WA-811_11171_CA_RPTS_20161221_MRP

SITE IDENTIFICATION
 Facility Name: The Green Apple (Former Red Apple Market #23)
 Location: 1304 US Highway 13 South
Ahoskie, Hertford County
 Ground Water Incident No.: 38048/11171
 Facility ID No: 0-009681
 Risk Classification: I227A
 Land Use Classification: Residential
 Property Owner: SKD Fuels, LLC
1304 US Highway 13 South
Ahoskie, North Carolina 27910
 UST Owner/Operator: SKD Fuels, LLC
105 Club Lane
Lebanon, Pennsylvania 17042-9445
 Consultant: Geological Resources, Inc.
3502 Hayes Road
Monroe, North Carolina 28110
[phone]
 Laboratory: Accutest Laboratories
4405 Vineland Road, Suite C-15
Orlando, Florida 32811
[phone]
State Certification Number: 573
Release Information
 Date Discovered: February 2010 and December 1992
 Estimated Quantity of Release: Unknown
 Cause of Release: Leaking UST System
 Source of Release: UST System
 UST System Size/Contents: According to the available information, two 8,000-gallon
gasoline USTs, one 4,000-gallon gasoline UST, one
1,000-gallon diesel UST and one 550-gallon kerosene
UST were removed in November 1992; subsequently,
incident number 11171 was issued for the 1992 release.
Please refer to reports submitted for this incident for
further historical information regarding the assessment
and remediation activities conducted at the site.
Currently, one 10,000-gallon gasoline UST, one 6,000-
gallon gasoline UST, one 6,000-gallon diesel UST, and
one 4,000-gallon kerosene UST operate at the site.

 Latitude/Longitude: 36.316722º North / 76.987917º West

EXECUTIVE SUMMARY
The Green Apple (Former Red Apple Market #23) is located at 1304 US Highway 13 South in Ahoskie,
Hertford County, North Carolina. A release from the onsite underground storage tank (UST) system
consisting of one 10,000-gallon gasoline, one 6,000-gallon gasoline, one 6,000-gallon diesel and one
4,000-gallon kerosene USTs was discovered during February 2010 site check activities. According to
historical information obtained from the project file, a previous release was discovered during the
removal of two 8,000-gallon gasoline, one 4,000-gallon gasoline, one 1,000-gallon diesel and one 550-
gallon kerosene underground storage tanks (USTs) in December 1992. Incident Number 11171 was
issued for the previous UST system release when the site was known as the Red Apple Market #23. In
March 2016, SKD Fuels, LLC agreed to take the lead in completing the required assessment and
remediation at the site. The adjoining properties are commercial, residential and agricultural. Public
water is available to the site and surrounding properties. The site risk classification is currently ranked as
intermediate risk due to the past presence of free product.

On December 5, 2016, six Type II and one Type III monitoring wells were gauged, purged and sampled.
Concentrations of requested method constituents that exceeded the Maximum Allowable Concentrations
specified in T15A NCAC 2L.0202 were reported in the ground water samples collected from MW-5,
MW-10, MWD-12, MW-13, MW-14, GMW-1 and GMW-2. None of the reported contaminant
concentrations exceeded the Gross Contamination Levels.

Following the completion of the December 2016 sampling event, an absorbent boom was installed in
GMW-1 in order to recover free product, should any recharge into the well between sampling events.

Based on this information, Geological Resources, Inc. recommends that ground water monitoring
continue at the site in order to confirm that free product does not return to GMW-1. The absorbent boom
installed in GMW-1 should be removed approximately 30 days prior to the ground water monitoring
event. The next semi-annual ground water monitoring event is tentatively scheduled for June 2017.

TABLE OF CONTENTS

1.0 SITE HISTORY AND CHARACTERIZATION .................................................................... 1

2.0 CURRENT SITE ASSESSMENT ............................................................................................ 1

3.0 GROUND WATER QUALITY ................................................................................................ 1

4.0 CONCLUSIONS AND RECOMMENDATIONS .................................................................... 2

5.0 LIMITATIONS ......................................................................................................................... 3

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Water Table Surface Map
Figure 4: Ground Water Quality Map

TABLES
Table 1: Well Construction and Gauging Information
Table 2: Summary of Ground Water Sample Analytical Results

APPENDIX
Appendix A: Laboratory Report - Ground Water Samples

1
1.0 SITE HISTORY AND CHARACTERIZATION
The Green Apple is a vacant convenience store and petroleum retail facility located at 1304 US Highway
13 South in Ahoskie, Hertford County, North Carolina (Figure 1). A release from the onsite underground
storage tank (UST) system consisting of one 10,000-gallon gasoline, one 6,000-gallon gasoline, one
6,000-gallon diesel and one 4,000-gallon kerosene USTs was discovered during February 2010 site check
activities. According to historical information obtained from the project file, a previous release was
discovered during the removal of two 8,000-gallon gasoline, one 4,000-gallon gasoline, one 1,000-gallon
diesel and one 550-gallon kerosene USTs in December 1992. Incident Number 11171 was issued for the
previous UST system release when the site was known as the Red Apple Market #23. In March 2016,
SKD Fuels, LLC agreed to take the lead in completing the required assessment and remediation at the
site. The adjoining properties are commercial, residential and agricultural. Public water is available to
the site and surrounding properties. The site risk classification is currently ranked as intermediate risk
due to the past presence of free product.

Fourteen Type II and two Type III monitoring wells were installed at the site during past ground water
assessment and remediation activities. Site activities conducted prior to the April 2008 updated receptor
survey and ground water sampling activities were completed by past consultants. Although Geological
Resources, Inc. (GRI) cannot verify the accuracy of information obtained from previous reports, for the
purposes of this report, it is assumed to be correct. Please refer to previous submittals for further
historical information regarding the site.

2.0 CURRENT SITE ASSESSMENT
The purpose of this report is to present the results of the ground water sampling activities conducted on
December 5, 2016 at The Green Apple site. The activities were conducted in accordance with GRI
proposal number 16-456 which was submitted to NCDEQ on June 17, 2016 and approved as Task
Authorization No. 11171-30 on July 15, 2016. A change order was submitted on July 19, 2016 and
approved as Task Authorization No. 11171-030-1 on August 12, 2016. The purpose of the activities was
to obtain current ground water quality data for the site.

3.0 GROUND WATER QUALITY
Six Type II monitoring wells (MW-5, MW-10, MW-13, MW-14, GWM-1 and GMW-2) and one Type III
monitoring well (MWD-12) were gauged, purged and/or sampled on December 5, 2016. The depths to

2
ground water in the Type II monitoring wells during the December 2016 sampling event ranged from 2.53
to 3.21 feet below the tops of well casings. Ground water elevations in the Type II monitoring wells
relative to a temporary benchmark with an assumed datum of 100.00 feet ranged from 97.40 to 98.28 feet.
Based on this information, the general ground water flow direction was generally toward the northeast
with an average horizontal hydraulic gradient of approximately 0.02 feet per foot. A Site Map showing
the structures on-site and the locations of the monitoring wells is included as Figure 2. A Water Table
Surface Map for the December 2016 sampling event has been included as Figure 3. Well construction
and gauging information is presented in Table 1.

Laboratory analyses were performed on the ground water samples collected from the monitoring wells
during the December 2016 sampling event for volatile organic compounds using EPA Method 6200B.
Concentrations of individual BTEX constituents, MTBE, naphthalene, IPE, isopropylbenzene, n-
propylbenzene, 1,2-dichloroethane and/or 1,2,4 trimethybenzene that exceeded the Maximum Allowable
Concentrations (MACs) specified in T15A NCAC 2L.0202 were reported in the ground water samples
collected from MW-5, MW-13, MW-14, GMW-1 and GMW-2. None of the reported contaminant
concentrations exceeded the Gross Contamination Levels (GCLs). A Ground Water Quality Map based
on the December 2016 sampling event has been included as Figure 4. A summary of ground water
sample analytical results is presented in Table 2. A copy of the laboratory report has been included as
Appendix A.

Following the completion of the December 2016 sampling event, an absorbent boom was installed in
GMW-1 in order to recover free product, should any recharge into the well between sampling events.

4.0 CONCLUSIONS AND RECOMMENDATIONS
 No free product was measured in GMW-1 in December 2016.
 The average depth to ground water in the Type II monitoring wells during the December 2016
sampling event was 2.90 feet. Ground water flow across the site was generally toward the
northeast with an average horizontal hydraulic gradient of approximately 0.02 feet per foot.
 Concentrations of individual BTEX constituents, MTBE, naphthalene, IPE, isopropylbenzene, n-
propylbenzene, 1,2-dichloroethane and/or 1,2,4 trimethybenzene that exceeded the MACs were
reported in the ground water samples collected from MW-5, MW-13, MW-14, GMW-1 and
GMW-2. None of the reported contaminant concentrations exceeded the GCLs.

3
 Based on this information, GRI recommends that ground water monitoring continue at the site in
order to confirm that free product does not return to GMW-1. The absorbent boom installed in
GMW-1 should be removed approximately 30 days prior to the ground water monitoring event.
The next semi-annual ground water monitoring event is tentatively scheduled for June 2017.

5.0 LIMITATIONS
This report has been prepared for the exclusive use of SKD Fuels, LLC for specific application to the
referenced site in Hertford County, North Carolina. The assessment was conducted based on the scope of
work and level of effort desired by NCDEQ and with resources adequate only for that scope of work. Our
findings have been developed in accordance with generally accepted standards of environmental practices
in the State of North Carolina, available information, and our professional judgment. No other warranty
is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would be
interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data. Please note that field data collected prior
to the April 2008 updated receptor survey and ground water sampling event was not obtained under the
supervision of GRI. Although the accuracy of this information cannot be verified, for the purpose of this
report GRI assumes that it is correct.

FIGURES

TABLES
04/25/08 NM ---NM Not Located
12/09/08 NM ---NM Not Sampled
03/15/10 0.81 ---98.85
09/14/15 2.77 ---96.89
03/17/16 0.94 ---98.72
04/25/08 101.47 3.33 ---98.14
12/09/08 6.82 ---94.64
03/15/10 2.80 ---98.66
09/14/15 5.83 ---95.63
04/25/08 1.71 ---98.29
12/09/08 4.72 ---95.28
03/15/10 1.02 ---98.98
09/14/15 3.33 ---96.67
03/17/16 0.59 ---99.41
04/25/08 1.83 ---98.09
12/09/08 5.42 ---94.50
03/15/10 1.36 ---98.56
09/14/15 4.46 ---95.46
03/17/16 0.52 ---99.40
04/25/08 2.25 ---98.20
12/09/08 5.24 ---95.21
03/15/10 1.58 ---98.87
09/14/15 4.50 ---95.95
03/17/16 1.26 ---99.19
12/05/16 2.88 ---97.57
04/25/08 0.83 ---98.06
12/09/08 4.29 ---94.6
03/15/10 NM ---NM
09/14/15 3.46 ---95.43
03/17/16 NM NM NM Top of Casing
04/25/08 0.94 ---98.02
12/09/08 4.50 ---94.46
03/15/10 NM ---NM
09/14/15 NM ---NM Not Located
04/25/08 0.80 ---98.01
12/09/08 4.25 ---94.56
03/15/10 NM ---NM
09/14/15 3.40 ---95.41
04/25/08 3.16 ---97.90
12/09/08 6.62 ---94.44
03/15/10 2.46 ---98.6
09/14/15 5.58 ---95.48
03/17/16 1.52 ---99.54
04/25/08 2.31 ---98.05
12/09/08 5.50 ---94.86
03/15/10 1.76 ---98.60
09/14/15 4.73 ---95.63
03/17/16 1.09 ---99.27
12/05/16 2.96 ---97.40
04/25/08 0.78 ---97.04
12/09/08 3.75 ---94.07
03/15/10 0.63 ---97.19
09/14/15 NM NM NM Not Located
03/17/16 NM NM NM Not Located
04/25/08 2.37 ---97.16
12/09/08 5.96 ---93.57
03/15/10 1.86 ---97.67
09/14/15 4.98 ---94.55
03/17/16 1.04 ---98.49
12/05/16 3.01 ---96.52
04/25/08 2.19 ---98.62
12/09/08 5.15 ---95.66
03/15/10 1.44 ---99.37
09/14/15 4.31 ---96.50
03/17/16 1.16 ---99.65
12/05/16 2.53 ---98.28
12/09/08 5.79 ---94.73
03/15/10 1.90 ---98.62
09/14/15 4.63 ---95.89
03/17/16 1.19 ---99.33
12/05/16 3.02 ---97.50
05/26/11 3.26 0.18 NM
09/14/15 4.97 0.07 NM
02/03/16 1.81 ---NM
03/17/16 1.54 0.01 NM
12/05/16 3.21 ---NM
GMW-1 05/25/11 2 2 - 10 12 NM
40 99.53
MW-13
MW-14
NA
12/09/08 18 3 - 18 18
NA NA 16 100.81
98.892010 - 2010
100.52
04/02/96MW-6
11/19/96 101.06177 - 177MW-9
MW-7 04/02/96 188 - 188 98.96
100.00166 - 16609/13/93MW-3
99.66166 - 16609/13/93MW-1
MW-2 16 101.46609/13/93 6 - 16
99.922419 - 241903/27/96MWD-4
MW-5 03/27/96 6 6 - 16 16 100.45
98.81188 - 18804/02/96MW-8
11/19/96MW-11 97.82199 - 199
MW-10 11/19/96 6 6 - 16 16 100.36
MWD-12 09/08/97 35 35 - 40

WELL CONSTRUCTION AND GAUGING INFORMATION
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Date: 12/08/16 Facility ID #: 0-009681
Comments
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground
Water
Elevation*
(ft.)
Well ID Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Page 1 of 2

WELL CONSTRUCTION AND GAUGING INFORMATION
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Date: 12/08/16 Facility ID #: 0-009681
Comments
Bottom of
Well
(ft. BGS)
Top of
Casing
Elevation*
(ft.)
Depth to
Water from
Top of
Casing
(ft.)
Free Product
Thickness
(ft.)
Ground
Water
Elevation*
(ft.)
Well ID Date Installed
(mm/dd/yy)
Date Water
Level Measured
(mm/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
05/26/11 2.87 ---NM
09/14/15 4.39 ---NM
03/17/16 1.32 ---NM
12/05/16 2.77 ---NM
Notes:
GMW-2 05/25/11 2 2 - 10 12 NM
• ft BGS : feet below ground surface
• NM: Not Measured
Page 2 of 2
Date: 12/05/16 Facility ID#: 0-009681
EPA
Method
6010B
EPA
Method
504.1
1 600 600 500 20 6 70 70 400 400 30 15 0.0200 400 700 10,000 200
5,000 260,000 84,500 87,500 20,000 6,000 70,000 30,000 25,000 28,500 12,500 15,000 50 NE NE NE NE
04/25/08 NS NS NS NS NS NS NS NS NS NS NR NS NR NS NS NS NS
12/09/08 NS NS NS NS NS NS NS NS NS NS NR NS NR NS NS NS NS
03/15/10 <0.280 <0.380 <0.300 <0.440 18.7 <1.00 254 <0.440 <0.360 <0.300 NR NR NR NR NR NR NR
09/14/15 <0.17 0.18 J <0.15 <0.43 3.2 <0.12 226 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 7.8 <0.13 231 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 2.25 V <1.0 0.150 I <1.0 <1.0 <1.0 NR 50.1 NR <100 <175 109 76.2
12/09/08 <0.60 <0.70 <0.50 <1.0 2.4 J <0.60 9.8 J <0.75 <0.50 <0.70 NR 21.6 NR <100 <214 <114 <214
03/15/10 0.142 J <0.190 <0.150 <0.220 1.89 <0.500 4.92 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 1.6 <0.12 0.66 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 1.29 V <1.0 6.30 <1.0 <1.0 <1.0 NR 12.8 NR <100 <175 <75 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 1.9 J <0.60 29 <0.75 <0.50 <0.70 NR 6.8 NR 164 <205 <105 <205
03/15/10 <0.140 <0.190 <0.150 <0.220 1.43 <0.500 25.2 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 0.17 J <0.12 0.74 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 0.23 J <0.13 2.9 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 3.67 V 1.00 IV 2.08 I <1.0 <1.0 <1.0 NR 3.34 NR <100 <175 <75 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 20 <0.60 6.9 J <0.75 <0.50 <0.70 NR 18.6 NR 120 <205 <105 <205
03/15/10 <0.140 <0.190 <0.150 <0.220 20.5 <0.500 8.96 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 0.39 J <0.12 0.58 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 6.6 <0.13 10.8 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 621 207 278 560 230 V 135 V 2.40 I 26.4 55.4 229 NR 26.5 NR 2,720 108 117 1,439
12/09/08 <0.60 <0.70 <0.50 <1.0 33 <0.60 2.9 J <0.75 <0.50 <0.70 NR 20.7 NR 1,340 <206 <106 <206
03/15/10 859 239 548 1,240 307 233 5.86 J 55.2 91.2 427 NR NR NR NR NR NR NR
09/14/15 982 22.4 461 221 96.3 414 <1.6 103 14.5 241 NR NR NR NR NR NR NR
03/17/16 443 60.8 166 109 54.2 123 9.8 40.7 16.1 102 NR NR NR NR NR NR NR
12/05/16 164 2.4 26.4 23.0 24.3 87.7 4.8 2.5 3.7 27.3 NR NR NR NR NR NR NR
MW-5 MTBEWell ID
Date
Collected
(mm/dd/yy)
Contaminant of
Concern BenzeneTolueneEthylbenzeneXylenes2L Standard (mg/l)
GCL (mg/l)
MW-2
MWD-4
MW-3
MW-1 C9 - C18 AliphaticsC19 - C36 AliphaticsC9 - C22 AromaticsNaphthaleneIPEn-Propylbenzene1,3,5-Trimethylbenzene1,2,4-Trimethylbenzene2 MethylnaphthaleneEDBC5 - C8 AliphaticsLeadTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Analytical Method EPA Methods 6200B and 625 MADEP Methods VPH and EPH
Page 1 of 4
Date: 12/05/16 Facility ID#: 0-009681
EPA
Method
6010B
EPA
Method
504.1
1 600 600 500 20 6 70 70 400 400 30 15 0.0200 400 700 10,000 200
5,000 260,000 84,500 87,500 20,000 6,000 70,000 30,000 25,000 28,500 12,500 15,000 50 NE NE NE NEMTBEWell ID
Date
Collected
(mm/dd/yy)
Contaminant of
Concern BenzeneTolueneEthylbenzeneXylenes2L Standard (mg/l)
GCL (mg/l)C9 - C18 AliphaticsC19 - C36 AliphaticsC9 - C22 AromaticsNaphthaleneIPEn-Propylbenzene1,3,5-Trimethylbenzene1,2,4-Trimethylbenzene2 MethylnaphthaleneEDBC5 - C8 AliphaticsLeadTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Analytical Method EPA Methods 6200B and 625 MADEP Methods VPH and EPH
04/25/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 NR 3.06 I NR <100 <175 79.8 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <1.0 <0.75 <0.50 <0.70 NR <1.5 NR <100 <205 <105 <205
03/15/10 NS NS NS NS NS NS NS NS NS NS NR NS NR NS NS NS NS
09/14/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.16 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 NR 3.33 I NR <100 <175 85.2 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <1.0 <0.75 <0.50 <0.70 NR 2.4 J NR <100 <205 <105 <205
03/15/10 NS NS NS NS NS NS NS NS NS NS NR NS NR NS NS NS NS
04/25/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 NR 5.54 NR <100 <175 96.7 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 <0.50 <0.60 <1.0 <0.75 <0.50 <0.70 NR 7.2 NR <100 <205 <105 <205
03/15/10 NS NS NS NS NS NS NS NS NS NS NR NS NR NS NS NS NS
09/14/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 1.7 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
04/25/08 0.350 I <1.0 <1.0 <3.0 21.5 V <1.0 0.530 I <1.0 <1.0 <1.0 NR 36.0 NR <100 <175 80.5 <150
12/09/08 <0.60 <0.70 <0.50 <1.0 17 <0.60 <1.0 <0.75 <0.50 <0.70 NR 5.4 NR <100 <214 <114 <214
03/15/10 <0.140 <0.190 <0.150 <0.220 15.0 <0.500 0.350 J <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 4.6 <0.12 <0.16 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 5.4 <0.13 0.14 J <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 5.55 V <1.0 <5.0 <1.0 <1.0 <1.0 NR 23.2 NR <100 <175 89.5 <150
12/09/08 100 10 75 63 39 46 B 2.9 J 7.3 5.0 J 23 NR 3.7 NR 7010 449 <105 280
03/15/10 <0.140 <0.190 <0.150 <0.220 16.1 <0.500 0.272 J <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 4.4 <0.12 0.19 J <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
04/25/08 <1.0 <1.0 <1.0 <3.0 36.2 V <1.0 <5.0 <1.0 <1.0 <1.0 NR 13.5 NR <100 <175 75.4 <150
12/09/08 1.0 <0.70 0.86 J <1.0 85 2.2 JB <1.0 <0.75 <0.50 <0.70 NR 2.3 J NR 102 <206 <106 <206
03/15/10 <0.140 <0.190 <0.150 <0.220 42.0 <0.500 <0.200 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
03/17/16 <0.13 <0.13 <0.13 <0.31 8.0 <0.13 0.72 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
12/05/16 <0.13 <0.13 <0.13 <0.31 6.5 0.18 J 0.57 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
MW-10
MW-8
MW-9
MW-6
MW-7
Page 2 of 4
Date: 12/05/16 Facility ID#: 0-009681
EPA
Method
6010B
EPA
Method
504.1
1 600 600 500 20 6 70 70 400 400 30 15 0.0200 400 700 10,000 200
5,000 260,000 84,500 87,500 20,000 6,000 70,000 30,000 25,000 28,500 12,500 15,000 50 NE NE NE NEMTBEWell ID
Date
Collected
(mm/dd/yy)
Contaminant of
Concern BenzeneTolueneEthylbenzeneXylenes2L Standard (mg/l)
GCL (mg/l)C9 - C18 AliphaticsC19 - C36 AliphaticsC9 - C22 AromaticsNaphthaleneIPEn-Propylbenzene1,3,5-Trimethylbenzene1,2,4-Trimethylbenzene2 MethylnaphthaleneEDBC5 - C8 AliphaticsLeadTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Analytical Method EPA Methods 6200B and 625 MADEP Methods VPH and EPH
04/25/08 <1.0 <1.0 <1.0 <3.0 36.2 V <1.0 <5.0 <1.0 <1.0 <1.0 NR 13.5 NR <100 <175 75.4 <150
12/09/08 1.0 <0.70 0.86 J <1.0 85 2.2 JB <1.0 <0.75 <0.50 <0.70 NR 2.3 J NR 102 <206 <106 <206
03/15/10 <0.140 <0.190 <0.150 <0.220 42.0 <0.500 <0.200 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
03/17/16 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
04/25/08 <1.0 <1.0 <1.0 <3.0 <1.0 <1.0 <5.0 <1.0 <1.0 <1.0 NR 4.19 I NR <100 <175 98.5 64.8
12/09/08 2.4 J <0.70 <0.50 <1.0 13 <0.60 190 <0.75 <0.50 <0.70 NR 3.9 NR 509 <211 <111 <211
03/15/10 44.7 <0.190 <0.150 0.725 J 10.7 <0.500 186 <0.220 <0.180 <0.150 NR NR NR NR NR NR NR
09/14/15 <0.17 <0.17 <0.15 <0.43 <0.16 <0.12 <0.16 <0.16 <0.14 <0.14 NR NR NR NR NR NR NR
03/17/16 139 13.1 1.5 J 40.7 58.7 9.4 300 13.6 <1.3 3.5 J NR NR NR NR NR NR NR
12/05/16 <0.13 <0.13 <0.13 <0.31 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 NR NR NR NR NR NR NR
04/25/08 4,530 4,790 1,850 6,400 698 V 795 V <100 153 382 1,480 NR 11.3 NR 15,500 601 <75 5,763
12/09/08 2,100 1,400 1,000 2,200 360 620 B <1.0 120 240 860 NR 1.5 NR 17,300 1,550 <108 4,114
03/15/10 3,820 2,180 1,630 6,740 171 792 <10.0 141 425 1,630 NR NR NR NR NR NR NR
09/14/15 948 90.8 1,270 E 1,430 26.2 648 3.4 139 144 734 NR NR NR NR NR NR NR
03/17/16 1,130 2,180 1,200 3,270 20.1 J 392 <6.3 93.3 135 657 NR NR NR NR NR NR NR
12/05/16 19.1 13.7 21.1 29.8 2.0 11.4 0.31 J 3.0 1.1 7.8 NR NR NR NR NR NR NR
12/09/09 4,700 450 1,200 3,000 120 220 B 180 69 120 540 NR 4.1 NR 30,800 4,720 <108 2,440
03/15/10 89.1 8.09 14.5 17.1 8.06 16.2 197 5.30 0.623 J 1.64 J NR NR NR NR NR NR NR
09/14/15 90.9 5.2 15.3 29.4 1.4 6.8 23.2 4.5 1.3 1.2 NR 1.5 NR 17,300 1,550 <108 4,114
03/17/16 189 3.5 2.7 33.0 6.5 60.9 56.5 25.9 2.0 1.7 NR NR NR NR NR NR NR
12/05/16 44.1 2.9 3.5 12.3 1.5 17.4 18.1 12.4 0.56 0.52 NR NR NR NR NR NR NR
05/26/11 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
09/14/15 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
03/17/16 FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP FP
12/05/16 2,280 684 1,570 6,040 44.9 J 1,020 113 433 360 1,640 NR NR NR NR NR NR NR
MWD-12
MW-13
MW-14
MW-11
GMW-1
Page 3 of 4
Date: 12/05/16 Facility ID#: 0-009681
EPA
Method
6010B
EPA
Method
504.1
1 600 600 500 20 6 70 70 400 400 30 15 0.0200 400 700 10,000 200
5,000 260,000 84,500 87,500 20,000 6,000 70,000 30,000 25,000 28,500 12,500 15,000 50 NE NE NE NEMTBEWell ID
Date
Collected
(mm/dd/yy)
Contaminant of
Concern BenzeneTolueneEthylbenzeneXylenes2L Standard (mg/l)
GCL (mg/l)C9 - C18 AliphaticsC19 - C36 AliphaticsC9 - C22 AromaticsNaphthaleneIPEn-Propylbenzene1,3,5-Trimethylbenzene1,2,4-Trimethylbenzene2 MethylnaphthaleneEDBC5 - C8 AliphaticsLeadTABLE 2
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
THE GREEN APPLE (FORMER RED APPLE MARKET #23) (INCIDENT NO. 38048)
Analytical Method EPA Methods 6200B and 625 MADEP Methods VPH and EPH
05/26/11 339 23.6 455 1,056.7 15.0 135 820 133 119 363 37.1 48.8 <0.0094 2,970 4,386 <100 3,954
09/14/15 50.2 52.6 179 224 <0.16 22.4 447 37.5 19.6 45.1 NR NR NR NR NR NR NR
03/17/16 97.7 29.3 149 308 4.0 43.0 218 37.4 12.2 63.6 NR NR NR NR NR NR NR
12/05/16 6.7 1.4 10.9 7.0 0.44 J 5.1 18.9 6.9 0.31 J 2.1 NR NR NR NR NR NR NR
TMW-1 02/15/10 236,000 2,860,000 E 1,310,000 5,510,000 <2,500 829,000 <2,000 NR 1,090,000 2,650,000 E NR NR NR NR NR NR NR
TMW-2 02/15/10 19,400 95,800 30,600 173,000 <250 26,800 <200 NR 29,200 120,000 NR NR NR NR NR NR NR
Notes:
• Results reported in µg/l (micrograms per liter).
• < : Less than the method detection limit specified in the laboratory report.
• 2L Standard specified in T15A NCAC 2L.0202.
• GCL: Gross contamination level.
• Concentrations in bold face type exceeded the 2L Standards.
• Concentrations in italics exceeded the GCL Standards.
• J: Estimated concentration.
• E: Indicates value exceeds calibration range.
• FP: Free Product.
• NR: Analysis not requested.
• Concentrations of isopropylbenzene (185 µg/L in GMW-1) and 1,2-dichloroethane (0.44 J µg/L in MW-5) were reported in the ground water samples collected on December 5, 2016.
• Refer to laboratory reports for dectectable contaminant concentrations that did not exceed 2L standards or for which no standards are established.
GMW-2
Page 4 of 4

APPENDIX

APPENDIX A
Laboratory Report – Ground Water Samples
12/13/16
Technical Report for
GRI (Geological Resources Inc.)
Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
38048/2681
SGS Accutest Job Number: FA39260
Sampling Date: 12/05/16
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: Justin Radford
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(L-A-B L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, GA, IA, KY, MA, NV, OK, OR, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of SGS Accutest.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Southeast 12/13/16
e-Hardcopy 2.0
Automated Report
41
SGS Accutest is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
1 of 41
FA39260
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................7
3.1: FA39260-1: GMW-1 .....................................................................................................8
3.2: FA39260-2: GMW-2 .....................................................................................................10
3.3: FA39260-3: MW-12 ......................................................................................................12
3.4: FA39260-4: MW-14 ......................................................................................................14
3.5: FA39260-5: MW-10 ......................................................................................................16
3.6: FA39260-6: MW-5 ........................................................................................................18
3.7: FA39260-7: MW-13 ......................................................................................................20
Section 4: Misc. Forms ............................................................................................................22
4.1: Chain of Custody ...........................................................................................................23
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................26
5.1: Method Blank Summary ................................................................................................27
5.2: Blank Spike Summary ...................................................................................................32
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................37 123452 of 41
FA39260
SGS Accutest
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA39260
Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Project No: 38048/2681
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA39260-1 12/05/16 10:14 JRW 12/06/16 AQ Ground Water GMW-1
FA39260-2 12/05/16 10:27 JRW 12/06/16 AQ Ground Water GMW-2
FA39260-3 12/05/16 10:37 JRW 12/06/16 AQ Ground Water MW-12
FA39260-4 12/05/16 10:46 JRW 12/06/16 AQ Ground Water MW-14
FA39260-5 12/05/16 10:53 JRW 12/06/16 AQ Ground Water MW-10
FA39260-6 12/05/16 11:00 JRW 12/06/16 AQ Ground Water MW-5
FA39260-7 12/05/16 11:07 JRW 12/06/16 AQ Ground Water MW-13
3 of 41
FA392601
Summary of Hits Page 1 of 3
Job Number:FA39260
Account:GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Collected:12/05/16
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA39260-1 GMW-1
Benzene 2280 50 13 ug/l SM 6200B
n-Butylbenzene 52.3 50 13 ug/l SM 6200B
sec-Butylbenzene 40.7 J 50 13 ug/l SM 6200B
Di-Isopropyl Ether 113 50 13 ug/l SM 6200B
Ethylbenzene 1570 50 13 ug/l SM 6200B
Isopropylbenzene 185 50 13 ug/l SM 6200B
p-Isopropyltoluene 21.8 J 50 13 ug/l SM 6200B
Methyl Tert Butyl Ether 44.9 J 50 13 ug/l SM 6200B
Naphthalene 1020 50 13 ug/l SM 6200B
n-Propylbenzene 433 50 13 ug/l SM 6200B
Toluene 684 50 13 ug/l SM 6200B
1,2,4-Trimethylbenzene 1640 50 13 ug/l SM 6200B
1,3,5-Trimethylbenzene 360 50 13 ug/l SM 6200B
m,p-Xylene 5940 100 18 ug/l SM 6200B
o-Xylene 97.0 50 13 ug/l SM 6200B
Xylene (total)6040 150 31 ug/l SM 6200B
FA39260-2 GMW-2
Benzene 6.7 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 0.67 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.81 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 18.9 0.50 0.13 ug/l SM 6200B
Ethylbenzene 10.9 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 3.9 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 0.40 J 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 0.44 J 0.50 0.13 ug/l SM 6200B
Naphthalene 5.1 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 6.9 0.50 0.13 ug/l SM 6200B
Toluene 1.4 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 2.1 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.31 J 0.50 0.13 ug/l SM 6200B
m,p-Xylene 6.2 1.0 0.18 ug/l SM 6200B
o-Xylene 0.81 0.50 0.13 ug/l SM 6200B
Xylene (total)7.0 1.5 0.31 ug/l SM 6200B
FA39260-3 MW-12
No hits reported in this sample.
FA39260-4 MW-14
Benzene 44.1 0.50 0.13 ug/l SM 6200B
4 of 41
FA392602
Summary of Hits Page 2 of 3
Job Number:FA39260
Account:GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Collected:12/05/16
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
sec-Butylbenzene 2.5 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 0.23 J 0.50 0.13 ug/l SM 6200B
Chloroethane a 0.50 0.50 0.20 ug/l SM 6200B
1,2-Dichloroethane 0.17 J 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 18.1 0.50 0.13 ug/l SM 6200B
Ethylbenzene 3.5 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 4.3 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 1.5 0.50 0.13 ug/l SM 6200B
Naphthalene 17.4 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 12.4 0.50 0.13 ug/l SM 6200B
Toluene 2.9 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 0.52 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 0.56 0.50 0.13 ug/l SM 6200B
m,p-Xylene 10.3 1.0 0.18 ug/l SM 6200B
o-Xylene 2.0 0.50 0.13 ug/l SM 6200B
Xylene (total)12.3 1.5 0.31 ug/l SM 6200B
FA39260-5 MW-10
Di-Isopropyl Ether 0.57 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 6.5 0.50 0.13 ug/l SM 6200B
Naphthalene 0.18 J 0.50 0.13 ug/l SM 6200B
FA39260-6 MW-5
Benzene 164 2.5 0.63 ug/l SM 6200B
n-Butylbenzene 0.74 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.63 0.50 0.13 ug/l SM 6200B
tert-Butylbenzene 1.9 0.50 0.13 ug/l SM 6200B
Chloroethane a 0.33 J 0.50 0.20 ug/l SM 6200B
1,2-Dichloroethane 0.44 J 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 4.8 0.50 0.13 ug/l SM 6200B
Ethylbenzene 26.4 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 1.5 0.50 0.13 ug/l SM 6200B
p-Isopropyltoluene 1.2 0.50 0.13 ug/l SM 6200B
Methyl Chloride 0.31 J 0.50 0.20 ug/l SM 6200B
Methyl Tert Butyl Ether 24.3 0.50 0.13 ug/l SM 6200B
Naphthalene 87.7 2.5 0.63 ug/l SM 6200B
n-Propylbenzene 2.5 0.50 0.13 ug/l SM 6200B
Toluene 2.4 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 27.3 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 3.7 0.50 0.13 ug/l SM 6200B
m,p-Xylene 21.5 1.0 0.18 ug/l SM 6200B
o-Xylene 1.5 0.50 0.13 ug/l SM 6200B
Xylene (total)23.0 1.5 0.31 ug/l SM 6200B
5 of 41
FA392602
Summary of Hits Page 3 of 3
Job Number:FA39260
Account:GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Collected:12/05/16
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA39260-7 MW-13
Benzene 19.1 0.50 0.13 ug/l SM 6200B
n-Butylbenzene 0.24 J 0.50 0.13 ug/l SM 6200B
sec-Butylbenzene 0.17 J 0.50 0.13 ug/l SM 6200B
Chloroethane a 0.29 J 0.50 0.20 ug/l SM 6200B
o-Chlorotoluene 0.14 J 0.50 0.13 ug/l SM 6200B
Di-Isopropyl Ether 0.31 J 0.50 0.13 ug/l SM 6200B
Ethylbenzene 21.1 0.50 0.13 ug/l SM 6200B
Isopropylbenzene 0.90 0.50 0.13 ug/l SM 6200B
Methyl Tert Butyl Ether 2.0 0.50 0.13 ug/l SM 6200B
Naphthalene 11.4 0.50 0.13 ug/l SM 6200B
n-Propylbenzene 3.0 0.50 0.13 ug/l SM 6200B
Toluene 13.7 0.50 0.13 ug/l SM 6200B
1,2,4-Trimethylbenzene 7.8 0.50 0.13 ug/l SM 6200B
1,3,5-Trimethylbenzene 1.1 0.50 0.13 ug/l SM 6200B
m,p-Xylene 26.2 1.0 0.18 ug/l SM 6200B
o-Xylene 3.6 0.50 0.13 ug/l SM 6200B
Xylene (total)29.8 1.5 0.31 ug/l SM 6200B
(a) Associated CCV outside control limits.
6 of 41
FA392602
SGS Accutest
Sample Results
Report of Analysis
Southeast
Section 3
7 of 41
FA392603
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:GMW-1
Lab Sample ID:FA39260-1 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0204366.D 100 12/09/16 TD n/a n/a VA2061
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2280 50 13 ug/l
108-86-1 Bromobenzene ND 50 13 ug/l
74-97-5 Bromochloromethane ND 50 13 ug/l
75-27-4 Bromodichloromethane ND 50 13 ug/l
75-25-2 Bromoform ND 50 13 ug/l
104-51-8 n-Butylbenzene 52.3 50 13 ug/l
135-98-8 sec-Butylbenzene 40.7 50 13 ug/l J
98-06-6 tert-Butylbenzene ND 50 13 ug/l
56-23-5 Carbon Tetrachloride a ND 50 13 ug/l
108-90-7 Chlorobenzene ND 50 13 ug/l
75-00-3 Chloroethane ND 50 20 ug/l
67-66-3 Chloroform ND 50 13 ug/l
95-49-8 o-Chlorotoluene ND 50 13 ug/l
106-43-4 p-Chlorotoluene ND 50 13 ug/l
124-48-1 Dibromochloromethane ND 50 13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 29 ug/l
106-93-4 1,2-Dibromoethane ND 50 13 ug/l
75-71-8 Dichlorodifluoromethane ND 50 20 ug/l
95-50-1 1,2-Dichlorobenzene ND 50 13 ug/l
541-73-1 1,3-Dichlorobenzene ND 50 13 ug/l
106-46-7 1,4-Dichlorobenzene ND 50 13 ug/l
75-34-3 1,1-Dichloroethane ND 50 13 ug/l
107-06-2 1,2-Dichloroethane ND 50 13 ug/l
75-35-4 1,1-Dichloroethylene ND 50 13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 13 ug/l
78-87-5 1,2-Dichloropropane ND 50 13 ug/l
142-28-9 1,3-Dichloropropane ND 50 13 ug/l
594-20-7 2,2-Dichloropropane ND 50 13 ug/l
563-58-6 1,1-Dichloropropene ND 50 13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 50 13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 41
FA3926033.1
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:GMW-1
Lab Sample ID:FA39260-1 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 113 50 13 ug/l
100-41-4 Ethylbenzene 1570 50 13 ug/l
87-68-3 Hexachlorobutadiene ND 50 13 ug/l
98-82-8 Isopropylbenzene 185 50 13 ug/l
99-87-6 p-Isopropyltoluene 21.8 50 13 ug/l J
74-83-9 Methyl Bromide ND 50 20 ug/l
74-87-3 Methyl Chloride ND 50 20 ug/l
74-95-3 Methylene Bromide ND 50 13 ug/l
75-09-2 Methylene Chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether 44.9 50 13 ug/l J
91-20-3 Naphthalene 1020 50 13 ug/l
103-65-1 n-Propylbenzene 433 50 13 ug/l
100-42-5 Styrene ND 50 13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 13 ug/l
127-18-4 Tetrachloroethylene ND 50 13 ug/l
108-88-3 Toluene 684 50 13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 13 ug/l
71-55-6 1,1,1-Trichloroethane ND 50 13 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 13 ug/l
79-01-6 Trichloroethylene ND 50 13 ug/l
75-69-4 Trichlorofluoromethane ND 50 20 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 14 ug/l
95-63-6 1,2,4-Trimethylbenzene 1640 50 13 ug/l
108-67-8 1,3,5-Trimethylbenzene 360 50 13 ug/l
75-01-4 Vinyl Chloride ND 50 13 ug/l
m,p-Xylene 5940 100 18 ug/l
95-47-6 o-Xylene 97.0 50 13 ug/l
1330-20-7 Xylene (total)6040 150 31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 41
FA3926033.1
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:GMW-2
Lab Sample ID:FA39260-2 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0204365.D 1 12/09/16 TD n/a n/a VA2061
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 6.7 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.67 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.81 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride a ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 41
FA3926033.2
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:GMW-2
Lab Sample ID:FA39260-2 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 18.9 0.50 0.13 ug/l
100-41-4 Ethylbenzene 10.9 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 3.9 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 0.40 0.50 0.13 ug/l J
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 0.44 0.50 0.13 ug/l J
91-20-3 Naphthalene 5.1 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 6.9 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 1.4 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene 2.1 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.31 0.50 0.13 ug/l J
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 6.2 1.0 0.18 ug/l
95-47-6 o-Xylene 0.81 0.50 0.13 ug/l
1330-20-7 Xylene (total)7.0 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 93%70-130%
17060-07-0 1,2-Dichloroethane-D4 111%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 41
FA3926033.2
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:MW-12
Lab Sample ID:FA39260-3 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E049783.D 1 12/09/16 TD n/a n/a VE1652
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 41
FA3926033.3
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:MW-12
Lab Sample ID:FA39260-3 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.18 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 41
FA3926033.3
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:MW-14
Lab Sample ID:FA39260-4 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E049784.D 1 12/09/16 TD n/a n/a VE1652
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 44.1 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 2.5 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 0.23 0.50 0.13 ug/l J
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane a 0.50 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane 0.17 0.50 0.13 ug/l J
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 41
FA3926033.4
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:MW-14
Lab Sample ID:FA39260-4 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 18.1 0.50 0.13 ug/l
100-41-4 Ethylbenzene 3.5 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 4.3 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 1.5 0.50 0.13 ug/l
91-20-3 Naphthalene 17.4 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 12.4 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 2.9 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene 0.52 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.56 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 10.3 1.0 0.18 ug/l
95-47-6 o-Xylene 2.0 0.50 0.13 ug/l
1330-20-7 Xylene (total)12.3 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 97%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
(a) Associated CCV outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 41
FA3926033.4
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:MW-10
Lab Sample ID:FA39260-5 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E049785.D 1 12/09/16 TD n/a n/a VE1652
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 41
FA3926033.5
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:MW-10
Lab Sample ID:FA39260-5 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.57 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 6.5 0.50 0.13 ug/l
91-20-3 Naphthalene 0.18 0.50 0.13 ug/l J
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.18 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
17 of 41
FA3926033.5
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:MW-5
Lab Sample ID:FA39260-6 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E049786.D 1 12/09/16 TD n/a n/a VE1652
Run #2 E049807.D 5 12/10/16 TD n/a n/a VE1653
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 164 a 2.5 0.63 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.74 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene 0.63 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene 1.9 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane b 0.33 0.50 0.20 ug/l J
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane 0.44 0.50 0.13 ug/l J
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 41
FA3926033.6
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:MW-5
Lab Sample ID:FA39260-6 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 4.8 0.50 0.13 ug/l
100-41-4 Ethylbenzene 26.4 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 1.5 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene 1.2 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride 0.31 0.50 0.20 ug/l J
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 24.3 0.50 0.13 ug/l
91-20-3 Naphthalene 87.7 a 2.5 0.63 ug/l
103-65-1 n-Propylbenzene 2.5 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 2.4 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene 27.3 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 3.7 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 21.5 1.0 0.18 ug/l
95-47-6 o-Xylene 1.5 0.50 0.13 ug/l
1330-20-7 Xylene (total)23.0 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%106%70-130%
2037-26-5 Toluene-D8 97%101%70-130%
460-00-4 4-Bromofluorobenzene 107%105%70-130%
(a) Result is from Run# 2
(b) Associated CCV outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 41
FA3926033.6
SGS Accutest
Report of Analysis Page 1 of 2
Client Sample ID:MW-13
Lab Sample ID:FA39260-7 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E049787.D 1 12/09/16 TD n/a n/a VE1652
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 19.1 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene 0.24 0.50 0.13 ug/l J
135-98-8 sec-Butylbenzene 0.17 0.50 0.13 ug/l J
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane a 0.29 0.50 0.20 ug/l J
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene 0.14 0.50 0.13 ug/l J
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 41
FA3926033.7
SGS Accutest
Report of Analysis Page 2 of 2
Client Sample ID:MW-13
Lab Sample ID:FA39260-7 Date Sampled:12/05/16
Matrix:AQ - Ground Water Date Received:12/06/16
Method:SM 6200B Percent Solids:n/a
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.31 0.50 0.13 ug/l J
100-41-4 Ethylbenzene 21.1 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene 0.90 0.50 0.13 ug/l
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 2.0 0.50 0.13 ug/l
91-20-3 Naphthalene 11.4 0.50 0.13 ug/l
103-65-1 n-Propylbenzene 3.0 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene 13.7 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene 7.8 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene 1.1 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene 26.2 1.0 0.18 ug/l
95-47-6 o-Xylene 3.6 0.50 0.13 ug/l
1330-20-7 Xylene (total)29.8 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 93%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
(a) Associated CCV outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 41
FA3926033.7
SGS Accutest
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Southeast
Section 4
22 of 41
FA392604
FA39260: Chain of Custody
Page 1 of 3
23 of 41
FA3926044.1
FA39260: Chain of Custody
Page 2 of 3
24 of 41
FA3926044.1
FA39260: Chain of Custody
Page 3 of 3
25 of 41
FA3926044.1
SGS Accutest
GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 5
26 of 41
FA392605
Method Blank Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1652-MB E049775.D 1 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
27 of 41
FA3926055.1.1
Method Blank Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1652-MB E049775.D 1 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride 1.3 2.0 1.0 ug/l J
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.18 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 105%70-130%
28 of 41
FA3926055.1.1
Method Blank Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2061-MB A0204364.D 1 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.29 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
29 of 41
FA3926055.1.2
Method Blank Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2061-MB A0204364.D 1 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.14 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.18 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.31 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
30 of 41
FA3926055.1.2
Method Blank Summary Page 1 of 1
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1653-MB E049806.D 1 12/10/16 TD n/a n/a VE1653
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-6
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
31 of 41
FA3926055.1.3
Blank Spike Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2061-BS A0204363.D 1 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 11.1 111 70-130
108-86-1 Bromobenzene 10 10.3 103 70-130
74-97-5 Bromochloromethane 10 10.7 107 70-130
75-27-4 Bromodichloromethane 10 10.4 104 70-130
75-25-2 Bromoform 10 9.5 95 70-130
104-51-8 n-Butylbenzene 10 11.1 111 70-130
135-98-8 sec-Butylbenzene 10 11.2 112 70-130
98-06-6 tert-Butylbenzene 10 11.0 110 70-130
56-23-5 Carbon Tetrachloride 10 13.4 134*70-130
108-90-7 Chlorobenzene 10 10.7 107 70-130
75-00-3 Chloroethane 10 11.2 112 60-140
67-66-3 Chloroform 10 10.9 109 70-130
95-49-8 o-Chlorotoluene 10 10.9 109 70-130
106-43-4 p-Chlorotoluene 10 10.6 106 70-130
124-48-1 Dibromochloromethane 10 10.0 100 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.1 91 70-130
106-93-4 1,2-Dibromoethane 10 9.7 97 70-130
75-71-8 Dichlorodifluoromethane 10 10.6 106 60-140
95-50-1 1,2-Dichlorobenzene 10 10.5 105 70-130
541-73-1 1,3-Dichlorobenzene 10 10.6 106 70-130
106-46-7 1,4-Dichlorobenzene 10 10.6 106 70-130
75-34-3 1,1-Dichloroethane 10 11.4 114 70-130
107-06-2 1,2-Dichloroethane 10 10.3 103 70-130
75-35-4 1,1-Dichloroethylene 10 11.9 119 70-130
156-59-2 cis-1,2-Dichloroethylene 10 11.3 113 70-130
156-60-5 trans-1,2-Dichloroethylene 10 11.9 119 70-130
78-87-5 1,2-Dichloropropane 10 10.8 108 70-130
142-28-9 1,3-Dichloropropane 10 9.8 98 70-130
594-20-7 2,2-Dichloropropane 10 12.8 128 70-130
563-58-6 1,1-Dichloropropene 10 11.2 112 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.3 93 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.0 90 70-130
108-20-3 Di-Isopropyl Ether 10 11.6 116 70-130
100-41-4 Ethylbenzene 10 11.3 113 70-130
87-68-3 Hexachlorobutadiene 10 11.2 112 70-130
98-82-8 Isopropylbenzene 10 11.6 116 70-130
* = Outside of Control Limits.
32 of 41
FA3926055.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2061-BS A0204363.D 1 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 11.0 110 70-130
74-83-9 Methyl Bromide 10 12.4 124 60-140
74-87-3 Methyl Chloride 10 10.2 102 60-140
74-95-3 Methylene Bromide 10 9.9 99 70-130
75-09-2 Methylene Chloride 10 11.2 112 70-130
1634-04-4 Methyl Tert Butyl Ether 10 11.2 112 70-130
91-20-3 Naphthalene 10 10.3 103 70-130
103-65-1 n-Propylbenzene 10 10.9 109 70-130
100-42-5 Styrene 10 10.7 107 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 11.3 113 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.9 99 70-130
127-18-4 Tetrachloroethylene 10 10.7 107 70-130
108-88-3 Toluene 10 10.5 105 70-130
87-61-6 1,2,3-Trichlorobenzene 10 10.7 107 70-130
120-82-1 1,2,4-Trichlorobenzene 10 10.7 107 70-130
71-55-6 1,1,1-Trichloroethane 10 12.2 122 70-130
79-00-5 1,1,2-Trichloroethane 10 9.9 99 70-130
79-01-6 Trichloroethylene 10 10.9 109 70-130
75-69-4 Trichlorofluoromethane 10 11.7 117 60-140
96-18-4 1,2,3-Trichloropropane 10 9.7 97 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.7 107 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.9 109 70-130
75-01-4 Vinyl Chloride 10 10.6 106 60-140
m,p-Xylene 20 22.7 114 70-130
95-47-6 o-Xylene 10 11.1 111 70-130
1330-20-7 Xylene (total)30 33.8 113 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 98%70-130%
460-00-4 4-Bromofluorobenzene 95%70-130%
* = Outside of Control Limits.
33 of 41
FA3926055.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1652-BS E049780.D 1 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 11.4 114 70-130
108-86-1 Bromobenzene 10 11.8 118 70-130
74-97-5 Bromochloromethane 10 11.3 113 70-130
75-27-4 Bromodichloromethane 10 11.4 114 70-130
75-25-2 Bromoform 10 10 100 70-130
104-51-8 n-Butylbenzene 10 11.5 115 70-130
135-98-8 sec-Butylbenzene 10 11.7 117 70-130
98-06-6 tert-Butylbenzene 10 12.0 120 70-130
56-23-5 Carbon Tetrachloride 10 11.2 112 70-130
108-90-7 Chlorobenzene 10 11.2 112 70-130
75-00-3 Chloroethane 10 11.2 112 60-140
67-66-3 Chloroform 10 11.2 112 70-130
95-49-8 o-Chlorotoluene 10 11.9 119 70-130
106-43-4 p-Chlorotoluene 10 11.9 119 70-130
124-48-1 Dibromochloromethane 10 11.1 111 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 10.5 105 70-130
106-93-4 1,2-Dibromoethane 10 11.5 115 70-130
75-71-8 Dichlorodifluoromethane 10 9.5 95 60-140
95-50-1 1,2-Dichlorobenzene 10 11.6 116 70-130
541-73-1 1,3-Dichlorobenzene 10 11.6 116 70-130
106-46-7 1,4-Dichlorobenzene 10 11.5 115 70-130
75-34-3 1,1-Dichloroethane 10 11.2 112 70-130
107-06-2 1,2-Dichloroethane 10 11.1 111 70-130
75-35-4 1,1-Dichloroethylene 10 11.3 113 70-130
156-59-2 cis-1,2-Dichloroethylene 10 11.3 113 70-130
156-60-5 trans-1,2-Dichloroethylene 10 11.2 112 70-130
78-87-5 1,2-Dichloropropane 10 11.4 114 70-130
142-28-9 1,3-Dichloropropane 10 11.6 116 70-130
594-20-7 2,2-Dichloropropane 10 11.5 115 70-130
563-58-6 1,1-Dichloropropene 10 11.2 112 70-130
10061-01-5 cis-1,3-Dichloropropene 10 11.5 115 70-130
10061-02-6 trans-1,3-Dichloropropene 10 11.5 115 70-130
108-20-3 Di-Isopropyl Ether 10 11.2 112 70-130
100-41-4 Ethylbenzene 10 11.4 114 70-130
87-68-3 Hexachlorobutadiene 10 10.5 105 70-130
98-82-8 Isopropylbenzene 10 11.5 115 70-130
* = Outside of Control Limits.
34 of 41
FA3926055.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1652-BS E049780.D 1 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 11.7 117 70-130
74-83-9 Methyl Bromide 10 11.0 110 60-140
74-87-3 Methyl Chloride 10 9.1 91 60-140
74-95-3 Methylene Bromide 10 11.3 113 70-130
75-09-2 Methylene Chloride 10 10.4 104 70-130
1634-04-4 Methyl Tert Butyl Ether 10 11.3 113 70-130
91-20-3 Naphthalene 10 11.9 119 70-130
103-65-1 n-Propylbenzene 10 12.0 120 70-130
100-42-5 Styrene 10 11.2 112 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 11.2 112 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 11.9 119 70-130
127-18-4 Tetrachloroethylene 10 11.2 112 70-130
108-88-3 Toluene 10 11.0 110 70-130
87-61-6 1,2,3-Trichlorobenzene 10 11.0 110 70-130
120-82-1 1,2,4-Trichlorobenzene 10 11.1 111 70-130
71-55-6 1,1,1-Trichloroethane 10 11.4 114 70-130
79-00-5 1,1,2-Trichloroethane 10 11.3 113 70-130
79-01-6 Trichloroethylene 10 11.3 113 70-130
75-69-4 Trichlorofluoromethane 10 10.1 101 60-140
96-18-4 1,2,3-Trichloropropane 10 12.2 122 70-130
95-63-6 1,2,4-Trimethylbenzene 10 12.0 120 70-130
108-67-8 1,3,5-Trimethylbenzene 10 12.0 120 70-130
75-01-4 Vinyl Chloride 10 9.9 99 60-140
m,p-Xylene 20 23.4 117 70-130
95-47-6 o-Xylene 10 11.4 114 70-130
1330-20-7 Xylene (total)30 34.7 116 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 104%70-130%
* = Outside of Control Limits.
35 of 41
FA3926055.2.2
Blank Spike Summary Page 1 of 1
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1653-BS E049805.D 1 12/10/16 TD n/a n/a VE1653
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-6
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.5 105 70-130
91-20-3 Naphthalene 10 10.4 104 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 100%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
36 of 41
FA3926055.2.3
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA39178-3MS E049797.D 100 12/09/16 TD n/a n/a VE1652
FA39178-3MSD E049798.D 100 12/09/16 TD n/a n/a VE1652
FA39178-3 E049779.D 100 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
FA39178-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1640 1000 2770 113 1000 2660 102 4 70-130/20
108-86-1 Bromobenzene ND 1000 1150 115 1000 1100 110 4 70-130/20
74-97-5 Bromochloromethane ND 1000 1130 113 1000 1100 110 3 70-130/20
75-27-4 Bromodichloromethane ND 1000 1140 114 1000 1090 109 4 70-130/20
75-25-2 Bromoform ND 1000 874 87 1000 821 82 6 70-130/20
104-51-8 n-Butylbenzene ND 1000 1190 119 1000 1100 110 8 70-130/20
135-98-8 sec-Butylbenzene ND 1000 1280 128 1000 1190 119 7 70-130/20
98-06-6 tert-Butylbenzene ND 1000 1260 126 1000 1180 118 7 70-130/20
56-23-5 Carbon Tetrachloride ND 1000 1150 115 1000 1110 111 4 70-130/20
108-90-7 Chlorobenzene ND 1000 1140 114 1000 1090 109 4 70-130/20
75-00-3 Chloroethane ND 1000 1030 103 1000 1010 101 2 60-140/20
67-66-3 Chloroform ND 1000 1140 114 1000 1090 109 4 70-130/20
95-49-8 o-Chlorotoluene 105 1000 1330 123 1000 1240 114 7 70-130/20
106-43-4 p-Chlorotoluene ND 1000 1220 122 1000 1140 114 7 70-130/20
124-48-1 Dibromochloromethane ND 1000 1050 105 1000 993 99 6 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 951 95 1000 924 92 3 70-130/20
106-93-4 1,2-Dibromoethane ND 1000 1120 112 1000 1080 108 4 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 828 83 1000 770 77 7 60-140/20
95-50-1 1,2-Dichlorobenzene ND 1000 1120 112 1000 1070 107 5 70-130/20
541-73-1 1,3-Dichlorobenzene ND 1000 1160 116 1000 1090 109 6 70-130/20
106-46-7 1,4-Dichlorobenzene ND 1000 1140 114 1000 1060 106 7 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 1190 119 1000 1150 115 3 70-130/20
107-06-2 1,2-Dichloroethane ND 1000 1150 115 1000 1090 109 5 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 1190 119 1000 1140 114 4 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 1060 106 1000 1040 104 2 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 1270 127 1000 1220 122 4 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 1160 116 1000 1110 111 4 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 1110 111 1000 1070 107 4 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 1120 112 1000 1080 108 4 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 1120 112 1000 1070 107 5 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 1120 112 1000 1090 109 3 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 1210 121 1000 1160 116 4 70-130/20
108-20-3 Di-Isopropyl Ether ND 1000 1170 117 1000 1150 115 2 70-130/20
100-41-4 Ethylbenzene 252 1000 1410 116 1000 1320 107 7 70-130/20
87-68-3 Hexachlorobutadiene ND 1000 1040 104 1000 981 98 6 70-130/20
98-82-8 Isopropylbenzene 14.6 J 1000 1210 120 1000 1140 113 6 70-130/20
* = Outside of Control Limits.
37 of 41
FA3926055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA39178-3MS E049797.D 100 12/09/16 TD n/a n/a VE1652
FA39178-3MSD E049798.D 100 12/09/16 TD n/a n/a VE1652
FA39178-3 E049779.D 100 12/09/16 TD n/a n/a VE1652
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-3, FA39260-4, FA39260-5, FA39260-6, FA39260-7
FA39178-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 16.4 J 1000 1240 122 1000 1150 113 8 70-130/20
74-83-9 Methyl Bromide ND 1000 904 90 1000 823 82 9 60-140/20
74-87-3 Methyl Chloride ND 1000 803 80 1000 771 77 4 60-140/20
74-95-3 Methylene Bromide ND 1000 1140 114 1000 1090 109 4 70-130/20
75-09-2 Methylene Chloride ND 1000 1110 111 1000 1060 106 5 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 1000 1130 113 1000 1120 112 1 70-130/20
91-20-3 Naphthalene 370 1000 1400 103 1000 1380 101 1 70-130/20
103-65-1 n-Propylbenzene 26.4 J 1000 1310 128 1000 1220 119 7 70-130/20
100-42-5 Styrene ND 1000 1130 113 1000 1080 108 5 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 1110 111 1000 1060 106 5 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 1140 114 1000 1100 110 4 70-130/20
127-18-4 Tetrachloroethylene ND 1000 1150 115 1000 1090 109 5 70-130/20
108-88-3 Toluene 1240 1000 2320 108 1000 2190 95 6 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 1010 101 1000 988 99 2 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 1040 104 1000 1010 101 3 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 1120 112 1000 1070 107 5 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 1150 115 1000 1110 111 4 70-130/20
79-01-6 Trichloroethylene ND 1000 1170 117 1000 1120 112 4 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 928 93 1000 814 81 13 60-140/20
96-18-4 1,2,3-Trichloropropane ND 1000 1160 116 1000 1140 114 2 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1790 1000 2880 109 1000 2690 90 7 70-130/20
108-67-8 1,3,5-Trimethylbenzene 913 1000 2070 116 1000 1940 103 6 70-130/20
75-01-4 Vinyl Chloride ND 1000 837 84 1000 799 80 5 60-140/20
m,p-Xylene 4390 2000 6410 101 2000 6080 85 5 70-130/20
95-47-6 o-Xylene 3080 1000 4070 99 1000 3860 78 5 70-130/20
1330-20-7 Xylene (total)7470 3000 10500 101 3000 9930 82 6 70-130/20
CAS No.Surrogate Recoveries MS MSD FA39178-3 Limits
1868-53-7 Dibromofluoromethane 99%99%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 105%104%102%70-130%
2037-26-5 Toluene-D8 100%98%98%70-130%
460-00-4 4-Bromofluorobenzene 106%105%103%70-130%
* = Outside of Control Limits.
38 of 41
FA3926055.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA39260-1MS A0204388.D 100 12/09/16 TD n/a n/a VA2061
FA39260-1MSD A0204389.D 100 12/09/16 TD n/a n/a VA2061
FA39260-1 A0204366.D 100 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
FA39260-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 2280 1000 3450 117 1000 3150 87 9 70-130/20
108-86-1 Bromobenzene ND 1000 998 100 1000 919 92 8 70-130/20
74-97-5 Bromochloromethane ND 1000 1040 104 1000 979 98 6 70-130/20
75-27-4 Bromodichloromethane ND 1000 921 92 1000 881 88 4 70-130/20
75-25-2 Bromoform ND 1000 553 55*1000 585 59*6 70-130/20
104-51-8 n-Butylbenzene 52.3 1000 1060 101 1000 945 89 11 70-130/20
135-98-8 sec-Butylbenzene 40.7 J 1000 1120 108 1000 1010 97 10 70-130/20
98-06-6 tert-Butylbenzene ND 1000 1060 106 1000 962 96 10 70-130/20
56-23-5 Carbon Tetrachloride ND 1000 1190 119 1000 1050 105 13 70-130/20
108-90-7 Chlorobenzene ND 1000 1030 103 1000 941 94 9 70-130/20
75-00-3 Chloroethane ND 1000 1080 108 1000 888 89 20 60-140/20
67-66-3 Chloroform ND 1000 1030 103 1000 936 94 10 70-130/20
95-49-8 o-Chlorotoluene ND 1000 1100 110 1000 1000 100 10 70-130/20
106-43-4 p-Chlorotoluene ND 1000 1010 101 1000 918 92 10 70-130/20
124-48-1 Dibromochloromethane ND 1000 762 76 1000 764 76 0 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 791 79 1000 776 78 2 70-130/20
106-93-4 1,2-Dibromoethane ND 1000 937 94 1000 918 92 2 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 1050 105 1000 883 88 17 60-140/20
95-50-1 1,2-Dichlorobenzene ND 1000 985 99 1000 911 91 8 70-130/20
541-73-1 1,3-Dichlorobenzene ND 1000 1010 101 1000 926 93 9 70-130/20
106-46-7 1,4-Dichlorobenzene ND 1000 994 99 1000 912 91 9 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 1120 112 1000 1010 101 10 70-130/20
107-06-2 1,2-Dichloroethane ND 1000 982 98 1000 958 96 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 1110 111 1000 968 97 14 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 1030 103 1000 924 92 11 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 1210 121 1000 1060 106 13 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 1030 103 1000 964 96 7 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 909 91 1000 873 87 4 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 1040 104 1000 881 88 17 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 1030 103 1000 912 91 12 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 790 79 1000 781 78 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 785 79 1000 793 79 1 70-130/20
108-20-3 Di-Isopropyl Ether 113 1000 1210 110 1000 1130 102 7 70-130/20
100-41-4 Ethylbenzene 1570 1000 2640 107 1000 2380 81 10 70-130/20
87-68-3 Hexachlorobutadiene ND 1000 1020 102 1000 898 90 13 70-130/20
98-82-8 Isopropylbenzene 185 1000 1270 109 1000 1140 96 11 70-130/20
* = Outside of Control Limits.
39 of 41
FA3926055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA39260-1MS A0204388.D 100 12/09/16 TD n/a n/a VA2061
FA39260-1MSD A0204389.D 100 12/09/16 TD n/a n/a VA2061
FA39260-1 A0204366.D 100 12/09/16 TD n/a n/a VA2061
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-1, FA39260-2
FA39260-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene 21.8 J 1000 1080 106 1000 974 95 10 70-130/20
74-83-9 Methyl Bromide ND 1000 1140 114 1000 1030 103 10 60-140/20
74-87-3 Methyl Chloride ND 1000 1080 108 1000 948 95 13 60-140/20
74-95-3 Methylene Bromide ND 1000 962 96 1000 927 93 4 70-130/20
75-09-2 Methylene Chloride ND 1000 1040 104 1000 970 97 7 70-130/20
1634-04-4 Methyl Tert Butyl Ether 44.9 J 1000 1100 106 1000 1030 99 7 70-130/20
91-20-3 Naphthalene 1020 1000 2110 109 1000 2010 99 5 70-130/20
103-65-1 n-Propylbenzene 433 1000 1520 109 1000 1370 94 10 70-130/20
100-42-5 Styrene ND 1000 980 98 1000 894 89 9 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 1000 100 1000 937 94 7 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 938 94 1000 905 91 4 70-130/20
127-18-4 Tetrachloroethylene ND 1000 1050 105 1000 922 92 13 70-130/20
108-88-3 Toluene 684 1000 1710 103 1000 1570 89 9 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 970 97 1000 920 92 5 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 969 97 1000 903 90 7 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 1070 107 1000 943 94 13 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 1020 102 1000 983 98 4 70-130/20
79-01-6 Trichloroethylene ND 1000 1060 106 1000 947 95 11 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 1140 114 1000 966 97 17 60-140/20
96-18-4 1,2,3-Trichloropropane ND 1000 921 92 1000 898 90 3 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1640 1000 2710 107 1000 2460 82 10 70-130/20
108-67-8 1,3,5-Trimethylbenzene 360 1000 1410 105 1000 1270 91 10 70-130/20
75-01-4 Vinyl Chloride ND 1000 1060 106 1000 906 91 16 60-140/20
m,p-Xylene 5940 2000 7990 103 2000 7190 63* a 11 70-130/20
95-47-6 o-Xylene 97.0 1000 1110 101 1000 1010 91 9 70-130/20
1330-20-7 Xylene (total)6040 3000 9100 102 3000 8200 72 10 70-130/20
CAS No.Surrogate Recoveries MS MSD FA39260-1 Limits
1868-53-7 Dibromofluoromethane 101%101%100%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%103%102%70-130%
2037-26-5 Toluene-D8 97%97%97%70-130%
460-00-4 4-Bromofluorobenzene 98%98%97%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
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FA3926055.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA39260
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sahara Food Mart/Greenapple; 1304 US 13 S, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA39260-6MS E049829.D 5 12/10/16 TD n/a n/a VE1653
FA39260-6MSD E049830.D 5 12/10/16 TD n/a n/a VE1653
FA39260-6 E049807.D 5 12/10/16 TD n/a n/a VE1653
The QC reported here applies to the following samples:Method: SM 6200B
FA39260-6
FA39260-6 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 164 50 212 96 50 204 80 4 70-130/20
91-20-3 Naphthalene 87.7 50 148 121 50 138 101 7 70-130/20
CAS No.Surrogate Recoveries MS MSD FA39260-6 Limits
1868-53-7 Dibromofluoromethane 99%98%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%102%106%70-130%
2037-26-5 Toluene-D8 100%99%101%70-130%
460-00-4 4-Bromofluorobenzene 107%106%105%70-130%
* = Outside of Control Limits.
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FA3926055.3.3