WA-1147_13418_CA_SCH_20190220

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
February 20, 2019

Ms. Carrie Stone
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: January 2019 Site Check Activities
Duck Thru Food Store #47
NC Highway 45 & Quebec Street
Harrellsville, Hertford County
Facility ID: 0-017542
GRI Project No. 5022

Dear Ms. Stone,

Geological Resources, Inc. (GRI) presents this information to complete the scope of work that was
requested in the Notice of Violation dated January 4, 2019, by NCDEQ for the above referenced site
(Figure 1). Please find enclosed the applicable site location map, site map and laboratory report for the
above referenced site.

Please note, ongoing assessment activities are being conducted at the site in relation to a past release. The
past release, Red Apple Market #1, was issued UST Incident Number 11941.

A ground water sample were collected from monitoring well MW-3 in lieu of soil samples due to the
presence of pea gravel in the UST basin on January 31, 2019. The collected ground water sample was
submitted for laboratory analyses of volatile organic compounds using EPA Method 6200B.
Concentrations of requested method constituents that exceeded the Maximum Allowable Concentrations
specified in T15A NCAC 2L.0202 were reported in the ground water sample collected from MW-3. The
reported contaminant concentrations were consistent with past sampling results for MW-3 and did not
indicate the presence of a new release at the site.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or require
additional information.

Duck Thru Food Store #47
January 2019 Site Check Activities
Page 2 of 2

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

Sincerely,

Geological Resources, Inc.

William Regenthal, P. G.
Branch Operations Manager
Enclosures: Site Location Map, Site Map and Laboratory Report
cc: file
02/20/19
Technical Report for
GRI (Geological Resources Inc.)
Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
2538
SGS Job Number: FA61341
Sampling Date: 01/31/19
Report to:
GRI
[e-mail]
[e-mail]; [e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 02/20/19
Reissue #1
e-Hardcopy 2.0
Automated Report
19
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 19
FA61341
Florida  4405 Vineland Road  Suite C-15  Orlando, FL 32811  tel: [phone]  fax: [phone]

February 20, 2019

Mr. William Regenthal
GRI
3502 Hayes Rd
Monroe, NC 28110

RE: SGS North America Inc. - Orlando job FA61341 Reissue

Dear Mr. Regenthal,

The final report for job number FA61341 has been edited to reflect requested corrections.
These edits have been incorporated into the revised report.

The project name has been revised.

Please feel free to contact us if we can be of further assistance.

Sincerely,

SGS North America Inc. - Orlando

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FA61341
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................4
Section 2: Summary of Hits ....................................................................................................5
Section 3: Sample Results ........................................................................................................6
3.1: FA61341-1: MW-3 ........................................................................................................7
Section 4: Misc. Forms ............................................................................................................9
4.1: Chain of Custody ...........................................................................................................10
Section 5: MS Volatiles - QC Data Summaries .....................................................................13
5.1: Method Blank Summary ................................................................................................14
5.2: Blank Spike Summary ...................................................................................................16
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................18 123453 of 19
FA61341
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA61341
Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Project No: 2538
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA61341-1 01/31/19 14:06 ER 02/05/19 AQ Ground Water MW-3
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FA613411
Summary of Hits Page 1 of 1
Job Number:FA61341
Account:GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Collected:01/31/19
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA61341-1 MW-3
Benzene 2450 250 63 ug/l SM 6200B
o-Chlorotoluene 92.1 J 250 63 ug/l SM 6200B
Ethylbenzene 1880 250 63 ug/l SM 6200B
Isopropylbenzene 73.7 J 250 63 ug/l SM 6200B
Methyl Tert Butyl Ether 196 J 250 63 ug/l SM 6200B
Naphthalene 695 250 63 ug/l SM 6200B
n-Propylbenzene 154 J 250 63 ug/l SM 6200B
Styrene 76.7 J 250 63 ug/l SM 6200B
Toluene 16200 250 63 ug/l SM 6200B
1,2,4-Trimethylbenzene 2310 250 63 ug/l SM 6200B
1,3,5-Trimethylbenzene 668 250 63 ug/l SM 6200B
m,p-Xylene 10000 500 63 ug/l SM 6200B
o-Xylene 4600 250 63 ug/l SM 6200B
Xylene (total)14600 750 130 ug/l SM 6200B
5 of 19
FA613412
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 19
FA613413
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FA61341-1 Date Sampled:01/31/19
Matrix:AQ - Ground Water Date Received:02/05/19
Method:SM 6200B Percent Solids:n/a
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0217076.D 500 02/06/19 16:51 AB n/a n/a VA2530
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2450 250 63 ug/l
108-86-1 Bromobenzene ND 250 63 ug/l
74-97-5 Bromochloromethane ND 250 63 ug/l
75-27-4 Bromodichloromethane ND 250 63 ug/l
75-25-2 Bromoform ND 250 63 ug/l
104-51-8 n-Butylbenzene ND 250 63 ug/l
135-98-8 sec-Butylbenzene ND 250 63 ug/l
98-06-6 tert-Butylbenzene ND 250 63 ug/l
56-23-5 Carbon Tetrachloride ND 250 63 ug/l
108-90-7 Chlorobenzene ND 250 63 ug/l
75-00-3 Chloroethane ND 250 100 ug/l
67-66-3 Chloroform ND 250 63 ug/l
95-49-8 o-Chlorotoluene 92.1 250 63 ug/l J
106-43-4 p-Chlorotoluene ND 250 63 ug/l
124-48-1 Dibromochloromethane ND 250 63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 120 ug/l
106-93-4 1,2-Dibromoethane ND 250 63 ug/l
75-71-8 Dichlorodifluoromethane ND 250 100 ug/l
95-50-1 1,2-Dichlorobenzene ND 250 63 ug/l
541-73-1 1,3-Dichlorobenzene ND 250 63 ug/l
106-46-7 1,4-Dichlorobenzene ND 250 63 ug/l
75-34-3 1,1-Dichloroethane ND 250 63 ug/l
107-06-2 1,2-Dichloroethane ND 250 63 ug/l
75-35-4 1,1-Dichloroethylene ND 250 63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 63 ug/l
78-87-5 1,2-Dichloropropane ND 250 63 ug/l
142-28-9 1,3-Dichloropropane ND 250 63 ug/l
594-20-7 2,2-Dichloropropane ND 250 63 ug/l
563-58-6 1,1-Dichloropropene ND 250 63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 250 63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 19
FA6134133.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FA61341-1 Date Sampled:01/31/19
Matrix:AQ - Ground Water Date Received:02/05/19
Method:SM 6200B Percent Solids:n/a
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 250 63 ug/l
100-41-4 Ethylbenzene 1880 250 63 ug/l
87-68-3 Hexachlorobutadiene ND 250 63 ug/l
98-82-8 Isopropylbenzene 73.7 250 63 ug/l J
99-87-6 p-Isopropyltoluene ND 250 63 ug/l
74-83-9 Methyl Bromide ND 250 100 ug/l
74-87-3 Methyl Chloride ND 250 100 ug/l
74-95-3 Methylene Bromide ND 250 63 ug/l
75-09-2 Methylene Chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether 196 250 63 ug/l J
91-20-3 Naphthalene 695 250 63 ug/l
103-65-1 n-Propylbenzene 154 250 63 ug/l J
100-42-5 Styrene 76.7 250 63 ug/l J
630-20-6 1,1,1,2-Tetrachloroethane ND 250 63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 63 ug/l
127-18-4 Tetrachloroethylene ND 250 63 ug/l
108-88-3 Toluene 16200 250 63 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 63 ug/l
71-55-6 1,1,1-Trichloroethane ND 250 63 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 63 ug/l
79-01-6 Trichloroethylene ND 250 63 ug/l
75-69-4 Trichlorofluoromethane ND 250 100 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 63 ug/l
95-63-6 1,2,4-Trimethylbenzene 2310 250 63 ug/l
108-67-8 1,3,5-Trimethylbenzene 668 250 63 ug/l
75-01-4 Vinyl Chloride ND 250 63 ug/l
m,p-Xylene 10000 500 63 ug/l
95-47-6 o-Xylene 4600 250 63 ug/l
1330-20-7 Xylene (total)14600 750 130 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 108%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 19
FA6134133.1
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
9 of 19
FA613414
FA61341: Chain of Custody
Page 1 of 3
10 of 19
FA6134144.1
Job Number:FA61341 Client:GRI
Date / Time Received:2/5/2019 9:15:00 AM Delivery Method:FX
Project:RAM #1
Airbill #'s:
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (3.6);
Cooler 1: (3.4);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.2; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:PETERH Date:Date:2/5/2019 9:15:00 AM
FA61341: Chain of Custody
Page 2 of 3
11 of 19
FA6134144.1
TAT (Days):7
Received Date:2/5/2019
Due Date:2/12/2019
Project Description:Duck Thru Food Store #47: 100 W. Main Street, Ha
Account Name:GRI (Geological Resources Inc.)
Deliverable:COMMB
CSR:MM
Requested Date:2/20/2019
Job Change Order:FA61341
Sample #:FA61341-ALL Change:
Per client project name should be Duck Thru Food Store #47.Dept:
====================================================================================================================
====================================================================================================================
TAT:7
Above Changes Per:
To Client: This Change Order is confirmation of the revisions, previously discussed with the Client Service Representative.
Date/Time:2/20/2019 10:35:44 AM
Page 1 of 1
William Regenthal
FA61341: Chain of Custody
Page 3 of 3
12 of 19
FA6134144.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
13 of 19
FA613415
Method Blank Summary Page 1 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2530-MB A0217058.D 1 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
14 of 19
FA6134155.1.1
Method Blank Summary Page 2 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2530-MB A0217058.D 1 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 109%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
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FA6134155.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2530-BS A0217056.D 1 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.3 103 70-130
108-86-1 Bromobenzene 10 9.8 98 70-130
74-97-5 Bromochloromethane 10 9.9 99 70-130
75-27-4 Bromodichloromethane 10 10.5 105 70-130
75-25-2 Bromoform 10 8.5 85 70-130
104-51-8 n-Butylbenzene 10 9.9 99 70-130
135-98-8 sec-Butylbenzene 10 10.5 105 70-130
98-06-6 tert-Butylbenzene 10 10 100 70-130
56-23-5 Carbon Tetrachloride 10 11.3 113 70-130
108-90-7 Chlorobenzene 10 9.7 97 70-130
75-00-3 Chloroethane 10 10.2 102 60-140
67-66-3 Chloroform 10 10.6 106 70-130
95-49-8 o-Chlorotoluene 10 10.2 102 70-130
106-43-4 p-Chlorotoluene 10 10.0 100 70-130
124-48-1 Dibromochloromethane 10 9.2 92 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.1 91 70-130
106-93-4 1,2-Dibromoethane 10 9.5 95 70-130
75-71-8 Dichlorodifluoromethane 10 12.0 120 60-140
95-50-1 1,2-Dichlorobenzene 10 9.7 97 70-130
541-73-1 1,3-Dichlorobenzene 10 10 100 70-130
106-46-7 1,4-Dichlorobenzene 10 9.5 95 70-130
75-34-3 1,1-Dichloroethane 10 10.7 107 70-130
107-06-2 1,2-Dichloroethane 10 10.4 104 70-130
75-35-4 1,1-Dichloroethylene 10 13.0 130 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.2 102 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.3 103 70-130
78-87-5 1,2-Dichloropropane 10 10.3 103 70-130
142-28-9 1,3-Dichloropropane 10 9.2 92 70-130
594-20-7 2,2-Dichloropropane 10 11.5 115 70-130
563-58-6 1,1-Dichloropropene 10 11.0 110 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.0 90 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.4 94 70-130
108-20-3 Di-Isopropyl Ether 10 10 100 70-130
100-41-4 Ethylbenzene 10 10.2 102 70-130
87-68-3 Hexachlorobutadiene 10 10.5 105 70-130
98-82-8 Isopropylbenzene 10 11.1 111 70-130
* = Outside of Control Limits.
16 of 19
FA6134155.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2530-BS A0217056.D 1 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.0 100 70-130
74-83-9 Methyl Bromide 10 7.4 74 60-140
74-87-3 Methyl Chloride 10 10.7 107 60-140
74-95-3 Methylene Bromide 10 10.2 102 70-130
75-09-2 Methylene Chloride 10 10.2 102 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.9 99 70-130
91-20-3 Naphthalene 10 9.5 95 70-130
103-65-1 n-Propylbenzene 10 10.2 102 70-130
100-42-5 Styrene 10 9.3 93 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.4 104 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.9 99 70-130
127-18-4 Tetrachloroethylene 10 10.5 105 70-130
108-88-3 Toluene 10 10 100 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.0 100 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.9 99 70-130
71-55-6 1,1,1-Trichloroethane 10 10.8 108 70-130
79-00-5 1,1,2-Trichloroethane 10 10 100 70-130
79-01-6 Trichloroethylene 10 10.4 104 70-130
75-69-4 Trichlorofluoromethane 10 9.8 98 60-140
96-18-4 1,2,3-Trichloropropane 10 9.4 94 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10 100 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.4 104 70-130
75-01-4 Vinyl Chloride 10 9.7 97 60-140
m,p-Xylene 20 20.6 103 70-130
95-47-6 o-Xylene 10 10.2 102 70-130
1330-20-7 Xylene (total)30 30.8 103 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 104%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
* = Outside of Control Limits.
17 of 19
FA6134155.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA61344-1MS A0217068.D 50 02/06/19 AB n/a n/a VA2530
FA61344-1MSD A0217069.D 50 02/06/19 AB n/a n/a VA2530
FA61344-1 A0217061.D 10 02/06/19 AB n/a n/a VA2530
FA61344-1 A0217072.D 50 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
FA61344-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 82.1 500 608 105 500 728 129 18 70-130/20
108-86-1 Bromobenzene ND 500 500 100 500 494 99 1 70-130/20
74-97-5 Bromochloromethane ND 500 499 100 500 585 117 16 70-130/20
75-27-4 Bromodichloromethane ND 500 554 111 500 538 108 3 70-130/20
75-25-2 Bromoform ND 500 447 89 500 441 88 1 70-130/20
104-51-8 n-Butylbenzene 11.3 500 539 106 500 531 104 1 70-130/20
135-98-8 sec-Butylbenzene 7.5 500 550 109 500 550 109 0 70-130/20
98-06-6 tert-Butylbenzene ND 500 515 103 500 507 101 2 70-130/20
56-23-5 Carbon Tetrachloride ND 500 589 118 500 626 125 6 70-130/20
108-90-7 Chlorobenzene ND 500 499 100 500 492 98 1 70-130/20
75-00-3 Chloroethane ND 500 379 76 500 544 109 36*60-140/20
67-66-3 Chloroform ND 500 556 111 500 620 124 11 70-130/20
95-49-8 o-Chlorotoluene 21.2 500 548 105 500 547 105 0 70-130/20
106-43-4 p-Chlorotoluene ND 500 505 101 500 503 101 0 70-130/20
124-48-1 Dibromochloromethane ND 500 474 95 500 469 94 1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 500 522 104 500 517 103 1 70-130/20
106-93-4 1,2-Dibromoethane ND 500 484 97 500 482 96 0 70-130/20
75-71-8 Dichlorodifluoromethane ND 500 581 116 500 674 135 15 60-140/20
95-50-1 1,2-Dichlorobenzene ND 500 509 102 500 494 99 3 70-130/20
541-73-1 1,3-Dichlorobenzene ND 500 516 103 500 515 103 0 70-130/20
106-46-7 1,4-Dichlorobenzene ND 500 492 98 500 488 98 1 70-130/20
75-34-3 1,1-Dichloroethane ND 500 553 111 500 662 132*18 70-130/20
107-06-2 1,2-Dichloroethane ND 500 560 112 500 527 105 6 70-130/20
75-35-4 1,1-Dichloroethylene ND 500 573 115 500 660 132*14 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 500 512 102 500 621 124 19 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 500 536 107 500 631 126 16 70-130/20
78-87-5 1,2-Dichloropropane ND 500 531 106 500 517 103 3 70-130/20
142-28-9 1,3-Dichloropropane ND 500 468 94 500 465 93 1 70-130/20
594-20-7 2,2-Dichloropropane ND 500 586 117 500 635 127 8 70-130/20
563-58-6 1,1-Dichloropropene ND 500 556 111 500 652 130 16 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 500 445 89 500 449 90 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 500 470 94 500 458 92 3 70-130/20
108-20-3 Di-Isopropyl Ether ND 500 503 101 500 624 125 21*70-130/20
100-41-4 Ethylbenzene 454 500 975 104 500 977 105 0 70-130/20
87-68-3 Hexachlorobutadiene ND 500 551 110 500 538 108 2 70-130/20
98-82-8 Isopropylbenzene 35.1 500 608 115 500 602 113 1 70-130/20
* = Outside of Control Limits.
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FA6134155.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA61341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Duck Thru Food Store 47; 100 W Main St, Harrellsville, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA61344-1MS A0217068.D 50 02/06/19 AB n/a n/a VA2530
FA61344-1MSD A0217069.D 50 02/06/19 AB n/a n/a VA2530
FA61344-1 A0217061.D 10 02/06/19 AB n/a n/a VA2530
FA61344-1 A0217072.D 50 02/06/19 AB n/a n/a VA2530
The QC reported here applies to the following samples:Method: SM 6200B
FA61341-1
FA61344-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 6.0 500 523 103 500 519 103 1 70-130/20
74-83-9 Methyl Bromide ND 500 338 68 500 448 90 28*60-140/20
74-87-3 Methyl Chloride ND 500 491 98 500 595 119 19 60-140/20
74-95-3 Methylene Bromide ND 500 534 107 500 507 101 5 70-130/20
75-09-2 Methylene Chloride ND 500 540 108 500 654 131*19 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 500 509 102 500 586 117 14 70-130/20
91-20-3 Naphthalene 182 500 694 102 500 678 99 2 70-130/20
103-65-1 n-Propylbenzene 108 500 629 104 500 625 103 1 70-130/20
100-42-5 Styrene ND 500 470 94 500 474 95 1 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 500 530 106 500 513 103 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 500 518 104 500 501 100 3 70-130/20
127-18-4 Tetrachloroethylene ND 500 530 106 500 532 106 0 70-130/20
108-88-3 Toluene 185 500 689 101 500 694 102 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 500 527 105 500 514 103 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 500 532 106 500 528 106 1 70-130/20
71-55-6 1,1,1-Trichloroethane ND 500 568 114 500 603 121 6 70-130/20
79-00-5 1,1,2-Trichloroethane ND 500 524 105 500 507 101 3 70-130/20
79-01-6 Trichloroethylene ND 500 534 107 500 524 105 2 70-130/20
75-69-4 Trichlorofluoromethane ND 500 449 90 500 565 113 23*60-140/20
96-18-4 1,2,3-Trichloropropane ND 500 487 97 500 474 95 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1170 a 500 1710 108 500 1700 106 1 70-130/20
108-67-8 1,3,5-Trimethylbenzene 191 500 747 111 500 741 110 1 70-130/20
75-01-4 Vinyl Chloride ND 500 443 89 500 554 111 22*60-140/20
m,p-Xylene 735 1000 1800 107 1000 1800 107 0 70-130/20
95-47-6 o-Xylene 357 500 886 106 500 886 106 0 70-130/20
1330-20-7 Xylene (total)1090 1500 2680 106 1500 2690 107 0 70-130/20
CAS No.Surrogate Recoveries MS MSD FA61344-1 FA61344-1 Limits
1868-53-7 Dibromofluoromethane 106%122%103%103%70-130%
17060-07-0 1,2-Dichloroethane-D4 112%112%111%106%70-130%
2037-26-5 Toluene-D8 97%98%98%98%70-130%
460-00-4 4-Bromofluorobenzene 98%99%98%97%70-130%
(a) Result is from Run #2.
* = Outside of Control Limits.
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FA6134155.3.1