RA-29659_48786_CA_IAR_20230118

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

January 18, 2023

Mr. John Maloy
NCDEQ-UST Section
Raleigh Regional Office
1628 Mail Service Center
Raleigh, NC 27699-1628

Re: Initial Abatement Action Report
December 2022
New Dixie Mart #229
5095 Dortches Boulevard
Rocky Mount, Nash County
North Carolina
Facility ID Number: 0-00-0000020652
Incident Number: 48786
GRI Project Number: 5960

Dear Mr. Maloy,

Please find enclosed the referenced report for the abovementioned site.
If you have any questions, please contact William Regenthal at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. John Elam; New Dixie Oil Company, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Initial Abatement Action Report
December 2022
New Dixie Mart #229
5095 Dortches Boulevard
Rocky Mount, Nash County
North Carolina
Facility ID Number: 0-00-0000020652
Incident Number: 48786
GRI Project Number: 5960

Prepared for:

Mr. John Elam
New Dixie Oil Company
1501 Marshall Street
Rocky Mount, NC 27870

January 18, 2023

William Regenthal, P.G.
Project Manager
Ethan Rogerson, G.I.T.
Report Writer

_____________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
ii
EXECUTIVE SUMMARY
New Dixie Mart #229 is a petroleum retail facility and convenience store. The site is located at 5095
Dortches Boulevard in Rocky Mount, Nash County, North Carolina. The adjoining properties are
commercial and residential. Municipal water is available to the site. The site contained a UST system
consisting of one 12,000-gallon gasoline, two 10,000-gallon gasoline and one 10,000-gallon diesel USTs,
associated product piping and dispensers. The UST system was removed from the site on November 29,
2022. The former UST basin was located on the western side of the former store building. Please note,
the former store building was demolished and a new store and UST system were installed on the eastern
side of the site property. The new UST system was installed in November 2022 and consists of two 21,000-
gallon compartmentalized gasoline and/or diesel USTs

During tank removal activities, petroleum contamination was noted in the overburden soil, beneath the
USTs, along the sidewalls of the UST basin and beneath the product piping and dispensers. Free product
was observed in the bottom of the UST basin. Ground water not encountered in the UST basin. UST
closure soil samples were collected beneath the USTs, product piping, dispensers and from each truck
load of excavated soil. The collected soil samples were submitted for on-site analysis of TPH-GRO and
TPH-DRO using a mobile UVF laboratory. Based on the field observations and UVF field screening results,
over-excavation activities were conducted in the UST basin, beneath the gasoline and diesel dispensers
and along the product lines following the UST system removal. Mobile UVF laboratory field screening
results were used to determine the horizontal and vertical extent of the over-excavation activities in the
UST basin. A total of 749.39 tons of contaminated soil was removed during UST closure activities.

Following over-excavation activities, confirmation soil samples were collected from the sidewalls and base
of the UST basin and were submitted for laboratory analysis for VOCs using EPA Method 8260B, SVOCs by
EPA Method 8270D and VPH and EPH by the MADEP Methods. Concentrations of benzene, ethylbenzene,
xylenes, naphthalene, n-butylbenzene, isopropylbenzene, p-isopropyltoluene, n-propylbenzene, 1,2,4-
trimethylbenzene, 1,3,5-trimethylbenzene, 1-methylnaphthalene, 2-methylnaphthalene, C5-C8
aliphatics, C9-C10 aromatics, C9-C18 aliphatics and C11-C22 aromatics that exceeded the soil-to-water
MCCs were reported in the confirmation soil samples collected from (NW-10’, SW-10’, SE-10’, NE-10’ and
OE-Base-17’). Concentrations of naphthalene, C9-C10 aromatics, C9-C18 aliphatics and/or C11-C22
aromatics that exceeded the residential SCLs were reported in soil samples SE-10’ and OE-Base-17’.

Based on these results, a release has occurred at the site. A Limited Site Assessment should be conducted
to determine the risk classification of the site.

_____________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant
Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

_____________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
TABLE OF CONTENTS

SITE INFORMATION ............................................................................................................................ i
EXECUTIVE SUMMARY ....................................................................................................................... ii
ACRONYMS ....................................................................................................................................... iii
A. SITE HISTORY AND CHARACTERIZATION ...................................................................................1
B. SITE CHECK ..............................................................................................................................2
C. UST CLOSURE ..........................................................................................................................2
D. FREE PRODUCT INVESTIGATION AND RECOVERY REPORT .........................................................3
E. GROUND WATER INVESTIGATION ............................................................................................4
F. INITIAL RESPONSE AND ABATEMENT ACTION ...........................................................................4
G. EXCAVATION OF CONTAMINATED SOIL ....................................................................................4
H. SOIL AND GROUNDWATER SAMPLE RESULTS ...........................................................................5
I. SUMMARY AND CONCLUSIONS ................................................................................................5
J. LIMITATIONS ...........................................................................................................................6
FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Soil Sample Location Map
Figure 4: Soil Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Summary of Soil Sample Analytical Results

APPENDICES
Appendix A: 24-Hour Release and UST Leak Reporting Form (UST-61)
Appendix B: Notice of Intent form (UST-3)
Appendix C: Site Investigation Report for Permanent Closure or Change-in-Service of UST (UST-2A)
Appendix D: Health and Safety Plan
Appendix E: Nash County Fire Marshal’s Office Tank Removal Permit
Appendix F: UST Disposal Manifests
Appendix G: Liquid Disposal Manifests
Appendix H: Soil Disposal Manifests
Appendix I: UVF Field Screening Results
Appendix J: Laboratory Report – Soil

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
1
A. SITE HISTORY AND CHARACTERIZATION
1. UST Owner and Operator Information:
In accordance with the Initial Abatement Action Report guidelines, the UST owner and operator
information has been summarized in Table 1.
2. UST System Information:
In accordance with the Initial Abatement Action Report guidelines, the UST system information has been
summarized in Table 2. Please note, a new UST system consisting of two 21,000-gallon
compartmentalized gasoline and/or diesel USTs was installed at the site in November 2022, according to
available information. A copy of the Registered Tank Report is shown below, please note, the Registered
Tank Report does not include the newly installed USTs:

3. Non-UST Information:
No AST are located at the site.
4. Comprehensive Description of the Release:
GRI initiated UST closure activities at the site on November 28, 2022. Based on the results of the soil
samples collected during UST removal activities, a release was documented at the site. A 24-Hour Release
and UST Leak Reporting Form (UST-61) was submitted to the Raleigh Regional office of NCDEQ on
December 2, 2022 (Appendix A).
5. Description of the Site Characteristics:
The New Dixie Mart #229 site is a former convenience store located at 5095 Dortches Boulevard in Rocky
Mount, Nash County, North Carolina (Figure 1). The site is bordered to the south by Dortches Boulevard
and northeast by I-95. A site map has been included as Figure 2.

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
2
6. Summary of Initial Abatement Actions, Assessment Activities, and Corrective Actions:
Prior to closure, the appropriate officials were notified by GRI (i.e. Fire Marshal and NCDEQ). A copy of
the UST-3 Notice of Intent form is included as Appendix B. One 12,000-gallon gasoline UST, two 10,000-
gallon gasoline USTs and one 10,000-gallon diesel UST, associated dispensers and product piping were
removed from the site between November 28-30, 2022. Petroleum contamination was noted in the
overburden soil, beneath the USTs, along the sidewalls of the UST basin, beneath product piping and
beneath the dispensers. The over-excavation of the sidewalls and the base of the UST basin was
conducted due to the presence of free product, strong petroleum odors and field screening results
following the removal of the USTs. Ground water was not encountered in the UST basin.
B. SITE CHECK
A site check was not part of the initial abatement activities.
C. UST CLOSURE
1. Preparation for Closure:
Prior to closure activities, GRI personnel notified the Nash County Fire Department. The Nash County Fire
Marshal approved of the inertion methods used by GRI. A copy of the Site Investigation Report for
Permanent Closure or Change-in-Service of UST Form (UST-2A Form) is included as Appendix C. A copy
of the site-specific health and safety plan is included as Appendix D. A copy of the Nash Fire Department
Tank Removal Permit is included as Appendix E.

2. Closure Procedure:
Between November 28-30, 2022, one 12,000-gallon gasoline, two 10,000-gallon gasoline and one 10,000-
gallon diesel USTs, associated dispensers and product piping were removed from the site. The USTs were
located on the west side of the store and covered with concrete and soil. The 12,000-gallon UST measured
8 feet in diameter by 32 feet in length and the 10,000-gallon USTs measured 8 feet in diameter by 26 feet
and 8 inches in length. All of the USTs were visually inspected and appeared to be in fair condition with
minor corrosion and pitting. All of the USTs were constructed of steel. The USTs were transported off
site for proper disposal. A disposal manifest for the USTs removed in November 2022 is included as
Appendix F. Photos of the USTs are shown below:

3. Residual Material:
A total of 444 gallons of residual liquids was removed from the USTs prior to UST closure activities. Copies
of the liquid disposal manifests are included as Appendix G.

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
3
4. Release Information:
Free product was observed; however, no ground water was encountered in the UST basin. Soil samples
collected during the November 2022 UST closure confirmed a release at the site. The soil samples
collected from the UST basin (UST-1-1-12', UST-1-2-12', UST-1-3-12', UST-1-4-12', UST-2-1-12', UST-2-2-
12', UST-2-3-12', UST-2-4-12', OE-BASE 17' and SE-10’) exceeded the RALs. The release was reported to
the NCDEQ Raleigh Regional Office on December 1, 2022. The release has been assigned incident number
48786.
5. Soil Excavation Activities:
Based on the presence of free product, site observations and soil analytical results, 749.39 tons of
contaminated soil were removed from the site during the November 2022 UST closure activities. Based
on the field observations and UVF results, over-excavation activities were conducted at the base and
sidewalls of the UST basin, as well as along the product piping and beneath the diesel dispenser. The over-
excavation of the sidewalls of the UST basin was extended in all directions to include the diesel dispenser
due to strong petroleum odors and field screening results following the removal of the USTs. The
excavation boundaries are shown on Figure 2. Soil disposal manifests are included as Appendix H.
6. Site Investigation:
Soil samples (UST-1-1-12’, UST-1-2-12’. UST-1-3-12’, UST-1-4-12, UST-2-1-12’, UST-2-2-12’, UST-2-3-12’,
UST-2-4-12’, UST-3-1-12’, UST-3-2-12’. UST-3-3-12’, UST-4-1-12’, UST-4-2-12’ and UST-4-3-12’) were
collected from beneath the USTs at depths of 12 feet BGS and from beneath the dispenser islands (DI-1-
3’ through DI-7-3’) at depths of 3 feet BGS, and from beneath the product piping (PP-1-’ through PP-4-3’)
at depths of 3 feet BGS. The collected soil samples were analyzed on-site for TPH-GRO and TPH-DRO using
a mobile UVF laboratory.

Following over-excavation of the UST basin, confirmation soil samples were collected from the base and
sidewalls of the basin (OE-Base-17, NW-10’, NE-10’, SE-10’ and SW-10’) and were submitted for on-site
analysis by the mobile laboratory for TPH-GRO and TPH-DRO. Since the contaminant concentrations
reported in the over excavation soil samples exceeded the RALS, confirmation soil samples (OE-Base-17,
NW-10’, NE-10’, SE-10’ and SW-10’) were submitted for laboratory analyses of VOCs using EPA Method
8260B, SVOCs using EPA Method 8270D and MADEP Methods VPH and EPH.

Soil samples collected from beneath the UST components and soil samples collected from truck loads 1
through 47 (T-1 though T-47), represent contaminated soil removed during initial abatement activities
and were submitted for on-site analysis by the mobile laboratory for TPH-GRO and TPH-DRO. All soil
samples were collected using either a hand auger or directly from the bucket of the excavator. Soil sample
locations are shown on Figure 3. A copy of UVF field screening results is included as Appendix I.
D. FREE PRODUCT INVESTIGATION AND RECOVERY REPORT
Free product was observed during the November 2022 UST closure activities. The free product was
removed from the site during soil excavation activities.

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
4
E. GROUND WATER INVESTIGATION
Ground water was not encountered during the November 2022 UST closure activities.

F. INITIAL RESPONSE AND ABATEMENT ACTION
1. Initial Response Actions:
One 12,000-gallon gasoline UST, two 10,000-gallon gasoline USTs and one 10,000-gallon diesel UST,
associated dispensers and product piping were removed from the site between November 28-30, 2022.
Petroleum contamination was noted in the overburden soil, beneath the USTs, along the sidewalls of the
UST basin, beneath product piping and beneath the dispensers. The over-excavation of the sidewalls and
the base of the UST basin was conducted due to the presence of free product, strong petroleum odors
and field screening results following the removal of the USTs. Ground water was not encountered in the
UST basin.
 Source Control Actions: One 12,000-gallon gasoline UST, two 10,000-gallon gasoline USTs and one
10,000-gallon diesel UST, associated dispensers and product piping were removed from the site
between November 28-30, 2022.
 Contaminant Migration Control Measures: The release was to the subsurface; therefore, no
contaminant migration control measures were necessary.
 Measures Taken to Mitigate Fire/Safety Hazards: Prior to closure, the appropriate officials were
notified (i.e. Fire Marshal). Free product was encountered during closure activities.
 Measures Taken to Identify and Mitigate Pollution Hazards: The release was to the sub-surface;
therefore, no migration control measures were necessary.
2. Initial Abatement Actions:
 Contaminated Soil Storage/Treatment and/or Disposal: Between November 28-30, 2022, GRI
supervised the soil excavation activities. Contaminated soil was loaded into dump trucks and
transported to a permitted facility for disposal.
G. EXCAVATION OF CONTAMINATED SOIL
1. Extent of Soil Contamination:
Over-excavation activities were conducted at the base and sidewalls of the UST basin. The over-
excavation of the sidewalls of the UST basin was due to strong odors and field screening results
following the removal of the USTs. A total of 749.39 tons of contaminated soil was transported offsite
to a permitted disposal facility during the November 2022 UST closure activities.

2. Excavation Process:
The excavation activities were conducted using a track-mounted excavator.

3. Sampling Description:
All soil samples were collected directly from the bucket of the excavator or using a hand auger by GRI
personnel. Samples were collected with clean, disposable nitrile gloves and immediately transferred

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
5
to the onsite mobile UVF laboratory for analysis or immediately placed in laboratory-supplied
glassware and placed on ice.

H. SOIL AND GROUNDWATER SAMPLE RESULTS
 Soil:
Concentrations of TPH-GRO and/or TPH-DRO that exceeded the RALs were reported from the following
soil samples; from the UST basin (UST-1-1-12', UST-1-2-12', UST-1-3-12', UST-1-4-12', UST-2-1-12', UST-2-
2-12', UST-2-3-12', UST-2-4-12', OE-BASE 17' and SE-10’) and from truck samples (T-1 through T-47).

Concentrations of benzene, ethylbenzene, xylenes, naphthalene, n-butylbenzene, isopropylbenzene, p-
isopropyltoluene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-
methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C10 aromatics, C9-C18 aliphatics and
C11-C22 aromatics that exceeded the soil-to-water MCCs were reported in the confirmation soil samples
collected from (NW-10’, SW-10’, SE-10’, NE-10’ and OE-Base-17’). Concentrations of naphthalene, C9-C10
aromatics, C9-C18 aliphatics and/or C11-C22 aromatics that exceeded the residential SCLs were reported
in soil samples SE-10’ and OE-Base-17’. A summary of soil sample analytical results is presented as Table
3. A Soil Quality Map has been included as Figure 4. A copy of the laboratory report for confirmation soil
samples collected during the November 2022 UST closure activities is included as Appendix J.

 Ground Water:
Ground water was not encountered during the November 2022 UST closure activities.
I. SUMMARY AND CONCLUSIONS
 One 12,000-gallon gasoline UST, two 10,000-gallon gasoline USTs and one 10,000-gallon diesel
associated dispensers and product piping were removed from the site between November 28-30,
2022.
 Free product was noted in the UST basin during closure activities.
 Petroleum contamination was noted in the overburden soil, along the excavation basin sidewalls, and
base of UST basin, along the product piping and beneath the dispenser islands.
 Based on the presence of free product, field observations and UVF results, over-excavation activities
were conducted.
 A total of 749.39 tons of contaminated soil was removed during the November 2022 UST closure
activities.

 Ground water was not encountered during the November 2022 UST closure activities.
 Concentrations of benzene, ethylbenzene, xylenes, naphthalene, n-butylbenzene, isopropylbenzene,
p-isopropyltoluene, n-propylbenzene, 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, 1-
methylnaphthalene, 2-methylnaphthalene, C5-C8 aliphatics, C9-C10 aromatics, C9-C18 aliphatics and
C11-C22 aromatics that exceeded the soil-to-water MCCs were reported in the confirmation soil
samples collected from (NW-10’, SW-10’, SE-10’, NE-10’ and OE-Base-17’).

____________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Initial Abatement Action Report
Prepared on: January 18, 2023 New Dixie Mart #229
Project Manager: William Regenthal, GRI Project No. 5960
6
 Concentrations of naphthalene, C9-C10 aromatics, C9-C18 aliphatics and/or C11-C22 aromatics that
exceeded the residential SCLs were reported in soil samples SE-10’ and OE-Base-17’.
 Based on these results, a release has occurred at the site. A Limited Site Assessment should be
conducted to determine the site risk classification of the incident.
J. LIMITATIONS
This report has been prepared for the exclusive use of New Dixie Oil Corporation for specific application
to the referenced site in Nash County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site LocationNew Dixie Mart 2295095 Dortches BlvdRocky Mount, North CarolinaNash CountyIncident No. 48786GRI Project No. 5960500 M2000 FTDate: 12/04/2022 Location: 36.012822° N -77.860330° W Dad

TABLES
UST ID Number A1A, A1B, A2A, A2B Facility ID Number
Owner or Operator?
Owner
UST ID Number 1 - 4 Facility ID Number
Owner or Operator?
Owner
UST ID Number 1 - 4 Facility ID Number
Owner or Operator?
Owner
UST ID Number 1 - 4 Facility ID Number
Owner or Operator?
Owner
Unknown
Telephone Number
Unknown
Address
M & S Oil Company, Inc.
00-0-0000020652
Dates of Ownership / OperationName of Owner or Operator
04/30/1978 - 09/01/1998
Address Telephone Number
Unknown Unknown
00-0-0000020652
Name of Owner or Operator
Address Telephone Number
1501 Marshall Street, Roanoke Rapids, NC 27870 252-537-4118
00-0-0000020652
Name of Owner or Operator Dates of Ownership / Operation
11/15/2022 - Current
TABLE 1
UST OWNER/OPERATOR INFORMATION
NEW DIXIE MART #229 (INCIDENT NO. 48786)
New Dixie Oil Corporation
Griffins Food Stores, Inc.09/01/1998 - 10/22/2012
00-0-0000020652
Name of Owner or Operator Dates of Ownership / Operation
New Dixie Oil Corporation 10/22/2012 - 11/29/2022
Address Telephone Number
1501 Marshall Street, Roanoke Rapids, NC 27870 252-537-4118
Dates of Ownership / Operation
Page 1 of 1
Date: 12/02/2022
Was Release
Associated
with UST
System?
(Yes / No)
1 Gasoline 10,000 04/30/1978 Single Wall
Steel/FRP 8' x 26' 8"Flex and Steel Removed
11/29/22 Yes
2 Diesel 10,000 04/30/1978 Single Wall
Steel/FRP 8' x 26' 8"Flex and Steel Removed
11/29/22 Yes
3 Gasoline 10,000 04/30/1978 Single Wall
Steel/FRP 8' x 26' 8"Flex and Steel Removed
11/29/22 Yes
4 Gasoline 12,000 04/30/1978 Single Wall
Steel/FRP 8' x 32'Flex and Steel Removed
11/29/22 Yes
A1A Gasoline 15,000 DW Flex Current No
A1B Gasoline 6,000 DW Flex Current No
A2A Diesel 15,000 DW Flex Current No
A2B Gasoline 6,000 DW Flex Current No10' x 37' 8 3/4 "
10' x 37' 8 3/4 "
DW Fiberglass
DW Fiberglass
11/15/2022
11/15/2022
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
TABLE 2
UST SYSTEM INFORMATION
NEW DIXIE MART #229 (INCIDENT NO. 48786)
Facility ID #: 00-0-0000020652
UST
ID
No.
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Date: 12/13/2022
Sample ID Date Collected
(mm/dd/yy)
Sample
Location
Sample
Depth
(ft-BGS)
NA NA 0.0072 5.4 8 6 0.085 0.2 2.4 1.3 0.12 1.4 6.6 6.6 0.054 1.5 68 540 31 540 NE 31
NA NA 12 1,250 60.3 3,120 156 5.5 782 1,560 1,560 1,560 156 156 22.8 62.5 625 1,560 469 1,560 31,200 469
50 100 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
PB-2 11/29/22 -239 396 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-1-1-12'11/29/22 12 216 264 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-1-2-12'11/29/22 12 720 176 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-1-3-12'11/29/22 12 280.4 134.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-1-4-12'11/29/22 12 130 220 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-2-1-12'11/29/22 12 50.8 13.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-2-2-12'11/29/22 12 1,814 254 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-2-3-12'11/29/22 12 56.4 41.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-2-4-12'11/29/22 12 71.2 51.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-3-1-12'11/29/22 12 21.6 20.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-3-2-12'11/29/22 12 26 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-3-3-12'11/29/22 12 36.8 2.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-4-1-12'11/29/22 12 21.6 5.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-4-2-12'11/29/22 12 22.8 7.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
UST-4-3-12'11/29/22 12 22 11.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-1-3'11/30/22 3 20.8 21.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-2-3'11/30/22 3 18.8 6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-3-3'11/30/22 3 11.6 1.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-4-3'11/30/22 3 11.2 2.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-5-3'11/30/22 3 11.2 3.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-6-3'11/30/22 3 16.4 0.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
DI-7-3'11/30/22 3 15.2 3.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
PP-1-3'11/30/22 3 14.4 2.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
PP-2-3'11/30/22 3 12 1.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
PP-3-3'11/30/22 3 13.2 6.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
PP-4-3'11/30/22 3 25.6 12.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
OE-BASE 17"11/30/22 17 840 85 <0.173 4.74 27.3 143 <0.185 12.9 2.07 3.45 0.540 J 10.9 65.9 20.3 1.79 4.12 245 <54.7 1,450 66.2 <14.6 82.5 J
NE-10'11/30/22 10 11.6 0.8 0.033 0.020 0.063 0.206 <0.0007 0.005 J 0.001 J 0.005 J <0.001 0.014 0.046 0.010 <0.119 <0.112 <1.37 <5.13 5.57 J <10.3 <13.7 26.2 J
NW-10'11/30/22 10 10.4 1.2 0.012 0.020 0.086 0.217 <0.0008 0.033 0.003 J 0.007 <0.001 0.023 0.080 0.013 <0.129 0.139 J <1.49 <5.56 4.74 J <11.2 <14.9 21.7 J
SE-10'11/30/22 10 2,176 2,144 <0.159 0.329 J 18.9 17.0 <0.170 31.1 4.68 4.55 1.67 15.3 56.3 3.86 11.2 24.2 387 J <251 5,940 1,740 415 1,590 J
SW-10'11/30/22 10 13.2 3.2 0.0009 J 0.037 0.140 0.487 <0.0007 0.023 0.005 J 0.014 0.001 J 0.038 0.164 0.037 <0.118 <0.111 <1.36 <5.10 9.34 <10.3 <13.6 <15.9
MADEP Methods VPH and EPH
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
NEW DIXIE MART #229 (INCIDENT NO. 48786)
Facility ID #: 00-0-0000020652
SW-8260DAnalytical Method 1-Methylnaphthalene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneC11-C22 AromaticsC19-C36 AliphaticsC9-C18 AliphaticsC9-C10 AromaticsC9-C12 AliphaticsC5-C8 Aliphatics2-Methylnaphthalenen-Propylbenzene4-Isopropyltoluene(p-isopropyltoluene)Isopropylbenzenen-ButylbenzeneNaphthaleneMethyl-tert-butyl-ether (MTBE)Total XylenesOverexcavation
Area Gasoline-Range TPHEthylbenzeneTolueneBenzeneSoil to Water MSCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)Diesel-Range TPHUVF
UST Basin
Dispenser Islands
Product Piping
RAL (mg/kg)
Contaminant of Concern 
Page 1 of 3
Date: 12/13/2022
Sample ID Date Collected
(mm/dd/yy)
Sample
Location
Sample
Depth
(ft-BGS)
NA NA 0.0072 5.4 8 6 0.085 0.2 2.4 1.3 0.12 1.4 6.6 6.6 0.054 1.5 68 540 31 540 NE 31
NA NA 12 1,250 60.3 3,120 156 5.5 782 1,560 1,560 1,560 156 156 22.8 62.5 625 1,560 469 1,560 31,200 469
50 100 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
MADEP Methods VPH and EPH
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
NEW DIXIE MART #229 (INCIDENT NO. 48786)
Facility ID #: 00-0-0000020652
SW-8260DAnalytical Method 1-Methylnaphthalene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneC11-C22 AromaticsC19-C36 AliphaticsC9-C18 AliphaticsC9-C10 AromaticsC9-C12 AliphaticsC5-C8 Aliphatics2-Methylnaphthalenen-Propylbenzene4-Isopropyltoluene(p-isopropyltoluene)Isopropylbenzenen-ButylbenzeneNaphthaleneMethyl-tert-butyl-ether (MTBE)Total XylenesGasoline-Range TPHEthylbenzeneTolueneBenzeneSoil to Water MSCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)Diesel-Range TPHUVF
RAL (mg/kg)
Contaminant of Concern 
T-1 11/29/22 -663 3,360 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-2 11/29/22 -57.6 31.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-3 11/29/22 -247.2 1,304 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-4 11/29/22 -62 51.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-5 11/29/22 -93.6 114.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-6 11/29/22 -788 467 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-7 11/29/22 -50.4 99.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-8 11/29/22 -64.8 117.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-9 11/29/22 -64 50.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-10 11/29/22 -73.6 74.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-11 11/29/22 -77.2 54.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-12 11/29/22 -76 114.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-13 11/29/22 -80 79.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-14 11/29/22 -61.6 27.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-15 11/29/22 -55.6 87.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-16 11/29/22 -77.2 46 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-17 11/29/22 -109.6 76.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-18 11/29/22 -144.4 102 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-19 11/29/22 -236.4 158.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-20 11/29/22 -350 304 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-21 11/29/22 -210 160.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-22 11/29/22 -864 256 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-23 11/29/22 -148.4 105.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-24 11/29/22 -74.4 72.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-25 11/29/22 -115.2 129.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-26 11/29/22 -93.2 178.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-27 11/30/22 -67.2 60.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-28 11/30/22 -90 48.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-29 11/30/22 -60 68.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-30 11/30/22 -79.6 62 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
Truck Samples
Page 2 of 3
Date: 12/13/2022
Sample ID Date Collected
(mm/dd/yy)
Sample
Location
Sample
Depth
(ft-BGS)
NA NA 0.0072 5.4 8 6 0.085 0.2 2.4 1.3 0.12 1.4 6.6 6.6 0.054 1.5 68 540 31 540 NE 31
NA NA 12 1,250 60.3 3,120 156 5.5 782 1,560 1,560 1,560 156 156 22.8 62.5 625 1,560 469 1,560 31,200 469
50 100 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA
MADEP Methods VPH and EPH
TABLE 3
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
NEW DIXIE MART #229 (INCIDENT NO. 48786)
Facility ID #: 00-0-0000020652
SW-8260DAnalytical Method 1-Methylnaphthalene1,3,5-Trimethylbenzene1,2,4-TrimethylbenzeneC11-C22 AromaticsC19-C36 AliphaticsC9-C18 AliphaticsC9-C10 AromaticsC9-C12 AliphaticsC5-C8 Aliphatics2-Methylnaphthalenen-Propylbenzene4-Isopropyltoluene(p-isopropyltoluene)Isopropylbenzenen-ButylbenzeneNaphthaleneMethyl-tert-butyl-ether (MTBE)Total XylenesGasoline-Range TPHEthylbenzeneTolueneBenzeneSoil to Water MSCC (mg/kg)
Residential Soil Cleanup Levels (mg/kg)Diesel-Range TPHUVF
RAL (mg/kg)
Contaminant of Concern 
T-31 11/30/22 -76.4 53.6 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-32 11/30/22 -68.4 66 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-33 11/30/22 -204.4 84 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-34 11/30/22 -516 91 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-35 11/30/22 -169.2 72.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-36 11/30/22 -50 35.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-37 11/30/22 -395.2 112.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-38 11/30/22 -66 54.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-39 11/30/22 -50.4 32.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-40 11/30/22 -106 64.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-41 11/30/22 -68 5.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-42 11/30/22 -51.6 98.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-43 11/30/22 -71.2 20.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-44 11/30/22 -52.8 2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-45 11/30/22 -56.8 53.2 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-46 11/30/22 -63.2 36.8 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
T-47 11/30/22 -54.4 0.4 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS
Truck Samples
• Concentrations in bold face type indicate the RALs were less than the reported
concentrations
Notes:
• Results reported in mg/kg; samples analyzed onsite by UVF.
• ft-BGS: feet below ground surface.
• RAL: Regulatory Action Level.
• < : Less than the UFV method detection limit .
Page 3 of 3

APPENDICES

APPENDIX A
24-Hour Release and UST Leak Reporting Form (UST-61)
New Dixie Mart 229
5095 Dortches Boulevard
Rocky Mount 27801
Nash
36.013119 -77.860288
00-0-000020652N
X
X
X
X
X
N
X
A release was discovered upon receipt of mobile laboratory analyses of soil samples collected during UST closure
X
12/01/2022Comm
RegY
Y
Y
Unknown
Former petroleum retailfacility
activities.
- Google Maps
Geological Resources, Inc.
3502 Hayes Rd., Monroe NC 28110
704-845-4010William Regenthal, P.G.
Project Manager 12/01/2022
New Dixie Oil Corporation
T Scott Aman 1501 Marshall Street
Roanoke Rapids NC 27870-4415 252-537-4118
NC
NA
New Dixie Oil Corporation 1501 Marshall Street
Roanoke Rapids 27870-4415 252-537-4118
See attached map
Roanoke Rapids
New Dixie Oil Corporation 1501 Marshall Street
27870-4415 252-537-4118NC

APPENDIX B
Notice of Intent form (UST-3)

APPENDIX C
Site Investigation Report for Permanent Closure or Change-in-Service of UST (UST-2A)
UST-2A Site Investigation Report for Permanent Closure or Change-in-
Service of
REGISTERED UST

Return completed form to:
NC DEQ / DWM / UST SECTION
1646 MAIL SERVICE CENTER
RALEIGH, NC 27699-1646
ATTN: REGISTRATION & PERMITTING

phone [phone] fax [phone] http://www.wastenotnc.org/

STATE USE ONLY:
Facility ID #

Date Received

INSTRUCTIONS (READ THIS FIRST)
1. UST permanent closure or change in service must be completed in accordance with the latest version of the Guidelines for Site Checks, Tank
Closure and Initial Response and Abatement. The guidelines can be obtained at http://deq.nc.gov/about/divisions/waste-management/waste-
management-permit-guidance/underground-storage-tanks-section.
2. Permanent closure: Complete all sections of this form.
3. Change-in-service: Where a UST system will be converted from storing a regulated substance to a non-regulated substance, complete sections I, II,
III, IV, and VI
4. For more than 5 registered UST systems, attach additional forms as needed
5. Tank Fee Refund: An annual tank fee may be refunded for a tank for which a tank fee was not required. An owner or operator must submit
a written request and include: (1) contact information, (2) federal identification # or SSN, and (3) a copy of UST-2 form. The annual tank
fee will be prorated based on the date of permanent closure.
6. UNREGISTERED USTs use Form UST-2B
I. OWNERSHIP OF TANKS II. LOCATION OF TANKS
Owner Name (Corporation, Individual, Public Agency, or Other Entity)

Facility Name or Company

Street Address

Facility ID # (If known)

City

County

Street Address

State

Zip Code

City

County

Zip Code

Phone Number

Phone Number

III. CONTACT PERSONNEL
Contact for Facility:

Job Title:

Phone #:

Closure Contractor Name:

Closure Contractor Company:

Address:

Phone #

Primary Consultant Name:

Primary Consultant Company:

Address:

Phone #

IV. UST INFORMATION FOR REGISTERED UST SYSTEMS
UNREGISTERED USTs use Form UST-2B
V. EXCAVATION CONDITION
Tank ID
No.
Size in
Gallons
Last
Contents
Last
Use
Date
Permanent
Close Date
Method of Permanent Closure:
Indicate REMOVED or enter fill
material, such as foam/
concrete/ sand
Change-in-
Service
Date
Water in
excavation Free product
Notable
odor or
visible soil
contaminatio
n
Yes No Yes No Yes No

VI. CERTIFICATION
I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents and that
based on my inquiry of those individuals immediately responsible for obtaining the information, I believe that the submitted information is true accurate
and complete.
Print name and official title of owner or owner’s authorized representative

Signature Date Signed

NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY, DIVISION OF WASTE MANAGEMENT, UST SECTION
1646 MAIL SERVICE CENTER, RALEIGH, NC 27699-1646 PHONE [phone] FAX [phone] http://www.wastenotnc.org/ 1/2016

APPENDIX D
Health and Safety Plan

1
GEOLOGICAL RESOURCES, INC.
Site Specific Health and Safety Plan

1.0 General Information:
a. Project name: New Dixie Mart #229
b. Location: 5095 Dortches Blvd, Rocky Mount, Nash County
c. GRI Job #: 5960

2.0 Project Organization:
a. Site Supervisor/H&S Officer: Justin Radford
b. Project Manager: William Regenthal
c. Subcontractor(s):

3.0 Safety Plan Preparation:
a. Prepared by & date: William Regenthal 11/18/2022
b. Reviewed/approved by & date: Justin Radford 11/18/2022

4.0 Site History and Description:
a. Type of site (i.e., spill, leaking UST system, etc.): Petroleum retail facility
b. Site/project description: UST Closure

5.0 Potential Hazards:
Physical Hazards: (check)
X Slips X Overhead X Explosion X Sun burn X Electricity
X Trips utilities X Noise Cold Weather Pressurized line/vessels
X Falls X Underground X Pinch points Hot Weather
X Fire utilities X Burns X Crush

Chemical Hazards: (check)
X Gasoline Used Oil
X Diesel Solvents
Kerosene Antifreeze
New Oil Acid (sample preservative)

Equipment/Vehicular/Other: (i.e., Geoprobe, drill rig, back hoe, track hoe, traffic, skid steer etc.)

Excavator, Bobcat

Biological Hazards: (i.e., toxic insects, spiders, poisonous plants, poisonous snakes, aggressive dogs)

2
6.0 Site Organization and Safety Control: (Evaluate the need for site control to protect
persons from exposure to hazardous conditions; i.e. work permits, cones, barricade tape,
exclusion zones, etc.)
a. Work area(s) identified: ____________________________________________________
b. Work area marked _____ Yes_____ No
c. Work area barricaded _____ Yes _____ No
d. Support area established: __________________________________________________
e. Entry and escape routes identified: ___________________________________________
f. Rally point identified: _____ Yes ____ No Location:________________
g. Emergency shut-off for water identified _____ Yes _____ No
h. Emergency fuel shut-off identified _____ Yes _____ No
i. Site map attached: __X__ Yes _____ No
**Emergency Response Procedures**
Action (i.e. shut off all power equipment) Assemble at rally point
Call 911 for medical or utilities emergency Do NOT enter confined spaces
Discuss what to do if …..cut product line, water line, cable/electric line

7.0 Job Activities in Work Plan:
X UST Removal X Soil Sampling Manual FP Recovery
Soil Excavation System O&M _ Other (specify)
Powered Drilling MMPE/AFVR ___ AST Removal
Hand Augering Water sampling __________________

8.0 Required Education and/or Training:
X OSHA 40 hr X Annual 8 hr Refresher OSHA Site Supervisor

9.0 Air Monitoring:
If, in the opinion of the site supervisor, petroleum hydrocarbon vapor concentrations are
excessive, site activities will cease until petroleum hydrocarbon vapor concentrations diminish to
acceptable levels.

10.0 Equipment:
X FID/PID X Combustible gas indicator Interface
Probe
X O2 meter Other

11.0 Personnel Protection Equipment:
X Hard hat Rubber boots Respirator X Hearing
X Safety glasses X Work gloves X Sun screen protection
X Steel toe boots X First aid kit Repellent X Nitrile
Tyvek suit S Fire extinguisher Dust mask gloves

12.0 Decontamination Procedures: (evaluate need for decon, describe procedures)

3
13.0 Emergency Contacts:
a. Local Assistance:
Site Phone NA Fire Department 911
Police 911 Ambulance 911
Water Department Sanitary Sewer
Natural Gas Power Company

Nearest Urgent Care (directions attached)
Name Nash General Hospital
Address 2460 Curtis Ellis Rd, Rocky Mount, NC

Number [phone]

b. National or Regional Sources of Assistance:
1) Geological Resources, Inc. [phone]
2) Chemtrec (24 Hours) [phone]
3) Bureau of Explosives (24 Hours) [phone]
4) National Response Center, NRC [phone]
(Oil/Hazardous Substances)
5) DOT, Off. Of Haz. Operations [phone]

14.0 Signatures:

This plan has been reviewed by all on-site personnel and all provisions are clear (signatures
required).

Project Manager:
Site Supervisor:
Other personnel:

4
15.0 Amendments:

a. Site Specific Health and Safety Plans are based on information available at the time of
plan preparation. Unexpected conditions may arise. It is important that personal
protective measures be thoroughly assessed prior to and during the planned activities.
Unplanned activities and/or changes in the hazard status should initiate a review of this
plan and may result in major changes to it.
b. Changes in the hazard status or unplanned activities are to be submitted on “Amendment
to the Site Specific Health and Safety Plan” which is included bellow.
c. Amendment must be approved by the Project Manager prior to implementation of the
amendment.

AMENDMENT TO THE SITE SPECIFIC HEALTH AND SAFETY PLAN

A. Changes in field activities or hazards:

B. Proposed amendment:

C. Approval:

Proposed by: ___________________________________date ______________________

Approved by: ___________________________________date _____________________

Amendment number: ____________________________

Amendment effective date: _______________________

APPENDIX E
Nash County Fire Marshal’s Office Tank Removal Permit

Nash County Fire Marshal's Office
ER Permit Number 546258 Permit Date 11/17/2022 12:00:00 AM
Permit Type Tank Removal Effective Date 11/17/2022 11:06:00 AM
Created By Jenkins, Chris Expiration Date 12/17/2022 11:06:00 AM
Authorized Date 11/17/2022 8:33:23 AM Authorized By Jenkins, Chris
Site Information Billing Information
NEW DIXIE MART
5095 DORTCHES BLVD
ROCKY MOUNT, NC 27804

Point of Contact
William Regenthal 704-698-1253
Permit Notes:
Permit Topics:
Permit Form:
Form: General
Description: General Information
Page 1 of 3Printed on 11/17/22 at 08:33:32
General Inforamtion
Information
Status: Passed
Information
Notes: Permit issued to remove (4) underground storage tanks at 5095 Dortches Blvd. Work is in connection with
demolishing the old convenient store for future development.
(3) 10,000 gal gasoline
(1) 10,000 gal diesel
NC Division of Waste Management has been notified and application submitted.
General Information
Information
Status: Passed
Information
Notes: Removal and disposal of the tanks and piping shall be in accordance with NC Fire Code section 5704.2.14
Closing Notes:
Page 2 of 3Printed on 11/17/22 at 08:33:32
Issued By:
Name: Jenkins, Chris
Rank: Fire Inspector
Work Phone(s): 252-459-1205
Email(s): [e-mail], cjenkinsnash
Signature Date
Signature of: Jenkins, Chris on 11/17/2022 11:33
Page 3 of 3Printed on 11/17/22 at 08:33:32

APPENDIX F
UST Disposal Manifests

APPENDIX G
Liquid Disposal Manifests

APPENDIX H
Soil Disposal Manifests
Date Sample Truck Gross Tare Gross Weigh Net Tons Manifest
11/28/2022 T-1 CC-10 27420 62200 34780 17.39 CS-1
11/28/2022 T-2 CC-07 30060 59980 29920 14.96 CS-2
11/28/2022 T-3 CC-03 31960 67400 35440 17.72 CS-3
11/28/2022 T-4 CC-07 30060 59280 29220 14.61 CS-4
11/28/2022 T-5 CC-10 27420 60460 33040 16.52 CS-5
11/29/2022 T-6 CC-08 39400 64320 24920 12.46 CS-6
11/29/2022 T-7 CC-07 30060 61520 31460 15.73 CS-7
11/29/2022 T-8 CC-10 27420 67260 39840 19.92 CS-8
11/29/2022 T-9 CC-07 30060 55220 25160 12.58 CS-9
11/29/2022 T-10 CC-10 27420 66100 38680 19.34 CS-10
11/29/2022 T-11 CC-08 39400 60260 20860 10.43 CS-11
11/29/2022 T-12 CC-09 38260 60560 22300 11.15 CS-12
11/29/2022 T-13 CC-03 31960 67040 35080 17.54 CS-13
11/29/2022 T-14 CC-10 27420 66100 38680 19.34 CS-14
11/29/2022 T-15 CC-07 30060 56580 26520 13.26 CS-15
11/29/2022 T-16 CC-08 39400 60120 20720 10.36 CS-16
11/29/2022 T-17 CC-09 38260 64980 26720 13.36 CS-17
11/29/2022 T-18 CC-03 31960 64480 32520 16.26 CS-18
11/29/2022 T-19 CC-07 30060 64400 34340 17.17 CS-19
11/29/2022 T-20 CC-10 27420 59660 32240 16.12 CS-20
11/29/2022 T-21 CC-08 39400 62500 23100 11.55 CS-21
11/29/2022 T-22 CC-03 31960 72440 40480 20.24 CS-22
11/29/2022 T-23 CC-09 38260 61320 23060 11.53 CS-23
11/29/2022 T-24 CC-10 27420 62020 34600 17.30 CS-24
11/29/2022 T-25 CC-08 39400 70720 31320 15.66 CS-25
11/29/2022 T-26 CC-09 38260 65820 27560 13.78 CS-26
11/30/2022 T-27 CC-10 27420 61800 34380 17.19 CS-27
11/30/2022 T-28 CC-07 30060 65680 35620 17.81 CS-28
11/30/2022 T-29 JA-9 31920 78660 46740 23.37 CS-29
11/30/2022 T-30 CC-09 38260 63080 24820 12.41 CS-30
11/30/2022 T-31 TTB-2 26200 53840 27640 13.82 CS-31
11/30/2022 T-32 CC-03 31960 68580 36620 18.31 CS-32
11/30/2022 T-33 CC-10 27420 69800 42380 21.19 CS-33
11/30/2022 T-34 JA-9 31920 79200 47280 23.64 CS-34
11/30/2022 T-35 CC-09 38260 71260 33000 16.50 CS-35
11/30/2022 T-36 CC-07 30060 65840 35780 17.89 CS-36
11/30/2022 T-37 TTB-2 26200 63200 37000 18.50 CS-37
11/30/2022 T-38 CC-03 31960 75660 43700 21.85 CS-38
11/30/2022 T-39 CC-10 27420 66540 39120 19.56 CS-39
11/30/2022 T-40 JA-9 31920 65500 33580 16.79 CS-40
11/30/2022 T-41 CC-09 38260 56460 18200 9.10 CS-41
11/30/2022 T-42 TTB-2 26200 49320 23120 11.56 CS-42
NEW DIXIE MART #229
CONTAMINATED SOIL DISPOSAL SUMMARY
Page 1 of 2
Date Sample Truck Gross Tare Gross Weigh Net Tons Manifest
NEW DIXIE MART #229
CONTAMINATED SOIL DISPOSAL SUMMARY
11/30/2022 T-43 CC-07 30060 57480 27420 13.71 CS-43
11/30/2022 T-44 CC-03 31960 65680 33720 16.86 CS-44
11/30/2022 T-45 CC-10 27420 57560 30140 15.07 CS-45
11/30/2022 T-46 JA-9 31920 75120 43200 21.60 CS-46
11/30/2022 T-47 CC-09 38260 51020 12760 6.38 CS-47
749.39
Page 2 of 2

APPENDIX I
UVF Field Screening Results

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
UVF Trilogy Analytical Report

Samples Collected: November 28-30, 2022
Samples Analyzed: November 28-30, 2022
Site Name: New Dixie Mart #229
Site Address: 5095 Dortches Boulevard, Rocky Mount, NC
GRI Project Number: 5960

December 1, 2022

AJ Discepolo, GIT
Operator

Technical Procedures
Calibration
The UFV Trilogy has standard calibrations stored for the following analysis:
 GRO
 DRO
 Total PAH
 Target PAH
 Heavy PAH
Prior to use, calibration standards are used to perform a 5-point verification on the factory stored
calibrations for GRO and DRO. The calibration standards used are as follows:
GRO
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
 10 ppm
DRO
 0.1 ppm
 0.5 ppm
 1 ppm
 3 ppm
 5 ppm
Operation
Sample Extraction
 5mg of soil are weighed into a clean extraction jar
 Methanol is added to the extraction jar to create a 2x or 4x dilution
o 2x Dilution: 10 mL of methanol
o 4x Dilution: 20 mL of methanol
 The extraction jar is shaken for several minutes to thoroughly mix the soil with solvent
(methanol)
 The mixture is allowed to settle for several minutes
 A clean syringe is used to draw liquid from the extraction jar
 A clean filter is attached to the end of the syringe and the liquid dispensed through the filter
into a clean test tube
 This liquid is referred to as the extraction
Dilution Preparation
 An adjustable micropipette is used to precisely measure out the amount of extract needed for
the dilution
 The measured out amount of the extract is added to a clean test tube and methanol is added
dilute the extract. Examples of dilutions are shown below:

Extract Amount
500 μL
200 μL
100 μL
50 μL
25 μL

Add Solvent to the
5 mL line
5 mL line
5 mL line
5 mL line
5 mL line
2x Extract
Dilution Factor
20x
50x
100x
200x
400x
4x Extract
Dilution Factor
40x
100x
200x
400x
800x

Technical Procedures
Sample Analyzation
 The dilution is shaken to thoroughly mix, then poured into a clean glass cuvette
 The desired module is inserted into the UVF Trilogy and the corresponding factory calibration is
selected
 “Measure Fluorescence” is pressed on the touchscreen and the reading is recorded
 The reading should be between the concentrations of the calibration standards (GRO: 0.5-10
ppm; DRO 0.1-5 ppm)
o Reading below the calibration standard range are recorded as below the detection limit
 Detection Limit = (lower range of calibration standards range) x dilution factor
(i.e. a GRO sample with a 100x dilution factor has a detection limit of 50 ppm)
o Readings above the calibration standard range should be further diluted and reanalyzed
o Negative readings are an indication of quenching (see below)
 The reading is multiplied by the dilution factor to calculate the final concentration
 Check suspected contaminated samples for quenching by running additional dilutions
o According to the siteLAB Quick Reference Guide:
“Quenching” can occur when the detector is swamped by too many hydrocarbons or
organic interferences, producing low or negative concentrations. Test the sample at
multiple dilutions to confirm results are linear and accurate.”
QA/QC
Method Blank
 A method blank of methanol will be analyzed following calibration and following the last sample
analyzed each day
Duplicates
 One duplicate will be analyzed for every 20 samples
 The duplicate will be prepared from the extract of the sample and diluted to the same factor as
the sample analyzed
Project Name:Date Collected:
Project Number:Date Analysed:
Project Manager:Operator:
Sample ID Matrix
Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
PB-2 Soil 100 2.39 239 100 3.96 396
UST-1-1-12'Soil 100 2.16 216 100 2.64 264
UST-1-2-12'Soil 100 7.2 720 100 1.76 176
UST-1-3-12'Soil 40 7.01 280.4 40 3.36 134.4
UST-1-4-12'Soil 100 1.3 130 100 2.2 220
T-1 Soil 100 6.63 663 800 4.2 3360
T-2 Soil 40 1.44 57.6 40 0.79 31.6
T-3 Soil 40 6.18 247.2 400 3.26 1304
T-4 Soil 40 1.55 62 40 1.29 51.6
T-5 Soil 40 2.34 93.6 40 2.86 114.4
T-6 Soil 100 7.88 788 100 4.67 467
UST-2-1-12'Soil 40 1.27 50.8 40 0.33 13.2
UST-2-2-12'Soil 200 9.07 1814 200 1.27 254
UST-2-3-12'Soil 40 1.41 56.4 40 1.03 41.2
UST-2-4-12'Soil 40 1.78 71.2 40 1.29 51.6
T-7 Soil 40 1.26 50.4 40 2.49 99.6
T-8 Soil 40 1.62 64.8 40 2.94 117.6
T-9 Soil 40 1.6 64 40 1.27 50.8
T-10 Soil 40 1.84 73.6 40 1.87 74.8
T-11 Soil 40 1.93 77.2 40 1.36 54.4
T-12 Soil 40 1.9 76 40 2.86 114.4
T-13 Soil 40 2 80 40 1.98 79.2
T-14 Soil 40 1.54 61.6 40 0.69 27.6
T-15 Soil 40 1.39 55.6 40 2.19 87.6
T-16 Soil 40 1.93 77.2 40 1.15 46
T-17 Soil 40 2.74 109.6 40 1.91 76.4
T-18 Soil 40 3.61 144.4 40 2.55 102
T-19 Soil 40 5.91 236.4 40 3.96 158.4
T-20 Soil 100 3.5 350 100 3.04 304
T-21 Soil 40 5.25 210 40 4.01 160.4
T-22 Soil 100 8.64 864 100 2.56 256
T-23 Soil 40 3.71 148.4 40 2.63 105.2
T-24 Soil 40 1.86 74.4 40 1.81 72.4
UVF Analytical Report
siteLAB UVF Trilogy
10/29-30/2022
10/29-30/2022
AJ Discepolo
New Dixie Mart #229
2925
William Regenthal
Site:
New Dixie Mart #229
Report Date:
12/1/2022
Page:
1 of 3
Project Name:Date Collected:
Project Number:Date Analysed:
Project Manager:Operator:
Sample ID Matrix
Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
UVF Analytical Report
siteLAB UVF Trilogy
10/29-30/2022
10/29-30/2022
AJ Discepolo
New Dixie Mart #229
2925
William Regenthal
T-25 Soil 40 2.88 115.2 40 3.24 129.6
T-26 Soil 40 2.33 93.2 40 4.47 178.8
UST-3-1-12'Soil 40 0.54 21.6 40 0.52 20.8
UST-3-2-12'Soil 40 0.65 26 40 0.05 2
UST-3-3-12'Soil 40 0.92 36.8 40 0.07 2.8
UST-4-1-12'Soil 40 0.54 21.6 40 0.13 5.2
UST-4-2-12'Soil 40 0.57 22.8 40 0.18 7.2
UST-4-3-12'Soil 40 0.55 22 40 0.28 11.2
T-27 Soil 40 1.68 67.2 40 1.51 60.4
T-28 Soil 40 2.25 90 40 1.21 48.4
T-29 Soil 40 1.5 60 40 1.71 68.4
T-30 Soil 40 1.99 79.6 40 1.55 62
T-31 Soil 40 1.91 76.4 40 1.34 53.6
OE-BASE 17"Soil 100 8.4 840 100 0.85 85
T-32 Soil 40 1.71 68.4 40 1.65 66
T-33 Soil 40 5.11 204.4 40 2.1 84
T-34 Soil 100 5.16 516 100 0.91 91
T-35 Soil 40 4.23 169.2 40 1.82 72.8
T-36 Soil 40 1.25 50 40 0.88 35.2
T-37 Soil 40 9.88 395.2 40 2.81 112.4
T-38 Soil 40 1.65 66 40 1.36 54.4
DI-1-3'Soil 40 0.52 20.8 40 0.54 21.6
DI-2-3'Soil 40 0.47 18.8 40 0.15 6
T-39 Soil 40 1.26 50.4 40 0.81 32.4
T-40 Soil 40 2.65 106 40 1.62 64.8
T-41 Soil 40 1.7 68 40 0.13 5.2
DI-3-3'Soil 40 0.29 11.6 40 0.03 1.2
DI-4-3'Soil 40 0.28 11.2 40 0.06 2.4
T-42 Soil 40 1.29 51.6 40 2.46 98.4
PP-1 Soil 40 0.36 14.4 40 0.06 2.4
T-43 Soil 40 1.78 71.2 40 0.52 20.8
T-44 Soil 40 1.32 52.8 40 0.05 2
DI-5-3'Soil 40 0.28 11.2 40 0.09 3.6
Site:
New Dixie Mart #229
Report Date:
12/1/2022
Page:
2 of 3
Project Name:Date Collected:
Project Number:Date Analysed:
Project Manager:Operator:
Sample ID Matrix
Dilution
Factor x
GRO
Output
(ppm)
=GRO Value
(mg/Kg)
Dilution
Factor x
DRO
Output
(ppm)
=DRO Value
(mg/Kg)
UVF Analytical Report
siteLAB UVF Trilogy
10/29-30/2022
10/29-30/2022
AJ Discepolo
New Dixie Mart #229
2925
William Regenthal
DI-6-3'Soil 40 0.41 16.4 40 0.02 0.8
PP-2-3'Soil 40 0.3 12 40 0.04 1.6
PP-3-3'Soil 40 0.33 13.2 40 0.16 6.4
PP-4-3'Soil 40 0.64 25.6 40 0.31 12.4
DI-7-3'Soil 40 0.38 15.2 40 0.08 3.2
T-45 Soil 40 1.42 56.8 40 1.33 53.2
T-46 Soil 40 1.58 63.2 40 0.92 36.8
T-47 Soil 40 1.36 54.4 40 0.01 0.4
NE-10'Soil 40 0.29 11.6 40 0.02 0.8
NW-10'Soil 40 0.26 10.4 40 0.03 1.2
SE-10'Soil 800 2.72 2176 800 2.68 2144
SW-10'Soil 40 0.33 13.2 40 0.08 3.2
Site:
New Dixie Mart #229
Report Date:
12/1/2022
Page:
3 of 3
Calibration
Standard Output Calibration
Standard Output
0.5 0.69 0.1 0.17
1 1.24 0.5 0.56
3 3.06 1 1.11
5 4.88 3 3.1
10 9.87 5 5.89
0 0.2 0 0.01
0 0.16 0 0.02
Calibration
Standard Output Calibration
Standard Output
0.5 0.63 0.1 0.17
1 1.21 0.5 0.52
3 2.64 1 1.05
5 4.32 3 2.92
10 9.27 5 5.51
0 0.07 0 0.01
0 0.26 0 0.01
GRO DRO
Method Blank
11/30/2022
Field Calibration
GRO DRO
Method Blank
11/29/2022
FINAL SAMPLE ID TIME DILUTION GRO VALUE DRO VALUE
X PB-2 1024 100 2.39 239 3.96 396
X UST-1-1-12'1052 100 2.16 216 2.64 264
X UST-1-2-12'1056 100 7.2 720 1.76 176
X UST-1-3-12'1102 40 7.01 280.4 3.36 134.4
X UST-1-4-12'1059 100 1.3 130 2.2 220
X T-1 1113 100 6.63 663 17.1 1710
X T-1 1116 800 0 4.2 3360
X T-2 1140 40 1.44 57.6 0.79 31.6
X T-3 1142 40 6.18 247.2 16.66 666.4
X T-3 1147 400 0 3.26 1304
X T-4 1149 40 1.55 62 1.29 51.6
X T-5 1151 40 2.34 93.6 2.86 114.4
X T-6 1154 100 7.88 788 4.67 467
X UST-2-1-12'1231 40 1.27 50.8 0.33 13.2
X UST-2-2-12'1237 200 9.07 1814 1.27 254
X UST-2-3-12'1240 40 1.41 56.4 1.03 41.2
X UST-2-4-12'1243 40 1.78 71.2 1.29 51.6
X T-7 1246 40 1.26 50.4 2.49 99.6
X T-8 1307 40 1.62 64.8 2.94 117.6
X T-9 1309 40 1.6 64 1.27 50.8
X T-10 1311 40 1.84 73.6 1.87 74.8
X T-11 1313 40 1.93 77.2 1.36 54.4
X T-12 1315 40 1.9 76 2.86 114.4
X T-13 1318 40 2 80 1.98 79.2
X T-14 1542 40 1.54 61.6 0.69 27.6
X T-15 1543 40 1.39 55.6 2.19 87.6
X T-16 1546 40 1.93 77.2 1.15 46
X T-17 1548 40 2.74 109.6 1.91 76.4
X T-18 1551 40 3.61 144.4 2.55 102
X T-19 1553 40 5.91 236.4 3.96 158.4
X T-20 1557 100 3.5 350 3.04 304
X T-21 1610 40 5.25 210 4.01 160.4
X T-22 1613 100 8.64 864 2.56 256
X T-23 1616 40 3.71 148.4 2.63 105.2
X T-24 1618 40 1.86 74.4 1.81 72.4
X T-25 1621 40 2.88 115.2 3.24 129.6
X T-26 1643 40 2.33 93.2 4.47 178.8
X UST-3-1-12'1636 40 0.54 21.6 0.52 20.8
X UST-3-2-12'1639 40 0.65 26 0.05 2
X UST-3-3-12'1641 40 0.92 36.8 0.07 2.8
X UST-4-1-12'1713 40 0.54 21.6 0.13 5.2
X UST-4-2-12'1715 40 0.57 22.8 0.18 7.2
X UST-4-3-12'1717 40 0.55 22 0.28 11.2
11/30/2022
UVF Field Sheet- New Dixie #229
FINAL SAMPLE ID TIME DILUTION GRO VALUE DRO VALUE
UVF Field Sheet- New Dixie #229
X T-27 936 40 1.68 67.2 1.51 60.4
X T-28 942 40 2.25 90 1.21 48.4
X T-29 948 40 1.5 60 1.71 68.4
X T-30 955 40 1.99 79.6 1.55 62
X T-31 1001 40 1.91 76.4 1.34 53.6
X OE-BASE 17"1006 100 8.4 840 0.85 85
X T-32 1025 40 1.71 68.4 1.65 66
X T-33 1112 40 5.11 204.4 2.1 84
X T-34 1127 100 5.16 516 0.91 91
X T-35 1132 40 4.23 169.2 1.82 72.8
X T-36 1138 40 1.25 50 0.88 35.2
X T-37 1144 40 9.88 395.2 2.81 112.4
X T-38 1149 40 1.65 66 1.36 54.4
X DI-1-3'1154 40 0.52 20.8 0.54 21.6
X DI-2-3'1159 40 0.47 18.8 0.15 6
X T-39 1216 40 1.26 50.4 0.81 32.4
X T-40 1220 40 2.65 106 1.62 64.8
X T-41 1226 40 1.7 68 0.13 5.2
X DI-3-3'1231 40 0.29 11.6 0.03 1.2
X DI-4-3'1233 40 0.28 11.2 0.06 2.4
X T-42 1239 40 1.29 51.6 2.46 98.4
X PP-1 1244 40 0.36 14.4 0.06 2.4
X T-43 1249 40 1.78 71.2 0.52 20.8
X T-44 1253 40 1.32 52.8 0.05 2
X DI-5-3'1304 40 0.28 11.2 0.09 3.6
X DI-6-3'1308 40 0.41 16.4 0.02 0.8
X PP-2-3'1312 40 0.3 12 0.04 1.6
X PP-3-3'1319 40 0.33 13.2 0.16 6.4
X PP-4-3'1322 40 0.64 25.6 0.31 12.4
X DI-7-3'1328 40 0.38 15.2 0.08 3.2
X T-45 1335 40 1.42 56.8 1.33 53.2
X T-46 1339 40 1.58 63.2 0.92 36.8
X T-47 1344 40 1.36 54.4 0.01 0.4
X NE-10'1443 40 0.29 11.6 0.02 0.8
X NW-10'1528 40 0.26 10.4 0.03 1.2
X SE-10'1546 800 2.72 2176 2.68 2144
X SW-10'1550 40 0.33 13.2 0.08 3.2

APPENDIX J
Laboratory Report – Soil Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

12/12/2022
Geological Resources, Inc. William Regenthal
113 West Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-336-0032 Client Project Description: New Dixie Mart #229
GRI #5960
Dear William Regenthal:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 12/2/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 91
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-336-0032
Page 2 of 91
Report Number:
Sample Summary Table
Client Project Description:
22-336-0032
New Dixie Mart #229
GRI #5960
Lab No Client Sample ID Matrix Date Collected Date Received
11/30/2022 16:00Solids 94669 NW-10'12/02/2022
11/30/2022 16:05Solids 94670 SW-10'12/02/2022
11/30/2022 16:15Solids 94671 NE-10'12/02/2022
11/30/2022 16:10Solids 94672 SE-10'12/02/2022
11/30/2022 16:20Solids 94673 OE-Base-17'12/02/2022
Page 3 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-336-0032
Report Limit
Project:New Dixie Mart #229
V 94669NW-10'
0.054 12/05/2022 13:328260DAcetonemg/Kg - dry 0.002
0.012 12/05/2022 13:328260DBenzenemg/Kg - dry 0.0007
J0.003 12/05/2022 13:328260Dn-Butylbenzene mg/Kg - dry 0.0006
J0.001 12/05/2022 13:328260Dsec-Butyl benzene mg/Kg - dry 0.0007
0.086 12/05/2022 13:328260DEthylbenzenemg/Kg - dry 0.0007
J0.004 12/05/2022 13:328260Dn-Hexane mg/Kg - dry 0.0008
0.007 12/05/2022 13:328260DIsopropylbenzenemg/Kg - dry 0.0006
0.033 12/05/2022 13:328260DNaphthalenemg/Kg - dry 0.001
0.023 12/05/2022 13:328260Dn-Propylbenzene mg/Kg - dry 0.0007
0.020 12/05/2022 13:328260DToluenemg/Kg - dry 0.0008
0.080 12/05/2022 13:328260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0006
0.013 12/05/2022 13:328260D1,3,5-Trimethylbenzene mg/Kg - dry 0.0007
0.055 12/05/2022 13:328260Do-Xylene mg/Kg - dry 0.0006
0.162 12/05/2022 13:328260Dm,p-Xylene mg/Kg - dry 0.001
0.217 12/05/2022 13:328260DXylene (Total)mg/Kg - dry 0.0006
J0.139 12/08/2022 22:308270E2-Methylnaphthalene mg/Kg - dry 0.121
J4.74 12/05/2022 11:40CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 0.760
J21.7 12/08/2022 14:06CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 17.3
J21.7 12/08/2022 14:06MADEP-EPH Aromatic C11-C22 mg/Kg - dry 17.3
J4.74 12/05/2022 11:40MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.760
18.0 12/05/2022 10:32SW-DRYWT Moisture %
V 94670SW-10'
J0.017 12/06/2022 12:418260DAcetonemg/Kg - dry 0.002
J0.0009 12/06/2022 12:418260DBenzenemg/Kg - dry 0.0006
J0.005 12/06/2022 12:418260Dn-Butylbenzene mg/Kg - dry 0.0005
J0.003 12/06/2022 12:418260Dsec-Butyl benzene mg/Kg - dry 0.0006
0.140 12/06/2022 12:418260DEthylbenzenemg/Kg - dry 0.0006
J0.003 12/06/2022 12:418260Dn-Hexane mg/Kg - dry 0.0007
0.014 12/06/2022 12:418260DIsopropylbenzenemg/Kg - dry 0.0005
J0.001 12/06/2022 12:418260D4-Isopropyl toluene mg/Kg - dry 0.001
0.023 12/06/2022 12:418260DNaphthalenemg/Kg - dry 0.001
0.038 12/06/2022 12:418260Dn-Propylbenzene mg/Kg - dry 0.0006
0.037 12/06/2022 12:418260DToluenemg/Kg - dry 0.0007
0.164 12/06/2022 12:418260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0005
0.037 12/06/2022 12:418260D1,3,5-Trimethylbenzene mg/Kg - dry 0.0006
0.140 12/06/2022 12:418260Do-Xylene mg/Kg - dry 0.0006
Page 4 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-336-0032
Report Limit
Project:New Dixie Mart #229
V 94670SW-10'
0.346 12/06/2022 12:418260Dm,p-Xylene mg/Kg - dry 0.001
0.487 12/06/2022 12:418260DXylene (Total)mg/Kg - dry 0.0006
9.34 12/05/2022 12:04CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 0.697
J6.22 12/05/2022 12:04MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 5.10
9.34 12/05/2022 12:04MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.697
10.6 12/05/2022 10:32SW-DRYWT Moisture %
V 94671NE-10'
0.061 12/05/2022 15:228260DAcetonemg/Kg - dry 0.002
0.033 12/05/2022 15:228260DBenzenemg/Kg - dry 0.0007
J0.001 12/05/2022 15:228260Dn-Butylbenzene mg/Kg - dry 0.0006
J0.001 12/05/2022 15:228260Dsec-Butyl benzene mg/Kg - dry 0.0006
0.063 12/05/2022 15:228260DEthylbenzenemg/Kg - dry 0.0007
J0.008 12/05/2022 15:228260Dn-Hexane mg/Kg - dry 0.0007
J0.005 12/05/2022 15:228260DIsopropylbenzenemg/Kg - dry 0.0005
J0.005 12/05/2022 15:228260DNaphthalenemg/Kg - dry 0.001
0.014 12/05/2022 15:228260Dn-Propylbenzene mg/Kg - dry 0.0006
0.020 12/05/2022 15:228260DToluenemg/Kg - dry 0.0007
0.046 12/05/2022 15:228260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0006
0.010 12/05/2022 15:228260D1,3,5-Trimethylbenzene mg/Kg - dry 0.0006
0.052 12/05/2022 15:228260Do-Xylene mg/Kg - dry 0.0006
0.154 12/05/2022 15:228260Dm,p-Xylene mg/Kg - dry 0.001
0.206 12/05/2022 15:228260DXylene (Total)mg/Kg - dry 0.0006
J5.57 12/05/2022 12:28CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 0.701
J26.2 12/08/2022 15:19CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 16.0
J26.2 12/08/2022 15:19MADEP-EPH Aromatic C11-C22 mg/Kg - dry 16.0
J5.57 12/05/2022 12:28MADEP-VPH Aromatic C9-C10 mg/Kg - dry 0.701
11.1 12/05/2022 10:32SW-DRYWT Moisture %
V 94672SE-10'
4.68 12/05/2022 17:128260Dn-Butylbenzene mg/Kg - dry 0.135
1.96 12/05/2022 17:128260Dsec-Butyl benzene mg/Kg - dry 0.153
18.9 12/05/2022 17:128260DEthylbenzenemg/Kg - dry 0.159
J0.888 12/05/2022 17:128260Dn-Hexane mg/Kg - dry 0.181
4.55 12/05/2022 17:128260DIsopropylbenzenemg/Kg - dry 0.126
1.67 12/05/2022 17:128260D4-Isopropyl toluene mg/Kg - dry 0.357
31.1 12/05/2022 17:128260DNaphthalenemg/Kg - dry 0.272
15.3 12/05/2022 17:128260Dn-Propylbenzene mg/Kg - dry 0.148
Page 5 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-336-0032
Report Limit
Project:New Dixie Mart #229
V 94672SE-10'
J0.329 12/05/2022 17:128260DToluenemg/Kg - dry 0.181
56.3 12/05/2022 17:128260D1,2,4-Trimethylbenzene mg/Kg - dry 0.135
3.86 12/05/2022 17:128260D1,3,5-Trimethylbenzene mg/Kg - dry 0.148
2.56 12/05/2022 17:128260Do-Xylene mg/Kg - dry 0.137
14.5 12/05/2022 17:128260Dm,p-Xylene mg/Kg - dry 0.346
17.0 12/05/2022 17:128260DXylene (Total)mg/Kg - dry 0.137
1.46 12/08/2022 23:378270EFluorenemg/Kg - dry 0.140
11.2 12/09/2022 11:348270E1-Methylnaphthalene mg/Kg - dry 0.582
24.2 12/09/2022 11:348270E2-Methylnaphthalene mg/Kg - dry 0.549
24.8 12/09/2022 11:348270ENaphthalenemg/Kg - dry 0.791
2.57 12/08/2022 23:378270EPhenanthrenemg/Kg - dry 0.228
J0.531 12/08/2022 23:378270EPyrenemg/Kg - dry 0.147
J38712/05/2022 17:12CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 66.8
5940 12/06/2022 08:58CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 34.3
J159012/08/2022 15:55CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 15.6
1740 12/08/2022 15:55MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 10.1
415 12/08/2022 15:55MADEP-EPH Aliphatic C19-C36 mg/Kg - dry 13.4
1630 12/08/2022 15:55MADEP-EPH Aromatic C11-C22 mg/Kg - dry 15.6
J38712/06/2022 08:58MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 66.8
2120 12/06/2022 08:58MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 251
5940 12/06/2022 08:58MADEP-VPH Aromatic C9-C10 mg/Kg - dry 34.3
9.05 12/05/2022 10:32SW-DRYWT Moisture %
V 94673OE-Base-17'
2.07 12/05/2022 18:358260Dn-Butylbenzene mg/Kg - dry 0.147
J1.09 12/05/2022 18:358260Dsec-Butyl benzene mg/Kg - dry 0.167
27.3 12/05/2022 18:358260DEthylbenzenemg/Kg - dry 0.173
5.14 12/05/2022 18:358260Dn-Hexane mg/Kg - dry 0.197
3.45 12/05/2022 18:358260DIsopropylbenzenemg/Kg - dry 0.137
J0.540 12/05/2022 18:358260D4-Isopropyl toluene mg/Kg - dry 0.389
12.9 12/05/2022 18:358260DNaphthalenemg/Kg - dry 0.297
10.9 12/05/2022 18:358260Dn-Propylbenzene mg/Kg - dry 0.161
4.74 12/05/2022 18:358260DToluenemg/Kg - dry 0.197
65.9 12/05/2022 18:358260D1,2,4-Trimethylbenzene mg/Kg - dry 0.147
20.3 12/05/2022 18:358260D1,3,5-Trimethylbenzene mg/Kg - dry 0.161
38.5 12/05/2022 18:358260Do-Xylene mg/Kg - dry 0.149
105 12/05/2022 18:358260Dm,p-Xylene mg/Kg - dry 0.377
Page 6 of 91
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-336-0032
Report Limit
Project:New Dixie Mart #229
V 94673OE-Base-17'
143 12/05/2022 18:358260DXylene (Total)mg/Kg - dry 0.149
J0.155 12/09/2022 00:228270EFluorenemg/Kg - dry 0.153
1.79 12/09/2022 00:228270E1-Methylnaphthalene mg/Kg - dry 0.127
4.12 12/09/2022 00:228270E2-Methylnaphthalene mg/Kg - dry 0.119
4.88 12/09/2022 00:228270ENaphthalenemg/Kg - dry 0.172
245 12/05/2022 18:35CALCULATIONAliphatic C5-C8 (Adjusted)mg/Kg - dry 14.6
1450 12/06/2022 08:10CALCULATIONAromatic C9-C10 (Adjusted)mg/Kg - dry 7.48
J82.5 12/08/2022 16:31CALCULATIONAromatic C11-C22 (Adjusted)mg/Kg - dry 17.0
66.2 12/08/2022 16:31MADEP-EPH Aliphatic C9-C18 mg/Kg - dry 11.1
87.5 12/08/2022 16:31MADEP-EPH Aromatic C11-C22 mg/Kg - dry 17.0
249 12/06/2022 08:10MADEP-VPH Aliphatic C5-C8 mg/Kg - dry 14.6
536 12/06/2022 08:10MADEP-VPH Aliphatic C9-C12 mg/Kg - dry 54.7
1450 12/06/2022 08:10MADEP-VPH Aromatic C9-C10 mg/Kg - dry 7.48
16.6 12/05/2022 10:32SW-DRYWT Moisture %
Page 7 of 91

Client: Geological Resources, Inc. CASE NARRATIVE
Project: New Dixie Mart #229 Lab Report Number: 22-336-0032
Date: 12/12/2022
Massachusetts EPH Method MADEP-EPH QC Batch No: V27568 This batch initially ran with a low percent recovery for the Breakthrough CCVs. A new Breakthrough CCV
Standard was prepared and met specifications and batch was rerun with confirming results. However, the 2nd run of this batch produced a high % recovery in the Chlorooctadecane surrogate (142%) and C19-C36 Aliphatic
range on the ending CCV. The initial results are reported and both runs included with PDFs.
Sample 94672 (SE-10') Analyte: 2-Bromonaphthalene
QC Batch No: V27568/V27432 Surrogate recovery(s) was flagged as outside QC limits due to high levels of target and/or non-target analytes.
Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits.
Sample 94672 (SE-10') Analyte: 2-Fluorobiphenyl
QC Batch No: V27568/V27432 Surrogate recovery(s) was flagged as outside QC limits due to high levels of target and/or non-target analytes.
Batch QC samples (method blank and laboratory control samples) all showed surrogates within QC limits.
Analyte: Aliphatic C9-C18 QC Batch No: V27568/V27432 LCSD failed % recovery in the C9-C18 Aliphatic range. The sample was re-fractionated to confirm initial results. Some of the smaller component molecules like n-nonane (C9) and n-decane (C10) had an extremely low
recovery percentage and is likely due to over-evaporation during initial extraction phase. The initial results for LCSD are reported. The LCS met specifications for % recovery.
Volatile Organic Compounds - GC/MS Method 8260D Analyte: 2-Hexanone QC Batch No: V27375/V27288 CCV result is above control limits but within method parameters. A standard at or below the RL was analzyed and found acceptable. Results are reported but considered estimated.
Semivolatile Organic Compounds - GC/MS Method 8270E Sample 94844 (TMW-1 19-20) Analyte: 3,3`-Dichlorobenzidine QC Batch No: V27547/V27511 Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the system was in control, but the reported result could be affected by matrix interference.
Sample 94844 (TMW-1 19-20) Analyte: 4-Nitroaniline QC Batch No: V27547/V27511 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Page 8 of 91

Sample 94844 (TMW-1 19-20)
Analyte: Aniline QC Batch No: V27547/V27511
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Benzoic Acid QC Batch No: V27547/V27511
This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for
a low bias.
Sample 94844 (TMW-1 19-20) Analyte: Pyridine
QC Batch No: V27547/V27511 Matrix spike/matrix spike duplicate recoveries are outside of control limits. Acceptable LCS recovery indicates the
system was in control, but the reported result could be affected by matrix interference.

Page 9 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
18.0 %Moisture 1 12/05/22 10:32 SW-DRYWTAMB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 10 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
0.054 mg/Kg - dry 0.002 0.024Acetone 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.024Acrolein 1 12/05/22 13:32 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.024Acrylonitrile 1 12/05/22 13:32 V27289TBL
0.012 mg/Kg - dry 0.0007 0.006Benzene 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.006Bromobenzene 1 12/05/22 13:32 V27289TBL
<0.0010 mg/Kg - dry 0.0010 0.006Bromochloromethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Bromodichloromethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Bromoform 1 12/05/22 13:32 V27289TBL
<0.002 mg/Kg - dry 0.002 0.012
Bromomethane 1 12/05/22 13:32 V27289TBL
0.003 J mg/Kg - dry 0.0006 0.006n-Butylbenzene 1 12/05/22 13:32 V27289TBL
0.001 J mg/Kg - dry 0.0007 0.006sec-Butyl benzene 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.006tert-Butyl benzene 1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.006Carbon Disulfide 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Carbon Tetrachloride 1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.006Chlorobenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006
Chlorodibromomethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.012Chloroethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Chloroform 1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.012Chloromethane 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.0062-Chlorotoluene 1 12/05/22 13:32 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.0064-Chlorotoluene 1 12/05/22 13:32 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.006Di-Isopropyl Ether (DIPE)1 12/05/22 13:32 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 11 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
<0.0005 mg/Kg - dry 0.0005 0.0121,2-Dibromo-3-Chloropropane 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,2-Dibromoethane 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.006Dibromomethane 1 12/05/22 13:32 V27289TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,2-Dichlorobenzene 1 12/05/22 13:32 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,3-Dichlorobenzene 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,4-Dichlorobenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.012Dichlorodifluoromethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0061,1-Dichloroethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006
1,2-Dichloroethane 1 12/05/22 13:32 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,1-Dichloroethene 1 12/05/22 13:32 V27289TBL
<0.0010 mg/Kg - dry 0.0010 0.006cis-1,2-Dichloroethene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006trans-1,2-Dichloroethene 1 12/05/22 13:32 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.0061,2-Dichloropropane 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0061,3-Dichloropropane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0062,2-Dichloropropane 1 12/05/22 13:32 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.006
1,1-Dichloropropene 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.006cis-1,3-Dichloropropene 1 12/05/22 13:32 V27289TBL
<0.0010 mg/Kg - dry 0.0010 0.006trans-1,3-Dichloropropene 1 12/05/22 13:32 V27289TBL
0.086 mg/Kg - dry 0.0007 0.006Ethylbenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.060Ethyl Tertiary Butyl Ether (ETBE)1 12/05/22 13:32 V27289TBL
<0.0010 mg/Kg - dry 0.0010 0.012Hexachlorobutadiene 1 12/05/22 13:32 V27289TBL
0.004 J mg/Kg - dry 0.0008 0.012n-Hexane 1 12/05/22 13:32 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 12 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
<0.0008 mg/Kg - dry 0.0008 0.0242-Hexanone 1 12/05/22 13:32 V27289TBL
0.007 mg/Kg - dry 0.0006 0.006Isopropylbenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0064-Isopropyl toluene 1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.024Methyl Ethyl Ketone (MEK)1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.006Methyl tert-butyl ether (MTBE)1 12/05/22 13:32 V27289TBL
<0.018 mg/Kg - dry 0.018 0.0244-Methyl-2-Pentanone 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.012Methylene Chloride 1 12/05/22 13:32 V27289TBL
0.033 mg/Kg - dry 0.001 0.012Naphthalene 1 12/05/22 13:32 V27289TBL
0.023 mg/Kg - dry 0.0007 0.006
n-Propylbenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Styrene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1,2-Tetrachloroethane 1 12/05/22 13:32 V27289TBL
<0.0004 mg/Kg - dry 0.0004 0.0061,1,2,2-Tetrachloroethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Tetrachloroethene 1 12/05/22 13:32 V27289TBL
0.020 mg/Kg - dry 0.0008 0.006Toluene 1 12/05/22 13:32 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0121,2,3-Trichlorobenzene 1 12/05/22 13:32 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.012
1,2,4-Trichlorobenzene 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0061,1,1-Trichloroethane 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.0061,1,2-Trichloroethane 1 12/05/22 13:32 V27289TBL
<0.001 mg/Kg - dry 0.001 0.006Trichloroethene 1 12/05/22 13:32 V27289TBL
<0.002 mg/Kg - dry 0.002 0.012Trichlorofluoromethane 1 12/05/22 13:32 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.0061,2,3-Trichloropropane 1 12/05/22 13:32 V27289TBL
0.080 mg/Kg - dry 0.0006 0.0061,2,4-Trimethylbenzene 1 12/05/22 13:32 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 13 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
0.013 mg/Kg - dry 0.0007 0.0061,3,5-Trimethylbenzene 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Acetate 1 12/05/22 13:32 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.012Vinyl Chloride 1 12/05/22 13:32 V27289TBL
0.055 mg/Kg - dry 0.0006 0.006o-Xylene 1 12/05/22 13:32 V27289TBL
0.162 mg/Kg - dry 0.001 0.012m,p-Xylene 1 12/05/22 13:32 V27289TBL
0.217 mg/Kg - dry 0.0006 0.006Xylene (Total)1 12/05/22 13:32 V27289KCC
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%12/05/22 13:321 TBL V27289
Surrogate: Dibromofluoromethane 103 Limits: 84-123%12/05/22 13:321 TBL V27289
Surrogate: Toluene-d8 93.8 Limits: 76-129%12/05/22 13:321 TBL V27289
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.141 mg/Kg - dry 0.141 0.804Acenaphthene 1 12/08/22 22:30 V27547JMV
<0.128 mg/Kg - dry 0.128 0.804Acenaphthylene 1 12/08/22 22:30 V27547JMV
<0.185 mg/Kg - dry 0.185 0.804Aniline 1 12/08/22 22:30 V27547JMV
<0.174 mg/Kg - dry 0.174 0.804Anthracene 1 12/08/22 22:30 V27547JMV
<0.169 mg/Kg - dry 0.169 0.804Benzo(a)anthracene 1 12/08/22 22:30 V27547JMV
<0.179 mg/Kg - dry 0.179 0.804
Benzo(a)pyrene 1 12/08/22 22:30 V27547JMV
<0.178 mg/Kg - dry 0.178 0.804Benzo(b)fluoranthene 1 12/08/22 22:30 V27547JMV
<0.165 mg/Kg - dry 0.165 0.804Benzo(g,h,i)perylene 1 12/08/22 22:30 V27547JMV
<0.167 mg/Kg - dry 0.167 0.804Benzo(k)fluoranthene 1 12/08/22 22:30 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 14 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.707 M mg/Kg - dry 0.707 2.44Benzoic Acid 1 12/08/22 22:30 V27547JMV
<0.128 mg/Kg - dry 0.128 0.804Benzyl alcohol 1 12/08/22 22:30 V27547JMV
<0.143 mg/Kg - dry 0.143 0.804Bis(2-Chloroethoxy)methane 1 12/08/22 22:30 V27547JMV
<0.130 mg/Kg - dry 0.130 0.804Bis(2-Chloroethyl)ether 1 12/08/22 22:30 V27547JMV
<0.165 mg/Kg - dry 0.165 0.402Bis(2-Chloroisopropyl)ether 1 12/08/22 22:30 V27547JMV
<0.146 mg/Kg - dry 0.146 0.804Bis(2-ethylhexyl)phthalate 1 12/08/22 22:30 V27547JMV
<0.132 mg/Kg - dry 0.132 0.8044-Bromophenyl phenyl ether 1 12/08/22 22:30 V27547JMV
<0.137 mg/Kg - dry 0.137 0.402Butyl benzyl phthalate 1 12/08/22 22:30 V27547JMV
<0.112 mg/Kg - dry 0.112 0.804
4-Chloro-3-methylphenol 1 12/08/22 22:30 V27547JMV
<0.136 mg/Kg - dry 0.136 0.4024-Chloroaniline 1 12/08/22 22:30 V27547JMV
<0.141 mg/Kg - dry 0.141 0.8042-Chloronaphthalene 1 12/08/22 22:30 V27547JMV
<0.119 mg/Kg - dry 0.119 0.8042-Chlorophenol 1 12/08/22 22:30 V27547JMV
<0.153 mg/Kg - dry 0.153 1.224-Chlorophenyl phenyl ether 1 12/08/22 22:30 V27547JMV
<0.173 mg/Kg - dry 0.173 0.804Chrysene 1 12/08/22 22:30 V27547JMV
<0.280 mg/Kg - dry 0.280 0.804Dibenz(a,h)anthracene 1 12/08/22 22:30 V27547JMV
<0.145 mg/Kg - dry 0.145 0.804
Dibenzofuran 1 12/08/22 22:30 V27547JMV
<0.115 mg/Kg - dry 0.115 0.8041,2-Dichlorobenzene 1 12/08/22 22:30 V27547JMV
<0.118 mg/Kg - dry 0.118 0.8041,3-Dichlorobenzene 1 12/08/22 22:30 V27547JMV
<0.118 mg/Kg - dry 0.118 0.4021,4-Dichlorobenzene 1 12/08/22 22:30 V27547JMV
<0.179 mg/Kg - dry 0.179 0.8043,3'-Dichlorobenzidine 1 12/08/22 22:30 V27547JMV
<0.116 mg/Kg - dry 0.116 0.8042,4-Dichlorophenol 1 12/08/22 22:30 V27547JMV
<0.219 mg/Kg - dry 0.219 0.804Diethyl phthalate 1 12/08/22 22:30 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 15 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.212 mg/Kg - dry 0.212 0.804Dimethyl phthalate 1 12/08/22 22:30 V27547JMV
<0.131 mg/Kg - dry 0.131 0.4022,4-Dimethylphenol 1 12/08/22 22:30 V27547JMV
<0.130 mg/Kg - dry 0.130 0.804Di-n-butyl phthalate 1 12/08/22 22:30 V27547JMV
<0.292 mg/Kg - dry 0.292 1.834,6-Dinitro-2-methylphenol 1 12/08/22 22:30 V27547JMV
<0.634 mg/Kg - dry 0.634 1.832,4-Dinitrophenol 1 12/08/22 22:30 V27547JMV
<0.117 mg/Kg - dry 0.117 0.8042,4-Dinitrotoluene 1 12/08/22 22:30 V27547JMV
<0.131 mg/Kg - dry 0.131 0.8042,6-Dinitrotoluene 1 12/08/22 22:30 V27547JMV
<0.174 mg/Kg - dry 0.174 0.402Di-n-Octyl Phthalate 1 12/08/22 22:30 V27547JMV
<0.150 mg/Kg - dry 0.150 0.804
Fluoranthene 1 12/08/22 22:30 V27547JMV
<0.156 mg/Kg - dry 0.156 0.804Fluorene 1 12/08/22 22:30 V27547JMV
<0.129 mg/Kg - dry 0.129 0.804Hexachlorobenzene 1 12/08/22 22:30 V27547JMV
<0.119 mg/Kg - dry 0.119 0.804Hexachlorobutadiene 1 12/08/22 22:30 V27547JMV
<0.191 mg/Kg - dry 0.191 0.804Hexachlorocyclopentadiene 1 12/08/22 22:30 V27547JMV
<0.096 mg/Kg - dry 0.096 0.804Hexachloroethane 1 12/08/22 22:30 V27547JMV
<0.218 mg/Kg - dry 0.218 0.804Indeno(1,2,3-cd)pyrene 1 12/08/22 22:30 V27547JMV
<0.232 mg/Kg - dry 0.232 0.804
Isophorone 1 12/08/22 22:30 V27547JMV
<0.129 mg/Kg - dry 0.129 0.8041-Methylnaphthalene 1 12/08/22 22:30 V27547JMV
0.139 J mg/Kg - dry 0.121 0.8042-Methylnaphthalene 1 12/08/22 22:30 V27547JMV
<0.118 mg/Kg - dry 0.118 0.8042-Methylphenol 1 12/08/22 22:30 V27547JMV
<0.103 mg/Kg - dry 0.103 0.8043&4 Methylphenol 1 12/08/22 22:30 V27547JMV
<0.175 mg/Kg - dry 0.175 0.804Naphthalene 1 12/08/22 22:30 V27547JMV
<0.117 mg/Kg - dry 0.117 0.8042-Nitroaniline 1 12/08/22 22:30 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 16 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.146 mg/Kg - dry 0.146 0.8043-Nitroaniline 1 12/08/22 22:30 V27547JMV
<0.113 mg/Kg - dry 0.113 0.4024-Nitroaniline 1 12/08/22 22:30 V27547JMV
<0.141 mg/Kg - dry 0.141 0.402Nitrobenzene 1 12/08/22 22:30 V27547JMV
<0.108 mg/Kg - dry 0.108 0.8042-Nitrophenol 1 12/08/22 22:30 V27547JMV
<0.142 mg/Kg - dry 0.142 0.8044-Nitrophenol 1 12/08/22 22:30 V27547JMV
<0.320 mg/Kg - dry 0.320 0.804N-Nitrosodimethylamine 1 12/08/22 22:30 V27547JMV
<0.220 mg/Kg - dry 0.220 0.804N-Nitrosodiphenylamine 1 12/08/22 22:30 V27547JMV
<0.143 mg/Kg - dry 0.143 0.804N-Nitroso-di-n-propylamine 1 12/08/22 22:30 V27547JMV
<0.423 mg/Kg - dry 0.423 1.22
Pentachlorophenol 1 12/08/22 22:30 V27547JMV
<0.253 mg/Kg - dry 0.253 0.804Phenanthrene 1 12/08/22 22:30 V27547JMV
<0.136 mg/Kg - dry 0.136 0.804Phenol 1 12/08/22 22:30 V27547JMV
<0.163 mg/Kg - dry 0.163 0.804Pyrene 1 12/08/22 22:30 V27547JMV
<0.096 mg/Kg - dry 0.096 0.402Pyridine 1 12/08/22 22:30 V27547JMV
<0.130 mg/Kg - dry 0.130 0.8041,2,4-Trichlorobenzene 1 12/08/22 22:30 V27547JMV
<0.117 mg/Kg - dry 0.117 0.8042,4,5-Trichlorophenol 1 12/08/22 22:30 V27547JMV
<0.117 mg/Kg - dry 0.117 0.804
2,4,6-Trichlorophenol 1 12/08/22 22:30 V27547JMV
8270ESurrogate: Phenol-d5 67.6 Limits: 34-121%12/08/22 22:301 JMV
Surrogate: 2-Fluorobiphenyl 84.4 Limits: 44-115%12/08/22 22:301 JMV V27547
Surrogate: 2-Fluorophenol 71.8 Limits: 35-115%12/08/22 22:301 JMV V27547
Surrogate: Nitrobenzene-d5 73.1 Limits: 37-122%12/08/22 22:301 JMV V27547
Surrogate: 4-Terphenyl-d14 104 Limits: 54-127%12/08/22 22:301 JMV V27547
Surrogate: 2,4,6-Tribromophenol 85.9 Limits: 39-132%12/08/22 22:301 JMV V27547
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 17 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.49 mg/Kg - dry 1.49 9.76Aliphatic C5-C8 (Adjusted)100 12/05/22 11:40
<5.56 mg/Kg - dry 5.56 9.76Aliphatics C9-C12 (Adjusted)100 12/05/22 11:40
4.74 J mg/Kg - dry 0.760 9.76Aromatic C9-C10 (Adjusted)100 12/05/22 11:40
21.7 J mg/Kg - dry 17.3 61.1Aromatic C11-C22 (Adjusted)1 12/08/22 14:06
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V27432 12/07/22 11:45
<11.2 mg/Kg - dry 11.2 61.1Aliphatic C9-C18 1 12/08/22 14:06 V27568JLK
<14.9 mg/Kg - dry 14.9 61.1Aliphatic C19-C36 1 12/08/22 14:06 V27568JLK
21.7 J mg/Kg - dry 17.3 61.1Aromatic C11-C22 1 12/08/22 14:06 V27568JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 118 Limits: 40-140%12/08/22 14:061 JLK
MADEP-EPHSurrogate: Chlorooctadecane 73.0 Limits: 40-140%12/08/22 14:061 JLK
MADEP-EPHSurrogate: OTP Surrogate 88.0 Limits: 40-140%12/08/22 14:061 JLK
Surrogate: 2-Fluorobiphenyl 114 Limits: 40-140%12/08/22 14:061 JLK V27568
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
<1.49 mg/Kg - dry 1.49 9.76Aliphatic C5-C8 100 12/05/22 11:40 V27228TBL
<5.56 mg/Kg - dry 5.56 9.76Aliphatic C9-C12 100 12/05/22 11:40 V27228TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 18 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NW-10'
94669 Matrix:
11/30/2022 16:00
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
4.74 J mg/Kg - dry 0.760 9.76Aromatic C9-C10 100 12/05/22 11:40 V27228TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)83.9 Limits: 70-130%12/05/22 11:40100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)90.6 Limits: 70-130%12/05/22 11:40100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 19 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
10.6 %Moisture 1 12/05/22 10:32 SW-DRYWTAMB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 20 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27374 12/06/22 08:00
0.017 J mg/Kg - dry 0.002 0.022Acetone 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 12/06/22 12:41 V27375TBL
<0.0008 mg/Kg - dry 0.0008 0.022Acrylonitrile 1 12/06/22 12:41 V27375TBL
0.0009 J mg/Kg - dry 0.0006 0.005Benzene 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 12/06/22 12:41 V27375TBL
<0.002 mg/Kg - dry 0.002 0.011
Bromomethane 1 12/06/22 12:41 V27375TBL
0.005 J mg/Kg - dry 0.0005 0.005n-Butylbenzene 1 12/06/22 12:41 V27375TBL
0.003 J mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.005Chlorobenzene 1 12/06/22 12:41 V27375TBL
<0.0010 mg/Kg - dry 0.0010 0.005
Chlorodibromomethane 1 12/06/22 12:41 V27375TBL
<0.0010 mg/Kg - dry 0.0010 0.011Chloroethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 12/06/22 12:41 V27375TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 12/06/22 12:41 V27375TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 12/06/22 12:41 V27375TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 21 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27374 12/06/22 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 12/06/22 12:41 V27375TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 12/06/22 12:41 V27375TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005
1,2-Dichloroethane 1 12/06/22 12:41 V27375TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 12/06/22 12:41 V27375TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.005
1,1-Dichloropropene 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 12/06/22 12:41 V27375TBL
0.140 mg/Kg - dry 0.0006 0.005Ethylbenzene 1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.055Ethyl Tertiary Butyl Ether (ETBE)1 12/06/22 12:41 V27375TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 12/06/22 12:41 V27375TBL
0.003 J mg/Kg - dry 0.0007 0.011n-Hexane 1 12/06/22 12:41 V27375TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 22 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27374 12/06/22 08:00
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 12/06/22 12:41 V27375TBL
0.014 mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 12/06/22 12:41 V27375TBL
0.001 J mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 12/06/22 12:41 V27375TBL
<0.016 mg/Kg - dry 0.016 0.0224-Methyl-2-Pentanone 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.011Methylene Chloride 1 12/06/22 12:41 V27375TBL
0.023 mg/Kg - dry 0.001 0.011Naphthalene 1 12/06/22 12:41 V27375TBL
0.038 mg/Kg - dry 0.0006 0.005
n-Propylbenzene 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 12/06/22 12:41 V27375TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Tetrachloroethene 1 12/06/22 12:41 V27375TBL
0.037 mg/Kg - dry 0.0007 0.005Toluene 1 12/06/22 12:41 V27375TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 12/06/22 12:41 V27375TBL
<0.0007 mg/Kg - dry 0.0007 0.011
1,2,4-Trichlorobenzene 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 12/06/22 12:41 V27375TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 12/06/22 12:41 V27375TBL
<0.001 mg/Kg - dry 0.001 0.005Trichloroethene 1 12/06/22 12:41 V27375TBL
<0.002 mg/Kg - dry 0.002 0.011Trichlorofluoromethane 1 12/06/22 12:41 V27375TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 12/06/22 12:41 V27375TBL
0.164 mg/Kg - dry 0.0005 0.0051,2,4-Trimethylbenzene 1 12/06/22 12:41 V27375TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 23 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27374 12/06/22 08:00
0.037 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 12/06/22 12:41 V27375TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 12/06/22 12:41 V27375TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 12/06/22 12:41 V27375TBL
0.140 mg/Kg - dry 0.0006 0.005o-Xylene 1 12/06/22 12:41 V27375TBL
0.346 mg/Kg - dry 0.001 0.011m,p-Xylene 1 12/06/22 12:41 V27375TBL
0.487 mg/Kg - dry 0.0006 0.005Xylene (Total)1 12/06/22 12:41 V27375KCC
Surrogate: 4-Bromofluorobenzene 98.4 Limits: 70-130%12/06/22 12:411 TBL V27375
Surrogate: Dibromofluoromethane 101 Limits: 84-123%12/06/22 12:411 TBL V27375
Surrogate: Toluene-d8 92.2 Limits: 76-129%12/06/22 12:411 TBL V27375
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.129 mg/Kg - dry 0.129 0.738Acenaphthene 1 12/08/22 22:52 V27547JMV
<0.117 mg/Kg - dry 0.117 0.738Acenaphthylene 1 12/08/22 22:52 V27547JMV
<0.170 mg/Kg - dry 0.170 0.738Aniline 1 12/08/22 22:52 V27547JMV
<0.159 mg/Kg - dry 0.159 0.738Anthracene 1 12/08/22 22:52 V27547JMV
<0.155 mg/Kg - dry 0.155 0.738Benzo(a)anthracene 1 12/08/22 22:52 V27547JMV
<0.164 mg/Kg - dry 0.164 0.738
Benzo(a)pyrene 1 12/08/22 22:52 V27547JMV
<0.163 mg/Kg - dry 0.163 0.738Benzo(b)fluoranthene 1 12/08/22 22:52 V27547JMV
<0.152 mg/Kg - dry 0.152 0.738Benzo(g,h,i)perylene 1 12/08/22 22:52 V27547JMV
<0.153 mg/Kg - dry 0.153 0.738Benzo(k)fluoranthene 1 12/08/22 22:52 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 24 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.648 M mg/Kg - dry 0.648 2.24Benzoic Acid 1 12/08/22 22:52 V27547JMV
<0.117 mg/Kg - dry 0.117 0.738Benzyl alcohol 1 12/08/22 22:52 V27547JMV
<0.131 mg/Kg - dry 0.131 0.738Bis(2-Chloroethoxy)methane 1 12/08/22 22:52 V27547JMV
<0.119 mg/Kg - dry 0.119 0.738Bis(2-Chloroethyl)ether 1 12/08/22 22:52 V27547JMV
<0.152 mg/Kg - dry 0.152 0.369Bis(2-Chloroisopropyl)ether 1 12/08/22 22:52 V27547JMV
<0.134 mg/Kg - dry 0.134 0.738Bis(2-ethylhexyl)phthalate 1 12/08/22 22:52 V27547JMV
<0.121 mg/Kg - dry 0.121 0.7384-Bromophenyl phenyl ether 1 12/08/22 22:52 V27547JMV
<0.126 mg/Kg - dry 0.126 0.369Butyl benzyl phthalate 1 12/08/22 22:52 V27547JMV
<0.103 mg/Kg - dry 0.103 0.738
4-Chloro-3-methylphenol 1 12/08/22 22:52 V27547JMV
<0.125 mg/Kg - dry 0.125 0.3694-Chloroaniline 1 12/08/22 22:52 V27547JMV
<0.129 mg/Kg - dry 0.129 0.7382-Chloronaphthalene 1 12/08/22 22:52 V27547JMV
<0.109 mg/Kg - dry 0.109 0.7382-Chlorophenol 1 12/08/22 22:52 V27547JMV
<0.140 mg/Kg - dry 0.140 1.124-Chlorophenyl phenyl ether 1 12/08/22 22:52 V27547JMV
<0.158 mg/Kg - dry 0.158 0.738Chrysene 1 12/08/22 22:52 V27547JMV
<0.257 mg/Kg - dry 0.257 0.738Dibenz(a,h)anthracene 1 12/08/22 22:52 V27547JMV
<0.133 mg/Kg - dry 0.133 0.738
Dibenzofuran 1 12/08/22 22:52 V27547JMV
<0.105 mg/Kg - dry 0.105 0.7381,2-Dichlorobenzene 1 12/08/22 22:52 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7381,3-Dichlorobenzene 1 12/08/22 22:52 V27547JMV
<0.109 mg/Kg - dry 0.109 0.3691,4-Dichlorobenzene 1 12/08/22 22:52 V27547JMV
<0.164 mg/Kg - dry 0.164 0.7383,3'-Dichlorobenzidine 1 12/08/22 22:52 V27547JMV
<0.107 mg/Kg - dry 0.107 0.7382,4-Dichlorophenol 1 12/08/22 22:52 V27547JMV
<0.201 mg/Kg - dry 0.201 0.738Diethyl phthalate 1 12/08/22 22:52 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 25 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.194 mg/Kg - dry 0.194 0.738Dimethyl phthalate 1 12/08/22 22:52 V27547JMV
<0.120 mg/Kg - dry 0.120 0.3692,4-Dimethylphenol 1 12/08/22 22:52 V27547JMV
<0.119 mg/Kg - dry 0.119 0.738Di-n-butyl phthalate 1 12/08/22 22:52 V27547JMV
<0.268 mg/Kg - dry 0.268 1.684,6-Dinitro-2-methylphenol 1 12/08/22 22:52 V27547JMV
<0.581 mg/Kg - dry 0.581 1.682,4-Dinitrophenol 1 12/08/22 22:52 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7382,4-Dinitrotoluene 1 12/08/22 22:52 V27547JMV
<0.120 mg/Kg - dry 0.120 0.7382,6-Dinitrotoluene 1 12/08/22 22:52 V27547JMV
<0.159 mg/Kg - dry 0.159 0.369Di-n-Octyl Phthalate 1 12/08/22 22:52 V27547JMV
<0.137 mg/Kg - dry 0.137 0.738
Fluoranthene 1 12/08/22 22:52 V27547JMV
<0.143 mg/Kg - dry 0.143 0.738Fluorene 1 12/08/22 22:52 V27547JMV
<0.118 mg/Kg - dry 0.118 0.738Hexachlorobenzene 1 12/08/22 22:52 V27547JMV
<0.109 mg/Kg - dry 0.109 0.738Hexachlorobutadiene 1 12/08/22 22:52 V27547JMV
<0.175 mg/Kg - dry 0.175 0.738Hexachlorocyclopentadiene 1 12/08/22 22:52 V27547JMV
<0.088 mg/Kg - dry 0.088 0.738Hexachloroethane 1 12/08/22 22:52 V27547JMV
<0.200 mg/Kg - dry 0.200 0.738Indeno(1,2,3-cd)pyrene 1 12/08/22 22:52 V27547JMV
<0.213 mg/Kg - dry 0.213 0.738
Isophorone 1 12/08/22 22:52 V27547JMV
<0.118 mg/Kg - dry 0.118 0.7381-Methylnaphthalene 1 12/08/22 22:52 V27547JMV
<0.111 mg/Kg - dry 0.111 0.7382-Methylnaphthalene 1 12/08/22 22:52 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7382-Methylphenol 1 12/08/22 22:52 V27547JMV
<0.094 mg/Kg - dry 0.094 0.7383&4 Methylphenol 1 12/08/22 22:52 V27547JMV
<0.161 mg/Kg - dry 0.161 0.738Naphthalene 1 12/08/22 22:52 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7382-Nitroaniline 1 12/08/22 22:52 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 26 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.134 mg/Kg - dry 0.134 0.7383-Nitroaniline 1 12/08/22 22:52 V27547JMV
<0.104 mg/Kg - dry 0.104 0.3694-Nitroaniline 1 12/08/22 22:52 V27547JMV
<0.129 mg/Kg - dry 0.129 0.369Nitrobenzene 1 12/08/22 22:52 V27547JMV
<0.099 mg/Kg - dry 0.099 0.7382-Nitrophenol 1 12/08/22 22:52 V27547JMV
<0.130 mg/Kg - dry 0.130 0.7384-Nitrophenol 1 12/08/22 22:52 V27547JMV
<0.294 mg/Kg - dry 0.294 0.738N-Nitrosodimethylamine 1 12/08/22 22:52 V27547JMV
<0.202 mg/Kg - dry 0.202 0.738N-Nitrosodiphenylamine 1 12/08/22 22:52 V27547JMV
<0.131 mg/Kg - dry 0.131 0.738N-Nitroso-di-n-propylamine 1 12/08/22 22:52 V27547JMV
<0.388 mg/Kg - dry 0.388 1.12
Pentachlorophenol 1 12/08/22 22:52 V27547JMV
<0.232 mg/Kg - dry 0.232 0.738Phenanthrene 1 12/08/22 22:52 V27547JMV
<0.125 mg/Kg - dry 0.125 0.738Phenol 1 12/08/22 22:52 V27547JMV
<0.149 mg/Kg - dry 0.149 0.738Pyrene 1 12/08/22 22:52 V27547JMV
<0.088 mg/Kg - dry 0.088 0.369Pyridine 1 12/08/22 22:52 V27547JMV
<0.119 mg/Kg - dry 0.119 0.7381,2,4-Trichlorobenzene 1 12/08/22 22:52 V27547JMV
<0.107 mg/Kg - dry 0.107 0.7382,4,5-Trichlorophenol 1 12/08/22 22:52 V27547JMV
<0.108 mg/Kg - dry 0.108 0.738
2,4,6-Trichlorophenol 1 12/08/22 22:52 V27547JMV
8270ESurrogate: Phenol-d5 65.8 Limits: 34-121%12/08/22 22:521 JMV
Surrogate: 2-Fluorobiphenyl 90.4 Limits: 44-115%12/08/22 22:521 JMV V27547
Surrogate: 2-Fluorophenol 69.4 Limits: 35-115%12/08/22 22:521 JMV V27547
Surrogate: Nitrobenzene-d5 70.1 Limits: 37-122%12/08/22 22:521 JMV V27547
Surrogate: 4-Terphenyl-d14 113 Limits: 54-127%12/08/22 22:521 JMV V27547
Surrogate: 2,4,6-Tribromophenol 85.3 Limits: 39-132%12/08/22 22:521 JMV V27547
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 27 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.36 mg/Kg - dry 1.36 8.95Aliphatic C5-C8 (Adjusted)100 12/05/22 12:04
<5.10 mg/Kg - dry 5.10 8.95Aliphatics C9-C12 (Adjusted)100 12/05/22 12:04
9.34 mg/Kg - dry 0.697 8.95Aromatic C9-C10 (Adjusted)100 12/05/22 12:04
<15.9 mg/Kg - dry 15.9 55.9Aromatic C11-C22 (Adjusted)1 12/08/22 14:42
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V27432 12/07/22 11:45
<10.3 mg/Kg - dry 10.3 55.9Aliphatic C9-C18 1 12/08/22 14:42 V27568JLK
<13.6 mg/Kg - dry 13.6 55.9Aliphatic C19-C36 1 12/08/22 14:42 V27568JLK
<15.9 mg/Kg - dry 15.9 55.9Aromatic C11-C22 1 12/08/22 14:42 V27568JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 121 Limits: 40-140%12/08/22 14:421 JLK
MADEP-EPHSurrogate: Chlorooctadecane 78.5 Limits: 40-140%12/08/22 14:421 JLK
MADEP-EPHSurrogate: OTP Surrogate 107 Limits: 40-140%12/08/22 14:421 JLK
Surrogate: 2-Fluorobiphenyl 118 Limits: 40-140%12/08/22 14:421 JLK V27568
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
<1.36 mg/Kg - dry 1.36 8.95Aliphatic C5-C8 100 12/05/22 12:04 V27228TBL
6.22 J mg/Kg - dry 5.10 8.95Aliphatic C9-C12 100 12/05/22 12:04 V27228TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 28 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SW-10'
94670 Matrix:
11/30/2022 16:05
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
9.34 mg/Kg - dry 0.697 8.95Aromatic C9-C10 100 12/05/22 12:04 V27228TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)87.0 Limits: 70-130%12/05/22 12:04100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)109 Limits: 70-130%12/05/22 12:04100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 29 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
11.1 %Moisture 1 12/05/22 10:32 SW-DRYWTAMB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 30 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
0.061 mg/Kg - dry 0.002 0.022Acetone 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.022Acrolein 1 12/05/22 15:22 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.022Acrylonitrile 1 12/05/22 15:22 V27289TBL
0.033 mg/Kg - dry 0.0007 0.005Benzene 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.005Bromobenzene 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.005Bromochloromethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Bromodichloromethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Bromoform 1 12/05/22 15:22 V27289TBL
<0.002 mg/Kg - dry 0.002 0.011
Bromomethane 1 12/05/22 15:22 V27289TBL
0.001 J mg/Kg - dry 0.0006 0.005n-Butylbenzene 1 12/05/22 15:22 V27289TBL
0.001 J mg/Kg - dry 0.0006 0.005sec-Butyl benzene 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.005tert-Butyl benzene 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.005Carbon Disulfide 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Carbon Tetrachloride 1 12/05/22 15:22 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.005Chlorobenzene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005
Chlorodibromomethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.011Chloroethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Chloroform 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.011Chloromethane 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.0052-Chlorotoluene 1 12/05/22 15:22 V27289TBL
<0.0004 mg/Kg - dry 0.0004 0.0054-Chlorotoluene 1 12/05/22 15:22 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.005Di-Isopropyl Ether (DIPE)1 12/05/22 15:22 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 31 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
<0.0005 mg/Kg - dry 0.0005 0.0111,2-Dibromo-3-Chloropropane 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,2-Dibromoethane 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.005Dibromomethane 1 12/05/22 15:22 V27289TBL
<0.0003 mg/Kg - dry 0.0003 0.0051,2-Dichlorobenzene 1 12/05/22 15:22 V27289TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,3-Dichlorobenzene 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.0051,4-Dichlorobenzene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.011Dichlorodifluoromethane 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.0051,1-Dichloroethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005
1,2-Dichloroethane 1 12/05/22 15:22 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,1-Dichloroethene 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.005cis-1,2-Dichloroethene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005trans-1,2-Dichloroethene 1 12/05/22 15:22 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,2-Dichloropropane 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.0051,3-Dichloropropane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0052,2-Dichloropropane 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.005
1,1-Dichloropropene 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.005cis-1,3-Dichloropropene 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.005trans-1,3-Dichloropropene 1 12/05/22 15:22 V27289TBL
0.063 mg/Kg - dry 0.0007 0.005Ethylbenzene 1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.056Ethyl Tertiary Butyl Ether (ETBE)1 12/05/22 15:22 V27289TBL
<0.0009 mg/Kg - dry 0.0009 0.011Hexachlorobutadiene 1 12/05/22 15:22 V27289TBL
0.008 J mg/Kg - dry 0.0007 0.011n-Hexane 1 12/05/22 15:22 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 32 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
<0.0007 mg/Kg - dry 0.0007 0.0222-Hexanone 1 12/05/22 15:22 V27289TBL
0.005 J mg/Kg - dry 0.0005 0.005Isopropylbenzene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0054-Isopropyl toluene 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.022Methyl Ethyl Ketone (MEK)1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.005Methyl tert-butyl ether (MTBE)1 12/05/22 15:22 V27289TBL
<0.016 mg/Kg - dry 0.016 0.0224-Methyl-2-Pentanone 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.011Methylene Chloride 1 12/05/22 15:22 V27289TBL
0.005 J mg/Kg - dry 0.001 0.011Naphthalene 1 12/05/22 15:22 V27289TBL
0.014 mg/Kg - dry 0.0006 0.005
n-Propylbenzene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Styrene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1,2-Tetrachloroethane 1 12/05/22 15:22 V27289TBL
<0.0004 mg/Kg - dry 0.0004 0.0051,1,2,2-Tetrachloroethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Tetrachloroethene 1 12/05/22 15:22 V27289TBL
0.020 mg/Kg - dry 0.0007 0.005Toluene 1 12/05/22 15:22 V27289TBL
<0.0006 mg/Kg - dry 0.0006 0.0111,2,3-Trichlorobenzene 1 12/05/22 15:22 V27289TBL
<0.0007 mg/Kg - dry 0.0007 0.011
1,2,4-Trichlorobenzene 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.0051,1,1-Trichloroethane 1 12/05/22 15:22 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.0051,1,2-Trichloroethane 1 12/05/22 15:22 V27289TBL
<0.001 mg/Kg - dry 0.001 0.005Trichloroethene 1 12/05/22 15:22 V27289TBL
<0.002 mg/Kg - dry 0.002 0.011Trichlorofluoromethane 1 12/05/22 15:22 V27289TBL
<0.0008 mg/Kg - dry 0.0008 0.0051,2,3-Trichloropropane 1 12/05/22 15:22 V27289TBL
0.046 mg/Kg - dry 0.0006 0.0051,2,4-Trimethylbenzene 1 12/05/22 15:22 V27289TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 33 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27288 12/05/22 08:00
0.010 mg/Kg - dry 0.0006 0.0051,3,5-Trimethylbenzene 1 12/05/22 15:22 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Acetate 1 12/05/22 15:22 V27289TBL
<0.0005 mg/Kg - dry 0.0005 0.011Vinyl Chloride 1 12/05/22 15:22 V27289TBL
0.052 mg/Kg - dry 0.0006 0.005o-Xylene 1 12/05/22 15:22 V27289TBL
0.154 mg/Kg - dry 0.001 0.011m,p-Xylene 1 12/05/22 15:22 V27289TBL
0.206 mg/Kg - dry 0.0006 0.005Xylene (Total)1 12/05/22 15:22 V27289KCC
Surrogate: 4-Bromofluorobenzene 99.3 Limits: 70-130%12/05/22 15:221 TBL V27289
Surrogate: Dibromofluoromethane 104 Limits: 84-123%12/05/22 15:221 TBL V27289
Surrogate: Toluene-d8 93.1 Limits: 76-129%12/05/22 15:221 TBL V27289
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.130 mg/Kg - dry 0.130 0.742Acenaphthene 1 12/08/22 23:15 V27547JMV
<0.118 mg/Kg - dry 0.118 0.742Acenaphthylene 1 12/08/22 23:15 V27547JMV
<0.170 mg/Kg - dry 0.170 0.742Aniline 1 12/08/22 23:15 V27547JMV
<0.160 mg/Kg - dry 0.160 0.742Anthracene 1 12/08/22 23:15 V27547JMV
<0.156 mg/Kg - dry 0.156 0.742Benzo(a)anthracene 1 12/08/22 23:15 V27547JMV
<0.165 mg/Kg - dry 0.165 0.742
Benzo(a)pyrene 1 12/08/22 23:15 V27547JMV
<0.164 mg/Kg - dry 0.164 0.742Benzo(b)fluoranthene 1 12/08/22 23:15 V27547JMV
<0.152 mg/Kg - dry 0.152 0.742Benzo(g,h,i)perylene 1 12/08/22 23:15 V27547JMV
<0.154 mg/Kg - dry 0.154 0.742Benzo(k)fluoranthene 1 12/08/22 23:15 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 34 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.652 M mg/Kg - dry 0.652 2.25Benzoic Acid 1 12/08/22 23:15 V27547JMV
<0.118 mg/Kg - dry 0.118 0.742Benzyl alcohol 1 12/08/22 23:15 V27547JMV
<0.132 mg/Kg - dry 0.132 0.742Bis(2-Chloroethoxy)methane 1 12/08/22 23:15 V27547JMV
<0.120 mg/Kg - dry 0.120 0.742Bis(2-Chloroethyl)ether 1 12/08/22 23:15 V27547JMV
<0.152 mg/Kg - dry 0.152 0.371Bis(2-Chloroisopropyl)ether 1 12/08/22 23:15 V27547JMV
<0.134 mg/Kg - dry 0.134 0.742Bis(2-ethylhexyl)phthalate 1 12/08/22 23:15 V27547JMV
<0.122 mg/Kg - dry 0.122 0.7424-Bromophenyl phenyl ether 1 12/08/22 23:15 V27547JMV
<0.127 mg/Kg - dry 0.127 0.371Butyl benzyl phthalate 1 12/08/22 23:15 V27547JMV
<0.103 mg/Kg - dry 0.103 0.742
4-Chloro-3-methylphenol 1 12/08/22 23:15 V27547JMV
<0.125 mg/Kg - dry 0.125 0.3714-Chloroaniline 1 12/08/22 23:15 V27547JMV
<0.130 mg/Kg - dry 0.130 0.7422-Chloronaphthalene 1 12/08/22 23:15 V27547JMV
<0.110 mg/Kg - dry 0.110 0.7422-Chlorophenol 1 12/08/22 23:15 V27547JMV
<0.141 mg/Kg - dry 0.141 1.124-Chlorophenyl phenyl ether 1 12/08/22 23:15 V27547JMV
<0.159 mg/Kg - dry 0.159 0.742Chrysene 1 12/08/22 23:15 V27547JMV
<0.258 mg/Kg - dry 0.258 0.742Dibenz(a,h)anthracene 1 12/08/22 23:15 V27547JMV
<0.133 mg/Kg - dry 0.133 0.742
Dibenzofuran 1 12/08/22 23:15 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7421,2-Dichlorobenzene 1 12/08/22 23:15 V27547JMV
<0.109 mg/Kg - dry 0.109 0.7421,3-Dichlorobenzene 1 12/08/22 23:15 V27547JMV
<0.109 mg/Kg - dry 0.109 0.3711,4-Dichlorobenzene 1 12/08/22 23:15 V27547JMV
<0.165 mg/Kg - dry 0.165 0.7423,3'-Dichlorobenzidine 1 12/08/22 23:15 V27547JMV
<0.107 mg/Kg - dry 0.107 0.7422,4-Dichlorophenol 1 12/08/22 23:15 V27547JMV
<0.202 mg/Kg - dry 0.202 0.742Diethyl phthalate 1 12/08/22 23:15 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 35 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.195 mg/Kg - dry 0.195 0.742Dimethyl phthalate 1 12/08/22 23:15 V27547JMV
<0.121 mg/Kg - dry 0.121 0.3712,4-Dimethylphenol 1 12/08/22 23:15 V27547JMV
<0.120 mg/Kg - dry 0.120 0.742Di-n-butyl phthalate 1 12/08/22 23:15 V27547JMV
<0.269 mg/Kg - dry 0.269 1.694,6-Dinitro-2-methylphenol 1 12/08/22 23:15 V27547JMV
<0.584 mg/Kg - dry 0.584 1.692,4-Dinitrophenol 1 12/08/22 23:15 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7422,4-Dinitrotoluene 1 12/08/22 23:15 V27547JMV
<0.121 mg/Kg - dry 0.121 0.7422,6-Dinitrotoluene 1 12/08/22 23:15 V27547JMV
<0.160 mg/Kg - dry 0.160 0.371Di-n-Octyl Phthalate 1 12/08/22 23:15 V27547JMV
<0.138 mg/Kg - dry 0.138 0.742
Fluoranthene 1 12/08/22 23:15 V27547JMV
<0.143 mg/Kg - dry 0.143 0.742Fluorene 1 12/08/22 23:15 V27547JMV
<0.119 mg/Kg - dry 0.119 0.742Hexachlorobenzene 1 12/08/22 23:15 V27547JMV
<0.109 mg/Kg - dry 0.109 0.742Hexachlorobutadiene 1 12/08/22 23:15 V27547JMV
<0.176 mg/Kg - dry 0.176 0.742Hexachlorocyclopentadiene 1 12/08/22 23:15 V27547JMV
<0.089 mg/Kg - dry 0.089 0.742Hexachloroethane 1 12/08/22 23:15 V27547JMV
<0.201 mg/Kg - dry 0.201 0.742Indeno(1,2,3-cd)pyrene 1 12/08/22 23:15 V27547JMV
<0.214 mg/Kg - dry 0.214 0.742
Isophorone 1 12/08/22 23:15 V27547JMV
<0.119 mg/Kg - dry 0.119 0.7421-Methylnaphthalene 1 12/08/22 23:15 V27547JMV
<0.112 mg/Kg - dry 0.112 0.7422-Methylnaphthalene 1 12/08/22 23:15 V27547JMV
<0.109 mg/Kg - dry 0.109 0.7422-Methylphenol 1 12/08/22 23:15 V27547JMV
<0.095 mg/Kg - dry 0.095 0.7423&4 Methylphenol 1 12/08/22 23:15 V27547JMV
<0.161 mg/Kg - dry 0.161 0.742Naphthalene 1 12/08/22 23:15 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7422-Nitroaniline 1 12/08/22 23:15 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 36 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.134 mg/Kg - dry 0.134 0.7423-Nitroaniline 1 12/08/22 23:15 V27547JMV
<0.104 mg/Kg - dry 0.104 0.3714-Nitroaniline 1 12/08/22 23:15 V27547JMV
<0.130 mg/Kg - dry 0.130 0.371Nitrobenzene 1 12/08/22 23:15 V27547JMV
<0.099 mg/Kg - dry 0.099 0.7422-Nitrophenol 1 12/08/22 23:15 V27547JMV
<0.131 mg/Kg - dry 0.131 0.7424-Nitrophenol 1 12/08/22 23:15 V27547JMV
<0.295 mg/Kg - dry 0.295 0.742N-Nitrosodimethylamine 1 12/08/22 23:15 V27547JMV
<0.203 mg/Kg - dry 0.203 0.742N-Nitrosodiphenylamine 1 12/08/22 23:15 V27547JMV
<0.132 mg/Kg - dry 0.132 0.742N-Nitroso-di-n-propylamine 1 12/08/22 23:15 V27547JMV
<0.390 mg/Kg - dry 0.390 1.12
Pentachlorophenol 1 12/08/22 23:15 V27547JMV
<0.233 mg/Kg - dry 0.233 0.742Phenanthrene 1 12/08/22 23:15 V27547JMV
<0.125 mg/Kg - dry 0.125 0.742Phenol 1 12/08/22 23:15 V27547JMV
<0.150 mg/Kg - dry 0.150 0.742Pyrene 1 12/08/22 23:15 V27547JMV
<0.089 mg/Kg - dry 0.089 0.371Pyridine 1 12/08/22 23:15 V27547JMV
<0.120 mg/Kg - dry 0.120 0.7421,2,4-Trichlorobenzene 1 12/08/22 23:15 V27547JMV
<0.108 mg/Kg - dry 0.108 0.7422,4,5-Trichlorophenol 1 12/08/22 23:15 V27547JMV
<0.108 mg/Kg - dry 0.108 0.742
2,4,6-Trichlorophenol 1 12/08/22 23:15 V27547JMV
8270ESurrogate: Phenol-d5 64.1 Limits: 34-121%12/08/22 23:151 JMV
Surrogate: 2-Fluorobiphenyl 80.8 Limits: 44-115%12/08/22 23:151 JMV V27547
Surrogate: 2-Fluorophenol 66.8 Limits: 35-115%12/08/22 23:151 JMV V27547
Surrogate: Nitrobenzene-d5 70.7 Limits: 37-122%12/08/22 23:151 JMV V27547
Surrogate: 4-Terphenyl-d14 102 Limits: 54-127%12/08/22 23:151 JMV V27547
Surrogate: 2,4,6-Tribromophenol 86.5 Limits: 39-132%12/08/22 23:151 JMV V27547
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 37 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.37 mg/Kg - dry 1.37 9.00Aliphatic C5-C8 (Adjusted)100 12/05/22 12:28
<5.13 mg/Kg - dry 5.13 9.00Aliphatics C9-C12 (Adjusted)100 12/05/22 12:28
5.57 J mg/Kg - dry 0.701 9.00Aromatic C9-C10 (Adjusted)100 12/05/22 12:28
26.2 J mg/Kg - dry 16.0 56.1Aromatic C11-C22 (Adjusted)1 12/08/22 15:19
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V27432 12/07/22 11:45
<10.3 mg/Kg - dry 10.3 56.1Aliphatic C9-C18 1 12/08/22 15:19 V27568JLK
<13.7 mg/Kg - dry 13.7 56.1Aliphatic C19-C36 1 12/08/22 15:19 V27568JLK
26.2 J mg/Kg - dry 16.0 56.1Aromatic C11-C22 1 12/08/22 15:19 V27568JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 117 Limits: 40-140%12/08/22 15:191 JLK
MADEP-EPHSurrogate: Chlorooctadecane 82.5 Limits: 40-140%12/08/22 15:191 JLK
MADEP-EPHSurrogate: OTP Surrogate 95.0 Limits: 40-140%12/08/22 15:191 JLK
Surrogate: 2-Fluorobiphenyl 116 Limits: 40-140%12/08/22 15:191 JLK V27568
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
<1.37 mg/Kg - dry 1.37 9.00Aliphatic C5-C8 100 12/05/22 12:28 V27228TBL
<5.13 mg/Kg - dry 5.13 9.00Aliphatic C9-C12 100 12/05/22 12:28 V27228TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 38 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:NE-10'
94671 Matrix:
11/30/2022 16:15
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
5.57 J mg/Kg - dry 0.701 9.00Aromatic C9-C10 100 12/05/22 12:28 V27228TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)88.7 Limits: 70-130%12/05/22 12:28100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)100 Limits: 70-130%12/05/22 12:28100 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 39 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
9.05 %Moisture 1 12/05/22 10:32 SW-DRYWTAMB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 40 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.659 mg/Kg - dry 0.659 5.50Acetone 500 12/05/22 17:12 V27300TBL
<0.333 mg/Kg - dry 0.333 5.50Acrolein 500 12/05/22 17:12 V27300TBL
<0.206 mg/Kg - dry 0.206 5.50Acrylonitrile 500 12/05/22 17:12 V27300TBL
<0.159 mg/Kg - dry 0.159 1.37Benzene 500 12/05/22 17:12 V27300TBL
<0.137 mg/Kg - dry 0.137 1.37Bromobenzene 500 12/05/22 17:12 V27300TBL
<0.219 mg/Kg - dry 0.219 1.37Bromochloromethane 500 12/05/22 17:12 V27300TBL
<0.327 mg/Kg - dry 0.327 1.37Bromodichloromethane 500 12/05/22 17:12 V27300TBL
<0.278 mg/Kg - dry 0.278 1.37Bromoform 500 12/05/22 17:12 V27300TBL
<0.500 mg/Kg - dry 0.500 2.75
Bromomethane 500 12/05/22 17:12 V27300TBL
4.68 mg/Kg - dry 0.135 1.37n-Butylbenzene 500 12/05/22 17:12 V27300TBL
1.96 mg/Kg - dry 0.153 1.37sec-Butyl benzene 500 12/05/22 17:12 V27300TBL
<0.137 mg/Kg - dry 0.137 1.37tert-Butyl benzene 500 12/05/22 17:12 V27300TBL
<0.175 mg/Kg - dry 0.175 1.37Carbon Disulfide 500 12/05/22 17:12 V27300TBL
<0.434 mg/Kg - dry 0.434 1.37Carbon Tetrachloride 500 12/05/22 17:12 V27300TBL
<0.184 mg/Kg - dry 0.184 1.37Chlorobenzene 500 12/05/22 17:12 V27300TBL
<0.245 mg/Kg - dry 0.245 1.37
Chlorodibromomethane 500 12/05/22 17:12 V27300TBL
<0.245 mg/Kg - dry 0.245 2.75Chloroethane 500 12/05/22 17:12 V27300TBL
<0.289 mg/Kg - dry 0.289 1.37Chloroform 500 12/05/22 17:12 V27300TBL
<0.173 mg/Kg - dry 0.173 2.75Chloromethane 500 12/05/22 17:12 V27300TBL
<0.140 mg/Kg - dry 0.140 1.372-Chlorotoluene 500 12/05/22 17:12 V27300TBL
<0.107 mg/Kg - dry 0.107 1.374-Chlorotoluene 500 12/05/22 17:12 V27300TBL
<0.201 mg/Kg - dry 0.201 1.37Di-Isopropyl Ether (DIPE)500 12/05/22 17:12 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 41 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.120 mg/Kg - dry 0.120 2.751,2-Dibromo-3-Chloropropane 500 12/05/22 17:12 V27300TBL
<0.162 mg/Kg - dry 0.162 1.371,2-Dibromoethane 500 12/05/22 17:12 V27300TBL
<0.272 mg/Kg - dry 0.272 1.37Dibromomethane 500 12/05/22 17:12 V27300TBL
<0.085 mg/Kg - dry 0.085 1.371,2-Dichlorobenzene 500 12/05/22 17:12 V27300TBL
<0.104 mg/Kg - dry 0.104 1.371,3-Dichlorobenzene 500 12/05/22 17:12 V27300TBL
<0.164 mg/Kg - dry 0.164 1.371,4-Dichlorobenzene 500 12/05/22 17:12 V27300TBL
<0.362 mg/Kg - dry 0.362 2.75Dichlorodifluoromethane 500 12/05/22 17:12 V27300TBL
<0.225 mg/Kg - dry 0.225 1.371,1-Dichloroethane 500 12/05/22 17:12 V27300TBL
<0.379 mg/Kg - dry 0.379 1.37
1,2-Dichloroethane 500 12/05/22 17:12 V27300TBL
<0.201 mg/Kg - dry 0.201 1.371,1-Dichloroethene 500 12/05/22 17:12 V27300TBL
<0.217 mg/Kg - dry 0.217 1.37cis-1,2-Dichloroethene 500 12/05/22 17:12 V27300TBL
<0.289 mg/Kg - dry 0.289 1.37trans-1,2-Dichloroethene 500 12/05/22 17:12 V27300TBL
<0.120 mg/Kg - dry 0.120 1.371,2-Dichloropropane 500 12/05/22 17:12 V27300TBL
<0.151 mg/Kg - dry 0.151 1.371,3-Dichloropropane 500 12/05/22 17:12 V27300TBL
<0.349 mg/Kg - dry 0.349 1.372,2-Dichloropropane 500 12/05/22 17:12 V27300TBL
<0.208 mg/Kg - dry 0.208 1.37
1,1-Dichloropropene 500 12/05/22 17:12 V27300TBL
<0.148 mg/Kg - dry 0.148 1.37cis-1,3-Dichloropropene 500 12/05/22 17:12 V27300TBL
<0.219 mg/Kg - dry 0.219 1.37trans-1,3-Dichloropropene 500 12/05/22 17:12 V27300TBL
18.9 mg/Kg - dry 0.159 1.37Ethylbenzene 500 12/05/22 17:12 V27300TBL
<0.228 mg/Kg - dry 0.228 27.5Ethyl Tertiary Butyl Ether (ETBE)500 12/05/22 17:12 V27300TBL
<0.217 mg/Kg - dry 0.217 2.75Hexachlorobutadiene 500 12/05/22 17:12 V27300TBL
0.888 J mg/Kg - dry 0.181 2.75n-Hexane 500 12/05/22 17:12 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 42 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.170 mg/Kg - dry 0.170 5.502-Hexanone 500 12/05/22 17:12 V27300TBL
4.55 mg/Kg - dry 0.126 1.37Isopropylbenzene 500 12/05/22 17:12 V27300TBL
1.67 mg/Kg - dry 0.357 1.374-Isopropyl toluene 500 12/05/22 17:12 V27300TBL
<0.179 mg/Kg - dry 0.179 5.50Methyl Ethyl Ketone (MEK)500 12/05/22 17:12 V27300TBL
<0.170 mg/Kg - dry 0.170 1.37Methyl tert-butyl ether (MTBE)500 12/05/22 17:12 V27300TBL
<4.12 mg/Kg - dry 4.12 5.504-Methyl-2-Pentanone 500 12/05/22 17:12 V27300TBL
<0.404 mg/Kg - dry 0.404 1.37Methylene Chloride 500 12/05/22 17:12 V27300TBL
31.1 mg/Kg - dry 0.272 2.75Naphthalene 500 12/05/22 17:12 V27300TBL
15.3 mg/Kg - dry 0.148 1.37
n-Propylbenzene 500 12/05/22 17:12 V27300TBL
<0.390 mg/Kg - dry 0.390 1.37Styrene 500 12/05/22 17:12 V27300TBL
<0.289 mg/Kg - dry 0.289 1.371,1,1,2-Tetrachloroethane 500 12/05/22 17:12 V27300TBL
<0.087 mg/Kg - dry 0.087 1.371,1,2,2-Tetrachloroethane 500 12/05/22 17:12 V27300TBL
<0.247 mg/Kg - dry 0.247 1.37Tetrachloroethene 500 12/05/22 17:12 V27300TBL
0.329 J mg/Kg - dry 0.181 1.37Toluene 500 12/05/22 17:12 V27300TBL
<0.148 mg/Kg - dry 0.148 2.751,2,3-Trichlorobenzene 500 12/05/22 17:12 V27300TBL
<0.175 mg/Kg - dry 0.175 2.75
1,2,4-Trichlorobenzene 500 12/05/22 17:12 V27300TBL
<0.395 mg/Kg - dry 0.395 1.371,1,1-Trichloroethane 500 12/05/22 17:12 V27300TBL
<0.129 mg/Kg - dry 0.129 1.371,1,2-Trichloroethane 500 12/05/22 17:12 V27300TBL
<0.252 mg/Kg - dry 0.252 1.37Trichloroethene 500 12/05/22 17:12 V27300TBL
<0.575 mg/Kg - dry 0.575 2.75Trichlorofluoromethane 500 12/05/22 17:12 V27300TBL
<0.197 mg/Kg - dry 0.197 1.371,2,3-Trichloropropane 500 12/05/22 17:12 V27300TBL
56.3 mg/Kg - dry 0.135 1.371,2,4-Trimethylbenzene 500 12/05/22 17:12 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 43 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
3.86 mg/Kg - dry 0.148 1.371,3,5-Trimethylbenzene 500 12/05/22 17:12 V27300TBL
<0.126 mg/Kg - dry 0.126 2.75Vinyl Acetate 500 12/05/22 17:12 V27300TBL
<0.131 mg/Kg - dry 0.131 2.75Vinyl Chloride 500 12/05/22 17:12 V27300TBL
2.56 mg/Kg - dry 0.137 1.37o-Xylene 500 12/05/22 17:12 V27300TBL
14.5 mg/Kg - dry 0.346 2.75m,p-Xylene 500 12/05/22 17:12 V27300TBL
17.0 mg/Kg - dry 0.137 1.37Xylene (Total)500 12/05/22 17:12 V27300KCC
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%12/05/22 17:12500 TBL V27300
Surrogate: Dibromofluoromethane 98.8 Limits: 70-130%12/05/22 17:12500 TBL V27300
Surrogate: Toluene-d8 93.2 Limits: 76-129%12/05/22 17:12500 TBL V27300
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.127 mg/Kg - dry 0.127 0.725Acenaphthene 1 12/08/22 23:37 V27547JMV
<0.115 mg/Kg - dry 0.115 0.725Acenaphthylene 1 12/08/22 23:37 V27547JMV
<0.167 mg/Kg - dry 0.167 0.725Aniline 1 12/08/22 23:37 V27547JMV
<0.157 mg/Kg - dry 0.157 0.725Anthracene 1 12/08/22 23:37 V27547JMV
<0.152 mg/Kg - dry 0.152 0.725Benzo(a)anthracene 1 12/08/22 23:37 V27547JMV
<0.161 mg/Kg - dry 0.161 0.725
Benzo(a)pyrene 1 12/08/22 23:37 V27547JMV
<0.160 mg/Kg - dry 0.160 0.725Benzo(b)fluoranthene 1 12/08/22 23:37 V27547JMV
<0.149 mg/Kg - dry 0.149 0.725Benzo(g,h,i)perylene 1 12/08/22 23:37 V27547JMV
<0.150 mg/Kg - dry 0.150 0.725Benzo(k)fluoranthene 1 12/08/22 23:37 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 44 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.637 M mg/Kg - dry 0.637 2.20Benzoic Acid 1 12/08/22 23:37 V27547JMV
<0.115 mg/Kg - dry 0.115 0.725Benzyl alcohol 1 12/08/22 23:37 V27547JMV
<0.129 mg/Kg - dry 0.129 0.725Bis(2-Chloroethoxy)methane 1 12/08/22 23:37 V27547JMV
<0.117 mg/Kg - dry 0.117 0.725Bis(2-Chloroethyl)ether 1 12/08/22 23:37 V27547JMV
<0.149 mg/Kg - dry 0.149 0.362Bis(2-Chloroisopropyl)ether 1 12/08/22 23:37 V27547JMV
<0.131 mg/Kg - dry 0.131 0.725Bis(2-ethylhexyl)phthalate 1 12/08/22 23:37 V27547JMV
<0.119 mg/Kg - dry 0.119 0.7254-Bromophenyl phenyl ether 1 12/08/22 23:37 V27547JMV
<0.124 mg/Kg - dry 0.124 0.362Butyl benzyl phthalate 1 12/08/22 23:37 V27547JMV
<0.101 mg/Kg - dry 0.101 0.725
4-Chloro-3-methylphenol 1 12/08/22 23:37 V27547JMV
<0.123 mg/Kg - dry 0.123 0.3624-Chloroaniline 1 12/08/22 23:37 V27547JMV
<0.127 mg/Kg - dry 0.127 0.7252-Chloronaphthalene 1 12/08/22 23:37 V27547JMV
<0.107 mg/Kg - dry 0.107 0.7252-Chlorophenol 1 12/08/22 23:37 V27547JMV
<0.138 mg/Kg - dry 0.138 1.104-Chlorophenyl phenyl ether 1 12/08/22 23:37 V27547JMV
<0.156 mg/Kg - dry 0.156 0.725Chrysene 1 12/08/22 23:37 V27547JMV
<0.252 mg/Kg - dry 0.252 0.725Dibenz(a,h)anthracene 1 12/08/22 23:37 V27547JMV
<0.130 mg/Kg - dry 0.130 0.725
Dibenzofuran 1 12/08/22 23:37 V27547JMV
<0.103 mg/Kg - dry 0.103 0.7251,2-Dichlorobenzene 1 12/08/22 23:37 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7251,3-Dichlorobenzene 1 12/08/22 23:37 V27547JMV
<0.107 mg/Kg - dry 0.107 0.3621,4-Dichlorobenzene 1 12/08/22 23:37 V27547JMV
<0.161 mg/Kg - dry 0.161 0.7253,3'-Dichlorobenzidine 1 12/08/22 23:37 V27547JMV
<0.105 mg/Kg - dry 0.105 0.7252,4-Dichlorophenol 1 12/08/22 23:37 V27547JMV
<0.197 mg/Kg - dry 0.197 0.725Diethyl phthalate 1 12/08/22 23:37 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 45 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.191 mg/Kg - dry 0.191 0.725Dimethyl phthalate 1 12/08/22 23:37 V27547JMV
<0.118 mg/Kg - dry 0.118 0.3622,4-Dimethylphenol 1 12/08/22 23:37 V27547JMV
<0.117 mg/Kg - dry 0.117 0.725Di-n-butyl phthalate 1 12/08/22 23:37 V27547JMV
<0.263 mg/Kg - dry 0.263 1.654,6-Dinitro-2-methylphenol 1 12/08/22 23:37 V27547JMV
<0.571 mg/Kg - dry 0.571 1.652,4-Dinitrophenol 1 12/08/22 23:37 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7252,4-Dinitrotoluene 1 12/08/22 23:37 V27547JMV
<0.118 mg/Kg - dry 0.118 0.7252,6-Dinitrotoluene 1 12/08/22 23:37 V27547JMV
<0.157 mg/Kg - dry 0.157 0.362Di-n-Octyl Phthalate 1 12/08/22 23:37 V27547JMV
<0.135 mg/Kg - dry 0.135 0.725
Fluoranthene 1 12/08/22 23:37 V27547JMV
1.46 mg/Kg - dry 0.140 0.725Fluorene 1 12/08/22 23:37 V27547JMV
<0.116 mg/Kg - dry 0.116 0.725Hexachlorobenzene 1 12/08/22 23:37 V27547JMV
<0.107 mg/Kg - dry 0.107 0.725Hexachlorobutadiene 1 12/08/22 23:37 V27547JMV
<0.172 mg/Kg - dry 0.172 0.725Hexachlorocyclopentadiene 1 12/08/22 23:37 V27547JMV
<0.087 mg/Kg - dry 0.087 0.725Hexachloroethane 1 12/08/22 23:37 V27547JMV
<0.196 mg/Kg - dry 0.196 0.725Indeno(1,2,3-cd)pyrene 1 12/08/22 23:37 V27547JMV
<0.210 mg/Kg - dry 0.210 0.725
Isophorone 1 12/08/22 23:37 V27547JMV
11.2 mg/Kg - dry 0.582 3.631-Methylnaphthalene 5 12/09/22 11:34 V27547JMV
24.2 mg/Kg - dry 0.549 3.632-Methylnaphthalene 5 12/09/22 11:34 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7252-Methylphenol 1 12/08/22 23:37 V27547JMV
<0.093 mg/Kg - dry 0.093 0.7253&4 Methylphenol 1 12/08/22 23:37 V27547JMV
24.8 mg/Kg - dry 0.791 3.63Naphthalene 5 12/09/22 11:34 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7252-Nitroaniline 1 12/08/22 23:37 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 46 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.131 mg/Kg - dry 0.131 0.7253-Nitroaniline 1 12/08/22 23:37 V27547JMV
<0.102 mg/Kg - dry 0.102 0.3624-Nitroaniline 1 12/08/22 23:37 V27547JMV
<0.127 mg/Kg - dry 0.127 0.362Nitrobenzene 1 12/08/22 23:37 V27547JMV
<0.097 mg/Kg - dry 0.097 0.7252-Nitrophenol 1 12/08/22 23:37 V27547JMV
<0.128 mg/Kg - dry 0.128 0.7254-Nitrophenol 1 12/08/22 23:37 V27547JMV
<0.289 mg/Kg - dry 0.289 0.725N-Nitrosodimethylamine 1 12/08/22 23:37 V27547JMV
<0.199 mg/Kg - dry 0.199 0.725N-Nitrosodiphenylamine 1 12/08/22 23:37 V27547JMV
<0.129 mg/Kg - dry 0.129 0.725N-Nitroso-di-n-propylamine 1 12/08/22 23:37 V27547JMV
<0.381 mg/Kg - dry 0.381 1.10
Pentachlorophenol 1 12/08/22 23:37 V27547JMV
2.57 mg/Kg - dry 0.228 0.725Phenanthrene 1 12/08/22 23:37 V27547JMV
<0.123 mg/Kg - dry 0.123 0.725Phenol 1 12/08/22 23:37 V27547JMV
0.531 J mg/Kg - dry 0.147 0.725Pyrene 1 12/08/22 23:37 V27547JMV
<0.087 mg/Kg - dry 0.087 0.362Pyridine 1 12/08/22 23:37 V27547JMV
<0.117 mg/Kg - dry 0.117 0.7251,2,4-Trichlorobenzene 1 12/08/22 23:37 V27547JMV
<0.105 mg/Kg - dry 0.105 0.7252,4,5-Trichlorophenol 1 12/08/22 23:37 V27547JMV
<0.106 mg/Kg - dry 0.106 0.725
2,4,6-Trichlorophenol 1 12/08/22 23:37 V27547JMV
8270ESurrogate: Phenol-d5 65.2 Limits: 34-121%12/08/22 23:371 JMV
Surrogate: 2-Fluorobiphenyl 83.2 Limits: 44-115%12/08/22 23:371 JMV V27547
Surrogate: 2-Fluorophenol 67.6 Limits: 35-115%12/08/22 23:371 JMV V27547
Surrogate: Nitrobenzene-d5 76.0 Limits: 37-122%12/08/22 23:371 JMV V27547
Surrogate: 4-Terphenyl-d14 104 Limits: 54-127%12/08/22 23:371 JMV V27547
Surrogate: 2,4,6-Tribromophenol 84.4 Limits: 39-132%12/08/22 23:371 JMV V27547
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 47 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
387 J mg/Kg - dry 66.8 440Aliphatic C5-C8 (Adjusted)500 12/05/22 17:12
<251 mg/Kg - dry 251 440Aliphatics C9-C12 (Adjusted)5000 12/06/22 08:58
5940 mg/Kg - dry 34.3 440Aromatic C9-C10 (Adjusted)5000 12/06/22 08:58
1590 J mg/Kg - dry 15.6 55.1Aromatic C11-C22 (Adjusted)1 12/08/22 15:55
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V27432 12/07/22 11:45
1740 mg/Kg - dry 10.1 55.1Aliphatic C9-C18 1 12/08/22 15:55 V27568JLK
415 mg/Kg - dry 13.4 55.1Aliphatic C19-C36 1 12/08/22 15:55 V27568JLK
1630 mg/Kg - dry 15.6 55.1Aromatic C11-C22 1 12/08/22 15:55 V27568JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 255 *Limits: 40-140%12/08/22 15:551 JLK
MADEP-EPHSurrogate: Chlorooctadecane 103 Limits: 40-140%12/08/22 15:551 JLK
MADEP-EPHSurrogate: OTP Surrogate 88.0 Limits: 40-140%12/08/22 15:551 JLK
Surrogate: 2-Fluorobiphenyl 147 *Limits: 40-140%12/08/22 15:551 JLK V27568
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
387 J mg/Kg - dry 66.8 440Aliphatic C5-C8 5000 12/06/22 08:58 V27228TBL
2120 mg/Kg - dry 251 440Aliphatic C9-C12 5000 12/06/22 08:58 V27228TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 48 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:SE-10'
94672 Matrix:
11/30/2022 16:10
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
5940 mg/Kg - dry 34.3 440Aromatic C9-C10 5000 12/06/22 08:58 V27228TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)107 Limits: 70-130%12/06/22 08:585000 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)124 Limits: 70-130%12/06/22 08:585000 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 49 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
16.6 %Moisture 1 12/05/22 10:32 SW-DRYWTAMB
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 50 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.719 mg/Kg - dry 0.719 6.00Acetone 500 12/05/22 18:35 V27300TBL
<0.363 mg/Kg - dry 0.363 6.00Acrolein 500 12/05/22 18:35 V27300TBL
<0.225 mg/Kg - dry 0.225 6.00Acrylonitrile 500 12/05/22 18:35 V27300TBL
<0.173 mg/Kg - dry 0.173 1.50Benzene 500 12/05/22 18:35 V27300TBL
<0.149 mg/Kg - dry 0.149 1.50Bromobenzene 500 12/05/22 18:35 V27300TBL
<0.239 mg/Kg - dry 0.239 1.50Bromochloromethane 500 12/05/22 18:35 V27300TBL
<0.357 mg/Kg - dry 0.357 1.50Bromodichloromethane 500 12/05/22 18:35 V27300TBL
<0.303 mg/Kg - dry 0.303 1.50Bromoform 500 12/05/22 18:35 V27300TBL
<0.545 mg/Kg - dry 0.545 3.00
Bromomethane 500 12/05/22 18:35 V27300TBL
2.07 mg/Kg - dry 0.147 1.50n-Butylbenzene 500 12/05/22 18:35 V27300TBL
1.09 J mg/Kg - dry 0.167 1.50sec-Butyl benzene 500 12/05/22 18:35 V27300TBL
<0.149 mg/Kg - dry 0.149 1.50tert-Butyl benzene 500 12/05/22 18:35 V27300TBL
<0.191 mg/Kg - dry 0.191 1.50Carbon Disulfide 500 12/05/22 18:35 V27300TBL
<0.473 mg/Kg - dry 0.473 1.50Carbon Tetrachloride 500 12/05/22 18:35 V27300TBL
<0.201 mg/Kg - dry 0.201 1.50Chlorobenzene 500 12/05/22 18:35 V27300TBL
<0.267 mg/Kg - dry 0.267 1.50
Chlorodibromomethane 500 12/05/22 18:35 V27300TBL
<0.267 mg/Kg - dry 0.267 3.00Chloroethane 500 12/05/22 18:35 V27300TBL
<0.315 mg/Kg - dry 0.315 1.50Chloroform 500 12/05/22 18:35 V27300TBL
<0.189 mg/Kg - dry 0.189 3.00Chloromethane 500 12/05/22 18:35 V27300TBL
<0.153 mg/Kg - dry 0.153 1.502-Chlorotoluene 500 12/05/22 18:35 V27300TBL
<0.116 mg/Kg - dry 0.116 1.504-Chlorotoluene 500 12/05/22 18:35 V27300TBL
<0.219 mg/Kg - dry 0.219 1.50Di-Isopropyl Ether (DIPE)500 12/05/22 18:35 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 51 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.131 mg/Kg - dry 0.131 3.001,2-Dibromo-3-Chloropropane 500 12/05/22 18:35 V27300TBL
<0.177 mg/Kg - dry 0.177 1.501,2-Dibromoethane 500 12/05/22 18:35 V27300TBL
<0.297 mg/Kg - dry 0.297 1.50Dibromomethane 500 12/05/22 18:35 V27300TBL
<0.092 mg/Kg - dry 0.092 1.501,2-Dichlorobenzene 500 12/05/22 18:35 V27300TBL
<0.113 mg/Kg - dry 0.113 1.501,3-Dichlorobenzene 500 12/05/22 18:35 V27300TBL
<0.179 mg/Kg - dry 0.179 1.501,4-Dichlorobenzene 500 12/05/22 18:35 V27300TBL
<0.395 mg/Kg - dry 0.395 3.00Dichlorodifluoromethane 500 12/05/22 18:35 V27300TBL
<0.245 mg/Kg - dry 0.245 1.501,1-Dichloroethane 500 12/05/22 18:35 V27300TBL
<0.413 mg/Kg - dry 0.413 1.50
1,2-Dichloroethane 500 12/05/22 18:35 V27300TBL
<0.219 mg/Kg - dry 0.219 1.501,1-Dichloroethene 500 12/05/22 18:35 V27300TBL
<0.237 mg/Kg - dry 0.237 1.50cis-1,2-Dichloroethene 500 12/05/22 18:35 V27300TBL
<0.315 mg/Kg - dry 0.315 1.50trans-1,2-Dichloroethene 500 12/05/22 18:35 V27300TBL
<0.131 mg/Kg - dry 0.131 1.501,2-Dichloropropane 500 12/05/22 18:35 V27300TBL
<0.165 mg/Kg - dry 0.165 1.501,3-Dichloropropane 500 12/05/22 18:35 V27300TBL
<0.381 mg/Kg - dry 0.381 1.502,2-Dichloropropane 500 12/05/22 18:35 V27300TBL
<0.227 mg/Kg - dry 0.227 1.50
1,1-Dichloropropene 500 12/05/22 18:35 V27300TBL
<0.161 mg/Kg - dry 0.161 1.50cis-1,3-Dichloropropene 500 12/05/22 18:35 V27300TBL
<0.239 mg/Kg - dry 0.239 1.50trans-1,3-Dichloropropene 500 12/05/22 18:35 V27300TBL
27.3 mg/Kg - dry 0.173 1.50Ethylbenzene 500 12/05/22 18:35 V27300TBL
<0.249 mg/Kg - dry 0.249 30.0Ethyl Tertiary Butyl Ether (ETBE)500 12/05/22 18:35 V27300TBL
<0.237 mg/Kg - dry 0.237 3.00Hexachlorobutadiene 500 12/05/22 18:35 V27300TBL
5.14 mg/Kg - dry 0.197 3.00n-Hexane 500 12/05/22 18:35 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 52 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
<0.185 mg/Kg - dry 0.185 6.002-Hexanone 500 12/05/22 18:35 V27300TBL
3.45 mg/Kg - dry 0.137 1.50Isopropylbenzene 500 12/05/22 18:35 V27300TBL
0.540 J mg/Kg - dry 0.389 1.504-Isopropyl toluene 500 12/05/22 18:35 V27300TBL
<0.195 mg/Kg - dry 0.195 6.00Methyl Ethyl Ketone (MEK)500 12/05/22 18:35 V27300TBL
<0.185 mg/Kg - dry 0.185 1.50Methyl tert-butyl ether (MTBE)500 12/05/22 18:35 V27300TBL
<4.50 mg/Kg - dry 4.50 6.004-Methyl-2-Pentanone 500 12/05/22 18:35 V27300TBL
<0.441 mg/Kg - dry 0.441 1.50Methylene Chloride 500 12/05/22 18:35 V27300TBL
12.9 mg/Kg - dry 0.297 3.00Naphthalene 500 12/05/22 18:35 V27300TBL
10.9 mg/Kg - dry 0.161 1.50
n-Propylbenzene 500 12/05/22 18:35 V27300TBL
<0.425 mg/Kg - dry 0.425 1.50Styrene 500 12/05/22 18:35 V27300TBL
<0.315 mg/Kg - dry 0.315 1.501,1,1,2-Tetrachloroethane 500 12/05/22 18:35 V27300TBL
<0.095 mg/Kg - dry 0.095 1.501,1,2,2-Tetrachloroethane 500 12/05/22 18:35 V27300TBL
<0.269 mg/Kg - dry 0.269 1.50Tetrachloroethene 500 12/05/22 18:35 V27300TBL
4.74 mg/Kg - dry 0.197 1.50Toluene 500 12/05/22 18:35 V27300TBL
<0.161 mg/Kg - dry 0.161 3.001,2,3-Trichlorobenzene 500 12/05/22 18:35 V27300TBL
<0.191 mg/Kg - dry 0.191 3.00
1,2,4-Trichlorobenzene 500 12/05/22 18:35 V27300TBL
<0.431 mg/Kg - dry 0.431 1.501,1,1-Trichloroethane 500 12/05/22 18:35 V27300TBL
<0.141 mg/Kg - dry 0.141 1.501,1,2-Trichloroethane 500 12/05/22 18:35 V27300TBL
<0.275 mg/Kg - dry 0.275 1.50Trichloroethene 500 12/05/22 18:35 V27300TBL
<0.627 mg/Kg - dry 0.627 3.00Trichlorofluoromethane 500 12/05/22 18:35 V27300TBL
<0.215 mg/Kg - dry 0.215 1.501,2,3-Trichloropropane 500 12/05/22 18:35 V27300TBL
65.9 mg/Kg - dry 0.147 1.501,2,4-Trimethylbenzene 500 12/05/22 18:35 V27300TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 53 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035
8260D Prep Batch(es):V27298 12/05/22 08:00
20.3 mg/Kg - dry 0.161 1.501,3,5-Trimethylbenzene 500 12/05/22 18:35 V27300TBL
<0.137 mg/Kg - dry 0.137 3.00Vinyl Acetate 500 12/05/22 18:35 V27300TBL
<0.143 mg/Kg - dry 0.143 3.00Vinyl Chloride 500 12/05/22 18:35 V27300TBL
38.5 mg/Kg - dry 0.149 1.50o-Xylene 500 12/05/22 18:35 V27300TBL
105 mg/Kg - dry 0.377 3.00m,p-Xylene 500 12/05/22 18:35 V27300TBL
143 mg/Kg - dry 0.149 1.50Xylene (Total)500 12/05/22 18:35 V27300KCC
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%12/05/22 18:35500 TBL V27300
Surrogate: Dibromofluoromethane 99.5 Limits: 70-130%12/05/22 18:35500 TBL V27300
Surrogate: Toluene-d8 94.8 Limits: 76-129%12/05/22 18:35500 TBL V27300
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.139 mg/Kg - dry 0.139 0.792Acenaphthene 1 12/09/22 00:22 V27547JMV
<0.125 mg/Kg - dry 0.125 0.792Acenaphthylene 1 12/09/22 00:22 V27547JMV
<0.182 mg/Kg - dry 0.182 0.792Aniline 1 12/09/22 00:22 V27547JMV
<0.171 mg/Kg - dry 0.171 0.792Anthracene 1 12/09/22 00:22 V27547JMV
<0.166 mg/Kg - dry 0.166 0.792Benzo(a)anthracene 1 12/09/22 00:22 V27547JMV
<0.176 mg/Kg - dry 0.176 0.792
Benzo(a)pyrene 1 12/09/22 00:22 V27547JMV
<0.175 mg/Kg - dry 0.175 0.792Benzo(b)fluoranthene 1 12/09/22 00:22 V27547JMV
<0.163 mg/Kg - dry 0.163 0.792Benzo(g,h,i)perylene 1 12/09/22 00:22 V27547JMV
<0.164 mg/Kg - dry 0.164 0.792Benzo(k)fluoranthene 1 12/09/22 00:22 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 54 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.695 M mg/Kg - dry 0.695 2.40Benzoic Acid 1 12/09/22 00:22 V27547JMV
<0.125 mg/Kg - dry 0.125 0.792Benzyl alcohol 1 12/09/22 00:22 V27547JMV
<0.141 mg/Kg - dry 0.141 0.792Bis(2-Chloroethoxy)methane 1 12/09/22 00:22 V27547JMV
<0.128 mg/Kg - dry 0.128 0.792Bis(2-Chloroethyl)ether 1 12/09/22 00:22 V27547JMV
<0.163 mg/Kg - dry 0.163 0.395Bis(2-Chloroisopropyl)ether 1 12/09/22 00:22 V27547JMV
<0.143 mg/Kg - dry 0.143 0.792Bis(2-ethylhexyl)phthalate 1 12/09/22 00:22 V27547JMV
<0.130 mg/Kg - dry 0.130 0.7924-Bromophenyl phenyl ether 1 12/09/22 00:22 V27547JMV
<0.135 mg/Kg - dry 0.135 0.395Butyl benzyl phthalate 1 12/09/22 00:22 V27547JMV
<0.110 mg/Kg - dry 0.110 0.792
4-Chloro-3-methylphenol 1 12/09/22 00:22 V27547JMV
<0.134 mg/Kg - dry 0.134 0.3954-Chloroaniline 1 12/09/22 00:22 V27547JMV
<0.139 mg/Kg - dry 0.139 0.7922-Chloronaphthalene 1 12/09/22 00:22 V27547JMV
<0.117 mg/Kg - dry 0.117 0.7922-Chlorophenol 1 12/09/22 00:22 V27547JMV
<0.151 mg/Kg - dry 0.151 1.204-Chlorophenyl phenyl ether 1 12/09/22 00:22 V27547JMV
<0.170 mg/Kg - dry 0.170 0.792Chrysene 1 12/09/22 00:22 V27547JMV
<0.275 mg/Kg - dry 0.275 0.792Dibenz(a,h)anthracene 1 12/09/22 00:22 V27547JMV
<0.142 mg/Kg - dry 0.142 0.792
Dibenzofuran 1 12/09/22 00:22 V27547JMV
<0.113 mg/Kg - dry 0.113 0.7921,2-Dichlorobenzene 1 12/09/22 00:22 V27547JMV
<0.116 mg/Kg - dry 0.116 0.7921,3-Dichlorobenzene 1 12/09/22 00:22 V27547JMV
<0.116 mg/Kg - dry 0.116 0.3951,4-Dichlorobenzene 1 12/09/22 00:22 V27547JMV
<0.176 mg/Kg - dry 0.176 0.7923,3'-Dichlorobenzidine 1 12/09/22 00:22 V27547JMV
<0.114 mg/Kg - dry 0.114 0.7922,4-Dichlorophenol 1 12/09/22 00:22 V27547JMV
<0.215 mg/Kg - dry 0.215 0.792Diethyl phthalate 1 12/09/22 00:22 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 55 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.208 mg/Kg - dry 0.208 0.792Dimethyl phthalate 1 12/09/22 00:22 V27547JMV
<0.129 mg/Kg - dry 0.129 0.3952,4-Dimethylphenol 1 12/09/22 00:22 V27547JMV
<0.128 mg/Kg - dry 0.128 0.792Di-n-butyl phthalate 1 12/09/22 00:22 V27547JMV
<0.287 mg/Kg - dry 0.287 1.804,6-Dinitro-2-methylphenol 1 12/09/22 00:22 V27547JMV
<0.623 mg/Kg - dry 0.623 1.802,4-Dinitrophenol 1 12/09/22 00:22 V27547JMV
<0.115 mg/Kg - dry 0.115 0.7922,4-Dinitrotoluene 1 12/09/22 00:22 V27547JMV
<0.129 mg/Kg - dry 0.129 0.7922,6-Dinitrotoluene 1 12/09/22 00:22 V27547JMV
<0.171 mg/Kg - dry 0.171 0.395Di-n-Octyl Phthalate 1 12/09/22 00:22 V27547JMV
<0.147 mg/Kg - dry 0.147 0.792
Fluoranthene 1 12/09/22 00:22 V27547JMV
0.155 J mg/Kg - dry 0.153 0.792Fluorene 1 12/09/22 00:22 V27547JMV
<0.127 mg/Kg - dry 0.127 0.792Hexachlorobenzene 1 12/09/22 00:22 V27547JMV
<0.117 mg/Kg - dry 0.117 0.792Hexachlorobutadiene 1 12/09/22 00:22 V27547JMV
<0.188 mg/Kg - dry 0.188 0.792Hexachlorocyclopentadiene 1 12/09/22 00:22 V27547JMV
<0.095 mg/Kg - dry 0.095 0.792Hexachloroethane 1 12/09/22 00:22 V27547JMV
<0.214 mg/Kg - dry 0.214 0.792Indeno(1,2,3-cd)pyrene 1 12/09/22 00:22 V27547JMV
<0.229 mg/Kg - dry 0.229 0.792
Isophorone 1 12/09/22 00:22 V27547JMV
1.79 mg/Kg - dry 0.127 0.7921-Methylnaphthalene 1 12/09/22 00:22 V27547JMV
4.12 mg/Kg - dry 0.119 0.7922-Methylnaphthalene 1 12/09/22 00:22 V27547JMV
<0.116 mg/Kg - dry 0.116 0.7922-Methylphenol 1 12/09/22 00:22 V27547JMV
<0.101 mg/Kg - dry 0.101 0.7923&4 Methylphenol 1 12/09/22 00:22 V27547JMV
4.88 mg/Kg - dry 0.172 0.792Naphthalene 1 12/09/22 00:22 V27547JMV
<0.116 mg/Kg - dry 0.116 0.7922-Nitroaniline 1 12/09/22 00:22 V27547JMV
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 56 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
3546
8270E Prep Batch(es):V27511 12/08/22 11:00
<0.143 mg/Kg - dry 0.143 0.7923-Nitroaniline 1 12/09/22 00:22 V27547JMV
<0.111 mg/Kg - dry 0.111 0.3954-Nitroaniline 1 12/09/22 00:22 V27547JMV
<0.139 mg/Kg - dry 0.139 0.395Nitrobenzene 1 12/09/22 00:22 V27547JMV
<0.106 mg/Kg - dry 0.106 0.7922-Nitrophenol 1 12/09/22 00:22 V27547JMV
<0.140 mg/Kg - dry 0.140 0.7924-Nitrophenol 1 12/09/22 00:22 V27547JMV
<0.315 mg/Kg - dry 0.315 0.792N-Nitrosodimethylamine 1 12/09/22 00:22 V27547JMV
<0.217 mg/Kg - dry 0.217 0.792N-Nitrosodiphenylamine 1 12/09/22 00:22 V27547JMV
<0.141 mg/Kg - dry 0.141 0.792N-Nitroso-di-n-propylamine 1 12/09/22 00:22 V27547JMV
<0.416 mg/Kg - dry 0.416 1.20
Pentachlorophenol 1 12/09/22 00:22 V27547JMV
<0.249 mg/Kg - dry 0.249 0.792Phenanthrene 1 12/09/22 00:22 V27547JMV
<0.134 mg/Kg - dry 0.134 0.792Phenol 1 12/09/22 00:22 V27547JMV
<0.160 mg/Kg - dry 0.160 0.792Pyrene 1 12/09/22 00:22 V27547JMV
<0.094 mg/Kg - dry 0.094 0.395Pyridine 1 12/09/22 00:22 V27547JMV
<0.128 mg/Kg - dry 0.128 0.7921,2,4-Trichlorobenzene 1 12/09/22 00:22 V27547JMV
<0.115 mg/Kg - dry 0.115 0.7922,4,5-Trichlorophenol 1 12/09/22 00:22 V27547JMV
<0.115 mg/Kg - dry 0.115 0.792
2,4,6-Trichlorophenol 1 12/09/22 00:22 V27547JMV
8270ESurrogate: Phenol-d5 69.2 Limits: 34-121%12/09/22 00:221 JMV
Surrogate: 2-Fluorobiphenyl 87.4 Limits: 44-115%12/09/22 00:221 JMV V27547
Surrogate: 2-Fluorophenol 79.0 Limits: 35-115%12/09/22 00:221 JMV V27547
Surrogate: Nitrobenzene-d5 74.9 Limits: 37-122%12/09/22 00:221 JMV V27547
Surrogate: 4-Terphenyl-d14 101 Limits: 54-127%12/09/22 00:221 JMV V27547
Surrogate: 2,4,6-Tribromophenol 83.5 Limits: 39-132%12/09/22 00:221 JMV V27547
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 57 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
245 mg/Kg - dry 14.6 95.9Aliphatic C5-C8 (Adjusted)1000 12/05/22 18:35
<54.7 mg/Kg - dry 54.7 95.9Aliphatics C9-C12 (Adjusted)1000 12/06/22 08:10
1450 mg/Kg - dry 7.48 95.9Aromatic C9-C10 (Adjusted)1000 12/06/22 08:10
82.5 J mg/Kg - dry 17.0 60.1Aromatic C11-C22 (Adjusted)1 12/08/22 16:31
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAEPH (Prep)
MADEP-EPH Prep Batch(es):V27432 12/07/22 11:45
66.2 mg/Kg - dry 11.1 60.1Aliphatic C9-C18 1 12/08/22 16:31 V27568JLK
<14.6 mg/Kg - dry 14.6 60.1Aliphatic C19-C36 1 12/08/22 16:31 V27568JLK
87.5 mg/Kg - dry 17.0 60.1Aromatic C11-C22 1 12/08/22 16:31 V27568JLK
MADEP-EPHSurrogate: 2-Bromonaphthalene 134 Limits: 40-140%12/08/22 16:311 JLK
MADEP-EPHSurrogate: Chlorooctadecane 90.0 Limits: 40-140%12/08/22 16:311 JLK
MADEP-EPHSurrogate: OTP Surrogate 92.0 Limits: 40-140%12/08/22 16:311 JLK
Surrogate: 2-Fluorobiphenyl 114 Limits: 40-140%12/08/22 16:311 JLK V27568
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
249 mg/Kg - dry 14.6 95.9Aliphatic C5-C8 1000 12/06/22 08:10 V27228TBL
536 mg/Kg - dry 54.7 95.9Aliphatic C9-C12 1000 12/06/22 08:10 V27228TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 58 of 91
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-336-0032
00087
Geological Resources, Inc.
113 West Firetower Road, Suite G
William Regenthal
Winterville
Danyale Love
Project Manager
GRI #5960 Received : 12/02/2022
New Dixie Mart #229
Report Date : 12/12/2022
Sample ID :
Lab No :
Sampled:OE-Base-17'
94673 Matrix:
11/30/2022 16:20
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27227 12/05/22 08:00
1450 mg/Kg - dry 7.48 95.9Aromatic C9-C10 1000 12/06/22 08:10 V27228TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)107 Limits: 70-130%12/06/22 08:101000 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)106 Limits: 70-130%12/06/22 08:101000 TBL
Qualifiers/
Definitions
Dilution FactorDFOutside QC Limit*
Minimum valueMEstimated valueJ
Method Quantitation LimitMQL
Page 59 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
Associated Lab Samples: 94669, 94671
LRB-V27288 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0200.002<0.002mg/KgAcetone
12/05/22 12:370.0200.001<0.001mg/KgAcrolein
12/05/22 12:370.0200.0008<0.0008mg/KgAcrylonitrile
12/05/22 12:370.0050.0006<0.0006mg/KgBenzene
12/05/22 12:370.0050.0005<0.0005mg/KgBromobenzene
12/05/22 12:370.0050.0008<0.0008mg/KgBromochloromethane
12/05/22 12:370.0050.001<0.001mg/KgBromodichloromethane
12/05/22 12:370.0050.001<0.001mg/KgBromoform
12/05/22 12:370.0100.001<0.001mg/KgBromomethane
12/05/22 12:370.0050.0005<0.0005mg/Kgn-Butylbenzene
12/05/22 12:370.0050.0006<0.0006mg/Kgsec-Butyl benzene
12/05/22 12:370.0050.0005<0.0005mg/Kgtert-Butyl benzene
12/05/22 12:370.0050.0006<0.0006mg/KgCarbon Disulfide
12/05/22 12:370.0050.001<0.001mg/KgCarbon Tetrachloride
12/05/22 12:370.0050.0007<0.0007mg/KgChlorobenzene
12/05/22 12:370.0050.0009<0.0009mg/KgChlorodibromomethane
12/05/22 12:370.0100.0009<0.0009mg/KgChloroethane
12/05/22 12:370.0050.001<0.001mg/KgChloroform
12/05/22 12:370.0100.0006<0.0006mg/KgChloromethane
12/05/22 12:370.0050.0005<0.0005mg/Kg2-Chlorotoluene
12/05/22 12:370.0050.0004<0.0004mg/Kg4-Chlorotoluene
12/05/22 12:370.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
12/05/22 12:370.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
12/05/22 12:370.0050.0006<0.0006mg/Kg1,2-Dibromoethane
12/05/22 12:370.0050.0006<0.0006mg/KgDibromomethane
12/05/22 12:370.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
12/05/22 12:370.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 1 of 30Date:12/12/2022 05:35 PM
Page 60 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
Associated Lab Samples: 94669, 94671
LRB-V27288 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
12/05/22 12:370.0100.001<0.001mg/KgDichlorodifluoromethane
12/05/22 12:370.0050.0008<0.0008mg/Kg1,1-Dichloroethane
12/05/22 12:370.0050.001<0.001mg/Kg1,2-Dichloroethane
12/05/22 12:370.0050.0007<0.0007mg/Kg1,1-Dichloroethene
12/05/22 12:370.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
12/05/22 12:370.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
12/05/22 12:370.0050.0004<0.0004mg/Kg1,2-Dichloropropane
12/05/22 12:370.0050.0006<0.0006mg/Kg1,3-Dichloropropane
12/05/22 12:370.0050.001<0.001mg/Kg2,2-Dichloropropane
12/05/22 12:370.0050.0008<0.0008mg/Kg1,1-Dichloropropene
12/05/22 12:370.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
12/05/22 12:370.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
12/05/22 12:370.0050.0006<0.0006mg/KgEthylbenzene
12/05/22 12:370.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
12/05/22 12:370.0100.0008<0.0008mg/KgHexachlorobutadiene
12/05/22 12:370.0100.0007<0.0007mg/Kgn-Hexane
12/05/22 12:370.0200.0006<0.0006mg/Kg2-Hexanone
12/05/22 12:370.0050.0005<0.0005mg/KgIsopropylbenzene
12/05/22 12:370.0050.001<0.001mg/Kg4-Isopropyl toluene
12/05/22 12:370.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
12/05/22 12:370.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
12/05/22 12:370.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
12/05/22 12:370.0100.001<0.001mg/KgMethylene Chloride
12/05/22 12:370.0100.0010<0.0010mg/KgNaphthalene
12/05/22 12:370.0050.0005<0.0005mg/Kgn-Propylbenzene
12/05/22 12:370.0050.001<0.001mg/KgStyrene
Page 2 of 30Date:12/12/2022 05:35 PM
Page 61 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
Associated Lab Samples: 94669, 94671
LRB-V27288 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
12/05/22 12:370.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
12/05/22 12:370.0050.0009<0.0009mg/KgTetrachloroethene
12/05/22 12:370.0050.0007<0.0007mg/KgToluene
12/05/22 12:370.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
12/05/22 12:370.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
12/05/22 12:370.0050.001<0.001mg/Kg1,1,1-Trichloroethane
12/05/22 12:370.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
12/05/22 12:370.0050.0009<0.0009mg/KgTrichloroethene
12/05/22 12:370.0100.002<0.002mg/KgTrichlorofluoromethane
12/05/22 12:370.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
12/05/22 12:370.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
12/05/22 12:370.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
12/05/22 12:370.0100.0005<0.0005mg/KgVinyl Acetate
12/05/22 12:370.0100.0005<0.0005mg/KgVinyl Chloride
12/05/22 12:370.0050.0005<0.0005mg/Kgo-Xylene
12/05/22 12:370.0100.001<0.001mg/Kgm,p-Xylene
12/05/22 12:374-Bromofluorobenzene (S)97.6 70-130
12/05/22 12:37Dibromofluoromethane (S)100 84-123
12/05/22 12:37Toluene-d8 (S)92.8 76-129
LCS-V27288 LCSD-V27288Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.088 88.289.60.0890.100mg/KgAcetone 29-198 1.5 20
0.105 10596.90.0960.100mg/KgAcrolein 70-130 8.0 20
Page 3 of 30Date:12/12/2022 05:35 PM
Page 62 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
LCS-V27288 LCSD-V27288Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.094 94.297.10.0970.100mg/KgAcrylonitrile 65-134 3.0 20
0.050 1021050.0520.050mg/KgBenzene 74-127 3.4 20
0.045 91.891.40.0450.050mg/KgBromobenzene 73-125 0.4 20
0.057 1151170.0580.050mg/KgBromochloromethane 72-134 1.7 20
0.050 1011050.0520.050mg/KgBromodichloromethane 75-122 3.1 20
0.043 87.087.00.0430.050mg/KgBromoform 66-135 0.0 20
0.046 93.096.60.0480.050mg/KgBromomethane 20-180 3.7 20
0.042 84.088.80.0440.050mg/Kgn-Butylbenzene 65-135 5.5 20
0.043 87.291.40.0450.050mg/Kgsec-Butyl benzene 66-131 4.7 20
0.044 88.890.20.0450.050mg/Kgtert-Butyl benzene 67-132 1.5 20
0.052 1041110.0550.050mg/KgCarbon Disulfide 61-129 6.4 20
0.051 1041120.0560.050mg/KgCarbon Tetrachloride 64-143 7.9 20
0.047 94.696.20.0480.050mg/KgChlorobenzene 74-118 1.6 20
0.053 1061080.0530.050mg/KgChlorodibromomethane 73-122 1.4 20
0.041 82.091.40.0450.050mg/KgChloroethane 33-149 10.8 20
0.050 1021030.0510.050mg/KgChloroform 73-127 1.3 20
0.038 76.280.00.0400.050mg/KgChloromethane 45-143 4.8 20
0.044 89.691.60.0450.050mg/Kg2-Chlorotoluene 67-124 2.2 20
0.044 89.691.60.0450.050mg/Kg4-Chlorotoluene 71-126 2.2 20
0.038 77.678.20.0390.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.7 20
0.048 97.698.40.0490.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 0.8 20
0.053 1071040.0510.050mg/Kg1,2-Dibromoethane 70-132 3.0 20
0.055 1101070.0530.050mg/KgDibromomethane 74-133 3.1 20
0.043 86.892.00.0460.050mg/Kg1,2-Dichlorobenzene 72-123 5.8 20
0.043 86.689.80.0440.050mg/Kg1,3-Dichlorobenzene 71-120 3.6 20
0.041 82.885.80.0420.050mg/Kg1,4-Dichlorobenzene 71-123 3.5 20
Page 4 of 30Date:12/12/2022 05:35 PM
Page 63 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
LCS-V27288 LCSD-V27288Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.051 1031080.0530.050mg/KgDichlorodifluoromethane 26-146 3.9 20
0.045 91.897.00.0480.050mg/Kg1,1-Dichloroethane 74-127 5.5 20
0.047 94.898.20.0490.050mg/Kg1,2-Dichloroethane 68-128 3.5 20
0.045 91.898.40.0490.050mg/Kg1,1-Dichloroethene 67-149 6.9 20
0.048 96.097.20.0480.050mg/Kgcis-1,2-Dichloroethene 76-134 1.2 20
0.046 93.899.60.0490.050mg/Kgtrans-1,2-Dichloroethene 73-132 5.9 20
0.046 93.495.20.0470.050mg/Kg1,2-Dichloropropane 73-130 1.9 20
0.048 96.494.20.0470.050mg/Kg1,3-Dichloropropane 75-124 2.3 20
0.048 96.01030.0510.050mg/Kg2,2-Dichloropropane 50-142 7.4 20
0.048 97.01020.0510.050mg/Kg1,1-Dichloropropene 71-130 5.4 20
0.051 1021060.0520.050mg/Kgcis-1,3-Dichloropropene 71-125 3.0 20
0.053 1071080.0540.050mg/Kgtrans-1,3-Dichloropropene 68-123 0.9 20
0.045 90.090.60.0450.050mg/KgEthylbenzene 74-128 0.6 20
0.093 93.392.20.0920.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.1 20
0.035 70.674.60.0370.050mg/KgHexachlorobutadiene 64-125 5.5 20
0.054 1101120.0560.050mg/Kgn-Hexane 70-130 2.3 20
0.037 74.473.00.0360.050mg/Kg2-Hexanone 61-157 1.8 20
0.044 89.693.20.0460.050mg/KgIsopropylbenzene 68-126 3.9 20
0.043 87.691.60.0450.050mg/Kg4-Isopropyl toluene 68-129 4.4 20
0.054 1091070.0530.050mg/KgMethyl Ethyl Ketone (MEK)63-149 1.1 20
0.050 1011020.0510.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.9 20
0.039 78.680.00.0400.050mg/Kg4-Methyl-2-Pentanone 57-162 1.7 20
0.042 85.287.00.0430.050mg/KgMethylene Chloride 74-129 2.0 20
0.048 97.297.00.0480.050mg/KgNaphthalene 57-157 0.2 20
0.043 86.290.20.0450.050mg/Kgn-Propylbenzene 67-130 4.5 20
0.048 96.297.60.0480.050mg/KgStyrene 77-121 1.4 20
Page 5 of 30Date:12/12/2022 05:35 PM
Page 64 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27289QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27288
LCS-V27288 LCSD-V27288Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.046 93.496.60.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 3.3 20
0.044 89.690.60.0450.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.1 20
0.048 97.898.60.0490.050mg/KgTetrachloroethene 68-130 0.8 20
0.047 95.496.20.0480.050mg/KgToluene 71-129 0.8 20
0.042 85.487.80.0430.050mg/Kg1,2,3-Trichlorobenzene 68-130 2.7 20
0.041 83.488.00.0440.050mg/Kg1,2,4-Trichlorobenzene 66-125 5.3 20
0.050 1011050.0520.050mg/Kg1,1,1-Trichloroethane 67-131 3.7 20
0.049 99.898.00.0490.050mg/Kg1,1,2-Trichloroethane 70-133 1.8 20
0.054 1081120.0560.050mg/KgTrichloroethene 75-133 3.4 20
0.045 90.497.40.0480.050mg/KgTrichlorofluoromethane 44-146 7.4 20
0.045 90.895.20.0470.050mg/Kg1,2,3-Trichloropropane 60-137 4.7 20
0.043 87.291.20.0450.050mg/Kg1,2,4-Trimethylbenzene 69-129 4.4 20
0.046 92.295.40.0470.050mg/Kg1,3,5-Trimethylbenzene 69-128 3.4 20
0.051 1031100.0550.050mg/KgVinyl Acetate 60-140 6.7 20
0.045 91.496.00.0480.050mg/KgVinyl Chloride 48-147 4.9 20
0.045 91.893.40.0460.050mg/Kgo-Xylene 74-126 1.7 20
0.092 92.193.60.0930.100mg/Kgm,p-Xylene 75-124 1.6 20
99.899.84-Bromofluorobenzene (S)70-130
101100Dibromofluoromethane (S)84-123
95.894.8Toluene-d8 (S)76-129
Page 6 of 30Date:12/12/2022 05:35 PM
Page 65 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
Associated Lab Samples: 94672, 94673
LRB-V27298 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0200.002<0.002mg/KgAcetone
12/05/22 12:370.0200.001<0.001mg/KgAcrolein
12/05/22 12:370.0200.0008<0.0008mg/KgAcrylonitrile
12/05/22 12:370.0050.0006<0.0006mg/KgBenzene
12/05/22 12:370.0050.0005<0.0005mg/KgBromobenzene
12/05/22 12:370.0050.0008<0.0008mg/KgBromochloromethane
12/05/22 12:370.0050.001<0.001mg/KgBromodichloromethane
12/05/22 12:370.0050.001<0.001mg/KgBromoform
12/05/22 12:370.0100.001<0.001mg/KgBromomethane
12/05/22 12:370.0050.0005<0.0005mg/Kgn-Butylbenzene
12/05/22 12:370.0050.0006<0.0006mg/Kgsec-Butyl benzene
12/05/22 12:370.0050.0005<0.0005mg/Kgtert-Butyl benzene
12/05/22 12:370.0050.0006<0.0006mg/KgCarbon Disulfide
12/05/22 12:370.0050.001<0.001mg/KgCarbon Tetrachloride
12/05/22 12:370.0050.0007<0.0007mg/KgChlorobenzene
12/05/22 12:370.0050.0009<0.0009mg/KgChlorodibromomethane
12/05/22 12:370.0100.0009<0.0009mg/KgChloroethane
12/05/22 12:370.0050.001<0.001mg/KgChloroform
12/05/22 12:370.0100.0006<0.0006mg/KgChloromethane
12/05/22 12:370.0050.0005<0.0005mg/Kg2-Chlorotoluene
12/05/22 12:370.0050.0004<0.0004mg/Kg4-Chlorotoluene
12/05/22 12:370.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
12/05/22 12:370.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
12/05/22 12:370.0050.0006<0.0006mg/Kg1,2-Dibromoethane
12/05/22 12:370.0050.0010<0.0010mg/KgDibromomethane
12/05/22 12:370.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
12/05/22 12:370.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 7 of 30Date:12/12/2022 05:35 PM
Page 66 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
Associated Lab Samples: 94672, 94673
LRB-V27298 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
12/05/22 12:370.0100.001<0.001mg/KgDichlorodifluoromethane
12/05/22 12:370.0050.0008<0.0008mg/Kg1,1-Dichloroethane
12/05/22 12:370.0050.001<0.001mg/Kg1,2-Dichloroethane
12/05/22 12:370.0050.0007<0.0007mg/Kg1,1-Dichloroethene
12/05/22 12:370.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
12/05/22 12:370.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
12/05/22 12:370.0050.0004<0.0004mg/Kg1,2-Dichloropropane
12/05/22 12:370.0050.0006<0.0006mg/Kg1,3-Dichloropropane
12/05/22 12:370.0050.001<0.001mg/Kg2,2-Dichloropropane
12/05/22 12:370.0050.0008<0.0008mg/Kg1,1-Dichloropropene
12/05/22 12:370.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
12/05/22 12:370.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
12/05/22 12:370.0050.0006<0.0006mg/KgEthylbenzene
12/05/22 12:370.1000.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
12/05/22 12:370.0100.0008<0.0008mg/KgHexachlorobutadiene
12/05/22 12:370.0100.0007<0.0007mg/Kgn-Hexane
12/05/22 12:370.0200.0006<0.0006mg/Kg2-Hexanone
12/05/22 12:370.0050.0005<0.0005mg/KgIsopropylbenzene
12/05/22 12:370.0050.001<0.001mg/Kg4-Isopropyl toluene
12/05/22 12:370.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
12/05/22 12:370.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
12/05/22 12:370.0050.001<0.001mg/KgMethylene Chloride
12/05/22 12:370.0100.0010<0.0010mg/KgNaphthalene
12/05/22 12:370.0050.0005<0.0005mg/Kgn-Propylbenzene
12/05/22 12:370.0050.001<0.001mg/KgStyrene
12/05/22 12:370.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
Page 8 of 30Date:12/12/2022 05:35 PM
Page 67 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
Associated Lab Samples: 94672, 94673
LRB-V27298 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 12:370.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
12/05/22 12:370.0050.0009<0.0009mg/KgTetrachloroethene
12/05/22 12:370.0050.0007<0.0007mg/KgToluene
12/05/22 12:370.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
12/05/22 12:370.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
12/05/22 12:370.0050.001<0.001mg/Kg1,1,1-Trichloroethane
12/05/22 12:370.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
12/05/22 12:370.0050.0009<0.0009mg/KgTrichloroethene
12/05/22 12:370.0100.002<0.002mg/KgTrichlorofluoromethane
12/05/22 12:370.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
12/05/22 12:370.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
12/05/22 12:370.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
12/05/22 12:370.0100.0005<0.0005mg/KgVinyl Acetate
12/05/22 12:370.0100.0005<0.0005mg/KgVinyl Chloride
12/05/22 12:370.0050.0005<0.0005mg/Kgo-Xylene
12/05/22 12:370.0100.001<0.001mg/Kgm,p-Xylene
12/05/22 12:374-Bromofluorobenzene (S)97.6 70-130
12/05/22 12:37Dibromofluoromethane (S)100 70-130
12/05/22 12:37Toluene-d8 (S)92.8 76-129
LCS-V27298 LCSD-V27298Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.088 88.289.60.0890.100mg/KgAcetone 29-198 1.5 20
0.105 10596.90.0960.100mg/KgAcrolein 70-130 8.0 20
0.094 94.297.10.0970.100mg/KgAcrylonitrile 65-134 3.0 20
Page 9 of 30Date:12/12/2022 05:35 PM
Page 68 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
LCS-V27298 LCSD-V27298Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.050 1021050.0520.050mg/KgBenzene 74-127 3.4 20
0.045 91.891.40.0450.050mg/KgBromobenzene 73-125 0.4 20
0.057 1151170.0580.050mg/KgBromochloromethane 72-134 1.7 20
0.050 1011050.0520.050mg/KgBromodichloromethane 75-122 3.1 20
0.043 87.087.00.0430.050mg/KgBromoform 66-135 0.0 20
0.046 93.096.60.0480.050mg/KgBromomethane 20-180 3.7 20
0.042 84.088.80.0440.050mg/Kgn-Butylbenzene 65-135 5.5 20
0.043 87.291.40.0450.050mg/Kgsec-Butyl benzene 66-131 4.7 20
0.044 88.890.20.0450.050mg/Kgtert-Butyl benzene 67-132 1.5 20
0.052 1041110.0550.050mg/KgCarbon Disulfide 61-129 6.4 20
0.051 1041120.0560.050mg/KgCarbon Tetrachloride 64-143 7.9 20
0.047 94.696.20.0480.050mg/KgChlorobenzene 74-118 1.6 20
0.053 1061080.0530.050mg/KgChlorodibromomethane 73-122 1.4 20
0.041 82.091.40.0450.050mg/KgChloroethane 33-149 10.8 20
0.050 1021030.0510.050mg/KgChloroform 73-127 1.3 20
0.038 76.280.00.0400.050mg/KgChloromethane 45-143 4.8 20
0.044 89.691.60.0450.050mg/Kg2-Chlorotoluene 67-124 2.2 20
0.044 89.691.60.0450.050mg/Kg4-Chlorotoluene 71-126 2.2 20
0.038 77.678.20.0390.050mg/KgDi-Isopropyl Ether (DIPE)59-159 0.7 20
0.048 97.698.40.0490.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 0.8 20
0.053 1071040.0510.050mg/Kg1,2-Dibromoethane 70-132 3.0 20
0.055 1101070.0530.050mg/KgDibromomethane 74-133 3.1 20
0.043 86.892.00.0460.050mg/Kg1,2-Dichlorobenzene 72-123 5.8 20
0.043 86.689.80.0440.050mg/Kg1,3-Dichlorobenzene 71-120 3.6 20
0.041 82.885.80.0420.050mg/Kg1,4-Dichlorobenzene 71-123 3.5 20
0.051 1031080.0530.050mg/KgDichlorodifluoromethane 26-146 3.9 20
Page 10 of 30Date:12/12/2022 05:35 PM
Page 69 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
LCS-V27298 LCSD-V27298Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.045 91.897.00.0480.050mg/Kg1,1-Dichloroethane 74-127 5.5 20
0.047 94.898.20.0490.050mg/Kg1,2-Dichloroethane 68-128 3.5 20
0.045 91.898.40.0490.050mg/Kg1,1-Dichloroethene 67-149 6.9 20
0.048 96.097.20.0480.050mg/Kgcis-1,2-Dichloroethene 76-134 1.2 20
0.046 93.899.60.0490.050mg/Kgtrans-1,2-Dichloroethene 73-132 5.9 20
0.046 93.495.20.0470.050mg/Kg1,2-Dichloropropane 73-130 1.9 20
0.048 96.494.20.0470.050mg/Kg1,3-Dichloropropane 75-124 2.3 20
0.048 96.01030.0510.050mg/Kg2,2-Dichloropropane 50-142 7.4 20
0.048 97.01020.0510.050mg/Kg1,1-Dichloropropene 71-130 5.4 20
0.051 1021060.0520.050mg/Kgcis-1,3-Dichloropropene 71-125 3.0 20
0.053 1071080.0540.050mg/Kgtrans-1,3-Dichloropropene 68-123 0.9 20
0.045 90.090.60.0450.050mg/KgEthylbenzene 74-128 0.6 20
0.093 93.392.20.0920.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.1 20
0.035 70.674.60.0370.050mg/KgHexachlorobutadiene 64-125 5.5 20
0.054 1101120.0560.050mg/Kgn-Hexane 70-130 2.3 20
0.037 74.473.00.0360.050mg/Kg2-Hexanone 61-157 1.8 20
0.044 89.693.20.0460.050mg/KgIsopropylbenzene 68-126 3.9 20
0.043 87.691.60.0450.050mg/Kg4-Isopropyl toluene 68-129 4.4 20
0.054 1091070.0530.050mg/KgMethyl Ethyl Ketone (MEK)63-149 1.1 20
0.050 1011020.0510.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.9 20
0.042 85.287.00.0430.050mg/KgMethylene Chloride 74-129 2.0 20
0.048 97.297.00.0480.050mg/KgNaphthalene 57-157 0.2 20
0.043 86.290.20.0450.050mg/Kgn-Propylbenzene 67-130 4.5 20
0.048 96.297.60.0480.050mg/KgStyrene 77-121 1.4 20
0.046 93.496.60.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 3.3 20
0.044 89.690.60.0450.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 1.1 20
Page 11 of 30Date:12/12/2022 05:35 PM
Page 70 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27300QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27298
LCS-V27298 LCSD-V27298Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.048 97.898.60.0490.050mg/KgTetrachloroethene 68-130 0.8 20
0.047 95.496.20.0480.050mg/KgToluene 71-129 0.8 20
0.042 85.487.80.0430.050mg/Kg1,2,3-Trichlorobenzene 68-130 2.7 20
0.041 83.488.00.0440.050mg/Kg1,2,4-Trichlorobenzene 66-125 5.3 20
0.050 1011050.0520.050mg/Kg1,1,1-Trichloroethane 67-131 3.7 20
0.049 99.898.00.0490.050mg/Kg1,1,2-Trichloroethane 70-133 1.8 20
0.054 1081120.0560.050mg/KgTrichloroethene 75-133 3.4 20
0.045 90.497.40.0480.050mg/KgTrichlorofluoromethane 44-146 7.4 20
0.045 90.895.20.0470.050mg/Kg1,2,3-Trichloropropane 60-137 4.7 20
0.043 87.291.20.0450.050mg/Kg1,2,4-Trimethylbenzene 69-129 4.4 20
0.046 92.295.40.0470.050mg/Kg1,3,5-Trimethylbenzene 69-128 3.4 20
0.051 1031100.0550.050mg/KgVinyl Acetate 60-140 6.7 20
0.045 91.496.00.0480.050mg/KgVinyl Chloride 48-147 4.9 20
0.045 91.893.40.0460.050mg/Kgo-Xylene 74-126 1.7 20
0.092 92.193.60.0930.100mg/Kgm,p-Xylene 75-124 1.6 20
99.899.84-Bromofluorobenzene (S)70-130
101100Dibromofluoromethane (S)70-130
95.894.8Toluene-d8 (S)76-129
Page 12 of 30Date:12/12/2022 05:35 PM
Page 71 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
Associated Lab Samples: 94670
LRB-V27374 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 11:460.0200.002<0.002mg/KgAcetone
12/06/22 11:460.0200.001<0.001mg/KgAcrolein
12/06/22 11:460.0200.0008<0.0008mg/KgAcrylonitrile
12/06/22 11:460.0050.0006<0.0006mg/KgBenzene
12/06/22 11:460.0050.0005<0.0005mg/KgBromobenzene
12/06/22 11:460.0050.0008<0.0008mg/KgBromochloromethane
12/06/22 11:460.0050.001<0.001mg/KgBromodichloromethane
12/06/22 11:460.0050.001<0.001mg/KgBromoform
12/06/22 11:460.0100.001<0.001mg/KgBromomethane
12/06/22 11:460.0050.0005<0.0005mg/Kgn-Butylbenzene
12/06/22 11:460.0050.0006<0.0006mg/Kgsec-Butyl benzene
12/06/22 11:460.0050.0005<0.0005mg/Kgtert-Butyl benzene
12/06/22 11:460.0050.0006<0.0006mg/KgCarbon Disulfide
12/06/22 11:460.0050.001<0.001mg/KgCarbon Tetrachloride
12/06/22 11:460.0050.0007<0.0007mg/KgChlorobenzene
12/06/22 11:460.0050.0009<0.0009mg/KgChlorodibromomethane
12/06/22 11:460.0100.0009<0.0009mg/KgChloroethane
12/06/22 11:460.0050.001<0.001mg/KgChloroform
12/06/22 11:460.0100.0006<0.0006mg/KgChloromethane
12/06/22 11:460.0050.0005<0.0005mg/Kg2-Chlorotoluene
12/06/22 11:460.0050.0004<0.0004mg/Kg4-Chlorotoluene
12/06/22 11:460.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
12/06/22 11:460.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
12/06/22 11:460.0050.0006<0.0006mg/Kg1,2-Dibromoethane
12/06/22 11:460.0050.0006<0.0006mg/KgDibromomethane
12/06/22 11:460.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
12/06/22 11:460.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 13 of 30Date:12/12/2022 05:35 PM
Page 72 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
Associated Lab Samples: 94670
LRB-V27374 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 11:460.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
12/06/22 11:460.0100.001<0.001mg/KgDichlorodifluoromethane
12/06/22 11:460.0050.0008<0.0008mg/Kg1,1-Dichloroethane
12/06/22 11:460.0050.001<0.001mg/Kg1,2-Dichloroethane
12/06/22 11:460.0050.0007<0.0007mg/Kg1,1-Dichloroethene
12/06/22 11:460.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
12/06/22 11:460.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
12/06/22 11:460.0050.0004<0.0004mg/Kg1,2-Dichloropropane
12/06/22 11:460.0050.0006<0.0006mg/Kg1,3-Dichloropropane
12/06/22 11:460.0050.001<0.001mg/Kg2,2-Dichloropropane
12/06/22 11:460.0050.0008<0.0008mg/Kg1,1-Dichloropropene
12/06/22 11:460.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
12/06/22 11:460.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
12/06/22 11:460.0050.0006<0.0006mg/KgEthylbenzene
12/06/22 11:460.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
12/06/22 11:460.0100.0008<0.0008mg/KgHexachlorobutadiene
12/06/22 11:460.0100.0007<0.0007mg/Kgn-Hexane
12/06/22 11:460.0200.0006<0.0006mg/Kg2-Hexanone
12/06/22 11:460.0050.0005<0.0005mg/KgIsopropylbenzene
12/06/22 11:460.0050.001<0.001mg/Kg4-Isopropyl toluene
12/06/22 11:460.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
12/06/22 11:460.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
12/06/22 11:460.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
12/06/22 11:460.0100.001<0.001mg/KgMethylene Chloride
12/06/22 11:460.0100.0010<0.0010mg/KgNaphthalene
12/06/22 11:460.0050.0005<0.0005mg/Kgn-Propylbenzene
12/06/22 11:460.0050.001<0.001mg/KgStyrene
Page 14 of 30Date:12/12/2022 05:35 PM
Page 73 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
Associated Lab Samples: 94670
LRB-V27374 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 11:460.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
12/06/22 11:460.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
12/06/22 11:460.0050.0009<0.0009mg/KgTetrachloroethene
12/06/22 11:460.0050.0007<0.0007mg/KgToluene
12/06/22 11:460.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
12/06/22 11:460.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
12/06/22 11:460.0050.001<0.001mg/Kg1,1,1-Trichloroethane
12/06/22 11:460.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
12/06/22 11:460.0050.0009<0.0009mg/KgTrichloroethene
12/06/22 11:460.0100.002<0.002mg/KgTrichlorofluoromethane
12/06/22 11:460.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
12/06/22 11:460.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
12/06/22 11:460.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
12/06/22 11:460.0100.0005<0.0005mg/KgVinyl Acetate
12/06/22 11:460.0100.0005<0.0005mg/KgVinyl Chloride
12/06/22 11:460.0050.0005<0.0005mg/Kgo-Xylene
12/06/22 11:460.0100.001<0.001mg/Kgm,p-Xylene
12/06/22 11:464-Bromofluorobenzene (S)102 70-130
12/06/22 11:46Dibromofluoromethane (S)101 84-123
12/06/22 11:46Toluene-d8 (S)92.8 76-129
LCS-V27374 LCSD-V27374Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.087 87.090.00.0900.100mg/KgAcetone 29-198 3.3 20
0.095 95.390.70.0900.100mg/KgAcrolein 70-130 4.9 20
Page 15 of 30Date:12/12/2022 05:35 PM
Page 74 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
LCS-V27374 LCSD-V27374Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.093 93.492.80.0920.100mg/KgAcrylonitrile 65-134 0.6 20
0.052 1041120.0560.050mg/KgBenzene 74-127 7.3 20
0.045 91.697.00.0480.050mg/KgBromobenzene 73-125 5.7 20
0.058 1161180.0590.050mg/KgBromochloromethane 72-134 1.7 20
0.053 1061080.0540.050mg/KgBromodichloromethane 75-122 1.6 20
0.041 82.488.60.0440.050mg/KgBromoform 66-135 7.2 20
0.048 97.093.80.0460.050mg/KgBromomethane 20-180 3.3 20
0.043 87.894.40.0470.050mg/Kgn-Butylbenzene 65-135 7.2 20
0.044 89.898.20.0490.050mg/Kgsec-Butyl benzene 66-131 8.9 20
0.045 90.494.80.0470.050mg/Kgtert-Butyl benzene 67-132 4.7 20
0.055 1111170.0580.050mg/KgCarbon Disulfide 61-129 5.0 20
0.057 1141210.0600.050mg/KgCarbon Tetrachloride 64-143 5.6 20
0.047 95.899.80.0490.050mg/KgChlorobenzene 74-118 4.0 20
0.050 1021050.0520.050mg/KgChlorodibromomethane 73-122 2.9 20
0.042 85.689.60.0440.050mg/KgChloroethane 33-149 4.5 20
0.052 1051080.0540.050mg/KgChloroform 73-127 3.1 20
0.039 79.683.40.0410.050mg/KgChloromethane 45-143 4.6 20
0.046 92.495.20.0470.050mg/Kg2-Chlorotoluene 67-124 2.9 20
0.046 92.495.20.0470.050mg/Kg4-Chlorotoluene 71-126 2.9 20
0.040 81.082.60.0410.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.9 20
0.046 92.294.00.0470.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 1.9 20
0.050 1001050.0520.050mg/Kg1,2-Dibromoethane 70-132 4.8 20
0.053 1071080.0540.050mg/KgDibromomethane 74-133 1.6 20
0.043 87.692.80.0460.050mg/Kg1,2-Dichlorobenzene 72-123 5.7 20
0.043 86.491.20.0450.050mg/Kg1,3-Dichlorobenzene 71-120 5.4 20
0.042 84.490.00.0450.050mg/Kg1,4-Dichlorobenzene 71-123 6.4 20
Page 16 of 30Date:12/12/2022 05:35 PM
Page 75 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
LCS-V27374 LCSD-V27374Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.052 1051140.0560.050mg/KgDichlorodifluoromethane 26-146 8.0 20
0.049 99.01020.0510.050mg/Kg1,1-Dichloroethane 74-127 2.9 20
0.048 97.81000.0500.050mg/Kg1,2-Dichloroethane 68-128 2.2 20
0.049 98.21060.0530.050mg/Kg1,1-Dichloroethene 67-149 8.0 20
0.049 98.21050.0520.050mg/Kgcis-1,2-Dichloroethene 76-134 6.3 20
0.050 1011060.0530.050mg/Kgtrans-1,2-Dichloroethene 73-132 5.2 20
0.047 95.899.40.0490.050mg/Kg1,2-Dichloropropane 73-130 3.6 20
0.047 94.697.00.0480.050mg/Kg1,3-Dichloropropane 75-124 2.5 20
0.051 1021120.0560.050mg/Kg2,2-Dichloropropane 50-142 9.5 20
0.051 1031100.0550.050mg/Kg1,1-Dichloropropene 71-130 6.7 20
0.053 1071070.0530.050mg/Kgcis-1,3-Dichloropropene 71-125 0.3 20
0.052 1061110.0550.050mg/Kgtrans-1,3-Dichloropropene 68-123 4.4 20
0.044 88.296.60.0480.050mg/KgEthylbenzene 74-128 9.0 20
0.094 94.496.30.0960.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 1.9 20
0.035 71.681.60.0400.050mg/KgHexachlorobutadiene 64-125 13.0 20
0.059 1181270.0630.050mg/Kgn-Hexane 70-130 7.1 20
0.034 68.871.00.0350.050mg/Kg2-Hexanone 61-157 3.1 20
0.045 91.898.80.0490.050mg/KgIsopropylbenzene 68-126 7.3 20
0.045 90.897.00.0480.050mg/Kg4-Isopropyl toluene 68-129 6.6 20
0.054 1091060.0530.050mg/KgMethyl Ethyl Ketone (MEK)63-149 2.6 20
0.051 1021040.0510.050mg/KgMethyl tert-butyl ether (MTBE)70-130 1.5 20
0.051 1031070.0530.050mg/Kg4-Methyl-2-Pentanone 57-162 4.0 20
0.042 85.088.00.0440.050mg/KgMethylene Chloride 74-129 3.4 20
0.046 92.095.60.0470.050mg/KgNaphthalene 57-157 3.8 20
0.044 89.096.80.0480.050mg/Kgn-Propylbenzene 67-130 8.3 20
0.048 97.21010.0500.050mg/KgStyrene 77-121 4.2 20
Page 17 of 30Date:12/12/2022 05:35 PM
Page 76 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V27375QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035
QC Prep:V27374
LCS-V27374 LCSD-V27374Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.045 91.896.00.0480.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 4.4 20
0.044 88.290.00.0450.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 2.0 20
0.049 99.01050.0520.050mg/KgTetrachloroethene 68-130 6.2 20
0.050 1001040.0520.050mg/KgToluene 71-129 3.7 20
0.042 84.091.20.0450.050mg/Kg1,2,3-Trichlorobenzene 68-130 8.2 20
0.041 83.291.40.0450.050mg/Kg1,2,4-Trichlorobenzene 66-125 9.3 20
0.053 1061120.0550.050mg/Kg1,1,1-Trichloroethane 67-131 4.7 20
0.045 91.897.80.0480.050mg/Kg1,1,2-Trichloroethane 70-133 6.3 20
0.055 1101160.0580.050mg/KgTrichloroethene 75-133 5.3 20
0.049 98.61050.0520.050mg/KgTrichlorofluoromethane 44-146 6.4 20
0.042 84.888.40.0440.050mg/Kg1,2,3-Trichloropropane 60-137 4.1 20
0.044 88.693.80.0460.050mg/Kg1,2,4-Trimethylbenzene 69-129 5.7 20
0.047 94.098.20.0490.050mg/Kg1,3,5-Trimethylbenzene 69-128 4.3 20
0.059 1191060.0530.050mg/KgVinyl Acetate 60-140 11.3 20
0.047 94.61020.0510.050mg/KgVinyl Chloride 48-147 7.5 20
0.046 92.098.60.0490.050mg/Kgo-Xylene 74-126 6.9 20
0.092 92.91010.1010.100mg/Kgm,p-Xylene 75-124 8.3 20
97.699.64-Bromofluorobenzene (S)70-130
10399.4Dibromofluoromethane (S)84-123
95.894.8Toluene-d8 (S)76-129
Page 18 of 30Date:12/12/2022 05:35 PM
Page 77 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
Associated Lab Samples: 94669, 94670, 94671, 94672, 94673
LRB-V27511 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/08/22 17:150.6600.116<0.116mg/KgAcenaphthene
12/08/22 17:150.6600.105<0.105mg/KgAcenaphthylene
12/08/22 17:150.6600.152<0.152mg/KgAniline
12/08/22 17:150.6600.143<0.143mg/KgAnthracene
12/08/22 17:150.6600.139<0.139mg/KgBenzo(a)anthracene
12/08/22 17:150.6600.147<0.147mg/KgBenzo(a)pyrene
12/08/22 17:150.6600.146<0.146mg/KgBenzo(b)fluoranthene
12/08/22 17:150.6600.136<0.136mg/KgBenzo(g,h,i)perylene
12/08/22 17:150.6600.137<0.137mg/KgBenzo(k)fluoranthene
12/08/22 17:152.000.580<0.580mg/KgBenzoic Acid
12/08/22 17:150.6600.105<0.105mg/KgBenzyl alcohol
12/08/22 17:150.6600.118<0.118mg/KgBis(2-Chloroethoxy)methane
12/08/22 17:150.6600.107<0.107mg/KgBis(2-Chloroethyl)ether
12/08/22 17:150.3300.136<0.136mg/KgBis(2-Chloroisopropyl)ether
12/08/22 17:150.6600.120<0.120mg/KgBis(2-ethylhexyl)phthalate
12/08/22 17:150.6600.109<0.109mg/Kg4-Bromophenyl phenyl ether
12/08/22 17:150.3300.113<0.113mg/KgButyl benzyl phthalate
12/08/22 17:150.6600.092<0.092mg/Kg4-Chloro-3-methylphenol
12/08/22 17:150.3300.112<0.112mg/Kg4-Chloroaniline
12/08/22 17:150.6600.116<0.116mg/Kg2-Chloronaphthalene
12/08/22 17:150.6600.098<0.098mg/Kg2-Chlorophenol
12/08/22 17:151.000.126<0.126mg/Kg4-Chlorophenyl phenyl ether
12/08/22 17:150.6600.142<0.142mg/KgChrysene
12/08/22 17:150.6600.230<0.230mg/KgDibenz(a,h)anthracene
12/08/22 17:150.6600.119<0.119mg/KgDibenzofuran
12/08/22 17:150.6600.094<0.094mg/Kg1,2-Dichlorobenzene
12/08/22 17:150.6600.097<0.097mg/Kg1,3-Dichlorobenzene
Page 19 of 30Date:12/12/2022 05:35 PM
Page 78 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
Associated Lab Samples: 94669, 94670, 94671, 94672, 94673
LRB-V27511 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/08/22 17:150.3300.097<0.097mg/Kg1,4-Dichlorobenzene
12/08/22 17:150.6600.147<0.147mg/Kg3,3'-Dichlorobenzidine
12/08/22 17:150.6600.095<0.095mg/Kg2,4-Dichlorophenol
12/08/22 17:150.6600.180<0.180mg/KgDiethyl phthalate
12/08/22 17:150.6600.174<0.174mg/KgDimethyl phthalate
12/08/22 17:150.3300.108<0.108mg/Kg2,4-Dimethylphenol
12/08/22 17:150.6600.107<0.107mg/KgDi-n-butyl phthalate
12/08/22 17:151.500.240<0.240mg/Kg4,6-Dinitro-2-methylphenol
12/08/22 17:151.500.520<0.520mg/Kg2,4-Dinitrophenol
12/08/22 17:150.6600.096<0.096mg/Kg2,4-Dinitrotoluene
12/08/22 17:150.6600.108<0.108mg/Kg2,6-Dinitrotoluene
12/08/22 17:150.3300.143<0.143mg/KgDi-n-Octyl Phthalate
12/08/22 17:150.6600.123<0.123mg/KgFluoranthene
12/08/22 17:150.6600.128<0.128mg/KgFluorene
12/08/22 17:150.6600.106<0.106mg/KgHexachlorobenzene
12/08/22 17:150.6600.097<0.097mg/KgHexachlorobutadiene
12/08/22 17:150.6600.157<0.157mg/KgHexachlorocyclopentadiene
12/08/22 17:150.6600.079<0.079mg/KgHexachloroethane
12/08/22 17:150.6600.179<0.179mg/KgIndeno(1,2,3-cd)pyrene
12/08/22 17:150.6600.191<0.191mg/KgIsophorone
12/08/22 17:150.6600.106<0.106mg/Kg1-Methylnaphthalene
12/08/22 17:150.6600.100<0.100mg/Kg2-Methylnaphthalene
12/08/22 17:150.6600.097<0.097mg/Kg2-Methylphenol
12/08/22 17:150.6600.084<0.084mg/Kg3&4 Methylphenol
12/08/22 17:150.6600.144<0.144mg/KgNaphthalene
12/08/22 17:150.6600.096<0.096mg/Kg2-Nitroaniline
12/08/22 17:150.6600.120<0.120mg/Kg3-Nitroaniline
Page 20 of 30Date:12/12/2022 05:35 PM
Page 79 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
Associated Lab Samples: 94669, 94670, 94671, 94672, 94673
LRB-V27511 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/08/22 17:150.3300.093<0.093mg/Kg4-Nitroaniline
12/08/22 17:150.3300.116<0.116mg/KgNitrobenzene
12/08/22 17:150.6600.088<0.088mg/Kg2-Nitrophenol
12/08/22 17:150.6600.117<0.117mg/Kg4-Nitrophenol
12/08/22 17:150.6600.263<0.263mg/KgN-Nitrosodimethylamine
12/08/22 17:150.6600.181<0.181mg/KgN-Nitrosodiphenylamine
12/08/22 17:150.6600.118<0.118mg/KgN-Nitroso-di-n-propylamine
12/08/22 17:151.000.347<0.347mg/KgPentachlorophenol
12/08/22 17:150.6600.208<0.208mg/KgPhenanthrene
12/08/22 17:150.6600.112<0.112mg/KgPhenol
12/08/22 17:150.6600.134<0.134mg/KgPyrene
12/08/22 17:150.3300.079<0.079mg/KgPyridine
12/08/22 17:150.6600.107<0.107mg/Kg1,2,4-Trichlorobenzene
12/08/22 17:150.6600.096<0.096mg/Kg2,4,5-Trichlorophenol
12/08/22 17:150.6600.096<0.096mg/Kg2,4,6-Trichlorophenol
12/08/22 17:152-Fluorobiphenyl (S)90.4 44-115
12/08/22 17:152-Fluorophenol (S)71.4 35-115
12/08/22 17:15Nitrobenzene-d5 (S)77.8 37-122
12/08/22 17:154-Terphenyl-d14 (S)100 54-127
12/08/22 17:152,4,6-Tribromophenol (S)85.5 39-132
12/08/22 17:15Phenol-d5 (S)69.6 34-121
LCS-V27511Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
85.61.431.67mg/KgAcenaphthene 40-123
88.01.471.67mg/KgAcenaphthylene 32-132
Page 21 of 30Date:12/12/2022 05:35 PM
Page 80 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
LCS-V27511Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
1202.001.67mg/KgAniline 12-197
94.01.571.67mg/KgAnthracene 47-123
95.21.591.67mg/KgBenzo(a)anthracene 49-126
1151.921.67mg/KgBenzo(a)pyrene 45-129
1131.881.67mg/KgBenzo(b)fluoranthene 45-132
1071.791.67mg/KgBenzo(g,h,i)perylene 43-134
1091.821.67mg/KgBenzo(k)fluoranthene 47-132
0.0*<0.5801.67mg/KgBenzoic Acid 10-83
77.81.301.67mg/KgBenzyl alcohol 29-122
77.21.291.67mg/KgBis(2-Chloroethoxy)methane 36-121
74.21.241.67mg/KgBis(2-Chloroethyl)ether 31-120
77.21.291.67mg/KgBis(2-Chloroisopropyl)ether 33-131
98.81.651.67mg/KgBis(2-ethylhexyl)phthalate 51-133
96.41.611.67mg/Kg4-Bromophenyl phenyl ether 46-124
98.21.641.67mg/KgButyl benzyl phthalate 48-132
74.81.251.67mg/Kg4-Chloro-3-methylphenol 45-122
76.01.271.67mg/Kg4-Chloroaniline 17-106
89.21.491.67mg/Kg2-Chloronaphthalene 41-114
82.61.381.67mg/Kg2-Chlorophenol 34-121
91.01.521.67mg/Kg4-Chlorophenyl phenyl ether 45-121
96.41.611.67mg/KgChrysene 50-124
1171.961.67mg/KgDibenz(a,h)anthracene 45-134
88.61.481.67mg/KgDibenzofuran 44-120
75.41.261.67mg/Kg1,2-Dichlorobenzene 33-117
71.21.191.67mg/Kg1,3-Dichlorobenzene 30-115
73.01.221.67mg/Kg1,4-Dichlorobenzene 31-115
68.81.151.67mg/Kg3,3'-Dichlorobenzidine 22-121
Page 22 of 30* QC Fail Date:12/12/2022 05:35 PM
Page 81 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
LCS-V27511Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
77.81.301.67mg/Kg2,4-Dichlorophenol 40-122
94.01.571.67mg/KgDiethyl phthalate 50-124
92.81.551.67mg/KgDimethyl phthalate 48-124
98.81.651.67mg/Kg2,4-Dimethylphenol 30-127
1021.701.67mg/KgDi-n-butyl phthalate 51-128
82.01.371.67mg/Kg4,6-Dinitro-2-methylphenol 29-132
56.00.9361.67mg/Kg2,4-Dinitrophenol 27-129
92.81.551.67mg/Kg2,4-Dinitrotoluene 48-126
89.81.501.67mg/Kg2,6-Dinitrotoluene 46-124
1051.751.67mg/KgDi-n-Octyl Phthalate 45-140
88.61.481.67mg/KgFluoranthene 50-127
90.41.511.67mg/KgFluorene 43-125
1011.691.67mg/KgHexachlorobenzene 45-122
72.41.211.67mg/KgHexachlorobutadiene 32-123
79.61.331.67mg/KgHexachlorocyclopentadiene 32-117
70.61.181.67mg/KgHexachloroethane 28-117
1061.771.67mg/KgIndeno(1,2,3-cd)pyrene 45-133
58.90.9841.67mg/KgIsophorone 30-122
73.61.231.67mg/Kg1-Methylnaphthalene 40-119
73.01.221.67mg/Kg2-Methylnaphthalene 38-122
84.41.411.67mg/Kg2-Methylphenol 32-122
76.01.271.67mg/Kg3&4 Methylphenol 34-119
71.21.191.67mg/KgNaphthalene 35-123
89.21.491.67mg/Kg2-Nitroaniline 44-127
88.01.471.67mg/Kg3-Nitroaniline 33-119
95.81.601.67mg/Kg4-Nitroaniline 63-147
68.21.141.67mg/KgNitrobenzene 34-122
Page 23 of 30Date:12/12/2022 05:35 PM
Page 82 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
LCS-V27511Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
70.61.181.67mg/Kg2-Nitrophenol 36-123
1021.711.67mg/Kg4-Nitrophenol 30-132
60.41.011.67mg/KgN-Nitrosodimethylamine 10-146
1121.871.67mg/KgN-Nitrosodiphenylamine 38-127
76.61.281.67mg/KgN-Nitroso-di-n-propylamine 36-120
1141.911.67mg/KgPentachlorophenol 25-133
94.61.581.67mg/KgPhenanthrene 50-121
83.21.391.67mg/KgPhenol 34-121
91.61.531.67mg/KgPyrene 47-127
48.90.8181.67mg/KgPyridine 10-80
71.21.191.67mg/Kg1,2,4-Trichlorobenzene 34-118
88.61.481.67mg/Kg2,4,5-Trichlorophenol 41-124
91.01.521.67mg/Kg2,4,6-Trichlorophenol 39-126
91.02-Fluorobiphenyl (S)44-115
74.42-Fluorophenol (S)35-115
68.8Nitrobenzene-d5 (S)37-122
1024-Terphenyl-d14 (S)54-127
91.52,4,6-Tribromophenol (S)39-132
70.2Phenol-d5 (S)34-121
V 94844-MS-V27511 V 94844-MSD-V27511Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.11 66.41.121.671.67<0.116mg/KgAcenaphthene 67.0 40-123 0.8 20
1.11 66.41.141.671.67<0.105mg/KgAcenaphthylene 68.2 32-132 2.6 20
0.577 34.50.7131.671.67<0.152mg/KgAniline 42.6 12-197 21.0*20
Page 24 of 30* QC Fail Date:12/12/2022 05:35 PM
Page 83 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
V 94844-MS-V27511 V 94844-MSD-V27511Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
1.14 68.21.211.671.67<0.143mg/KgAnthracene 72.4 47-123 5.9 20
1.14 68.21.211.671.67<0.139mg/KgBenzo(a)anthracene 72.4 49-126 5.9 20
1.36 81.41.451.671.67<0.147mg/KgBenzo(a)pyrene 86.8 45-129 6.4 20
1.31 78.41.381.671.67<0.146mg/KgBenzo(b)fluoranthene 82.6 45-132 5.2 20
1.25 74.81.301.671.67<0.136mg/KgBenzo(g,h,i)perylene 77.8 43-134 3.9 20
1.32 79.01.391.671.67<0.137mg/KgBenzo(k)fluoranthene 83.2 47-132 5.1 20
<0.580 0.0*<0.5801.671.67<0.580mg/KgBenzoic Acid 0.0 10-83 0.0 20
0.909 54.41.031.671.67<0.105mg/KgBenzyl alcohol 61.6 29-122 12.4 20
0.952 57.00.9951.671.67<0.118mg/KgBis(2-Chloroethoxy)methane 59.5 36-121 4.4 20
1.02 61.01.131.671.67<0.107mg/KgBis(2-Chloroethyl)ether 67.6 31-120 10.2 20
0.963 57.61.071.671.67<0.136mg/KgBis(2-Chloroisopropyl)ether 64.0 33-131 10.5 20
1.16 69.41.251.671.67<0.120mg/KgBis(2-ethylhexyl)phthalate 74.8 51-133 7.4 20
1.15 68.81.281.671.67<0.109mg/Kg4-Bromophenyl phenyl ether 76.6 46-124 10.6 20
1.13 67.61.211.671.67<0.113mg/KgButyl benzyl phthalate 72.4 48-132 6.8 20
0.857 51.30.9371.671.67<0.092mg/Kg4-Chloro-3-methylphenol 56.1 45-122 8.9 20
0.766 45.80.8791.671.67<0.112mg/Kg4-Chloroaniline 52.6 17-106 13.7 20
1.13 67.61.131.671.67<0.116mg/Kg2-Chloronaphthalene 67.6 41-114 0.0 20
0.991 59.31.101.671.67<0.098mg/Kg2-Chlorophenol 65.8 34-121 10.4 20
1.14 68.21.091.671.67<0.126mg/Kg4-Chlorophenyl phenyl ether 65.2 45-121 4.4 20
1.14 68.21.221.671.67<0.142mg/KgChrysene 73.0 50-124 6.7 20
1.41 84.41.461.671.67<0.230mg/KgDibenz(a,h)anthracene 87.4 45-134 3.4 20
1.09 65.21.141.671.67<0.119mg/KgDibenzofuran 68.2 44-120 4.4 20
0.912 54.61.031.671.67<0.094mg/Kg1,2-Dichlorobenzene 61.6 33-117 12.1 20
0.894 53.50.9661.671.67<0.097mg/Kg1,3-Dichlorobenzene 57.8 30-115 7.7 20
0.929 55.60.9871.671.67<0.097mg/Kg1,4-Dichlorobenzene 59.1 31-115 6.0 20
0.283 16.9*0.2771.671.67<0.147mg/Kg3,3'-Dichlorobenzidine 16.5 22-121 2.1 20
Page 25 of 30Date:12/12/2022 05:35 PM
Page 84 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
V 94844-MS-V27511 V 94844-MSD-V27511Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.979 58.60.9581.671.67<0.095mg/Kg2,4-Dichlorophenol 57.3 40-122 2.1 20
1.12 67.01.051.671.67<0.180mg/KgDiethyl phthalate 62.8 50-124 6.4 20
1.10 65.81.111.671.67<0.174mg/KgDimethyl phthalate 66.4 48-124 0.9 30
0.746 44.60.8301.671.67<0.108mg/Kg2,4-Dimethylphenol 49.7 30-127 10.6 20
1.25 74.81.321.671.67<0.107mg/KgDi-n-butyl phthalate 79.0 51-128 5.4 20
0.998 59.71.021.671.67<0.240mg/Kg4,6-Dinitro-2-methylphenol 61.0 29-132 2.1 20
0.817 48.90.9051.671.67<0.520mg/Kg2,4-Dinitrophenol 54.1 27-129 10.2 20
1.11 66.41.121.671.67<0.096mg/Kg2,4-Dinitrotoluene 67.0 48-126 0.8 20
1.09 65.21.081.671.67<0.108mg/Kg2,6-Dinitrotoluene 64.6 46-124 0.9 20
1.25 74.81.331.671.67<0.143mg/KgDi-n-Octyl Phthalate 79.6 45-140 6.2 20
1.04 62.21.141.671.67<0.123mg/KgFluoranthene 68.2 50-127 9.1 20
1.14 68.21.071.671.67<0.128mg/KgFluorene 64.0 43-125 6.3 20
1.22 73.01.321.671.67<0.106mg/KgHexachlorobenzene 79.0 45-122 7.8 20
0.980 58.61.051.671.67<0.097mg/KgHexachlorobutadiene 62.8 32-123 6.8 20
1.07 64.01.121.671.67<0.157mg/KgHexachlorocyclopentadiene 67.0 32-117 4.5 20
0.911 54.50.9231.671.67<0.079mg/KgHexachloroethane 55.2 28-117 1.3 20
1.25 74.81.311.671.67<0.179mg/KgIndeno(1,2,3-cd)pyrene 78.4 45-133 4.6 20
0.749 44.80.7651.671.67<0.191mg/KgIsophorone 45.8 30-122 2.1 20
0.947 56.71.011.671.67<0.106mg/Kg1-Methylnaphthalene 60.4 40-119 6.4 20
0.941 56.31.011.671.67<0.100mg/Kg2-Methylnaphthalene 60.4 38-122 7.0 20
0.868 51.90.9981.671.67<0.097mg/Kg2-Methylphenol 59.7 32-122 13.9 20
0.770 46.10.8391.671.67<0.084mg/Kg3&4 Methylphenol 50.2 34-119 8.5 20
0.950 56.81.011.671.67<0.144mg/KgNaphthalene 60.4 35-123 6.1 20
1.06 63.41.051.671.67<0.096mg/Kg2-Nitroaniline 62.8 44-127 0.9 20
1.01 60.41.031.671.67<0.120mg/Kg3-Nitroaniline 61.6 33-119 1.9 20
1.10 65.81.011.671.67<0.093mg/Kg4-Nitroaniline 60.4 63-147 8.5 20
Page 26 of 30Date:12/12/2022 05:35 PM
Page 85 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Semivolatile Organic Compounds - GC/MS
8270E
V27547QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3546
QC Prep:V27511
V 94844-MS-V27511 V 94844-MSD-V27511Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
0.881 52.70.8831.671.67<0.116mg/KgNitrobenzene 52.8 34-122 0.2 20
0.921 55.10.8861.671.67<0.088mg/Kg2-Nitrophenol 53.0 32-123 3.8 20
1.19 71.21.171.671.67<0.117mg/Kg4-Nitrophenol 70.0 30-132 1.6 20
0.794 47.50.8311.671.67<0.263mg/KgN-Nitrosodimethylamine 49.7 10-146 4.5 30
0.954 57.11.131.671.67<0.181mg/KgN-Nitrosodiphenylamine 67.6 38-127 16.8 20
0.948 56.70.9761.671.67<0.118mg/KgN-Nitroso-di-n-propylamine 58.4 36-120 2.9 20
1.22 73.01.421.671.67<0.347mg/KgPentachlorophenol 85.0 25-133 15.1 20
1.14 68.21.231.671.67<0.208mg/KgPhenanthrene 73.6 50-121 7.5 20
0.953 57.01.001.671.67<0.112mg/KgPhenol 59.8 34-121 4.8 20
1.08 64.61.181.671.67<0.134mg/KgPyrene 70.6 47-127 8.8 20
<0.079 0.0*<0.0791.671.67<0.079mg/KgPyridine 0.0 10-80 0.0 20
0.938 56.10.9831.671.67<0.107mg/Kg1,2,4-Trichlorobenzene 58.8 34-118 4.6 20
1.08 64.61.091.671.67<0.096mg/Kg2,4,5-Trichlorophenol 65.2 41-124 0.9 20
1.06 63.41.061.671.67<0.096mg/Kg2,4,6-Trichlorophenol 63.4 39-126 0.0 20
67.62-Fluorobiphenyl (S)67.6 44-115
52.52-Fluorophenol (S)52.9 35-115
53.9Nitrobenzene-d5 (S)52.2 37-122
69.44-Terphenyl-d14 (S)73.6 54-127
60.62,4,6-Tribromophenol (S)56.8 39-132
48.9Phenol-d5 (S)50.5 34-121
Page 27 of 30Date:12/12/2022 05:35 PM
Page 86 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Massachusetts EPH
MADEP-EPH
V27568QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAEPH (Prep)
QC Prep:V27432
Associated Lab Samples: 94669, 94670, 94671, 94672, 94673
LRB-V27432 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/08/22 12:1750.09.20<9.20mg/KgAliphatic C9-C18
12/08/22 12:1750.012.2<12.2mg/KgAliphatic C19-C36
12/08/22 12:1750.014.2<14.2mg/KgAromatic C11-C22
12/08/22 12:172-Fluorobiphenyl (S)117 40-140
12/08/22 12:172-Bromonaphthalene (S)116 40-140
12/08/22 12:17Chlorooctadecane (S)82.5 40-140
12/08/22 12:17OTP Surrogate (S)96.5 40-140
LCS-V27432 LCSD-V27432Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.5 32.5*71.342.860.0mg/KgAliphatic C9-C18 40-140 74.7*50
70.0 87.598.078.480.0mg/KgAliphatic C19-C36 40-140 11.3 50
139 81.7106181170mg/KgAromatic C11-C22 40-140 26.2 50
1021102-Fluorobiphenyl (S)40-140
1031132-Bromonaphthalene (S)40-140
79.089.0Chlorooctadecane (S)40-140
78.595.0OTP Surrogate (S)40-140
Page 28 of 30* QC Fail Date:12/12/2022 05:35 PM
Page 87 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V27228QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V27227
Associated Lab Samples: 94669, 94670, 94671, 94672, 94673
LRB-V27227 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/05/22 11:168.001.22<1.22mg/KgAliphatic C5-C8
12/05/22 11:168.004.56<4.56mg/KgAliphatic C9-C12
12/05/22 11:168.000.624<0.624mg/KgAromatic C9-C10
12/05/22 11:162,5-Dibromotoluene (FID) (S)81.7 70-130
12/05/22 11:162,5-Dibromotoluene (PID) (S)95.3 70-130
LCS-V27227 LCSD-V27227Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
29.3 91.587.528.032.0mg/KgAliphatic C5-C8 70-130 4.5 50
38.3 12012439.832.0mg/KgAliphatic C9-C12 70-130 3.8 50
12.4 11694.310.110.7mg/KgAromatic C9-C10 70-130 20.4 50
81.687.12,5-Dibromotoluene (FID) (S)70-130
99.01102,5-Dibromotoluene (PID) (S)70-130
Page 29 of 30Date:12/12/2022 05:35 PM
Page 88 of 91
Quality Control Data
22-336-0032Report No:
Project Description:
Client ID:Geological Resources, Inc.
New Dixie Mart #229
Dry Weight Determination
SW-DRYWT
V27216QC Analytical Batch:
Analysis Method:
Analysis Description:
V 94670-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 12/05/22 10:3212.89.3210.6%Moisture
V 94711-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 12/05/22 10:322.618.919.4%Moisture
Page 30 of 30Date:12/12/2022 05:35 PM
Page 89 of 91
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-336-0032
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT15 1.8C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Danyale Love Date & Time:12/02/2022 15:50:05
Special precautions or instructions included?
Comments:
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Page 91 of 91