 11:213721461
Diethylphthalate ND ug/kg 12/06/22 08:51 84-66-212/05/22 11:213721371
2,4-Dimethylphenol ND ug/kg 12/06/22 08:51 105-67-912/05/22 11:213721551
Dimethylphthalate ND ug/kg 12/06/22 08:51 131-11-312/05/22 11:213721351
Di-n-butylphthalate ND ug/kg 12/06/22 08:51 84-74-212/05/22 11:213721251
4,6-Dinitro-2-methylphenol ND ug/kg 12/06/22 08:51 534-52-112/05/22 11:217453481
2,4-Dinitrophenol ND ug/kg 12/06/22 08:51 51-28-512/05/22 11:21186011501
2,4-Dinitrotoluene ND ug/kg 12/06/22 08:51 121-14-212/05/22 11:213721431
2,6-Dinitrotoluene ND ug/kg 12/06/22 08:51 606-20-212/05/22 11:213721371
Di-n-octylphthalate ND ug/kg 12/06/22 08:51 117-84-012/05/22 11:213721471
bis(2-Ethylhexyl)phthalate ND ug/kg 12/06/22 08:51 117-81-712/05/22 11:213721441
Fluoranthene ND ug/kg 12/06/22 08:51 206-44-012/05/22 11:213721281
Fluorene ND ug/kg 12/06/22 08:51 86-73-712/05/22 11:213721311
Hexachloro-1,3-butadiene ND ug/kg 12/06/22 08:51 87-68-312/05/22 11:213721611
Hexachlorobenzene ND ug/kg 12/06/22 08:51 118-74-112/05/22 11:213721461
Hexachlorocyclopentadiene ND ug/kg 12/06/22 08:51 77-47-412/05/22 11:213722131
Hexachloroethane ND ug/kg 12/06/22 08:51 67-72-112/05/22 11:213721421
Indeno(1,2,3-cd)pyrene ND ug/kg 12/06/22 08:51 193-39-512/05/22 11:213721471
Isophorone ND ug/kg 12/06/22 08:51 78-59-112/05/22 11:213721661
1-Methylnaphthalene ND ug/kg 12/06/22 08:51 90-12-012/05/22 11:213721311
2-Methylnaphthalene ND ug/kg 12/06/22 08:51 91-57-612/05/22 11:213721491
2-Methylphenol(o-Cresol)ND ug/kg 12/06/22 08:51 95-48-712/05/22 11:213721521
3&4-Methylphenol(m&p Cresol)ND ug/kg 12/06/22 08:51 15831-10-412/05/22 11:213721501
Naphthalene ND ug/kg 12/06/22 08:51 91-20-312/05/22 11:213721261
2-Nitroaniline ND ug/kg 12/06/22 08:51 88-74-412/05/22 11:2118603051
3-Nitroaniline ND ug/kg 12/06/22 08:51 99-09-212/05/22 11:2118602921
4-Nitroaniline ND ug/kg 12/06/22 08:51 100-01-612/05/22 11:217452831
Nitrobenzene ND ug/kg 12/06/22 08:51 98-95-312/05/22 11:213721731
2-Nitrophenol ND ug/kg 12/06/22 08:51 88-75-512/05/22 11:213721611
4-Nitrophenol ND ug/kg 12/06/22 08:51 100-02-712/05/22 11:2118607201
N-Nitrosodimethylamine ND ug/kg 12/06/22 08:51 62-75-912/05/22 11:213721251
N-Nitroso-di-n-propylamine ND ug/kg 12/06/22 08:51 621-64-712/05/22 11:213721401
N-Nitrosodiphenylamine ND ug/kg 12/06/22 08:51 86-30-612/05/22 11:213721321
2,2'-Oxybis(1-chloropropane)ND ug/kg 12/06/22 08:51 108-60-112/05/22 11:213721771
Pentachlorophenol ND ug/kg 12/06/22 08:51 87-86-512/05/22 11:217453651
Phenanthrene ND ug/kg 12/06/22 08:51 85-01-812/05/22 11:213721221
Phenol ND ug/kg 12/06/22 08:51 108-95-212/05/22 11:213721661
Pyrene ND ug/kg 12/06/22 08:51 129-00-012/05/22 11:213721511
Pyridine ND ug/kg 12/06/22 08:51 110-86-112/05/22 11:213721171
1,2,4-Trichlorobenzene ND ug/kg 12/06/22 08:51 120-82-112/05/22 11:213721471
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:WEST Lab ID:92639042004 Collected:11/29/22 11:50 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,4,5-Trichlorophenol ND ug/kg 12/06/22 08:51 95-95-412/05/22 11:213721701
2,4,6-Trichlorophenol ND ug/kg 12/06/22 08:51 88-06-212/05/22 11:213721531
Surrogates
Nitrobenzene-d5 (S)66 %12/06/22 08:51 4165-60-012/05/22 11:2110-130 1
2-Fluorobiphenyl (S)53 %12/06/22 08:51 321-60-812/05/22 11:2110-130 1
Terphenyl-d14 (S)61 %12/06/22 08:51 1718-51-012/05/22 11:2110-130 1
Phenol-d6 (S)67 %12/06/22 08:51 13127-88-312/05/22 11:2110-130 1
2-Fluorophenol (S)67 %12/06/22 08:51 367-12-412/05/22 11:2110-130 1
2,4,6-Tribromophenol (S)75 %12/06/22 08:51 118-79-612/05/22 11:2110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 12/02/22 01:00 67-64-111/30/22 18:4819963.9 1
Benzene 5.7J ug/kg 12/02/22 01:00 71-43-211/30/22 18:48104.0 1
Bromobenzene ND ug/kg 12/02/22 01:00 108-86-111/30/22 18:48103.2 1
Bromochloromethane ND ug/kg 12/02/22 01:00 74-97-511/30/22 18:48102.9 1
Bromodichloromethane ND ug/kg 12/02/22 01:00 75-27-411/30/22 18:48103.8 1
Bromoform ND ug/kg 12/02/22 01:00 75-25-211/30/22 18:48103.5 1
Bromomethane ND ug/kg 12/02/22 01:00 74-83-9 IK11/30/22 18:4819.9 15.7 1
2-Butanone (MEK)ND ug/kg 12/02/22 01:00 78-93-311/30/22 18:4819947.8 1
n-Butylbenzene ND ug/kg 12/02/22 01:00 104-51-811/30/22 18:48104.7 1
sec-Butylbenzene ND ug/kg 12/02/22 01:00 135-98-811/30/22 18:48104.4 1
tert-Butylbenzene ND ug/kg 12/02/22 01:00 98-06-611/30/22 18:48103.5 1
Carbon tetrachloride ND ug/kg 12/02/22 01:00 56-23-511/30/22 18:48103.7 1
Chlorobenzene ND ug/kg 12/02/22 01:00 108-90-711/30/22 18:48101.9 1
Chloroethane ND ug/kg 12/02/22 01:00 75-00-311/30/22 18:4819.9 7.7 1
Chloroform ND ug/kg 12/02/22 01:00 67-66-311/30/22 18:48106.1 1
Chloromethane ND ug/kg 12/02/22 01:00 74-87-311/30/22 18:4819.9 8.4 1
2-Chlorotoluene ND ug/kg 12/02/22 01:00 95-49-811/30/22 18:48103.5 1
4-Chlorotoluene ND ug/kg 12/02/22 01:00 106-43-411/30/22 18:48101.8 1
1,2-Dibromo-3-chloropropane ND ug/kg 12/02/22 01:00 96-12-811/30/22 18:48103.9 1
Dibromochloromethane ND ug/kg 12/02/22 01:00 124-48-111/30/22 18:48105.6 1
1,2-Dibromoethane (EDB)ND ug/kg 12/02/22 01:00 106-93-411/30/22 18:48104.4 1
Dibromomethane ND ug/kg 12/02/22 01:00 74-95-311/30/22 18:48102.1 1
1,2-Dichlorobenzene ND ug/kg 12/02/22 01:00 95-50-111/30/22 18:48103.6 1
1,3-Dichlorobenzene ND ug/kg 12/02/22 01:00 541-73-111/30/22 18:48103.1 1
1,4-Dichlorobenzene ND ug/kg 12/02/22 01:00 106-46-711/30/22 18:48102.6 1
Dichlorodifluoromethane ND ug/kg 12/02/22 01:00 75-71-8 v111/30/22 18:4819.9 4.3 1
1,1-Dichloroethane ND ug/kg 12/02/22 01:00 75-34-311/30/22 18:48104.1 1
1,2-Dichloroethane ND ug/kg 12/02/22 01:00 107-06-211/30/22 18:48106.6 1
1,1-Dichloroethene ND ug/kg 12/02/22 01:00 75-35-411/30/22 18:48104.1 1
cis-1,2-Dichloroethene ND ug/kg 12/02/22 01:00 156-59-211/30/22 18:48103.4 1
trans-1,2-Dichloroethene ND ug/kg 12/02/22 01:00 156-60-511/30/22 18:48103.5 1
1,2-Dichloropropane ND ug/kg 12/02/22 01:00 78-87-511/30/22 18:48103.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:WEST Lab ID:92639042004 Collected:11/29/22 11:50 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,3-Dichloropropane ND ug/kg 12/02/22 01:00 142-28-911/30/22 18:48103.1 1
2,2-Dichloropropane ND ug/kg 12/02/22 01:00 594-20-7 IK11/30/22 18:48103.2 1
1,1-Dichloropropene ND ug/kg 12/02/22 01:00 563-58-611/30/22 18:48104.8 1
cis-1,3-Dichloropropene ND ug/kg 12/02/22 01:00 10061-01-511/30/22 18:48102.7 1
trans-1,3-Dichloropropene ND ug/kg 12/02/22 01:00 10061-02-611/30/22 18:48103.4 1
Diisopropyl ether ND ug/kg 12/02/22 01:00 108-20-311/30/22 18:48102.7 1
Ethylbenzene 14.0 ug/kg 12/02/22 01:00 100-41-411/30/22 18:48104.6 1
Hexachloro-1,3-butadiene ND ug/kg 12/02/22 01:00 87-68-311/30/22 18:4819.9 16.3 1
2-Hexanone ND ug/kg 12/02/22 01:00 591-78-611/30/22 18:4899.5 9.6 1
Isopropylbenzene (Cumene)ND ug/kg 12/02/22 01:00 98-82-811/30/22 18:48103.4 1
p-Isopropyltoluene ND ug/kg 12/02/22 01:00 99-87-611/30/22 18:48104.9 1
Methylene Chloride ND ug/kg 12/02/22 01:00 75-09-2 IK11/30/22 18:4839.8 27.3 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 12/02/22 01:00 108-10-111/30/22 18:4899.5 9.6 1
Methyl-tert-butyl ether ND ug/kg 12/02/22 01:00 1634-04-411/30/22 18:48103.7 1
Naphthalene ND ug/kg 12/02/22 01:00 91-20-311/30/22 18:48105.2 1
n-Propylbenzene 5.9J ug/kg 12/02/22 01:00 103-65-111/30/22 18:48103.5 1
Styrene ND ug/kg 12/02/22 01:00 100-42-511/30/22 18:48102.6 1
1,1,1,2-Tetrachloroethane ND ug/kg 12/02/22 01:00 630-20-611/30/22 18:48103.8 1
1,1,2,2-Tetrachloroethane ND ug/kg 12/02/22 01:00 79-34-511/30/22 18:48102.6 1
Tetrachloroethene ND ug/kg 12/02/22 01:00 127-18-411/30/22 18:48103.1 1
Toluene 24.1 ug/kg 12/02/22 01:00 108-88-311/30/22 18:48102.8 1
1,2,3-Trichlorobenzene ND ug/kg 12/02/22 01:00 87-61-611/30/22 18:48108.0 1
1,2,4-Trichlorobenzene ND ug/kg 12/02/22 01:00 120-82-111/30/22 18:48108.4 1
1,1,1-Trichloroethane ND ug/kg 12/02/22 01:00 71-55-611/30/22 18:48105.2 1
1,1,2-Trichloroethane ND ug/kg 12/02/22 01:00 79-00-511/30/22 18:48103.3 1
Trichloroethene ND ug/kg 12/02/22 01:00 79-01-611/30/22 18:48102.6 1
Trichlorofluoromethane ND ug/kg 12/02/22 01:00 75-69-411/30/22 18:48105.5 1
1,2,3-Trichloropropane ND ug/kg 12/02/22 01:00 96-18-411/30/22 18:48105.0 1
1,2,4-Trimethylbenzene 15.2 ug/kg 12/02/22 01:00 95-63-611/30/22 18:48102.7 1
1,3,5-Trimethylbenzene 7.2J ug/kg 12/02/22 01:00 108-67-811/30/22 18:48103.3 1
Vinyl acetate ND ug/kg 12/02/22 01:00 108-05-4 IK11/30/22 18:4899.5 7.2 1
Vinyl chloride ND ug/kg 12/02/22 01:00 75-01-411/30/22 18:4819.9 5.1 1
Xylene (Total)56.2 ug/kg 12/02/22 01:00 1330-20-711/30/22 18:4819.9 5.7 1
m&p-Xylene 32.5 ug/kg 12/02/22 01:00 179601-23-111/30/22 18:4819.9 6.8 1
o-Xylene 23.7 ug/kg 12/02/22 01:00 95-47-611/30/22 18:48104.4 1
Surrogates
Toluene-d8 (S)102 %12/02/22 01:00 2037-26-511/30/22 18:4870-130 1
4-Bromofluorobenzene (S)102 %12/02/22 01:00 460-00-411/30/22 18:4870-130 1
1,2-Dichloroethane-d4 (S)106 %12/02/22 01:00 17060-07-011/30/22 18:4870-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.3 %12/01/22 15:19 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 56
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Sample:WEST Lab ID:92639042004 Collected:11/29/22 11:50 Received:11/30/22 10:50 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 85.7 %12/05/22 15:4312/05/22 15:371
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1969685
KS LRH/MADEPV/MTDEQ
VPH/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3869345-3
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
Aliphatic (C05-C08)mg/kg ND 5.00 12/06/22 16:431.67
Aliphatic (C09-C12)mg/kg ND 5.00 12/06/22 16:431.67
Aromatic (C09-C10),Unadjusted mg/kg ND 5.00 12/06/22 16:431.67
Total VPH mg/kg ND 5.00 12/06/22 16:431.67
2,5-Dibromotoluene (FID)%80.6 70.0-130 12/06/22 16:43
2,5-Dibromotoluene (PID)%80.5 70.0-130 12/06/22 16:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3869345-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3869345-2
Aliphatic (C05-C08)mg/kg 53.960.0 89.8 70.0-13010462.5 14.8 25
Aliphatic (C09-C12)mg/kg 67.570.0 96.4 70.0-13010171.0 5.05 25
Aromatic (C09-C10),Unadjusted mg/kg 12.310.0 123 70.0-13012512.5 1.61 25
Total VPH mg/kg 134140 95.7 70.0-130104146 8.57 25
2,5-Dibromotoluene (FID)%95.4 70.0-13094.6
2,5-Dibromotoluene (PID)%96.0 70.0-13095.3
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
R3869345-4MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92639042001
R3869345-5
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Aliphatic (C05-C08)mg/kg ML66.3 65.4 70.0-13073.4 11.4 2566.3ND 43.4 48.6
Aliphatic (C09-C12)mg/kg ML77.3 65.1 70.0-13078.5 17.9 2577.32.36 52.7 63.1
Aromatic (C09-
C10),Unadjusted mg/kg 11.0 79.4 70.0-13095.5 13.8 2511.03.19 12.0 13.7
Total VPH mg/kg ML15566.2 70.0-13077.4 14.9 251555.55 108 125
2,5-Dibromotoluene (FID)%89.0 70.0-13088.1
2,5-Dibromotoluene (PID)%91.0 70.0-13091.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
740295
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92639042001, 92639042003, 92639042004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3851761
Associated Lab Samples:92639042001, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 12/01/22 19:141.9
1,1,1-Trichloroethane ug/kg ND 5.0 12/01/22 19:142.6
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 12/01/22 19:141.3
1,1,2-Trichloroethane ug/kg ND 5.0 12/01/22 19:141.7
1,1-Dichloroethane ug/kg ND 5.0 12/01/22 19:142.1
1,1-Dichloroethene ug/kg ND 5.0 12/01/22 19:142.1
1,1-Dichloropropene ug/kg ND 5.0 12/01/22 19:142.4
1,2,3-Trichlorobenzene ug/kg ND 5.0 12/01/22 19:144.0
1,2,3-Trichloropropane ug/kg ND 5.0 12/01/22 19:142.5
1,2,4-Trichlorobenzene ug/kg ND 5.0 12/01/22 19:144.2
1,2,4-Trimethylbenzene ug/kg ND 5.0 12/01/22 19:141.4
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 12/01/22 19:141.9
1,2-Dibromoethane (EDB)ug/kg ND 5.0 12/01/22 19:142.2
1,2-Dichlorobenzene ug/kg ND 5.0 12/01/22 19:141.8
1,2-Dichloroethane ug/kg ND 5.0 12/01/22 19:143.3
1,2-Dichloropropane ug/kg ND 5.0 12/01/22 19:141.5
1,3,5-Trimethylbenzene ug/kg ND 5.0 12/01/22 19:141.7
1,3-Dichlorobenzene ug/kg ND 5.0 12/01/22 19:141.6
1,3-Dichloropropane ug/kg ND 5.0 12/01/22 19:141.6
1,4-Dichlorobenzene ug/kg ND 5.0 12/01/22 19:141.3
2,2-Dichloropropane ug/kg ND 5.0 IK12/01/22 19:141.6
2-Butanone (MEK)ug/kg ND 100 12/01/22 19:1424.0
2-Chlorotoluene ug/kg ND 5.0 12/01/22 19:141.8
2-Hexanone ug/kg ND 50.0 12/01/22 19:144.8
4-Chlorotoluene ug/kg ND 5.0 12/01/22 19:140.88
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 12/01/22 19:144.8
Acetone ug/kg ND 100 12/01/22 19:1432.1
Benzene ug/kg ND 5.0 12/01/22 19:142.0
Bromobenzene ug/kg ND 5.0 12/01/22 19:141.6
Bromochloromethane ug/kg ND 5.0 12/01/22 19:141.5
Bromodichloromethane ug/kg ND 5.0 12/01/22 19:141.9
Bromoform ug/kg ND 5.0 12/01/22 19:141.8
Bromomethane ug/kg ND 10.0 IK12/01/22 19:147.9
Carbon tetrachloride ug/kg ND 5.0 12/01/22 19:141.9
Chlorobenzene ug/kg ND 5.0 12/01/22 19:140.96
Chloroethane ug/kg ND 10.0 12/01/22 19:143.9
Chloroform ug/kg 42.0 5.0 C912/01/22 19:143.0
Chloromethane ug/kg ND 10.0 12/01/22 19:144.2
cis-1,2-Dichloroethene ug/kg ND 5.0 12/01/22 19:141.7
cis-1,3-Dichloropropene ug/kg ND 5.0 12/01/22 19:141.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3851761
Associated Lab Samples:92639042001, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg ND 5.0 12/01/22 19:142.8
Dibromomethane ug/kg ND 5.0 12/01/22 19:141.1
Dichlorodifluoromethane ug/kg ND 10.0 v112/01/22 19:142.2
Diisopropyl ether ug/kg ND 5.0 12/01/22 19:141.4
Ethylbenzene ug/kg ND 5.0 12/01/22 19:142.3
Hexachloro-1,3-butadiene ug/kg ND 10.0 12/01/22 19:148.2
Isopropylbenzene (Cumene)ug/kg ND 5.0 12/01/22 19:141.7
m&p-Xylene ug/kg ND 10.0 12/01/22 19:143.4
Methyl-tert-butyl ether ug/kg ND 5.0 12/01/22 19:141.9
Methylene Chloride ug/kg ND 20.0 IK12/01/22 19:1413.7
n-Butylbenzene ug/kg ND 5.0 12/01/22 19:142.4
n-Propylbenzene ug/kg ND 5.0 12/01/22 19:141.8
Naphthalene ug/kg ND 5.0 12/01/22 19:142.6
o-Xylene ug/kg ND 5.0 12/01/22 19:142.2
p-Isopropyltoluene ug/kg ND 5.0 12/01/22 19:142.5
sec-Butylbenzene ug/kg ND 5.0 12/01/22 19:142.2
Styrene ug/kg ND 5.0 12/01/22 19:141.3
tert-Butylbenzene ug/kg ND 5.0 12/01/22 19:141.8
Tetrachloroethene ug/kg ND 5.0 12/01/22 19:141.6
Toluene ug/kg ND 5.0 12/01/22 19:141.4
trans-1,2-Dichloroethene ug/kg ND 5.0 12/01/22 19:141.8
trans-1,3-Dichloropropene ug/kg ND 5.0 12/01/22 19:141.7
Trichloroethene ug/kg ND 5.0 12/01/22 19:141.3
Trichlorofluoromethane ug/kg ND 5.0 12/01/22 19:142.8
Vinyl acetate ug/kg ND 50.0 IK12/01/22 19:143.6
Vinyl chloride ug/kg ND 10.0 12/01/22 19:142.5
Xylene (Total)ug/kg ND 10.0 12/01/22 19:142.8
1,2-Dichloroethane-d4 (S)%105 70-130 12/01/22 19:14
4-Bromofluorobenzene (S)%101 70-130 12/01/22 19:14
Toluene-d8 (S)%100 70-130 12/01/22 19:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3851762LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 13001250 104 70-130
1,1,1-Trichloroethane ug/kg 12601250 101 70-130
1,1,2,2-Tetrachloroethane ug/kg 13001250 104 70-130
1,1,2-Trichloroethane ug/kg 13001250 104 70-130
1,1-Dichloroethane ug/kg 12501250 100 70-130
1,1-Dichloroethene ug/kg 13201250 106 70-130
1,1-Dichloropropene ug/kg 12801250 103 70-130
1,2,3-Trichlorobenzene ug/kg 13301250 107 70-130
1,2,3-Trichloropropane ug/kg 12401250 99 70-130
1,2,4-Trichlorobenzene ug/kg 13001250 104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3851762LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 12601250 101 70-130
1,2-Dibromo-3-chloropropane ug/kg 11701250 94 67-130
1,2-Dibromoethane (EDB)ug/kg 12701250 102 70-130
1,2-Dichlorobenzene ug/kg 12601250 101 70-130
1,2-Dichloroethane ug/kg 12001250 96 70-130
1,2-Dichloropropane ug/kg 12501250 100 70-130
1,3,5-Trimethylbenzene ug/kg 13001250 104 70-130
1,3-Dichlorobenzene ug/kg 12801250 102 70-130
1,3-Dichloropropane ug/kg 12601250 100 70-130
1,4-Dichlorobenzene ug/kg 11801250 94 70-130
2,2-Dichloropropane ug/kg 1170 IK12509467-130
2-Butanone (MEK)ug/kg 24102500 97 66-130
2-Chlorotoluene ug/kg 12301250 98 70-130
2-Hexanone ug/kg 26502500 106 70-130
4-Chlorotoluene ug/kg 12301250 99 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 25602500 102 70-130
Acetone ug/kg 24602500 99 67-130
Benzene ug/kg 11601250 93 70-130
Bromobenzene ug/kg 12701250 102 70-130
Bromochloromethane ug/kg 12501250 100 70-130
Bromodichloromethane ug/kg 12601250 101 70-130
Bromoform ug/kg 13801250 110 70-130
Bromomethane ug/kg 1280 IK125010353-175
Carbon tetrachloride ug/kg 12901250 103 70-130
Chlorobenzene ug/kg 12801250 103 70-130
Chloroethane ug/kg 13801250 111 70-135
Chloroform ug/kg 12401250 99 70-130
Chloromethane ug/kg 15601250 125 64-130
cis-1,2-Dichloroethene ug/kg 12301250 99 70-130
cis-1,3-Dichloropropene ug/kg 13001250 104 70-130
Dibromochloromethane ug/kg 13801250 110 70-130
Dibromomethane ug/kg 12601250 100 70-130
Dichlorodifluoromethane ug/kg 1630 v1125013063-145
Diisopropyl ether ug/kg 12001250 96 68-130
Ethylbenzene ug/kg 11901250 95 70-130
Hexachloro-1,3-butadiene ug/kg 12201250 98 70-130
Isopropylbenzene (Cumene)ug/kg 12601250 101 70-130
m&p-Xylene ug/kg 25402500 102 70-130
Methyl-tert-butyl ether ug/kg 11201250 90 70-130
Methylene Chloride ug/kg 1090 IK12508767-130
n-Butylbenzene ug/kg 12901250 103 70-130
n-Propylbenzene ug/kg 12301250 99 70-130
Naphthalene ug/kg 13201250 106 70-130
o-Xylene ug/kg 12901250 103 70-130
p-Isopropyltoluene ug/kg 13201250 106 70-130
sec-Butylbenzene ug/kg 12701250 102 70-130
Styrene ug/kg 13701250 110 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3851762LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 12401250 99 64-130
Tetrachloroethene ug/kg 13501250 108 70-130
Toluene ug/kg 12001250 96 70-130
trans-1,2-Dichloroethene ug/kg 12801250 102 70-130
trans-1,3-Dichloropropene ug/kg 13301250 107 70-130
Trichloroethene ug/kg 12601250 101 70-130
Trichlorofluoromethane ug/kg 13701250 110 70-130
Vinyl acetate ug/kg 2510 IK250010070-134
Vinyl chloride ug/kg 14301250 115 68-130
Xylene (Total)ug/kg 38203750 102 70-130
1,2-Dichloroethane-d4 (S)%92 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3851763MATRIX SPIKE SAMPLE:
MSSpike
Result
92638981001
1,1,1,2-Tetrachloroethane ug/kg 584705 83 58-140ND
1,1,1-Trichloroethane ug/kg 618705 88 58-144ND
1,1,2,2-Tetrachloroethane ug/kg 618705 88 52-139ND
1,1,2-Trichloroethane ug/kg 655705 93 56-140ND
1,1-Dichloroethane ug/kg 674705 96 58-145ND
1,1-Dichloroethene ug/kg 642705 91 57-158ND
1,1-Dichloropropene ug/kg 584705 83 58-151ND
1,2,3-Trichlorobenzene ug/kg 507705 72 48-149ND
1,2,3-Trichloropropane ug/kg 585705 83 54-132ND
1,2,4-Trichlorobenzene ug/kg 495705 70 51-151ND
1,2,4-Trimethylbenzene ug/kg 533705 76 38-170ND
1,2-Dibromo-3-chloropropane ug/kg 443705 63 44-134ND
1,2-Dibromoethane (EDB)ug/kg 619705 88 60-138ND
1,2-Dichlorobenzene ug/kg 561705 80 59-147ND
1,2-Dichloroethane ug/kg 617705 88 57-139ND
1,2-Dichloropropane ug/kg 638705 91 62-145ND
1,3,5-Trimethylbenzene ug/kg 540705 77 47-159ND
1,3-Dichlorobenzene ug/kg 539705 77 58-144ND
1,3-Dichloropropane ug/kg 629705 89 60-142ND
1,4-Dichlorobenzene ug/kg 509705 72 57-143ND
2,2-Dichloropropane ug/kg 513 IK7057337-144ND
2-Butanone (MEK)ug/kg 12401400 88 28-146ND
2-Chlorotoluene ug/kg 539705 76 55-158ND
2-Hexanone ug/kg 12201400 86 44-141ND
4-Chlorotoluene ug/kg 539705 77 55-146ND
4-Methyl-2-pentanone (MIBK)ug/kg 12401400 88 50-138ND
Acetone ug/kg 11501400 82 20-136ND
Benzene ug/kg 609705 87 60-145ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3851763MATRIX SPIKE SAMPLE:
MSSpike
Result
92638981001
Bromobenzene ug/kg 592705 84 59-145ND
Bromochloromethane ug/kg 638705 91 57-143ND
Bromodichloromethane ug/kg 594705 84 53-133ND
Bromoform ug/kg 535705 76 48-133ND
Bromomethane ug/kg 474 IK7056710-167ND
Carbon tetrachloride ug/kg 567705 80 57-147ND
Chlorobenzene ug/kg 609705 86 61-144ND
Chloroethane ug/kg 268705 38 10-153ND
Chloroform ug/kg 639705 91 58-141ND
Chloromethane ug/kg 674705 96 54-165ND
cis-1,2-Dichloroethene ug/kg 635705 90 59-144ND
cis-1,3-Dichloropropene ug/kg 616705 87 56-137ND
Dibromochloromethane ug/kg 559705 79 53-139ND
Dibromomethane ug/kg 645705 92 60-136ND
Dichlorodifluoromethane ug/kg 753 v170510749-177ND
Diisopropyl ether ug/kg 589705 84 53-136ND
Ethylbenzene ug/kg 545705 77 53-150ND
Hexachloro-1,3-butadiene ug/kg 455705 65 42-186ND
Isopropylbenzene (Cumene)ug/kg 568705 81 62-154ND
m&p-Xylene ug/kg 11501400 82 49-156ND
Methyl-tert-butyl ether ug/kg 571705 81 54-133ND
Methylene Chloride ug/kg 380 IK7055450-153ND
n-Butylbenzene ug/kg 494705 70 44-174ND
n-Propylbenzene ug/kg 509705 72 52-157ND
Naphthalene ug/kg 517705 73 37-150ND
o-Xylene ug/kg 602705 86 54-150ND
p-Isopropyltoluene ug/kg 523705 74 50-164ND
sec-Butylbenzene ug/kg 533705 76 58-161ND
Styrene ug/kg 625705 89 60-148ND
tert-Butylbenzene ug/kg 556705 79 44-151ND
Tetrachloroethene ug/kg 532705 75 53-151ND
Toluene ug/kg 598705 85 52-148ND
trans-1,2-Dichloroethene ug/kg 577705 82 60-148ND
trans-1,3-Dichloropropene ug/kg 636705 90 55-133ND
Trichloroethene ug/kg 592705 84 60-148ND
Trichlorofluoromethane ug/kg 446705 63 10-154ND
Vinyl acetate ug/kg 1150 IK14008150-149ND
Vinyl chloride ug/kg 722705 103 57-157ND
Xylene (Total)ug/kg 17502110 83 52-153ND
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638981002
3851764SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND 30ND
1,1,1-Trichloroethane ug/kg ND 30ND
1,1,2,2-Tetrachloroethane ug/kg ND 30ND
1,1,2-Trichloroethane ug/kg ND 30ND
1,1-Dichloroethane ug/kg ND 30ND
1,1-Dichloroethene ug/kg ND 30ND
1,1-Dichloropropene ug/kg ND 30ND
1,2,3-Trichlorobenzene ug/kg ND 30ND
1,2,3-Trichloropropane ug/kg ND 30ND
1,2,4-Trichlorobenzene ug/kg ND 30ND
1,2,4-Trimethylbenzene ug/kg ND 30ND
1,2-Dibromo-3-chloropropane ug/kg ND 30ND
1,2-Dibromoethane (EDB)ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,2-Dichloroethane ug/kg ND 30ND
1,2-Dichloropropane ug/kg ND 30ND
1,3,5-Trimethylbenzene ug/kg ND 30ND
1,3-Dichlorobenzene ug/kg ND 30ND
1,3-Dichloropropane ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
2,2-Dichloropropane ug/kg ND IK30ND
2-Butanone (MEK)ug/kg ND 30ND
2-Chlorotoluene ug/kg ND 30ND
2-Hexanone ug/kg ND 30ND
4-Chlorotoluene ug/kg ND 30ND
4-Methyl-2-pentanone (MIBK)ug/kg ND 30ND
Acetone ug/kg ND 30ND
Benzene ug/kg ND 30ND
Bromobenzene ug/kg ND 30ND
Bromochloromethane ug/kg ND 30ND
Bromodichloromethane ug/kg ND 30ND
Bromoform ug/kg ND 30ND
Bromomethane ug/kg ND IK30ND
Carbon tetrachloride ug/kg ND 30ND
Chlorobenzene ug/kg ND 30ND
Chloroethane ug/kg ND 30ND
Chloroform ug/kg ND 30ND
Chloromethane ug/kg ND 30ND
cis-1,2-Dichloroethene ug/kg ND 30ND
cis-1,3-Dichloropropene ug/kg ND 30ND
Dibromochloromethane ug/kg ND 30ND
Dibromomethane ug/kg ND 30ND
Dichlorodifluoromethane ug/kg ND v130ND
Diisopropyl ether ug/kg ND 30ND
Ethylbenzene ug/kg 4.5J 30ND
Hexachloro-1,3-butadiene ug/kg ND 30ND
Isopropylbenzene (Cumene)ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638981002
3851764SAMPLE DUPLICATE:
m&p-Xylene ug/kg ND 30ND
Methyl-tert-butyl ether ug/kg ND 30ND
Methylene Chloride ug/kg ND IK30ND
n-Butylbenzene ug/kg ND 30ND
n-Propylbenzene ug/kg ND 30ND
Naphthalene ug/kg ND 30ND
o-Xylene ug/kg ND 305.9J
p-Isopropyltoluene ug/kg ND 30ND
sec-Butylbenzene ug/kg ND 30ND
Styrene ug/kg ND 30ND
tert-Butylbenzene ug/kg ND 30ND
Tetrachloroethene ug/kg ND 30ND
Toluene ug/kg ND 30ND
trans-1,2-Dichloroethene ug/kg ND 30ND
trans-1,3-Dichloropropene ug/kg ND 30ND
Trichloroethene ug/kg ND 30ND
Trichlorofluoromethane ug/kg ND 30ND
Vinyl acetate ug/kg ND IK30ND
Vinyl chloride ug/kg ND 30ND
Xylene (Total)ug/kg ND 305.9J
1,2-Dichloroethane-d4 (S)%106103
4-Bromofluorobenzene (S)%100103
Toluene-d8 (S)%100100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
740648
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92639042002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3853271
Associated Lab Samples:92639042002
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 12/02/22 14:151.9
1,1,1-Trichloroethane ug/kg ND 5.0 12/02/22 14:152.6
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 12/02/22 14:151.3
1,1,2-Trichloroethane ug/kg ND 5.0 12/02/22 14:151.7
1,1-Dichloroethane ug/kg ND 5.0 12/02/22 14:152.1
1,1-Dichloroethene ug/kg ND 5.0 12/02/22 14:152.1
1,1-Dichloropropene ug/kg ND 5.0 12/02/22 14:152.4
1,2,3-Trichlorobenzene ug/kg ND 5.0 12/02/22 14:154.0
1,2,3-Trichloropropane ug/kg ND 5.0 12/02/22 14:152.5
1,2,4-Trichlorobenzene ug/kg ND 5.0 12/02/22 14:154.2
1,2,4-Trimethylbenzene ug/kg ND 5.0 12/02/22 14:151.4
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 12/02/22 14:151.9
1,2-Dibromoethane (EDB)ug/kg ND 5.0 12/02/22 14:152.2
1,2-Dichlorobenzene ug/kg ND 5.0 12/02/22 14:151.8
1,2-Dichloroethane ug/kg ND 5.0 12/02/22 14:153.3
1,2-Dichloropropane ug/kg ND 5.0 12/02/22 14:151.5
1,3,5-Trimethylbenzene ug/kg ND 5.0 12/02/22 14:151.7
1,3-Dichlorobenzene ug/kg ND 5.0 12/02/22 14:151.6
1,3-Dichloropropane ug/kg ND 5.0 12/02/22 14:151.6
1,4-Dichlorobenzene ug/kg ND 5.0 12/02/22 14:151.3
2,2-Dichloropropane ug/kg ND 5.0 IK12/02/22 14:151.6
2-Butanone (MEK)ug/kg ND 100 12/02/22 14:1524.0
2-Chlorotoluene ug/kg ND 5.0 12/02/22 14:151.8
2-Hexanone ug/kg ND 50.0 v112/02/22 14:154.8
4-Chlorotoluene ug/kg ND 5.0 12/02/22 14:150.88
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 v112/02/22 14:154.8
Acetone ug/kg ND 100 12/02/22 14:1532.1
Benzene ug/kg ND 5.0 12/02/22 14:152.0
Bromobenzene ug/kg ND 5.0 12/02/22 14:151.6
Bromochloromethane ug/kg ND 5.0 12/02/22 14:151.5
Bromodichloromethane ug/kg ND 5.0 12/02/22 14:151.9
Bromoform ug/kg ND 5.0 12/02/22 14:151.8
Bromomethane ug/kg ND 10.0 IK12/02/22 14:157.9
Carbon tetrachloride ug/kg ND 5.0 12/02/22 14:151.9
Chlorobenzene ug/kg ND 5.0 12/02/22 14:150.96
Chloroethane ug/kg ND 10.0 12/02/22 14:153.9
Chloroform ug/kg ND 5.0 12/02/22 14:153.0
Chloromethane ug/kg ND 10.0 12/02/22 14:154.2
cis-1,2-Dichloroethene ug/kg ND 5.0 12/02/22 14:151.7
cis-1,3-Dichloropropene ug/kg ND 5.0 12/02/22 14:151.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3853271
Associated Lab Samples:92639042002
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg ND 5.0 12/02/22 14:152.8
Dibromomethane ug/kg ND 5.0 12/02/22 14:151.1
Dichlorodifluoromethane ug/kg ND 10.0 12/02/22 14:152.2
Diisopropyl ether ug/kg ND 5.0 12/02/22 14:151.4
Ethylbenzene ug/kg ND 5.0 12/02/22 14:152.3
Hexachloro-1,3-butadiene ug/kg ND 10.0 12/02/22 14:158.2
Isopropylbenzene (Cumene)ug/kg ND 5.0 12/02/22 14:151.7
m&p-Xylene ug/kg ND 10.0 12/02/22 14:153.4
Methyl-tert-butyl ether ug/kg ND 5.0 12/02/22 14:151.9
Methylene Chloride ug/kg ND 20.0 IK12/02/22 14:1513.7
n-Butylbenzene ug/kg ND 5.0 12/02/22 14:152.4
n-Propylbenzene ug/kg ND 5.0 12/02/22 14:151.8
Naphthalene ug/kg ND 5.0 12/02/22 14:152.6
o-Xylene ug/kg ND 5.0 12/02/22 14:152.2
p-Isopropyltoluene ug/kg ND 5.0 12/02/22 14:152.5
sec-Butylbenzene ug/kg ND 5.0 12/02/22 14:152.2
Styrene ug/kg ND 5.0 12/02/22 14:151.3
tert-Butylbenzene ug/kg ND 5.0 12/02/22 14:151.8
Tetrachloroethene ug/kg ND 5.0 12/02/22 14:151.6
Toluene ug/kg ND 5.0 12/02/22 14:151.4
trans-1,2-Dichloroethene ug/kg ND 5.0 12/02/22 14:151.8
trans-1,3-Dichloropropene ug/kg ND 5.0 12/02/22 14:151.7
Trichloroethene ug/kg ND 5.0 12/02/22 14:151.3
Trichlorofluoromethane ug/kg ND 5.0 12/02/22 14:152.8
Vinyl acetate ug/kg ND 50.0 IK12/02/22 14:153.6
Vinyl chloride ug/kg ND 10.0 12/02/22 14:152.5
Xylene (Total)ug/kg ND 10.0 12/02/22 14:152.8
1,2-Dichloroethane-d4 (S)%112 70-130 12/02/22 14:15
4-Bromofluorobenzene (S)%101 70-130 12/02/22 14:15
Toluene-d8 (S)%102 70-130 12/02/22 14:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3853272LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 13001250 104 70-130
1,1,1-Trichloroethane ug/kg 13001250 104 70-130
1,1,2,2-Tetrachloroethane ug/kg 13301250 107 70-130
1,1,2-Trichloroethane ug/kg 13001250 104 70-130
1,1-Dichloroethane ug/kg 13001250 104 70-130
1,1-Dichloroethene ug/kg 13401250 107 70-130
1,1-Dichloropropene ug/kg 13201250 105 70-130
1,2,3-Trichlorobenzene ug/kg 14201250 114 70-130
1,2,3-Trichloropropane ug/kg 13301250 106 70-130
1,2,4-Trichlorobenzene ug/kg 13301250 106 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3853272LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 12301250 98 70-130
1,2-Dibromo-3-chloropropane ug/kg 13001250 104 67-130
1,2-Dibromoethane (EDB)ug/kg 13401250 107 70-130
1,2-Dichlorobenzene ug/kg 12801250 102 70-130
1,2-Dichloroethane ug/kg 12101250 97 70-130
1,2-Dichloropropane ug/kg 12601250 101 70-130
1,3,5-Trimethylbenzene ug/kg 13301250 106 70-130
1,3-Dichlorobenzene ug/kg 12501250 100 70-130
1,3-Dichloropropane ug/kg 12801250 103 70-130
1,4-Dichlorobenzene ug/kg 11801250 95 70-130
2,2-Dichloropropane ug/kg 1450 IK125011667-130
2-Butanone (MEK)ug/kg 26902500 108 66-130
2-Chlorotoluene ug/kg 12601250 101 70-130
2-Hexanone ug/kg 3010 v1250012070-130
4-Chlorotoluene ug/kg 12601250 101 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 2800 v1250011270-130
Acetone ug/kg 25402500 102 67-130
Benzene ug/kg 11701250 94 70-130
Bromobenzene ug/kg 13001250 104 70-130
Bromochloromethane ug/kg 13001250 104 70-130
Bromodichloromethane ug/kg 12801250 102 70-130
Bromoform ug/kg 13701250 109 70-130
Bromomethane ug/kg 1650 IK125013253-175
Carbon tetrachloride ug/kg 14701250 118 70-130
Chlorobenzene ug/kg 12801250 102 70-130
Chloroethane ug/kg 14201250 113 70-135
Chloroform ug/kg 12701250 101 70-130
Chloromethane ug/kg 12201250 97 64-130
cis-1,2-Dichloroethene ug/kg 12501250 100 70-130
cis-1,3-Dichloropropene ug/kg 13601250 109 70-130
Dibromochloromethane ug/kg 13801250 110 70-130
Dibromomethane ug/kg 12601250 101 70-130
Dichlorodifluoromethane ug/kg 16401250 132 63-145
Diisopropyl ether ug/kg 12201250 97 68-130
Ethylbenzene ug/kg 12001250 96 70-130
Hexachloro-1,3-butadiene ug/kg 12701250 101 70-130
Isopropylbenzene (Cumene)ug/kg 12501250 100 70-130
m&p-Xylene ug/kg 25402500 101 70-130
Methyl-tert-butyl ether ug/kg 11901250 95 70-130
Methylene Chloride ug/kg 1060 IK12508567-130
n-Butylbenzene ug/kg 13301250 106 70-130
n-Propylbenzene ug/kg 12801250 102 70-130
Naphthalene ug/kg 14501250 116 70-130
o-Xylene ug/kg 12801250 102 70-130
p-Isopropyltoluene ug/kg 13401250 107 70-130
sec-Butylbenzene ug/kg 12901250 103 70-130
Styrene ug/kg 13701250 109 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3853272LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 13201250 105 64-130
Tetrachloroethene ug/kg 13501250 108 70-130
Toluene ug/kg 11901250 96 70-130
trans-1,2-Dichloroethene ug/kg 12901250 103 70-130
trans-1,3-Dichloropropene ug/kg 14001250 112 70-130
Trichloroethene ug/kg 12201250 97 70-130
Trichlorofluoromethane ug/kg 14501250 116 70-130
Vinyl acetate ug/kg 2670 IK250010770-134
Vinyl chloride ug/kg 14701250 118 68-130
Xylene (Total)ug/kg 38103750 102 70-130
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3853273MATRIX SPIKE SAMPLE:
MSSpike
Result
92638985001
1,1,1,2-Tetrachloroethane ug/kg 762731 104 58-140ND
1,1,1-Trichloroethane ug/kg 846731 116 58-144ND
1,1,2,2-Tetrachloroethane ug/kg 842731 115 52-139ND
1,1,2-Trichloroethane ug/kg 861731 118 56-140ND
1,1-Dichloroethane ug/kg 884731 121 58-145ND
1,1-Dichloroethene ug/kg 851731 116 57-158ND
1,1-Dichloropropene ug/kg 802731 110 58-151ND
1,2,3-Trichlorobenzene ug/kg 595731 81 48-149ND
1,2,3-Trichloropropane ug/kg 802731 110 54-132ND
1,2,4-Trichlorobenzene ug/kg 624731 85 51-151ND
1,2,4-Trimethylbenzene ug/kg 718731 98 38-170ND
1,2-Dibromo-3-chloropropane ug/kg 642731 88 44-134ND
1,2-Dibromoethane (EDB)ug/kg 813731 111 60-138ND
1,2-Dichlorobenzene ug/kg 746731 102 59-147ND
1,2-Dichloroethane ug/kg 795731 109 57-139ND
1,2-Dichloropropane ug/kg 848731 116 62-145ND
1,3,5-Trimethylbenzene ug/kg 751731 103 47-159ND
1,3-Dichlorobenzene ug/kg 693731 95 58-144ND
1,3-Dichloropropane ug/kg 808731 111 60-142ND
1,4-Dichlorobenzene ug/kg 676731 92 57-143ND
2,2-Dichloropropane ug/kg 640 IK7318837-144ND
2-Butanone (MEK)ug/kg 17401470 119 28-146ND
2-Chlorotoluene ug/kg 728731 100 55-158ND
2-Hexanone ug/kg 1750 v1147012044-141ND
4-Chlorotoluene ug/kg 728731 100 55-146ND
4-Methyl-2-pentanone (MIBK)ug/kg 1780 v1147012250-138ND
Acetone ug/kg 16701470 114 20-136ND
Benzene ug/kg 791731 108 60-145ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3853273MATRIX SPIKE SAMPLE:
MSSpike
Result
92638985001
Bromobenzene ug/kg 776731 106 59-145ND
Bromochloromethane ug/kg 823731 113 57-143ND
Bromodichloromethane ug/kg 770731 105 53-133ND
Bromoform ug/kg 754731 103 48-133ND
Bromomethane ug/kg 567 IK7317810-167ND
Carbon tetrachloride ug/kg 689731 94 57-147ND
Chlorobenzene ug/kg 790731 108 61-144ND
Chloroethane ug/kg 310731 42 10-153ND
Chloroform ug/kg 851731 116 58-141ND
Chloromethane ug/kg 925731 127 54-165ND
cis-1,2-Dichloroethene ug/kg 823731 113 59-144ND
cis-1,3-Dichloropropene ug/kg 824731 113 56-137ND
Dibromochloromethane ug/kg 764731 105 53-139ND
Dibromomethane ug/kg 801731 110 60-136ND
Dichlorodifluoromethane ug/kg 970731 133 49-177ND
Diisopropyl ether ug/kg 808731 111 53-136ND
Ethylbenzene ug/kg 729731 100 53-150ND
Hexachloro-1,3-butadiene ug/kg 635731 87 42-186ND
Isopropylbenzene (Cumene)ug/kg 748731 102 62-154ND
m&p-Xylene ug/kg 15201470 104 49-156ND
Methyl-tert-butyl ether ug/kg 766731 105 54-133ND
Methylene Chloride ug/kg 551 IK7317550-153ND
n-Butylbenzene ug/kg 696731 95 44-174ND
n-Propylbenzene ug/kg 709731 97 52-157ND
Naphthalene ug/kg 664731 91 37-150ND
o-Xylene ug/kg 800731 110 54-150ND
p-Isopropyltoluene ug/kg 739731 101 50-164ND
sec-Butylbenzene ug/kg 748731 102 58-161ND
Styrene ug/kg 823731 113 60-148ND
tert-Butylbenzene ug/kg 751731 103 44-151ND
Tetrachloroethene ug/kg 693731 95 53-151ND
Toluene ug/kg 772731 106 52-148ND
trans-1,2-Dichloroethene ug/kg 793731 109 60-148ND
trans-1,3-Dichloropropene ug/kg 828731 113 55-133ND
Trichloroethene ug/kg 763731 104 60-148ND
Trichlorofluoromethane ug/kg 499731 68 10-154ND
Vinyl acetate ug/kg 1410 IK14709750-149ND
Vinyl chloride ug/kg 901731 123 57-157ND
Xylene (Total)ug/kg 23202190 106 52-153ND
1,2-Dichloroethane-d4 (S)%105 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638985002
3853274SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND 30ND
1,1,1-Trichloroethane ug/kg ND 30ND
1,1,2,2-Tetrachloroethane ug/kg ND 30ND
1,1,2-Trichloroethane ug/kg ND 30ND
1,1-Dichloroethane ug/kg ND 30ND
1,1-Dichloroethene ug/kg ND 30ND
1,1-Dichloropropene ug/kg ND 30ND
1,2,3-Trichlorobenzene ug/kg ND 30ND
1,2,3-Trichloropropane ug/kg ND 30ND
1,2,4-Trichlorobenzene ug/kg ND 30ND
1,2,4-Trimethylbenzene ug/kg ND 30ND
1,2-Dibromo-3-chloropropane ug/kg ND 30ND
1,2-Dibromoethane (EDB)ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,2-Dichloroethane ug/kg ND 30ND
1,2-Dichloropropane ug/kg ND 30ND
1,3,5-Trimethylbenzene ug/kg ND 30ND
1,3-Dichlorobenzene ug/kg ND 30ND
1,3-Dichloropropane ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
2,2-Dichloropropane ug/kg ND IK30ND
2-Butanone (MEK)ug/kg ND 30ND
2-Chlorotoluene ug/kg ND 30ND
2-Hexanone ug/kg ND v130ND
4-Chlorotoluene ug/kg ND 30ND
4-Methyl-2-pentanone (MIBK)ug/kg ND v130ND
Acetone ug/kg ND 30ND
Benzene ug/kg ND 30ND
Bromobenzene ug/kg ND 30ND
Bromochloromethane ug/kg ND 30ND
Bromodichloromethane ug/kg ND 30ND
Bromoform ug/kg ND 30ND
Bromomethane ug/kg ND IK30ND
Carbon tetrachloride ug/kg ND 30ND
Chlorobenzene ug/kg ND 30ND
Chloroethane ug/kg ND 30ND
Chloroform ug/kg ND 30ND
Chloromethane ug/kg ND 30ND
cis-1,2-Dichloroethene ug/kg ND 30ND
cis-1,3-Dichloropropene ug/kg ND 30ND
Dibromochloromethane ug/kg ND 30ND
Dibromomethane ug/kg ND 30ND
Dichlorodifluoromethane ug/kg ND 30ND
Diisopropyl ether ug/kg ND 30ND
Ethylbenzene ug/kg ND 30ND
Hexachloro-1,3-butadiene ug/kg ND 30ND
Isopropylbenzene (Cumene)ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638985002
3853274SAMPLE DUPLICATE:
m&p-Xylene ug/kg ND 30ND
Methyl-tert-butyl ether ug/kg ND 30ND
Methylene Chloride ug/kg ND IK30ND
n-Butylbenzene ug/kg ND 30ND
n-Propylbenzene ug/kg ND 30ND
Naphthalene ug/kg ND 30ND
o-Xylene ug/kg ND 30ND
p-Isopropyltoluene ug/kg ND 30ND
sec-Butylbenzene ug/kg ND 30ND
Styrene ug/kg ND 30ND
tert-Butylbenzene ug/kg ND 30ND
Tetrachloroethene ug/kg ND 30ND
Toluene ug/kg ND 30ND
trans-1,2-Dichloroethene ug/kg ND 30ND
trans-1,3-Dichloropropene ug/kg ND 30ND
Trichloroethene ug/kg ND 30ND
Trichlorofluoromethane ug/kg ND 30ND
Vinyl acetate ug/kg ND IK30ND
Vinyl chloride ug/kg ND 30ND
Xylene (Total)ug/kg ND 30ND
1,2-Dichloroethane-d4 (S)%111106
4-Bromofluorobenzene (S)%104103
Toluene-d8 (S)%103102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
741034
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3854964
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
1,2,4-Trichlorobenzene ug/kg ND 326 12/05/22 14:15128
1,2-Dichlorobenzene ug/kg ND 326 12/05/22 14:15117
1,3-Dichlorobenzene ug/kg ND 326 12/05/22 14:15115
1,4-Dichlorobenzene ug/kg ND 326 12/05/22 14:15124
1-Methylnaphthalene ug/kg ND 326 12/05/22 14:15114
2,2'-Oxybis(1-chloropropane)ug/kg ND 326 12/05/22 14:15155
2,4,5-Trichlorophenol ug/kg ND 326 12/05/22 14:15149
2,4,6-Trichlorophenol ug/kg ND 326 12/05/22 14:15134
2,4-Dichlorophenol ug/kg ND 326 12/05/22 14:15127
2,4-Dimethylphenol ug/kg ND 326 12/05/22 14:15135
2,4-Dinitrophenol ug/kg ND 1630 12/05/22 14:151010
2,4-Dinitrotoluene ug/kg ND 326 12/05/22 14:15125
2,6-Dinitrotoluene ug/kg ND 326 12/05/22 14:15119
2-Chloronaphthalene ug/kg ND 326 12/05/22 14:15129
2-Chlorophenol ug/kg ND 326 12/05/22 14:15122
2-Methylnaphthalene ug/kg ND 326 12/05/22 14:15130
2-Methylphenol(o-Cresol)ug/kg ND 326 12/05/22 14:15133
2-Nitroaniline ug/kg ND 1630 12/05/22 14:15266
2-Nitrophenol ug/kg ND 326 12/05/22 14:15141
3&4-Methylphenol(m&p Cresol)ug/kg ND 326 12/05/22 14:15131
3,3'-Dichlorobenzidine ug/kg ND 651 v212/05/22 14:15220
3-Nitroaniline ug/kg ND 1630 12/05/22 14:15256
4,6-Dinitro-2-methylphenol ug/kg ND 651 12/05/22 14:15304
4-Bromophenylphenyl ether ug/kg ND 326 12/05/22 14:15125
4-Chloro-3-methylphenol ug/kg ND 651 12/05/22 14:15229
4-Chloroaniline ug/kg ND 651 12/05/22 14:15256
4-Chlorophenylphenyl ether ug/kg ND 326 12/05/22 14:15121
4-Nitroaniline ug/kg ND 651 12/05/22 14:15248
4-Nitrophenol ug/kg ND 1630 12/05/22 14:15630
Acenaphthene ug/kg ND 326 12/05/22 14:15114
Acenaphthylene ug/kg ND 326 12/05/22 14:15114
Aniline ug/kg ND 326 12/05/22 14:15127
Anthracene ug/kg ND 326 12/05/22 14:15107
Benzo(a)anthracene ug/kg ND 326 12/05/22 14:15109
Benzo(a)pyrene ug/kg ND 326 12/05/22 14:15112
Benzo(b)fluoranthene ug/kg ND 326 12/05/22 14:15109
Benzo(g,h,i)perylene ug/kg ND 326 12/05/22 14:15126
Benzo(k)fluoranthene ug/kg ND 326 12/05/22 14:15114
Benzoic Acid ug/kg ND 1630 12/05/22 14:15700
Benzyl alcohol ug/kg ND 651 12/05/22 14:15247
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3854964
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/kg ND 326 12/05/22 14:15135
bis(2-Chloroethyl) ether ug/kg ND 326 12/05/22 14:15122
bis(2-Ethylhexyl)phthalate ug/kg ND 326 12/05/22 14:15126
Butylbenzylphthalate ug/kg ND 326 12/05/22 14:15137
Chrysene ug/kg ND 326 v212/05/22 14:15118
Di-n-butylphthalate ug/kg ND 326 12/05/22 14:15110
Di-n-octylphthalate ug/kg ND 326 12/05/22 14:15128
Dibenz(a,h)anthracene ug/kg ND 326 12/05/22 14:15125
Dibenzofuran ug/kg ND 326 12/05/22 14:15117
Diethylphthalate ug/kg ND 326 12/05/22 14:15119
Dimethylphthalate ug/kg ND 326 12/05/22 14:15118
Fluoranthene ug/kg ND 326 12/05/22 14:15112
Fluorene ug/kg ND 326 12/05/22 14:15114
Hexachloro-1,3-butadiene ug/kg ND 326 12/05/22 14:15141
Hexachlorobenzene ug/kg ND 326 12/05/22 14:15127
Hexachlorocyclopentadiene ug/kg ND 326 12/05/22 14:15187
Hexachloroethane ug/kg ND 326 12/05/22 14:15124
Indeno(1,2,3-cd)pyrene ug/kg ND 326 12/05/22 14:15128
Isophorone ug/kg ND 326 12/05/22 14:15145
N-Nitroso-di-n-propylamine ug/kg ND 326 12/05/22 14:15122
N-Nitrosodimethylamine ug/kg ND 326 12/05/22 14:15110
N-Nitrosodiphenylamine ug/kg ND 326 12/05/22 14:15115
Naphthalene ug/kg ND 326 12/05/22 14:15111
Nitrobenzene ug/kg ND 326 12/05/22 14:15151
Pentachlorophenol ug/kg ND 651 12/05/22 14:15319
Phenanthrene ug/kg ND 326 12/05/22 14:15107
Phenol ug/kg ND 326 12/05/22 14:15145
Pyrene ug/kg ND 326 12/05/22 14:15132
Pyridine ug/kg ND 326 12/05/22 14:15103
2,4,6-Tribromophenol (S)%73 10-131 12/05/22 14:15
2-Fluorobiphenyl (S)%65 10-130 12/05/22 14:15
2-Fluorophenol (S)%69 10-130 12/05/22 14:15
Nitrobenzene-d5 (S)%66 10-130 12/05/22 14:15
Phenol-d6 (S)%72 10-130 12/05/22 14:15
Terphenyl-d14 (S)%82 10-130 12/05/22 14:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3854965LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 11201660 68 43-130
1,2-Dichlorobenzene ug/kg 11401660 69 43-130
1,3-Dichlorobenzene ug/kg 11201660 68 43-130
1,4-Dichlorobenzene ug/kg 11201660 67 44-130
1-Methylnaphthalene ug/kg 12301660 74 47-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3854965LABORATORY CONTROL SAMPLE:
LCSSpike
2,2'-Oxybis(1-chloropropane)ug/kg 10301660 62 29-130
2,4,5-Trichlorophenol ug/kg 11901660 72 47-130
2,4,6-Trichlorophenol ug/kg 11701660 71 47-130
2,4-Dichlorophenol ug/kg 11701660 70 45-130
2,4-Dimethylphenol ug/kg 14401660 87 45-130
2,4-Dinitrophenol ug/kg 63308280 76 27-140
2,4-Dinitrotoluene ug/kg 13601660 82 46-130
2,6-Dinitrotoluene ug/kg 13901660 84 48-130
2-Chloronaphthalene ug/kg 12401660 75 46-130
2-Chlorophenol ug/kg 11601660 70 43-130
2-Methylnaphthalene ug/kg 11801660 71 47-130
2-Methylphenol(o-Cresol)ug/kg 11601660 70 42-130
2-Nitroaniline ug/kg 22603310 68 41-130
2-Nitrophenol ug/kg 12301660 74 48-130
3&4-Methylphenol(m&p Cresol)ug/kg 11801660 72 39-130
3,3'-Dichlorobenzidine ug/kg 2320 v333107041-130
3-Nitroaniline ug/kg 21803310 66 37-130
4,6-Dinitro-2-methylphenol ug/kg 27203310 82 38-141
4-Bromophenylphenyl ether ug/kg 13201660 79 47-130
4-Chloro-3-methylphenol ug/kg 24603310 74 44-130
4-Chloroaniline ug/kg 21703310 65 41-130
4-Chlorophenylphenyl ether ug/kg 12001660 73 45-130
4-Nitroaniline ug/kg 23603310 71 42-130
4-Nitrophenol ug/kg 59708280 72 39-131
Acenaphthene ug/kg 12401660 75 49-130
Acenaphthylene ug/kg 12401660 75 50-130
Aniline ug/kg 9401660 57 38-130
Anthracene ug/kg 12301660 74 49-130
Benzo(a)anthracene ug/kg 13701660 82 51-130
Benzo(a)pyrene ug/kg 13001660 79 51-130
Benzo(b)fluoranthene ug/kg 13301660 80 49-130
Benzo(g,h,i)perylene ug/kg 13701660 83 48-140
Benzo(k)fluoranthene ug/kg 13601660 82 51-130
Benzoic Acid ug/kg 53608280 65 22-130
Benzyl alcohol ug/kg 23703310 72 43-130
bis(2-Chloroethoxy)methane ug/kg 11901660 72 43-130
bis(2-Chloroethyl) ether ug/kg 11301660 68 42-130
bis(2-Ethylhexyl)phthalate ug/kg 15001660 90 43-130
Butylbenzylphthalate ug/kg 16301660 98 44-131
Chrysene ug/kg 1330 v316608151-130
Di-n-butylphthalate ug/kg 13901660 84 46-130
Di-n-octylphthalate ug/kg 15001660 90 45-130
Dibenz(a,h)anthracene ug/kg 14101660 85 48-130
Dibenzofuran ug/kg 12601660 76 10-130
Diethylphthalate ug/kg 13201660 80 48-130
Dimethylphthalate ug/kg 12801660 78 48-130
Fluoranthene ug/kg 12301660 74 48-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3854965LABORATORY CONTROL SAMPLE:
LCSSpike
Fluorene ug/kg 12201660 74 48-130
Hexachloro-1,3-butadiene ug/kg 10301660 62 39-130
Hexachlorobenzene ug/kg 12901660 78 47-130
Hexachlorocyclopentadiene ug/kg 9451660 57 17-130
Hexachloroethane ug/kg 11401660 69 40-130
Indeno(1,2,3-cd)pyrene ug/kg 13401660 81 50-130
Isophorone ug/kg 11701660 71 41-130
N-Nitroso-di-n-propylamine ug/kg 12101660 73 36-130
N-Nitrosodimethylamine ug/kg 10601660 64 34-130
N-Nitrosodiphenylamine ug/kg 13301660 80 48-130
Naphthalene ug/kg 11401660 69 46-130
Nitrobenzene ug/kg 11301660 68 39-130
Pentachlorophenol ug/kg 23803310 72 42-130
Phenanthrene ug/kg 13301660 80 50-130
Phenol ug/kg 12601660 76 42-130
Pyrene ug/kg 14801660 89 50-130
Pyridine ug/kg 9471660 57 26-130
2,4,6-Tribromophenol (S)%81 10-131
2-Fluorobiphenyl (S)%68 10-130
2-Fluorophenol (S)%66 10-130
Nitrobenzene-d5 (S)%65 10-130
Phenol-d6 (S)%71 10-130
Terphenyl-d14 (S)%87 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3854966MATRIX SPIKE SAMPLE:
MSSpike
Result
92639042001
1,2,4-Trichlorobenzene ug/kg 13301950 68 16-130ND
1,2-Dichlorobenzene ug/kg 13901950 71 19-130ND
1,3-Dichlorobenzene ug/kg 13701950 70 19-130ND
1,4-Dichlorobenzene ug/kg 13801950 71 20-130ND
1-Methylnaphthalene ug/kg 14601950 75 19-130ND
2,2'-Oxybis(1-chloropropane)ug/kg 12901950 66 10-130ND
2,4,5-Trichlorophenol ug/kg 16001950 82 19-130ND
2,4,6-Trichlorophenol ug/kg 15701950 80 18-130ND
2,4-Dichlorophenol ug/kg 15201950 78 16-130ND
2,4-Dimethylphenol ug/kg 19001950 98 10-130ND
2,4-Dinitrophenol ug/kg 88209750 90 10-143ND
2,4-Dinitrotoluene ug/kg 18401950 94 19-130ND
2,6-Dinitrotoluene ug/kg 18201950 94 22-130ND
2-Chloronaphthalene ug/kg 14701950 76 18-130ND
2-Chlorophenol ug/kg 14601950 75 20-130ND
2-Methylnaphthalene ug/kg 14001950 72 18-130ND
2-Methylphenol(o-Cresol)ug/kg 15001950 77 13-130ND
2-Nitroaniline ug/kg 30503900 78 18-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/08/2022 01:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3854966MATRIX SPIKE SAMPLE:
MSSpike
Result
92639042001
2-Nitrophenol ug/kg 15901950 81 19-130ND
3&4-Methylphenol(m&p Cresol)ug/kg 15101950 78 13-130ND
3,3'-Dichlorobenzidine ug/kg 3110 v339008010-130ND
3-Nitroaniline ug/kg 32303900 83 22-130ND
4,6-Dinitro-2-methylphenol ug/kg 36903900 95 10-144ND
4-Bromophenylphenyl ether ug/kg 15401950 79 18-130ND
4-Chloro-3-methylphenol ug/kg 33003900 85 16-130ND
4-Chloroaniline ug/kg 29303900 75 17-130ND
4-Chlorophenylphenyl ether ug/kg 14101950 72 17-130ND
4-Nitroaniline ug/kg 33603900 86 21-130ND
4-Nitrophenol ug/kg 84009750 86 13-131ND
Acenaphthene ug/kg 14601950 75 20-130ND
Acenaphthylene ug/kg 14801950 76 21-130ND
Aniline ug/kg 11601950 60 10-130ND
Anthracene ug/kg 14301950 74 19-130ND
Benzo(a)anthracene ug/kg 15701950 80 17-130ND
Benzo(a)pyrene ug/kg 15001950 77 14-130ND
Benzo(b)fluoranthene ug/kg 15601950 80 11-134ND
Benzo(g,h,i)perylene ug/kg 15601950 80 12-130ND
Benzo(k)fluoranthene ug/kg 15801950 81 15-130ND
Benzoic Acid ug/kg 76109750 78 10-130ND
Benzyl alcohol ug/kg 30603900 78 20-130ND
bis(2-Chloroethoxy)methane ug/kg 15101950 77 16-130ND
bis(2-Chloroethyl) ether ug/kg 14201950 73 18-130ND
bis(2-Ethylhexyl)phthalate ug/kg 17801950 91 11-130ND
Butylbenzylphthalate ug/kg 19001950 97 10-130ND
Chrysene ug/kg 1530 v319507917-130ND
Di-n-butylphthalate ug/kg 16101950 83 16-130ND
Di-n-octylphthalate ug/kg 18301950 94 16-130ND
Dibenz(a,h)anthracene ug/kg 15901950 81 13-130ND
Dibenzofuran ug/kg 14901950 77 19-130ND
Diethylphthalate ug/kg 17001950 87 22-130ND
Dimethylphthalate ug/kg 17101950 88 23-130ND
Fluoranthene ug/kg 14701950 75 14-130ND
Fluorene ug/kg 14701950 75 19-130ND
Hexachloro-1,3-butadiene ug/kg 11701950 60 12-130ND
Hexachlorobenzene ug/kg 15301950 79 17-130ND
Hexachlorocyclopentadiene ug/kg 10501950 54 10-130ND
Hexachloroethane ug/kg 13201950 67 14-130ND
Indeno(1,2,3-cd)pyrene ug/kg 15501950 79 13-130ND
Isophorone ug/kg 15501950 80 17-130ND
N-Nitroso-di-n-propylamine ug/kg 15701950 81 10-130ND
N-Nitrosodimethylamine ug/kg 13301950 68 16-130ND
N-Nitrosodiphenylamine ug/kg 16201950 83 19-130ND
Naphthalene ug/kg 13801950 71 18-130ND
Nitrobenzene ug/kg 14401950 74 15-130ND
Pentachlorophenol ug/kg 32603900 84 10-130ND
REPORT OF LABORATORY ANALYSIS
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Page 46 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3854966MATRIX SPIKE SAMPLE:
MSSpike
Result
92639042001
Phenanthrene ug/kg 15601950 80 17-130ND
Phenol ug/kg 15701950 81 15-130ND
Pyrene ug/kg 16901950 87 31-130ND
Pyridine ug/kg 6411950 33 10-130ND
2,4,6-Tribromophenol (S)%77 10-131
2-Fluorobiphenyl (S)%55 10-130
2-Fluorophenol (S)%64 10-130
Nitrobenzene-d5 (S)%64 10-130
Phenol-d6 (S)%67 10-130
Terphenyl-d14 (S)%74 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92639042003
3854967SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,3-Dichlorobenzene ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
1-Methylnaphthalene ug/kg ND 30ND
2,2'-Oxybis(1-chloropropane)ug/kg ND 30ND
2,4,5-Trichlorophenol ug/kg ND 30ND
2,4,6-Trichlorophenol ug/kg ND 30ND
2,4-Dichlorophenol ug/kg ND 30ND
2,4-Dimethylphenol ug/kg ND 30ND
2,4-Dinitrophenol ug/kg ND 30ND
2,4-Dinitrotoluene ug/kg ND 30ND
2,6-Dinitrotoluene ug/kg ND 30ND
2-Chloronaphthalene ug/kg ND 30ND
2-Chlorophenol ug/kg ND 30ND
2-Methylnaphthalene ug/kg ND 30ND
2-Methylphenol(o-Cresol)ug/kg ND 30ND
2-Nitroaniline ug/kg ND 30ND
2-Nitrophenol ug/kg ND 30ND
3&4-Methylphenol(m&p Cresol)ug/kg ND 30ND
3,3'-Dichlorobenzidine ug/kg ND 30ND
3-Nitroaniline ug/kg ND 30ND
4,6-Dinitro-2-methylphenol ug/kg ND 30ND
4-Bromophenylphenyl ether ug/kg ND 30ND
4-Chloro-3-methylphenol ug/kg ND 30ND
4-Chloroaniline ug/kg ND 30ND
4-Chlorophenylphenyl ether ug/kg ND 30ND
4-Nitroaniline ug/kg ND 30ND
4-Nitrophenol ug/kg ND 30ND
Acenaphthene ug/kg ND 30ND
Acenaphthylene ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 47 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92639042003
3854967SAMPLE DUPLICATE:
Aniline ug/kg ND 30ND
Anthracene ug/kg ND 30ND
Benzo(a)anthracene ug/kg ND 30ND
Benzo(a)pyrene ug/kg ND 30ND
Benzo(b)fluoranthene ug/kg ND 30ND
Benzo(g,h,i)perylene ug/kg ND 30ND
Benzo(k)fluoranthene ug/kg ND 30ND
Benzoic Acid ug/kg ND 30ND
Benzyl alcohol ug/kg ND 30ND
bis(2-Chloroethoxy)methane ug/kg ND 30ND
bis(2-Chloroethyl) ether ug/kg ND 30ND
bis(2-Ethylhexyl)phthalate ug/kg ND 30ND
Butylbenzylphthalate ug/kg ND 30ND
Chrysene ug/kg ND 30ND
Di-n-butylphthalate ug/kg ND 30ND
Di-n-octylphthalate ug/kg ND 30ND
Dibenz(a,h)anthracene ug/kg ND 30ND
Dibenzofuran ug/kg ND 30ND
Diethylphthalate ug/kg ND 30ND
Dimethylphthalate ug/kg ND 30ND
Fluoranthene ug/kg ND 30ND
Fluorene ug/kg ND 30ND
Hexachloro-1,3-butadiene ug/kg ND 30ND
Hexachlorobenzene ug/kg ND 30ND
Hexachlorocyclopentadiene ug/kg ND 30ND
Hexachloroethane ug/kg ND 30ND
Indeno(1,2,3-cd)pyrene ug/kg ND 30ND
Isophorone ug/kg ND 30ND
N-Nitroso-di-n-propylamine ug/kg ND 30ND
N-Nitrosodimethylamine ug/kg ND 30ND
N-Nitrosodiphenylamine ug/kg ND 30ND
Naphthalene ug/kg ND 30ND
Nitrobenzene ug/kg ND 30ND
Pentachlorophenol ug/kg ND 30ND
Phenanthrene ug/kg ND 30ND
Phenol ug/kg ND 30ND
Pyrene ug/kg ND 30ND
Pyridine ug/kg ND 30ND
2,4,6-Tribromophenol (S)%6759
2-Fluorobiphenyl (S)%4842
2-Fluorophenol (S)%6766
Nitrobenzene-d5 (S)%6562
Phenol-d6 (S)%6967
Terphenyl-d14 (S)%6960
REPORT OF LABORATORY ANALYSIS
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Page 48 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
741030
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3854951
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
Aliphatic (C09-C18)mg/kg ND 9.9 N212/06/22 09:009.9
Aliphatic (C19-C36)mg/kg ND 9.9 N212/06/22 09:009.9
Aromatic (C11-C22)mg/kg ND 9.9 N212/06/22 09:009.9
1-Chlorooctadecane (S)%80 40-140 12/06/22 09:00
2-Bromonaphthalene (S)%122 40-140 12/06/22 09:00
2-Fluorobiphenyl (S)%112 40-140 12/06/22 09:00
o-Terphenyl (S)%94 40-140 12/06/22 09:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3854952LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3854953
Aliphatic (C09-C18)mg/kg ND N2106240-14059ND 50
Aliphatic (C19-C36)mg/kg 12.1 N213.4 91 40-1408611.3 7 50
Aromatic (C11-C22)mg/kg 24.3 N228.4 85 40-1408122.6 7 50
1-Chlorooctadecane (S)%87 40-14082
2-Bromonaphthalene (S)%112 40-140104
2-Fluorobiphenyl (S)%106 40-14099
o-Terphenyl (S)%90 40-14084
REPORT OF LABORATORY ANALYSIS
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Page 49 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
740555
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92638144001
3852788SAMPLE DUPLICATE:
Percent Moisture %33.3 N2152538.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92639042004
3852789SAMPLE DUPLICATE:
Percent Moisture %12.8 N242512.3
REPORT OF LABORATORY ANALYSIS
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Page 50 of 56
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1968717
SM 2540 G
SM 2540G
Total Solids 2540 G-2011
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3868697-1
Associated Lab Samples:92639042001, 92639042002, 92639042003, 92639042004
Matrix:Solid
AnalyzedMDL
Total Solids %0.00200 12/05/22 15:43
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3868697-2LABORATORY CONTROL SAMPLE:
LCSSpike
Total Solids %50.050.0 100 85.0-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92639042003
R3868697-3SAMPLE DUPLICATE:
Total Solids %86.7 0.815 1086.0
REPORT OF LABORATORY ANALYSIS
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Page 51 of 56
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.IK
Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs.J
Matrix spike recovery and/or matrix spike duplicate recovery was below laboratory control limits. Result may be biased
low.ML
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5
Data does not meet all conditions for compliance monitoring due to use of soil jars.u8
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.v2
The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.v3
REPORT OF LABORATORY ANALYSIS
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Page 52 of 56
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92639042
WOOTEN DIESEL FUEL SPILL HWY53
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92639042001 741030 741285EASTMADEP EPH MADEP EPH
92639042002 741030 741285NORTHMADEP EPH MADEP EPH
92639042003 741030 741285SOUTHMADEP EPH MADEP EPH
92639042004 741030 741285WESTMADEP EPH MADEP EPH
92639042001 1969685 1969685EASTMADEPVMADEP VPH
92639042002 1969685 1969685NORTHMADEPVMADEP VPH
92639042003 1969685 1969685SOUTHMADEPVMADEP VPH
92639042004 1969685 1969685WESTMADEPVMADEP VPH
92639042001 741034 741269EASTEPA 3546 EPA 8270E
92639042002 741034 741269NORTHEPA 3546 EPA 8270E
92639042003 741034 741269SOUTHEPA 3546 EPA 8270E
92639042004 741034 741269WESTEPA 3546 EPA 8270E
92639042001 740295 740317EASTEPA 5035A/5030B EPA 8260D
92639042002 740648 740816NORTHEPA 5035A/5030B EPA 8260D
92639042003 740295 740317SOUTHEPA 5035A/5030B EPA 8260D
92639042004 740295 740317WESTEPA 5035A/5030B EPA 8260D
92639042001 740555EASTSW-846
92639042002 740555NORTHSW-846
92639042003 740555SOUTHSW-846
92639042004 740555WESTSW-846
92639042001 1968717 1968717EASTSM 2540 G SM 2540G
92639042002 1968717 1968717NORTHSM 2540 G SM 2540G
92639042003 1968717 1968717SOUTHSM 2540 G SM 2540G
92639042004 1968717 1968717WESTSM 2540 G SM 2540G
REPORT OF LABORATORY ANALYSIS
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Page 53 of 56
Page 54 of 56
Page 55 of 56
Page 56 of 56
#=CL#
January 16, 2023
LIMS USE: FR - BEN ASHBA
LIMS OBJECT ID: 92644826
92644826
Project:
Pace Project No.:
RE:
Ben Ashba
CATLIN Engineers & Scientists, Inc.
220 Old Dairy Road
Wilmington, NC 28405
QUALITY TURF DIESEL FUEL SPILL
Dear Ben Ashba:
Enclosed are the analytical results for sample(s) received by the laboratory on January 03, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Bonnie Vang
[e-mail]
Project Manager
[phone]
Enclosures
cc:Matthew Ginther, Catlin Engineers and Scientists
REPORT OF LABORATORY ANALYSIS
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Page 1 of 38
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 2 of 38
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Lab ID Sample ID Matrix Date Collected Date Received
92644826001 MW-01 Water 01/03/23 12:05 01/03/23 16:20
REPORT OF LABORATORY ANALYSIS
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Page 3 of 38
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92644826001 MW-01 MADEP EPH 7 PASI-CBAJ
EPA 625.1 58 PASI-CPKS
SM 6200B 63 PASI-CLMB
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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Page 4 of 38
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92644826001 MW-01
Benzene 3.2 ug/L 01/07/23 11:470.50SM 6200B
Ethylbenzene 7.8 ug/L 01/07/23 11:470.50SM 6200B
Isopropylbenzene (Cumene)1.3 ug/L 01/07/23 11:470.50SM 6200B
Naphthalene 1.4J ug/L 01/07/23 11:472.0SM 6200B
n-Propylbenzene 2.2 ug/L 01/07/23 11:470.50SM 6200B
Toluene 0.72 ug/L 01/07/23 11:470.50SM 6200B
1,2,4-Trimethylbenzene 16.1 ug/L 01/07/23 11:470.50SM 6200B
1,3,5-Trimethylbenzene 5.8 ug/L 01/07/23 11:470.50SM 6200B
m&p-Xylene 13.5 ug/L 01/07/23 11:471.0SM 6200B
o-Xylene 25.2 ug/L 01/07/23 11:470.50SM 6200B
REPORT OF LABORATORY ANALYSIS
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Page 5 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Sample:MW-01 Lab ID:92644826001 Collected:01/03/23 12:05 Received:01/03/23 16:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Water
Aliphatic (C09-C18)ND ug/L 01/09/23 13:47 N201/08/23 14:5597.1 97.1 1
Aliphatic (C19-C36)ND ug/L 01/09/23 13:47 N201/08/23 14:5597.1 97.1 1
Aromatic (C11-C22)ND ug/L 01/09/23 13:47 N201/08/23 14:5597.1 97.1 1
Surrogates
1-Chlorooctadecane (S)31 %01/09/23 13:47 3386-33-2 S201/08/23 14:5540-140 1
o-Terphenyl (S)65 %01/09/23 13:47 84-15-101/08/23 14:5540-140 1
2-Fluorobiphenyl (S)99 %01/09/23 13:47 321-60-801/08/23 14:5540-140 1
2-Bromonaphthalene (S)106 %01/09/23 13:47 580-13-201/08/23 14:5540-140 1
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Acenaphthene ND ug/L 01/09/23 21:49 83-32-901/09/23 12:534.2 1.7 1
Acenaphthylene ND ug/L 01/09/23 21:49 208-96-801/09/23 12:534.2 1.6 1
Anthracene ND ug/L 01/09/23 21:49 120-12-701/09/23 12:534.2 1.9 1
Benzo(a)anthracene ND ug/L 01/09/23 21:49 56-55-301/09/23 12:534.2 2.2 1
Benzo(a)pyrene ND ug/L 01/09/23 21:49 50-32-801/09/23 12:534.2 2.3 1
Benzo(b)fluoranthene ND ug/L 01/09/23 21:49 205-99-201/09/23 12:534.2 2.2 1
Benzo(g,h,i)perylene ND ug/L 01/09/23 21:49 191-24-201/09/23 12:534.2 2.4 1
Benzo(k)fluoranthene ND ug/L 01/09/23 21:49 207-08-901/09/23 12:534.2 2.3 1
4-Bromophenylphenyl ether ND ug/L 01/09/23 21:49 101-55-301/09/23 12:534.2 1.5 1
Butylbenzylphthalate ND ug/L 01/09/23 21:49 85-68-701/09/23 12:534.2 2.6 1
4-Chloro-3-methylphenol ND ug/L 01/09/23 21:49 59-50-701/09/23 12:534.2 2.8 1
bis(2-Chloroethoxy)methane ND ug/L 01/09/23 21:49 111-91-101/09/23 12:538.3 1.5 1
bis(2-Chloroethyl) ether ND ug/L 01/09/23 21:49 111-44-401/09/23 12:534.2 1.6 1
2-Chloronaphthalene ND ug/L 01/09/23 21:49 91-58-701/09/23 12:534.2 1.4 1
2-Chlorophenol ND ug/L 01/09/23 21:49 95-57-801/09/23 12:534.2 1.0 1
4-Chlorophenylphenyl ether ND ug/L 01/09/23 21:49 7005-72-301/09/23 12:534.2 1.7 1
Chrysene ND ug/L 01/09/23 21:49 218-01-901/09/23 12:534.2 2.3 1
Dibenz(a,h)anthracene ND ug/L 01/09/23 21:49 53-70-301/09/23 12:534.2 2.5 1
3,3'-Dichlorobenzidine ND ug/L 01/09/23 21:49 91-94-101/09/23 12:538.3 6.8 1
2,4-Dichlorophenol ND ug/L 01/09/23 21:49 120-83-201/09/23 12:534.2 1.2 1
Diethylphthalate ND ug/L 01/09/23 21:49 84-66-201/09/23 12:534.2 1.7 1
2,4-Dimethylphenol ND ug/L 01/09/23 21:49 105-67-901/09/23 12:538.3 1.4 1
Dimethylphthalate ND ug/L 01/09/23 21:49 131-11-301/09/23 12:534.2 1.8 1
Di-n-butylphthalate ND ug/L 01/09/23 21:49 84-74-201/09/23 12:534.2 1.8 1
4,6-Dinitro-2-methylphenol ND ug/L 01/09/23 21:49 534-52-101/09/23 12:538.3 6.5 1
2,4-Dinitrophenol ND ug/L 01/09/23 21:49 51-28-501/09/23 12:5341.7 21.7 1
2,4-Dinitrotoluene ND ug/L 01/09/23 21:49 121-14-201/09/23 12:534.2 1.4 1
2,6-Dinitrotoluene ND ug/L 01/09/23 21:49 606-20-201/09/23 12:534.2 1.4 1
Di-n-octylphthalate ND ug/L 01/09/23 21:49 117-84-001/09/23 12:534.2 3.3 1
bis(2-Ethylhexyl)phthalate ND ug/L 01/09/23 21:49 117-81-701/09/23 12:534.2 3.1 1
Fluoranthene ND ug/L 01/09/23 21:49 206-44-001/09/23 12:534.2 1.8 1
Fluorene ND ug/L 01/09/23 21:49 86-73-701/09/23 12:534.2 1.7 1
Hexachloro-1,3-butadiene ND ug/L 01/09/23 21:49 87-68-301/09/23 12:534.2 1.5 1
Hexachlorobenzene ND ug/L 01/09/23 21:49 118-74-101/09/23 12:534.2 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Sample:MW-01 Lab ID:92644826001 Collected:01/03/23 12:05 Received:01/03/23 16:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services - Charlotte
625 RVE
Hexachlorocyclopentadiene ND ug/L 01/09/23 21:49 77-47-401/09/23 12:538.3 1.3 1
Hexachloroethane ND ug/L 01/09/23 21:49 67-72-1 L201/09/23 12:534.2 1.2 1
Indeno(1,2,3-cd)pyrene ND ug/L 01/09/23 21:49 193-39-501/09/23 12:534.2 2.4 1
Isophorone ND ug/L 01/09/23 21:49 78-59-101/09/23 12:538.3 1.4 1
Naphthalene ND ug/L 01/09/23 21:49 91-20-301/09/23 12:534.2 1.7 1
Nitrobenzene ND ug/L 01/09/23 21:49 98-95-301/09/23 12:534.2 1.6 1
2-Nitrophenol ND ug/L 01/09/23 21:49 88-75-501/09/23 12:534.2 1.2 1
4-Nitrophenol ND ug/L 01/09/23 21:49 100-02-701/09/23 12:538.3 5.5 1
N-Nitrosodimethylamine ND ug/L 01/09/23 21:49 62-75-901/09/23 12:534.2 1.6 1
N-Nitroso-di-n-propylamine ND ug/L 01/09/23 21:49 621-64-701/09/23 12:534.2 1.1 1
N-Nitrosodiphenylamine ND ug/L 01/09/23 21:49 86-30-601/09/23 12:538.3 2.5 1
2,2'-Oxybis(1-chloropropane)ND ug/L 01/09/23 21:49 108-60-101/09/23 12:534.2 0.96 1
Pentachlorophenol ND ug/L 01/09/23 21:49 87-86-5 R101/09/23 12:538.3 3.1 1
Phenanthrene ND ug/L 01/09/23 21:49 85-01-801/09/23 12:534.2 1.7 1
Phenol ND ug/L 01/09/23 21:49 108-95-201/09/23 12:534.2 1.1 1
Pyrene ND ug/L 01/09/23 21:49 129-00-0 L101/09/23 12:534.2 1.8 1
1,2,4-Trichlorobenzene ND ug/L 01/09/23 21:49 120-82-101/09/23 12:534.2 1.4 1
2,4,6-Trichlorophenol ND ug/L 01/09/23 21:49 88-06-201/09/23 12:538.3 1.3 1
Surrogates
Nitrobenzene-d5 (S)61 %01/09/23 21:49 4165-60-001/09/23 12:5310-120 1
2-Fluorobiphenyl (S)66 %01/09/23 21:49 321-60-801/09/23 12:5315-120 1
Terphenyl-d14 (S)92 %01/09/23 21:49 1718-51-001/09/23 12:5311-131 1
Phenol-d6 (S)36 %01/09/23 21:49 13127-88-301/09/23 12:5310-120 1
2-Fluorophenol (S)33 %01/09/23 21:49 367-12-401/09/23 12:5310-120 1
2,4,6-Tribromophenol (S)68 %01/09/23 21:49 118-79-601/09/23 12:5310-137 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 3.2 ug/L 01/07/23 11:47 71-43-20.50 0.34 1
Bromobenzene ND ug/L 01/07/23 11:47 108-86-10.50 0.29 1
Bromochloromethane ND ug/L 01/07/23 11:47 74-97-50.50 0.47 1
Bromodichloromethane ND ug/L 01/07/23 11:47 75-27-40.50 0.31 1
Bromoform ND ug/L 01/07/23 11:47 75-25-20.50 0.34 1
Bromomethane ND ug/L 01/07/23 11:47 74-83-95.0 1.7 1
n-Butylbenzene ND ug/L 01/07/23 11:47 104-51-80.50 0.49 1
sec-Butylbenzene ND ug/L 01/07/23 11:47 135-98-80.50 0.40 1
tert-Butylbenzene ND ug/L 01/07/23 11:47 98-06-60.50 0.32 1
Carbon tetrachloride ND ug/L 01/07/23 11:47 56-23-50.50 0.33 1
Chlorobenzene ND ug/L 01/07/23 11:47 108-90-70.50 0.28 1
Chloroethane ND ug/L 01/07/23 11:47 75-00-31.0 0.65 1
Chloroform ND ug/L 01/07/23 11:47 67-66-30.50 0.43 1
Chloromethane ND ug/L 01/07/23 11:47 74-87-31.0 0.54 1
2-Chlorotoluene ND ug/L 01/07/23 11:47 95-49-80.50 0.32 1
4-Chlorotoluene ND ug/L 01/07/23 11:47 106-43-40.50 0.32 1
1,2-Dibromo-3-chloropropane ND ug/L 01/07/23 11:47 96-12-81.0 0.34 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 7 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Sample:MW-01 Lab ID:92644826001 Collected:01/03/23 12:05 Received:01/03/23 16:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Dibromochloromethane ND ug/L 01/07/23 11:47 124-48-10.50 0.36 1
1,2-Dibromoethane (EDB)ND ug/L 01/07/23 11:47 106-93-40.50 0.27 1
Dibromomethane ND ug/L 01/07/23 11:47 74-95-30.50 0.39 1
1,2-Dichlorobenzene ND ug/L 01/07/23 11:47 95-50-10.50 0.34 1
1,3-Dichlorobenzene ND ug/L 01/07/23 11:47 541-73-10.50 0.34 1
1,4-Dichlorobenzene ND ug/L 01/07/23 11:47 106-46-70.50 0.33 1
Dichlorodifluoromethane ND ug/L 01/07/23 11:47 75-71-80.50 0.35 1
1,1-Dichloroethane ND ug/L 01/07/23 11:47 75-34-30.50 0.37 1
1,2-Dichloroethane ND ug/L 01/07/23 11:47 107-06-20.50 0.32 1
1,1-Dichloroethene ND ug/L 01/07/23 11:47 75-35-40.50 0.35 1
cis-1,2-Dichloroethene ND ug/L 01/07/23 11:47 156-59-20.50 0.38 1
trans-1,2-Dichloroethene ND ug/L 01/07/23 11:47 156-60-50.50 0.40 1
1,2-Dichloropropane ND ug/L 01/07/23 11:47 78-87-50.50 0.36 1
1,3-Dichloropropane ND ug/L 01/07/23 11:47 142-28-90.50 0.28 1
2,2-Dichloropropane ND ug/L 01/07/23 11:47 594-20-70.50 0.39 1
1,1-Dichloropropene ND ug/L 01/07/23 11:47 563-58-60.50 0.43 1
cis-1,3-Dichloropropene ND ug/L 01/07/23 11:47 10061-01-50.50 0.36 1
trans-1,3-Dichloropropene ND ug/L 01/07/23 11:47 10061-02-60.50 0.36 1
Diisopropyl ether ND ug/L 01/07/23 11:47 108-20-30.50 0.31 1
Ethylbenzene 7.8 ug/L 01/07/23 11:47 100-41-40.50 0.30 1
Hexachloro-1,3-butadiene ND ug/L 01/07/23 11:47 87-68-32.0 1.5 1
Isopropylbenzene (Cumene)1.3 ug/L 01/07/23 11:47 98-82-80.50 0.33 1
Methylene Chloride ND ug/L 01/07/23 11:47 75-09-22.0 2.0 1
Methyl-tert-butyl ether ND ug/L 01/07/23 11:47 1634-04-40.50 0.42 1
Naphthalene 1.4J ug/L 01/07/23 11:47 91-20-32.0 0.64 1
n-Propylbenzene 2.2 ug/L 01/07/23 11:47 103-65-10.50 0.34 1
Styrene ND ug/L 01/07/23 11:47 100-42-50.50 0.29 1
1,1,1,2-Tetrachloroethane ND ug/L 01/07/23 11:47 630-20-60.50 0.31 1
1,1,2,2-Tetrachloroethane ND ug/L 01/07/23 11:47 79-34-50.50 0.22 1
Tetrachloroethene ND ug/L 01/07/23 11:47 127-18-40.50 0.29 1
Toluene 0.72 ug/L 01/07/23 11:47 108-88-30.50 0.24 1
1,2,3-Trichlorobenzene ND ug/L 01/07/23 11:47 87-61-62.0 0.81 1
1,2,4-Trichlorobenzene ND ug/L 01/07/23 11:47 120-82-12.0 0.64 1
1,1,1-Trichloroethane ND ug/L 01/07/23 11:47 71-55-60.50 0.33 1
1,1,2-Trichloroethane ND ug/L 01/07/23 11:47 79-00-50.50 0.32 1
Trichloroethene ND ug/L 01/07/23 11:47 79-01-60.50 0.38 1
Trichlorofluoromethane ND ug/L 01/07/23 11:47 75-69-41.0 0.30 1
1,2,3-Trichloropropane ND ug/L 01/07/23 11:47 96-18-40.50 0.26 1
1,2,4-Trimethylbenzene 16.1 ug/L 01/07/23 11:47 95-63-60.50 0.50 1
1,3,5-Trimethylbenzene 5.8 ug/L 01/07/23 11:47 108-67-80.50 0.33 1
Vinyl chloride ND ug/L 01/07/23 11:47 75-01-41.0 0.39 1
m&p-Xylene 13.5 ug/L 01/07/23 11:47 179601-23-11.0 0.71 1
o-Xylene 25.2 ug/L 01/07/23 11:47 95-47-60.50 0.34 1
Surrogates
1,2-Dichloroethane-d4 (S)99 %01/07/23 11:47 17060-07-070-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 38
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Sample:MW-01 Lab ID:92644826001 Collected:01/03/23 12:05 Received:01/03/23 16:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Surrogates
4-Bromofluorobenzene (S)103 %01/07/23 11:47 460-00-470-130 1
Toluene-d8 (S)106 %01/07/23 11:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
747893
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92644826001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888315
Associated Lab Samples:92644826001
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/07/23 10:540.31
1,1,1-Trichloroethane ug/L ND 0.50 01/07/23 10:540.33
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/07/23 10:540.22
1,1,2-Trichloroethane ug/L ND 0.50 01/07/23 10:540.32
1,1-Dichloroethane ug/L ND 0.50 01/07/23 10:540.37
1,1-Dichloroethene ug/L ND 0.50 01/07/23 10:540.35
1,1-Dichloropropene ug/L ND 0.50 01/07/23 10:540.43
1,2,3-Trichlorobenzene ug/L ND 2.0 01/07/23 10:540.81
1,2,3-Trichloropropane ug/L ND 0.50 01/07/23 10:540.26
1,2,4-Trichlorobenzene ug/L ND 2.0 01/07/23 10:540.64
1,2,4-Trimethylbenzene ug/L ND 0.50 01/07/23 10:540.50
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/07/23 10:540.34
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/07/23 10:540.27
1,2-Dichlorobenzene ug/L ND 0.50 01/07/23 10:540.34
1,2-Dichloroethane ug/L ND 0.50 01/07/23 10:540.32
1,2-Dichloropropane ug/L ND 0.50 01/07/23 10:540.36
1,3,5-Trimethylbenzene ug/L ND 0.50 01/07/23 10:540.33
1,3-Dichlorobenzene ug/L ND 0.50 01/07/23 10:540.34
1,3-Dichloropropane ug/L ND 0.50 01/07/23 10:540.28
1,4-Dichlorobenzene ug/L ND 0.50 01/07/23 10:540.33
2,2-Dichloropropane ug/L ND 0.50 01/07/23 10:540.39
2-Chlorotoluene ug/L ND 0.50 01/07/23 10:540.32
4-Chlorotoluene ug/L ND 0.50 01/07/23 10:540.32
Benzene ug/L ND 0.50 01/07/23 10:540.34
Bromobenzene ug/L ND 0.50 01/07/23 10:540.29
Bromochloromethane ug/L ND 0.50 01/07/23 10:540.47
Bromodichloromethane ug/L ND 0.50 01/07/23 10:540.31
Bromoform ug/L ND 0.50 01/07/23 10:540.34
Bromomethane ug/L ND 5.0 01/07/23 10:541.7
Carbon tetrachloride ug/L ND 0.50 01/07/23 10:540.33
Chlorobenzene ug/L ND 0.50 01/07/23 10:540.28
Chloroethane ug/L ND 1.0 01/07/23 10:540.65
Chloroform ug/L ND 0.50 01/07/23 10:540.43
Chloromethane ug/L ND 1.0 01/07/23 10:540.54
cis-1,2-Dichloroethene ug/L ND 0.50 01/07/23 10:540.38
cis-1,3-Dichloropropene ug/L ND 0.50 01/07/23 10:540.36
Dibromochloromethane ug/L ND 0.50 01/07/23 10:540.36
Dibromomethane ug/L ND 0.50 01/07/23 10:540.39
Dichlorodifluoromethane ug/L ND 0.50 01/07/23 10:540.35
Diisopropyl ether ug/L ND 0.50 01/07/23 10:540.31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888315
Associated Lab Samples:92644826001
Matrix:Water
AnalyzedMDL
Ethylbenzene ug/L ND 0.50 01/07/23 10:540.30
Hexachloro-1,3-butadiene ug/L ND 2.0 01/07/23 10:541.5
Isopropylbenzene (Cumene)ug/L ND 0.50 01/07/23 10:540.33
m&p-Xylene ug/L ND 1.0 01/07/23 10:540.71
Methyl-tert-butyl ether ug/L ND 0.50 01/07/23 10:540.42
Methylene Chloride ug/L ND 2.0 01/07/23 10:542.0
n-Butylbenzene ug/L ND 0.50 01/07/23 10:540.49
n-Propylbenzene ug/L ND 0.50 01/07/23 10:540.34
Naphthalene ug/L ND 2.0 01/07/23 10:540.64
o-Xylene ug/L ND 0.50 01/07/23 10:540.34
sec-Butylbenzene ug/L ND 0.50 01/07/23 10:540.40
Styrene ug/L ND 0.50 01/07/23 10:540.29
tert-Butylbenzene ug/L ND 0.50 01/07/23 10:540.32
Tetrachloroethene ug/L ND 0.50 01/07/23 10:540.29
Toluene ug/L ND 0.50 01/07/23 10:540.24
trans-1,2-Dichloroethene ug/L ND 0.50 01/07/23 10:540.40
trans-1,3-Dichloropropene ug/L ND 0.50 01/07/23 10:540.36
Trichloroethene ug/L ND 0.50 01/07/23 10:540.38
Trichlorofluoromethane ug/L ND 1.0 01/07/23 10:540.30
Vinyl chloride ug/L ND 1.0 01/07/23 10:540.39
1,2-Dichloroethane-d4 (S)%98 70-130 01/07/23 10:54
4-Bromofluorobenzene (S)%103 70-130 01/07/23 10:54
Toluene-d8 (S)%108 70-130 01/07/23 10:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888316LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 45.950 92 60-140
1,1,1-Trichloroethane ug/L 50.850 102 60-140
1,1,2,2-Tetrachloroethane ug/L 46.550 93 60-140
1,1,2-Trichloroethane ug/L 50.050 100 60-140
1,1-Dichloroethane ug/L 51.150 102 60-140
1,1-Dichloroethene ug/L 52.350 105 60-140
1,1-Dichloropropene ug/L 55.150 110 60-140
1,2,3-Trichlorobenzene ug/L 43.350 87 60-140
1,2,3-Trichloropropane ug/L 46.750 93 60-140
1,2,4-Trichlorobenzene ug/L 42.850 86 60-140
1,2,4-Trimethylbenzene ug/L 44.050 88 60-140
1,2-Dibromo-3-chloropropane ug/L 45.250 90 60-140
1,2-Dibromoethane (EDB)ug/L 47.250 94 60-140
1,2-Dichlorobenzene ug/L 43.650 87 60-140
1,2-Dichloroethane ug/L 51.450 103 60-140
1,2-Dichloropropane ug/L 51.950 104 60-140
1,3,5-Trimethylbenzene ug/L 44.350 89 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888316LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 42.850 86 60-140
1,3-Dichloropropane ug/L 47.450 95 60-140
1,4-Dichlorobenzene ug/L 42.150 84 60-140
2,2-Dichloropropane ug/L 43.850 88 60-140
2-Chlorotoluene ug/L 42.650 85 60-140
4-Chlorotoluene ug/L 43.350 87 60-140
Benzene ug/L 47.450 95 60-140
Bromobenzene ug/L 43.050 86 60-140
Bromochloromethane ug/L 49.450 99 60-140
Bromodichloromethane ug/L 48.850 98 60-140
Bromoform ug/L 45.350 91 60-140
Bromomethane ug/L 36.150 72 60-140
Carbon tetrachloride ug/L 46.550 93 60-140
Chlorobenzene ug/L 44.450 89 60-140
Chloroethane ug/L 59.450 119 60-140
Chloroform ug/L 49.250 98 60-140
Chloromethane ug/L 56.250 112 60-140
cis-1,2-Dichloroethene ug/L 52.050 104 60-140
cis-1,3-Dichloropropene ug/L 50.450 101 60-140
Dibromochloromethane ug/L 47.150 94 60-140
Dibromomethane ug/L 47.950 96 60-140
Dichlorodifluoromethane ug/L 49.650 99 60-140
Diisopropyl ether ug/L 54.050 108 60-140
Ethylbenzene ug/L 43.850 88 60-140
Hexachloro-1,3-butadiene ug/L 38.150 76 60-140
Isopropylbenzene (Cumene)ug/L 42.550 85 60-140
m&p-Xylene ug/L 87.1100 87 60-140
Methyl-tert-butyl ether ug/L 48.550 97 60-140
Methylene Chloride ug/L 51.550 103 60-140
n-Butylbenzene ug/L 42.050 84 60-140
n-Propylbenzene ug/L 42.050 84 60-140
Naphthalene ug/L 45.250 90 60-140
o-Xylene ug/L 42.950 86 60-140
sec-Butylbenzene ug/L 42.150 84 60-140
Styrene ug/L 45.350 91 60-140
tert-Butylbenzene ug/L 35.550 71 60-140
Tetrachloroethene ug/L 41.550 83 60-140
Toluene ug/L 45.650 91 60-140
trans-1,2-Dichloroethene ug/L 52.850 106 60-140
trans-1,3-Dichloropropene ug/L 50.050 100 60-140
Trichloroethene ug/L 49.250 98 60-140
Trichlorofluoromethane ug/L 46.750 93 60-140
Vinyl chloride ug/L 51.650 103 60-140
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3888317MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92644623001
3888318
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 109 60-140108 0 3020ND21.8 21.7
1,1,1-Trichloroethane ug/L 20 105 60-140103 2 3020ND21.1 20.6
1,1,2,2-Tetrachloroethane ug/L 20 110 60-140108 2 3020ND22.0 21.6
1,1,2-Trichloroethane ug/L 20 106 60-140105 1 3020ND21.1 20.9
1,1-Dichloroethane ug/L 20 110 60-140105 5 3020ND21.9 20.9
1,1-Dichloroethene ug/L 20 112 60-140108 3 3020ND22.3 21.6
1,1-Dichloropropene ug/L 20 111 60-140109 1 3020ND22.1 21.8
1,2,3-Trichlorobenzene ug/L 20 101 60-14096 5 3020ND20.3 19.2
1,2,3-Trichloropropane ug/L 20 111 60-140111 0 3020ND22.2 22.2
1,2,4-Trichlorobenzene ug/L 20 99 60-14095 4 3020ND19.8 19.0
1,2,4-Trimethylbenzene ug/L 20 101 60-14098 4 3020ND20.3 19.6
1,2-Dibromo-3-
chloropropane ug/L 20 100 60-140103 3 3020ND19.9 20.6
1,2-Dibromoethane (EDB)ug/L 20 109 60-140106 3 3020ND21.8 21.2
1,2-Dichlorobenzene ug/L 20 105 60-140102 3 3020ND20.9 20.4
1,2-Dichloroethane ug/L 20 103 60-140100 3 3020ND20.6 20.0
1,2-Dichloropropane ug/L 20 114 60-140109 4 3020ND22.7 21.8
1,3,5-Trimethylbenzene ug/L 20 101 60-140100 1 3020ND20.2 20.0
1,3-Dichlorobenzene ug/L 20 103 60-140102 2 3020ND20.7 20.4
1,3-Dichloropropane ug/L 20 112 60-140108 3 3020ND22.4 21.6
1,4-Dichlorobenzene ug/L 20 102 60-140100 2 3020ND20.4 20.0
2,2-Dichloropropane ug/L 20 100 60-14096 4 3020ND20.0 19.2
2-Chlorotoluene ug/L 20 105 60-140104 1 3020ND20.9 20.8
4-Chlorotoluene ug/L 20 104 60-140103 1 3020ND20.9 20.7
Benzene ug/L 20 105 60-140102 3 3020ND20.9 20.4
Bromobenzene ug/L 20 103 60-140104 1 3020ND20.6 20.8
Bromochloromethane ug/L 20 106 60-140103 3 3020ND21.2 20.6
Bromodichloromethane ug/L 20 104 60-140102 3 3020ND20.9 20.3
Bromoform ug/L 20 101 60-140100 2 3020ND20.2 19.9
Bromomethane ug/L 20 72 60-14069 5 3020ND14.4 13.7
Carbon tetrachloride ug/L 20 103 60-140103 1 3020ND20.6 20.5
Chlorobenzene ug/L 20 109 60-140108 1 3020ND21.7 21.6
Chloroethane ug/L 20 126 60-140121 4 3020ND25.3 24.3
Chloroform ug/L 20 102 60-140100 2 3020ND20.4 20.0
Chloromethane ug/L 20 113 60-140109 3 3020ND22.5 21.8
cis-1,2-Dichloroethene ug/L 20 108 60-140104 4 3020ND21.7 20.8
cis-1,3-Dichloropropene ug/L 20 104 60-140103 1 3020ND20.8 20.7
Dibromochloromethane ug/L 20 107 60-140103 4 3020ND21.3 20.6
Dibromomethane ug/L 20 105 60-140102 2 3020ND20.9 20.4
Dichlorodifluoromethane ug/L 20 87 60-14083 4 3020ND17.3 16.7
Diisopropyl ether ug/L 20 106 60-140103 3 3020ND21.2 20.7
Ethylbenzene ug/L 20 108 60-140106 2 3020ND21.5 21.2
Hexachloro-1,3-butadiene ug/L 20 96 60-14099 4 3020ND19.1 19.9
Isopropylbenzene(Cumene)ug/L 20 103 60-140103 0 3020ND20.7 20.7
m&p-Xylene ug/L 40 105 60-140104 2 3040ND42.1 41.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3888317MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92644623001
3888318
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Methyl-tert-butyl ether ug/L 20 95 60-14092 4 3020ND19.1 18.4
Methylene Chloride ug/L 20 104 60-140100 5 3020ND20.8 19.9
n-Butylbenzene ug/L 20 102 60-140104 2 3020ND20.4 20.7
n-Propylbenzene ug/L 20 103 60-140104 1 3020ND20.6 20.8
Naphthalene ug/L 20 107 60-140103 4 3020ND21.4 20.6
o-Xylene ug/L 20 106 60-140105 1 3020ND21.2 21.0
sec-Butylbenzene ug/L 20 105 60-140105 0 3020ND21.0 21.0
Styrene ug/L 20 106 60-140106 0 3020ND21.2 21.2
tert-Butylbenzene ug/L 20 89 60-14088 1 3020ND17.9 17.7
Tetrachloroethene ug/L 20 99 60-140103 4 3020ND19.8 20.5
Toluene ug/L 20 102 60-140102 0 3020ND20.4 20.5
trans-1,2-Dichloroethene ug/L 20 110 60-140106 4 3020ND22.0 21.2
trans-1,3-Dichloropropene ug/L 20 104 60-140102 1 3020ND20.8 20.5
Trichloroethene ug/L 20 106 60-140106 1 3020ND21.2 21.1
Trichlorofluoromethane ug/L 20 94 60-14092 2 3020ND18.8 18.3
Vinyl chloride ug/L 20 108 60-140104 3 3020ND21.6 20.9
1,2-Dichloroethane-d4 (S)%100 70-13093
4-Bromofluorobenzene (S)%99 70-13099
Toluene-d8 (S)%98 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
748071
EPA 625.1
EPA 625.1
625 MSS
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92644826001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888943
Associated Lab Samples:92644826001
Matrix:Water
AnalyzedMDL
1,2,4-Trichlorobenzene ug/L ND 5.0 01/09/23 16:171.7
2,2'-Oxybis(1-chloropropane)ug/L ND 5.0 01/09/23 16:171.2
2,4,6-Trichlorophenol ug/L ND 10.0 01/09/23 16:171.6
2,4-Dichlorophenol ug/L ND 5.0 01/09/23 16:171.4
2,4-Dimethylphenol ug/L ND 10.0 01/09/23 16:171.7
2,4-Dinitrophenol ug/L ND 50.0 01/09/23 16:1726.0
2,4-Dinitrotoluene ug/L ND 5.0 01/09/23 16:171.6
2,6-Dinitrotoluene ug/L ND 5.0 01/09/23 16:171.7
2-Chloronaphthalene ug/L ND 5.0 01/09/23 16:171.7
2-Chlorophenol ug/L ND 5.0 01/09/23 16:171.2
2-Nitrophenol ug/L ND 5.0 01/09/23 16:171.4
3,3'-Dichlorobenzidine ug/L ND 10.0 01/09/23 16:178.1
4,6-Dinitro-2-methylphenol ug/L ND 10.0 01/09/23 16:177.8
4-Bromophenylphenyl ether ug/L ND 5.0 01/09/23 16:171.8
4-Chloro-3-methylphenol ug/L ND 5.0 01/09/23 16:173.3
4-Chlorophenylphenyl ether ug/L ND 5.0 01/09/23 16:172.0
4-Nitrophenol ug/L ND 10.0 01/09/23 16:176.6
Acenaphthene ug/L ND 5.0 01/09/23 16:172.0
Acenaphthylene ug/L ND 5.0 01/09/23 16:172.0
Anthracene ug/L ND 5.0 01/09/23 16:172.3
Benzo(a)anthracene ug/L ND 5.0 01/09/23 16:172.7
Benzo(a)pyrene ug/L ND 5.0 01/09/23 16:172.8
Benzo(b)fluoranthene ug/L ND 5.0 01/09/23 16:172.6
Benzo(g,h,i)perylene ug/L ND 5.0 01/09/23 16:172.8
Benzo(k)fluoranthene ug/L ND 5.0 01/09/23 16:172.7
bis(2-Chloroethoxy)methane ug/L ND 10.0 01/09/23 16:171.8
bis(2-Chloroethyl) ether ug/L ND 5.0 01/09/23 16:171.9
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 01/09/23 16:173.7
Butylbenzylphthalate ug/L ND 5.0 01/09/23 16:173.1
Chrysene ug/L ND 5.0 01/09/23 16:172.8
Di-n-butylphthalate ug/L ND 5.0 01/09/23 16:172.2
Di-n-octylphthalate ug/L ND 5.0 01/09/23 16:173.9
Dibenz(a,h)anthracene ug/L ND 5.0 01/09/23 16:173.0
Diethylphthalate ug/L ND 5.0 01/09/23 16:172.0
Dimethylphthalate ug/L ND 5.0 01/09/23 16:172.1
Fluoranthene ug/L ND 5.0 01/09/23 16:172.2
Fluorene ug/L ND 5.0 01/09/23 16:172.1
Hexachloro-1,3-butadiene ug/L ND 5.0 01/09/23 16:171.8
Hexachlorobenzene ug/L ND 5.0 01/09/23 16:172.2
Hexachlorocyclopentadiene ug/L ND 10.0 01/09/23 16:171.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888943
Associated Lab Samples:92644826001
Matrix:Water
AnalyzedMDL
Hexachloroethane ug/L ND 5.0 01/09/23 16:171.4
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 01/09/23 16:172.9
Isophorone ug/L ND 10.0 01/09/23 16:171.7
N-Nitroso-di-n-propylamine ug/L ND 5.0 01/09/23 16:171.3
N-Nitrosodimethylamine ug/L ND 5.0 01/09/23 16:171.9
N-Nitrosodiphenylamine ug/L ND 10.0 01/09/23 16:173.0
Naphthalene ug/L ND 5.0 01/09/23 16:172.1
Nitrobenzene ug/L ND 5.0 01/09/23 16:171.9
Pentachlorophenol ug/L ND 10.0 01/09/23 16:173.8
Phenanthrene ug/L ND 5.0 01/09/23 16:172.0
Phenol ug/L ND 5.0 01/09/23 16:171.4
Pyrene ug/L ND 5.0 01/09/23 16:172.2
2,4,6-Tribromophenol (S)%32 10-137 01/09/23 16:17
2-Fluorobiphenyl (S)%49 15-120 01/09/23 16:17
2-Fluorophenol (S)%21 10-120 01/09/23 16:17
Nitrobenzene-d5 (S)%78 10-120 01/09/23 16:17
Phenol-d6 (S)%40 10-120 01/09/23 16:17
Terphenyl-d14 (S)%133 11-131 S301/09/23 16:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888944LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/L 28.450 57 44-142
2,2'-Oxybis(1-chloropropane)ug/L 35.850 72 36-166
2,4,6-Trichlorophenol ug/L 53.050 106 37-144
2,4-Dichlorophenol ug/L 46.650 93 1-191
2,4-Dimethylphenol ug/L 56.650 113 32-119
2,4-Dinitrophenol ug/L 371250 149 1-181
2,4-Dinitrotoluene ug/L 62.750 125 39-139
2,6-Dinitrotoluene ug/L 62.050 124 50-158
2-Chloronaphthalene ug/L 48.250 96 60-118
2-Chlorophenol ug/L 40.650 81 23-134
2-Nitrophenol ug/L 48.050 96 29-182
3,3'-Dichlorobenzidine ug/L 101100 101 1-262
4,6-Dinitro-2-methylphenol ug/L 154100 154 1-181
4-Bromophenylphenyl ether ug/L 49.250 98 53-127
4-Chloro-3-methylphenol ug/L 100100 100 22-147
4-Chlorophenylphenyl ether ug/L 51.350 103 25-158
4-Nitrophenol ug/L 176250 71 1-132
Acenaphthene ug/L 49.850 100 47-145
Acenaphthylene ug/L 50.150 100 33-145
Anthracene ug/L 51.050 102 1-166
Benzo(a)anthracene ug/L 56.050 112 33-143
Benzo(a)pyrene ug/L 58.350 117 17-163
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888944LABORATORY CONTROL SAMPLE:
LCSSpike
Benzo(b)fluoranthene ug/L 57.950 116 24-159
Benzo(g,h,i)perylene ug/L 57.150 114 1-219
Benzo(k)fluoranthene ug/L 61.850 124 11-162
bis(2-Chloroethoxy)methane ug/L 47.650 95 33-184
bis(2-Chloroethyl) ether ug/L 42.050 84 12-158
bis(2-Ethylhexyl)phthalate ug/L 67.250 134 8-158
Butylbenzylphthalate ug/L 64.150 128 1-152
Chrysene ug/L 57.450 115 17-168
Di-n-butylphthalate ug/L 57.650 115 1-118
Di-n-octylphthalate ug/L 61.850 124 4-146
Dibenz(a,h)anthracene ug/L 57.850 116 1-227
Diethylphthalate ug/L 56.550 113 1-114
Dimethylphthalate ug/L 54.850 110 1-112
Fluoranthene ug/L 53.850 108 26-137
Fluorene ug/L 52.750 105 59-121
Hexachloro-1,3-butadiene ug/L 20.650 41 24-116
Hexachlorobenzene ug/L 47.050 94 1-152
Hexachlorocyclopentadiene ug/L 30.350 61 25-150
Hexachloroethane ug/L 16.3 L2503340-113
Indeno(1,2,3-cd)pyrene ug/L 56.950 114 1-171
Isophorone ug/L 48.950 98 21-196
N-Nitroso-di-n-propylamine ug/L 47.550 95 1-230
N-Nitrosodimethylamine ug/L 40.550 81 25-150
N-Nitrosodiphenylamine ug/L 53.850 108 25-150
Naphthalene ug/L 32.850 66 21-133
Nitrobenzene ug/L 44.250 88 35-180
Pentachlorophenol ug/L 123100 123 14-176
Phenanthrene ug/L 54.850 110 54-120
Phenol ug/L 29.750 59 5-112
Pyrene ug/L 58.4 L15011752-115
2,4,6-Tribromophenol (S)%112 10-137
2-Fluorobiphenyl (S)%86 15-120
2-Fluorophenol (S)%64 10-120
Nitrobenzene-d5 (S)%84 10-120
Phenol-d6 (S)%57 10-120
Terphenyl-d14 (S)%117 11-131
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3888977MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92644826001
3888978
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,2,4-Trichlorobenzene ug/L 41.7 58 44-14261 5 3041.7ND 24.3 25.5
2,2'-Oxybis(1-
chloropropane)ug/L 41.7 68 36-16666 3 3041.7ND 28.3 27.5
2,4,6-Trichlorophenol ug/L 41.7 49 37-14447 3 3041.7ND 20.2 19.7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3888977MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92644826001
3888978
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4-Dichlorophenol ug/L 41.7 65 1-19160 9 3041.7ND 27.3 24.9
2,4-Dimethylphenol ug/L 41.7 76 32-11970 8 3041.7ND 31.6 29.3
2,4-Dinitrophenol ug/L 208 5 1-1815 30208NDNDND
2,4-Dinitrotoluene ug/L 41.7 83 39-13971 16 3041.7ND 34.5 29.5
2,6-Dinitrotoluene ug/L 41.7 90 50-15879 14 3041.7ND 37.7 32.8
2-Chloronaphthalene ug/L 41.7 75 60-11869 8 3041.7ND 31.4 28.9
2-Chlorophenol ug/L 41.7 58 23-13455 5 3041.7ND 24.0 22.9
2-Nitrophenol ug/L 41.7 70 29-18267 5 3041.7ND 29.3 28.0
3,3'-Dichlorobenzidine ug/L 83.3 78 1-26279 1 3083.3ND 65.3 65.6
4,6-Dinitro-2-methylphenol ug/L 83.3 25 1-18127 8 3083.3ND 21.0 22.7
4-Bromophenylphenyl ether ug/L 41.7 74 53-12770 6 3041.7ND 31.0 29.1
4-Chloro-3-methylphenol ug/L 83.3 65 22-14758 11 3083.3ND 54.2 48.7
4-Chlorophenylphenyl ether ug/L 41.7 71 25-15863 12 3041.7ND 29.4 26.1
4-Nitrophenol ug/L 208 7 1-1329 21 30208ND15.3 18.9
Acenaphthene ug/L 41.7 76 47-14568 11 3041.7ND 31.5 28.2
Acenaphthylene ug/L 41.7 78 33-14570 11 3041.7ND 32.5 29.0
Anthracene ug/L 41.7 71 1-16665 9 3041.7ND 29.7 27.1
Benzo(a)anthracene ug/L 41.7 77 33-14375 3 3041.7ND 32.3 31.2
Benzo(a)pyrene ug/L 41.7 78 17-16371 9 3041.7ND 32.6 29.7
Benzo(b)fluoranthene ug/L 41.7 78 24-15972 8 3041.7ND 32.5 30.2
Benzo(g,h,i)perylene ug/L 41.7 85 1-21976 10 3041.7ND 35.4 31.8
Benzo(k)fluoranthene ug/L 41.7 79 11-16274 7 3041.7ND 32.9 30.8
bis(2-
Chloroethoxy)methane ug/L 41.7 63 33-18457 11 3041.7ND 26.4 23.6
bis(2-Chloroethyl) ether ug/L 41.7 58 12-15855 6 3041.7ND 24.2 22.9
bis(2-Ethylhexyl)phthalate ug/L 41.7 93 8-15891 3 3041.7ND 38.8 37.7
Butylbenzylphthalate ug/L 41.7 92 1-15291 1 3041.7ND 38.3 37.9
Chrysene ug/L 41.7 75 17-16876 2 3041.7ND 31.1 31.8
Di-n-butylphthalate ug/L 41.7 86 1-11881 5 3041.7ND 35.7 33.8
Di-n-octylphthalate ug/L 41.7 102 4-146103 1 3041.7ND 42.6 43.0
Dibenz(a,h)anthracene ug/L 41.7 83 1-22779 4 3041.7ND 34.4 33.0
Diethylphthalate ug/L 41.7 87 1-11472 19 3041.7ND 36.3 30.0
Dimethylphthalate ug/L 41.7 77 1-11266 14 3041.7ND 31.9 27.7
Fluoranthene ug/L 41.7 81 26-13774 9 3041.7ND 33.8 31.0
Fluorene ug/L 41.7 78 59-12167 14 3041.7ND 32.4 28.1
Hexachloro-1,3-butadiene ug/L 41.7 51 24-11656 8 3041.7ND 21.4 23.2
Hexachlorobenzene ug/L 41.7 78 1-15270 12 3041.7ND 32.6 29.0
Hexachlorocyclopentadiene ug/L 41.7 58 25-15056 4 3041.7ND 24.4 23.4
Hexachloroethane ug/L 41.7 45 40-11357 25 3041.7ND 18.6 23.8
Indeno(1,2,3-cd)pyrene ug/L 41.7 87 1-17180 8 3041.7ND 36.1 33.4
Isophorone ug/L 41.7 68 21-19661 10 3041.7ND 28.3 25.5
N-Nitroso-di-n-propylamine ug/L 41.7 64 1-23060 7 3041.7ND 26.7 25.0
N-Nitrosodimethylamine ug/L 41.7 56 25-15052 8 3041.7ND 23.4 21.7
N-Nitrosodiphenylamine ug/L 41.7 77 25-15069 12 3041.7ND 32.3 28.7
Naphthalene ug/L 41.7 64 21-13364 0 3041.7ND 26.8 26.8
Nitrobenzene ug/L 41.7 65 35-18062 5 3041.7ND 27.1 25.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3888977MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92644826001
3888978
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Pentachlorophenol ug/L R183.3 14 14-17620 40 3083.3ND 11.3 17.0
Phenanthrene ug/L 41.7 79 54-12070 12 3041.7ND 33.1 29.3
Phenol ug/L 41.7 34 5-11233 4 3041.7ND 14.4 13.8
Pyrene ug/L 41.7 76 52-11572 5 3041.7ND 31.6 30.1
2,4,6-Tribromophenol (S)%79 10-13778
2-Fluorobiphenyl (S)%78 15-12073
2-Fluorophenol (S)%44 10-12043
Nitrobenzene-d5 (S)%73 10-12069
Phenol-d6 (S)%41 10-12039
Terphenyl-d14 (S)%89 11-13183
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 38
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
748038
MADEP EPH
MADEP EPH
MADEP EPH NC Water
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92644826001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3888879
Associated Lab Samples:92644826001
Matrix:Water
AnalyzedMDL
Aliphatic (C09-C18)ug/L ND 100 N201/09/23 09:28100
Aliphatic (C19-C36)ug/L ND 100 N201/09/23 09:28100
Aromatic (C11-C22)ug/L ND 100 N201/09/23 09:28100
1-Chlorooctadecane (S)%46 40-140 01/09/23 09:28
2-Bromonaphthalene (S)%104 40-140 01/09/23 09:28
2-Fluorobiphenyl (S)%99 40-140 01/09/23 09:28
o-Terphenyl (S)%81 40-140 01/09/23 09:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3888880LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3888881
Aliphatic (C09-C18)ug/L 171 N23005740-14054162 5 50
Aliphatic (C19-C36)ug/L 327 N24008240-14078311 5 50
Aromatic (C11-C22)ug/L 726 N28508540-14095810 11 50
1-Chlorooctadecane (S)%69 40-14065
2-Bromonaphthalene (S)%88 40-140103
2-Fluorobiphenyl (S)%87 40-140101
o-Terphenyl (S)%87 40-14095
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 38
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits due to matrix interferences (confirmed by similar results from sample
re-analysis).S2
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 38
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92644826
QUALITY TURF DIESEL FUEL SPILL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92644826001 748038 748073MW-01 MADEP EPH MADEP EPH
92644826001 748071 748236MW-01 EPA 625.1 EPA 625.1
92644826001 747893MW-01 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/16/2023 12:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 38
Page 23 of 38
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Page 25 of 38
39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
January 13, 2023
Bonnie Vang
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
Project Location: Quality Turf Diesel fuel Spill
Client Job Number:
Project Number: 92644826
Laboratory Work Order Number: 23A0405
Enclosed are results of analyses for samples as received by the laboratory on January 5, 2023. If you have any questions
concerning this report, please feel free to contact me.
Sincerely,
Rebecca Faust
Project Manager
Page 1 of 13
Table of Contents
Page 26 of 38
Table of Contents
Sample Summary 3
Case Narrative 4
Sample Results 5
23A0405-01 5
Sample Preparation Information 6
QC Data 7
Petroleum Hydrocarbons Analyses - VPH 7
B328452 7
Flag/Qualifier Summary 9
Certifications 10
Chain of Custody/Sample Receipt 11
Page 2 of 13
Table of Contents
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
ANALYTICAL SUMMARY
1/13/2023
Pace Analytical Services - NC
9800 Kincey Avenue, Suite 100
Huntersville, NC 28078
ATTN: Bonnie Vang
92644826
23A0405
The results of analyses performed on the following samples submitted to CON-TEST, a Pace Analytical Laboratory, are found in this report.
PROJECT LOCATION:
PURCHASE ORDER NUMBER:
PROJECT NUMBER:
REPORT DATE:
WORK ORDER NUMBER:
FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB
Quality Turf Diesel fuel Spill
MW-01 23A0405-01 Water MADEP-VPH-Feb
2018 Rev 2.1
[TOC_1]Sample Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CASE NARRATIVE SUMMARY
All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report.
For method MA VPH only adjusted hydrocarbon ranges were requested and reported.
[TOC_1]Case Narrative[TOC]
MADEP-VPH-Feb 2018 Rev 2.1
Qualifications:
Elevated reporting limit due to sample matrix interference. MA CAM reporting limit not met.
Analyte & Samples(s) Qualified:
RL-08
23A0405-01[MW-01]
Average of 3 markers passes
Analyte & Samples(s) Qualified:
Z-01
2,2,4-Trimethylpentane
S081854-CCV2
Butylcyclohexane
B328452-BS1, B328452-BSD1, S081854-CCV1, S081854-CCV2
MADEP-VPH-Feb 2018 Rev 2.1
No significant modifications were made to the method. All VPH samples were received preserved properly at pH <2 in the proper containers as specified on the chain-of-custody
form unless specified in this narrative.
Analytical column used for VPH analysis is Restek, Rtx-502.2, 105meter, 0.53mmID, 3um df. Trap used for VPH analysis is Carbopack B/CarboSieveS-III.
The results of analyses reported only relate to samples submitted to Con-Test, a Pace Analytical Laboratory, for testing.
I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed
in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the
best of my knowledge and belief, accurate and complete.
Tod E. Kopyscinski
Laboratory Director
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Date Received: 1/5/2023
Work Order: 23A0405Sample Description:Project Location: Quality Turf Diesel fuel Spill
Sample ID: 23A0405-01
Field Sample #: MW-01
Sample Matrix: Water
Sampled: 1/3/2023 12:05
[TOC_2]23A0405-01[TOC]
AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte
Date/Time
Units
Date
PreparedMethod
Sample Flags: RL-08 Petroleum Hydrocarbons Analyses - VPH
210 200 1/13/23 4:04 EEHg/L 1/12/23MADEP-VPH-Feb 2018
Rev 2.1
2C5-C8 Aliphatics
ND 200 1/13/23 4:04 EEHg/L 1/12/23MADEP-VPH-Feb 2018
Rev 2.1
2C9-C12 Aliphatics
ND 200 1/13/23 4:04 EEHg/L 1/12/23MADEP-VPH-Feb 2018
Rev 2.1
2C9-C10 Aromatics
Surrogates % Recovery Recovery Limits Flag/Qual
2,5-Dibromotoluene (FID)83.0 1/13/23 4:0470-130
2,5-Dibromotoluene (PID)83.2 1/13/23 4:0470-130
[TOC_1]Sample Results[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Sample Extraction Data
Prep Method: MA VPH Analytical Method: MADEP-VPH-Feb 2018 Rev 2.1
Lab Number [Field ID]Batch DateInitial [mL]Final [mL]
B328452 01/12/232.5 5.0023A0405-01 [MW-01]
[TOC_1]Sample Preparation Information[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
[TOC_2]Petroleum Hydrocarbons Analyses - VPH[TOC]
Batch B328452 - MA VPH
[TOC_3]B328452[TOC]
Blank (B328452-BLK1) Prepared & Analyzed: 01/12/23
C5-C8 Aliphatics g/L100ND
C9-C12 Aliphatics g/L100ND
C9-C10 Aromatics g/L100ND
Benzene g/L1.0ND
Butylcyclohexane g/L1.0ND
Decane g/L1.0ND
Ethylbenzene g/L1.0ND
Methyl tert-Butyl Ether (MTBE)g/L1.0ND
2-Methylpentane g/L1.0ND
Naphthalene g/L5.0ND
Nonane g/L1.0ND
Pentane g/L1.0ND
Toluene g/L1.0ND
1,2,4-Trimethylbenzene g/L1.0ND
2,2,4-Trimethylpentane g/L1.0ND
m+p Xylene g/L2.0ND
o-Xylene g/L1.0ND
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)72.428.9
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)70.228.1
LCS (B328452-BS1) Prepared & Analyzed: 01/12/23
C9-C10 Aromatics g/L100 50.0 70-13010653.0
Benzene g/L1.0 50.0 70-13012763.6
Butylcyclohexane g/L1.0 50.0 Z-0170-130132*66.2
Decane g/L1.0 50.0 70-13084.342.2
Ethylbenzene g/L1.0 50.0 70-13096.048.0
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 70-13011557.6
2-Methylpentane g/L1.0 50.0 70-13011054.8
Naphthalene g/L5.0 50.0 70-13099.549.7
Nonane g/L1.0 50.0 70-13011658.0
Pentane g/L1.0 50.0 70-13085.342.6
Toluene g/L1.0 50.0 70-13012361.7
1,2,4-Trimethylbenzene g/L1.0 50.0 70-13010653.0
2,2,4-Trimethylpentane g/L1.0 50.0 70-13011859.2
m+p Xylene g/L2.0 100 70-130112112
o-Xylene g/L1.0 50.0 70-13011256.2
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)96.538.6
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)90.836.3
LCS Dup (B328452-BSD1) Prepared & Analyzed: 01/12/23
C9-C10 Aromatics g/L100 50.0 2570-130103 2.6951.6
Benzene g/L1.0 50.0 2570-130128 0.94064.2
Butylcyclohexane g/L1.0 50.0 25 Z-0170-130130 1.7465.1
Decane g/L1.0 50.0 2570-13082.4 2.2541.2
Ethylbenzene g/L1.0 50.0 2570-13094.5 1.6147.2
Methyl tert-Butyl Ether (MTBE)g/L1.0 50.0 2570-130108 6.3154.1
2-Methylpentane g/L1.0 50.0 2570-130110 0.60855.1
Naphthalene g/L5.0 50.0 2570-13083.3 17.741.6
Nonane g/L1.0 50.0 2570-130114 1.9456.8
Pentane g/L1.0 50.0 2570-13085.1 0.28442.5
Toluene g/L1.0 50.0 2570-130124 0.63662.1
1,2,4-Trimethylbenzene g/L1.0 50.0 2570-130103 2.6951.6
[TOC_1]QC Data[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
Result Limit
Reporting
Units Level
Spike
Result
Source
%REC
%REC
Limits RPD
RPD
Limit Notes Analyte
Petroleum Hydrocarbons Analyses - VPH - Quality Control
QUALITY CONTROL
Batch B328452 - MA VPH
LCS Dup (B328452-BSD1) Prepared & Analyzed: 01/12/23
2,2,4-Trimethylpentane g/L1.0 50.0 2570-130115 2.6357.6
m+p Xylene g/L2.0 100 2570-130112 0.0778112
o-Xylene g/L1.0 50.0 2570-130112 0.67155.8
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (FID)84.633.8
g/L 40.0 70-130Surrogate: 2,5-Dibromotoluene (PID)82.733.1
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
FLAG/QUALIFIER SUMMARY
*QC result is outside of established limits.
Wide recovery limits established for difficult compound.
Wide RPD limits established for difficult compound.
#Data exceeded client recommended or regulatory level
Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the
calculation which have not been rounded.
No results have been blank subtracted unless specified in the case narrative section.
RL Reporting Limit is at the level of quantitation (LOQ)
DL Detection Limit is the lower limit of detection determined by the MDL study
MCL Maximum Contaminant Level
ND Not Detected
Elevated reporting limit due to sample matrix interference. MA CAM reporting limit not met.RL-08
Average of 3 markers passesZ-01
[TOC_1]Flag/Qualifier Summary[TOC]
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39 Spruce Street * East Longmeadow, MA 01028 * FAX [phone] * TEL. [phone]
CertificationsAnalyte
CERTIFICATIONS
Certified Analyses included in this Report
MADEP-VPH-Feb 2018 Rev 2.1 in Water
CT,NC,ME,NH-PC5-C8 Aliphatics
CT,NC,ME,NH-PC9-C12 Aliphatics
CT,NC,ME,NH-PC9-C10 Aromatics
[TOC_1]Certifications[TOC]
Con-Test, a Pace Environmental Laboratory, operates under the following certifications and accreditations:
Code Description Number Expires
PH-0165Connecticut Department of Public HealthCT 12/31/2022
652North Carolina Div. of Water QualityNC 12/31/2023
MA00100State of MaineME 06/9/2023
2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2023
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