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HomeMy WebLinkAboutWA-1039_12716_CA_RPTS_20160418_MRP April 18, 2016 Mr. Bill Crew North Carolina Department of Environmental Quality Division of Waste Management, UST Section Washington Regional Office 943 Washington Square Mall Washington, NC 27889 Re.: Transmittal Letter March 2016 Groundwater Monitoring Report Town of Edenton Street Department Groundwater Incident #12716 Solutions-IES Project No. 2016.0013.TEDE Dear Mr. Crew: Solutions-IES, Inc. (SIES), on behalf of the Town of Edenton, is submitting the enclosed March 2016 Groundwater Monitoring Report for your review and files. The report summarizes the groundwater monitoring activities conducted in March 2016 at the Edenton Street Department location at 120 West Hicks Street. If you have any questions or need additional information, please call us at (919) 873-1060. Truly yours, Solutions-IES Michael W. Branson, P.G. Project Manager cc: Anne-Marie Knighton, Town of Edenton Enclosure MARCH 2016 GROUNDWATER MONITORING REPORT TOWN OF EDENTON STREET DEPARTMENT 120 WEST HICKS STREET EDENTON, CHOWAN COUNTY, NORTH CAROLINA GROUNDWATER INCIDENT # 12716 RISK, RANK AND ABATEMENT SCORE: H65R Prepared for: Town of Edenton PO Box 300 Edenton, NC 27932 Prepared by: Solutions-IES, Inc. 1101 Nowell Road Raleigh, North Carolina 27607 Solutions-IES Project No. 2016.0013.TEDE April 18, 2016 Michael W. Branson, P.G. James Y. Joyner, II, RSM Project Manager Senior Consultant i TABLE OF CONTENTS 1.0 INTRODUCTION AND SITE BACKGROUND ................................................................................ 1 2.0 MARCH GROUNDWATER SAMPLING EVENT ............................................................................ 2 2.1 GROUNDWATER ELEVATIONS ................................................................................................ 2 2.2 GROUNDWATER SAMPLING .................................................................................................... 2 2.3 GROUNDWATER MONITORING RESULTS .............................................................................. 3 3.0 CONCLUSIONS ............................................................................................................................... 3 4.0 REFERENCES ................................................................................................................................. 4 FIGURES Figure 1 Site Location Map Figure 2 Site Map Figure 3 Shallow Groundwater Contour Map Figure 4 Contaminant Concentration Map TABLES Table 1 Summary of Groundwater Elevation Data Table 2 Summary of Groundwater Field Parameters Table 3 Summary of Detected Compounds in Groundwater Table 4 Summary of Historical Groundwater Analytical Results APPENDICES Appendix A Groundwater Sampling Logs Appendix B Laboratory Analytical Report and Chain of Custody Record March 2016 Groundwater Monitoring Report Solutions-IES Project No. 2016.0013.TEDE Town of Edenton Street Department April 18, 2016 Edenton, Chowan County, NC 1 1.0 INTRODUCTION AND SITE BACKGROUND Solutions-IES, Inc. (SIES), has prepared this March 2016 Groundwater Monitoring Report for the Town of Edenton (Edenton) to document the groundwater conditions at the Street Department facility (Site) located at 120 West Hicks Street in Edenton, Chowan County, North Carolina (Figure 1). This report provides information pertaining to relative groundwater elevations and groundwater contaminant concentrations. The Site is an active maintenance facility for Edenton’s Street Department and is also the location of Edenton’s solid waste transfer station. In January 1994, two underground storage tanks (USTs) were removed from the Site, one 550-gallon diesel fuel tank and one 1,000-gallon gasoline tank. During the UST removal, soil contamination was detected and a release of petroleum was confirmed (Spangler, 2005). Subsequently, an assessment was conducted and a Corrective Action Plan (CAP) was developed that recommended monitored natural attenuation (MNA) as the remediation method. NCDEQ approved the CAP in November 1998. In September 2004, the NCDEQ completed a Risk, Rank and Abatement Ranking Form for the site and assigned the site a high groundwater risk with a score of H65R. According to the rating form, the presence of a public water supply well within 1,000 feet of the source area was the criterion causing the site to be classified as high risk. Other factors contributing to the ranking included the potential for migration and the contaminant concentrations in the groundwater. Following the groundwater monitoring event in April 2005, Edenton was advised that the NCDEQ considered the Site a “non-directed” site, meaning further work and remedial efforts were not required until it became a high enough priority to resume remedial activities. In a Notice of Regulatory Requirements (NORR) dated February 25, 2015, the NCDEQ directed Edenton to resume groundwater monitoring. Five monitoring wells (MW-1 through MW-5) were installed at the site after the USTs were removed in 1994. Four of these wells were located during a May 2015, sampling event; however, well MW-4 was buried under 1 to 1.5 feet of gravel and could not be located. Based on the sampling activities and results, the NCDEQ issued an Acknowledgement of Groundwater Monitoring Report Receipt, which required the following:  Re-install well MW-4;  Conduct a receptor survey update; and  Sample all monitoring wells, including new MW-4, and any water supply wells within 250 feet of the contaminant plume as identified during the receptor survey. In November 2015, SIES installed a replacement monitoring well, MW-4R. A receptor survey was performed, which indicated that the site continued to be classified as high risk, based upon the presence of a public water supply well in the vicinity. March 2016 Groundwater Monitoring Report Solutions-IES Project No. 2016.0013.TEDE Town of Edenton Street Department April 18, 2016 Edenton, Chowan County, NC 2 On November 18, 2015, SIES collected groundwater samples from five monitoring wells at the site (MW-1 through MW-3, MW-4R, and MW-5; Figure 2). The laboratory analytical results indicated that two constituents, tetrachloroethene (PCE) and 1,2-dichloroethane (1,2-DCA) were reported at concentrations above the 15A NCAC 2L Groundwater Standards (2L Standards). Based on these results, the NCDEQ issued a NORR directing Edenton to “either file a Notice of Residual Petroleum (NRP) Contamination for groundwater only, or resample all the monitoring wells using EPA Method 6200B and MADEP VPH and EPH.” This monitoring report describes the activities related to the well resampling 2.0 MARCH GROUNDWATER SAMPLING EVENT 2.1 GROUNDWATER ELEVATIONS Prior to collecting groundwater level measurements, SIES personnel opened each monitoring well to allow the water level to equilibrate. SIES measured the depth-to-water (DTW) using an electronic water level indicator and converted these measurements to elevations by subtracting the depth-to-water measurement from the top-of-casing elevation that was referenced to a site datum with an assumed elevation. When the replacement well was installed, SIES conducted a survey of all the monitoring wells tying the top; of casing elevation to an assumed benchmark in order to provide an elevation for all the wells from a consistent benchmark. Table 1 presents the March 2016 water level data with historical water level measurements (Spangler, 2005). SIES used the groundwater elevation data for wells screened in the shallow aquifer to develop a shallow potentiometric surface map for March 2016, shown as Figure 3. The groundwater contour map prepared suggests that shallow groundwater generally flows to the southwest towards a tributary of Pembroke Creek. However, this flow direction was interpreted with data from a limited area and a relatively flat water table. Local variations over time may influence the groundwater flow direction. 2.2 GROUNDWATER SAMPLING Following the completion of DTW measurements, five monitoring wells (MW-1, -2, -3, -4R and -5) were purged and sampled. Monitoring well purging was performed using a variable speed peristaltic pump and dedicated polyethylene tubing with a YSI Model 556 multi-parameter water quality meter and flow-through cell assembled in line with the discharge train. Wells were purged, to the extent possible, at a pumping rate approximately less than or equal to the recharge rate of the well. Well purging continued until field parameters (pH, temperature, specific conductivity, dissolved oxygen [DO], and oxidation-reduction potential [ORP]) stabilized or until the wells were nearly purged dry. Table 2 summarizes the stabilized field parameters measured during this sampling event and the groundwater sampling logs are provided in Appendix A. March 2016 Groundwater Monitoring Report Solutions-IES Project No. 2016.0013.TEDE Town of Edenton Street Department April 18, 2016 Edenton, Chowan County, NC 3 Groundwater samples were placed directly into laboratory-supplied bottles. The samples were stored on ice under chain-of-custody control and transported to Prism Laboratories, Inc., in Charlotte, North Carolina for analysis. Samples were analyzed for volatile organic compounds (VOCs) by EPA Method 6200B, and for volatile petroleum hydrocarbons (VPH) and extractable petroleum hydrocarbons (EPH) by the Massachusetts Department of Environmental Protection (MADEP) method. 2.3 GROUNDWATER MONITORING RESULTS Table 3 summarizes the results of the target compounds detected in March 2016 and Table 4 summarizes the historical target compounds results, which includes the applicable 2L Standards for comparison. The laboratory analytical report for the March 2016 monitoring event is included as Appendix B. Figure 4 is a contaminant concentration map that shows the concentrations detected in March 2016. The laboratory analytical results indicated that the following VOCs were reported at concentrations above the 2L Standards in groundwater samples collected from monitoring wells MW-2 and MW-4R:  1,2-DCA in MW-2 (1.1 micrograms per liter (µg/L)) and MW-4R (1.8 µg/L); and,  1,2,3-Trichloropropane in MW-4R (1.7 µg/L). The 2L Standards for 1,2-DCA and 1,2,3-Trichloropropane are 0.4 µg/L and 0.005 µg/L , respectively. Additional constituents were reported at concentrations above the laboratory analytical method detection limits but below the NC 2L Standards in monitoring wells MW-1, MW-2, and MW-4R. No constituents were detected in wells MW-3 and MW-5. The results are presented in Table 3. The laboratory analytical results indicated that VPH/EPH carbon fractions were not reported at concentrations above the 2L Standards in any of the groundwater samples collected from the site . VPH/EPH carbon fractions were reported at concentrations above the laboratory analytical method detection limits but below the 2L Standards in groundwater samples collected from MW-1, MW-2, and MW-4R. Each of the detections was flagged with a “J” by the laboratory, indicating that the value was detected above the method detection limit but below the reporting limit, and is considered estimated. The results are presented in Table 3. 3.0 CONCLUSIONS The presumed source area for the contamination is in the former location of the diesel fuel and gasoline USTs that have been removed from the site. The available historical analytical results indicate that the March 2016 Groundwater Monitoring Report Solutions-IES Project No. 2016.0013.TEDE Town of Edenton Street Department April 18, 2016 Edenton, Chowan County, NC 4 petroleum constituents are decreasing with time, and petroleum constituents that have been detected in the past are all below the 2L Standards. The only remaining constituents detected above the 2L Standards are 1,2-DCA and 1,2,3-trichloropropane. It is unknown whether these constituents are related to the petroleum release. As such, SIES recommends that Edenton submit this report to the NCDEQ Division of Waste Management, UST Section in the Washington Regional Office with a request for No Further Action for the petroleum incident. 4.0 REFERENCES Spangler Environmental Inc., 2005, Semi-Annual Monitoring Report, City of Edenton Street Department, 120 West Hicks Street, Edenton, North Carolina, prepared by Spangler Environmental, Inc., 3961-B Market Street, Wilmington, North Carolina. SIES, May 2015, May 2015 Groundwater Monitoring Report, Town of Edenton Street Department, 120 West Hicks Street, Edenton, Chowan County, North Carolina, Groundwater Incident # 12716, Risk, Rank, and Abatement Score H65R, prepared by Solutions-IES, Inc., 1101 Nowell Road, Raleigh, North Carolina. SIES, November 2015 Groundwater Monitoring, Town of Edenton Street Department, 120 West Hicks Street, Edenton, Chowan County, North Carolina, prepared by Solutions-IES, Inc., 1101 Nowell Road, Raleigh, North Carolina. FIGURES SITE 2000 40000 SCALE IN FEETPROJECTNUMBERDRAFTERCHECKEDBYPROJECTMANAGERDATEFILE FIGURE: RALEIGH, NORTH CAROLINA 27607 1101 NOWELL ROAD TEL.: (919) 873-1060 FAX.: (919) 873-1074 Industrial & Environmental ServicesIndustrial & Environmental Services2016.0013.TEDEKTSCEMWB3/25/2016TownofEdentonStDept.dwg1 EDENTON, NORTH CAROLINA EDENTON STREET DEPARTMENT SITE LOCATION MAP J:\Project Files\Edenton\Town of Edenton Street Dept\Current Drawings\Town of Edenton St Dept.dwg REFERENCE: USGS TOPOGRAPHIC MAP EDENTON, NC 2010 WESTHICKSSTREET CHAINLINKFENCE FORMER DISPENSER AREA MW-5 MW-1MW-3 MW-2 MW-4R 30 600 SCALE IN FEETPROJECTNUMBERDRAFTERCHECKEDBYPROJECTMANAGERDATEFILE FIGURE: RALEIGH, NORTH CAROLINA 27607 1101 NOWELL ROAD TEL.: (919) 873-1060 FAX.: (919) 873-1074 Industrial & Environmental ServicesIndustrial & Environmental Services2016.0013.TEDEKTSCEMB3/25/2016TownofEdentonStDept.dwg2 EDENTON, NORTH CAROLINA EDENTON STREET DEPARTMENT SITE LAYOUT J:\Project Files\Edenton\Town of Edenton Street Dept\Current Drawings\Town of Edenton St Dept.dwg LEGEND MONITORING WELL GASOLINE UST DIESEL UST NOTE: BASEMAP BASED ON SPANGLER ENVIRONMENTAL INC, MAP 2005 WESTHICKSSTREET CHAINLINKFENCE FORMER DISPENSER AREA MW-5 MW-1MW-3 MW-2 MW-4R MW-1 ETHYLBENZENE 2.3 TOLUENE 0.61 TOTAL XYLENES 2.0 C5-C8 ALIPHATICS 26 J C9-C18 ALIPHATICS 28 J C9-C22 AROMATICS 1.8 J MW-2 1,2-DICHLOROETHANE 1.1 MTBE 7.6 C5-C8 ALIPHATICS 6.1 J MW-4R 1,2-DICHLOROETHANE 1.8 1,2,3-TRICHLOROPROPANE 1.7 MTBE 12 NAPHTHALENE 1.0 C5-C8 ALIPHATICS 30 J C9-C18 ALIPHATICS 16 J PROJECTNUMBERDRAFTERCHECKEDBYPROJECTMANAGERDATEFILEFIGURE: RALEIGH, NORTH CAROLINA 27607 1101 NOWELL ROAD TEL.: (919) 873-1060 FAX.: (919) 873-1074 Industrial & Environmental ServicesIndustrial & Environmental Services2016.0013.TEDEKTSCEMB3/25/2016TownofEdentonStDept.dwg4 EDENTON, NORTH CAROLINA EDENTON STREET DEPARTMENT MARCH 2016 CONTAMINANT CONCENTRATION MAP J:\Project Files\Edenton\Town of Edenton Street Dept\Current Drawings\Town of Edenton St Dept.dwg NOTES: 1) BASEMAP BASED ON SPANGLER ENVIRONMENTAL INC, MAP 2005 2) SHADED COMPOUNDS ARE ABOVE THE NC 2L STANDARDS 3) CONCENTRATIONS IN µg/L. 4) J = CONCENTRATION IS ESTIMATED BELOW THE REPORTING LIMIT. 30 600 SCALE IN FEET LEGEND MONITORING WELL GASOLINE UST DIESEL UST TABLES Well Casing Screened Bottom Top of Casing Depth to Groundwater Depth Interval of Well Elevation Water Elevation (ft btoc) (ft bgs) (ft bgs) (feet) (ft btoc) (feet) 3/2/2016 6.40 89.92 11/18/2015 7.17 89.15 5/7/2015 6.94 93.24 2/7/2005 7.72 92.46 7/19/2004 7.35 92.83 1/15/2004 6.86 93.32 7/28/2003 7.02 93.16 7/11/2002 8.20 91.98 6/29/1999 8.13 92.05 2/26/1999 8.20 91.98 5/14/1998 7.68 92.50 3/2/2016 6.89 89.92 11/18/2015 7.68 89.13 5/7/2015 7.43 92.73 2/7/2005 8.17 91.99 7/19/2004 7.85 92.31 1/15/2004 NA NA 7/28/2003 7.53 92.63 7/11/2002 8.52 91.64 6/29/1999 8.38 91.78 2/26/1999 8.10 92.06 5/14/1998 7.62 92.54 3/2/2016 6.68 89.81 11/18/2015 7.37 89.12 5/7/2015 7.22 92.78 2/7/2005 7.91 92.09 7/19/2004 7.54 92.46 1/15/2004 NA NA 7/28/2003 7.06 92.94 7/11/2002 8.29 91.71 6/29/1999 8.06 91.94 2/26/1999 8.10 91.90 5/14/1998 7.62 92.38 5/7/2015 NA NA 2/7/2005 8.01 92.30 7/19/2004 7.58 92.73 1/15/2004 6.58 93.73 7/28/2003 7.18 93.13 7/11/2002 8.35 91.96 6/29/1999 8.11 92.20 2/26/1999 7.90 92.41 5/14/1998 7.69 92.62 3/2/2016 7.19 90.27 11/18/2015 8.11 89.35 MW-3 12.96 Unknown 12.96 MW-4R 15 5 - 15 15 Unknown 9.41 96.32 MW-2 8.33 Unknown 8.33 96.81 EDENTON, CHOWAN COUNTY, NORTH CAROLINA INCIDENT # 12716 SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE UnknownMW-4 100.16 MW-1 TABLE 1 SUMMARY OF GROUNDWATER ELEVATION DATA TOWN OF EDENTON STREET DEPARTMENT 120 WEST HICKS STREET Well ID 100.18 Date Measured 9.41 Unknown 100.00 100.31 96.49 97.46 Unknown 1 of 2 Well Casing Screened Bottom Top of Casing Depth to Groundwater Depth Interval of Well Elevation Water Elevation (ft btoc) (ft bgs) (ft bgs) (feet) (ft btoc) (feet) EDENTON, CHOWAN COUNTY, NORTH CAROLINA INCIDENT # 12716 SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE TABLE 1 SUMMARY OF GROUNDWATER ELEVATION DATA TOWN OF EDENTON STREET DEPARTMENT 120 WEST HICKS STREET Well ID Date Measured 3/2/2016 6.19 90.20 11/18/2015 6.86 89.53 5/7/2015 6.65 93.55 2/7/2005 7.29 92.91 7/19/2004 7.22 92.98 1/15/2004 7.12 93.08 7/28/2003 6.71 93.49 7/11/2002 8.11 92.09 6/29/1999 7.90 92.30 2/26/1999 7.50 92.70 5/14/1998 7.38 92.82 Notes: 2. ft bgs: feet below ground surface 3. ft btoc: feet below top of casing 4. NA - Information not available. MW-4 could not be located during the 5/7/2015 sampling event. 5. Well elevations re-surveyed with rod and level by Solutions-IES on November 9, 2015. 6. Well MW-4R installed November 9, 2015. 1. Data before 5/1/2015 are from the Semi-Annual Monitoring Report dated April 7, 2005 prepared by Spangler Environmental, Inc. MW-5 24.87 Unknown 24.87 96.39 100.20 2 of 2 Well pH Specific Conductivity ORP Temperature DO ID (SU) (µS/cm) (mV) (ºC) (mg/L) MW-1 6.08 225 -66.8 16.33 0.90 MW-2 4.98 236 96.8 16.43 0.90 MW-3 5.34 167 69.3 16.06 5.15 MW-4R 5.25 414 107.8 15.99 0.33 MW-5 6.75 279 -99.4 19.24 0.23 Notes: 1. SU = Standard units 2. µS/cm = Microsiemens per centimeter 3. ORP = Oxidation Reduction Potential 4. mV = Millivolts 5. ºC = degrees centigrade 6. DO = Dissolved oxygen 7. mg/L = milligrams per liter MONITORING WELLS TABLE 2 SUMMARY OF GROUNDWATER FIELD PARAMETERS - MARCH 2016 EDENTON, CHOWAN COUNTY, NORTH CAROLINA INCIDENT # 12716 TOWN OF EDENTON STREET DEPARTMENT 120 WEST HICKS STREET SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE VOCs by EPA Method 6200B 15A NCAC 2L Groundwater Standards MW-1 MW-2 MW-3 MW-4R MW-5 1,2-Dichloroethane 0.4 <0.5 1.1 <0.5 1.8 <0.5 1,2,3-Trichloropropane 0.005 <0.5 <0.5 <0.5 1.7 <0.5 1,2,4-Trimethylbenzene 400 <0.5 <0.5 <0.5 <0.5 <0.5 Benzene 1 <0.5 <0.5 <0.5 <0.5 <0.5 Ethylbenzene 600 2.3 <0.5 <0.5 <0.5 <0.5 MTBE 20 <2.0 7.6 <1.0 12 <1.0 IPE 70 <0.5 <0.5 <0.5 <0.5 <0.5 Toluene 600 0.61 <0.5 <0.5 <0.5 <0.5 Total Xylenes 500 2.0 <1.5 <1.5 <1.5 <1.5 Isopropylbenzene 70 <0.5 <0.5 <0.5 <0.5 <0.5 n-Propylbenzene 70 <0.5 <0.5 <0.5 <0.5 <0.5 Naphthalene 6 <1.0 <1.0 <1.0 1.0 <1.0 Tetrachloroethylene 0.7 <0.5 <0.5 <0.5 <0.5 <0.5 Trichloroethylene 3 <0.5 <0.5 <0.5 <0.5 <0.5 VPH/EPH by MADEP Method C5-C8 Aliphatics 400 26 J 6.1 J <50 30 J <50 C9-C18 Aliphatics 700 28 J <400 <400 16 J <400 C-19-C36 Aliphatics 10,000 <500 <500 <500 <500 <500 C9-C22 Aromatics 200 1.8 J <150 <150 <150 <150 Notes: 1. Bolded cells indicate detected constituents; shaded cells exceed the NCAC 2L Groundwater Standards. 2. All concentrations expressed as micrograms per liter (ug/L) 3. NCAC 2L Standards: 15A NCAC 2L Groundwater Standards 4. VOCs: Volatile Organic Compounds 5. VPH/EPH: Volatile Petroleum Hydrocarbons/ Extractible Petroleum Hydrocarbons 6. MADEP: Massachusetts Department of Environmental Protection 7. J: Estimated concentration SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE TABLE 3 SUMMARY OF DETECTED COMPOUNDS IN GROUNDWATER - MARCH 2016 TOWN OF EDENTON STREET DEPARTMENT 120 WEST HICKS STREET EDENTON, CHOWAN COUNTY, NORTH CAROLINA INCIDENT # 12716 Well ID Date Collected Benzene (ug/L) Toluene (ug/L) Ethylbenzene (ug/L) Total Xylenes (ug/L) MTBE (ug/L) IPE (ug/L) Naphthalene (ug/L) TCE (ug/L) PCE (ug/L) 1,2,3- Trichloropropane 1,2-DCA (ug/L) 1 600 600 500 20 70 6 3 0.7 0.005 0.4 3/2/2016 <0.5 0.61 2.3 2.0 <2.0 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 11/18/2015 <0.5 <0.5 <0.5 0.67J <1.0 <0.5 0.82J <0.5 1.2 <0.5 <0.066 5/7/2015 <0.5 <0.5 0.51 <1.5 <1.0 <0.5 14 <0.5 0.74 <0.5 <0.5 2/7/2005 95.8 139 1400 3111 ND ND NA NA NA NA NA 7/19/2004 39.1 140 612 1274 ND ND NA NA NA NA NA 1/15/2004 ND ND 1300 3300 ND ND NA NA NA NA NA 7/28/2003 ND 130 1200 4620 ND ND NA NA NA NA NA 7/11/2002 ND 130 1200 2860 ND ND NA NA NA NA NA 6/29/1999 140 840 1200 4600 NA NA NA NA NA NA NA 2/26/1999 160 870 910 3420 NA NA NA NA NA NA NA 5/14/1998 <200 480 1100 4500 NA NA NA NA NA NA NA 3/2/2016 <0.5 <0.5 <0.5 <1.5 7.6 <0.5 <1.0 <0.5 <0.5 <0.5 1.1 11/18/2015 <0.5 <0.5 <0.5 <1.5 16 <0.5 <1.0 0.59 1.5 <0.5 2.2 5/7/2015 <0.5 <0.5 <0.5 <1.5 14 <0.5 <1.0 0.65 0.57 <0.5 2.8 2/7/2005 1.22 ND ND ND ND ND NA NA NA NA NA 7/19/2004 ND ND ND ND ND ND NA NA NA NA NA 1/15/2004 ND ND ND ND ND ND NA NA NA NA NA 7/28/2003 ND ND ND ND ND ND NA NA NA NA NA 7/11/2002 15 ND ND ND 3 ND NA NA NA NA NA 6/29/1999 ND ND ND ND NA NA NA NA NA NA NA 2/26/1999 ND ND ND ND NA NA NA NA NA NA NA 5/14/1998 ND ND ND ND NA NA NA NA NA NA NA 3/2/2016 <0.5 <0.5 <0.5 <1.5 <1.0 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 11/18/2015 <0.5 <0.5 <0.5 <1.5 16 <0.5 <1.0 <0.5 1.4 <0.5 <0.066 5/7/2015 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 2/7/2005 ND ND ND ND ND ND NA NA NA NA NA 7/19/2004 ND ND ND ND ND ND NA NA NA NA NA 1/15/2004 ND ND ND ND ND ND NA NA NA NA NA 7/28/2003 ND ND ND ND ND ND NA NA NA NA NA 7/11/2002 ND ND ND ND ND ND NA NA NA NA NA 6/29/1999 ND ND ND ND NA NA NA NA NA NA NA 2/26/1999 ND ND ND ND NA NA NA NA NA NA NA 5/14/1998 ND ND ND ND NA NA NA NA NA NA NA 5/7/2015 NA NA NA NA NA NA NA NA NA NA NA 2/7/2005 6.51 ND ND ND 33.8 ND NA NA NA NA NA 7/19/2004 27 ND ND ND 24.9 ND NA NA NA NA NA 1/15/2004 17 ND ND ND 29 ND NA NA NA NA NA 7/28/2003 3.2 ND ND ND 38 1.2 NA NA NA NA NA 7/11/2002 1 ND ND ND 32 ND NA NA NA NA NA 6/29/1999 ND ND ND ND 38 NA NA NA NA NA NA 2/26/1999 ND ND ND ND 26 NA NA NA NA NA NA 5/14/1998 ND ND ND ND 22 NA NA NA NA NA NA EDENTON, CHOWAN COUNTY, NORTH CAROLINA SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE MW-2 MONITORING WELLS 2L Standard MW-1 MW-4 120 WEST HICKS STREET TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER ANALYTICAL RESULTS Analytical Method VOCs by Method 6200B TOWN OF EDENTON STREET DEPARTMENT MW-3 INCIDENT # 12716 1 of 2 Well ID Date Collected Benzene (ug/L) Toluene (ug/L) Ethylbenzene (ug/L) Total Xylenes (ug/L) MTBE (ug/L) IPE (ug/L) Naphthalene (ug/L) TCE (ug/L) PCE (ug/L) 1,2,3- Trichloropropane 1,2-DCA (ug/L) 1 600 600 500 20 70 6 3 0.7 0.005 0.4 EDENTON, CHOWAN COUNTY, NORTH CAROLINA SOLUTIONS-IES PROJECT NUMBER 2016.0013.TEDE 2L Standard 120 WEST HICKS STREET TABLE 4 SUMMARY OF HISTORICAL GROUNDWATER ANALYTICAL RESULTS Analytical Method VOCs by Method 6200B TOWN OF EDENTON STREET DEPARTMENT INCIDENT # 12716 3/2/2016 <0.5 <0.5 <0.5 <1.5 12 <0.5 1 <0.5 <0.5 1.7 1.8 11/18/2015 <0.5 <0.5 <0.5 <1.5 17 <0.5 <1.0 <0.5 <0.5 <0.5 2.0 3/2/2016 <0.5 <0.5 <0.5 <1.5 <1.0 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 11/18/2015 <0.5 <0.5 <0.5 <1.5 16 <0.5 <1.0 <0.5 <0.5 <0.5 <0.066 5/7/2015 <0.5 <0.5 <0.5 <1.5 <0.5 <0.5 <1.0 <0.5 <0.5 <0.5 <0.5 2/7/2005 ND ND ND ND ND ND NA NA NA NA NA 7/19/2004 ND ND ND ND ND ND NA NA NA NA NA 1/15/2004 ND ND ND ND ND ND NA NA NA NA NA 7/28/2003 ND ND ND ND ND ND NA NA NA NA NA 7/11/2002 ND ND ND ND ND ND NA NA NA NA NA 6/29/1999 ND ND ND ND NA NA NA NA NA NA NA 2/26/1999 ND ND ND ND NA NA NA NA NA NA NA 5/14/1998 ND ND ND ND NA NA NA NA NA NA NA Notes: 1. Bolded cells indicate detected constituents; shaded cells exceed the NCAC 2L Groundwater Standards. 2. Compounds not listed were below the quantitation limit. 4. J - Estimated concentration between the method detection limit and the reporting limit. 5. ND - Not Detected 6. NA - Not Analyzed 7. ug/L = micrograms per liter 9. Prior to March 2015, the analytical method used was EPA Method 602. 3. Data before 5/1/2015 are from the Semi-Annual Monitoring Report dated April 7, 2005 prepared by Spangler Environmental, Inc. MW-4R 8. 2L Standard: 15A NCAC 2L Groundwater Standard MW-5 2 of 2 APPENDIX A GROUNDWATER SAMPLING LOGS APPENDIX B LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY RECORD Page 1 of 27 Page 2 of 27 Page 3 of 27 Page 4 of 27 Page 5 of 27 Page 6 of 27 Page 7 of 27 Page 8 of 27 Page 9 of 27 Page 10 of 27 Page 11 of 27 Page 12 of 27 Page 13 of 27 Page 14 of 27 Page 15 of 27 Page 16 of 27 Page 17 of 27 Page 18 of 27 Page 19 of 27 Page 20 of 27 Page 21 of 27 Page 22 of 27 Page 23 of 27 Page 24 of 27 Page 25 of 27 Page 26 of 27 Page 27 of 27