WI-29719_48840_CA_CLO_20230119

DRAFT

UST CLOSURE REPORT

Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina

ECS Project Number 49-18240

Prepared For:
Mr. Cameron Zurbruegg
SOCOL LLC
PO Box 1441
Wilmington, North Carolina 28480
January 19, 2023

DRAFT

January 19, 2023

Mr. Cameron Zurbruegg
SOCOL LLC
PO Box 1441
Wrightsville Beach, North Carolina 28480

Reference: UST Closure Report
Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

Dear Mr. Zurbruegg:

As authorized by your acceptance of ECS Proposal No. 49: 25979P, Rev. 3 dated April 18, 2022; ECS has
prepared a UST Closure Report for the above-referenced site. This report includes a description of the
work performed, the results obtained, and our conclusions and recommendations.

ECS appreciates the opportunity to provide our environmental consulting services to you on this project. If
you have any questions concerning this report or this project, please contact us.

Sincerely,

ECS SOUTHEAST, LLP

Samantha M. Szakasits, G.I.T. Scott M. Werley, P.G.
Environmental Staff Project Manager Environmental Principal
[e-mail] [e-mail]
919-616-2679 984-297-7285
DRAFT
TABLE OF CONTENTS

1.0 SITE INFORMATION ......................................................................................................................................... 1
2.0 BACKGROUND INFORMATION ........................................................................................................................ 3
3.0 UST CLOSURE ACTIVITIES ................................................................................................................................ 4
4.0 RESULTS ........................................................................................................................................................... 6
6.0 CONCLUSIONS & RECOMMENDATIONS ......................................................................................................... 7
7.0 QUALIFICATIONS OF REPORT .......................................................................................................................... 8

FIGURES

Figure 1 Topographic Site Location Map
Figure 2 Aerial Site Location Map
Figure 3 UST Closure Sample Location Map
Figure 4 Monitoring Well Location Map

TABLES

Table 1 Monitoring Well Construction and Depth to Water Summary
Table 2 Soil Analytical Results Summary – UST Closure
Table 3 Summary of Groundwater Analytical Results

APPENDCIES

Appendix A UST-3 and UST-2A Forms
Appendix B 24-hour Release Notification Form (UST-61 Form)
Appendix C UST and Liquids Disposal Documentation
Appendix D Fire Marshall Inspection Documentation
Appendix E Photo Documentation
Appendix F Monitoring Well Construction Records (MW-1 through MW-3)
Appendix G Laboratory Analytical Reports and Chain of Custody Records (COCs)
UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

1
1.0 SITE INFORMATION

UST Incident No.: Pending
Site Rank: Unknown
Land Use Category: Commercial
Parcel Identification Numbers: R08514-003-004-000, R08514-003-005-000, R08514-003-005-001,
R08514-003-006-001, R08514-003-006-000, R08514-003-007-000,
& R08514-003-007-001

Facility Identification Number: 00-0-0000035295

Site Name and Location: Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina

Date of Report: January 19, 2023

Former Operator and
Owner of UST: William E. Freeman
924 Roscoe Freeman Avenue
Wilmington, North Carolina 28409

Primary Contact: Mr. Cameron Zurbruegg
SOCOL LLC
PO Box 1441
Wrightsville Beach, North Carolina 28480

Location Method: Google Earth
Latitude and Longitude: 35.4284419, -78.0624517

Consultant: ECS Southeast, LLP
5260 Greens Dairy Road
Raleigh, North Carolina 27616
[phone]

Laboratory: Pace Analytical Services, LLC
9800 Kincey Avenue, #100
Huntersville, North Carolina 28078
NC Certification No. ##

Closure Contractor: Contaminant Control, Inc. (CCI)
281 Lane Parkway
Salisbury, North Carolina 28416
[phone]

UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

3
2.0 BACKGROUND INFORMATION
2.1 Site Information
The subject property is located at 7617 Carolina Beach Road in Wilmington, New Hanover County, North
Carolina and contains seven parcels, which are identified by New Hanover County parcel identification
numbers (PINs) R08514-003-004-000, R08514-003-005-000, R08514-003-005-001, R08514-003-006-001,
R08514-003-006-000, R08514-003-007-000, and R08514-003-007-001 (Figures 1 and 2). The site is
developed with an approximate 1,276 square foot residence, reportedly constructed in 1960, and a 900
square foot commercial building, that was reportedly constructed in 1958. The building is currently
occupied by a snow cone store; however, it was historically occupied by Snow’s Cut Convenience Store, a
petroleum retailer. Two 4,000-gallon gasoline underground storage tanks (USTs) were reportedly installed
at this facility in 1993 and temporarily closed in place in 2007. The UST facility ID on record with the
NCDEQ is 00-0-0000035295 and the owner/operator is named as William Freeman.

Based on a review of the North Carolina Department of Environmental Quality (NCDEQ) Laserfiche
database, there do not appear to be previous documented releases associated with the UST system at this
facility. The records available through the NCDEQ’s online Permits and Inspection Program date to 2012
and indicate that three notices of violation have been issued since 2013 to this facility for failure to obtain
operator training.

ECS was requested to provide environmental services associated with the closure of the two existing
4,000-gallon gasoline USTs and associated piping at the site, observation and documentation of UST
closure activities, collection of soil and groundwater samples, project management, and UST closure
reporting.

2.2 Site History
No previous releases are known to exist at this site. The two 4,000-gallon gasoline USTs were reportedly
installed at this facility in 1993 and temporarily closed in place in 2007. The UST facility ID on record with
the NCDEQ is 00-0-0000035295 and the owner/operator is named as William Freeman.

2.3 Site Geology
As determined from the USGS Topographic Map, Carolina Beach, North Carolina Quadrangle (Figure 1),
the site is at an approximate elevation of 10 feet above mean sea level.

Site geology has been characterized through observations of the sidewalls and bottoms of the excavated
UST basin. Observations indicated that site soils consisted of approximately 4 feet of greyish white, loamy
quartz sand over approximately 8 feet of dark grey coarse sand. Groundwater was observed at a depth of
approximately 4 feet below ground surface (bgs) in the former UST basin during removal activities;
however, during monitoring well installation activities, the groundwater table was measured at depths
ranging from approximately 2.41 to 2.84 feet below top of casing (btoc) in monitoring wells MW-1 through
MW-3, respectively. Bedrock was not encountered or observed in excavated areas or borings performed
on site to a maximum depth of approximately 12 feet bgs.

UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

4
3.0 UST CLOSURE ACTIVITIES On September 27 through 29, 2022, ECS mobilized to the site to observe, document, and collect soil
samples during the closure by removal of the two 4,000-gallon gasoline USTs and associated fiberglass
product lines conducted by Contaminant Control, Inc. (CCI). ECS completed the UST closure
documentation including submitted a UST-3 Form on August 19, 2022 and the UST-2A Form on January 19,
2023. The documents are provided in Appendix A. A release was discovered on September 28, 2022
during UST closure by permanent removal activities. A copy of the 24-Hour Release and UST Leak
Reporting Form submitted to the North Carolina Department of Environmental Quality (NCDEQ) has been
included in Appendix B.

CCI pumped and permanently closed the two USTs by removal from their one contiguous basin. The
contents of the USTs were pumped on September 27, 2022 and subsequently closed by permanent
removal on September 28, 2022. The location of the two USTs and associated product lines are included in
Figure 3.

3.1 UST Removal
Removal activities included the use of a tracked excavator and skid steer provided by CCI. Approximately 6
inches of concrete and 1.5 feet of overburden soil was removed with the excavator bucket to expose the top
of the steel USTs. The two USTs were observed to be filled with water and near full capacity, believed to be
from stormwater entering the observed opened fill ports from previous precipitation events. CCI was
contracted to remove the residual materials. A total of 8,000-gallons of petroleum contact water was
evacuated from the two USTs on September 28, 2022 utilizing a vacuum truck operated by CCI. Additionally, a
release was observed to have occurred based on petroleum sheens observed on the surface of the
groundwater in the UST basin. The impacted water below the two USTs was skimmed and combined with the
water evacuated from USTs, totaling 12,156-gallons of liquid. The non-hazardous liquids were transported by
CCI to the SR&R Environmental, Inc. facility located in Wilmington, North Carolina or to their CCI
Environmental facility located in Thomasville, North Carolina for disposal. Copies of the non-hazardous waste
liquids manifests is included in Appendix C.

Following removal of the residual liquid, the USTs were cleaned and checked for hazardous vapors and gases
using a lower explosive limit (LEL) gas detector. After the gas detector did not indicate the presence of
hazardous vapors or gases, and following the inspection by the New Hanover County Fire Marshal, the two
USTs were removed from the excavation. A copy of the Fire Marshall inspection documentation has been
included in Appendix D. The dimensions of the two USTs were each measured to be approximately 23 feet
long by 5 feet 3 inches in diameter. The USTs were transported by CCI to the Southern Metals Recycling, LLC
facility located in Wilmington, North Carolina. A copy of UST disposal manifest is included in Appendix C.

Following sampling activities, the excavation was backfilled with clean materials imported from Pelton
Aggregates Company located in Wilmington, NC and completed by CCI. Photo documentation of the closure
activities are included in Appendix E.

3.2 Soil Sample Collection
On September 28, 2022, following the removal of the UST, ECS collected ten UST closure samples, identified
as UST-1 through UST-10, at depth of approximately 3.0 feet bgs at an approximate interval of every 10 linear
feet from around the sidewalls of the UST basin. On September 29, 2022, approximately 50 feet of product
UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

5
line was removed and five product line closure samples, identified as L-1 through L-5, were collected from
beneath the product line at a depth of 2.5 feet bgs.

Due to the former dispenser and a portion of the product line being beneath a wooden deck, and unable to
be accessed on September 29, 2022, ECS remobilized with CCI on November 2, 2022 to finish collecting the
additional product line and dispenser closure samples following deck removal. Approximately 2.5 feet of
overburden soil was removed with the excavator bucket to expose the top of the remaining fiberglass product
line and stockpiled to the side of the excavation. An additional 20 feet of product line was removed and two
product line closure samples, identified as L-6 and L-7, were collected from beneath the product line at a
depth of 2.5 feet bgs. Additionally, ECS collected one closure sample beneath the center of each of the four
former dispenser locations for a total of four dispenser closure samples, identified as D-1 through D-4, at a
depth of approximately 2.5 feet bgs.

The soil samples were collected from the bucket of the excavator. ECS personnel wore new, disposable nitrile
gloves to collect each sample. The approximate locations of the samples have been illustrated on Figure 3.
The soil samples were field screened with a photo-ionization detector (PID) prior to placing the samples in
laboratory supplied/preserved containers. The sample containers were labeled and placed into a cooler
containing ice to maintain the samples at approximately 4° Celsius. ECS maintained chain of custody (COC)
procedures throughout the sample collection and transportation process.

3.3 Soil Sample Assessment
A total of 10 UST closure samples, 7 product line closure samples, and 4 dispenser closure samples were
submitted to Pace Analytical Services, LLC (Pace), a North Carolina certified lab, located in Huntersville,
North Carolina to be analyzed for total petroleum hydrocarbons (TPH) gasoline range organics (GRO) using
EPA Method 8015 and volatile petroleum hydrocarbons (VPH) using Massachusetts Department of
Environmental Protection (MADEP) method.

3.4 Monitoring Well Installation (MW-1 through MW-3)
Due to encountering groundwater in the excavations performed during UST removal activities, on
November 3, 2022, ECS contracted Mid-Atlantic Drilling, Inc. (Mid-Atlantic), a North Carolina Certified Well
Contractor (NCCWC) based out of Carolina Beach, North Carolina to install three monitoring wells.
Monitoring well MW-1 was installed near the former UST basin, monitoring well MW-2 was installed near
the vicinity of the former dispenser locations, and monitoring well MW-3 was installed topographically
downgradient of the UST system. The locations of the installed wells have been illustrated on Figure 4.

The borings for the monitoring wells were drilled to depths approximately 12 feet bgs for MW-1 through
MW-2 using hollow-stem augers (HSAs). The monitoring wells were constructed with two-inch I.D.
Schedule 40 PVC flush-threaded casing and screen. The PVC screen and casing for each well was placed
into its borehole through HSAs. A 10-foot length of slotted well screen with machined 0.010-inch slot
widths and a threaded bottom plug were installed at the bottom of the boreholes. The screens were
installed to a depth such that the screened interval intersected the estimated groundwater surface as
encountered during drilling activities. A solid section of PVC casing was placed above the screened interval
and extended to a point just below the ground surface for monitoring wells MW-1 through MW-3. The
annular space around each well was filled with a washed and graded medium sand to approximately 6
inches above the top of the screen. The sand was poured into the HSAs as they were being extracted.

UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

6
A minimum 6-inch-thick seal of bentonite pellets was placed immediately above the sand pack. After
placement in the well, the bentonite pellets were allowed to hydrate. After hydrating the bentonite
pellets, a bentonite/neat cement mixture was poured down the borehole to fill the annular space from the
bentonite seal to the ground surface. The top of each well casing was equipped with a lockable, water-
tight well plug and a flush-mounted 8-inch diameter, steel, bolt-down manhole was installed over each
well and completed within a concrete pad. Monitoring well construction details are summarized in Table 1
and the well construction record (GW-1) forms are provided in Appendix F.

Following completion, the three monitoring wells were developed by purging at least five well volumes
using a dedicated disposable polyethylene bailer and string. The wells were developed to remove sand,
silt, and other fine sediments that may have entered the wells during their construction.

3.5 Monitoring Well Groundwater Sample Collection
Groundwater samples were collected from monitoring wells MW-1 through MW-3 on November 3, 2022.
The groundwater samples were collected with the use of new dedicated disposable polyethylene bailers
and nylon string. Samples were collected directly into laboratory supplied/preserved sample containers.
The sample containers were labeled with ECS project number, sample identification, sample date and
time, and requested analysis. The containers were properly packaged and placed into a cooler with ice to
maintain the samples at approximately 4˚C.

The groundwater samples were submitted to Pace to be analyzed for volatile organic compounds (VOCs)
using EPA Method 8260, VPH using MADEP, and total lead using EPA Method 6010. ECS maintained COC
procedures throughout the sample collection and transportation process. A copy of the laboratory
analytical report along with accompanying COC documentation is included in Appendix G.

4.0 RESULTS
4.1 Closure Samples
Laboratory analysis did not report TPH-GRO at a concentration above its North Carolina Department of
Environmental Quality (NCDEQ) Action Level of 50 milligrams per Kilogram (mg/Kg) in soil samples
collected, with the exception of soil samples identified as L-4, L-6, and D-1. Additionally, laboratory
analysis reported select targeted volatile petroleum hydrocarbon ranges above their respective Soil-to-
Groundwater Maximum Soil Contaminant Concentrations (MSCCs) in L-4 and D-1, and above Residential
MSCCs in the soil sample identified as D-1.

A summary of the UST closure soil analytical results is included in Table 2. The laboratory analytical reports
and COCs are included in Appendix G.

4.2 Groundwater Samples
Laboratory analysis reported several petroleum-related compounds at concentrations above their
respective North Carolina 2L groundwater quality standards (NC2LGWQS) but below their respective Gross
Contamination Levels in the groundwater samples collected from MW-1 through MW-3. Total lead was
report above its NC2LGWQS in the groundwater samples collected from MW-1 and MW-2.

A summary of the groundwater analytical results is included in Table 3. The laboratory analytical reports and
COCs are included in Appendix G.

UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

7
5.0 CONCLUSIONS & RECOMMENDATIONS

Based on the field observations and laboratory analytical results of the soil samples collected during this
assessment, ECS concludes the following:

• On September 27-29, 2022 and November 2, 2022, respectively, an ECS professional observed the
closure by removal of two 4,000-gallon gasoline USTs along with approximately 80 feet of associated
product line. ECS collected a total of 21 soil samples collected from the UST sidewalls, associated
product line, and the four former dispenser locations, and submitted them for North Carolina
certified laboratory analysis.
• Laboratory analysis of the 21 soil samples collected from the UST sidewalls, associated product line,
and the four former dispenser locations did not report TPH-GRO above its NCDEQ Action Level, with
the exception of soil samples L-4, L-6, and D-1. Additionally, MADEP VPH analysis reported select
targeted volatile petroleum hydrocarbon ranges above their respective Soil-to-Groundwater MSCCs
in L-4 and D-1, and above respective Residential MSCCs in the soil sample identified as D-1. However,
based on the depths the three soil samples with exceedances were collected (2.5 feet bgs), and the
measured depth to water at the site averaging approximately 2.6 feet bgs, ECS believes these samples
were collected in the “smear zone” and therefore not representative of soil conditions.
• A total of 8,000-gallons of petroleum impacted water was evacuated from the two USTs on
September 28, 2022 utilizing a vacuum truck operated by CCI. Additionally, a release was observed to
have occurred based on petroleum sheens observed on the surface of the groundwater in the UST
basin. The impacted water below the two USTs was skimmed and combined with the water
evacuated from USTs, totaling 12,156-gallons of liquid.
• On November 3, 2022, ECS contracted Mid-Atlantic to install three Type-II permanent monitoring
wells. Monitoring well MW-1 was installed near the former UST basin, monitoring well MW-2 was
installed near the vicinity of the former dispenser locations, and monitoring well MW-3 was installed
topographically downgradient of the UST system. Following installation, ECS collected three
groundwater samples, identified as MW-1 through MW-3, and submitted them for North Carolina
certified laboratory analysis.
• Groundwater was measured at depths of 2.41, 2.84, and 2.84 feet btoc in monitoring wells MW-1
through MW-3, respectively.
• Laboratory analysis of the groundwater samples collected November 3, 2022 reported benzene,
naphthalene, and total xylenes at concentrations above their respective NC2LGWQS in one or more
sampled wells, but below their respective Gross Contamination Levels. Total lead was also reported
above its NC2LGWQS in the groundwater samples collected from MW-1 and MW-2.
• Based on the analytical results obtained, and in an effort to pursue risk-based closure of the incident,
ECS recommends conducting a Phase I Limited Site Assessment (LSA) including but not limited to
collecting an additional round groundwater samples from the onsite monitoring wells, and the
conductance of a potential receptor and land use survey within 1,500-feet of the source area of
release.
• ECS recommends that a copy of this report to be submitted to the NCDEQ DWM UST Section for
review.
• ECS recommends that a copy of this report be retained by the property owner to document
assessment activities.

UST Closure Report – Pelican’s SnoBalls
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
ECS Project No. 49-18240

8
6.0 QUALIFICATIONS OF REPORT

The activities and evaluative approaches used in this assessment are consistent with those normally
employed in UST closure projects of this type. Our evaluation of site conditions has been based on our
understanding of the site project information and the data obtained during our field activities.

FIGURES
FIGURE 1
TOPOGRAPHIC SITE LOCATION MAP
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
SOURCE:
USGS TOPOGRAPHIC MAP
7.5 –MINUTE SERIES
CAROLINA BEACH, NC
DATED 2019
SCALE: 1 : 24,000
CONTOUR INTERVAL = 5’
LEGEND
Site Parcel Boundary
SITE
SOURCE:
GOOGLE EARTH
IMAGERY DATED 2021
SCALE SHOWN ABOVE
FIGURE 2
AERIAL SITE LOCATION MAP7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
LEGEND
Site Parcel Boundary
SITE
R08514-003-007-000
R08514-003-006-001
R08514-003-005-001
R08514-003-006-000
SOURCE:
GOOGLE EARTH
IMAGERY DATED 2021
APPROXIMATE SCALE:
FIGURE 3
UST CLOSURE SAMPLE LOCATION MAP7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
LEGEND
Closure Sample Location Location of Former Product Line
Location of Former USTs Location of Former Dispensers
Notes:
1.) UST Dimensions: 23’ long x 5’ 3” in diameter
2.) Length of Product Line Removed: ~80 feet
3.) Closure samples collected on 9/28-29/2022 and 11/2/2022, respectively
Two 4,000-Gal UST
Locations
50 Feet
UST-5
UST-6
UST-7
UST-1
L-4
L-1
L-3
L-2
L-5
L-7L-6
D-1
D-2
D-4
D-3
SOURCE:
GOOGLE EARTH
IMAGERY DATED 2021
APPROXIMATE SCALE:
FIGURE 4
MONITORING WELL LOCATION MAP7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
LEGEND
Monitoring Well Location
Location of Former
4,000-Gal USTs
50 Feet
MW-1
MW-2
MW-3

TABLES
Monitoring
Well ID Date Measured
Depth to
Groundwater
(ft. btoc)Date Installed
Total Well
Depth
(ft. btoc)
Screen Interval
(ft. btoc)TOC Elevation
Groundwater
Elevation (ft.)
MW-1 11/3/2022 2.41 11/3/2022 12 2-12 NM NA
MW-2 11/3/2022 2.84 11/3/2022 12 2-12 NM NA
MW-3 11/3/2022 2.54 11/3/2022 12 2-12 NM NA
Notes:
ft. = Feet
ft. btoc = Feet Below Top of Casing
Wilmington, New Hanover County, North Carolina
NCDEQ UST Incident No. Pending
ECS Project No. 49:18240
Table 1: Monitoring Well Construction and Depth to Water Summary
Pelicans SnoBalls UST Removal
7617 Carolina Beach Road
Sample EPA Method 8015SampleSample Depth PID Reading TPH Aromatics
ID Date (feet bgs)(ppm)GRO C5-C8 C9-C12 C9-C10
UST-1 9/28/2022 3.0 0.0 BRL BRL BRL BRLUST-2 9/28/2022 3.0 0.0 BRL BRL BRL BRLUST-3 9/28/2022 3.0 0.0 BRL BRL BRL BRL
UST-4 9/28/2022 3.0 0.0 BRL BRL BRL BRL
UST-5 9/28/2022 3.0 6.9 BRL BRL BRL BRLUST-6 9/28/2022 3.0 0.0 BRL BRL BRL BRLUST-7 9/28/2022 3.0 32.4 BRL BRL BRL BRLUST-8 9/28/2022 3.0 14.1 BRL BRL BRL BRLUST-9 9/28/2022 3.0 0.0 BRL BRL BRL BRLUST-10 9/28/2022 3.0 15.9 BRL BRL BRL BRLL-1 9/29/2022 2.5 0.0 BRL BRL BRL 6.8
L-2 9/29/2022 2.5 6.6 17.2 3.4 BRL 5.4
L-3 9/29/2022 2.5 0.0 BRL BRL BRL BRL
L-4 9/29/2022 2.5 <15,000 605 193 169 250L-5 9/29/2022 2.5 23.7 BRL BRL BRL BRLL-6 11/2/2022 2.5 121.3 72.3 BRL BRL BRLL-7 11/2/2022 2.5 0.0 BRL BRL BRL BRLD-1 11/2/2022 2.5 <15,000 5,170 994 3,480 4,170D-2 11/2/2022 2.5 6.7 BRL BRL BRL BRLD-3 11/2/2022 2.5 0.0 BRL BRL BRL 6.65D-4 11/2/2022 2.5 0.0 BRL BRL BRL BRL50------
--68 540 31
--625 1,560 469
--9,340 23,300 7,000
Notes:
Concentrations are shown in mg/Kg (milligams per Kilograms).
RED SHADED indicates exceedance of the North Carolina Department of Environmental Quality (NCDEQ) Action Level.
NCDEQ Maximum Soil Contaminant Concentration Levels (MSCCs) as of October 10, 2021
BOLD indicated an exceedance of the Soil-to-Groundwater MSCCs
UNDERLINED indicates an exceedance of the Residential MSCCs
PID denotes Photoionization Detector.
ppm denotes parts per million.
bgs denotes below the ground surface
Table 2: Soil Analytical Results Summary - UST Closure
Pelicans SnoBalls UST Removal
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
Residential MSCCs (mg/Kg)Industrial/Commercial MSCCs (mg/Kg)
ECS Project No. 49:18240
MADEP VPHAliphatics
NCDEQ Incident No. Pending
NCDEQ Action Level (mg/Kg)
Soil-to-Groundwater MSCCs (mg/Kg)
Sample ID MW-1 MW-2 MW-3
Collection Date NC2LGWQS GCL
Benzene 11.6 2.3 9.6 1 5,000
n-Butylbenzene 19.2 1.9 3.7 70 5,900
tert-Butylbenzene BRL 0.66 BRL 70 14,750
Chloromethane BRL 1.3 BRL 3 3,000
Ethylbenzene 152 5.6 24.5 600 80,000
Isopropylbenzene 20.5 BRL 6.0 70 30,500
Methyl-tert-butyl ether (MTBE)2.3 5.9 BRL 20 20,000
Naphthalene 83.0 25.3 32.5 6 6,000
n-Propylbenzene 52.5 4.1 14.9 70 26,100
Toluene 324 2.6 9.7 600 260,000
1,2,4-Trimethylbenzene 395 104 58.8 400 24,100
1,3,5-Trimethylbenzene 107 20.1 15.0 400 25,000
Total Xylenes 851 81.6 82.4 500 50,000
EPA METHOD 6010 TOTAL LEAD
Lead 143 84.0 9.2 15 15,000
VOLATILE PETROLEUM HYDROCARBONS (VPH) BY MADEP
C5-C8 Aliphatics BRL BRL BRL 400 --
C9-C12 Aliphatics 1,480 BRL BRL 700 --
C9-C10 Aromatics 1,390 BRL BRL 200 --
Notes:
NC2LGWQS = North Carolina 2L Groundwater Quality Standard as of October 8, 2020
GCL = NCDEQ's Gross Contamination Levels for Groundwater as of October 8, 2020
Concentrations are shown in µg/L (micrograms per Liter).
BRL = Below Laboratory Reporting Limit
BOLD = Detected above the NC2LGWQS
COMPARISON CRITERIA
EPA METHOD 6200B VOLATILE ORGANIC COMPOUNDS (VOCS)
11/3/2022
Table 3: Summary of Groundwater Analytical Results
Pelicans SnoBalls UST Removal
7617 Carolina Beach Road
Wilmington, New Hanover County, North Carolina
NCDEQ UST Incident No. Pending
ECS Project No. 49:18240

APPENDIX A
UST-3 AND UST-2A Forms

APPENDIX B
24-HOUR RELEASE NOTIFICATION FORM (UST-61 Form)

Pelicans SnoBalls
7617 Carolina Beach Road New Hanover
Wilmington 28409
X
X X
X X
X
X
Center of UST Basin
Y
Y
N
Y
N
N/A
00-0-0000035295
9/28/2022
Comm
Regulated
A suspected release was observed during a UST system closure of two 4K gallon gasoline USTs on 9/28/2022. The USTs
were closed by permanent removal and groundwater observed exhibiting a petroleum sheen was skimmed from the open
excavations; however, free product was not observed to be present within the UST system closure excavation. Amount
of release is unknown. Impacts to receptors is unknown; site is on municipal water. Due encountering groundwater in the
excavation area, monitoring wells were installed at the site and the groundwater samples collected confirmed petroleum
impacts to the groundwater.
34.064845 -77.897756
N/A
William E Freeman
924 Roscoe Freeman Avenue
Wilmington NC 28409
SOCOL, LLC (Attn: Richard Yang)
919-622-3277
PO Box 1441
Wrightsville Beach NC 28480 404-312-8697
S. Szakasits ECS Southeast, LLP 919-616-2679
Project Manager 5260 Greens Dairy Rd, Raleigh, NC 1/12/2023
Same as above
See attached map
Map data ©2022 Google 50 ft
7617 Carolina Beach Rd

APPENDIX C
UST AND LIQUIDS DISPOSAL DOCUMENTATION

APPENDIX D
FIRE MARSHALL INSPECTION DOCUMENTATION

APPENDIX E
PHOTO DOCUMENTATION

Photo 1 –View of the two UST locations and initial site conditions on 9/27/2022.
Photo 2 –View of the tanks observed to be at full capacity with petroleum-impacted water on 9/27/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 3 –View of the vacuum truck evacuating liquids from with the two USTs on 9/27/2022.
Photo 4 –Removing the overburden soil above UST-1 utilizing a tracked excavator on 9/27/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 5 –Initial view of the UST-1 once overlying soils have been removed on 9/27/2022.
Photo 6 –Removing the overburden soil above UST-2 utilizing a tracked excavator on 9/27/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 7 –View of the cleaning procedures conducted to remove any residual material inside the two USTs.
Photo 8 –View of the petroleum sheen observed on the groundwater encountered within the UST basin.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 9 –View of the underside of UST-1 once removed from its basin on 9/28/2022.
Photo 10 –View of UST-1 being prepped and strapped for transport to the recycling facility on 9/28/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 11 –View of the underside of UST-2 once removed from its basin on 9/28/2022.
Photo 12 –View of UST-2 being prepped and strapped for transport to the recycling facility on 9/28/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 13 –View of the groundwater observed with a petroleum sheen in the former UST basin on 9/28/2022.
Photo 14 –View of the petroleum-impacted water being siphoned out of the former UST basin with the vacuum truck.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 17 –View of the initial conditions of the product lines uncovered on 9/29/2022.
Photo 16 –Approximately 50 feet of product line was removed on 9/29/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 17 –View of the former UST basin backfilled clean overburden and imported soil on 9/29/2022.
Photo 18 –View of the former UST basin backfilled and capped with ABC stone on 9/29/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 19 –View of the 50 feet of former product lie trench backfilled and capped with ABC stone on 9/29/2022.
Photo 20 –View of the westernmost dispenser island that previously contained two dispensers.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 21 –View of the easternmost dispenser island that previously contained two dispensers.
Photo 22 –View of the soil conditions once the remaining 30 feet of product line and dispenser islands were removed.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 23 –Additional view of the soil conditions once the remaining product line and dispenser islands were removed.
Photo 24 –View of the former product lines and dispenser islands backfilled and capped with ABC stone on 11/2/2022.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 25 –View of the drilling activities using hollow stem augers to install monitoring well MW-3 on 11/3/2022.
Photo 26 –View of the location of monitoring well MW-3.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 27 –View of the drilling activities using hollow stem augers to install monitoring well MW-1 on 11/3/2022.
Photo 28 –View of the location of monitoring well MW-1.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240
Photo 29 –View of the drilling activities using hollow stem augers to install monitoring well MW-2 on 11/3/2022.
Photo 30 –View of the location of monitoring well MW-2.
Photo Documentation
7617 Carolina Beach Road
Wilmington, New Hanover County,
North Carolina
ECS Project Number: 49-18240

APPENDIX F
MONITORING WELL CONSTRUCTION RECORDS

APPENDIX G
LABORATORY DATA SHEETS & CHAIN OF CUSTODY RECORDS
#=CL#
October 07, 2022
LIMS USE: FR - SAMANTHA
LIMS OBJECT ID: 92628485
92628485
Project:
Pace Project No.:
RE:
Samantha M. Szakasits, G.I.T.
ECS Southeast, LLP
5260 Greens Dary Road
Raleigh, NC 27616
Pelican's SnoBall UST Removal
Dear Samantha Szakasits, G.I.T.:
Enclosed are the analytical results for sample(s) received by the laboratory on September 29, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
cc:ECS Southeast Reporting, ECS Southeast
Scott Werley, ECS Southeast, LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92628485001 UST-1 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485002 UST-2 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485003 UST-3 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485004 UST-4 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485005 UST-5 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485006 UST-6 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485007 UST-7 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485008 UST-8 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485009 UST-9 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485010 UST-10 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485011 L-1 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
92628485012 L-2 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
92628485013 L-3 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SW-846 1 PASI-CKDF
92628485014 L-4 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
92628485015 L-5 EPA 8015C 2 PASI-CTEG
MADEP VPH 5 PASI-CTEG
SW-846 1 PASI-CKDF
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-1 Lab ID:92628485001 Collected:09/28/22 10:25 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 14:5510/05/22 11:2910.9 1
Surrogates
4-Bromofluorobenzene (S)98 %10/05/22 14:55 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 09/30/22 22:11 N209/30/22 15:252.8 1
Aliphatic(C09-C12) Adjusted ND mg/kg 09/30/22 22:11 N209/30/22 15:252.8 1
Aromatic (C09-C10)ND mg/kg 09/30/22 22:11 N209/30/22 15:252.8 1
Surrogates
4-Bromofluorobenzene (FID) (S)94 %09/30/22 22:11 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)110 %09/30/22 22:11 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 5.7 %09/30/22 15:19 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-2 Lab ID:92628485002 Collected:09/28/22 10:28 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 15:4610/05/22 11:297.6 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 15:46 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 09/30/22 22:39 N209/30/22 15:252.9 1
Aliphatic(C09-C12) Adjusted ND mg/kg 09/30/22 22:39 N209/30/22 15:252.9 1
Aromatic (C09-C10)ND mg/kg 09/30/22 22:39 N209/30/22 15:252.9 1
Surrogates
4-Bromofluorobenzene (FID) (S)88 %09/30/22 22:39 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)103 %09/30/22 22:39 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 8.7 %09/30/22 15:19 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-3 Lab ID:92628485003 Collected:09/28/22 10:34 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 16:1210/05/22 11:296.9 1
Surrogates
4-Bromofluorobenzene (S)96 %10/05/22 16:12 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 09/30/22 23:07 N209/30/22 15:253.4 1
Aliphatic(C09-C12) Adjusted ND mg/kg 09/30/22 23:07 N209/30/22 15:253.4 1
Aromatic (C09-C10)ND mg/kg 09/30/22 23:07 N209/30/22 15:253.4 1
Surrogates
4-Bromofluorobenzene (FID) (S)90 %09/30/22 23:07 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)106 %09/30/22 23:07 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 7.2 %09/30/22 15:19 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-4 Lab ID:92628485004 Collected:09/28/22 10:24 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 16:3810/05/22 11:296.5 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 16:38 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 09/30/22 23:35 N209/30/22 15:254.4 1
Aliphatic(C09-C12) Adjusted ND mg/kg 09/30/22 23:35 N209/30/22 15:254.4 1
Aromatic (C09-C10)ND mg/kg 09/30/22 23:35 N209/30/22 15:254.4 1
Surrogates
4-Bromofluorobenzene (FID) (S)85 %09/30/22 23:35 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)100 %09/30/22 23:35 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 3.1 %09/30/22 15:20 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-5 Lab ID:92628485005 Collected:09/28/22 11:28 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 17:0410/05/22 11:296.8 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 17:04 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 00:04 N209/30/22 15:254.2 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 00:04 N209/30/22 15:254.2 1
Aromatic (C09-C10)ND mg/kg 10/01/22 00:04 N209/30/22 15:254.2 1
Surrogates
4-Bromofluorobenzene (FID) (S)84 %10/01/22 00:04 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)98 %10/01/22 00:04 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 13.6 %09/30/22 15:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-6 Lab ID:92628485006 Collected:09/28/22 11:31 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 17:2910/05/22 11:297.0 1
Surrogates
4-Bromofluorobenzene (S)96 %10/05/22 17:29 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 00:32 N209/30/22 15:252.9 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 00:32 N209/30/22 15:252.9 1
Aromatic (C09-C10)ND mg/kg 10/01/22 00:32 N209/30/22 15:252.9 1
Surrogates
4-Bromofluorobenzene (FID) (S)98 %10/01/22 00:32 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)116 %10/01/22 00:32 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 12.0 %09/30/22 15:42 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-7 Lab ID:92628485007 Collected:09/28/22 11:35 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 17:5510/05/22 11:296.5 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 17:55 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 01:00 N209/30/22 15:253.4 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 01:00 N209/30/22 15:253.4 1
Aromatic (C09-C10)ND mg/kg 10/01/22 01:00 N209/30/22 15:253.4 1
Surrogates
4-Bromofluorobenzene (FID) (S)95 %10/01/22 01:00 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)112 %10/01/22 01:00 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 5.4 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-8 Lab ID:92628485008 Collected:09/28/22 11:40 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 18:2110/05/22 11:296.7 1
Surrogates
4-Bromofluorobenzene (S)96 %10/05/22 18:21 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 01:28 N209/30/22 15:252.7 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 01:28 N209/30/22 15:252.7 1
Aromatic (C09-C10)ND mg/kg 10/01/22 01:28 N209/30/22 15:252.7 1
Surrogates
4-Bromofluorobenzene (FID) (S)87 %10/01/22 01:28 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)103 %10/01/22 01:28 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.2 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-9 Lab ID:92628485009 Collected:09/28/22 12:00 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 18:4710/05/22 11:296.7 1
Surrogates
4-Bromofluorobenzene (S)96 %10/05/22 18:47 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 01:57 N209/30/22 15:252.9 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 01:57 N209/30/22 15:252.9 1
Aromatic (C09-C10)ND mg/kg 10/01/22 01:57 N209/30/22 15:252.9 1
Surrogates
4-Bromofluorobenzene (FID) (S)88 %10/01/22 01:57 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)104 %10/01/22 01:57 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.3 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:UST-10 Lab ID:92628485010 Collected:09/28/22 13:16 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 19:1210/05/22 11:297.9 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 19:12 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 02:25 N209/30/22 15:253.3 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 02:25 N209/30/22 15:253.3 1
Aromatic (C09-C10)ND mg/kg 10/01/22 02:25 N209/30/22 15:253.3 1
Surrogates
4-Bromofluorobenzene (FID) (S)90 %10/01/22 02:25 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)106 %10/01/22 02:25 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 17.4 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:L-1 Lab ID:92628485011 Collected:09/29/22 10:10 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/06/22 18:1010/06/22 10:407.4 1
Surrogates
4-Bromofluorobenzene (S)97 %10/06/22 18:10 460-00-410/06/22 10:4066-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 02:53 N209/30/22 15:252.8 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 02:53 N209/30/22 15:252.8 1
Aromatic (C09-C10)6.8 mg/kg 10/01/22 02:53 N209/30/22 15:252.8 1
Surrogates
4-Bromofluorobenzene (FID) (S)87 %10/01/22 02:53 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)102 %10/01/22 02:53 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.7 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:L-2 Lab ID:92628485012 Collected:09/29/22 10:15 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)17.9 mg/kg 10/05/22 22:3810/05/22 11:295.7 1
Surrogates
4-Bromofluorobenzene (S)98 %10/05/22 22:38 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)3.4 mg/kg 10/01/22 03:21 N209/30/22 15:252.3 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 03:21 N209/30/22 15:252.3 1
Aromatic (C09-C10)5.4 mg/kg 10/01/22 03:21 N209/30/22 15:252.3 1
Surrogates
4-Bromofluorobenzene (FID) (S)88 %10/01/22 03:21 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)103 %10/01/22 03:21 460-00-409/30/22 15:2570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:L-3 Lab ID:92628485013 Collected:09/29/22 10:18 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 19:3810/05/22 11:298.4 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 19:38 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 03:49 N209/30/22 15:253.5 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 03:49 N209/30/22 15:253.5 1
Aromatic (C09-C10)ND mg/kg 10/01/22 03:49 N209/30/22 15:253.5 1
Surrogates
4-Bromofluorobenzene (FID) (S)88 %10/01/22 03:49 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)104 %10/01/22 03:49 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 22.6 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:L-4 Lab ID:92628485014 Collected:09/29/22 10:20 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "wet-weight" basis
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)605 mg/kg 10/06/22 20:1810/06/22 10:4014.8 2.5
Surrogates
4-Bromofluorobenzene (S)112 %10/06/22 20:18 460-00-410/06/22 10:4066-130 2.5
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)193 mg/kg 10/04/22 01:25 N210/03/22 11:349.1 2
Aliphatic(C09-C12) Adjusted 169 mg/kg 10/04/22 01:25 N210/03/22 11:349.1 2
Aromatic (C09-C10)250 mg/kg 10/04/22 01:25 N210/03/22 11:349.1 2
Surrogates
4-Bromofluorobenzene (FID) (S)103 %10/04/22 01:25 460-00-410/03/22 11:3470-130 2
4-Bromofluorobenzene (PID) (S)106 %10/04/22 01:25 460-00-410/03/22 11:3470-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Sample:L-5 Lab ID:92628485015 Collected:09/29/22 10:23 Received:09/29/22 15:45 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 10/05/22 20:0410/05/22 11:297.0 1
Surrogates
4-Bromofluorobenzene (S)97 %10/05/22 20:04 460-00-410/05/22 11:2966-130 1
Analytical Method: MADEP VPH Preparation Method: MADEP VPH
Pace Analytical Services - Charlotte
VPH NC Soil
Aliphatic (C05-C08)ND mg/kg 10/01/22 04:45 N209/30/22 15:252.9 1
Aliphatic(C09-C12) Adjusted ND mg/kg 10/01/22 04:45 N209/30/22 15:252.9 1
Aromatic (C09-C10)ND mg/kg 10/01/22 04:45 N209/30/22 15:252.9 1
Surrogates
4-Bromofluorobenzene (FID) (S)91 %10/01/22 04:45 460-00-409/30/22 15:2570-130 1
4-Bromofluorobenzene (PID) (S)104 %10/01/22 04:45 460-00-409/30/22 15:2570-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 8.1 %09/30/22 15:43 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
727993
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485001, 92628485002, 92628485003, 92628485004, 92628485005, 92628485006, 92628485007,
92628485008, 92628485009, 92628485010, 92628485012, 92628485013, 92628485015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3790964
Associated Lab Samples:92628485001, 92628485002, 92628485003, 92628485004, 92628485005, 92628485006, 92628485007,
92628485008, 92628485009, 92628485010, 92628485012, 92628485013, 92628485015
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.1 10/05/22 14:29
4-Bromofluorobenzene (S)%97 66-130 10/05/22 14:29
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3790965LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 50.650.5 100 70-130
4-Bromofluorobenzene (S)%100 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3790967MATRIX SPIKE SAMPLE:
MSSpike
Result
92628485002
Gas Range Organics (C6-C10)mg/kg 55.663.1 86 65-146ND
4-Bromofluorobenzene (S)%98 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92628485001
3790966SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg NDND
4-Bromofluorobenzene (S)%9798
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
728329
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485011, 92628485014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3792697
Associated Lab Samples:92628485011, 92628485014
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 10/06/22 13:27
4-Bromofluorobenzene (S)%96 66-130 10/06/22 13:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3792698LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 49.749.6 100 70-130
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3792699MATRIX SPIKE SAMPLE:
MSSpike
Result
92629437001
Gas Range Organics (C6-C10)mg/kg 90.095.7 93 65-146ND
4-Bromofluorobenzene (S)%95 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92629437002
3792700SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg NDND
4-Bromofluorobenzene (S)%9697
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
727160
MADEP VPH
MADEP VPH
VPH NC Soil
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485001, 92628485002, 92628485003, 92628485004, 92628485005, 92628485006, 92628485007,
92628485008, 92628485009, 92628485010, 92628485011, 92628485012, 92628485013, 92628485015
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3787025
Associated Lab Samples:92628485001, 92628485002, 92628485003, 92628485004, 92628485005, 92628485006, 92628485007,
92628485008, 92628485009, 92628485010, 92628485011, 92628485012, 92628485013, 92628485015
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 2.5 N209/30/22 21:15
Aromatic (C09-C10)mg/kg ND 2.5 N209/30/22 21:15
4-Bromofluorobenzene (FID) (S)%92 70-130 09/30/22 21:15
4-Bromofluorobenzene (PID) (S)%109 70-130 09/30/22 21:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3787026LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3787027
Aliphatic (C05-C08)mg/kg 13.6 N2159170-1309313.9 2 25
Aromatic (C09-C10)mg/kg 5.9 N2511970-1301185.9 1 25
4-Bromofluorobenzene (FID) (S)%90 70-13090
4-Bromofluorobenzene (PID) (S)%109 70-130108
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
727439
MADEP VPH
MADEP VPH
VPH NC Soil
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485014
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3788099
Associated Lab Samples:92628485014
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 2.5 N210/03/22 19:47
Aromatic (C09-C10)mg/kg ND 2.5 N210/03/22 19:47
4-Bromofluorobenzene (FID) (S)%93 70-130 10/03/22 19:47
4-Bromofluorobenzene (PID) (S)%113 70-130 10/03/22 19:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3788100LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3788101
Aliphatic (C05-C08)mg/kg 12.6 N2158470-1308412.6 0 25
Aromatic (C09-C10)mg/kg 5.9 N2511870-1301195.9 0 25
4-Bromofluorobenzene (FID) (S)%86 70-13084
4-Bromofluorobenzene (PID) (S)%106 70-130103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
726894
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485001, 92628485002, 92628485003, 92628485004
Parameter Units
Dup
Result QualifiersRPDResult
92628376007
3785710SAMPLE DUPLICATE:
Percent Moisture %17.3 N2117.4
Parameter Units
Dup
Result QualifiersRPDResult
92628485004
3787067SAMPLE DUPLICATE:
Percent Moisture %3.7 N2163.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
727180
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92628485005, 92628485006, 92628485007, 92628485008, 92628485009, 92628485010, 92628485011,
92628485013, 92628485015
Parameter Units
Dup
Result QualifiersRPDResult
92628485005
3787256SAMPLE DUPLICATE:
Percent Moisture %15.7 N21513.6
Parameter Units
Dup
Result QualifiersRPDResult
92628479011
3787257SAMPLE DUPLICATE:
Percent Moisture %13.6 N2213.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92628485
Pelican's SnoBall UST Removal
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92628485001 727993 728059UST-1 EPA 5030B EPA 8015C
92628485002 727993 728059UST-2 EPA 5030B EPA 8015C
92628485003 727993 728059UST-3 EPA 5030B EPA 8015C
92628485004 727993 728059UST-4 EPA 5030B EPA 8015C
92628485005 727993 728059UST-5 EPA 5030B EPA 8015C
92628485006 727993 728059UST-6 EPA 5030B EPA 8015C
92628485007 727993 728059UST-7 EPA 5030B EPA 8015C
92628485008 727993 728059UST-8 EPA 5030B EPA 8015C
92628485009 727993 728059UST-9 EPA 5030B EPA 8015C
92628485010 727993 728059UST-10 EPA 5030B EPA 8015C
92628485011 728329 728359L-1 EPA 5030B EPA 8015C
92628485012 727993 728059L-2 EPA 5030B EPA 8015C
92628485013 727993 728059L-3 EPA 5030B EPA 8015C
92628485014 728329 728359L-4 EPA 5030B EPA 8015C
92628485015 727993 728059L-5 EPA 5030B EPA 8015C
92628485001 727160 727233UST-1 MADEP VPH MADEP VPH
92628485002 727160 727233UST-2 MADEP VPH MADEP VPH
92628485003 727160 727233UST-3 MADEP VPH MADEP VPH
92628485004 727160 727233UST-4 MADEP VPH MADEP VPH
92628485005 727160 727233UST-5 MADEP VPH MADEP VPH
92628485006 727160 727233UST-6 MADEP VPH MADEP VPH
92628485007 727160 727233UST-7 MADEP VPH MADEP VPH
92628485008 727160 727233UST-8 MADEP VPH MADEP VPH
92628485009 727160 727233UST-9 MADEP VPH MADEP VPH
92628485010 727160 727233UST-10 MADEP VPH MADEP VPH
92628485011 727160 727233L-1 MADEP VPH MADEP VPH
92628485012 727160 727233L-2 MADEP VPH MADEP VPH
92628485013 727160 727233L-3 MADEP VPH MADEP VPH
92628485014 727439 727491L-4 MADEP VPH MADEP VPH
92628485015 727160 727233L-5 MADEP VPH MADEP VPH
92628485001 726894UST-1 SW-846
92628485002 726894UST-2 SW-846
92628485003 726894UST-3 SW-846
92628485004 726894UST-4 SW-846
92628485005 727180UST-5 SW-846
92628485006 727180UST-6 SW-846
92628485007 727180UST-7 SW-846
92628485008 727180UST-8 SW-846
92628485009 727180UST-9 SW-846
92628485010 727180UST-10 SW-846
92628485011 727180L-1 SW-846
92628485013 727180L-3 SW-846
92628485015 727180L-5 SW-846
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 10/07/2022 04:16 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 32
Page 28 of 32
Page 29 of 32
Page 30 of 32
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Page 32 of 32
#=CL#
November 29, 2022
LIMS USE: FR - SAMANTHA
LIMS OBJECT ID: 92635122
92635122
Project:
Pace Project No.:
RE:
Samantha M. Szakasits, G.I.T.
ECS Southeast, LLP
5260 Greens Dary Road
Raleigh, NC 27616
PELICANS SNOBALLS UST REMOVAL
Dear Samantha Szakasits, G.I.T.:
Enclosed are the analytical results for sample(s) received by the laboratory on November 04, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
cc:ECS Southeast Reporting, ECS Southeast
Scott Werley, ECS Southeast, LLP
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 32
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Mold Certification #: LAB0152
Texas Certification #: T 104704245-17-14
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: VT2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 32
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92635122001 L-6 MADEP VPH 6 PANACG
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122002 L-7 MADEP VPH 6 PANACG
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122003 D-1 MADEP VPH 6 PANADM
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122004 D-2 MADEP VPH 6 PANADM
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122005 D-3 MADEP VPH 6 PANADM
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122006 D-4 MADEP VPH 6 PANACG
EPA 8015C 2 PASI-CTEG
SW-846 1 PASI-CKDF
92635122007 MW-3 MADEP VPH 6 PANACG
EPA 6020B 7 PASI-ADBB1
SM 6200B 63 PASI-CCL
92635122008 MW-2 MADEP VPH 6 PANACG
EPA 6020B 7 PASI-ADBB1
SM 6200B 63 PASI-CCL
92635122009 MW-1 MADEP VPH 6 PANACG
EPA 6020B 7 PASI-ADBB1
SM 6200B 63 PASI-CCL
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:L-6 Lab ID:92635122001 Collected:11/02/22 10:45 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 11/20/22 00:0311/02/22 10:455.84 1
Aliphatic (C09-C12)ND mg/kg 11/20/22 00:0311/02/22 10:455.84 1
Aromatic (C09-C10),Unadjusted ND mg/kg 11/20/22 00:03 TPHC9C10A11/02/22 10:455.84 1
Total VPH ND mg/kg 11/20/22 00:03 VPH11/02/22 10:455.84 1
Surrogates
2,5-Dibromotoluene (FID)87.0 %11/20/22 00:03 615-59-8FID11/02/22 10:4570.0-130 1
2,5-Dibromotoluene (PID)87.8 %11/20/22 00:03 615-59-8PID11/02/22 10:4570.0-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)72.3 mg/kg 11/08/22 15:0811/08/22 10:2312.3 1
Surrogates
4-Bromofluorobenzene (S)96 %11/08/22 15:08 460-00-411/08/22 10:2366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 7.2 %11/07/22 17:39 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:L-7 Lab ID:92635122002 Collected:11/02/22 11:21 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 11/20/22 00:3611/02/22 11:216.03 1
Aliphatic (C09-C12)ND mg/kg 11/20/22 00:3611/02/22 11:216.03 1
Aromatic (C09-C10),Unadjusted ND mg/kg 11/20/22 00:36 TPHC9C10A11/02/22 11:216.03 1
Total VPH ND mg/kg 11/20/22 00:36 VPH11/02/22 11:216.03 1
Surrogates
2,5-Dibromotoluene (FID)93.6 %11/20/22 00:36 615-59-8FID11/02/22 11:2170.0-130 1
2,5-Dibromotoluene (PID)93.5 %11/20/22 00:36 615-59-8PID11/02/22 11:2170.0-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/08/22 15:3411/08/22 10:236.7 1
Surrogates
4-Bromofluorobenzene (S)94 %11/08/22 15:34 460-00-411/08/22 10:2366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.1 %11/07/22 17:39 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:D-1 Lab ID:92635122003 Collected:11/02/22 10:50 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)994 mg/kg 11/21/22 17:2911/02/22 10:5026340
Aliphatic (C09-C12)3480 mg/kg 11/21/22 17:2911/02/22 10:5026340
Aromatic (C09-C10),Unadjusted 4170 mg/kg 11/21/22 17:29 TPHC9C10A11/02/22 10:5026340
Total VPH 8650 mg/kg 11/21/22 17:29 VPH11/02/22 10:5026340
Surrogates
2,5-Dibromotoluene (FID)96.8 %11/21/22 17:29 615-59-8FID11/02/22 10:5070.0-130 40
2,5-Dibromotoluene (PID)87.5 %11/21/22 17:29 615-59-8PID11/02/22 10:5070.0-130 40
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)5170 mg/kg 11/09/22 16:4411/09/22 10:4394.2 12.5
Surrogates
4-Bromofluorobenzene (S)109 %11/09/22 16:44 460-00-411/09/22 10:4366-130 12.5
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 13.0 %11/07/22 17:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:D-2 Lab ID:92635122004 Collected:11/02/22 10:55 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 11/21/22 15:5211/02/22 10:557.57 1.16
Aliphatic (C09-C12)ND mg/kg 11/21/22 15:5211/02/22 10:557.57 1.16
Aromatic (C09-C10),Unadjusted ND mg/kg 11/21/22 15:52 TPHC9C10A11/02/22 10:557.57 1.16
Total VPH 11.4 mg/kg 11/21/22 15:52 VPH11/02/22 10:557.57 1.16
Surrogates
2,5-Dibromotoluene (FID)88.1 %11/21/22 15:52 615-59-8FID11/02/22 10:5570.0-130 1.16
2,5-Dibromotoluene (PID)88.2 %11/21/22 15:52 615-59-8PID11/02/22 10:5570.0-130 1.16
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/08/22 16:0011/08/22 10:238.0 1
Surrogates
4-Bromofluorobenzene (S)93 %11/08/22 16:00 460-00-411/08/22 10:2366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 14.1 %11/07/22 17:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:D-3 Lab ID:92635122005 Collected:11/02/22 11:25 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 11/21/22 16:2511/02/22 11:256.28 1.01
Aliphatic (C09-C12)ND mg/kg 11/21/22 16:2511/02/22 11:256.28 1.01
Aromatic (C09-C10),Unadjusted 6.65 mg/kg 11/21/22 16:25 TPHC9C10A11/02/22 11:256.28 1.01
Total VPH 9.54 mg/kg 11/21/22 16:25 VPH11/02/22 11:256.28 1.01
Surrogates
2,5-Dibromotoluene (FID)86.7 %11/21/22 16:25 615-59-8FID11/02/22 11:2570.0-130 1.01
2,5-Dibromotoluene (PID)87.7 %11/21/22 16:25 615-59-8PID11/02/22 11:2570.0-130 1.01
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/08/22 16:2511/08/22 10:237.3 1
Surrogates
4-Bromofluorobenzene (S)93 %11/08/22 16:25 460-00-411/08/22 10:2366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 10.9 %11/07/22 17:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:D-4 Lab ID:92635122006 Collected:11/02/22 11:30 Received:11/04/22 14:30 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 11/20/22 02:4711/02/22 11:306.05 1
Aliphatic (C09-C12)ND mg/kg 11/20/22 02:4711/02/22 11:306.05 1
Aromatic (C09-C10),Unadjusted ND mg/kg 11/20/22 02:47 TPHC9C10A11/02/22 11:306.05 1
Total VPH 6.21 mg/kg 11/20/22 02:47 VPH11/02/22 11:306.05 1
Surrogates
2,5-Dibromotoluene (FID)89.3 %11/20/22 02:47 615-59-8FID11/02/22 11:3070.0-130 1
2,5-Dibromotoluene (PID)89.4 %11/20/22 02:47 615-59-8PID11/02/22 11:3070.0-130 1
Analytical Method: EPA 8015C Preparation Method: EPA 5030B
Pace Analytical Services - Charlotte
Gasoline Range Organics
Gas Range Organics (C6-C10)ND mg/kg 11/08/22 16:5111/08/22 10:236.5 1
Surrogates
4-Bromofluorobenzene (S)94 %11/08/22 16:51 460-00-411/08/22 10:2366-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 9.1 %11/07/22 17:40 N20.10 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-3 Lab ID:92635122007 Collected:11/03/22 15:25 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND ug/L 11/14/22 06:2311/14/22 06:23100010
Aliphatic (C09-C12)ND ug/L 11/14/22 06:2311/14/22 06:23100010
Aromatic (C09-C10),Unadjusted ND ug/L 11/14/22 06:23 TPHC9C10A11/14/22 06:23100010
Total VPH ND ug/L 11/14/22 06:23 VPH11/14/22 06:23100010
Surrogates
2,5-Dibromotoluene (FID)95.7 %11/14/22 06:23 615-59-8FID11/14/22 06:2370.0-130 10
2,5-Dibromotoluene (PID)84.0 %11/14/22 06:23 615-59-8PID11/14/22 06:2370.0-130 10
Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6020 MET ICPMS
Arsenic 32.2 ug/L 11/10/22 06:00 7440-38-211/09/22 00:541.0 1
Barium 39.5 ug/L 11/10/22 06:00 7440-39-311/09/22 00:541.0 1
Cadmium ND ug/L 11/10/22 06:00 7440-43-911/09/22 00:540.20 1
Chromium 10.8 ug/L 11/10/22 06:00 7440-47-311/09/22 00:541.0 1
Lead 9.2 ug/L 11/10/22 06:00 7439-92-111/09/22 00:541.0 1
Selenium ND ug/L 11/10/22 06:00 7782-49-211/09/22 00:542.0 1
Silver ND ug/L 11/10/22 06:00 7440-22-411/09/22 00:540.40 1
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 9.6 ug/L 11/11/22 14:55 71-43-20.50 1
Bromobenzene ND ug/L 11/11/22 14:55 108-86-10.50 1
Bromochloromethane ND ug/L 11/11/22 14:55 74-97-50.50 1
Bromodichloromethane ND ug/L 11/11/22 14:55 75-27-40.50 1
Bromoform ND ug/L 11/11/22 14:55 75-25-20.50 1
Bromomethane ND ug/L 11/11/22 14:55 74-83-95.0 1
n-Butylbenzene 3.7 ug/L 11/11/22 14:55 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/11/22 14:55 135-98-80.50 1
tert-Butylbenzene ND ug/L 11/11/22 14:55 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/11/22 14:55 56-23-50.50 1
Chlorobenzene ND ug/L 11/11/22 14:55 108-90-70.50 1
Chloroethane ND ug/L 11/11/22 14:55 75-00-31.0 1
Chloroform ND ug/L 11/11/22 14:55 67-66-30.50 1
Chloromethane ND ug/L 11/11/22 14:55 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/11/22 14:55 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/11/22 14:55 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/11/22 14:55 96-12-81.0 1
Dibromochloromethane ND ug/L 11/11/22 14:55 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/11/22 14:55 106-93-40.50 1
Dibromomethane ND ug/L 11/11/22 14:55 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/11/22 14:55 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/11/22 14:55 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/11/22 14:55 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/11/22 14:55 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/11/22 14:55 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/11/22 14:55 107-06-20.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-3 Lab ID:92635122007 Collected:11/03/22 15:25 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethene ND ug/L 11/11/22 14:55 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/11/22 14:55 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/11/22 14:55 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/11/22 14:55 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/11/22 14:55 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/11/22 14:55 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/11/22 14:55 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/11/22 14:55 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/11/22 14:55 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/11/22 14:55 108-20-30.50 1
Ethylbenzene 24.5 ug/L 11/11/22 14:55 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/11/22 14:55 87-68-32.0 1
Isopropylbenzene (Cumene)6.0 ug/L 11/11/22 14:55 98-82-80.50 1
Methylene Chloride ND ug/L 11/11/22 14:55 75-09-22.0 1
Methyl-tert-butyl ether ND ug/L 11/11/22 14:55 1634-04-40.50 1
Naphthalene 32.5 ug/L 11/11/22 14:55 91-20-32.0 1
n-Propylbenzene 14.9 ug/L 11/11/22 14:55 103-65-10.50 1
Styrene ND ug/L 11/11/22 14:55 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/11/22 14:55 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/11/22 14:55 79-34-50.50 1
Tetrachloroethene ND ug/L 11/11/22 14:55 127-18-40.50 1
Toluene 9.7 ug/L 11/11/22 14:55 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/11/22 14:55 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/11/22 14:55 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/11/22 14:55 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/11/22 14:55 79-00-50.50 1
Trichloroethene ND ug/L 11/11/22 14:55 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/11/22 14:55 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/11/22 14:55 96-18-40.50 1
1,2,4-Trimethylbenzene 58.8 ug/L 11/11/22 14:55 95-63-60.50 1
1,3,5-Trimethylbenzene 15.0 ug/L 11/11/22 14:55 108-67-80.50 1
Vinyl chloride ND ug/L 11/11/22 14:55 75-01-41.0 1
m&p-Xylene 74.1 ug/L 11/11/22 14:55 179601-23-11.0 1
o-Xylene 8.3 ug/L 11/11/22 14:55 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %11/11/22 14:55 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %11/11/22 14:55 460-00-470-130 1
Toluene-d8 (S)100 %11/11/22 14:55 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-2 Lab ID:92635122008 Collected:11/03/22 15:30 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND ug/L 11/14/22 06:5511/14/22 06:55200020
Aliphatic (C09-C12)ND ug/L 11/14/22 06:5511/14/22 06:55200020
Aromatic (C09-C10),Unadjusted ND ug/L 11/14/22 06:55 TPHC9C10A11/14/22 06:55200020
Total VPH ND ug/L 11/14/22 06:55 VPH11/14/22 06:55200020
Surrogates
2,5-Dibromotoluene (FID)93.1 %11/14/22 06:55 615-59-8FID11/14/22 06:5570.0-130 20
2,5-Dibromotoluene (PID)81.6 %11/14/22 06:55 615-59-8PID11/14/22 06:5570.0-130 20
Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6020 MET ICPMS
Arsenic 123 ug/L 11/10/22 06:04 7440-38-211/09/22 00:545.0 5
Barium 800 ug/L 11/10/22 06:04 7440-39-311/09/22 00:545.0 5
Cadmium ND ug/L 11/10/22 06:04 7440-43-9 D311/09/22 00:541.0 5
Chromium 152 ug/L 11/10/22 06:04 7440-47-311/09/22 00:545.0 5
Lead 84.0 ug/L 11/10/22 06:04 7439-92-111/09/22 00:545.0 5
Selenium 11.7 ug/L 11/10/22 06:04 7782-49-211/09/22 00:5410.0 5
Silver ND ug/L 11/10/22 06:04 7440-22-4 D311/09/22 00:542.0 5
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 2.3 ug/L 11/11/22 15:13 71-43-20.50 1
Bromobenzene ND ug/L 11/11/22 15:13 108-86-10.50 1
Bromochloromethane ND ug/L 11/11/22 15:13 74-97-50.50 1
Bromodichloromethane ND ug/L 11/11/22 15:13 75-27-40.50 1
Bromoform ND ug/L 11/11/22 15:13 75-25-20.50 1
Bromomethane ND ug/L 11/11/22 15:13 74-83-95.0 1
n-Butylbenzene 1.9 ug/L 11/11/22 15:13 104-51-80.50 1
sec-Butylbenzene ND ug/L 11/11/22 15:13 135-98-80.50 1
tert-Butylbenzene 0.66 ug/L 11/11/22 15:13 98-06-60.50 1
Carbon tetrachloride ND ug/L 11/11/22 15:13 56-23-50.50 1
Chlorobenzene ND ug/L 11/11/22 15:13 108-90-70.50 1
Chloroethane ND ug/L 11/11/22 15:13 75-00-31.0 1
Chloroform ND ug/L 11/11/22 15:13 67-66-30.50 1
Chloromethane 1.3 ug/L 11/11/22 15:13 74-87-31.0 1
2-Chlorotoluene ND ug/L 11/11/22 15:13 95-49-80.50 1
4-Chlorotoluene ND ug/L 11/11/22 15:13 106-43-40.50 1
1,2-Dibromo-3-chloropropane ND ug/L 11/11/22 15:13 96-12-81.0 1
Dibromochloromethane ND ug/L 11/11/22 15:13 124-48-10.50 1
1,2-Dibromoethane (EDB)ND ug/L 11/11/22 15:13 106-93-40.50 1
Dibromomethane ND ug/L 11/11/22 15:13 74-95-30.50 1
1,2-Dichlorobenzene ND ug/L 11/11/22 15:13 95-50-10.50 1
1,3-Dichlorobenzene ND ug/L 11/11/22 15:13 541-73-10.50 1
1,4-Dichlorobenzene ND ug/L 11/11/22 15:13 106-46-70.50 1
Dichlorodifluoromethane ND ug/L 11/11/22 15:13 75-71-80.50 1
1,1-Dichloroethane ND ug/L 11/11/22 15:13 75-34-30.50 1
1,2-Dichloroethane ND ug/L 11/11/22 15:13 107-06-20.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-2 Lab ID:92635122008 Collected:11/03/22 15:30 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethene ND ug/L 11/11/22 15:13 75-35-40.50 1
cis-1,2-Dichloroethene ND ug/L 11/11/22 15:13 156-59-20.50 1
trans-1,2-Dichloroethene ND ug/L 11/11/22 15:13 156-60-50.50 1
1,2-Dichloropropane ND ug/L 11/11/22 15:13 78-87-50.50 1
1,3-Dichloropropane ND ug/L 11/11/22 15:13 142-28-90.50 1
2,2-Dichloropropane ND ug/L 11/11/22 15:13 594-20-70.50 1
1,1-Dichloropropene ND ug/L 11/11/22 15:13 563-58-60.50 1
cis-1,3-Dichloropropene ND ug/L 11/11/22 15:13 10061-01-50.50 1
trans-1,3-Dichloropropene ND ug/L 11/11/22 15:13 10061-02-60.50 1
Diisopropyl ether ND ug/L 11/11/22 15:13 108-20-30.50 1
Ethylbenzene 5.6 ug/L 11/11/22 15:13 100-41-40.50 1
Hexachloro-1,3-butadiene ND ug/L 11/11/22 15:13 87-68-32.0 1
Isopropylbenzene (Cumene)6.0 ug/L 11/11/22 15:13 98-82-80.50 1
Methylene Chloride ND ug/L 11/11/22 15:13 75-09-22.0 1
Methyl-tert-butyl ether 5.9 ug/L 11/11/22 15:13 1634-04-40.50 1
Naphthalene 25.3 ug/L 11/11/22 15:13 91-20-32.0 1
n-Propylbenzene 4.1 ug/L 11/11/22 15:13 103-65-10.50 1
Styrene ND ug/L 11/11/22 15:13 100-42-50.50 1
1,1,1,2-Tetrachloroethane ND ug/L 11/11/22 15:13 630-20-60.50 1
1,1,2,2-Tetrachloroethane ND ug/L 11/11/22 15:13 79-34-50.50 1
Tetrachloroethene ND ug/L 11/11/22 15:13 127-18-40.50 1
Toluene 2.6 ug/L 11/11/22 15:13 108-88-30.50 1
1,2,3-Trichlorobenzene ND ug/L 11/11/22 15:13 87-61-62.0 1
1,2,4-Trichlorobenzene ND ug/L 11/11/22 15:13 120-82-12.0 1
1,1,1-Trichloroethane ND ug/L 11/11/22 15:13 71-55-60.50 1
1,1,2-Trichloroethane ND ug/L 11/11/22 15:13 79-00-50.50 1
Trichloroethene ND ug/L 11/11/22 15:13 79-01-60.50 1
Trichlorofluoromethane ND ug/L 11/11/22 15:13 75-69-41.0 1
1,2,3-Trichloropropane ND ug/L 11/11/22 15:13 96-18-40.50 1
1,2,4-Trimethylbenzene 104 ug/L 11/11/22 15:13 95-63-60.50 1
1,3,5-Trimethylbenzene 20.1 ug/L 11/11/22 15:13 108-67-80.50 1
Vinyl chloride ND ug/L 11/11/22 15:13 75-01-41.0 1
m&p-Xylene 47.9 ug/L 11/11/22 15:13 179601-23-11.0 1
o-Xylene 33.7 ug/L 11/11/22 15:13 95-47-60.50 1
Surrogates
1,2-Dichloroethane-d4 (S)98 %11/11/22 15:13 17060-07-070-130 1
4-Bromofluorobenzene (S)96 %11/11/22 15:13 460-00-470-130 1
Toluene-d8 (S)99 %11/11/22 15:13 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-1 Lab ID:92635122009 Collected:11/03/22 15:40 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND ug/L 11/14/22 07:2811/14/22 07:28100010
Aliphatic (C09-C12)1480 ug/L 11/14/22 07:2811/14/22 07:28100010
Aromatic (C09-C10),Unadjusted 1390 ug/L 11/14/22 07:28 TPHC9C10A11/14/22 07:28100010
Total VPH 3420 ug/L 11/14/22 07:28 VPH11/14/22 07:28100010
Surrogates
2,5-Dibromotoluene (FID)96.0 %11/14/22 07:28 615-59-8FID11/14/22 07:2870.0-130 10
2,5-Dibromotoluene (PID)84.4 %11/14/22 07:28 615-59-8PID11/14/22 07:2870.0-130 10
Analytical Method: EPA 6020B Preparation Method: EPA 3010A
Pace Analytical Services - Asheville
6020 MET ICPMS
Arsenic 82.6 ug/L 11/10/22 06:07 7440-38-211/09/22 00:545.0 5
Barium 233 ug/L 11/10/22 06:07 7440-39-311/09/22 00:545.0 5
Cadmium 2.4 ug/L 11/10/22 06:07 7440-43-911/09/22 00:541.0 5
Chromium 106 ug/L 11/10/22 06:07 7440-47-311/09/22 00:545.0 5
Lead 143 ug/L 11/10/22 06:07 7439-92-111/09/22 00:545.0 5
Selenium ND ug/L 11/10/22 06:07 7782-49-2 D311/09/22 00:5410.0 5
Silver ND ug/L 11/10/22 06:07 7440-22-4 D311/09/22 00:542.0 5
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 11.6 ug/L 11/11/22 15:31 71-43-21.2 2.5
Bromobenzene ND ug/L 11/11/22 15:31 108-86-11.2 2.5
Bromochloromethane ND ug/L 11/11/22 15:31 74-97-51.2 2.5
Bromodichloromethane ND ug/L 11/11/22 15:31 75-27-41.2 2.5
Bromoform ND ug/L 11/11/22 15:31 75-25-21.2 2.5
Bromomethane ND ug/L 11/11/22 15:31 74-83-912.5 2.5
n-Butylbenzene 19.2 ug/L 11/11/22 15:31 104-51-81.2 2.5
sec-Butylbenzene ND ug/L 11/11/22 15:31 135-98-81.2 2.5
tert-Butylbenzene ND ug/L 11/11/22 15:31 98-06-61.2 2.5
Carbon tetrachloride ND ug/L 11/11/22 15:31 56-23-51.2 2.5
Chlorobenzene ND ug/L 11/11/22 15:31 108-90-71.2 2.5
Chloroethane ND ug/L 11/11/22 15:31 75-00-32.5 2.5
Chloroform ND ug/L 11/11/22 15:31 67-66-31.2 2.5
Chloromethane ND ug/L 11/11/22 15:31 74-87-32.5 2.5
2-Chlorotoluene ND ug/L 11/11/22 15:31 95-49-81.2 2.5
4-Chlorotoluene ND ug/L 11/11/22 15:31 106-43-41.2 2.5
1,2-Dibromo-3-chloropropane ND ug/L 11/11/22 15:31 96-12-82.5 2.5
Dibromochloromethane ND ug/L 11/11/22 15:31 124-48-11.2 2.5
1,2-Dibromoethane (EDB)ND ug/L 11/11/22 15:31 106-93-41.2 2.5
Dibromomethane ND ug/L 11/11/22 15:31 74-95-31.2 2.5
1,2-Dichlorobenzene ND ug/L 11/11/22 15:31 95-50-11.2 2.5
1,3-Dichlorobenzene ND ug/L 11/11/22 15:31 541-73-11.2 2.5
1,4-Dichlorobenzene ND ug/L 11/11/22 15:31 106-46-71.2 2.5
Dichlorodifluoromethane ND ug/L 11/11/22 15:31 75-71-81.2 2.5
1,1-Dichloroethane ND ug/L 11/11/22 15:31 75-34-31.2 2.5
1,2-Dichloroethane ND ug/L 11/11/22 15:31 107-06-21.2 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 32
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Sample:MW-1 Lab ID:92635122009 Collected:11/03/22 15:40 Received:11/04/22 14:30 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
1,1-Dichloroethene ND ug/L 11/11/22 15:31 75-35-41.2 2.5
cis-1,2-Dichloroethene ND ug/L 11/11/22 15:31 156-59-21.2 2.5
trans-1,2-Dichloroethene ND ug/L 11/11/22 15:31 156-60-51.2 2.5
1,2-Dichloropropane ND ug/L 11/11/22 15:31 78-87-51.2 2.5
1,3-Dichloropropane ND ug/L 11/11/22 15:31 142-28-91.2 2.5
2,2-Dichloropropane ND ug/L 11/11/22 15:31 594-20-71.2 2.5
1,1-Dichloropropene ND ug/L 11/11/22 15:31 563-58-61.2 2.5
cis-1,3-Dichloropropene ND ug/L 11/11/22 15:31 10061-01-51.2 2.5
trans-1,3-Dichloropropene ND ug/L 11/11/22 15:31 10061-02-61.2 2.5
Diisopropyl ether ND ug/L 11/11/22 15:31 108-20-31.2 2.5
Ethylbenzene 152 ug/L 11/11/22 15:31 100-41-41.2 2.5
Hexachloro-1,3-butadiene ND ug/L 11/11/22 15:31 87-68-35.0 2.5
Isopropylbenzene (Cumene)20.5 ug/L 11/11/22 15:31 98-82-81.2 2.5
Methylene Chloride ND ug/L 11/11/22 15:31 75-09-25.0 2.5
Methyl-tert-butyl ether 2.3 ug/L 11/11/22 15:31 1634-04-41.2 2.5
Naphthalene 83.0 ug/L 11/11/22 15:31 91-20-35.0 2.5
n-Propylbenzene 52.5 ug/L 11/11/22 15:31 103-65-11.2 2.5
Styrene ND ug/L 11/11/22 15:31 100-42-51.2 2.5
1,1,1,2-Tetrachloroethane ND ug/L 11/11/22 15:31 630-20-61.2 2.5
1,1,2,2-Tetrachloroethane ND ug/L 11/11/22 15:31 79-34-51.2 2.5
Tetrachloroethene ND ug/L 11/11/22 15:31 127-18-41.2 2.5
Toluene 324 ug/L 11/11/22 15:31 108-88-31.2 2.5
1,2,3-Trichlorobenzene ND ug/L 11/11/22 15:31 87-61-65.0 2.5
1,2,4-Trichlorobenzene ND ug/L 11/11/22 15:31 120-82-15.0 2.5
1,1,1-Trichloroethane ND ug/L 11/11/22 15:31 71-55-61.2 2.5
1,1,2-Trichloroethane ND ug/L 11/11/22 15:31 79-00-51.2 2.5
Trichloroethene ND ug/L 11/11/22 15:31 79-01-61.2 2.5
Trichlorofluoromethane ND ug/L 11/11/22 15:31 75-69-42.5 2.5
1,2,3-Trichloropropane ND ug/L 11/11/22 15:31 96-18-41.2 2.5
1,2,4-Trimethylbenzene 395 ug/L 11/11/22 15:31 95-63-61.2 2.5
1,3,5-Trimethylbenzene 107 ug/L 11/11/22 15:31 108-67-81.2 2.5
Vinyl chloride ND ug/L 11/11/22 15:31 75-01-42.5 2.5
m&p-Xylene 590 ug/L 11/11/22 15:31 179601-23-12.5 2.5
o-Xylene 261 ug/L 11/11/22 15:31 95-47-61.2 2.5
Surrogates
1,2-Dichloroethane-d4 (S)97 %11/11/22 15:31 17060-07-070-130 2.5
4-Bromofluorobenzene (S)95 %11/11/22 15:31 460-00-470-130 2.5
Toluene-d8 (S)99 %11/11/22 15:31 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1958804
KS LRH/MADEPV/MTDEQ
VPH/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92635122007, 92635122008, 92635122009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3860532-2
Associated Lab Samples:92635122007, 92635122008, 92635122009
Matrix:Water
Analyzed
Aliphatic (C05-C08)ug/L ND 100 11/13/22 20:33
Aliphatic (C09-C12)ug/L ND 100 11/13/22 20:33
Aromatic (C09-C10),Unadjusted ug/L ND 100 11/13/22 20:33
Total VPH ug/L ND 100 11/13/22 20:33
2,5-Dibromotoluene (FID)%88.4 70.0-130 11/13/22 20:33
2,5-Dibromotoluene (PID)%79.1 70.0-130 11/13/22 20:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3860532-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3860532-3
Aliphatic (C05-C08)ug/L 10801200 90.0 70.0-13080.1961 11.7 25
Aliphatic (C09-C12)ug/L 13501400 96.4 70.0-13080.01120 18.6 25
Aromatic (C09-C10),Unadjusted ug/L 211200 105 70.0-13090.5181 15.3 25
Total VPH ug/L 26402800 94.3 70.0-13080.72260 15.5 25
2,5-Dibromotoluene (FID)%97.7 70.0-13094.0
2,5-Dibromotoluene (PID)%87.0 70.0-13085.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1961050
KS LRH/MADEPV/MTDEQ
VPH/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92635122001, 92635122002, 92635122006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3863148-3
Associated Lab Samples:92635122001, 92635122002, 92635122006
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 5.00 11/19/22 23:30
Aliphatic (C09-C12)mg/kg ND 5.00 11/19/22 23:30
Aromatic (C09-C10),Unadjusted mg/kg ND 5.00 11/19/22 23:30
Total VPH mg/kg ND 5.00 11/19/22 23:30
2,5-Dibromotoluene (FID)%82.8 70.0-130 11/19/22 23:30
2,5-Dibromotoluene (PID)%84.9 70.0-130 11/19/22 23:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3863148-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3863148-2
Aliphatic (C05-C08)mg/kg 51.260.0 85.3 70.0-13086.351.8 1.17 25
Aliphatic (C09-C12)mg/kg 53.770.0 76.7 70.0-13080.456.3 4.73 25
Aromatic (C09-C10),Unadjusted mg/kg 10.210.0 102 70.0-13010610.6 3.85 25
Total VPH mg/kg 115140 82.1 70.0-13085.0119 3.42 25
2,5-Dibromotoluene (FID)%98.8 70.0-13096.4
2,5-Dibromotoluene (PID)%100 70.0-13097.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1962729
KS LRH/MADEPV/MTDEQ
VPH/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92635122003, 92635122004, 92635122005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3863712-3
Associated Lab Samples:92635122003, 92635122004, 92635122005
Matrix:Solid
Analyzed
Aliphatic (C05-C08)mg/kg ND 5.00 11/21/22 09:54
Aliphatic (C09-C12)mg/kg ND 5.00 11/21/22 09:54
Aromatic (C09-C10),Unadjusted mg/kg ND 5.00 11/21/22 09:54
Total VPH mg/kg ND 5.00 11/21/22 09:54
2,5-Dibromotoluene (FID)%84.9 70.0-130 11/21/22 09:54
2,5-Dibromotoluene (PID)%86 70.0-130 11/21/22 09:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3863712-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3863712-2
Aliphatic (C05-C08)mg/kg 52.360.0 87.2 70.0-13093.055.8 6.48 25
Aliphatic (C09-C12)mg/kg 62.270.0 88.9 70.0-13086.360.4 2.94 25
Aromatic (C09-C10),Unadjusted mg/kg 11.910.0 119 70.0-13011211.2 6.06 25
Total VPH mg/kg 126140 90.0 70.0-13090.7127 0.791 25
2,5-Dibromotoluene (FID)%103 70.0-13098.1
2,5-Dibromotoluene (PID)%103 70.0-13097.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735547
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92635122001, 92635122002, 92635122004, 92635122005, 92635122006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3828010
Associated Lab Samples:92635122001, 92635122002, 92635122004, 92635122005, 92635122006
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.0 11/08/22 13:00
4-Bromofluorobenzene (S)%93 66-130 11/08/22 13:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3828011LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 47.550 95 70-130
4-Bromofluorobenzene (S)%96 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3828013MATRIX SPIKE SAMPLE:
MSSpike
Result
92634858006
Gas Range Organics (C6-C10)mg/kg 71.164.9 108 65-146ND
4-Bromofluorobenzene (S)%98 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92634751030
3828012SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg NDND
4-Bromofluorobenzene (S)%9493
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735856
EPA 5030B
EPA 8015C
Gasoline Range Organics
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92635122003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3829633
Associated Lab Samples:92635122003
Matrix:Solid
Analyzed
Gas Range Organics (C6-C10)mg/kg ND 6.1 11/09/22 13:18
4-Bromofluorobenzene (S)%94 66-130 11/09/22 13:18
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3829634LABORATORY CONTROL SAMPLE:
LCSSpike
Gas Range Organics (C6-C10)mg/kg 46.450.5 92 70-130
4-Bromofluorobenzene (S)%97 66-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3829636MATRIX SPIKE SAMPLE:
MSSpike
Result
92635371005
Gas Range Organics (C6-C10)mg/kg 111131 84 65-146ND
4-Bromofluorobenzene (S)%96 66-130
Parameter Units
Dup
Result QualifiersRPDResult
92635363001
3829635SAMPLE DUPLICATE:
Gas Range Organics (C6-C10)mg/kg 11.8JND
4-Bromofluorobenzene (S)%100101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735753
EPA 3010A
EPA 6020B
6020 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92635122007, 92635122008, 92635122009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3829284
Associated Lab Samples:92635122007, 92635122008, 92635122009
Matrix:Water
Analyzed
Arsenic ug/L ND 1.0 11/10/22 04:22
Barium ug/L ND 1.0 11/10/22 04:22
Cadmium ug/L ND 0.20 11/10/22 04:22
Chromium ug/L ND 1.0 11/10/22 04:22
Lead ug/L ND 1.0 11/10/22 04:22
Selenium ug/L ND 2.0 11/10/22 04:22
Silver ug/L ND 0.40 11/10/22 04:22
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3829285LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 49.850 100 80-120
Barium ug/L 51.250 102 80-120
Cadmium ug/L 51.350 103 80-120
Chromium ug/L 49.250 98 80-120
Lead ug/L 50.550 101 80-120
Selenium ug/L 49.450 99 80-120
Silver ug/L 25.825 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3829286MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92633655001
3829287
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 20.17J 50.5 51.4
Barium ug/L 20.73J 53.3 52.2
Cadmium ug/L 30.18J 51.1 52.5
Chromium ug/L 0ND50.2 50.0
Lead ug/L 20.095J 50.7 52.0
Selenium ug/L 20.13J 49.9 50.9
Silver ug/L 2ND25.3 25.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
736499
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92635122007, 92635122008, 92635122009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3833116
Associated Lab Samples:92635122007, 92635122008, 92635122009
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 11/11/22 14:01
1,1,1-Trichloroethane ug/L ND 0.50 11/11/22 14:01
1,1,2,2-Tetrachloroethane ug/L ND 0.50 11/11/22 14:01
1,1,2-Trichloroethane ug/L ND 0.50 11/11/22 14:01
1,1-Dichloroethane ug/L ND 0.50 11/11/22 14:01
1,1-Dichloroethene ug/L ND 0.50 11/11/22 14:01
1,1-Dichloropropene ug/L ND 0.50 11/11/22 14:01
1,2,3-Trichlorobenzene ug/L ND 2.0 11/11/22 14:01
1,2,3-Trichloropropane ug/L ND 0.50 11/11/22 14:01
1,2,4-Trichlorobenzene ug/L ND 2.0 11/11/22 14:01
1,2,4-Trimethylbenzene ug/L ND 0.50 11/11/22 14:01
1,2-Dibromo-3-chloropropane ug/L ND 1.0 11/11/22 14:01
1,2-Dibromoethane (EDB)ug/L ND 0.50 11/11/22 14:01
1,2-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01
1,2-Dichloroethane ug/L ND 0.50 11/11/22 14:01
1,2-Dichloropropane ug/L ND 0.50 11/11/22 14:01
1,3,5-Trimethylbenzene ug/L ND 0.50 11/11/22 14:01
1,3-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01
1,3-Dichloropropane ug/L ND 0.50 11/11/22 14:01
1,4-Dichlorobenzene ug/L ND 0.50 11/11/22 14:01
2,2-Dichloropropane ug/L ND 0.50 11/11/22 14:01
2-Chlorotoluene ug/L ND 0.50 11/11/22 14:01
4-Chlorotoluene ug/L ND 0.50 11/11/22 14:01
Benzene ug/L ND 0.50 11/11/22 14:01
Bromobenzene ug/L ND 0.50 11/11/22 14:01
Bromochloromethane ug/L ND 0.50 11/11/22 14:01
Bromodichloromethane ug/L ND 0.50 11/11/22 14:01
Bromoform ug/L ND 0.50 11/11/22 14:01
Bromomethane ug/L ND 5.0 11/11/22 14:01
Carbon tetrachloride ug/L ND 0.50 11/11/22 14:01
Chlorobenzene ug/L ND 0.50 11/11/22 14:01
Chloroethane ug/L ND 1.0 11/11/22 14:01
Chloroform ug/L ND 0.50 11/11/22 14:01
Chloromethane ug/L ND 1.0 11/11/22 14:01
cis-1,2-Dichloroethene ug/L ND 0.50 11/11/22 14:01
cis-1,3-Dichloropropene ug/L ND 0.50 11/11/22 14:01
Dibromochloromethane ug/L ND 0.50 11/11/22 14:01
Dibromomethane ug/L ND 0.50 11/11/22 14:01
Dichlorodifluoromethane ug/L ND 0.50 11/11/22 14:01
Diisopropyl ether ug/L ND 0.50 11/11/22 14:01
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3833116
Associated Lab Samples:92635122007, 92635122008, 92635122009
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 11/11/22 14:01
Hexachloro-1,3-butadiene ug/L ND 2.0 11/11/22 14:01
Isopropylbenzene (Cumene)ug/L ND 0.50 11/11/22 14:01
m&p-Xylene ug/L ND 1.0 11/11/22 14:01
Methyl-tert-butyl ether ug/L ND 0.50 11/11/22 14:01
Methylene Chloride ug/L ND 2.0 11/11/22 14:01
n-Butylbenzene ug/L ND 0.50 11/11/22 14:01
n-Propylbenzene ug/L ND 0.50 11/11/22 14:01
Naphthalene ug/L ND 2.0 11/11/22 14:01
o-Xylene ug/L ND 0.50 11/11/22 14:01
sec-Butylbenzene ug/L ND 0.50 11/11/22 14:01
Styrene ug/L ND 0.50 11/11/22 14:01
tert-Butylbenzene ug/L ND 0.50 11/11/22 14:01
Tetrachloroethene ug/L ND 0.50 11/11/22 14:01
Toluene ug/L ND 0.50 11/11/22 14:01
trans-1,2-Dichloroethene ug/L ND 0.50 11/11/22 14:01
trans-1,3-Dichloropropene ug/L ND 0.50 11/11/22 14:01
Trichloroethene ug/L ND 0.50 11/11/22 14:01
Trichlorofluoromethane ug/L ND 1.0 11/11/22 14:01
Vinyl chloride ug/L ND 1.0 11/11/22 14:01
1,2-Dichloroethane-d4 (S)%100 70-130 11/11/22 14:01
4-Bromofluorobenzene (S)%98 70-130 11/11/22 14:01
Toluene-d8 (S)%99 70-130 11/11/22 14:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3833117LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.450 97 60-140
1,1,1-Trichloroethane ug/L 43.050 86 60-140
1,1,2,2-Tetrachloroethane ug/L 48.050 96 60-140
1,1,2-Trichloroethane ug/L 47.550 95 60-140
1,1-Dichloroethane ug/L 42.250 84 60-140
1,1-Dichloroethene ug/L 43.050 86 60-140
1,1-Dichloropropene ug/L 46.850 94 60-140
1,2,3-Trichlorobenzene ug/L 51.050 102 60-140
1,2,3-Trichloropropane ug/L 49.450 99 60-140
1,2,4-Trichlorobenzene ug/L 46.450 93 60-140
1,2,4-Trimethylbenzene ug/L 44.550 89 60-140
1,2-Dibromo-3-chloropropane ug/L 49.050 98 60-140
1,2-Dibromoethane (EDB)ug/L 49.150 98 60-140
1,2-Dichlorobenzene ug/L 47.150 94 60-140
1,2-Dichloroethane ug/L 43.750 87 60-140
1,2-Dichloropropane ug/L 47.650 95 60-140
1,3,5-Trimethylbenzene ug/L 43.550 87 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3833117LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 46.750 93 60-140
1,3-Dichloropropane ug/L 47.850 96 60-140
1,4-Dichlorobenzene ug/L 45.050 90 60-140
2,2-Dichloropropane ug/L 36.750 73 60-140
2-Chlorotoluene ug/L 43.250 86 60-140
4-Chlorotoluene ug/L 44.550 89 60-140
Benzene ug/L 43.550 87 60-140
Bromobenzene ug/L 46.150 92 60-140
Bromochloromethane ug/L 43.250 86 60-140
Bromodichloromethane ug/L 44.750 89 60-140
Bromoform ug/L 49.850 100 60-140
Bromomethane ug/L 45.750 91 60-140
Carbon tetrachloride ug/L 44.850 90 60-140
Chlorobenzene ug/L 46.050 92 60-140
Chloroethane ug/L 43.650 87 60-140
Chloroform ug/L 42.350 85 60-140
Chloromethane ug/L 45.350 91 60-140
cis-1,2-Dichloroethene ug/L 43.150 86 60-140
cis-1,3-Dichloropropene ug/L 45.450 91 60-140
Dibromochloromethane ug/L 48.150 96 60-140
Dibromomethane ug/L 48.350 97 60-140
Dichlorodifluoromethane ug/L 45.750 91 60-140
Diisopropyl ether ug/L 44.650 89 60-140
Ethylbenzene ug/L 44.650 89 60-140
Hexachloro-1,3-butadiene ug/L 43.350 87 60-140
Isopropylbenzene (Cumene)ug/L 43.850 88 60-140
m&p-Xylene ug/L 89.0100 89 60-140
Methyl-tert-butyl ether ug/L 47.050 94 60-140
Methylene Chloride ug/L 44.750 89 60-140
n-Butylbenzene ug/L 41.950 84 60-140
n-Propylbenzene ug/L 42.550 85 60-140
Naphthalene ug/L 53.950 108 60-140
o-Xylene ug/L 44.850 90 60-140
sec-Butylbenzene ug/L 43.350 87 60-140
Styrene ug/L 45.950 92 60-140
tert-Butylbenzene ug/L 37.350 75 60-140
Tetrachloroethene ug/L 44.450 89 60-140
Toluene ug/L 43.750 87 60-140
trans-1,2-Dichloroethene ug/L 44.050 88 60-140
trans-1,3-Dichloropropene ug/L 46.050 92 60-140
Trichloroethene ug/L 48.550 97 60-140
Trichlorofluoromethane ug/L 42.450 85 60-140
Vinyl chloride ug/L 47.450 95 60-140
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3833118MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92635033002
3833119
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 114 60-140104 920ND22.8 20.9
1,1,1-Trichloroethane ug/L 20 118 60-140110 720ND23.5 21.9
1,1,2,2-Tetrachloroethane ug/L 20 110 60-140102 720ND22.0 20.4
1,1,2-Trichloroethane ug/L 20 107 60-140104 320ND21.4 20.9
1,1-Dichloroethane ug/L 20 108 60-140102 620ND21.6 20.4
1,1-Dichloroethene ug/L 20 114 60-140112 220ND22.8 22.4
1,1-Dichloropropene ug/L 20 127 60-140121 520ND25.3 24.1
1,2,3-Trichlorobenzene ug/L 20 107 60-140106 020ND21.3 21.2
1,2,3-Trichloropropane ug/L 20 104 60-14094 1020ND20.8 18.8
1,2,4-Trichlorobenzene ug/L 20 108 60-140101 720ND21.7 20.1
1,2,4-Trimethylbenzene ug/L 20 108 60-140104 520ND21.7 20.7
1,2-Dibromo-3-chloropropane ug/L 20 101 60-14096 520ND20.2 19.2
1,2-Dibromoethane (EDB)ug/L 20 110 60-140104 620ND22.0 20.7
1,2-Dichlorobenzene ug/L 20 106 60-140101 520ND21.3 20.2
1,2-Dichloroethane ug/L 20 107 60-140105 220ND21.5 21.0
1,2-Dichloropropane ug/L 20 108 60-140102 620ND21.7 20.3
1,3,5-Trimethylbenzene ug/L 20 114 60-140108 520ND22.7 21.6
1,3-Dichlorobenzene ug/L 20 106 60-140104 220ND21.1 20.8
1,3-Dichloropropane ug/L 20 107 60-140101 620ND21.4 20.2
1,4-Dichlorobenzene ug/L 20 109 60-140100 820ND21.7 20.1
2,2-Dichloropropane ug/L 20 119 60-140113 520ND23.8 22.7
2-Chlorotoluene ug/L 20 101 60-140104 320ND20.2 20.8
4-Chlorotoluene ug/L 20 101 60-140104 320ND20.2 20.8
Benzene ug/L 20 105 60-14099 6200.53 21.5 20.2
Bromobenzene ug/L 20 106 60-140102 320ND21.1 20.4
Bromochloromethane ug/L 20 112 60-140108 420ND22.5 21.7
Bromodichloromethane ug/L 20 110 60-140105 520ND22.0 21.0
Bromoform ug/L 20 114 60-140107 620ND22.8 21.4
Bromomethane ug/L 20 112 60-140106 520ND22.3 21.2
Carbon tetrachloride ug/L 20 117 60-140111 520ND23.4 22.3
Chlorobenzene ug/L 20 110 60-140102 720ND21.9 20.4
Chloroethane ug/L 20 121 60-140116 420ND24.2 23.2
Chloroform ug/L 20 105 60-140104 220ND21.1 20.8
Chloromethane ug/L 20 125 60-140117 720ND25.1 23.5
cis-1,2-Dichloroethene ug/L 20 111 60-140108 320ND22.2 21.5
cis-1,3-Dichloropropene ug/L 20 112 60-140109 220ND22.3 21.8
Dibromochloromethane ug/L 20 113 60-140103 1020ND22.7 20.5
Dibromomethane ug/L 20 108 60-140102 620ND21.6 20.4
Dichlorodifluoromethane ug/L 20 118 60-140111 720ND23.7 22.1
Diisopropyl ether ug/L 20 104 60-140100 420ND20.8 19.9
Ethylbenzene ug/L 20 112 60-140103 820ND22.4 20.7
Hexachloro-1,3-butadiene ug/L 20 121 60-140116 420ND24.1 23.2
Isopropylbenzene (Cumene)ug/L 20 113 60-140103 1020ND22.6 20.5
m&p-Xylene ug/L 40 114 60-140104 940ND45.5 41.6
Methyl-tert-butyl ether ug/L 20 107 60-140103 3202.2 23.7 22.9
Methylene Chloride ug/L 20 92 60-14089 320ND18.4 17.8
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
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Huntersville, NC 28078
[phone]
Page 25 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3833118MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92635033002
3833119
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L 20 117 60-140109 720ND23.5 21.8
n-Propylbenzene ug/L 20 111 60-140107 420ND22.2 21.3
Naphthalene ug/L 20 102 60-140100 220ND20.5 20.0
o-Xylene ug/L 20 113 60-140106 620ND22.6 21.2
sec-Butylbenzene ug/L 20 113 60-140107 620ND22.6 21.3
Styrene ug/L 20 111 60-140100 1020ND22.2 20.1
tert-Butylbenzene ug/L 20 97 60-14094 320ND19.4 18.8
Tetrachloroethene ug/L 20 118 60-140107 1020ND23.6 21.4
Toluene ug/L 20 106 60-140102 420ND21.2 20.3
trans-1,2-Dichloroethene ug/L 20 114 60-140110 420ND22.8 21.9
trans-1,3-Dichloropropene ug/L 20 112 60-140107 420ND22.3 21.5
Trichloroethene ug/L 20 114 60-140111 220ND22.7 22.2
Trichlorofluoromethane ug/L 20 116 60-140109 620ND23.1 21.8
Vinyl chloride ug/L 20 126 60-140121 420ND25.2 24.1
1,2-Dichloroethane-d4 (S)%100 70-130108
4-Bromofluorobenzene (S)%104 70-130101
Toluene-d8 (S)%98 70-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 26 of 32
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
735422
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92635122001, 92635122002, 92635122003, 92635122004, 92635122005, 92635122006
Parameter Units
Dup
Result QualifiersRPDResult
92634902004
3827647SAMPLE DUPLICATE:
Percent Moisture %22.9 N2322.3
Parameter Units
Dup
Result QualifiersRPDResult
92635118002
3827648SAMPLE DUPLICATE:
Percent Moisture %24.3 N2024.2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 32
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
WORKORDER QUALIFIERS
WO: 92635122
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size, and any dilutions. Please
see the Analytical Results section of this report for applicable Dry Weight / %M per Sample ID.[1]
SAMPLE QUALIFIERS
Sample: 92635122007
Volatile Petroleum Hydrocarbons by Method MADEPV - Lowest possible dilution due to sample foaming.[1]
Sample: 92635122008
Volatile Petroleum Hydrocarbons by Method MADEPV - Lowest possible dilution due to sample foaming.[1]
Sample: 92635122009
Volatile Petroleum Hydrocarbons by Method MADEPV - Lowest possible dilution due to sample foaming.[1]
ANALYTE QUALIFIERS
Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 32
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92635122
PELICANS SNOBALLS UST REMOVAL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92635122007 1958804 1958804MW-3 MADEPV MADEP VPH
92635122008 1958804 1958804MW-2 MADEPV MADEP VPH
92635122009 1958804 1958804MW-1 MADEPV MADEP VPH
92635122001 1961050 1961050L-6 MADEPV MADEP VPH
92635122002 1961050 1961050L-7 MADEPV MADEP VPH
92635122003 1962729 1962729D-1 MADEPV MADEP VPH
92635122004 1962729 1962729D-2 MADEPV MADEP VPH
92635122005 1962729 1962729D-3 MADEPV MADEP VPH
92635122006 1961050 1961050D-4 MADEPV MADEP VPH
92635122001 735547 735581L-6 EPA 5030B EPA 8015C
92635122002 735547 735581L-7 EPA 5030B EPA 8015C
92635122003 735856 735885D-1 EPA 5030B EPA 8015C
92635122004 735547 735581D-2 EPA 5030B EPA 8015C
92635122005 735547 735581D-3 EPA 5030B EPA 8015C
92635122006 735547 735581D-4 EPA 5030B EPA 8015C
92635122007 735753 735761MW-3 EPA 3010A EPA 6020B
92635122008 735753 735761MW-2 EPA 3010A EPA 6020B
92635122009 735753 735761MW-1 EPA 3010A EPA 6020B
92635122007 736499MW-3 SM 6200B
92635122008 736499MW-2 SM 6200B
92635122009 736499MW-1 SM 6200B
92635122001 735422L-6 SW-846
92635122002 735422L-7 SW-846
92635122003 735422D-1 SW-846
92635122004 735422D-2 SW-846
92635122005 735422D-3 SW-846
92635122006 735422D-4 SW-846
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 11/29/2022 04:53 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 32
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