WA-1016_12613_CA_RPTS_20190110_MRP MANNKENDALL

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
January 10, 2019

Mr. Jeff Welti
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: December 2018 Ground Water Sampling and
Plume Stability Analysis
Phelps Amoco
US Highway 64 West
Creswell, Washington County
Incident No. 12613
GRI Project No. 2720

Dear Mr. Welti,

Geological Resources, Inc. (GRI) presents this information to complete the scope of work that was
requested and approved as Task Authorization 12613-30 for the above referenced site (Figure 1). These
activities were conducted in accordance with the North Carolina Department of Environmental Quality
(NCDEQ) correspondence dated January 3, 2018. Please find enclosed the applicable site location map,
site map and laboratory report for the above referenced site.

Ground water samples were collected from monitoring wells MW-14 and MW-21 on December 27, 2018.
The collected ground water samples were submitted for laboratory analyses of volatile organic
compounds using EPA Method 6200B. Concentrations of requested method constituents that exceeded
the Maximum Allowable Concentrations specified in T15A NCAC 2L.0202 were reported in the ground
water samples collected from MW-14 and MW-21. The concentration of benzene reported in the ground
water sample collected from MW-21 exceeded the Gross Contamination Level.

A Plume Stability Analysis using the GSI Mann-Kendall Toolkit was completed on January 10, 2019.
The results of the Plume Stability Analysis indicate that benzene concentrations are decreasing in MW-
14, while no trend is observed for MW-21.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or require
additional information.

Phelps Amoco
December 2018 Ground Water Sampling and
Plume Stability Analysis
Page 2 of 2

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

Sincerely,

Geological Resources, Inc.

William Regenthal, P. G.
Branch Operations Manager
Enclosures: Site Location Map, Site Map, GSI Mann-Kendall Toolkit Chart and Laboratory Report
cc: file
Evaluation Date:Job ID:
Facility Name:Constituent:
Conducted By:Concentration Units:ug/L
Sampling Point ID:MW-14 MW-21
Sampling Sampling
Event Date
1 11-Nov-08 5,400
2 2-Jun-09 14,300
3 8-Jun-11 FP 19,400
4 17-Nov-11 8,970
5 12-Jun-12 14,600 26,000
6 7-May-13 12,500 FP
7 3-Oct-13 13,500 26,500
8 11-Sep-14 7,030 22,800
9 1-Apr-15 8,340 26,900
10 11-Nov-15 1,750 24,800
11 18-Jul-16 2,920 30,800
12 7-Feb-17 1,370 32,700
13 2-May-17 225 30,400
14 31-Oct-17 1,310 9,680
15 27-Dec-18 194 28,200
16
17
18
19
20
Coefficient of Variation:0.83 0.25
Mann-Kendall Statistic (S):-61 17
Confidence Factor:>99.9%89.1%
Concentration Trend:Decreasing No Trend
Notes:
1.At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples.
2.Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
≥ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S≤0, and COV ≥ 1 = No Trend; < 90% and COV < 1 = Stable.
3.Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann-Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.gsi-net.com
BENZENE CONCENTRATION (ug/L)
10-Jan-19
Phelps Amoco Benzene
GSI MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
William Regenthal
12613
1
10
100
1000
10000
100000
02/08 07/09 11/10 04/12 08/13 12/14 05/16 09/17 02/19 06/20Concentration (ug/L)Sampling Date
MW-14
MW-21
01/04/19
Technical Report for
GRI (Geological Resources Inc.)
Former Phelps Amoco; Hwy 64 E, Creswell, NC
12613/2720
SGS Job Number: FA60518
Sampling Date: 12/27/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail]
ATTN: William Regenthall
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 01/04/19
e-Hardcopy 2.0
Automated Report
19
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 19
FA60518
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA60518-1: MW-14 ......................................................................................................6
3.2: FA60518-2: MW-21 ......................................................................................................8
Section 4: Misc. Forms ............................................................................................................10
4.1: Chain of Custody ...........................................................................................................11
Section 5: MS Volatiles - QC Data Summaries .....................................................................13
5.1: Method Blank Summary ................................................................................................14
5.2: Blank Spike Summary ...................................................................................................16
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................18 123452 of 19
FA60518
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA60518
Former Phelps Amoco; Hwy 64 E, Creswell, NC
Project No: 12613/2720
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA60518-1 12/27/18 10:50 JR 12/28/18 AQ Ground Water MW-14
FA60518-2 12/27/18 11:05 JR 12/28/18 AQ Ground Water MW-21
3 of 19
FA605181
Summary of Hits Page 1 of 1
Job Number:FA60518
Account:GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Collected:12/27/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA60518-1 MW-14
Benzene 194 2.5 0.63 ug/l SM 6200B
n-Butylbenzene 0.87 J 2.5 0.63 ug/l SM 6200B
o-Chlorotoluene 1.1 J 2.5 0.63 ug/l SM 6200B
Ethylbenzene 27.7 2.5 0.63 ug/l SM 6200B
Isopropylbenzene 1.6 J 2.5 0.63 ug/l SM 6200B
Methyl Chloride 2.0 J 2.5 1.0 ug/l SM 6200B
Methylene Chloride a 5.9 J 10 5.0 ug/l SM 6200B
Naphthalene 6.4 2.5 0.63 ug/l SM 6200B
n-Propylbenzene 3.5 2.5 0.63 ug/l SM 6200B
Toluene 76.9 2.5 0.63 ug/l SM 6200B
1,2,4-Trimethylbenzene 26.9 2.5 0.63 ug/l SM 6200B
1,3,5-Trimethylbenzene 8.8 2.5 0.63 ug/l SM 6200B
m,p-Xylene 77.1 5.0 0.63 ug/l SM 6200B
o-Xylene 24.8 2.5 0.63 ug/l SM 6200B
Xylene (total)102 7.5 1.3 ug/l SM 6200B
FA60518-2 MW-21
Benzene 28200 500 130 ug/l SM 6200B
1,2-Dichloroethane 157 J 500 130 ug/l SM 6200B
Ethylbenzene 1520 500 130 ug/l SM 6200B
Methylene Chloride a 1210 J 2000 1000 ug/l SM 6200B
Naphthalene 362 J 500 130 ug/l SM 6200B
Toluene 31600 500 130 ug/l SM 6200B
1,2,4-Trimethylbenzene 1180 500 130 ug/l SM 6200B
1,3,5-Trimethylbenzene 351 J 500 130 ug/l SM 6200B
m,p-Xylene 6490 1000 130 ug/l SM 6200B
o-Xylene 2530 500 130 ug/l SM 6200B
Xylene (total)9020 1500 250 ug/l SM 6200B
(a) Suspected laboratory contaminant.
4 of 19
FA605182
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
5 of 19
FA605183
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-14
Lab Sample ID:FA60518-1 Date Sampled:12/27/18
Matrix:AQ - Ground Water Date Received:12/28/18
Method:SM 6200B Percent Solids:n/a
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0216736.D 5 01/03/19 16:35 AB n/a n/a VA2516
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 194 2.5 0.63 ug/l
108-86-1 Bromobenzene ND 2.5 0.63 ug/l
74-97-5 Bromochloromethane ND 2.5 0.63 ug/l
75-27-4 Bromodichloromethane ND 2.5 0.63 ug/l
75-25-2 Bromoform ND 2.5 0.63 ug/l
104-51-8 n-Butylbenzene 0.87 2.5 0.63 ug/l J
135-98-8 sec-Butylbenzene ND 2.5 0.63 ug/l
98-06-6 tert-Butylbenzene ND 2.5 0.63 ug/l
56-23-5 Carbon Tetrachloride ND 2.5 0.63 ug/l
108-90-7 Chlorobenzene ND 2.5 0.63 ug/l
75-00-3 Chloroethane ND 2.5 1.0 ug/l
67-66-3 Chloroform ND 2.5 0.63 ug/l
95-49-8 o-Chlorotoluene 1.1 2.5 0.63 ug/l J
106-43-4 p-Chlorotoluene ND 2.5 0.63 ug/l
124-48-1 Dibromochloromethane ND 2.5 0.63 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 2.5 1.2 ug/l
106-93-4 1,2-Dibromoethane ND 2.5 0.63 ug/l
75-71-8 Dichlorodifluoromethane ND 2.5 1.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 2.5 0.63 ug/l
541-73-1 1,3-Dichlorobenzene ND 2.5 0.63 ug/l
106-46-7 1,4-Dichlorobenzene ND 2.5 0.63 ug/l
75-34-3 1,1-Dichloroethane ND 2.5 0.63 ug/l
107-06-2 1,2-Dichloroethane ND 2.5 0.63 ug/l
75-35-4 1,1-Dichloroethylene ND 2.5 0.63 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 2.5 0.63 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 2.5 0.63 ug/l
78-87-5 1,2-Dichloropropane ND 2.5 0.63 ug/l
142-28-9 1,3-Dichloropropane ND 2.5 0.63 ug/l
594-20-7 2,2-Dichloropropane ND 2.5 0.63 ug/l
563-58-6 1,1-Dichloropropene ND 2.5 0.63 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 2.5 0.63 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 2.5 0.63 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 19
FA6051833.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-14
Lab Sample ID:FA60518-1 Date Sampled:12/27/18
Matrix:AQ - Ground Water Date Received:12/28/18
Method:SM 6200B Percent Solids:n/a
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 2.5 0.63 ug/l
100-41-4 Ethylbenzene 27.7 2.5 0.63 ug/l
87-68-3 Hexachlorobutadiene ND 2.5 0.63 ug/l
98-82-8 Isopropylbenzene 1.6 2.5 0.63 ug/l J
99-87-6 p-Isopropyltoluene ND 2.5 0.63 ug/l
74-83-9 Methyl Bromide ND 2.5 1.0 ug/l
74-87-3 Methyl Chloride 2.0 2.5 1.0 ug/l J
74-95-3 Methylene Bromide ND 2.5 0.63 ug/l
75-09-2 Methylene Chloride a 5.9 10 5.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 2.5 0.63 ug/l
91-20-3 Naphthalene 6.4 2.5 0.63 ug/l
103-65-1 n-Propylbenzene 3.5 2.5 0.63 ug/l
100-42-5 Styrene ND 2.5 0.63 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 2.5 0.63 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 2.5 0.63 ug/l
127-18-4 Tetrachloroethylene ND 2.5 0.63 ug/l
108-88-3 Toluene 76.9 2.5 0.63 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 2.5 0.63 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.5 0.63 ug/l
71-55-6 1,1,1-Trichloroethane ND 2.5 0.63 ug/l
79-00-5 1,1,2-Trichloroethane ND 2.5 0.63 ug/l
79-01-6 Trichloroethylene ND 2.5 0.63 ug/l
75-69-4 Trichlorofluoromethane ND 2.5 1.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.5 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene 26.9 2.5 0.63 ug/l
108-67-8 1,3,5-Trimethylbenzene 8.8 2.5 0.63 ug/l
75-01-4 Vinyl Chloride ND 2.5 0.63 ug/l
m,p-Xylene 77.1 5.0 0.63 ug/l
95-47-6 o-Xylene 24.8 2.5 0.63 ug/l
1330-20-7 Xylene (total)102 7.5 1.3 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
(a) Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 19
FA6051833.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-21
Lab Sample ID:FA60518-2 Date Sampled:12/27/18
Matrix:AQ - Ground Water Date Received:12/28/18
Method:SM 6200B Percent Solids:n/a
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0216737.D 1000 01/03/19 16:57 AB n/a n/a VA2516
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 28200 500 130 ug/l
108-86-1 Bromobenzene ND 500 130 ug/l
74-97-5 Bromochloromethane ND 500 130 ug/l
75-27-4 Bromodichloromethane ND 500 130 ug/l
75-25-2 Bromoform ND 500 130 ug/l
104-51-8 n-Butylbenzene ND 500 130 ug/l
135-98-8 sec-Butylbenzene ND 500 130 ug/l
98-06-6 tert-Butylbenzene ND 500 130 ug/l
56-23-5 Carbon Tetrachloride ND 500 130 ug/l
108-90-7 Chlorobenzene ND 500 130 ug/l
75-00-3 Chloroethane ND 500 200 ug/l
67-66-3 Chloroform ND 500 130 ug/l
95-49-8 o-Chlorotoluene ND 500 130 ug/l
106-43-4 p-Chlorotoluene ND 500 130 ug/l
124-48-1 Dibromochloromethane ND 500 130 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 500 250 ug/l
106-93-4 1,2-Dibromoethane ND 500 130 ug/l
75-71-8 Dichlorodifluoromethane ND 500 200 ug/l
95-50-1 1,2-Dichlorobenzene ND 500 130 ug/l
541-73-1 1,3-Dichlorobenzene ND 500 130 ug/l
106-46-7 1,4-Dichlorobenzene ND 500 130 ug/l
75-34-3 1,1-Dichloroethane ND 500 130 ug/l
107-06-2 1,2-Dichloroethane 157 500 130 ug/l J
75-35-4 1,1-Dichloroethylene ND 500 130 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 500 130 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 500 130 ug/l
78-87-5 1,2-Dichloropropane ND 500 130 ug/l
142-28-9 1,3-Dichloropropane ND 500 130 ug/l
594-20-7 2,2-Dichloropropane ND 500 130 ug/l
563-58-6 1,1-Dichloropropene ND 500 130 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 500 130 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 500 130 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 19
FA6051833.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-21
Lab Sample ID:FA60518-2 Date Sampled:12/27/18
Matrix:AQ - Ground Water Date Received:12/28/18
Method:SM 6200B Percent Solids:n/a
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 500 130 ug/l
100-41-4 Ethylbenzene 1520 500 130 ug/l
87-68-3 Hexachlorobutadiene ND 500 130 ug/l
98-82-8 Isopropylbenzene ND 500 130 ug/l
99-87-6 p-Isopropyltoluene ND 500 130 ug/l
74-83-9 Methyl Bromide ND 500 200 ug/l
74-87-3 Methyl Chloride ND 500 200 ug/l
74-95-3 Methylene Bromide ND 500 130 ug/l
75-09-2 Methylene Chloride a 1210 2000 1000 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 500 130 ug/l
91-20-3 Naphthalene 362 500 130 ug/l J
103-65-1 n-Propylbenzene ND 500 130 ug/l
100-42-5 Styrene ND 500 130 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 500 130 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 500 130 ug/l
127-18-4 Tetrachloroethylene ND 500 130 ug/l
108-88-3 Toluene 31600 500 130 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 500 130 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 500 130 ug/l
71-55-6 1,1,1-Trichloroethane ND 500 130 ug/l
79-00-5 1,1,2-Trichloroethane ND 500 130 ug/l
79-01-6 Trichloroethylene ND 500 130 ug/l
75-69-4 Trichlorofluoromethane ND 500 200 ug/l
96-18-4 1,2,3-Trichloropropane ND 500 130 ug/l
95-63-6 1,2,4-Trimethylbenzene 1180 500 130 ug/l
108-67-8 1,3,5-Trimethylbenzene 351 500 130 ug/l J
75-01-4 Vinyl Chloride ND 500 130 ug/l
m,p-Xylene 6490 1000 130 ug/l
95-47-6 o-Xylene 2530 500 130 ug/l
1330-20-7 Xylene (total)9020 1500 250 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
2037-26-5 Toluene-D8 104%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
(a) Suspected laboratory contaminant.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 19
FA6051833.2
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
10 of 19
FA605184
FA60518: Chain of Custody
Page 1 of 2
11 of 19
FA6051844.1
Job Number:FA60518 Client:GRI
Date / Time Received:12/28/2018 9:30:00 AM Delivery Method:FED EX
Project:PHRLPS AMOCO
Airbill #'s:1015899974060003281100812565571930
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (4.0);
Cooler 1: (3.8);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-0.2; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:SHAYLAP Date:Date:12/28/2018 9:30:00 A
FA60518: Chain of Custody
Page 2 of 2
12 of 19
FA6051844.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
13 of 19
FA605185
Method Blank Summary Page 1 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2516-MB A0216722.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
14 of 19
FA6051855.1.1
Method Blank Summary Page 2 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2516-MB A0216722.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 103%70-130%
15 of 19
FA6051855.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2516-BS A0216720.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.3 103 70-130
108-86-1 Bromobenzene 10 10.0 100 70-130
74-97-5 Bromochloromethane 10 9.0 90 70-130
75-27-4 Bromodichloromethane 10 10.6 106 70-130
75-25-2 Bromoform 10 9.7 97 70-130
104-51-8 n-Butylbenzene 10 10 100 70-130
135-98-8 sec-Butylbenzene 10 9.9 99 70-130
98-06-6 tert-Butylbenzene 10 9.4 94 70-130
56-23-5 Carbon Tetrachloride 10 11.3 113 70-130
108-90-7 Chlorobenzene 10 10.0 100 70-130
75-00-3 Chloroethane 10 8.1 81 60-140
67-66-3 Chloroform 10 10.3 103 70-130
95-49-8 o-Chlorotoluene 10 10.2 102 70-130
106-43-4 p-Chlorotoluene 10 10.3 103 70-130
124-48-1 Dibromochloromethane 10 10.3 103 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.9 89 70-130
106-93-4 1,2-Dibromoethane 10 10.1 101 70-130
75-71-8 Dichlorodifluoromethane 10 9.3 93 60-140
95-50-1 1,2-Dichlorobenzene 10 9.8 98 70-130
541-73-1 1,3-Dichlorobenzene 10 10.3 103 70-130
106-46-7 1,4-Dichlorobenzene 10 9.9 99 70-130
75-34-3 1,1-Dichloroethane 10 10.6 106 70-130
107-06-2 1,2-Dichloroethane 10 9.9 99 70-130
75-35-4 1,1-Dichloroethylene 10 10.8 108 70-130
156-59-2 cis-1,2-Dichloroethylene 10 10.0 100 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.5 105 70-130
78-87-5 1,2-Dichloropropane 10 10.5 105 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
594-20-7 2,2-Dichloropropane 10 10.7 107 70-130
563-58-6 1,1-Dichloropropene 10 10.8 108 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.8 98 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.9 99 70-130
108-20-3 Di-Isopropyl Ether 10 9.0 90 70-130
100-41-4 Ethylbenzene 10 10.2 102 70-130
87-68-3 Hexachlorobutadiene 10 10.2 102 70-130
98-82-8 Isopropylbenzene 10 11.0 110 70-130
* = Outside of Control Limits.
16 of 19
FA6051855.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2516-BS A0216720.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 9.9 99 70-130
74-83-9 Methyl Bromide 10 7.0 70 60-140
74-87-3 Methyl Chloride 10 10.0 100 60-140
74-95-3 Methylene Bromide 10 10.3 103 70-130
75-09-2 Methylene Chloride 10 9.6 96 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.7 87 70-130
91-20-3 Naphthalene 10 9.2 92 70-130
103-65-1 n-Propylbenzene 10 10.4 104 70-130
100-42-5 Styrene 10 9.7 97 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.0 100 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.1 101 70-130
127-18-4 Tetrachloroethylene 10 10.6 106 70-130
108-88-3 Toluene 10 9.9 99 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.7 97 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.3 93 70-130
71-55-6 1,1,1-Trichloroethane 10 10.4 104 70-130
79-00-5 1,1,2-Trichloroethane 10 10 100 70-130
79-01-6 Trichloroethylene 10 10.4 104 70-130
75-69-4 Trichlorofluoromethane 10 9.5 95 60-140
96-18-4 1,2,3-Trichloropropane 10 9.8 98 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.2 92 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.4 94 70-130
75-01-4 Vinyl Chloride 10 8.9 89 60-140
m,p-Xylene 20 20.8 104 70-130
95-47-6 o-Xylene 10 10.1 101 70-130
1330-20-7 Xylene (total)30 30.9 103 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
17 of 19
FA6051855.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA60512-4MS A0216731.D 5 01/03/19 AB n/a n/a VA2516
FA60512-4MSD A0216732.D 5 01/03/19 AB n/a n/a VA2516
FA60512-4 A0216723.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
FA60512-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene ND 50 52.8 106 50 53.8 108 2 70-130/20
108-86-1 Bromobenzene ND 50 50.1 100 50 51.9 104 4 70-130/20
74-97-5 Bromochloromethane ND 50 46.2 92 50 47.3 95 2 70-130/20
75-27-4 Bromodichloromethane ND 50 48.8 98 50 50.1 100 3 70-130/20
75-25-2 Bromoform ND 50 32.8 66*50 34.9 70 6 70-130/20
104-51-8 n-Butylbenzene ND 50 50.4 101 50 52.0 104 3 70-130/20
135-98-8 sec-Butylbenzene ND 50 50.7 101 50 52.3 105 3 70-130/20
98-06-6 tert-Butylbenzene ND 50 48.2 96 50 49.4 99 2 70-130/20
56-23-5 Carbon Tetrachloride ND 50 55.4 111 50 57.3 115 3 70-130/20
108-90-7 Chlorobenzene ND 50 50.6 101 50 52.4 105 3 70-130/20
75-00-3 Chloroethane ND 50 64.8 130 50 54.2 108 18 60-140/20
67-66-3 Chloroform ND 50 54.0 108 50 55.2 110 2 70-130/20
95-49-8 o-Chlorotoluene ND 50 52.9 106 50 54.4 109 3 70-130/20
106-43-4 p-Chlorotoluene ND 50 51.7 103 50 53.7 107 4 70-130/20
124-48-1 Dibromochloromethane ND 50 40.5 81 50 42.7 85 5 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 50 43.3 87 50 43.7 87 1 70-130/20
106-93-4 1,2-Dibromoethane ND 50 46.8 94 50 49.3 99 5 70-130/20
75-71-8 Dichlorodifluoromethane ND 50 65.4 131 50 57.5 115 13 60-140/20
95-50-1 1,2-Dichlorobenzene ND 50 50.2 100 50 51.5 103 3 70-130/20
541-73-1 1,3-Dichlorobenzene ND 50 52.5 105 50 53.7 107 2 70-130/20
106-46-7 1,4-Dichlorobenzene ND 50 50.1 100 50 51.7 103 3 70-130/20
75-34-3 1,1-Dichloroethane ND 50 54.6 109 50 56.6 113 4 70-130/20
107-06-2 1,2-Dichloroethane ND 50 50.2 100 50 51.1 102 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 50 56.2 112 50 57.8 116 3 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 50 51.9 104 50 53.7 107 3 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 50 54.3 109 50 56.2 112 3 70-130/20
78-87-5 1,2-Dichloropropane ND 50 52.0 104 50 54.2 108 4 70-130/20
142-28-9 1,3-Dichloropropane ND 50 46.4 93 50 48.0 96 3 70-130/20
594-20-7 2,2-Dichloropropane ND 50 56.9 114 50 59.5 119 4 70-130/20
563-58-6 1,1-Dichloropropene ND 50 55.2 110 50 56.9 114 3 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 50 42.3 85 50 43.1 86 2 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 50 43.4 87 50 45.5 91 5 70-130/20
108-20-3 Di-Isopropyl Ether ND 50 46.7 93 50 48.4 97 4 70-130/20
100-41-4 Ethylbenzene ND 50 52.4 105 50 54.2 108 3 70-130/20
87-68-3 Hexachlorobutadiene ND 50 50.8 102 50 52.1 104 3 70-130/20
98-82-8 Isopropylbenzene ND 50 56.1 112 50 58.0 116 3 70-130/20
* = Outside of Control Limits.
18 of 19
FA6051855.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA60518
Account:GRINCC GRI (Geological Resources Inc.)
Project:Former Phelps Amoco; Hwy 64 E, Creswell, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA60512-4MS A0216731.D 5 01/03/19 AB n/a n/a VA2516
FA60512-4MSD A0216732.D 5 01/03/19 AB n/a n/a VA2516
FA60512-4 A0216723.D 1 01/03/19 AB n/a n/a VA2516
The QC reported here applies to the following samples:Method: SM 6200B
FA60518-1, FA60518-2
FA60512-4 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 50 50.8 102 50 52.1 104 3 70-130/20
74-83-9 Methyl Bromide ND 50 52.6 105 50 46.1 92 13 60-140/20
74-87-3 Methyl Chloride ND 50 69.0 138 50 60.8 122 13 60-140/20
74-95-3 Methylene Bromide ND 50 51.6 103 50 52.1 104 1 70-130/20
75-09-2 Methylene Chloride ND 50 55.6 111 50 57.2 114 3 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 50 44.3 89 50 46.2 92 4 70-130/20
91-20-3 Naphthalene ND 50 44.8 90 50 47.1 94 5 70-130/20
103-65-1 n-Propylbenzene ND 50 53.1 106 50 55.3 111 4 70-130/20
100-42-5 Styrene ND 50 46.4 93 50 48.3 97 4 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 50 51.7 103 50 53.2 106 3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 50 51.2 102 50 53.1 106 4 70-130/20
127-18-4 Tetrachloroethylene ND 50 52.3 105 50 54.4 109 4 70-130/20
108-88-3 Toluene 0.17 J 50 50.9 101 50 52.5 105 3 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 50 48.8 98 50 51.0 102 4 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 50 46.9 94 50 48.9 98 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 50 53.7 107 50 55.8 112 4 70-130/20
79-00-5 1,1,2-Trichloroethane ND 50 49.6 99 50 51.2 102 3 70-130/20
79-01-6 Trichloroethylene ND 50 51.8 104 50 53.1 106 2 70-130/20
75-69-4 Trichlorofluoromethane ND 50 68.4 137 50 59.8 120 13 60-140/20
96-18-4 1,2,3-Trichloropropane ND 50 48.5 97 50 50.1 100 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 50 47.1 94 50 48.8 98 4 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 50 48.6 97 50 50.1 100 3 70-130/20
75-01-4 Vinyl Chloride ND 50 66.9 134 50 58.7 117 13 60-140/20
m,p-Xylene ND 100 106 106 100 109 109 3 70-130/20
95-47-6 o-Xylene ND 50 52.0 104 50 54.1 108 4 70-130/20
1330-20-7 Xylene (total)ND 150 158 105 150 163 109 3 70-130/20
CAS No.Surrogate Recoveries MS MSD FA60512-4 Limits
1868-53-7 Dibromofluoromethane 103%103%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%103%101%70-130%
2037-26-5 Toluene-D8 98%98%97%70-130%
460-00-4 4-Bromofluorobenzene 99%100%101%70-130%
* = Outside of Control Limits.
19 of 19
FA6051855.3.1