WA-803_11086_CA_MMPE_20141120

10/14/14
Technical Report for
GRI (Geological Resources Inc.)
Ram 40; 901 Memorial Dr, Ahoskie, NC
Accutest Job Number: FA18889
Sampling Date: 10/03/14
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: Nicole Long
Total number of pages in report:
Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001)
DoD ELAP (L-A-B L2229), CA (04226CA), TX (T104704404), PA (68-03573), VA (460177),
AK, AR, GA, KY, MA, NV, OK, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Norm Farmer
Technical Director
Southeast
10/14/14
e-Hardcopy 2.0
Automated Report
33
Accutest Laboratories is the sole authority for authorizing edits or modifications to this
document. Unauthorized modification of this report is strictly prohibited.
1 of 33
FA18889
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA18889-1: MW-10 ......................................................................................................7
3.2: FA18889-2: MW-11 ......................................................................................................9
3.3: FA18889-3: PMW-6 .....................................................................................................11
3.4: FA18889-4: PMW-3 .....................................................................................................13
3.5: FA18889-5: RW-3 .........................................................................................................15
Section 4: Misc. Forms ............................................................................................................17
4.1: Chain of Custody ...........................................................................................................18
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................21
5.1: Method Blank Summary ................................................................................................22
5.2: Blank Spike Summary ...................................................................................................26
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................30 123452 of 33
FA18889
Accutest Laboratories
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA18889
Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA18889-1 10/03/14 09:38 HM 10/04/14 AQ Ground Water MW-10
FA18889-2 10/03/14 09:46 HM 10/04/14 AQ Ground Water MW-11
FA18889-3 10/03/14 09:59 HM 10/04/14 AQ Ground Water PMW-6
FA18889-4 10/03/14 10:08 HM 10/04/14 AQ Ground Water PMW-3
FA18889-5 10/03/14 09:25 HM 10/04/14 AQ Ground Water RW-3
3 of 33
FA18889 1
Summary of Hits Page 1 of 2
Job Number:FA18889
Account:GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Collected:10/03/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA18889-1 MW-10
Benzene 2820 50 10 ug/l SM 6200B
1,2-Dibromoethane 20.9 J 50 10 ug/l SM 6200B
1,2-Dichloroethane 23.9 J 50 10 ug/l SM 6200B
Ethylbenzene 122 50 10 ug/l SM 6200B
Naphthalene 48.3 J 50 10 ug/l SM 6200B
n-Propylbenzene 44.2 J 50 10 ug/l SM 6200B
1,2,4-Trimethylbenzene 286 50 10 ug/l SM 6200B
1,3,5-Trimethylbenzene 101 50 10 ug/l SM 6200B
Toluene 2400 50 10 ug/l SM 6200B
Xylene (total)673 150 20 ug/l SM 6200B
m,p-Xylene 477 100 10 ug/l SM 6200B
o-Xylene 196 50 10 ug/l SM 6200B
FA18889-2 MW-11
Benzene 5690 250 50 ug/l SM 6200B
1,2-Dibromoethane 95.1 J 250 50 ug/l SM 6200B
1,2-Dichloroethane 83.8 J 250 50 ug/l SM 6200B
Ethylbenzene 1700 250 50 ug/l SM 6200B
Isopropylbenzene 64.3 J 250 50 ug/l SM 6200B
Naphthalene 445 250 50 ug/l SM 6200B
n-Propylbenzene 214 J 250 50 ug/l SM 6200B
1,2,4-Trimethylbenzene 1500 250 50 ug/l SM 6200B
1,3,5-Trimethylbenzene 399 250 50 ug/l SM 6200B
Toluene 13900 250 50 ug/l SM 6200B
Xylene (total)8920 750 100 ug/l SM 6200B
m,p-Xylene 6180 500 50 ug/l SM 6200B
o-Xylene 2740 250 50 ug/l SM 6200B
FA18889-3 PMW-6
Benzene 2670 500 100 ug/l SM 6200B
Ethylbenzene 2940 500 100 ug/l SM 6200B
Naphthalene 426 J 500 100 ug/l SM 6200B
1,2,4-Trimethylbenzene 1370 500 100 ug/l SM 6200B
1,3,5-Trimethylbenzene 396 J 500 100 ug/l SM 6200B
Toluene 34000 500 100 ug/l SM 6200B
Xylene (total)19000 1500 200 ug/l SM 6200B
m,p-Xylene 12800 1000 100 ug/l SM 6200B
o-Xylene 6200 500 100 ug/l SM 6200B
4 of 33
FA18889 2
Summary of Hits Page 2 of 2
Job Number:FA18889
Account:GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Collected:10/03/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA18889-4 PMW-3
Benzene 3600 250 50 ug/l SM 6200B
Ethylbenzene 1310 250 50 ug/l SM 6200B
Methyl Tert Butyl Ether 429 250 50 ug/l SM 6200B
Naphthalene 717 250 50 ug/l SM 6200B
n-Propylbenzene 59.9 J 250 50 ug/l SM 6200B
Styrene 55.3 J 250 50 ug/l SM 6200B
1,2,4-Trimethylbenzene 2270 250 50 ug/l SM 6200B
1,3,5-Trimethylbenzene 655 250 50 ug/l SM 6200B
Toluene 20200 250 50 ug/l SM 6200B
Xylene (total)16100 750 100 ug/l SM 6200B
m,p-Xylene 10300 500 50 ug/l SM 6200B
o-Xylene 5760 250 50 ug/l SM 6200B
FA18889-5 RW-3
Benzene 3830 130 25 ug/l SM 6200B
Ethylbenzene 1930 130 25 ug/l SM 6200B
Isopropylbenzene 58.6 J 130 25 ug/l SM 6200B
Naphthalene 547 130 25 ug/l SM 6200B
n-Propylbenzene 192 130 25 ug/l SM 6200B
1,2,4-Trimethylbenzene 1970 130 25 ug/l SM 6200B
1,3,5-Trimethylbenzene 470 130 25 ug/l SM 6200B
Toluene 11700 250 50 ug/l SM 6200B
Xylene (total)11500 380 50 ug/l SM 6200B
m,p-Xylene 8020 250 25 ug/l SM 6200B
o-Xylene 3450 130 25 ug/l SM 6200B
5 of 33
FA18889 2
Accutest Laboratories
Sample Results
Report of Analysis
Southeast
Section 3
6 of 33
FA18889 3
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-10
Lab Sample ID:FA18889-1 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E033828.D 100 10/10/14 EG n/a n/a VE1128
Run #2 a A0190000.D 100 10/09/14 EG n/a n/a VA1565
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2820 50 10 ug/l
108-86-1 Bromobenzene ND 50 10 ug/l
74-97-5 Bromochloromethane ND 50 10 ug/l
75-27-4 Bromodichloromethane ND 50 10 ug/l
75-25-2 Bromoform ND 50 10 ug/l
104-51-8 n-Butylbenzene ND 50 10 ug/l
135-98-8 sec-Butylbenzene ND 50 10 ug/l
98-06-6 tert-Butylbenzene ND 50 10 ug/l
108-90-7 Chlorobenzene ND 50 10 ug/l
75-00-3 Chloroethane ND 50 12 ug/l
67-66-3 Chloroform ND 50 10 ug/l
95-49-8 o-Chlorotoluene ND 50 10 ug/l
106-43-4 p-Chlorotoluene ND 50 10 ug/l
56-23-5 Carbon tetrachloride b ND 50 10 ug/l
75-34-3 1,1-Dichloroethane ND 50 10 ug/l
75-35-4 1,1-Dichloroethylene ND 50 10 ug/l
563-58-6 1,1-Dichloropropene ND 50 10 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 50 17 ug/l
106-93-4 1,2-Dibromoethane 20.9 50 10 ug/l J
107-06-2 1,2-Dichloroethane 23.9 50 10 ug/l J
78-87-5 1,2-Dichloropropane ND 50 10 ug/l
142-28-9 1,3-Dichloropropane ND 50 10 ug/l
108-20-3 Di-Isopropyl ether ND 50 10 ug/l
594-20-7 2,2-Dichloropropane b ND 50 10 ug/l
124-48-1 Dibromochloromethane ND 50 10 ug/l
75-71-8 Dichlorodifluoromethane ND 50 10 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 50 10 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 50 10 ug/l
541-73-1 m-Dichlorobenzene ND 50 10 ug/l
95-50-1 o-Dichlorobenzene ND 50 10 ug/l
106-46-7 p-Dichlorobenzene ND 50 10 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 50 10 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 33
FA18889 33.1
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-10
Lab Sample ID:FA18889-1 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 50 10 ug/l
100-41-4 Ethylbenzene 122 50 10 ug/l
87-68-3 Hexachlorobutadiene b ND 50 10 ug/l
98-82-8 Isopropylbenzene ND 50 10 ug/l
99-87-6 p-Isopropyltoluene ND 50 10 ug/l
74-83-9 Methyl bromide ND 50 10 ug/l
74-87-3 Methyl chloride ND 50 10 ug/l
74-95-3 Methylene bromide ND 50 10 ug/l
75-09-2 Methylene chloride ND 200 100 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 50 10 ug/l
91-20-3 Naphthalene 48.3 50 10 ug/l J
103-65-1 n-Propylbenzene 44.2 50 10 ug/l J
100-42-5 Styrene ND 50 10 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 50 10 ug/l
71-55-6 1,1,1-Trichloroethane b ND 50 10 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 50 10 ug/l
79-00-5 1,1,2-Trichloroethane ND 50 11 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 50 10 ug/l
96-18-4 1,2,3-Trichloropropane ND 50 12 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 50 10 ug/l
95-63-6 1,2,4-Trimethylbenzene 286 50 10 ug/l
108-67-8 1,3,5-Trimethylbenzene 101 50 10 ug/l
127-18-4 Tetrachloroethylene ND 50 10 ug/l
108-88-3 Toluene 2400 50 10 ug/l
79-01-6 Trichloroethylene ND 50 10 ug/l
75-69-4 Trichlorofluoromethane b ND 50 10 ug/l
75-01-4 Vinyl chloride ND 50 10 ug/l
1330-20-7 Xylene (total)673 150 20 ug/l
m,p-Xylene 477 100 10 ug/l
95-47-6 o-Xylene 196 50 10 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 113%106%70-130%
17060-07-0 1,2-Dichloroethane-D4 122%109%70-130%
2037-26-5 Toluene-D8 96%103%70-130%
460-00-4 4-Bromofluorobenzene 96%103%70-130%
(a) Confirmation run.
(b) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 33
FA18889 33.1
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-11
Lab Sample ID:FA18889-2 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E033829.D 500 10/10/14 EG n/a n/a VE1128
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 5690 250 50 ug/l
108-86-1 Bromobenzene ND 250 50 ug/l
74-97-5 Bromochloromethane ND 250 50 ug/l
75-27-4 Bromodichloromethane ND 250 50 ug/l
75-25-2 Bromoform ND 250 50 ug/l
104-51-8 n-Butylbenzene ND 250 50 ug/l
135-98-8 sec-Butylbenzene ND 250 50 ug/l
98-06-6 tert-Butylbenzene ND 250 50 ug/l
108-90-7 Chlorobenzene ND 250 50 ug/l
75-00-3 Chloroethane ND 250 61 ug/l
67-66-3 Chloroform ND 250 50 ug/l
95-49-8 o-Chlorotoluene ND 250 50 ug/l
106-43-4 p-Chlorotoluene ND 250 50 ug/l
56-23-5 Carbon tetrachloride a ND 250 50 ug/l
75-34-3 1,1-Dichloroethane ND 250 50 ug/l
75-35-4 1,1-Dichloroethylene ND 250 50 ug/l
563-58-6 1,1-Dichloropropene ND 250 50 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 86 ug/l
106-93-4 1,2-Dibromoethane 95.1 250 50 ug/l J
107-06-2 1,2-Dichloroethane 83.8 250 50 ug/l J
78-87-5 1,2-Dichloropropane ND 250 50 ug/l
142-28-9 1,3-Dichloropropane ND 250 50 ug/l
108-20-3 Di-Isopropyl ether ND 250 50 ug/l
594-20-7 2,2-Dichloropropane a ND 250 50 ug/l
124-48-1 Dibromochloromethane ND 250 50 ug/l
75-71-8 Dichlorodifluoromethane ND 250 50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 50 ug/l
541-73-1 m-Dichlorobenzene ND 250 50 ug/l
95-50-1 o-Dichlorobenzene ND 250 50 ug/l
106-46-7 p-Dichlorobenzene ND 250 50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 50 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 33
FA18889 33.2
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-11
Lab Sample ID:FA18889-2 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 250 50 ug/l
100-41-4 Ethylbenzene 1700 250 50 ug/l
87-68-3 Hexachlorobutadiene a ND 250 50 ug/l
98-82-8 Isopropylbenzene 64.3 250 50 ug/l J
99-87-6 p-Isopropyltoluene ND 250 50 ug/l
74-83-9 Methyl bromide ND 250 50 ug/l
74-87-3 Methyl chloride ND 250 50 ug/l
74-95-3 Methylene bromide ND 250 50 ug/l
75-09-2 Methylene chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 250 50 ug/l
91-20-3 Naphthalene 445 250 50 ug/l
103-65-1 n-Propylbenzene 214 250 50 ug/l J
100-42-5 Styrene ND 250 50 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 250 50 ug/l
71-55-6 1,1,1-Trichloroethane a ND 250 50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 50 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 53 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 50 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 59 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 50 ug/l
95-63-6 1,2,4-Trimethylbenzene 1500 250 50 ug/l
108-67-8 1,3,5-Trimethylbenzene 399 250 50 ug/l
127-18-4 Tetrachloroethylene ND 250 50 ug/l
108-88-3 Toluene 13900 250 50 ug/l
79-01-6 Trichloroethylene ND 250 50 ug/l
75-69-4 Trichlorofluoromethane a ND 250 50 ug/l
75-01-4 Vinyl chloride ND 250 50 ug/l
1330-20-7 Xylene (total)8920 750 100 ug/l
m,p-Xylene 6180 500 50 ug/l
95-47-6 o-Xylene 2740 250 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 117%70-130%
17060-07-0 1,2-Dichloroethane-D4 123%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 33
FA18889 33.2
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:PMW-6
Lab Sample ID:FA18889-3 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E033833.D 1000 10/10/14 EG n/a n/a VE1128
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 2670 500 100 ug/l
108-86-1 Bromobenzene ND 500 100 ug/l
74-97-5 Bromochloromethane ND 500 100 ug/l
75-27-4 Bromodichloromethane ND 500 100 ug/l
75-25-2 Bromoform ND 500 100 ug/l
104-51-8 n-Butylbenzene ND 500 100 ug/l
135-98-8 sec-Butylbenzene ND 500 100 ug/l
98-06-6 tert-Butylbenzene ND 500 100 ug/l
108-90-7 Chlorobenzene ND 500 100 ug/l
75-00-3 Chloroethane ND 500 120 ug/l
67-66-3 Chloroform ND 500 100 ug/l
95-49-8 o-Chlorotoluene ND 500 100 ug/l
106-43-4 p-Chlorotoluene ND 500 100 ug/l
56-23-5 Carbon tetrachloride a ND 500 100 ug/l
75-34-3 1,1-Dichloroethane ND 500 100 ug/l
75-35-4 1,1-Dichloroethylene ND 500 100 ug/l
563-58-6 1,1-Dichloropropene ND 500 100 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 500 170 ug/l
106-93-4 1,2-Dibromoethane ND 500 100 ug/l
107-06-2 1,2-Dichloroethane ND 500 100 ug/l
78-87-5 1,2-Dichloropropane ND 500 100 ug/l
142-28-9 1,3-Dichloropropane ND 500 100 ug/l
108-20-3 Di-Isopropyl ether ND 500 100 ug/l
594-20-7 2,2-Dichloropropane a ND 500 100 ug/l
124-48-1 Dibromochloromethane ND 500 100 ug/l
75-71-8 Dichlorodifluoromethane ND 500 100 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 500 100 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 500 100 ug/l
541-73-1 m-Dichlorobenzene ND 500 100 ug/l
95-50-1 o-Dichlorobenzene ND 500 100 ug/l
106-46-7 p-Dichlorobenzene ND 500 100 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 500 100 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 33
FA18889 33.3
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:PMW-6
Lab Sample ID:FA18889-3 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 500 100 ug/l
100-41-4 Ethylbenzene 2940 500 100 ug/l
87-68-3 Hexachlorobutadiene a ND 500 100 ug/l
98-82-8 Isopropylbenzene ND 500 100 ug/l
99-87-6 p-Isopropyltoluene ND 500 100 ug/l
74-83-9 Methyl bromide ND 500 100 ug/l
74-87-3 Methyl chloride ND 500 100 ug/l
74-95-3 Methylene bromide ND 500 100 ug/l
75-09-2 Methylene chloride ND 2000 1000 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 500 100 ug/l
91-20-3 Naphthalene 426 500 100 ug/l J
103-65-1 n-Propylbenzene ND 500 100 ug/l
100-42-5 Styrene ND 500 100 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 500 100 ug/l
71-55-6 1,1,1-Trichloroethane a ND 500 100 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 500 100 ug/l
79-00-5 1,1,2-Trichloroethane ND 500 110 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 500 100 ug/l
96-18-4 1,2,3-Trichloropropane ND 500 120 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 500 100 ug/l
95-63-6 1,2,4-Trimethylbenzene 1370 500 100 ug/l
108-67-8 1,3,5-Trimethylbenzene 396 500 100 ug/l J
127-18-4 Tetrachloroethylene ND 500 100 ug/l
108-88-3 Toluene 34000 500 100 ug/l
79-01-6 Trichloroethylene ND 500 100 ug/l
75-69-4 Trichlorofluoromethane a ND 500 100 ug/l
75-01-4 Vinyl chloride ND 500 100 ug/l
1330-20-7 Xylene (total)19000 1500 200 ug/l
m,p-Xylene 12800 1000 100 ug/l
95-47-6 o-Xylene 6200 500 100 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 112%70-130%
17060-07-0 1,2-Dichloroethane-D4 120%70-130%
2037-26-5 Toluene-D8 95%70-130%
460-00-4 4-Bromofluorobenzene 97%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 33
FA18889 33.3
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:PMW-3
Lab Sample ID:FA18889-4 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E033834.D 500 10/10/14 EG n/a n/a VE1128
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3600 250 50 ug/l
108-86-1 Bromobenzene ND 250 50 ug/l
74-97-5 Bromochloromethane ND 250 50 ug/l
75-27-4 Bromodichloromethane ND 250 50 ug/l
75-25-2 Bromoform ND 250 50 ug/l
104-51-8 n-Butylbenzene ND 250 50 ug/l
135-98-8 sec-Butylbenzene ND 250 50 ug/l
98-06-6 tert-Butylbenzene ND 250 50 ug/l
108-90-7 Chlorobenzene ND 250 50 ug/l
75-00-3 Chloroethane ND 250 61 ug/l
67-66-3 Chloroform ND 250 50 ug/l
95-49-8 o-Chlorotoluene ND 250 50 ug/l
106-43-4 p-Chlorotoluene ND 250 50 ug/l
56-23-5 Carbon tetrachloride a ND 250 50 ug/l
75-34-3 1,1-Dichloroethane ND 250 50 ug/l
75-35-4 1,1-Dichloroethylene ND 250 50 ug/l
563-58-6 1,1-Dichloropropene ND 250 50 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 250 86 ug/l
106-93-4 1,2-Dibromoethane ND 250 50 ug/l
107-06-2 1,2-Dichloroethane ND 250 50 ug/l
78-87-5 1,2-Dichloropropane ND 250 50 ug/l
142-28-9 1,3-Dichloropropane ND 250 50 ug/l
108-20-3 Di-Isopropyl ether ND 250 50 ug/l
594-20-7 2,2-Dichloropropane a ND 250 50 ug/l
124-48-1 Dibromochloromethane ND 250 50 ug/l
75-71-8 Dichlorodifluoromethane ND 250 50 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 250 50 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 250 50 ug/l
541-73-1 m-Dichlorobenzene ND 250 50 ug/l
95-50-1 o-Dichlorobenzene ND 250 50 ug/l
106-46-7 p-Dichlorobenzene ND 250 50 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 250 50 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 33
FA18889 33.4
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:PMW-3
Lab Sample ID:FA18889-4 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 250 50 ug/l
100-41-4 Ethylbenzene 1310 250 50 ug/l
87-68-3 Hexachlorobutadiene a ND 250 50 ug/l
98-82-8 Isopropylbenzene ND 250 50 ug/l
99-87-6 p-Isopropyltoluene ND 250 50 ug/l
74-83-9 Methyl bromide ND 250 50 ug/l
74-87-3 Methyl chloride ND 250 50 ug/l
74-95-3 Methylene bromide ND 250 50 ug/l
75-09-2 Methylene chloride ND 1000 500 ug/l
1634-04-4 Methyl Tert Butyl Ether 429 250 50 ug/l
91-20-3 Naphthalene 717 250 50 ug/l
103-65-1 n-Propylbenzene 59.9 250 50 ug/l J
100-42-5 Styrene 55.3 250 50 ug/l J
630-20-6 1,1,1,2-Tetrachloroethane ND 250 50 ug/l
71-55-6 1,1,1-Trichloroethane a ND 250 50 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 250 50 ug/l
79-00-5 1,1,2-Trichloroethane ND 250 53 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 250 50 ug/l
96-18-4 1,2,3-Trichloropropane ND 250 59 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 250 50 ug/l
95-63-6 1,2,4-Trimethylbenzene 2270 250 50 ug/l
108-67-8 1,3,5-Trimethylbenzene 655 250 50 ug/l
127-18-4 Tetrachloroethylene ND 250 50 ug/l
108-88-3 Toluene 20200 250 50 ug/l
79-01-6 Trichloroethylene ND 250 50 ug/l
75-69-4 Trichlorofluoromethane a ND 250 50 ug/l
75-01-4 Vinyl chloride ND 250 50 ug/l
1330-20-7 Xylene (total)16100 750 100 ug/l
m,p-Xylene 10300 500 50 ug/l
95-47-6 o-Xylene 5760 250 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 113%70-130%
17060-07-0 1,2-Dichloroethane-D4 121%70-130%
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
(a) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 33
FA18889 33.4
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:RW-3
Lab Sample ID:FA18889-5 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0190004.D 250 10/09/14 EG n/a n/a VA1565
Run #2 E033835.D 500 10/10/14 EG n/a n/a VE1128
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 3830 130 25 ug/l
108-86-1 Bromobenzene ND 130 25 ug/l
74-97-5 Bromochloromethane ND 130 25 ug/l
75-27-4 Bromodichloromethane ND 130 25 ug/l
75-25-2 Bromoform ND 130 25 ug/l
104-51-8 n-Butylbenzene ND 130 25 ug/l
135-98-8 sec-Butylbenzene ND 130 25 ug/l
98-06-6 tert-Butylbenzene ND 130 25 ug/l
108-90-7 Chlorobenzene ND 130 25 ug/l
75-00-3 Chloroethane ND 130 31 ug/l
67-66-3 Chloroform ND 130 25 ug/l
95-49-8 o-Chlorotoluene ND 130 25 ug/l
106-43-4 p-Chlorotoluene ND 130 25 ug/l
56-23-5 Carbon tetrachloride ND 130 25 ug/l
75-34-3 1,1-Dichloroethane ND 130 25 ug/l
75-35-4 1,1-Dichloroethylene ND 130 25 ug/l
563-58-6 1,1-Dichloropropene ND 130 25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 130 43 ug/l
106-93-4 1,2-Dibromoethane ND 130 25 ug/l
107-06-2 1,2-Dichloroethane ND 130 25 ug/l
78-87-5 1,2-Dichloropropane ND 130 25 ug/l
142-28-9 1,3-Dichloropropane ND 130 25 ug/l
108-20-3 Di-Isopropyl ether ND 130 25 ug/l
594-20-7 2,2-Dichloropropane ND 130 25 ug/l
124-48-1 Dibromochloromethane ND 130 25 ug/l
75-71-8 Dichlorodifluoromethane ND 130 25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 130 25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 130 25 ug/l
541-73-1 m-Dichlorobenzene ND 130 25 ug/l
95-50-1 o-Dichlorobenzene ND 130 25 ug/l
106-46-7 p-Dichlorobenzene ND 130 25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 130 25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 33
FA18889 33.5
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:RW-3
Lab Sample ID:FA18889-5 Date Sampled:10/03/14
Matrix:AQ - Ground Water Date Received:10/04/14
Method:SM 6200B Percent Solids:n/a
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 130 25 ug/l
100-41-4 Ethylbenzene 1930 130 25 ug/l
87-68-3 Hexachlorobutadiene ND 130 25 ug/l
98-82-8 Isopropylbenzene 58.6 130 25 ug/l J
99-87-6 p-Isopropyltoluene ND 130 25 ug/l
74-83-9 Methyl bromide ND 130 25 ug/l
74-87-3 Methyl chloride ND 130 25 ug/l
74-95-3 Methylene bromide ND 130 25 ug/l
75-09-2 Methylene chloride ND 500 250 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 130 25 ug/l
91-20-3 Naphthalene 547 130 25 ug/l
103-65-1 n-Propylbenzene 192 130 25 ug/l
100-42-5 Styrene ND 130 25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 130 25 ug/l
71-55-6 1,1,1-Trichloroethane ND 130 25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 130 25 ug/l
79-00-5 1,1,2-Trichloroethane ND 130 26 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 130 25 ug/l
96-18-4 1,2,3-Trichloropropane ND 130 30 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 130 25 ug/l
95-63-6 1,2,4-Trimethylbenzene 1970 130 25 ug/l
108-67-8 1,3,5-Trimethylbenzene 470 130 25 ug/l
127-18-4 Tetrachloroethylene ND 130 25 ug/l
108-88-3 Toluene 11700 a 250 50 ug/l
79-01-6 Trichloroethylene ND 130 25 ug/l
75-69-4 Trichlorofluoromethane ND 130 25 ug/l
75-01-4 Vinyl chloride ND 130 25 ug/l
1330-20-7 Xylene (total)11500 380 50 ug/l
m,p-Xylene 8020 250 25 ug/l
95-47-6 o-Xylene 3450 130 25 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 105%114%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%123%70-130%
2037-26-5 Toluene-D8 99%93%70-130%
460-00-4 4-Bromofluorobenzene 100%95%70-130%
(a) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 33
FA18889 33.5
Accutest Laboratories
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Southeast
Section 4
17 of 33
FA18889 4
FA18889: Chain of Custody
Page 1 of 3
18 of 33
FA18889 44.1
FA18889: Chain of Custody
Page 2 of 3
19 of 33
FA18889 44.1
FA18889: Chain of Custody
Page 3 of 3
20 of 33
FA18889 44.1
Accutest Laboratories
GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 5
21 of 33
FA18889 5
Method Blank Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA1565-MB A0189996.D 1 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.10 ug/l
108-86-1 Bromobenzene ND 0.50 0.10 ug/l
74-97-5 Bromochloromethane ND 0.50 0.10 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l
75-25-2 Bromoform ND 0.50 0.10 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l
108-90-7 Chlorobenzene ND 0.50 0.10 ug/l
75-00-3 Chloroethane ND 0.50 0.12 ug/l
67-66-3 Chloroform ND 0.50 0.10 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l
56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.10 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l
108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l
100-41-4 Ethylbenzene ND 0.50 0.10 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l
22 of 33
FA18889 55.1.1
Method Blank Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA1565-MB A0189996.D 1 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l
74-83-9 Methyl bromide ND 0.50 0.10 ug/l
74-87-3 Methyl chloride ND 0.50 0.10 ug/l
74-95-3 Methylene bromide ND 0.50 0.10 ug/l
75-09-2 Methylene chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l
100-42-5 Styrene ND 0.50 0.10 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l
79-01-6 Trichloroethylene ND 0.50 0.10 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.10 ug/l
75-01-4 Vinyl chloride ND 0.50 0.10 ug/l
1330-20-7 Xylene (total)ND 1.5 0.20 ug/l
m,p-Xylene ND 1.0 0.10 ug/l
95-47-6 o-Xylene ND 0.50 0.10 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 106%70-130%
23 of 33
FA18889 55.1.1
Method Blank Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1128-MB E033823.D 1 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.10 ug/l
108-86-1 Bromobenzene ND 0.50 0.10 ug/l
74-97-5 Bromochloromethane ND 0.50 0.10 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l
75-25-2 Bromoform ND 0.50 0.10 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l
108-90-7 Chlorobenzene ND 0.50 0.10 ug/l
75-00-3 Chloroethane ND 0.50 0.12 ug/l
67-66-3 Chloroform ND 0.50 0.10 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l
56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.10 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l
108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l
100-41-4 Ethylbenzene ND 0.50 0.10 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l
24 of 33
FA18889 55.1.2
Method Blank Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1128-MB E033823.D 1 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l
74-83-9 Methyl bromide ND 0.50 0.10 ug/l
74-87-3 Methyl chloride ND 0.50 0.10 ug/l
74-95-3 Methylene bromide ND 0.50 0.10 ug/l
75-09-2 Methylene chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l
100-42-5 Styrene ND 0.50 0.10 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l
108-88-3 Toluene ND 0.50 0.10 ug/l
79-01-6 Trichloroethylene ND 0.50 0.10 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.10 ug/l
75-01-4 Vinyl chloride ND 0.50 0.10 ug/l
1330-20-7 Xylene (total)ND 1.5 0.20 ug/l
m,p-Xylene ND 1.0 0.10 ug/l
95-47-6 o-Xylene ND 0.50 0.10 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 104%70-130%
17060-07-0 1,2-Dichloroethane-D4 113%70-130%
2037-26-5 Toluene-D8 96%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
25 of 33
FA18889 55.1.2
Blank Spike Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA1565-BS A0189994.D 1 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.2 102 70-130
108-86-1 Bromobenzene 10 9.8 98 70-130
74-97-5 Bromochloromethane 10 9.9 99 70-130
75-27-4 Bromodichloromethane 10 10.2 102 70-130
75-25-2 Bromoform 10 9.4 94 70-130
104-51-8 n-Butylbenzene 10 10.6 106 70-130
135-98-8 sec-Butylbenzene 10 11.8 118 70-130
98-06-6 tert-Butylbenzene 10 11.7 117 70-130
108-90-7 Chlorobenzene 10 10.7 107 70-130
75-00-3 Chloroethane 10 10.8 108 60-140
67-66-3 Chloroform 10 9.5 95 70-130
95-49-8 o-Chlorotoluene 10 10.8 108 70-130
106-43-4 p-Chlorotoluene 10 11.4 114 70-130
56-23-5 Carbon tetrachloride 10 10.8 108 70-130
75-34-3 1,1-Dichloroethane 10 10.1 101 70-130
75-35-4 1,1-Dichloroethylene 10 10.8 108 70-130
563-58-6 1,1-Dichloropropene 10 11.2 112 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 8.6 86 70-130
106-93-4 1,2-Dibromoethane 10 10.0 100 70-130
107-06-2 1,2-Dichloroethane 10 10.2 102 70-130
78-87-5 1,2-Dichloropropane 10 9.8 98 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
108-20-3 Di-Isopropyl ether 10 10.1 101 70-130
594-20-7 2,2-Dichloropropane 10 11.4 114 70-130
124-48-1 Dibromochloromethane 10 9.9 99 70-130
75-71-8 Dichlorodifluoromethane 10 11.0 110 60-140
156-59-2 cis-1,2-Dichloroethylene 10 10.2 102 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.1 101 70-130
541-73-1 m-Dichlorobenzene 10 10.9 109 70-130
95-50-1 o-Dichlorobenzene 10 10.4 104 70-130
106-46-7 p-Dichlorobenzene 10 9.7 97 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.1 101 70-130
10061-02-6 trans-1,3-Dichloropropene 10 11.2 112 70-130
100-41-4 Ethylbenzene 10 10.4 104 70-130
87-68-3 Hexachlorobutadiene 10 10.5 105 70-130
98-82-8 Isopropylbenzene 10 11.9 119 70-130
* = Outside of Control Limits.
26 of 33
FA18889 55.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA1565-BS A0189994.D 1 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 11.7 117 70-130
74-83-9 Methyl bromide 10 10.7 107 60-140
74-87-3 Methyl chloride 10 10.5 105 60-140
74-95-3 Methylene bromide 10 9.9 99 70-130
75-09-2 Methylene chloride 10 9.2 92 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.0 100 70-130
91-20-3 Naphthalene 10 9.5 95 70-130
103-65-1 n-Propylbenzene 10 11.3 113 70-130
100-42-5 Styrene 10 10.6 106 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10.0 100 70-130
71-55-6 1,1,1-Trichloroethane 10 10.7 107 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.3 93 70-130
79-00-5 1,1,2-Trichloroethane 10 9.5 95 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.5 95 70-130
96-18-4 1,2,3-Trichloropropane 10 9.4 94 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.7 97 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.6 106 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.3 103 70-130
127-18-4 Tetrachloroethylene 10 10.6 106 70-130
79-01-6 Trichloroethylene 10 10.2 102 70-130
75-69-4 Trichlorofluoromethane 10 11.7 117 60-140
75-01-4 Vinyl chloride 10 11.3 113 60-140
1330-20-7 Xylene (total)30 33.0 110 70-130
m,p-Xylene 20 21.8 109 70-130
95-47-6 o-Xylene 10 11.2 112 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 103%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 99%70-130%
* = Outside of Control Limits.
27 of 33
FA18889 55.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1128-BS E033821.D 1 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.1 101 70-130
108-86-1 Bromobenzene 10 10.6 106 70-130
74-97-5 Bromochloromethane 10 11.2 112 70-130
75-27-4 Bromodichloromethane 10 11.8 118 70-130
75-25-2 Bromoform 10 11.6 116 70-130
104-51-8 n-Butylbenzene 10 10.6 106 70-130
135-98-8 sec-Butylbenzene 10 11.9 119 70-130
98-06-6 tert-Butylbenzene 10 12.4 124 70-130
108-90-7 Chlorobenzene 10 11.2 112 70-130
75-00-3 Chloroethane 10 11.8 118 60-140
67-66-3 Chloroform 10 11.6 116 70-130
95-49-8 o-Chlorotoluene 10 11.1 111 70-130
106-43-4 p-Chlorotoluene 10 11.4 114 70-130
56-23-5 Carbon tetrachloride 10 13.6 136*70-130
75-34-3 1,1-Dichloroethane 10 10.5 105 70-130
75-35-4 1,1-Dichloroethylene 10 11.9 119 70-130
563-58-6 1,1-Dichloropropene 10 12.0 120 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 10.3 103 70-130
106-93-4 1,2-Dibromoethane 10 10.5 105 70-130
107-06-2 1,2-Dichloroethane 10 12.1 121 70-130
78-87-5 1,2-Dichloropropane 10 9.3 93 70-130
142-28-9 1,3-Dichloropropane 10 9.4 94 70-130
108-20-3 Di-Isopropyl ether 10 8.9 89 70-130
594-20-7 2,2-Dichloropropane 10 13.7 137*70-130
124-48-1 Dibromochloromethane 10 11.1 111 70-130
75-71-8 Dichlorodifluoromethane 10 11.4 114 60-140
156-59-2 cis-1,2-Dichloroethylene 10 10.4 104 70-130
10061-01-5 cis-1,3-Dichloropropene 10 10.6 106 70-130
541-73-1 m-Dichlorobenzene 10 11.8 118 70-130
95-50-1 o-Dichlorobenzene 10 11.6 116 70-130
106-46-7 p-Dichlorobenzene 10 10.6 106 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.7 107 70-130
10061-02-6 trans-1,3-Dichloropropene 10 11.3 113 70-130
100-41-4 Ethylbenzene 10 10.4 104 70-130
87-68-3 Hexachlorobutadiene 10 13.4 134*70-130
98-82-8 Isopropylbenzene 10 12.3 123 70-130
* = Outside of Control Limits.
28 of 33
FA18889 55.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE1128-BS E033821.D 1 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 12.1 121 70-130
74-83-9 Methyl bromide 10 13.5 135 60-140
74-87-3 Methyl chloride 10 9.8 98 60-140
74-95-3 Methylene bromide 10 11.2 112 70-130
75-09-2 Methylene chloride 10 9.0 90 70-130
1634-04-4 Methyl Tert Butyl Ether 10 10.6 106 70-130
91-20-3 Naphthalene 10 10.7 107 70-130
103-65-1 n-Propylbenzene 10 11.4 114 70-130
100-42-5 Styrene 10 10.5 105 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 11.3 113 70-130
71-55-6 1,1,1-Trichloroethane 10 13.2 132*70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.0 90 70-130
79-00-5 1,1,2-Trichloroethane 10 9.2 92 70-130
87-61-6 1,2,3-Trichlorobenzene 10 11.4 114 70-130
96-18-4 1,2,3-Trichloropropane 10 10.8 108 70-130
120-82-1 1,2,4-Trichlorobenzene 10 11.3 113 70-130
95-63-6 1,2,4-Trimethylbenzene 10 10.9 109 70-130
108-67-8 1,3,5-Trimethylbenzene 10 10.8 108 70-130
127-18-4 Tetrachloroethylene 10 11.9 119 70-130
108-88-3 Toluene 10 9.7 97 70-130
79-01-6 Trichloroethylene 10 11.4 114 70-130
75-69-4 Trichlorofluoromethane 10 14.6 146*60-140
75-01-4 Vinyl chloride 10 11.5 115 60-140
1330-20-7 Xylene (total)30 34.2 114 70-130
m,p-Xylene 20 22.7 114 70-130
95-47-6 o-Xylene 10 11.6 116 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 110%70-130%
17060-07-0 1,2-Dichloroethane-D4 121%70-130%
2037-26-5 Toluene-D8 94%70-130%
460-00-4 4-Bromofluorobenzene 95%70-130%
* = Outside of Control Limits.
29 of 33
FA18889 55.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA18889-1MS A0190005.D 100 10/09/14 EG n/a n/a VA1565
FA18889-1MSD A0190006.D 100 10/09/14 EG n/a n/a VA1565
FA18889-1 a A0190000.D 100 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
FA18889-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 3570 1000 4510 94 1000 4090 52* b 10 70-130/20
108-86-1 Bromobenzene ND 1000 995 100 1000 896 90 10 70-130/20
74-97-5 Bromochloromethane ND 1000 1030 103 1000 931 93 10 70-130/20
75-27-4 Bromodichloromethane ND 1000 1080 108 1000 943 94 14 70-130/20
75-25-2 Bromoform ND 1000 952 95 1000 847 85 12 70-130/20
104-51-8 n-Butylbenzene 12.8 J 1000 1110 110 1000 990 98 11 70-130/20
135-98-8 sec-Butylbenzene ND 1000 1200 120 1000 1090 109 10 70-130/20
98-06-6 tert-Butylbenzene ND 1000 1190 119 1000 1080 108 10 70-130/20
108-90-7 Chlorobenzene ND 1000 1080 108 1000 965 97 11 70-130/20
75-00-3 Chloroethane ND 1000 1040 104 1000 1010 101 3 60-140/20
67-66-3 Chloroform ND 1000 983 98 1000 864 86 13 70-130/20
95-49-8 o-Chlorotoluene ND 1000 1120 112 1000 1010 101 10 70-130/20
106-43-4 p-Chlorotoluene ND 1000 1130 113 1000 1020 102 10 70-130/20
56-23-5 Carbon tetrachloride ND 1000 1120 112 1000 988 99 13 70-130/20
75-34-3 1,1-Dichloroethane ND 1000 1060 106 1000 927 93 13 70-130/20
75-35-4 1,1-Dichloroethylene ND 1000 1110 111 1000 998 100 11 70-130/20
563-58-6 1,1-Dichloropropene ND 1000 1140 114 1000 1010 101 12 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 1000 928 93 1000 846 85 9 70-130/20
106-93-4 1,2-Dibromoethane 22.0 J 1000 1020 100 1000 944 92 8 70-130/20
107-06-2 1,2-Dichloroethane 25.8 J 1000 1090 106 1000 972 95 11 70-130/20
78-87-5 1,2-Dichloropropane ND 1000 995 100 1000 917 92 8 70-130/20
142-28-9 1,3-Dichloropropane ND 1000 977 98 1000 903 90 8 70-130/20
108-20-3 Di-Isopropyl ether ND 1000 1040 104 1000 931 93 11 70-130/20
594-20-7 2,2-Dichloropropane ND 1000 1150 115 1000 1020 102 12 70-130/20
124-48-1 Dibromochloromethane ND 1000 1010 101 1000 915 92 10 70-130/20
75-71-8 Dichlorodifluoromethane ND 1000 1100 110 1000 989 99 11 60-140/20
156-59-2 cis-1,2-Dichloroethylene ND 1000 1020 102 1000 914 91 11 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 1000 1020 102 1000 933 93 9 70-130/20
541-73-1 m-Dichlorobenzene ND 1000 1100 110 1000 1000 100 10 70-130/20
95-50-1 o-Dichlorobenzene ND 1000 1070 107 1000 965 97 10 70-130/20
106-46-7 p-Dichlorobenzene ND 1000 982 98 1000 898 90 9 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 1000 1050 105 1000 922 92 13 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 1000 1140 114 1000 1020 102 11 70-130/20
100-41-4 Ethylbenzene 156 1000 1200 104 1000 1080 92 11 70-130/20
87-68-3 Hexachlorobutadiene ND 1000 1100 110 1000 995 100 10 70-130/20
98-82-8 Isopropylbenzene 12.6 J 1000 1210 120 1000 1060 105 13 70-130/20
* = Outside of Control Limits.
30 of 33
FA18889 55.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA18889-1MS A0190005.D 100 10/09/14 EG n/a n/a VA1565
FA18889-1MSD A0190006.D 100 10/09/14 EG n/a n/a VA1565
FA18889-1 a A0190000.D 100 10/09/14 EG n/a n/a VA1565
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-5
FA18889-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 1000 1190 119 1000 1070 107 11 70-130/20
74-83-9 Methyl bromide ND 1000 1040 104 1000 976 98 6 60-140/20
74-87-3 Methyl chloride ND 1000 1000 100 1000 965 97 4 60-140/20
74-95-3 Methylene bromide ND 1000 1030 103 1000 946 95 9 70-130/20
75-09-2 Methylene chloride ND 1000 1020 102 1000 891 89 14 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 1000 1190 119 1000 1080 108 10 70-130/20
91-20-3 Naphthalene 53.5 1000 1060 101 1000 993 94 7 70-130/20
103-65-1 n-Propylbenzene 60.5 1000 1190 113 1000 1080 102 10 70-130/20
100-42-5 Styrene ND 1000 1070 107 1000 950 95 12 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 1000 1030 103 1000 921 92 11 70-130/20
71-55-6 1,1,1-Trichloroethane ND 1000 1090 109 1000 971 97 12 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 1000 948 95 1000 882 88 7 70-130/20
79-00-5 1,1,2-Trichloroethane ND 1000 975 98 1000 906 91 7 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 1000 1000 100 1000 914 91 9 70-130/20
96-18-4 1,2,3-Trichloropropane ND 1000 969 97 1000 906 91 7 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 1000 1060 106 1000 947 95 11 70-130/20
95-63-6 1,2,4-Trimethylbenzene 427 1000 1540 111 1000 1390 96 10 70-130/20
108-67-8 1,3,5-Trimethylbenzene 148 1000 1210 106 1000 1090 94 10 70-130/20
127-18-4 Tetrachloroethylene ND 1000 1060 106 1000 947 95 11 70-130/20
79-01-6 Trichloroethylene ND 1000 1050 105 1000 931 93 12 70-130/20
75-69-4 Trichlorofluoromethane ND 1000 1180 118 1000 1050 105 12 60-140/20
75-01-4 Vinyl chloride ND 1000 1060 106 1000 1030 103 3 60-140/20
1330-20-7 Xylene (total)857 3000 4240 113 3000 3790 98 11 70-130/20
m,p-Xylene 605 2000 2810 110 2000 2520 96 11 70-130/20
95-47-6 o-Xylene 252 1000 1430 118 1000 1270 102 12 70-130/20
CAS No.Surrogate Recoveries MS MSD FA18889-1 Limits
1868-53-7 Dibromofluoromethane 106%103%106%70-130%
17060-07-0 1,2-Dichloroethane-D4 110%107%109%70-130%
2037-26-5 Toluene-D8 97%98%103%70-130%
460-00-4 4-Bromofluorobenzene 97%100%103%70-130%
(a) Confirmation run.
(b) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
31 of 33
FA18889 55.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA18889-2MS E033830.D 500 10/10/14 EG n/a n/a VE1128
FA18889-2MSD E033831.D 500 10/10/14 EG n/a n/a VE1128
FA18889-2 E033829.D 500 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
FA18889-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 5690 5000 10300 92 5000 10700 100 4 70-130/20
108-86-1 Bromobenzene ND 5000 5080 102 5000 5340 107 5 70-130/20
74-97-5 Bromochloromethane ND 5000 5300 106 5000 5700 114 7 70-130/20
75-27-4 Bromodichloromethane ND 5000 5890 118 5000 6200 124 5 70-130/20
75-25-2 Bromoform ND 5000 5610 112 5000 5980 120 6 70-130/20
104-51-8 n-Butylbenzene ND 5000 4950 99 5000 5180 104 5 70-130/20
135-98-8 sec-Butylbenzene ND 5000 5620 112 5000 5800 116 3 70-130/20
98-06-6 tert-Butylbenzene ND 5000 5980 120 5000 6100 122 2 70-130/20
108-90-7 Chlorobenzene ND 5000 5310 106 5000 5500 110 4 70-130/20
75-00-3 Chloroethane ND 5000 5430 109 5000 5460 109 1 60-140/20
67-66-3 Chloroform ND 5000 5680 114 5000 5850 117 3 70-130/20
95-49-8 o-Chlorotoluene ND 5000 5380 108 5000 5600 112 4 70-130/20
106-43-4 p-Chlorotoluene ND 5000 5310 106 5000 5520 110 4 70-130/20
56-23-5 Carbon tetrachloride ND 5000 6910 138*5000 6930 139*0 70-130/20
75-34-3 1,1-Dichloroethane ND 5000 5070 101 5000 5230 105 3 70-130/20
75-35-4 1,1-Dichloroethylene ND 5000 5870 117 5000 5960 119 2 70-130/20
563-58-6 1,1-Dichloropropene ND 5000 5780 116 5000 5850 117 1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 5000 4640 93 5000 5190 104 11 70-130/20
106-93-4 1,2-Dibromoethane 95.1 J 5000 4950 97 5000 5480 108 10 70-130/20
107-06-2 1,2-Dichloroethane 83.8 J 5000 6070 120 5000 6410 127 5 70-130/20
78-87-5 1,2-Dichloropropane ND 5000 4500 90 5000 4810 96 7 70-130/20
142-28-9 1,3-Dichloropropane ND 5000 4360 87 5000 4740 95 8 70-130/20
108-20-3 Di-Isopropyl ether ND 5000 4300 86 5000 4570 91 6 70-130/20
594-20-7 2,2-Dichloropropane ND 5000 6700 134*5000 6690 134*0 70-130/20
124-48-1 Dibromochloromethane ND 5000 5370 107 5000 5660 113 5 70-130/20
75-71-8 Dichlorodifluoromethane ND 5000 5350 107 5000 5340 107 0 60-140/20
156-59-2 cis-1,2-Dichloroethylene ND 5000 5030 101 5000 5270 105 5 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 5000 5080 102 5000 5400 108 6 70-130/20
541-73-1 m-Dichlorobenzene ND 5000 5510 110 5000 5870 117 6 70-130/20
95-50-1 o-Dichlorobenzene ND 5000 5470 109 5000 5810 116 6 70-130/20
106-46-7 p-Dichlorobenzene ND 5000 5080 102 5000 5300 106 4 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 5000 5150 103 5000 5290 106 3 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 5000 5240 105 5000 5610 112 7 70-130/20
100-41-4 Ethylbenzene 1700 5000 6700 100 5000 6920 104 3 70-130/20
87-68-3 Hexachlorobutadiene ND 5000 6380 128 5000 6490 130 2 70-130/20
98-82-8 Isopropylbenzene 64.3 J 5000 5980 118 5000 6170 122 3 70-130/20
* = Outside of Control Limits.
32 of 33
FA18889 55.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA18889
Account:GRINCC GRI (Geological Resources Inc.)
Project:Ram 40; 901 Memorial Dr, Ahoskie, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA18889-2MS E033830.D 500 10/10/14 EG n/a n/a VE1128
FA18889-2MSD E033831.D 500 10/10/14 EG n/a n/a VE1128
FA18889-2 E033829.D 500 10/10/14 EG n/a n/a VE1128
The QC reported here applies to the following samples:Method: SM 6200B
FA18889-1, FA18889-2, FA18889-3, FA18889-4, FA18889-5
FA18889-2 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 5000 5790 116 5000 5930 119 2 70-130/20
74-83-9 Methyl bromide ND 5000 6330 127 5000 6530 131 3 60-140/20
74-87-3 Methyl chloride ND 5000 4250 85 5000 4590 92 8 60-140/20
74-95-3 Methylene bromide ND 5000 5560 111 5000 5710 114 3 70-130/20
75-09-2 Methylene chloride ND 5000 4380 88 5000 4580 92 4 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 5000 5170 103 5000 5450 109 5 70-130/20
91-20-3 Naphthalene 445 5000 5410 99 5000 5930 110 9 70-130/20
103-65-1 n-Propylbenzene 214 J 5000 5570 107 5000 5700 110 2 70-130/20
100-42-5 Styrene ND 5000 5060 101 5000 5440 109 7 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 5000 5590 112 5000 5730 115 2 70-130/20
71-55-6 1,1,1-Trichloroethane ND 5000 6630 133*5000 6840 137*3 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 5000 4200 84 5000 4430 89 5 70-130/20
79-00-5 1,1,2-Trichloroethane ND 5000 4320 86 5000 4600 92 6 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 5000 5320 106 5000 5720 114 7 70-130/20
96-18-4 1,2,3-Trichloropropane ND 5000 4970 99 5000 5270 105 6 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 5000 5340 107 5000 5660 113 6 70-130/20
95-63-6 1,2,4-Trimethylbenzene 1500 5000 6800 106 5000 7120 112 5 70-130/20
108-67-8 1,3,5-Trimethylbenzene 399 5000 5570 103 5000 5780 108 4 70-130/20
127-18-4 Tetrachloroethylene ND 5000 5660 113 5000 5630 113 1 70-130/20
108-88-3 Toluene 13900 5000 17100 64* a 5000 17800 78 4 70-130/20
79-01-6 Trichloroethylene ND 5000 5540 111 5000 5630 113 2 70-130/20
75-69-4 Trichlorofluoromethane ND 5000 7210 144*5000 6980 140 3 60-140/20
75-01-4 Vinyl chloride ND 5000 5040 101 5000 5330 107 6 60-140/20
1330-20-7 Xylene (total)8920 15000 25200 109 15000 26100 115 4 70-130/20
m,p-Xylene 6180 10000 16700 105 10000 17300 111 4 70-130/20
95-47-6 o-Xylene 2740 5000 8500 115 5000 8760 120 3 70-130/20
CAS No.Surrogate Recoveries MS MSD FA18889-2 Limits
1868-53-7 Dibromofluoromethane 115%113%117%70-130%
17060-07-0 1,2-Dichloroethane-D4 127%122%123%70-130%
2037-26-5 Toluene-D8 92%92%95%70-130%
460-00-4 4-Bromofluorobenzene 95%95%96%70-130%
(a) Outside control limits due to high level in sample relative to spike amount.
* = Outside of Control Limits.
33 of 33
FA18889 55.3.2