RA-28474_47726_CA_LSA_20230207_3963 Raleigh Rd Henderson NC

100 East Ruffin Street ꞏMebane, North Carolina 27302
Telephone [phone] ꞏFacsimile [phone]
www.terraquestpc.com

SITE CHECK & LIMITED SITE ASSESSMENT REPORT
(PHASE I)

BEARPOND MARKET
3963 RALEIGH RD.
HENDERSON, VANCE COUNTY, NORTH CAROLINA

Latitude: 36.27755° N Longitude: -78.40579° W

Release Information
Date Discovered: April 14, 2021
Estimated Release Quantity: Unknown
Release Cause/Source: Commercial USTs
Capacities: 8,000-gal. Gas, One-10,000-gal. Gas
Facility ID: 00-0-0000030637
NCDWM-UST Incident No.: 47726

Prepared For:
Mr. Billy Stanton
Bearpond Market, Inc.
1600 N Lynnbank Rd
Henderson, NC 27537

Terraquest Project No. 00323
February 7, 2023

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 i Henderson, NC
CERTIFICATION FOR THE SUBMITTAL
OF AN ENVIRONMENTAL / GEOLOGICAL ASSESSMENT

Attached is the Site Check & Limited Site Assessment Report (Phase I) for:

Property Owner: NQ Investments, LLC
Address: 3963 Raleigh Rd.
City: Henderson State: NC Zip Code: 27537

Tank Owner: JNH Investments, Inc.
Address: 11521 Colbert Creek Loop, Apt. 306
City: Raleigh State: NC Zip Code: 27614

Site Name: Bearpond Market
Address: 3963 Raleigh Rd.
City: Henderson State: NC Zip Code: 27537

I, Jonathan R. Grubbs, a Licensed Geologist in the State of North Carolina for Terraquest
Environmental Consultants, P.C. do hereby certify that I am familiar with and have reviewed all
material including figures within this report and that to the best of my knowledge the data, site
assessments, figures, and other associated materials are correct and accurate. All work was
performed under my direct supervision. My seal and signature are affixed below. Additional
seals and/or signatures are also affixed below.

Terraquest Environmental Consultants, P.C. is licensed to practice geology and engineering in
North Carolina. The geology certification number of the corporation is C-291. The engineering
certification number of the corporation is C-4634. Engineering is practiced out of the Cary, NC
office.

TERRAQUEST ENVIRONMENTAL CONSULTANTS, P.C.

Ryan D. Kerins Jonathan R. Grubbs, P.G.
Project Manager Vice President

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 ii Henderson, NC
TABLE OF CONTENTS
1.0 INTRODUCTION ................................................................................................................. 1
2.0 Site Characteristics and History ......................................................................................... 1
3.0 RISK CHARACTERIZATION AND RECEPTOR INFORMATION ................................................ 2
4.0 SITE GEOLOGY AND HYDROGEOLOGY ............................................................................... 4
5.0 SOURCE INVESTIGATION ................................................................................................... 5
5.1 LSA Investigation ........................................................................................................... 5
6.0 CONCLUSIONS AND RECOMMENDATIONS ........................................................................ 8
7.0 LIMITATIONS ..................................................................................................................... 9
REFERENCES ................................................................................................................................ 10

TABLES

1. Site History (UST System Information)
2. Surrounding Property Owners
3. Water Supply Well Information
4. Monitoring Well Construction Information
5. Summary of Soil Sampling Results – Site Check
6. Summary of Soil Sampling Results – LSA
7. Summary of Groundwater Sampling Results

FIGURES

1. Site Location Map
2. Site Vicinity Map
3. Site Layout & Site Check/LSA Sample Location Map

APPENDICES

A. Environmental Acronyms and Technical Methods /Standard Procedures
B. UST and Product Line Tightness Testing & Phase II ESA Report dated April 12, 2021
C. Limited Site Assessment Risk Classification and Land Use Form
D. Well Construction Record and Boring Logs
E. Analytical Reports

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 1 Henderson, NC
1.0 INTRODUCTION

Terraquest Environmental Consultants, P.C. has performed limited site assessment activities at
the Bearpond Market property located at 3963 Raleigh Rd. in Henderson, Vance County, North
Carolina. A release was discovered in April 2021 during a Phase II Environmental Site Assessment
(ESA). During that ESA, a groundwater sample collected in the vicinity of the gasoline USTs
revealed the presence of a petroleum-type compound above the Title 15A NCAC 2L Groundwater
Quality Standards (2L Standards). This report has been prepared to comply with those
requirements set forth under Title 15A of the NCAC Subchapter 2L Section .0405. The gasoline
UST system is a commercial and regulated given its current use for fueling cars and trucks for
resale.

The site location is shown in Figure 1. The surrounding vicinity is shown in Figure 2. A site layout
map is included as Figure 3. Environmental Acronyms and Technical Methods and Standard
Procedures typically utilized by Terraquest personnel are detailed in Appendix A.

2.0 Site Characteristics and History

The subject property totals 1.67-acres in size and contains a 3,382 sq. ft. convenience store
building built in 1993. The remaining property is an asphalt parking lot and grass pasture. The
subject property is located outside the city limits of Henderson, NC at the intersection of Raleigh
Rd. and Bearpond Rd. The subject property is relatively flat with a gentle slope to the northeast.

On March 24, 2021, Highlands Environmental Solutions, Inc. of Raleigh, NC personnel mobilized
to the Bearpond Market site to conduct a Phase II ESA. The Phase II ESA was completed as part
of a pending sale of the property. Table 1 lists the UST information for the UST system. The
locations of the USTs are depicted in Figure 3.

Results of the Phase II ESA revealed the absence of soil contamination above the above the
NCDEQ DWM-UST Action Limits and the presence of groundwater contamination above the 2L

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 2 Henderson, NC
Standards in the vicinity of the current UST basin. Summary tables of the soil and groundwater
samples are included Phase II ESA dated April 12, 2021 in Appendix B.

Based upon the presence of groundwater contamination above the 2L Standards, the NCDEQ
DWM-UST required the completion of a LSA Phase I, some additional soil borings in the vicinity
of the UST system to satisfy the site check investigation beyond the March 24, 2021 Phase II ESA,
and product line and UST tightness testing. All of the product line and UST compliance testing
indicates the UST system is currently operating correctly. Copies of the most recent product line
and UST tightness testing are included in Appendix B.

3.0 RISK CHARACTERIZATION AND RECEPTOR INFORMATION

In order to determine the risk classification of the site, Terraquest personnel performed a
reconnaissance of properties within a 1,000-foot radius of the source area on January 5, 2023.
The reconnaissance effort consisted of obtaining tax department and local zoning information on
properties and conducting door-to-door visits of certain properties within 1,000 feet of the
source area, in addition to collecting other pertinent information from the appropriate local and
state officials. Terraquest personnel inspected all properties within 1,000 feet of the site and
contacted all of the property owners within 1,000 feet in person. Property owners were
questioned, if available, as to the source of their water and if any water supply wells were located
on their property. In all cases, Terraquest also conducted a visual survey of the property.

According to the City of Henderson Water Department, municipal water is available to properties
within a 1,000-ft. radius of the subject property along Raleigh Rd. and Bearpond Rd. Municipal
water is not available along N. Lynnbank Rd. to the west from the Bearpond Rd. intersection and
further south along Raleigh Rd. from the Bearpond Rd. intersection. The site vicinity and
surrounding properties are presented in Figure 2. Twenty-three (23) water supply wells were
found within a 1,000-foot radius. Eleven (11) of those wells are active drinking water supply
wells. The locations of the identified water supply wells are depicted in Figure 2. Surrounding

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 3 Henderson, NC
property owners/occupants are detailed in Table 2. Water supply wells within a 1,000-ft. radius
are listed in Table 3.

Surface Water:

As part of the reconnaissance effort, Terraquest also searched for any surface water bodies
within a 500-foot radius of the site. No perennial surface water bodies were identified within
this search area.

Zoning:

The subject property is located outside the city limits of Henderson, NC within the Vance County
zoning jurisdiction. The subject property is currently occupied by a convenience store with a
commercial UST system. The subject property and surrounding properties to the north, south,
and further west have Vance County residential zoning classifications. The surrounding
properties to the west have a Vance County Office/Institutional zoning classification. The
surrounding properties to the south and east have a Vance County General Commercial zoning
classification. The surrounding properties to the east have a Vance County Highway Commercial
zoning classification. The surrounding properties to the southwest and northeast have a Vance
County Manufactured Housing Community zoning classification. Zoning information of the
subject and surrounding properties is shown in Figure 2.

LSA Risk Classification and Land Use Form

A review of the Limited Site Assessment Risk Classification and Land Use Form reveals that the
UST release incident should be ranked a “High Risk”. The ranking is due to the presence of soil
contamination above the Soil-to-Groundwater Maximum Soil Contaminant Concentrations (S-t-
G MSCCs) and the presence of active water supply wells within a 1,000-foot radius; however,
given the very minor soil contaminant concentrations and the absence of groundwater
contamination detected in the monitoring well MW1 above the 2L Standards, the release

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 4 Henderson, NC
incident may qualify for a “Low” risk classification. A completed Limited Site Assessment Risk
Classification and Land Use Form has been included as Appendix C.

4.0 SITE GEOLOGY AND HYDROGEOLOGY

Regional Geology and Topography:

The subject property is located in the Piedmont Physiographic Province of North Carolina. On a
regional scale, the Piedmont is characterized by land with medium to low relief. Based upon the
examination of the Henderson, NC USGS topo maps and Vance County GIS website, the general
elevation of the subject property ranges from approximately 514 feet above mean sea level (MSL)
in the southeast corner to 506 feet above MSL along the northern property boundary. Elevations
in the vicinity range from approximately 414 feet above MSL at the subject property to 502 feet
above MSL to the north.

The subject property slopes from south to north. Overland water across the subject property will
flow to the north-northeast.

More specifically within the Piedmont Physiographic Province, and according to the 1985
Geologic Map of North Carolina, the subject property lies within the Raleigh Belt of the Piedmont
Physiographic Province. The subsurface geology is mapped as mostly intrusive rocks consisting
of foliated to massive granitic rock.

Monitoring Well Installation:

As part of the LSA, Terraquest personnel supervised the installation of groundwater monitoring
well MW1 on January 5, 2023. The well was installed adjacent to the UST basin in the interpreted
downgradient direction. The monitoring well was installed with solid-stem augers using a
Geoprobe Model 7728DT drilling rig operated by an NC-Licensed driller. The well was
constructed with a screen interval that brackets the water table to allow for the entry of any

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 5 Henderson, NC
present free-phase product (LNAPL). After the construction, Terraquest developed the well to
allow for the removal of fine sediment that might otherwise clog the screen and prevent
collection of a representative aquifer sample. Construction details for the monitoring wells are
listed in Table 4. The location of the monitoring well is depicted in Figure 3. The well construction
record and boring log are included in Appendix D.

The following lithologies were encountered at the site during the installation of the monitoring
well:
0' – 0.5’ BGL
Asphalt

0.5’ – 6’ BGL
SANDY CLAY (CL)
Medium stiff, yellowish/orange, mostly clay with some fine-grained sand, dry

6’ – 11’ BGL
SANDY CLAY (CL)
Medium stiff to soft at 8 feet BGL, grey/tan minor yellowish-orange, moist @ 9
feet BGL

11’ – 20’ BGL
SANDY SILT (ML)
Soft, white/grey, mostly silt, little fine-grained sand, dry

5.0 SOURCE INVESTIGATION

Assessment of the subject petroleum release incident was performed during the Site Check and
LSA investigations.

5.1 LSA Investigation

Since the gasoline UST system is considered a commercial UST, the NCDEQ DWM DEQ required
that site check soil borings be collected in the vicinity of the UST system and an LSA be completed
to determine the risk-classification of the release incident. The following is a summary of the soil
and groundwater sampling completed for the Site Check and LSA.

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 6 Henderson, NC
Soil Sampling:

During the Site Check and Phase I LSA, Terraquest collected soil samples in the vicinity of the UST
system in areas not addressed in the March 2021 Phase II ESA.

To determine soil quality at the subject property, Terraquest advanced the following soil borings:
 SB1 through SB6 - in the vicinity of the current gasoline UST basin
 SB7 – in the vicinity of the current southern gasoline dispenser

The soil borings were advanced using direct push technology and a Macro-Core tube retrieval
sampling system. Direct push technology consists of advancing a sampling device into the
subsurface soils by applying static pressure, by applying impacts, by applying vibration, or any
combination thereof, to the above ground portion of the sampler extensions until the sampler
has advanced to the desired depth (ASTM D6282). A single tube Macro-Core sample system was
utilized to collect soil samples in five-foot intervals. A single tube sample system used a hollow
extension/drive rod to advance and retrieve the sampler. Within the hollow extension, a new,
single-use, poly-vinyl chloride (PVC) liner retained the soil sample as the tube is driven into the
ground. The specific direct push equipment utilized was a Geoprobe 7822DT. The Macro-Core
tube was decontaminated between each 5-foot sample interval in a soil boring using a Liquinox
and tap-water mixture. A new PVC liner was used to collect soil from each sample interval in a
soil boring. Technical Methods and Standard Procedures utilized by Terraquest are attached.

The soil boring depths were determined based upon the depth of the component sampled and
to determine if a potential release has migrated vertically. The SB1, SB2, SB3, SB6, and SB7 soil
borings were advanced to 10 feet below ground level (BGL). Soil borings MW1/SB4 and SB5 were
advanced to a depth of 15 feet BGL to determine the depth to groundwater and for the LSA soil
sample. In each soil boring, soils from the sample intervals were placed in sealable plastic bags
and screened for volatile organic compounds (VOCs) utilizing a Photoionization Detector (PID).
Soil lithology and PID measurements are included in the soil borings in Appendix D.

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 7 Henderson, NC

The soils to be submitted for analysis were determined by the estimated depths of the UST
system components:
 SB1 through SB3, MW1/SB4, SB5, and SB6 - the current gasoline UST basin (8 to 10 feet
BGL)
 SB7 – the current northern gasoline dispenser island (3 to 5 feet BGL)

The soil samples collected for analysis were placed in the proper laboratory-prepared sampling
containers, labeled with the project name, project number, sample identification, required
analysis, and date and time of collection. The samples were immediately placed on ice and
analyzed before the expiration of an analytical method’s prescribed holding time. The SB1, SB2,
SB3, SB5, SB6, and SB7 soil samples were analyzed for total petroleum hydrocarbons (TPH) for
low boiling point petroleum hydrocarbons (GRO) by UVF Trilogy technology to satisfy the Site
Check soil sampling requirements. The MW1/SB4 soil sample was analyzed by EPA Methods 8260
and MADEP Methods VPH to satisfy the LSA soil sampling requirements. Chain-of-custody
documentation was maintained for the soil samples. The soil borings were backfilled with
bentonite. The locations of the soil borings are depicted in Figure 3.

Soil Sample Analytical Results

The North Carolina Department of Environmental Quality Division of Waste Management UST
Section (NCDEQ DWM-UST) Action Limit of 50 milligram/kilogram (mg/kg) for TPH GRO was not
exceeded in any of the soil samples. The MW1/SB4 soil sample analytical results revealed a lone
estimated benzene concentration of 0.00615J mg/kg above its Soil-to-Groundwater Maximum
Soil Contaminant Concentration (S-t-G MSCC) of 0.0056 mg/kg. The soil analytical results are
included in Appendix E.

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 8 Henderson, NC
Groundwater Sampling:

On January 5, 2023, a groundwater sample was retrieved from monitoring well MW1 using the
standard sampling protocol detailed in Appendix A. Prior to sampling, Terraquest purged the
monitoring well of at least three well volumes using a new disposable bailer. The purge bailer
was also used to retrieve a representative groundwater sample. No free product was noted in
the monitoring well during the sampling event. The collected groundwater sample was placed in
laboratory-prepared sample containers, labeled, packed in ice, and shipped to a North Carolina-
certified laboratory for analysis prior to the expiration of the analytical method’s hold time. The
sample was submitted for laboratory analysis per EPA Method 6200B, MADEP VPH, 504.1 EDB,
and lead.

Analytical results for the groundwater samples collected from monitoring well MW1 revealed
detected concentrations of petroleum-type contaminant concentrations of benzene, toluene,
and lead. None of the detected concentrations were above their 2L Standards. Analytical results
for the MW1 groundwater sample are summarized in Table 7, and the location of monitoring well
MW1 is depicted in Figure 3. The full analytical report is contained in Appendix E.

6.0 CONCLUSIONS AND RECOMMENDATIONS

Terraquest performed various activities associated with the completion of a Site Check and
Limited Site Assessment. Primary assessment efforts focused on determining onsite soil and
groundwater quality in the vicinity of the UST system and identifying potential receptors in the
area; both critical steps in determining the extent of the release incident and risk ranking of the
site.

Terraquest concludes:

 The commercial, regulated gasoline UST system is active and in compliance with NCDEQ
DWM-UST regulations based upon recent UST compliance testing.

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 9 Henderson, NC
 Analytical results of soil samples collected during the Site Check and Phase I LSA revealed
the presence of a lone estimated benzene concentration in the MW1/SB4 soil sample of
0.00615 J mg/kg that exceeded its Soil-to-Groundwater MSCC (0.0056 mg/kg).
 A groundwater sample from monitoring well MW1 had no detected concentrations
greater than their 2L Standard.
 Through reconnaissance efforts, eleven (11) active drinking water supply wells were
identified within 1,000 feet of the source area. The subject property is connected to the
City of Henderson municipal water system.
 The risk classification can be lowered to a Low risk given the minor estimated benzene
soil concentration above its S-t-G MSCC and the absence of groundwater contamination
above the 2L Standards.

7.0 LIMITATIONS

This report is limited to the investigation of petroleum hydrocarbons in soil and groundwater and
does not imply that other unforeseen adverse impacts to the environment are not present at or
around the site in question. In addition, subsurface heterogeneities not identified during the
current study may influence the migration of groundwater or contaminants in unpredicted ways.
The limited amount of sampling and testing conducted during this study cannot practically reveal
all subsurface heterogeneities. Furthermore, the subsurface conditions, particularly
groundwater flow, elevations, and water quality, may vary through time. The opinions and
conclusions determined in this report are in accordance with industry-accepted geologic and
hydrogeologic practices at this time and location. No warranty is implied or intended.

Site Check & Phase I Limited Site Assessment Bearpond Market
Prepared by: Terraquest Environmental Consultants, P.C. 3963 Raleigh Rd.
Report Prepared: February 7, 2023 10 Henderson, NC
REFERENCE

Brown, Philip M., et al, 1985, Geologic Map of North Carolina, North Carolina Department of
Natural Resources and Community Development, 1:500,000 scale.

UST Section Assessment Guidelines, Petroleum and Hazardous Substance UST Releases, North
Carolina Department of Environmental Quality Division of Waste Management – UST
Section, January 19, 2021.

USGS 7.5-Minute Quadrangle Topographic Map, Henderson, NC 2019.

TABLES
Table 1
1/30/2023 Facility ID No.: 00-0-0000030637
Capacity
UST Product (Gallons) Release Discovered
T1 Gasoline 8,000 1/15/1993 In Use YES
T2 Gasoline 10,000 1/15/1993 In Use YES
Notes:
1. NA - Not Applicalbe
Date Installed Date Closed
Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726
SITE HISTORY (UST SYSTEM INFORMATION)
Table 2
Date: 1/30/23 Facility ID No.: 00-0-0000030637
Tax Parcel Number (PIN
Number)Property Owner Property Owner Address Property Address
Billy C. Stanton Deceased 735 N. Lynnbank Rd. 35 Bearpond Rd.
Henderson, NC 27537 Henderson, NC 27537
Billy C. Stanton Deceased 735 N. Lynnbank Rd. 59 Bearpond Rd.
Henderson, NC 27537 Henderson, NC 27537
Ruby Jean Investments, LLC 175 Bearpond Rd. 175 Bearpond Rd.
Henderson, NC 27537 Henderson, NC 27537
Fred A. & Loretta J. Bowes 3905 Raleigh Rd. 3905 Raleigh Rd.
Henderson, NC 27537 Henderson, NC 27537
Raleigh Road Baptist Church 3892 Raleigh Rd. 3892 Raleigh Rd.
Henderson, NC 27537 Henderson, NC 27537
Raleigh Road Baptist Church 3892 Raleigh Rd. 3964 Raleigh Rd.
Henderson, NC 27537 Henderson, NC 27537
Stewart T P Co., Inc.7416 Ligon Mill Rd. Raleigh Rd.
Wake Forest, NC 27587 Henderson, NC 27537
J. Patterson Enterprises, LLC P.O. Box 493 4005 Raleigh Rd.
Henderson, NC 27536 Henderson, NC 27537
NQ Investment, LLC 3963 Raleigh Rd. 3963 Raleigh Rd.
Henderson, NC 27537 Henderson, NC 27537
Notes:
1. Information gathered from field interviews and Vance County GIS Online.
2. Last four numbers of PIN correspond with those displayed on Figure 2.
SURROUNDING PROPERTY OWNERS
Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726
0224 02016
SITE
0224 02018
0224 02019
0224 02020
0224 02014
0453 01012 & 0453 01017A
0453 01017
0453 02001
0453 03001
Table 3
Date: 1/30/23 Facility ID No: 00-0-0000030637
Well Depth Type Casing Depth Screen Interval Distance from Source
Well ID No. Well Owner/Address Well Address Well Use (feet BGS)of Well (feet BGS)(feet BGS)Area of Release (feet)
Raleigh Road Baptist Church
PW1 3892 Raleigh Rd.3964 Raleigh Rd.Not in Use unknown drilled unknown unknown 178
Henderson, NC 27537 Henderson, NC 27537
Raleigh Road Baptist Church
PW2 3892 Raleigh Rd.3940 Raleigh Rd.Not in Use unknown drilled unknown unknown 150
Henderson, NC 27537 Henderson, NC 27537
Raleigh Road Baptist Church
PW3 3892 Raleigh Rd.3892 Raleigh Rd.Not in Use unknown drilled unknown unknown 540
Henderson, NC 27537 Henderson, NC 27537
Ruby Tant
PW4 P. O. Box 985 106 N. Lynnbank Rd.In Use unknown drilled unknown unknown 650
Henderson, NC 27536 Henderson, NC 27537
Dolly Woodruff
PW5 3881 Raleigh Rd 3881 Raleigh Rd Not in Use unknown drilled unknown unknown 340
Henderson, NC 27537 Henderson, NC 27537
Jo Ann Robertson Vaughan
PW6 3895 Raleigh Rd 3895 Raleigh Rd In Use unknown drilled unknown unknown 261
Henderson, NC 27537 Henderson, NC 27537
J Patterson Enterprises, LLC
PW7 P.O. Box 493 4005 Raleigh Rd In Use unknown drilled unknown unknown 365
Henderson, NC 27536 Henderson, NC 27537
Raleigh Road Baptist Church
PW8 3892 Raleigh Rd.3892 Raleigh Rd Not in Use unknown drilled unknown unknown 425
Henderson, NC 27537 Henderson, NC 27537
Ernest, Jr. & Jeanette Walker
PW9 126 N. Lynnbank Rd 126 N. Lynnbank Rd In Use unknown drilled unknown unknown 843
Henderson, NC 27537 Henderson, NC 27537
Linwood A. Cole
PW10 4167 Fairport Rd.150 N. Lynnbank Rd In Use unknown drilled unknown unknown 880
Kittrell, NC 27544 Henderson, NC 27537
Fred A. Bowes
PW11 3905 Raleigh Rd.3905 Raleigh Rd Not in Use unknown drilled unknown unknown 200
Henderson, NC 27537 Henderson, NC 27537
Billy C. & Elsie Stanton
PW12 735 N. Lynnbank Rd.35 Bearpond Rd.Not in Use unknown drilled unknown unknown 180
Henderson, NC 27537 Henderson, NC 27537
Billy C. & Elsie Stanton
PW13 735 N. Lynnbank Rd.59 Bearpond Rd.Not in Use unknown drilled unknown unknown 300
Henderson, NC 27537 Henderson, NC 27537
J Patterson Enterprises, LLC
PW14 P.O. Box 493 46 Bearpond Rd.In Use unknown drilled unknown unknown 375
Henderson, NC 27536 Henderson, NC 27537
Phyllis Hayes
PW15 118 Old Thomas Ln 128 Bearpond Rd.In Use unknown drilled unknown unknown 765
Henderson, NC 27537 Henderson, NC 27537
WATER SUPPLY WELL INFORMATION
Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726
Table 3
Date: 1/30/23 Facility ID No: 00-0-0000030637
Well Depth Type Casing Depth Screen Interval Distance from Source
Well ID No. Well Owner/Address Well Address Well Use (feet BGS)of Well (feet BGS)(feet BGS)Area of Release (feet)
WATER SUPPLY WELL INFORMATION
Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726
Marie Floyd
PW16 4051 Raleigh Rd 4051 Raleigh Rd In Use unknown drilled unknown unknown 580
Henderson, NC 27537 Henderson, NC 27537
Linwood Stokes
PW17 4081 Raleigh Rd 4081 Raleigh Rd In Use unknown drilled unknown unknown 670
Henderson, NC 27537 Henderson, NC 27537
Celister Richardson
PW18 4151 Raleigh Rd 4121 Raleigh Rd In Use unknown drilled unknown unknown 980
Henderson, NC 27537 Henderson, NC 27537
Kens Construction Company
PW19 451 Satterwhite Point Rd.3845 Raleigh Rd Not in Use unknown drilled unknown unknown 730
Henderson, NC 27537 Henderson, NC 27537
Frances Roberts
PW20 3813 Raleigh Rd 3813 Raleigh Rd In Use unknown drilled unknown unknown 730
Henderson, NC 27537 Henderson, NC 27537
Larry Daeke
PW21 3850 Raleigh Rd 3850 Raleigh Rd Not in Use unknown drilled unknown unknown 560
Henderson, NC 27537 Henderson, NC 27537
Robert Abbott
PW22 3860 Raleigh Rd 3860 Raleigh Rd Not in Use unknown drilled unknown unknown 440
Henderson, NC 27537 Henderson, NC 27537
Woody Evans
PW23 3788 Raleigh Rd 3788 Raleigh Rd Not in Use unknown drilled unknown unknown 895
Henderson, NC 27537 Henderson, NC 27537
Notes:
1. Information obtained from Terraquest field interviews and observations and converstations with the City of Henderson Water Department.
2. Well ID numbers are displayed on Figure 2.
Table 41/30/2023Facility ID No: 00-0-0000030637Well ID Date InstalledDate Water Level MeasuredScreened Interval (x to y ft. BGS)Bottom of Well (ft. BGS)Top of Casing Elevation (ft.)Depth to Water from Top of Casing (ft.)Free Product Thickness (ft.)Groundwater Elevation (ft.) CommentsMW1 1/5/23 1/5/23 5-20 20 100 9.75 - 90.25 2"-diameter Type II monitoring wellNotes:1. All units in feet.2. "-" = not detectedMONITORING WELL CONSTRUCTION INFORMATIONProject Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726Well Casing Depth (ft. BGS)20
Table 5
Date: 1/30/23 Facility ID No: 00-0-0000030637
TPH 5030Date
Collected Sample Depth
SB1 1/5/23 8 - 10 <1
SB2 1/5/23 8 - 10 <1
SB3 1/5/23 8 - 10 <1
SB5 1/5/23 8 - 10 <1
SB6 1/5/23 8 - 10 <1
SB7 1/5/23 3 - 5 3.40
50
Notes:
1. All results in mg/kg.
2. Bold denotes a compound detection. < - less than sample detection limit
3. Shading denotes a NCDEQ DWM-UST Action Limit Exceedence.
TPH Action Limit
Analytical Method
Sample ID
Contaminant of Concern
TPH GROSUMMARY OF SOIL SAMPLING RESULTS - Site Check
Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident
Table 6Date: 1/30/23Facility ID No: 00-0-00000306378260D8260D8260D8260D8260D8260DMADEP VPHMADEP VPHMADEP VPHSample ID Date Collected Sample DepthMW11/5/23 8 - 100.00615 J 0.00188 J<0.001020.00613 J<0.124 <0.00168 <3.66 <1.90 <1.020.0056 4.3 4.9 4.6 16 0.091 68 540 3118 1,200 1,560 3,129 7,000 350 939 1,500 469164 32,000 40,000 81,760 200,000 3,100 24,528 40,000 12,264Notes:1. All results in mg/kg. 2. Bold denotes a compound detection.3. Shading denotes a Soil-to-Groundwater MSCC violation.4. "<" = less than sample detection limit5. Sample depths in feet below ground level.6. "MSCC" = Maximum Soil Contaminant Concentration7. "#" = considered immobile. Soil-to-Groundwater MSCCResidential MSCCIndustrial/Commercial MSCCC5-C8 AliphaticsContaminant of ConcernBenzeneTolueneEthylbenzeneTotal XylenesC9-C12 AliphaticsC9-C10 AromaticsEthanolMTBEAnalytical Method SUMMARY OF SOIL SAMPLING RESULTS - LSA Project Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726
Table 7Date: 1/30/23Facility ID No: 00-0-00000306376200B6200B6200B6200B6200B6200B6200B6200BMADEP VPHMADEP VPHMADEP VPH504.1303CWell IDDate CollectedBenzeneTolueneEthylbenzeneTotal XylenesMTBEDiisopropyl etherNapthalene EthanolC5-C8 AliphaticsC9-C12 AliphaticsC9-C10 AromaticsEDBLeadMW1 1/5/20230.635 J 0.467 J<0.5 <1.60 <0.220 <0.2 <3 <24 <26 <11 <7 <0.01500.02451 600 600 500 20 70 6 4,000 400 700 200 0.02 155,000 260,000 84,500 85,500 20,000 70,000 6,000 4,000,000NE NE NE50 15,000Notes:1. All results in µg/L. 2. Bold denotes a detected concentration. NA - Not Analyzed for3. Shading denotes a 2L Standard exceedence4. Italics denotes a Gross Contaminantion Level (GCL) exceedence 5. < - denotes less than sample detection limit.6. NE - Not Established; J- estimated concentrationGCLAnalytical Method:2L StandardSUMMARY OF GROUNDWATER SAMPLING RESULTSProject Name: Bearpond Market - 3963 Raleigh Rd., Henderson, NC Incident No. 47726

FIGURES
ONSULTANTS, P.C.CENVIRONMENTAL

APPENDIX A
TECHNICAL METHODS/STANDARD PROCEDURES

Equipment Decontamination

All soil sampling equipment utilized during site assessment activities is decontaminated according
to standard and accepted protocol. Cleaning solutions range from clean potable water to acidic
solutions or organic solvents depending on the contaminants present at the site. Equipment
utilized at sites, such as hand augers, contaminated with petroleum hydrocarbons, is generally
decontaminated with a low-sudsing detergent such as Luiquinox® and triple rinsed with distilled
water. Larger equipment, such as drill rigs and associated tools, is steam cleaned. All
decontamination procedures are completed within an established decontamination area which is
located away from the active study area. Frequency of equipment decontamination depends on
the nature of work being performed, but in no case is decontamination performed less frequently
than once per test (i.e., soil boring, well installation, sample collection, etc.). Equipment blanks are
collected as a quality control measure when required by job specifications.

Soil Boring Installation

Soil borings are completed using hand-operated sampling tools, truck-mounted drills, or
Geoprobe® drilling rigs depending on the depth of sample collection and other site-specific
conditions. Hand operated stainless-steel bucket augers are utilized to collect soil samples at
regular intervals to determine site stratigraphy and to test for the presence of volatile organic
compounds. Samples retrieved from the hand auger are necessarily disturbed during the augering
process, but can provide accurate information on soil type and contaminant concentrations when
properly interpreted. Soil samples from hand augered borings are generally retrieved at one to
two foot intervals.

Truck-mounted or Geoprobe® drilling equipment is often utilized when sample retrieval depths
exceed twenty feet or subsurface conditions prevent utilization of hand augers (i.e., buried rocks,
wood, bricks or other materials occur in the subsurface). Truck-mounted drilling rigs usually
retrieve soil via a hollow-stem auger/split spoon collection method. Geoprobe® rigs usually employ
a Macro-Core® tube retrieval system.

Hollow stem augers provide relatively undisturbed 2-foot cores of soil samples. Soil samples are
generally collected at five foot intervals utilizing standard penetration test procedures as defined
by the American Society for Testing and Materials (ASTM) or are pushed to the desired depth using
the head of the drill rig. The standard penetration test involves driving a 2" outside diameter by 1-
3/8" inside diameter split-spoon sampler a minimum distance of one foot with a 340-lb. slide
hammer falling a distance of 30 inches.

A Geoprobe® rig is a hydraulically-powered soil probing machine. The probe utilizes static force
and percussion to advance a small diameter sampling device into the subsurface. The sampling
apparatus provides relatively undisturbed 5-foot cores of soil samples. Soil samples are collected
continuously. The Macro-Core® tube contains an inserted poly-vinyl chloride (PVC) liner which
retains the soil sample as the tube is driven into the ground. The Macro-Core® tube is
decontaminated between each 5-foot sample interval in a soil boring using a Liquinox and tap-
water mixture. A new PVC liner is used to collect soil from each sample interval in a soil boring.

Soil samples retrieved from the hollow-stem augers or Geoprobe are then carefully described
according to the Unified Soil Classification System. Soil descriptions are recorded on a soil
boring log.

Soil Sampling

Soils to be analyzed by a North Carolina-certified laboratory are prepared according to the specified
analytical method. Initially, soil samples are removed from the ground using either a hand auger,
backhoe bucket, spilt spoon auger, or a Macro-Core® sampling tube. During the removal, care is
taken to keep the disturbance of the soil structure to a minimum to reduce the loss of
contaminants. Once removed, the samples are placed in the proper sample container for the
specified analytical method. For samples collected for the MADEP VPH and EPA Method 8260, a
TerraCore® sampler is used to collect one 5-gram allotment of soil. The allotment is placed in
methanol-preserved 40 mL vials. Also, one 5-gram allotment of soil is placed into sodium bisulfate-
preserved 40 mL vials (one 5-gram allotment per vial, 2 vials per sample) for the 8260 low
concentration method. A 250-mL glass jar of the sampled soil is also collected to provide moisture
content information. Soils sampled for MADEP EPH, EPA Method 8270 and TPH 5030 and 3550 are
placed in a 250-mL glass jar (for MADEP EPH analysis an amber jar is required). TPH 5030 samples
are preserved in methanol similar to the 8260 analysis. Field personnel wear new, disposable
nitrile gloves during the collection of each sample.

The soil samples are labeled with the sample location, sample identification, date and time of
collection, and the analytical method. The samples are placed on ice, sent to a laboratory, and
analyzed before the expiration of an analytical method’s prescribed holding time. Chain-of-custody
documentation is maintained for each sample collected in the field.

If the soil is being sampled for volatile or semi-volatile compounds, a portion of the collected soil is
placed in a sealable bag and screened for volatile organic vapors. Head screening procedures are
described in the following paragraph.

Headspace Screening

Collected soil samples are routinely tested for the presence of volatile organic compounds (VOCs).
After retrieval from the ground, a portion of a soil sample is placed in a sealable plastic bag. The
soil samples are then set aside for approximately five minutes so that volatile constituents present
in the sample can reach equilibrium concentrations with headspace gases in the bag. Once a
suitable time period has passed, the probe of the sampling instrument, typically an Organic Vapor
Monitor (OVM) or a Photo Ionization Detector (PID), is inserted into the bag and the relative
concentration of total VOCs is measured and permanently recorded in a field note book. VOC
concentrations are measured using either a Thermo Electron Corp. Innova Series catalytic OVM or
an Ion Science PhoCheck PID. Both the OVM and PID instrumentation are periodically calibrated
according to the manufacturer’s recommended procedures.

The OVM and PID are qualitative tools employed to detect and estimate the concentration of
organic or hydrocarbon vapors. A thin probe is inserted through a small break in the seal of a
bagged soil sample. For the OVM, an air sample from the headspace of the bag is drawn through
the probe into an internal chamber where the vapors are catalyzed. The concentration of the VOCs
is registered on a digital scale in parts per million (ppm). For the PID, an air sample from the
headspace of the bag is drawn across the face of a lamp causing the sample to emit photons, the
presence of which are converted into a VOC ppm reading that is displayed. Oxygen levels are field
calibrated prior to each use. VOC calibration occurs periodically depending upon use by using a
span gas of known concentration in a process recommended by the manufacturer.

Well Installation/Construction

Monitoring wells are installed using hand-operated sampling tools, a truck-mounted drill rig, or a
Geoprobe drilling rig depending on the depth of well and other site-specific conditions. All
monitoring wells are installed according to the requirements of 15A NCAC 2C-Well Construction
Standards. Specifically, individual monitoring wells are constructed of 2-inch diameter, schedule 40
PVC casing riser and screen. The screen interval is generally 10 to 15 feet of machine slotted PVC
with a slot size of 0.010". Only flush threaded joints are used. The annulus space around the
screen is filled with washed filter pack No. 2 sand. The filter pack extends one to two feet above
the top of the screen. A one to two foot-thick bentonite pellet seal is then placed above the filter
pack. The remainder of the well annulus is completely filled with a Portland (Type I/II) cement
grout mixture. A protective outer steel manhole, locking cap, and concrete pad is installed for each
well.

Type II Monitoring Well Construction

Single-cased monitoring wells are generally used in delineation of groundwater quality within the
surficial aquifer. The wells are constructed of 2-inch diameter, schedule 40 PVC casing and screen.
The screen interval is generally 10 to 15 feet of machine slotted PVC with a slot size of 0.010". Only
flush threaded joints are used. The annulus space around the screen is filled with washed filter
pack No. 2 sand. The filter pack extends one to two feet above the top of the screen. A one to two
foot-thick bentonite pellet seal is then placed above the filter pack. The remainder of the well
annulus is completely filled with a Portland (Type I/II) cement grout mixture. A protective outer
steel manhole, locking cap, and concrete pad are installed for each well.

Type III Monitoring Well Construction

Double-cased monitoring wells are used in the delineation of groundwater quality within a deeper
portion of the surficial aquifer or an additional aquifer (e.g. aquitard, bedrock). A four to six-inch
outer casing is installed through the surficial aquifer until a sufficient depth or until the deeper
aquifer is encountered. The casing is secured with a Portland-grout collar that is tremmied into the
annular spaced from the bottom of the bore hole to the surface. Once the grout has sufficiently
cured, the bore hole is continued through the bottom of the outer casing to a depth approximately
15 - 20 feet beneath the outer casing. The inner casing is constructed of 2-inch diameter, schedule
40 PVC casing riser and screen. The screen interval is generally 5 to 10 feet of machine slotted PVC
with a slot size of 0.010". Only flush threaded joints are used. The annulus space around the
screen is filled with washed filter pack No. 2 sand. The filter pack extends one to two feet above
the top of the screen. A one to two foot-thick bentonite pellet seal is then placed above the filter
pack. The remainder of the well annulus is completely filled with the same Portland grout mixture
used in the outer casing. A protective outer steel manhole, locking cap, and concrete pad are
installed for each well.

Well Development

Following installation of each well, surging and pumping or bailing techniques will be used to
remove fines from the screened interval. Groundwater is removed from each well until clear water
is retrieved or a noticeable reduction in the amount of silt is achieved. Purged groundwater is
disposed of in an environmentally safe manner.

Groundwater Sampling

Petroleum Sites

Groundwater samples are collected from temporary or permanent monitoring wells according to
established sampling protocol. When multiple monitoring wells or sampling points are sampled,
sampling is completed beginning with the least contaminated well to the most contaminated well,
if it is known. When permanent monitoring wells for petroleum sites are sampled, the well is
purged of a minimum of three well-bore volumes prior to sample collection in order to assure that
sampled water is representative of aquifer conditions. In temporary wells, the first water which
migrates into the open borehole is sampled. Samples from both temporary and permanent
monitoring wells are collected using individually wrapped disposable polyethylene bailers by field
personnel wearing disposable nitrile gloves. Only one well is sampled with a given bailer in order to
prevent sample cross-contamination. During both well purging and sampling, proper protective
clothing and equipment is used and is dependent upon the type and level of contaminants present.
Also, field personnel change gloves between different samples to reduce the chance of cross-
contamination. Water samples are transferred from the bailer to laboratory-prepared sampling
containers using slow emptying devices to reduce the chance of contamination loss through
volatilization. Preservatives, such as acids, are provided by the laboratory in pre-prepared
containers in which collected samples are placed if in-field preservation is necessary. The samples
are labeled with the project name, project number, sample identification, required analysis, and
date and time of collection. The samples are placed on ice, shipped to a certified laboratory, and
analyzed before the expiration of an analytical method’s prescribed holding time. Chain-of-custody
documentation is maintained for each sample collected in the field.

Other Groundwater Sampling Protocols

When required by state or federal regulations, low-flow groundwater sampling procedures are
instituted. Groundwater samples collected in low-flow situations are collected using a peristaltic
pump. A peristaltic pump is a type of positive displacement pump. The fluid is contained within a
flexible tube fitted inside a circular pump casing. A rotor with a number of rollers attached to the
external circumference compresses the flexible tube. As the rotor turns, the part of tube under
compression closes thus forcing the fluid to be pumped to move through the tube. Groundwater
parameters such as water level drawdown, pH, conductivity, dissolved oxygen (DO) and turbidity.
Pumping rate, drawdown, and the time or volume required to obtain stabilization of parameter
readings can be used as a future guide to purge the well. Measurements are collected at a pre-
pumping established interval (typically five to ten minutes). Once all or a majority of the
parameters have stabilized for three successive readings, stabilization has been achieved. In lieu of
measuring all five parameters, a minimum subset would include pH, conductivity, and turbidity or
DO. Three successive readings should be within ± 0.1 for pH, ± 3% for conductivity, and ± 10% for
turbidity and DO.

Upon parameter stabilization, sampling is initiated. Sampling flow rate is maintained at the estab-
lished purge rate or is adjusted slightly to minimize aeration, bubble formation, turbulent filling of
sample bottles, or loss of volatiles due to extended residence time in tubing. The same device used
for purging is used to collect the groundwater sample. Generally, volatile parameters are sampled
first. The sequence in which samples for inorganic parameters are collected is not determined
unless filtered (dissolved) samples are collected. Preservatives, such as acids, are provided by the
laboratory in pre-prepared containers in which collected samples are placed if in-field preservation
is necessary. The samples are labeled with the project name, project number, sample
identification, required analysis, and date and time of collection. The samples are placed on ice,
shipped to a certified laboratory, and analyzed before the expiration of an analytical method’s
prescribed holding time. Chain-of-custody documentation is maintained for each sample collected
in the field.

During both well purging and sampling, proper protective clothing and equipment is used and is
dependent upon the type and level of contaminants present. Also, field personnel change gloves
between different monitoring wells or sampling points to reduce the chance of cross-
contamination. When multiple monitoring wells or sampling points are sampled, sampling is
completed beginning with the least contaminated well to the most contaminated well, if it is
known.

Stockpile Sampling

The number of composite samples collected from a stockpile or a total quantity of excavated soil is
based upon the cubic yardage. One composite sample is collected for every 100 cubic yards of
contaminated soil excavated. The volume of a stockpile or total quantity of excavated soil is
calculated by approximating the general geometry of a stockpile or estimating the capacity of the
dump trucks used for hauling. If a stockpile is sampled, a grid pattern is laid out on the stockpile,
dividing the stockpile into segments of approximately 200 cubic yards. Two soil borings are
advanced within a grid and three soil samples are collected from each soil boring at various depths.
The six soil samples are mixed into a composite sample by a trained TerraQuest technician. If truck
loads are sampled, an aliquot sample is collected from the hauling trucks at a frequency based
upon the capacity of the hauling trucks.

Aliquots are gently mixed into a composite sample by a trained TerraQuest technician. Every effort
is made to minimize the loss of contaminants through volatilization. The composited soil samples
are jarred in the appropriate laboratory-prepared containers, labeled with the sample location,
sample identification, date of collection, time of collection, the analytical method, and the
preservative. The samples are placed on ice, shipped to a laboratory, and analyzed before the
expiration of an analytical method’s prescribed holding time. Chain-of-custody documentation is
maintained for each sample collected in the field.

Surface Water Sampling

Surface water samples, specifically samples from creeks or streams, are collected from a
moving/flowing portion of the creek or stream to ensure that stagnant water is not collected. Field
personnel are careful to collect samples from flowing areas that are not so turbulent as to cause a
loss of volatile contaminants which might have been contained in the creek’s/stream’s water.
Samples are collected by field personnel wearing disposable nitrile gloves. Field personnel change
gloves between different locations to reduce the chance of cross-contamination. Samples are
collected directly from the appropriate creek or stream location and placed into the appropriate
laboratory-prepared containers. Preservatives, such as acids, are provided by the laboratory in pre-
prepared containers in which collected samples are placed if in-field preservation is necessary. The
samples are labeled with the project name, project number, sample identification, required
analysis, and date and time of collection. The samples are cooled on ice to approximately four
degrees centigrade, shipped to a certified laboratory, and analyzed before the expiration of an
analytical method’s prescribed holding time. Chain-of-custody documentation is maintained for
each sample collected in the field.

Potable Well Sampling

Groundwater samples from potable wells are collected from sampling points, typically spigots,
located in the closest proximity to the potable well pump house as possible. Prior to sample
collection, the water is run for a sufficient amount of time to purge the bladder tank and assure
that sampled water is representative of aquifer conditions. Once purged, the flow rate is reduced
and samples are placed in the appropriate laboratory prepared containers with the appropriate
acid preservatives added if preservation of the sample is necessary. The samples are labeled with
the project name, project number, sample identification, required analysis, and date and time of
collection. The samples are placed on ice, shipped to a laboratory, and analyzed before the
expiration of an analytical method’s prescribed holding time. Chain-of-custody documentation is
maintained for each sample collected in the field.
Public Water Supply Line Sampling

Groundwater samples from public water supply lines are collected from sampling points, typically
spigots. To sample the spigot, the flow rate is reduced and samples are placed in the appropriate
laboratory prepared containers. The samples are labeled with the sample location, sample
identification, date of collection, time of collection, and required analytical method. The samples
are placed on ice, shipped to a laboratory, and analyzed before the expiration of an analytical
method’s prescribed holding time. Chain-of-custody documentation is maintained for each sample
collected in the field.

Air Sampling

Air samples are collected with the aide of a manually operated MityVac® pump manufactured by
Pristech, Inc. The air sampling process begins by connecting a length of rubber hose from the
MityVac® pump to the port to be sampled, or by hanging the hose inside of an emissions stack in
such a manner as to ensure no outside air causes dilution. Another length of hose is fixed to the
outlet port of the pump and is connected to a new Tedlar bag. Once the pump is hooked up, a
valve on the Tedlar collection bag is opened and air is manually forced into the bag by the pumping
action of sampling personnel.

Field Measurements

Field measurements taken to determine the pH, conductivity, temperature, and dissolved oxygen
concentration of a particular groundwater sample are taken directly after a particular monitoring
well has been adequately purged. This ensures that the groundwater parameter data collected is
representative of the aquifer conditions at a given location. Once purging of the monitoring well is
complete, the decontaminated probe head and cord of the appropriate unit is lowered into the
required monitoring well. If the depth to water in a specific monitoring well is greater than the
length of cord for a particular unit, a new, disposable bailer is slowly lowered into the appropriate
monitoring well and a representative groundwater sample is retrieved. A slow pouring device is
fitted onto the end of the disposable bailer and the sample is slowly poured into a new, disposable
plastic cup. Groundwater parameter data are then collected from the groundwater in the cup
using the required unit.

For pH, conductivity, and temperature, a Hanna Instruments Model 991300 portable meter is
utilized. This unit is periodically calibrated and maintained in accordance with the unit’s operations
manual by field personnel. Prior to data collection, the unit is properly decontaminated to prevent
cross-contamination. The unit is decontaminated between each sample. The procedure used for
sample measurement involves lowering the meter’s probe into the new, disposable cup containing
the groundwater sample to be measured and slowly stirring the probe to force groundwater across
the probe’s membrane. The measurements displayed by the meter are then recorded.

For dissolved oxygen concentration measurements, a YSI® Model 55 Handheld Dissolved Oxygen
System is utilized. This unit is periodically calibrated and maintained in accordance with the unit’s
operations manual by field personnel. Prior to data collection, the unit is properly decontaminated
to prevent cross-contamination. The unit is decontaminated between each sample. The procedure
used for sample measurement involves adjusting the unit for the correct altitude where the
sampling will take place and adjusting the reported units desired. Once this is done, the unit’s
probe is inserted into the groundwater sample to be measured and the probe is slowly stirred to
force the groundwater across the probe’s membrane. The measurements displayed by the unit are
then recorded.

For turbidity measurements, a Hach 2100P Portable Turbidity meter or equal equivalent is utilized.
The unit is calibrated prior to use in accordance with the unit’s operations manual by field
personnel. Groundwater samples are collected in glass containers for measurement by the
instrument. The glass containers are washed with bottled-water between each measurement
collection. Once the sample is collected and inserted into the instrument, the measurements
displayed by the instrument are then recorded.

APPENDIX B
National Tank Monitor, Inc.
TANK OWNER:JNH INVESTMENT
Customer Service
CONTACT PERSON:AHMED QAEMI 1.800.643.8265
OWNER ADDRESS:3963 RALEIGH RD.
OWNER CITY, STATE:HENDERSON, NC
OWNER TELEPHONE:[phone]
SITE NAME:BEARPOND MARKET
SITE ADDRESS:3963 RALEIGH RD.
SITE CITY, STATE:HENDERSON, NC
SITE TELEPHONE:[phone]
TEST DATE:12/12/2022
TEST METHOD:EZ-3 Locator Plus AcuRite Pipeline Tester
Cathodic
Product Capacity System Tank Line L.D.S.Stage II Protection
1 UNL 10000 PRESS PASS DNT DNT N/A N/A
2 PREM 8000 PRESS PASS DNT DNT N/A N/A
3
4
5
6
7
8
Comments:
Hasstech Number:4645.LTN Signature
EZ-3 Locator Plus Number:31-1815 TED URCINOLA
National Tank Monitor, Inc.
TANK OWNER:BEARPOND MARKET
Customer Service
CONTACT PERSON:N/A 1.800.643.8265
OWNER ADDRESS:3963 RALEIGH RD.
OWNER CITY, STATE:HENDERSON, NC
OWNER TELEPHONE:[phone]
SITE NAME:BEARPOND MARKET
SITE ADDRESS:3963 RALEIGH RD.
SITE CITY, STATE:HENDERSON, NC
SITE TELEPHONE:[phone]
TEST DATE:5/3/2021
TEST METHOD:EZ-3 Locator Plus AcuRite Pipeline Tester
Cathodic
Product Capacity System Tank Line L.D.S.Stage II Protection
1 UNL 8000 PRESS DNT DNT PASS N/A N/A
2 PREM 8000 PRESS DNT DNT PASS N/A N/A
3
4
5
6
7
8
Comments:PLEASE SEE ATTACHED UST-22 B FORM.
Hasstech Number:4146.LTN Signature
EZ-3 Locator Plus Number:31-1815 TED URCINOLA
UST-22B Annual Leak Detection Equipment Operability Check D_E C)----;
Page 3 (Mechanical and Electronic Line Leak Detectors)
UST FACILITY
Owner / Operator Name
BEARPOND MARKET
Facility Name
BEARPOND MARKET
Facility ID#:
0-00030637
Facility Street Address
3963 RALEIGH RD.
Facility City
HENDERSON
County
CONTRACTOR/PERSON CONDUCTING INSPECTIONS
Company Name
NATIONAL TANK MONITOR, INC.
Phone
1-800-643-8265
Email Address
[e-mail]
I certify, under penalty of law, that the testing data provided on this for um the U sy equipment was cked in accordance with
the manufacturer's guidelines and the applicable national industry st -.• • . ds I -d in 1 C N .0407/ 0501.
TED URCINOLA , .. 5/3/2021
Inspection Date a.- ignature of person conducting inspection Print Name of person conducting inspection
Tank #: 1 2
Tank Size: 8000 8000
Product: UNL PREM
Leak Detector Manufacturer V/R V/R
Leak Detector Model WPLLD WPLLD
n MLLD
n ELLD
Type of Leak Detector n MLLD
ELLD
n MLLD
ELLD
n MLLD
n ELLD
n MLLD
n ELLD
MLLD (ALL PRESSURE MEASUREMENTS ARE MADE IN PSIG)
STP Full Operating Pressure
Check Valve Holding Pressure
Line Resiliency (ml) (line bleed back
volume as measured from check
valve holding pressure to 0 psig)
Step Through Time in Seconds
(time the MLLD hesitates at
metering pressure before going to
full operating pressure as measured
from 0 psig with no leak induced on
the line)
Metering Pressure (STP pressure
when simulated leak rate, 3 gph at
10 psig)
Opening Time in Seconds (the time
the MLLD opens to allow full
pressure after simulated leak is
stopped)
Does the STP pressure remain at or
below the metering pressure for at
least 60 seconds when the
simulated leak is induced?
• Yes n No n Yes n No n Yes n No n Yes n No n Yes n No
Does the leak detector reset (trip)
when the line pressure is bled off to
zero psig?
n Yes n No n Yes n No n Yes n No n Yes n No n Yes n No
Does the STP properly cycle on/off
under normal fuel system operation
conditions?
n Yes n No n Yes n No n Yes n No n Yes n No n Yes n No
A "No" answer to any of the above questions indicates the MLLD fails the test.
ELLD (ALL PRESSURE MEASUREMENTS ARE MADE IN PSIG)
33 STP Full Operating Pressure 34
How many test cycles are observed
before alarm/shutdown occurs? 2 3
Does the simulated leak cause an
alarm? (If "No" then leak detector
fails) (Attach alarm report to form)
El Yes n No n► Yes n No n Yes n No n Yes n No n Yes n No
Does the simulated leak cause an
STP shutdown?
r Yes n No
n N/A
Yes n No n N/A
n Yes n No n N/A
n Yes n No
n N/A
n Yes n No
n N/A
Test Results n► Pass n Fail Pass n Fail n Pass n Fail q Pass n Fail n Pass n Fail
Comments:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY, DIVISION OF WASTE MANAGEMENT, UST SECTION
1646 MAIL SERVICE CENTER, RALEIGH, NC 27699-1646 PHONE [phone] FAX [phone] http://www.wastenotnc.orq 12/2020

PHASE II ENVIRONMENTAL SITE ASSESSMENT
Bearpond Market
3963 Raleigh Road
Henderson, North Carolina

Prepared for:
Mr. AJ Qaemi
JNH Investments, Inc.
11521 Colbert Creek Loop, Apt 306
Raleigh, North Carolina 27614

Prepared by:
Highlands Environmental Solutions, Inc.
8410-D Falls of Neuse Road
Raleigh, North Carolina 27615

April 12, 2021
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page ii

EXECUTIVE SUMMARY

At the request of Mr. AJ Qaemi of JNH Investments, Inc., Highlands Environmental Solutions, Inc. (HES)
conducted a Phase II Environmental Site Assessment (ESA) of the property located at 3963 Raleigh Road,
Henderson, in Vance County, North Carolina. As presently configured, the subject property consists of a
single parcel, encompassing a total of 1.67 acres. This property has been identified with Vance County Parcel
Identification Number (PIN) 0224 02016. According to information obtained from the Vance County GIS and
Register of Deeds Office, the parcel is owned by Billy and Elise Stanton of Henderson, North Carolina

The subject property is developed for commercial uses, as a convenience/grocery store with fuel dispensers
and is situated in an area of predominantly residential land uses. The property is developed with four
structures, a paved parking area, and two pump islands with a total of four dispensers located under a
canopy. Water supply wells are not located on the property, and the subject site is connected to municipal
water and sewer.

Historically, the property has been used as a convenience store and retail petroleum outlet since its
development in 1993. Prior to its development, the property consisted of undeveloped land. Surrounding
properties consist of commercial and residential land uses.

HES performed a review of online records with the North Carolina Department of Environmental Quality
(NCDEQ) for the subject property. This review did not result in the finding of environmental incdients with
respect to the subject property; however, a underground storage tank removal (RUST), occurred on the
opposite end of Raleigh Road from the subject site. The NCDEQ has issued the incident as “high risk” and
assigned Incident Number 5430 for this incident. Petroleum-impacted soil and groundwater are present on
this adjacent property, and the groundwater contaminant plume from this site has reportedly migrated off-site.
A review of available NCDEQ online files indicate regulartory semi-annual sampling of the site monitoring
wells and downgradient potable wells are being currently completed on this off-site incident; therefore
regulatory closure has not yet been attained.

HES conducted this Phase II ESA to determine if the subject property had been impacted by petroleum
releases from the underground storage tanks and dispensers. The primary objectives of our investigation
were:

• To assess for the presence of regulated chemical constituents in subsurface soil beneath the subject
property; and,
• To assess for the presence of regulated chemical constituents in the groundwater beneath the
subject property;

During this investigation, a total of six soil borings were installed at the site. Based on field evaluation, a total
of four soil samples were selected and submitted for laboratory analysis of Gasoline Range Organics (GROs),
by Method 8015C; and Diesel Range Organics (DROs), by Method 8015C. Also, two groundwater samples
were collected for laboratory analysis of Extractable and Volatile Petroleum Hydrocarbons (EPH/VPH), by the
MADEP Method; Volatile Organic Compounds (VOCs), by Method 8260D; and Semi-Volatile Organic
Compounds (SVOCs); by Method 8270E.

Laboratory analysis of soil samples collected during this investigation resulted in the detection of DRO and
GRO in two out of the seven samples collected. None of the DRO or GRO detected in the soil samples at
concentrations greater than their respective State Action Limit.

Laboratory analysis of the groundwater samples collected at the site resulted in the detection of several
dissolved petroleum constituents. The concentrations of benzene and C9-C22 aromatic compounds
exceeded their respective NC 2L Groundwater Quality Standards (GQSs) in groundwater sample TW-1; and
the concentrations of MTBE and C9-C22 Aromatic compounds exceeded their respective NC 2L GQS in
groundwater sample TW-2.

Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page iii

Based on the results of this investigation, HES concludes that a release of petroleum did occur at the retail
petroleum station. The detection of concentrations of various VOCs and SVOCs in the groundwater at
concentrations exceeding their respective NC 2L GQSs triggers regulatory reporting requirements.
Additionally, the presence of petroleum-impacted media requires the filing of a Notice of Residual Petroleum
(NRP) on the property deed prior to the sale of the property.

Based on the results of this investigation, HES concludes the following:

• The discovery of petroleum-impacted media should be properly reported to the North Carolina
Department of Environmental Quality (NCDEQ).

• A Notice of Residual Petroleum should be prepared, executed, and filed on the property deed to
facilitate the sale of the property.
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page iv

TABLE OF CONTENTS

EXECUTIVE SUMMARY ........................................................................................................................... ii

1.0 INTRODUCTION ........................................................................................................................... 1
1.1 Objective and Scope of Work….…………………………………………………………………1
1.2 General Property Description………………………………………………………………..…..1
1.3 Property Location Description ............................................................................................. 1

2.0 EVIRONMENTAL SETTINGS…………………………………………………………………………2
2.1 Regional Geology and Soils..….…………………………………………………………………2
2.2 Groundwater……………………………………………………………………………………….2

3.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT ACTIVITIES ....................................... 2
3.1 Utility Locator………………………………………………………………………………………2
3.2 Soil Sampling Methodology ................................................................................................ 1
3.3 Monitoring Well Installation and Sampling .......................................................................... 2

4.0 CONCLUSION AND RECOMMENDATIONS .......................................................................... 2

5.0 RELIANCE AND LIMITATIONS OF WORK PRODUCT……………………………………..…3

APPENDICES
Appendix A - Figures
Appendix B - Photos
Appendix C - Data Summary Tables
Appendix D - Laboratory Analytical Reports

Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page 1

1.0 INTRODUCTION

1.1 Objective and Scope of Work
At the request of Mr. AJ Qaemi, Highlands Environmental Solutions, Inc. (HES) conducted a Phase II
Environmental Site Assessment (ESA) of the property located at 3963 Raleigh Road, Henderson, in Vance
County, North Carolina. The study area of the subject property is developed for commercial use as a retail
convenience/grocery store with fuel dispensers and underground storage tanks (USTs); and is situated in an
area of predominantly residential land uses. The property is developed with four structures, a paved parking
area, and two pump islands with a total of four dispensers located under a canopy. Water supply wells are
not located on the property, and the subject site is connected to municipal water and sewer. The subject
property location is depicted on Figure 1, Figure 2, and Figure 3 included in Appendix A.

The purpose of this Phase II ESA investigation was to:

• Conduct environmental sampling to determine if soil and/or groundwater beneath the site have been
impacted by regulated chemical constituents from historical and current retail petroleum operations
on the property.

1.2 General Property Description
The subject property is located at 3963 Raleigh Road in Henderson, North Carolina. The study area of the
subject property is developed for commercial uses, and consists of one parcel (PIN #0224 02016),
encompassing approximately 1.67 acres. The property is developed with four structures, a paved parking
area, and two pump islands with a total of four dispensers located under a canopy. Water supply wells are
not located on the property and the subject site is connected to municipal water and sewer. Surrounding
properties are primarily for commercial land uses.

1.3 Property Location Description
The subject property is located in Henderson, in Vance County, North Carolina. Adjacent property uses are
as follows:

North: Residential land uses, beyond which are commercial land uses;
East: Commerical land uses, beyond which is US Rte 1 Business;
South: Bear Pond Road, beyond which are residential land uses; and,
West: N Lynnbank Rd, beyond which are former commercial land uses, as well as institutional and
residential land uses.
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page 2

2.0 ENVIRONMENTAL SETTING

2.1 Regional Geology and Soils
The site is located in the South-central portion of Vance County, approximately 0.43 miles West of US Route
1 Business. This area is situated in the Piedmont Physiographic Province of North Carolina. Topographic
relief in this province is moderate.

Based on a review of the Geologic Map of North Carolina (1985), the site resides with the Raleigh Belt. This
region is dominated by Foliated to massive granitic rock and metamorphosed granitic rock. The site and
surrounding area are underlain by meta-ultramafic rock, felsic mica gneiss and lineated felsic mica gneiss of
the Vance group.

A review of the USDA Soil Survey for Vance County (web soil survey), the soil type on the property is
identified as Vance sandy loam. These soils are derived from cecil and appling, and are found on hillslopes
and ridges. These soils are considered to be moderately well drained.

2.2 Groundwater
Groundwater occurs within two distinct water-bearing units in the subsurface in this region. The initial water-
bearing unit is the surficial aquifer. Where present, within the surficial aquifer, groundwater movement is
facilitated through pore spaces between soil particles. The direction of groundwater movement typically
mirrors surface topography, as flow is generally in response to gravity. The second water-bearing unit is the
bedrock aquifer. In the bedrock aquifer, groundwater may be found in bedrock fractures and/or cavities.
Groundwater movement in the bedrock unit is controlled by fracture orientation and connectivity, and is not
necessarily controlled by gravity. The two aquifers may or may not be locally interconnected depending on
local conditions. Discharge of stored groundwater occurs primarily as baseflow to surface water bodies,
and/or discharge from springs. Hydraulic conductivity values for the surficial aquifer range from less than one
to several feet per day, while values for fractured rock vary greatly. Groundwater recharge to the surficial and
bedrock aquifer systems is generally accomplished by infiltration from precipitation. Generally, surplus
conditions begin in the autumn and continue through the winter. Some aquifer recharge occurs via infiltration
from losing streams.

During this investigation, groundwater was encountered at a depth of approximately 10 to 11 feet below grade
in wells TW-1 and TW-2. The direction of groundwater flow was outside the scope of this Phase II ESA, and
was not determined. It is, however, reasonable to assume that the direction of groundwater flow in the
shallow aquifer beneath the site is toward the West. Groundwater discharge areas (or springs) were not
observed on the property.
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page 3

3.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT ACTIVITES

Soil and groundwater sampling activities were performed at the site on March 24, 2021, to facilitate
environmental sampling and to determine the depth of groundwater beneath the site. A total of six soil
borings (SB-1 through SB-6), with two borings near each of the four dispensers, three borings surrounding the
UST cavity and one boring downgradient of the dispenser island. In addition, two temporary monitoring wells
were installed with TW-1 located in SB-1, and TW-2 installed in SB-6. The approximate locations of sampling
points are depicted on Figure 4. Information regarding the ownership and capacities of the UST systems at
the site are presented on Table 1 and Table 2, included in Appendix C.

3.1 Utility Locator
Prior to performing drilling activities, to ensure that no utilities were present at the proposed drilling
location HES notified the North Carolina “One Call” center (i.e. ULOCO) to have subsurface utilities
identified at the subject site, in accordance with North Carolina law.

3.2 Soil Sampling Methodology
During the Phase II ESA, six soil borings were advanced on the subject property. Figure 4 is a
generalized site diagram and depicts the boring locations. Select photographs of site activities are
included in Appendix B.

Each soil boring advanced around the UST basin and for the two temporary monitoring wells was
advanced using a Geoprobe® (i.e. direct-push) drilling rig utilizing five-foot long MacroCore soil samplers.
The MacroCore samplers were equipped with acetate sampling sleeves, which were changed between
sample intervals. At each soil boring location, continuous soil samples were collected from the ground
surface to the boring termination depth which was 15 feet below ground surface (BGS) around the UST
basin. The two borings advanced near the dispensers were advanced using a clean, stainless steel
hand auger, and were terminated at 5 feet BGS.

Upon retrieval of each soil sample interval, the sampling sleeve was opened, and the soil sample was
examined for evidence of soil impact (i.e. staining, odor, etc.) by regulated chemical constituents,
hydrocarbon staining, or obvious odors. A soil sample was then collected along the length of the
sampling sleeve and divided into two aliquots. The first aliquot was placed in a clean, labeled, zip-lock
bag that was evacuated of air and maintained on ice pending possible selection for laboratory analysis.
The second aliquot was placed in a clean, labeled, zip-lock bag that was sealed and placed in direct
sunlight to equilibrate for approximately 10 minutes. At the end of the equilibration period, the headspace
in the sample bag was then field screened for the presence of organic vapors using a RAE Systems
MiniRAE photoionization detector (PID). To field screen the headspace, the sample probe for the field
screening instrument was inserted into the headspace in the bag, and the approximate concentration of
organic vapors in headspace was displayed on the field unit. Soil screening data are summarized on
Table 3.

Based on soil recovery and field observations, soil samples from four of the six soil borings were selected
for laboratory analysis. Soil samples selected for laboratory analysis were placed in labeled, laboratory-
supplied containers, maintained on ice, and transported under proper chain-of-custody via overnight
courier to SGS North America (SGS in Orlando, Florida) for analysis of diesel range organics (DRO) and
gasoline range organics (GRO) via EPA Method 5035/8015. Laboratory analytical data for the soil
samples are summarized on Table 3. Copies of the complete laboratory data report are included in
Appendix D.

3.3 Monitoring Well Installation and Groundwater Sampling
Two temporary groundwater monitoring wells were installed at the site. The two wells identified as TW-1
and TW-2 were installed in selected soil borings, SB-1 and SB-6, respectively. Each well was
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page 4

constructed using one-inch diameter Schedule 40 PVC well materials and was installed to depths 15 feet
BGS (five feet of riser and 10 feet of screen). Water saturated soils were encountered at a depth
approximately 13 feet below grade in both temporary wells.

Upon completion of the temporary wells (TW-1 and TW-2), the depth to water was measured (11.75 feet
and 10.85 feet respectively) using an electronic water level indicator. Prior to sampling, the wells were
purged of water for five minutes. Neither free-product nor hydrocarbon sheens were observed in the
purge water; therefore, the purge water was discharged to paved surfaces at the site. The groundwater
samples were collected using dedicated, disposable, polyethylene bailers, and nylon twine. To collect the
groundwater sample, the bailer was carefully lowered to a depth just beneath the water surface in each
monitoring well. The bailer was allowed to fill and then recovered.The water sample was placed in labeled,
laboratory-supplied containers, maintained on ice, and transported to SGS Environmental Services for
laboratory analysis of Extractable and Volatile Petroleum Hydrocarbons (EPH and VPH, respectively), by
the MADEP Method; VOCs, by Method 8260; and SVOCs, by Method 8270. Laboratory analytical data for
the groundwater samples are summarized on Table 4A and 4B. Copies of the complete laboratory data
report are included in Appendix D.
Phase II Environmental Site Assessment
3963 Raleigh Road; Henderson, NC
Page 5

4.0 CONCLUSIONS AND RECOMMENDATIONS

At the request of Mr. AJ Qaemi, HES conducted a Limited Phase II ESA of the property located at 3963
Raleigh Road, Henderson, in Vance County, North Carolina (Bearpond Market). The purpose of the Phase II
ESA was to assess for the presence of regulated chemical constituents in the soil and/or groundwater beneath
the site, associated with the existing petroleum UST systems.

Based on the results of this investigation, HES concludes that a release of petroleum has occurred at the site.
This conclusion is based on:

• The detection of low concentrations of petroleum constituents (analyzed as GRO/DRO) in all four soil
samples. Neither DRO nor GRO were detected at concentrations greater than their respective State
Action Limits in the soil sample.

• The detection of several petroleum constituents in both groundwater samples.

In the groundwater, the following petroleum constituents were detected at concentrations greater than their
respective NC 2L GQS:

• TW-1: Benzene.

• TW-2: Methyl Tert Butyl Ether.

• C11-C22 Aromatics was detected in both groundwater samples at concentrations of 395 ug/L (TW-1)
and 209 ug/L (TW-2).

Based on the results of this investigation, HES concludes that a release of petroleum did occur at the retail
petroleum station. While the soil concentrations were found to be below state action limits, petroleum VOCs
and EPH/VPH in the groundwater are present at concentrations greater than the NCDEQ groundwater 2L
Standards. The scope of this assessment was not to delineate the extent of petroleum-impacted media (if
encountered), and it should be noted that the concentrations of petroleum constituents in the soil and
groundwater samples collected the site were relatively low.

The ground surface of the property is capped with pavement; as such, the low concentrations of petroleum
constituents in the soil beneath the pavement do not present a threat to human health and safety or the
environment. Residual petroleum-impacted groundwater does present an environmental liability for the
property; however, a responsible party for this issue has been identified. The subject and adjacent properties
utilize municipal water supplies for potable water.

Because petroleum-impacted media are present on the property, current North Carolina environmental
regulations require a Notice of Residual Petroleum (NRP) be filed on the property deed prior to property
transfer or sale. The NRP would carry the following two restrictions:

1 – The use of the property would be restricted to commercial or industrial land use.
2 – Groundwater beneath the property could not be utilized for any purpose (drinking, irrigation, etc.).

The filing of the NRP would facilitate the sale of the property. The land use restrictions in the NRP would not
impact the operation of the facility as a commercial entity or retail petroleum outlet and convenience store.

Given the presence of regulated petroleum constituents, the NCDEQ may require additional environmental
assessment activities (Phase I Limited Site Assessment - LSA) at the site. The scope of work for a Phase I
LSA would include the installation of one permanent groundwater monitoring well, and a receptor survey to
formally evaluate the “risk ranking” of the site. Once the risk ranking has been formally determined to be “Low
Risk,” then regulatory closure can be attained since the NRP would have already been filed on the property.

317037491

APPENDIX A

Drawing / Project Name
Client
Project #
DB Fig. Scale
Date
N
Base diagram from Google Maps
Site Location Diagram
Phase II ESA - Bearpond Market
Henderson, North Carolina
JNH Investments, Inc.
574001
JB As Shown
March 2021
1
PM PG
BA
PE

Approximate Scale
feet
0 1200 600
JB
Site Location

Drawing / Project Name
Client
Project #
DB Fig. Scale
Date
N
Base diagram from USGS Topographic Quadrangle; Henderson, NC; 2016
Topographic Location Diagram
Phase II ESA - Bearpond Market
Henderson, North Carolina

JNH Investments
574001
JB As Shown
March 2021
2
PM PG
BA
PE

JB
Approximate Scale
feet
0 2700 1350
Site Location

Drawing / Project Name
Client
Project #
DB Fig. Scale
Date
N
Base diagram from Google Earth
Aerial Location Diagram
Phase II ESA – Bearpond Market
Henderson, North Carolina

JNH Investments
574001
JB As Shown
April 2021
3
Site Location
PM PG
BA
PE

Approximate Scale
feet
0 120 60
Former Gas
Station
JB

Drawing / Project Name
Client
Project #
DB Fig. Scale
Date
N
Base diagram from Google Earth
Sample Location Diagram
Phase II ESA – Bearpond Market
Henderson, North Carolina

JNH Investments, Inc.
574001
JB As Shown
April 2021
4
PM PG
BA
PE

Approximate Scale
feet
0 120 60
JB
Site Location
SB-6/TW-2
SB-1/TW-1

SB-2

SB-3

SB-4

SB-5

Soil Boring Location
Soil Boring and Temporary
Well Location

APPENDIX B

Photograph Number 1: Photo of the dispenser island and store-front property (3/24/21).

Photograph Number 2: North side of property and location of USTs.

Photograph Number 3: Geoprobe boring at location (SB-2) adjacent to the tank basin.

Photograph Number 4: Boring location (SB-4) advanced adjacent to the dispenser island.

Photograph Number 5: Boring location (SB-6) advanced downgradient of the dispenser islands.

Photograph Number 6: Groundwater sampling completed at TW-2.

Photograph Number 7: Boring location (SB-3) drill cuttings placed back as refill.

Photograph Number 8: Boring location (SB-5) drilling cuttings placed back as refill and concrete
seal.

APPENDIX C

Tank Number Status Installation Date Size In Gallons Tank Dimensions Last Contents1In service Not determined 10,0008' x 26.75' Regular Unleaded Gasoline2In service Not determined 8,0008' X 21.33' Premium Unleaded GasolineTable 1Phase II ESA - Bearpond Market3963 Raleigh Road; Henderson, North CarolinaHES Project #574001Summary of UST Information
1Bearpond MarketOwner and OperatorUST ID Number Name of Owner or OperatorOwner or Operator2Bearpond MarketOwner and OperatorDates of Ownership/OperationTable 2Phase II ESA - Bearpond Market3963 Raleigh Road; Henderson, North CarolinaHES Project #574001Summary of UST Ownership InformationUST ID Number Name of Owner or OperatorDates of Ownership/ Operation Owner or OperatorAddressTelephone Number3963 Raleigh Road; Henderson, NC 27537252-438-6452AddressTelephone Number3963 Raleigh Road; Henderson, NC 27537252-438-6452
Field
SB-1 3/24/21 0-5 3.2 ND 7.28
Lab sample collected from 0-5 ft
BGS.
SB-1-2 3/24/21 5-10 2
SB-1-3 3/24/21 10-15 0
SB-2 3/24/21 0-5 8.0 ND 12.7
Lab sample collected from 0-5 ft
BGS.
SB-2-2 3/24/21 5-10 4.6
SB-2-3 3/24/21 10-15 5.8
SB-3 3/24/21 0-5 0.0
SB-3-2 3/24/21 5-10 0.7
SB-3-3 3/24/21 10-15 0.2
S-4 3/24/21 0-5 0
S-5 3/24/21 0-5 165.0 4.26 5.97
Lab sample collected from 3-5 ft BGS.
SB-6 3/24/21 0-5 1.0 ND 16.5
Lab sample collected from 0-5 ft
BGS.
SB-6-2 3/24/21 5-10 0.8
SB-6-3 3/24/21 10-15 0.3
50 100
Notes:"ND" denotes not detected. "na" denotes not analyzed. Shaded area denotes not analyzed.
Bold denotes concentration greater than State Action Limits.
NCDEQ State Action Limit Gasoline Range Organics (mg/kg)Constituent of Concern
Table 3
Phase II ESA - Bearpond Market
3963 Raleigh Road; Henderson, North Carolina
HES Project #574001
Summary of Analytical Data
(Soil Samples)
Comments
Analytical Method (e.g., VOC by EPA 8260B)
Well ID Number PID Screening (ppm)Collection
Depth
(ft. BGS)
Collection
Date
5035 / 8015
Diesel Range Organics (mg/kg)
Constituent of ConcernCollection DateTW-1 3/24/21 11.9 J1.6ND 0.82 J 1.1 J ND 3.8 2.1 0.59 J 3.8 1.9 5.6 csTW-2 3/24/21 ND ND 0.52 J ND ND22.5ND ND ND ND ND ND cs6000 1 6 600 3 20 600 400 400 none none 500 cs6000000 5000 6000 84500 3000 20000 260000 28500 25000 none none 85500 csNotes:"BQL" denotes below quantitation limit. "cs" denotes compound specific. "J" denotes estimated value. Bold denotes concentration greater than Groundwater Quality Standard. Bold denotes concentration greater than Gross Contaminant Limit.NCDEQ Groundwater Quality StandardNCDEQ Gross Contaminant LimitToluene1,2,4-Trimethylbenzene1,3,5-TrimethylbenzeneAnalytical Method (e.g., VOC by EPA 8260B)8260D (ug/L)Well ID Number AcetoneBenzene 1,1 DichloroethaneEthylbenzeneMethyl ChlorideAll Other Target Compounds m&p Xyleneo XyleneTotal XyleneMethyl Tert Butyl Ether (MTBE)(Groundwater Sample)Table 4APhase II ESA - Bearpond Market3963 Raleigh Road; Henderson, North CarolinaHES Project #574001Summary of Analytical Data
8270E
(ug/L)
Constituent of
Concern
Collection Date
TW-1 3/24/21 BQL BQL BQL BQL 395
TW-2 3/24/21 BQL BQL BQL BQL 209
cs 400 700 10000 200
cs
Notes:"BQL" denotes below quantitation limit.
"cs" denotes compound specific. "J" denotes estimated value.
Bold denotes concentration greater than Groundwater Quality Standard.
Bold denotes concentration greater than Gross Contaminant Limit.
Summary of Analytical Data
(Groundwater Sample)
Table 4B
Phase II ESA - Bearpond Market
3963 Raleigh Road; Henderson, North Carolina
HES Project #574001
Well ID Number
Analytical Method (e.g., VOC by
EPA 8260B)EPH and VPH (mg/Kg)
NCDEQ Groundwater Quality
Standard
NCDEQ Gross Contaminant Limit C5-C8 AliphaticsC19-C36 AliphaticsC9-C22 AromaticsAll Other Target CompoundsC9-C18 Aliphatics

APPENDIX D

04/05/21
Technical Report for
Highlands Environmental Solutions, Inc
574001
SGS Job Number: FA84163
Sampling Date: 03/24/21
Report to:
Highlands Environmental Solutions, Inc
8410-D Falls of Neuse Rd
Raleigh, NC 27615
[e-mail]; [e-mail];
[e-mail]
ATTN: Joe Beaman
Total number of pages in report:
Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)
DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),
AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WV
This report shall not be reproduced, except in its entirety, without the written approval of SGS.
Test results relate only to samples analyzed.
SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: [phone] • fax: [phone]
Test results contained within this data package meet the requirements
of the National Environmental Laboratory Accreditation Program
and/or state specific certification programs as applicable.
Client Service contact: Jean Dent-Smith 407-425-6700
Norm Farmer
Technical Director
Orlando, FL 04/05/21
e-Hardcopy 2.0
Automated Report
63
SGS is the sole authority for authorizing edits or modifications to this document.
Unauthorized modification of this report is strictly prohibited.
Review standard terms at: http://www.sgs.com/en/terms-and-conditions
The results set forth herein are provided by SGS North America Inc.
Please share your ideas about
how we can serve you better at:
[e-mail]
1 of 63
FA84163
Table of Contents
-1-
Sections:
Section 1: Sample Summary ................................................................................................... 3
Section 2: Summary of Hits .................................................................................................... 4
Section 3: Sample Results ........................................................................................................5
3.1: FA84163-1: TW-1 ......................................................................................................... 6
3.2: FA84163-2: TW-2 ......................................................................................................... 14
3.3: FA84163-3: SB-1 .......................................................................................................... 21
3.4: FA84163-4: SB-2 .......................................................................................................... 23
3.5: FA84163-5: SB-5 .......................................................................................................... 25
3.6: FA84163-6: SB-6 .......................................................................................................... 27
Section 4: Misc. Forms ............................................................................................................29
4.1: Chain of Custody ........................................................................................................... 30
Section 5: MS Volatiles - QC Data Summaries ..................................................................... 32
5.1: Method Blank Summary ................................................................................................ 33
5.2: Blank Spike Summary ................................................................................................... 36
5.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 39
Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 42
6.1: Method Blank Summary ................................................................................................ 43
6.2: Blank Spike Summary ................................................................................................... 45
6.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 47
Section 7: GC Volatiles - QC Data Summaries ..................................................................... 49
7.1: Method Blank Summary ................................................................................................ 50
7.2: Blank Spike Summary ................................................................................................... 52
7.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 53
7.4: Matrix Spike Summary .................................................................................................. 54
7.5: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 55
7.6: Duplicate Summary ....................................................................................................... 56
Section 8: GC/LC Semi-volatiles - QC Data Summaries ..................................................... 57
8.1: Method Blank Summary ................................................................................................ 58
8.2: Blank Spike Summary ................................................................................................... 60
8.3: Blank Spike/Blank Spike Duplicate Summary .............................................................. 61
8.4: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 62
8.5: Duplicate Summary ....................................................................................................... 63 123456782 of 63
FA84163
SGS North America Inc.
Sample Summary
Highlands Environmental Solutions, Inc
Job No:FA84163
574001
Sample Collected Matrix Client
Number Date Time By Received Code Type Sample ID
This report contains results reported as ND = Not detected. The following applies:
Organics ND = Not detected above the MDL
FA84163-1 03/24/21 11:40 BA 03/25/21 AQ Ground Water TW-1
FA84163-2 03/24/21 11:50 BA 03/25/21 AQ Ground Water TW-2
FA84163-3 03/24/21 12:14 BA 03/25/21 SO Soil SB-1
FA84163-4 03/24/21 12:08 BA 03/25/21 SO Soil SB-2
FA84163-5 03/24/21 11:53 BA 03/25/21 SO Soil SB-5
FA84163-6 03/24/21 11:59 BA 03/25/21 SO Soil SB-6
Soil samples reported on a dry weight basis unless otherwise indicated on result page.
3 of 63
FA841631
Summary of Hits Page 1 of 1
Job Number:FA84163
Account:Highlands Environmental Solutions, Inc
Project:574001
Collected:03/24/21
Lab Sample ID Client Sample ID Result/
Analyte Qual RL MDL Units Method
FA84163-1 TW-1
Acetone 11.9 J 25 10 ug/l SW846 8260D
Benzene 1.6 1.0 0.31 ug/l SW846 8260D
Ethylbenzene 0.82 J 1.0 0.36 ug/l SW846 8260D
Methyl Chloride 1.1 J 2.0 0.50 ug/l SW846 8260D
Toluene 3.8 1.0 0.30 ug/l SW846 8260D
1,2,4-Trimethylbenzene 2.1 1.0 0.32 ug/l SW846 8260D
1,3,5-Trimethylbenzene 0.59 J 1.0 0.27 ug/l SW846 8260D
m,p-Xylene 3.8 2.0 0.47 ug/l SW846 8260D
o-Xylene 1.9 1.0 0.26 ug/l SW846 8260D
Xylene (total)5.6 3.0 0.72 ug/l SW846 8260D
Toluene 1.5 J 2.0 1.0 ug/l MADEP VPH REV 2.1
C11-C22 Aromatics (Unadj.)395 200 79 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 395 200 79 ug/l MADEP EPH REV 2.1
FA84163-2 TW-2
1,1-Dichloroethane 0.52 J 1.0 0.34 ug/l SW846 8260D
Methyl Tert Butyl Ether 22.5 1.0 0.23 ug/l SW846 8260D
Methyl Tert Butyl Ether 18.5 2.0 1.0 ug/l MADEP VPH REV 2.1
C11-C22 Aromatics (Unadj.)209 200 79 ug/l MADEP EPH REV 2.1
C11-C22 Aromatics 209 200 79 ug/l MADEP EPH REV 2.1
FA84163-3 SB-1
TPH (C10-C28) a 7.28 5.8 2.9 mg/kg SW846 8015C
FA84163-4 SB-2
TPH (C10-C28) a 12.7 5.8 2.9 mg/kg SW846 8015C
FA84163-5 SB-5
TPH-GRO (C6-C10)4.26 4.0 2.0 mg/kg SW846 8015C
TPH (C10-C28)5.97 5.9 3.0 mg/kg SW846 8015C
FA84163-6 SB-6
TPH (C10-C28) a 16.5 6.3 3.1 mg/kg SW846 8015C
(a) Petroleum hydrocarbon pattern extends beyond C28.
4 of 63
FA841632
SGS North America Inc.
Sample Results
Report of Analysis
Orlando, FL
Section 3
5 of 63
FA841633
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8260D Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 C0147705.D 1 03/30/21 11:16 SO n/a n/a VC5948
Run #2 a C0147692.D 5 03/29/21 19:23 SO n/a n/a VC5947
Purge Volume
Run #1 5.0 ml
Run #2 5.0 ml
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1 Acetone 11.9 25 10 ug/l J
71-43-2 Benzene 1.6 1.0 0.31 ug/l
108-86-1 Bromobenzene ND 1.0 0.37 ug/l
74-97-5 Bromochloromethane ND 1.0 0.45 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.24 ug/l
75-25-2 Bromoform ND 1.0 0.41 ug/l
78-93-3 2-Butanone (MEK)ND 5.0 2.0 ug/l
104-51-8 n-Butylbenzene ND 1.0 0.23 ug/l
135-98-8 sec-Butylbenzene ND 1.0 0.24 ug/l
98-06-6 tert-Butylbenzene ND 1.0 0.31 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.36 ug/l
108-90-7 Chlorobenzene ND 1.0 0.20 ug/l
75-00-3 Chloroethane ND 2.0 0.67 ug/l
67-66-3 Chloroform ND 1.0 0.30 ug/l
95-49-8 o-Chlorotoluene ND 1.0 0.22 ug/l
106-43-4 p-Chlorotoluene ND 1.0 0.31 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.28 ug/l
106-93-4 1,2-Dibromoethane ND 2.0 0.28 ug/l
75-71-8 Dichlorodifluoromethane ND 2.0 0.50 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.32 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.22 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.26 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.34 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.31 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.32 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.28 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.22 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.43 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.31 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.24 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.34 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.29 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
6 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8260D Percent Solids:n/a
Project:574001
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
108-20-3 Di-Isopropyl Ether ND 1.0 0.24 ug/l
64-17-5 Ethyl Alcohol ND 200 82 ug/l
100-41-4 Ethylbenzene 0.82 1.0 0.36 ug/l J
591-78-6 2-Hexanone ND 10 2.0 ug/l
98-82-8 Isopropylbenzene ND 1.0 0.22 ug/l
99-87-6 p-Isopropyltoluene ND 1.0 0.21 ug/l
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride 1.1 2.0 0.50 ug/l J
75-09-2 Methylene Chloride ND 5.0 2.0 ug/l
108-10-1 4-Methyl-2-pentanone (MIBK)ND 5.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.23 ug/l
91-20-3 Naphthalene ND 5.0 1.0 ug/l
103-65-1 n-Propylbenzene ND 1.0 0.29 ug/l
100-42-5 Styrene ND 1.0 0.22 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.28 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.30 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.22 ug/l
108-88-3 Toluene 3.8 1.0 0.30 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 2.0 0.61 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.47 ug/l
79-01-6 Trichloroethylene ND 1.0 0.35 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene 2.1 1.0 0.32 ug/l
108-67-8 1,3,5-Trimethylbenzene 0.59 1.0 0.27 ug/l J
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.41 ug/l
m,p-Xylene 3.8 2.0 0.47 ug/l
95-47-6 o-Xylene 1.9 1.0 0.26 ug/l
1330-20-7 Xylene (total)5.6 3.0 0.72 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%99%83-118%
17060-07-0 1,2-Dichloroethane-D4 103%103%79-125%
2037-26-5 Toluene-D8 97%96%85-112%
460-00-4 4-Bromofluorobenzene 101%102%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
7 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8260D Percent Solids:n/a
Project:574001
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(a) Confirmation run.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
8 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F08014.D 1 03/30/21 20:29 WH 03/29/21 10:00 OP84691 S6F307
Run #2
Initial Volume Final Volume
Run #1 1020 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 49 9.8 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.9 0.58 ug/l
95-57-8 2-Chlorophenol ND 4.9 0.62 ug/l
120-83-2 2,4-Dichlorophenol ND 4.9 0.82 ug/l
105-67-9 2,4-Dimethylphenol ND 4.9 0.72 ug/l
51-28-5 2,4-Dinitrophenol ND 25 4.9 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.8 2.0 ug/l
95-48-7 2-Methylphenol ND 4.9 0.55 ug/l
3&4-Methylphenol ND 4.9 0.96 ug/l
88-75-5 2-Nitrophenol ND 4.9 0.84 ug/l
100-02-7 4-Nitrophenol ND 25 4.9 ug/l
87-86-5 Pentachlorophenol a ND 25 4.9 ug/l
108-95-2 Phenol ND 4.9 0.49 ug/l
88-06-2 2,4,6-Trichlorophenol ND 4.9 0.74 ug/l
83-32-9 Acenaphthene ND 4.9 0.61 ug/l
208-96-8 Acenaphthylene ND 4.9 0.63 ug/l
120-12-7 Anthracene ND 4.9 0.78 ug/l
56-55-3 Benzo(a)anthracene ND 4.9 0.75 ug/l
50-32-8 Benzo(a)pyrene ND 4.9 0.77 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.9 0.76 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.9 0.81 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.9 0.84 ug/l
100-51-6 Benzyl Alcohol ND 4.9 0.60 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.9 0.83 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.9 0.98 ug/l
106-47-8 4-Chloroaniline ND 4.9 0.62 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 4.9 0.79 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.9 0.72 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.9 0.74 ug/l
91-58-7 2-Chloronaphthalene ND 4.9 0.49 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 4.9 0.53 ug/l
218-01-9 Chrysene ND 4.9 0.83 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
9 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
53-70-3 Dibenzo(a,h)anthracene ND 4.9 0.79 ug/l
132-64-9 Dibenzofuran ND 4.9 0.59 ug/l
95-50-1 1,2-Dichlorobenzene ND 4.9 0.49 ug/l
541-73-1 1,3-Dichlorobenzene ND 4.9 0.49 ug/l
106-46-7 1,4-Dichlorobenzene ND 4.9 0.49 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 4.9 0.63 ug/l
84-66-2 Diethyl Phthalate ND 4.9 0.98 ug/l
131-11-3 Dimethyl Phthalate ND 4.9 0.98 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.9 0.98 ug/l
117-84-0 Di-n-octyl Phthalate ND 4.9 0.98 ug/l
122-66-7 1,2-Diphenylhydrazine ND 4.9 0.75 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 4.9 0.98 ug/l
206-44-0 Fluoranthene ND 4.9 0.54 ug/l
86-73-7 Fluorene ND 4.9 0.69 ug/l
118-74-1 Hexachlorobenzene ND 4.9 0.68 ug/l
87-68-3 Hexachlorobutadiene ND 4.9 0.49 ug/l
77-47-4 Hexachlorocyclopentadiene ND 4.9 1.8 ug/l
67-72-1 Hexachloroethane ND 4.9 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.9 0.70 ug/l
78-59-1 Isophorone b ND 4.9 0.76 ug/l
90-12-0 1-Methylnaphthalene ND 4.9 0.51 ug/l
91-57-6 2-Methylnaphthalene ND 4.9 0.59 ug/l
91-20-3 Naphthalene ND 4.9 0.49 ug/l
98-95-3 Nitrobenzene ND 4.9 0.91 ug/l
621-64-7 N-Nitrosodi-n-propylamine a ND 4.9 0.66 ug/l
86-30-6 N-Nitrosodiphenylamine ND 4.9 0.79 ug/l
85-01-8 Phenanthrene ND 4.9 0.85 ug/l
129-00-0 Pyrene ND 4.9 0.67 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 4.9 1.0 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 40%14-67%
4165-62-2 Phenol-d5 30%10-50%
118-79-6 2,4,6-Tribromophenol 84%33-118%
4165-60-0 Nitrobenzene-d5 67%42-108%
321-60-8 2-Fluorobiphenyl 65%40-106%
1718-51-0 Terphenyl-d14 73%39-121%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
10 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
11 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1S5861.D 1 03/26/21 14:02 BJ n/a n/a G1S196
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No. Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene 1.5 2.0 1.0 ug/l J
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 111%70-130%
460-00-4 BFB 114%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
12 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:TW-1
Lab Sample ID:FA84163-1 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN032127.D 1 03/30/21 20:14 AF 03/27/21 07:48 OP84665 GNN1565
Run #2
Initial Volume Final Volume
Run #1 1010 ml 2.0 ml
Run #2
MAEPH List
CAS No. Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)395 200 79 ug/l
C11-C22 Aromatics 395 200 79 ug/l
C9-C18 Aliphatics ND 200 50 ug/l
C19-C36 Aliphatics ND 200 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 58% a 40-140%
580-13-2 2-Bromonaphthalene 119%40-140%
84-15-1 o-Terphenyl 84% a 40-140%
321-60-8 2-Fluorobiphenyl 116%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
13 of 63
FA8416333.1
SGS North America Inc.
Report of Analysis Page 1 of 2
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8260D Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 C0147706.D 1 03/30/21 11:42 SO n/a n/a VC5948
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 10 ug/l
71-43-2 Benzene ND 1.0 0.31 ug/l
108-86-1 Bromobenzene ND 1.0 0.37 ug/l
74-97-5 Bromochloromethane ND 1.0 0.45 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.24 ug/l
75-25-2 Bromoform ND 1.0 0.41 ug/l
78-93-3 2-Butanone (MEK)ND 5.0 2.0 ug/l
104-51-8 n-Butylbenzene ND 1.0 0.23 ug/l
135-98-8 sec-Butylbenzene ND 1.0 0.24 ug/l
98-06-6 tert-Butylbenzene ND 1.0 0.31 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.36 ug/l
108-90-7 Chlorobenzene ND 1.0 0.20 ug/l
75-00-3 Chloroethane ND 2.0 0.67 ug/l
67-66-3 Chloroform ND 1.0 0.30 ug/l
95-49-8 o-Chlorotoluene ND 1.0 0.22 ug/l
106-43-4 p-Chlorotoluene ND 1.0 0.31 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.28 ug/l
106-93-4 1,2-Dibromoethane ND 2.0 0.28 ug/l
75-71-8 Dichlorodifluoromethane ND 2.0 0.50 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.32 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.22 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.26 ug/l
75-34-3 1,1-Dichloroethane 0.52 1.0 0.34 ug/l J
107-06-2 1,2-Dichloroethane ND 1.0 0.31 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.32 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.28 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.22 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.43 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.31 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.24 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.34 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.29 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
14 of 63
FA8416333.2
SGS North America Inc.
Report of Analysis Page 2 of 2
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8260D Percent Solids:n/a
Project:574001
VOA List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
108-20-3 Di-Isopropyl Ether ND 1.0 0.24 ug/l
64-17-5 Ethyl Alcohol ND 200 82 ug/l
100-41-4 Ethylbenzene ND 1.0 0.36 ug/l
591-78-6 2-Hexanone ND 10 2.0 ug/l
98-82-8 Isopropylbenzene ND 1.0 0.22 ug/l
99-87-6 p-Isopropyltoluene ND 1.0 0.21 ug/l
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride ND 2.0 0.50 ug/l
75-09-2 Methylene Chloride ND 5.0 2.0 ug/l
108-10-1 4-Methyl-2-pentanone (MIBK)ND 5.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 22.5 1.0 0.23 ug/l
91-20-3 Naphthalene ND 5.0 1.0 ug/l
103-65-1 n-Propylbenzene ND 1.0 0.29 ug/l
100-42-5 Styrene ND 1.0 0.22 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.28 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.30 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.22 ug/l
108-88-3 Toluene ND 1.0 0.30 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 2.0 0.61 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.47 ug/l
79-01-6 Trichloroethylene ND 1.0 0.35 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 1.0 0.32 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 1.0 0.27 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.41 ug/l
m,p-Xylene ND 2.0 0.47 ug/l
95-47-6 o-Xylene ND 1.0 0.26 ug/l
1330-20-7 Xylene (total)ND 3.0 0.72 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
1868-53-7 Dibromofluoromethane 99%83-118%
17060-07-0 1,2-Dichloroethane-D4 104%79-125%
2037-26-5 Toluene-D8 95%85-112%
460-00-4 4-Bromofluorobenzene 99%83-118%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
15 of 63
FA8416333.2
SGS North America Inc.
Report of Analysis Page 1 of 3
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 6F08015.D 1 03/30/21 20:54 WH 03/29/21 10:00 OP84691 S6F307
Run #2
Initial Volume Final Volume
Run #1 1020 ml 1.0 ml
Run #2
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 49 9.8 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 4.9 0.58 ug/l
95-57-8 2-Chlorophenol ND 4.9 0.62 ug/l
120-83-2 2,4-Dichlorophenol ND 4.9 0.82 ug/l
105-67-9 2,4-Dimethylphenol ND 4.9 0.72 ug/l
51-28-5 2,4-Dinitrophenol ND 25 4.9 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 9.8 2.0 ug/l
95-48-7 2-Methylphenol ND 4.9 0.55 ug/l
3&4-Methylphenol ND 4.9 0.96 ug/l
88-75-5 2-Nitrophenol ND 4.9 0.84 ug/l
100-02-7 4-Nitrophenol ND 25 4.9 ug/l
87-86-5 Pentachlorophenol a ND 25 4.9 ug/l
108-95-2 Phenol ND 4.9 0.49 ug/l
88-06-2 2,4,6-Trichlorophenol ND 4.9 0.74 ug/l
83-32-9 Acenaphthene ND 4.9 0.61 ug/l
208-96-8 Acenaphthylene ND 4.9 0.63 ug/l
120-12-7 Anthracene ND 4.9 0.78 ug/l
56-55-3 Benzo(a)anthracene ND 4.9 0.75 ug/l
50-32-8 Benzo(a)pyrene ND 4.9 0.77 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.9 0.76 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.9 0.81 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.9 0.84 ug/l
100-51-6 Benzyl Alcohol ND 4.9 0.60 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 4.9 0.83 ug/l
85-68-7 Butyl Benzyl Phthalate ND 4.9 0.98 ug/l
106-47-8 4-Chloroaniline ND 4.9 0.62 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 4.9 0.79 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 4.9 0.72 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 4.9 0.74 ug/l
91-58-7 2-Chloronaphthalene ND 4.9 0.49 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 4.9 0.53 ug/l
218-01-9 Chrysene ND 4.9 0.83 ug/l
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
16 of 63
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SGS North America Inc.
Report of Analysis Page 2 of 3
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
53-70-3 Dibenzo(a,h)anthracene ND 4.9 0.79 ug/l
132-64-9 Dibenzofuran ND 4.9 0.59 ug/l
95-50-1 1,2-Dichlorobenzene ND 4.9 0.49 ug/l
541-73-1 1,3-Dichlorobenzene ND 4.9 0.49 ug/l
106-46-7 1,4-Dichlorobenzene ND 4.9 0.49 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 4.9 0.63 ug/l
84-66-2 Diethyl Phthalate ND 4.9 0.98 ug/l
131-11-3 Dimethyl Phthalate ND 4.9 0.98 ug/l
84-74-2 Di-n-butyl Phthalate ND 4.9 0.98 ug/l
117-84-0 Di-n-octyl Phthalate ND 4.9 0.98 ug/l
122-66-7 1,2-Diphenylhydrazine ND 4.9 0.75 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 4.9 0.98 ug/l
206-44-0 Fluoranthene ND 4.9 0.54 ug/l
86-73-7 Fluorene ND 4.9 0.69 ug/l
118-74-1 Hexachlorobenzene ND 4.9 0.68 ug/l
87-68-3 Hexachlorobutadiene ND 4.9 0.49 ug/l
77-47-4 Hexachlorocyclopentadiene ND 4.9 1.8 ug/l
67-72-1 Hexachloroethane ND 4.9 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.9 0.70 ug/l
78-59-1 Isophorone b ND 4.9 0.76 ug/l
90-12-0 1-Methylnaphthalene ND 4.9 0.51 ug/l
91-57-6 2-Methylnaphthalene ND 4.9 0.59 ug/l
91-20-3 Naphthalene ND 4.9 0.49 ug/l
98-95-3 Nitrobenzene ND 4.9 0.91 ug/l
621-64-7 N-Nitrosodi-n-propylamine a ND 4.9 0.66 ug/l
86-30-6 N-Nitrosodiphenylamine ND 4.9 0.79 ug/l
85-01-8 Phenanthrene ND 4.9 0.85 ug/l
129-00-0 Pyrene ND 4.9 0.67 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 4.9 1.0 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
367-12-4 2-Fluorophenol 46%14-67%
4165-62-2 Phenol-d5 34%10-50%
118-79-6 2,4,6-Tribromophenol 88%33-118%
4165-60-0 Nitrobenzene-d5 74%42-108%
321-60-8 2-Fluorobiphenyl 73%40-106%
1718-51-0 Terphenyl-d14 82%39-121%
(a) Associated CCV outside of control limits high, sample was ND.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
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FA8416333.2
SGS North America Inc.
Report of Analysis Page 3 of 3
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:SW846 8270E SW846 3510C Percent Solids:n/a
Project:574001
ABN List for NC, May 2012
CAS No. Compound Result RL MDL Units Q
(b) Associated BS recovery outside control limits.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
18 of 63
FA8416333.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:MADEP VPH REV 2.1 Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1S5862.D 1 03/26/21 14:30 BJ n/a n/a G1S196
Run #2
Purge Volume
Run #1 5.0 ml
Run #2
MADEP VPH List
CAS No. Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether 18.5 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 BFB 113%70-130%
460-00-4 BFB 116%70-130%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
19 of 63
FA8416333.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:TW-2
Lab Sample ID:FA84163-2 Date Sampled:03/24/21
Matrix:AQ - Ground Water Date Received:03/25/21
Method:MADEP EPH REV 2.1 SW846 3510C Percent Solids:n/a
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 NN032128.D 1 03/30/21 20:44 AF 03/27/21 07:48 OP84665 GNN1565
Run #2
Initial Volume Final Volume
Run #1 1010 ml 2.0 ml
Run #2
MAEPH List
CAS No. Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)209 200 79 ug/l
C11-C22 Aromatics 209 200 79 ug/l
C9-C18 Aliphatics ND 200 50 ug/l
C19-C36 Aliphatics ND 200 50 ug/l
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
3386-33-2 1-Chlorooctadecane 53% a 40-140%
580-13-2 2-Bromonaphthalene 95%40-140%
84-15-1 o-Terphenyl 65% a 40-140%
321-60-8 2-Fluorobiphenyl 90%40-140%
(a) Surrogate recoveries corrected for double spike.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
20 of 63
FA8416333.2
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1
Lab Sample ID:FA84163-3 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C Percent Solids:86.3
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U4386.D 1 03/26/21 12:37 BJ n/a n/a G1U209
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 10.4 g 5.0 ml 100 ul
Run #2
CAS No. Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 3.6 1.8 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 102%56-149%
98-08-8 aaa-Trifluorotoluene 93%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
21 of 63
FA8416333.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-1
Lab Sample ID:FA84163-3 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C SW846 3546 Percent Solids:86.3
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW27493.D 1 03/30/21 13:04 SJL 03/29/21 09:55 OP84685 GWW1131
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No. Compound Result RL MDL Units Q
TPH (C10-C28) a 7.28 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 79%56-122%
(a) Petroleum hydrocarbon pattern extends beyond C28.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
22 of 63
FA8416333.3
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-2
Lab Sample ID:FA84163-4 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C Percent Solids:85.7
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U4387.D 1 03/26/21 13:09 BJ n/a n/a G1U209
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 10.5 g 5.0 ml 100 ul
Run #2
CAS No. Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 3.6 1.8 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 80%56-149%
98-08-8 aaa-Trifluorotoluene 79%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
23 of 63
FA8416333.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-2
Lab Sample ID:FA84163-4 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C SW846 3546 Percent Solids:85.7
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW27494.D 1 03/30/21 13:43 SJL 03/29/21 09:55 OP84685 GWW1131
Run #2
Initial Weight Final Volume
Run #1 20.0 g 1.0 ml
Run #2
CAS No. Compound Result RL MDL Units Q
TPH (C10-C28) a 12.7 5.8 2.9 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 89%56-122%
(a) Petroleum hydrocarbon pattern extends beyond C28.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
24 of 63
FA8416333.4
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-5
Lab Sample ID:FA84163-5 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C Percent Solids:84.3
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U4388.D 1 03/26/21 13:42 BJ n/a n/a G1U209
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 9.70 g 5.0 ml 100 ul
Run #2
CAS No. Compound Result RL MDL Units Q
TPH-GRO (C6-C10)4.26 4.0 2.0 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 83%56-149%
98-08-8 aaa-Trifluorotoluene 81%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
25 of 63
FA8416333.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-5
Lab Sample ID:FA84163-5 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C SW846 3546 Percent Solids:84.3
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW27495.D 1 03/30/21 14:22 SJL 03/29/21 09:55 OP84685 GWW1131
Run #2
Initial Weight Final Volume
Run #1 20.1 g 1.0 ml
Run #2
CAS No. Compound Result RL MDL Units Q
TPH (C10-C28)5.97 5.9 3.0 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 82%56-122%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
26 of 63
FA8416333.5
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-6
Lab Sample ID:FA84163-6 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C Percent Solids:78.9
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 1U4389.D 1 03/26/21 14:14 BJ n/a n/a G1U209
Run #2
Initial Weight Final Volume Methanol Aliquot
Run #1 8.77 g 5.0 ml 100 ul
Run #2
CAS No. Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.5 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
460-00-4 4-Bromofluorobenzene 96%56-149%
98-08-8 aaa-Trifluorotoluene 93%66-132%
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
27 of 63
FA8416333.6
SGS North America Inc.
Report of Analysis Page 1 of 1
Client Sample ID:SB-6
Lab Sample ID:FA84163-6 Date Sampled:03/24/21
Matrix:SO - Soil Date Received:03/25/21
Method:SW846 8015C SW846 3546 Percent Solids:78.9
Project:574001
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #1 WW27496.D 1 03/30/21 15:01 SJL 03/29/21 09:55 OP84685 GWW1131
Run #2
Initial Weight Final Volume
Run #1 20.2 g 1.0 ml
Run #2
CAS No. Compound Result RL MDL Units Q
TPH (C10-C28) a 16.5 6.3 3.1 mg/kg
CAS No.Surrogate Recoveries Run# 1 Run# 2 Limits
84-15-1 o-Terphenyl 82%56-122%
(a) Petroleum hydrocarbon pattern extends beyond C28.
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte found in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
28 of 63
FA8416333.6
SGS North America Inc.
Misc. Forms
Custody Documents and Other Forms
Includes the following where applicable:
• Chain of Custody
Orlando, FL
Section 4
29 of 63
FA841634
FA84163: Chain of Custody
Page 1 of 2
30 of 63
FA8416344.1
Job Number:FA84163 Client:HIGHLANDS ENV.
Date / Time Received:3/25/2021 10:15:00 AM Delivery Method:FX
Project:574001
Airbill #'s:7732 5322 8414
Cooler Information
1. Custody Seals Present
2. Custody Seals Intact
4. Cooler temp verification
3. Temp criteria achieved
5. Cooler media
N/A
N/A
Trip Blank Information
1. Trip Blank present / cooler
2. Trip Blank listed on COC
2. Samples preserved properly
Sample Information
1. Sample labels present on bottles
5. Sample recvd within HT
4. Condition of sample
3. Sufficient volume/containers recvd for analysis:
Intact
Comments RECEIVED ONLY 1 VIAL FOR TB
FROZEN @3/25/21 1300
SM001Rev. Date 05/24/17
SGS Sample Receipt Summary
Cooler Temps (Raw Measured) °C:
Cooler Temps (Corrected) °C:
Cooler 1: (2.8); Cooler 2: (4.0);
Cooler 1: (1.0); Cooler 2: (2.2);
3. Type Of TB Received
W or S N/A
6. Dates/Times/IDs on COC match Sample Label
7. VOCs have headspace
8. Bottles received for unspecified tests
9. Compositing instructions clear
10. Voa Soil Kits/Jars received past 48hrs?
11. % Solids Jar received?
Misc. Information
25-Gram 5-GramNumber of Encores:Number of 5035 Field Kits:Number of Lab Filtered Metals:
Test Strip Lot #s:pH 0-3 230315 pH 10-12 219813A Other: (Specify)
Y or N N/A
Y or N
Therm ID:IR 1; Therm CF:-1.8; # of Coolers:N/A
Y or N N/A
12. Residual Chlorine Present?
Residual Chlorine Test Strip Lot #:
Technician:Reviewer:PETERH Date:Date: 3/25/2021 10:15:00 A
FA84163: Chain of Custody
Page 2 of 2
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MS Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 5
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FA841635
Method Blank Summary Page 1 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-MB a C0147703.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
67-64-1 Acetone ND 25 10 ug/l
71-43-2 Benzene ND 1.0 0.31 ug/l
108-86-1 Bromobenzene ND 1.0 0.37 ug/l
74-97-5 Bromochloromethane ND 1.0 0.45 ug/l
75-27-4 Bromodichloromethane ND 1.0 0.24 ug/l
75-25-2 Bromoform ND 1.0 0.41 ug/l
78-93-3 2-Butanone (MEK)ND 5.0 2.0 ug/l
104-51-8 n-Butylbenzene ND 1.0 0.23 ug/l
135-98-8 sec-Butylbenzene ND 1.0 0.24 ug/l
98-06-6 tert-Butylbenzene ND 1.0 0.31 ug/l
56-23-5 Carbon Tetrachloride ND 1.0 0.36 ug/l
108-90-7 Chlorobenzene ND 1.0 0.20 ug/l
75-00-3 Chloroethane ND 2.0 0.67 ug/l
67-66-3 Chloroform ND 1.0 0.30 ug/l
95-49-8 o-Chlorotoluene ND 1.0 0.22 ug/l
106-43-4 p-Chlorotoluene ND 1.0 0.31 ug/l
124-48-1 Dibromochloromethane ND 1.0 0.28 ug/l
106-93-4 1,2-Dibromoethane ND 2.0 0.28 ug/l
75-71-8 Dichlorodifluoromethane ND 2.0 0.50 ug/l
95-50-1 1,2-Dichlorobenzene ND 1.0 0.32 ug/l
541-73-1 1,3-Dichlorobenzene ND 1.0 0.22 ug/l
106-46-7 1,4-Dichlorobenzene ND 1.0 0.26 ug/l
75-34-3 1,1-Dichloroethane ND 1.0 0.34 ug/l
107-06-2 1,2-Dichloroethane ND 1.0 0.31 ug/l
75-35-4 1,1-Dichloroethylene ND 1.0 0.32 ug/l
156-59-2 cis-1,2-Dichloroethylene ND 1.0 0.28 ug/l
156-60-5 trans-1,2-Dichloroethylene ND 1.0 0.22 ug/l
78-87-5 1,2-Dichloropropane ND 1.0 0.43 ug/l
142-28-9 1,3-Dichloropropane ND 1.0 0.31 ug/l
594-20-7 2,2-Dichloropropane ND 1.0 0.24 ug/l
563-58-6 1,1-Dichloropropene ND 1.0 0.34 ug/l
10061-01-5 cis-1,3-Dichloropropene ND 1.0 0.29 ug/l
10061-02-6 trans-1,3-Dichloropropene ND 1.0 0.21 ug/l
108-20-3 Di-Isopropyl Ether ND 1.0 0.24 ug/l
64-17-5 Ethyl Alcohol ND 200 82 ug/l
100-41-4 Ethylbenzene ND 1.0 0.36 ug/l
33 of 63
FA8416355.1.1
Method Blank Summary Page 2 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-MB a C0147703.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
591-78-6 2-Hexanone ND 10 2.0 ug/l
98-82-8 Isopropylbenzene ND 1.0 0.22 ug/l
99-87-6 p-Isopropyltoluene ND 1.0 0.21 ug/l
74-83-9 Methyl Bromide ND 5.0 2.0 ug/l
74-87-3 Methyl Chloride ND 2.0 0.50 ug/l
75-09-2 Methylene Chloride ND 5.0 2.0 ug/l
108-10-1 4-Methyl-2-pentanone (MIBK)ND 5.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 1.0 0.23 ug/l
91-20-3 Naphthalene ND 5.0 1.0 ug/l
103-65-1 n-Propylbenzene ND 1.0 0.29 ug/l
100-42-5 Styrene ND 1.0 0.22 ug/l
630-20-6 1,1,1,2-Tetrachloroethane ND 1.0 0.28 ug/l
79-34-5 1,1,2,2-Tetrachloroethane ND 1.0 0.30 ug/l
127-18-4 Tetrachloroethylene ND 1.0 0.22 ug/l
108-88-3 Toluene ND 1.0 0.30 ug/l
87-61-6 1,2,3-Trichlorobenzene ND 2.0 0.61 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 2.0 0.50 ug/l
71-55-6 1,1,1-Trichloroethane ND 1.0 0.25 ug/l
79-00-5 1,1,2-Trichloroethane ND 1.0 0.47 ug/l
79-01-6 Trichloroethylene ND 1.0 0.35 ug/l
75-69-4 Trichlorofluoromethane ND 2.0 0.50 ug/l
96-18-4 1,2,3-Trichloropropane ND 2.0 0.63 ug/l
95-63-6 1,2,4-Trimethylbenzene ND 1.0 0.32 ug/l
108-67-8 1,3,5-Trimethylbenzene ND 1.0 0.27 ug/l
108-05-4 Vinyl Acetate ND 10 2.0 ug/l
75-01-4 Vinyl Chloride ND 1.0 0.41 ug/l
m,p-Xylene ND 2.0 0.47 ug/l
95-47-6 o-Xylene ND 1.0 0.26 ug/l
1330-20-7 Xylene (total)ND 3.0 0.72 ug/l
CAS No.Surrogate Recoveries Limits
1868-53-7 Dibromofluoromethane 100%83-118%
17060-07-0 1,2-Dichloroethane-D4 102%79-125%
2037-26-5 Toluene-D8 95%85-112%
34 of 63
FA8416355.1.1
Method Blank Summary Page 3 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-MB a C0147703.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
CAS No. Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 99%83-118%
(a) Sample was treated with an anti-foaming agent.
35 of 63
FA8416355.1.1
Blank Spike Summary Page 1 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-BS C0147700.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
Spike BSP BSP
CAS No. Compound ug/l ug/l % Limits
67-64-1 Acetone 125 112 90 50-147
71-43-2 Benzene 25 23.5 94 81-122
108-86-1 Bromobenzene 25 23.8 95 80-121
74-97-5 Bromochloromethane 25 21.8 87 76-123
75-27-4 Bromodichloromethane 25 25.8 103 79-123
75-25-2 Bromoform 25 23.9 96 66-123
78-93-3 2-Butanone (MEK)125 100 80 56-143
104-51-8 n-Butylbenzene 25 23.3 93 79-126
135-98-8 sec-Butylbenzene 25 25.4 102 83-133
98-06-6 tert-Butylbenzene 25 24.4 98 80-133
56-23-5 Carbon Tetrachloride 25 26.0 104 76-136
108-90-7 Chlorobenzene 25 23.3 93 82-124
75-00-3 Chloroethane 25 22.6 90 62-144
67-66-3 Chloroform 25 24.1 96 80-124
95-49-8 o-Chlorotoluene 25 23.8 95 81-127
106-43-4 p-Chlorotoluene 25 23.0 92 83-130
124-48-1 Dibromochloromethane 25 24.5 98 78-122
106-93-4 1,2-Dibromoethane 25 23.6 94 75-120
75-71-8 Dichlorodifluoromethane 25 21.1 84 42-167
95-50-1 1,2-Dichlorobenzene 25 23.4 94 82-124
541-73-1 1,3-Dichlorobenzene 25 23.6 94 84-125
106-46-7 1,4-Dichlorobenzene 25 22.5 90 78-120
75-34-3 1,1-Dichloroethane 25 25.5 102 81-122
107-06-2 1,2-Dichloroethane 25 23.6 94 75-125
75-35-4 1,1-Dichloroethylene 25 24.5 98 78-137
156-59-2 cis-1,2-Dichloroethylene 25 23.9 96 78-120
156-60-5 trans-1,2-Dichloroethylene 25 24.0 96 76-127
78-87-5 1,2-Dichloropropane 25 22.7 91 76-124
142-28-9 1,3-Dichloropropane 25 22.1 88 80-118
594-20-7 2,2-Dichloropropane 25 25.2 101 74-139
563-58-6 1,1-Dichloropropene 25 23.7 95 79-131
10061-01-5 cis-1,3-Dichloropropene 25 22.5 90 75-118
10061-02-6 trans-1,3-Dichloropropene 25 23.1 92 80-120
108-20-3 Di-Isopropyl Ether 25 21.4 86 68-123
64-17-5 Ethyl Alcohol 500 471 94 46-145
100-41-4 Ethylbenzene 25 24.2 97 81-121
* = Outside of Control Limits.
36 of 63
FA8416355.2.1
Blank Spike Summary Page 2 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-BS C0147700.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
Spike BSP BSP
CAS No. Compound ug/l ug/l % Limits
591-78-6 2-Hexanone 125 104 83 61-129
98-82-8 Isopropylbenzene 25 24.5 98 83-132
99-87-6 p-Isopropyltoluene 25 25.0 100 79-130
74-83-9 Methyl Bromide 25 23.1 92 59-143
74-87-3 Methyl Chloride 25 20.7 83 50-159
75-09-2 Methylene Chloride 25 22.2 89 69-135
108-10-1 4-Methyl-2-pentanone (MIBK)125 103 82 66-122
1634-04-4 Methyl Tert Butyl Ether 25 21.3 85 72-117
91-20-3 Naphthalene 25 24.6 98 63-132
103-65-1 n-Propylbenzene 25 24.4 98 82-133
100-42-5 Styrene 25 23.5 94 78-119
630-20-6 1,1,1,2-Tetrachloroethane 25 23.9 96 77-122
79-34-5 1,1,2,2-Tetrachloroethane 25 22.2 89 72-120
127-18-4 Tetrachloroethylene 25 23.8 95 76-135
108-88-3 Toluene 25 22.3 89 80-120
87-61-6 1,2,3-Trichlorobenzene 25 25.7 103 68-131
120-82-1 1,2,4-Trichlorobenzene 25 23.6 94 73-129
71-55-6 1,1,1-Trichloroethane 25 25.5 102 75-130
79-00-5 1,1,2-Trichloroethane 25 22.9 92 76-119
79-01-6 Trichloroethylene 25 24.6 98 81-126
75-69-4 Trichlorofluoromethane 25 26.6 106 71-156
96-18-4 1,2,3-Trichloropropane 25 21.2 85 77-120
95-63-6 1,2,4-Trimethylbenzene 25 23.7 95 79-120
108-67-8 1,3,5-Trimethylbenzene 25 24.3 97 79-120
108-05-4 Vinyl Acetate 125 96.4 77 43-154
75-01-4 Vinyl Chloride 25 22.9 92 69-159
m,p-Xylene 50 49.0 98 79-126
95-47-6 o-Xylene 25 23.7 95 80-127
1330-20-7 Xylene (total)75 72.7 97 80-126
CAS No.Surrogate Recoveries BSP Limits
1868-53-7 Dibromofluoromethane 101%83-118%
17060-07-0 1,2-Dichloroethane-D4 100%79-125%
2037-26-5 Toluene-D8 99%85-112%
* = Outside of Control Limits.
37 of 63
FA8416355.2.1
Blank Spike Summary Page 3 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
VC5948-BS C0147700.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
CAS No. Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 100%83-118%
* = Outside of Control Limits.
38 of 63
FA8416355.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84176-3MS C0147722.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3MSD C0147723.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3 C0147709.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
FA84176-3 Spike MS MS Spike MSD MSD Limits
CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD
67-64-1 Acetone ND 125 129 103 125 119 95 8 50-147/21
71-43-2 Benzene ND 25 27.2 109 25 25.0 100 8 81-122/14
108-86-1 Bromobenzene ND 25 27.3 109 25 24.5 98 11 80-121/14
74-97-5 Bromochloromethane ND 25 26.2 105 25 24.3 97 8 76-123/14
75-27-4 Bromodichloromethane ND 25 28.7 115 25 27.1 108 6 79-123/19
75-25-2 Bromoform ND 25 28.7 115 25 26.0 104 10 66-123/21
78-93-3 2-Butanone (MEK)ND 125 124 99 125 117 94 6 56-143/18
104-51-8 n-Butylbenzene ND 25 25.5 102 25 25.2 101 1 79-126/16
135-98-8 sec-Butylbenzene ND 25 28.5 114 25 27.0 108 5 83-133/16
98-06-6 tert-Butylbenzene ND 25 26.9 108 25 25.5 102 5 80-133/16
56-23-5 Carbon Tetrachloride ND 25 29.7 119 25 27.6 110 7 76-136/23
108-90-7 Chlorobenzene ND 25 27.2 109 25 24.4 98 11 82-124/14
75-00-3 Chloroethane ND 25 25.6 102 25 21.8 87 16 62-144/20
67-66-3 Chloroform ND 25 28.5 114 25 26.6 106 7 80-124/15
95-49-8 o-Chlorotoluene ND 25 26.9 108 25 24.4 98 10 81-127/15
106-43-4 p-Chlorotoluene ND 25 26.6 106 25 24.1 96 10 83-130/15
124-48-1 Dibromochloromethane ND 25 28.4 114 25 25.9 104 9 78-122/19
106-93-4 1,2-Dibromoethane ND 25 27.5 110 25 25.1 100 9 75-120/13
75-71-8 Dichlorodifluoromethane ND 25 21.2 85 25 18.9 76 11 42-167/19
95-50-1 1,2-Dichlorobenzene ND 25 26.8 107 25 25.1 100 7 82-124/14
541-73-1 1,3-Dichlorobenzene ND 25 26.9 108 25 24.6 98 9 84-125/14
106-46-7 1,4-Dichlorobenzene ND 25 26.3 105 25 24.4 98 7 78-120/15
75-34-3 1,1-Dichloroethane ND 25 28.6 114 25 26.9 108 6 81-122/15
107-06-2 1,2-Dichloroethane ND 25 27.9 112 25 25.6 102 9 75-125/14
75-35-4 1,1-Dichloroethylene ND 25 27.8 111 25 26.1 104 6 78-137/18
156-59-2 cis-1,2-Dichloroethylene ND 25 27.9 112 25 25.8 103 8 78-120/15
156-60-5 trans-1,2-Dichloroethylene ND 25 27.0 108 25 25.1 100 7 76-127/17
78-87-5 1,2-Dichloropropane ND 25 26.8 107 25 24.7 99 8 76-124/14
142-28-9 1,3-Dichloropropane ND 25 25.8 103 25 24.3 97 6 80-118/13
594-20-7 2,2-Dichloropropane ND 25 27.0 108 25 24.8 99 8 74-139/17
563-58-6 1,1-Dichloropropene ND 25 26.6 106 25 24.6 98 8 79-131/16
10061-01-5 cis-1,3-Dichloropropene ND 25 25.7 103 25 23.5 94 9 75-118/23
10061-02-6 trans-1,3-Dichloropropene ND 25 26.8 107 25 24.5 98 9 80-120/22
108-20-3 Di-Isopropyl Ether ND 25 24.4 98 25 23.0 92 6 68-123/16
64-17-5 Ethyl Alcohol ND 500 466 93 500 409 82 13 46-145/30
100-41-4 Ethylbenzene ND 25 27.3 109 25 24.8 99 10 81-121/14
* = Outside of Control Limits.
39 of 63
FA8416355.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84176-3MS C0147722.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3MSD C0147723.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3 C0147709.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
FA84176-3 Spike MS MS Spike MSD MSD Limits
CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD
591-78-6 2-Hexanone ND 125 133 106 125 124 99 7 61-129/18
98-82-8 Isopropylbenzene ND 25 28.5 114 25 25.8 103 10 83-132/15
99-87-6 p-Isopropyltoluene ND 25 27.9 112 25 26.9 108 4 79-130/16
74-83-9 Methyl Bromide ND 25 12.0 48*25 12.6 50*5 59-143/19
74-87-3 Methyl Chloride ND 25 6.6 26*25 15.2 61 79*50-159/19
75-09-2 Methylene Chloride ND 25 24.9 100 25 23.4 94 6 69-135/16
108-10-1 4-Methyl-2-pentanone (MIBK)ND 125 131 105 125 123 98 6 66-122/16
1634-04-4 Methyl Tert Butyl Ether ND 25 25.2 101 25 24.3 97 4 72-117/14
91-20-3 Naphthalene 15.3 25 29.8 58*25 28.3 52*5 63-132/25
103-65-1 n-Propylbenzene ND 25 27.1 108 25 24.9 100 8 82-133/15
100-42-5 Styrene ND 25 27.7 111 25 25.5 102 8 78-119/23
630-20-6 1,1,1,2-Tetrachloroethane ND 25 27.2 109 25 24.9 100 9 77-122/19
79-34-5 1,1,2,2-Tetrachloroethane ND 25 26.3 105 25 25.2 101 4 72-120/14
127-18-4 Tetrachloroethylene ND 25 27.8 111 25 25.2 101 10 76-135/16
108-88-3 Toluene ND 25 25.5 102 25 23.3 93 9 80-120/14
87-61-6 1,2,3-Trichlorobenzene ND 25 28.9 116 25 27.4 110 5 68-131/25
120-82-1 1,2,4-Trichlorobenzene ND 25 26.7 107 25 26.2 105 2 73-129/20
71-55-6 1,1,1-Trichloroethane ND 25 29.2 117 25 27.5 110 6 75-130/16
79-00-5 1,1,2-Trichloroethane ND 25 28.0 112 25 25.2 101 11 76-119/14
79-01-6 Trichloroethylene ND 25 26.9 108 25 24.8 99 8 81-126/15
75-69-4 Trichlorofluoromethane ND 25 26.2 105 25 25.5 102 3 71-156/21
96-18-4 1,2,3-Trichloropropane ND 25 26.8 107 25 26.3 105 2 77-120/16
95-63-6 1,2,4-Trimethylbenzene ND 25 26.8 107 25 25.0 100 7 79-120/18
108-67-8 1,3,5-Trimethylbenzene ND 25 27.8 111 25 26.1 104 6 79-120/19
108-05-4 Vinyl Acetate ND 125 105 84 125 96.9 78 8 43-154/14
75-01-4 Vinyl Chloride ND 25 22.1 88 25 20.6 82 7 69-159/18
m,p-Xylene ND 50 55.6 111 50 51.0 102 9 79-126/15
95-47-6 o-Xylene ND 25 27.1 108 25 24.5 98 10 80-127/14
1330-20-7 Xylene (total)ND 75 82.6 110 75 75.5 101 9 80-126/15
CAS No.Surrogate Recoveries MS MSD FA84176-3 Limits
1868-53-7 Dibromofluoromethane 99%102%99%83-118%
17060-07-0 1,2-Dichloroethane-D4 102%102%104%79-125%
2037-26-5 Toluene-D8 98%97%95%85-112%
* = Outside of Control Limits.
40 of 63
FA8416355.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 3 of 3
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84176-3MS C0147722.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3MSD C0147723.D 1 03/30/21 SO n/a n/a VC5948
FA84176-3 C0147709.D 1 03/30/21 SO n/a n/a VC5948
The QC reported here applies to the following samples:Method: SW846 8260D
FA84163-1, FA84163-2
CAS No. Surrogate Recoveries MS MSD FA84176-3 Limits
460-00-4 4-Bromofluorobenzene 100%100%99%83-118%
* = Outside of Control Limits.
41 of 63
FA8416355.3.1
SGS North America Inc.
MS Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 6
42 of 63
FA841636
Method Blank Summary Page 1 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-MB 6F08007.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
65-85-0 Benzoic Acid ND 50 10 ug/l
59-50-7 4-Chloro-3-methyl Phenol ND 5.0 0.59 ug/l
95-57-8 2-Chlorophenol ND 5.0 0.63 ug/l
120-83-2 2,4-Dichlorophenol ND 5.0 0.84 ug/l
105-67-9 2,4-Dimethylphenol ND 5.0 0.74 ug/l
51-28-5 2,4-Dinitrophenol ND 25 5.0 ug/l
534-52-1 4,6-Dinitro-o-cresol ND 10 2.0 ug/l
95-48-7 2-Methylphenol ND 5.0 0.56 ug/l
3&4-Methylphenol ND 5.0 0.98 ug/l
88-75-5 2-Nitrophenol ND 5.0 0.85 ug/l
100-02-7 4-Nitrophenol ND 25 5.0 ug/l
87-86-5 Pentachlorophenol ND 25 5.0 ug/l
108-95-2 Phenol ND 5.0 0.50 ug/l
88-06-2 2,4,6-Trichlorophenol ND 5.0 0.75 ug/l
83-32-9 Acenaphthene ND 5.0 0.63 ug/l
208-96-8 Acenaphthylene ND 5.0 0.64 ug/l
120-12-7 Anthracene ND 5.0 0.80 ug/l
56-55-3 Benzo(a)anthracene ND 5.0 0.76 ug/l
50-32-8 Benzo(a)pyrene ND 5.0 0.78 ug/l
205-99-2 Benzo(b)fluoranthene ND 5.0 0.78 ug/l
191-24-2 Benzo(g,h,i)perylene ND 5.0 0.82 ug/l
207-08-9 Benzo(k)fluoranthene ND 5.0 0.86 ug/l
100-51-6 Benzyl Alcohol ND 5.0 0.61 ug/l
101-55-3 4-Bromophenyl Phenyl Ether ND 5.0 0.85 ug/l
85-68-7 Butyl Benzyl Phthalate ND 5.0 1.0 ug/l
106-47-8 4-Chloroaniline ND 5.0 0.63 ug/l
111-91-1 bis(2-Chloroethoxy)methane ND 5.0 0.81 ug/l
111-44-4 bis(2-Chloroethyl)ether ND 5.0 0.73 ug/l
108-60-1 2,2'-Oxybis(1-chloropropane)ND 5.0 0.76 ug/l
91-58-7 2-Chloronaphthalene ND 5.0 0.50 ug/l
7005-72-3 4-Chlorophenyl Phenyl Ether ND 5.0 0.54 ug/l
218-01-9 Chrysene ND 5.0 0.85 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 5.0 0.80 ug/l
132-64-9 Dibenzofuran ND 5.0 0.60 ug/l
95-50-1 1,2-Dichlorobenzene ND 5.0 0.50 ug/l
541-73-1 1,3-Dichlorobenzene ND 5.0 0.50 ug/l
43 of 63
FA8416366.1.1
Method Blank Summary Page 2 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-MB 6F08007.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
106-46-7 1,4-Dichlorobenzene ND 5.0 0.50 ug/l
91-94-1 3,3'-Dichlorobenzidine ND 5.0 0.64 ug/l
84-66-2 Diethyl Phthalate ND 5.0 1.0 ug/l
131-11-3 Dimethyl Phthalate ND 5.0 1.0 ug/l
84-74-2 Di-n-butyl Phthalate ND 5.0 1.0 ug/l
117-84-0 Di-n-octyl Phthalate ND 5.0 1.0 ug/l
122-66-7 1,2-Diphenylhydrazine ND 5.0 0.76 ug/l
117-81-7 bis(2-Ethylhexyl)phthalate ND 5.0 1.0 ug/l
206-44-0 Fluoranthene ND 5.0 0.55 ug/l
86-73-7 Fluorene ND 5.0 0.70 ug/l
118-74-1 Hexachlorobenzene ND 5.0 0.69 ug/l
87-68-3 Hexachlorobutadiene ND 5.0 0.50 ug/l
77-47-4 Hexachlorocyclopentadiene ND 5.0 1.8 ug/l
67-72-1 Hexachloroethane ND 5.0 1.6 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 5.0 0.71 ug/l
78-59-1 Isophorone ND 5.0 0.78 ug/l
90-12-0 1-Methylnaphthalene ND 5.0 0.53 ug/l
91-57-6 2-Methylnaphthalene ND 5.0 0.60 ug/l
91-20-3 Naphthalene ND 5.0 0.50 ug/l
98-95-3 Nitrobenzene ND 5.0 0.93 ug/l
621-64-7 N-Nitrosodi-n-propylamine ND 5.0 0.67 ug/l
86-30-6 N-Nitrosodiphenylamine ND 5.0 0.81 ug/l
85-01-8 Phenanthrene ND 5.0 0.86 ug/l
129-00-0 Pyrene ND 5.0 0.68 ug/l
120-82-1 1,2,4-Trichlorobenzene ND 5.0 1.1 ug/l
CAS No.Surrogate Recoveries Limits
367-12-4 2-Fluorophenol 33%14-67%
4165-62-2 Phenol-d5 22%10-50%
118-79-6 2,4,6-Tribromophenol 82%33-118%
4165-60-0 Nitrobenzene-d5 79%42-108%
321-60-8 2-Fluorobiphenyl 69%40-106%
1718-51-0 Terphenyl-d14 79%39-121%
44 of 63
FA8416366.1.1
Blank Spike Summary Page 1 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-BS 6F08006.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
Spike BSP BSP
CAS No. Compound ug/l ug/l % Limits
65-85-0 Benzoic Acid 100 29.7 30 10-69
59-50-7 4-Chloro-3-methyl Phenol 50 47.5 95 54-103
95-57-8 2-Chlorophenol 50 35.7 71 52-98
120-83-2 2,4-Dichlorophenol 50 46.3 93 53-103
105-67-9 2,4-Dimethylphenol 50 43.7 87 43-90
51-28-5 2,4-Dinitrophenol 100 88.7 89 44-112
534-52-1 4,6-Dinitro-o-cresol 100 102 102 66-121
95-48-7 2-Methylphenol 50 37.8 76 43-90
3&4-Methylphenol 100 78.5 79 36-88
88-75-5 2-Nitrophenol 50 47.0 94 53-102
100-02-7 4-Nitrophenol 100 31.3 31 18-62
87-86-5 Pentachlorophenol 100 104 104 61-115
108-95-2 Phenol 50 22.0 44 19-56
88-06-2 2,4,6-Trichlorophenol 50 46.9 94 59-107
83-32-9 Acenaphthene 50 44.1 88 61-107
208-96-8 Acenaphthylene 50 46.9 94 60-104
120-12-7 Anthracene 50 47.4 95 65-108
56-55-3 Benzo(a)anthracene 50 47.6 95 66-111
50-32-8 Benzo(a)pyrene 50 50.9 102 62-107
205-99-2 Benzo(b)fluoranthene 50 49.1 98 65-114
191-24-2 Benzo(g,h,i)perylene 50 45.8 92 66-116
207-08-9 Benzo(k)fluoranthene 50 50.2 100 65-114
100-51-6 Benzyl Alcohol 50 36.2 72 46-94
101-55-3 4-Bromophenyl Phenyl Ether 50 48.6 97 65-109
85-68-7 Butyl Benzyl Phthalate 50 51.4 103 65-112
106-47-8 4-Chloroaniline 50 44.8 90 49-105
111-91-1 bis(2-Chloroethoxy)methane 50 50.1 100 51-102
111-44-4 bis(2-Chloroethyl)ether 50 43.3 87 53-100
108-60-1 2,2'-Oxybis(1-chloropropane)50 43.9 88 45-106
91-58-7 2-Chloronaphthalene 50 45.6 91 57-103
7005-72-3 4-Chlorophenyl Phenyl Ether 50 47.8 96 62-105
218-01-9 Chrysene 50 47.6 95 66-111
53-70-3 Dibenzo(a,h)anthracene 50 46.9 94 66-119
132-64-9 Dibenzofuran 50 47.9 96 61-106
95-50-1 1,2-Dichlorobenzene 50 42.2 84 48-97
541-73-1 1,3-Dichlorobenzene 50 40.8 82 45-95
* = Outside of Control Limits.
45 of 63
FA8416366.2.1
Blank Spike Summary Page 2 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-BS 6F08006.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
Spike BSP BSP
CAS No. Compound ug/l ug/l % Limits
106-46-7 1,4-Dichlorobenzene 50 38.7 77 45-98
91-94-1 3,3'-Dichlorobenzidine 50 49.3 99 46-117
84-66-2 Diethyl Phthalate 50 49.3 99 64-108
131-11-3 Dimethyl Phthalate 50 49.5 99 63-106
84-74-2 Di-n-butyl Phthalate 50 51.1 102 65-107
117-84-0 Di-n-octyl Phthalate 50 52.4 105 62-118
122-66-7 1,2-Diphenylhydrazine 50 47.8 96 61-110
117-81-7 bis(2-Ethylhexyl)phthalate 50 49.9 100 61-117
206-44-0 Fluoranthene 50 49.4 99 63-106
86-73-7 Fluorene 50 47.7 95 62-108
118-74-1 Hexachlorobenzene 50 47.4 95 63-108
87-68-3 Hexachlorobutadiene 50 42.8 86 42-102
77-47-4 Hexachlorocyclopentadiene 50 45.5 91 39-102
67-72-1 Hexachloroethane 50 39.4 79 42-100
193-39-5 Indeno(1,2,3-cd)pyrene 50 47.2 94 64-119
78-59-1 Isophorone 50 46.6 93*43-87
90-12-0 1-Methylnaphthalene 50 43.4 87 53-102
91-57-6 2-Methylnaphthalene 50 44.6 89 51-102
91-20-3 Naphthalene 50 43.7 87 47-100
98-95-3 Nitrobenzene 50 45.8 92 50-104
621-64-7 N-Nitrosodi-n-propylamine 50 46.8 94 52-104
86-30-6 N-Nitrosodiphenylamine 50 45.2 90 64-108
85-01-8 Phenanthrene 50 48.5 97 66-110
129-00-0 Pyrene 50 47.4 95 64-113
120-82-1 1,2,4-Trichlorobenzene 50 43.7 87 45-97
CAS No.Surrogate Recoveries BSP Limits
367-12-4 2-Fluorophenol 44%14-67%
4165-62-2 Phenol-d5 39%10-50%
118-79-6 2,4,6-Tribromophenol 95%33-118%
4165-60-0 Nitrobenzene-d5 91%42-108%
321-60-8 2-Fluorobiphenyl 88%40-106%
1718-51-0 Terphenyl-d14 83%39-121%
* = Outside of Control Limits.
46 of 63
FA8416366.2.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-MS 6F08012.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
OP84691-MSD 6F08013.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
FA84176-3 6F08011.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
FA84176-3 Spike MS MS Spike MSD MSD Limits
CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD
65-85-0 Benzoic Acid ND 192 77.4 40 192 71.6 37 8 10-69/39
59-50-7 4-Chloro-3-methyl Phenol ND 96.2 86.5 90 96.2 86.9 90 0 54-103/23
95-57-8 2-Chlorophenol ND 96.2 73.3 76 96.2 77.3 80 5 52-98/25
120-83-2 2,4-Dichlorophenol ND 96.2 88.1 92 96.2 86.2 90 2 53-103/26
105-67-9 2,4-Dimethylphenol ND 96.2 84.5 88 96.2 81.6 85 3 43-90/27
51-28-5 2,4-Dinitrophenol ND 192 178 93 192 163 85 9 44-112/25
534-52-1 4,6-Dinitro-o-cresol ND 192 198 103 192 188 98 5 66-121/23
95-48-7 2-Methylphenol ND 96.2 63.5 66 96.2 72.3 75 13 43-90/28
3&4-Methylphenol ND 192 132 69 192 158 82 18 36-88/28
88-75-5 2-Nitrophenol ND 96.2 81.1 84 96.2 81.5 85 0 53-102/29
100-02-7 4-Nitrophenol ND 192 83.5 43 192 97.3 51 15 18-62/33
87-86-5 Pentachlorophenol ND 192 206 107 192 199 103 3 61-115/26
108-95-2 Phenol ND 96.2 38.3 40 96.2 58.6 61*42*19-56/35
88-06-2 2,4,6-Trichlorophenol ND 96.2 90.1 94 96.2 82.2 85 9 59-107/23
83-32-9 Acenaphthene ND 96.2 81.0 84 96.2 74.6 78 8 61-107/22
208-96-8 Acenaphthylene ND 96.2 86.0 89 96.2 79.8 83 7 60-104/22
120-12-7 Anthracene ND 96.2 87.6 91 96.2 83.3 87 5 65-108/20
56-55-3 Benzo(a)anthracene ND 96.2 91.9 96 96.2 85.9 89 7 66-111/22
50-32-8 Benzo(a)pyrene ND 96.2 94.4 98 96.2 89.2 93 6 62-107/23
205-99-2 Benzo(b)fluoranthene ND 96.2 94.6 98 96.2 82.5 86 14 65-114/23
191-24-2 Benzo(g,h,i)perylene ND 96.2 84.8 88 96.2 79.8 83 6 66-116/23
207-08-9 Benzo(k)fluoranthene ND 96.2 88.1 92 96.2 85.5 89 3 65-114/24
100-51-6 Benzyl Alcohol ND 96.2 79.5 83 96.2 70.0 73 13 46-94/27
101-55-3 4-Bromophenyl Phenyl Ether ND 96.2 92.5 96 96.2 87.3 91 6 65-109/23
85-68-7 Butyl Benzyl Phthalate ND 96.2 98.6 103 96.2 93.0 97 6 65-112/24
106-47-8 4-Chloroaniline ND 96.2 76.4 79 96.2 74.4 77 3 49-105/27
111-91-1 bis(2-Chloroethoxy)methane ND 96.2 91.5 95 96.2 84.7 88 8 51-102/28
111-44-4 bis(2-Chloroethyl)ether ND 96.2 77.3 80 96.2 76.4 79 1 53-100/27
108-60-1 2,2'-Oxybis(1-chloropropane)ND 96.2 85.7 89 96.2 83.3 87 3 45-106/26
91-58-7 2-Chloronaphthalene ND 96.2 85.6 89 96.2 80.2 83 7 57-103/23
7005-72-3 4-Chlorophenyl Phenyl Ether ND 96.2 86.0 89 96.2 83.7 87 3 62-105/20
218-01-9 Chrysene ND 96.2 93.0 97 96.2 84.9 88 9 66-111/22
53-70-3 Dibenzo(a,h)anthracene ND 96.2 87.6 91 96.2 81.6 85 7 66-119/24
132-64-9 Dibenzofuran ND 96.2 86.0 89 96.2 80.8 84 6 61-106/21
95-50-1 1,2-Dichlorobenzene ND 96.2 78.9 82 96.2 74.1 77 6 48-97/24
541-73-1 1,3-Dichlorobenzene ND 96.2 78.8 82 96.2 72.0 75 9 45-95/25
* = Outside of Control Limits.
47 of 63
FA8416366.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 2 of 2
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84691-MS 6F08012.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
OP84691-MSD 6F08013.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
FA84176-3 6F08011.D 1 03/30/21 WH 03/29/21 OP84691 S6F307
The QC reported here applies to the following samples:Method: SW846 8270E
FA84163-1, FA84163-2
FA84176-3 Spike MS MS Spike MSD MSD Limits
CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD
106-46-7 1,4-Dichlorobenzene ND 96.2 76.9 80 96.2 70.0 73 9 45-98/25
91-94-1 3,3'-Dichlorobenzidine ND 96.2 75.6 79 96.2 73.2 76 3 46-117/29
131-11-3 Dimethyl Phthalate ND 96.2 88.7 92 96.2 84.6 88 5 63-106/22
84-74-2 Di-n-butyl Phthalate ND 96.2 95.7 100 96.2 87.0 90 10 65-107/21
117-84-0 Di-n-octyl Phthalate ND 96.2 97.4 101 96.2 91.6 95 6 62-118/24
122-66-7 1,2-Diphenylhydrazine ND 96.2 87.5 91 96.2 82.9 86 5 61-110/24
117-81-7 bis(2-Ethylhexyl)phthalate ND 96.2 97.1 101 96.2 88.7 92 9 61-117/23
206-44-0 Fluoranthene ND 96.2 92.1 96 96.2 83.6 87 10 63-106/21
86-73-7 Fluorene ND 96.2 87.7 91 96.2 82.1 85 7 62-108/20
118-74-1 Hexachlorobenzene ND 96.2 88.8 92 96.2 80.3 84 10 63-108/22
87-68-3 Hexachlorobutadiene ND 96.2 82.2 85 96.2 77.0 80 7 42-102/28
77-47-4 Hexachlorocyclopentadiene ND 96.2 83.2 87 96.2 75.2 78 10 39-102/29
67-72-1 Hexachloroethane ND 96.2 74.6 78 96.2 71.0 74 5 42-100/29
193-39-5 Indeno(1,2,3-cd)pyrene ND 96.2 88.3 92 96.2 79.0 82 11 64-119/24
78-59-1 Isophorone ND 96.2 88.0 92*96.2 81.0 84 8 43-87/25
90-12-0 1-Methylnaphthalene ND 96.2 82.0 85 96.2 75.2 78 9 53-102/27
91-57-6 2-Methylnaphthalene ND 96.2 83.4 87 96.2 77.4 80 7 51-102/26
91-20-3 Naphthalene ND 96.2 82.3 86 96.2 76.3 79 8 47-100/29
98-95-3 Nitrobenzene ND 96.2 87.1 91 96.2 79.1 82 10 50-104/28
621-64-7 N-Nitrosodi-n-propylamine ND 96.2 1.6 2*96.2 1.7 2*6 52-104/25
86-30-6 N-Nitrosodiphenylamine ND 96.2 84.3 88 96.2 77.2 80 9 64-108/23
85-01-8 Phenanthrene ND 96.2 91.4 95 96.2 83.7 87 9 66-110/21
129-00-0 Pyrene ND 96.2 91.5 95 96.2 86.7 90 5 64-113/23
120-82-1 1,2,4-Trichlorobenzene ND 96.2 83.3 87 96.2 76.6 80 8 45-97/28
CAS No.Surrogate Recoveries MS MSD FA84176-3 Limits
367-12-4 2-Fluorophenol 48%65%40%14-67%
4165-62-2 Phenol-d5 37%55%* a 30%10-50%
118-79-6 2,4,6-Tribromophenol 92%89%83%33-118%
4165-60-0 Nitrobenzene-d5 92%85%71%42-108%
321-60-8 2-Fluorobiphenyl 85%78%71%40-106%
1718-51-0 Terphenyl-d14 89%84%74%39-121%
(a) Outside control limits.
* = Outside of Control Limits.
48 of 63
FA8416366.3.1
SGS North America Inc.
GC Volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 7
49 of 63
FA841637
Method Blank Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S196-MB 1S5857.D 1 03/26/21 BJ n/a n/a G1S196
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
71-43-2 Benzene ND 1.0 1.0 ug/l
100-41-4 Ethylbenzene ND 2.0 1.0 ug/l
1634-04-4 Methyl Tert Butyl Ether ND 2.0 1.0 ug/l
91-20-3 Naphthalene ND 5.0 3.0 ug/l
108-88-3 Toluene ND 2.0 1.0 ug/l
m,p-Xylene ND 4.0 2.0 ug/l
95-47-6 o-Xylene ND 2.0 1.0 ug/l
C5- C8 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C12 Aliphatics (Unadj.)ND 100 35 ug/l
C9- C10 Aromatics (Unadj.)ND 100 35 ug/l
C5- C8 Aliphatics ND 100 35 ug/l
C9- C12 Aliphatics ND 100 35 ug/l
C9- C10 Aromatics ND 100 35 ug/l
CAS No.Surrogate Recoveries Limits
460-00-4 BFB 103%70-130%
460-00-4 BFB 105%70-130%
50 of 63
FA8416377.1.1
Method Blank Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U209-MB 1U4385.D 1 03/26/21 BJ n/a n/a G1U209
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
CAS No. Compound Result RL MDL Units Q
TPH-GRO (C6-C10)ND 5.0 2.5 mg/kg
CAS No.Surrogate Recoveries Limits
460-00-4 4-Bromofluorobenzene 98%56-149%
98-08-8 aaa-Trifluorotoluene 92%66-132%
51 of 63
FA8416377.1.2
Blank Spike Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1U209-BS 1U4384.D 1 03/26/21 BJ n/a n/a G1U209
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
Spike BSP BSP
CAS No. Compound mg/kg mg/kg % Limits
TPH-GRO (C6-C10) 20 21.2 106 74-128
CAS No.Surrogate Recoveries BSP Limits
460-00-4 4-Bromofluorobenzene 98%56-149%
98-08-8 aaa-Trifluorotoluene 92%66-132%
* = Outside of Control Limits.
52 of 63
FA8416377.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
G1S196-BS 1S5855.D 1 03/26/21 BJ n/a n/a G1S196
G1S196-BSD 1S5856.D 1 03/26/21 BJ n/a n/a G1S196
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA84163-1, FA84163-2
Spike BSP BSP BSD BSD Limits
CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD
71-43-2 Benzene 80 75.4 94 81.1 101 7 70-130/25
100-41-4 Ethylbenzene 80 77.3 97 81.1 101 5 70-130/25
1634-04-4 Methyl Tert Butyl Ether 80 70.8 89 83.0 104 16 70-130/25
91-20-3 Naphthalene 80 73.3 92 86.8 109 17 70-130/25
108-88-3 Toluene 80 75.2 94 79.6 100 6 70-130/25
m,p-Xylene 160 153 96 161 101 5 70-130/25
95-47-6 o-Xylene 80 76.5 96 80.6 101 5 70-130/25
C5- C8 Aliphatics (Unadj.)240 231 96 236 98 2 70-130/25
C9- C12 Aliphatics (Unadj.)160 163 102 163 102 0 70-130/25
C9- C10 Aromatics (Unadj.)80 75.8 95 83.2 104 9 70-130/25
C9- C10 Aromatics 80 75.8 95 83.2 104 9 70-130/25
CAS No.Surrogate Recoveries BSP BSD Limits
460-00-4 BFB 80%89%70-130%
460-00-4 BFB 82%91%70-130%
* = Outside of Control Limits.
53 of 63
FA8416377.3.1
Matrix Spike Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84025-2MS 1S5864.D 1 03/26/21 BJ n/a n/a G1S196
FA84025-2 1S5858.D 1 03/26/21 BJ n/a n/a G1S196
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA84163-1, FA84163-2
FA84025-2 Spike MS MS
CAS No. Compound ug/l Q ug/l ug/l % Limits
71-43-2 Benzene ND 80 79.8 100 70-130
100-41-4 Ethylbenzene ND 80 80.7 101 70-130
1634-04-4 Methyl Tert Butyl Ether ND 80 88.1 110 70-130
91-20-3 Naphthalene ND 80 89.4 112 70-130
108-88-3 Toluene ND 80 78.7 98 70-130
m,p-Xylene ND 160 159 99 70-130
95-47-6 o-Xylene ND 80 81.1 101 70-130
C5- C8 Aliphatics (Unadj.)ND 480 503 105 70-130
C9- C12 Aliphatics (Unadj.)ND 400 427 107 70-130
C9- C10 Aromatics (Unadj.)ND 240 246 103 70-130
C9- C10 Aromatics ND 240 246 103 70-130
CAS No.Surrogate Recoveries MS FA84025-2 Limits
460-00-4 BFB 97%113%70-130%
460-00-4 BFB 100%116%70-130%
* = Outside of Control Limits.
54 of 63
FA8416377.4.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84163-3MS 1U4390.D 1 03/26/21 BJ n/a n/a G1U209
FA84163-3MSD 1U4391.D 1 03/26/21 BJ n/a n/a G1U209
FA84163-3 1U4386.D 1 03/26/21 BJ n/a n/a G1U209
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
FA84163-3 Spike MS MS Spike MSD MSD Limits
CAS No. Compound mg/kg Q mg/kg mg/kg % mg/kg mg/kg % RPD Rec/RPD
TPH-GRO (C6-C10) ND 14.3 15.2 106 14.3 15.4 107 1 74-128/17
CAS No.Surrogate Recoveries MS MSD FA84163-3 Limits
460-00-4 4-Bromofluorobenzene 98%99%102%56-149%
98-08-8 aaa-Trifluorotoluene 92%94%93%66-132%
* = Outside of Control Limits.
55 of 63
FA8416377.5.1
Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
FA84025-2DUP 1S5859.D 1 03/26/21 BJ n/a n/a G1S196
FA84025-2 1S5858.D 1 03/26/21 BJ n/a n/a G1S196
The QC reported here applies to the following samples:Method: MADEP VPH REV 2.1
FA84163-1, FA84163-2
FA84025-2 DUP
CAS No. Compound ug/l Q ug/l Q RPD Limits
71-43-2 Benzene ND ND nc 50
100-41-4 Ethylbenzene ND ND nc 50
1634-04-4 Methyl Tert Butyl Ether ND ND nc 50
91-20-3 Naphthalene ND ND nc 50
108-88-3 Toluene ND ND nc 50
m,p-Xylene ND ND nc 50
95-47-6 o-Xylene ND ND nc 50
C5- C8 Aliphatics (Unadj.)ND ND nc 50
C9- C12 Aliphatics (Unadj.)ND ND nc 50
C9- C10 Aromatics (Unadj.)ND ND nc 50
C5- C8 Aliphatics ND ND nc 50
C9- C12 Aliphatics ND ND nc 50
C9- C10 Aromatics ND ND nc 50
CAS No.Surrogate Recoveries DUP FA84025-2 Limits
460-00-4 BFB 114%113%70-130%
460-00-4 BFB 116%116%70-130%
* = Outside of Control Limits.
56 of 63
FA8416377.6.1
SGS North America Inc.
GC/LC Semi-volatiles
QC Data Summaries
Includes the following where applicable:
• Method Blank Summaries
• Blank Spike Summaries
• Matrix Spike and Duplicate Summaries
Orlando, FL
Section 8
57 of 63
FA841638
Method Blank Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84665-MB NN032120.D 1 03/30/21 AF 03/27/21 OP84665 GNN1565
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA84163-1, FA84163-2
CAS No. Compound Result RL MDL Units Q
83-32-9 Acenaphthene ND 4.0 2.0 ug/l
208-96-8 Acenaphthylene ND 4.0 2.0 ug/l
120-12-7 Anthracene ND 4.0 2.0 ug/l
56-55-3 Benzo(a)anthracene ND 4.0 2.0 ug/l
50-32-8 Benzo(a)pyrene ND 4.0 2.0 ug/l
205-99-2 Benzo(b)fluoranthene ND 4.0 2.0 ug/l
191-24-2 Benzo(g,h,i)perylene ND 4.0 2.0 ug/l
207-08-9 Benzo(k)fluoranthene ND 4.0 2.0 ug/l
218-01-9 Chrysene ND 4.0 2.0 ug/l
53-70-3 Dibenzo(a,h)anthracene ND 4.0 2.0 ug/l
206-44-0 Fluoranthene ND 4.0 2.0 ug/l
86-73-7 Fluorene ND 4.0 2.0 ug/l
193-39-5 Indeno(1,2,3-cd)pyrene ND 4.0 2.0 ug/l
91-57-6 2-Methylnaphthalene ND 4.0 2.0 ug/l
91-20-3 Naphthalene ND 4.0 2.0 ug/l
85-01-8 Phenanthrene ND 4.0 2.0 ug/l
129-00-0 Pyrene ND 4.0 2.0 ug/l
C11-C22 Aromatics (Unadj.)ND 200 80 ug/l
C11-C22 Aromatics ND 200 80 ug/l
C9-C18 Aliphatics ND 200 50 ug/l
C19-C36 Aliphatics ND 200 50 ug/l
CAS No.Surrogate Recoveries Limits
3386-33-2 1-Chlorooctadecane 81%40-140%
580-13-2 2-Bromonaphthalene 97%40-140%
84-15-1 o-Terphenyl 74%40-140%
321-60-8 2-Fluorobiphenyl 94%40-140%
58 of 63
FA8416388.1.1
Method Blank Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84685-MB WW27482.D 1 03/30/21 SJL 03/29/21 OP84685 GWW1131
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
CAS No. Compound Result RL MDL Units Q
TPH (C10-C28)ND 5.0 2.5 mg/kg
CAS No.Surrogate Recoveries Limits
84-15-1 o-Terphenyl 70%56-122%
59 of 63
FA8416388.1.2
Blank Spike Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84685-BS WW27481.D 1 03/30/21 SJL 03/29/21 OP84685 GWW1131
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
Spike BSP BSP
CAS No. Compound mg/kg mg/kg % Limits
TPH (C10-C28)50 43.8 88 62-116
CAS No.Surrogate Recoveries BSP Limits
84-15-1 o-Terphenyl 90%56-122%
* = Outside of Control Limits.
60 of 63
FA8416388.2.1
Blank Spike/Blank Spike Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84665-BS NN032121.D 1 03/30/21 AF 03/27/21 OP84665 GNN1565
OP84665-BSD NN032122.D 1 03/30/21 AF 03/27/21 OP84665 GNN1565
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA84163-1, FA84163-2
Spike BSP BSP BSD BSD Limits
CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD
83-32-9 Acenaphthene 100 83.9 84 78.5 79 7 40-140/30
208-96-8 Acenaphthylene 100 84.9 85 79.4 79 7 40-140/30
120-12-7 Anthracene 100 93.1 93 87.2 87 7 40-140/30
56-55-3 Benzo(a)anthracene 100 102 102 95.7 96 6 40-140/30
50-32-8 Benzo(a)pyrene 100 103 103 96.7 97 6 40-140/30
205-99-2 Benzo(b)fluoranthene 100 114 114 107 107 6 40-140/30
191-24-2 Benzo(g,h,i)perylene 100 104 104 97.9 98 6 40-140/30
207-08-9 Benzo(k)fluoranthene 100 90.6 91 84.8 85 7 40-140/30
218-01-9 Chrysene 100 104 104 97.6 98 6 40-140/30
53-70-3 Dibenzo(a,h)anthracene 100 118 118 111 111 6 40-140/30
206-44-0 Fluoranthene 100 98.6 99 92.7 93 6 40-140/30
86-73-7 Fluorene 100 90.6 91 85.3 85 6 40-140/30
193-39-5 Indeno(1,2,3-cd)pyrene 100 111 111 104 104 7 40-140/30
91-57-6 2-Methylnaphthalene 100 74.3 74 69.3 69 7 40-140/30
91-20-3 Naphthalene 100 67.4 67 62.4 62 8 40-140/30
85-01-8 Phenanthrene 100 91.6 92 86.3 86 6 40-140/30
129-00-0 Pyrene 100 101 101 95.4 95 6 40-140/30
C11-C22 Aromatics (Unadj.)1700 1680 99 1570 92 7 40-140/30
C9-C18 Aliphatics 600 384 64 379 63 1 40-140/30
C19-C36 Aliphatics 800 636 80 606 76 5 40-140/30
CAS No.Surrogate Recoveries BSP BSD Limits
3386-33-2 1-Chlorooctadecane 84%81%40-140%
580-13-2 2-Bromonaphthalene 113%100%40-140%
84-15-1 o-Terphenyl 85%81%40-140%
321-60-8 2-Fluorobiphenyl 104%95%40-140%
Sample Compound Col #1 Col #2 Breakthrough Limit
OP84665-BS 2-Methylnaphthalene 74.3 ND 0.0%5.0
OP84665-BS Naphthalene 67.4 ND 0.0%5.0
OP84665-BSD 2-Methylnaphthalene 69.3 ND 0.0%5.0
OP84665-BSD Naphthalene 62.4 ND 0.0%5.0
* = Outside of Control Limits.
61 of 63
FA8416388.3.1
Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84685-MS WW27486.D 1 03/30/21 SJL 03/29/21 OP84685 GWW1131
OP84685-MSD WW27487.D 1 03/30/21 SJL 03/29/21 OP84685 GWW1131
FA84108-2 WW27485.D 1 03/30/21 SJL 03/29/21 OP84685 GWW1131
The QC reported here applies to the following samples:Method: SW846 8015C
FA84163-3, FA84163-4, FA84163-5, FA84163-6
FA84108-2 Spike MS MS Spike MSD MSD Limits
CAS No. Compound mg/kg Q mg/kg mg/kg % mg/kg mg/kg % RPD Rec/RPD
TPH (C10-C28)ND 56 54.0 96 56 54.9 98 2 62-116/35
CAS No.Surrogate Recoveries MS MSD FA84108-2 Limits
84-15-1 o-Terphenyl 96%98%82%56-122%
* = Outside of Control Limits.
62 of 63
FA8416388.4.1
Duplicate Summary Page 1 of 1
Job Number:FA84163
Account:HESNCR Highlands Environmental Solutions, Inc
Project:574001
Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
OP84665-DUP NN032123.D 1 03/30/21 AF 03/27/21 OP84665 GNN1565
JD22268-1 NN032125.D 1 03/30/21 AF 03/27/21 OP84665 GNN1565
The QC reported here applies to the following samples:Method: MADEP EPH REV 2.1
FA84163-1, FA84163-2
JD22268-1 DUP
CAS No. Compound ug/l Q ug/l Q RPD Limits
83-32-9 Acenaphthene ND ND nc 30 a
208-96-8 Acenaphthylene ND ND nc 30 a
120-12-7 Anthracene ND ND nc 30 a
56-55-3 Benzo(a)anthracene ND ND nc 30 a
50-32-8 Benzo(a)pyrene ND ND nc 30 a
205-99-2 Benzo(b)fluoranthene ND ND nc 30 a
191-24-2 Benzo(g,h,i)perylene ND ND nc 30 a
207-08-9 Benzo(k)fluoranthene ND ND nc 30 a
218-01-9 Chrysene ND ND nc 30 a
53-70-3 Dibenzo(a,h)anthracene ND ND nc 30 a
206-44-0 Fluoranthene ND ND nc 30 a
86-73-7 Fluorene ND ND nc 30 a
193-39-5 Indeno(1,2,3-cd)pyrene ND ND nc 30 a
91-57-6 2-Methylnaphthalene ND ND nc 30 a
91-20-3 Naphthalene ND ND nc 30 a
85-01-8 Phenanthrene ND ND nc 30 a
129-00-0 Pyrene ND ND nc 30 a
C11-C22 Aromatics (Unadj.)828 776 6 30 a
C11-C22 Aromatics 828 776 6 30 a
C9-C18 Aliphatics 437 97.1 J 127*30 a
C19-C36 Aliphatics 183 78.5 J 80*30 a
CAS No.Surrogate Recoveries DUP JD22268-1 Limits
3386-33-2 1-Chlorooctadecane 67%50% b 40-140%
580-13-2 2-Bromonaphthalene 118%123%40-140%
84-15-1 o-Terphenyl 73%63% b 40-140%
321-60-8 2-Fluorobiphenyl 108%112%40-140%
(a) Advisory control limits.
(b) Surrogate recoveries corrected for double spike.
* = Outside of Control Limits.
63 of 63
FA8416388.5.1

APPENDIX C
BEARPOND MARKET. 3963 RALEIGH RD., HENDERSON, VANCE COUNTY, NORTH CAROLINA
Limited Site Assessment Risk Classification and Land Use Form
Part I - Groundwater/Surface Water/Vapor Impacts
High Risk
1. Has the discharge or release contaminated any water supply well including any used for
non-drinking purposes? YES/NO
If yes, explain.
2. Is a water supply well used for drinking water located within 1,000 feet of the source area
of the discharge or release? YES/NO
Numerous active sole source water supply wells are located within a 1,000-ft. radius. See Figure 2 and Table 3.
3. Is a water supply well used for any purpose (e.g., irrigation, washing cars, industrial cooling
water, filling swimming pools) located within 250 feet of the source area of the release or
discharge? YES/NO 4. Does groundwater within 500 feet of the source area of the discharge or release have the potential for future use in that there is no other source of water supply other than the
groundwater? YES/NO
Explain
Municipal water is not available to all properties within a 500-ft. radius. 5. Do vapors from the discharge or release pose a threat of explosion because of accumulation
of the vapors in a confined space or pose any serious threat to public health, public safety,
or the environment? YES/NO
Explain.
Terraquest did not discover any confined spaces that may trap vapors or notice any high petroleum vapor levels that may pose a threat to public health.
6. Are there any other factors that would cause the discharge or release to pose an imminent
danger to public health, public safety, or the environment? YES/NO
If yes, explain.

BEARPOND MARKET. 3963 RALEIGH RD., HENDERSON, VANCE COUNTY, NORTH CAROLINA

LSA Risk Classification and Land Use Form
By: Terraquest Environmental Consultants, P.C.
Page 2 of 4
Intermediate Risk 7. Is a surface water body located within 500 feet of the source area of the discharge or
release? YES/NO

If yes, does the maximum groundwater contaminant concentration exceed the surface water quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10?
YES/NO

8. Is the source area of the discharge or release located within a protection area as defined in
42 USC 300h-7(e)? YES/NO
If yes, explain

9. Is the discharge or release located in the Coastal Plain physiographic region as designated on a map entitled Geology of North Carolina published by the Department in 1985?
YES/NO If yes, is the source area of the discharge or release located in an area in which there is a
recharge to an unconfined or semi-confined deeper aquifer that is being used or may be
used as a source of drinking water? YES/NO
If yes, explain.

10. Do levels of groundwater contamination exceed the gross contamination levels established
(see Table 7) by the Department? YES/NO
See Table 7.

BEARPOND MARKET. 3963 RALEIGH RD., HENDERSON, VANCE COUNTY, NORTH CAROLINA

LSA Risk Classification and Land Use Form
By: Terraquest Environmental Consultants, P.C.
Page 3 of 4
Part II - Land Use Property Containing Source Area of Discharge or Release
The questions below pertain to the property containing the source area of the release.
1. Does the property contain one or more primary or secondary residences (permanent or
temporary)? YES/NO
Explain.
The property is a convenience store, gas station, grill, and meat market. 2. Does the property contain a school, daycare center, hospital, playground, park, recreation
area, church, nursing home, or other place of public assembly? YES/NO
Explain.
The property is a convenience store, gas station, grill, and meat market. 3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.)
Or industrial (e.g., manufacturing, utilities, industrial research and development,
chemical/petroleum bulk storage, etc.) Enterprise, an inactive commercial or industrial
enterprise, or is the land undeveloped? YES/NO Explain. The property is a convenience store, gas station, grill, and meat market.

4. Do children visit the property? YES/NO
Explain.
Children can visit the property. 5. Is access to the property reliably restricted consistent with its use (e.g., by fences, security
personnel, or both)? YES/NO
Explain.
No fences.
6. Do pavement, buildings, or other structures cap the contaminated soil? YES/NO
Explain.

The contaminated soil is covered by an asphalt and concrete surface.
If yes, what mechanisms are in place or can be put in place to ensure that the contaminated soil will remain capped in the foreseeable future?

Maintenance of the asphalt and concrete surfaces. 7. What is the zoning status of the property?
Vance County Residential (R-20)
BEARPOND MARKET. 3963 RALEIGH RD., HENDERSON, VANCE COUNTY, NORTH CAROLINA

LSA Risk Classification and Land Use Form
By: Terraquest Environmental Consultants, P.C.
Page 4 of 4

8. Is the use of the property likely to change in the next 20 years? Explain. The site will most likely remain in a commercial capacity given its current location and
convenience store and gas station development.
Property Surrounding Source Area of Discharge or Release The questions below pertain to the area within 1,500 feet of the source area of the discharge or release (excludes property containing source area of the release):

1. What is the distance from the source area of the release to the nearest primary or secondary residence (permanent or temporary)? The closest residence is located 120 feet to the southeast on the adjacent property.

2. What is the distance from the source area of the release to the nearest school, daycare center, hospital, playground, park, recreation area, church, nursing home, or other place of public assembly?
A church is located approximately 430 feet to the northwest.
3. What is the zoning status of properties in the surrounding area? The subject property and surrounding properties to the north, south, and further west
have Vance County residential zoning classifications. The surrounding properties to the
west have a Vance County Office/Institutional zoning classification. The surrounding properties to the south and east have a Vance County General Commercial zoning classification. The surrounding properties to the east have a Vance County Highway Commercial zoning classification. The surrounding properties to the southwest and
northeast have a Vance County Manufactured Housing Community zoning
classification. 4. Briefly characterize the use and activities of the land in the surrounding area.
Properties to the north, east, and further south and west are single-family residences. A
church is located to the west and a railroad track and manufacturing facility are located to the east.

APPENDIX D
WELL CONSTRUCTION RECORD (GW-1) For Internal Use Only:
Form GW-1 North Carolina Department of Environmental Quality - Division of Water Resources Revised 2-22-2016
1. Well Contractor Information:
Well Contractor Name
NC Well Contractor Certification Number
Company Name
2. Well Construction Permit #:
List all applicable well construction permits (i.e. UIC, County, State, Variance, etc.)
3. Well Use (check well use):
Water Supply Well:
Agricultural Municipal/Public
Geothermal (Heating/Cooling Supply) Residential Water Supply (single)
Industrial/Commercial Residential Water Supply (shared)
Irrigation
Non-Water Supply Well:
Monitoring Recovery
Injection Well:
Aquifer Recharge Groundwater Remediation
Aquifer Storage and Recovery Salinity Barrier
Aquifer Test Stormwater Drainage
Experimental Technology Subsidence Control
Geothermal (Closed Loop) Tracer
Geothermal (Heating/Cooling Return) Other (explain under #21 Remarks)
4. Date Well(s) Completed: Well ID#
5a. Well Location:

Facility/Owner Name Facility ID# (if applicable)

Physical Address, City, and Zip

County Parcel Identification No. (PIN)
5b. Latitude and longitude in degrees/minutes/seconds or decimal degrees:
(if well field, one lat/long is sufficient)
N W
6. Is(are) the well(s): Permanent or Temporary
7. Is this a repair to an existing well: Yes or No
If this is a repair, fill out known well construction information and explain the nature of the
repair under #21 remarks section or on the back of this form.
8. For Geoprobe/DPT or Closed-Loop Geothermal Wells having the same
construction, only 1 GW-1 is needed. Indicate TOTAL NUMBER of wells
drilled:
9. Total well depth below land surface: (ft.)
For multiple wells list all depths if different (example- )
10. Static water level below top of casing: (ft.)
If water level is above casing,
11. Borehole diameter: (in.)
12. Well construction method:
(i.e. auger, rotary, cable, direct push, etc.)
FOR WATER SUPPLY WELLS ONLY:
13a. Yield (gpm) Method of test:
13b. Disinfection type: Amount:
14. WATER ZONES
FROM TO DESCRIPTION
ft.ft.
ft.ft.
15. OUTER CASING (for multi-cased wells) OR LINER (if applicable)
FROM TO DIAMETER THICKNESS MATERIAL
ft.ft.in.
16. INNER CASING OR TUBING (geothermal closed-loop)
FROM TO DIAMETER THICKNESS MATERIAL
ft.ft.in.
ft.ft.in.
17. SCREEN
FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL
ft.ft.in.
ft.ft.in.
18. GROUT
FROM TO MATERIAL EMPLACEMENT METHOD & AMOUNT
ft.ft.
ft.ft.
ft.ft.
19. SAND/GRAVEL PACK (if applicable)
FROM TO MATERIAL EMPLACEMENT METHOD
ft.ft.
ft.ft.
20. DRILLING LOG (attach additional sheets if necessary)
FROM TO DESCRIPTION (color, hardness, soil/rock type, grain size, etc.)
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
ft.ft.
21. REMARKS
22. Certification:
Signature of Certified Well Contractor Date
By signing this form, I hereby certify that the well(s) was (were) constructed in accordance
with 15A NCAC 02C .0100 or 15A NCAC 02C .0200 Well Construction Standards and that a copy of this record has been provided to the well owner.
23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well
construction details. You may also attach additional pages if necessary.
SUBMITTAL INSTRUCTIONS
24a. For All Wells: Submit this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Information Processing Unit,
1617 Mail Service Center, Raleigh, NC 27699-1617
24b. For Injection Wells: In addition to sending the form to the address in 24a
above, also submit one copy of this form within 30 days of completion of well
construction to the following:
Division of Water Resources, Underground Injection Control Program,
1636 Mail Service Center, Raleigh, NC 27699-1636
24c. For Water Supply & Injection Wells: In addition to sending the form to
the address(es) above, also submit one copy of this form within 30 days of
completion of well construction to the county health department of the county
where constructed.
Wesley J. Sorrells
3577
Terraquest Environmental Consultants
1
1/5/2023 MW1
Bear Pond
3963 Raliegh Rd. Henderson NC.
Vance
36.277358 -78.405784
20
9.75
4.25
Solid Stem Augers
1/5/2023
5 20 2 10Slot Scd.40 PVC
1
0.5
3
3
1
20
Bentonite
Portland
No.2 Sand Pour
Pour
0
0.5
1
11
0.5
1
11
20
Asphalt
Gravel
Sandy Clay
Silt With Little Sand
Pour

5
10
15
20

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine
sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor
yellowish-orange, moist @ 9 feet BGL.
Sandy Silt (ML)
soft, grey/white, mostly silt, little fine sand, moist.
Boring Terminated at 15 Ft. BGL

1.5
2.0
0.2
NA
NA
NA
BORING LOG/MONITORING WELL INSTALLATION DETAIL
1/5/23
00323
Date Started:
Logged by:
Contractor:
Drill Method:
Site:
Project No.:1
Boring Number:SampleBlow
Counts Completion Depth Lithology DescriptionFeet
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC 27537
MW1/SB4
Scale as shown; Hatch pattern denotes soil sample depth;
1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Well Construction
2" diameter Sch. 40 PVC; .010" slotted screen
Sand: no. 2 sand; Grout: poured portland; Bentonite: poured pellets
Finished with 8"-diameter metal bolt down manhole.
Driller:
Date Finished:
Terraquest
Solid Stem
W. Sorrells
NA - Not Applicable; BGL - Below Ground Level

5
10

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Boring Terminated at 10 feet BGL.

NA
NA

0.1
0.2
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB1
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Boring Terminated at 10 feet BGL.

NA
NA

0.0
1.0
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB2
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sand (SC)
loose, grey, mostly fine sand, trace clay, dry
Sandy Clay (CL)med. stiff, yellowish-orange, mostly clay, w/little fine sand/mica, dry
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Boring Terminated at 10 feet BGL.

NA
NA

0.9
1.6
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB3
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10
15

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Sandy Silt (ML)
soft, grey/white, mostly silt, little fine sand, moist.
Boring Terminated at 15 Ft. BGL

NA
NA
NA

0.3
0.5
0
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB5
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Boring Terminated at 10 feet BGL.

NA
NA

0.0
0.0
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraquest
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB6
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

5
10

Asphalt
Sandy Clay (CL)
med. stiff, yellowish-orange, mostly clay, w/ little fine sand/mica, dry.
Sandy Clay (CL)
med. stiff, to soft at 8 ft. BGL, grey/tan minor yellowish-orange, moist
@ 9 feet BGL.
Boring Terminated at 10 feet BGL.

NA
NA

0.0
0.0
BORING LOG
1/5/23
00323
Date Started:
Logged by:
Contractor:
Equipment:
Site:
Project No.:1
Boring Number:SampleBlow
Counts
Depth Lithology DescriptionFeet
Terraqueste
J. Grubbs
Bearpond Market3963 Raleigh Rd.Henderson, NC
W. Sorrells SB7
Scale as shown: Hatch pattern denotes soil sample depth;
Driller:
Date Finished:
Page
OVM
(ppm)
Client:Bearpond Market, Inc.1600 N Lynnbank RdHenderson, NC 27537
Geoprobe 1/5/23
Solid denotes lab sample depth; Lithology hatch pattern legend is attached;
NA - Not Applicable; BGL - Below Groundlevel

APPENDIX E
0
UVF TRILOGY ANALYTICAL REPORT
Project Name: Bearpond Market
Project Number: 00323
Date: 1/6/2023
Standard Technical Procedures

The UVF TRILOGY instrument is a fixed-wavelength fluorometer but uses deep UV LEDS to detect
monoaromatic and polyaromatic hydrocarbons.
SITELAB’s CAL-025 GRO Module is used to detect volatile petroleum hydrocarbons in the C6 to C10 range.
This test matches well to EPA Methods for GRO, BTEX, BPH or VOC’s using GC/FID instrumentation.
SITELAB’s CAL-042 EDRO Module is used to detect petroleum hydrocarbons in the C10 to C36 diesel and
oil range. This test matches well to EPA methods for TPH, EPH, DRO, and others using GC-FID
instrumentation.
Prior to field usage, the UVF TRILOGY is calibrated with five calibration standard solutions per targeted
analyte.
Soil samples are weighed to the nearest gram (i.e. 5.0 g) and added to a 1-ounce HDPE Nalgene bottle
with a measured amount of laboratory grade methanol to the nearest mL (i.e. 10 mL) to create a sample
extract. After addition of both the soil and methanol, the bottle is agitated for several minutes. Next, the
sample rests for several minutes allowing for the soil and methanol extract to separate.
After ample resting time, the methanol extract is collected with a syringe. A filter is connected to the end
of the syringe and dispensed into a clean sample test tube. The test tube is labeled with sample ID and
extract dilution factor (i.e. 2X).
Known amounts of extract are pipetted into a second test tube and diluted with methanol. The sample
ID and dilution factor are labeled on the test tube (i.e. 100X).
Samples are placed into a clean cuvette and carefully inserted into the selected UV Module. Prior to
analyzing the sample, the stored calibration that matches the UV Module being used, is selected. The
UVF TRILOGY produces a result that when multiplied to the dilution factor equals the true TPH value.
Quenching occurs when the detector is swamped by too many or certain type of hydrocarbons, producing
low or negative concentrations. The sample is tested at multiple dilutions to confirm the results are linear
and accurate.
Solvent blank samples are periodically analyzed to confirm the solvent is clean and the calibration of the
machine is maintained.

UVF Analytical Report
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB1 8-10 1/5/2023 GRO 2 <1 1 mg/kg
Friday, January 6, 2023 Page 1 of 6
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB2 8-10 1/5/2023 GRO 2 <1 1 mg/kg
Friday, January 6, 2023 Page 2 of 6
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB3 8-10 1/5/2023 GRO 2 <1 1 mg/kg
Friday, January 6, 2023 Page 3 of 6
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB5 8-10 1/5/2023 GRO 2 <1`1 mg/kg
Friday, January 6, 2023 Page 4 of 6
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB6 8-10 1/5/2023 GRO 2 <1 1 mg/kg
Friday, January 6, 2023 Page 5 of 6
Project Name Bearpond Market
Project Number 00322
Method UVF Trilogy
Sample Name Sample Depth Sample Date Analyte Name Dilution Result MDL Units
SB7 3-5 1/5/2023 GRO 2 3.4 1 mg/kg
Friday, January 6, 2023 Page 6 of 6
ANALYTICAL REPORT
PREPARED FOR
Attn: Jonathan Grubs
Terraquest Environmental Consultants, PC
100 E. Ruffin Street
Mebane, North Carolina 27302
Generated 1/16/2023 2:59:08 PM
JOB DESCRIPTION
Bear Pond Market
JOB NUMBER
400-231380-1
See page two for job notes and contact information.
Pensacola FL 32514
3355 McLemore Drive
Eurofins Pensacola
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Eurofins Pensacola
Eurofins Pensacola is a laboratory within Eurofins Environment Testing Southeast, LLC, a company within Eurofins Environment Testing Group of Companies
Job Notes
The test results in this report meet all NELAP requirements for accredited parameters, unless otherwise noted, and relate
only to the referenced samples. Pursuant to NELAP, this report may not be reproduced, except in full, without written
approval from the laboratory. For questions please contact the Project Manager at the e-mail address listed on this page, or
the telephone number at the bottom of the page. Eurofins Environment Testing Southeast LLC, Pensacola Certifications and
Approvals: Alabama (40150), Arizona (AZ0710), Arkansas (88-0689), Florida (E81010), Illinois (200041), Iowa (367), Kansas
(E-10253), Kentucky UST (53), Louisiana (30748), Maryland (233), Massachusetts (M-FL094), Michigan (9912), New
Hampshire (250510), New Jersey (FL006), North Carolina (314), Oklahoma (9810), Pennsylvania (68-00467), Rhode Island
(LAO00307), South Carolina (96026), Tennessee (TN02907), Texas (T104704286-10-2), Virginia (00008), Washington
(C2043), West Virginia (136), USDA Foreign Soil Permit (P330-08-00006).
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the
methodology, with any exceptions noted. This report shall not be reproduced except in full, without the express written
approval of the laboratory. All questions should be directed to the Eurofins Environment Testing Southeast, LLC Project
Manager.
Authorization
Generated
1/16/2023 2:59:08 PM
Authorized for release by
Chad Bechtold, Project Manager
[e-mail]
[phone]
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Table of Contents
Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Laboratory Job ID: 400-231380-1
Page 3 of 34 Eurofins Pensacola1/16/2023
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .12
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .17
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .27
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .33
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .34
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Case Narrative
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Job ID: 400-231380-1
Laboratory: Eurofins Pensacola
Narrative
Job Narrative
400-231380-1
Receipt
The samples were received on 1/6/2023 8:58 AM. Unless otherwise noted below, the samples arrived in good condition, and, where
required, properly preserved and on ice. The temperature of the cooler at receipt time was 1.3°C
GC/MS VOA
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Hydrocarbons
Method MAVPH: The following sample was diluted because the base dilution for methanol preserved soil analysis is 1:50: MW1 (8-10)
(400-231380-2).
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
GC Semi VOA
Method 504.1: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for preparation batch
400-608226 and analytical batch 400-608260 recovered outside control limits for the following analytes: 1,2-Dibromoethane (EDB).
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
Metals
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
General Chemistry
No additional analytical or quality issues were noted, other than those described above or in the Definitions/ Glossary page.
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Detection Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Client Sample ID: MW1 Lab Sample ID: 400-231380-1
Benzene
RL
1.00 ug/L
MDL
0.130
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.635 SM6200-B
Toluene 1.00 ug/L0.410 Total/NA10.467 J SM6200-B
Lead 0.0100 mg/L0.00200 Total/NA10.0245 6010D
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2
☼Benzene
RL
0.00840 mg/Kg
MDL
0.00113
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1J0.00615 8260D
☼Toluene 0.00840 mg/Kg0.00168 Total/NA10.00188 J 8260D
☼Xylenes, Total 0.0168 mg/Kg0.00319 Total/NA10.00613 J 8260D
Eurofins Pensacola
This Detection Summary does not include radiochemical test results.
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Sample Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Lab Sample ID Client Sample ID Matrix Collected Received
400-231380-1 MW1 Ground Water 01/05/23 13:45 01/06/23 08:58
400-231380-2 MW1 (8-10)Soil 01/05/23 10:47 01/06/23 08:58
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Client Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Lab Sample ID: 400-231380-1Client Sample ID: MW1
Matrix: Ground WaterDate Collected: 01/05/23 13:45
Date Received: 01/06/23 08:58
Method: SM6200-B - Volatile Organic Compounds
RL MDL
0.160 U 1.00 0.160 ug/L 01/08/23 17:42 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
1.00 0.180 ug/L 01/08/23 17:42 10.180 U1,1,1-Trichloroethane
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,1,2,2-Tetrachloroethane
5.00 0.210 ug/L 01/08/23 17:42 10.210 U1,1,2-Trichloroethane
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,1-Dichloroethane
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,1-Dichloroethene
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,1-Dichloropropene
1.00 0.900 ug/L 01/08/23 17:42 10.900 U1,2,3-Trichlorobenzene
5.00 0.840 ug/L 01/08/23 17:42 10.840 U1,2,3-Trichloropropane
1.00 0.820 ug/L 01/08/23 17:42 10.820 U1,2,4-Trichlorobenzene
1.00 0.820 ug/L 01/08/23 17:42 10.820 U1,2,4-Trimethylbenzene
1.00 0.230 ug/L 01/08/23 17:42 10.230 U1,2-Dibromoethane (EDB)
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,2-Dichlorobenzene
1.00 0.190 ug/L 01/08/23 17:42 10.190 U1,2-Dichloroethane
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,2-Dichloropropane
1.00 0.560 ug/L 01/08/23 17:42 10.560 U1,3,5-Trimethylbenzene
1.00 0.540 ug/L 01/08/23 17:42 10.540 U1,3-Dichlorobenzene
1.00 0.500 ug/L 01/08/23 17:42 10.500 U1,3-Dichloropropane
1.00 0.640 ug/L 01/08/23 17:42 10.640 U1,4-Dichlorobenzene
1.00 0.500 ug/L 01/08/23 17:42 10.500 U2,2-Dichloropropane
25.0 2.60 ug/L 01/08/23 17:42 12.60 U2-Butanone (MEK)
1.00 0.570 ug/L 01/08/23 17:42 10.570 U2-Chlorotoluene
25.0 1.40 ug/L 01/08/23 17:42 11.40 U2-Hexanone
1.00 0.560 ug/L 01/08/23 17:42 10.560 U4-Chlorotoluene
25.0 1.80 ug/L 01/08/23 17:42 11.80 U4-Methyl-2-pentanone (MIBK)
25.0 10.0 ug/L 01/08/23 17:42 110.0 UAcetone
1.00 0.130 ug/L 01/08/23 17:42 10.635 JBenzene
1.00 0.540 ug/L 01/08/23 17:42 10.540 UBromobenzene
1.00 0.210 ug/L 01/08/23 17:42 10.210 UBromochloromethane
1.00 0.500 ug/L 01/08/23 17:42 10.500 UBromodichloromethane
5.00 0.250 ug/L 01/08/23 17:42 10.250 UBromoform
1.00 0.980 ug/L 01/08/23 17:42 10.980 UBromomethane
1.00 0.190 ug/L 01/08/23 17:42 10.190 UCarbon tetrachloride
1.00 0.150 ug/L 01/08/23 17:42 10.150 UChlorobenzene
1.00 0.760 ug/L 01/08/23 17:42 10.760 UChloroethane
1.00 1.00 ug/L 01/08/23 17:42 11.00 UChloroform
1.00 0.320 ug/L 01/08/23 17:42 10.320 UChloromethane
1.00 0.200 ug/L 01/08/23 17:42 10.200 Ucis-1,2-Dichloroethene
5.00 0.500 ug/L 01/08/23 17:42 10.500 Ucis-1,3-Dichloropropene
1.00 0.240 ug/L 01/08/23 17:42 10.240 UDibromochloromethane
1.00 0.850 ug/L 01/08/23 17:42 10.850 UDichlorodifluoromethane
1.00 0.200 ug/L 01/08/23 17:42 10.200 UDiisopropyl ether
100 24.0 ug/L 01/08/23 17:42 124.0 UEthanol
1.00 0.500 ug/L 01/08/23 17:42 10.500 UEthylbenzene
1.00 0.530 ug/L 01/08/23 17:42 10.530 UIsopropylbenzene
1.00 0.220 ug/L 01/08/23 17:42 10.220 UMethyl tert-butyl ether
5.00 3.00 ug/L 01/08/23 17:42 13.00 UMethylene Chloride
5.00 0.630 ug/L 01/08/23 17:42 10.630 Um-Xylene & p-Xylene
5.00 3.00 ug/L 01/08/23 17:42 13.00 UNaphthalene
Eurofins Pensacola
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Client Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Lab Sample ID: 400-231380-1Client Sample ID: MW1
Matrix: Ground WaterDate Collected: 01/05/23 13:45
Date Received: 01/06/23 08:58
Method: SM6200-B - Volatile Organic Compounds (Continued)
RL MDL
0.760 U 1.00 0.760 ug/L 01/08/23 17:42 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Butylbenzene
1.00 0.690 ug/L 01/08/23 17:42 10.690 UN-Propylbenzene
5.00 0.600 ug/L 01/08/23 17:42 10.600 Uo-Xylene
1.00 0.710 ug/L 01/08/23 17:42 10.710 Up-Cymene (p-Isopropyltoluene)
1.00 0.700 ug/L 01/08/23 17:42 10.700 Usec-Butylbenzene
1.00 1.00 ug/L 01/08/23 17:42 11.00 UStyrene
1.00 0.630 ug/L 01/08/23 17:42 10.630 Utert-Butylbenzene
1.00 0.900 ug/L 01/08/23 17:42 10.900 UTetrachloroethene
1.00 0.410 ug/L 01/08/23 17:42 10.467 JToluene
1.00 0.500 ug/L 01/08/23 17:42 10.500 Utrans-1,2-Dichloroethene
5.00 0.200 ug/L 01/08/23 17:42 10.200 Utrans-1,3-Dichloropropene
1.00 0.150 ug/L 01/08/23 17:42 10.150 UTrichloroethene
1.00 0.520 ug/L 01/08/23 17:42 10.520 UTrichlorofluoromethane
25.0 0.930 ug/L 01/08/23 17:42 10.930 UVinyl acetate
1.00 0.500 ug/L 01/08/23 17:42 10.500 UVinyl chloride
10.0 1.60 ug/L 01/08/23 17:42 11.60 UXylenes, Total
4-Bromofluorobenzene 94 72-119 01/08/23 17:42 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 108 01/08/23 17:42 175-126
Toluene-d8 (Surr)95 01/08/23 17:42 164-132
Method: MA DEP MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
RL MDL
26.0 U 26.0 26.0 ug/L 01/09/23 16:23 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
C5-C8 Aliphatics
11.0 11.0 ug/L 01/09/23 16:23 111.0 UC9-C12 Aliphatics
7.00 7.00 ug/L 01/09/23 16:23 17.00 UC9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)108 70-130 01/09/23 16:23 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
a,a,a-Trifluorotoluene (pid)110 01/09/23 16:23 170-130
Method: EPA-DW 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
RL MDL
0.0150 U *1 0.0201 0.0150 ug/L 01/12/23 13:01 01/12/23 17:39 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,2-Dibromoethane (EDB)
4-Bromofluorobenzene 142 56-150 01/12/23 13:01 01/12/23 17:39 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Method: SW846 6010D - Metals (ICP)
RL MDL
0.0245 0.0100 0.00200 mg/L 01/07/23 10:56 01/10/23 12:49 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Lead
Eurofins Pensacola
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Client Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Lab Sample ID: 400-231380-2Client Sample ID: MW1 (8-10)
Matrix: SoilDate Collected: 01/05/23 10:47
Percent Solids: 76.9Date Received: 01/06/23 08:58
Method: SW846 8260D - Volatile Organic Compounds by GC/MS
RL MDL
0.00185 U 0.00840 0.00185 mg/Kg ☼01/08/23 09:30 01/08/23 19:49 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
1,1,1,2-Tetrachloroethane
0.00840 0.00185 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00185 U1,1,1-Trichloroethane
0.00840 0.00138 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00138 U1,1,2,2-Tetrachloroethane
0.00840 0.00131 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00131 U1,1,2-Trichloroethane
0.00840 0.00139 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00139 U1,1-Dichloroethane
0.00840 0.00143 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00143 U1,1-Dichloroethene
0.00840 0.00139 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00139 U1,1-Dichloropropene
0.00840 0.00185 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00185 U1,2,3-Trichlorobenzene
0.00840 0.00134 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00134 U1,2,3-Trichloropropane
0.00840 0.00155 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00155 U1,2,4-Trichlorobenzene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 U1,2,4-Trimethylbenzene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 U1,2-Dibromoethane
0.00840 0.00119 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00119 U1,2-Dichlorobenzene
0.00840 0.00138 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00138 U1,2-Dichloroethane
0.00840 0.00128 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00128 U1,2-Dichloropropane
0.00840 0.00139 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00139 U1,3,5-Trimethylbenzene
0.00840 0.00160 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00160 U1,3-Dichlorobenzene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 U1,3-Dichloropropane
0.00840 0.00144 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00144 U1,4-Dichlorobenzene
0.00840 0.00185 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00185 U2,2-Dichloropropane
0.0420 0.0101 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.0101 U2-Butanone (MEK)
0.00840 0.00136 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00136 U2-Chlorotoluene
0.0420 0.00840 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00840 U2-Hexanone
0.00840 0.00165 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00165 U4-Chlorotoluene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 U4-Isopropyltoluene
0.0420 0.00840 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00840 U4-Methyl-2-pentanone (MIBK)
0.0420 0.0202 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.0202 UAcetone
0.00840 0.00113 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00615 JBenzene
0.00840 0.00218 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00218 UBromobenzene
0.00840 0.00136 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00136 UBromochloromethane
0.00840 0.00155 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00155 UBromodichloromethane
0.00840 0.00218 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00218 UBromoform
0.00840 0.00420 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00420 UBromomethane
0.00840 0.00286 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00286 UCarbon tetrachloride
0.00840 0.000874 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.000874 UChlorobenzene
0.00840 0.00202 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00202 UChloroethane
0.00840 0.00840 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00840 UChloroform
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 UChloromethane
0.00840 0.00128 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00128 Ucis-1,2-Dichloroethene
0.00840 0.00202 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00202 Ucis-1,3-Dichloropropene
0.00840 0.00202 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00202 UDibromochloromethane
0.00840 0.00218 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00218 UDichlorodifluoromethane
0.168 0.124 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.124 UEthanol
0.00840 0.00102 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00102 UEthylbenzene
0.00840 0.000924 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.000924 UIsopropyl ether
0.00840 0.00114 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00114 UIsopropylbenzene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 UMethyl tert-butyl ether
0.0252 0.0168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.0168 UMethylene Chloride
0.00840 0.00504 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00504 UNaphthalene
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Client Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Lab Sample ID: 400-231380-2Client Sample ID: MW1 (8-10)
Matrix: SoilDate Collected: 01/05/23 10:47
Percent Solids: 76.9Date Received: 01/06/23 08:58
Method: SW846 8260D - Volatile Organic Compounds by GC/MS (Continued)
RL MDL
0.00161 U 0.00840 0.00161 mg/Kg ☼01/08/23 09:30 01/08/23 19:49 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
n-Butylbenzene
0.00840 0.00151 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00151 UN-Propylbenzene
0.00840 0.00160 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00160 Usec-Butylbenzene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 UStyrene
0.00840 0.00185 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00185 Utert-Butylbenzene
0.00840 0.00504 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00504 UTetrachloroethene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00188 JToluene
0.00840 0.00161 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00161 Utrans-1,2-Dichloroethene
0.00840 0.00185 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00185 Utrans-1,3-Dichloropropene
0.00840 0.00168 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00168 UTrichloroethene
0.00840 0.00144 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00144 UTrichlorofluoromethane
0.0420 0.00319 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00319 UVinyl acetate
0.00840 0.00134 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00134 UVinyl chloride
0.0168 0.00319 mg/Kg 01/08/23 09:30 01/08/23 19:49 1☼0.00613 JXylenes, Total
4-Bromofluorobenzene 101 67-130 01/08/23 09:30 01/08/23 19:49 1
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
Dibromofluoromethane 105 01/08/23 09:30 01/08/23 19:49 177-127
Toluene-d8 (Surr)94 01/08/23 09:30 01/08/23 19:49 176-127
Method: MA DEP MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
RL MDL
3.66 U 3.66 3.66 mg/Kg ☼01/09/23 09:43 01/09/23 13:34 50
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
C5-C8 Aliphatics
1.90 1.90 mg/Kg 01/09/23 09:43 01/09/23 13:34 50☼1.90 UC9-C12 Aliphatics
1.02 1.02 mg/Kg 01/09/23 09:43 01/09/23 13:34 50☼1.02 UC9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)99 70-130 01/09/23 09:43 01/09/23 13:34 50
Surrogate Dil FacAnalyzedPreparedQualifierLimits%Recovery
a,a,a-Trifluorotoluene (pid)101 01/09/23 09:43 01/09/23 13:34 5070-130
General Chemistry
RL MDL
76.9 0.01 0.01 %01/10/23 10:41 1
Analyte Dil FacAnalyzedPreparedUnitDResultQualifier
Percent Solids (EPA Moisture)
0.01 0.01 %01/10/23 10:41 123.1Percent Moisture (EPA Moisture)
Eurofins Pensacola
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Definitions/Glossary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Qualifiers
GC/MS VOA
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
U Indicates the analyte was analyzed for but not detected.
GC VOA
Qualifier Description
U Indicates the analyte was analyzed for but not detected.
Qualifier
GC Semi VOA
Qualifier Description
*1 LCS/LCSD RPD exceeds control limits.
Qualifier
p The %RPD between the primary and confirmation column/detector is >40%. The lower value has been reported.
U Indicates the analyte was analyzed for but not detected.
Metals
Qualifier Description
U Indicates the analyte was analyzed for but not detected.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CFU Colony Forming Unit
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MCL EPA recommended "Maximum Contaminant Level"
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
MPN Most Probable Number
MQL Method Quantitation Limit
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
NEG Negative / Absent
POS Positive / Present
PQL Practical Quantitation Limit
PRES Presumptive
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TNTC Too Numerous To Count
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Surrogate Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 8260D - Volatile Organic Compounds by GC/MS
Prep Type: Total/NAMatrix: Soil
Lab Sample ID Client Sample ID (67-130)(77-127)(76-127)
BFB DBFM TOL
101 105 94400-231380-2
Percent Surrogate Recovery (Acceptance Limits)
MW1 (8-10)
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Method: 8260D - Volatile Organic Compounds by GC/MS
Prep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (67-130)(77-127)(76-127)
BFB DBFM TOL
98 101 96LCS 400-607681/1-A
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
101 100 96MB 400-607681/2-A Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Ground Water
Lab Sample ID Client Sample ID (72-119)(75-126)(64-132)
BFB DBFM TOL
94 108 95400-231380-1
Percent Surrogate Recovery (Acceptance Limits)
MW1
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Method: SM6200-B - Volatile Organic Compounds
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (72-119)(75-126)(64-132)
BFB DBFM TOL
99 105 98LCS 400-607652/1002
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
97 105 96MB 400-607652/4 Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL = Toluene-d8 (Surr)
Eurofins Pensacola
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Surrogate Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Prep Type: Total/NAMatrix: Ground Water
Lab Sample ID Client Sample ID (70-130)(70-130)
TFT-F1 TFT-P1
108 110400-231380-1
Percent Surrogate Recovery (Acceptance Limits)
MW1
Surrogate Legend
TFT-F = a,a,a-Trifluorotoluene (fid)
TFT-P = a,a,a-Trifluorotoluene (pid)
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Prep Type: Total/NAMatrix: Soil
Lab Sample ID Client Sample ID (70-130)(70-130)
TFT-F1 TFT-P1
99 101400-231380-2
Percent Surrogate Recovery (Acceptance Limits)
MW1 (8-10)
101 102400-231380-2 MS MW1 (8-10)
101 103400-231380-2 MSD MW1 (8-10)
Surrogate Legend
TFT-F = a,a,a-Trifluorotoluene (fid)
TFT-P = a,a,a-Trifluorotoluene (pid)
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Prep Type: Total/NAMatrix: Solid
Lab Sample ID Client Sample ID (70-130)(70-130)
TFT-F1 TFT-P1
100 101LCS 400-607535/2-A
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
101 102LCSD 400-607535/3-A Lab Control Sample Dup
98 100MB 400-607535/1-A Method Blank
Surrogate Legend
TFT-F = a,a,a-Trifluorotoluene (fid)
TFT-P = a,a,a-Trifluorotoluene (pid)
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (70-130)(70-130)
TFT-F1 TFT-P1
110 109LCS 400-607724/4
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
108 108LCSD 400-607724/5 Lab Control Sample Dup
106 107MB 400-607724/3 Method Blank
Surrogate Legend
TFT-F = a,a,a-Trifluorotoluene (fid)
TFT-P = a,a,a-Trifluorotoluene (pid)
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Surrogate Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Prep Type: Total/NAMatrix: Ground Water
Lab Sample ID Client Sample ID (56-150)
BFB1
142400-231380-1
Percent Surrogate Recovery (Acceptance Limits)
MW1
Surrogate Legend
BFB = 4-Bromofluorobenzene
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Prep Type: Total/NAMatrix: Water
Lab Sample ID Client Sample ID (56-150)
BFB1
103LCS 400-608226/2-A
Percent Surrogate Recovery (Acceptance Limits)
Lab Control Sample
104LCSD 400-608226/3-A Lab Control Sample Dup
102MB 400-608226/1-A Method Blank
Surrogate Legend
BFB = 4-Bromofluorobenzene
Eurofins Pensacola
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QC Association Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
GC/MS VOA
Analysis Batch: 607652
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water SM6200-B400-231380-1 MW1 Total/NA
Water SM6200-BMB 400-607652/4 Method Blank Total/NA
Water SM6200-BLCS 400-607652/1002 Lab Control Sample Total/NA
Analysis Batch: 607662
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Soil 8260D 607681400-231380-2 MW1 (8-10)Total/NA
Solid 8260D 607681MB 400-607681/2-A Method Blank Total/NA
Solid 8260D 607681LCS 400-607681/1-A Lab Control Sample Total/NA
Prep Batch: 607681
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Soil 5035400-231380-2 MW1 (8-10)Total/NA
Solid 5035MB 400-607681/2-A Method Blank Total/NA
Solid 5035LCS 400-607681/1-A Lab Control Sample Total/NA
GC VOA
Analysis Batch: 607496
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Soil MAVPH 607535400-231380-2 MW1 (8-10)Total/NA
Solid MAVPH 607535MB 400-607535/1-A Method Blank Total/NA
Solid MAVPH 607535LCS 400-607535/2-A Lab Control Sample Total/NA
Solid MAVPH 607535LCSD 400-607535/3-A Lab Control Sample Dup Total/NA
Soil MAVPH 607535400-231380-2 MS MW1 (8-10)Total/NA
Soil MAVPH 607535400-231380-2 MSD MW1 (8-10)Total/NA
Prep Batch: 607535
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Soil 5035400-231380-2 MW1 (8-10)Total/NA
Solid 5035MB 400-607535/1-A Method Blank Total/NA
Solid 5035LCS 400-607535/2-A Lab Control Sample Total/NA
Solid 5035LCSD 400-607535/3-A Lab Control Sample Dup Total/NA
Soil 5035400-231380-2 MS MW1 (8-10)Total/NA
Soil 5035400-231380-2 MSD MW1 (8-10)Total/NA
Analysis Batch: 607724
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water MAVPH400-231380-1 MW1 Total/NA
Water MAVPHMB 400-607724/3 Method Blank Total/NA
Water MAVPHLCS 400-607724/4 Lab Control Sample Total/NA
Water MAVPHLCSD 400-607724/5 Lab Control Sample Dup Total/NA
GC Semi VOA
Prep Batch: 608226
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water 504.1400-231380-1 MW1 Total/NA
Water 504.1MB 400-608226/1-A Method Blank Total/NA
Water 504.1LCS 400-608226/2-A Lab Control Sample Total/NA
Water 504.1LCSD 400-608226/3-A Lab Control Sample Dup Total/NA
Eurofins Pensacola
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QC Association Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
GC Semi VOA
Analysis Batch: 608260
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water 504.1 608226400-231380-1 MW1 Total/NA
Water 504.1 608226MB 400-608226/1-A Method Blank Total/NA
Water 504.1 608226LCS 400-608226/2-A Lab Control Sample Total/NA
Water 504.1 608226LCSD 400-608226/3-A Lab Control Sample Dup Total/NA
Metals
Prep Batch: 607626
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water 3010A400-231380-1 MW1 Total/NA
Water 3010AMB 400-607626/1-A Method Blank Total/NA
Water 3010ALCS 400-607626/2-A Lab Control Sample Total/NA
Analysis Batch: 607811
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6010D 607626MB 400-607626/1-A Method Blank Total/NA
Water 6010D 607626LCS 400-607626/2-A Lab Control Sample Total/NA
Analysis Batch: 607983
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Ground Water 6010D 607626400-231380-1 MW1 Total/NA
General Chemistry
Analysis Batch: 607870
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Soil Moisture400-231380-2 MW1 (8-10)Total/NA
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 8260D - Volatile Organic Compounds by GC/MS
Client Sample ID: Method BlankLab Sample ID: MB 400-607681/2-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607662 Prep Batch: 607681
RL MDL
1,1,1,2-Tetrachloroethane 0.00110 U 0.00500 0.00110 mg/Kg 01/08/23 09:30 01/08/23 11:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.00110 U 0.001100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1,1-Trichloroethane
0.000820 U 0.0008200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1,2,2-Tetrachloroethane
0.000780 U 0.0007800.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1,2-Trichloroethane
0.000830 U 0.0008300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1-Dichloroethane
0.000850 U 0.0008500.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1-Dichloroethene
0.000830 U 0.0008300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,1-Dichloropropene
0.00110 U 0.001100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2,3-Trichlorobenzene
0.000800 U 0.0008000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2,3-Trichloropropane
0.000920 U 0.0009200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2,4-Trichlorobenzene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2,4-Trimethylbenzene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2-Dibromoethane
0.000710 U 0.0007100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2-Dichlorobenzene
0.000820 U 0.0008200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2-Dichloroethane
0.000760 U 0.0007600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,2-Dichloropropane
0.000830 U 0.0008300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,3,5-Trimethylbenzene
0.000950 U 0.0009500.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,3-Dichlorobenzene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,3-Dichloropropane
0.000860 U 0.0008600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 11,4-Dichlorobenzene
0.00110 U 0.001100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 12,2-Dichloropropane
0.00600 U 0.006000.0250 mg/Kg 01/08/23 09:30 01/08/23 11:40 12-Butanone (MEK)
0.000810 U 0.0008100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 12-Chlorotoluene
0.00500 U 0.005000.0250 mg/Kg 01/08/23 09:30 01/08/23 11:40 12-Hexanone
0.000980 U 0.0009800.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 14-Chlorotoluene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 14-Isopropyltoluene
0.00500 U 0.005000.0250 mg/Kg 01/08/23 09:30 01/08/23 11:40 14-Methyl-2-pentanone (MIBK)
0.0120 U 0.01200.0250 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Acetone
0.000670 U 0.0006700.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Benzene
0.00130 U 0.001300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Bromobenzene
0.000810 U 0.0008100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Bromochloromethane
0.000920 U 0.0009200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Bromodichloromethane
0.00130 U 0.001300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Bromoform
0.00250 U 0.002500.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Bromomethane
0.00170 U 0.001700.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Carbon tetrachloride
0.000520 U 0.0005200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Chlorobenzene
0.00120 U 0.001200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Chloroethane
0.00500 U 0.005000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Chloroform
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Chloromethane
0.000760 U 0.0007600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1cis-1,2-Dichloroethene
0.00120 U 0.001200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1cis-1,3-Dichloropropene
0.00120 U 0.001200.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Dibromochloromethane
0.00130 U 0.001300.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Dichlorodifluoromethane
0.0740 U 0.07400.100 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Ethanol
0.000610 U 0.0006100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Ethylbenzene
0.000550 U 0.0005500.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Isopropyl ether
0.000680 U 0.0006800.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Isopropylbenzene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Methyl tert-butyl ether
0.0100 U 0.01000.0150 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Methylene Chloride
Eurofins Pensacola
Page 17 of 34 1/16/2023
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-607681/2-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607662 Prep Batch: 607681
RL MDL
Naphthalene 0.00300 U 0.00500 0.00300 mg/Kg 01/08/23 09:30 01/08/23 11:40 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.000960 U 0.0009600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1n-Butylbenzene
0.000900 U 0.0009000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1N-Propylbenzene
0.000950 U 0.0009500.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1sec-Butylbenzene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Styrene
0.00110 U 0.001100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1tert-Butylbenzene
0.00300 U 0.003000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Tetrachloroethene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Toluene
0.000960 U 0.0009600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1trans-1,2-Dichloroethene
0.00110 U 0.001100.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1trans-1,3-Dichloropropene
0.00100 U 0.001000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Trichloroethene
0.000860 U 0.0008600.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Trichlorofluoromethane
0.00190 U 0.001900.0250 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Vinyl acetate
0.000800 U 0.0008000.00500 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Vinyl chloride
0.00190 U 0.001900.0100 mg/Kg 01/08/23 09:30 01/08/23 11:40 1Xylenes, Total
4-Bromofluorobenzene 101 67-130 01/08/23 11:40 1
MB MB
Surrogate
01/08/23 09:30
Dil FacPreparedAnalyzedQualifierLimits%Recovery
100 01/08/23 09:30 01/08/23 11:40 1Dibromofluoromethane77-127
96 01/08/23 09:30 01/08/23 11:40 1Toluene-d8 (Surr)76-127
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607681/1-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607662 Prep Batch: 607681
1,1,1,2-Tetrachloroethane 0.0500 0.03832 mg/Kg 77 65-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 0.0500 0.03683 mg/Kg 74 63-130
1,1,2,2-Tetrachloroethane 0.0500 0.03805 mg/Kg 76 60-131
1,1,2-Trichloroethane 0.0500 0.03928 mg/Kg 79 65-130
1,1-Dichloroethane 0.0500 0.03757 mg/Kg 75 59-130
1,1-Dichloroethene 0.0500 0.03884 mg/Kg 78 55-137
1,1-Dichloropropene 0.0500 0.03866 mg/Kg 77 65-130
1,2,3-Trichlorobenzene 0.0500 0.04457 mg/Kg 89 58-135
1,2,3-Trichloropropane 0.0500 0.03669 mg/Kg 73 60-130
1,2,4-Trichlorobenzene 0.0500 0.04307 mg/Kg 86 56-138
1,2,4-Trimethylbenzene 0.0500 0.03780 mg/Kg 76 66-130
1,2-Dibromoethane 0.0500 0.04027 mg/Kg 81 67-130
1,2-Dichlorobenzene 0.0500 0.03976 mg/Kg 80 64-130
1,2-Dichloroethane 0.0500 0.03836 mg/Kg 77 62-130
1,2-Dichloropropane 0.0500 0.03837 mg/Kg 77 64-130
1,3,5-Trimethylbenzene 0.0500 0.03702 mg/Kg 74 67-130
1,3-Dichlorobenzene 0.0500 0.03924 mg/Kg 78 66-130
1,3-Dichloropropane 0.0500 0.03999 mg/Kg 80 67-130
1,4-Dichlorobenzene 0.0500 0.03985 mg/Kg 80 65-130
2,2-Dichloropropane 0.0500 0.03990 mg/Kg 80 51-132
2-Butanone (MEK)0.200 0.1593 mg/Kg 80 55-130
2-Chlorotoluene 0.0500 0.03692 mg/Kg 74 67-130
Eurofins Pensacola
Page 18 of 34 1/16/2023
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 8260D - Volatile Organic Compounds by GC/MS (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607681/1-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607662 Prep Batch: 607681
2-Hexanone 0.200 0.1597 mg/Kg 80 57-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Chlorotoluene 0.0500 0.03663 mg/Kg 73 66-130
4-Isopropyltoluene 0.0500 0.03724 mg/Kg 74 68-130
4-Methyl-2-pentanone (MIBK)0.200 0.1690 mg/Kg 84 58-130
Acetone 0.200 0.1676 mg/Kg 84 48-160
Benzene 0.0500 0.03798 mg/Kg 76 65-130
Bromobenzene 0.0500 0.03796 mg/Kg 76 65-130
Bromochloromethane 0.0500 0.04125 mg/Kg 82 65-130
Bromodichloromethane 0.0500 0.03963 mg/Kg 79 61-130
Bromoform 0.0500 0.03831 mg/Kg 77 52-136
Bromomethane 0.0500 0.04257 mg/Kg 85 12-160
Carbon tetrachloride 0.0500 0.03591 mg/Kg 72 60-130
Chlorobenzene 0.0500 0.03818 mg/Kg 76 70-130
Chloroethane 0.0500 0.03348 mg/Kg 67 55-134
Chloroform 0.0500 0.03725 mg/Kg 75 62-130
Chloromethane 0.0500 0.03330 mg/Kg 67 49-136
cis-1,2-Dichloroethene 0.0500 0.03653 mg/Kg 73 53-135
cis-1,3-Dichloropropene 0.0500 0.04095 mg/Kg 82 61-130
Dibromochloromethane 0.0500 0.03824 mg/Kg 76 58-132
Dichlorodifluoromethane 0.0500 0.03096 mg/Kg 62 34-143
Ethanol 2.00 1.537 mg/Kg 77 29-160
Ethylbenzene 0.0500 0.03743 mg/Kg 75 70-130
Isopropyl ether 0.0500 0.04210 mg/Kg 84 62-130
Isopropylbenzene 0.0500 0.03665 mg/Kg 73 70-130
Methyl tert-butyl ether 0.0500 0.04206 mg/Kg 84 63-130
Methylene Chloride 0.0500 0.04179 mg/Kg 84 57-132
m-Xylene & p-Xylene 0.0500 0.03775 mg/Kg 75 70-130
Naphthalene 0.0500 0.04476 mg/Kg 90 45-144
n-Butylbenzene 0.0500 0.03836 mg/Kg 77 66-130
N-Propylbenzene 0.0500 0.03688 mg/Kg 74 67-130
o-Xylene 0.0500 0.03733 mg/Kg 75 70-130
sec-Butylbenzene 0.0500 0.03670 mg/Kg 73 67-130
Styrene 0.0500 0.03744 mg/Kg 75 68-130
tert-Butylbenzene 0.0500 0.04040 mg/Kg 81 67-130
Tetrachloroethene 0.0500 0.04111 mg/Kg 82 67-130
Toluene 0.0500 0.03654 mg/Kg 73 70-130
trans-1,2-Dichloroethene 0.0500 0.03654 mg/Kg 73 58-134
trans-1,3-Dichloropropene 0.0500 0.03969 mg/Kg 79 60-130
Trichloroethene 0.0500 0.03838 mg/Kg 77 65-130
Trichlorofluoromethane 0.0500 0.04344 mg/Kg 87 61-136
Vinyl acetate 0.100 0.09625 mg/Kg 96 24-160
Vinyl chloride 0.0500 0.03972 mg/Kg 79 52-132
Xylenes, Total 0.100 0.07508 mg/Kg 75 70-130
4-Bromofluorobenzene 67 -130
Surrogate
98
LCS LCS
Qualifier Limits%Recovery
101Dibromofluoromethane 77 -127
96Toluene-d8 (Surr)76 -127
Eurofins Pensacola
Page 19 of 34 1/16/2023
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: SM6200-B - Volatile Organic Compounds
Client Sample ID: Method BlankLab Sample ID: MB 400-607652/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607652
RL MDL
1,1,1,2-Tetrachloroethane 0.160 U 1.00 0.160 ug/L 01/08/23 09:48 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.180 U 0.1801.00 ug/L 01/08/23 09:48 11,1,1-Trichloroethane
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,1,2,2-Tetrachloroethane
0.210 U 0.2105.00 ug/L 01/08/23 09:48 11,1,2-Trichloroethane
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,1-Dichloroethane
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,1-Dichloroethene
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,1-Dichloropropene
0.900 U 0.9001.00 ug/L 01/08/23 09:48 11,2,3-Trichlorobenzene
0.840 U 0.8405.00 ug/L 01/08/23 09:48 11,2,3-Trichloropropane
0.820 U 0.8201.00 ug/L 01/08/23 09:48 11,2,4-Trichlorobenzene
0.820 U 0.8201.00 ug/L 01/08/23 09:48 11,2,4-Trimethylbenzene
0.230 U 0.2301.00 ug/L 01/08/23 09:48 11,2-Dibromoethane (EDB)
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,2-Dichlorobenzene
0.190 U 0.1901.00 ug/L 01/08/23 09:48 11,2-Dichloroethane
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,2-Dichloropropane
0.560 U 0.5601.00 ug/L 01/08/23 09:48 11,3,5-Trimethylbenzene
0.540 U 0.5401.00 ug/L 01/08/23 09:48 11,3-Dichlorobenzene
0.500 U 0.5001.00 ug/L 01/08/23 09:48 11,3-Dichloropropane
0.640 U 0.6401.00 ug/L 01/08/23 09:48 11,4-Dichlorobenzene
0.500 U 0.5001.00 ug/L 01/08/23 09:48 12,2-Dichloropropane
2.60 U 2.6025.0 ug/L 01/08/23 09:48 12-Butanone (MEK)
0.570 U 0.5701.00 ug/L 01/08/23 09:48 12-Chlorotoluene
1.40 U 1.4025.0 ug/L 01/08/23 09:48 12-Hexanone
0.560 U 0.5601.00 ug/L 01/08/23 09:48 14-Chlorotoluene
1.80 U 1.8025.0 ug/L 01/08/23 09:48 14-Methyl-2-pentanone (MIBK)
10.0 U 10.025.0 ug/L 01/08/23 09:48 1Acetone
0.130 U 0.1301.00 ug/L 01/08/23 09:48 1Benzene
0.540 U 0.5401.00 ug/L 01/08/23 09:48 1Bromobenzene
0.210 U 0.2101.00 ug/L 01/08/23 09:48 1Bromochloromethane
0.500 U 0.5001.00 ug/L 01/08/23 09:48 1Bromodichloromethane
0.250 U 0.2505.00 ug/L 01/08/23 09:48 1Bromoform
0.980 U 0.9801.00 ug/L 01/08/23 09:48 1Bromomethane
0.190 U 0.1901.00 ug/L 01/08/23 09:48 1Carbon tetrachloride
0.150 U 0.1501.00 ug/L 01/08/23 09:48 1Chlorobenzene
0.760 U 0.7601.00 ug/L 01/08/23 09:48 1Chloroethane
1.00 U 1.001.00 ug/L 01/08/23 09:48 1Chloroform
0.320 U 0.3201.00 ug/L 01/08/23 09:48 1Chloromethane
0.200 U 0.2001.00 ug/L 01/08/23 09:48 1cis-1,2-Dichloroethene
0.500 U 0.5005.00 ug/L 01/08/23 09:48 1cis-1,3-Dichloropropene
0.240 U 0.2401.00 ug/L 01/08/23 09:48 1Dibromochloromethane
0.850 U 0.8501.00 ug/L 01/08/23 09:48 1Dichlorodifluoromethane
0.200 U 0.2001.00 ug/L 01/08/23 09:48 1Diisopropyl ether
24.0 U 24.0100 ug/L 01/08/23 09:48 1Ethanol
0.500 U 0.5001.00 ug/L 01/08/23 09:48 1Ethylbenzene
0.530 U 0.5301.00 ug/L 01/08/23 09:48 1Isopropylbenzene
0.220 U 0.2201.00 ug/L 01/08/23 09:48 1Methyl tert-butyl ether
3.00 U 3.005.00 ug/L 01/08/23 09:48 1Methylene Chloride
0.630 U 0.6305.00 ug/L 01/08/23 09:48 1m-Xylene & p-Xylene
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Method BlankLab Sample ID: MB 400-607652/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607652
RL MDL
Naphthalene 3.00 U 5.00 3.00 ug/L 01/08/23 09:48 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
0.760 U 0.7601.00 ug/L 01/08/23 09:48 1n-Butylbenzene
0.690 U 0.6901.00 ug/L 01/08/23 09:48 1N-Propylbenzene
0.600 U 0.6005.00 ug/L 01/08/23 09:48 1o-Xylene
0.710 U 0.7101.00 ug/L 01/08/23 09:48 1p-Cymene (p-Isopropyltoluene)
0.700 U 0.7001.00 ug/L 01/08/23 09:48 1sec-Butylbenzene
1.00 U 1.001.00 ug/L 01/08/23 09:48 1Styrene
0.630 U 0.6301.00 ug/L 01/08/23 09:48 1tert-Butylbenzene
0.900 U 0.9001.00 ug/L 01/08/23 09:48 1Tetrachloroethene
0.410 U 0.4101.00 ug/L 01/08/23 09:48 1Toluene
0.500 U 0.5001.00 ug/L 01/08/23 09:48 1trans-1,2-Dichloroethene
0.200 U 0.2005.00 ug/L 01/08/23 09:48 1trans-1,3-Dichloropropene
0.150 U 0.1501.00 ug/L 01/08/23 09:48 1Trichloroethene
0.520 U 0.5201.00 ug/L 01/08/23 09:48 1Trichlorofluoromethane
0.930 U 0.93025.0 ug/L 01/08/23 09:48 1Vinyl acetate
0.500 U 0.5001.00 ug/L 01/08/23 09:48 1Vinyl chloride
1.60 U 1.6010.0 ug/L 01/08/23 09:48 1Xylenes, Total
4-Bromofluorobenzene 97 72-119 01/08/23 09:48 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
105 01/08/23 09:48 1Dibromofluoromethane75-126
96 01/08/23 09:48 1Toluene-d8 (Surr)64-132
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607652/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607652
1,1,1,2-Tetrachloroethane 50.0 47.37 ug/L 95 67-131
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
1,1,1-Trichloroethane 50.0 44.31 ug/L 89 68-130
1,1,2,2-Tetrachloroethane 50.0 47.52 ug/L 95 70-131
1,1,2-Trichloroethane 50.0 46.27 ug/L 93 70-130
1,1-Dichloroethane 50.0 45.91 ug/L 92 70-130
1,1-Dichloroethene 50.0 44.75 ug/L 89 63-134
1,1-Dichloropropene 50.0 44.94 ug/L 90 70-130
1,2,3-Trichlorobenzene 50.0 49.91 ug/L 100 60-138
1,2,3-Trichloropropane 50.0 47.74 ug/L 95 70-130
1,2,4-Trichlorobenzene 50.0 49.55 ug/L 99 60-140
1,2,4-Trimethylbenzene 50.0 46.09 ug/L 92 70-130
1,2-Dibromoethane (EDB)50.0 47.41 ug/L 95 70-130
1,2-Dichlorobenzene 50.0 47.98 ug/L 96 67-130
1,2-Dichloroethane 50.0 46.32 ug/L 93 69-130
1,2-Dichloropropane 50.0 45.93 ug/L 92 70-130
1,3,5-Trimethylbenzene 50.0 45.64 ug/L 91 69-130
1,3-Dichlorobenzene 50.0 47.43 ug/L 95 70-130
1,3-Dichloropropane 50.0 47.61 ug/L 95 70-130
1,4-Dichlorobenzene 50.0 47.57 ug/L 95 70-130
2,2-Dichloropropane 50.0 42.79 ug/L 86 52-135
Eurofins Pensacola
Page 21 of 34 1/16/2023
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607652/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607652
2-Butanone (MEK)200 189.6 ug/L 95 61-145
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
2-Chlorotoluene 50.0 45.61 ug/L 91 70-130
2-Hexanone 200 189.5 ug/L 95 65-137
4-Chlorotoluene 50.0 46.52 ug/L 93 70-130
4-Methyl-2-pentanone (MIBK)200 192.3 ug/L 96 69-138
Acetone 200 193.6 ug/L 97 43-160
Benzene 50.0 44.98 ug/L 90 70-130
Bromobenzene 50.0 48.16 ug/L 96 70-132
Bromochloromethane 50.0 48.36 ug/L 97 70-130
Bromodichloromethane 50.0 46.13 ug/L 92 67-133
Bromoform 50.0 47.51 ug/L 95 57-140
Bromomethane 50.0 40.09 ug/L 80 10-160
Carbon tetrachloride 50.0 45.03 ug/L 90 61-137
Chlorobenzene 50.0 46.16 ug/L 92 70-130
Chloroethane 50.0 56.52 ug/L 113 55-141
Chloroform 50.0 45.52 ug/L 91 69-130
Chloromethane 50.0 44.64 ug/L 89 58-137
cis-1,2-Dichloroethene 50.0 45.38 ug/L 91 68-130
cis-1,3-Dichloropropene 50.0 46.90 ug/L 94 69-132
Dibromochloromethane 50.0 46.66 ug/L 93 67-135
Dichlorodifluoromethane 50.0 52.92 ug/L 106 41-146
Diisopropyl ether 50.0 41.84 ug/L 84 64-132
Ethanol 2000 1710 ug/L 85 20-160
Ethylbenzene 50.0 45.95 ug/L 92 70-130
Isopropylbenzene 50.0 45.90 ug/L 92 70-130
Methyl tert-butyl ether 50.0 44.67 ug/L 89 66-130
Methylene Chloride 50.0 46.21 ug/L 92 66-135
m-Xylene & p-Xylene 50.0 45.02 ug/L 90 70-130
Naphthalene 50.0 46.91 ug/L 94 47-149
n-Butylbenzene 50.0 45.77 ug/L 92 67-130
N-Propylbenzene 50.0 48.72 ug/L 97 70-130
o-Xylene 50.0 45.06 ug/L 90 70-130
p-Cymene (p-Isopropyltoluene)50.0 47.51 ug/L 95 65-130
sec-Butylbenzene 50.0 47.64 ug/L 95 66-130
Styrene 50.0 44.88 ug/L 90 70-130
tert-Butylbenzene 50.0 46.10 ug/L 92 64-139
Tetrachloroethene 50.0 45.05 ug/L 90 65-130
Toluene 50.0 44.56 ug/L 89 70-130
trans-1,2-Dichloroethene 50.0 44.64 ug/L 89 70-130
trans-1,3-Dichloropropene 50.0 45.88 ug/L 92 63-130
Trichloroethene 50.0 46.81 ug/L 94 70-130
Trichlorofluoromethane 50.0 57.88 ug/L 116 65-138
Vinyl acetate 100 111.1 ug/L 111 26-160
Vinyl chloride 50.0 58.59 ug/L 117 59-136
Xylenes, Total 100 90.08 ug/L 90 70-130
4-Bromofluorobenzene 72 -119
Surrogate
99
LCS LCS
Qualifier Limits%Recovery
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: SM6200-B - Volatile Organic Compounds (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607652/1002
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607652
Dibromofluoromethane 75 -126
Surrogate
105
LCS LCS
Qualifier Limits%Recovery
98Toluene-d8 (Surr)64 -132
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC)
Client Sample ID: Method BlankLab Sample ID: MB 400-607535/1-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607496 Prep Batch: 607535
RL MDL
C5-C8 Aliphatics 2.70 U 2.70 2.70 mg/Kg 01/06/23 09:30 01/06/23 12:04 50
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
1.40 U 1.401.40 mg/Kg 01/06/23 09:30 01/06/23 12:04 50C9-C12 Aliphatics
0.750 U 0.7500.750 mg/Kg 01/06/23 09:30 01/06/23 12:04 50C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)98 70-130 01/06/23 12:04 50
MB MB
Surrogate
01/06/23 09:30
Dil FacPreparedAnalyzedQualifierLimits%Recovery
100 01/06/23 09:30 01/06/23 12:04 50a,a,a-Trifluorotoluene (pid)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607535/2-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607496 Prep Batch: 607535
C5-C8 Aliphatics 15.0 15.55 mg/Kg 104 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
C9-C12 Aliphatics 17.5 17.95 mg/Kg 103 70-130
C9-C10 Aromatics 2.50 2.879 mg/Kg 115 70-130
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
100
LCS LCS
Qualifier Limits%Recovery
101a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-607535/3-A
Matrix: Solid Prep Type: Total/NA
Analysis Batch: 607496 Prep Batch: 607535
C5-C8 Aliphatics 15.0 14.90 mg/Kg 99 70-130 4 25
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
C9-C12 Aliphatics 17.5 17.12 mg/Kg 98 70-130 5 25
C9-C10 Aromatics 2.50 2.769 mg/Kg 111 70-130 4 25
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
101
LCSD LCSD
Qualifier Limits%Recovery
102a,a,a-Trifluorotoluene (pid)70 -130
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC) (Continued)
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2 MS
Matrix: Soil Prep Type: Total/NA
Analysis Batch: 607496 Prep Batch: 607535
C5-C8 Aliphatics 3.66 U 20.3 19.79 mg/Kg 97 70-130☼
Analyte
MS MS
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits
C9-C12 Aliphatics 1.90 U 23.7 22.97 mg/Kg 97 70-130☼
C9-C10 Aromatics 1.02 U 3.39 4.306 mg/Kg 127 70-130☼
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
101
MS MS
Qualifier Limits%Recovery
102a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2 MSD
Matrix: Soil Prep Type: Total/NA
Analysis Batch: 607496 Prep Batch: 607535
C5-C8 Aliphatics 3.66 U 20.3 20.26 mg/Kg 100 70-130 2 25☼
Analyte
MSD MSD
DUnitResultQualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec
Limits LimitRPD
RPD
C9-C12 Aliphatics 1.90 U 23.7 22.01 mg/Kg 93 70-130 4 25☼
C9-C10 Aromatics 1.02 U 3.39 3.842 mg/Kg 113 70-130 11 25☼
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
101
MSD MSD
Qualifier Limits%Recovery
103a,a,a-Trifluorotoluene (pid)70 -130
Client Sample ID: Method BlankLab Sample ID: MB 400-607724/3
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607724
RL MDL
C5-C8 Aliphatics 26.0 U 26.0 26.0 ug/L 01/09/23 11:19 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
11.0 U 11.011.0 ug/L 01/09/23 11:19 1C9-C12 Aliphatics
7.00 U 7.007.00 ug/L 01/09/23 11:19 1C9-C10 Aromatics
a,a,a-Trifluorotoluene (fid)106 70-130 01/09/23 11:19 1
MB MB
Surrogate Dil FacPreparedAnalyzedQualifierLimits%Recovery
107 01/09/23 11:19 1a,a,a-Trifluorotoluene (pid)70-130
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607724/4
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607724
C5-C8 Aliphatics 300 341.5 ug/L 114 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
C9-C12 Aliphatics 350 341.1 ug/L 97 70-130
C9-C10 Aromatics 50.0 56.16 ug/L 112 70-130
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
110
LCS LCS
Qualifier Limits%Recovery
109a,a,a-Trifluorotoluene (pid)70 -130
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: MAVPH - Massachusetts - Volatile Petroleum Hydrocarbons (GC) (Continued)
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-607724/5
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607724
C5-C8 Aliphatics 300 337.4 ug/L 112 70-130 1 25
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
C9-C12 Aliphatics 350 332.4 ug/L 95 70-130 3 25
C9-C10 Aromatics 50.0 54.69 ug/L 109 70-130 3 25
a,a,a-Trifluorotoluene (fid)70 -130
Surrogate
108
LCSD LCSD
Qualifier Limits%Recovery
108a,a,a-Trifluorotoluene (pid)70 -130
Method: 504.1 - EDB, DBCP and 1,2,3-TCP (GC)
Client Sample ID: Method BlankLab Sample ID: MB 400-608226/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 608260 Prep Batch: 608226
RL MDL
1,2-Dibromoethane (EDB)0.0150 U 0.0200 0.0150 ug/L 01/12/23 13:01 01/12/23 16:14 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
4-Bromofluorobenzene 102 56-150 01/12/23 16:14 1
MB MB
Surrogate
01/12/23 13:01
Dil FacPreparedAnalyzedQualifierLimits%Recovery
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-608226/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 608260 Prep Batch: 608226
1,2-Dibromoethane (EDB)0.101 0.09601 p ug/L 95 70-130
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
4-Bromofluorobenzene 56 -150
Surrogate
103
LCS LCS
Qualifier Limits%Recovery
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 400-608226/3-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 608260 Prep Batch: 608226
1,2-Dibromoethane (EDB)0.101 0.1163 *1 ug/L 115 70-130 19 10
Analyte
LCSD LCSD
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits LimitRPD
RPD
4-Bromofluorobenzene 56 -150
Surrogate
104
LCSD LCSD
Qualifier Limits%Recovery
Method: 6010D - Metals (ICP)
Client Sample ID: Method BlankLab Sample ID: MB 400-607626/1-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607811 Prep Batch: 607626
RL MDL
Lead 0.00200 U 0.0100 0.00200 mg/L 01/07/23 10:56 01/09/23 17:44 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResultQualifier
Eurofins Pensacola
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QC Sample Results
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method: 6010D - Metals (ICP)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 400-607626/2-A
Matrix: Water Prep Type: Total/NA
Analysis Batch: 607811 Prep Batch: 607626
Lead 1.00 1.046 mg/L 105 80-120
Analyte
LCS LCS
DUnitResultQualifier %Rec
Spike
Added
%Rec
Limits
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Client Sample ID: MW1 Lab Sample ID: 400-231380-1
Matrix: Ground WaterDate Collected: 01/05/23 13:45
Date Received: 01/06/23 08:58
Analysis SM6200-B AGW01/08/23 17:421 EET PEN607652
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Analysis MAVPH 1 607724 01/09/23 16:23 SAB EET PENTotal/NA 5 mL 5 mL
Prep 504.1 608226 01/12/23 13:01 JAW EET PENTotal/NA 34.9 mL 35 mL
Analysis 504.1 1 608260 01/12/23 17:39 JAW EET PENTotal/NA
Prep 3010A 607626 01/07/23 10:56 JL EET PENTotal/NA 50 mL 50 mL
Completed:01/07/23 15:40 ¹
Analysis 6010D 1 607983 01/10/23 12:49 LSS EET PENTotal/NA
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2
Matrix: SoilDate Collected: 01/05/23 10:47
Date Received: 01/06/23 08:58
Analysis Moisture WJM01/10/23 10:411 EET PEN607870
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2
Matrix: SoilDate Collected: 01/05/23 10:47
Percent Solids: 76.9Date Received: 01/06/23 08:58
Prep 5035 BEP01/08/23 09:30 EET PEN607681
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 3.869 g 5.00 g
Analysis 8260D 1 607662 01/08/23 19:49 BEP EET PENTotal/NA 5 mL 5 mL
Prep 5035 607535 01/09/23 09:43 SAB EET PENTotal/NA 6.158 g 5.00 g
Analysis MAVPH 50 607496 01/09/23 13:34 SAB EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-607535/1-A
Matrix: SolidDate Collected: N/A
Date Received: N/A
Prep 5035 SAB01/06/23 09:30 EET PEN607535
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.00 g 5.00 g
Analysis MAVPH 50 607496 01/06/23 12:04 SAB EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-607626/1-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 3010A JL01/07/23 10:56 EET PEN607626
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Completed:01/07/23 15:40 ¹
Analysis 6010D 1 607811 01/09/23 17:44 LSS EET PENTotal/NA
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Client Sample ID: Method Blank Lab Sample ID: MB 400-607652/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW01/08/23 09:481 EET PEN607652
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-607681/2-A
Matrix: SolidDate Collected: N/A
Date Received: N/A
Prep 5035 BEP01/08/23 09:30 EET PEN607681
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.00 g 5.00 g
Analysis 8260D 1 607662 01/08/23 11:40 BEP EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-607724/3
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB01/09/23 11:191 EET PEN607724
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Method Blank Lab Sample ID: MB 400-608226/1-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW01/12/23 13:01 EET PEN608226
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 608260 01/12/23 16:14 JAW EET PENTotal/NA
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-607535/2-A
Matrix: SolidDate Collected: N/A
Date Received: N/A
Prep 5035 SAB01/06/23 09:30 EET PEN607535
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.00 g 5.00 g
Analysis MAVPH 50 607496 01/06/23 13:46 SAB EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-607626/2-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 3010A JL01/07/23 10:56 EET PEN607626
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 50 mL 50 mL
Completed:01/07/23 15:40 ¹
Analysis 6010D 1 607811 01/09/23 17:48 LSS EET PENTotal/NA
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-607652/1002
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis SM6200-B AGW01/08/23 08:511 EET PEN607652
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-607681/1-A
Matrix: SolidDate Collected: N/A
Date Received: N/A
Prep 5035 BEP01/08/23 09:30 EET PEN607681
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.00 g 5.00 g
Analysis 8260D 1 607662 01/08/23 10:51 BEP EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-607724/4
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB01/09/23 11:521 EET PEN607724
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Lab Sample ID: LCS 400-608226/2-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW01/12/23 13:01 EET PEN608226
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 608260 01/12/23 16:58 JAW EET PENTotal/NA
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-607535/3-A
Matrix: SolidDate Collected: N/A
Date Received: N/A
Prep 5035 SAB01/06/23 09:30 EET PEN607535
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5.00 g 5.00 g
Analysis MAVPH 50 607496 01/06/23 14:37 SAB EET PENTotal/NA 5 mL 5 mL
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-607724/5
Matrix: WaterDate Collected: N/A
Date Received: N/A
Analysis MAVPH SAB01/09/23 12:261 EET PEN607724
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 5 mL 5 mL
Eurofins Pensacola
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Lab Chronicle
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Client Sample ID: Lab Control Sample Dup Lab Sample ID: LCSD 400-608226/3-A
Matrix: WaterDate Collected: N/A
Date Received: N/A
Prep 504.1 JAW01/12/23 13:01 EET PEN608226
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 35 mL 35 mL
Analysis 504.1 1 608260 01/12/23 17:18 JAW EET PENTotal/NA
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2 MS
Matrix: SoilDate Collected: 01/05/23 10:47
Percent Solids: 76.9Date Received: 01/06/23 08:58
Prep 5035 SAB01/09/23 09:43 EET PEN607535
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 6.158 g 5.00 g
Analysis MAVPH 50 607496 01/10/23 09:46 SAB EET PENTotal/NA 5 mL 5 mL
Client Sample ID: MW1 (8-10)Lab Sample ID: 400-231380-2 MSD
Matrix: SoilDate Collected: 01/05/23 10:47
Percent Solids: 76.9Date Received: 01/06/23 08:58
Prep 5035 SAB01/09/23 09:43 EET PEN607535
Type
Batch
Method
Batch
Prep Type LabAnalystRun
Prepared
or Analyzed
Initial
Amount Amount
Final Batch
NumberFactor
Dil
Total/NA 6.158 g 5.00 g
Analysis MAVPH 50 607496 01/10/23 10:37 SAB EET PENTotal/NA 5 mL 5 mL
¹ Completion dates and times are reported or not reported per method requirements or individual lab discretion.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Method Summary
Job ID: 400-231380-1Client: Terraquest Environmental Consultants, PC
Project/Site: Bear Pond Market
Method Method Description LaboratoryProtocol
SW8468260DVolatile Organic Compounds by GC/MS EET PEN
SMSM6200-B Volatile Organic Compounds EET PEN
MA DEPMAVPHMassachusetts - Volatile Petroleum Hydrocarbons (GC)EET PEN
EPA-DW504.1 EDB, DBCP and 1,2,3-TCP (GC)EET PEN
SW8466010DMetals (ICP)EET PEN
EPAMoisturePercent Moisture EET PEN
SW8463010APreparation, Total Metals EET PEN
SW8465030BPurge and Trap EET PEN
SW8465035Closed System Purge and Trap EET PEN
EPA-DW504.1 Microextraction EET PEN
Protocol References:
EPA = US Environmental Protection Agency
EPA-DW = "Methods For The Determination Of Organic Compounds In Drinking Water", EPA/600/4-88/039, December 1988 And Its Supplements.
MA DEP = Massachusetts Department Of Environmental Protection
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
EET PEN = Eurofins Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Eurofins Pensacola
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Accreditation/Certification Summary
Client: Terraquest Environmental Consultants, PC Job ID: 400-231380-1
Project/Site: Bear Pond Market
Laboratory: Eurofins Pensacola
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program Identification Number Expiration Date
North Carolina (WW/SW)State 314 12-31-23
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
Moisture Soil Percent Moisture
Moisture Soil Percent Solids
SM6200-B Ground Water 2-Butanone (MEK)
SM6200-B Ground Water 2-Hexanone
SM6200-B Ground Water 4-Methyl-2-pentanone (MIBK)
SM6200-B Ground Water Acetone
SM6200-B Ground Water Vinyl acetate
Eurofins Pensacola
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Login Sample Receipt Checklist
Client: Terraquest Environmental Consultants, PC Job Number: 400-231380-1
Login Number: 231380
Question Answer Comment
Creator: Whitley, Adrian
List Source: Eurofins Pensacola
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey
meter.
N/AThe cooler's custody seal, if present, is intact.
N/ASample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or
tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.1.3°C IR9
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate
HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is
<6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins Pensacola
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