RA-29471_48615_CA_SCH_20220809

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
August 9, 2022

Mr. Mark Powers
NCDEQ-UST Section
Raleigh Regional Office
1628 Mail Service Center
Raleigh, NC 27699-1628

Re: Site Check Report
Flash Market #370
1390 NW Maynard Road
Cary, Wake County
North Carolina
Facility ID Number: 00-0-0000035687
Incident Number: Pending
GRI Project No: 6117

Dear Mr. Powers,

Please find enclosed the referenced report for the above mentioned site.
If you have any questions, please contact Laura Minor at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Scott Gordon; Transit Energy Group, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Site Check Report
Flash Market #370
1390 NW Maynard Road
Cary, Wake County
North Carolina
Facility ID Number: 00-0-0000035687
Incident Number: Pending
GRI Project Number: 6117

Prepared for:

Mr. Scott Gordon
Transit Energy Group
501 River Street
Floor 3
Greenville, SC 29602

August 9, 2022

Laura Minor
Project Manager
Sharon Lowther
Report Writer

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
i
EXECUTIVE SUMMARY
The Flash Market #370 site is located at 1390 NW Maynard Road in Cary, Wake County, North Carolina.
The property operates as a petroleum retail facility and convenience store. The site is covered by asphalt,
concrete and grass. There is one 10,000-gallon gasoline UST and one 17,000-gallon gasoline UST currently
in use at the site with six associated dispensers.

On May 23, 2022, during triennial testing activities, one non-passing spill bucket was reported for the
17,000-gallon gasoline UST. Therefore, a site check was required by the NCDEQ. Repairs to the spill bucket
are scheduled to be conducted during the week of August 8, 2022.

On July 6, 2022, GRI conducted a site check in the area of the one 10,000-gallon gasoline and one 17,000
gasoline UST spill bucket. Three soil samples were collected during the installation of a monitoring well.
The monitoring well is located adjacent to the spill bucket of the 17,000-gallon gasoline UST. The soil
boring was advanced to 30 feet and soil samples were collected at 10 foot intervals (SS-1-10’, SS-2-20’ and
SS-3-30’). With the exception of concentrations of MTBE that exceeded the MCCs in soil sample SS-1-10’
and SS-3-30’, no other requested method constituent exceeded the MCCs.

As part of the site check activities, a ground water sample was collected from monitoring well MW-1 on
July 6, 2022. The concentrations of benzene, MTBE, naphthalene, tert-amyl alcohol, tert-butyl alcohol,
C5-C8 aliphatics and C9-C10 aromatics exceeded the MACs. The reported concentrations were below the
GCLs. No free product was noted at the site.

Based on this information, a release has occurred at the site. Please note that the presence of MTBE in
the soil and ground water samples indicate that the release pre-dates 2009, when MTBE use was phased
out. GRI recommends that a receptor survey is conducted in order to determine this risk classification of
the release.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
ii
SITE INFORMATION
1. Site Identification
 Flash Market #370 (Facility ID 00-0-0000035687)
 Incident Number Pending – Risk Ranking Undetermined
 Location of Source Area: 1390 NW Maynard Road
Cary, NC 27513
Wake County
35.788162°N, 78.809742°W (Topographical Map)
2. Information about Contacts Associated with the Leaking UST System

UST/AST Owner
Flash Market LLC (Table 1)
501 River Street
Floor 3
Greenville, SC 29602
[e-mail]
704-221-3405

UST/AST Operator
Flash Market LLC
501 River Street
Floor 3
Greenville, SC 29602
[e-mail]
704-221-3405

Property Owner
Getty Leasing, INC.
292 Madison Avenue Fl 9
New York, NY 10017
Email: Unknown
Phone No.: Unknown

Property Occupant
Rose Oil Company, Inc.
613 US Highway 158 Bypass
Henderson, NC 27537
[e-mail]
252-438-7141

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical
449 Springbrook Road
Charlotte, NC 28217
NC Certification No. 402/3375
704-525-0429
3. Information about Release
 Suspected release of petroleum from operation of a UST system currently in use at the site.
 An unknown amount of product was released from the leaking UST System
 One 10,000-gallon gasoline UST and one 17,000-gallon gasoline UST are in use at the site

Certification:
I, Samuel L. McKay III, a Licensed Geologist for Geological Resources, Inc., do certify that the information
contained in this report is correct and accurate to the best of my knowledge.

Geological Resources, Inc. is licensed to practice geology and engineering in North Carolina. The
certification numbers of the corporation are C-127 and C-2727, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality

NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
PID: Photo Ionization Detector
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
TABLE OF CONTENTS

EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ............................................................................................................................ ii
ACRONYMS ....................................................................................................................................... iii
A. SITE HISTORY AND CHARACTERIZATION ..............................................................................1
B. SITE CHECK PROCEDURES ....................................................................................................2
C. SITE INVESTIGATION ...........................................................................................................2
D. SUMMARY AND CONCLUSIONS ...........................................................................................4
E. LIMITATIONS ......................................................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Soil Quality Map
Figure 4: Ground Water Quality Map

TABLES
Table 1: UST Owner/Operator Information
Table 2: UST System Information
Table 3: Well Construction and Gauging Information
Table 4: Summary of Soil Sample Analytical Results
Table 5: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: UST Suspected Release 24 Hour Notice Form (UST-17A)
Appendix B: 24-Hour Release and UST Leak Reporting Form (UST-61)
Appendix C: Well Construction Record and Subsurface Boring Log
Appendix D: Laboratory Analytical Report

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
1
A. SITE HISTORY AND CHARACTERIZATION
1. UST Owner and Operator Information:
In accordance with the Site Check Report guidelines, the UST owner and operator information has been
summarized in the attached Table 1.

2. UST System Information:
In accordance with the Site Check Report guidelines, the UST system information has been summarized
in the attached Table 2. There are one 10,000-gallon gasoline and one 17,000-gallon diesel USTs
currently in use at the site with six associated gasoline dispenser islands. The dispensers are located on
the southwest side of the store building. The UST information is summarized in Table 2. A copy of the
current UST Permit is shown below:

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
2
3. Non-UST Information:
There are currently no ASTs and no known ASTs formerly at the site.

4. Comprehensive Description of the Release:
Annual compliance testing was completed on May 23, 2022. Based on the testing, non-passing hydrostatic
results were reported for one 17,000-gallon regular gasoline UST spill bucket. A copy of the UST Suspected
Release 24 Hour Notice (UST-17A) form is included as Appendix A.

A site check was required according to the NCDEQ. On July 6, 2022, three soil samples (SS-1-10’, SS-1-20’
and SS-1-30’) were collected during installation of a monitoring well (MW-1) adjacent to the non-passing
spill bucket. All of the reported contaminant concentrations were below the applicable standards. A
ground water sample collected from MW-1 was analyzed. Upon receipt of the laboratory analytical results
on July 20, 2022, a release was confirmed at the site. A copy of the UST-61 Form has been included as
Appendix B.

5. Description of the Site Characteristics:
The Flash Market #370 site is located at 1390 NW Maynard Road in Cary, Wake County, North Carolina.
(Figure 1). The property operates as a petroleum retail facility and convenience store. The site is covered
by asphalt, concrete and grass. There are one 10,000-gallon gasoline and one 17,000-gallon gasoline USTs
currently in use at the site with and six gasoline dispensers. The surrounding properties are commercial
and residential. A Site Map has been included as Figure 2.

B. SITE CHECK PROCEDURES
1. Results of Tank and Line Tightness Testing:
On May 23, 2022, the spill bucket associated with the 17,000-gallon regular spill bucket failed the triennial
hydrostatic test conducted by a testing company. A crack was identified in the spill bucket. Liners are
scheduled to be installed at the earliest possible date. Testing results will be forwarded to the NCDEQ
upon receipt subsequent to spill bucket repairs.

2. Summary of Site Check Procedure:
GRI performed a site check on July 6, 2022, that included the collection of three soil samples during the
installation of a monitoring well. The monitoring well is located adjacent to the regular gasoline UST spill
bucket. The soil boring was advanced to 30 feet and soil samples were collected at 10-foot intervals (SS-
1-10’, SS-2-20’ and SS-3-30’). A Well Construction Record and soil boring log are provided as Appendix C.

3. Soil Excavation Activities:
No soil excavation activities were conducted.

C. SITE INVESTIGATION
1. Field Screening:
Soil samples (SB-1, SB-2 and SB-3) collected on July 6, 2022, were not screened with a PID for VOCs.

2. Soil Sampling Information:
Soil samples (SS-1-10’, SS-1-20’ and SS-1-30’) were collected on July 6, 2022, and submitted for laboratory
analyses of VPH by the MADEP Method. In addition, SS-1-10’ and SS-1-30’ were submitted for laboratory
analysis of BTEX by EPA Method 8260B. With the exception of concentrations of MTBE that exceeded the
MCCs in soil samples SS-1-10’ and SS-3-30’, no other requested method constituent exceeded the MCCs.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
3
Please note that the sample collected from 30 feet BGS was below the water table. A soil quality map is
presented as Figure 3. A summary of soil sample analytical results is presented in Table 4. The laboratory
analytical report is provided as Appendix D. A summary of the soil sampling data from the July 2022 Site
Check activities is show below:
Sample ID Sample Depth (ft-BGS) Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Soil to Water MCC (mg/kg) 0.0072 5.4 8 6 0.085 0.2
Residential SCLs (mg/kg) 12 1,250 60 3,120 156 5.5
SS-1-10' 10 0.002 J 0.001 J 0.001 J 0.009 J 0.234 <0.001
SS-1-20' 20 NR NR NR NR NR NR
SS-1-30' 30 <0.0008 <0.001 <0.0008 0.0008 J 2.24 <0.001

3. Ground Water and Surface Water Sampling Information:
On July 6, 2022, monitoring well MW-1 was installed to 30 feet BGS. The depth to water in MW-1 was
23.71 feet BGS. A ground water elevation of 76.29 feet was measured, based on an assumed top of
casing elevation of 100.00 feet. A summarily of gauging data is provided in Table 3. The location of
MW-1 is shown in Figure 2.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
4
A ground water sample was collected from MW-1 on July 6, 2022, and submitted for analysis of VOC by
EPA Method 6200B, EDB by EPA Method 504.1, total lead by EPA Method 6010 and VPH by the MADEP
Method. The concentrations of benzene, MTBE, naphthalene, tert-amyl alcohol, tert-butyl alcohol, C5-
C8 aliphatics and C9-C10 aromatics exceeded the MACs. The reported concentrations were below the
GCLs. A ground water quality map is presented as Figure 4. A summary of ground water sample
analytical results is presented in Table 5. The laboratory analytical report is provided as Appendix D. A
summary of the ground water sampling data from the July 6, 2022, Site Check activities is show below:

Contaminant of
Concern Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MAC (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
MW-1 99.2 40 40.9 210 3,550 8.01

4. Quality-Control Measures:
Clean, disposable nitrile gloves were used for the collection of the soil samples. The samples were
collected in laboratory supplied containers and shipped to the laboratory in a cooler following proper
chain-of-custody procedures. A laboratory supplied trip blank was included in the sample cooler. With
the exception of acetone (common laboratory contaminant), no detectable concentrations of requested
method constituents were reported in the trip blank.

D. SUMMARY AND CONCLUSIONS
 The site is commercial and surrounding properties are commercial and residential.
 On May 23, 2022, non-passing hydrostatic results were reported for the 17,000-gallon regular
gasoline UST spill bucket. Repairs, including the installation of liners in both spill buckets, are
scheduled to be conducted as soon as possible. Post-repair testing results will be forwarded to
the NCDEQ upon receipt.
 A Site Check was conducted on July 6, 2022, to determine if a petroleum release had occurred.
 Three soil samples (SS-1-10’, SS-2-10’ and SS-3’30’) were collected during the advancement of
monitoring well (MW-1), located adjacent to the non-passing spill bucket. Concentrations of
MTBE reported in the soil samples collected from 10 feet and 30 feet, exceeded the soil to water
MSCC. All other reported contaminant concentrations were below the applicable standards.
 Monitoring well MW-1 was installed and a ground water sample was collected on July 6, 2022.
The concentrations of benzene, MTBE, naphthalene, tert-amyl alcohol, tert-butyl alcohol, C5-C8
aliphatics and C9-C10 aromatics exceeded the MACs. The reported concentrations were below
the GCLs. No free product was noted at the site.
 Based on this information, a petroleum release has occurred. It appears that the release pre-
dates 2009 due to the presence of MTBE. A receptor survey and a Phase I LSA should be
conducted in order to determine the risk classification of the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Site Check Report
Prepared on: August 9, 2022 Flash Market #370
Project Manager: Laura Minor GRI Project No. 6117
5
E. LIMITATIONS
This report has been prepared for the exclusive use of Transit Energy Group for the specific application to
the referenced site in Wake County, North Carolina. The assessment was conducted based on the scope
of work and level of effort specified by the NCDEQ and with resources adequate only for that scope of
work. Our findings have been developed in accordance with generally accepted standards of geology and
hydrogeology practices in the State of North Carolina, available information, and our professional
judgment. No other warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATIONFigure 1 Site Location Flash Market #3701390 NW Maynard RoadCary, North CarolinaWake CountyIncident No. PendingGRI Project No. 6117500 M2000 FTDate: 06/18/2022 Location: 35.788162° N -78.809742° W Dad

TABLES
UST ID Number 1A-1 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1A-1 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1A-1 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1A-1 Facility ID Number
Owner or Operator?
Owner/Operator
UST ID Number 1A-1 Facility ID Number
Owner or Operator?
Owner/Operator
613 US Highway 158 Bypass, Henderson, NC 27537 252-438-7141
00-0-0000035687
Name of Owner or Operator Dates of Ownership / Operation
Rose Oil Company, Inc.3/2/2016 - 7/29/2022
Address Telephone Number
Tirath, Inc.12/18/2008 - 3/2/2016
Address Telephone Number
Unknown Unknown
Address Telephone Number
Unknown Unknown
00-0-0000035687
Name of Owner or Operator Dates of Ownership / Operation
TABLE 1
00-0-0000035687
Name of Owner or Operator Dates of Ownership / Operation
Laws Enterprises, Inc.8/26/2004 - 12/18/2008
Rose Oil Company, Inc.1/1/1997 - 8/26/2004
Address Telephone Number
613 US Highway 158 Bypass, Henderson, NC 27537 252-438-7141
UST OWNER/OPERATOR INFORMATION
FLASH MARKET #370 (INCIDENT NO. PENDING)
00-0-0000035687
Name of Owner or Operator Dates of Ownership / Operation
501 River Street, Floor 3, Greenville, SC 29602 864-626-5553
00-0-0000035687
Name of Owner or Operator Dates of Ownership / Operation
Flash Market LLC 7/29/2022 - Current
Address Telephone Number
Date: 08/02/22 Facility ID #: 00-0-0000035687
Was Release
Associated
with UST
System?
(Yes / No)
1A Gasoline NA 10,000 06/01/1997 Single Wall FRP 8' x 26' 8"Single Wall FRP Current No
1 Gasoline NA 17,000 06/01/1997 Single Wall FRP 10' 6" x 31'Single Wall FRP Current No
TABLE 2
UST SYSTEM INFORMATION
FLASH MARKET #370 (INCIDENT NO. PENDING)
UST
ID
No.
Current
or Most
Recent
Contents
Previous
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Date: 08/02/22 Facility ID # : 00-0-0000035687
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
MW-1 07/06/22 07/06/22 20 20-30 30 100.00 23.71 ---76.29
TABLE 3
WELL CONSTRUCTION AND GAUGING INFORMATION
FLASH MARKET #370 (INCIDENT NO. PENDING)
Date: 08/02/22
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)BenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneC5 - C8 AliphaticsC9-C12 Aliphaticsc9-C10 Aromatics0.0072 5.4 8 6 0.085 0.2 68 540 31
12 1,250 60 3,120 156 5.5 625 1,560 469
59.4 18,600 297 46,700 1,810 27 9,340 23,300 7,000
SS-1-10'07/06/22 10 0.002 J 0.001 J 0.001 J 0.009 J 0.234 <0.001 <1.96 <7.36 <1.01
SS-1-20'07/06/22 20 NR NR NR NR NR NR <2.89 <10.8 <1.48
SS-1-30'07/06/22 30 <0.0008 <0.001 <0.0008 0.0008 J 2.24 <0.001 <1.92 <7.21 <0.986
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface
• < : Less than the method detection limit specified in the laboratory report
• MCCs: Maximum Contaminant Concentrations (soils)
• SCLs: Soil Cleanup Levels.
• Concentrations in bold face type exceed the soil-to-water MCC
• Concentrations in italic type exceed the residential SCL
• NE: Not Established
• NR: Not Requested
MADEP VPH/EPH
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
Industrial/Commercial Soil
Cleanup Levels (mg/kg)
Facility ID #: 00-0-0000035687
TABLE 4
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
FLASH MARKET #370 (INCIDENT NO. PENDING)
Analytical Method EPA 8260B
Date: 08/02/22
SW-6020B
Well
ID
Date Sampled
(mm/dd/yy)
1 600 600 500 20 6 40 10 70 0.02 15 400 700 200
5,000 260,000 80,000 50,000 20,000 6,000 40,000 10,000 70,000 50 15,000 NE NE NE
MW-1 07/06/22 99.2 40 40.9 210 3,550 8.01 1,210 2,640 5.59 <0.00345 <0.500 846 164 308
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• < : Less than the method detection limit specified in the laboratory report.
• GCL: Gross contamination level.
• Concentrations in bold face type exceed the MAC
• Concentrations in italic type exceed the GCL
• J: Estimated value.
• NE: Not established.
• NR: Not requested.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
MAC (μg/l)
GCL (μg/l)EthylbenzeneXylenesC9-C10 Aromaticstert-Amyl alcohol(TAA)tert-Butyl alcohol(TBA)Lead1,2-Dibromoethane(EDB)BenzeneTolueneTABLE 5
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS
FLASH MARKET #370 (INCIDENT NO. PENDING)
Analytical Method EPA 602 MADEP VPH
Contaminant of Concern
MTBENaphthaleneC9-C12 AliphaticsC5-C8 AliphaticsDi-isopropyl ether

APPENDICES

Appendix A
UST Suspected Release 24 Hour Notice Form (UST-17A)
UST-17A UST Suspected Release 24 Hour Notice
Do not use this form to report a 24 hour notice of a Pollution Incident. You must use form UST-61, 24 Hour Release and UST Leak
Reporting Form.
 This form must be used to report to DEQ, within 24 hours of discovery, a Suspected Release from any of the following:
a) Failed or inconclusive leak detection or tightness test results. This includes positive test results, such as “Increase”, which
indicates the level in the UST system has increased more than 0.2 gph.
b) Unusual operating conditions which can include, but are not limited to: the erratic behavior of dispensing equipment; the
unexplained presence of water in the tank; the presence of fuel in containment sumps or interstitial spaces; or the degradation of
any equipment or element of an underground storage tank system to the point where that equipment or element can not reasonably
be expected to perform its intended function.
c) Internal inspection results such as, perforations, corrosion holes, weld failures, or other similar defects that indicate a release
could have occurred.
 If you have more than four UST systems to report suspected releases, then attach additional sheets of the UST-17A form. You only
need to list the UST systems at your site that have suspected releases.
 Within 7 days of discovery, submit a UST-17B form to document the response activities taken to investigate the suspected release.
 Please submit this form to: NCDEQ/DWM, UST Section
1646 Mail Service Center
Raleigh, North Carolina 27699-1646
OR
Fax to [phone] OR [e-mail]
I. UST OWNER II. UST FACILITY
Name:
Transit Energy Group
Name:
Flash Market 370
Facility ID:
00-0-0000035687
Address:
501 River St.
Address:
1390 NW Maynard Rd.
City:
Greenville
State:
SC
Zip:
29601
City:
Cary
County:
Wake
Person Reporting:
Scott Gordon
Title of Person Reporting:
UST Compliance Field Technician
Telephone Number:
(704) 221-3405
Date Submitted:
6/1/2022
III. UST INFORMATION
Tank Number / Size: 1 / 16,676 / / /
Product Stored: Regular Unleaded
Location and/or source of
suspected release:
(check all that apply)
Tank
Piping
Tank Sump
Dispenser Sump
Spill Bucket
Internal Inspection
Other (Explain in
comments)
Tank
Piping
Tank Sump
Dispenser Sump
Spill Bucket
Internal Inspection
Other (Explain in
comments)
Tank
Piping
Tank Sump
Dispenser Sump
Spill Bucket
Internal Inspection
Other (Explain in
comments)
Tank
Piping
Tank Sump
Dispenser Sump
Spill Bucket
Internal Inspection
Other (Explain in
comments)
Leak detection method or
other observation that
indicates a suspected
release. (e.g., ATG, SIR,
visual contamination, fuel
in sump, etc.):
Failed hydro-static test.
Crack in side of spill
bucket

Failed/Inconclusive date or
date that leak detection
method suspected release
discovered:
5/23/2022
IV. COMMENTS
The failing test was performed on 5-23-22. I received the email about the failed trienial test from Petro Test on 5-27-22. Because of the
holiday weekend I did not read it until 5-31. I have contacted Oakes Petroleum about installing Fairfield liners in the both spill buckets.
They will install as quickly as they can. I will be in Cary tomorrow. I will do my best to fill the crack to prevent leaks in the mean time. I
have also contacted Geological Resources about the required site check.
UST-17A Revised 10/2018 http://www.wastenotnc.org/

Appendix B
24-Hour Release and UST Leak Reporting Form (UST-61)

UST-61 24-Hour Release and UST Leak Reporting Form.
For Releases
in NC
This form should be completed and submitted to the UST Section’s regional office following a known or suspected release from an underground storage tank (UST) system. This form is required to be submitted within 24 hours of discovery of a known or
suspected release
(DWM USE ONLY) Incident # ________ Risk (H,I,L,U)_______ Received On ________ Received By ________
Reported by (circle one): Phone, Fax or Report Region _______
Suspected Contamination? (Y/N) ________ Confirmed GW Contamination? (Y/N) ______ Confirmed Soil Contamination ?(Y/N) ______
Samples Taken?(Y/N) ______ Free Product? (Y/N) _____ If Yes, State Greatest Thickness ______________
Facility ID Number ______________ Date Leak Discovered ___________ Comm/Non-Commercial? ________
Reg/Non-regulated? _____________
INCIDENT DESCRIPTION
Incident Name:
Address: County:
City/Town: Zip Code: Regional Office (circle one): Asheville, Mooresville, Fayetteville, Raleigh, Washington, Wilmington, Winston-Salem
Latitude (decimal degrees): Longitude (decimal degrees) : Obtained by:
Briefly describe suspected or confirmed release: (including but not limited to: nature of release, date of release, amount
of release, amount of free product present and recovery efforts, initial responses conducted, impacts to receptors)  GPS
 Topographic map
 GIS Address matching
 Other
 Unknown
Describe location:

HOW RELEASE WAS DISCOVERED (Release Code)
(Check one)
 Release Detection Equipment or Methods
 During UST Closure/Removal
 Property Transfer
 Visual/Odor
 Water in Tank
 Water Supply Well Contamination
 Groundwater Contamination
 Surface Water Contamination
 Other (specify) _______________

SOURCE OF CONTAMINATION
Source of Release (Check primary source) Cause of Release (Check primary cause) Type of Release (Check one) Product Type Released (Check primary product type released)

 Tank
 Piping
 Dispenser
 Submersible Turbine Pump
 Delivery Problem
 Spill Bucket
 Other
 Unknown
Definitions presented on reverse

 Spill
 Overfill
 Corrosion
 Physical/Mechanical
Damage
 Install Problem
 Other
 Unknown
Definitions presented on reverse

 Petroleum
 Non-Petroleum
 Both
Location
(Check one)
 Facility
 Residence
 Other

 Gasoline/ Diesel/
Kerosene
 Heating Oil
 Other Petroleum
Products
 Metals
 Other Inorganics
 Other Organics

 Diesel/Veg. Oil
Blend
 Vegetable Oil 100%
 E10 – E20
 E21 – E84
 E85 – E99
 Ethanol 100%
 E01 – E09
Ownership
1. Municipal 2. Military 3. Unknown 4. Private 5. Federal 6. County 7. State Operation Type 1. Public Service 2. Agricultural 3. Residential 4. Education/Relig. 5. Industrial 6. Commercial 7. Mining
UST Form 61 (02/19) Page 1 of 2

Y
YNYN---
00-0-0035687
7/20/22
CommReg
Friendly Mart #370
1390 NW Maynard Road
Cary 27513
Wake
35.788007 78.809130
x
Google Earth
Site Check completed due to damaged Reg Gas (tank #3) tank spill bucket. Pea gravel beneath spill bucket.
Therefore, monitoring well installed adjacent to spill bucket. MTBE in soil sample collected @ 10' exceeded MCC.
7/6/22.
No compounds exceed GCLs, if published. Site Map and analytical summary attached.
X
X
X
X
X
Ground water sample collected from MW-1 on
Concentrations of 6200B compounds (inlcuding MTBE*) & VPH that exceeded the MACs reported in sample.
X
*Presence of MTBE in soil & GW indicates that the release pre-dates ~2009.

IMPACT ON DRINKING WATER SUPPLIES
Water Supply Wells Affected? 1. Yes 2. No 3. Unknown Number of Water Supply Wells Affected __________________
Water Supply Wells Contaminated: (Include Users Names, Addresses and Phone Numbers. Attach additional sheet if necessary) 1. 2. 3.
UST SYSTEM OWNER UST Owner/Company
Point of Contact Address
City State Zip Code Telephone Number
UST SYSTEM OPERATOR
UST Operator/Company Address
City State Zip Code Telephone Number
LANDOWNER AT LOCATION OF UST INCIDENT
Landowner Address
City State Zip Code Telephone Number
Draw Sketch of Area (showing two major road intersections) or Attach Map
Person Reporting Incident Company Telephone Number
Title Address Date
UST Form 61 (02/19) Page 2 of 2
Definitions of Sources Tank: means the tank that stores the product and is part of the underground storage tank system Piping: means the piping and connectors running from the tank or submersible turbine pump to the dispenser or other end-use equipment (Vent, vapor recovery, or fill lines are excluded.) Dispenser: includes the dispenser and the equipment used to connect the dispenser to the piping (e.g., a release from a suction pump or from components located above the shear valve) Submersible Turbine Pump (STP) Area includes the submersible turbine pump head (typically located in the tank sump), the line leak detector, and the piping that connects the submersible turbine pump to the tank Delivery Problem: identifies releases that occurred during product delivery to the tank. (Typical causes associated with this source are spills and overfills.)
Other: serves as the option to use when the release source is known but does not fit into one of the preceding categories (e.g., for releases from vent lines, vapor recovery lines, and fill lines) Unknown: identifies releases for which the source has not been determined Definitions of Causes
Spill: use this cause when a spill occurs (e.g., when the delivery hose is disconnected from the tank fill pipe or when the nozzle is removed from the dispenser) Overfill: use when an overfill occurs (e.g., overfills may occur from the fill pipe at the tank or when the nozzle fails to shut off at the dispenser) Physical or Mechanical Damage: use for all types of physical or mechanical damage, except corrosion (e.g., puncture of tank or piping, loose fittings, broken components, and components that have changed dimension) Corrosion: use when a metal tank, piping, or other component has a release due to corrosion (e.g., for steel, corrosion takes the form of rust) Installation Problem: use when the problem is determined to have occurred specifically because the UST system was not installed properly Other: use this option when the cause is known but does not fit into one of the preceding categories (e.g., putting regulated substances into monitoring wells) Unknown: use when the cause has not been determined
Transit Energy Group
Scott Gordon 501 River Street
Greenville SC 29601 704-221-3405
Same as above
Getty Leasing Inc.292 Madison Ave, Fl 9
New York NY 10017
L. Minor Geological Resources, Inc.704-845-4010
8.3.223502 Hayes Rd, Monroe NC 28110Project Mgr.
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-189-0051
Report Limit
Project:Flash Market #370
V 93939MW-1
54.5 07/14/2022 23:346200BAcetoneµg/L 1.80
99.2 07/14/2022 23:346200BBenzeneµg/L 0.180
2.86 07/14/2022 23:346200Bn-Butylbenzene µg/L 0.180
1.35 07/14/2022 23:346200Bsec-Butyl benzene µg/L 0.200
5.59 07/14/2022 23:346200BDi-Isopropyl Ether (DIPE)µg/L 0.500
J66.7 07/14/2022 23:346200BEthanolµg/L 42.0
40.9 07/14/2022 23:346200BEthylbenzeneµg/L 0.170
J0.829 07/14/2022 23:346200BEthyl Tertiary Butyl Ether (ETBE)µg/L 0.059
5.24 07/14/2022 23:346200B2-Hexanone µg/L 0.380
6.89 07/14/2022 23:346200BIsopropylbenzeneµg/L 0.180
0.826 07/14/2022 23:346200B4-Isopropyl toluene µg/L 0.089
23.7 07/14/2022 23:346200BMethyl Ethyl Ketone (MEK)µg/L 0.710
3550 07/15/2022 18:146200BMethyl tert-butyl ether (MTBE)µg/L 14.0
3.78 07/14/2022 23:346200B4-Methyl-2-Pentanone µg/L 0.078
8.01 07/14/2022 23:346200BNaphthaleneµg/L 0.470
11.0 07/14/2022 23:346200Bn-Propylbenzene µg/L 0.190
2640 07/15/2022 18:146200Btert-Butyl Alcohol (TBA)µg/L 160
1210 07/15/2022 18:146200Btert-Amyl Alcohol (TAA)µg/L 190
69.0 07/14/2022 23:346200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
40.0 07/14/2022 23:346200BTolueneµg/L 0.220
95.7 07/14/2022 23:346200B1,2,4-Trimethylbenzene µg/L 0.190
26.4 07/14/2022 23:346200B1,3,5-Trimethylbenzene µg/L 0.180
66.9 07/14/2022 23:346200Bo-Xylene µg/L 0.210
143 07/14/2022 23:346200Bm,p-Xylene µg/L 0.420
210 07/14/2022 23:346200BXylene (Total)µg/L 0.210
846 07/14/2022 23:34CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
164 07/14/2022 18:59CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
308 07/14/2022 18:59CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
985 07/15/2022 08:41MADEP-VPH Aliphatic C5-C8 µg/L 115
723 07/14/2022 18:59MADEP-VPH Aliphatic C9-C12 µg/L 25.8
308 07/14/2022 18:59MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93940SB-1-10'
0.200 07/12/2022 14:008260DAcetonemg/Kg - dry 0.003
J0.002 07/12/2022 14:008260DBenzenemg/Kg - dry 0.0008
J0.002 07/12/2022 14:008260DBromomethanemg/Kg - dry 0.002
J0.002 07/12/2022 14:008260DCarbon Disulfide mg/Kg - dry 0.0009
Page 4 of 50
Disclaimer
iMaps makes every effort to produce and publishthe most current and accurate information possible.
However, the maps are produced for information purposes,and are NOT surveys. No warranties, expressed or implied
,are provided for the data therein, its use,or its interpretation.
25 100 ft500
±
PARCEL_PK: 118995
REID: 0232220
PIN_NUM: 0754615887
PIN_EXT: 000
LAND_VAL: 822236
BLDG_VAL: 844621
TOTAL_VALUE_ASSD: 1666857
DEED_ACRES: 1.32
TOTSALPRICE: 1300000
SALE_DATE: 10/8/2021
YEAR_BUILT: 1997
HEATEDAREA: 2868
TYPE_AND_USE: 46
TYPE_USE_DECODE: CONV STORE
DESIGNSTYL: CVL
DESIGN_STYLE_DECODE: Conventional
CITY: CAR
CITY_DECODE: CARY
PLANNING_JURISDICTION: CA
TOWNSHIP: 04
TOWNSHIP_DECODE: Cary
OWNER: GETTY LEASING INC
ADDR1: 292 MADISON AVE FL 9
ADDR2: NEW YORK NY 10017-6376
DEED_BOOK: 018765
DEED_PAGE: 01681
DEED_DATE: 10/26/2021
LAND_CODE: C
LAND_CLASS: COM
LAND_CLASS_DECODE: Commercial
OWNERSHIP: 1020
ACTIVITY: 2110
FUNCTION: 2152
STRUCTURE: 2591
FM #370
1 inch equals 50 feet
Property

Appendix C
Well Construction Record and Soil Boring Log
WELL CONSTRUCTION RECORD
This form can be used for single or multiple wells
Form GW-1 North Carolina Department of Environment and Natural Resources – Division of Water 5HVRXUFHV Revised AXJXVW 2013
1. Well Contractor Information:

Well Contractor Name

NC Well Contractor Certification Number

Company Name 2. Well Construction Permit #: List all applicable well permits (i.e. County, State, Variance, ,QMHFWLRQetc.) 3. Well Use (check well use): Water Supply Well: □Agricultural □Municipal/Public □Geothermal (Heating/Cooling Supply) □Residential Water Supply (single)
□Industrial/Commercial □Residential Water Supply (shared) □Irrigation
Non-Water Supply Well: □Monitoring □Recovery
Injection Well: □Aquifer Recharge □Groundwater Remediation
□Aquifer Storage and Recovery □Salinity Barrier □Aquifer Test □Stormwater Drainage
□Experimental Technology □Subsidence Control
□Geothermal (Closed Loop) □Tracer □Geothermal (Heating/Cooling Return) □Other (explain under #21 Remarks)
4. Date Well(s) Completed: ____________ Well ID#______________________ 5a. Well Location:
Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip
County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (if well field, one lat/long is sufficient) N W
6. Is (are) the well(s): □Permanent or □Temporary

7. Is this a repair to an existing well: □Yes or □No If this is a repair, fill out known well construction information and explain the nature of the repair under #21 remarks section or on the back of this form.
8. Number of wells constructed: For multiple injection or non-water supply wells ONLY with the same construction, you can submit one form. 9. Total well depth below land surface: (ft.) For multiple wells list all depths if different (example- 3@200’ and 2@100′) 10. Static water level below top of casing: (ft.) If water level is above casing, use “+” 11. Borehole diameter: (in.) 12. Well construction method: (i.e. auger, rotary, cable, direct push, etc.) FOR WATER SUPPLY WELLS ONLY: 13a. Yield (gpm) Method of test: 13b. Disinfection type: Amount:

14. WATER ZONES
FROM TO DESCRIPTION
ft. ft.
ft. ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable) FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
17. SCREEN FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft. ft. in.
ft. ft. in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft. ft.
ft. ft.
ft. ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft. ft.
ft. ft.
20. DRILLING LOG (attach additional sheets if necessary) FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
ft. ft.
21. REMARKS

22. Certification:
Signature of Certified Well Contractor Date By signing this form, I hereby certify that the well(s) was (were) constructed in accordance with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages if necessary. SUBMITTAL INSTUCTIONS 24a. For All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Resources, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells ONLY: In addition to sending the form to the address in
24a above, also submit a copy of this form within 30 days of completion of well construction to the following: Division of Water Resources, Underground Injection Control Program, 1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells:
Also submit one copy of this form within 30 days of completion ofwell construction to the county health department of the county whereconstructed.
For Internal Use ONLY:
_______________
Matt Steele
4548 A
Geological Resources, Inc.
4
07/05/22 MW-1
Flash Market #370 00-0-0000035687
1390 NW Maynard Road, Cary, NC
Wake 0754-61-5887
35.788162 78.809742
4
4
1
30
23.71
6
Steel flight auger
0 15 2"sch 40 PVC
15 30 2 0.010 sch 40 PVC
10 13 Grout Pour
10 13 Bentonite Pour
13 30 Sand
0 0.25 Asphalt
0.25 1 Gravel
1 2 Gravel & Gray/tan fine sand
2 3 Tan/gray fine sand
3 20 Red clay
20 23 Red clay
23 28 Tan clay
28© - 30©; Tan clay
Geological Resources, Inc.Phone:[phone]
3502 Hayes Road Fax:[phone]
Monroe, NC 28110
Project Flash Market #370 Project #6117
Address 1390 NW Maynard Road, Cary NC
Boring Number MW-1 Date Drilled 07/06/22
Sample Method Grab Drilling Method 6.25 SSA
Completion DetailsWell installed at 30' with 15' screen, 15' riser, flush mounted
Driller Matt Steele License #4548A Log By AJ Discepolo
Boring Lab Sample PID GW USCS
Depth Sample Type ppm depth class From To Color Moisture Odor
0
2
0.0 3.0 Gray/tan
4 3.0 23.0 CLAY Red
6
8
10 SB-1-10'grab 10'CL Red moist

12
14
16

18
20 SB-2-20'grab 20'CL Red moist
22
q 23.0 30.0 Tan moist
24
26
28

30 SB-3-30'grab 30'CL Tan moist
32
34
35
Depth (feet)
SUBSURFACE LOG
Soil Type
LITHOLOGY
Fine SAND
CLAY
CLAY
CLAY
CLAY

Appendix D
Laboratory Analytical Report

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

7/20/2022
Geological Resources, Inc. Laura Minor
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 22-189-0051 Client Project Description: Flash Market #370
GRI #6117
Dear Laura Minor:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 7/8/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 50
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-189-0051
Page 2 of 50
Report Number:
Sample Summary Table
Client Project Description:
22-189-0051
Flash Market #370
GRI #6117
Lab No Client Sample ID Matrix Date Collected Date Received
07/06/2022 08:50Aqueous 93939 MW-1 07/08/2022 11:45
07/06/2022 07:17Solids 93940 SB-1-10'07/08/2022 11:45
07/06/2022 08:28Solids 93941 SB-2-20'07/08/2022 11:45
07/06/2022 08:32Aqueous 93942 Trip Blank 07/08/2022 11:45
07/06/2022 08:38Solids 93943 SB-3-30'07/08/2022 11:45
Page 3 of 50
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-189-0051
Report Limit
Project:Flash Market #370
V 93939MW-1
54.5 07/14/2022 23:346200BAcetoneµg/L 1.80
99.2 07/14/2022 23:346200BBenzeneµg/L 0.180
2.86 07/14/2022 23:346200Bn-Butylbenzene µg/L 0.180
1.35 07/14/2022 23:346200Bsec-Butyl benzene µg/L 0.200
5.59 07/14/2022 23:346200BDi-Isopropyl Ether (DIPE)µg/L 0.500
J66.7 07/14/2022 23:346200BEthanolµg/L 42.0
40.9 07/14/2022 23:346200BEthylbenzeneµg/L 0.170
J0.829 07/14/2022 23:346200BEthyl Tertiary Butyl Ether (ETBE)µg/L 0.059
5.24 07/14/2022 23:346200B2-Hexanone µg/L 0.380
6.89 07/14/2022 23:346200BIsopropylbenzeneµg/L 0.180
0.826 07/14/2022 23:346200B4-Isopropyl toluene µg/L 0.089
23.7 07/14/2022 23:346200BMethyl Ethyl Ketone (MEK)µg/L 0.710
3550 07/15/2022 18:146200BMethyl tert-butyl ether (MTBE)µg/L 14.0
3.78 07/14/2022 23:346200B4-Methyl-2-Pentanone µg/L 0.078
8.01 07/14/2022 23:346200BNaphthaleneµg/L 0.470
11.0 07/14/2022 23:346200Bn-Propylbenzene µg/L 0.190
2640 07/15/2022 18:146200Btert-Butyl Alcohol (TBA)µg/L 160
1210 07/15/2022 18:146200Btert-Amyl Alcohol (TAA)µg/L 190
69.0 07/14/2022 23:346200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
40.0 07/14/2022 23:346200BTolueneµg/L 0.220
95.7 07/14/2022 23:346200B1,2,4-Trimethylbenzene µg/L 0.190
26.4 07/14/2022 23:346200B1,3,5-Trimethylbenzene µg/L 0.180
66.9 07/14/2022 23:346200Bo-Xylene µg/L 0.210
143 07/14/2022 23:346200Bm,p-Xylene µg/L 0.420
210 07/14/2022 23:346200BXylene (Total)µg/L 0.210
846 07/14/2022 23:34CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
164 07/14/2022 18:59CALCULATIONAliphatics C9-C12 (Adjusted)µg/L 25.8
308 07/14/2022 18:59CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
985 07/15/2022 08:41MADEP-VPH Aliphatic C5-C8 µg/L 115
723 07/14/2022 18:59MADEP-VPH Aliphatic C9-C12 µg/L 25.8
308 07/14/2022 18:59MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 93940SB-1-10'
0.200 07/12/2022 14:008260DAcetonemg/Kg - dry 0.003
J0.002 07/12/2022 14:008260DBenzenemg/Kg - dry 0.0008
J0.002 07/12/2022 14:008260DBromomethanemg/Kg - dry 0.002
J0.002 07/12/2022 14:008260DCarbon Disulfide mg/Kg - dry 0.0009
Page 4 of 50
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-189-0051
Report Limit
Project:Flash Market #370
V 93940SB-1-10'
J0.001 07/12/2022 14:008260DEthylbenzenemg/Kg - dry 0.0008
J0.007 07/12/2022 14:008260D2-Hexanone mg/Kg - dry 0.0009
0.098 07/12/2022 14:008260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.0009
0.234 07/12/2022 14:008260DMethyl tert-butyl ether (MTBE)mg/Kg - dry 0.0009
J0.001 07/12/2022 14:008260DToluenemg/Kg - dry 0.0009
J0.004 07/12/2022 14:008260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0007
J0.001 07/12/2022 14:008260D1,3,5-Trimethylbenzene mg/Kg - dry 0.0008
J0.002 07/12/2022 14:008260Do-Xylene mg/Kg - dry 0.0007
J0.006 07/12/2022 14:008260Dm,p-Xylene mg/Kg - dry 0.001
J0.009 07/12/2022 14:008260DXylene (Total)mg/Kg - dry 0.0007
29.5 07/15/2022 10:33SW-DRYWT Moisture %
V 93942Trip Blank
J2.21 07/14/2022 19:426200BAcetoneµg/L 1.80
V 93943SB-3-30'
0.123 07/12/2022 14:278260DAcetonemg/Kg - dry 0.003
J0.001 07/12/2022 14:278260DDi-Isopropyl Ether (DIPE)mg/Kg - dry 0.001
J0.018 07/12/2022 14:278260DMethyl Ethyl Ketone (MEK)mg/Kg - dry 0.0009
2.24 07/14/2022 12:178260DMethyl tert-butyl ether (MTBE)mg/Kg - dry 0.022
J0.001 07/12/2022 14:278260D1,2,4-Trimethylbenzene mg/Kg - dry 0.0007
J0.0008 07/12/2022 14:278260Do-Xylene mg/Kg - dry 0.0007
J0.0008 07/12/2022 14:278260DXylene (Total)mg/Kg - dry 0.0007
31.2 07/15/2022 10:33SW-DRYWT Moisture %
Page 5 of 50

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Flash Market #370 Lab Report Number: 22-189-0051
Date: 7/20/2022
EDB and DBCP by Microextraction GC/ECD Method EPA-504.1 Analyte: 1,2-Dibromoethane QC Batch No: V21440/V21417
Confirmation column CCV above range for this Analyte. No hits in samples. No further action taken. Volatile Organic Compounds - GC/MS Method 6200B Analyte: tert-Amyl alcohol
QC Batch No: V21339/V21408 Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.

Page 6 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.500 µg/L 0.500 1.00Lead 1 07/14/22 13:55 6020BEDV
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00 V21408 07/15/22 09:00
54.5 µg/L 1.80 10.0Acetone 1 07/14/22 23:34 V21339JLB
99.2 µg/L 0.180 0.500Benzene 1 07/14/22 23:34 V21339JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/14/22 23:34 V21339JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/14/22 23:34 V21339JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/14/22 23:34 V21339JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/14/22 23:34 V21339JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/14/22 23:34 V21339JLB
2.86 µg/L 0.180 0.500n-Butylbenzene 1 07/14/22 23:34 V21339JLB
1.35 µg/L 0.200 0.500
sec-Butyl benzene 1 07/14/22 23:34 V21339JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/14/22 23:34 V21339JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/14/22 23:34 V21339JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/14/22 23:34 V21339JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/14/22 23:34 V21339JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/14/22 23:34 V21339JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/14/22 23:34 V21339JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/14/22 23:34 V21339JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/14/22 23:34 V21339JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/14/22 23:34 V21339JLB
5.59 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/14/22 23:34 V21339JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/14/22 23:34 V21339JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/14/22 23:34 V21339JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/14/22 23:34 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00 V21408 07/15/22 09:00
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/14/22 23:34 V21339JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/14/22 23:34 V21339JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/14/22 23:34 V21339JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/14/22 23:34 V21339JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/14/22 23:34 V21339JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/14/22 23:34 V21339JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/14/22 23:34 V21339JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 07/14/22 23:34 V21339JLB
<0.190 µg/L 0.190 0.500
1,2-Dichloropropane 1 07/14/22 23:34 V21339JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/14/22 23:34 V21339JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/14/22 23:34 V21339JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/14/22 23:34 V21339JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/14/22 23:34 V21339JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/14/22 23:34 V21339JLB
66.7 J µg/L 42.0 200Ethanol 1 07/14/22 23:34 V21339JLB
40.9 µg/L 0.170 0.500
Ethylbenzene 1 07/14/22 23:34 V21339JLB
0.829 J µg/L 0.059 10.0Ethyl Tertiary Butyl Ether (ETBE)1 07/14/22 23:34 V21339JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/14/22 23:34 V21339JLB
5.24 µg/L 0.380 1.002-Hexanone 1 07/14/22 23:34 V21339JLB
6.89 µg/L 0.180 0.500Isopropylbenzene 1 07/14/22 23:34 V21339JLB
0.826 µg/L 0.089 0.5004-Isopropyl toluene 1 07/14/22 23:34 V21339JLB
23.7 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/14/22 23:34 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00 V21408 07/15/22 09:00
3550 µg/L 14.0 100Methyl tert-butyl ether (MTBE)100 07/15/22 18:14 V21409JLB
3.78 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/14/22 23:34 V21339JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/14/22 23:34 V21339JLB
8.01 µg/L 0.470 1.00Naphthalene 1 07/14/22 23:34 V21339JLB
11.0 µg/L 0.190 0.500n-Propylbenzene 1 07/14/22 23:34 V21339JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/14/22 23:34 V21339JLB
2640 µg/L 160 1000tert-Butyl Alcohol (TBA)100 07/15/22 18:14 V21409JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 07/14/22 23:34 V21339JLB
1210 µg/L 190 1000
tert-Amyl Alcohol (TAA)100 07/15/22 18:14 V21409JLB
69.0 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 07/14/22 23:34 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/14/22 23:34 V21339JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/14/22 23:34 V21339JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 07/14/22 23:34 V21339JLB
40.0 µg/L 0.220 0.500Toluene 1 07/14/22 23:34 V21339JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/14/22 23:34 V21339JLB
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 07/14/22 23:34 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/14/22 23:34 V21339JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/14/22 23:34 V21339JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/14/22 23:34 V21339JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 07/14/22 23:34 V21339JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/14/22 23:34 V21339JLB
95.7 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/14/22 23:34 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00 V21408 07/15/22 09:00
26.4 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/14/22 23:34 V21339JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/14/22 23:34 V21339JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/14/22 23:34 V21339JLB
66.9 µg/L 0.210 0.500o-Xylene 1 07/14/22 23:34 V21339JLB
143 µg/L 0.420 1.00m,p-Xylene 1 07/14/22 23:34 V21339JLB
210 µg/L 0.210 0.500Xylene (Total)1 07/14/22 23:34 V21339
Surrogate: 4-Bromofluorobenzene 96.8 Limits: 70-130%07/14/22 23:341 JLB V21339
Surrogate: Dibromofluoromethane 99.2 Limits: 70-130%07/14/22 23:341 JLB V21339
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%07/14/22 23:341 JLB V21339
Surrogate: Toluene-d8 100 Limits: 70-130%07/14/22 23:341 JLB V21339
Surrogate: 4-Bromofluorobenzene 99.4 Limits: 70-130%07/15/22 18:14100 JLB V21409
Surrogate: Dibromofluoromethane 96.6 Limits: 70-130%07/15/22 18:14100 JLB V21409
Surrogate: 1,2-Dichloroethane - d4 97.8 Limits: 70-130%07/15/22 18:14100 JLB V21409
Surrogate: Toluene-d8 99.0 Limits: 70-130%07/15/22 18:14100 JLB V21409
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
EPA-504.1(PREP)
EPA-504.1 Prep Batch(es):V21417 07/18/22 13:00
<0.00345 µg/L 0.00345 0.02091,2-Dibromoethane 1 07/18/22 14:04 V21440JC1
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:MW-1
93939 Matrix:
7/6/2022 8:50
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
846 µg/L 115 500Aliphatic C5-C8 (Adjusted)1 07/14/22 23:34
164 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 07/14/22 18:59
308 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 07/14/22 18:59
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21307 07/14/22 08:00
985 µg/L 115 500Aliphatic C5-C8 10 07/15/22 08:41 V21308TBL
723 µg/L 25.8 50.0Aliphatic C9-C12 1 07/14/22 18:59 V21308TBL
308 µg/L 4.02 50.0Aromatic C9-C10 1 07/14/22 18:59 V21308TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)93.8 Limits: 70-130%07/14/22 18:591 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)90.0 Limits: 70-130%07/14/22 18:591 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)94.1 Limits: 70-130%07/15/22 08:4110 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)83.9 Limits: 70-130%07/15/22 08:4110 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
29.5 %Moisture 1 07/15/22 10:33 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00
0.200 mg/Kg - dry 0.003 0.028Acetone 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.028Acrolein 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.028Acrylonitrile 1 07/12/22 14:00 V21180TBL
0.002 J mg/Kg - dry 0.0008 0.007Benzene 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007Bromobenzene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromochloromethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromodichloromethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromoform 1 07/12/22 14:00 V21180TBL
0.002 J
mg/Kg - dry 0.002 0.014
Bromomethane 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007n-Butylbenzene 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007sec-Butyl benzene 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007tert-Butyl benzene 1 07/12/22 14:00 V21180TBL
0.002 J mg/Kg - dry 0.0009 0.007Carbon Disulfide 1 07/12/22 14:00 V21180TBL
<0.002 mg/Kg - dry 0.002 0.007Carbon Tetrachloride 1 07/12/22 14:00 V21180TBL
<0.0010 mg/Kg - dry 0.0010 0.007Chlorobenzene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007
Chlorodibromomethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Chloroethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Chloroform 1 07/12/22 14:00 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.014Chloromethane 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.0072-Chlorotoluene 1 07/12/22 14:00 V21180TBL
<0.0006 mg/Kg - dry 0.0006 0.0074-Chlorotoluene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Di-Isopropyl Ether (DIPE)1 07/12/22 14:00 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.0141,2-Dibromo-3-Chloropropane 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.0071,2-Dibromoethane 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007Dibromomethane 1 07/12/22 14:00 V21180TBL
<0.0004 mg/Kg - dry 0.0004 0.0071,2-Dichlorobenzene 1 07/12/22 14:00 V21180TBL
<0.0005 mg/Kg - dry 0.0005 0.0071,3-Dichlorobenzene 1 07/12/22 14:00 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.0071,4-Dichlorobenzene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Dichlorodifluoromethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1-Dichloroethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007
1,2-Dichloroethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1-Dichloroethene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007cis-1,2-Dichloroethene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007trans-1,2-Dichloroethene 1 07/12/22 14:00 V21180TBL
<0.0006 mg/Kg - dry 0.0006 0.0071,2-Dichloropropane 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.0071,3-Dichloropropane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0072,2-Dichloropropane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007
1,1-Dichloropropene 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007cis-1,3-Dichloropropene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007trans-1,3-Dichloropropene 1 07/12/22 14:00 V21180TBL
0.001 J mg/Kg - dry 0.0008 0.007Ethylbenzene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.070Ethyl Tertiary Butyl Ether (ETBE)1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Hexachlorobutadiene 1 07/12/22 14:00 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.014n-Hexane 1 07/12/22 14:00 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00
0.007 J mg/Kg - dry 0.0009 0.0282-Hexanone 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007Isopropylbenzene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0074-Isopropyl toluene 1 07/12/22 14:00 V21180TBL
0.098 mg/Kg - dry 0.0009 0.028Methyl Ethyl Ketone (MEK)1 07/12/22 14:00 V21180TBL
0.234 mg/Kg - dry 0.0009 0.007Methyl tert-butyl ether (MTBE)1 07/12/22 14:00 V21180TBL
<0.021 mg/Kg - dry 0.021 0.0284-Methyl-2-Pentanone 1 07/12/22 14:00 V21180TBL
<0.002 mg/Kg - dry 0.002 0.014Methylene Chloride 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Naphthalene 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007
n-Propylbenzene 1 07/12/22 14:00 V21180TBL
<0.002 mg/Kg - dry 0.002 0.007Styrene 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1,1,2-Tetrachloroethane 1 07/12/22 14:00 V21180TBL
<0.0005 mg/Kg - dry 0.0005 0.0071,1,2,2-Tetrachloroethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Tetrachloroethene 1 07/12/22 14:00 V21180TBL
0.001 J mg/Kg - dry 0.0009 0.007Toluene 1 07/12/22 14:00 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.0141,2,3-Trichlorobenzene 1 07/12/22 14:00 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.014
1,2,4-Trichlorobenzene 1 07/12/22 14:00 V21180TBL
<0.002 mg/Kg - dry 0.002 0.0071,1,1-Trichloroethane 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.0071,1,2-Trichloroethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Trichloroethene 1 07/12/22 14:00 V21180TBL
<0.002 mg/Kg - dry 0.002 0.014Trichlorofluoromethane 1 07/12/22 14:00 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,2,3-Trichloropropane 1 07/12/22 14:00 V21180TBL
0.004 J mg/Kg - dry 0.0007 0.0071,2,4-Trimethylbenzene 1 07/12/22 14:00 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00
0.001 J mg/Kg - dry 0.0008 0.0071,3,5-Trimethylbenzene 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.014Vinyl Acetate 1 07/12/22 14:00 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.014Vinyl Chloride 1 07/12/22 14:00 V21180TBL
0.002 J mg/Kg - dry 0.0007 0.007o-Xylene 1 07/12/22 14:00 V21180TBL
0.006 J mg/Kg - dry 0.001 0.014m,p-Xylene 1 07/12/22 14:00 V21180TBL
0.009 J mg/Kg - dry 0.0007 0.007Xylene (Total)1 07/12/22 14:00 V21180KCC
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/12/22 14:001 TBL V21180
Surrogate: Dibromofluoromethane 106 Limits: 84-123%07/12/22 14:001 TBL V21180
Surrogate: Toluene-d8 94.1 Limits: 76-129%07/12/22 14:001 TBL V21180
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-1-10'
93940 Matrix:
7/6/2022 7:17
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.96 mg/Kg - dry 12.9Aliphatic C5-C8 (Adjusted)100 07/13/22 15:07
<7.36 mg/Kg - dry 12.9Aliphatics C9-C12 (Adjusted)100 07/13/22 15:07
<1.01 mg/Kg - dry 1.01 12.9Aromatic C9-C10 (Adjusted)100 07/13/22 15:07
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21222 07/13/22 08:00
<1.96 mg/Kg - dry 1.96 12.9Aliphatic C5-C8 100 07/13/22 15:07 V21223TBL
<7.36 mg/Kg - dry 7.36 12.9Aliphatic C9-C12 100 07/13/22 15:07 V21223TBL
<1.01 mg/Kg - dry 1.01 12.9Aromatic C9-C10 100 07/13/22 15:07 V21223TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)76.9 Limits: 70-130%07/13/22 15:07100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)80.8 Limits: 70-130%07/13/22 15:07100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-2-20'
93941 Matrix:
7/6/2022 8:28
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21222 07/13/22 08:00
<2.89 mg/Kg 2.89 19.0Aliphatic C5-C8 100 07/13/22 15:31 V21223TBL
<10.8 mg/Kg 10.8 19.0Aliphatic C9-C12 100 07/13/22 15:31 V21223TBL
<1.48 mg/Kg 1.48 19.0Aromatic C9-C10 100 07/13/22 15:31 V21223TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)96.3 Limits: 70-130%07/13/22 15:31100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)102 Limits: 70-130%07/13/22 15:31100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93942 Matrix:
7/6/2022 8:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
2.21 J µg/L 1.80 10.0Acetone 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500Benzene 1 07/14/22 19:42 V21339JLB
<0.210 µg/L 0.210 0.500Bromobenzene 1 07/14/22 19:42 V21339JLB
<0.420 µg/L 0.420 1.00Bromochloromethane 1 07/14/22 19:42 V21339JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 07/14/22 19:42 V21339JLB
<1.50 µg/L 1.50 5.00Bromoform 1 07/14/22 19:42 V21339JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 07/14/22 19:42 V21339JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 07/14/22 19:42 V21339JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 07/14/22 19:42 V21339JLB
<0.220 µg/L 0.220 0.500Chloroform 1 07/14/22 19:42 V21339JLB
<0.220 µg/L 0.220 0.500
Chloromethane 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 07/14/22 19:42 V21339JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 07/14/22 19:42 V21339JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 07/14/22 19:42 V21339JLB
<0.230 µg/L 0.230 0.500Dibromomethane 1 07/14/22 19:42 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93942 Matrix:
7/6/2022 8:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 07/14/22 19:42 V21339JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 07/14/22 19:42 V21339JLB
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 07/14/22 19:42 V21339JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 07/14/22 19:42 V21339JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 07/14/22 19:42 V21339JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 07/14/22 19:42 V21339JLB
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 07/14/22 19:42 V21339JLB
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 07/14/22 19:42 V21339JLB
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 07/14/22 19:42 V21339JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 07/14/22 19:42 V21339JLB
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 07/14/22 19:42 V21339JLB
<42.0 µg/L 42.0 200
Ethanol 1 07/14/22 19:42 V21339JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 07/14/22 19:42 V21339JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 07/14/22 19:42 V21339JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 07/14/22 19:42 V21339JLB
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 07/14/22 19:42 V21339JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 07/14/22 19:42 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93942 Matrix:
7/6/2022 8:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 07/14/22 19:42 V21339JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 07/14/22 19:42 V21339JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 07/14/22 19:42 V21339JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 07/14/22 19:42 V21339JLB
<0.220 µg/L 0.220 0.500Styrene 1 07/14/22 19:42 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 07/14/22 19:42 V21339JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 07/14/22 19:42 V21339JLB
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 07/14/22 19:42 V21339JLB
<0.220 µg/L 0.220 0.500Toluene 1 07/14/22 19:42 V21339JLB
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 07/14/22 19:42 V21339JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 07/14/22 19:42 V21339JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 07/14/22 19:42 V21339JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 07/14/22 19:42 V21339JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 07/14/22 19:42 V21339JLB
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 07/14/22 19:42 V21339JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 07/14/22 19:42 V21339JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 07/14/22 19:42 V21339JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 07/14/22 19:42 V21339JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 07/14/22 19:42 V21339JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:Trip Blank
93942 Matrix:
7/6/2022 8:32
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V21337 07/14/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 07/14/22 19:42 V21339JLB
<0.21 µg/L 0.210 0.500Xylene (Total)1 07/14/22 19:42 V21339
Surrogate: 4-Bromofluorobenzene 97.2 Limits: 70-130%07/14/22 19:421 JLB V21339
Surrogate: Dibromofluoromethane 96.6 Limits: 70-130%07/14/22 19:421 JLB V21339
Surrogate: 1,2-Dichloroethane - d4 96.6 Limits: 70-130%07/14/22 19:421 JLB V21339
Surrogate: Toluene-d8 99.4 Limits: 70-130%07/14/22 19:421 JLB V21339
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
31.2 %Moisture 1 07/15/22 10:33 SW-DRYWTADC
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00 V21287 07/14/22 08:00
0.123 mg/Kg - dry 0.003 0.029Acetone 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.029Acrolein 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.029Acrylonitrile 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007Benzene 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007Bromobenzene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromochloromethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromodichloromethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Bromoform 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.014
Bromomethane 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007n-Butylbenzene 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007sec-Butyl benzene 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007tert-Butyl benzene 1 07/12/22 14:27 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.007Carbon Disulfide 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.007Carbon Tetrachloride 1 07/12/22 14:27 V21180TBL
<0.0010 mg/Kg - dry 0.0010 0.007Chlorobenzene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007
Chlorodibromomethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Chloroethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Chloroform 1 07/12/22 14:27 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.014Chloromethane 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.0072-Chlorotoluene 1 07/12/22 14:27 V21180TBL
<0.0006 mg/Kg - dry 0.0006 0.0074-Chlorotoluene 1 07/12/22 14:27 V21180TBL
0.001 J mg/Kg - dry 0.001 0.007Di-Isopropyl Ether (DIPE)1 07/12/22 14:27 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00 V21287 07/14/22 08:00
<0.0006 mg/Kg - dry 0.0006 0.0141,2-Dibromo-3-Chloropropane 1 07/12/22 14:27 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.0071,2-Dibromoethane 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007Dibromomethane 1 07/12/22 14:27 V21180TBL
<0.0005 mg/Kg - dry 0.0005 0.0071,2-Dichlorobenzene 1 07/12/22 14:27 V21180TBL
<0.0006 mg/Kg - dry 0.0006 0.0071,3-Dichlorobenzene 1 07/12/22 14:27 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.0071,4-Dichlorobenzene 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.014Dichlorodifluoromethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1-Dichloroethane 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.007
1,2-Dichloroethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1-Dichloroethene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007cis-1,2-Dichloroethene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007trans-1,2-Dichloroethene 1 07/12/22 14:27 V21180TBL
<0.0006 mg/Kg - dry 0.0006 0.0071,2-Dichloropropane 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.0071,3-Dichloropropane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0072,2-Dichloropropane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007
1,1-Dichloropropene 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007cis-1,3-Dichloropropene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007trans-1,3-Dichloropropene 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007Ethylbenzene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.072Ethyl Tertiary Butyl Ether (ETBE)1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Hexachlorobutadiene 1 07/12/22 14:27 V21180TBL
<0.0010 mg/Kg - dry 0.0010 0.014n-Hexane 1 07/12/22 14:27 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00 V21287 07/14/22 08:00
<0.0009 mg/Kg - dry 0.0009 0.0292-Hexanone 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.007Isopropylbenzene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0074-Isopropyl toluene 1 07/12/22 14:27 V21180TBL
0.018 J mg/Kg - dry 0.0009 0.029Methyl Ethyl Ketone (MEK)1 07/12/22 14:27 V21180TBL
2.24 mg/Kg - dry 0.022 0.181Methyl tert-butyl ether (MTBE)50 07/14/22 12:17 V21288TBL
<0.021 mg/Kg - dry 0.021 0.0294-Methyl-2-Pentanone 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.014Methylene Chloride 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014Naphthalene 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.007
n-Propylbenzene 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.007Styrene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,1,1,2-Tetrachloroethane 1 07/12/22 14:27 V21180TBL
<0.0005 mg/Kg - dry 0.0005 0.0071,1,2,2-Tetrachloroethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Tetrachloroethene 1 07/12/22 14:27 V21180TBL
<0.0010 mg/Kg - dry 0.0010 0.007Toluene 1 07/12/22 14:27 V21180TBL
<0.0008 mg/Kg - dry 0.0008 0.0141,2,3-Trichlorobenzene 1 07/12/22 14:27 V21180TBL
<0.0009 mg/Kg - dry 0.0009 0.014
1,2,4-Trichlorobenzene 1 07/12/22 14:27 V21180TBL
<0.002 mg/Kg - dry 0.002 0.0071,1,1-Trichloroethane 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.0071,1,2-Trichloroethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.007Trichloroethene 1 07/12/22 14:27 V21180TBL
<0.003 mg/Kg - dry 0.003 0.014Trichlorofluoromethane 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.0071,2,3-Trichloropropane 1 07/12/22 14:27 V21180TBL
0.001 J mg/Kg - dry 0.0007 0.0071,2,4-Trimethylbenzene 1 07/12/22 14:27 V21180TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
5035 LOW
8260D Prep Batch(es):V21179 07/12/22 08:00 V21287 07/14/22 08:00
<0.0008 mg/Kg - dry 0.0008 0.0071,3,5-Trimethylbenzene 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.014Vinyl Acetate 1 07/12/22 14:27 V21180TBL
<0.0007 mg/Kg - dry 0.0007 0.014Vinyl Chloride 1 07/12/22 14:27 V21180TBL
0.0008 J mg/Kg - dry 0.0007 0.007o-Xylene 1 07/12/22 14:27 V21180TBL
<0.001 mg/Kg - dry 0.001 0.014m,p-Xylene 1 07/12/22 14:27 V21180TBL
0.0008 J mg/Kg - dry 0.0007 0.007Xylene (Total)1 07/12/22 14:27 V21180KCC
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%07/12/22 14:271 TBL V21180
Surrogate: Dibromofluoromethane 104 Limits: 84-123%07/12/22 14:271 TBL V21180
Surrogate: Toluene-d8 94.2 Limits: 76-129%07/12/22 14:271 TBL V21180
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%07/14/22 12:1750 TBL V21288
Surrogate: Dibromofluoromethane 103 Limits: 70-130%07/14/22 12:1750 TBL V21288
Surrogate: Toluene-d8 93.8 Limits: 76-129%07/14/22 12:1750 TBL V21288
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 50
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-189-0051
00087
Geological Resources, Inc.
3502 Hayes Road
Laura Minor
Monroe
Danyale Love
Project Manager
GRI #6117 Received : 07/08/2022
Flash Market #370
Report Date : 07/20/2022
Sample ID :
Lab No :
Sampled:SB-3-30'
93943 Matrix:
7/6/2022 8:38
Solids
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<1.92 mg/Kg - dry 1.92 12.7Aliphatic C5-C8 (Adjusted)1 07/12/22 14:27
<7.21 mg/Kg - dry 12.7Aliphatics C9-C12 (Adjusted)100 07/13/22 15:54
<0.986 mg/Kg - dry 0.986 12.7Aromatic C9-C10 (Adjusted)100 07/13/22 15:54
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V21222 07/13/22 08:00
<1.92 mg/Kg - dry 1.92 12.7Aliphatic C5-C8 100 07/13/22 15:54 V21223TBL
<7.21 mg/Kg - dry 7.21 12.7Aliphatic C9-C12 100 07/13/22 15:54 V21223TBL
<0.986 mg/Kg - dry 0.986 12.7Aromatic C9-C10 100 07/13/22 15:54 V21223TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)83.1 Limits: 70-130%07/13/22 15:54100 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)82.5 Limits: 70-130%07/13/22 15:54100 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Page 29 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Metals Analyses
6020B
V21310QC Analytical Batch(es):
Analysis Method:
Analysis Description:
3005A
QC Prep:V21216
Associated Lab Samples: 93939
LRB-V21216 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
07/14/22 13:421.000.500<0.500µg/LLead
LCS-V21216Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
99.098.7100µg/LLead 80-120
V 93939-MS-V21216 V 93939-MSD-V21216Matrix Spike & Matrix Spike Duplicate
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
MSD
%Rec RPD
98.6 99.098.6100100< 0.500µg/LLead 99.0 75-125 0.0 20.0
V 93939-PDS-V21216Post Digestion Spike
Parameter
Analyzed%
Recovery
PDS
ResultUnits
07/14/22 14:1410451.8µg/LLead
Page 1 of 19Date:07/20/2022 04:15 PM
Page 30 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93939, 93942
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:2410.01.80<1.80µg/LAcetone
07/14/22 18:240.5000.180<0.180µg/LBenzene
07/14/22 18:240.5000.210<0.210µg/LBromobenzene
07/14/22 18:241.000.420<0.420µg/LBromochloromethane
07/14/22 18:240.5000.160<0.160µg/LBromodichloromethane
07/14/22 18:245.001.50<1.50µg/LBromoform
07/14/22 18:241.000.280<0.280µg/LBromomethane
07/14/22 18:240.5000.180<0.180µg/Ln-Butylbenzene
07/14/22 18:240.5000.200<0.200µg/Lsec-Butyl benzene
07/14/22 18:242.000.920<0.920µg/Ltert-Butyl benzene
07/14/22 18:240.5000.180<0.180µg/LCarbon Tetrachloride
07/14/22 18:240.5000.190<0.190µg/LChlorobenzene
07/14/22 18:240.5000.190<0.190µg/LChlorodibromomethane
07/14/22 18:241.000.430<0.430µg/LChloroethane
07/14/22 18:240.5000.220<0.220µg/LChloroform
07/14/22 18:240.5000.220<0.220µg/LChloromethane
07/14/22 18:240.5000.200<0.200µg/L2-Chlorotoluene
07/14/22 18:240.5000.200<0.200µg/L4-Chlorotoluene
07/14/22 18:240.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
07/14/22 18:242.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
07/14/22 18:240.5000.200<0.200µg/L1,2-Dibromoethane
07/14/22 18:240.5000.230<0.230µg/LDibromomethane
07/14/22 18:240.5000.220<0.220µg/L1,2-Dichlorobenzene
07/14/22 18:240.5000.190<0.190µg/L1,3-Dichlorobenzene
07/14/22 18:240.5000.210<0.210µg/L1,4-Dichlorobenzene
07/14/22 18:245.001.20<1.20µg/LDichlorodifluoromethane
07/14/22 18:240.5000.240<0.240µg/L1,1-Dichloroethane
Page 2 of 19Date:07/20/2022 04:15 PM
Page 31 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93939, 93942
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:240.5000.150<0.150µg/L1,2-Dichloroethane
07/14/22 18:240.5000.150<0.150µg/L1,1-Dichloroethene
07/14/22 18:240.5000.200<0.200µg/Lcis-1,2-Dichloroethene
07/14/22 18:240.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
07/14/22 18:240.5000.190<0.190µg/L1,2-Dichloropropane
07/14/22 18:240.5000.130<0.130µg/L1,3-Dichloropropane
07/14/22 18:242.000.210<0.210µg/L2,2-Dichloropropane
07/14/22 18:240.5000.200<0.200µg/L1,1-Dichloropropene
07/14/22 18:240.5000.210<0.210µg/Lcis-1,3-Dichloropropene
07/14/22 18:240.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
07/14/22 18:2420042.0<42.0µg/LEthanol
07/14/22 18:240.5000.170<0.170µg/LEthylbenzene
07/14/22 18:2410.00.059<0.059µg/LEthyl Tertiary Butyl Ether (ETBE)
07/14/22 18:243.000.350<0.350µg/LHexachlorobutadiene
07/14/22 18:241.000.380<0.380µg/L2-Hexanone
07/14/22 18:240.5000.180<0.180µg/LIsopropylbenzene
07/14/22 18:240.5000.089<0.089µg/L4-Isopropyl toluene
07/14/22 18:245.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
07/14/22 18:241.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/14/22 18:241.000.078<0.078µg/L4-Methyl-2-Pentanone
07/14/22 18:242.000.330<0.330µg/LMethylene Chloride
07/14/22 18:241.000.470<0.470µg/LNaphthalene
07/14/22 18:240.5000.190<0.190µg/Ln-Propylbenzene
07/14/22 18:240.5000.220<0.220µg/LStyrene
07/14/22 18:2410.00.350<0.350µg/Ltert-Butyl formate (TBF)
07/14/22 18:2410.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
07/14/22 18:240.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 3 of 19Date:07/20/2022 04:15 PM
Page 32 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
Associated Lab Samples: 93939, 93942
LRB-V21337 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:240.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
07/14/22 18:240.5000.220<0.220µg/LTetrachloroethene
07/14/22 18:240.5000.220<0.220µg/LToluene
07/14/22 18:240.5000.380<0.380µg/L1,2,3-Trichlorobenzene
07/14/22 18:240.5000.310<0.310µg/L1,2,4-Trichlorobenzene
07/14/22 18:240.5000.160<0.160µg/L1,1,1-Trichloroethane
07/14/22 18:240.5000.096<0.096µg/L1,1,2-Trichloroethane
07/14/22 18:240.5000.180<0.180µg/LTrichloroethene
07/14/22 18:240.5000.180<0.180µg/LTrichlorofluoromethane
07/14/22 18:240.5000.270<0.270µg/L1,2,3-Trichloropropane
07/14/22 18:240.5000.190<0.190µg/L1,2,4-Trimethylbenzene
07/14/22 18:240.5000.180<0.180µg/L1,3,5-Trimethylbenzene
07/14/22 18:245.001.00<1.00µg/LVinyl Acetate
07/14/22 18:240.5000.170<0.170µg/LVinyl Chloride
07/14/22 18:240.5000.210<0.210µg/Lo-Xylene
07/14/22 18:241.000.420<0.420µg/Lm,p-Xylene
07/14/22 18:244-Bromofluorobenzene (S)99.6 70-130
07/14/22 18:24Dibromofluoromethane (S)98.2 70-130
07/14/22 18:241,2-Dichloroethane - d4 (S)98.0 70-130
07/14/22 18:24Toluene-d8 (S)99.4 70-130
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
39.7 99.299.739.940.0µg/LAcetone 40-160 0.5 20.0
19.5 97.510420.720.0µg/LBenzene 70-130 5.9 20.0
Page 4 of 19Date:07/20/2022 04:15 PM
Page 33 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
19.6 98.010120.220.0µg/LBromobenzene 70-130 3.0 20.0
19.7 98.510220.320.0µg/LBromochloromethane 70-130 3.0 20.0
20.6 10310420.720.0µg/LBromodichloromethane 70-130 0.4 20.0
23.1 11611523.020.0µg/LBromoform 70-130 0.4 20.0
19.5 97.594.018.820.0µg/LBromomethane 60-140 3.6 20.0
19.8 99.010420.720.0µg/Ln-Butylbenzene 70-130 4.4 20.0
19.9 99.510420.720.0µg/Lsec-Butyl benzene 70-130 3.9 20.0
20.2 10110320.620.0µg/Ltert-Butyl benzene 70-130 1.9 20.0
20.5 10310320.520.0µg/LCarbon Tetrachloride 70-130 0.0 20.0
20.4 10210721.320.0µg/LChlorobenzene 70-130 4.3 20.0
21.3 10711422.720.0µg/LChlorodibromomethane 70-130 6.3 20.0
19.0 95.096.519.320.0µg/LChloroethane 60-140 1.5 20.0
20.1 10110521.020.0µg/LChloroform 70-130 4.3 20.0
19.1 95.599.019.820.0µg/LChloromethane 60-140 3.5 20.0
19.9 99.510320.520.0µg/L2-Chlorotoluene 70-130 2.9 20.0
19.8 99.010120.220.0µg/L4-Chlorotoluene 70-130 2.0 20.0
19.9 99.510420.720.0µg/LDi-Isopropyl Ether (DIPE)70-130 3.9 20.0
17.7 88.598.519.720.0µg/L1,2-Dibromo-3-Chloropropane 70-130 10.6 20.0
20.7 10410521.020.0µg/L1,2-Dibromoethane 70-130 1.4 20.0
20.1 10199.519.920.0µg/LDibromomethane 70-130 1.0 20.0
20.9 10510420.820.0µg/L1,2-Dichlorobenzene 70-130 0.4 20.0
19.8 99.010420.720.0µg/L1,3-Dichlorobenzene 70-130 4.4 20.0
19.3 96.510020.020.0µg/L1,4-Dichlorobenzene 70-130 3.5 20.0
20.1 10110821.520.0µg/LDichlorodifluoromethane 60-140 6.7 20.0
19.9 99.510420.820.0µg/L1,1-Dichloroethane 70-130 4.4 20.0
18.7 93.597.019.420.0µg/L1,2-Dichloroethane 70-130 3.6 20.0
Page 5 of 19Date:07/20/2022 04:15 PM
Page 34 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10010320.520.0µg/L1,1-Dichloroethene 70-130 2.4 20.0
20.2 10110621.220.0µg/Lcis-1,2-Dichloroethene 70-130 4.8 20.0
20.4 10210921.720.0µg/Ltrans-1,2-Dichloroethene 70-130 6.1 20.0
18.8 94.010120.120.0µg/L1,2-Dichloropropane 70-130 6.6 20.0
20.1 10110721.420.0µg/L1,3-Dichloropropane 70-130 6.2 20.0
19.9 99.510621.220.0µg/L2,2-Dichloropropane 70-130 6.3 20.0
19.9 99.510320.520.0µg/L1,1-Dichloropropene 70-130 2.9 20.0
20.3 10210721.420.0µg/Lcis-1,3-Dichloropropene 70-130 5.2 20.0
20.3 10210721.420.0µg/Ltrans-1,3-Dichloropropene 70-130 5.2 20.0
575 115105526500µg/LEthanol 60-140 8.9 20.0
19.8 99.010220.420.0µg/LEthylbenzene 70-130 2.9 20.0
42.5 10611043.840.0µg/LEthyl Tertiary Butyl Ether (ETBE)70-130 3.0 20.0
20.5 10310821.620.0µg/LHexachlorobutadiene 70-130 5.2 20.0
19.9 99.510120.220.0µg/L2-Hexanone 60-140 1.4 20.0
19.9 99.510220.320.0µg/LIsopropylbenzene 70-130 1.9 20.0
20.5 10310721.320.0µg/L4-Isopropyl toluene 70-130 3.8 20.0
22.4 11294.518.920.0µg/LMethyl Ethyl Ketone (MEK)60-140 16.9 20.0
20.6 10310521.020.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
19.8 99.010520.920.0µg/L4-Methyl-2-Pentanone 60-140 5.4 20.0
20.0 10010420.720.0µg/LMethylene Chloride 70-130 3.4 20.0
18.2 91.094.518.920.0µg/LNaphthalene 70-130 3.7 20.0
19.8 99.010320.620.0µg/Ln-Propylbenzene 70-130 3.9 20.0
20.7 10410821.520.0µg/LStyrene 70-130 3.7 20.0
49.1 12312248.840.0µg/Ltert-Butyl formate (TBF)40-140 0.6 20.0
43.0 10810943.540.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 1.1 20.0
21.0 10510621.220.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.9 20.0
Page 6 of 19Date:07/20/2022 04:15 PM
Page 35 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21339QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21337
LCS-V21337 LCSD-V21337Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.8 10410120.220.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.9 20.0
19.8 99.010420.720.0µg/LTetrachloroethene 70-130 4.4 20.0
19.3 96.510020.020.0µg/LToluene 70-130 3.5 20.0
19.5 97.510420.720.0µg/L1,2,3-Trichlorobenzene 70-130 5.9 20.0
19.7 98.510120.220.0µg/L1,2,4-Trichlorobenzene 70-130 2.5 20.0
20.5 10310621.120.0µg/L1,1,1-Trichloroethane 70-130 2.8 20.0
21.0 10510420.820.0µg/L1,1,2-Trichloroethane 70-130 0.9 20.0
19.7 98.510320.520.0µg/LTrichloroethene 70-130 3.9 20.0
20.1 10110621.220.0µg/LTrichlorofluoromethane 60-140 5.3 20.0
19.4 97.010320.520.0µg/L1,2,3-Trichloropropane 70-130 5.5 20.0
19.8 99.010020.020.0µg/L1,2,4-Trimethylbenzene 70-130 1.0 20.0
19.9 99.510420.720.0µg/L1,3,5-Trimethylbenzene 70-130 3.9 20.0
23.6 11812725.320.0µg/LVinyl Acetate 60-140 6.9 20.0
19.0 95.010220.420.0µg/LVinyl Chloride 60-140 7.1 20.0
20.1 10110320.620.0µg/Lo-Xylene 70-130 2.4 20.0
40.7 10210642.340.0µg/Lm,p-Xylene 70-130 3.8 20.0
99.099.44-Bromofluorobenzene (S)70-130
99.8102Dibromofluoromethane (S)70-130
98.498.61,2-Dichloroethane - d4 (S)70-130
99.4101Toluene-d8 (S)70-130
Page 7 of 19Date:07/20/2022 04:15 PM
Page 36 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V21409QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V21408
Associated Lab Samples: 93939
LRB-V21408 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/15/22 13:431.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
07/15/22 13:4310.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
07/15/22 13:4310.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
07/15/22 13:434-Bromofluorobenzene (S)100 70-130
07/15/22 13:43Dibromofluoromethane (S)96.6 70-130
07/15/22 13:431,2-Dichloroethane - d4 (S)98.4 70-130
07/15/22 13:43Toluene-d8 (S)98.8 70-130
LCS-V21408 LCSD-V21408Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.8 10410220.420.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
43.6 10910642.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 3.2 20.0
19.3 96.511322.520.0µg/Ltert-Amyl Alcohol (TAA)40-140 15.3 20.0
98.899.04-Bromofluorobenzene (S)70-130
99.699.8Dibromofluoromethane (S)70-130
99.096.41,2-Dichloroethane - d4 (S)70-130
98.699.2Toluene-d8 (S)70-130
Page 8 of 19Date:07/20/2022 04:15 PM
Page 37 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
Associated Lab Samples: 93940, 93943
LRB-V21179 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 12:080.0200.002<0.002mg/KgAcetone
07/12/22 12:080.0200.001<0.001mg/KgAcrolein
07/12/22 12:080.0200.0008<0.0008mg/KgAcrylonitrile
07/12/22 12:080.0050.0006<0.0006mg/KgBenzene
07/12/22 12:080.0050.0005<0.0005mg/KgBromobenzene
07/12/22 12:080.0050.0008<0.0008mg/KgBromochloromethane
07/12/22 12:080.0050.001<0.001mg/KgBromodichloromethane
07/12/22 12:080.0050.001<0.001mg/KgBromoform
07/12/22 12:080.0100.001<0.001mg/KgBromomethane
07/12/22 12:080.0050.0005<0.0005mg/Kgn-Butylbenzene
07/12/22 12:080.0050.0006<0.0006mg/Kgsec-Butyl benzene
07/12/22 12:080.0050.0005<0.0005mg/Kgtert-Butyl benzene
07/12/22 12:080.0050.0006<0.0006mg/KgCarbon Disulfide
07/12/22 12:080.0050.001<0.001mg/KgCarbon Tetrachloride
07/12/22 12:080.0050.0007<0.0007mg/KgChlorobenzene
07/12/22 12:080.0050.0009<0.0009mg/KgChlorodibromomethane
07/12/22 12:080.0100.0009<0.0009mg/KgChloroethane
07/12/22 12:080.0050.001<0.001mg/KgChloroform
07/12/22 12:080.0100.0006<0.0006mg/KgChloromethane
07/12/22 12:080.0050.0005<0.0005mg/Kg2-Chlorotoluene
07/12/22 12:080.0050.0004<0.0004mg/Kg4-Chlorotoluene
07/12/22 12:080.0050.0007<0.0007mg/KgDi-Isopropyl Ether (DIPE)
07/12/22 12:080.0100.0004<0.0004mg/Kg1,2-Dibromo-3-Chloropropane
07/12/22 12:080.0050.0006<0.0006mg/Kg1,2-Dibromoethane
07/12/22 12:080.0050.0006<0.0006mg/KgDibromomethane
07/12/22 12:080.0050.0003<0.0003mg/Kg1,2-Dichlorobenzene
07/12/22 12:080.0050.0004<0.0004mg/Kg1,3-Dichlorobenzene
Page 9 of 19Date:07/20/2022 04:15 PM
Page 38 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
Associated Lab Samples: 93940, 93943
LRB-V21179 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 12:080.0050.0006<0.0006mg/Kg1,4-Dichlorobenzene
07/12/22 12:080.0100.001<0.001mg/KgDichlorodifluoromethane
07/12/22 12:080.0050.0008<0.0008mg/Kg1,1-Dichloroethane
07/12/22 12:080.0050.001<0.001mg/Kg1,2-Dichloroethane
07/12/22 12:080.0050.0007<0.0007mg/Kg1,1-Dichloroethene
07/12/22 12:080.0050.0008<0.0008mg/Kgcis-1,2-Dichloroethene
07/12/22 12:080.0050.001<0.001mg/Kgtrans-1,2-Dichloroethene
07/12/22 12:080.0050.0004<0.0004mg/Kg1,2-Dichloropropane
07/12/22 12:080.0050.0006<0.0006mg/Kg1,3-Dichloropropane
07/12/22 12:080.0050.001<0.001mg/Kg2,2-Dichloropropane
07/12/22 12:080.0050.0008<0.0008mg/Kg1,1-Dichloropropene
07/12/22 12:080.0050.0005<0.0005mg/Kgcis-1,3-Dichloropropene
07/12/22 12:080.0050.0008<0.0008mg/Kgtrans-1,3-Dichloropropene
07/12/22 12:080.0050.0006<0.0006mg/KgEthylbenzene
07/12/22 12:080.0500.0008<0.0008mg/KgEthyl Tertiary Butyl Ether (ETBE)
07/12/22 12:080.0100.0008<0.0008mg/KgHexachlorobutadiene
07/12/22 12:080.0100.0007<0.0007mg/Kgn-Hexane
07/12/22 12:080.0200.0006<0.0006mg/Kg2-Hexanone
07/12/22 12:080.0050.0005<0.0005mg/KgIsopropylbenzene
07/12/22 12:080.0050.001<0.001mg/Kg4-Isopropyl toluene
07/12/22 12:080.0200.0007<0.0007mg/KgMethyl Ethyl Ketone (MEK)
07/12/22 12:080.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
07/12/22 12:080.0200.015<0.015mg/Kg4-Methyl-2-Pentanone
07/12/22 12:080.0100.001<0.001mg/KgMethylene Chloride
07/12/22 12:080.0100.0010<0.0010mg/KgNaphthalene
07/12/22 12:080.0050.0005<0.0005mg/Kgn-Propylbenzene
07/12/22 12:080.0050.001<0.001mg/KgStyrene
Page 10 of 19Date:07/20/2022 04:15 PM
Page 39 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
Associated Lab Samples: 93940, 93943
LRB-V21179 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/12/22 12:080.0050.001<0.001mg/Kg1,1,1,2-Tetrachloroethane
07/12/22 12:080.0050.0003<0.0003mg/Kg1,1,2,2-Tetrachloroethane
07/12/22 12:080.0050.0009<0.0009mg/KgTetrachloroethene
07/12/22 12:080.0050.0007<0.0007mg/KgToluene
07/12/22 12:080.0100.0005<0.0005mg/Kg1,2,3-Trichlorobenzene
07/12/22 12:080.0100.0006<0.0006mg/Kg1,2,4-Trichlorobenzene
07/12/22 12:080.0050.001<0.001mg/Kg1,1,1-Trichloroethane
07/12/22 12:080.0050.0005<0.0005mg/Kg1,1,2-Trichloroethane
07/12/22 12:080.0050.0009<0.0009mg/KgTrichloroethene
07/12/22 12:080.0100.002<0.002mg/KgTrichlorofluoromethane
07/12/22 12:080.0050.0007<0.0007mg/Kg1,2,3-Trichloropropane
07/12/22 12:080.0050.0005<0.0005mg/Kg1,2,4-Trimethylbenzene
07/12/22 12:080.0050.0005<0.0005mg/Kg1,3,5-Trimethylbenzene
07/12/22 12:080.0100.0005<0.0005mg/KgVinyl Acetate
07/12/22 12:080.0100.0005<0.0005mg/KgVinyl Chloride
07/12/22 12:080.0050.0005<0.0005mg/Kgo-Xylene
07/12/22 12:080.0100.001<0.001mg/Kgm,p-Xylene
07/12/22 12:084-Bromofluorobenzene (S)101 70-130
07/12/22 12:08Dibromofluoromethane (S)103 84-123
07/12/22 12:08Toluene-d8 (S)95.8 76-129
LCS-V21179 LCSD-V21179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.094 94.996.40.0960.100mg/KgAcetone 29-198 1.5 20
0.093 93.089.90.0890.100mg/KgAcrolein 70-130 3.3 20
Page 11 of 19Date:07/20/2022 04:15 PM
Page 40 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
LCS-V21179 LCSD-V21179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.113 1131120.1120.100mg/KgAcrylonitrile 65-134 0.8 20
0.052 1051080.0540.050mg/KgBenzene 74-127 2.8 20
0.048 96.699.00.0490.050mg/KgBromobenzene 73-125 2.4 20
0.055 1111140.0560.050mg/KgBromochloromethane 72-134 2.3 20
0.052 1051060.0520.050mg/KgBromodichloromethane 75-122 0.9 20
0.048 96.096.60.0480.050mg/KgBromoform 66-135 0.6 20
0.051 1031060.0530.050mg/KgBromomethane 20-180 3.0 20
0.049 98.01020.0510.050mg/Kgn-Butylbenzene 65-135 4.0 20
0.046 93.897.60.0480.050mg/Kgsec-Butyl benzene 66-131 3.9 20
0.046 93.295.40.0470.050mg/Kgtert-Butyl benzene 67-132 2.3 20
0.052 1061120.0560.050mg/KgCarbon Disulfide 61-129 5.8 20
0.050 1011050.0520.050mg/KgCarbon Tetrachloride 64-143 3.5 20
0.049 99.01030.0510.050mg/KgChlorobenzene 74-118 3.7 20
0.047 95.896.40.0480.050mg/KgChlorodibromomethane 73-122 0.6 20
0.052 1051120.0560.050mg/KgChloroethane 33-149 6.2 20
0.052 1041080.0530.050mg/KgChloroform 73-127 3.0 20
0.045 91.297.00.0480.050mg/KgChloromethane 45-143 6.1 20
0.047 95.698.40.0490.050mg/Kg2-Chlorotoluene 67-124 2.8 20
0.047 95.898.40.0490.050mg/Kg4-Chlorotoluene 71-126 2.6 20
0.058 1161170.0580.050mg/KgDi-Isopropyl Ether (DIPE)59-159 1.1 20
0.047 94.490.00.0450.050mg/Kg1,2-Dibromo-3-Chloropropane 55-157 4.7 20
0.049 98.898.60.0490.050mg/Kg1,2-Dibromoethane 70-132 0.2 20
0.053 1081090.0540.050mg/KgDibromomethane 74-133 0.9 20
0.048 96.296.80.0480.050mg/Kg1,2-Dichlorobenzene 72-123 0.6 20
0.048 96.499.00.0490.050mg/Kg1,3-Dichlorobenzene 71-120 2.6 20
0.048 96.098.40.0490.050mg/Kg1,4-Dichlorobenzene 71-123 2.4 20
Page 12 of 19Date:07/20/2022 04:15 PM
Page 41 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
LCS-V21179 LCSD-V21179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.040 81.084.20.0420.050mg/KgDichlorodifluoromethane 26-146 3.8 20
0.055 1101130.0560.050mg/Kg1,1-Dichloroethane 74-127 2.5 20
0.055 1111110.0550.050mg/Kg1,2-Dichloroethane 68-128 0.3 20
0.054 1081130.0560.050mg/Kg1,1-Dichloroethene 67-149 4.5 20
0.055 1111150.0570.050mg/Kgcis-1,2-Dichloroethene 76-134 3.1 20
0.055 1101150.0570.050mg/Kgtrans-1,2-Dichloroethene 73-132 4.6 20
0.055 1101120.0550.050mg/Kg1,2-Dichloropropane 73-130 1.2 20
0.050 1011020.0510.050mg/Kg1,3-Dichloropropane 75-124 0.9 20
0.053 1061110.0550.050mg/Kg2,2-Dichloropropane 50-142 4.5 20
0.052 1041140.0560.050mg/Kg1,1-Dichloropropene 71-130 8.6 20
0.054 1091110.0550.050mg/Kgcis-1,3-Dichloropropene 71-125 1.6 20
0.054 1101110.0550.050mg/Kgtrans-1,3-Dichloropropene 68-123 1.6 20
0.048 96.61010.0500.050mg/KgEthylbenzene 74-128 4.0 20
0.113 1131120.1120.100mg/KgEthyl Tertiary Butyl Ether (ETBE)70-130 0.8 20
0.046 92.094.40.0470.050mg/KgHexachlorobutadiene 64-125 2.5 20
0.053 1061160.0570.050mg/Kgn-Hexane 70-130 8.8 20
0.051 1031030.0510.050mg/Kg2-Hexanone 61-157 0.3 20
0.043 87.892.20.0460.050mg/KgIsopropylbenzene 68-126 4.8 20
0.047 95.098.20.0490.050mg/Kg4-Isopropyl toluene 68-129 3.3 20
0.053 1081060.0520.050mg/KgMethyl Ethyl Ketone (MEK)63-149 1.8 20
0.052 1061060.0530.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.5 20
0.058 1161150.0570.050mg/Kg4-Methyl-2-Pentanone 57-162 1.2 20
0.055 1111130.0560.050mg/KgMethylene Chloride 74-129 1.7 20
0.047 94.291.00.0450.050mg/KgNaphthalene 57-157 3.4 20
0.048 97.01000.0500.050mg/Kgn-Propylbenzene 67-130 3.4 20
0.049 99.41020.0500.050mg/KgStyrene 77-121 2.3 20
Page 13 of 19Date:07/20/2022 04:15 PM
Page 42 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21180QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 LOW
QC Prep:V21179
LCS-V21179 LCSD-V21179Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.050 1001000.0500.050mg/Kg1,1,1,2-Tetrachloroethane 72-115 0.3 20
0.047 94.895.00.0470.050mg/Kg1,1,2,2-Tetrachloroethane 56-126 0.2 20
0.052 1051110.0550.050mg/KgTetrachloroethene 68-130 5.1 20
0.052 1051090.0540.050mg/KgToluene 71-129 4.1 20
0.048 96.494.20.0470.050mg/Kg1,2,3-Trichlorobenzene 68-130 2.3 20
0.048 97.298.20.0490.050mg/Kg1,2,4-Trichlorobenzene 66-125 1.0 20
0.051 1021070.0530.050mg/Kg1,1,1-Trichloroethane 67-131 4.0 20
0.047 94.295.80.0470.050mg/Kg1,1,2-Trichloroethane 70-133 1.6 20
0.053 1071110.0550.050mg/KgTrichloroethene 75-133 3.8 20
0.053 1061140.0560.050mg/KgTrichlorofluoromethane 44-146 7.0 20
0.048 97.695.60.0470.050mg/Kg1,2,3-Trichloropropane 60-137 2.0 20
0.048 96.098.60.0490.050mg/Kg1,2,4-Trimethylbenzene 69-129 2.6 20
0.047 94.498.60.0490.050mg/Kg1,3,5-Trimethylbenzene 69-128 4.3 20
0.047 95.093.80.0460.050mg/KgVinyl Acetate 60-140 1.2 20
0.050 1011060.0530.050mg/KgVinyl Chloride 48-147 5.2 20
0.047 95.499.60.0490.050mg/Kgo-Xylene 74-126 4.3 20
0.095 95.599.20.0990.100mg/Kgm,p-Xylene 75-124 3.8 20
99.898.24-Bromofluorobenzene (S)70-130
103103Dibromofluoromethane (S)84-123
95.096.4Toluene-d8 (S)76-129
Page 14 of 19Date:07/20/2022 04:15 PM
Page 43 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
8260D
V21288QC Analytical Batch(es):
Analysis Method:
Analysis Description:
5035 MED
QC Prep:V21287
Associated Lab Samples: 93943
LRB-V21287 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 11:490.0050.0006<0.0006mg/KgMethyl tert-butyl ether (MTBE)
07/14/22 11:494-Bromofluorobenzene (S)101 70-130
07/14/22 11:49Dibromofluoromethane (S)101 70-130
07/14/22 11:49Toluene-d8 (S)94.6 76-129
LCS-V21287 LCSD-V21287Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.049 99.499.00.0490.050mg/KgMethyl tert-butyl ether (MTBE)70-130 0.4 20
98.698.44-Bromofluorobenzene (S)70-130
105103Dibromofluoromethane (S)70-130
95.094.8Toluene-d8 (S)76-129
Page 15 of 19Date:07/20/2022 04:15 PM
Page 44 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V21440QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V21417
Associated Lab Samples: 93939
LRB-V21417 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
07/18/22 12:570.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V21417 LCSD-V21417Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.277 1111070.2670.250µg/L1,2-Dibromoethane 70-130 3.6 20.0
V 93965-DUP-V21417Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/18/22 15:340.0<0.0210< 0.0210µg/L1,2-Dibromoethane
V 93939-MS-V21417Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.255 95.80.266< 0.00351µg/L1,2-Dibromoethane 70-130
Page 16 of 19Date:07/20/2022 04:15 PM
Page 45 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V21223QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V21222
Associated Lab Samples: 93940, 93941, 93943
LRB-V21222 Matrix: SOLLab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/13/22 14:438.001.22<1.22mg/KgAliphatic C5-C8
07/13/22 14:438.004.56<4.56mg/KgAliphatic C9-C12
07/13/22 14:438.000.624<0.624mg/KgAromatic C9-C10
07/13/22 14:432,5-Dibromotoluene (FID) (S)100 70-130
07/13/22 14:432,5-Dibromotoluene (PID) (S)84.4 70-130
LCS-V21222 LCSD-V21222Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
36.2 11311436.632.0mg/KgAliphatic C5-C8 70-130 1.0 50
38.6 12111837.932.0mg/KgAliphatic C9-C12 70-130 1.8 50
12.6 11811912.710.7mg/KgAromatic C9-C10 70-130 0.7 50
77.390.72,5-Dibromotoluene (FID) (S)70-130
76.182.82,5-Dibromotoluene (PID) (S)70-130
Page 17 of 19Date:07/20/2022 04:15 PM
Page 46 of 50
Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V21308QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V21307
Associated Lab Samples: 93939
LRB-V21307 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
07/14/22 18:3550.011.5<11.5µg/LAliphatic C5-C8
07/14/22 18:3550.025.8<25.8µg/LAliphatic C9-C12
07/14/22 18:3550.04.02<4.02µg/LAromatic C9-C10
07/14/22 18:352,5-Dibromotoluene (FID) (S)95.4 70-130
07/14/22 18:352,5-Dibromotoluene (PID) (S)91.0 70-130
LCS-V21307 LCSD-V21307Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
294 98.096.0288300µg/LAliphatic C5-C8 70-130 2.0 50.0
318 106106318300µg/LAliphatic C9-C12 70-130 0.0 50.0
102 102105105100µg/LAromatic C9-C10 70-130 2.8 50.0
79.979.32,5-Dibromotoluene (FID) (S)70-130
77.577.82,5-Dibromotoluene (PID) (S)70-130
Page 18 of 19Date:07/20/2022 04:15 PM
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Quality Control Data
22-189-0051Report No:
Project Description:
Client ID:Geological Resources, Inc.
Flash Market #370
Dry Weight Determination
SW-DRYWT
V21320QC Analytical Batch:
Analysis Method:
Analysis Description:
V 93768-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/15/22 10:330.920.921.1%Moisture
V 94001-DUPDuplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 07/15/22 10:330.423.924.0%Moisture
Page 19 of 19Date:07/20/2022 04:15 PM
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Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-189-0051
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 1.3
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
ü
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)ü
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Sample SP-2-2 missing jar for % solids. Results can not be reported as dry
weight.
Signature:Adam Crouch Date & Time:07/08/2022 18:43:37
Special precautions or instructions included?
Comments:
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