WA-769_10679_CA_RPTS_20140328_MRP

3502 Hayes Road • Monroe, North Carolina 28110
Phone [phone] • [phone] • Fax [phone]
March 26, 2013

Ms. Rose Ballance
NCDENR-UST Section Washington Regional Office
943 Washington Square Mall Washington, North Carolina 27889
Re: Ground Water Monitoring Results – March 2014 Former Sunrise BP
2005 East Ash Street Goldsboro, Wayne County
Incident No. 10679
Site Ranking: I 172 D
Dear Ms. Ballance:
The purpose of this report is to present the results of ground water monitoring activities conducted in
March 2014 at the former Sunrise BP site, located at 2005 East Ash Street in Goldsboro, Wayne County,
North Carolina (Figures 1 and 2). This scope of work was completed in accordance with North Carolina Department of Environment and Natural Resources correspondence dated September 4, 2013. Task
authorization 10679-20 was approved on November 20, 2013. Ground water monitoring activities were conducted in order to obtain ground water quality data for wells historically impacted by free product.
On December 4, 2013 and February 7 and March 17, 2014, monitoring wells MW-1 and MW-8A were gauged (Figure 3). Free product was present in MW-8A during each gauging event. A total of 1.5 gallons of free product was removed by hand bailing MW-8A during the gauging events. Product was
containerized in a drum stored on-site. Monitoring well MW-1 was purged and sampled on March 17, 2014. A summary of well construction and gauging data is presented in Table 1. A summary of free
product recovery information is presented in Table 2.
Laboratory analyses were performed on the ground water samples collected from MW-1 for volatile
organic compounds using EPA Method 6200B. Concentrations of BTEX constituents, MTBE,
naphthalene, isopropylbenzene, n-propylbenzene, sec-butylbenzene, tert-butylbenzene, 1,3,5-trimethylbenzene and 1,2,4-trimethylbenzene that exceeded the maximum allowable concentrations
(MACs) specified in T15A NCAC 2L.0202 were reported in the ground water samples collected from MW-1. None of the reported concentrations exceeded the gross contamination levels (GCLs). A summary of ground water sample analytical results is presented in Table 3. A complete copy of the
laboratory report has been included in Appendix A.
"J
SITE
ASH ST
BEST STROSE ST
WALNUT ST TAYLOR STCLAIBORNE STPALM ST
RANDOLPH STMULBERRY ST
RIDGEWOOD DRMADISON AVSPENCE AVEVERGREEN AV OVERBROOK RDPEACHTREE ST
PINE ST
HILLDALE LN
HILLCREST DRDURANT STDENTON PLPEACHTREE ST
DURANT STUt Stoney CreekUt
3509834917
35098378763509836709
350983553735098346603509836515WSW-13509835039³
FIGURE 2: SITE VICINITY MAPSUNRISE BP2005 EAST ASH STREETGOLDSBORO, WAYNE COUNTYNORTH CAROLINAINCIDENT NO. 10679
PREPARED BY:GEOLOGICAL RESOURCES, INC.NOVEMBER 24, 2009
0 300150Feet
1 inch equals 300 feet
1,500-FOOT RADIUS 1,000-FOOT RADIUS
250-FOOT RADIUS
Legend
"J Water Supply Well
All_Ditches_Streams_Rivers
Wayne_Centerlines_master
parcels_view
3509836709 PIN Number
Date: 03/24/1411/30/09 6.85 0.02 93.1706/07/10 7.73 0.17 92.4211/24/10 7.75 0.06 92.30 Before FP Eval11/24/10 7.73 0.00 92.27 After FP Eval07/27/11 9.07 0.06 90.9802/13/12 7.77 0.00 92.23 Before MMPE02/17/12 9.21 0.00 90.79 After MMPE03/20/12 7.23 0.09 92.8510/26/12 8.72 0.09 91.3611/21/12 8.74 0.01 91.2712/12/12 8.51 0.01 91.5001/22/13 7.60 0.00 92.4002/25/13 6.72 0.01 93.2903/25/13 7.09 0.14 93.0308/06/13 6.60 0.00 93.4012/04/13 6.72 0.00 93.2802/07/14 5.95 0.00 94.0503/17/14 5.77 0.00 94.2311/30/09 6.96 --- 93.9711/24/10 7.79 --- 93.1407/27/11 9.11 --- 91.8202/13/12 7.90 --- 93.03 Before MMPE02/17/12 9.96 --- 90.97 After MMPE03/20/12 7.30 --- 93.63TABLE 1WELL CONSTRUCTION AND GAUGING INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Facility ID #: 0-006025Well IDDate Water Level Measured (mm/dd/yy)Well Casing Depth (ft. BGS)Screened Interval (x to y ft. BGS)Bottom of Well (ft. BGS)Top of Casing Elevation (ft.)Depth to Water from Top of Casing (ft.)Free Product Thickness (ft.)GroundWaterElevation (ft.)CommentsMW-2A 5 5 - 15 15 100.93MW-1 7 7 - 17 17 100.00Page 1 of 4
Date: 03/24/14TABLE 1WELL CONSTRUCTION AND GAUGING INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Facility ID #: 0-006025Well IDDate Water Level Measured (mm/dd/yy)Well Casing Depth (ft. BGS)Screened Interval (x to y ft. BGS)Bottom of Well (ft. BGS)Top of Casing Elevation (ft.)Depth to Water from Top of Casing (ft.)Free Product Thickness (ft.)GroundWaterElevation (ft.)Comments11/30/09 6.64 --- NM07/27/11 8.93 --- NM03/20/12 6.96 --- NM11/30/09 6.70 --- 94.8207/27/11 8.73 --- 92.7903/20/12 7.02 --- 94.50MW-5 11/30/09 3 3 - 18 18 99.13 NM NM NM Destroyed11/30/09 7.08 0.11 93.2206/07/10 7.69 0.00 92.5211/24/10 7.80 0.00 92.4107/27/11 9.13 0.00 91.0802/13/12 7.89 0.00 92.32 Before MMPE02/17/12 9.01 0.00 91.20 After MMPE03/20/12 7.35 0.10 92.9510/26/12 8.76 0.01 91.4611/21/12 8.86 0.01 91.3612/12/12 8.67 0.01 91.5501/22/13 7.73 0.00 92.4802/25/13 7.05 0.22 93.3503/25/13 7.28 0.23 93.1308/06/13 6.94 0.39 93.6012/04/13 7.05 0.34 93.4502/07/14 6.39 0.11 93.9103/17/14 5.79 0.04 94.45MW-8A 3 3 - 18 18 100.21MW-4 3 3 - 18 18 101.52MW-3A 5 5 - 15 15 NMPage 2 of 4
Date: 03/24/14TABLE 1WELL CONSTRUCTION AND GAUGING INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Facility ID #: 0-006025Well IDDate Water Level Measured (mm/dd/yy)Well Casing Depth (ft. BGS)Screened Interval (x to y ft. BGS)Bottom of Well (ft. BGS)Top of Casing Elevation (ft.)Depth to Water from Top of Casing (ft.)Free Product Thickness (ft.)GroundWaterElevation (ft.)Comments11/30/09 7.34 --- 93.7107/27/11 9.43 --- 91.6203/20/12 7.62 --- 93.4311/30/09 5.00 --- 92.6307/27/11 7.20 --- 90.4303/20/12 5.23 --- 92.4011/30/09 7.03 --- 93.1907/27/11 9.27 --- 90.9503/20/12 7.20 --- 93.0211/30/09 5.68 --- 92.3907/27/11 8.00 --- 90.0703/20/12 6.02 --- 92.0511/30/09 4.60 --- 91.9607/27/11 6.80 --- 89.7603/20/12 4.87 --- 91.6911/30/09 3.06 --- 91.9407/27/11 5.40 --- 89.6003/20/12 3.33 --- 91.6711/30/09 4.40 --- 91.6707/27/11 6.51 --- 89.5603/20/12 4.63 --- 91.4411/30/09 5.60 --- 92.7807/27/11 7.70 --- 90.6803/20/12 5.87 --- 92.51MW-16 2 2 - 14 14 98.38MW-15 2 2 - 8 8 96.07MW-14 2 2 - 6.5 6.5 95.00MW-13 1.5 1.5 - 9 9 96.56MW-12 1.5 1.5 - 9.5 9.5 98.07MW-11 1 1 - 10 10 100.22MW-10 3 3 - 18 18 97.63MW-9 3 3 - 18 18 101.05Page 3 of 4
Date: 03/24/14TABLE 1WELL CONSTRUCTION AND GAUGING INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Facility ID #: 0-006025Well IDDate Water Level Measured (mm/dd/yy)Well Casing Depth (ft. BGS)Screened Interval (x to y ft. BGS)Bottom of Well (ft. BGS)Top of Casing Elevation (ft.)Depth to Water from Top of Casing (ft.)Free Product Thickness (ft.)GroundWaterElevation (ft.)Comments11/30/09 3.50 --- 92.8207/27/11 5.95 --- 90.3703/20/12 3.73 --- 92.5911/30/09 5.30 --- 93.2907/27/11 7.55 --- 91.0403/20/12 5.63 --- 92.9611/30/09 7.93 --- 92.5607/27/11 10.15 --- 90.3403/20/12 8.18 --- 92.31Notes:• **: If free product is present in a well, ground water elevation should be calculated by: (Top of Casing Elevation - Depth to Water) + (Free Product Thickness x 0.8581)MW-18 2 2 - 14 14 98.59• ft BGS : feet below ground surface• NM: Not measured.TW-2 29 29 - 34 34 100.492 - 6 6 96.32MW-17 2Page 4 of 4
Date: 03/24/14Facility ID#: 0-0060251 600 600 500 20 6 70 70 70 70 70 400 4005,000 260,000 84,500 85,500 20,000 6,000 70,000 8,500 15,000 25,000 30,000 25,000 28,50012/01/09FP FP FP FP FP FP FP FP FP FP FP FP FP06/07/10FP FP FP FP FP FP FP FP FP FP FP FP FP07/27/11FP FP FP FP FP FP FP FP FP FP FP FP FP03/20/12FP FP FP FP FP FP FP FP FP FP FP FP FP08/06/131,450 3,960 1,970 9,320 111 645<10 21.1 J <10119 403 761 3,21003/17/141,200 2,830 1,830 9,560 105 674<5.0 25.0 <5.0139 444 849 4,18012/01/09171625 3191,240<2.5090.5<2.00 11.8 <1.90 32.487.416063307/27/11750 9181891,50814.297.1<2.1 12.7 <2.0 26.3 56.2 16362003/20/12147539 3271,780<2.6149<2.1 16.2 <2.0 53.41573151,05012/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.10Contaminant of Concern BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzeneMTBENaphthaleneIPEsec-Butylbenzenetert-ButylbenzeneIsopropylbenzenen-PropylbenzeneTABLE 3SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTSSUNRISE BP (INCIDENT NO. 10679)Analytical Method EPA Method 6200B / 6021,3,5-TrimethylbenzeneWell IDDate Collected (mm/dd/yy)2L StandardGCLMW-4MW-3AMW-2AMW-1Page 1 of 5
Date: 03/24/14Facility ID#: 0-0060251 600 600 500 20 6 70 70 70 70 70 400 4005,000 260,000 84,500 85,500 20,000 6,000 70,000 8,500 15,000 25,000 30,000 25,000 28,500Contaminant of Concern BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzeneMTBENaphthaleneIPEsec-Butylbenzenetert-ButylbenzeneIsopropylbenzenen-PropylbenzeneTABLE 3SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTSSUNRISE BP (INCIDENT NO. 10679)Analytical Method EPA Method 6200B / 6021,3,5-TrimethylbenzeneWell IDDate Collected (mm/dd/yy)2L StandardGCL12/01/09FP FP FP FP FP FP FP FP FP FP FP FP FP06/07/101,420 4,570 2,550 12,200<125419 J<100 NR NR NR NR1,110 5,34007/27/112,550 7,970 2,100 8,730 141 830<27 34.6 J <25117 J 386 905 3,95003/20/12FP FP FP FP FP FP FP FP FP FP FP FP FP08/06/13FP FP FP FP FP FP FP FP FP FP FP FP FP03/17/14FP FP FP FP FP FP FP FP FP FP FP FP FP12/01/0990.5248 121510<1.2554.2<1.00 15.8 14.6 18.290.0152 37507/27/11161317 94.01,0501.7 J45.4<1.1 33.1 1.9 J 19.210124556803/20/1261.3107 119506<1.357.5<1.1 32.8 1.7 J 20.089.2150 38612/01/09 0.384 J 0.634 J 10.5 <0.220 9.37 14.3 0.949 J 1.60 <0.190 10.7 25.5 <0.180 <0.15007/27/11 <0.13 0.24 J 0.83 0.72 J 5.87.90.50 0.93 0.33 J 3.1 4.4 <0.10 0.16 J03/20/12 0.65 1.4 10.2 3.8 6.17.71.0 4.6 0.51 24.2 58.9 <0.10 0.5712/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 1.3 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.10MW-9MW-8AMW-10MW-12MW-11Page 2 of 5
Date: 03/24/14Facility ID#: 0-0060251 600 600 500 20 6 70 70 70 70 70 400 4005,000 260,000 84,500 85,500 20,000 6,000 70,000 8,500 15,000 25,000 30,000 25,000 28,500Contaminant of Concern BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzeneMTBENaphthaleneIPEsec-Butylbenzenetert-ButylbenzeneIsopropylbenzenen-PropylbenzeneTABLE 3SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTSSUNRISE BP (INCIDENT NO. 10679)Analytical Method EPA Method 6200B / 6021,3,5-TrimethylbenzeneWell IDDate Collected (mm/dd/yy)2L StandardGCL12/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 2.18 <0.500 0.460 J <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 3.8 <0.10 0.60 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 0.38 J <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 1.59 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 0.23 J 0.44 J <0.15 <0.30 0.75 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 <0.30 2.2 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/09 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/1189.10.49 J 21.8 24.725.02.6 0.42 J <0.10 <0.10 1.0 1.7 0.52 11.003/20/12 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1012/01/0934.43.44 96.8 7.02 25.135.30.826 J 1.69 <0.190 8.41 20.1 0.498 J 0.598 J07/27/1161.14.1 53.8 16.528.3 1120.76 J 1.7 0.25 J 15.8 37.3 1.1 1.103/20/1215.32.6 5.6 7.4 14.340.20.93 1.4 0.26 J 8.7 19.1 0.32 J 0.56MW-18MW-17MW-16MW-15MW-14MW-13Page 3 of 5
Date: 03/24/14Facility ID#: 0-0060251 600 600 500 20 6 70 70 70 70 70 400 4005,000 260,000 84,500 85,500 20,000 6,000 70,000 8,500 15,000 25,000 30,000 25,000 28,500Contaminant of Concern BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzeneMTBENaphthaleneIPEsec-Butylbenzenetert-ButylbenzeneIsopropylbenzenen-PropylbenzeneTABLE 3SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTSSUNRISE BP (INCIDENT NO. 10679)Analytical Method EPA Method 6200B / 6021,3,5-TrimethylbenzeneWell IDDate Collected (mm/dd/yy)2L StandardGCL12/01/09 0.217 J <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 <0.140 <0.190 <0.150 <0.220 <0.180 <0.15007/27/11 <0.13 <0.13 <0.15 <0.30 <0.13 <0.10 <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 <0.1003/20/12 <0.13 <0.13 <0.15 0.41 J <0.13 0.31 J <0.11 <0.10 <0.10 <0.10 <0.11 <0.10 0.19 J07/30/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 NR NR NR NR <0.180 <0.15007/27/11 NR NR NR NR NR NR NR NR NR NR NR NR NR03/20/12 NR NR NR NR NR NR NR NR NR NR NR NR NR07/30/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 NR NR NR NR <0.180 <0.15007/27/11 NR NR NR NR NR NR NR NR NR NR NR NR NR03/20/12 NR NR NR NR NR NR NR NR NR NR NR NR NR07/30/10 <0.140 <0.190 <0.150 <0.220 <0.250 <0.500 <0.200 NR NR NR NR <0.180 <0.15007/27/11 NR NR NR NR NR NR NR NR NR NR NR NR NR03/20/12 NR NR NR NR NR NR NR NR NR NR NR NR NRKellum LawKinsey InsuranceEdward JonesTW-2Page 4 of 5
Date: 03/24/14Facility ID#: 0-0060251 600 600 500 20 6 70 70 70 70 70 400 4005,000 260,000 84,500 85,500 20,000 6,000 70,000 8,500 15,000 25,000 30,000 25,000 28,500Contaminant of Concern BenzeneTolueneEthylbenzeneXylenes1,2,4-TrimethylbenzeneMTBENaphthaleneIPEsec-Butylbenzenetert-ButylbenzeneIsopropylbenzenen-PropylbenzeneTABLE 3SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTSSUNRISE BP (INCIDENT NO. 10679)Analytical Method EPA Method 6200B / 6021,3,5-TrimethylbenzeneWell IDDate Collected (mm/dd/yy)2L StandardGCLNotes:• Results reported in µg/l (micrograms per liter).• < : Less than the method detection limit specified in the laboratory report.• 2L Standard specified in T15A NCAC 2L.0202.• GCL: Gross contamination level.• Concentrations in bold face type exceeded the 2L Standards.• NE: Not established.• J: Estimated concentration.• NS: Well not found, therefore, not sampled.• NR: Not requested.• Please refer to the laboratory report for other detectable constituents that did not exceed the MACs.Page 5 of 5
Date: 3/21/14Facility ID #:0-006025MW-1 and MW-8A 10/26/12 Hand bail NA NA NA NA 0.35 0.35 0.35MW-1 and MW-8A 11/21/12 Hand bail NA NA NA NA 0.2 0.2 0.2MW-1 and MW-8A 12/12/12 Hand bail NA NA NA NA 0.2 0.2 0.2MW-1 and MW-8A 02/25/13 Hand bail NA NA NA NA 0.3 0.3 0.3MW-1 and MW-8A 03/25/13 Hand bail NA NA NA NA 1.5 1.5 1.5MW-8A 08/06/13 Hand bail NA NA NA NA 0.5 0.5 0.5MW-8A 12/04/13 Hand bail NA NA NA NA 0.5 0.5 0.5MW-8A 02/07/14 Hand bail NA NA NA NA 0.5 0.5 0.5MW-8A 03/17/14 Hand bail NA NA NA NA 0.5 0.5 0.5239.72 10832.55 4.55 244.27TABLE 2FREE PRODUCT RECOVERY EVENT INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Well IDDate (mm/dd/yy)Product Recovery Method*Average Effluent Velocity (ft/min)Average Effluent Temperature (°F)Average Effluent Concentration (ppm)Amount of Vaporized Product (gallons)Amount of Liquid Recovered (gallons) Amount of Product Recovered as Liquid (gallons)Total Amount of Product Recovered (gallons)MMPE 4,000Total To Date 244.27Summary4.55135.6 85,400 239.72 10,828 0 239.72Total Fluids Removed (in gallons) Total Product Removed (in gallons)TotalsSUMMARY OF FLUID REMOVALCurrent Event 1.5 4.55MW-1, MW-2A, and MW-8A2/13/12 - 2/17/12
Date: 3/21/14Facility ID #:0-006025TABLE 2FREE PRODUCT RECOVERY EVENT INFORMATIONSUNRISE BP (INCIDENT NO. 10679)Well IDDate (mm/dd/yy)Product Recovery Method*Average Effluent Velocity (ft/min)Average Effluent Temperature (°F)Average Effluent Concentration (ppm)Amount of Vaporized Product (gallons)Amount of Liquid Recovered (gallons) Amount of Product Recovered as Liquid (gallons)Total Amount of Product Recovered (gallons)Notes:• *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE)• Amount of Vaporized Product (in gallons) is based on Vapor Emissions Summary Sheet, = lbs emitted/6.25• Amount of Liquid Recovered includes Total liquids (Water and Free Product) as indicated on Disposal Manifest.• Amount of Product Recovered as Liquid includes only the volume of free product in the tanker at the end of the event (based on Disposal Manifest and/or Field Notes).• Total Amount of Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid• Total Fluids Removed = Amount of Vaporized Product + Amount of Liquid Recovered• Information regarding historical free product recovery activities is not available.
03/24/14
Technical Report for
GRI (Geological Resources Inc.)
Sunrise BP; 2005 E Ash St, Goldsboro, NC
10679
Accutest Job Number: FA13341
Sampling Date: 03/17/14
Report to:
GRI
3502 Hayes Rd
Monroe, NC 28110
[e-mail]; [e-mail];
[e-mail]; [e-mail];
ATTN: Rae Brown
Total number of pages in report:
Certifications: FL (E83510), LA (03051), KS (E-10327), IA (366), IL (200063), NC (573), NJ (FL002), SC (96038001)
DoD ELAP (L-A-B L2229), CA (04226CA), TX (T104704404), PA (68-03573), VA (460177),
AK, AR, GA, KY, MA, NV, OK, UT, WA
This report shall not be reproduced, except in its entirety, without the written approval of Accutest Laboratories.
Test results relate only to samples analyzed.
Southeast • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone] • http://www.accutest.com
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Muna Mohammed 407-425-6700
Harry Behzadi, Ph.D.
Laboratory Director
Southeast
03/24/14
e-Hardcopy 2.0
Automated Report
18
Accutest Laboratories is the sole authority for authorizing edits or modifications to this
document. Unauthorized modification of this report is strictly prohibited.
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FA13341
Table of Contents
-1-
Sections:
Section 1: Sample Summary ...................................................................................................3
Section 2: Summary of Hits ....................................................................................................4
Section 3: Sample Results ........................................................................................................5
3.1: FA13341-1: MW-1 ........................................................................................................6
Section 4: Misc. Forms ............................................................................................................8
4.1: Chain of Custody ...........................................................................................................9
Section 5: GC/MS Volatiles - QC Data Summaries ..............................................................12
5.1: Method Blank Summary ................................................................................................13
5.2: Blank Spike Summary ...................................................................................................15
5.3: Matrix Spike/Matrix Spike Duplicate Summary ...........................................................17 123452 of 18
FA13341
Accutest Laboratories
Sample Summary
GRI (Geological Resources Inc.)
Job No:FA13341
Sunrise BP; 2005 E Ash St, Goldsboro, NC
Project No: 10679
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
FA13341-1 03/17/14 13:58 HM 03/18/14 AQ Ground Water MW-1
3 of 18
FA13341 1
Summary of Hits Page 1 of 1
Job Number:FA13341
Account:GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Collected:03/17/14
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA13341-1 MW-1
Benzene 1200 25 5.0 ug/l SM 6200B
n-Butylbenzene 41.2 25 5.0 ug/l SM 6200B
sec-Butylbenzene 25.0 25 5.0 ug/l SM 6200B
Ethylbenzene 1830 25 5.0 ug/l SM 6200B
Isopropylbenzene 139 25 5.0 ug/l SM 6200B
p-Isopropyltoluene 18.7 J 25 5.0 ug/l SM 6200B
Methyl Tert Butyl Ether 105 25 5.0 ug/l SM 6200B
Naphthalene 674 25 5.0 ug/l SM 6200B
n-Propylbenzene 444 25 5.0 ug/l SM 6200B
1,2,4-Trimethylbenzene 4180 50 10 ug/l SM 6200B
1,3,5-Trimethylbenzene 849 25 5.0 ug/l SM 6200B
Toluene 2830 50 10 ug/l SM 6200B
Xylene (total)9560 150 20 ug/l SM 6200B
m,p-Xylene 6840 100 10 ug/l SM 6200B
o-Xylene 2720 50 10 ug/l SM 6200B
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FA13341 2
Accutest Laboratories
Sample Results
Report of Analysis
Southeast
Section 3
5 of 18
FA13341 3
Accutest Laboratories
Report of Analysis Page 1 of 2
Client Sample ID:MW-1
Lab Sample ID:FA13341-1 Date Sampled:03/17/14
Matrix:AQ - Ground Water Date Received:03/18/14
Method:SM 6200B Percent Solids:n/a
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 E029642.D 50 03/19/14 TD n/a n/a VE995
Run #2 E029649.D 100 03/19/14 TD n/a n/a VE995
Purge Volume
Run #1 10.0 ml
Run #2 10.0 ml
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene 1200 25 5.0 ug/l
108-86-1 Bromobenzene ND 25 5.0 ug/l
74-97-5 Bromochloromethane ND 25 5.0 ug/l
75-27-4 Bromodichloromethane ND 25 5.0 ug/l
75-25-2 Bromoform ND 25 5.0 ug/l
104-51-8 n-Butylbenzene 41.2 25 5.0 ug/l
135-98-8 sec-Butylbenzene 25.0 25 5.0 ug/l
98-06-6 tert-Butylbenzene ND 25 5.0 ug/l
108-90-7 Chlorobenzene ND 25 5.0 ug/l
75-00-3 Chloroethane ND 25 6.1 ug/l
67-66-3 Chloroform ND 25 5.0 ug/l
95-49-8 o-Chlorotoluene ND 25 5.0 ug/l
106-43-4 p-Chlorotoluene ND 25 5.0 ug/l
56-23-5 Carbon tetrachloride ND 25 5.0 ug/l
75-34-3 1,1-Dichloroethane ND 25 5.0 ug/l
75-35-4 1,1-Dichloroethylene ND 25 5.0 ug/l
563-58-6 1,1-Dichloropropene ND 25 5.0 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 25 8.6 ug/l
106-93-4 1,2-Dibromoethane ND 25 5.0 ug/l
107-06-2 1,2-Dichloroethane ND 25 5.0 ug/l
78-87-5 1,2-Dichloropropane ND 25 5.0 ug/l
142-28-9 1,3-Dichloropropane ND 25 5.0 ug/l
108-20-3 Di-Isopropyl ether ND 25 5.0 ug/l
594-20-7 2,2-Dichloropropane ND 25 5.0 ug/l
124-48-1 Dibromochloromethane ND 25 5.0 ug/l
75-71-8 Dichlorodifluoromethane ND 25 5.0 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 25 5.0 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 25 5.0 ug/l
541-73-1 m-Dichlorobenzene ND 25 5.0 ug/l
95-50-1 o-Dichlorobenzene ND 25 5.0 ug/l
106-46-7 p-Dichlorobenzene ND 25 5.0 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 25 5.0 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 18
FA13341 33.1
Accutest Laboratories
Report of Analysis Page 2 of 2
Client Sample ID:MW-1
Lab Sample ID:FA13341-1 Date Sampled:03/17/14
Matrix:AQ - Ground Water Date Received:03/18/14
Method:SM 6200B Percent Solids:n/a
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
VOA 6200B List
CAS No.Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 25 5.0 ug/l
100-41-4 Ethylbenzene 1830 25 5.0 ug/l
87-68-3 Hexachlorobutadiene ND 25 5.0 ug/l
98-82-8 Isopropylbenzene 139 25 5.0 ug/l
99-87-6 p-Isopropyltoluene 18.7 25 5.0 ug/l J
74-83-9 Methyl bromide ND 25 5.0 ug/l
74-87-3 Methyl chloride ND 25 5.0 ug/l
74-95-3 Methylene bromide ND 25 5.0 ug/l
75-09-2 Methylene chloride ND 100 50 ug/l
1634-04-4 Methyl Tert Butyl Ether 105 25 5.0 ug/l
91-20-3 Naphthalene 674 25 5.0 ug/l
103-65-1 n-Propylbenzene 444 25 5.0 ug/l
100-42-5 Styrene ND 25 5.0 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 25 5.0 ug/l
71-55-6 1,1,1-Trichloroethane ND 25 5.0 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 25 5.0 ug/l
79-00-5 1,1,2-Trichloroethane ND 25 5.3 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 25 5.0 ug/l
96-18-4 1,2,3-Trichloropropane ND 25 5.9 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 25 5.0 ug/l
95-63-6 1,2,4-Trimethylbenzene 4180 a 50 10 ug/l
108-67-8 1,3,5-Trimethylbenzene 849 25 5.0 ug/l
127-18-4 Tetrachloroethylene ND 25 5.0 ug/l
108-88-3 Toluene 2830 a 50 10 ug/l
79-01-6 Trichloroethylene ND 25 5.0 ug/l
75-69-4 Trichlorofluoromethane ND 25 5.0 ug/l
75-01-4 Vinyl chloride ND 25 5.0 ug/l
1330-20-7 Xylene (total)9560 a 150 20 ug/l
m,p-Xylene 6840 a 100 10 ug/l
95-47-6 o-Xylene 2720 a 50 10 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 100%101%70-130%
17060-07-0 1,2-Dichloroethane-D4 102%103%70-130%
2037-26-5 Toluene-D8 97%97%70-130%
460-00-4 4-Bromofluorobenzene 97%97%70-130%
(a) Result is from Run# 2
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 18
FA13341 33.1
Accutest Laboratories
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Southeast
Section 4
8 of 18
FA13341 4
FA13341: Chain of Custody
Page 1 of 3
9 of 18
FA13341 44.1
FA13341: Chain of Custody
Page 2 of 3
10 of 18
FA13341 44.1
FA13341: Chain of Custody
Page 3 of 3
11 of 18
FA13341 44.1
Accutest Laboratories
GC/MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Southeast
Section 5
12 of 18
FA13341 5
Method Blank Summary Page 1 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE995-MB E029641.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
CAS No.Compound Result RL MDL Units Q
71-43-2 Benzene ND 0.50 0.10 ug/l
108-86-1 Bromobenzene ND 0.50 0.10 ug/l
74-97-5 Bromochloromethane ND 0.50 0.10 ug/l
75-27-4 Bromodichloromethane ND 0.50 0.10 ug/l
75-25-2 Bromoform ND 0.50 0.10 ug/l
104-51-8 n-Butylbenzene ND 0.50 0.10 ug/l
135-98-8 sec-Butylbenzene ND 0.50 0.10 ug/l
98-06-6 tert-Butylbenzene ND 0.50 0.10 ug/l
108-90-7 Chlorobenzene ND 0.50 0.10 ug/l
75-00-3 Chloroethane ND 0.50 0.12 ug/l
67-66-3 Chloroform ND 0.50 0.10 ug/l
95-49-8 o-Chlorotoluene ND 0.50 0.10 ug/l
106-43-4 p-Chlorotoluene ND 0.50 0.10 ug/l
56-23-5 Carbon tetrachloride ND 0.50 0.10 ug/l
75-34-3 1,1-Dichloroethane ND 0.50 0.10 ug/l
75-35-4 1,1-Dichloroethylene ND 0.50 0.10 ug/l
563-58-6 1,1-Dichloropropene ND 0.50 0.10 ug/l
96-12-8 1,2-Dibromo-3-chloropropane ND 0.50 0.17 ug/l
106-93-4 1,2-Dibromoethane ND 0.50 0.10 ug/l
107-06-2 1,2-Dichloroethane ND 0.50 0.10 ug/l
78-87-5 1,2-Dichloropropane ND 0.50 0.10 ug/l
142-28-9 1,3-Dichloropropane ND 0.50 0.10 ug/l
108-20-3 Di-Isopropyl ether ND 0.50 0.10 ug/l
594-20-7 2,2-Dichloropropane ND 0.50 0.10 ug/l
124-48-1 Dibromochloromethane ND 0.50 0.10 ug/l
75-71-8 Dichlorodifluoromethane ND 0.50 0.10 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 0.50 0.10 ug/l
541-73-1 m-Dichlorobenzene ND 0.50 0.10 ug/l
95-50-1 o-Dichlorobenzene ND 0.50 0.10 ug/l
106-46-7 p-Dichlorobenzene ND 0.50 0.10 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 0.50 0.10 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 0.50 0.10 ug/l
100-41-4 Ethylbenzene ND 0.50 0.10 ug/l
87-68-3 Hexachlorobutadiene ND 0.50 0.10 ug/l
98-82-8 Isopropylbenzene ND 0.50 0.10 ug/l
13 of 18
FA13341 55.1.1
Method Blank Summary Page 2 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE995-MB E029641.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
CAS No.Compound Result RL MDL Units Q
99-87-6 p-Isopropyltoluene ND 0.50 0.10 ug/l
74-83-9 Methyl bromide ND 0.50 0.10 ug/l
74-87-3 Methyl chloride ND 0.50 0.10 ug/l
74-95-3 Methylene bromide ND 0.50 0.10 ug/l
75-09-2 Methylene chloride ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 0.50 0.10 ug/l
91-20-3 Naphthalene ND 0.50 0.10 ug/l
103-65-1 n-Propylbenzene ND 0.50 0.10 ug/l
100-42-5 Styrene ND 0.50 0.10 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 0.50 0.10 ug/l
71-55-6 1,1,1-Trichloroethane ND 0.50 0.10 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 0.50 0.10 ug/l
79-00-5 1,1,2-Trichloroethane ND 0.50 0.11 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 0.50 0.10 ug/l
96-18-4 1,2,3-Trichloropropane ND 0.50 0.12 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 0.50 0.10 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 0.50 0.10 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 0.50 0.10 ug/l
127-18-4 Tetrachloroethylene ND 0.50 0.10 ug/l
108-88-3 Toluene ND 0.50 0.10 ug/l
79-01-6 Trichloroethylene ND 0.50 0.10 ug/l
75-69-4 Trichlorofluoromethane ND 0.50 0.10 ug/l
75-01-4 Vinyl chloride ND 0.50 0.10 ug/l
1330-20-7 Xylene (total)ND 1.5 0.20 ug/l
m,p-Xylene ND 1.0 0.10 ug/l
95-47-6 o-Xylene ND 0.50 0.10 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 99%70-130%
17060-07-0 1,2-Dichloroethane-D4 99%70-130%
2037-26-5 Toluene-D8 97%70-130%
460-00-4 4-Bromofluorobenzene 96%70-130%
14 of 18
FA13341 55.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE995-BS E029639.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
71-43-2 Benzene 10 9.6 96 70-130
108-86-1 Bromobenzene 10 9.9 99 70-130
74-97-5 Bromochloromethane 10 10.1 101 70-130
75-27-4 Bromodichloromethane 10 9.0 90 70-130
75-25-2 Bromoform 10 8.8 88 70-130
104-51-8 n-Butylbenzene 10 9.0 90 70-130
135-98-8 sec-Butylbenzene 10 10.1 101 70-130
98-06-6 tert-Butylbenzene 10 9.9 99 70-130
108-90-7 Chlorobenzene 10 10.2 102 70-130
75-00-3 Chloroethane 10 7.4 74 60-140
67-66-3 Chloroform 10 9.4 94 70-130
95-49-8 o-Chlorotoluene 10 9.8 98 70-130
106-43-4 p-Chlorotoluene 10 10.3 103 70-130
56-23-5 Carbon tetrachloride 10 8.9 89 70-130
75-34-3 1,1-Dichloroethane 10 9.5 95 70-130
75-35-4 1,1-Dichloroethylene 10 9.1 91 70-130
563-58-6 1,1-Dichloropropene 10 9.6 96 70-130
96-12-8 1,2-Dibromo-3-chloropropane 10 9.5 95 70-130
106-93-4 1,2-Dibromoethane 10 10.1 101 70-130
107-06-2 1,2-Dichloroethane 10 9.8 98 70-130
78-87-5 1,2-Dichloropropane 10 9.7 97 70-130
142-28-9 1,3-Dichloropropane 10 9.9 99 70-130
108-20-3 Di-Isopropyl ether 10 9.4 94 70-130
594-20-7 2,2-Dichloropropane 10 8.8 88 70-130
124-48-1 Dibromochloromethane 10 9.1 91 70-130
75-71-8 Dichlorodifluoromethane 10 7.0 70 60-140
156-59-2 cis-1,2-Dichloroethylene 10 9.7 97 70-130
10061-01-5 cis-1,3-Dichloropropene 10 9.0 90 70-130
541-73-1 m-Dichlorobenzene 10 10.4 104 70-130
95-50-1 o-Dichlorobenzene 10 10.5 105 70-130
106-46-7 p-Dichlorobenzene 10 9.5 95 70-130
156-60-5 trans-1,2-Dichloroethylene 10 9.1 91 70-130
10061-02-6 trans-1,3-Dichloropropene 10 10.4 104 70-130
100-41-4 Ethylbenzene 10 9.2 92 70-130
87-68-3 Hexachlorobutadiene 10 9.6 96 70-130
98-82-8 Isopropylbenzene 10 10.2 102 70-130
* = Outside of Control Limits.
15 of 18
FA13341 55.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VE995-BS E029639.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
Spike BSP BSP
CAS No.Compound ug/l ug/l %Limits
99-87-6 p-Isopropyltoluene 10 10.1 101 70-130
74-83-9 Methyl bromide 10 7.5 75 60-140
74-87-3 Methyl chloride 10 7.1 71 60-140
74-95-3 Methylene bromide 10 10 100 70-130
75-09-2 Methylene chloride 10 9.6 96 70-130
1634-04-4 Methyl Tert Butyl Ether 10 9.8 98 70-130
91-20-3 Naphthalene 10 9.8 98 70-130
103-65-1 n-Propylbenzene 10 10.1 101 70-130
100-42-5 Styrene 10 8.7 87 70-130
630-20-6 1,1,1,2-Tetrachloroethane 10 9.9 99 70-130
71-55-6 1,1,1-Trichloroethane 10 8.9 89 70-130
79-34-5 1,1,2,2-Tetrachloroethane 10 9.7 97 70-130
79-00-5 1,1,2-Trichloroethane 10 9.8 98 70-130
87-61-6 1,2,3-Trichlorobenzene 10 9.7 97 70-130
96-18-4 1,2,3-Trichloropropane 10 10.4 104 70-130
120-82-1 1,2,4-Trichlorobenzene 10 9.4 94 70-130
95-63-6 1,2,4-Trimethylbenzene 10 9.4 94 70-130
108-67-8 1,3,5-Trimethylbenzene 10 9.2 92 70-130
127-18-4 Tetrachloroethylene 10 9.7 97 70-130
108-88-3 Toluene 10 9.2 92 70-130
79-01-6 Trichloroethylene 10 9.5 95 70-130
75-69-4 Trichlorofluoromethane 10 7.1 71 60-140
75-01-4 Vinyl chloride 10 7.3 73 60-140
1330-20-7 Xylene (total)30 29.4 98 70-130
m,p-Xylene 20 19.3 97 70-130
95-47-6 o-Xylene 10 10.0 100 70-130
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 101%70-130%
17060-07-0 1,2-Dichloroethane-D4 100%70-130%
2037-26-5 Toluene-D8 99%70-130%
460-00-4 4-Bromofluorobenzene 98%70-130%
* = Outside of Control Limits.
16 of 18
FA13341 55.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA13340-2MS E029647.D 1 03/19/14 TD n/a n/a VE995
FA13340-2MSD E029648.D 1 03/19/14 TD n/a n/a VE995
FA13340-2 E029644.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
FA13340-2 Spike MS MS MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l %RPD Rec/RPD
71-43-2 Benzene ND 10 9.9 99 9.8 98 1 70-130/20
108-86-1 Bromobenzene ND 10 10.2 102 10.2 102 0 70-130/20
74-97-5 Bromochloromethane ND 10 10.2 102 10.2 102 0 70-130/20
75-27-4 Bromodichloromethane ND 10 9.3 93 9.0 90 3 70-130/20
75-25-2 Bromoform ND 10 8.1 81 7.9 79 2 70-130/20
104-51-8 n-Butylbenzene ND 10 9.4 94 9.4 94 0 70-130/20
135-98-8 sec-Butylbenzene ND 10 10.7 107 10.7 107 0 70-130/20
98-06-6 tert-Butylbenzene ND 10 10.5 105 10.5 105 0 70-130/20
108-90-7 Chlorobenzene ND 10 10.6 106 10.5 105 1 70-130/20
75-00-3 Chloroethane ND 10 10 100 9.9 99 1 60-140/20
67-66-3 Chloroform ND 10 9.9 99 9.9 99 0 70-130/20
95-49-8 o-Chlorotoluene ND 10 10.3 103 10.3 103 0 70-130/20
106-43-4 p-Chlorotoluene ND 10 10.7 107 10.5 105 2 70-130/20
56-23-5 Carbon tetrachloride ND 10 10.2 102 9.9 99 3 70-130/20
75-34-3 1,1-Dichloroethane ND 10 10 100 10.2 102 2 70-130/20
75-35-4 1,1-Dichloroethylene ND 10 10.5 105 10.6 106 1 70-130/20
563-58-6 1,1-Dichloropropene ND 10 10.7 107 10.6 106 1 70-130/20
96-12-8 1,2-Dibromo-3-chloropropane ND 10 8.9 89 9.4 94 5 70-130/20
106-93-4 1,2-Dibromoethane ND 10 9.8 98 9.8 98 0 70-130/20
107-06-2 1,2-Dichloroethane ND 10 10.4 104 10.4 104 0 70-130/20
78-87-5 1,2-Dichloropropane ND 10 9.9 99 9.8 98 1 70-130/20
142-28-9 1,3-Dichloropropane ND 10 9.7 97 9.4 94 3 70-130/20
108-20-3 Di-Isopropyl ether ND 10 9.5 95 9.7 97 2 70-130/20
594-20-7 2,2-Dichloropropane ND 10 10.7 107 10.4 104 3 70-130/20
124-48-1 Dibromochloromethane ND 10 8.7 87 8.6 86 1 70-130/20
75-71-8 Dichlorodifluoromethane ND 10 10.3 103 10.3 103 0 60-140/20
156-59-2 cis-1,2-Dichloroethylene ND 10 9.8 98 9.9 99 1 70-130/20
10061-01-5 cis-1,3-Dichloropropene ND 10 8.6 86 8.4 84 2 70-130/20
541-73-1 m-Dichlorobenzene ND 10 10.7 107 10.7 107 0 70-130/20
95-50-1 o-Dichlorobenzene ND 10 10.5 105 10.7 107 2 70-130/20
106-46-7 p-Dichlorobenzene ND 10 9.7 97 9.6 96 1 70-130/20
156-60-5 trans-1,2-Dichloroethylene ND 10 9.9 99 10 100 1 70-130/20
10061-02-6 trans-1,3-Dichloropropene ND 10 10 100 9.5 95 5 70-130/20
100-41-4 Ethylbenzene ND 10 9.7 97 9.7 97 0 70-130/20
87-68-3 Hexachlorobutadiene ND 10 9.3 93 9.5 95 2 70-130/20
98-82-8 Isopropylbenzene ND 10 10.8 108 10.8 108 0 70-130/20
* = Outside of Control Limits.
17 of 18
FA13341 55.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA13341
Account:GRINCC GRI (Geological Resources Inc.)
Project:Sunrise BP; 2005 E Ash St, Goldsboro, NC
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA13340-2MS E029647.D 1 03/19/14 TD n/a n/a VE995
FA13340-2MSD E029648.D 1 03/19/14 TD n/a n/a VE995
FA13340-2 E029644.D 1 03/19/14 TD n/a n/a VE995
The QC reported here applies to the following samples:Method: SM 6200B
FA13341-1
FA13340-2 Spike MS MS MSD MSD Limits
CAS No.Compound ug/l Q ug/l ug/l %ug/l %RPD Rec/RPD
99-87-6 p-Isopropyltoluene ND 10 10.6 106 10.4 104 2 70-130/20
74-83-9 Methyl bromide ND 10 10.2 102 10.3 103 1 60-140/20
74-87-3 Methyl chloride ND 10 10.0 100 10.0 100 0 60-140/20
74-95-3 Methylene bromide ND 10 10 100 10.0 100 0 70-130/20
75-09-2 Methylene chloride ND 10 9.8 98 9.9 99 1 70-130/20
1634-04-4 Methyl Tert Butyl Ether ND 10 9.7 97 10.0 100 3 70-130/20
91-20-3 Naphthalene ND 10 9.4 94 10 100 6 70-130/20
103-65-1 n-Propylbenzene ND 10 10.6 106 10.5 105 1 70-130/20
100-42-5 Styrene ND 10 8.7 87 8.5 85 2 70-130/20
630-20-6 1,1,1,2-Tetrachloroethane ND 10 10.2 102 9.8 98 4 70-130/20
71-55-6 1,1,1-Trichloroethane ND 10 10.3 103 10.2 102 1 70-130/20
79-34-5 1,1,2,2-Tetrachloroethane ND 10 9.7 97 9.6 96 1 70-130/20
79-00-5 1,1,2-Trichloroethane ND 10 9.4 94 9.4 94 0 70-130/20
87-61-6 1,2,3-Trichlorobenzene ND 10 9.5 95 10.1 101 6 70-130/20
96-18-4 1,2,3-Trichloropropane ND 10 10.1 101 10.1 101 0 70-130/20
120-82-1 1,2,4-Trichlorobenzene ND 10 9.4 94 9.9 99 5 70-130/20
95-63-6 1,2,4-Trimethylbenzene ND 10 9.9 99 9.7 97 2 70-130/20
108-67-8 1,3,5-Trimethylbenzene ND 10 9.7 97 9.6 96 1 70-130/20
127-18-4 Tetrachloroethylene ND 10 10.3 103 10.0 100 3 70-130/20
108-88-3 Toluene ND 10 9.5 95 9.4 94 1 70-130/20
79-01-6 Trichloroethylene ND 10 10.1 101 9.9 99 2 70-130/20
75-69-4 Trichlorofluoromethane ND 10 11.0 110 10.9 109 1 60-140/20
75-01-4 Vinyl chloride ND 10 9.5 95 9.7 97 2 60-140/20
1330-20-7 Xylene (total)ND 30 31.2 104 30.6 102 2 70-130/20
m,p-Xylene ND 20 20.7 104 20.3 102 2 70-130/20
95-47-6 o-Xylene ND 10 10.4 104 10.3 103 1 70-130/20
CAS No.Surrogate Recoveries MS MSD FA13340-2 Limits
1868-53-7 Dibromofluoromethane 105%105%100%70-130%
17060-07-0 1,2-Dichloroethane-D4 107%106%100%70-130%
2037-26-5 Toluene-D8 97%96%97%70-130%
460-00-4 4-Bromofluorobenzene 98%98%96%70-130%
* = Outside of Control Limits.
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FA13341 55.3.1