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HomeMy WebLinkAboutWA-1010_12511_CA_RPTS_20180112_MRP  January 11, 2018 Danny S. Pender 603 Foxwood Drive Goldsboro, NC 27530-8461 Reference: Groundwater Monitoring Report BP Service Center 4673 US Highway 117 North Pikeville, Wayne County, North Carolina 27863 Incident #12511; Facility ID #0-006989 Risk Classification: High Dear Mr. Pender: Please find enclosed a report summarizing groundwater monitoring activities conducted at the above referenced facility. Previous assessment activities at this site revealed a release of petroleum in groundwater in the vicinity of the former location of a gasoline UST and dispenser island. Ten on and off site monitor wells and two local supply/irrigation wells were sampled in November, 2017 to evaluate the site for the presence of dissolved gasoline constituents. Other activities included installation of nutrient socks in on-site and off-site monitoring wells to accelerate natural processes. The findings of this investigation are summarized herein. Mr. Pender, if you have questions regarding this report please contact my office. Sincerely, Henry Nemargut, P.E. Henry Nemargut Engineering Services   GROUNDWATER MONITORING REPORT BP SERVICE CENTER 4673 US HIGHWAY 117 NORTH, PIKEVILLE, WAYNE COUNTY, NC 27863 GROUNDWATER INCIDENT #: 12511 FACILITY ID #: 0-006989 JANUARY 11, 2018 UST OWNER/OPERATOR: MARY P. PENDER (DECEASED) PROPERTY OWNER: DANNY S. PENDER 603 FOXWOOD DRIVE, GOLDSBORO, NC 27530-8461 PHONE NUMBER: (919) 735-6066 CONSULTANT: HENRY NEMARGUT ENGINEERING SERVICES 2211 CHESTNUT STREET, WILMINGTON, NC 28405 PHONE NUMBER: (910) 762-5475 RELEASE INFORMATION: DATE DISCOVERED: 12/27/93 ESTIMATED QUANTITY OF RELEASE: UNKNOWN CAUSE OF RELEASE: UNKNOWN SOURCE OF RELEASE: UST SYSTEM SIZE AND CONTENTS: (1) 3,000 GALLON GASOLINE LATITUDE: N 35o 29'17"; LONGITUDE: W 77o 58’55” The Monitoring Report for this site has been prepared by Henry Nemargut Engineering Services. All engineering work performed on this project was conducted under my direct supervision: Henry Nemargut, P.E. Henry Nemargut Engineering Services North Carolina License #17669 TABLE OF CONTENTS Section Page 1.0 Introduction and Background 1.1 Introduction 1 1.2 Scope of Services 1 2.0 Field Activities 2 2.1 Groundwater Flow Direction and Gradient 2 2.2 Monitor Well Sampling and Analysis 2 2.3 Supply Well Sampling and Analysis 3 2.4 Plume Development 4 3.0 Conclusions and Recommendations 3.1 General Summary 5 3.2 Recommendations 5 3.3 Limitations 6 LIST OF FIGURES Figure 1: Project Location Figure 2: Receptor Map & Monitor Well Location Map Figure 3: Potentiometric Surface Map 11/2/17) Figure 4: Benzene Iso-Concentration Map Figure 5: Total BTEX Iso-Concentration Map Figure 6: Naphthalene Iso-Concentration Map Figure 7: MTBE Iso-Concentration Map LIST OF TABLES Table 1: Monitoring Well Information and Groundwater Elevations Table 2: Summary of Groundwater Laboratory Analytical Results Table 3: Total BTEX vs. Time Table 4: Historical Water Analytical Summary Table 5: Supply Well Information APPENDICES Appendix A: Groundwater Laboratory Analytical Results Page - 1 GROUNDWATER MONITORING REPORT BP SERVICE CENTER 4673 US HIGHWAY 117 NORTH PIKEVILLE, NORTH CAROLINA 27863 1.0 Introduction and Background 1.1 Introduction Danny S. Pender is the property owner of a site which was formerly operated as the BP Service Center facility located at 4673 US Highway 117 North in Pikeville, North Carolina. Figure 1 illustrates the location of this facility on the Pikeville Quadrangle U.S.G.S. Topo Map. This facility contains one permanent structure which is used as a gasoline convenience store but is currently vacant. The site formerly contained (1) 3,000 gallon gasoline UST which was removed from this facility on December 27, 1993. A release was noted from this UST during closure activities. Assessment activities including a LSA report, CSA activities conducted in 1994, and installation of additional monitoring wells have been conducted at this site through 2010. Most recently, secondary sources (contaminated soil) were removed from the site in the former pump island area in October, 2012. Figure 2 illustrates the layout of this site, the UST locations, and the monitor well locations. The NCDEQ recently issued an NORR requesting that the following tasks be conducted at this site prior to proceeding with development of a Corrective Action Plan for this facility: • Sample (10) existing wells and (2) area supply wells • Install nutrient socks in wells formerly containing 2L violations • Submit a groundwater monitoring report This report contains findings reached following conducting these requested activities at 4673 US Highway 117 North in Pikeville, NC. 1.2 Scope of Services This Groundwater monitoring report contains documentation concerning the following activities which have been conducted at this facility: o A monitoring well sampling event conducted on November 2, 2017, consisting of sampling of 10 monitoring wells installed in conjunction with the on-site release and sampling of 2 nearby water supply wells. o Laboratory analyses of groundwater samples conducted by Pace Analytical, Inc. of Huntersville, NC o Estimation of the approximate groundwater flow direction and hydraulic gradient at the site. Page - 2 o Isoconcentration maps illustrating the current contaminant levels in the monitoring wells at the facility. 2.0 Field Activities 2.1 Ground Water Flow Direction and Gradient In order to estimate the groundwater flow direction in the vicinity of the petroleum release, elevations of the monitor well casings were measured using surveying equipment. Static water levels were obtained from each of the wells and the data was used to compute a potentiometric surface map which is included as Figure 3. Groundwater data and monitoring well information, which are summarized in Table 1, were also used to estimate the hydraulic gradient at the project site. Using the horizontal distance between the monitor wells and the static water levels, the groundwater was estimated to be flowing in both a southwest direction with a horizontal hydraulic gradient of approximately 0.0144 ft/ft and a northwest direction with a gradient of 0.003 ft/ft. These apparent flow directions result from apparent remedial pit excavation groundwater mounding as was noted on November 2, 2017. 2.2 Monitor Well Sampling and Analyses On November 2, 2017, ten on-site and off-site monitor wells were sampled for analyses utilizing EPA Methods 6200B plus MTBE, IPE, & EDB. Before sampling, the monitor wells were purged by removing a minimum of three well volumes to ensure that the samples were representative of the actual groundwater conditions. The monitor wells were developed using disposable plastic balers suspended with unused nylon string. Following development of the groundwater monitoring wells, samples were obtained from the disposable balers. All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler, chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory utilizing EPA approved chain-of-custody procedures. Laboratory analytical results indicate the presence of 6 compounds above the current listed 2L Standards in the monitor well network at this site. Total BTEX was detected at a maximum level of 1,060 ug/l in well MW-7. Benzene was detected at a maximum concentration of 110 ug/l in MW-7, above its 2L standard of 1 ug/l but below its GCL of 5,000 ug/l. No GCL violations were noted at the site. Naphthalene was detected at a maximum concentration of 130 ug/l in monitoring well MW-7, and MTBE was noted at a maximum level of 420 ug/l in well MW-18 above its 2L Standard of 20 ug/l. Table 2 summarizes the laboratory analytical results, and Appendix A contains a copy of the laboratory analytical report and chain of custody records. Figure 4 contains a benzene iso-concentration map, Figure 5 illustrates the estimated Total BTEX concentration map, Figure 6 illustrates the naphthalene isoconcentration for the site, and Figure 7 illustrates the MTBE isoconcentrations. Page - 3 2.3 Supply Well Sampling and Analyses On November 2, 2017, two off-site area supply wells were sampled for analyses utilizing EPA Methods 6200B plus MTBE, IPE, & EDB. Before sampling, the supply wells were purged by pumping from the wells for approximately 10 minutes to ensure that the samples were representative of the actual groundwater conditions. After pumping, the flowrate was reduced for collection of samples. Samples were obtained from spigots closest to the various supply wells. The two supply wells sampled included: IW-3 (Incorrectly labeled SW4), owned by Mattie Artis, used for irrigation purposes and SW-8, owned by David Daw, used as a water source at JuDee’s Hair & Body. Supply well SW-1 formerly operated by the NC State Historic Mechanics Shop is no longer in service since this tenant has vacated the property. Additionally, supply well SW-4 is no longer in service since Morris Reed has connected his residence to municipal water supply. All samples were placed in laboratory supplied glassware, labeled with sample location, analysis to be performed, time, date and sampler's name. The sample jars were then immediately placed in a cooler, chilled with ice to approximately 4oC in preparation of transportation to an analytical laboratory utilizing EPA approved chain-of-custody procedures. Laboratory analytical results failed to indicate the presence of any compounds above laboratory detection limits in either supply well sampled. Table 2 summarizes the laboratory analytical results, and Appendix A contains a copy of the laboratory analytical report and chain of custody records. Table 5 summarizes supply well owner information 2.4 Plume Development In prior sampling events conducted at the site, contaminants have been reported above 2L Standards in on-site and off-site monitoring wells and in off-site water supply wells. The Travis Thigpen well (SW- 1) is no longer in operation since the tenant vacated the property. The contaminant concentrations in well MW-18 downgradient of the source area had continually decreased since the initial sampling event conducted on April 18, 2013, most likely due to soil remediation; however, the latest 3 sampling events indicate an increase in the MW-18 BTEX level. Total BTEX concentrations in groundwater in the pump island source area, previously above its GCL for benzene, have remained below detection limits in MW-8A as a result of soil remediation. The groundwater flow direction has remained towards both the southwest and southeast during the November 2, 2017 sampling event. This flow direction is apparently due to significant groundwater mounding the dispenser island remedial excavation area in which gravely backfill was used within a predominantly clay-rich native soil site. Seasonal BTEX increases in the southeast direction towards MW-7 and MW-2 were noted during the November 2, 2017 sampling event. In general, contaminant concentrations appear to be reducing at site in all wells except for the recent spikes noted in downgradient directions. Historical analytical laboratory data are summarized in detail on Table 3 and Table 4. Installation of nutrient socks in monitoring wells MW-1, MW-2, MW-3, MW-7, MW-9, MW- 14, MW-12, MW-16, MW-17 & MW-18 should accelerate natural processes in these areas. Page - 4 4.0 Conclusions and Recommendations 4.1 General Summary A groundwater monitoring sampling event has been conducted at the BP Service Center facility located at 4673 US Highway 117 North in Pikeville, NC. From a review of all information gathered during this remediation project, Henry Nemargut Engineering Services makes the following conclusions: o 6 petroleum compounds were detected in on and off site monitoring wells above 2L Standards during the November, 2017 sampling event. Total BTEX was detected at a maximum level of 1,060 ug/l in well MW-7. Benzene was detected at a maximum concentration of 110 ug/l in MW-7, above its 2L standard of 1 ug/l but below its GCL of 5,000 ug/l. No GCL violations were noted at the site. Naphthalene was detected at a maximum concentration of 130 ug/l in monitoring well MW-7, and MTBE was noted at a maximum level of 420 ug/l in well MW-18 above its 2L Standard of 20 ug/l. o Two nearby in-use water supply wells were sampled, indicating no petroleum contamination. The two supply wells sampled included: IW-3 (incorrectly labeled SW4), owned by Mattie Artis, used for irrigation purposes, and SW-8, owned by David Daw, used as a water source at JuDee’s Hair & Body. o The groundwater flow direction remains towards both the southwest and southeast during the November 2, 2017 sampling event. This shift in the flow direction is apparently due to significant groundwater mounding the dispenser island remedial excavation area in which gravely backfill was used within a predominantly clay-rich native soil site. o Seasonal BTEX increases in the southeast direction towards MW-7 and MW-2 were noted during the November 2, 2017 sampling event. In general, contaminant concentrations appear to be reducing at site in all wells except for the recent spikes noted in downgradient directions. o Nutrient socks were installed in monitoring wells MW-1, MW-2, MW-3, MW-7, MW-9, MW- 14, MW-12, MW-16, MW-17 & MW-18. Installation of these socks should accelerate natural processes in these areas. 4.2 Recommendations Based on information obtained during this sampling event, Henry Nemargut Engineering Services makes the following recommendations for this site: o Semi-annual monitoring should be continued at this site. o Nutrient socks should be replaced on a semi-annual basis at this site. A copy of this monitoring report has been forwarded to: Page - 5 Carrie Stone NCDEQ-WaRO UST Section 943 Washington Square Mall Washington, NC 27889 4.3 Limitations This report has been prepared for the exclusive use of Danny S. Pender for the specific application to the referenced site located in Wayne County, North Carolina. The assessment was conducted based on the scope of work and level of effort desired by the client. Our findings have been developed in accordance with generally accepted standards in the practice of Groundwater Monitoring in the State of North Carolina, available information and our professional judgment. No other warranty is expressed or implied. The data presented in this report are indicative of conditions that existed at the precise locations sampled and at the time the samples were collected. Additionally, the data obtained from the samples would be interpreted as meaningful with respect to the parameters indicated in the laboratory reports. No additional information can be logically inferred from this data. FIGURES Center: 35.4876°N 77.981°W Elevation at center: 131 feet (40 meters) Quad: USGS Northeast Goldsboro Drg Name: o35077d8 Drg Source Scale: 1:24,000 TABLES TABLE 1Monitoring Well Information and Groundwater ElevationsBP Service Center4673 US Hwy 117 North, Goldsboro, NCWell Number Top of Casing Elevation Top of Screen Elevation Bottom of Screen Elevation Depth to Water Groundwater ElevationMW-1 98.12 93.12 78.12 5.94 92.18MW-2 98.49 93.49 78.49 3.67 94.82MW-3 100.00 95.00 80.00 4.67 95.33MW-4 99.95 94.95 79.95 n/a #VALUE!MW-5 98.06 93.06 78.06 n/a #VALUE!MW-6 98.68 93.68 78.68 n/a #VALUE!MW-7 96.74 91.74 76.74 1.83 94.91MW-8A 97.66 95.16 80.16 n/a #VALUE!MW-9 96.73 94.23 76.73 1.45 95.28MW-10 95.68 93.18 75.68 n/a #VALUE!MW-11 96.84 94.34 77.84 n/a #VALUE!MW-12 97.98 95.48 77.98 5.82 92.16MW-13 98.68 96.18 78.18 n/a #VALUE!MW-14 98.90 96.40 78.40 6.78 92.12MW-15 98.44 95.44 78.44 n/a #VALUE!MW-16 97.62 94.62 77.62 5.64 91.98MW-17 97.33 92.33 77.33 5.21 92.12MW-18 97.99 95.49 70.49 2.88 95.11VEW-198.0958.0948.09n/a#VALUE!All measurements taken in feet and based on an arbitrary benchmark of 100.00 feet at MW-3Groundwater levels measured on 11/2/17BP Service Constituent MW-1 MW-2 MW-3 MW-7 GCL 2L Standard Date 11/2/17 11/2/17 11/2/17 11/2/17 Method 6210D (ug/L) Benzene 22 29 4.2 110 5,000 1 Toluene BDL 8.8 6.9 BDL 260,000 600 Ethylbenzene 11 9.3 5.1 400 84,500 600 Xylenes (total) BDL 6.5 0.8 550 85,500 500 BTEX (total) 33 53.6 17 1060 NSE NSE p-Isopropyltoluene BDL BDL BDL BDL NSE NSE Isopropylbenzene 4.1 5.3 9.8 60 25,000 70 Chloromethane BDL BDL BDL BDL 3,000 3 Naphthalene 12 17 11 130 6,000 6 n-propylbenzene 6 4.8 6.2 110 30,000 70 n-butylbenzene BDL 0.89 BDL 8.1 6,900 70 sec-Butylbenzene 0.88 BDL 3.5 7.6 15,000 70 tert-Butylbenzene BDL BDL BDL BDL 15,000 70 Acetone BDL 8.3 BDL BDL 6,000,000 6,000 MTBE 280 32 2.5 BDL 20,000 20 1,2-Dichloroethane 2.5 1.6 4 BDL 400 0.4 Isopropyl Ether (IPE) 3 BDL BDL BDL 70,000 70 trans-1,2-Dichloroethene BDL BDL BDL BDL 100,000 100 1,2,4-Trimethylbenzene 0.76 BDL BDL 620 28,500 400 1,3,5-Trimethylbenzene BDL BDL BDL 190 25,000 400 Lead (3030C) N/A N/A N/A N/A 15,000 15 Aliphatic Fraction Classes (ug/L) C5-C8 Volatile Aliphatics N/A N/A N/A N/A NSE 420 C9-C12 Volatile Aliphatics N/A N/A N/A N/A NSE NSE C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE 4,200 C9-C18 Aliphatics (total) N/A N/A N/A N/A NSE 4,200 C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 42,000 Aromatic Fraction Classes (ug/L) C9-C10 Volatile Aromatics N/A N/A N/A N/A NSE NSE C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE C9-C22 Aromatics (total)N/A N/A N/A N/A NSE 210 N/A = Not Analyzed BDL = Below Detection Limits NSE = No Standard Established TABLE 2 SUMMARY OF GROUNDWATER ANALYTICAL RESULTS BP SERVICE CENTER 4673 US HWY 117 NORTH, GOLDSBORO, NC Constituent MW-9 MW-12 MW-14 MW-16 GCL 2L Standard Date 11/2/17 11/2/17 11/2/17 11/2/17 Method 6210D (ug/L) Benzene 3 0.59 BDL BDL 5,000 1 Toluene 2 BDL BDL BDL 260,000 600 Ethylbenzene BDL BDL 3.2 BDL 84,500 600 Xylenes (total) BDL BDL BDL BDL 85,500 500 BTEX (total) 5 0.59 3.2 0 NSE NSE p-Isopropyltoluene BDL BDL 0.62 BDL NSE NSE Isopropylbenzene BDL 0.8 2.1 2 25,000 70 Methylene Chloride BDL BDL BDL BDL 5,000 5 Naphthalene BDL BDL 11 31 6,000 6 n-propylbenzene BDL BDL 3.4 1.6 30,000 70 n-butylbenzene BDL BDL 0.9 1.1 6,900 70 sec-Butylbenzene BDL BDL 1.5 BDL 15,000 70 tert-Butylbenzene BDL BDL 0.55 BDL 15,000 70 MTBE 0.62 10 BDL BDL 20,000 20 1,2-Dichloroethane 2.2 1.6 BDL BDL 400 0.4 Acetone BDL BDL 5.6 BDL 6,000,000 6000 Isopropyl Ether (IPE) 0.61 0.55 BDL BDL 70,000 70 trans-1,2-Dichloroethene BDL BDL BDL BDL 100,000 100 1,2,4-Trimethylbenzene BDL BDL 6.1 BDL 28,500 400 1,3,5-Trimethylbenzene BDL BDL BDL BDL 25,000 400 Lead (3030C) N/A N/A N/A N/A 15,000 15 Aliphatic Fraction Classes (ug/L) C5-C8 Volatile Aliphatics N/A N/A N/A N/A NSE 420 C9-C12 Volatile Aliphatics N/A N/A N/A N/A NSE NSE C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE 4,200 C9-C18 Aliphatics (total) N/A N/A N/A N/A NSE 4,200 C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 42,000 Aromatic Fraction Classes (ug/L) C9-C10 Volatile Aromatics N/A N/A N/A N/A NSE NSE C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE C9-C22 Aromatics (total)N/A N/A N/A N/A NSE 210 N/A = Not Analyzed BDL = Below Detection Limits NSE = No Standard Established TABLE 2 (Continued) SUMMARY OF GROUNDWATER ANALYTICAL RESULTS BP SERVICE CENTER 4673 US HWY 117 NORTH, GOLDSBORO, NC Constituent MW-17 MW-18 SW4 SW8 GCL 2L Standard Date 11/2/17 11/2/17 11/2/17 11/2/17 Method 6210D (ug/L) Benzene BDL 59 BDL BDL 5,000 1 Toluene BDL 0.53 BDL BDL 260,000 600 Ethylbenzene BDL 39 BDL BDL 84,500 600 Xylenes (total) BDL 2.5 BDL BDL 85,500 500 BTEX (total) 0 101.03 0 0 NSE NSE p-Isopropyltoluene BDL 1.7 BDL BDL NSE NSE Isopropylbenzene BDL 7.2 BDL BDL 25,000 70 Acetone BDL BDL BDL BDL 6,000,000 6,000 Naphthalene 1.2 47 BDL BDL 6,000 6 n-propylbenzene BDL 13 BDL BDL 30,000 70 n-butylbenzene BDL 1.2 BDL BDL 6,900 70 sec-Butylbenzene BDL 2.3 BDL BDL 15,000 70 tert-Butylbenzene BDL 0.84 BDL BDL 15,000 70 MTBE BDL 420 BDL BDL 20,000 20 1,2-Dichloropropane BDL BDL BDL BDL 600 0.6 Isopropyl Ether (IPE) BDL 1.2 BDL BDL 70,000 70 1,2-Dichloroethane BDL 7.1 BDL BDL 400 0.4 1,2,4-Trimethylbenzene BDL 7.4 BDL BDL 28,500 400 1,3,5-Trimethylbenzene BDL 1.2 BDL BDL 25,000 400 Lead (3030C) N/A N/A N/A N/A 15,000 15 Aliphatic Fraction Classes (ug/L) C5-C8 Volatile Aliphatics N/A N/A N/A N/A NSE 420 C9-C12 Volatile Aliphatics N/A N/A N/A N/A NSE NSE C9-C18 Extractable Aliphatics N/A N/A N/A N/A NSE 4,200 C9-C18 Aliphatics (total) N/A N/A N/A N/A NSE 4,200 C19-C36 Extractable Aliphatics N/A N/A N/A N/A NSE 42,000 Aromatic Fraction Classes (ug/L) C9-C10 Volatile Aromatics N/A N/A N/A N/A NSE NSE C11-C22 Extractable Aromatics N/A N/A N/A N/A NSE NSE C9-C22 Aromatics (total)N/A N/A N/A N/A NSE 210 N/A = Not Analyzed BDL = Below Detection Limits NSE = No Standard Established TABLE 2 (Continued) SUMMARY OF GROUNDWATER ANALYTICAL RESULTS BP SERVICE CENTER 4673 US HWY 117 NORTH, GOLDSBORO, NC TABLE 3TABLE 3Time Based Analytical Data Total BTEXTime Based Analytical Data - Total BTEXyBP S i C tBP Service CenterBP Service Center4673 N Hwy 117 Pikeville NC4673 N Hwy 117, Pikeville, NCDate of SamplingMW 1MW 2MW 3MW 7MW 8MW 12MW 15MW 18Date of SamplingMW-1MW-2MW-3MW-7MW-8MW-12MW-15MW-18pg5/27/19946 7017431 2115/27/19946,7017431,2117/8/20082 15619157458037 8002097/8/20082,15619157458037,8002093/31/20101 0951462607036 30023/31/20101,0951462607036,30028/6/20102 67934562481547 50094298/6/20102,67934562481547,500942910/6/201113818129245833 900285210/6/201113818129245833,90028524/18/20132603831332200497654/18/201326038313322004976510/29/20133732674300972029310/29/2013373267430097202937/30/20142053021315980135597/30/20142053021315980135595/15/2015156819866019345/15/2015156819866019348/17/2016859522114202498/17/2016859522114202493/9/20179752549101573/9/201797525491015711/2/20173354171060110111/2/201733541710601101// 77Rlti /lResults in ug/lResults in ug/l Benzene Toluene Ethyl- Xylenes TOTAL Isopropyl Isopropyl Napht n-propyl 1,2-Dich MTBE 1,2,4-tri- 1,3,5-tri- Well Date Benzene BTEX benzene ether halene benzene loroeth methylbenz methylbenz # Sampled (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) (ug/l) MW-1 7/8/2008 760 16 710 670 2,156 65 BDL 200 160 27 12 740 220 3/31/2010 690 1 320 84 1,095 39 3 100 76 BDL 9 110 9 8/6/2010 760 19 930 970 2,679 69 3 250 200 21 34 980 330 10/6/2011 110 BDL 12 16 138 7 BDL 22 38 929 25 BDL 4/18/2013 90 1 89 80 260 14 1 33 31 448110 40 10/29/2013 106 BDL 124 143 373 14 BDL 57 32 3 51 152 36 7/30/2014 100 2 77 26 205 9 BDL 28 18 12 29 41 15 5/15/2015 142 BDL 14 BDL 156 9 1 21 10 9 18 1 BDL 8/17/2016 62 BDL 18 4 85 6 2 17 9 3 138 51 3/9/2017 55 BDL 30 13 97 7 2 22 11 3 215 19 2 11/2/2017 22 BDL 11 BDL 33 4 3 12 6 3 280 1 BDL TABLE 4: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS BP Service Center, 4673 US Hwy 117 North, Pikeville, NC 27863 11/2/2017 22 BDL 11 BDL 33 4 3 12 6 3 280 1BDL MW-2 7/8/2008 14 BDL 3 2 19 43 BDL 44 20 322 6 BDL 3/31/2010 11 BDL 3 BDL 14 2 BDL BDL BDL 324 2 BDL 8/6/2010 210 4 97 34 345 13 BDL 48 23 570 34 5 10/6/2011 100 1 74 6 181 22 1 43 38 360 62 1 4/18/2013 21 BDL 12 5 38 6 1 10 9 442 7 BDL 10/29/2013 23 BDL BDL 3 26 6 BDL 17 10 242 51 7/30/2014 145 BDL 149 8 302 39 1 113 100 1 34 47 BDL 5/15/2015 6 BDL 1 BDL 8 3 BDL 5 2 327 1 BDL 8/17/2016 49 BDL 45 1 95 21 BDL 45 32 227 9 BDL 3/9/2017 26 7 19 1 52 12 BDL 27 16 221 1 BDL 11/2/2017 29 9 9 7 54 5 BDL 17 6 232BDL BDL MW-3 7/8/2008 100 BDL 49 157 306 43 1 77 83 12 13 16 13 3/31/2010 47 13 2 BDL 62 11 BDL 48 15 14 10 4 2 8/6/2010 37 BDL 23 2 62 30 BDL 67 64 10 10 1 2 10/6/2011 15 BDL 14 BDL 29 20 BDL 27 48 4 3 BDL BDL 4/18/2013 13 BDL 14 4 31 12 BDL 20 15 6 413 3 10/29/2013 4 BDL 3 BDL 7 5 BDL 8 6 3 2 BDL BDL 5 BDL 8 BDL 13 13 BDL 13 21 1 1 BDL BDL7/30/2014 5 BDL 8BDL 13 13 BDL 13 21 1 1BDL BDL 5/15/2015 11 BDL 8 BDL 19 5 BDL 11 8 4 3 2 BDL 8/17/2016 10 BDL 11 BDL 22 23 BDL 23 BDL 4 32 1 3/9/2017 3 BDL 2 BDL 5 5 BDL 4 BDL 4 BDL BDL BDL 11/2/2017 4 7 5 1 17 10 BDL 11 6 4 3 BDL BDL MW-4 7/8/2008 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 3/31/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 5/15/2015 190 3 21 16 229 5 1 71 8 BDL 178 11 3 8/17/2016 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL MW-5 7/8/2008 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 3/31/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 5/15/2015 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL MW-6 7/8/2008 BDL BDL BDL BDL 0 BDL 1 BDL BDL 229BDL BDL 3/31/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL 22 BDL BDL 8/6/2010 BDL BDL BDL BDL 0 BDL 1 BDL BDL 249BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL BDL BDL 130BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL 125BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL 126BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL 25 BDL BDL 5/15/2015 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL 27 BDL BDL MW-7 7/8/2008 270 180 1,000 3,130 4,580 210 8 170 470 BDL 230 2,500 580 3/31/2010 370 120 1,700 3,880 6,070 180 BDL 270 430 BDL 200 2,000 510 8/6/2010 320 95 1,300 3,100 4,815 160 BDL 290 400 BDL 140 1,800 500 10/6/2011 270 48 140 2,000 2,458 130 BDL 260 190 BDL 78 1,500 410 4/18/2013 200 22 1,200 1,900 3,322 140 BDL 220 300 BDL 41 2,100 540 10/29/2013 85 10 335 BDL 430 40 BDL 159 79 BDL 18 1,050 334 7/30/2014 120 8 639 831 1,598 114 BDL 185 276 BDL 22 1,120 351 5/15/2015 159 4 327 376 866 91 6 88 122 4 367 480 160 8/17/2016 135 4 405 598 1,142 95 3 149 206 3 20 986 296 3/9/2017 89 3 79 321 491 19 BDL 75 25 3 23 402 145 11/2/2017 110 BDL 400 550 1,060 60 BDL 130 110 BDL BDL 620 190 MW-8 9/14/2009 5,400 9,900 4,000 18,500 37,800 150 BDL 620 400 130 5,800 4,300 1,100 3/31/2010 7,200 12,000 3,200 13,900 36,300 97 BDL 480 310 BDL 9,200 2,700 710 8/6/2010 9,100 12,000 5,400 21,000 47,500 97 BDL 1,000 670 140 8,300 6,000 1,600 10/6/2011 7,100 9,400 3,400 14,000 33,900 BDL BDL 920 340 65 7,700 3,400 860 8A 4/18/2013 BDL BDL BDL BDL 0 BDL 1 BDL BDL 5 230 BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL 1 17 BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL 127BDL BDL 5/15/2015 BDL BDL BDL BDL 0 1 BDL BDL BDL 4 107 BDL BDL 8/17/2016 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL 9 BDL BDL MW-9 9/14/2009 9 BDL BDL BDL 9 2 2 BDL BDL 11 BDL BDL BDL 3/31/2010 4 BDL BDL BDL 4 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 6 BDL BDL BDL 6 BDL BDL 3 BDL 1 BDL BDL BDL 10/6/2011 5 BDL BDL BDL 5 BDL BDL BDL BDL 1 BDL BDL BDL 4/18/2013 1 BDL BDL BDL 1 BDL 1 BDL BDL 4 BDL BDL BDL 10/29/2013 1 BDL BDL BDL 1 BDL BDL BDL BDL 19 1 BDL BDL 7/30/2014 3 BDL BDL BDL 3 4 10 BDL BDL 40 BDL BDL BDL 5/15/2015 2 BDL BDL BDL 2 BDL BDL BDL BDL 15 1 BDL BDL 8/17/2016 2 BDL BDL BDL 2 5 BDL BDL BDL 18 1 BDL BDL 3/9/2017 BDL BDL BDL BDL 0 1 BDL BDL BDL 7 BDL BDL BDL 11/2/2017 3 2 BDL BDL 5 BDL 1 BDL BDL 2 1 BDL BDL MW-10 9/14/2009 BDL 1 BDL 1 2 BDL BDL BDL BDL BDL BDL BDL BDL 3/31/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL BDL BDL BDL 0BDLBDL BDL BDL BDL BDL BDL BDLBDL 5/15/2015 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 8/17/2016 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL MW-11 9/14/2009 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 3/31/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 5/15/2015 780 5 22 14 820 58 8 290 125 BDL 1,770 25 8/17/2016 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL MW-12 9/14/2009 180 2271209 5 BDL 6 6 19 BDL BDL BDL 3/31/2010 2 BDL BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL BDL 8/6/2010 9 BDL BDL BDL 9 BDL 2 BDL BDL BDL 3 BDL BDL 10/6/2011 2 BDL BDL BDL 2 BDL BDL BDL BDL 4 2 BDL BDL 4/18/2013 BDL BDL BDL BDL 0BDLBDL BDL BDL 1 2BDL BDL4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL 1 2 BDL BDL 10/29/2013 8 BDL BDL 1 9 3 BDL BDL BDL 10 8 BDL BDL 7/30/2014 1 BDL BDL BDL 1 BDL BDL BDL BDL 3 1 BDL BDL 5/15/2015 1 BDL BDL BDL 1 BDL BDL BDL BDL 2 BDL BDL BDL 11/2/2017 1 BDL BDL BDL 1 1 1 BDL BDL 2 10 BDL BDL MW-13 12/17/2009 3 24 1 1 29 BDL BDL 10 BDL BDL BDL 1 BDL 3/31/2010 BDL 51 BDL BDL 51 BDL BDL BDL BDL BDL BDL 1 BDL 8/6/2010 BDL 76 BDL BDL 76 BDL BDL BDL BDL BDL BDL 1 BDL 10/6/2011 3 6 BDL BDL 9 BDL BDL 7 BDL BDL BDL BDL BDL 4/18/2013 BDL 2 BDL BDL 2 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL 9 BDL BDL 9 BDL BDL BDL BDL BDL BDL BDL BDL 5/15/2015 BDL 11 BDL BDL 11 BDL BDL BDL BDL BDL BDL BDL BDL MW-14 12/17/2009 11 25320 1 BDL 160 3 BDL BDL 22 BDL 3/31/2010 3 BDL 27 BDL 30 BDL BDL 410 15 BDL BDL 85 5 8/6/2010 3 BDL 16 2 21 5 BDL 360 7 BDL BDL 55 1 10/6/2011 2 BDL 6 1 8 3 BDL 190 4 BDL BDL 590 98 4/18/2013 1 BDL 3 BDL 4 2 BDL 88 BDL BDL BDL 10 14/18/2013 1 BDL 3 BDL 4 2 BDL 88 BDL BDL BDL 10 1 10/29/2013 2 BDL 8 BDL 10 BDL BDL 196 5 BDL BDL 27 BDL 7/30/2014 1 BDL 2 BDL 3 1 BDL 44 2 BDL BDL 5 BDL 5/15/2015 1 BDL 3 BDL 3 2 BDL 50 1 BDL BDL 9 BDL 3/9/2017 BDL 2 1 BDL 3 1 BDL 4 1 BDL BDL BDL BDL 11/2/2017 BDL BDL 3 BDL 3 2 BDL 11 3 BDL BDL 6 BDL MW-15 8/6/2010 6 3 260 160 429 28 BDL 160 76 BDL BDL 90 41 10/6/2011 1 2 380 470 853 44 BDL 320 120 BDL BDL BDL BDL 4/18/2013 BDL BDL 37 12 49 9 BDL 53 17 BDL BDL 49 9 10/29/2013 BDL BDL 300 420 720 35 BDL 307 85 BDL BDL BDL BDL 7/30/2014 BDL BDL 11 25 35 4 BDL 35 6 BDL BDL 27 5 5/15/2015 BDL BDL 9 BDL 9 2 BDL 14 4 BDL BDL 2 BDL 3/9/2017 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL MW-16 8/6/2010 5 24717 1 BDL 26 1 BDL BDL 3 1 10/6/2011 3 BDL 13 1 17 3 BDL 220 27 BDL BDL 20 BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 1 BDL 1 BDL 1 2 BDL 43 2 BDL BDL 2 BDL 7/30/2014 1 BDL 6 1 8 10 BDL 139 13 BDL BDL 5 1 5/15/2015 1 BDL 1 BDL 2 4 BDL 79 4 BDL BDL 4 BDL 3/9/2017 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 11/2/2017 BDL BDL BDL BDL 0 BDL BDL 31 2 BDL BDL BDL BDL MW-17 8/6/2010 3 13412 BDL BDL 28 1 BDL BDL 2 BDL 10/6/2011 2 BDL BDL BDL 2 BDL BDL 32 BDL BDL BDL BDL BDL 4/18/2013 1 BDL BDL BDL 1 BDL BDL 19 BDL BDL BDL BDL BDL 10/29/2013 1 BDL BDL BDL 1 BDL BDL 16 BDL BDL BDL BDL BDL 7/30/2014 2 BDL BDL BDL 2 BDL BDL 68 BDL BDL BDL BDL BDL 5/15/2015 1 BDL BDL BDL 1 BDL BDL 40 BDL BDL BDL BDL BDL 3/9/2017 BDL BDL BDL BDL 0 BDL BDL 23 BDL BDL BDL BDL BDL 11/2/2017 BDL BDL BDL BDL 0 BDL BDL 1 BDL BDL BDL BDL BDL MW-18 4/18/2013 470 5 240 50 765 30 BDL 100 74 14 460 92 26 10/29/2013 187 BDL 100 6 293 13 BDL 65 34 6 294 BDL BDL 7/30/2014 56 1 3 BDL 59 BDL BDL 16 8 1 161 4 BDL 5/15/2015 25 BDL 10 BDL 34 3 BDL 54 1 130 BDL BDL 8/17/2016 144 BDL 105 BDL 249 21 BDL 63 46 7 360 2 BDL 3/9/2017 88 BDL 62 6 157 11 BDL 45 20 5 385 12 2 11/2/2017 59 1 39 3 101 7 1 47 13 7 420 711 VEW-1 12/17/2009 4 BDL 1 BDL 5 BDL BDL BDL BDL BDL BDL BDL BDL 3/31/2010 2 62616 BDL BDL BDL BDL BDL BDL 2 2 8/6/2010 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/6/2011 BDL BDL BDL BDL 0 BDL BDL 1 BDL BDL BDL BDL BDL 4/18/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 10/29/2013 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 7/30/2014 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL 5/15/2015 BDL BDL BDL BDL 0 BDL BDL BDL BDL BDL BDL BDL BDL NC 2L Standard 1 600 600 500 N/A 70 70 6 70 0 20 400 400 NC GCL Standard 5,000 260,000 84,500 85,500 N/A 25,000 70,000 6,000 30,000 400 20,000 28,500 25,000 BDL = Below Detection Limits NSE = No Standard Established N/A = Not Applicable TABLE 5SUPPLY WELL INFORMATION1,500' RADIUSB.P. Service Center4673 US 117 N., Pikevile, NCUST Incident No. 0‐0069891Well Identification SW‐1IW‐2IW‐3IW‐4IW‐7PIN Number 3603247015 3603246379 3603237868 3603239839 3603248382PIN Address Pearl & Railroad St.Pearl St. (Rear)(PO Box 71)129 Pearl St. (Rear) 4667 N. US 117 HY 4691 US 117N Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863Owner Name Pearl St Prop. of Pikevil Francis E. SuggsMattie Artis & C. B. HortonTedaro Reid Andrea CostonOwner Address 457 Washington St 150 Vance St. 129 Pearl St. (Rear) PO Box 506 4691 US 117NPikeville, NC 27863 Goldsboro, NC 27534 Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863OccupantUnoccupied Vacant Mattie Artis Tedaro Reid Apple Dumpling Day CareTelephone # 919.733.7862 xt 241 919.734.7220 919.736.1622 919.736.7887 919.242.5555Use Potable ‐Bathroom Not in use Washing Cars Not in use Not in UseDistance 165' 340' 215' 135' 360'City/County Water? NO Unknown Yes Yes YesDepth of Well Unknown 30' Unknown Unknown UnknownWell Diameter Unknown Unknown Unknown Unknown UnknownWell Yield Unknown Unknown Unknown Unknown UnknownDepth to Pump Unknown Unknown Unknown Unknown UnknownDepth of Casing Unknown Unknown Unknown Unknown UnknownStatic Water Unknown Unknown Unknown Unknown UnknownBPS Well TABLE 5SUPPLY WELL INFORMATION1,500' RADIUSB.P. Service Center4673 US 117 N., Pikevile, NCUST Incident No. 0‐0069892Well Identification SW‐8SW‐4IW‐6IW‐ 9IW‐10PIN Number 3603249413 36032382833603257054 3603258053 3603259063PIN Address 4697 US 117 N 4611 US 117N125 Booker St. 102 Booker St. NW 107 Booker St.Pikeville, NC 27863 Pikeville, NC 27863Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863Owner Name David E. Daw Sr. Morris ReedWillie Walker Leon & Kay N. Cox Joseph T. & C.F. CoreOwner Address 139 Zekes Lane PO Box 25531125 Booker St. 102 Booker St. PO Box 452Goldsboro, NC  27534 Raleigh, NC  27611Pikeville, NC 27863 Pikeville, NC 27863 Pikeville, NC 27863Occupant JuDee's Hair & Body Morris ReedDora B. Williams Kaye Cox Joseph Thurman CoreTelephone # 919.242.5652 (919) 215‐5057 (919) 242‐5697 (919) 766‐3050 (919) 242‐4466Use Potable PotableNot in Use Not in Use Not in UseDistance 380' 810'990' 980' 980'City Water? YesNO Yes Yes YesDepth of Well Unknown UnknownUnknown Unknown UnknownWell Diameter Unknown UnknownUnknown Unknown UnknownWell Yield Unknown UnknownUnknown Unknown UnknownDepth to Pump Unknown UnknownUnknown Unknown UnknownDepth of Casing Unknown UnknownUnknown Unknown UnknownStatic Water Unknown UnknownUnknown Unknown UnknownBPS Well APPENDIX A LABORATORY ANALYTICAL RESULTS Page 1 of 41 Page 2 of 41 Page 3 of 41 Page 4 of 41 Page 5 of 41 Page 6 of 41 Page 7 of 41 Page 8 of 41 Page 9 of 41 Page 10 of 41 Page 11 of 41 Page 12 of 41 Page 13 of 41 Page 14 of 41 Page 15 of 41 Page 16 of 41 Page 17 of 41 Page 18 of 41 Page 19 of 41 Page 20 of 41 Page 21 of 41 Page 22 of 41 Page 23 of 41 Page 24 of 41 Page 25 of 41 Page 26 of 41 Page 27 of 41 Page 28 of 41 Page 29 of 41 Page 30 of 41 Page 31 of 41 Page 32 of 41 Page 33 of 41 Page 34 of 41 Page 35 of 41 Page 36 of 41 Page 37 of 41 Page 38 of 41 Page 39 of 41 Page 40 of 41 Page 41 of 41