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HomeMy WebLinkAboutWA-688_9785_CA_FPR_20141030EXECUTIVE SUMMARY The former Red Apple Market #21 site is located along NC Highway 561 West in Saint John, Hertford County, North Carolina (Figure 1). Two 1,000-gallon gasoline USTs and one 550-gallon gasoline UST were removed from the site in October 1992. In addition, one 550-gallon gasoline UST was closed in-place in October 1992. The site risk classification is currently High due to the presence of potable water supply wells within a 1,000-foot radius of the site. A Mobile Multi-Phase Extraction (MMPE) event was conducted between October 13 and October 17, 2014, by Greenwood Applied Services (GAS) on MW-2R, MW-3R, MW-4R and MW-5R, under the supervision of Geological Resources Inc. (GRI) personnel. A free product thickness of 0.02 feet was measured in MW-4R prior to the start of the event. No measurable free product was observed in MW-2R, MW-3R or MW-5R. A total of 9,500 gallons of affected ground water was recovered during the MMPE event. Approximately 4 gallons of free product were observed in the tanker at the conclusion of the MMPE event. Upon conclusion of the event, a free product thickness of 0.09 feet was observed in MW-4R. No measurable free product was observed in MW-2R, MW-3R or MW-5R. The average fluid recovery rate was 98.96 gallons per hour. Based on mass-removal calculations, an additional 1.38 gallons of vapor phase hydrocarbons were removed during the event. Once GRI receives the results of the ground water sampling event that is tentatively scheduled for November 2014, the overall effectiveness of the MMPE event can be determined. TABLE OF CONTENTS 1.0 SITE HISTORY AND CHARACTERIZATION .............................................................................. 1 2.0 MMPE EVENT ...................................................................................................................................... 2 3.0 CONCLUSIONS AND RECOMMENDATIONS .............................................................................. 3 4.0 LIMITATIONS...................................................................................................................................... 3 FIGURES Figure 1: Site Location Map Figure 2: Site Map TABLES Table 1: Well Construction and Gauging Information Table 2: Free Product Recovery Results Table 3: Free Product Recovery Event Information Table 4: Free Product Recovery Cost Summary APPENDICES Appendix A: MMPE Data and Calculations Appendix B: Disposal Manifests 1 1.0 SITE HISTORY AND CHARACTERIZATION The purpose of this report is to present the results of a Mobile Multi-Phase Extraction (MMPE) event conducted between October 13 and 17, 2014 at the former Red Apple Market #21 site, located along NC Highway 561 West in Saint John, Hertford County, North Carolina (Figure 1). The activities were conducted in accordance with Geological Resources, Inc. (GRI) Proposal No. 14-397, which was submitted to NCDENR on July 23, 2014 and approved as Task Authorization No. 9785-060 on October 2, 2014. The purpose of the activities was to remove free product and reduce contaminant concentrations in monitoring wells MW-2R, MW-3R, MW-4R and MW-5R. According to available information, two 1,000-gallon gasoline and one 550-gallon gasoline underground storage tanks (USTs) were removed from the site in October 1992. In addition, one 550-gallon gasoline UST was closed in-place in October 1992. Twenty-seven Type II monitoring wells (MW-1 through MW-6, MW-8 through MW- 23, MW-25 and MW-27 through MW-30), one Type III monitoring well (MWD-7) and three recovery wells (RW-1 through RW-3) were installed at the site during past ground water assessment and remediation activities. A total of 4,381.57 tons of contaminated soil was removed from the site between May 16 and June 2, 2011. Prior to the May-June 2011 soil excavation, monitoring wells MW-1 through MW5, MWD-7 as well as recovery wells RW-1 and RW-3 were abandoned. Monitoring wells MW-1R through MW-5R were installed following the completion of the May-June 2011 excavation activities. Please note, monitoring wells MW-6, MW-11, MW-12, MW-13 and MW-29 were destroyed during past site activities. Ground water samples collected from monitoring wells at the site and nearby water supply wells have exceeded the maximum allowable concentrations (MACs) during past sampling events. Free product has been historically reported in monitoring wells MW-2, MW-3, MW-5, MW-2R, MW-3R, MW-4R and MW-5R. Please note that certain information contained in this report was obtained under the supervision of previous consultants. Although GRI cannot verify the accuracy of information obtained from previous reports, for the purpose of this report, it is assumed to be correct. A Site Map showing the locations of the monitoring wells and the structures on-site and on surrounding properties has been included as Figure 2. Please refer to previous submittals for further historical information regarding the site. 2 2.0 MMPE EVENT A MMPE event was conducted at the site by Greenwood Applied Services (GAS) under the supervision of GRI beginning on October 13, 2014 and ending on October 17, 2014. The MMPE equipment included a liquid ring pump, 9,500-gallon capacity tanker, flexible vacuum hoses, 1-inch diameter PVC stinger pipes and associated couplings and pipe fittings to manifold to four monitoring wells (MW-2R, MW-3R, MW-4R and MW-5R). The MMPE system was rated at 24in./Hg at 280 cfm. Monitoring wells MW-2R, MW-3R, MW-4R and MW-5R were gauged on October 13, 2014 prior to the event. A free product thickness of 0.02 feet was measured in MW- 4R prior to the start of the event. No measurable free product was observed in MW-2R, MW-3R or MW-5R. The stinger pipes were set at depths of 15.48, 16.23, 15.07 and 15.85 feet in MW-2R, MW-3R, MW-4R and MW-5R, respectively. Monitoring wells MW-2R, MW-3R, MW-4R and MW-5R were vacuumed continuously for a total of 96 hours during the event. Measurements of relative humidity, temperature, vacuum, exhaust velocity, and off-gas concentrations were recorded at the discharge stack at a minimum of two times per 24-hour period. Vacuum at the extraction wells ranged from 22 to 28 in./Hg. Exhaust velocities ranged from 161 to 1,167 fpm. Temperatures ranged from 92.3 to 131.2ºF and relative humidity ranged from 37.8 to 100.0 percent. Total VOC off-gas concentrations ranged from 269.0 to 1,504 ppm during the event. At the conclusion of the event, no measurable free product was observed in MW-2R, MW-3R or MW-5R; however, a free product thickness of 0.09 feet was measured in MW-4R. A summary of well construction and gauging data obtained before start up and at the conclusion of the MMPE event is presented in Table 1. A copy of the MMPE data and calculations has been included as Appendix A. The results of the MMPE event indicate that a total of 9,500 gallons of liquid was removed during the event. Of the 9,500 gallons of liquid recovered, 4 gallons of free phase product were present in the tanker. Based on 96 hours of operation, the average fluid recovery rate was 98.96 gallons per hour. Based on mass-removal calculations, an additional 8.64 pounds or 1.38 gallons of vapor phase hydrocarbons were removed. Based on 96 hours of operation, an average of approximately 0.01 gallons of vapor phase hydrocarbons was removed per hour by the MMPE system. Based on the October 2014 MMPE event, the cost of free product and contaminated ground water recovered per gallon was $1.06. A summary of free product recovery results has been included as Table 2. A summary of information collected during the MMPE event as well as a breakdown of fluids removed 3 is included as Table 3. A summary of costs associated with free product recovery is included as Table 4. At the conclusion of the MMPE event, all wastewater was transported to a permitted facility for disposal. Copies of disposal manifests have been included as Appendix B. 3.0 CONCLUSIONS AND RECOMMENDATIONS  A total of 9,500 gallons of affected ground water was recovered during the MMPE event conducted between October 13 and 17, 2014. Of the 9,500 gallons recovered, 4 gallons of free product were observed in the tanker at the conclusion of the event. The average fluid recovery rate was 98.96 gallons per hour. Based on mass-removal calculations, an additional 8.64 pounds or 1.38 gallons of vapor phase hydrocarbons were removed at an average of approximately 0.01 gallons per hour by the MMPE system. Based on the October 2014 MMPE event, the cost of free product and contaminated ground water recovered per gallon was $1.06. Upon conclusion of the event, no measurable free product was observed in MW-2R, MW-3R or MW-5R; however, a free product thickness of 0.09 feet was measured in MW- 4R.  Based on the above information, the MMPE removed contaminated ground water and free product from monitoring wells MW-2R, MW-3R, MW-4R and MW-5R. GRI personnel will return to the site in November 2014 to conduct a comprehensive ground water sampling event. Once the data from the November 2014 sampling event are evaluated, the overall effectiveness of the MMPE event will be evaluated. 4.0 LIMITATIONS This report has been prepared for the exclusive use of North East Oil Company, Inc, for specific application to the referenced site in Hertford County, North Carolina. The assessment was conducted based on the scope of work and level of effort specified by NCDENR and with resources adequate only for that scope of work. Our findings have been developed in accordance with generally accepted standards of geology and hydrogeology practices in the State of North Carolina, available information, and our professional judgment. No other warranty is expressed or implied. 4 The data that are presented in this report are indicative of conditions that existed at the precise locations sampled and at the time the samples were collected. In addition, the data obtained from samples would be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No additional information can logically be inferred from these data. Please note that field data collected prior to the July 2007 sampling and updated receptor survey event was not obtained under the supervision of GRI. Although the accuracy of this information cannot be verified, for the purpose of this report GRI assumes that it is correct. FIGURES TABLES 01/18/07 12.87 0.00 87.13       06/06/07 13.15 0.00 86.85 06/02/08 14.10 0.00 85.90 12/18/08 16.41 0.00 83.59 03/24/09 14.62 0.00 85.38 06/25/09 15.00 0.00 85.00 09/16/09 15.58 0.02 84.44 Before AFVR 09/16/09 15.64 0.00 84.36 After AFVR 09/21/09 15.66 0.00 84.34 11/17/09 15.42 0.00 84.58 Before AFVR 11/17/09 15.55 0.01 84.46 After AFVR 12/30/09 14.85 0.00 85.15 10/05/10 14.74 0.00 85.26 06/28/10 14.02 0.00 85.98 Abandoned 10/12/11 15.73 0.00 39.03 01/31/12 15.71 0.00 39.05 05/15/12 14.77 0.00 39.99 01/22/13 14.68 0.00 40.08 11/18/13 15.84 0.00 38.92 05/27/14 14.36 0.00 40.40 01/18/07 14.81 3.25 87.58 06/06/07 13.07 0.69 87.12 06/02/08 15.20 2.27 86.35 11/06/08 16.90 2.60 84.93 Before AFVR 11/06/08 15.04 0.16 84.70 After AFVR 12/18/08 15.25 0.69 84.94 03/24/09 16.90 3.54 85.74 06/10/09 15.84 2.12 85.58 Before AFVR 06/10/06 14.29 0.01 85.32 After AFVR 06/25/09 14.90 0.46 85.09 09/16/09 14.85 1.17 85.75 Before AFVR 09/16/09 15.05 0.00 84.55 After AFVR 09/21/09 15.07 0.03 84.56 11/17/09 15.44 0.59 84.67 Before AFVR 11/17/09 14.98 0.02 84.64 After AFVR 12/30/09 14.65 0.33 85.23 10/05/10 15.81 2.04 85.54 06/28/10 15.65 2.79 86.34 Abandoned 10/12/11 14.71 0.00 39.18 01/31/12 14.67 0.22 39.41 05/15/12 13.96 0.23 40.13 12/17/12 15.25 0.75 39.28 Before MMPE 12/21/12 17.94 0.00 35.95 After MMPE 01/22/13 13.85 0.00 40.04 10/07/13 15.00 0.00 38.89 Before MMPE 10/11/13 15.99 0.00 37.90 After MMPE 11/18/13 14.95 0.00 38.94 04/28/14 13.22 0.00 40.67 Before MMPE 05/02/14 16.95 0.00 36.94 After MMPE 05/27/14 13.71 0.00 40.18 10/13/14 14.48 0.00 39.41 Before MMPE 10/17/14 16.70 0.00 37.19 After MMPE 01/18/07 14.02 0.00 86.99 06/06/07 13.86 0.00 87.15 06/02/08 14.77 0.00 86.24 12/18/08 16.27 0.00 84.74 03/24/09 15.90 0.00 85.11 06/25/09 15.80 0.00 85.21 09/16/09 16.72 0.02 84.31 Before AFVR 09/16/09 16.40 0.01 84.62 After AFVR 09/21/09 16.40 0.00 84.61 11/17/09 16.77 0.00 84.24 Before AFVR 11/17/09 16.40 0.01 84.62 After AFVR 12/30/09 13.97 0.00 87.04 10/05/10 15.50 0.00 85.51 06/28/10 15.76 0.00 85.25 Abandoned 10/12/11 14.48 0.00 40.12 01/31/12 15.88 0.00 38.72 05/15/12 14.31 0.00 40.29 12/17/12 14.54 0.00 40.06 Before MMPE 12/21/12 11.85 0.30 43.01 After MMPE 01/22/13 15.09 0.00 39.51 10/07/13 16.20 0.00 38.40 Before MMPE 10/11/13 11.58 0.00 43.02 After MMPE 11/18/13 16.48 0.00 38.12 04/28/14 13.75 0.00 40.85 Before MMPE 05/02/14 10.23 0.00 44.37 After MMPE 05/27/14 16.74 0.00 37.86 10/13/14 15.23 0.00 39.37 Before MMPE 10/17/14 11.74 0.00 42.86 After MMPE 01/18/07 12.69 0.00 87.37 06/14/07 13.06 0.00 87.00 06/02/08 NM NM NM Destroyed 54.602010-201010/12/11MW-3R 10/12/11MW-1R 53.892010-201010/12/11MW-2R TABLE 1 WELL CONSTRUCTION AND GAUGING INFORMATION RED APPLE MARKET # 21 (INCIDENT NO. 9785) Date: 10/23/14 Facility ID # : 0-030290 Well ID Date Installed (mm/dd/yy) Date Water Level Measured (mm/dd/yy) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness** (ft.) Ground Water Elevation* (ft.) Comments MW-1 05/06/93 7 7-27 27 100.00 10 10-20 20 99.60 54.762010-2010 MW-3 05/07/93 10 10-20 20 101.01 MW-4 NA NA NA NA 100.06 MW-2 05/07/93 Page 1 of 5 TABLE 1 WELL CONSTRUCTION AND GAUGING INFORMATION RED APPLE MARKET # 21 (INCIDENT NO. 9785) Date: 10/23/14 Facility ID # : 0-030290 Well ID Date Installed (mm/dd/yy) Date Water Level Measured (mm/dd/yy) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness** (ft.) Ground Water Elevation* (ft.) Comments 10/12/11 13.28 0.13 40.85 01/31/12 13.12 0.29 41.15 05/15/12 14.13 0.51 40.33 01/22/13 14.22 0.30 40.06 10/07/13 15.16 0.43 39.23 Before MMPE 10/11/13 11.65 0.03 42.40 After MMPE 11/18/13 14.86 0.01 39.17 04/28/14 11.21 0.00 42.81 Before MMPE 05/02/14 11.55 0.45 42.86 After MMPE 05/27/14 13.58 0.00 40.44 10/13/14 15.08 0.02 38.96 Before MMPE 10/17/14 13.64 0.09 40.46 After MMPE 01/18/07 13.02 0.00 87.80 06/06/07 13.23 0.00 87.59 06/02/08 NM NM NM Not Located 12/18/08 NM NM NM Dry 03/24/09 NM NM NM Dry 06/25/09 NM NM NM Dry 09/21/09 15.47 0.00 85.35 12/30/09 14.44 0.00 86.38 10/05/10 14.60 0.00 86.22 06/28/10 13.99 0.00 86.83 Abandoned 10/12/11 14.16 0.02 40.32 01/31/12 15.36 0.00 39.10 05/15/12 14.20 0.00 40.26 12/17/12 14.57 0.00 39.89 Before MMPE 12/21/12 14.10 0.00 40.36 After MMPE 01/22/13 14.45 0.00 40.01 11/18/13 15.44 0.00 39.02 04/28/14 13.97 0.00 40.49 Before MMPE 05/02/14 13.75 0.00 40.71 After MMPE 05/27/14 13.98 0.00 40.48 10/13/14 14.85 0.00 39.61 Before MMPE 10/17/14 14.90 0.00 39.56 After MMPE MW-6 NA 01/18/07 NA NA NA 100.49 NM NM NM Destroyed 01/18/07 12.35 0.00 87.45 06/06/07 12.43 0.00 87.37 06/02/08 21.80 0.00 78.00 12/18/08 15.27 0.00 84.53 03/24/09 14.55 0.00 85.25 06/25/09 14.85 0.00 84.95 09/21/09 15.52 0.00 84.28 12/30/09 14.70 0.00 85.10 06/28/10 13.87 0.00 85.93 10/05/10 NM NM NM Abandoned 01/18/07 8.59 0.00 92.27 06/06/07 12.87 0.00 87.99 06/02/08 NM NM NM Not Located 12/18/08 17.22 0.00 83.64 03/24/09 4.97 0.00 95.89 06/25/09 16.10 0.00 84.76 09/21/09 17.35 0.00 83.51 12/30/09 6.28 0.00 94.58 06/28/10 14.79 0.00 86.07 10/05/10 12.08 0.00 88.78 10/12/11 16.24 0.00 38.52 01/31/12 11.46 0.00 43.30 05/15/12 13.32 0.00 41.44 11/18/13 15.30 0.00 39.46 05/27/14 12.74 0.00 42.02 01/18/07 7.73 0.00 92.95 06/06/07 9.35 0.00 91.33 06/02/08 8.21 0.00 92.47 12/18/08 11.72 0.00 88.96 03/24/09 11.60 0.00 89.08 06/25/09 11.73 0.00 88.95 09/21/09 12.62 0.00 88.06 12/30/09 12.24 0.00 88.44 06/28/10 12.40 0.00 88.28 10/05/10 12.69 0.00 87.99 10/12/11 10.00 0.00 44.67 01/31/12 10.59 0.00 44.08 05/15/12 9.94 0.00 44.73 12/17/12 10.88 0.00 43.79 Before MMPE 12/21/12 9.41 0.00 45.26 After MMPE 01/22/13 5.34 0.00 49.33 11/18/13 11.49 0.00 43.18 05/27/14 9.64 0.00 45.03 903/14/94MW-8 903/14/94MW-9 100.68 54.46201010/12/11MW-5R 10-20 54.022010-201010/12/11MW-4R MW-5 NA NA NA NA 100.82 MWD-7 02/08/94 30 30-35 35 99.80 100.86 54.76 199-19 54.67 199-19 Page 2 of 5 TABLE 1 WELL CONSTRUCTION AND GAUGING INFORMATION RED APPLE MARKET # 21 (INCIDENT NO. 9785) Date: 10/23/14 Facility ID # : 0-030290 Well ID Date Installed (mm/dd/yy) Date Water Level Measured (mm/dd/yy) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness** (ft.) Ground Water Elevation* (ft.) Comments 01/18/07 14.26 0.00 86.86 06/06/07 14.38 0.00 86.74 06/02/08 15.50 0.00 85.62 12/18/08 16.62 0.00 84.50 03/24/09 15.99 0.00 85.13 06/25/09 16.16 0.00 84.96 09/21/09 16.85 0.00 84.27 12/30/09 15.98 0.00 85.14 06/28/10 15.45 0.00 85.67 10/05/10 15.97 0.00 85.15 10/12/11 16.40 0.00 38.81 01/31/12 16.05 0.00 39.16 05/15/12 NS NS NS Inaccessable 01/22/13 15.50 0.00 39.71 11/18/13 16.48 0.00 38.73 05/27/14 15.12 0.00 40.09 MW-11 NA 01/18/07 NA NA NA 100.08 NM NM NM Destroyed MW-12 NA 01/18/07 NA NA NA 99.49 NM NM NM Destroyed 01/18/07 12.72 0.00 87.11 06/06/07 12.83 0.00 87.00 Destroyed 01/18/07 13.78 0.00 87.59 06/06/07 13.93 0.00 87.44 06/02/08 14.90 0.00 86.47 12/18/08 16.49 0.00 84.88 03/24/09 13.73 0.00 87.64 06/25/09 15.85 0.00 85.52 09/21/09 16.60 0.00 84.77 12/30/09 15.92 0.00 85.45 06/28/10 14.92 0.00 86.45 10/05/10 15.83 0.00 85.54 10/12/11 16.28 0.00 39.11 01/31/12 16.00 0.00 39.39 01/22/13 15.44 0.00 39.95 11/18/13 16.22 0.00 39.17 05/27/14 14.91 0.00 40.48 01/18/07 14.32 0.00 87.66 06/06/07 14.43 0.00 87.55 06/02/08 15.47 0.00 86.51 12/18/08 NM NM NM Not Sampled 03/24/09 16.26 0.00 85.72 06/25/09 16.38 0.00 85.60 09/21/09 17.10 0.00 84.88 12/30/09 NM NM NM Not Sampled 06/28/10 15.42 0.00 86.56 10/05/10 16.35 0.00 85.63 10/12/11 16.79 0.00 39.22 01/31/12 16.55 0.00 39.46 11/18/13 16.75 0.00 39.26 05/27/14 15.42 0.00 40.59 01/18/07 NM NM NM 06/06/07 13.34 0.00 87.56 06/02/08 NM NM NM NA 12/18/08 NM NM NM Not Sampled 03/24/09 15.31 0.00 85.59 06/25/09 15.31 0.00 85.59 09/21/09 NM NM NM Not Sampled 12/30/09 NM NM NM Not Sampled 06/28/10 NM NM NM Not Sampled 10/05/10 15.28 0.00 85.62 10/12/11 15.70 0.00 39.18 01/31/12 15.46 0.00 39.42 11/18/13 NM NM NM Not Sampled 05/27/14 14.40 0.00 40.48 01/18/07 NM NM NM 06/06/07 11.93 0.00 87.36 06/02/08 NM NM NM NA 12/18/08 NM NM NM Not Sampled 03/24/09 13.81 0.00 85.48 06/25/09 13.84 0.00 85.45 09/21/09 NM NM NM Not Sampled 12/30/09 NM NM NM Not Sampled 06/28/10 NM NM NM Not Sampled 10/05/10 13.82 0.00 85.47 10/12/11 14.33 0.00 39.28 01/31/12 14.07 0.00 39.54 11/18/13 NM NM NM Not Sampled 05/27/14 12.99 0.00 40.62 1103/14/94MW-10 12-22 22 55.39 55.21 2111-21 NA NA 54.88 56.01 NANA 53.61 NANA 101.12 MW-13 NA NA NA NA 99.83 101.37 MW-14 04/05/95 12 101.98 NANAMW-15 100.90 MW-16 NA NA 99.29 NANAMW-17 Page 3 of 5 TABLE 1 WELL CONSTRUCTION AND GAUGING INFORMATION RED APPLE MARKET # 21 (INCIDENT NO. 9785) Date: 10/23/14 Facility ID # : 0-030290 Well ID Date Installed (mm/dd/yy) Date Water Level Measured (mm/dd/yy) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness** (ft.) Ground Water Elevation* (ft.) Comments 01/18/07 14.09 0.00 87.89 06/06/07 14.38 0.00 87.60 06/02/08 15.24 0.00 86.74 12/18/08 16.68 0.00 85.30 03/24/09 16.04 0.00 85.94 06/25/09 16.19 0.00 85.79 09/21/09 16.92 0.00 85.06 12/30/09 16.01 0.00 85.97 06/28/10 15.38 0.00 86.60 10/05/10 NM NM NM 10/12/11 16.46 0.00 38.83 01/31/12 16.14 0.00 39.15 05/15/12 NS NS NS Inaccessable 11/18/13 16.46 0.00 38.83 05/27/14 15.23 0.00 40.06 01/18/07 13.14 0.00 86.80 06/06/07 13.27 0.00 86.67 06/02/08 14.15 0.00 85.79 12/18/08 15.52 0.00 84.42 03/24/09 14.81 0.00 85.13 06/25/09 15.03 0.00 84.91 09/21/09 15.73 0.00 84.21 12/30/09 14.87 0.00 85.07 06/28/10 14.19 0.00 85.75 10/05/10 NM NM NM 10/12/11 15.30 0.00 38.76 01/31/12 15.01 0.00 39.05 05/15/12 NS NS NS Inaccessable 11/18/13 15.33 0.00 38.73 05/27/14 14.55 0.00 39.51 01/18/07 12.86 0.00 86.93 06/06/07 13.25 0.00 86.54 06/02/08 14.07 0.00 85.72 12/18/08 15.46 0.00 84.33 03/24/09 14.75 0.00 85.04 06/25/09 14.98 0.00 84.81 09/21/09 15.40 0.00 84.39 12/30/09 14.88 0.00 84.91 06/28/10 14.23 0.00 85.56 10/05/10 NM NM NM 10/12/11 15.28 0.00 38.80 01/31/12 15.02 0.00 39.06 05/15/12 14.20 0.00 39.88 11/18/13 15.30 0.00 38.78 05/27/14 NM NM NM Inaccessable 01/18/07 14.18 0.00 86.51 06/06/07 13.97 0.00 86.72 06/02/08 14.95 0.00 85.74 12/18/08 16.25 0.00 84.44 03/24/09 15.56 0.00 85.13 06/25/09 15.80 0.00 84.89 09/21/09 16.55 0.00 84.14 12/30/09 16.62 0.00 84.07 06/28/10 15.07 0.00 84.93 10/05/10 15.59 0.00 85.10 10/12/11 16.22 0.00 38.62 01/31/12 15.54 0.00 39.30 05/15/12 15.00 0.00 39.84 01/22/13 15.16 0.00 39.68 11/18/13 16.19 0.00 38.65 05/27/14 14.83 0.00 40.01 06/02/08 16.13 0.00 NM 12/18/08 NM NM NM 05/15/12 15.80 0.00 NM 11/18/13 16.88 0.00 NM 05/27/14 NM NM NM Inaccessable 06/02/08 1.69 0.00 NM 12/18/08 NM NM NM 10/12/11 NM NM NM 05/15/12 0.68 0.00 54.09 11/18/13 1.50 0.00 53.27 05/27/14 2.04 0.00 52.73 03/24/09 12.41 0.00 85.25 06/25/09 12.78 0.00 84.88 09/21/09 13.42 0.00 84.24 12/30/09 12.54 0.00 85.12 06/28/10 11.88 0.00 85.78 10/05/10 12.52 0.00 85.14 10/12/11 12.98 0.00 38.89 01/31/12 12.62 0.00 39.25 05/15/12 11.94 0.00 39.93 11/18/13 12.99 0.00 38.88 05/27/14 11.72 0.00 40.15 NMNANANANAMW-22 51.87 NA MW-25 03/24/09 10 10-22 22 55.29 22 54.08 54.06 2210-2210 54.84 2210-221004/10/95MW-21 MW-20 54.77 NANANAMW-23 101.98 MW-18 04/07/95 10 99.94 04/07/95MW-19 99.79 04/10/95 10 10-22 100.69 NM 97.66 10-20 20 Page 4 of 5 TABLE 1 WELL CONSTRUCTION AND GAUGING INFORMATION RED APPLE MARKET # 21 (INCIDENT NO. 9785) Date: 10/23/14 Facility ID # : 0-030290 Well ID Date Installed (mm/dd/yy) Date Water Level Measured (mm/dd/yy) Well Casing Depth (ft. BGS) Screened Interval (x to y ft. BGS) Bottom of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing (ft.) Free Product Thickness** (ft.) Ground Water Elevation* (ft.) Comments 03/24/09 16.33 0.00 83.26 06/25/09 13.47 0.00 86.12 09/21/09 NM NM NM Not Sampled 12/30/09 11.74 0.00 87.85 06/28/10 11.10 0.00 88.49 10/05/10 10.50 0.00 89.09 10/12/11 13.03 0.00 40.71 01/31/12 11.45 0.00 42.29 11/18/13 14.23 0.00 39.51 05/27/14 12.05 0.00 41.69 03/24/09 18.06 0.00 82.13 06/25/09 15.00 0.00 85.19 09/21/09 15.65 0.00 84.54 12/30/09 14.96 0.00 85.23 06/28/10 13.96 0.00 86.23 10/05/10 14.68 0.00 85.51 10/12/11 15.25 0.00 39.05 01/31/12 14.89 0.00 39.41 11/18/13 15.19 0.00 39.11 05/27/14 12.53 0.00 41.77 03/24/09 14.55 0.00 85.67 06/25/09 15.20 0.00 85.02 09/21/09 NM NM NM Not Sampled 12/30/09 15.14 0.00 85.08 06/28/10 14.30 0.00 85.92 10/05/10 15.00 0.00 85.22 10/12/11 54.34 NM NM NM Destroyed 03/24/09 13.10 0.00 85.77 06/25/09 13.92 0.00 84.95 09/21/09 14.62 0.00 84.25 12/30/09 13.84 0.00 85.03 06/28/10 13.04 0.00 85.83 10/05/10 13.72 0.00 85.15 10/12/11 14.16 0.00 38.86 01/31/12 13.84 0.00 39.18 05/15/12 13.12 0.00 39.90 11/18/13 14.17 0.00 38.85 05/27/14 12.88 0.00 40.14 Notes: •  *: Reference point for elevation measurements; assumed elevation 100.00 feet. •  **: If free product is present in a well, ground water elevation should be calculated by: (Top of Casing Elevation - Depth to Water) +    (Free Product Thickness x 0.8581) •  ft BGS : feet below ground surface. •  NA: Not Available. •  NM:  Not Measured. •  Well construction details for monitoring wells installed prior to March 2009 are reproduced from well identification tags, where available. 1003/24/09MW-27 MW-30 MW-28 03/24/09 10 10-20 20 53.02 2010-2010 54.30 53.74 2010-20 100.19 99.59 98.87 MW-29 03/24/09 10 10-20 20 100.22 03/24/09 Page 5 of 5 Method of Measurement: Well ID Product Type (gas, diesel, etc.) Date of Recovery (mm/dd/yy) Free Product Recovery Method* Casing Diameter (inches) Product Thickness before Recovery (feet) Product Thickness after Recovery (feet) Amount of Liquid Recovered (gallons) Amount of Product Recovered (gallons) 02/20/07 3.45 0.02 2,952 40.00 12/17/08 2.60 0.00 3,078 5.25 06/10/09 2.12 0.01 2,115 0.00 09/16/09 1.17 0.16 3,055 0.00 11/17/09 0.59 0.00 3,060 0.00 MW-2R 0.75 0.00 MW-4R 0.00 0.31 MW-5R 0.00 0.00 MW-9 0.00 0.00 MW-2R 0.00 0.00 MW-3R 0.00 0.00 MW-4R 0.43 0.03 MW-2R 0.00 0.00 MW-3R 0.00 0.00 MW-4R 0.00 0.45 MW-5R 0.00 0.00 MW-2R 0.00 0.00 MW-3R 0.00 0.00 MW-4R 0.02 0.09 MW-5R 0.00 0.00 Notes : • *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE). • Amount of Liquid Recovered (gallons) includes Total liquids (Water and Free Product) as indicated on Disposal Manifest. • Amount of Product Recovered (in gallons) includes only the volume of free product in the tanker at the end of the event (based on Disposal Manifest and Field Notes). 5.389,5002"MMPE10/13/14 - 10/17/14Gasoline 9.009,3172"MMPE04/28/14- 05/02/14Gasoline Gasoline MMPE10/07/13 - 10/11/13 2"3,493 6.97 Gasoline 12/17/12 - 12/21/12 MMPE 2"4.054,577 TABLE 2 FREE PRODUCT RECOVERY RESULTS RED APPLE MARKET #21 (INCIDENT NO. 9785) Interface probe at top-of-casing 2"AFVRGasolineMW-2 Date: 10/23/14 Facility ID#: 0-030290 02/20/07 1,334.62 164.15 1,033.69 1.14 2,952 40 41.14 12/17/08 7,901.24 201.39 8.03 0.20 3,078 5.25 5.45 06/10/09 7,461.43 234.14 53.57 1.24 2,115 0 1.24 09/16/09 2,873.67 229.52 60.13 0.54 3,055 0 0.54 11/17/09 4,006.48 178.69 26.88 0.52 3,060 0 0.52 MW-2R MW-4R MW-5R MW-9 MW-2R MW-3R MW-4R MW-2R MW-3R MW-4R MW-5R MW-2R MW-3R MW-4R MW-5R 18.00 41,147 58.25 76.25 Notes: • *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE) • Amount of Vaporized Product (in gallons) is based on Vapor Emissions Summary Sheet, = lbs emitted/6.25 • Amount of Liquid Recovered includes Total liquids (Water and Free Product) as indicated on Disposal Manifest. • Amount of Product Recovered as Liquid includes only the volume of free product in the tanker at the end of the event (based on Disposal Manifest and/or Field Notes). • Total Amount of Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid • Total Fluids Removed = Amount of Vaporized Product + Amount of Liquid Recovered 583.00MMPE10/13/14 - 10/17/14 5.3849,5001.38532.51104.15 209.54MMPE04/28/14- 05/02/14 10.9699,3171.961,434.7778.78 3,493 0 6.9710/07/13 - 10/11/13 MMPE 1,211.57 105.25 982.39 6.97 SUMMARY OF FLUID REMOVAL Current Event Total To Date Total Fluids Removed (in gallons)Total Amount of Product Removed (in gallons) 9,501.38 41,165.00 5.38 76.25 Summary TABLE 3 FREE PRODUCT RECOVERY EVENT INFORMATION RED APPLE MARKET #21 (INCIDENT NO. 9785) Well ID Date (mm/dd/yy) Total Amount of Product Recovered (gallons) Product Recovery Method* Amount of Liquid Recovered (gallons) Average Effluent Concentration (ppm) Totals Average Effluent Velocity (ft/min) Average Effluent Temperature (°F) AFVRMW-2 12/17/12 - 12/21/12 MMPE 1,747.82104.72384.36 Date: 10/23/14 4.0504,577 Amount of Vaporized Product (gallons) 4.05 Amount of Product Recovered as Liquid (gallons) Facility ID #: 0-030290 Date: 10/23/14 Wells Included in Event Product Recovery Method* Date of Event (mm/dd/yy) Total Amount of Free Product plus Ground Water Recovered (gallons) Cost of Free Product Recovery Event Cost Per Gallon (Total Fluids) MW-2R, MW-4R, MW-5R and MW-9 MMPE 12/17/12 - 12/21/12 4,581.05 $8,717.25 $1.90 MW-2R, MW-3R and MW-4R MMPE 10/07/13 - 10/11/13 3,499.97 $8,542.25 $2.44 MW-2R, MW-3R, MW-4R and MW-5R MMPE 04/28/14 - 05/02/14 9,318.96 $10,302.33 $1.11 MW-2R, MW-3R, MW-4R and MW-5R MMPE 10/13/14 - 10/17/14 9,501.38 $10,113.20 $1.06 26,901.36 $37,675.03 $1.40 Notes: • *: Bailing, Skimming, Aggressive Fluid Vapor Recovery (AFVR), Mobile Multiphase Extraction (MMPE) • Total Amount of Free Product Recovered = Amount of Vaporized Product + Amount of Product Recovered as Liquid • Cost of Free Product Recovery Event includes supervision, travel, mileage, per diem, subcontractor costs, report preparation and project management. • Costs of Free Product Recovery Events conducted prior to current event are not included in the above total. TOTAL TABLE 4 FREE PRODUCT RECOVERY COST SUMMARY RED APPLE MARKET #21 (INCIDENT NO. 9785) Comments Cost per gallon for the event is based on a total volume of 4581.05 gallons of contaminated water and vaporized product. Cost per gallon for the event is based on a total volume of 3,499.97 gallons of contaminated water and vaporized product. Cost per gallon for the event is based on a total volume of 9,318.96 gallons of contaminated water and vaporized product. Facility ID #: 0-030290 Cost per gallon for the event is based on a total volume of 9,501.38 gallons of contaminated water and vaporized product. APPENDICES APPENDIX A MMPE Data and Calculations Site Name :Red Apple Market #21 Incident Number :9785 Site Location:NC Highway 561, Saint John, Hertford County, NC Client Name:Geological Resources Inc Blower Specifications For Vacuum Truck (e.g: 960 cfm @ 24 in. of Hg) :280 cfm @ 24 in. of Hg Stack Diameter (inches):2 Start Time :10:30 Start Date:10/13/14 End Time :10:30 End Date:10/17/14 Note: Take all the readings listed below about 3 to 4 times every day at approximately the same time. MMPE Contractor:Greenwood Applied Services,LLC Consultant:Geological Resources, Inc. EXTRACTION WELL INFORMATION: MW-2R MW-3R MW-4R MW-5R 2 2 2 2 15.48 16.23 15.07 15.85 18.50 18.00 17.00 17.25 Date Time System Vacuum Exhaust Velocity Temperature Rel. Humidity OVA (in. of Hg)(ft/min)(°F)(%)(ppm) 10:45 23.00 845 107.1 52.1 319.9 0.0 12:00 23.00 1,045 127.1 41.1 321.9 0.0 16:00 23.00 1,167 131.2 37.8 320.0 5.0 6:45 23.00 885 113.2 47.0 280.8 13.0 12:00 28.00 161 93.1 100.0 1127 17.0 16:00 28.00 204 104.9 100.0 1210 19.0 6:20 27.00 224 92.3 100.0 1504 30.0 12:00 25.00 554 99.0 100.0 357.1 34.0 16:00 25.00 545 96.5 100.0 350.3 36.0 6:50 25.00 511 95.0 100.0 352.3 45.0 12:00 25.00 501 100.6 100.0 269.0 49.0 16:00 25.00 520 101.0 100.0 292.1 33.0 7:00 25.00 486 97.0 100.0 404.1 42.0 10:20 25.00 514 100.1 100.0 346.6 FLUID RECOVERY SUMMARY: Day 1 (24 hours)Day 2 (48 hrs)Day 3 (72 hrs)Day 4 (96 hrs) Total Fluid Recovered (gallons)1,968 2,775 2,684 2,073 Total Product Recovered (gallons)-------- Tank Stick (inch) Vol. Rec. (gal) MOBILE MULTI-PHASE EXTRACTION EVENT DATA SHEET - FIELD LOG 1 Well Number Diameter (inch) Initial Stinger Depth (ft.) Final Stinger Depth (ft.) TOTAL (event) 9,500 4 10/13/2014 10/14/2014 10/15/2014 10/16/2014 10/17/2014 Day Page 1 of 2 Site Name :Red Apple Market #21 Incident Number :9785 Site Location:NC Highway 561, Saint John, Hertford County, NC Client Name:Geological Resources Inc Start Time :10:30 10/17/14 Note: Take all the readings listed below about 3 to 4 times every day at approximately the same time. MMPE Contractor:Greenwood Applied Services,LLC Consultant:Geological Resources, Inc. MW-2R MW-3R MW-4R MW-5R Initial DTW (ft.)14.48 15.23 15.08 14.85 Initial DTP (ft.)------15.06 --- Final DTW (ft.)16.70 11.74 13.64 14.90 Final DTP (ft.)------13.55 --- DTW = Depth to Water; DTP = Depth to Product OBSERVATION WELLS (VACUUM /WATER LEVELS) Well 1 Well 2 Well 3 Well 4 Well 5 Well 6 Vacuum Water Lvl Vacuum Water Lvl Vacuum Water Lvl Vacuum Water Lvl (in. H2O)(ft.)(in. H2O)(ft.)(in. H2O)(ft.)(in. H2O)(ft.) 10:45 22.00 23.00 20.00 22.00 12:00 22.00 23.00 20.00 22.00 0.10 0.10 0.10 16:00 22.00 23.00 20.00 22.00 0.10 0.10 0.10 6:45 22.00 23.00 20.00 22.00 0.10 15.48 0.20 1.55 0.10 11.58 12:00 27.00 28.00 25.00 27.00 0.10 0.20 0.10 16:00 27.00 28.00 25.00 27.00 0.10 0.20 0.10 6:20 27.00 27.00 25.00 26.00 0.10 15.48 0.30 1.57 0.10 11.58 12:00 24.00 25.00 25.00 24.00 0.10 0.30 0.10 16:00 24.00 25.00 25.00 24.00 0.10 0.30 0.10 6:50 24.00 25.00 23.00 24.00 0.10 15.48 0.30 1.58 0.10 11.58 12:00 24.00 25.00 23.00 24.00 0.10 0.30 0.10 16:00 24.00 25.00 23.00 24.00 0.10 0.20 0.10 7:00 24.00 25.00 23.00 24.00 0.10 0.20 0.10 10:20 24.00 25.00 23.00 24.00 0.10 0.20 0.10 MOBILE MULTI-PHASE EXTRACTION EVENT DATA SHEET - FIELD LOG 2 10:30 Start Date:10/13/14 End Time:End Date: Water/Product Levels EXTRACTION POINTS - VACUUM (inches of Hg)OBSERVATION WELLS (WATER LEVELS) MW-1R MW-23 MW-9 15.23 1.48 11.45 --------- 15.44 0.87 11.43 --------- DATE TIME EXTRACTION POINTS - VACUUM (inches of Hg) MW-1R MW-23 MW-2R MW-3R MW-4R MW-5R MW-9 10/13/2014 10/14/2014 10/15/2014 10/16/2014 10/17/2014 Page 2 of 2 MOBILE MULTI-PHASE EXTRACTION EVENT (MMPE) SITE NAME:Red Apple Mart #21 INCIDENT NUMBER:9785 AVERAGE DEPTH TO GROUNDWATER: DESCRIBE SOIL IN THE SATURATED ZONE: INDICATE AVERAGE HYDRAULIC CONDUCTIVITY (if known, in feet/day):Not available IDENTIFY THE WELL AND THE I.D. OF EACH WELL USED FOR MMPE:MW-2R, MW-3R, MW-4R and MW-5R PROVIDE BLOWER SPECIFICATIONS OF THE VACUUM UNIT (cfm @ in Hg):280 CFM @ 24 "/Hg TOTAL NUMBER OF DATA POINTS :14 (No. of readings taken during MMPE event) DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS (Qstd) Vacuum Velocity Pipe ID Temp Rel Humid Water Qstd (inches of Hg)(ft/min)(in)(°F)(%)Vapor (%)(flow) 10/13/14 10:45 23.00 845 2 107.1 52.1 0.0271 16.70 10/13/14 12:00 23.00 1,045 2 127.1 41.1 0.0381 19.72 10/13/14 16:00 23.00 1,167 2 131.2 37.8 0.0392 21.85 10/14/14 6:45 23.00 885 2 113.2 47.0 0.0292 17.27 10/14/14 12:00 28.00 161 2 93.1 100.0 0.0345 3.24 10/14/14 16:00 28.00 204 2 104.9 100.0 0.0505 3.95 10/15/14 6:20 27.00 224 2 92.3 100.0 0.0336 4.51 10/15/14 12:00 25.00 554 2 99.0 100.0 0.0418 10.94 10/15/14 16:00 25.00 545 2 96.5 100.0 0.0385 10.85 10/16/14 6:50 25.00 511 2 95.0 100.0 0.0367 10.22 10/16/14 12:00 25.00 501 2 100.6 100.0 0.0431 9.85 10/16/14 16:00 25.00 520 2 101.0 100.0 0.0445 10.20 10/17/14 7:00 25.00 486 2 97.0 100.0 0.0391 9.66 10/17/14 10:20 25.00 514 2 100.1 100.0 0.0433 10.11 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Averages 25.00 583.00 2.00 104.15 84.14 0.0385 11.36 NOTES Qstd = Flow at DSCFM Vacuum = The level of vacuum being applied should be recorded from the vacuum truck tank (inches of Hg) Velocity = The rate at which air flows is measured at the blower discharge piping (anemometer or pitot tube) Pipe ID = The inside diameter of the blower discharge piping (from the vacuum truck) Temperature = The temperature of the air stream exiting the blower discharge piping (dry bulb temp., in deg.°F) Relative humidity = The % relative humidity of the air stream exiting the blower discharge piping Water Vapor in % = Pounds of water per pound of dry air, derived from the Psychrometric chart (temp Vs relative humidity) EQUATION Qstd = (1-Water Vapor) * velocity * (PI * (diameter/24)^2) * (528°R/(Temp + 460)) Date Time Page 1 of 2 EMISSION CALCULATIONS 15 16.70 319.9 1 319.90 1,701.17 0.000106204 0.11 0.03 90 19.72 321.9 1 321.90 1,711.81 0.000106868 0.13 0.16 330 21.85 320.0 1 320.00 1,701.70 0.000106237 0.14 0.56 1,215 17.27 280.8 1 280.80 1,493.24 0.000093223 0.10 1.42 1,530 3.24 1127.0 1 1,127.00 5,993.19 0.000374155 0.07 0.38 1,770 3.95 1210.0 1 1,210.00 6,434.57 0.000401710 0.10 0.38 2,630 4.51 1504.0 1 1,504.00 7,998.01 0.000499316 0.14 1.94 2,950 10.94 357.1 1 357.10 1,898.99 0.000118554 0.08 0.41 3,190 10.85 350.3 1 350.30 1,862.83 0.000116297 0.08 0.30 4,080 10.22 352.3 1 352.30 1,873.47 0.000116961 0.07 1.06 4,390 9.85 269.0 1 269.00 1,430.49 0.000089306 0.05 0.27 4,360 10.20 292.1 1 292.10 1,553.34 0.000096975 0.06 -0.03 5,530 9.66 404.1 1 404.10 2148.93 0.000134158 0.08 1.52 5,730 10.11 346.6 1.0 346.60 1,843.16 0.000115068 0.07 0.23 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 0.00 0.0 0.0 0.00 0.00 0.000000000 0.00 0.00 Averages 11.36 532.51 1.00 532.51 2,831.78 0.000176788 0.09 0.62 Total emissions in pounds 8.64 NOTES PPM measured = Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping K = Number of carbons in calibration gas: (Methane K = 1, or Propane K = 3, or Hexane K = 6) PPMg = PPMv, Volumetric concentration as gasoline emission, dry basis at STP Cg:m = mg/dsm3, mass concentration of gasoline emission Mg = 128 mg/mg-mole, molecular weight of gasoline (this value may vary depending on contaminant) K3 = 24.07 dsm^3/1E6 mg-mole, mass to volume conversion factor at STP Cg = lb/dcsf, mass concentration of gasoline emission, dry basis at STP PMRg = lb/hr, pollutant mass removal rate of gasoline emission PMR = pollutant mass removal of gasoline emission over time NM = Not measured due to OVA malfunction. EQUATIONS PPMg = PPM measured * K Cg:m = PPMg * (Mg / K3) Cg = Cg:m * 62.43E-09 lb-m^3/mg-ft^3 PMRg = Cg * Qstd * 60 min/hr PMR = PMRg * ((T2 - T1) / 60) K (#C-gas) Elapsed Time (min) Flow (DSCFM) PPM measured (ppm) PPMg Cg:m (mg/dsm^3) Cg (lb/dscf) PMRg (lb/hr)PMR (lb) Page 2 of 2 APPENDIX B Disposal Manifests