WA-802_11085_CA_MRP_20180925

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
September 25, 2018

Mr. Jeff Welti
North Carolina Department of
Environmental Quality
Washington Regional Office
943 Washington Square Mall
Washington, North Carolina 27889

Re: September 2018 Ground Water Sampling
Granny’s Grill/Leggett’s Grocery
1727 & 1731 US Highway 13
Windsor, Bertie County
Incident No. 11085/12111
GRI Project No. 2924

Dear Mr. Welti,

Geological Resources, Inc. (GRI) presents this information to complete the scope of work that was
requested and approved as Task Authorization (TA) 11085-56 for the above referenced site (Figure 1).
These activities were conducted in accordance with the North Carolina Department of Environmental
Quality (NCDEQ) correspondence dated March 23, 2018. Please find enclosed the applicable site
location map, site map and laboratory report for the above referenced site.

Ground water samples were collected from three Type II monitoring wells (MW-3, MW-10, and MW-17)
on September 4, 2018. The collected ground water samples were submitted for laboratory analyses of
volatile organic compounds using EPA Method 6200B. Concentrations of requested method constituents
that exceeded the Maximum Allowable Concentrations specified in T15A NCAC 2L.0202 were reported
in the ground water samples collected from MW-3, MW-10 and MW-17. None of the reported
contaminant concentrations exceeded the Gross Contamination Levels.

Additionally, field parameters were collected during the ground water sampling event, and the ORC-A
socks installed in February 2018 were returned to the respective wells following the completion of the
September 2018 sampling event.

Please do not hesitate to contact the undersigned at [phone] if you have any questions or require
additional information.

Granny’s Grill/Leggett’s Grocery
September 2018 Ground Water Sampling
Page 2 of 2

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

Sincerely,

William Regenthal, P. G.
Project Manager

Enclosures: Site Location Map, Site Map and Laboratory Report
cc: file

09/11/18
Technical Report for
GRI (Geological Resources Inc.)
Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
11085/2924
SGS Job Number: FA57384
Sampling Date: 09/04/18
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]
ATTN: Nicole Long
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Caitlin Brice, M.S.
General Manager
Orlando, FL 09/11/18
e-Hardcopy 2.0
Automated Report
25
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
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1 of 25
FA57384
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................6
3.1: FA57384-1: MW-3 ........................................................................................................7
3.2: FA57384-2: MW-10 ......................................................................................................9
3.3: FA57384-3: MW-17 ......................................................................................................11
Section 4: Misc. Forms ............................................................................................................13
4.1: Chain of Custody ...........................................................................................................14
Section 5: MS Volatiles - QC Data Summaries .....................................................................16
5.1: Method Blank Summary ................................................................................................17
5.2: Blank Spike Summary ...................................................................................................20
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................23 123452 of 25
FA57384
SGS North America Inc.
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA57384
Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Project No: 11085/2924
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA57384-1 09/04/18 10:24 ER 09/05/18 AQ Ground Water MW-3
FA57384-2 09/04/18 10:46 ER 09/05/18 AQ Ground Water MW-10
FA57384-3 09/04/18 10:37 ER 09/05/18 AQ Ground Water MW-17
3 of 25
FA573841
Summary of Hits Page 1 of 2
Job Number:FA57384
Account:GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Collected:09/04/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA57384-1 MW-3
Benzene 949 25 6.3 ug/l SM 6200B
Chloroethane 9.9 J 10 4.0 ug/l SM 6200B
1,2-Dichloroethane 12.6 10 2.5 ug/l SM 6200B
Di-Isopropyl Ether 6.2 J 10 2.5 ug/l SM 6200B
Ethylbenzene 132 10 2.5 ug/l SM 6200B
Isopropylbenzene 6.8 J 10 2.5 ug/l SM 6200B
Methyl Chloride 9.6 J 10 4.0 ug/l SM 6200B
Naphthalene 163 10 2.5 ug/l SM 6200B
n-Propylbenzene 16.8 10 2.5 ug/l SM 6200B
Toluene 185 10 2.5 ug/l SM 6200B
m,p-Xylene 19.9 J 20 2.5 ug/l SM 6200B
o-Xylene 10.2 10 2.5 ug/l SM 6200B
Xylene (total)30.1 30 5.0 ug/l SM 6200B
FA57384-2 MW-10
Benzene 470 5.0 1.3 ug/l SM 6200B
n-Butylbenzene 4.1 J 5.0 1.3 ug/l SM 6200B
sec-Butylbenzene 3.2 J 5.0 1.3 ug/l SM 6200B
o-Chlorotoluene 6.3 5.0 1.3 ug/l SM 6200B
1,2-Dichloroethane 100 5.0 1.3 ug/l SM 6200B
Di-Isopropyl Ether 19.3 5.0 1.3 ug/l SM 6200B
Ethylbenzene 182 5.0 1.3 ug/l SM 6200B
Isopropylbenzene 21.5 5.0 1.3 ug/l SM 6200B
Naphthalene 147 5.0 1.3 ug/l SM 6200B
n-Propylbenzene 56.1 5.0 1.3 ug/l SM 6200B
Toluene 66.0 5.0 1.3 ug/l SM 6200B
1,2,4-Trimethylbenzene 230 5.0 1.3 ug/l SM 6200B
1,3,5-Trimethylbenzene 54.5 5.0 1.3 ug/l SM 6200B
m,p-Xylene 125 10 1.3 ug/l SM 6200B
o-Xylene 190 5.0 1.3 ug/l SM 6200B
Xylene (total)315 15 2.5 ug/l SM 6200B
FA57384-3 MW-17
Benzene a 91.3 1.0 0.25 ug/l SM 6200B
n-Butylbenzene a 0.68 J 1.0 0.25 ug/l SM 6200B
sec-Butylbenzene a 0.45 J 1.0 0.25 ug/l SM 6200B
1,2-Dichloroethane a 3.4 1.0 0.25 ug/l SM 6200B
Di-Isopropyl Ether a 0.57 J 1.0 0.25 ug/l SM 6200B
Ethylbenzene a 27.6 1.0 0.25 ug/l SM 6200B
Isopropylbenzene a 1.9 1.0 0.25 ug/l SM 6200B
Naphthalene a 18.1 1.0 0.25 ug/l SM 6200B
4 of 25
FA573842
Summary of Hits Page 2 of 2
Job Number:FA57384
Account:GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Collected:09/04/18
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
n-Propylbenzene a 4.8 1.0 0.25 ug/l SM 6200B
Toluene a 12.5 1.0 0.25 ug/l SM 6200B
1,2,3-Trichloropropane a 0.42 J 1.0 0.25 ug/l SM 6200B
1,2,4-Trimethylbenzene a 6.6 1.0 0.25 ug/l SM 6200B
m,p-Xylene a 8.1 2.0 0.25 ug/l SM 6200B
o-Xylene a 6.3 1.0 0.25 ug/l SM 6200B
Xylene (total) a 14.5 3.0 0.50 ug/l SM 6200B
(a) Sample was not preserved to a pH < 2.
5 of 25
FA573842
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
6 of 25
FA573843
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-3
Lab Sample ID:FA57384-1 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215226.D 20 09/10/18 13:36 AB n/a n/a VA2452
Run #2 A0215203.D 50 09/07/18 15:17 AB n/a n/a VA2451
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 949 a 25 6.3 ug/l
108-86-1 Bromobenzene ND 10 2.5 ug/l
74-97-5 Bromochloromethane ND 10 2.5 ug/l
75-27-4 Bromodichloromethane ND 10 2.5 ug/l
75-25-2 Bromoform ND 10 2.5 ug/l
104-51-8 n-Butylbenzene ND 10 2.5 ug/l
135-98-8 sec-Butylbenzene ND 10 2.5 ug/l
98-06-6 tert-Butylbenzene ND 10 2.5 ug/l
56-23-5 Carbon Tetrachloride ND 10 2.5 ug/l
108-90-7 Chlorobenzene ND 10 2.5 ug/l
75-00-3 Chloroethane 9.9 10 4.0 ug/l J
67-66-3 Chloroform ND 10 2.5 ug/l
95-49-8 o-Chlorotoluene ND 10 2.5 ug/l
106-43-4 p-Chlorotoluene ND 10 2.5 ug/l
124-48-1 Dibromochloromethane ND 10 2.5 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 10 4.9 ug/l
106-93-4 1,2-Dibromoethane ND 10 2.5 ug/l
75-71-8 Dichlorodifluoromethane b ND 10 4.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 10 2.5 ug/l
541-73-1 1,3-Dichlorobenzene ND 10 2.5 ug/l
106-46-7 1,4-Dichlorobenzene ND 10 2.5 ug/l
75-34-3 1,1-Dichloroethane ND 10 2.5 ug/l
107-06-2 1,2-Dichloroethane 12.6 10 2.5 ug/l
75-35-4 1,1-Dichloroethylene ND 10 2.5 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 10 2.5 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 10 2.5 ug/l
78-87-5 1,2-Dichloropropane ND 10 2.5 ug/l
142-28-9 1,3-Dichloropropane ND 10 2.5 ug/l
594-20-7 2,2-Dichloropropane ND 10 2.5 ug/l
563-58-6 1,1-Dichloropropene ND 10 2.5 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 10 2.5 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 10 2.5 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 25
FA5738433.1
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-3
Lab Sample ID:FA57384-1 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 6.2 10 2.5 ug/l J
100-41-4 Ethylbenzene 132 10 2.5 ug/l
87-68-3 Hexachlorobutadiene ND 10 2.5 ug/l
98-82-8 Isopropylbenzene 6.8 10 2.5 ug/l J
99-87-6 p-Isopropyltoluene ND 10 2.5 ug/l
74-83-9 Methyl Bromide ND 10 4.0 ug/l
74-87-3 Methyl Chloride 9.6 10 4.0 ug/l J
74-95-3 Methylene Bromide ND 10 2.5 ug/l
75-09-2 Methylene Chloride ND 40 20 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 10 2.5 ug/l
91-20-3 Naphthalene 163 10 2.5 ug/l
103-65-1 n-Propylbenzene 16.8 10 2.5 ug/l
100-42-5 Styrene ND 10 2.5 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 10 2.5 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 10 2.5 ug/l
127-18-4 Tetrachloroethylene ND 10 2.5 ug/l
108-88-3 Toluene 185 10 2.5 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 10 2.5 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 10 2.5 ug/l
71-55-6 1,1,1-Trichloroethane ND 10 2.5 ug/l
79-00-5 1,1,2-Trichloroethane ND 10 2.5 ug/l
79-01-6 Trichloroethylene ND 10 2.5 ug/l
75-69-4 Trichlorofluoromethane ND 10 4.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 10 2.5 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 10 2.5 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 10 2.5 ug/l
75-01-4 Vinyl Chloride ND 10 2.5 ug/l
m,p-Xylene 19.9 20 2.5 ug/l J
95-47-6 o-Xylene 10.2 10 2.5 ug/l
1330-20-7 Xylene (total)30.1 30 5.0 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%98%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%101%70-130%
2037-26-5 Toluene-D8 102%103%70-130%
460-00-4 4-Bromofluorobenzene 101%101%70-130%
(a) Result is from Run# 2
(b) Associated ICV and BS outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 25
FA5738433.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-10
Lab Sample ID:FA57384-2 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 A0215227.D 10 09/10/18 13:58 AB n/a n/a VA2452
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 470 5.0 1.3 ug/l
108-86-1 Bromobenzene ND 5.0 1.3 ug/l
74-97-5 Bromochloromethane ND 5.0 1.3 ug/l
75-27-4 Bromodichloromethane ND 5.0 1.3 ug/l
75-25-2 Bromoform ND 5.0 1.3 ug/l
104-51-8 n-Butylbenzene 4.1 5.0 1.3 ug/l J
135-98-8 sec-Butylbenzene 3.2 5.0 1.3 ug/l J
98-06-6 tert-Butylbenzene ND 5.0 1.3 ug/l
56-23-5 Carbon Tetrachloride ND 5.0 1.3 ug/l
108-90-7 Chlorobenzene ND 5.0 1.3 ug/l
75-00-3 Chloroethane ND 5.0 2.0 ug/l
67-66-3 Chloroform ND 5.0 1.3 ug/l
95-49-8 o-Chlorotoluene 6.3 5.0 1.3 ug/l
106-43-4 p-Chlorotoluene ND 5.0 1.3 ug/l
124-48-1 Dibromochloromethane ND 5.0 1.3 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 5.0 2.5 ug/l
106-93-4 1,2-Dibromoethane ND 5.0 1.3 ug/l
75-71-8 Dichlorodifluoromethane a ND 5.0 2.0 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 1.3 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 1.3 ug/l
106-46-7 1,4-Dichlorobenzene ND 5.0 1.3 ug/l
75-34-3 1,1-Dichloroethane ND 5.0 1.3 ug/l
107-06-2 1,2-Dichloroethane 100 5.0 1.3 ug/l
75-35-4 1,1-Dichloroethylene ND 5.0 1.3 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 5.0 1.3 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 5.0 1.3 ug/l
78-87-5 1,2-Dichloropropane ND 5.0 1.3 ug/l
142-28-9 1,3-Dichloropropane ND 5.0 1.3 ug/l
594-20-7 2,2-Dichloropropane ND 5.0 1.3 ug/l
563-58-6 1,1-Dichloropropene ND 5.0 1.3 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 5.0 1.3 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 5.0 1.3 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 25
FA5738433.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-10
Lab Sample ID:FA57384-2 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 19.3 5.0 1.3 ug/l
100-41-4 Ethylbenzene 182 5.0 1.3 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 1.3 ug/l
98-82-8 Isopropylbenzene 21.5 5.0 1.3 ug/l
99-87-6 p-Isopropyltoluene ND 5.0 1.3 ug/l
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride ND 5.0 2.0 ug/l
74-95-3 Methylene Bromide ND 5.0 1.3 ug/l
75-09-2 Methylene Chloride ND 20 10 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 5.0 1.3 ug/l
91-20-3 Naphthalene 147 5.0 1.3 ug/l
103-65-1 n-Propylbenzene 56.1 5.0 1.3 ug/l
100-42-5 Styrene ND 5.0 1.3 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 5.0 1.3 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 5.0 1.3 ug/l
127-18-4 Tetrachloroethylene ND 5.0 1.3 ug/l
108-88-3 Toluene 66.0 5.0 1.3 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 5.0 1.3 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.3 ug/l
71-55-6 1,1,1-Trichloroethane ND 5.0 1.3 ug/l
79-00-5 1,1,2-Trichloroethane ND 5.0 1.3 ug/l
79-01-6 Trichloroethylene ND 5.0 1.3 ug/l
75-69-4 Trichlorofluoromethane ND 5.0 2.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 5.0 1.3 ug/l
95-63-6 1,2,4-Trimethylbenzene 230 5.0 1.3 ug/l
108-67-8 1,3,5-Trimethylbenzene 54.5 5.0 1.3 ug/l
75-01-4 Vinyl Chloride ND 5.0 1.3 ug/l
m,p-Xylene 125 10 1.3 ug/l
95-47-6 o-Xylene 190 5.0 1.3 ug/l
1330-20-7 Xylene (total)315 15 2.5 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 104%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
(a) Associated ICV and BS outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 25
FA5738433.2
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:MW-17
Lab Sample ID:FA57384-3 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 a A0215228.D 2 09/10/18 14:21 AB n/a n/a VA2452
Run #2
Purge Volume
Run #1 10.0 ml
Run #2
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 91.3 1.0 0.25 ug/l
108-86-1 Bromobenzene ND 1.0 0.25 ug/l
74-97-5 Bromochloromethane ND 1.0 0.25 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.25 ug/l
75-25-2 Bromoform ND 1.0 0.25 ug/l
104-51-8 n-Butylbenzene 0.68 1.0 0.25 ug/l J
135-98-8 sec-Butylbenzene 0.45 1.0 0.25 ug/l J
98-06-6 tert-Butylbenzene ND 1.0 0.25 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.25 ug/l
108-90-7 Chlorobenzene ND 1.0 0.25 ug/l
75-00-3 Chloroethane ND 1.0 0.40 ug/l
67-66-3 Chloroform ND 1.0 0.25 ug/l
95-49-8 o-Chlorotoluene ND 1.0 0.25 ug/l
106-43-4 p-Chlorotoluene ND 1.0 0.25 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.25 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 1.0 0.49 ug/l
106-93-4 1,2-Dibromoethane ND 1.0 0.25 ug/l
75-71-8 Dichlorodifluoromethane b ND 1.0 0.40 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.25 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.25 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.25 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.25 ug/l
107-06-2 1,2-Dichloroethane 3.4 1.0 0.25 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.25 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.25 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.25 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.25 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.25 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.25 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.25 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.25 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.25 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 25
FA5738433.3
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:MW-17
Lab Sample ID:FA57384-3 Date Sampled:09/04/18
Matrix:AQ - Ground Water Date Received:09/05/18
Method:SM 6200B Percent Solids:n/a
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
108-20-3 Di-Isopropyl Ether 0.57 1.0 0.25 ug/l J
100-41-4 Ethylbenzene 27.6 1.0 0.25 ug/l
87-68-3 Hexachlorobutadiene ND 1.0 0.25 ug/l
98-82-8 Isopropylbenzene 1.9 1.0 0.25 ug/l
99-87-6 p-Isopropyltoluene ND 1.0 0.25 ug/l
74-83-9 Methyl Bromide ND 1.0 0.40 ug/l
74-87-3 Methyl Chloride ND 1.0 0.40 ug/l
74-95-3 Methylene Bromide ND 1.0 0.25 ug/l
75-09-2 Methylene Chloride ND 4.0 2.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.25 ug/l
91-20-3 Naphthalene 18.1 1.0 0.25 ug/l
103-65-1 n-Propylbenzene 4.8 1.0 0.25 ug/l
100-42-5 Styrene ND 1.0 0.25 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.25 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.25 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.25 ug/l
108-88-3 Toluene 12.5 1.0 0.25 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 1.0 0.25 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 1.0 0.25 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.25 ug/l
79-01-6 Trichloroethylene ND 1.0 0.25 ug/l
75-69-4 Trichlorofluoromethane ND 1.0 0.40 ug/l
96-18-4 1,2,3-Trichloropropane 0.42 1.0 0.25 ug/l J
95-63-6 1,2,4-Trimethylbenzene 6.6 1.0 0.25 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 1.0 0.25 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.25 ug/l
m,p-Xylene 8.1 2.0 0.25 ug/l
95-47-6 o-Xylene 6.3 1.0 0.25 ug/l
1330-20-7 Xylene (total)14.5 3.0 0.50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 103%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
(a) Sample was not preserved to a pH < 2.
(b) Associated ICV and BS outside control limits high, however sample ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 25
FA5738433.3
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
13 of 25
FA573844
FA57384: Chain of Custody
Page 1 of 2
14 of 25
FA5738444.1
Job Number:FA57384 Client:GRI
Date / Time Received:9/5/2018 9:00:00 AM Delivery Method:FX
Project:GRANYS & LEGGETTS
Airbill #'s:8125655682570662
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
IR Gun
Ice (Bag)
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (1.2);
Cooler 1: (1.3);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:0.1; # of Coolers:1
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:PETERH Date:Date:9/5/2018 9:00:00 AM
FA57384: Chain of Custody
Page 2 of 2
15 of 25
FA5738444.1
SGS North America Inc.
MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
16 of 25
FA573845
Method Blank Summary Page 1 of 1
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2451-MB A0215194.D 1 09/07/18 AB n/a n/a VA2451
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 98%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 100%70-130%
17 of 25
FA5738455.1.1
Method Blank Summary Page 1 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2452-MB A0215218.D 1 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.13 ug/l
108-86-1 Bromobenzene ND 0.50 0.13 ug/l
74-97-5 Bromochloromethane ND 0.50 0.13 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.13 ug/l
75-25-2 Bromoform ND 0.50 0.13 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.13 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.13 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.13 ug/l
56-23-5 Carbon Tetrachloride ND 0.50 0.13 ug/l
108-90-7 Chlorobenzene ND 0.50 0.13 ug/l
75-00-3 Chloroethane ND 0.50 0.20 ug/l
67-66-3 Chloroform ND 0.50 0.13 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.13 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.13 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.13 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.25 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.13 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.20 ug/l
95-50-1 1,2-Dichlorobenzene ND 0.50 0.13 ug/l
541-73-1 1,3-Dichlorobenzene ND 0.50 0.13 ug/l
106-46-7 1,4-Dichlorobenzene ND 0.50 0.13 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.13 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.13 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.13 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.13 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.13 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.13 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.13 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.13 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.13 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.13 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.13 ug/l
108-20-3 Di-Isopropyl Ether ND 0.50 0.13 ug/l
100-41-4 Ethylbenzene ND 0.50 0.13 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.13 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.13 ug/l
18 of 25
FA5738455.1.2
Method Blank Summary Page 2 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2452-MB A0215218.D 1 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.13 ug/l
74-83-9 Methyl Bromide ND 0.50 0.20 ug/l
74-87-3 Methyl Chloride ND 0.50 0.20 ug/l
74-95-3 Methylene Bromide ND 0.50 0.13 ug/l
75-09-2 Methylene Chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.13 ug/l
91-20-3 Naphthalene ND 0.50 0.13 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.13 ug/l
100-42-5 Styrene ND 0.50 0.13 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.13 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.13 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.13 ug/l
108-88-3 Toluene ND 0.50 0.13 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.13 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.13 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.13 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.13 ug/l
79-01-6 Trichloroethylene ND 0.50 0.13 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.20 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.13 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.13 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.13 ug/l
75-01-4 Vinyl Chloride ND 0.50 0.13 ug/l
m,p-Xylene ND 1.0 0.13 ug/l
95-47-6 o-Xylene ND 0.50 0.13 ug/l
1330-20-7 Xylene (total)ND 1.5 0.25 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 102%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
19 of 25
FA5738455.1.2
Blank Spike Summary Page 1 of 1
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2451-BS A0215192.D 1 09/07/18 AB n/a n/a VA2451
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.7 97 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 101%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 102%70-130%
* = Outside of Control Limits.
20 of 25
FA5738455.2.1
Blank Spike Summary Page 1 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2452-BS A0215216.D 1 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 10.0 100 70-130
108-86-1 Bromobenzene 10 9.7 97 70-130
74-97-5 Bromochloromethane 10 8.5 85 70-130
75-27-4 Bromodichloromethane 10 9.9 99 70-130
75-25-2 Bromoform 10 9.5 95 70-130
104-51-8 n-Butylbenzene 10 10.4 104 70-130
135-98-8 sec-Butylbenzene 10 10.1 101 70-130
98-06-6 tert-Butylbenzene 10 10.0 100 70-130
56-23-5 Carbon Tetrachloride 10 10.7 107 70-130
108-90-7 Chlorobenzene 10 9.9 99 70-130
75-00-3 Chloroethane 10 10.0 100 60-140
67-66-3 Chloroform 10 10.0 100 70-130
95-49-8 o-Chlorotoluene 10 9.9 99 70-130
106-43-4 p-Chlorotoluene 10 10.0 100 70-130
124-48-1 Dibromochloromethane 10 9.8 98 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.1 91 70-130
106-93-4 1,2-Dibromoethane 10 9.6 96 70-130
75-71-8 Dichlorodifluoromethane 10 15.3 153*60-140
95-50-1 1,2-Dichlorobenzene 10 10 100 70-130
541-73-1 1,3-Dichlorobenzene 10 10.3 103 70-130
106-46-7 1,4-Dichlorobenzene 10 10 100 70-130
75-34-3 1,1-Dichloroethane 10 10.3 103 70-130
107-06-2 1,2-Dichloroethane 10 9.6 96 70-130
75-35-4 1,1-Dichloroethylene 10 10.3 103 70-130
156-59-2 cis-1,2-Dichloroethylene 10 9.9 99 70-130
156-60-5 trans-1,2-Dichloroethylene 10 10.2 102 70-130
78-87-5 1,2-Dichloropropane 10 9.9 99 70-130
142-28-9 1,3-Dichloropropane 10 9.6 96 70-130
594-20-7 2,2-Dichloropropane 10 10.2 102 70-130
563-58-6 1,1-Dichloropropene 10 10.2 102 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.2 92 70-130
10061-02-6 trans-1,3-Dichloropropene 10 9.8 98 70-130
108-20-3 Di-Isopropyl Ether 10 8.8 88 70-130
100-41-4 Ethylbenzene 10 10.1 101 70-130
87-68-3 Hexachlorobutadiene 10 10.1 101 70-130
98-82-8 Isopropylbenzene 10 10.7 107 70-130
* = Outside of Control Limits.
21 of 25
FA5738455.2.2
Blank Spike Summary Page 2 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VA2452-BS A0215216.D 1 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.2 102 70-130
74-83-9 Methyl Bromide 10 10.6 106 60-140
74-87-3 Methyl Chloride 10 12.6 126 60-140
74-95-3 Methylene Bromide 10 9.5 95 70-130
75-09-2 Methylene Chloride 10 10.1 101 70-130
1634-04-4 Methyl Tert Butyl Ether 10 8.4 84 70-130
91-20-3 Naphthalene 10 9.5 95 70-130
103-65-1 n-Propylbenzene 10 10.1 101 70-130
100-42-5 Styrene 10 9.9 99 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 10 100 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 10.2 102 70-130
127-18-4 Tetrachloroethylene 10 10.5 105 70-130
108-88-3 Toluene 10 10.3 103 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.8 98 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.7 97 70-130
71-55-6 1,1,1-Trichloroethane 10 10.1 101 70-130
79-00-5 1,1,2-Trichloroethane 10 9.9 99 70-130
79-01-6 Trichloroethylene 10 10 100 70-130
75-69-4 Trichlorofluoromethane 10 11.8 118 60-140
96-18-4 1,2,3-Trichloropropane 10 9.6 96 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.6 96 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.9 99 70-130
75-01-4 Vinyl Chloride 10 10.9 109 60-140
m,p-Xylene 20 20.1 101 70-130
95-47-6 o-Xylene 10 10.1 101 70-130
1330-20-7 Xylene (total)30 30.2 101 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 100%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%70-130%
2037-26-5 Toluene-D8 101%70-130%
460-00-4 4-Bromofluorobenzene 101%70-130%
* = Outside of Control Limits.
22 of 25
FA5738455.2.2
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57382-1MS A0215210.D 200 09/07/18 AB n/a n/a VA2451
FA57382-1MSD A0215211.D 200 09/07/18 AB n/a n/a VA2451
FA57382-1 A0215206.D 50 09/07/18 AB n/a n/a VA2451
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1
FA57382-1 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1030 2000 2760 87 2000 3000 99 8 70-130/20
CAS No.Surrogate Recoveries MS MSD FA57382-1 Limits
1868-53-7 Dibromofluoromethane 100%101%99%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%103%101%70-130%
2037-26-5 Toluene-D8 102%102%102%70-130%
460-00-4 4-Bromofluorobenzene 102%102%101%70-130%
* = Outside of Control Limits.
23 of 25
FA5738455.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57382-3MS A0215229.D 50 09/10/18 AB n/a n/a VA2452
FA57382-3MSD A0215230.D 50 09/10/18 AB n/a n/a VA2452
FA57382-3 a A0215220.D 50 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
FA57382-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
71-43-2 Benzene 1430 500 1940 102 500 1970 108 2 70-130/20
108-86-1 Bromobenzene ND 500 487 97 500 512 102 5 70-130/20
74-97-5 Bromochloromethane ND 500 412 82 500 436 87 6 70-130/20
75-27-4 Bromodichloromethane ND 500 483 97 500 516 103 7 70-130/20
75-25-2 Bromoform ND 500 451 90 500 478 96 6 70-130/20
104-51-8 n-Butylbenzene ND 500 522 104 500 553 111 6 70-130/20
135-98-8 sec-Butylbenzene ND 500 506 101 500 538 108 6 70-130/20
98-06-6 tert-Butylbenzene ND 500 506 101 500 536 107 6 70-130/20
56-23-5 Carbon Tetrachloride ND 500 508 102 500 557 111 9 70-130/20
108-90-7 Chlorobenzene ND 500 494 99 500 520 104 5 70-130/20
75-00-3 Chloroethane ND 500 421 84 500 504 101 18 60-140/20
67-66-3 Chloroform ND 500 499 100 500 530 106 6 70-130/20
95-49-8 o-Chlorotoluene 19.9 J 500 515 99 500 549 106 6 70-130/20
106-43-4 p-Chlorotoluene ND 500 501 100 500 528 106 5 70-130/20
124-48-1 Dibromochloromethane ND 500 478 96 500 508 102 6 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 500 457 91 500 492 98 7 70-130/20
106-93-4 1,2-Dibromoethane ND 500 478 96 500 505 101 5 70-130/20
75-71-8 Dichlorodifluoromethane ND 500 645 129 500 784 157*19 60-140/20
95-50-1 1,2-Dichlorobenzene ND 500 494 99 500 519 104 5 70-130/20
541-73-1 1,3-Dichlorobenzene ND 500 514 103 500 537 107 4 70-130/20
106-46-7 1,4-Dichlorobenzene ND 500 497 99 500 522 104 5 70-130/20
75-34-3 1,1-Dichloroethane ND 500 513 103 500 540 108 5 70-130/20
107-06-2 1,2-Dichloroethane ND 500 486 97 500 513 103 5 70-130/20
75-35-4 1,1-Dichloroethylene ND 500 501 100 500 533 107 6 70-130/20
156-59-2 cis-1,2-Dichloroethylene ND 500 492 98 500 528 106 7 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 500 497 99 500 531 106 7 70-130/20
78-87-5 1,2-Dichloropropane ND 500 494 99 500 519 104 5 70-130/20
142-28-9 1,3-Dichloropropane ND 500 476 95 500 501 100 5 70-130/20
594-20-7 2,2-Dichloropropane ND 500 475 95 500 499 100 5 70-130/20
563-58-6 1,1-Dichloropropene ND 500 510 102 500 542 108 6 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 500 455 91 500 477 95 5 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 500 484 97 500 506 101 4 70-130/20
108-20-3 Di-Isopropyl Ether 649 500 1130 96 500 1160 102 3 70-130/20
100-41-4 Ethylbenzene 714 500 1240 105 500 1250 107 1 70-130/20
87-68-3 Hexachlorobutadiene ND 500 501 100 500 534 107 6 70-130/20
98-82-8 Isopropylbenzene 16.7 J 500 551 107 500 573 111 4 70-130/20
* = Outside of Control Limits.
24 of 25
FA5738455.3.2
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA57384
Account:GRINCC GRI (Geological Resources Inc.)
Project:Grannys Grill/Leggetts Grocery; 1727 & 1731 US Hwy 13 N, Windsor, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA57382-3MS A0215229.D 50 09/10/18 AB n/a n/a VA2452
FA57382-3MSD A0215230.D 50 09/10/18 AB n/a n/a VA2452
FA57382-3 a A0215220.D 50 09/10/18 AB n/a n/a VA2452
The QC reported here applies to the following samples:Method: SM 6200B
FA57384-1, FA57384-2, FA57384-3
FA57382-3 Spike MS MS Spike MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 500 501 100 500 546 109 9 70-130/20
74-83-9 Methyl Bromide ND 500 443 89 500 536 107 19 60-140/20
74-87-3 Methyl Chloride 14.5 J 500 572 112 500 647 127 12 60-140/20
74-95-3 Methylene Bromide ND 500 479 96 500 503 101 5 70-130/20
75-09-2 Methylene Chloride ND 500 510 102 500 541 108 6 70-130/20
1634-04-4 Methyl Tert Butyl Ether 218 500 653 87 500 677 92 4 70-130/20
91-20-3 Naphthalene 132 500 620 98 500 655 105 5 70-130/20
103-65-1 n-Propylbenzene 24.2 J 500 529 101 500 558 107 5 70-130/20
100-42-5 Styrene ND 500 500 100 500 525 105 5 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 500 498 100 500 518 104 4 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 500 517 103 500 543 109 5 70-130/20
127-18-4 Tetrachloroethylene ND 500 518 104 500 539 108 4 70-130/20
108-88-3 Toluene 2140 500 2600 92 500 2620 96 1 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 500 478 96 500 511 102 7 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 500 477 95 500 509 102 6 70-130/20
71-55-6 1,1,1-Trichloroethane ND 500 486 97 500 519 104 7 70-130/20
79-00-5 1,1,2-Trichloroethane ND 500 504 101 500 524 105 4 70-130/20
79-01-6 Trichloroethylene ND 500 504 101 500 531 106 5 70-130/20
75-69-4 Trichlorofluoromethane ND 500 505 101 500 593 119 16 60-140/20
96-18-4 1,2,3-Trichloropropane ND 500 477 95 500 498 100 4 70-130/20
95-63-6 1,2,4-Trimethylbenzene 541 500 1030 98 500 1070 106 4 70-130/20
108-67-8 1,3,5-Trimethylbenzene 173 500 677 101 500 709 107 5 70-130/20
75-01-4 Vinyl Chloride ND 500 454 91 500 542 108 18 60-140/20
m,p-Xylene 2820 1000 3840 102 1000 3870 105 1 70-130/20
95-47-6 o-Xylene 1280 500 1760 96 500 1790 102 2 70-130/20
1330-20-7 Xylene (total)4100 1500 5600 100 1500 5670 105 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FA57382-3 Limits
1868-53-7 Dibromofluoromethane 99%100%97%70-130%
17060-07-0 1,2-Dichloroethane-D4 103%103%99%70-130%
2037-26-5 Toluene-D8 102%102%103%70-130%
460-00-4 4-Bromofluorobenzene 102%102%101%70-130%
(a) Sample was not preserved to a pH < 2.
* = Outside of Control Limits.
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