WI-28368_47621_CA_CSA_20220909

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 12, 2022

Mr. Stephen Kay
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Comprehensive Site Assessment Report
June 2022
RL Village Store
5194 South NC 41 Highway
Wallace, Duplin County
North Carolina
Facility ID Number: 00-0-0000036169
Incident Number: 47621
GRI Project Number: 5586

Dear Mr. Kay,

Please find enclosed the referenced report for the above mentioned site.
If you have any questions, please contact Rae Brown at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Mills Bryant; RL Village Store, LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Comprehensive Site Assessment Report
June 2022
RL Village Store
5194 South NC 41 Highway
Wallace, Duplin County
North Carolina
Facility ID Number: 00-0-0000036169
Incident Number: 47621
GRI Project Number: 5586

Prepared for:

Mr. Mills Bryant
RL Village Store, LLC
5194 S NC 41 Highway
Wallace, North Carolina 28466

September 9, 2022

Rae Troiano Brown, P.G.
Project Manager
Eric Eubanks, P.G.
Staff Geologist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
i
EXECUTIVE SUMMARY
The RL Village Store site is an active convenience store and gasoline retail facility located at 5194 South
NC 41 Highway in Wallace, Duplin County, North Carolina. The site is covered by concrete and asphalt.
The surrounding properties are a mix of residential, commercial and office. There are one 15,000-gallon
gasoline UST and one 10,000-gallon gasoline UST currently in use at the site with eight associated gasoline
dispenser islands.

On October 12, 2020, one non-passing UST spill bucket was reported during triennial integrity testing
activities and on February 15, 2021, GRI conducted a site check at the subject site. Site Check results
confirmed a release at the site and an LSA was required.

Based on the April 2021 receptor survey, nine water supply wells were identified within a 1,500-foot
radius of the site. One non-potable well (WSW-6) was identified within 1,000 feet of the site. No water
supply wells were identified within 250 feet of the source area. No surface water bodies were identified
within 500 feet of the source area. Public water is available to the site and the surrounding properties.

On June 1, 2021, three monitoring wells were installed and sampled as part of the Phase II LSA activities.
Based on the results of the LSA activities, a CSA was required.

On June 28, 2022, and June 29, 2022, four Type II monitoring wells and one Type III telescoping well were
installed as part of the CSA activities. Please note, MW-1 was re-drilled to a depth of 18-feet to allow for
seasonal low water levels. Contaminant concentrations of benzene, toluene, ethylbenzene, xylenes,
naphthalene, tert-amyl alcohol, tert-butyl alcohol, n-butylbenzene, sec-butylbenzene, isopropylbenzene,
p-isopropyltoluene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, C5-C8 aliphatics,
C9-C12 aliphatics, and/or C9-C10 aromatics reported in the ground water samples collected from MW-1R,
MW-2, MW-3, and MW-5 through MW-8 exceeded the MACs. All reported contaminant concentrations
were below GCLs.

During monitoring well installation activities, twenty-nine soil samples were collected and screened using
a PID. The sample from each soil boring with the highest PID reading was submitted for analysis of TPH-
GRO and TPH-DRO using UVF technology. The two samples with the highest reported concentrations of
TPH GRO and DRO were submitted for laboratory analysis. Concentrations of xylenes, naphthalene, n-
butylbenzene, isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene,
and/or C9-C10 aromatics reported in SS-1-15’ and MW-1R 10’ exceeded soil-to-water MCCs.

Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts, and sands to varying depths (approximately 0.5 to 30 feet) where a layer of fossiliferous
limestone was encountered, overlaying clay to a depth of at least 45’ BGL. Ground water flow was
generally toward the east with a gradient of less than 0.01 feet/foot. The vertical hydraulic gradient was
not calculated due to insufficient well volume for gauging in TW-1. Rising head slug tests were conducted

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
ii
on MW-7, MW-8, and TW-1. The average hydraulic conductivity and seepage velocity for the Type II
monitoring wells were 9.078 x 10-3 feet per minute (13.07 feet per day) and 2.61 x 10-1 feet per day (95.4
feet per year). The hydraulic conductivity and seepage velocity in the Type III monitoring were 4.678 x 10-
5 feet per minute (0.067 feet per day) and 3.37 x 10-3 feet per day (1.23 feet per year), respectively.

Based on the results of this well installation, soil sampling, and ground water sampling event, this site no
longer meets the criteria of an intermediate risk site. Due to the lack of receptors and none of the
reported contaminant concentrations exceeding GCLs, an NRP should be filed for the property, and the
incident should be closed with an NFA.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
iii
SITE INFORMATION
1. Site Identification
 RL Village Store (Facility ID 00-0-0000036169)
 Incident Number 47621 – Intermediate Risk (I120D)
 Location of Source Area: 5194 South NC 41 Highway
Wallace, NC 28466
Duplin County
34.757452°N, 77.949057°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

UST Owner (Table 1)
RL Village Store, LLC
PO Box 1139
Wallace, NC 28466
910-463-8746

Drilling Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]

UST Operator
RL Village Store, LLC
PO Box 1139
Wallace, NC 28466
910-463-8746
Property Owner
RL Village Store, LLC
PO Box 1139
Wallace, NC 28466
910-463-8746

Property Occupant
RL Village Store, LLC
PO Box 1139
Wallace, NC 28466
910-463-8746

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010
Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
State Certification No. 573
704-529-6364

3. Information about Release
 Release was discovered on March 5, 2021.
 An unknown amount of product was released from the leaking UST System via a non-passing spill
bucket.
 One 15,000-gallon UST and one 10,000-gallon gasoline UST are in use at this site.

Certification:

I, John M. Brown, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the company are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
iv
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWAP: Source Water Assessment and
Protection
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586

TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ........................................................................................................................... iii
ACRONYMS ....................................................................................................................................... iv
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 RECEPTOR INFORMATION ........................................................................................................2
3.0 LAND USE ................................................................................................................................3
4.0 SOIL ASSESSMENT ...................................................................................................................3
5.0 GROUND WATER ASSESSMENT ................................................................................................4
6.0 HYDROGEOLOGIC INVESTIGATION ...........................................................................................6
7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY .............................................................................7
8.0 SITE GEOLOGY AND HYDROGEOLOGY ......................................................................................7
9.0 DISCUSSION ............................................................................................................................7
10.0 CONCLUSIONS AND RECOMMENDATIONS ...............................................................................8
11.0 PUBLIC NOTICE ........................................................................................................................8
12.0 LIMITATIONS ...........................................................................................................................8
13.0 REFERENCES ............................................................................................................................9

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Soil Quality Map
Figure 5: Cross-Section A-A’
Figure 6: Cross-Section B-B’
Figure 7: Ground Water Quality Map
Figure 8: Water Table Surface Map
TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Receptor Information
Table 4: Land Use Information
Table 5: Adjacent Property Owner Information
Table 6a: Summary of Soil Sample Analytical Results
Table 6b: Summary of Soil Sample Analytical Results – Field Data
Table 7: Summary of Ground Water Sample Analytical Results
Table 8: Well Construction and Gauging Information
Table 9: Summary of Slug Test Analyses

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586

APPENDICES
Appendix A: State Correspondence
Appendix B: UVF Report
Appendix C: Well Photographs
Appendix D: Well Permit, Well Construction Records, and Subsurface Logs
Appendix E: Laboratory Analytical Report
Appendix F: Slug Test Data
Appendix G: Public Notification Letters

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the June 2022 CSA activities at the RL Village Store site, located at 5194 South
NC 41 Highway in Wallace, Duplin County, North Carolina (Figure 1). These activities were conducted in
accordance with GRI Proposal No. 22-109, which was submitted to the NCDEQ on March 10, 2022, and
was approved as Task Authorization No. 47621-4 on March 24, 2022. State correspondence has been
included as Appendix A.

The site is currently owned and operated by RL Village Store LLC as a petroleum retail facility. One 15,000-
gallon gasoline UST and one 10,000-gallon gasoline UST are currently in use at the site with eight
associated gasoline dispenser islands. UST owner/operator information and UST system information are
included as Tables 1 and 2, respectively. The Registered Tank Report is shown below:

On October 12, 2020, hydrostatic tests were conducted on the spill buckets associated with the active UST
system. The spill bucket for the 15,000-gallon UST received a non-passing test and was subsequently
replaced. Therefore, a site check was required. On February 15, 2021, GRI conducted a site check.
However, pea gravel in the area of the 15,000-gallon gasoline UST spill bucket prevented collection of a
soil sample. Therefore, a monitoring well was installed and sampled. The benzene concentration
exceeded the GCL. On March 18, 2021, based on these results, the NCDEQ issued a NORR that required
an LSA.

On June 16, 2021, during Phase II LSA activities, three additional monitoring wells were installed at the
site in order to determine the ground water flow direction. Monitoring wells MW-2 through MW-4 were
each installed to a total depth of 18 feet BGS each with a screened interval of 10 feet. One soil sample
(SB-1-5’) was collected in the vicinity of MW-1, beneath the pea gravel. Contaminant concentrations
reported in the soil sample exceeded the soil-to-water MCCs. Contaminant concentrations reported in
the monitoring wells exceeded the MACs. The concentration of benzene in MW-3 exceeded the GCL.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
2
In March 2022, a CSA was requested in order to delineate the horizontal and vertical extent of the
petroleum contamination. On June 28-29, 2022, four additional Type II monitoring wells (MW-5 through
MW-8) and one Type III telescoping monitoring well (TW-1) were installed as part of the CSA activities.
MW-1 was replaced by MW-1R, which was installed to the same depth as the other site monitoring wells
(18 feet BGL with a fifteen-foot screened interval). Contaminant concentrations reported in the ground
water samples collected from MW-1R, MW-2, MW-3, and MW-5 through MW-8 exceeded the MACs.

During monitoring well installation activities, twenty-nine soil samples were collected and screened using
a PID. The eleven most contaminated soil samples, as indicated by the PID, were submitted for UVF
analysis by the mobile laboratory for gasoline and diesel range TPH. Of those eleven samples, the two soil
samples with the highest concentration were submitted for laboratory analysis of VOCs by EPA Method
8260 and VPH by the MADEP Method. Concentrations of xylenes, naphthalene, n-butylbenzene,
isopropylbenzene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and/or C9-C10
aromatics reported in soil samples SS-1 (15’) and MW-1R (10’) exceeded the MCCs. A Site Map showing
the locations of the monitoring wells and the structures on-site has been included as Figure 2.
2.0 RECEPTOR INFORMATION
Water Supply Wells:
A receptor survey was conducted in April 2021. Public water is available to the subject site and to all
surrounding properties. According to the well survey responses, one active non-potable well (WSW-6) is
located 800 feet east of the site. Wells WSW-1 through 5, WSW-8, and WSW-9 were identified during site
reconnaissance; but, according to the well surveys received, the wells are no longer in use and the
properties are connected to municipal water. No well survey response was received for WSW-7 (1,300
feet east of the site), but the well is assumed to be inactive and non-potable since the property is
undeveloped. A table summarizing the receptor information is included as Table 3. A Site Vicinity Map
showing the locations of the water supply wells has been included as Figure 3A.

Public Water Supplies:
Public water is available to the site and all of the surrounding properties. Water lines run along the public
streets in the area. Public water is supplied by Town of Wallace.

Surface Water:
Two ponds were identified approximately 1,000 feet to the northeast and the east-northeast of the site
during the April 2021 receptor survey.

Wellhead Protection Areas:
On July 11, 2022, GRI personnel accessed the NCDEQ SWAP Program’s website to identify wellhead
protection areas in the vicinity of the subject site. The site is not located within a wellhead protection
area.

Deep Aquifers in the Coastal Plain Physiographic Region:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
3
According to the NCDEQ Visual Hydrologic Framework website, the site is located in the surficial aquifer
and is underlain by the Castle Hayne confining unit and Castle Hayne aquifer at approximately 60 feet and
70 feet BGS, respectively.

Subsurface Structures:
No structures with basements were observed in the vicinity of the source area. Utilities in the source area
are located along NC 41 Highway South, and do not appear to intersect the seasonal high-water table.

3.0 LAND USE
The site is currently occupied by a petroleum retail facility and convenience store. The closest primary
residence is located on an adjacent property approximately 675 feet northeast of the source area. Vidant
Family Medicine is located approximately 850 feet to the north of the source area. The adjoining
properties are commercial and residential. According to the City of Wallace Official Zoning Map, the
surrounding areas are zoned Residential. Land use and adjacent property owner information have been
summarized in Tables 4 and 5, respectively. A zoning map has been included as Figure 3B.

4.0 SOIL ASSESSMENT
On June 16, 2021, during the installation of monitoring well MW-1, a soil sample was collected at 5 feet
(MW-1 (5’)) and submitted for laboratory analysis of VOCs by EPA Method 8260B and VPH by the MADEP
Method. The reported concentrations of benzene and tetrachloroethylene (PCE) exceeded the soil-to-
water MCCs.

In June 2022, during the CSA well installation activities, soil samples MW-7 (15’), MW-8 (15’) and TW-1
(45’) were collected during the installation of monitoring wells MW-7, MW-8, and TW-1, respectively for
grain size analyses. On June 28, 2022, twenty-nine soil samples were collected and screened using a PID.
The soil sample from each monitoring well or soil boring that had the highest PID reading was submitted
for onsite UVF analysis. A UVF report is included at Appendix B. A summary of UVF field data is presented
in Table 6a.

The soil samples with the highest GRO response during UVF analysis (SS-1 (15’) and MW-1R (10’)) were
submitted for laboratory analyses of VOCs by EPA Method 8260 and VPH by the MADEP Method.
Concentrations of xylenes, naphthalene, n-butylbenzene, isopropylbenzene, n-propylbenzene, 1,2,4-
trimethylbenzene, 1,3,5-trimethylbenzene, and/or C9-C10 aromatics reported in soil samples SS-1 (15’)
and MW-1R (10’) exceeded the soil-to-water MCCs. The soil sampling analytical results are presented in
Table 6b. A Soil Quality Map with the results of the soil sampling in 2022 has been included as Figure 4.
A summary of the soil sampling data from the June 2022 CSA activities is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
4 Sample ID Sample Depth (ft-BGS) PID Reading GRO DRO Benzene Toluene Ethylbenzene Total Xylenes Naphthalene C9-C10 Aromatics RAL (mg/kg) NE 50 100 NE NE NE NE NE NE
Soil to Water MCC (mg/kg) NE NE NE 0.0072 5.4 8 6 0.2 31
Residential SCLs (mg/kg) NE NE NE 12 1,250 60.3 3,120 5.5 469
SS-1 (15’) 15 645 396 61.6 <0.190 5.16 5.85 32.6 5.43 239
MW-1R (10’) 10 107 228.4 32.4 <0.217 <0.246 5.71 52.5 8.69 393

Clean, disposable nitrile gloves were used for the collection of the soil samples. The samples were
collected in laboratory supplied containers and shipped to the laboratory in a cooler following proper
chain-of-custody procedures.

5.0 GROUND WATER ASSESSMENT
On February 15, 2021, GRI conducted a site check and installed one Type II monitoring well (MW-1) in the
area of the 15,000-gallon gasoline UST spill bucket. MW-1 was gauged, purged, and sampled in
accordance with NCDEQ guidelines. The benzene concentration reported in the ground water sample
collected from MW-1 exceeded the GCL.

On June 16, 2021, three Type II monitoring wells (MW-2, MW-3, MW-4) were installed during LSA activities
at the site. No free product was observed. Concentrations of benzene, ethylbenzene, xylenes,
naphthalene, tert-amyl alcohol, n-propylbenzene, 1,2,4-trimethylbenzene, C5-C8 aliphatics, and/or C9-
C10 aromatics in the ground water samples collected from MW-2 and MW-3 exceeded the MACs. The
concentration of benzene reported in the ground water sample collected from MW-3 exceeded the GCL.
Based on the results of the LSA, a CSA was required.

On June 28-29, 2022, five additional Type II monitoring wells (MW-1R and MW-5 through MW-8) and one
Type III monitoring well (TW-1) were installed at the site. MW-1R was drilled adjacent to MW-1 as a
replacement well that would bracket the water table. Monitoring wells MW-1R, and MW-5 through MW-
8 were installed to total depths of 18 feet BGS with a 15-foot screened interval for each well. The Type III
Telescoping well, TW-1, was installed to a total depth of 45-feet BGS with a 5-foot screened interval. Well
photographs have been included in Appendix C. The well locations are shown on the picture below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
5

From June 28-30, 2022, monitoring wells MW-1R, MW-2 through MW-8, and TW-1 were gauged, purged,
and/or sampled. Contaminant concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene,
tert-amyl alcohol, tert-butyl alcohol, n-butylbenzene, sec-butylbenzene, isopropylbenzene, p-
isopropyltoluene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, C5-C8 aliphatics,
C9-C12 aliphatics, and/or C9-C10 aromatics reported in the ground water samples collected from MW-1R,
MW-2, MW-3, and MW-5 through MW-8 exceeded the MACs. All reported contaminant concentrations
were below the GCLs. A summary of the June 28-30, 2022, ground water analytical data is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
6
Contaminant
of Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well
ID
MACs (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1R 4,790 29,100 3,360 19,800 <1.40 3,060
MW-2 16.4 <0.220 <0.170 <0.210 <0.140 <0.470
MW-3 4,020 23.2 944 384 J <1.40 183
MW-4 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
MW-5 1.50 0.241 J 0.677 <0.210 0.246 J 3.75
MW-6 34.8 35.9 6.72 53.1 <0.140 0.933 J
MW-7 61.4 1.62 3.01 14.3 <0.140 <0.470
MW-8 2,870 187 1,720 711 4.44 383
TW-1 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470

All samples were collected in accordance with the NCDEQ guidelines. Clean, disposable bailers and nitrile
gloves were used for the collection of the ground water samples. The samples were collected in
laboratory supplied containers and shipped to the laboratory in a cooler following proper chain-of-custody
procedures. A laboratory supplied trip blank was included in the sample cooler. No detectable
concentrations of requested method constituents were reported in the trip blank.

The locations of the monitoring wells are shown on Figure 2. The well permit, the well construction
records, and the boring logs for the monitoring wells installed during CSA activities are included as
Appendix D.

Cross sections A-A’ and B-B’ are included as Figures 5 and 6. A Ground Water Quality Map for the June
2022 ground water sampling event has been included as Figure 7. A summary of laboratory analyses for
the ground water samples collected during CSA activities has been included as Table 7. Complete copies
of the laboratory reports for the ground water samples have been included as Appendix E.

6.0 HYDROGEOLOGIC INVESTIGATION
The depths to ground water in the Type II monitoring wells (MW-1R through MW-8) measured on June
29, 2022, ranged from 12.45 to 14.24 feet below the tops of well casings. Ground water elevations at the
site, based on an assumed datum of 100.00 feet, ranged from 86.47 to 87.00 feet relative to a temporary
benchmark. Based on this information, the ground water flow direction was generally toward the east-
northeast. The horizontal hydraulic gradient across the site was less than 0.01 feet per foot. The vertical
hydraulic gradient could not be calculated due to insufficient recharge in TW-1. A summary of ground
water elevation data obtained during assessment activities to date is presented in Table 8. A Water Table
Surface Map based on the June 29, 2022 gauging data is included as Figure 8.

Rising head slug tests were conducted in MW-7 and MW-8 on June 30, 2022. Hydraulic conductivities in
the Type II monitoring wells, calculated using the Bouwer and Rice method, ranged from 2.525 x 10-3 feet
per minute (3.636 feet per day) to 1.563 x 10-2 feet per minute (22.51 feet per day). The average hydraulic

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
7
conductivity was 9.078 x 10-3 feet per minute (13.07 feet per day). Seepage velocities, calculated using
the equation V = k(dh/dl)/ne, ranged from 7.27 x 10-2 to 4.50 x 10-1 feet per day (26.5 to 164 feet per year).
The average seepage velocity was 2.61 x 10-1 feet per day (95.4 feet per year). A rising head slug test was
conducted in TW-1 on July 14, 2022. The hydraulic conductivity in the Type III monitoring well, calculated
using the Bouwer and Rice method, was 4.678 x 10-5 feet per minute (0.067 feet per day). The seepage
velocity calculated for the Type III monitoring well was 3.37 x 10-3 feet per day (1.23 feet per year). A
summary of the results of slug test analyses is presented in Table 9. Calculations and raw data from the
slug tests have been included as Appendix F.

7.0 REGIONAL GEOLOGY AND HYDROGEOLOGY
According to the 1985 Geologic Map of North Carolina, the site is located in the Coastal Plain
Physiographic Province and Peedee Formation. The Peedee Formation is described as sand, clayey sand,
and clay, greenish gray to olive black, massive, glauconitic, locally fossiliferous and calcareous. The
surficial aquifer in the vicinity of site directly overlies the Castle Hayne confining unit and aquifer.
8.0 SITE GEOLOGY AND HYDROGEOLOGY
Based on observations made during assessment activities, surficial soils observed at the site consist of
various clays, silts and sands to varying depths (approximately 0.5 to 30 feet) where a layer of fossiliferous
limestone was encountered, overlaying clay. A summary of the current ground water gauging data is
shown below:

Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
MW-1R 3-18 18 100.10 13.27 --- 86.83
MW-2 3-18 18 100.69 13.89 --- 86.80
MW-3 3-18 18 100.92 14.24 --- 86.68
MW-4 3-18 18 100.17 13.33 --- 86.84
MW-5 3-18 18 99.17 12.45 --- 86.72
MW-6 3-18 18 99.56 13.09 --- 86.47
MW-7 3-18 18 99.72 12.72 --- 87.00
MW-8 3-18 18 100.01 13.35 --- 86.66
TW-1 40-45 45 100.28 dry --- dry

On June 29, 2022, monitoring wells MW-1R, MW-2 through MW-8, and TW-1 were gauged, purged,
and/or sampled. Depths to ground water in the Type II monitoring wells ranged from 12.45 to 14.24 feet
below the tops of well casings. Ground water elevations at the site, based on an assumed datum of 100.00
feet assigned to MW-1, ranged from 86.47 to 87.00 feet. Ground water flow was generally toward the
east-northeast.
9.0 DISCUSSION
On October 12, 2020, hydrostatic tests were conducted on the spill buckets associated with the active UST
system. The spill bucket for the 15,000-gallon UST received a non-passing test and was subsequently
replaced. Therefore, a site check was required. On February 15, 2021, GRI conducted a site check.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
8
However, pea gravel in the area of the 15,000-gallon gasoline UST spill bucket prevented collection of a
soil sample. Therefore, a monitoring well (MW-1) was installed and sampled. The benzene concentration
of the ground water sample collected from MW-1 exceeded the GCL.

To date, nine Type II monitoring wells and one telescoping well have been installed to determine the
horizontal and vertical extent of petroleum contamination at the site. Monitoring well MW-1R contained
the highest ground water contamination levels during the CSA activities. Please note that MW-3 and MW-
8 are down gradient of the UST basin and have the next highest concentration of contaminants.
10.0 CONCLUSIONS AND RECOMMENDATIONS
 Between June 29-30, 2022, eight Type II monitoring wells and one Type III telescoping well were
gauged, purged, and sampled at the site.
 Concentrations of benzene, toluene, ethylbenzene, xylenes, naphthalene, tert-amyl alcohol, tert-
butyl alcohol, n-butylbenzene, sec-butylbenzene, isopropylbenzene, p-isopropyltoluene, n-
propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, C5-C8 aliphatics, C9-C12
aliphatics, and/or C9-C10 aromatics reported in the ground water samples collected from MW-
1R, MW-2, MW-3, and MW-5 through MW-8 exceeded the MACs.
 All reported contaminant concentrations were below GCLs.
 Ground water flow direction is to the east-northeast.
 No active, potable water supply wells were identified within 1,500 feet of the source area.
 No surface water bodies were identified within 500 feet of the site.
 The ground water contaminant plume is adequately defined for this risk ranking.
 Based on this site assessment, the site risk classification should be changed to low, an NRP should
be filed for the property, and the incident should be closed with an NFA.
11.0 PUBLIC NOTICE
Copies of the applicable portions of this CSA report have been forwarded to the appropriate local officials
by certified mail. Copies of the cover letters have been included in Appendix G.
12.0 LIMITATIONS
This report has been prepared for the exclusive use of RL Village Store, LLC. for specific application to the
referenced site in Duplin County, North Carolina. The assessment was conducted based on the scope of
work and level of effort desired by the NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from this data.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Comprehensive Site Assessment Report
Prepared on: September 9, 2022 RL Village Store
Project Manager: Rae Troiano Brown, P.G. GRI Project No. 5586
9
13.0 REFERENCES
Bouwer, H., 1989, The Bouwer and Rice slug test - an update, Ground Water, vol.27, no. 3, pp.304-309
Bouwer, H. and R.C. Rice, 1976, A slug test method for determining hydraulic conductivity of unconfined
aquifers with completely or partially penetrating wells, Water Resources Research, vol. 12, no.3,
pp. 423-428
Department of Natural Resources and Community Development, 1985, Geologic Map of North Carolina,
1 sheet
Fetter, C. W., 1988, Applied Hydrogeology, Second Edition, Macmillan Publishing Company, 592 p.
North Carolina Department of Environmental Quality, Division of Water Resources, 2017, Ground Water
Section Guidelines for the Investigation and Remediation of Soil and Ground Water, 80 p.
North Carolina Department of Environmental Quality, Division of Waste Management – UST Section
Assessment Guidelines: Petroleum and Hazardous Substances UST Releases; Petroleum Non-UST
Releases, January 19, 2021 Version
Site Check Report, RL Village Store, Geological Resources, Inc., March 15, 2021
Phase II Limited Site Assessment Report, RL Village Store, Geological Resources, Inc., August 26, 2021

FIGURES
SITE LOCATIONFigure 1 Site LocationRL Village Store5194 S NC 41 HighwayWallace, North CarolinaDuplin CountyIncident No. 47621GRI Project No. 5586500 M2000 FTDate: 09/09/2022 Location: 34.757452° N -77.949057° W Dad
!>
DJ
DJ
DJ
DJ
DJ
DJ
DJ
"6
SITE
331600671349
331600377569
331700507596
331600891066
331600891066
331600584953
331600681286
331600587603
331600584953
331600589145
331602586405
331600584953
331600584293
331600681177
331600891066
331600688134331602684810
331602689412
331602682693
WSW-7
WSW-9
WSW-8
WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
WSW-6 S NC 41 HWYW INTERSTATE 40
E INTERSTATE 40
RIVER VILLAGE PL
PADDLEWHEEL DR
INTE
R
S
TATE 40 O
FFR
A
M
P
UNKNOWNLEGACY OAKS DRLAKE SI
DE LNLAKE LEAMON RDINTERSTATE 40 OFFRAMP
UNKNOWN³
FIGURE 3: SITE VICINITY MAPRL VILLAGE STORE5194 NC 41 HIGHWAYWALLACE, DUPLIN COUNTYNORTH CAROLINAINCIDENT NO. 47621GRI NO. 5586
PREPARED BY:GEOLOGICAL RESOURCES, INC.APRIL 5, 2021
0 300150Feet
1 inch = 300 feet
1,500-FOOT RADIUS1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
2
1 3
4
LEGEND
"6 Water Supply Well (Unknown)
DJ Abandoned Water Supply Well
!>Irrigation Well
ncrivers
Centerlines
Ponds
Adjacent Properties and Well Owners
nc_duplin_parcels_poly
Features/Land Use Code1

TABLES
UST ID Number 1-2 Facility ID Number
Owner or Operator?
Owner/Operator
00-0-0000036169
TABLE 1
UST OWNER/OPERATOR INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
PO Box 1139, Wallace NC 28466-1139 910-285-4171
Name of Owner or Operator Dates of Ownership / Operation
RL Village Store LLC 01/30/2000 - Current
Address Telephone Number
Page 1 of 1
Date: 3/8/21
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline NA 15,000 1/30/2000 Double Wall FRP unknown Single Wall FRP Current Yes
2 Gasoline NA 10,000 1/30/2000 Double Wall FRP unknown Single Wall FRP Current No
TABLE 2
UST SYSTEM INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
FACID: 00-0-0000036169
Page 1 of 1
Facility ID # : 00-0-0000036169
Well ID. Parcel ID No.Well Owner Mailing Address Well Address
Well Status
(Active/In-Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance from
source area of
release
(ft.)
WSW-1 3316-0058-4293 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
5208 NC 41 Highway
Wallace, NC 28466 None None Yes Yes ~300' SW
WSW-2 3316-0067-1349 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
110 River Village Place
Wallace, NC 28466 None None Yes Yes ~600' SE
WSW-3 3316-0067-6331 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
154 River Village Place
Wallace, NC 28466 None None Yes Yes ~1,300' SE
WSW-4 3316-0068-1286 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
5185 NC 41 Highway
Wallace, NC 28466 None None Yes Yes ~750' E
WSW-5 3316-0268-4810 Duplin Land Development
110 River Village Place
Wallace, NC 28466
127 Firethorn Circle
Wallace, NC 28466 None None Yes Yes ~950' E
WSW-6 3316-0268-2693 Billy & Elizabeth Floyd
139 Firethorn Circle
Wallace, NC 28466
139 Firethorn Circle
Wallace, NC 28466 Active Non-Potable Yes Yes ~800' E
WSW-7 3316-0068-8134 Laken Elizabeth Clifton & Owen Heflin Rouse, II
150 Cherry Laurel Drive
Wallace, NC 28466
150 Cherry Laurel Drive
Wallace, NC 28466 Unknown Unknown Yes Unknown ~1,300' E
WSW-8 3316-0268-9412 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
139 Cherry Laurel Drive
Wallace, NC 28466 None None Yes Yes ~1,400' E
WSW-9 3316-0089-1066 Duplin Land Dev. Inc.P.O. Box 1139
Wallace, NC 28466
41 @ River Landing
Wallace, NC 28466 None None Yes Yes ~1,550' NE
Receptor
ID
Latitude/
Longitude of Any
Significant Points
Up or
Down-
Gradient
Distance from
the source
area
of release (ft.)
3 n/a cross ~1,000' N
4 n/a down ~975' E
Notes:
• Receptors are shown on Figure 2.
• n/a: not applicable.
• Responses to well survey are included in Appendix A.
N/A
TABLE 3
RECEPTOR INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
Date: 09/09/22
Well Construction Details
(Depth, Screened Interval, Type of Well, ect.)
N/A
N/A
N/A
N/A
Well Depth approx 140-180 ft.
Unknown
N/A
N/A
pond residential pond n/a Drainage
Description Location Contact/Phone Number Usage
pond north of site along west side of NC Highway 41 n/a Drainage
Page 1 of 1
Date: 06/30/21 Facility ID # :00-0-0000036169
Map ID No. Land Use Feature Zoning Description Address
Distance from
Source Area
(feet)
1 Vidant Family Medicine HB Doctor's Office
125 River Vine Parkway
Wallace, NC 28466 ~850 NE
2 The Inn at River Landing HB Hotel
131 River Village Place
Wallace, NC 28466 ~750 ESE
Note:
• Properties are keyed to Figure 3.
TABLE 4
LAND USE INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
Page 1 of 1
Date: 09/09/22 Facility ID #: 00-0-0000036169
PIN Number Property Owner Name Property Owner Address
3316-0258-6405(site) R L Village Store, LLC
P.O. Box 1139
Wallace, NC 28466
3316-0058-4293
3316-0058-4953
3316-0068-1286
3316-0068-1177
3316-0067-1349
3316-0037-7569 Kristin Davenport Trustee & Susan K.
Harrison
606 Fleetwood Drive
Lookout Mountain, TN 37350
3316-0058-7603 Redco Properties, LLC
335 North Queen Street
Kinston, NC 28502
3316-0058-9145 Duplin Restaurant, LLC
P.O. Box 1139
Wallace, NC 28466
Note:
• Properties are keyed to Figure 2.
TABLE 5
ADJACENT PROPERTY OWNER INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
P.O. Box 1139
Wallace, NC 28466Duplin Land Dev. Inc.
Page 1 of 1
Date: 08/02/22 Facility ID #: 00-0-0000036169
PID
Sample ID
Date
Collected
(mm/dd/y
y)
Sample
Location
Sample
Depth
(ft-BGS)
n/a 50 100
5 4 <20 <4
10 2 NS NS
5 7 <20 <4
10 1 NS NS
15 0 NS NS
5 9 <20 10.8
10 7 NS NS
5 3 <20 <4
10 2 NS NS
5 2 NS NS
10 1 NS NS
15 645 396 61.6
5 0 NS NS
10 0 NS NS
15 0 <20 <4
5 0 NS NS
10 0 NS NS
15 0 <20 <4
5 0 NS NS
10 0 NS NS
15 0 <20 <4
5 0 NS NS
10 0 NS NS
15 4 <20 <4
5 10 NS NS
10 107 228.4 32.4
5 7 NS NS
10 2 NS NS
15 9 <20 5.2
Notes:
• Only the sample with the highest PID reading in each soil boring/well was submitted for UVF analysis.
• Concentrations in bold face type exceeded the RAL.
• PID readings in red were the highest observed .Gasoline-Range TPH(mg/kg)Diesel-Range TPH(mg/kg)TABLE 6a
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS - FIELD DATA
RL VILLAGE STORE (INCIDENT NO. 47621)
Analytical Method UVF
MW-6
MW-8
MW-1R
RAL (mg/kg)Total VOC(ppm)UST-1
UST-4/
MW-7
UST-3
UST-2
Contaminant of Concern
East of UST
Basin
Northeast of
UST Basin
East of UST
BasinTW-1
6/28/2022
6/29/2022
UST basin NW
UST Basin SW
UST Basin SE
UST Basin NE
East of UST
Basin
East of UST
Basin
Southeast of
UST Basin
SS-1
SS-2
MW-5
Date: 07/14/22
Sample ID Date Collected
(mm/dd/yy)
Sample Depth
(feet)
0.0072 5.4 8.0 6.0 0.085 0.20 2.4 1.3 1.4 0.005 6.6 6.6 68 540 31
12 1,250 60.3 3,120 156 5.5 782 1,560 1,560 93.8 156 156 625 1,560 469
59.4 18,600 297 46,700 1,810 27 11,600 23,300 23,300 1,400 2,330 2,330 9,340 23,300 46,000
SB-1-5' 06/16/2021 5 0.568 0.582 J 0.114 0.888 0.0033 J <0.0019 <0.00095 0.0071 0.0110 0.0167 0.0780 0.0303 <2.1 <2.1 <2.1
SS-1-15' 06/28/2022 15 <0.190 5.16 5.85 32.6 <0.203 5.43 2.29 1.12 J 4.95 <0.294 32.4 8.86 60.2 72.9 239
MW-1R 10' 06/28/2022 10 <0.217 <0.246 5.71 52.5 <0.232 8.69 3.16 2.12 7.27 <0.336 75.3 22.0 64.3 119 393
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• MSCC: Maximum Soil Contaminant Concentration level as specified by T 15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report
• Concentrations in bold face type exceeded the soil to ground water MSCCs.
• NE: Not Established
• J: Estimated value.
Analytical Method SW846 8260D MADEP VPH
TABLE 6b
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
RL VILLAGE STORE (INCIDENT NO. 47621)
Facility ID #: 00-0-0000036169
C9-C12 AliphaticsC9-C10 Aromatics1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneTetrachloroethylene(PCE)Soil to Water MSCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)
Industrial/Commercial Soil Cleanup Levels (mg/kg)C5-C8 Aliphaticsn-PropylbenzeneIsopropylbenzeneNaphthaleneContaminant of Concern BenzeneTolueneEthylbenzeneTotal XylenesMethyl-tert-butyl-ether (MTBE)n-Butylbenzene
Date: 07/14/22
EPA
Method
SW846/
6010C
Well ID
Date
Collected
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 70 70 25 70 400 400 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 5,900 8,800 30,500 11,700 26,100 28,500 24,100 15,000 NE NE NE
02/15/21 5,080 24,800 2,920 24,000 <63 634 <1000 <1000 <63 <63 124 J <63 310 3,830 934 30.8 <18,000 <18,000 20,100 J
12/01/21 2,090 12,700 4,710 39,000 <130 6,130 5,230 J <2000 1,080 452 J 586 286 J 2,130 29,300 7,380 NR NR NR NR
MW-1R 06/29/22 4,790 29,100 3,360 19,800 <1.40 3,060 <19.0 <16.0 163 96.6 507 65.9 470 4,760 1,180 NR NR NR NR
06/16/21 7.9 0.38 J 0.24 J 1.5 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 0.19 J 0.19 J <0.13 NR <35 <35 <35
12/01/21 5.4 <0.63 <0.63 <1.3 <0.63 <0.63 <10 <10 <0.63 <0.63 <0.63 <0.63 <0.63 <0.63 <0.63 NR NR NR NR
06/29/22 16.4 <0.220 <0.170 <0.210 <0.140 <0.470 13.5 <1.60 <0.180 0.205 J 0.238 J <0.089 <0.190 <0.190 <0.180 NR NR NR NR
06/16/21 5,890 459 1,830 3,020 <25 232 <400 <400 <25 <25 42.5 J <25 136 517 101 NR 3,220 <35 6,520
12/01/21 6,750 45.7 J 1,360 112 J <31 330 <500 <500 <31 <31 45.9 J <31 122 J <31 <31 NR NR NR NR
06/29/22 4,020 23.2 944 384 J <1.40 183 474 <16.0 7.90 5.38 44.8 2.16 J 113 748 135 NR NR NR NR
06/16/21 0.56 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR <35 <35 <35
12/01/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 <2.0 <2.0 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR
06/29/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.200 <0.180 <0.089 <0.190 <0.190 <0.180 NR NR NR NR
MW-5 06/29/22 1.50 0.241 J 0.677 <0.210 0.246 J 3.75 38.7 11.8 <0.180 0.705 0.554 <0.089 0.291 J 0.432 J <0.180 NR 189 J 42.0 J 33.1 J
MW-6 06/29/22 34.8 35.9 6.72 53.1 <0.140 0.933 J 16.6 <1.60 <0.180 0.288 J 0.991 <0.089 1.13 8.25 2.72 NR 141 72.1 J 31.1 J
MW-7 06/29/22 61.4 1.62 3.01 14.3 <0.140 <0.470 18.3 13.8 <0.180 <0.200 1.60 <0.089 2.02 6.87 1.91 NR <11.5 42.9 J 14.8 J
MW-8 06/29/22 2,870 187 1,720 711 4.44 383 657 J 94.6 9.91 6.21 74.9 2.48 187 181 96.4 NR 833 959 1,470
TW-1 06/30/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <1.90 <1.60 <0.180 <0.200 <0.180 <0.089 <0.190 <0.190 <0.180 NR <11.5 <25.8 <4.02
12/01/21 <0.13 <0.13 <0.13 <0.25 <0.13 <0.13 NR NR <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR
06/28/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 NR NR <0.180 <0.200 <0.180 <0.089 <0.190 <0.190 <0.180 NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• NE: Not Established
• Concentrations in bold face type exceeded the 2L standards.
• Concentrations in italics exceeded the gross contamination levels.
• Refer to laboratory report for detected constituents that did not exceed the MACs, or for which no standard has been established.
Trip Blank
MW-2
MW-3
MW-4 NaphthaleneMW-1 TolueneEthylbenzeneTotal XylenesMethyl-tert-butyl ether(MTBE)TABLE 7
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
RL VILLAGE STORE (INCIDENT NO. 47621)
Facility ID #: 00-0-0000036169
2L Standard (µg/l)
GCL (µg/l)C5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsLead1,3,5-Trimethylbenzene1,2,4-Trimethylbenzenen-Propylbenzenep-Isopropyltoluene(4-Isopropyltoluene)IsopropylbenzeneContaminant of Concern Benzenetert-Amyl alcohol(TAA)tert-Butyl alcohol(TBA)n-Butylbenzenesec-ButylbenzeneAnalytical Method MADEP VPH SM 6200B
Page 1 of 1
Date: 07/11/22 Facility ID #: 00-0-0000036169
Well ID Date Installed
(mm/dd/yy)
Date Water
Level
Measured
(mm/dd/yy)
Well Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(ft.)
Free Product
Thickness
(ft.)
Groundwater
Elevation
(ft.)
Comments
02/15/21 7.91 ---92.09
06/16/21 11.70 ---88.30
12/01/21 11.75 ---88.25
MW-1R 06/28/22 06/29/22 3 3-18 18 100.10 13.27 ---86.83
06/16/21 13.52 ---87.17
12/01/21 14.41 ---86.28
06/29/22 13.89 ---86.80
06/16/21 14.00 ---86.92
12/01/21 14.89 ---86.03
06/29/22 14.24 ---86.68
06/16/21 13.50 ---86.67
12/01/21 14.02 ---86.15
06/29/22 13.33 ---86.84
MW-5 06/28/22 06/29/22 3 3-18 18 99.17 12.45 ---86.72
MW-6 06/28/22 06/29/22 3 3-18 18 99.56 13.09 ---86.47
MW-7 06/28/22 06/29/22 3 3-18 18 99.72 12.72 ---87.00
MW-8 06/28/22 06/29/22 3 3-18 18 100.01 13.35 ---86.66
TW-1 06/29/22 07/14/22 40 40-45 45 100.28 28.66 --- 71.62
Bailed dry during
sampling
Notes:
• ft BGS : feet below ground surface.
• NA: Not available.
• NM: Not measured.
18
18
18
100.69
100.92
100.17
8
8
8
3-18
3-18
3-18
06/16/21
06/16/21
06/16/21
MW-2
MW-3
MW-4
02/15/21MW-1
TABLE 8
WELL CONSTRUCTION AND GAUGING INFORMATION
RL VILLAGE STORE (INCIDENT NO. 47621)
13 100.003 3- 13
Page 1 of 1
Facility ID#: 00-0-0000036169
ft/min ft/day ft/day ft/year
MW-7 2.525E-03 3.636E+00 7.27E-02 2.65E+01
MW-8 1.563E-02 2.251E+01 4.50E-01 1.64E+02
TW-1 4.678E-05 6.736E-02 3.37E-03 1.23E+00
Note:
Seepage velocities calculated using the equation v = k(dh/dl)/ne , where:
k = hydraulic conductivity
ne = effective porosity: MW-7 & MW-8 = 0.25
dh/dl = hydraulic gradient = 0.005 ft/ft
TW-1 = 0.10
TABLE 9
SUMMARY OF SLUG TEST ANALYSES
RL Village Store (INCIDENT NO. 47621)
Date : 07/15/22
Well Hydraulic Conductivity (k)Seepage Velocity (v)
Page 1 of 1

APPENDICES

APPENDIX A
State Correspondence

North Carolina Department of Environmental Quality | Division of Waste Management
Wilmington Regional Office | 127 Cardinal Drive Extension | Wilmington, NC 28405 |
[phone]

February 3, 2022

Mr. Mills Bryant
RL Village Store, LLC
P.O. Box 1139
Wallace, NC. 28466-1139

Re: Notice of Regulatory Requirements
15A NCAC 2L .0407(d) [Intermediate Risk]
Risk-based Assessment and Corrective Action
For Petroleum Underground Storage Tanks

RL Village Store
5194 South NC 41 Hwy., Wallace, NC
Duplin County
Incident Number: 47621
Risk Classification: Intermediate
Ranking: I120D

Dear Mr. Bryant:

The Limited Site Assessment Report received on January 6, 2022 has been reviewed by the UST
Section, Division of Waste Management, Wilmington Regional Office. The risk posed by the discharge or
release at the subject site is classified by the Department of Environmental Quality as intermediate, as
stipulated under Title 15A NCAC 2L .0406. The land use at the site is classified as industrial/commercial.
Title 15A NCAC 2L .0407(a) requires you to notify the Department of any changes that might affect the
risk or land use classifications that have been assigned.
Title 15A NCAC 2L .0407(d) [Intermediate Risk] requires you to comply with the assessment and
cleanup requirements of Title 15A NCAC 2N .0706 and Title15A NCAC 2L .0106(c) and 2L .0106(g). A
Comprehensive Site Assessment (CSA) Report prepared in accordance with these requirements and the
most recent version of the UST Section Assessment Guidelines must be received by this office within 90
days of the date of this notice. In addition, you must submit a summary of the CSA Report to the local
Health Director and the local Chief Administrative Officer in accordance with 15A NCAC 2L .0114. The
summary should be submitted to these persons no later than five working days after submittal of the CSA
Report to this office.
Failure to comply in the manner and time specified may result in the assessment of civil
penalties and/or the use of other enforcement mechanisms.

North Carolina Department of Environmental Quality | Division of Waste Management
Wilmington Regional Office | 127 Cardinal Drive Extension | Wilmington, NC 28405 |
[phone]

Effective October 1, 2004, the Department of Environmental Quality requires that all work not
determined to be an emergency response or associated with risk assessment (i.e., the Limited Site
Assessment Report, per Title 15A NCAC 2L .0405) must be preapproved if State Trust Fund reimbursement
is anticipated. To comply with this requirement, a completed Preapproval/Claim Authorization Form,
encompassing the required remedial activities, must be received in this office within 14 days of the date of
this letter. Upon completion of the preapproved activities, you should submit your claim promptly.
Reimbursement funds are budgeted based on completed preapprovals, but delays in reimbursement or even
denial due to exceeding the statute of limitations on claiming eligible costs can result where claims are not
submitted immediately following work completion.
Because a release or discharge has been confirmed, a Licensed Geologist or a Professional
Engineer, certified by the State of North Carolina, is required to prepare and certify all reports submitted to
the Department in accordance with 15A NCAC 2L .0103(e) and 2L .0111(b).
If you have any questions regarding trust fund eligibility or reimbursement from the Commercial
Leaking Petroleum Underground Storage Tank Cleanup Fund, please contact the UST Section Trust Fund
Branch at [phone]. If you have any questions regarding the actions that must be taken or the rules
mentioned in this letter, please contact me at [phone] or at the address listed below.

Sincerely,

Steve Kay
Environmental Engineer
Wilmington Regional Office
UST Section, Division of Waste Management, NCDEQ

cc: Duplin County Health Department
Geological Resources, Inc. - Rae Brown
WiRO-UST

Wilmington Regional Office | 127 Cardinal Drive Ext| Wilmington, NC 28405 | [phone]

Site Name City / County /Duplin Incident #47621
Resp Pty Name / Contact Incident Mgr Region WIL
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #3
Consultant / Project Mgr /Rae Troiano Brown
Telephone / Fax Number /Task Authorization Number:4 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I120D RRA Date:9/7/2021
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.080 1 /permit y $250.00 Y $250.00 $250.00 /
3.101 190 /feet y $12.50 Y $2,375.00 $2,375.00 /
3.101 45 /feet y $18.00 Y $810.00 $810.00 /
3.111 100 /feet y $20.00 Y $2,000.00 $2,000.00 /
3.113 90 /feet y $50.00 Y $4,500.00 $4,500.00 /
3.115 45 /feet y $75.00 Y $3,375.00 $3,375.00 /
3.310 1 /agreement y $625.00 Y $625.00 $625.00 /
3.351 6 /wells y $80.00 Y $480.00 $480.00 /
3.398 2 /events y $350.00 Y $700.00 $700.00 /
3.500 6 /nights y $151.00 Y $906.00 $906.00 /
4.031 9 /wells y $110.00 Y $990.00 $990.00 /
4.080 13 /sample pt.y $45.00 Y $585.00 $585.00 /
4.090 #240 9 /samples y $88.00 Y $792.00 $792.00 /
4.090 #271 1 /sample y $62.00 Y $62.00 $62.00 /
4.090 #341 5 /samples y $52.00 Y $260.00 $260.00 /
4.090 #409 2 /samples y $79.00 Y $158.00 $158.00 /
4.090 #421 2 /samples y $54.00 Y $108.00 $108.00 /
4.090 #590 3 /samples y $35.00 Y $105.00 $105.00 /
4.090 #640 3 /samples y $121.00 Y $363.00 $363.00 /
4.091 2 /shipments y $60.00 Y $120.00 $120.00 /
5.010 1 /event y $1,300.00 Y $1,300.00 $1,300.00 /
6.050 1 /report y $4,400.00 Y $4,400.00 $4,400.00 /
6.082 1 /site y $500.00 Y $500.00 $500.00 /
12.030 2 /nights y $151.00 Y $302.00 $302.00 /
12.050 2 /trips y $250.00 Y $500.00 $500.00 /
//
/
Requested Preapproved Claimed3
TOTAL:$26,566.00 $26,566.00 TOTAL:
Total Standard Costs (Not Third Party)$26,566.00 $26,566.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:3/10/22 by:(PM)(Reserved for RO)
RO Review:3/22/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 3/24/2022
RO Supv. Review:3/24/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 8/1/2020
RTB
Proposed
Units / Type
(Consultant)
Steve Kay
activeFALSE
22-109 Apr-22
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
[e-mail]
RL Village Rl Village
Geological Resources, Inc.
DIRECTED - CAB ONLY
Wallace
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
RL Village
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be
attached to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for theproposed activities.If, following completion ofthis ePATA,
you discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order"in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 months of the completion date of the FIRST completed task to remain within the Statute of Limitations. All ePATAs submitted within a claim are closed with
that claim, and may not be re-used ina separate submittal,evenfor costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
SAK
MHH
(Initials)
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management
Site Name City / County /Duplin Incident #47621
Resp Pty Name / Contact Incident Mgr Region WIL
RP Type (Owner/Operator / Landowner / Attny-in-fact)Change Order?Prev. TA #4
Consultant / Project Mgr /
Telephone / Fax Number /Task Authorization Number:5 ChangeOrd:
Project Mgr Email Site Risk / Rank / Abatement:I120D RRA Date:9/7/2022
Proposal# / Scope Dates /% Commercial (C=100%, NC=0%, Both=1%-99%)
Has STF Eligibility Been Determined? (Y/N)Site Status (Active or NFA Date)
With Claim: [ ] All Main Consultant/Contractor invoices attached?[ ] Proof of payment attached directly to the front of each invoice?
w Important: The date of reimbursement is dependent on the Trust Fund balance. There may be a delay in the reimbursement of claims for work under this ePATA.3rd Pty Ded?Task #Lab /
SubCode
RO IM AuthProposed
Rate/Price
(Consultant)RO Supv. AuthProposed Task
Subtotal
(Consultant)
Final
Preapproved
Subtotal
(UST Section)
Claimed
Amount3
(Consultant)
3.118 235 /feet y $5.00 Y $1,175.00 $1,175.00 /
3.397 2 /mobes y $100.00 Y $200.00 $200.00 /
4.090 #240 9 /samples y $6.00 Y $54.00 $54.00 /
4.090 #271 1 /sample y $4.00 Y $4.00 $4.00 /
4.090 #341 5 /samples y $4.00 Y $20.00 $20.00 /
4.090 #409 2 /samples y $5.00 Y $10.00 $10.00 /
4.090 #421 2 /samples y $4.00 Y $8.00 $8.00 /
4.090 #590 3 /samples y $3.00 Y $9.00 $9.00 /
4.090 #640 3 /samples y $8.00 Y $24.00 $24.00 /
12.055 2 /trip y $50.00 Y $100.00 $100.00 /
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
//
Requested Preapproved Claimed 3
TOTAL:$1,604.00 $1,604.00 TOTAL:
Total Standard Costs (Not Third Party)$1,604.00 $1,604.00 Total Standard Costs
Total applied as Third Party Deductible/Damage Costs $0.00 $0.00 Total Third Pty Costs
Process Tracking (Date)
TA Submittal:4/18/22 by:(PM)(Reserved for RO)
RO Review:4/19/22 by:(IM)Joint UST Preapproval Confirmed By:Date1 4/19/2022
RO Supv. Review:4/19/22 by:(STF)RP or Designee Receipt Confirmation By:Date 4
1 - This ePATA expires one year from the Joint UST Preapproval date. This does not extend, alter, or supersede any regulatory deadlines (e.g., NORR's, NOV's, Enforcements, etc.)
2 - THE ONE YEAR STATUTE OF LIMITATIONS APPLIES TO EACH INDIVIDUAL TASK. Costs must be claimed within one year of completion of that task to be reimbursable.
3 - Only Tasks included on this ePATA may be claimed. Do not include other Tasks or claimed costs (i.e., Claim preparation) that were not preapproved or the claim will be returned.
4 - Preapproval is not valid (i.e., claimable) until receipt is signed as 'Confirmed' by the RP or their designee within a week of approval. The signed pre-approval must be submitted
in the submitted claim. Signature indicates acknowledgement of the tasks and amounts approved. Any objections/appeals must be submitted via Change Order prior to work
proceeding. Scope/cost negotiations do not supersede other regulatory deadlines as described in #1 above. Also, any ePATA that has been signed as 'Confirmed' by both the
UST Section and RP is not to be modified without written consent by all signatories.
5 - Tasks approved on Directed - CAB Only ePATAs must be performed in accordance with all applicable rules, statutes, and RRD Task Scopes of Work to be reimbursed in full.
DWM/UST ePATA 4/1/2022
DIRECTED - CAB ONLY
Wallace
(Must Complete with Claim Submittal)(See Instructions / RRD for Tasks requiring Preapproval / Task Authorization)
Owner/Operator
704-845-4010
(Reserved for Incident Manager)
PREAPPROVAL / TASK AUTHORIZATION
RL Village
Note: This Electronic Preapproval Task Authorization (ePATA) shall be used to receive preapproval from the UST Section. A proposal,including maps and figures,must be
attached to elaborate on the costs for the tasks listed below that describes the scope of work and the rationale for the proposed activities.If, following completion of this ePATA,
you discover that unexpected tasks must be performed, incurring costs for tasks not originally included with this form, you must complete and submit a separate ePATA request
designated as a "Change Order"in the provided space above prior to conducting those tasks. Include a copy of the prior ePATA form for confirmation. Please attach this form to
the cover of the corresponding claim when requesting reimbursement. IMPORTANT:Only one claim may be submitted per ePATA and all work on the ePATA must have been
completed within 12 months of the completion dateof the FIRST completed task to remain within the Statuteof Limitations. All ePATAs submitted within a claim are closed with that
claim, and may not be re-used in a separate submittal,even for costs or tasks that were not originally claimed. Final reimbursement of costs associated with the Total Claimed
amount below may be affected by the eligibility status of the site (i.e., deductibles, apportionment, etc.), and the documentary validation of incurred costs as reasonable and
necessary expenses per 15A NCAC 2P .0402 and .0404.
sak
MHH
(Initials)
Proposed
Units / Type
(Consultant)
Steve Kay
activeYes
22-109 22-Apr
704-845-4012
Dates of Work
(Consultant)
Started1 / Completed2
FINAL REIMBURSEMENT
100.00%
[e-mail]
RL Village Store, LLC
Geological Resources, Inc.
ELECTRONIC PREAPPROVAL TASK AUTHORIZATION FORM
Dept of Environmental Quality -Division of Waste Management

APPENDIX B
UVF Report

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
UVF Trilogy Analytical Report

Samples Collected: June 28-29, 2022
Samples Analyzed: June 28, 2022 & July 1,2022
Site Name: RL Village
Site Address: 5194 South NC 41 Highway, Wallace, NC
GRI Project Number: 5586

July 1, 2022

AJ Discepolo, GIT
Operator

Technical Procedures
Sample Collection and Handling
Soil samples may be collected using any acceptable procedure. Sampler must use a clean pair of nitrile
gloves for each sample collected. The sample will be placed in a clean, sealable bag (ziplock). Once
collected, the sample must be analyzed immediately or placed on ice. The sample may be kept on ice for
up to 48 hours prior to UVF analyses. If the sample cannot be analyzed within 48 hours, the sample may
be extracted and kept at 4 degrees C for up to 14 days. Proper chain-of-custody procedures must be
followed.
Calibration
The UFV Trilogy has standard calibrations stored for the following analysis:
 GRO
 DRO
 Total PAH
 Target PAH
 Heavy PAH
Prior to use, calibration standards are used to perform a 5-point verification on the factory stored
calibrations for GRO and DRO. The calibration standards used are as follows:
GRO
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
 10 ppm
DRO
 0.1 ppm
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
Operation
Sample Extraction
 5mg of soil are weighed into a clean extraction jar
 Methanol is added to the extraction jar to create a 2x or 4x dilution
o 2x Dilution: 10 mL of methanol
o 4x Dilution: 20 mL of methanol
 The extraction jar is shaken for several minutes to thoroughly mix the soil with solvent
(methanol)
 The mixture is allowed to settle for several minutes
 A clean syringe is used to draw liquid from the extraction jar
 A clean filter is attached to the end of the syringe and the liquid dispensed through the filter
into a clean test tube
 This liquid is referred to as the extraction
Dilution Preparation
 An adjustable micropipette is used to precisely measure out the amount of extract needed for
the dilution
Technical Procedures
 The measured out amount of the extract is added to a clean test tube and methanol is added
dilute the extract. Examples of dilutions are shown below:

Extract Amount
500 μL
200 μL
100 μL
50 μL
25 μL

Add Solvent to the
5 mL line
5 mL line
5 mL line
5 mL line
5 mL line
2x Extract
Dilution Factor
20x
50x
100x
200x
400x
4x Extract
Dilution Factor
40x
100x
200x
400x
800x

Sample Analyzation
 The dilution is shaken to thoroughly mix, then poured into a clean glass cuvette
 The desired module is inserted into the UVF Trilogy and the corresponding factory calibration is
selected
 “Measure Fluorescence” is pressed on the touchscreen and the reading is recorded
 The reading should be between the concentrations of the calibration standards (GRO: 0.5-10
ppm; DRO 0.1-5 ppm)
o Reading below the calibration standard range are recorded as below the detection limit
 Detection Limit = (lower range of calibration standards range) x dilution factor
(i.e. a GRO sample with a 100x dilution factor has a detection limit of 50 ppm)
o Readings above the calibration standard range should be further diluted and reanalyzed
o Negative readings are an indication of quenching (see below)
 The reading is multiplied by the dilution factor to calculate the final concentration
 Check suspected contaminated samples for quenching by running additional dilutions
o According to the siteLAB Quick Reference Guide:
“Quenching” can occur when the detector is swamped by too many hydrocarbons or
organic interferences, producing low or negative concentrations. Test the sample at
multiple dilutions to confirm results are linear and accurate.”
QA/QC
Calibration
 The UFV Trilogy will be calibrated daily prior to use
 The calibration results will be saved and entered into the calibration log
Method Blank
 A method blank of methanol will be analyzed following calibration and following the last sample
analyzed for each site
Duplicates
 One duplicate will be analyzed for every 20 samples
 The duplicate will be prepared from the extract of the sample and diluted to the same factor as
the sample analyzed
Project Name:Date Collected:
Project Number:Date Analysed:
Project Manager:Operator:
Sample ID Matrix
Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
UST-1-5'Soil 40 <0.5 <20 40 <0.1 <4
UST-4/MW-7-5'Soil 40 <0.5 <20 40 <0.1 <4
UST-3-5'Soil 40 <0.5 <20 40 0.27 10.8
UST-2-5'Soil 40 <0.5 <20 40 <0.1 <4
SS-1-15'Soil 40 9.9 396 40 1.54 61.6
SS-2-15'Soil 40 <0.5 <20 40 <0.1 <4
MW-5-15'Soil 40 <0.5 <20 40 <0.1 <4
MW-6-15'Soil 40 <0.5 <20 40 <0.1 <4
MW-8-15'Soil 40 <0.5 <20 40 <0.1 <4
MW-1R-10'Soil 40 5.71 228.4 40 0.81 32.4
TW-1-15'Soil 40 <0.5 <20 40 0.13 5.2
UVF Analytical Report
siteLAB UVF Trilogy
6/28/22&7/1/22
6/28-29/22
AJ Discepolo
RL Village
5586
Rae Brown
Site:
RL Village
Report Date:
8/2/2022
Page:
1 of 1

APPENDIX C
Well Photographs
Appendix C – Well Photographs

APPENDIX D
Well Permit, Well Construction Records, and Subsurface Logs
PERMIT NO. WM0801195

C:\PROGRAMDATA\ACTIVEPDF\TEMP\DOCCONVERTER\API\INPUT\$B7F989A5ED79$590541EB226A44EE99D714D86A
17FCF0.DOCX

NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENTAL QUALITY
RALEIGH, NORTH CAROLINA

PERMIT FOR THE CONSTRUCTION OF A WELL OR WELL SYSTEM

In accordance with the provisions of Article 7, Chapter 87, North Carolina General Statutes,
and other applicable Laws, Rules and Regulations

PERMISSION IS HEREBY GRANTED TO
Geological Resources, Inc.

FOR THE CONSTRUCTION OF 2 (two) monitoring wells, which will be located on property owned NC
Department of Transportation and located at 5194 S NC 41 Highway (PIN 331602586405), Wallace, Duplin
County, in accordance with the application received June 2, 2022, and in conformity with specifications and
supporting data, all of which are filed with the Department of Environmental Quality and are considered part
of the Permit.

This Permit is for well construction only and does not waive any provisions or requirements of the Water Use
Act of 1967, or any other applicable laws and regulations. Well construction shall be in compliance with the
North Carolina Well Construction Regulations and Standards. However, this Permit pertains to the
jurisdictional authority of the Division of Water Resource and does not waive the requirements of other
jurisdictions.

This Permit will be effective from the date of its issuance until June 3, 2023, and shall be subject to other
specified conditions, limitations, or exceptions as follows:

1. The well(s) shall be located and constructed as shown on the attachments submitted as part of the permit
application.
2. Well construction record (GW-1) for each well must be supplied to the Division of Water Resources’
Information Processing Unit within 30 days of well completion. Provide the well construction permit
number on the GW-1 form.
3. Issuance of this Permit does not obligate reimbursement from State trust funds, if these wells are being
installed as part of an investigation for contamination from an underground storage tank or dry cleaner
incident.
4. Issuance of this Permit does not supersede any other agreement, permit, or requirement issued by another
agency.
5. The well(s) shall have a Well Contractor Identification Plate in accordance with 15A NCAC 02C.0108(o).
6. When the well(s) are discontinued or abandoned, they shall be abandoned in accordance with 15A NCAC
02C.0113 and a well abandonment record (GW-30) shall be submitted to the Division of Water Resource’s
Information Processing Unit within 30 days of well abandonment.

If any requirements or limitations of this Permit are unacceptable, you have the right to an adjudicatory hearing
upon written request within 30 days. The request must be in the form of a written petition conforming to Chapter
150B of the North Carolina General Statutes and filed with the Office of Administrative Hearings, 6714 Mail
Service Center, Raleigh, North Carolina 27699-6714. Unless such demand is made, this Permit is final and
binding.

DocuSign Envelope ID: 5E0ABF99-C15B-45CB-AA10-2E9C75435906
PERMIT NO. WM0801195

C:\PROGRAMDATA\ACTIVEPDF\TEMP\DOCCONVERTER\API\INPUT\$B7F989A5ED79$590541EB226A44EE99D714D86A
17FCF0.DOCX

Permit issued this 3rd day of June 2022
NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION

Morella Sanchez King, PhD, PE, Regional Supervisor
Water Quality Regional Operations Section, Division of Water Resources
By Authority of the Environmental Management Commission

Cc: Rae Troiano Brown, P.G. – Geological Resources, Inc. (via email)
NC DWR - Laserfiche files
DocuSign Envelope ID: 5E0ABF99-C15B-45CB-AA10-2E9C75435906
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number MW-1R Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
10.0
6
8
10 Sampled grab 10.7

12
14
16

18
20
22

24
26
28

30
06/28/2022
6" Auger
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 3'; Brown sandy silt
3' - 7'; Brown fine sandy clay
7' - 10'; Brown fine sandy clay
10' - 15'; Red fine sandy clay
15' -18'; Gray fine sand (moist)
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number MW-5 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 2'; Brown silt
2
4
0.0
6
8
10 0.0

12
14
0.0
16

18
20
22

24
26
28

30
06/28/2022
6" Auger
Direct push, borehole abandoned with Bentonite, Capped with concrete
2' - 7'; Brown fine sandy clay
7' - 14'; Red fine sandy clay
14' - 18'; Tan fine sand (moist)
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number MW-6 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 2'; Brown silt
2
4
0.0
6
8
10 0.0

12
14
0.0
16

18
20
22

24
26
28

30
06/28/2022
6" Auger
Direct push, borehole abandoned with Bentonite, Capped with concrete
2' - 7'; Brown fine sandy clay
7' - 14'; Red fine sandy clay
14' - 18'; Tan fine sand (moist)
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number MW-7/UST-4 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
7.0
6
8
10 1.0

12
14
0.0
16

18
20
22

24
26
28

30
06/28/2022
6" Auger
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 4'; Brown fine sand
7' - 10'; Tan fine sandy clay
10' - 18'; Red/gray fine sand (moist)
4' - 7'; Tan fine sandy clay
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number MW-8 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
0.0
6
8
10 0.0

12
14
4.0
16

18
20
22

24
26
28

30
06/28/2022
6" Auger
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 2'; Brown sandy silt
2' - 7'; Brown fine sandy clay
7' - 14'; Red fine sandy clay
14' - 18'; Tan fine sand (moist)
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number TW-1 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
7.0
6
8
10 2.0

12
14
9.0
16

18
20
22

24
26
28

30
32
34
36
38
40
42
44
11' - 15'; Red fine sandy clay
15' - 20'; Tan fine sand (moist)
20' -25'; Tan fine sand (moist)
25' - 30'; Gray sandy clay (tacky)
30' - 33'; Lime stone with shells
33'- 40'; Gray sandy clay (tacky)
40' - 45'; Gray clay (tacky)
06/29/2022
6.25" Hollow Stem
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 3'; Brown sandy silt
3' - 11'; Brown fine sand clay
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number SS-1 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
2.0
6
8
10 Sampled grab 1.0

12
14
645.0
16

18
20
22

24
26
28

30
06/28/2022
DPT
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 4'; Brown/gray fine sand
4' - 5'; Brown fine sandy clay
5' - 10'; Brown fine sandy clay
10' - 15'; Brown fine sandy clay (moist)
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number SS-2 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 1'; Brown silt
2
4
0.0
6
8
10 0.0

12
14
0.0
16

18
20
22

24
26
28

30
06/28/2022
DPT
Direct push, borehole abandoned with Bentonite, Capped with concrete
1' - 4'; Brown fine sand
10' - 15'; Brown/gray fine sand (moist)
4' - 10'; Brown fine sandy clay
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number UST-1 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Concrete
2
4
4.0
6
8
10 2.0

12
14
16

18
20
22

24
26
28

30
06/28/2022
DPT
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 3'; Brown fine sand
3' - 3.5'; Gravel
3.5' -5'; Brown fine sand
5' - 7'; Tan fine sand
7' - 10'; Gray fine sand
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number UST-2 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
3.0
6
8
10 2.0

12
14
16

18
20
22

24
26
28

30
06/28/2022
DPT
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 3.5'; Brown fine sand
3.5' - 4'; Gravel
4' -5'; Brown fine sand
5' - 10'; Tan/gray fine sandy clay
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
SUBSURFACE LOG
Project RL Village
Address 5194 South NC 41 Highway, Wallace, NC
Boring Number UST-3 Date Drilled
Sample Method Grab Drilling Method
Geoprobe Macro-Core
Completion Details
Driller Sammy Bowers (GRI)Log By J. Brooks
Lab Sample PIDDepthSampleTypeppm LITHOLOGY
0 0' - 0.5'; Asphalt
2
4
9.0
6
8
10 7.0

12
14
16

18
20
22

24
26
28

30
06/28/2022
DPT
Direct push, borehole abandoned with Bentonite, Capped with concrete
0.5' - 1.5'; Gravel
1.5' - 4'; Brown fine sandy clay
4' -10'; Brown fine sandy clay

APPENDIX E
Laboratory Analytical Report

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

7/13/2022
Geological Resources, Inc. Rae Brown
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-182-0020 Client Project Description: RL Village Store
GRI # 5586
Dear Rae Brown:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 7/1/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 104
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State Program Lab ID Expiration Date
02/28/202340750State ProgramAlabama
02/07/202388-0650State ProgramArkansas
06/30/20232904State ProgramCalifornia
06/30/2023E871157State Program - NELAPFlorida
02/18/2023C044State ProgramGeorgia
06/30/202304015State ProgramGeorgia
10/10/2022200078State Program - NELAPIllinois
06/30/202280215State ProgramKentucky
12/31/2022KY90047State ProgramKentucky
12/31/2022LA037State Program - NELAPLouisiana
06/30/202304015State Program - NELAPLouisiana
02/11/2023MSState ProgramMississippi
12/31/2022415State ProgramNorth Carolina
05/31/202368-03195State Program - NELAPPennsylvania
06/30/202284002State ProgramSouth Carolina
02/11/202302027State ProgramTennessee
09/30/2022T104704180State Program - NELAPTexas
06/30/202300106State ProgramVirginia
09/14/2022460181State Program - NELAPVirginia
Page 1 of 1 00016/22-182-0020
Page 2 of 104
Report Number:
Sample Summary Table
Client Project Description:
22-182-0020
RL Village Store
GRI # 5586
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
06/28/2022 11:48Solids 93415 SS-1 15'07/01/2022 11:00
06/28/2022 15:57Solids 93416 MW-1R 10'07/01/2022 11:00
06/28/2022 09:42Solids 93417 MW-7 15'07/01/2022 11:00 WALK-BLACK WP MTN -
06/28/2022 09:42Solids 93417 MW-7 15'07/01/2022 11:00 Texture WP MTN -
06/28/2022 15:36Solids 93418 MW-8 15'07/01/2022 11:00 WALK-BLACK WP MTN -
06/28/2022 15:36Solids 93418 MW-8 15'07/01/2022 11:00 Texture WP MTN -
06/28/2022 07:24Aqueous 93419 Trip Blank 07/01/2022 11:00
06/29/2022 12:02Aqueous 93420 MW-2 07/01/2022 11:00
06/29/2022 12:14Aqueous 93421 MW-3 07/01/2022 11:00
06/29/2022 12:23Aqueous 93422 MW-4 07/01/2022 11:00
06/29/2022 12:32Aqueous 93423 MW-5 07/01/2022 11:00
06/29/2022 12:44Aqueous 93424 MW-6 07/01/2022 11:00
06/29/2022 12:53Aqueous 93425 MW-7 07/01/2022 11:00
06/29/2022 13:02Aqueous 93426 MW-8 07/01/2022 11:00
06/29/2022 13:11Aqueous 93427 MW-1R 07/01/2022 11:00
06/30/2022 11:42Solids 93428 TW-1 45'07/01/2022 11:00 WALK-BLACK WP MTN -
06/30/2022 11:42Solids 93428 TW-1 45'07/01/2022 11:00 Texture WP MTN -
06/30/2022 14:15Aqueous 93429 TW-1 07/01/2022 11:00
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 3 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93415SS-1 15'
2.29 07/07/2022 11:278260Dn-Butylbenzene mg/Kg - dry 0.161
J0.693 07/07/2022 11:278260Dsec-Butyl benzene mg/Kg - dry 0.183
5.85 07/07/2022 11:278260DEthylbenzenemg/Kg - dry 0.190
8.28 07/07/2022 11:278260Dn-Hexane mg/Kg - dry 0.216
J1.12 07/07/2022 11:278260DIsopropylbenzenemg/Kg - dry 0.150
5.43 07/07/2022 11:278260DNaphthalenemg/Kg - dry 0.325
4.95 07/07/2022 11:278260Dn-Propylbenzene mg/Kg - dry 0.176
5.16 07/07/2022 11:278260DToluenemg/Kg - dry 0.216
32.4 07/07/2022 11:278260D1,2,4-Trimethylbenzene mg/Kg - dry 0.161
8.86 07/07/2022 11:278260D1,3,5-Trimethylbenzene mg/Kg - dry 0.176
8.15 07/07/2022 11:278260Do-Xylene mg/Kg - dry 0.163
24.5 07/07/2022 11:278260Dm,p-Xylene mg/Kg - dry 0.412
32.6 07/07/2022 11:278260DXylene (Total)mg/Kg - dry 0.163
60.2 07/06/2022 17:37CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 7.97
72.9 07/06/2022 17:37CALCULATIONAliphatics C9-C12 (Adjusted)mg/Kg - dry 29.9
239 07/06/2022 17:37CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 4.09
65.3 07/06/2022 17:37MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 7.97
350 07/06/2022 17:37MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 29.9
239 07/06/2022 17:37MADEP-VPH Aromatic C9-C10 mg/Kg - dry 4.09
23.7 07/06/2022 12:17SW-DRYWT Moisture %
V 93416MW-1R 10'
J1.02 07/07/2022 10:028260DAcetonemg/Kg - dry 0.896
3.16 07/07/2022 10:028260Dn-Butylbenzene mg/Kg - dry 0.183
J1.23 07/07/2022 10:028260Dsec-Butyl benzene mg/Kg - dry 0.209
5.71 07/07/2022 10:028260DEthylbenzenemg/Kg - dry 0.217
2.12 07/07/2022 10:028260DIsopropylbenzenemg/Kg - dry 0.171
J0.838 07/07/2022 10:028260D4-Isopropyl toluene mg/Kg - dry 0.486
8.69 07/07/2022 10:028260DNaphthalenemg/Kg - dry 0.370
7.27 07/07/2022 10:028260Dn-Propylbenzene mg/Kg - dry 0.202
75.3 07/07/2022 10:028260D1,2,4-Trimethylbenzene mg/Kg - dry 0.183
22.0 07/07/2022 10:028260D1,3,5-Trimethylbenzene mg/Kg - dry 0.202
10.5 07/07/2022 10:028260Do-Xylene mg/Kg - dry 0.187
42.0 07/07/2022 10:028260Dm,p-Xylene mg/Kg - dry 0.471
52.5 07/07/2022 10:028260DXylene (Total)mg/Kg - dry 0.187
64.3 07/06/2022 16:25CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 1.54
119 07/06/2022 16:49CALCULATIONAliphatics C9-C12 (Adjusted)mg/Kg - dry 28.8
Page 4 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93416MW-1R 10'
393 07/06/2022 16:49CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 3.94
64.3 07/06/2022 16:25MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 1.54
570 07/06/2022 16:49MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 28.8
393 07/06/2022 16:49MADEP-VPH Aromatic C9-C10 mg/Kg - dry 3.94
20.9 07/06/2022 12:17SW-DRYWT Moisture %
V 93417MW-7 15'
7.0 07/11/2022 10:45Texture%Clay %
90.0 07/11/2022 10:45Texture%Sand %
3.0 07/11/2022 10:45Texture%Silt %
Sand 07/11/2022 10:45TextureSoil Classification
0.10 07/08/2022 10:28WALK-BLACK Total Organic Carbon %0.05
V 93418MW-8 15'
17.0 07/11/2022 10:45Texture%Clay %
80.0 07/11/2022 10:45Texture%Sand %
3.0 07/11/2022 10:45Texture%Silt %
Sandy Loam 07/11/2022 10:45TextureSoil Classification
0.07 07/08/2022 10:28WALK-BLACK Total Organic Carbon %0.05
V 93420MW-2
16.4 07/11/2022 17:286200BBenzeneµg/L 0.180
J0.205 07/11/2022 17:286200Bsec-Butyl benzene µg/L 0.200
J0.238 07/11/2022 17:286200BIsopropylbenzeneµg/L 0.180
13.5 07/11/2022 17:286200Btert-Amyl Alcohol (TAA)µg/L 1.90
V 93421MW-3
4020 07/11/2022 21:036200BBenzeneµg/L 18.0
7.90 07/11/2022 20:396200Bn-Butylbenzene µg/L 1.80
5.38 07/11/2022 20:396200Bsec-Butyl benzene µg/L 2.00
944 07/11/2022 20:396200BEthylbenzeneµg/L 1.70
44.8 07/11/2022 20:396200BIsopropylbenzeneµg/L 1.80
J2.16 07/11/2022 20:396200B4-Isopropyl toluene µg/L 0.890
183 07/11/2022 20:396200BNaphthaleneµg/L 4.70
113 07/11/2022 20:396200Bn-Propylbenzene µg/L 1.90
474 07/11/2022 20:396200Btert-Amyl Alcohol (TAA)µg/L 19.0
23.2 07/11/2022 20:396200BTolueneµg/L 2.20
748 07/11/2022 20:396200B1,2,4-Trimethylbenzene µg/L 1.90
Page 5 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93421MW-3
135 07/11/2022 20:396200B1,3,5-Trimethylbenzene µg/L 1.80
J2.20 07/11/2022 20:396200Bo-Xylene µg/L 2.10
382 07/11/2022 20:396200Bm,p-Xylene µg/L 4.20
J38407/11/2022 20:396200BXylene (Total)µg/L 2.10
V 93423MW-5
14.4 07/11/2022 19:516200BAcetoneµg/L 1.80
1.50 07/11/2022 19:516200BBenzeneµg/L 0.180
0.705 07/11/2022 19:516200Bsec-Butyl benzene µg/L 0.200
0.677 07/11/2022 19:516200BEthylbenzeneµg/L 0.170
0.554 07/11/2022 19:516200BIsopropylbenzeneµg/L 0.180
J0.246 07/11/2022 19:516200BMethyl tert-butyl ether (MTBE)µg/L 0.140
3.75 07/11/2022 19:516200BNaphthaleneµg/L 0.470
J0.291 07/11/2022 19:516200Bn-Propylbenzene µg/L 0.190
11.8 07/11/2022 19:516200Btert-Butyl Alcohol (TBA)µg/L 1.60
38.7 07/11/2022 19:516200Btert-Amyl Alcohol (TAA)µg/L 1.90
J0.241 07/11/2022 19:516200BTolueneµg/L 0.220
J0.432 07/11/2022 19:516200B1,2,4-Trimethylbenzene µg/L 0.190
J18907/05/2022 16:53CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J42.0 07/05/2022 16:53CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J33.1 07/05/2022 16:53CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
191 07/05/2022 16:53MADEP-VPH Aliphatic C5-C8 µg/L 11.5
75.8 07/05/2022 16:53MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J33.1 07/05/2022 16:53MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93424MW-6
34.8 07/11/2022 18:166200BBenzeneµg/L 0.180
J0.288 07/11/2022 18:166200Bsec-Butyl benzene µg/L 0.200
6.72 07/11/2022 18:166200BEthylbenzeneµg/L 0.170
0.991 07/11/2022 18:166200BIsopropylbenzeneµg/L 0.180
J0.933 07/11/2022 18:166200BNaphthaleneµg/L 0.470
1.13 07/11/2022 18:166200Bn-Propylbenzene µg/L 0.190
16.6 07/11/2022 18:166200Btert-Amyl Alcohol (TAA)µg/L 1.90
35.9 07/11/2022 18:166200BTolueneµg/L 0.220
8.25 07/11/2022 18:166200B1,2,4-Trimethylbenzene µg/L 0.190
2.72 07/11/2022 18:166200B1,3,5-Trimethylbenzene µg/L 0.180
13.2 07/11/2022 18:166200Bo-Xylene µg/L 0.210
39.9 07/11/2022 18:166200Bm,p-Xylene µg/L 0.420
Page 6 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93424MW-6
53.1 07/11/2022 18:166200BXylene (Total)µg/L 0.210
141 07/06/2022 11:51CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
J72.1 07/06/2022 11:51CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J31.1 07/06/2022 11:51CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
212 07/06/2022 11:51MADEP-VPH Aliphatic C5-C8 µg/L 11.5
163 07/06/2022 11:51MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J31.1 07/06/2022 11:51MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93425MW-7
27.7 07/11/2022 18:396200BAcetoneµg/L 1.80
61.4 07/11/2022 18:396200BBenzeneµg/L 0.180
3.01 07/11/2022 18:396200BEthylbenzeneµg/L 0.170
1.60 07/11/2022 18:396200BIsopropylbenzeneµg/L 0.180
6.51 07/11/2022 18:396200BMethyl Ethyl Ketone (MEK)µg/L 0.710
2.02 07/11/2022 18:396200Bn-Propylbenzene µg/L 0.190
13.8 07/11/2022 18:396200Btert-Butyl Alcohol (TBA)µg/L 1.60
18.3 07/11/2022 18:396200Btert-Amyl Alcohol (TAA)µg/L 1.90
1.62 07/11/2022 18:396200BTolueneµg/L 0.220
6.87 07/11/2022 18:396200B1,2,4-Trimethylbenzene µg/L 0.190
1.91 07/11/2022 18:396200B1,3,5-Trimethylbenzene µg/L 0.180
2.45 07/11/2022 18:396200Bo-Xylene µg/L 0.210
11.8 07/11/2022 18:396200Bm,p-Xylene µg/L 0.420
14.3 07/11/2022 18:396200BXylene (Total)µg/L 0.210
J42.9 07/05/2022 17:17CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
J14.8 07/05/2022 17:17CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
67.3 07/05/2022 17:17MADEP-VPH Aliphatic C5-C8 µg/L 11.5
75.0 07/05/2022 17:17MADEP-VPH Aliphatic C9-C12 µg/L 25.8
J14.8 07/05/2022 17:17MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93426MW-8
2870 07/12/2022 16:206200BBenzeneµg/L 18.0
9.91 07/11/2022 19:036200Bn-Butylbenzene µg/L 0.180
6.21 07/11/2022 19:036200Bsec-Butyl benzene µg/L 0.200
2.63 07/11/2022 19:036200BDi-Isopropyl Ether (DIPE)µg/L 0.500
1720 07/12/2022 16:206200BEthylbenzeneµg/L 17.0
74.9 07/11/2022 19:036200BIsopropylbenzeneµg/L 0.180
2.48 07/11/2022 19:036200B4-Isopropyl toluene µg/L 0.089
4.44 07/11/2022 19:036200BMethyl tert-butyl ether (MTBE)µg/L 0.140
Page 7 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93426MW-8
383 07/12/2022 16:206200BNaphthaleneµg/L 47.0
187 07/12/2022 16:206200Bn-Propylbenzene µg/L 19.0
94.6 07/11/2022 19:036200Btert-Butyl Alcohol (TBA)µg/L 1.60
J65707/12/2022 16:206200Btert-Amyl Alcohol (TAA)µg/L 190
187 07/12/2022 16:206200BTolueneµg/L 22.0
181 07/12/2022 16:206200B1,2,4-Trimethylbenzene µg/L 19.0
96.4 07/11/2022 19:036200B1,3,5-Trimethylbenzene µg/L 0.180
67.0 07/11/2022 19:036200Bo-Xylene µg/L 0.210
644 07/12/2022 16:206200Bm,p-Xylene µg/L 42.0
711 07/11/2022 19:036200BXylene (Total)µg/L 0.210
833 07/06/2022 11:28CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
959 07/06/2022 11:28CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 258
1470 07/06/2022 11:28CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
3890 07/06/2022 11:28MADEP-VPH Aliphatic C5-C8 µg/L 115
4860 07/06/2022 11:28MADEP-VPH Aliphatic C9-C12 µg/L 258
1470 07/06/2022 11:28MADEP-VPH Aromatic C9-C10 µg/L 40.2
V 93427MW-1R
4790 07/11/2022 21:506200BBenzeneµg/L 18.0
163 07/11/2022 21:276200Bn-Butylbenzene µg/L 1.80
96.6 07/11/2022 21:276200Bsec-Butyl benzene µg/L 2.00
3360 07/11/2022 21:506200BEthylbenzeneµg/L 17.0
507 07/11/2022 21:276200BIsopropylbenzeneµg/L 1.80
65.9 07/11/2022 21:276200B4-Isopropyl toluene µg/L 0.890
3060 07/11/2022 21:506200BNaphthaleneµg/L 47.0
470 07/11/2022 21:506200Bn-Propylbenzene µg/L 19.0
29100 07/12/2022 15:326200BTolueneµg/L 220
4760 07/11/2022 21:506200B1,2,4-Trimethylbenzene µg/L 19.0
1180 07/11/2022 21:506200B1,3,5-Trimethylbenzene µg/L 18.0
4790 07/11/2022 21:506200Bo-Xylene µg/L 21.0
15000 07/11/2022 21:506200Bm,p-Xylene µg/L 42.0
19800 07/11/2022 21:506200BXylene (Total)µg/L 21.0
V 93428TW-1 45'
51.0 07/11/2022 10:45Texture%Clay %
24.0 07/11/2022 10:45Texture%Sand %
25.0 07/11/2022 10:45Texture%Silt %
Clay 07/11/2022 10:45TextureSoil Classification
Page 8 of 104
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-182-0020
Report Limit
Project:RL Village Store
V 93428TW-1 45'
2.37 07/08/2022 10:28WALK-BLACK Total Organic Carbon %0.05
V 93429TW-1
23.5 07/12/2022 15:096200BAcetoneµg/L 1.80
1.41 07/12/2022 15:096200BChloroformµg/L 0.220
J72.9 07/12/2022 15:096200BEthanolµg/L 42.0
Page 9 of 104

Client: Geological Resources, Inc. CASE NARRATIVE
Project: RL Village Store Lab Report Number: 22-182-0020
Date: 7/13/2022
Volatile Organic Compounds - GC/MS Method 8260D Analyte: 1,2-Dichloroethane QC Batch No: V20990/V20989
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: Methylene chloride QC Batch No: V20990/V20989
CCV result above control limits but within method parameters. Results are reported but considered estimated.

Page 10 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
23.7 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
<0.786 mg/Kg - dry 0.786 6.55Acetone 500 07/07/22 11:27 V20990TBL
<0.397 mg/Kg - dry 0.397 6.55Acrolein 500 07/07/22 11:27 V20990TBL
<0.246 mg/Kg - dry 0.246 6.55Acrylonitrile 500 07/07/22 11:27 V20990TBL
<0.190 mg/Kg - dry 0.190 1.64Benzene 500 07/07/22 11:27 V20990TBL
<0.163 mg/Kg - dry 0.163 1.64Bromobenzene 500 07/07/22 11:27 V20990TBL
<0.262 mg/Kg - dry 0.262 1.64Bromochloromethane 500 07/07/22 11:27 V20990TBL
<0.390 mg/Kg - dry 0.390 1.64Bromodichloromethane 500 07/07/22 11:27 V20990TBL
<0.331 mg/Kg - dry 0.331 1.64Bromoform 500 07/07/22 11:27 V20990TBL
<0.596 mg/Kg - dry 0.596 3.28
Bromomethane 500 07/07/22 11:27 V20990TBL
2.29 mg/Kg - dry 0.161 1.64n-Butylbenzene 500 07/07/22 11:27 V20990TBL
0.693 J mg/Kg - dry 0.183 1.64sec-Butyl benzene 500 07/07/22 11:27 V20990TBL
<0.163 mg/Kg - dry 0.163 1.64tert-Butyl benzene 500 07/07/22 11:27 V20990TBL
<0.209 mg/Kg - dry 0.209 1.64Carbon Disulfide 500 07/07/22 11:27 V20990TBL
<0.517 mg/Kg - dry 0.517 1.64Carbon Tetrachloride 500 07/07/22 11:27 V20990TBL
<0.220 mg/Kg - dry 0.220 1.64Chlorobenzene 500 07/07/22 11:27 V20990TBL
<0.292 mg/Kg - dry 0.292 1.64
Chlorodibromomethane 500 07/07/22 11:27 V20990TBL
<0.292 mg/Kg - dry 0.292 3.28Chloroethane 500 07/07/22 11:27 V20990TBL
<0.344 mg/Kg - dry 0.344 1.64Chloroform 500 07/07/22 11:27 V20990TBL
<0.207 mg/Kg - dry 0.207 3.28Chloromethane 500 07/07/22 11:27 V20990TBL
<0.167 mg/Kg - dry 0.167 1.642-Chlorotoluene 500 07/07/22 11:27 V20990TBL
<0.127 mg/Kg - dry 0.127 1.644-Chlorotoluene 500 07/07/22 11:27 V20990TBL
<0.239 mg/Kg - dry 0.239 1.64Di-Isopropyl Ether (DIPE)500 07/07/22 11:27 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
<0.144 mg/Kg - dry 0.144 3.281,2-Dibromo-3-Chloropropane 500 07/07/22 11:27 V20990TBL
<0.193 mg/Kg - dry 0.193 1.641,2-Dibromoethane 500 07/07/22 11:27 V20990TBL
<0.325 mg/Kg - dry 0.325 1.64Dibromomethane 500 07/07/22 11:27 V20990TBL
<0.101 mg/Kg - dry 0.101 1.641,2-Dichlorobenzene 500 07/07/22 11:27 V20990TBL
<0.124 mg/Kg - dry 0.124 1.641,3-Dichlorobenzene 500 07/07/22 11:27 V20990TBL
<0.196 mg/Kg - dry 0.196 1.641,4-Dichlorobenzene 500 07/07/22 11:27 V20990TBL
<0.432 mg/Kg - dry 0.432 3.28Dichlorodifluoromethane 500 07/07/22 11:27 V20990TBL
<0.268 mg/Kg - dry 0.268 1.641,1-Dichloroethane 500 07/07/22 11:27 V20990TBL
<0.452 mg/Kg - dry 0.452 1.64
1,2-Dichloroethane 500 07/07/22 11:27 V20990TBL
<0.239 mg/Kg - dry 0.239 1.641,1-Dichloroethene 500 07/07/22 11:27 V20990TBL
<0.259 mg/Kg - dry 0.259 1.64cis-1,2-Dichloroethene 500 07/07/22 11:27 V20990TBL
<0.344 mg/Kg - dry 0.344 1.64trans-1,2-Dichloroethene 500 07/07/22 11:27 V20990TBL
<0.144 mg/Kg - dry 0.144 1.641,2-Dichloropropane 500 07/07/22 11:27 V20990TBL
<0.180 mg/Kg - dry 0.180 1.641,3-Dichloropropane 500 07/07/22 11:27 V20990TBL
<0.416 mg/Kg - dry 0.416 1.642,2-Dichloropropane 500 07/07/22 11:27 V20990TBL
<0.249 mg/Kg - dry 0.249 1.64
1,1-Dichloropropene 500 07/07/22 11:27 V20990TBL
<0.176 mg/Kg - dry 0.176 1.64cis-1,3-Dichloropropene 500 07/07/22 11:27 V20990TBL
<0.262 mg/Kg - dry 0.262 1.64trans-1,3-Dichloropropene 500 07/07/22 11:27 V20990TBL
5.85 mg/Kg - dry 0.190 1.64Ethylbenzene 500 07/07/22 11:27 V20990TBL
<0.272 mg/Kg - dry 0.272 32.8Ethyl Tertiary Butyl Ether (ETBE)500 07/07/22 11:27 V20990TBL
<0.259 mg/Kg - dry 0.259 3.28Hexachlorobutadiene 500 07/07/22 11:27 V20990TBL
8.28 mg/Kg - dry 0.216 3.28n-Hexane 500 07/07/22 11:27 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
<0.203 mg/Kg - dry 0.203 6.552-Hexanone 500 07/07/22 11:27 V20990TBL
1.12 J mg/Kg - dry 0.150 1.64Isopropylbenzene 500 07/07/22 11:27 V20990TBL
<0.425 mg/Kg - dry 0.425 1.644-Isopropyl toluene 500 07/07/22 11:27 V20990TBL
<0.213 mg/Kg - dry 0.213 6.55Methyl Ethyl Ketone (MEK)500 07/07/22 11:27 V20990TBL
<0.203 mg/Kg - dry 0.203 1.64Methyl tert-butyl ether (MTBE)500 07/07/22 11:27 V20990TBL
<4.91 mg/Kg - dry 4.91 6.554-Methyl-2-Pentanone 500 07/07/22 11:27 V20990TBL
<0.482 mg/Kg - dry 0.482 1.64Methylene Chloride 500 07/07/22 11:27 V20990TBL
5.43 mg/Kg - dry 0.325 3.28Naphthalene 500 07/07/22 11:27 V20990TBL
4.95 mg/Kg - dry 0.176 1.64
n-Propylbenzene 500 07/07/22 11:27 V20990TBL
<0.465 mg/Kg - dry 0.465 1.64Styrene 500 07/07/22 11:27 V20990TBL
<0.344 mg/Kg - dry 0.344 1.641,1,1,2-Tetrachloroethane 500 07/07/22 11:27 V20990TBL
<0.104 mg/Kg - dry 0.104 1.641,1,2,2-Tetrachloroethane 500 07/07/22 11:27 V20990TBL
<0.294 mg/Kg - dry 0.294 1.64Tetrachloroethene 500 07/07/22 11:27 V20990TBL
5.16 mg/Kg - dry 0.216 1.64Toluene 500 07/07/22 11:27 V20990TBL
<0.176 mg/Kg - dry 0.176 3.281,2,3-Trichlorobenzene 500 07/07/22 11:27 V20990TBL
<0.209 mg/Kg - dry 0.209 3.28
1,2,4-Trichlorobenzene 500 07/07/22 11:27 V20990TBL
<0.471 mg/Kg - dry 0.471 1.641,1,1-Trichloroethane 500 07/07/22 11:27 V20990TBL
<0.154 mg/Kg - dry 0.154 1.641,1,2-Trichloroethane 500 07/07/22 11:27 V20990TBL
<0.301 mg/Kg - dry 0.301 1.64Trichloroethene 500 07/07/22 11:27 V20990TBL
<0.685 mg/Kg - dry 0.685 3.28Trichlorofluoromethane 500 07/07/22 11:27 V20990TBL
<0.235 mg/Kg - dry 0.235 1.641,2,3-Trichloropropane 500 07/07/22 11:27 V20990TBL
32.4 mg/Kg - dry 0.161 1.641,2,4-Trimethylbenzene 500 07/07/22 11:27 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
8.86 mg/Kg - dry 0.176 1.641,3,5-Trimethylbenzene 500 07/07/22 11:27 V20990TBL
<0.150 mg/Kg - dry 0.150 3.28Vinyl Acetate 500 07/07/22 11:27 V20990TBL
<0.157 mg/Kg - dry 0.157 3.28Vinyl Chloride 500 07/07/22 11:27 V20990TBL
8.15 mg/Kg - dry 0.163 1.64o-Xylene 500 07/07/22 11:27 V20990TBL
24.5 mg/Kg - dry 0.412 3.28m,p-Xylene 500 07/07/22 11:27 V20990TBL
32.6 mg/Kg - dry 0.163 1.64Xylene (Total)500 07/07/22 11:27 V20990
Surrogate: 4-Bromofluorobenzene 98.7 Limits: 70-130%07/07/22 11:27500 TBL V20990
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/07/22 11:27500 TBL V20990
Surrogate: Toluene-d8 98.4 Limits: 76-129%07/07/22 11:27500 TBL V20990
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:SS-1 15'
93415 Matrix:
6/28/2022 11:48
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
60.2 mg/Kg - dry 7.97 52.4Aliphatic C5-C8 (Adjusted)500 07/06/22 17:37
72.9 mg/Kg - dry 29.9 52.4Aliphatics C9-C12 (Adjusted)500 07/06/22 17:37
239 mg/Kg - dry 4.09 52.4Aromatic C9-C10 (Adjusted)500 07/06/22 17:37
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20938 07/06/22 08:00
65.3 mg/Kg - dry 7.97 52.4Aliphatic C5-C8 500 07/06/22 17:37 V20939TBL
350 mg/Kg - dry 29.9 52.4Aliphatic C9-C12 500 07/06/22 17:37 V20939TBL
239 mg/Kg - dry 4.09 52.4Aromatic C9-C10 500 07/06/22 17:37 V20939TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)112 Limits: 70-130%07/06/22 17:37500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)83.3 Limits: 70-130%07/06/22 17:37500 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
20.9 %Moisture 1 07/06/22 12:17 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
1.02 J mg/Kg - dry 0.896 7.47Acetone 500 07/07/22 10:02 V20990TBL
<0.452 mg/Kg - dry 0.452 7.47Acrolein 500 07/07/22 10:02 V20990TBL
<0.280 mg/Kg - dry 0.280 7.47Acrylonitrile 500 07/07/22 10:02 V20990TBL
<0.217 mg/Kg - dry 0.217 1.87Benzene 500 07/07/22 10:02 V20990TBL
<0.187 mg/Kg - dry 0.187 1.87Bromobenzene 500 07/07/22 10:02 V20990TBL
<0.299 mg/Kg - dry 0.299 1.87Bromochloromethane 500 07/07/22 10:02 V20990TBL
<0.445 mg/Kg - dry 0.445 1.87Bromodichloromethane 500 07/07/22 10:02 V20990TBL
<0.378 mg/Kg - dry 0.378 1.87Bromoform 500 07/07/22 10:02 V20990TBL
<0.681 mg/Kg - dry 0.681 3.74
Bromomethane 500 07/07/22 10:02 V20990TBL
3.16 mg/Kg - dry 0.183 1.87n-Butylbenzene 500 07/07/22 10:02 V20990TBL
1.23 J mg/Kg - dry 0.209 1.87sec-Butyl benzene 500 07/07/22 10:02 V20990TBL
<0.187 mg/Kg - dry 0.187 1.87tert-Butyl benzene 500 07/07/22 10:02 V20990TBL
<0.238 mg/Kg - dry 0.238 1.87Carbon Disulfide 500 07/07/22 10:02 V20990TBL
<0.591 mg/Kg - dry 0.591 1.87Carbon Tetrachloride 500 07/07/22 10:02 V20990TBL
<0.250 mg/Kg - dry 0.250 1.87Chlorobenzene 500 07/07/22 10:02 V20990TBL
<0.332 mg/Kg - dry 0.332 1.87
Chlorodibromomethane 500 07/07/22 10:02 V20990TBL
<0.332 mg/Kg - dry 0.332 3.74Chloroethane 500 07/07/22 10:02 V20990TBL
<0.393 mg/Kg - dry 0.393 1.87Chloroform 500 07/07/22 10:02 V20990TBL
<0.235 mg/Kg - dry 0.235 3.74Chloromethane 500 07/07/22 10:02 V20990TBL
<0.190 mg/Kg - dry 0.190 1.872-Chlorotoluene 500 07/07/22 10:02 V20990TBL
<0.145 mg/Kg - dry 0.145 1.874-Chlorotoluene 500 07/07/22 10:02 V20990TBL
<0.273 mg/Kg - dry 0.273 1.87Di-Isopropyl Ether (DIPE)500 07/07/22 10:02 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
<0.164 mg/Kg - dry 0.164 3.741,2-Dibromo-3-Chloropropane 500 07/07/22 10:02 V20990TBL
<0.221 mg/Kg - dry 0.221 1.871,2-Dibromoethane 500 07/07/22 10:02 V20990TBL
<0.370 mg/Kg - dry 0.370 1.87Dibromomethane 500 07/07/22 10:02 V20990TBL
<0.116 mg/Kg - dry 0.116 1.871,2-Dichlorobenzene 500 07/07/22 10:02 V20990TBL
<0.141 mg/Kg - dry 0.141 1.871,3-Dichlorobenzene 500 07/07/22 10:02 V20990TBL
<0.225 mg/Kg - dry 0.225 1.871,4-Dichlorobenzene 500 07/07/22 10:02 V20990TBL
<0.494 mg/Kg - dry 0.494 3.74Dichlorodifluoromethane 500 07/07/22 10:02 V20990TBL
<0.307 mg/Kg - dry 0.307 1.871,1-Dichloroethane 500 07/07/22 10:02 V20990TBL
<0.515 mg/Kg - dry 0.515 1.87
1,2-Dichloroethane 500 07/07/22 10:02 V20990TBL
<0.273 mg/Kg - dry 0.273 1.871,1-Dichloroethene 500 07/07/22 10:02 V20990TBL
<0.295 mg/Kg - dry 0.295 1.87cis-1,2-Dichloroethene 500 07/07/22 10:02 V20990TBL
<0.393 mg/Kg - dry 0.393 1.87trans-1,2-Dichloroethene 500 07/07/22 10:02 V20990TBL
<0.164 mg/Kg - dry 0.164 1.871,2-Dichloropropane 500 07/07/22 10:02 V20990TBL
<0.206 mg/Kg - dry 0.206 1.871,3-Dichloropropane 500 07/07/22 10:02 V20990TBL
<0.475 mg/Kg - dry 0.475 1.872,2-Dichloropropane 500 07/07/22 10:02 V20990TBL
<0.284 mg/Kg - dry 0.284 1.87
1,1-Dichloropropene 500 07/07/22 10:02 V20990TBL
<0.202 mg/Kg - dry 0.202 1.87cis-1,3-Dichloropropene 500 07/07/22 10:02 V20990TBL
<0.299 mg/Kg - dry 0.299 1.87trans-1,3-Dichloropropene 500 07/07/22 10:02 V20990TBL
5.71 mg/Kg - dry 0.217 1.87Ethylbenzene 500 07/07/22 10:02 V20990TBL
<0.310 mg/Kg - dry 0.310 37.4Ethyl Tertiary Butyl Ether (ETBE)500 07/07/22 10:02 V20990TBL
<0.295 mg/Kg - dry 0.295 3.74Hexachlorobutadiene 500 07/07/22 10:02 V20990TBL
<0.246 mg/Kg - dry 0.246 3.74n-Hexane 500 07/07/22 10:02 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
<0.231 mg/Kg - dry 0.231 7.472-Hexanone 500 07/07/22 10:02 V20990TBL
2.12 mg/Kg - dry 0.171 1.87Isopropylbenzene 500 07/07/22 10:02 V20990TBL
0.838 J mg/Kg - dry 0.486 1.874-Isopropyl toluene 500 07/07/22 10:02 V20990TBL
<0.242 mg/Kg - dry 0.242 7.47Methyl Ethyl Ketone (MEK)500 07/07/22 10:02 V20990TBL
<0.232 mg/Kg - dry 0.232 1.87Methyl tert-butyl ether (MTBE)500 07/07/22 10:02 V20990TBL
<5.60 mg/Kg - dry 5.60 7.474-Methyl-2-Pentanone 500 07/07/22 10:02 V20990TBL
<0.549 mg/Kg - dry 0.549 1.87Methylene Chloride 500 07/07/22 10:02 V20990TBL
8.69 mg/Kg - dry 0.370 3.74Naphthalene 500 07/07/22 10:02 V20990TBL
7.27 mg/Kg - dry 0.202 1.87
n-Propylbenzene 500 07/07/22 10:02 V20990TBL
<0.530 mg/Kg - dry 0.530 1.87Styrene 500 07/07/22 10:02 V20990TBL
<0.393 mg/Kg - dry 0.393 1.871,1,1,2-Tetrachloroethane 500 07/07/22 10:02 V20990TBL
<0.119 mg/Kg - dry 0.119 1.871,1,2,2-Tetrachloroethane 500 07/07/22 10:02 V20990TBL
<0.336 mg/Kg - dry 0.336 1.87Tetrachloroethene 500 07/07/22 10:02 V20990TBL
<0.246 mg/Kg - dry 0.246 1.87Toluene 500 07/07/22 10:02 V20990TBL
<0.202 mg/Kg - dry 0.202 3.741,2,3-Trichlorobenzene 500 07/07/22 10:02 V20990TBL
<0.238 mg/Kg - dry 0.238 3.74
1,2,4-Trichlorobenzene 500 07/07/22 10:02 V20990TBL
<0.538 mg/Kg - dry 0.538 1.871,1,1-Trichloroethane 500 07/07/22 10:02 V20990TBL
<0.175 mg/Kg - dry 0.175 1.871,1,2-Trichloroethane 500 07/07/22 10:02 V20990TBL
<0.343 mg/Kg - dry 0.343 1.87Trichloroethene 500 07/07/22 10:02 V20990TBL
<0.782 mg/Kg - dry 0.782 3.74Trichlorofluoromethane 500 07/07/22 10:02 V20990TBL
<0.269 mg/Kg - dry 0.269 1.871,2,3-Trichloropropane 500 07/07/22 10:02 V20990TBL
75.3 mg/Kg - dry 0.183 1.871,2,4-Trimethylbenzene 500 07/07/22 10:02 V20990TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 MED
8260D Prep Batch(es):V20989 07/07/22 08:00
22.0 mg/Kg - dry 0.202 1.871,3,5-Trimethylbenzene 500 07/07/22 10:02 V20990TBL
<0.171 mg/Kg - dry 0.171 3.74Vinyl Acetate 500 07/07/22 10:02 V20990TBL
<0.179 mg/Kg - dry 0.179 3.74Vinyl Chloride 500 07/07/22 10:02 V20990TBL
10.5 mg/Kg - dry 0.187 1.87o-Xylene 500 07/07/22 10:02 V20990TBL
42.0 mg/Kg - dry 0.471 3.74m,p-Xylene 500 07/07/22 10:02 V20990TBL
52.5 mg/Kg - dry 0.187 1.87Xylene (Total)500 07/07/22 10:02 V20990
Surrogate: 4-Bromofluorobenzene 98.5 Limits: 70-130%07/07/22 10:02500 TBL V20990
Surrogate: Dibromofluoromethane 104 Limits: 70-130%07/07/22 10:02500 TBL V20990
Surrogate: Toluene-d8 96.6 Limits: 76-129%07/07/22 10:02500 TBL V20990
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R 10'
93416 Matrix:
6/28/2022 15:57
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
64.3 mg/Kg - dry 1.54 10.1Aliphatic C5-C8 (Adjusted)100 07/06/22 16:25
119 mg/Kg - dry 28.8 50.6Aliphatics C9-C12 (Adjusted)500 07/06/22 16:49
393 mg/Kg - dry 3.94 50.6Aromatic C9-C10 (Adjusted)500 07/06/22 16:49
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20938 07/06/22 08:00
64.3 mg/Kg - dry 1.54 10.1Aliphatic C5-C8 100 07/06/22 16:25 V20939TBL
570 mg/Kg - dry 28.8 50.6Aliphatic C9-C12 500 07/06/22 16:49 V20939TBL
393 mg/Kg - dry 3.94 50.6Aromatic C9-C10 500 07/06/22 16:49 V20939TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.2 Limits: 70-130%07/06/22 16:25100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.5 Limits: 70-130%07/06/22 16:25100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.6 Limits: 70-130%07/06/22 16:49500 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)85.7 Limits: 70-130%07/06/22 16:49500 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7 15'
93417 Matrix:
6/28/2022 9:42
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
7.0 %0.1%Clay 1 07/11/22 10:45 TextureEB
90.0 %%Sand 1 07/11/22 10:45 TextureEB
3.0 %0.1%Silt 1 07/11/22 10:45 TextureEB
SandSoil Classification 1 07/11/22 10:45 TextureEB
0.10 %0.05 0.05Total Organic Carbon 1 07/08/22 10:28 WALK-BLACKAAB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8 15'
93418 Matrix:
6/28/2022 15:36
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
17.0 %0.1%Clay 1 07/11/22 10:45 TextureEB
80.0 %%Sand 1 07/11/22 10:45 TextureEB
3.0 %0.1%Silt 1 07/11/22 10:45 TextureEB
Sandy LoamSoil Classification 1 07/11/22 10:45 TextureEB
0.07 %0.05 0.05Total Organic Carbon 1 07/08/22 10:28 WALK-BLACKAAB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93419 Matrix:
6/28/2022 7:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/11/22 16:40 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 16:40 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 16:40 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 16:40 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 16:40 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 16:40 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 16:40 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 16:40 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 16:40 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 16:40 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 16:40 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 16:40 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 16:40 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93419 Matrix:
6/28/2022 7:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 16:40 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 16:40 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 16:40 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 16:40 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 16:40 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 16:40 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 16:40 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 16:40 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 16:40 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 16:40 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 16:40 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 16:40 V21155JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 16:40 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 16:40 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 16:40 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 16:40 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 16:40 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93419 Matrix:
6/28/2022 7:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 16:40 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 16:40 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 16:40 V21155JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 16:40 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 16:40 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 16:40 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 16:40 V21155JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 07/11/22 16:40 V21155JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/11/22 16:40 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 16:40 V21155JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/11/22 16:40 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 16:40 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 07/11/22 16:40 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 16:40 V21155JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 16:40 V21155JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 16:40 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 16:40 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 16:40 V21155JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/11/22 16:40 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93419 Matrix:
6/28/2022 7:24
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 16:40 V21155JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/11/22 16:40 V21155
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%07/11/22 16:401 JLB V21155
Surrogate: Dibromofluoromethane 101 Limits: 70-130%07/11/22 16:401 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 90.2 Limits: 70-130%07/11/22 16:401 JLB V21155
Surrogate: Toluene-d8 87.8 Limits: 70-130%07/11/22 16:401 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-2
93420 Matrix:
6/29/2022 12:02
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 17:28 6200BJLB
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: Dibromofluoromethane 101 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 92.0 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: Toluene-d8 87.0 Limits: 70-130%07/11/22 17:281 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-2
93420 Matrix:
6/29/2022 12:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/11/22 17:28 V21155JLB
16.4 µg/L 0.180 0.500Benzene 1 07/11/22 17:28 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 17:28 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 17:28 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 17:28 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 17:28 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 17:28 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 17:28 V21155JLB
0.205 J
µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 17:28 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 17:28 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 17:28 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 17:28 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 17:28 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 17:28 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 17:28 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 17:28 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 17:28 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 17:28 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 17:28 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 17:28 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-2
93420 Matrix:
6/29/2022 12:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 17:28 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 17:28 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 17:28 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 17:28 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 17:28 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 17:28 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 17:28 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 17:28 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 17:28 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 17:28 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 17:28 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 17:28 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 17:28 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 17:28 V21155JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 17:28 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 17:28 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 17:28 V21155JLB
0.238 J µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 17:28 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 17:28 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 17:28 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-2
93420 Matrix:
6/29/2022 12:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 17:28 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 17:28 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 17:28 V21155JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 17:28 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 17:28 V21155JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 17:28 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 17:28 V21155JLB
13.5 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/11/22 17:28 V21155JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 17:28 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 17:28 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 17:28 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 17:28 V21155JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/11/22 17:28 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 17:28 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 17:28 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 17:28 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 17:28 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 17:28 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 17:28 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 17:28 V21155JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 17:28 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-2
93420 Matrix:
6/29/2022 12:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 17:28 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 17:28 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 17:28 V21155JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/11/22 17:28 V21155JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 17:28 V21155JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/11/22 17:28 V21155
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: Dibromofluoromethane 101 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 92.0 Limits: 70-130%07/11/22 17:281 JLB V21155
Surrogate: Toluene-d8 87.0 Limits: 70-130%07/11/22 17:281 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-3
93421 Matrix:
6/29/2022 12:14
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 07/11/22 20:39 6200BJLB
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 88.0 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: Toluene-d8 86.2 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 86.8 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: Toluene-d8 85.8 Limits: 70-130%07/11/22 21:03100 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-3
93421 Matrix:
6/29/2022 12:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<18.0 µg/L 18.0 100Acetone 10 07/11/22 20:39 V21155JLB
4020 µg/L 18.0 50.0Benzene 100 07/11/22 21:03 V21155JLB
<2.10 µg/L 2.10 5.00Bromobenzene 10 07/11/22 20:39 V21155JLB
<4.20 µg/L 4.20 10.0Bromochloromethane 10 07/11/22 20:39 V21155JLB
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 07/11/22 20:39 V21155JLB
<15.0 µg/L 15.0 50.0Bromoform 10 07/11/22 20:39 V21155JLB
<2.80 µg/L 2.80 10.0Bromomethane 10 07/11/22 20:39 V21155JLB
7.90 µg/L 1.80 5.00n-Butylbenzene 10 07/11/22 20:39 V21155JLB
5.38 µg/L 2.00 5.00
sec-Butyl benzene 10 07/11/22 20:39 V21155JLB
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 07/11/22 20:39 V21155JLB
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 07/11/22 20:39 V21155JLB
<1.90 µg/L 1.90 5.00Chlorobenzene 10 07/11/22 20:39 V21155JLB
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 07/11/22 20:39 V21155JLB
<4.30 µg/L 4.30 10.0Chloroethane 10 07/11/22 20:39 V21155JLB
<2.20 µg/L 2.20 5.00Chloroform 10 07/11/22 20:39 V21155JLB
<2.20 µg/L 2.20 5.00
Chloromethane 10 07/11/22 20:39 V21155JLB
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 07/11/22 20:39 V21155JLB
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 07/11/22 20:39 V21155JLB
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 07/11/22 20:39 V21155JLB
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 07/11/22 20:39 V21155JLB
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 07/11/22 20:39 V21155JLB
<2.30 µg/L 2.30 5.00Dibromomethane 10 07/11/22 20:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-3
93421 Matrix:
6/29/2022 12:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 07/11/22 20:39 V21155JLB
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 07/11/22 20:39 V21155JLB
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 07/11/22 20:39 V21155JLB
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 07/11/22 20:39 V21155JLB
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 07/11/22 20:39 V21155JLB
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 07/11/22 20:39 V21155JLB
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 07/11/22 20:39 V21155JLB
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 07/11/22 20:39 V21155JLB
<1.80 µg/L 1.80 5.00
trans-1,2-Dichloroethene 10 07/11/22 20:39 V21155JLB
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 07/11/22 20:39 V21155JLB
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 07/11/22 20:39 V21155JLB
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 07/11/22 20:39 V21155JLB
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 07/11/22 20:39 V21155JLB
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 07/11/22 20:39 V21155JLB
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 07/11/22 20:39 V21155JLB
<420 µg/L 420 2000
Ethanol 10 07/11/22 20:39 V21155JLB
944 µg/L 1.70 5.00Ethylbenzene 10 07/11/22 20:39 V21155JLB
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 07/11/22 20:39 V21155JLB
<3.80 µg/L 3.80 10.02-Hexanone 10 07/11/22 20:39 V21155JLB
44.8 µg/L 1.80 5.00Isopropylbenzene 10 07/11/22 20:39 V21155JLB
2.16 J µg/L 0.890 5.004-Isopropyl toluene 10 07/11/22 20:39 V21155JLB
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 07/11/22 20:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-3
93421 Matrix:
6/29/2022 12:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 07/11/22 20:39 V21155JLB
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 07/11/22 20:39 V21155JLB
<3.30 µg/L 3.30 20.0Methylene Chloride 10 07/11/22 20:39 V21155JLB
183 µg/L 4.70 10.0Naphthalene 10 07/11/22 20:39 V21155JLB
113 µg/L 1.90 5.00n-Propylbenzene 10 07/11/22 20:39 V21155JLB
<2.20 µg/L 2.20 5.00Styrene 10 07/11/22 20:39 V21155JLB
<16.0 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 07/11/22 20:39 V21155JLB
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 07/11/22 20:39 V21155JLB
474 µg/L 19.0 100
tert-Amyl Alcohol (TAA)10 07/11/22 20:39 V21155JLB
<2.80 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 07/11/22 20:39 V21155JLB
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 07/11/22 20:39 V21155JLB
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 07/11/22 20:39 V21155JLB
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 07/11/22 20:39 V21155JLB
23.2 µg/L 2.20 5.00Toluene 10 07/11/22 20:39 V21155JLB
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 07/11/22 20:39 V21155JLB
<3.10 µg/L 3.10 5.00
1,2,4-Trichlorobenzene 10 07/11/22 20:39 V21155JLB
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 07/11/22 20:39 V21155JLB
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 07/11/22 20:39 V21155JLB
<1.80 µg/L 1.80 5.00Trichloroethene 10 07/11/22 20:39 V21155JLB
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 07/11/22 20:39 V21155JLB
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 07/11/22 20:39 V21155JLB
748 µg/L 1.90 5.001,2,4-Trimethylbenzene 10 07/11/22 20:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-3
93421 Matrix:
6/29/2022 12:14
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
135 µg/L 1.80 5.001,3,5-Trimethylbenzene 10 07/11/22 20:39 V21155JLB
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 07/11/22 20:39 V21155JLB
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 07/11/22 20:39 V21155JLB
2.20 J µg/L 2.10 5.00o-Xylene 10 07/11/22 20:39 V21155JLB
382 µg/L 4.20 10.0m,p-Xylene 10 07/11/22 20:39 V21155JLB
384 J µg/L 2.10 5.00Xylene (Total)10 07/11/22 20:39 V21155
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 88.0 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: Toluene-d8 86.2 Limits: 70-130%07/11/22 20:3910 JLB V21155
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 86.8 Limits: 70-130%07/11/22 21:03100 JLB V21155
Surrogate: Toluene-d8 85.8 Limits: 70-130%07/11/22 21:03100 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-4
93422 Matrix:
6/29/2022 12:23
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 17:52 6200BJLB
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 91.4 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: Toluene-d8 88.2 Limits: 70-130%07/11/22 17:521 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-4
93422 Matrix:
6/29/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/11/22 17:52 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 17:52 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 17:52 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 17:52 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 17:52 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 17:52 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 17:52 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 17:52 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 17:52 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 17:52 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 17:52 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 17:52 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 17:52 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-4
93422 Matrix:
6/29/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 17:52 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 17:52 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 17:52 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 17:52 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 17:52 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 17:52 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 17:52 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 17:52 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 17:52 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 17:52 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 17:52 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 17:52 V21155JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 17:52 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 17:52 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 17:52 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 17:52 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 17:52 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-4
93422 Matrix:
6/29/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 17:52 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 17:52 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 17:52 V21155JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 17:52 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 17:52 V21155JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 17:52 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 17:52 V21155JLB
<1.90 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/11/22 17:52 V21155JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 17:52 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 17:52 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 17:52 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 17:52 V21155JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/11/22 17:52 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 17:52 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 17:52 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 17:52 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 17:52 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 17:52 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 17:52 V21155JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 17:52 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-4
93422 Matrix:
6/29/2022 12:23
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 17:52 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 17:52 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 17:52 V21155JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/11/22 17:52 V21155JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 17:52 V21155JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/11/22 17:52 V21155
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 91.4 Limits: 70-130%07/11/22 17:521 JLB V21155
Surrogate: Toluene-d8 88.2 Limits: 70-130%07/11/22 17:521 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 19:51 6200BJLB
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: Dibromofluoromethane 102 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: Toluene-d8 85.8 Limits: 70-130%07/11/22 19:511 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
14.4 µg/L 1.80 10.0Acetone 1 07/11/22 19:51 V21155JLB
1.50 µg/L 0.180 0.500Benzene 1 07/11/22 19:51 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 19:51 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 19:51 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 19:51 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 19:51 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 19:51 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 19:51 V21155JLB
0.705 µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 19:51 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 19:51 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 19:51 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 19:51 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 19:51 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 19:51 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 19:51 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 19:51 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 19:51 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 19:51 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 19:51 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 19:51 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 19:51 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 19:51 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 19:51 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 19:51 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 19:51 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 19:51 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 19:51 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 19:51 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 19:51 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 19:51 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 19:51 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 19:51 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 19:51 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 19:51 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 19:51 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 19:51 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 19:51 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 19:51 V21155JLB
0.677 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 19:51 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 19:51 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 19:51 V21155JLB
0.554 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 19:51 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 19:51 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 19:51 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 46 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
0.246 J µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 19:51 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 19:51 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 19:51 V21155JLB
3.75 µg/L 0.470 1.00Naphthalene 1 07/11/22 19:51 V21155JLB
0.291 J µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 19:51 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 19:51 V21155JLB
11.8 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 19:51 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 19:51 V21155JLB
38.7 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/11/22 19:51 V21155JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 19:51 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 19:51 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 19:51 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 19:51 V21155JLB
0.241 J µg/L 0.220 0.500Toluene 1 07/11/22 19:51 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 19:51 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 19:51 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 19:51 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 19:51 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 19:51 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 19:51 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 19:51 V21155JLB
0.432 J µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 19:51 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 47 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 19:51 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 19:51 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 19:51 V21155JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/11/22 19:51 V21155JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 19:51 V21155JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/11/22 19:51 V21155
Surrogate: 4-Bromofluorobenzene 99.6 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: Dibromofluoromethane 102 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 94.6 Limits: 70-130%07/11/22 19:511 JLB V21155
Surrogate: Toluene-d8 85.8 Limits: 70-130%07/11/22 19:511 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 48 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-5
93423 Matrix:
6/29/2022 12:32
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
189 J µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/05/22 16:53
42.0 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/05/22 16:53
33.1 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/05/22 16:53
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20868 07/05/22 08:00
191 µg/L 11.5 50.0Aliphatic C5-C8 1 07/05/22 16:53 V20869TBL
75.8 µg/L 25.8 50.0Aliphatic C9-C12 1 07/05/22 16:53 V20869TBL
33.1 J µg/L 4.02 50.0Aromatic C9-C10 1 07/05/22 16:53 V20869TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)89.7 Limits: 70-130%07/05/22 16:531 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)86.8 Limits: 70-130%07/05/22 16:531 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 49 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 18:16 6200BJLB
Surrogate: 4-Bromofluorobenzene 98.6 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 88.4 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: Toluene-d8 87.8 Limits: 70-130%07/11/22 18:161 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 50 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/11/22 18:16 V21155JLB
34.8 µg/L 0.180 0.500Benzene 1 07/11/22 18:16 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 18:16 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 18:16 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 18:16 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 18:16 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 18:16 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 18:16 V21155JLB
0.288 J
µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 18:16 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 18:16 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 18:16 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 18:16 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 18:16 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 18:16 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 18:16 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 18:16 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 18:16 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 18:16 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 18:16 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 18:16 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 18:16 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 18:16 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 51 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 18:16 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 18:16 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 18:16 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 18:16 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 18:16 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 18:16 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 18:16 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 18:16 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 18:16 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 18:16 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 18:16 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 18:16 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 18:16 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 18:16 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 18:16 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 18:16 V21155JLB
6.72 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 18:16 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 18:16 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 18:16 V21155JLB
0.991 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 18:16 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 18:16 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 18:16 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 52 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 18:16 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 18:16 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 18:16 V21155JLB
0.933 J µg/L 0.470 1.00Naphthalene 1 07/11/22 18:16 V21155JLB
1.13 µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 18:16 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 18:16 V21155JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 18:16 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 18:16 V21155JLB
16.6 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/11/22 18:16 V21155JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 18:16 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 18:16 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 18:16 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 18:16 V21155JLB
35.9 µg/L 0.220 0.500Toluene 1 07/11/22 18:16 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 18:16 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 18:16 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 18:16 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 18:16 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 18:16 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 18:16 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 18:16 V21155JLB
8.25 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 18:16 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 53 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
2.72 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 18:16 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 18:16 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 18:16 V21155JLB
13.2 µg/L 0.210 0.500o-Xylene 1 07/11/22 18:16 V21155JLB
39.9 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 18:16 V21155JLB
53.1 µg/L 0.210 0.500Xylene (Total)1 07/11/22 18:16 V21155
Surrogate: 4-Bromofluorobenzene 98.6 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 88.4 Limits: 70-130%07/11/22 18:161 JLB V21155
Surrogate: Toluene-d8 87.8 Limits: 70-130%07/11/22 18:161 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 54 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-6
93424 Matrix:
6/29/2022 12:44
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
141 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/06/22 11:51
72.1 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/06/22 11:51
31.1 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/06/22 11:51
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20868 07/05/22 08:00
212 µg/L 11.5 50.0Aliphatic C5-C8 1 07/06/22 11:51 V20869TBL
163 µg/L 25.8 50.0Aliphatic C9-C12 1 07/06/22 11:51 V20869TBL
31.1 J µg/L 4.02 50.0Aromatic C9-C10 1 07/06/22 11:51 V20869TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)78.7 Limits: 70-130%07/06/22 11:511 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)79.7 Limits: 70-130%07/06/22 11:511 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 55 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 18:39 6200BJLB
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: Toluene-d8 85.2 Limits: 70-130%07/11/22 18:391 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 56 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
27.7 µg/L 1.80 10.0Acetone 1 07/11/22 18:39 V21155JLB
61.4 µg/L 0.180 0.500Benzene 1 07/11/22 18:39 V21155JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 18:39 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 18:39 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 18:39 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 18:39 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 18:39 V21155JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 18:39 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 18:39 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 18:39 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 18:39 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 18:39 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 18:39 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 18:39 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 18:39 V21155JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 18:39 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 18:39 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 18:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 57 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 18:39 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 18:39 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 18:39 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 18:39 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 18:39 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 18:39 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 18:39 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 18:39 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 18:39 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 18:39 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 18:39 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 18:39 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 18:39 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 18:39 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 18:39 V21155JLB
3.01 µg/L 0.170 0.500Ethylbenzene 1 07/11/22 18:39 V21155JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 18:39 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 18:39 V21155JLB
1.60 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 18:39 V21155JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 18:39 V21155JLB
6.51 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 18:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 58 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 18:39 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 18:39 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 18:39 V21155JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/11/22 18:39 V21155JLB
2.02 µg/L 0.190 0.500n-Propylbenzene 1 07/11/22 18:39 V21155JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 18:39 V21155JLB
13.8 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 18:39 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 18:39 V21155JLB
18.3 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/11/22 18:39 V21155JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 18:39 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 18:39 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 18:39 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 18:39 V21155JLB
1.62 µg/L 0.220 0.500Toluene 1 07/11/22 18:39 V21155JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 18:39 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 18:39 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 18:39 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 18:39 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 18:39 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 18:39 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 18:39 V21155JLB
6.87 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/11/22 18:39 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 59 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00
1.91 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 18:39 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 18:39 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 18:39 V21155JLB
2.45 µg/L 0.210 0.500o-Xylene 1 07/11/22 18:39 V21155JLB
11.8 µg/L 0.420 1.00m,p-Xylene 1 07/11/22 18:39 V21155JLB
14.3 µg/L 0.210 0.500Xylene (Total)1 07/11/22 18:39 V21155
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 92.6 Limits: 70-130%07/11/22 18:391 JLB V21155
Surrogate: Toluene-d8 85.2 Limits: 70-130%07/11/22 18:391 JLB V21155
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 60 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-7
93425 Matrix:
6/29/2022 12:53
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/05/22 17:17
42.9 J µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/05/22 17:17
14.8 J µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/05/22 17:17
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20868 07/05/22 08:00
67.3 µg/L 11.5 50.0Aliphatic C5-C8 1 07/05/22 17:17 V20869TBL
75.0 µg/L 25.8 50.0Aliphatic C9-C12 1 07/05/22 17:17 V20869TBL
14.8 J µg/L 4.02 50.0Aromatic C9-C10 1 07/05/22 17:17 V20869TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.7 Limits: 70-130%07/05/22 17:171 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)80.1 Limits: 70-130%07/05/22 17:171 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 61 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/11/22 19:03 6200BJLB
Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: Toluene-d8 87.0 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: Dibromofluoromethane 100 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 87.2 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: Toluene-d8 83.0 Limits: 70-130%07/12/22 16:20100 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 62 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 07/11/22 19:03 V21155JLB
2870 µg/L 18.0 50.0Benzene 100 07/12/22 16:20 V21202JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/11/22 19:03 V21155JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/11/22 19:03 V21155JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/11/22 19:03 V21155JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/11/22 19:03 V21155JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/11/22 19:03 V21155JLB
9.91 µg/L 0.180 0.500n-Butylbenzene 1 07/11/22 19:03 V21155JLB
6.21 µg/L 0.200 0.500
sec-Butyl benzene 1 07/11/22 19:03 V21155JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/11/22 19:03 V21155JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/11/22 19:03 V21155JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/11/22 19:03 V21155JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/11/22 19:03 V21155JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/11/22 19:03 V21155JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/11/22 19:03 V21155JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/11/22 19:03 V21155JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/11/22 19:03 V21155JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/11/22 19:03 V21155JLB
2.63 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/11/22 19:03 V21155JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/11/22 19:03 V21155JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/11/22 19:03 V21155JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/11/22 19:03 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 63 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/11/22 19:03 V21155JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/11/22 19:03 V21155JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/11/22 19:03 V21155JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/11/22 19:03 V21155JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/11/22 19:03 V21155JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/11/22 19:03 V21155JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/11/22 19:03 V21155JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/11/22 19:03 V21155JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/11/22 19:03 V21155JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/11/22 19:03 V21155JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/11/22 19:03 V21155JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/11/22 19:03 V21155JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/11/22 19:03 V21155JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/11/22 19:03 V21155JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/11/22 19:03 V21155JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/11/22 19:03 V21155JLB
1720 µg/L 17.0 50.0Ethylbenzene 100 07/12/22 16:20 V21202JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/11/22 19:03 V21155JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/11/22 19:03 V21155JLB
74.9 µg/L 0.180 0.500Isopropylbenzene 1 07/11/22 19:03 V21155JLB
2.48 µg/L 0.089 0.5004-Isopropyl toluene 1 07/11/22 19:03 V21155JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/11/22 19:03 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 64 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
4.44 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/11/22 19:03 V21155JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/11/22 19:03 V21155JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/11/22 19:03 V21155JLB
383 µg/L 47.0 100Naphthalene 100 07/12/22 16:20 V21202JLB
187 µg/L 19.0 50.0n-Propylbenzene 100 07/12/22 16:20 V21202JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/11/22 19:03 V21155JLB
94.6 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/11/22 19:03 V21155JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/11/22 19:03 V21155JLB
657 J
µg/L 190 1000
tert-Amyl Alcohol (TAA)100 07/12/22 16:20 V21202JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/11/22 19:03 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/11/22 19:03 V21155JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/11/22 19:03 V21155JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/11/22 19:03 V21155JLB
187 µg/L 22.0 50.0Toluene 100 07/12/22 16:20 V21202JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/11/22 19:03 V21155JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/11/22 19:03 V21155JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/11/22 19:03 V21155JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/11/22 19:03 V21155JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/11/22 19:03 V21155JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/11/22 19:03 V21155JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/11/22 19:03 V21155JLB
181 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 07/12/22 16:20 V21202JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 65 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
96.4 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/11/22 19:03 V21155JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/11/22 19:03 V21155JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/11/22 19:03 V21155JLB
67.0 µg/L 0.210 0.500o-Xylene 1 07/11/22 19:03 V21155JLB
644 µg/L 42.0 100m,p-Xylene 100 07/12/22 16:20 V21202JLB
711 µg/L 0.210 0.500Xylene (Total)1 07/11/22 19:03 V21202
Surrogate: 4-Bromofluorobenzene 96.4 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 94.0 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: Toluene-d8 87.0 Limits: 70-130%07/11/22 19:031 JLB V21155
Surrogate: 4-Bromofluorobenzene 98.0 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: Dibromofluoromethane 100 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 87.2 Limits: 70-130%07/12/22 16:20100 JLB V21202
Surrogate: Toluene-d8 83.0 Limits: 70-130%07/12/22 16:20100 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 66 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-8
93426 Matrix:
6/29/2022 13:02
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
833 µg/L 115 500Aliphatic C5-C8 (Adjusted)10 07/06/22 11:28
959 µg/L 258 500Aliphatics C9-C12 (Adjusted)1 07/06/22 11:28
1470 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 07/06/22 11:28
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20868 07/05/22 08:00
3890 µg/L 115 500Aliphatic C5-C8 10 07/06/22 11:28 V20869TBL
4860 µg/L 258 500Aliphatic C9-C12 10 07/06/22 11:28 V20869TBL
1470 µg/L 40.2 500Aromatic C9-C10 10 07/06/22 11:28 V20869TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)103 Limits: 70-130%07/06/22 11:2810 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)82.6 Limits: 70-130%07/06/22 11:2810 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 67 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R
93427 Matrix:
6/29/2022 13:11
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<10.0 µg/L 10.0 1003,3-Dimethyl-1-butanol 10 07/11/22 21:27 6200BJLB
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: Dibromofluoromethane 104 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 110 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: Toluene-d8 86.4 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: Dibromofluoromethane 100 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 87.2 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: Toluene-d8 88.4 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: Dibromofluoromethane 102 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 86.6 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: Toluene-d8 83.2 Limits: 70-130%07/12/22 15:321000 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 68 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R
93427 Matrix:
6/29/2022 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
<18.0 µg/L 18.0 100Acetone 10 07/11/22 21:27 V21155JLB
4790 µg/L 18.0 50.0Benzene 100 07/11/22 21:50 V21155JLB
<2.10 µg/L 2.10 5.00Bromobenzene 10 07/11/22 21:27 V21155JLB
<4.20 µg/L 4.20 10.0Bromochloromethane 10 07/11/22 21:27 V21155JLB
<1.60 µg/L 1.60 5.00Bromodichloromethane 10 07/11/22 21:27 V21155JLB
<15.0 µg/L 15.0 50.0Bromoform 10 07/11/22 21:27 V21155JLB
<2.80 µg/L 2.80 10.0Bromomethane 10 07/11/22 21:27 V21155JLB
163 µg/L 1.80 5.00n-Butylbenzene 10 07/11/22 21:27 V21155JLB
96.6 µg/L 2.00 5.00
sec-Butyl benzene 10 07/11/22 21:27 V21155JLB
<9.20 µg/L 9.20 20.0tert-Butyl benzene 10 07/11/22 21:27 V21155JLB
<1.80 µg/L 1.80 5.00Carbon Tetrachloride 10 07/11/22 21:27 V21155JLB
<1.90 µg/L 1.90 5.00Chlorobenzene 10 07/11/22 21:27 V21155JLB
<1.90 µg/L 1.90 5.00Chlorodibromomethane 10 07/11/22 21:27 V21155JLB
<4.30 µg/L 4.30 10.0Chloroethane 10 07/11/22 21:27 V21155JLB
<2.20 µg/L 2.20 5.00Chloroform 10 07/11/22 21:27 V21155JLB
<2.20 µg/L 2.20 5.00
Chloromethane 10 07/11/22 21:27 V21155JLB
<2.00 µg/L 2.00 5.002-Chlorotoluene 10 07/11/22 21:27 V21155JLB
<2.00 µg/L 2.00 5.004-Chlorotoluene 10 07/11/22 21:27 V21155JLB
<5.00 µg/L 5.00 5.00Di-Isopropyl Ether (DIPE)10 07/11/22 21:27 V21155JLB
<11.0 µg/L 11.0 20.01,2-Dibromo-3-Chloropropane 10 07/11/22 21:27 V21155JLB
<2.00 µg/L 2.00 5.001,2-Dibromoethane 10 07/11/22 21:27 V21155JLB
<2.30 µg/L 2.30 5.00Dibromomethane 10 07/11/22 21:27 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 69 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R
93427 Matrix:
6/29/2022 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
<2.20 µg/L 2.20 5.001,2-Dichlorobenzene 10 07/11/22 21:27 V21155JLB
<1.90 µg/L 1.90 5.001,3-Dichlorobenzene 10 07/11/22 21:27 V21155JLB
<2.10 µg/L 2.10 5.001,4-Dichlorobenzene 10 07/11/22 21:27 V21155JLB
<12.0 µg/L 12.0 50.0Dichlorodifluoromethane 10 07/11/22 21:27 V21155JLB
<2.40 µg/L 2.40 5.001,1-Dichloroethane 10 07/11/22 21:27 V21155JLB
<1.50 µg/L 1.50 5.001,2-Dichloroethane 10 07/11/22 21:27 V21155JLB
<1.50 µg/L 1.50 5.001,1-Dichloroethene 10 07/11/22 21:27 V21155JLB
<2.00 µg/L 2.00 5.00cis-1,2-Dichloroethene 10 07/11/22 21:27 V21155JLB
<1.80 µg/L 1.80 5.00
trans-1,2-Dichloroethene 10 07/11/22 21:27 V21155JLB
<1.90 µg/L 1.90 5.001,2-Dichloropropane 10 07/11/22 21:27 V21155JLB
<1.30 µg/L 1.30 5.001,3-Dichloropropane 10 07/11/22 21:27 V21155JLB
<2.10 µg/L 2.10 20.02,2-Dichloropropane 10 07/11/22 21:27 V21155JLB
<2.00 µg/L 2.00 5.001,1-Dichloropropene 10 07/11/22 21:27 V21155JLB
<2.10 µg/L 2.10 5.00cis-1,3-Dichloropropene 10 07/11/22 21:27 V21155JLB
<1.50 µg/L 1.50 5.00trans-1,3-Dichloropropene 10 07/11/22 21:27 V21155JLB
<420 µg/L 420 2000
Ethanol 10 07/11/22 21:27 V21155JLB
3360 µg/L 17.0 50.0Ethylbenzene 100 07/11/22 21:50 V21155JLB
<3.50 µg/L 3.50 30.0Hexachlorobutadiene 10 07/11/22 21:27 V21155JLB
<3.80 µg/L 3.80 10.02-Hexanone 10 07/11/22 21:27 V21155JLB
507 µg/L 1.80 5.00Isopropylbenzene 10 07/11/22 21:27 V21155JLB
65.9 µg/L 0.890 5.004-Isopropyl toluene 10 07/11/22 21:27 V21155JLB
<7.10 µg/L 7.10 50.0Methyl Ethyl Ketone (MEK)10 07/11/22 21:27 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 70 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R
93427 Matrix:
6/29/2022 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
<1.40 µg/L 1.40 10.0Methyl tert-butyl ether (MTBE)10 07/11/22 21:27 V21155JLB
<0.780 µg/L 0.780 10.04-Methyl-2-Pentanone 10 07/11/22 21:27 V21155JLB
<3.30 µg/L 3.30 20.0Methylene Chloride 10 07/11/22 21:27 V21155JLB
3060 µg/L 47.0 100Naphthalene 100 07/11/22 21:50 V21155JLB
470 µg/L 19.0 50.0n-Propylbenzene 100 07/11/22 21:50 V21155JLB
<2.20 µg/L 2.20 5.00Styrene 10 07/11/22 21:27 V21155JLB
<16.0 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 07/11/22 21:27 V21155JLB
<3.50 µg/L 3.50 100tert-Butyl formate (TBF)10 07/11/22 21:27 V21155JLB
<19.0 µg/L 19.0 100
tert-Amyl Alcohol (TAA)10 07/11/22 21:27 V21155JLB
<2.80 µg/L 2.80 100tert-Amyl Methyl Ether (TAME)10 07/11/22 21:27 V21155JLB
<1.60 µg/L 1.60 5.001,1,1,2-Tetrachloroethane 10 07/11/22 21:27 V21155JLB
<1.60 µg/L 1.60 5.001,1,2,2-Tetrachloroethane 10 07/11/22 21:27 V21155JLB
<2.20 µg/L 2.20 5.00Tetrachloroethene 10 07/11/22 21:27 V21155JLB
29100 µg/L 220 500Toluene 1000 07/12/22 15:32 V21202JLB
<3.80 µg/L 3.80 5.001,2,3-Trichlorobenzene 10 07/11/22 21:27 V21155JLB
<3.10 µg/L 3.10 5.00
1,2,4-Trichlorobenzene 10 07/11/22 21:27 V21155JLB
<1.60 µg/L 1.60 5.001,1,1-Trichloroethane 10 07/11/22 21:27 V21155JLB
<0.960 µg/L 0.960 5.001,1,2-Trichloroethane 10 07/11/22 21:27 V21155JLB
<1.80 µg/L 1.80 5.00Trichloroethene 10 07/11/22 21:27 V21155JLB
<1.80 µg/L 1.80 5.00Trichlorofluoromethane 10 07/11/22 21:27 V21155JLB
<2.70 µg/L 2.70 5.001,2,3-Trichloropropane 10 07/11/22 21:27 V21155JLB
4760 µg/L 19.0 50.01,2,4-Trimethylbenzene 100 07/11/22 21:50 V21155JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 71 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:MW-1R
93427 Matrix:
6/29/2022 13:11
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21154 07/11/22 09:00 V21201 07/12/22 09:00
1180 µg/L 18.0 50.01,3,5-Trimethylbenzene 100 07/11/22 21:50 V21155JLB
<10.0 µg/L 10.0 50.0Vinyl Acetate 10 07/11/22 21:27 V21155JLB
<1.70 µg/L 1.70 5.00Vinyl Chloride 10 07/11/22 21:27 V21155JLB
4790 µg/L 21.0 50.0o-Xylene 100 07/11/22 21:50 V21155JLB
15000 µg/L 42.0 100m,p-Xylene 100 07/11/22 21:50 V21155JLB
19800 µg/L 21.0 50.0Xylene (Total)100 07/11/22 21:50 V21155
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: Dibromofluoromethane 104 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 110 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: Toluene-d8 86.4 Limits: 70-130%07/11/22 21:2710 JLB V21155
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: Dibromofluoromethane 100 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: 1,2-Dichloroethane - d4 87.2 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: Toluene-d8 88.4 Limits: 70-130%07/11/22 21:50100 JLB V21155
Surrogate: 4-Bromofluorobenzene 97.0 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: Dibromofluoromethane 102 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 86.6 Limits: 70-130%07/12/22 15:321000 JLB V21202
Surrogate: Toluene-d8 83.2 Limits: 70-130%07/12/22 15:321000 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 72 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1 45'
93428 Matrix:
6/30/2022 11:42
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
51.0 %0.1%Clay 1 07/11/22 10:45 TextureEB
24.0 %%Sand 1 07/11/22 10:45 TextureEB
25.0 %0.1%Silt 1 07/11/22 10:45 TextureEB
ClaySoil Classification 1 07/11/22 10:45 TextureEB
2.37 %0.05 0.05Total Organic Carbon 1 07/08/22 10:28 WALK-BLACKAAB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 73 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 07/12/22 15:09 6200BJLB
Surrogate: 4-Bromofluorobenzene 98.2 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: Dibromofluoromethane 104 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 108 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: Toluene-d8 80.4 Limits: 70-130%07/12/22 15:091 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 74 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21201 07/12/22 09:00
23.5 µg/L 1.80 10.0Acetone 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/12/22 15:09 V21202JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/12/22 15:09 V21202JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/12/22 15:09 V21202JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/12/22 15:09 V21202JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/12/22 15:09 V21202JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/12/22 15:09 V21202JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/12/22 15:09 V21202JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/12/22 15:09 V21202JLB
1.41 µg/L 0.220 0.500Chloroform 1 07/12/22 15:09 V21202JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/12/22 15:09 V21202JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/12/22 15:09 V21202JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/12/22 15:09 V21202JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/12/22 15:09 V21202JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 75 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21201 07/12/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/12/22 15:09 V21202JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/12/22 15:09 V21202JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/12/22 15:09 V21202JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/12/22 15:09 V21202JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/12/22 15:09 V21202JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/12/22 15:09 V21202JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/12/22 15:09 V21202JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/12/22 15:09 V21202JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/12/22 15:09 V21202JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/12/22 15:09 V21202JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/12/22 15:09 V21202JLB
72.9 J
µg/L 42.0 200
Ethanol 1 07/12/22 15:09 V21202JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/12/22 15:09 V21202JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/12/22 15:09 V21202JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/12/22 15:09 V21202JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/12/22 15:09 V21202JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/12/22 15:09 V21202JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 76 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21201 07/12/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/12/22 15:09 V21202JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/12/22 15:09 V21202JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/12/22 15:09 V21202JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/12/22 15:09 V21202JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/12/22 15:09 V21202JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 07/12/22 15:09 V21202JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/12/22 15:09 V21202JLB
<1.90 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 07/12/22 15:09 V21202JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/12/22 15:09 V21202JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/12/22 15:09 V21202JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/12/22 15:09 V21202JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/12/22 15:09 V21202JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/12/22 15:09 V21202JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/12/22 15:09 V21202JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/12/22 15:09 V21202JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/12/22 15:09 V21202JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/12/22 15:09 V21202JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/12/22 15:09 V21202JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/12/22 15:09 V21202JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/12/22 15:09 V21202JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 77 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21201 07/12/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/12/22 15:09 V21202JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/12/22 15:09 V21202JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/12/22 15:09 V21202JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/12/22 15:09 V21202JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/12/22 15:09 V21202JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/12/22 15:09 V21202
Surrogate: 4-Bromofluorobenzene 98.2 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: Dibromofluoromethane 104 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: 1,2-Dichloroethane - d4 108 Limits: 70-130%07/12/22 15:091 JLB V21202
Surrogate: Toluene-d8 80.4 Limits: 70-130%07/12/22 15:091 JLB V21202
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 78 of 104
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-182-0020
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
Rae Brown
Winterville
Danyale Love
Project Manager
GRI # 5586 Received : 07/01/2022
RL Village Store
Report Date : 07/13/2022
Sample ID :
Lab No :
Sampled:TW-1
93429 Matrix:
6/30/2022 14:15
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 07/05/22 14:55
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/05/22 14:55
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/05/22 14:55
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V20868 07/05/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 07/05/22 14:55 V20869TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 07/05/22 14:55 V20869TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 07/05/22 14:55 V20869TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)93.0 Limits: 70-130%07/05/22 14:551 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)84.6 Limits: 70-130%07/05/22 14:551 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Page 79 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
Associated Lab Samples: 93419, 93420, 93421, 93422, 93423, 93424, 93425, 93426, 93427
LRB-V21154 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/11/22 13:0610.01.80<1.80µg/LAcetone
07/11/22 13:060.5000.180<0.180µg/LBenzene
07/11/22 13:060.5000.210<0.210µg/LBromobenzene
07/11/22 13:061.000.420<0.420µg/LBromochloromethane
07/11/22 13:060.5000.160<0.160µg/LBromodichloromethane
07/11/22 13:065.001.50<1.50µg/LBromoform
07/11/22 13:061.000.280<0.280µg/LBromomethane
07/11/22 13:060.5000.180<0.180µg/Ln-Butylbenzene
07/11/22 13:060.5000.200<0.200µg/Lsec-Butyl benzene
07/11/22 13:062.000.920<0.920µg/Ltert-Butyl benzene
07/11/22 13:060.5000.180<0.180µg/LCarbon Tetrachloride
07/11/22 13:060.5000.190<0.190µg/LChlorobenzene
07/11/22 13:060.5000.190<0.190µg/LChlorodibromomethane
07/11/22 13:061.000.430<0.430µg/LChloroethane
07/11/22 13:060.5000.220<0.220µg/LChloroform
07/11/22 13:060.5000.220<0.220µg/LChloromethane
07/11/22 13:060.5000.200<0.200µg/L2-Chlorotoluene
07/11/22 13:060.5000.200<0.200µg/L4-Chlorotoluene
07/11/22 13:060.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/11/22 13:062.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/11/22 13:060.5000.200<0.200µg/L1,2-Dibromoethane
07/11/22 13:060.5000.230<0.230µg/LDibromomethane
07/11/22 13:060.5000.220<0.220µg/L1,2-Dichlorobenzene
07/11/22 13:060.5000.190<0.190µg/L1,3-Dichlorobenzene
07/11/22 13:060.5000.210<0.210µg/L1,4-Dichlorobenzene
07/11/22 13:065.001.20<1.20µg/LDichlorodifluoromethane
07/11/22 13:060.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 22Date:07/13/2022 03:10 PM
Page 80 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
Associated Lab Samples: 93419, 93420, 93421, 93422, 93423, 93424, 93425, 93426, 93427
LRB-V21154 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/11/22 13:060.5000.150<0.150µg/L1,2-Dichloroethane
07/11/22 13:060.5000.150<0.150µg/L1,1-Dichloroethene
07/11/22 13:060.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/11/22 13:060.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/11/22 13:060.5000.190<0.190µg/L1,2-Dichloropropane
07/11/22 13:060.5000.130<0.130µg/L1,3-Dichloropropane
07/11/22 13:062.000.210<0.210µg/L2,2-Dichloropropane
07/11/22 13:060.5000.200<0.200µg/L1,1-Dichloropropene
07/11/22 13:060.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/11/22 13:060.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/11/22 13:0620042.0<42.0µg/LEthanol
07/11/22 13:060.5000.170<0.170µg/LEthylbenzene
07/11/22 13:063.000.350<0.350µg/LHexachlorobutadiene
07/11/22 13:061.000.380<0.380µg/L2-Hexanone
07/11/22 13:060.5000.180<0.180µg/LIsopropylbenzene
07/11/22 13:060.5000.089<0.089µg/L4-Isopropyl toluene
07/11/22 13:065.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/11/22 13:061.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/11/22 13:061.000.078<0.078µg/L4-Methyl-2-Pentanone
07/11/22 13:062.000.330<0.330µg/LMethylene Chloride
07/11/22 13:061.000.470<0.470µg/LNaphthalene
07/11/22 13:060.5000.190<0.190µg/Ln-Propylbenzene
07/11/22 13:060.5000.220<0.220µg/LStyrene
07/11/22 13:0610.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/11/22 13:0610.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/11/22 13:0610.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/11/22 13:0610.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 22Date:07/13/2022 03:10 PM
Page 81 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
Associated Lab Samples: 93419, 93420, 93421, 93422, 93423, 93424, 93425, 93426, 93427
LRB-V21154 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/11/22 13:060.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/11/22 13:060.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/11/22 13:060.5000.220<0.220µg/LTetrachloroethene
07/11/22 13:060.5000.220<0.220µg/LToluene
07/11/22 13:060.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/11/22 13:060.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/11/22 13:060.5000.160<0.160µg/L1,1,1-Trichloroethane
07/11/22 13:060.5000.096<0.096µg/L1,1,2-Trichloroethane
07/11/22 13:060.5000.180<0.180µg/LTrichloroethene
07/11/22 13:060.5000.180<0.180µg/LTrichlorofluoromethane
07/11/22 13:060.5000.270<0.270µg/L1,2,3-Trichloropropane
07/11/22 13:060.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/11/22 13:060.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/11/22 13:065.001.00<1.00µg/LVinyl Acetate
07/11/22 13:060.5000.170<0.170µg/LVinyl Chloride
07/11/22 13:060.5000.210<0.210µg/Lo-Xylene
07/11/22 13:061.000.420<0.420µg/Lm,p-Xylene
07/11/22 13:0610.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/11/22 13:064-Bromofluorobenzene (S)96.6 70-130
07/11/22 13:06Dibromofluoromethane (S)102 70-130
07/11/22 13:061,2-Dichloroethane - d4 (S)90.0 70-130
07/11/22 13:06Toluene-d8 (S)85.8 70-130
Page 3 of 22Date:07/13/2022 03:10 PM
Page 82 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
LCS-V21154 LCSD-V21154Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.4 81.078.231.340.0µg/LAcetone 40-160 3.4 20.0
22.7 11411923.820.0µg/LBenzene 70-130 4.7 20.0
17.5 87.592.018.420.0µg/LBromobenzene 70-130 5.0 20.0
23.4 11712324.520.0µg/LBromochloromethane 70-130 4.5 20.0
23.9 12012424.820.0µg/LBromodichloromethane 70-130 3.6 20.0
23.9 12012224.320.0µg/LBromoform 70-130 1.6 20.0
22.7 11412023.920.0µg/LBromomethane 60-140 5.1 20.0
17.4 87.093.018.620.0µg/Ln-Butylbenzene 70-130 6.6 20.0
17.4 87.094.018.820.0µg/Lsec-Butyl benzene 70-130 7.7 20.0
17.6 88.093.518.720.0µg/Ltert-Butyl benzene 70-130 6.0 20.0
25.2 12612925.820.0µg/LCarbon Tetrachloride 70-130 2.3 20.0
19.1 95.510320.520.0µg/LChlorobenzene 70-130 7.0 20.0
21.5 10810821.620.0µg/LChlorodibromomethane 70-130 0.4 20.0
20.2 10110320.520.0µg/LChloroethane 60-140 1.4 20.0
22.9 11512324.520.0µg/LChloroform 70-130 6.7 20.0
18.9 94.596.519.320.0µg/LChloromethane 60-140 2.0 20.0
18.1 90.594.018.820.0µg/L2-Chlorotoluene 70-130 3.7 20.0
17.6 88.094.018.820.0µg/L4-Chlorotoluene 70-130 6.5 20.0
17.7 88.590.518.120.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.2 20.0
20.5 10310821.620.0µg/L1,2-Dibromo-3-Chloropropane 70-130 5.2 20.0
20.4 10210520.920.0µg/L1,2-Dibromoethane 70-130 2.4 20.0
24.3 12211522.920.0µg/LDibromomethane 70-130 5.9 20.0
18.4 92.094.518.920.0µg/L1,2-Dichlorobenzene 70-130 2.6 20.0
18.2 91.097.519.520.0µg/L1,3-Dichlorobenzene 70-130 6.8 20.0
18.2 91.095.019.020.0µg/L1,4-Dichlorobenzene 70-130 4.3 20.0
25.1 12612825.620.0µg/LDichlorodifluoromethane 60-140 1.9 20.0
Page 4 of 22Date:07/13/2022 03:10 PM
Page 83 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
LCS-V21154 LCSD-V21154Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.4 10711322.620.0µg/L1,1-Dichloroethane 70-130 5.4 20.0
22.3 11211523.020.0µg/L1,2-Dichloroethane 70-130 3.0 20.0
21.5 10811523.020.0µg/L1,1-Dichloroethene 70-130 6.7 20.0
20.7 10411222.420.0µg/Lcis-1,2-Dichloroethene 70-130 7.8 20.0
20.7 10411322.620.0µg/Ltrans-1,2-Dichloroethene 70-130 8.7 20.0
21.1 10611222.420.0µg/L1,2-Dichloropropane 70-130 5.9 20.0
19.0 95.097.019.420.0µg/L1,3-Dichloropropane 70-130 2.0 20.0
23.5 11812424.720.0µg/L2,2-Dichloropropane 70-130 4.9 20.0
22.4 11211923.720.0µg/L1,1-Dichloropropene 70-130 5.6 20.0
24.1 12112524.920.0µg/Lcis-1,3-Dichloropropene 70-130 3.2 20.0
24.1 12112524.920.0µg/Ltrans-1,3-Dichloropropene 70-130 3.2 20.0
395 79.083.4417500µg/LEthanol 60-140 5.4 20.0
19.3 96.510120.220.0µg/LEthylbenzene 70-130 4.5 20.0
18.8 94.098.519.720.0µg/LHexachlorobutadiene 70-130 4.6 20.0
15.1 75.570.514.120.0µg/L2-Hexanone 60-140 6.8 20.0
18.0 90.095.019.020.0µg/LIsopropylbenzene 70-130 5.4 20.0
17.9 89.595.519.120.0µg/L4-Isopropyl toluene 70-130 6.4 20.0
21.4 10710721.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 0.0 20.0
24.1 12112124.120.0µg/LMethyl tert-butyl ether (MTBE)70-130 0.0 20.0
17.0 85.093.018.620.0µg/L4-Methyl-2-Pentanone 60-140 8.9 20.0
16.6 83.088.017.620.0µg/LMethylene Chloride 70-130 5.8 20.0
19.9 99.595.019.020.0µg/LNaphthalene 70-130 4.6 20.0
17.6 88.093.518.720.0µg/Ln-Propylbenzene 70-130 6.0 20.0
19.4 97.010120.220.0µg/LStyrene 70-130 4.0 20.0
47.8 12012048.040.0µg/Ltert-Butyl Alcohol (TBA)40-140 0.4 20.0
48.3 12111746.840.0µg/Ltert-Butyl formate (TBF)40-140 3.1 20.0
Page 5 of 22Date:07/13/2022 03:10 PM
Page 84 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21155QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21154
LCS-V21154 LCSD-V21154Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.5 10810220.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 5.2 20.0
48.3 12112148.440.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.2 20.0
20.5 10310520.920.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.9 20.0
17.0 85.087.017.420.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.3 20.0
19.4 97.010521.020.0µg/LTetrachloroethene 70-130 7.9 20.0
23.0 11512124.220.0µg/LToluene 70-130 5.0 20.0
22.2 11110621.220.0µg/L1,2,3-Trichlorobenzene 70-130 4.6 20.0
19.0 95.010020.020.0µg/L1,2,4-Trichlorobenzene 70-130 5.1 20.0
23.7 11912825.620.0µg/L1,1,1-Trichloroethane 70-130 7.7 20.0
24.0 12012023.920.0µg/L1,1,2-Trichloroethane 70-130 0.4 20.0
23.6 11812324.620.0µg/LTrichloroethene 70-130 4.1 20.0
25.7 12912925.820.0µg/LTrichlorofluoromethane 60-140 0.3 20.0
17.4 87.093.518.720.0µg/L1,2,3-Trichloropropane 70-130 7.2 20.0
18.1 90.594.518.920.0µg/L1,2,4-Trimethylbenzene 70-130 4.3 20.0
18.4 92.097.519.520.0µg/L1,3,5-Trimethylbenzene 70-130 5.8 20.0
25.1 12612324.620.0µg/LVinyl Acetate 60-140 2.0 20.0
22.8 11412424.820.0µg/LVinyl Chloride 60-140 8.4 20.0
19.2 96.010220.320.0µg/Lo-Xylene 70-130 5.5 20.0
41.3 10310943.540.0µg/Lm,p-Xylene 70-130 5.1 20.0
24.4 12210821.620.0µg/L3,3-Dimethyl-1-butanol 70-130 12.1 20.0
97.098.44-Bromofluorobenzene (S)70-130
102101Dibromofluoromethane (S)70-130
89.493.01,2-Dichloroethane - d4 (S)70-130
89.890.2Toluene-d8 (S)70-130
Page 6 of 22Date:07/13/2022 03:10 PM
Page 85 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
Associated Lab Samples: 93426, 93427, 93429
LRB-V21201 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 14:2110.01.80<1.80µg/LAcetone
07/12/22 14:210.5000.180<0.180µg/LBenzene
07/12/22 14:210.5000.210<0.210µg/LBromobenzene
07/12/22 14:211.000.420<0.420µg/LBromochloromethane
07/12/22 14:210.5000.160<0.160µg/LBromodichloromethane
07/12/22 14:215.001.50<1.50µg/LBromoform
07/12/22 14:211.000.280<0.280µg/LBromomethane
07/12/22 14:210.5000.180<0.180µg/Ln-Butylbenzene
07/12/22 14:210.5000.200<0.200µg/Lsec-Butyl benzene
07/12/22 14:212.000.920<0.920µg/Ltert-Butyl benzene
07/12/22 14:210.5000.180<0.180µg/LCarbon Tetrachloride
07/12/22 14:210.5000.190<0.190µg/LChlorobenzene
07/12/22 14:210.5000.190<0.190µg/LChlorodibromomethane
07/12/22 14:211.000.430<0.430µg/LChloroethane
07/12/22 14:210.5000.220<0.220µg/LChloroform
07/12/22 14:210.5000.220<0.220µg/LChloromethane
07/12/22 14:210.5000.200<0.200µg/L2-Chlorotoluene
07/12/22 14:210.5000.200<0.200µg/L4-Chlorotoluene
07/12/22 14:210.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/12/22 14:212.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/12/22 14:210.5000.200<0.200µg/L1,2-Dibromoethane
07/12/22 14:210.5000.230<0.230µg/LDibromomethane
07/12/22 14:210.5000.220<0.220µg/L1,2-Dichlorobenzene
07/12/22 14:210.5000.190<0.190µg/L1,3-Dichlorobenzene
07/12/22 14:210.5000.210<0.210µg/L1,4-Dichlorobenzene
07/12/22 14:215.001.20<1.20µg/LDichlorodifluoromethane
07/12/22 14:210.5000.240<0.240µg/L1,1-Dichloroethane
Page 7 of 22Date:07/13/2022 03:10 PM
Page 86 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
Associated Lab Samples: 93426, 93427, 93429
LRB-V21201 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 14:210.5000.150<0.150µg/L1,2-Dichloroethane
07/12/22 14:210.5000.150<0.150µg/L1,1-Dichloroethene
07/12/22 14:210.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/12/22 14:210.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/12/22 14:210.5000.190<0.190µg/L1,2-Dichloropropane
07/12/22 14:210.5000.130<0.130µg/L1,3-Dichloropropane
07/12/22 14:212.000.210<0.210µg/L2,2-Dichloropropane
07/12/22 14:210.5000.200<0.200µg/L1,1-Dichloropropene
07/12/22 14:210.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/12/22 14:210.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/12/22 14:2120042.0<42.0µg/LEthanol
07/12/22 14:210.5000.170<0.170µg/LEthylbenzene
07/12/22 14:213.000.350<0.350µg/LHexachlorobutadiene
07/12/22 14:211.000.380<0.380µg/L2-Hexanone
07/12/22 14:210.5000.180<0.180µg/LIsopropylbenzene
07/12/22 14:210.5000.089<0.089µg/L4-Isopropyl toluene
07/12/22 14:215.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/12/22 14:211.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/12/22 14:211.000.078<0.078µg/L4-Methyl-2-Pentanone
07/12/22 14:212.000.330<0.330µg/LMethylene Chloride
07/12/22 14:211.000.470<0.470µg/LNaphthalene
07/12/22 14:210.5000.190<0.190µg/Ln-Propylbenzene
07/12/22 14:210.5000.220<0.220µg/LStyrene
07/12/22 14:2110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/12/22 14:2110.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/12/22 14:2110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/12/22 14:2110.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 8 of 22Date:07/13/2022 03:10 PM
Page 87 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
Associated Lab Samples: 93426, 93427, 93429
LRB-V21201 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 14:210.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
07/12/22 14:210.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/12/22 14:210.5000.220<0.220µg/LTetrachloroethene
07/12/22 14:210.5000.220<0.220µg/LToluene
07/12/22 14:210.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/12/22 14:210.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/12/22 14:210.5000.160<0.160µg/L1,1,1-Trichloroethane
07/12/22 14:210.5000.096<0.096µg/L1,1,2-Trichloroethane
07/12/22 14:210.5000.180<0.180µg/LTrichloroethene
07/12/22 14:210.5000.180<0.180µg/LTrichlorofluoromethane
07/12/22 14:210.5000.270<0.270µg/L1,2,3-Trichloropropane
07/12/22 14:210.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/12/22 14:210.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/12/22 14:215.001.00<1.00µg/LVinyl Acetate
07/12/22 14:210.5000.170<0.170µg/LVinyl Chloride
07/12/22 14:210.5000.210<0.210µg/Lo-Xylene
07/12/22 14:211.000.420<0.420µg/Lm,p-Xylene
07/12/22 14:2110.01.00<1.00µg/L3,3-Dimethyl-1-butanol
07/12/22 14:214-Bromofluorobenzene (S)99.8 70-130
07/12/22 14:21Dibromofluoromethane (S)101 70-130
07/12/22 14:211,2-Dichloroethane - d4 (S)85.4 70-130
07/12/22 14:21Toluene-d8 (S)84.0 70-130
Page 9 of 22Date:07/13/2022 03:10 PM
Page 88 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
LCS-V21201 LCSD-V21201Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
31.8 79.580.532.240.0µg/LAcetone 40-160 1.2 20.0
23.4 11712525.020.0µg/LBenzene 70-130 6.6 20.0
17.7 88.594.518.920.0µg/LBromobenzene 70-130 6.5 20.0
25.0 12512725.320.0µg/LBromochloromethane 70-130 1.1 20.0
25.0 12512925.720.0µg/LBromodichloromethane 70-130 2.7 20.0
22.8 11411522.920.0µg/LBromoform 70-130 0.4 20.0
23.1 11611222.320.0µg/LBromomethane 60-140 3.5 20.0
17.9 89.595.519.120.0µg/Ln-Butylbenzene 70-130 6.4 20.0
18.3 91.595.019.020.0µg/Lsec-Butyl benzene 70-130 3.7 20.0
18.3 91.596.019.220.0µg/Ltert-Butyl benzene 70-130 4.8 20.0
25.6 12812925.720.0µg/LCarbon Tetrachloride 70-130 0.3 20.0
20.8 10410220.420.0µg/LChlorobenzene 70-130 1.9 20.0
22.3 11210821.620.0µg/LChlorodibromomethane 70-130 3.1 20.0
21.5 10811222.320.0µg/LChloroethane 60-140 3.6 20.0
24.1 12112825.620.0µg/LChloroform 70-130 6.0 20.0
18.2 91.094.518.920.0µg/LChloromethane 60-140 3.7 20.0
18.4 92.095.519.120.0µg/L2-Chlorotoluene 70-130 3.7 20.0
18.0 90.095.519.120.0µg/L4-Chlorotoluene 70-130 5.9 20.0
17.9 89.593.518.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 4.3 20.0
21.4 10710921.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130 1.8 20.0
20.7 10410220.420.0µg/L1,2-Dibromoethane 70-130 1.4 20.0
23.3 11712124.220.0µg/LDibromomethane 70-130 3.7 20.0
18.6 93.096.519.320.0µg/L1,2-Dichlorobenzene 70-130 3.6 20.0
18.6 93.096.519.320.0µg/L1,3-Dichlorobenzene 70-130 3.6 20.0
18.7 93.597.019.420.0µg/L1,4-Dichlorobenzene 70-130 3.6 20.0
26.4 13213927.720.0µg/LDichlorodifluoromethane 60-140 4.8 20.0
Page 10 of 22Date:07/13/2022 03:10 PM
Page 89 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
LCS-V21201 LCSD-V21201Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.3 11212124.120.0µg/L1,1-Dichloroethane 70-130 7.7 20.0
22.7 11412124.220.0µg/L1,2-Dichloroethane 70-130 6.3 20.0
22.0 11011522.920.0µg/L1,1-Dichloroethene 70-130 4.0 20.0
21.5 10811523.020.0µg/Lcis-1,2-Dichloroethene 70-130 6.7 20.0
21.5 10811422.820.0µg/Ltrans-1,2-Dichloroethene 70-130 5.8 20.0
22.6 11311923.720.0µg/L1,2-Dichloropropane 70-130 4.7 20.0
20.4 10299.519.920.0µg/L1,3-Dichloropropane 70-130 2.4 20.0
25.1 12612925.820.0µg/L2,2-Dichloropropane 70-130 2.7 20.0
23.9 12012524.920.0µg/L1,1-Dichloropropene 70-130 4.0 20.0
24.4 12212925.720.0µg/Lcis-1,3-Dichloropropene 70-130 5.1 20.0
24.4 12212925.720.0µg/Ltrans-1,3-Dichloropropene 70-130 5.1 20.0
404 80.878.6393500µg/LEthanol 60-140 2.7 20.0
20.5 10310320.520.0µg/LEthylbenzene 70-130 0.0 20.0
20.1 10110420.820.0µg/LHexachlorobutadiene 70-130 3.4 20.0
14.1 70.571.514.320.0µg/L2-Hexanone 60-140 1.4 20.0
18.5 92.597.519.520.0µg/LIsopropylbenzene 70-130 5.2 20.0
18.8 94.097.519.520.0µg/L4-Isopropyl toluene 70-130 3.6 20.0
25.0 12511523.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 8.3 20.0
23.5 11812525.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 6.1 20.0
17.2 86.091.518.320.0µg/L4-Methyl-2-Pentanone 60-140 6.1 20.0
16.6 83.088.517.720.0µg/LMethylene Chloride 70-130 6.4 20.0
19.1 95.599.019.820.0µg/LNaphthalene 70-130 3.5 20.0
18.3 91.595.019.020.0µg/Ln-Propylbenzene 70-130 3.7 20.0
20.8 10410320.620.0µg/LStyrene 70-130 0.9 20.0
39.6 99.097.739.140.0µg/Ltert-Butyl Alcohol (TBA)40-140 1.2 20.0
45.6 11412047.840.0µg/Ltert-Butyl formate (TBF)40-140 4.7 20.0
Page 11 of 22Date:07/13/2022 03:10 PM
Page 90 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21202QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21201
LCS-V21201 LCSD-V21201Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.6 12311022.020.0µg/Ltert-Amyl Alcohol (TAA)40-140 11.1 20.0
48.7 12212047.840.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.8 20.0
22.4 11211022.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 1.8 20.0
17.4 87.089.517.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.8 20.0
20.9 10510420.820.0µg/LTetrachloroethene 70-130 0.4 20.0
23.8 11912725.320.0µg/LToluene 70-130 6.1 20.0
20.6 10310320.620.0µg/L1,2,3-Trichlorobenzene 70-130 0.0 20.0
19.6 98.010420.720.0µg/L1,2,4-Trichlorobenzene 70-130 5.4 20.0
24.7 12413025.920.0µg/L1,1,1-Trichloroethane 70-130 4.7 20.0
24.0 12012725.420.0µg/L1,1,2-Trichloroethane 70-130 5.6 20.0
24.0 12012825.620.0µg/LTrichloroethene 70-130 6.4 20.0
25.8 12913827.520.0µg/LTrichlorofluoromethane 60-140 6.3 20.0
17.5 87.591.518.320.0µg/L1,2,3-Trichloropropane 70-130 4.4 20.0
18.6 93.097.019.420.0µg/L1,2,4-Trimethylbenzene 70-130 4.2 20.0
18.7 93.595.019.020.0µg/L1,3,5-Trimethylbenzene 70-130 1.5 20.0
22.9 11512725.420.0µg/LVinyl Acetate 60-140 10.3 20.0
23.3 11712424.820.0µg/LVinyl Chloride 60-140 6.2 20.0
20.7 10410320.520.0µg/Lo-Xylene 70-130 0.9 20.0
44.1 11010943.740.0µg/Lm,p-Xylene 70-130 0.9 20.0
19.6 98.010721.420.0µg/L3,3-Dimethyl-1-butanol 70-130 8.7 20.0
97.41014-Bromofluorobenzene (S)70-130
98.6102Dibromofluoromethane (S)70-130
87.291.61,2-Dichloroethane - d4 (S)70-130
90.488.4Toluene-d8 (S)70-130
Page 12 of 22Date:07/13/2022 03:10 PM
Page 91 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
Associated Lab Samples: 93415, 93416
LRB-V20989 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0200.002<0.002mg/KgAcetone
07/07/22 00:170.0200.001<0.001mg/KgAcrolein
07/07/22 00:170.0200.0008<0.0008mg/KgAcrylonitrile
07/07/22 00:170.0050.0006<0.0006mg/KgBenzene
07/07/22 00:170.0050.0005<0.0005mg/KgBromobenzene
07/07/22 00:170.0050.0008<0.0008mg/KgBromochloromethane
07/07/22 00:170.0050.001<0.001mg/KgBromodichloromethane
07/07/22 00:170.0050.001<0.001mg/KgBromoform
07/07/22 00:170.0100.001<0.001mg/KgBromomethane
07/07/22 00:170.0050.0005<0.0005mg/Kgn-Butylbenzene
07/07/22 00:170.0050.0006<0.0006mg/Kgsec-Butyl benzene
07/07/22 00:170.0050.0005<0.0005mg/Kgtert-Butyl benzene
07/07/22 00:170.0050.0006<0.0006mg/KgCarbon Disulfide
07/07/22 00:170.0050.001<0.001mg/KgCarbon Tetrachloride
07/07/22 00:170.0050.0007<0.0007mg/KgChlorobenzene
07/07/22 00:170.0050.0009<0.0009mg/KgChlorodibromomethane
07/07/22 00:170.0100.0009<0.0009mg/KgChloroethane
07/07/22 00:170.0050.001<0.001mg/KgChloroform
07/07/22 00:170.0100.0006<0.0006mg/KgChloromethane
07/07/22 00:170.0050.0005<0.0005mg/Kg2-Chlorotoluene
07/07/22 00:170.0050.0004<0.0004mg/Kg4-Chlorotoluene
07/07/22 00:170.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
07/07/22 00:170.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
07/07/22 00:170.0050.0006<0.0006mg/Kg1,2-Dibromoethane
07/07/22 00:170.0050.0010<0.0010mg/KgDibromomethane
07/07/22 00:170.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
07/07/22 00:170.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 13 of 22Date:07/13/2022 03:10 PM
Page 92 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
Associated Lab Samples: 93415, 93416
LRB-V20989 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
07/07/22 00:170.0100.001<0.001mg/KgDichlorodifluoromethane
07/07/22 00:170.0050.0008<0.0008mg/Kg1,1-Dichloroethane
07/07/22 00:170.0050.001<0.001mg/Kg1,2-Dichloroethane
07/07/22 00:170.0050.0007<0.0007mg/Kg1,1-Dichloroethene
07/07/22 00:170.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
07/07/22 00:170.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
07/07/22 00:170.0050.0004<0.0004mg/Kg1,2-Dichloropropane
07/07/22 00:170.0050.0006<0.0006mg/Kg1,3-Dichloropropane
07/07/22 00:170.0050.001<0.001mg/Kg2,2-Dichloropropane
07/07/22 00:170.0050.0008<0.0008mg/Kg1,1-Dichloropropene
07/07/22 00:170.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
07/07/22 00:170.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
07/07/22 00:170.0050.0006<0.0006mg/KgEthylbenzene
07/07/22 00:170.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
07/07/22 00:170.0100.0008<0.0008mg/KgHexachlorobutadiene
07/07/22 00:170.0100.0007<0.0007mg/Kgn-Hexane
07/07/22 00:170.0200.0006<0.0006mg/Kg2-Hexanone
07/07/22 00:170.0050.0005<0.0005mg/KgIsopropylbenzene
07/07/22 00:170.0050.001<0.001mg/Kg4-Isopropyl toluene
07/07/22 00:170.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
07/07/22 00:170.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
07/07/22 00:170.0050.0010.002mg/KgMethylene Chloride
07/07/22 00:170.0100.0010<0.0010mg/KgNaphthalene
07/07/22 00:170.0050.0005<0.0005mg/Kgn-Propylbenzene
07/07/22 00:170.0050.001<0.001mg/KgStyrene
07/07/22 00:170.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
Page 14 of 22Date:07/13/2022 03:10 PM
Page 93 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
Associated Lab Samples: 93415, 93416
LRB-V20989 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/07/22 00:170.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
07/07/22 00:170.0050.0009<0.0009mg/KgTetrachloroethene
07/07/22 00:170.0050.0007<0.0007mg/KgToluene
07/07/22 00:170.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
07/07/22 00:170.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
07/07/22 00:170.0050.001<0.001mg/Kg1,1,1-Trichloroethane
07/07/22 00:170.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
07/07/22 00:170.0050.0009<0.0009mg/KgTrichloroethene
07/07/22 00:170.0100.002<0.002mg/KgTrichlorofluoromethane
07/07/22 00:170.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
07/07/22 00:170.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
07/07/22 00:170.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
07/07/22 00:170.0100.0005<0.0005mg/KgVinyl Acetate
07/07/22 00:170.0100.0005<0.0005mg/KgVinyl Chloride
07/07/22 00:170.0050.0005<0.0005mg/Kgo-Xylene
07/07/22 00:170.0100.001<0.001mg/Kgm,p-Xylene
07/07/22 00:174-Bromofluorobenzene (S)102 70-130
07/07/22 00:17Dibromofluoromethane (S)106 70-130
07/07/22 00:17Toluene-d8 (S)98.8 76-129
LCS-V20989 LCSD-V20989Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.108 1081030.1030.100mg/KgAcetone 29-198 4.7 20
0.098 98.098.30.0980.100mg/KgAcrolein 70-130 0.3 20
0.127 1271230.1230.100mg/KgAcrylonitrile 65-134 3.2 20
Page 15 of 22Date:07/13/2022 03:10 PM
Page 94 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
LCS-V20989 LCSD-V20989Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.057 1151150.0570.050mg/KgBenzene 74-127 0.3 20
0.053 1061050.0520.050mg/KgBromobenzene 73-125 1.3 20
0.060 1221200.0590.050mg/KgBromochloromethane 72-134 1.6 20
0.059 1181170.0580.050mg/KgBromodichloromethane 75-122 1.5 20
0.053 1071010.0500.050mg/KgBromoform 66-135 5.3 20
0.056 1141200.0590.050mg/KgBromomethane 20-180 4.9 20
0.050 1001000.0500.050mg/Kgn-Butylbenzene 65-135 0.0 20
0.050 1011010.0500.050mg/Kgsec-Butyl benzene 66-131 0.1 20
0.050 1001030.0510.050mg/Kgtert-Butyl benzene 67-132 3.1 20
0.056 1121110.0550.050mg/KgCarbon Disulfide 61-129 0.8 20
0.056 1131150.0570.050mg/KgCarbon Tetrachloride 64-143 1.7 20
0.053 1081060.0530.050mg/KgChlorobenzene 74-118 1.6 20
0.052 1051050.0520.050mg/KgChlorodibromomethane 73-122 0.3 20
0.060 1201200.0600.050mg/KgChloroethane 33-149 0.1 20
0.058 1171170.0580.050mg/KgChloroform 73-127 0.1 20
0.063 1261300.0640.050mg/KgChloromethane 45-143 2.6 20
0.052 1041050.0520.050mg/Kg2-Chlorotoluene 67-124 0.7 20
0.052 1041050.0520.050mg/Kg4-Chlorotoluene 71-126 0.5 20
0.070 1401380.0690.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.4 20
0.049 98.493.20.0460.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 5.4 20
0.052 1061040.0510.050mg/Kg1,2-Dibromoethane 70-132 1.9 20
0.059 1191170.0580.050mg/KgDibromomethane 74-133 1.6 20
0.052 1061040.0510.050mg/Kg1,2-Dichlorobenzene 72-123 1.7 20
0.051 1041030.0510.050mg/Kg1,3-Dichlorobenzene 71-120 0.9 20
0.051 1031000.0500.050mg/Kg1,4-Dichlorobenzene 71-123 2.3 20
0.057 1151180.0590.050mg/KgDichlorodifluoromethane 26-146 2.5 20
Page 16 of 22Date:07/13/2022 03:10 PM
Page 95 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
LCS-V20989 LCSD-V20989Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.061 1231240.0610.050mg/Kg1,1-Dichloroethane 74-127 0.3 20
0.064 129*1270.0630.050mg/Kg1,2-Dichloroethane 68-128 1.7 20
0.059 1191220.0600.050mg/Kg1,1-Dichloroethene 67-149 2.1 20
0.064 1291260.0630.050mg/Kgcis-1,2-Dichloroethene 76-134 1.7 20
0.061 1231250.0620.050mg/Kgtrans-1,2-Dichloroethene 73-132 1.7 20
0.061 1231220.0600.050mg/Kg1,2-Dichloropropane 73-130 1.3 20
0.055 1111090.0540.050mg/Kg1,3-Dichloropropane 75-124 1.2 20
0.058 1171160.0570.050mg/Kg2,2-Dichloropropane 50-142 1.0 20
0.057 1151150.0570.050mg/Kg1,1-Dichloropropene 71-130 0.1 20
0.060 1201180.0580.050mg/Kgcis-1,3-Dichloropropene 71-125 2.0 20
0.060 1211190.0590.050mg/Kgtrans-1,3-Dichloropropene 68-123 2.0 20
0.052 1041030.0510.050mg/KgEthylbenzene 74-128 0.9 20
0.126 1261250.1250.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.7 20
0.049 98.097.20.0480.050mg/KgHexachlorobutadiene 64-125 0.8 20
0.055 1111060.0520.050mg/Kgn-Hexane 70-130 4.8 20
0.059 1181120.0560.050mg/Kg2-Hexanone 61-157 5.0 20
0.047 95.695.20.0470.050mg/KgIsopropylbenzene 68-126 0.4 20
0.050 1011020.0500.050mg/Kg4-Isopropyl toluene 68-129 0.9 20
0.059 1181160.0570.050mg/KgMethyl Ethyl Ketone (MEK)63-149 2.2 20
0.057 1161120.0560.050mg/KgMethyl tert-butyl ether (MTBE)70-130 2.9 20
0.056 1121130.0560.050mg/KgMethylene Chloride 74-129 0.7 20
0.047 95.292.00.0460.050mg/KgNaphthalene 57-157 3.4 20
0.051 1031030.0510.050mg/Kgn-Propylbenzene 67-130 0.1 20
0.053 1071070.0530.050mg/KgStyrene 77-121 0.1 20
0.055 1101100.0550.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.1 20
0.049 99.097.20.0480.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.8 20
Page 17 of 22* QC Fail Date:07/13/2022 03:10 PM
Page 96 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V20990QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V20989
LCS-V20989 LCSD-V20989Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.056 1131110.0550.050mg/KgTetrachloroethene 68-130 2.1 20
0.057 1151130.0560.050mg/KgToluene 71-129 2.1 20
0.050 10197.20.0480.050mg/Kg1,2,3-Trichlorobenzene 68-130 3.6 20
0.049 99.295.20.0470.050mg/Kg1,2,4-Trichlorobenzene 66-125 4.1 20
0.056 1141150.0570.050mg/Kg1,1,1-Trichloroethane 67-131 1.5 20
0.051 1021010.0500.050mg/Kg1,1,2-Trichloroethane 70-133 0.9 20
0.058 1161170.0580.050mg/KgTrichloroethene 75-133 0.8 20
0.059 1181220.0610.050mg/KgTrichlorofluoromethane 44-146 3.4 20
0.051 1041010.0500.050mg/Kg1,2,3-Trichloropropane 60-137 2.5 20
0.050 1001000.0500.050mg/Kg1,2,4-Trimethylbenzene 69-129 0.3 20
0.050 1011010.0500.050mg/Kg1,3,5-Trimethylbenzene 69-128 0.0 20
0.051 10298.40.0490.050mg/KgVinyl Acetate 60-140 3.9 20
0.060 1221250.0620.050mg/KgVinyl Chloride 48-147 2.9 20
0.051 1031040.0510.050mg/Kgo-Xylene 74-126 0.1 20
0.103 1031030.1030.100mg/Kgm,p-Xylene 75-124 0.0 20
97.697.64-Bromofluorobenzene (S)70-130
107105Dibromofluoromethane (S)70-130
97.496.8Toluene-d8 (S)76-129
Page 18 of 22Date:07/13/2022 03:10 PM
Page 97 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V20869QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V20868
Associated Lab Samples: 93423, 93424, 93425, 93426, 93429
LRB-V20868 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/05/22 14:3150.011.5<11.5µg/LAliphatic C5-C8
07/05/22 14:3150.025.8<25.8µg/LAliphatic C9-C12
07/05/22 14:3150.04.02<4.02µg/LAromatic C9-C10
07/05/22 14:312,5-Dibromotoluene (FID) (S)82.9 70-130
07/05/22 14:312,5-Dibromotoluene (PID) (S)83.3 70-130
LCS-V20868 LCSD-V20868Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
289 96.395.6287300µg/LAliphatic C5-C8 70-130 0.6 50.0
341 114111334300µg/LAliphatic C9-C12 70-130 2.0 50.0
113 113112112100µg/LAromatic C9-C10 70-130 0.8 50.0
82.882.12,5-Dibromotoluene (FID) (S)70-130
80.480.62,5-Dibromotoluene (PID) (S)70-130
Page 19 of 22Date:07/13/2022 03:10 PM
Page 98 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V20939QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V20938
Associated Lab Samples: 93415, 93416
LRB-V20938 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/06/22 16:018.001.22<1.22mg/KgAliphatic C5-C8
07/06/22 16:018.004.56<4.56mg/KgAliphatic C9-C12
07/06/22 16:018.000.624<0.624mg/KgAromatic C9-C10
07/06/22 16:012,5-Dibromotoluene (FID) (S)78.5 70-130
07/06/22 16:012,5-Dibromotoluene (PID) (S)79.7 70-130
LCS-V20938 LCSD-V20938Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
28.7 89.687.127.932.0mg/KgAliphatic C5-C8 70-130 2.8 50
36.3 11311135.532.0mg/KgAliphatic C9-C12 70-130 2.2 50
12.2 11411312.110.7mg/KgAromatic C9-C10 70-130 0.8 50
79.476.62,5-Dibromotoluene (FID) (S)70-130
78.375.72,5-Dibromotoluene (PID) (S)70-130
Page 20 of 22Date:07/13/2022 03:10 PM
Page 99 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
Dry Weight Determination
SW-DRYWT
V20924QC Analytical Batch:
Analysis Method:
Analysis Description:
V 93369-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/06/22 12:172.721.921.3%Moisture
V 93500-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/06/22 12:171.39.279.15%Moisture
Page 21 of 22Date:07/13/2022 03:10 PM
Page 100 of 104
Quality Control Data
22-182-0020Report No:
Project Description:
Client ID:Geological Resources, Inc.
RL Village Store
Total Organic Carbon - Walkley Black
WALK-BLACK
L625688QC Analytical Batch:
Analysis Method:
Analysis Description:
Associated Lab Samples: 93417, 93418, 93428
LRB Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
07/08/22 10:280.050.05<0.05%Total Organic Carbon
V 93417-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/08/22 10:2835.2*0.070.10%Total Organic Carbon
Page 22 of 22* QC Fail Date:07/13/2022 03:10 PM
Page 101 of 104
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-182-0020
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 3.0 C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Adam Crouch Date & Time:07/01/2022 13:08:22
Special precautions or instructions included?
Comments:
Page 102 of 104
Page 103 of 104
Page 104 of 104

APPENDIX F
Slug Test Data
0. 1. 2. 3. 4. 5.
0.001
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-7 JA.aqt
Date: 07/13/22 Time: 16:05:51
PROJECT INFORMATION
Company: GRI
Client: RL Village Store
Project: 5586
Location: Wallace, NC
Test Well: MW-7
Test Date: 06/30/22
AQUIFER DATA
Saturated Thickness: 36.81 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-7)
Initial Displacement: 1.75 ft Static Water Column Height: 5.62 ft
Total Well Penetration Depth: 5.62 ft Screen Length: 5.62 ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.002525 ft/min y0 = 0.7661 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 12.38 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 14.13 Test well
Total well depth (TWD)TWD 18.00 Test well
Top of Casing Elevation (TOC)TOC 100.01 Test well
Highest historical ground water elevation at site (HGWE)HGWE 92.09 All site wells
Deepest well depth elevation (DWDE)DWDE 55.28 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o)1.75 Use 1.75
H: Static water column height H 5.62 TWD minus SDTW
Well #MW-7 Test well ID
7 b: Saturated thickness of aquifer b 36.81
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.62 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w)0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o)1.75 Use H(o)
RL Village Store
Wallace, NC
MW-7
6/30/2022
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
File: MW-7 AQTESOLV Data Entry Form
RL Village Store
Well MW-7
Test Date 06/30/22
Initial DTW (ft) 12.38

Time Displacement
(min) (ft)
0.000 0.0000
0.017 0.0098
0.033 0.3248
0.050 0.2067
0.067 0.0886
0.083 0.5315
0.100 1.1417
0.117 1.0925
0.133 1.0433
0.150 1.0138
0.167 0.9744
0.183 0.9350
0.200 0.9153
0.217 0.8858
0.233 0.8661
0.250 0.8464
0.267 0.8268
0.283 0.8071
0.300 0.7972
0.317 0.7775
0.333 0.7677
0.350 0.7579
0.367 0.7382
0.383 0.7283
0.400 0.7087
0.417 0.6988
0.433 0.6890
0.450 0.6791
0.467 0.6693
0.483 0.6594
0.500 0.6496
0.517 0.6398
0.533 0.6299
0.550 0.6201
0.567 0.6102
Time Displacement
(min) (ft)
0.583 0.6004
0.600 0.6004
0.617 0.5905
0.633 0.5905
0.650 0.5807
0.667 0.5709
0.683 0.5709
0.700 0.5709
0.717 0.5610
0.733 0.5610
0.750 0.5512
0.767 0.5512
0.783 0.5413
0.800 0.5413
0.817 0.5413
0.833 0.5315
0.850 0.5315
0.867 0.5216
0.883 0.5216
0.900 0.5118
0.917 0.5118
0.933 0.5118
0.950 0.5118
0.967 0.5020
0.983 0.5020
1.000 0.4921
1.017 0.4921
1.033 0.4921
1.050 0.4823
1.067 0.4823
1.083 0.4823
1.100 0.4724
1.117 0.4724
1.133 0.4626
1.150 0.4626
1.167 0.4626
1.183 0.4528
1.200 0.4528
1.217 0.4528
1.233 0.4429
1.250 0.4429
Time Displacement
(min) (ft)
1.267 0.4429
1.283 0.4331
1.300 0.4331
1.317 0.4331
1.333 0.4232
1.350 0.4232
1.367 0.4232
1.383 0.4134
1.400 0.4134
1.417 0.4134
1.433 0.4035
1.450 0.4035
1.467 0.4035
1.483 0.3937
1.500 0.4035
1.517 0.3937
1.533 0.3937
1.550 0.3937
1.567 0.3839
1.583 0.3839
1.600 0.3839
1.617 0.3839
1.633 0.3740
1.650 0.3740
1.667 0.3740
1.683 0.3642
1.700 0.3642
1.717 0.3642
1.733 0.3642
1.750 0.3543
1.767 0.3543
1.783 0.3543
1.800 0.3543
1.817 0.3445
1.833 0.3445
1.850 0.3445
1.867 0.3445
1.883 0.3346
1.900 0.3346
1.917 0.3346
1.933 0.3346
Time Displacement
(min) (ft)
1.950 0.3248
1.967 0.3248
1.983 0.3248
2.000 0.3248
2.017 0.3150
2.033 0.3150
2.050 0.3150
2.067 0.3150
2.083 0.3051
2.100 0.3051
2.117 0.3051
2.133 0.3051
2.150 0.3051
2.167 0.2953
2.183 0.2953
2.200 0.2953
2.217 0.2953
2.233 0.2953
2.250 0.2854
2.267 0.2854
2.283 0.2854
2.300 0.2854
2.317 0.2854
2.333 0.2756
2.350 0.2756
2.367 0.2756
2.383 0.2756
2.400 0.2756
2.417 0.2657
2.433 0.2657
2.450 0.2657
2.467 0.2657
2.483 0.2657
2.500 0.2657
2.517 0.2559
2.533 0.2559
2.550 0.2559
2.567 0.2559
2.583 0.2559
2.600 0.2461
2.617 0.2461
Time Displacement
(min) (ft)
2.633 0.2461
2.650 0.2461
2.667 0.2461
2.683 0.2461
2.700 0.2461
2.717 0.2362
2.733 0.2362
2.750 0.2362
2.767 0.2362
2.783 0.2362
2.800 0.2362
2.817 0.2264
2.833 0.2264
2.850 0.2264
2.867 0.2264
2.883 0.2264
2.900 0.2264
2.917 0.2264
2.933 0.2165
2.950 0.2165
2.967 0.2165
2.983 0.2165
3.000 0.2165
3.017 0.2165
3.033 0.2165
3.050 0.2165
3.067 0.2067
3.083 0.2067
3.100 0.2067
3.117 0.2067
3.133 0.2067
3.150 0.2067
3.167 0.2067
3.183 0.2067
3.200 0.1968
3.217 0.1968
3.233 0.1968
3.250 0.1968
3.267 0.1968
3.283 0.1968
3.300 0.1968
Time Displacement
(min) (ft)
3.317 0.1968
3.333 0.1968
3.350 0.1870
3.367 0.1870
3.383 0.1870
3.400 0.1870
3.417 0.1870
3.433 0.1870
3.450 0.1870
3.467 0.1870
3.483 0.1870
3.500 0.1772
3.517 0.1772
3.533 0.1772
3.550 0.1772
3.567 0.1772
3.583 0.1772
3.600 0.1772
3.617 0.1772
3.633 0.1772
3.650 0.1772
3.667 0.1772
3.683 0.1673
3.700 0.1673
3.717 0.1673
3.733 0.1673
3.750 0.1673
3.767 0.1673
3.783 0.1673
3.800 0.1673
3.817 0.1673
3.833 0.1673
3.850 0.1673
3.867 0.1673
3.883 0.1575
3.900 0.1575
3.917 0.1575
3.933 0.1575
3.950 0.1575
3.967 0.1575
3.983 0.1575
Time Displacement
(min) (ft)
4.000 0.1575
4.017 0.1575
4.033 0.1575
4.050 0.1575
4.067 0.1575
4.083 0.1575
4.100 0.1575
4.117 0.1575
4.133 0.1476
4.150 0.1476
4.167 0.1476
4.183 0.1476
4.200 0.1476
4.217 0.1476
4.233 0.1476
4.250 0.1476
4.267 0.1476
4.283 0.1476
4.300 0.1476
4.317 0.1476
4.333 0.1476
4.350 0.1476
4.367 0.1476
4.383 0.1378
4.400 0.1378
4.417 0.1378
4.433 0.1378
4.450 0.1378
4.467 0.1378
4.483 0.1378
4.500 0.1378
4.517 0.1378
4.533 0.1378
4.550 0.1378
4.567 0.1378
4.583 0.1378
4.600 0.1378
4.617 0.1378
4.633 0.1378
4.650 0.1378
4.667 0.1378
Time Displacement
(min) (ft)
4.683 0.1378
4.700 0.1280
4.717 0.1280
4.733 0.1280
4.750 0.1280
4.767 0.1280
4.783 0.1280
4.800 0.1280
4.817 0.1280
4.833 0.1280
4.850 0.1280
4.867 0.1280
4.883 0.1280
4.900 0.1280
4.917 0.1280
4.933 0.1280
4.950 0.1280
4.967 0.1280
4.983 0.1280
5.000 0.1280

0. 1.2 2.4 3.6 4.8 6.
0.01
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\MW-8 JA.aqt
Date: 07/13/22 Time: 16:12:25
PROJECT INFORMATION
Company: Geoloogical Resources Inc
Client: RL Village Store
Project: 5586
Location: Wallace, NC
Test Well: MW-8
Test Date: 6/30/22
AQUIFER DATA
Saturated Thickness: 5.72 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (MW-8)
Initial Displacement: 1.75 ft Static Water Column Height: 5.29 ft
Total Well Penetration Depth: 18. ft Screen Length: 15. ft
Casing Radius: 0.085 ft Well Radius: 0.25 ft
Gravel Pack Porosity: 0.3
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 0.01563 ft/min y0 = 0.4414 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 12.98 Test well
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 14.73 Test well
Total well depth (TWD)TWD 18.00 Test well
Top of Casing Elevation (TOC)TOC 99.72 Test well
Highest historical ground water elevation at site (HGWE)HGWE 92.09 All site wells
Deepest well depth elevation (DWDE)DWDE 55.28 Deepest well
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW)H(o)1.75 Use 1.75
H: Static water column height H 5.02 TWD minus SDTW
Well #MW-8 Test well ID
7 b: Saturated thickness of aquifer b 36.81
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.1 Use 0.1
8 D: Casing length 0 Use 0.0 If water table intersects screen
L: Well screen length 5.02 Use H If H is less than L
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells
R(w): Well radius R(w)0.2500 1/2 auger outside diameter in feet
R(sk): Well skin radius R(sk)0.2500 1/2 auger outside diameter in feet
10 N(e): N(e): 0.3 Use 0.3
H(o): H(o)1.75 Use H(o)
RL Village Store
Wallace, NC
MW-8
6/30/2022
AQTESOLV DATA ENTRY FORM
(For wells screened ACROSS water table)
File: MW-8 Copy of AQTESOLV Data Entry Form
RL Village Store
Well MW-8
Test Date 06/30/22
Initial DTW (ft) 12.98

Time Displacement
(min) (ft)
0.000 0.000
0.017 0.069
0.033 1.063
0.050 0.778
0.067 0.561
0.083 0.433
0.100 0.364
0.117 0.325
0.133 0.305
0.150 0.285
0.167 0.276
0.183 0.256
0.200 0.256
0.217 0.246
0.233 0.236
0.250 0.236
0.267 0.226
0.283 0.226
0.300 0.217
0.317 0.217
0.333 0.207
0.350 0.197
0.367 0.197
0.383 0.187
0.400 0.177
0.417 0.187
0.433 0.187
0.450 0.187
0.467 0.177
0.483 0.177
0.500 0.167
0.517 0.167
0.533 0.167
0.550 0.167
0.567 0.157
Time Displacement
(min) (ft)
0.583 0.157
0.600 0.157
0.617 0.148
0.633 0.148
0.650 0.148
0.667 0.148
0.683 0.138
0.700 0.138
0.717 0.138
0.733 0.138
0.750 0.128
0.767 0.128
0.783 0.128
0.800 0.128
0.817 0.128
0.833 0.128
0.850 0.118
0.867 0.118
0.883 0.118
0.900 0.118
0.917 0.118
0.933 0.118
0.950 0.108
0.967 0.108
0.983 0.108
1.000 0.108
1.017 0.108
1.033 0.108
1.050 0.098
1.067 0.098
1.083 0.098
1.100 0.098
1.117 0.098
1.133 0.098
1.150 0.098
1.167 0.089
1.183 0.089
1.200 0.089
1.217 0.089
1.233 0.089
1.250 0.089
Time Displacement
(min) (ft)
1.267 0.089
1.283 0.089
1.300 0.089
1.317 0.089
1.333 0.079
1.350 0.079
1.367 0.079
1.383 0.079
1.400 0.079
1.417 0.079
1.433 0.079
1.450 0.069
1.467 0.069
1.483 0.069
1.500 0.069
1.517 0.069
1.533 0.069
1.550 0.069
1.567 0.069
1.583 0.069
1.600 0.069
1.617 0.069
1.633 0.059
1.650 0.059
1.667 0.059
1.683 0.059
1.700 0.059
1.717 0.049
1.733 0.059
1.750 0.059
1.767 0.059
1.783 0.059
1.800 0.059
1.817 0.059
1.833 0.059
1.850 0.059
1.867 0.059
1.883 0.059
1.900 0.049
1.917 0.049
1.933 0.049
Time Displacement
(min) (ft)
1.950 0.049
1.967 0.049
1.983 0.049
2.000 0.049
2.017 0.049
2.033 0.049
2.050 0.049
2.067 0.049
2.083 0.049
2.100 0.049
2.117 0.049
2.133 0.049
2.150 0.039
2.167 0.039
2.183 0.039
2.200 0.039
2.217 0.039
2.233 0.039
2.250 0.039
2.267 0.039
2.283 0.039
2.300 0.039
2.317 0.039
2.333 0.039
2.350 0.039
2.367 0.039
2.383 0.039
2.400 0.039
2.417 0.039
2.433 0.039
2.450 0.039
2.467 0.039
2.483 0.039
2.500 0.030
2.517 0.030
2.533 0.030
2.550 0.030
2.567 0.030
2.583 0.030
2.600 0.030
2.617 0.030
Time Displacement
(min) (ft)
2.633 0.030
2.650 0.030
2.667 0.030
2.683 0.030
2.700 0.030
2.717 0.030
2.733 0.030
2.750 0.030
2.767 0.030
2.783 0.030
2.800 0.030
2.817 0.030
2.833 0.030
2.850 0.030
2.867 0.030
2.883 0.030
2.900 0.030
2.917 0.030
2.933 0.030
2.950 0.030
2.967 0.030
2.983 0.030
3.000 0.030
3.017 0.020
3.033 0.020
3.050 0.020
3.067 0.020
3.083 0.020
3.100 0.020
3.117 0.020
3.133 0.020
3.150 0.020
3.167 0.020
3.183 0.020
3.200 0.020
3.217 0.020
3.233 0.020
3.250 0.020
3.267 0.020
3.283 0.020
3.300 0.020
Time Displacement
(min) (ft)
3.317 0.020
3.333 0.010
3.350 0.020
3.367 0.020
3.383 0.020
3.400 0.010
3.417 0.020
3.433 0.020
3.450 0.020
3.467 0.020
3.483 0.010
3.500 0.020
3.517 0.020
3.533 0.020
3.550 0.010
3.567 0.010
3.583 0.010
3.600 0.010
3.617 0.010
3.633 0.010
3.650 0.010
3.667 0.010
3.683 0.010
3.700 0.010
3.717 0.010
3.733 0.010
3.750 0.010
3.767 0.010
3.783 0.010
3.800 0.010
3.817 0.010
3.833 0.010
3.850 0.010
3.867 0.010
3.883 0.010
3.900 0.010
3.917 0.010
3.933 0.010
3.950 0.010
3.967 0.010
3.983 0.010
Time Displacement
(min) (ft)
4.000 0.010
4.017 0.010
4.033 0.010
4.050 0.010
4.067 0.010
4.083 0.010
4.100 0.010
4.117 0.010
4.133 0.010
4.150 0.010
4.167 0.010
4.183 0.010
4.200 0.010
4.217 0.010
4.233 0.010
4.250 0.010
4.267 0.010
4.283 0.010
4.300 0.010
4.317 0.010
4.333 0.010
4.350 0.010
4.367 0.010
4.383 0.010
4.400 0.010
4.417 0.010
4.433 0.010
4.450 0.010
4.467 0.010
4.483 0.010
4.500 0.010
4.517 0.010
4.533 0.010
4.550 0.010
4.567 0.010
4.583 0.010
4.600 0.010
4.617 0.010
4.633 0.010
4.650 0.010
4.667 0.010
Time Displacement
(min) (ft)
4.683 0.010
4.700 0.010
4.717 0.010
4.733 0.010
4.750 0.010
4.767 0.010
4.783 0.010
4.800 0.010
4.817 0.010
4.833 0.010
4.850 0.010
4.867 0.010
4.883 0.010
4.900 0.010
4.917 0.010
4.933 0.010
4.950 0.010
4.967 0.010
4.983 0.010
5.000 0.010
5.017 0.010
5.033 0.010
5.050 0.010
5.067 0.010
5.083 0.000
5.100 0.010
5.117 0.010
5.133 0.010
5.150 0.010
5.167 0.010
5.183 0.010
5.200 0.010
5.217 0.010
5.233 0.000

0. 0.4 0.8 1.2 1.6 2.
0.1
1.
10.
Time (min)Displacement (ft)WELL TEST ANALYSIS
Data Set: F:\...\TW-1 EE.aqt
Date: 08/24/22 Time: 16:54:32
PROJECT INFORMATION
Company: Geological Resources, Inc.
Client: RL Village Store
Project: 5586
Location: Wallace, NC
Test Well: TW-1
Test Date: 7/14/22
AQUIFER DATA
Saturated Thickness: 36.81 ft Anisotropy Ratio (Kz/Kr): 0.1
WELL DATA (TW-1)
Initial Displacement: 1.75 ft Static Water Column Height: 16.69 ft
Total Well Penetration Depth: 16.69 ft Screen Length: 5. ft
Casing Radius: 0.085 ft Well Radius: 0.1875 ft
SOLUTION
Aquifer Model: Unconfined Solution Method: Bouwer-Rice
K = 4.678E-5 ft/min y0 = 1.657 ft
Page Item Value Remarks
NA Static depth to water (SDTW) from TOC SDTW 28.31 Test well (ft)
Initial DTW (IDTW) - after remove/introduce slug from TOC IDTW 30.06 Test well (ft)
Total well depth (TWD)TWD 45.00 Test well (ft)
Top of Casing Elevation (TOC)TOC 100.28 Test well (ft)
Highest ground water elevation at site (HGWE)HGWE 92.09 All site wells (ft)
Deepest well depth elevation (DWDE)DWDE 55.28 Deepest well (ft)
5 Project Name
Project location (city, state)
Test Well #
Date slug test conducted
6 H(o): Initial displacement (IDTW minus SDTW (ft))H(o)1.75 Use 1.75
H: Static water column height H 16.69 TWD minus SDTW (ft)
Well #TW-1 Test well ID
7 b: Saturated thickness of aquifer b 36.81
HGWE - DWDE
* If no telescoping well, use H
KV/KH: Vertical/Horizontal KV/KH 0.10 Use 0.1
8 D: Casing length D 11.69 TWD minus SDTW minus screen length (ft)
L: Well screen length L 5.00 Screen length (ft)
9 R(c ): Inside radius of well casing R(c)0.085 Use 0.085 for 2" wells; use 0.167 for 4" wells(ft)
R(w): Well radius R(w)0.1875 1/2 auger outside diameter (ft)
R(sk): Well skin radius R(sk)0.1875 1/2 auger outside diameter (ft)
7/14/22
AQTESOLV DATA ENTRY FORM
(For wells screened BELOW water table)
RL Village Store
Wallace, NC
TW-1
File: MW-8 Copy of AQTESOLV Data Entry Form
Time Displacement Time Displacement
Well TW-1 (min)(ft)(min)(ft)
Test Date 07/14/22 0.700 1.614 1.483 1.604
Initial DTW (ft)28.31 0.717 1.614 1.500 1.604
0.733 1.614 1.517 1.604
Time Displacement 0.750 1.594 1.533 1.604
(min)(ft)0.767 1.594 1.550 1.604
0.000 0 0.783 1.614 1.567 1.604
0.017 0.334 0.800 1.614 1.583 1.604
0.033 1.299 0.817 1.614 1.600 1.604
0.050 1.683 0.833 1.614 1.617 1.604
0.067 1.663 0.850 1.614 1.633 1.604
0.083 1.643 0.867 1.614 1.650 1.604
0.100 1.624 0.883 1.614 1.667 1.604
0.117 1.633 0.900 1.614 1.683 1.604
0.133 1.624 0.917 1.614 1.700 1.604
0.150 1.633 0.933 1.614 1.717 1.604
0.167 1.614 0.950 1.614 1.733 1.604
0.183 1.624 0.967 1.614 1.750 1.604
0.200 1.624 0.983 1.614 1.767 1.604
0.217 1.624 1.000 1.604 1.783 1.604
0.233 1.633 1.017 1.614 1.800 1.604
0.250 1.643 1.033 1.614 1.817 1.604
0.267 1.633 1.050 1.614 1.833 1.604
0.283 1.633 1.067 1.614 1.850 1.604
0.300 1.633 1.083 1.604 1.867 1.604
0.317 1.633 1.100 1.604 1.883 1.604
0.333 1.633 1.117 1.604 1.900 1.604
0.350 1.633 1.133 1.614 1.917 1.604
0.367 1.633 1.150 1.614 1.933 1.604
0.383 1.633 1.167 1.604 1.950 1.604
0.400 1.633 1.183 1.614 1.967 1.604
0.417 1.633 1.200 1.614 1.983 1.594
0.433 1.633 1.217 1.604 2.000 1.604
0.450 1.633 1.233 1.604
0.467 1.633 1.250 1.604
0.483 1.624 1.267 1.604
0.500 1.624 1.283 1.604
0.517 1.624 1.300 1.604
0.533 1.624 1.317 1.614
0.550 1.624 1.333 1.604
0.567 1.624 1.350 1.604
0.583 1.624 1.367 1.604
0.600 1.624 1.383 1.604
0.617 1.624 1.400 1.604
0.633 1.624 1.417 1.604
0.650 1.614 1.433 1.604
0.667 1.614 1.450 1.604
0.683 1.614 1.467 1.604
RL Village Store

APPENDIX G
Public Notification Letters

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 9, 2022

CERTIFIED MAIL

Mr. Laurence C Bergman
Town Manager, Town of Wallace
316 East Murray Street
Wallace, NC 28466

RE: Comprehensive Site Assessment – Public Notice
RL Village Store
5194 South NC 41 Highway
Wallace, North Carolina
Duplin County
Incident Number: 47621
GRI Project Number: 5586
Dear Mr. Bergman:

In February 2021, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Phase I/II Limited Site Assessment (LSA) and Comprehensive Site Assessment
(CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,

Rae Troiano Brown, P.G.
Project Manager

enclosure

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 9, 2022

CERTIFIED MAIL

Mr. Jason Wells
Mayor, Town of Wallace
316 East Murray Street
Wallace, NC 28466

RE: Comprehensive Site Assessment – Public Notice
RL Village Store
5194 South NC 41 Highway
Wallace, North Carolina
Duplin County
Incident Number: 47621
GRI Project Number: 5586
Dear Mr. Wells:

In February 2021, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Phase I/II Limited Site Assessment (LSA) and Comprehensive Site Assessment
(CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,

Rae Troiano Brown, P.G.
Project Manager

enclosure

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 9, 2022

CERTIFIED MAIL

Mr. Brent Dean
Director of Public services, Town of Wallace
838 Old Wilmington Road
Wallace, NC 28466

RE: Comprehensive Site Assessment – Public Notice
RL Village Store
5194 South NC 41 Highway
Wallace, North Carolina
Duplin County
Incident Number: 47621
GRI Project Number: 5586
Dear Mr. Dean:

In February 2021, a petroleum release was reported at the above referenced property. In conjunction with
North Carolina Department of Environmental Quality (NCDEQ), soil and ground water assessment
activities, including those Phase I/II Limited Site Assessment (LSA) and Comprehensive Site Assessment
(CSA), were conducted at the site.

Please find enclosed a copy of the executive summary and pertinent figures and tables associated with the
CSA Report for the above referenced site in accordance with the public notice requirements listed 15A
NCAC 2L .0114 of the Guidelines for Assessment and Corrective Action published by the UST Section of
NCDEQ.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or comments.

Sincerely,

Rae Troiano Brown, P.G.
Project Manager

enclosure