MO-88896_96877_CA_LET_20230131_lab

#=CL#
January 25, 2023
LIMS USE: FR - PHIL RAHN
LIMS OBJECT ID: 92646404
92646404
Project:
Pace Project No.:
RE:
Mr. Phil Rahn
Waters Edge Environmental
1434 Chester Road
Raleigh, NC 27606
R22-64 SHAMROCK SPILL PINEVILL
Dear Mr. Rahn:
Enclosed are the analytical results for sample(s) received by the laboratory on January 11, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace National - Mt. Juliet
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 31
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
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DOD Certification: #1461.01
EPA# TN00003
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Georgia DW Certification #: 923
Georgia Certification: NELAP
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Illinois Certification #: 200008
Indiana Certification #: C-TN-01
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Kentucky Certification #: 90010
Louisiana Certification #: AI30792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TN003
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TN002
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LAO00356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 31
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Lab ID Sample ID Matrix Date Collected Date Received
92646404001 SS-3-2 Solid 01/10/23 11:30 01/11/23 11:21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 31
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92646404001 SS-3-2 MADEP EPH 7 PASI-CSEM
MADEP VPH 6 PANADM
EPA 8270E 75 PASI-CBPJ
EPA 8260D 70 PASI-CSAS
SW-846 1 PASI-CKDF
SM 2540G 1 PANCMK
PAN = Pace National - Mt. Juliet
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Sample:SS-3-2 Lab ID:92646404001 Collected:01/10/23 11:30 Received:01/11/23 11:21 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: MADEP EPH Preparation Method: MADEP EPH
Pace Analytical Services - Charlotte
MADEP EPH NC Soil
Aliphatic (C09-C18)17.3 mg/kg 01/18/23 15:52 N201/15/23 13:1411.9 11.9 1
Aliphatic (C19-C36)37.8 mg/kg 01/18/23 15:52 N201/15/23 13:1411.9 11.9 1
Aromatic (C11-C22)58.9 mg/kg 01/18/23 15:52 N201/15/23 13:1411.9 11.9 1
Surrogates
1-Chlorooctadecane (S)59 %01/18/23 15:52 3386-33-201/15/23 13:1440-140 1
o-Terphenyl (S)79 %01/18/23 15:52 84-15-101/15/23 13:1440-140 1
2-Fluorobiphenyl (S)112 %01/18/23 15:52 321-60-801/15/23 13:1440-140 1
2-Bromonaphthalene (S)115 %01/18/23 15:52 580-13-201/15/23 13:1440-140 1
Analytical Method: MADEP VPH Preparation Method: MADEPV
Pace National - Mt. Juliet
MADEPV
Aliphatic (C05-C08)ND mg/kg 01/17/23 00:2701/10/23 11:306.24 2.08 1
Aliphatic (C09-C12)ND mg/kg 01/17/23 00:2701/10/23 11:306.24 2.08 1
Aromatic (C09-C10),Unadjusted ND mg/kg 01/17/23 00:27 TPHC9C10A01/10/23 11:306.24 2.08 1
Total VPH 8.85 mg/kg 01/17/23 00:27 VPH01/10/23 11:306.24 2.08 1
Surrogates
2,5-Dibromotoluene (FID)91.5 %01/17/23 00:27 615-59-8FID01/10/23 11:3070.0-130 1
2,5-Dibromotoluene (PID)91.8 %01/17/23 00:27 615-59-8PID01/10/23 11:3070.0-130 1
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
Acenaphthene ND ug/kg 01/20/23 16:33 83-32-901/19/23 12:313881361
Acenaphthylene ND ug/kg 01/20/23 16:33 208-96-801/19/23 12:313881361
Aniline ND ug/kg 01/20/23 16:33 62-53-301/19/23 12:313881521
Anthracene ND ug/kg 01/20/23 16:33 120-12-701/19/23 12:313881271
Benzo(a)anthracene ND ug/kg 01/20/23 16:33 56-55-301/19/23 12:313881291
Benzo(a)pyrene ND ug/kg 01/20/23 16:33 50-32-801/19/23 12:313881341
Benzo(b)fluoranthene ND ug/kg 01/20/23 16:33 205-99-201/19/23 12:313881291
Benzo(g,h,i)perylene ND ug/kg 01/20/23 16:33 191-24-201/19/23 12:313881501
Benzo(k)fluoranthene ND ug/kg 01/20/23 16:33 207-08-901/19/23 12:313881361
Benzoic Acid ND ug/kg 01/20/23 16:33 65-85-001/19/23 12:3119408331
Benzyl alcohol ND ug/kg 01/20/23 16:33 100-51-601/19/23 12:317752941
4-Bromophenylphenyl ether ND ug/kg 01/20/23 16:33 101-55-301/19/23 12:313881491
Butylbenzylphthalate ND ug/kg 01/20/23 16:33 85-68-701/19/23 12:313881631
4-Chloro-3-methylphenol ND ug/kg 01/20/23 16:33 59-50-701/19/23 12:317752731
4-Chloroaniline ND ug/kg 01/20/23 16:33 106-47-801/19/23 12:317753041
bis(2-Chloroethoxy)methane ND ug/kg 01/20/23 16:33 111-91-101/19/23 12:313881611
bis(2-Chloroethyl) ether ND ug/kg 01/20/23 16:33 111-44-401/19/23 12:313881461
2-Chloronaphthalene ND ug/kg 01/20/23 16:33 91-58-701/19/23 12:313881541
2-Chlorophenol ND ug/kg 01/20/23 16:33 95-57-801/19/23 12:313881461
4-Chlorophenylphenyl ether ND ug/kg 01/20/23 16:33 7005-72-301/19/23 12:313881451
Chrysene ND ug/kg 01/20/23 16:33 218-01-901/19/23 12:313881411
Dibenz(a,h)anthracene ND ug/kg 01/20/23 16:33 53-70-301/19/23 12:313881491
Dibenzofuran ND ug/kg 01/20/23 16:33 132-64-901/19/23 12:313881401
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Sample:SS-3-2 Lab ID:92646404001 Collected:01/10/23 11:30 Received:01/11/23 11:21 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
1,2-Dichlorobenzene ND ug/kg 01/20/23 16:33 95-50-101/19/23 12:313881401
1,3-Dichlorobenzene ND ug/kg 01/20/23 16:33 541-73-101/19/23 12:313881371
1,4-Dichlorobenzene ND ug/kg 01/20/23 16:33 106-46-701/19/23 12:313881481
3,3'-Dichlorobenzidine ND ug/kg 01/20/23 16:33 91-94-101/19/23 12:317752621
2,4-Dichlorophenol ND ug/kg 01/20/23 16:33 120-83-201/19/23 12:313881521
Diethylphthalate ND ug/kg 01/20/23 16:33 84-66-201/19/23 12:313881421
2,4-Dimethylphenol ND ug/kg 01/20/23 16:33 105-67-901/19/23 12:313881611
Dimethylphthalate ND ug/kg 01/20/23 16:33 131-11-301/19/23 12:313881411
Di-n-butylphthalate ND ug/kg 01/20/23 16:33 84-74-201/19/23 12:313881301
4,6-Dinitro-2-methylphenol ND ug/kg 01/20/23 16:33 534-52-101/19/23 12:317753621
2,4-Dinitrophenol ND ug/kg 01/20/23 16:33 51-28-501/19/23 12:31194012001
2,4-Dinitrotoluene ND ug/kg 01/20/23 16:33 121-14-201/19/23 12:313881491
2,6-Dinitrotoluene ND ug/kg 01/20/23 16:33 606-20-201/19/23 12:313881421
Di-n-octylphthalate ND ug/kg 01/20/23 16:33 117-84-001/19/23 12:313881531
bis(2-Ethylhexyl)phthalate ND ug/kg 01/20/23 16:33 117-81-701/19/23 12:313881501
Fluoranthene ND ug/kg 01/20/23 16:33 206-44-001/19/23 12:313881331
Fluorene ND ug/kg 01/20/23 16:33 86-73-701/19/23 12:313881361
Hexachloro-1,3-butadiene ND ug/kg 01/20/23 16:33 87-68-301/19/23 12:313881681
Hexachlorobenzene ND ug/kg 01/20/23 16:33 118-74-101/19/23 12:313881521
Hexachlorocyclopentadiene ND ug/kg 01/20/23 16:33 77-47-401/19/23 12:313882221
Hexachloroethane ND ug/kg 01/20/23 16:33 67-72-101/19/23 12:313881481
Indeno(1,2,3-cd)pyrene ND ug/kg 01/20/23 16:33 193-39-501/19/23 12:313881531
Isophorone ND ug/kg 01/20/23 16:33 78-59-101/19/23 12:313881731
1-Methylnaphthalene ND ug/kg 01/20/23 16:33 90-12-001/19/23 12:313881361
2-Methylnaphthalene ND ug/kg 01/20/23 16:33 91-57-601/19/23 12:313881551
2-Methylphenol(o-Cresol)ND ug/kg 01/20/23 16:33 95-48-701/19/23 12:313881591
3&4-Methylphenol(m&p Cresol)ND ug/kg 01/20/23 16:33 15831-10-401/19/23 12:313881561
Naphthalene ND ug/kg 01/20/23 16:33 91-20-301/19/23 12:313881321
2-Nitroaniline ND ug/kg 01/20/23 16:33 88-74-401/19/23 12:3119403171
3-Nitroaniline ND ug/kg 01/20/23 16:33 99-09-201/19/23 12:3119403041
4-Nitroaniline ND ug/kg 01/20/23 16:33 100-01-601/19/23 12:317752951
Nitrobenzene ND ug/kg 01/20/23 16:33 98-95-301/19/23 12:313881801
2-Nitrophenol ND ug/kg 01/20/23 16:33 88-75-501/19/23 12:313881681
4-Nitrophenol ND ug/kg 01/20/23 16:33 100-02-701/19/23 12:3119407501
N-Nitrosodimethylamine ND ug/kg 01/20/23 16:33 62-75-9 v101/19/23 12:313881301
N-Nitroso-di-n-propylamine ND ug/kg 01/20/23 16:33 621-64-701/19/23 12:313881461
N-Nitrosodiphenylamine ND ug/kg 01/20/23 16:33 86-30-601/19/23 12:313881371
2,2'-Oxybis(1-chloropropane)ND ug/kg 01/20/23 16:33 108-60-101/19/23 12:313881841
Pentachlorophenol ND ug/kg 01/20/23 16:33 87-86-501/19/23 12:317753791
Phenanthrene ND ug/kg 01/20/23 16:33 85-01-801/19/23 12:313881271
Phenol ND ug/kg 01/20/23 16:33 108-95-201/19/23 12:313881731
Pyrene ND ug/kg 01/20/23 16:33 129-00-001/19/23 12:313881571
Pyridine ND ug/kg 01/20/23 16:33 110-86-1 v101/19/23 12:313881221
1,2,4-Trichlorobenzene ND ug/kg 01/20/23 16:33 120-82-101/19/23 12:313881531
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Sample:SS-3-2 Lab ID:92646404001 Collected:01/10/23 11:30 Received:01/11/23 11:21 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270E Preparation Method: EPA 3546
Pace Analytical Services - Charlotte
8270E MSSV Microwave
2,4,5-Trichlorophenol ND ug/kg 01/20/23 16:33 95-95-401/19/23 12:313881771
2,4,6-Trichlorophenol ND ug/kg 01/20/23 16:33 88-06-201/19/23 12:313881601
Surrogates
Nitrobenzene-d5 (S)77 %01/20/23 16:33 4165-60-001/19/23 12:3110-130 1
2-Fluorobiphenyl (S)62 %01/20/23 16:33 321-60-801/19/23 12:3110-130 1
Terphenyl-d14 (S)68 %01/20/23 16:33 1718-51-001/19/23 12:3110-130 1
Phenol-d6 (S)71 %01/20/23 16:33 13127-88-301/19/23 12:3110-130 1
2-Fluorophenol (S)70 %01/20/23 16:33 367-12-401/19/23 12:3110-130 1
2,4,6-Tribromophenol (S)69 %01/20/23 16:33 118-79-601/19/23 12:3110-131 1
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
Acetone ND ug/kg 01/24/23 23:58 67-64-101/24/23 15:0913543.5 1
Benzene ND ug/kg 01/24/23 23:58 71-43-201/24/23 15:096.8 2.7 1
Bromobenzene ND ug/kg 01/24/23 23:58 108-86-101/24/23 15:096.8 2.2 1
Bromochloromethane ND ug/kg 01/24/23 23:58 74-97-501/24/23 15:096.8 2.0 1
Bromodichloromethane ND ug/kg 01/24/23 23:58 75-27-401/24/23 15:096.8 2.6 1
Bromoform ND ug/kg 01/24/23 23:58 75-25-201/24/23 15:096.8 2.4 1
Bromomethane ND ug/kg 01/24/23 23:58 74-83-9 v101/24/23 15:0913.5 10.7 1
2-Butanone (MEK)ND ug/kg 01/24/23 23:58 78-93-301/24/23 15:0913532.5 1
n-Butylbenzene ND ug/kg 01/24/23 23:58 104-51-801/24/23 15:096.8 3.2 1
sec-Butylbenzene ND ug/kg 01/24/23 23:58 135-98-801/24/23 15:096.8 3.0 1
tert-Butylbenzene ND ug/kg 01/24/23 23:58 98-06-601/24/23 15:096.8 2.4 1
Carbon tetrachloride ND ug/kg 01/24/23 23:58 56-23-501/24/23 15:096.8 2.5 1
Chlorobenzene ND ug/kg 01/24/23 23:58 108-90-701/24/23 15:096.8 1.3 1
Chloroethane ND ug/kg 01/24/23 23:58 75-00-301/24/23 15:0913.5 5.2 1
Chloroform ND ug/kg 01/24/23 23:58 67-66-301/24/23 15:096.8 4.1 1
Chloromethane ND ug/kg 01/24/23 23:58 74-87-3 L101/24/23 15:0913.5 5.7 1
2-Chlorotoluene ND ug/kg 01/24/23 23:58 95-49-801/24/23 15:096.8 2.4 1
4-Chlorotoluene ND ug/kg 01/24/23 23:58 106-43-401/24/23 15:096.8 1.2 1
1,2-Dibromo-3-chloropropane ND ug/kg 01/24/23 23:58 96-12-801/24/23 15:096.8 2.6 1
Dibromochloromethane ND ug/kg 01/24/23 23:58 124-48-101/24/23 15:096.8 3.8 1
1,2-Dibromoethane (EDB)ND ug/kg 01/24/23 23:58 106-93-401/24/23 15:096.8 3.0 1
Dibromomethane ND ug/kg 01/24/23 23:58 74-95-301/24/23 15:096.8 1.4 1
1,2-Dichlorobenzene ND ug/kg 01/24/23 23:58 95-50-101/24/23 15:096.8 2.4 1
1,3-Dichlorobenzene ND ug/kg 01/24/23 23:58 541-73-101/24/23 15:096.8 2.1 1
1,4-Dichlorobenzene ND ug/kg 01/24/23 23:58 106-46-701/24/23 15:096.8 1.8 1
Dichlorodifluoromethane ND ug/kg 01/24/23 23:58 75-71-801/24/23 15:0913.5 2.9 1
1,1-Dichloroethane ND ug/kg 01/24/23 23:58 75-34-301/24/23 15:096.8 2.8 1
1,2-Dichloroethane ND ug/kg 01/24/23 23:58 107-06-201/24/23 15:096.8 4.5 1
1,1-Dichloroethene ND ug/kg 01/24/23 23:58 75-35-401/24/23 15:096.8 2.8 1
cis-1,2-Dichloroethene ND ug/kg 01/24/23 23:58 156-59-201/24/23 15:096.8 2.3 1
trans-1,2-Dichloroethene ND ug/kg 01/24/23 23:58 156-60-501/24/23 15:096.8 2.4 1
1,2-Dichloropropane ND ug/kg 01/24/23 23:58 78-87-501/24/23 15:096.8 2.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Sample:SS-3-2 Lab ID:92646404001 Collected:01/10/23 11:30 Received:01/11/23 11:21 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8260D Preparation Method: EPA 5035A/5030B
Pace Analytical Services - Charlotte
8260D/5035A/5030B Volatiles
1,3-Dichloropropane ND ug/kg 01/24/23 23:58 142-28-901/24/23 15:096.8 2.1 1
2,2-Dichloropropane ND ug/kg 01/24/23 23:58 594-20-701/24/23 15:096.8 2.2 1
1,1-Dichloropropene ND ug/kg 01/24/23 23:58 563-58-601/24/23 15:096.8 3.2 1
cis-1,3-Dichloropropene ND ug/kg 01/24/23 23:58 10061-01-501/24/23 15:096.8 1.8 1
trans-1,3-Dichloropropene ND ug/kg 01/24/23 23:58 10061-02-601/24/23 15:096.8 2.3 1
Diisopropyl ether ND ug/kg 01/24/23 23:58 108-20-301/24/23 15:096.8 1.8 1
Ethylbenzene ND ug/kg 01/24/23 23:58 100-41-401/24/23 15:096.8 3.2 1
Hexachloro-1,3-butadiene ND ug/kg 01/24/23 23:58 87-68-301/24/23 15:0913.5 11.1 1
2-Hexanone ND ug/kg 01/24/23 23:58 591-78-601/24/23 15:0967.7 6.5 1
Isopropylbenzene (Cumene)ND ug/kg 01/24/23 23:58 98-82-801/24/23 15:096.8 2.3 1
p-Isopropyltoluene ND ug/kg 01/24/23 23:58 99-87-601/24/23 15:096.8 3.3 1
Methylene Chloride ND ug/kg 01/24/23 23:58 75-09-201/24/23 15:0927.1 18.5 1
4-Methyl-2-pentanone (MIBK)ND ug/kg 01/24/23 23:58 108-10-101/24/23 15:0967.7 6.5 1
Methyl-tert-butyl ether ND ug/kg 01/24/23 23:58 1634-04-401/24/23 15:096.8 2.5 1
Naphthalene ND ug/kg 01/24/23 23:58 91-20-301/24/23 15:096.8 3.6 1
n-Propylbenzene ND ug/kg 01/24/23 23:58 103-65-101/24/23 15:096.8 2.4 1
Styrene ND ug/kg 01/24/23 23:58 100-42-501/24/23 15:096.8 1.8 1
1,1,1,2-Tetrachloroethane ND ug/kg 01/24/23 23:58 630-20-601/24/23 15:096.8 2.6 1
1,1,2,2-Tetrachloroethane ND ug/kg 01/24/23 23:58 79-34-501/24/23 15:096.8 1.8 1
Tetrachloroethene ND ug/kg 01/24/23 23:58 127-18-401/24/23 15:096.8 2.1 1
Toluene ND ug/kg 01/24/23 23:58 108-88-301/24/23 15:096.8 1.9 1
1,2,3-Trichlorobenzene ND ug/kg 01/24/23 23:58 87-61-601/24/23 15:096.8 5.5 1
1,2,4-Trichlorobenzene ND ug/kg 01/24/23 23:58 120-82-101/24/23 15:096.8 5.7 1
1,1,1-Trichloroethane ND ug/kg 01/24/23 23:58 71-55-601/24/23 15:096.8 3.5 1
1,1,2-Trichloroethane ND ug/kg 01/24/23 23:58 79-00-501/24/23 15:096.8 2.2 1
Trichloroethene ND ug/kg 01/24/23 23:58 79-01-601/24/23 15:096.8 1.7 1
Trichlorofluoromethane ND ug/kg 01/24/23 23:58 75-69-401/24/23 15:096.8 3.7 1
1,2,3-Trichloropropane ND ug/kg 01/24/23 23:58 96-18-401/24/23 15:096.8 3.4 1
1,2,4-Trimethylbenzene ND ug/kg 01/24/23 23:58 95-63-601/24/23 15:096.8 1.9 1
1,3,5-Trimethylbenzene ND ug/kg 01/24/23 23:58 108-67-801/24/23 15:096.8 2.3 1
Vinyl acetate ND ug/kg 01/24/23 23:58 108-05-4 v101/24/23 15:0967.7 4.9 1
Vinyl chloride ND ug/kg 01/24/23 23:58 75-01-401/24/23 15:0913.5 3.4 1
Xylene (Total)ND ug/kg 01/24/23 23:58 1330-20-701/24/23 15:0913.5 3.9 1
m&p-Xylene ND ug/kg 01/24/23 23:58 179601-23-101/24/23 15:0913.5 4.6 1
o-Xylene ND ug/kg 01/24/23 23:58 95-47-601/24/23 15:096.8 3.0 1
Surrogates
Toluene-d8 (S)101 %01/24/23 23:58 2037-26-5 u801/24/23 15:0970-130 1
4-Bromofluorobenzene (S)107 %01/24/23 23:58 460-00-401/24/23 15:0970-130 1
1,2-Dichloroethane-d4 (S)109 %01/24/23 23:58 17060-07-001/24/23 15:0970-130 1
Analytical Method: SW-846
Pace Analytical Services - Charlotte
Percent Moisture
Percent Moisture 15.4 %01/13/23 15:31 N20.10 0.10 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 31
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Sample:SS-3-2 Lab ID:92646404001 Collected:01/10/23 11:30 Received:01/11/23 11:21 Matrix:Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2540G Preparation Method: SM 2540 G
Pace National - Mt. Juliet
Total Solids 2540 G-2011
Total Solids 89.7 %01/16/23 14:3001/16/23 14:211
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1989609
KS LRH/MADEPV/MTDEQ
VPH/VPH
MADEP VPH
MADEPV
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92646404001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3881557-3
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
Aliphatic (C05-C08)mg/kg ND 5.00 01/16/23 15:081.67
Aliphatic (C09-C12)mg/kg ND 5.00 01/16/23 15:081.67
Aromatic (C09-C10),Unadjusted mg/kg ND 5.00 01/16/23 15:081.67
Total VPH mg/kg ND 5.00 01/16/23 15:081.67
2,5-Dibromotoluene (FID)%84.6 70.0-130 01/16/23 15:08
2,5-Dibromotoluene (PID)%86 70.0-130 01/16/23 15:08
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3881557-1LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
R3881557-2
Aliphatic (C05-C08)mg/kg 50.760.0 84.5 70.0-13084.350.6 0.197 25
Aliphatic (C09-C12)mg/kg 57.470.0 82.0 70.0-13082.057.4 0.00 25
Aromatic (C09-C10),Unadjusted mg/kg 8.6310.0 86.3 70.0-13085.48.54 1.05 25
Total VPH mg/kg 117140 83.6 70.0-13083.6117 0.00 25
2,5-Dibromotoluene (FID)%98.8 70.0-13092.0
2,5-Dibromotoluene (PID)%102 70.0-13096.4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
751446
EPA 5035A/5030B
EPA 8260D
8260D 5035A 5030B
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92646404001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3904958
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/kg ND 5.0 01/24/23 23:021.9
1,1,1-Trichloroethane ug/kg ND 5.0 01/24/23 23:022.6
1,1,2,2-Tetrachloroethane ug/kg ND 5.0 01/24/23 23:021.3
1,1,2-Trichloroethane ug/kg ND 5.0 01/24/23 23:021.7
1,1-Dichloroethane ug/kg ND 5.0 01/24/23 23:022.1
1,1-Dichloroethene ug/kg ND 5.0 01/24/23 23:022.1
1,1-Dichloropropene ug/kg ND 5.0 01/24/23 23:022.4
1,2,3-Trichlorobenzene ug/kg ND 5.0 01/24/23 23:024.0
1,2,3-Trichloropropane ug/kg ND 5.0 01/24/23 23:022.5
1,2,4-Trichlorobenzene ug/kg ND 5.0 01/24/23 23:024.2
1,2,4-Trimethylbenzene ug/kg ND 5.0 01/24/23 23:021.4
1,2-Dibromo-3-chloropropane ug/kg ND 5.0 01/24/23 23:021.9
1,2-Dibromoethane (EDB)ug/kg ND 5.0 01/24/23 23:022.2
1,2-Dichlorobenzene ug/kg ND 5.0 01/24/23 23:021.8
1,2-Dichloroethane ug/kg ND 5.0 01/24/23 23:023.3
1,2-Dichloropropane ug/kg ND 5.0 01/24/23 23:021.5
1,3,5-Trimethylbenzene ug/kg ND 5.0 01/24/23 23:021.7
1,3-Dichlorobenzene ug/kg ND 5.0 01/24/23 23:021.6
1,3-Dichloropropane ug/kg ND 5.0 01/24/23 23:021.6
1,4-Dichlorobenzene ug/kg ND 5.0 01/24/23 23:021.3
2,2-Dichloropropane ug/kg ND 5.0 01/24/23 23:021.6
2-Butanone (MEK)ug/kg ND 100 01/24/23 23:0224.0
2-Chlorotoluene ug/kg ND 5.0 01/24/23 23:021.8
2-Hexanone ug/kg ND 50.0 01/24/23 23:024.8
4-Chlorotoluene ug/kg ND 5.0 01/24/23 23:020.88
4-Methyl-2-pentanone (MIBK)ug/kg ND 50.0 01/24/23 23:024.8
Acetone ug/kg ND 100 01/24/23 23:0232.1
Benzene ug/kg ND 5.0 01/24/23 23:022.0
Bromobenzene ug/kg ND 5.0 01/24/23 23:021.6
Bromochloromethane ug/kg ND 5.0 01/24/23 23:021.5
Bromodichloromethane ug/kg ND 5.0 01/24/23 23:021.9
Bromoform ug/kg ND 5.0 01/24/23 23:021.8
Bromomethane ug/kg ND 10.0 v101/24/23 23:027.9
Carbon tetrachloride ug/kg ND 5.0 01/24/23 23:021.9
Chlorobenzene ug/kg ND 5.0 01/24/23 23:020.96
Chloroethane ug/kg ND 10.0 01/24/23 23:023.9
Chloroform ug/kg ND 5.0 01/24/23 23:023.0
Chloromethane ug/kg ND 10.0 01/24/23 23:024.2
cis-1,2-Dichloroethene ug/kg ND 5.0 01/24/23 23:021.7
cis-1,3-Dichloropropene ug/kg ND 5.0 01/24/23 23:021.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3904958
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
Dibromochloromethane ug/kg ND 5.0 01/24/23 23:022.8
Dibromomethane ug/kg ND 5.0 01/24/23 23:021.1
Dichlorodifluoromethane ug/kg ND 10.0 01/24/23 23:022.2
Diisopropyl ether ug/kg ND 5.0 01/24/23 23:021.4
Ethylbenzene ug/kg ND 5.0 01/24/23 23:022.3
Hexachloro-1,3-butadiene ug/kg ND 10.0 01/24/23 23:028.2
Isopropylbenzene (Cumene)ug/kg ND 5.0 01/24/23 23:021.7
m&p-Xylene ug/kg ND 10.0 01/24/23 23:023.4
Methyl-tert-butyl ether ug/kg ND 5.0 01/24/23 23:021.9
Methylene Chloride ug/kg ND 20.0 01/24/23 23:0213.7
n-Butylbenzene ug/kg ND 5.0 01/24/23 23:022.4
n-Propylbenzene ug/kg ND 5.0 01/24/23 23:021.8
Naphthalene ug/kg ND 5.0 01/24/23 23:022.6
o-Xylene ug/kg ND 5.0 01/24/23 23:022.2
p-Isopropyltoluene ug/kg ND 5.0 01/24/23 23:022.5
sec-Butylbenzene ug/kg ND 5.0 01/24/23 23:022.2
Styrene ug/kg ND 5.0 01/24/23 23:021.3
tert-Butylbenzene ug/kg ND 5.0 01/24/23 23:021.8
Tetrachloroethene ug/kg ND 5.0 01/24/23 23:021.6
Toluene ug/kg ND 5.0 01/24/23 23:021.4
trans-1,2-Dichloroethene ug/kg ND 5.0 01/24/23 23:021.8
trans-1,3-Dichloropropene ug/kg ND 5.0 01/24/23 23:021.7
Trichloroethene ug/kg ND 5.0 01/24/23 23:021.3
Trichlorofluoromethane ug/kg ND 5.0 01/24/23 23:022.8
Vinyl acetate ug/kg ND 50.0 v101/24/23 23:023.6
Vinyl chloride ug/kg ND 10.0 01/24/23 23:022.5
Xylene (Total)ug/kg ND 10.0 01/24/23 23:022.8
1,2-Dichloroethane-d4 (S)%114 70-130 01/24/23 23:02
4-Bromofluorobenzene (S)%103 70-130 01/24/23 23:02
Toluene-d8 (S)%101 70-130 01/24/23 23:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3904959LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/kg 500500 100 70-130
1,1,1-Trichloroethane ug/kg 455500 91 70-130
1,1,2,2-Tetrachloroethane ug/kg 505500 101 70-130
1,1,2-Trichloroethane ug/kg 471500 94 70-130
1,1-Dichloroethane ug/kg 529500 106 70-130
1,1-Dichloroethene ug/kg 560500 112 70-130
1,1-Dichloropropene ug/kg 558500 112 70-130
1,2,3-Trichlorobenzene ug/kg 508500 102 70-130
1,2,3-Trichloropropane ug/kg 521500 104 70-130
1,2,4-Trichlorobenzene ug/kg 496500 99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3904959LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trimethylbenzene ug/kg 505500 101 70-130
1,2-Dibromo-3-chloropropane ug/kg 428500 86 67-130
1,2-Dibromoethane (EDB)ug/kg 499500 100 70-130
1,2-Dichlorobenzene ug/kg 516500 103 70-130
1,2-Dichloroethane ug/kg 524500 105 70-130
1,2-Dichloropropane ug/kg 544500 109 70-130
1,3,5-Trimethylbenzene ug/kg 511500 102 70-130
1,3-Dichlorobenzene ug/kg 504500 101 70-130
1,3-Dichloropropane ug/kg 520500 104 70-130
1,4-Dichlorobenzene ug/kg 497500 99 70-130
2,2-Dichloropropane ug/kg 484500 97 67-130
2-Butanone (MEK)ug/kg 10301000 103 66-130
2-Chlorotoluene ug/kg 535500 107 70-130
2-Hexanone ug/kg 10701000 107 70-130
4-Chlorotoluene ug/kg 521500 104 70-130
4-Methyl-2-pentanone (MIBK)ug/kg 10601000 106 70-130
Acetone ug/kg 9841000 98 67-130
Benzene ug/kg 493500 99 70-130
Bromobenzene ug/kg 497500 99 70-130
Bromochloromethane ug/kg 487500 97 70-130
Bromodichloromethane ug/kg 484500 97 70-130
Bromoform ug/kg 486500 97 70-130
Bromomethane ug/kg 627 v150012553-175
Carbon tetrachloride ug/kg 513500 103 70-130
Chlorobenzene ug/kg 507500 101 70-130
Chloroethane ug/kg 598500 120 70-135
Chloroform ug/kg 524500 105 70-130
Chloromethane ug/kg 660 L150013264-130
cis-1,2-Dichloroethene ug/kg 526500 105 70-130
cis-1,3-Dichloropropene ug/kg 519500 104 70-130
Dibromochloromethane ug/kg 485500 97 70-130
Dibromomethane ug/kg 491500 98 70-130
Dichlorodifluoromethane ug/kg 665500 133 63-145
Diisopropyl ether ug/kg 538500 108 68-130
Ethylbenzene ug/kg 492500 98 70-130
Hexachloro-1,3-butadiene ug/kg 479500 96 70-130
Isopropylbenzene (Cumene)ug/kg 489500 98 70-130
m&p-Xylene ug/kg 10501000 105 70-130
Methyl-tert-butyl ether ug/kg 516500 103 70-130
Methylene Chloride ug/kg 520500 104 67-130
n-Butylbenzene ug/kg 567500 113 70-130
n-Propylbenzene ug/kg 534500 107 70-130
Naphthalene ug/kg 497500 99 70-130
o-Xylene ug/kg 511500 102 70-130
p-Isopropyltoluene ug/kg 533500 107 70-130
sec-Butylbenzene ug/kg 512500 102 70-130
Styrene ug/kg 505500 101 70-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3904959LABORATORY CONTROL SAMPLE:
LCSSpike
tert-Butylbenzene ug/kg 511500 102 64-130
Tetrachloroethene ug/kg 519500 104 70-130
Toluene ug/kg 500500 100 70-130
trans-1,2-Dichloroethene ug/kg 544500 109 70-130
trans-1,3-Dichloropropene ug/kg 523500 105 70-130
Trichloroethene ug/kg 511500 102 70-130
Trichlorofluoromethane ug/kg 545500 109 70-130
Vinyl acetate ug/kg 1230 v1100012370-134
Vinyl chloride ug/kg 603500 121 68-130
Xylene (Total)ug/kg 15601500 104 70-130
1,2-Dichloroethane-d4 (S)%101 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3904960MATRIX SPIKE SAMPLE:
MSSpike
Result
92647971001
1,1,1,2-Tetrachloroethane ug/kg 656625 105 58-140ND
1,1,1-Trichloroethane ug/kg 685625 110 58-144ND
1,1,2,2-Tetrachloroethane ug/kg 788625 126 52-139ND
1,1,2-Trichloroethane ug/kg 784625 125 56-140ND
1,1-Dichloroethane ug/kg 807625 129 58-145ND
1,1-Dichloroethene ug/kg 801625 128 57-158ND
1,1-Dichloropropene ug/kg 759625 121 58-151ND
1,2,3-Trichlorobenzene ug/kg 205 M16253348-149ND
1,2,3-Trichloropropane ug/kg 723625 116 54-132ND
1,2,4-Trichlorobenzene ug/kg 143 M16252351-151ND
1,2,4-Trimethylbenzene ug/kg 623625 100 38-170ND
1,2-Dibromo-3-chloropropane ug/kg 278625 44 44-134ND
1,2-Dibromoethane (EDB)ug/kg 693625 111 60-138ND
1,2-Dichlorobenzene ug/kg 555625 89 59-147ND
1,2-Dichloroethane ug/kg 772625 124 57-139ND
1,2-Dichloropropane ug/kg 837625 134 62-145ND
1,3,5-Trimethylbenzene ug/kg 586625 94 47-159ND
1,3-Dichlorobenzene ug/kg 535625 86 58-144ND
1,3-Dichloropropane ug/kg 743625 119 60-142ND
1,4-Dichlorobenzene ug/kg 530625 85 57-143ND
2,2-Dichloropropane ug/kg 615625 98 37-144ND
2-Butanone (MEK)ug/kg 15201240 122 28-146ND
2-Chlorotoluene ug/kg 563625 90 55-158ND
2-Hexanone ug/kg 15401240 123 44-141ND
4-Chlorotoluene ug/kg 539625 86 55-146ND
4-Methyl-2-pentanone (MIBK)ug/kg 1910 M1124015350-138ND
Acetone ug/kg 13701240 106 20-136ND
Benzene ug/kg 746625 119 60-145ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3904960MATRIX SPIKE SAMPLE:
MSSpike
Result
92647971001
Bromobenzene ug/kg 587625 94 59-145ND
Bromochloromethane ug/kg 722625 116 57-143ND
Bromodichloromethane ug/kg 713625 114 53-133ND
Bromoform ug/kg 639625 102 48-133ND
Bromomethane ug/kg 478 v16257710-167ND
Carbon tetrachloride ug/kg 625625 100 57-147ND
Chlorobenzene ug/kg 648625 104 61-144ND
Chloroethane ug/kg 320625 51 10-153ND
Chloroform ug/kg 780625 124 58-141ND
Chloromethane ug/kg 1130 M062518054-165ND
cis-1,2-Dichloroethene ug/kg 794625 127 59-144ND
cis-1,3-Dichloropropene ug/kg 762625 122 56-137ND
Dibromochloromethane ug/kg 662625 106 53-139ND
Dibromomethane ug/kg 706625 113 60-136ND
Dichlorodifluoromethane ug/kg 1100625 176 49-177ND
Diisopropyl ether ug/kg 824625 132 53-136ND
Ethylbenzene ug/kg 593625 90 53-15027.5
Hexachloro-1,3-butadiene ug/kg 241 M16253842-186ND
Isopropylbenzene (Cumene)ug/kg 1070625 75 62-154604
m&p-Xylene ug/kg 12201240 98 49-156ND
Methyl-tert-butyl ether ug/kg 751625 120 54-133ND
Methylene Chloride ug/kg 875625 140 50-153ND
n-Butylbenzene ug/kg 3450 M1625-6 44-1743480
n-Propylbenzene ug/kg 2640 M16252352-1572490
Naphthalene ug/kg 64.2 M16251037-150ND
o-Xylene ug/kg 617625 96 54-15017.1
p-Isopropyltoluene ug/kg 677625 108 50-164ND
sec-Butylbenzene ug/kg 1760625 69 58-1611330
Styrene ug/kg 628625 101 60-148ND
tert-Butylbenzene ug/kg 673625 108 44-151ND
Tetrachloroethene ug/kg 525625 84 53-151ND
Toluene ug/kg 697625 111 52-148ND
trans-1,2-Dichloroethene ug/kg 749625 120 60-148ND
trans-1,3-Dichloropropene ug/kg 758625 121 55-133ND
Trichloroethene ug/kg 698625 112 60-148ND
Trichlorofluoromethane ug/kg 381625 61 10-154ND
Vinyl acetate ug/kg 1440 v1124011550-149ND
Vinyl chloride ug/kg 953625 152 57-157ND
Xylene (Total)ug/kg 18401880 97 52-15317.1
1,2-Dichloroethane-d4 (S)%113 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%104 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 15 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646404001
3904961SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/kg ND H130ND
1,1,1-Trichloroethane ug/kg ND H130ND
1,1,2,2-Tetrachloroethane ug/kg ND H130ND
1,1,2-Trichloroethane ug/kg ND H130ND
1,1-Dichloroethane ug/kg ND H130ND
1,1-Dichloroethene ug/kg ND H130ND
1,1-Dichloropropene ug/kg ND H130ND
1,2,3-Trichlorobenzene ug/kg ND H130ND
1,2,3-Trichloropropane ug/kg ND H130ND
1,2,4-Trichlorobenzene ug/kg ND H130ND
1,2,4-Trimethylbenzene ug/kg 3.4J H130ND
1,2-Dibromo-3-chloropropane ug/kg ND H130ND
1,2-Dibromoethane (EDB)ug/kg ND H130ND
1,2-Dichlorobenzene ug/kg ND H130ND
1,2-Dichloroethane ug/kg ND H130ND
1,2-Dichloropropane ug/kg ND H130ND
1,3,5-Trimethylbenzene ug/kg ND H130ND
1,3-Dichlorobenzene ug/kg ND H130ND
1,3-Dichloropropane ug/kg ND H130ND
1,4-Dichlorobenzene ug/kg ND H130ND
2,2-Dichloropropane ug/kg ND H130ND
2-Butanone (MEK)ug/kg 34.6J H130ND
2-Chlorotoluene ug/kg ND H130ND
2-Hexanone ug/kg ND H130ND
4-Chlorotoluene ug/kg ND H130ND
4-Methyl-2-pentanone (MIBK)ug/kg ND H130ND
Acetone ug/kg 103J H130ND
Benzene ug/kg ND H130ND
Bromobenzene ug/kg ND H130ND
Bromochloromethane ug/kg ND H130ND
Bromodichloromethane ug/kg ND H130ND
Bromoform ug/kg ND H130ND
Bromomethane ug/kg ND H1,v130ND
Carbon tetrachloride ug/kg ND H130ND
Chlorobenzene ug/kg ND H130ND
Chloroethane ug/kg ND H130ND
Chloroform ug/kg ND H130ND
Chloromethane ug/kg ND H130ND
cis-1,2-Dichloroethene ug/kg ND H130ND
cis-1,3-Dichloropropene ug/kg ND H130ND
Dibromochloromethane ug/kg ND H130ND
Dibromomethane ug/kg ND H130ND
Dichlorodifluoromethane ug/kg ND H130ND
Diisopropyl ether ug/kg ND H130ND
Ethylbenzene ug/kg ND H130ND
Hexachloro-1,3-butadiene ug/kg ND H130ND
Isopropylbenzene (Cumene)ug/kg ND H130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 16 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646404001
3904961SAMPLE DUPLICATE:
m&p-Xylene ug/kg ND H130ND
Methyl-tert-butyl ether ug/kg ND H130ND
Methylene Chloride ug/kg ND H130ND
n-Butylbenzene ug/kg ND H130ND
n-Propylbenzene ug/kg ND H130ND
Naphthalene ug/kg ND H130ND
o-Xylene ug/kg ND H130ND
p-Isopropyltoluene ug/kg ND H130ND
sec-Butylbenzene ug/kg ND H130ND
Styrene ug/kg ND H130ND
tert-Butylbenzene ug/kg ND H130ND
Tetrachloroethene ug/kg ND H130ND
Toluene ug/kg ND H130ND
trans-1,2-Dichloroethene ug/kg ND H130ND
trans-1,3-Dichloropropene ug/kg ND H130ND
Trichloroethene ug/kg ND H130ND
Trichlorofluoromethane ug/kg ND H130ND
Vinyl acetate ug/kg ND H1,v130ND
Vinyl chloride ug/kg ND H130ND
Xylene (Total)ug/kg ND 30ND
1,2-Dichloroethane-d4 (S)%109109
4-Bromofluorobenzene (S)%106107
Toluene-d8 (S)%102101
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 17 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
750377
EPA 3546
EPA 8270E
8270E Solid MSSV Microwave
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92646404001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3900090
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
1,2,4-Trichlorobenzene ug/kg ND 334 01/20/23 07:54132
1,2-Dichlorobenzene ug/kg ND 334 01/20/23 07:54121
1,3-Dichlorobenzene ug/kg ND 334 01/20/23 07:54119
1,4-Dichlorobenzene ug/kg ND 334 01/20/23 07:54128
1-Methylnaphthalene ug/kg ND 334 01/20/23 07:54118
2,2'-Oxybis(1-chloropropane)ug/kg ND 334 01/20/23 07:54159
2,4,5-Trichlorophenol ug/kg ND 334 01/20/23 07:54153
2,4,6-Trichlorophenol ug/kg ND 334 01/20/23 07:54138
2,4-Dichlorophenol ug/kg ND 334 01/20/23 07:54131
2,4-Dimethylphenol ug/kg ND 334 01/20/23 07:54139
2,4-Dinitrophenol ug/kg ND 1670 01/20/23 07:541030
2,4-Dinitrotoluene ug/kg ND 334 01/20/23 07:54129
2,6-Dinitrotoluene ug/kg ND 334 01/20/23 07:54123
2-Chloronaphthalene ug/kg ND 334 01/20/23 07:54133
2-Chlorophenol ug/kg ND 334 01/20/23 07:54126
2-Methylnaphthalene ug/kg ND 334 01/20/23 07:54134
2-Methylphenol(o-Cresol)ug/kg ND 334 01/20/23 07:54137
2-Nitroaniline ug/kg ND 1670 01/20/23 07:54274
2-Nitrophenol ug/kg ND 334 01/20/23 07:54145
3&4-Methylphenol(m&p Cresol)ug/kg ND 334 01/20/23 07:54135
3,3'-Dichlorobenzidine ug/kg ND 669 01/20/23 07:54226
3-Nitroaniline ug/kg ND 1670 01/20/23 07:54262
4,6-Dinitro-2-methylphenol ug/kg ND 669 01/20/23 07:54312
4-Bromophenylphenyl ether ug/kg ND 334 01/20/23 07:54129
4-Chloro-3-methylphenol ug/kg ND 669 01/20/23 07:54235
4-Chloroaniline ug/kg ND 669 01/20/23 07:54262
4-Chlorophenylphenyl ether ug/kg ND 334 01/20/23 07:54125
4-Nitroaniline ug/kg ND 669 01/20/23 07:54254
4-Nitrophenol ug/kg ND 1670 01/20/23 07:54647
Acenaphthene ug/kg ND 334 01/20/23 07:54118
Acenaphthylene ug/kg ND 334 01/20/23 07:54118
Aniline ug/kg ND 334 01/20/23 07:54131
Anthracene ug/kg ND 334 01/20/23 07:54109
Benzo(a)anthracene ug/kg ND 334 01/20/23 07:54111
Benzo(a)pyrene ug/kg ND 334 01/20/23 07:54116
Benzo(b)fluoranthene ug/kg ND 334 01/20/23 07:54111
Benzo(g,h,i)perylene ug/kg ND 334 01/20/23 07:54130
Benzo(k)fluoranthene ug/kg ND 334 01/20/23 07:54118
Benzoic Acid ug/kg ND 1670 01/20/23 07:54719
Benzyl alcohol ug/kg ND 669 01/20/23 07:54253
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 18 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3900090
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
bis(2-Chloroethoxy)methane ug/kg ND 334 01/20/23 07:54139
bis(2-Chloroethyl) ether ug/kg ND 334 01/20/23 07:54126
bis(2-Ethylhexyl)phthalate ug/kg ND 334 01/20/23 07:54130
Butylbenzylphthalate ug/kg ND 334 01/20/23 07:54141
Chrysene ug/kg ND 334 01/20/23 07:54122
Di-n-butylphthalate ug/kg ND 334 01/20/23 07:54112
Di-n-octylphthalate ug/kg ND 334 01/20/23 07:54132
Dibenz(a,h)anthracene ug/kg ND 334 01/20/23 07:54129
Dibenzofuran ug/kg ND 334 01/20/23 07:54121
Diethylphthalate ug/kg ND 334 01/20/23 07:54123
Dimethylphthalate ug/kg ND 334 01/20/23 07:54122
Fluoranthene ug/kg ND 334 01/20/23 07:54115
Fluorene ug/kg ND 334 01/20/23 07:54118
Hexachloro-1,3-butadiene ug/kg ND 334 01/20/23 07:54145
Hexachlorobenzene ug/kg ND 334 01/20/23 07:54131
Hexachlorocyclopentadiene ug/kg ND 334 01/20/23 07:54192
Hexachloroethane ug/kg ND 334 01/20/23 07:54128
Indeno(1,2,3-cd)pyrene ug/kg ND 334 01/20/23 07:54132
Isophorone ug/kg ND 334 01/20/23 07:54149
N-Nitroso-di-n-propylamine ug/kg ND 334 01/20/23 07:54126
N-Nitrosodimethylamine ug/kg ND 334 01/20/23 07:54112
N-Nitrosodiphenylamine ug/kg ND 334 01/20/23 07:54119
Naphthalene ug/kg ND 334 01/20/23 07:54114
Nitrobenzene ug/kg ND 334 01/20/23 07:54155
Pentachlorophenol ug/kg ND 669 01/20/23 07:54327
Phenanthrene ug/kg ND 334 01/20/23 07:54109
Phenol ug/kg ND 334 01/20/23 07:54149
Pyrene ug/kg ND 334 01/20/23 07:54136
Pyridine ug/kg ND 334 01/20/23 07:54105
2,4,6-Tribromophenol (S)%69 10-131 01/20/23 07:54
2-Fluorobiphenyl (S)%72 10-130 01/20/23 07:54
2-Fluorophenol (S)%74 10-130 01/20/23 07:54
Nitrobenzene-d5 (S)%77 10-130 01/20/23 07:54
Phenol-d6 (S)%75 10-130 01/20/23 07:54
Terphenyl-d14 (S)%82 10-130 01/20/23 07:54
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3900091LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4-Trichlorobenzene ug/kg 9101660 55 43-130
1,2-Dichlorobenzene ug/kg 9371660 57 43-130
1,3-Dichlorobenzene ug/kg 9181660 55 43-130
1,4-Dichlorobenzene ug/kg 9311660 56 44-130
1-Methylnaphthalene ug/kg 10701660 65 47-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 19 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3900091LABORATORY CONTROL SAMPLE:
LCSSpike
2,2'-Oxybis(1-chloropropane)ug/kg 9921660 60 29-130
2,4,5-Trichlorophenol ug/kg 10801660 65 47-130
2,4,6-Trichlorophenol ug/kg 10501660 64 47-130
2,4-Dichlorophenol ug/kg 10001660 61 45-130
2,4-Dimethylphenol ug/kg 12601660 76 45-130
2,4-Dinitrophenol ug/kg 56608280 68 27-140
2,4-Dinitrotoluene ug/kg 11301660 68 46-130
2,6-Dinitrotoluene ug/kg 11701660 71 48-130
2-Chloronaphthalene ug/kg 10401660 63 46-130
2-Chlorophenol ug/kg 10101660 61 43-130
2-Methylnaphthalene ug/kg 10201660 62 47-130
2-Methylphenol(o-Cresol)ug/kg 10301660 62 42-130
2-Nitroaniline ug/kg 21403310 65 41-130
2-Nitrophenol ug/kg 10501660 64 48-130
3&4-Methylphenol(m&p Cresol)ug/kg 9941660 60 39-130
3,3'-Dichlorobenzidine ug/kg 19103310 58 41-130
3-Nitroaniline ug/kg 20803310 63 37-130
4,6-Dinitro-2-methylphenol ug/kg 25003310 75 38-141
4-Bromophenylphenyl ether ug/kg 11001660 67 47-130
4-Chloro-3-methylphenol ug/kg 21303310 64 44-130
4-Chloroaniline ug/kg 20103310 61 41-130
4-Chlorophenylphenyl ether ug/kg 10501660 64 45-130
4-Nitroaniline ug/kg 22503310 68 42-130
4-Nitrophenol ug/kg 55408280 67 39-131
Acenaphthene ug/kg 11101660 67 49-130
Acenaphthylene ug/kg 11101660 67 50-130
Aniline ug/kg 9411660 57 38-130
Anthracene ug/kg 10901660 66 49-130
Benzo(a)anthracene ug/kg 11701660 71 51-130
Benzo(a)pyrene ug/kg 14701660 89 51-130
Benzo(b)fluoranthene ug/kg 14801660 90 49-130
Benzo(g,h,i)perylene ug/kg 15601660 94 48-140
Benzo(k)fluoranthene ug/kg 15101660 91 51-130
Benzoic Acid ug/kg 44408280 54 22-130
Benzyl alcohol ug/kg 19603310 59 43-130
bis(2-Chloroethoxy)methane ug/kg 10801660 65 43-130
bis(2-Chloroethyl) ether ug/kg 10501660 63 42-130
bis(2-Ethylhexyl)phthalate ug/kg 12701660 77 43-130
Butylbenzylphthalate ug/kg 13501660 82 44-131
Chrysene ug/kg 11601660 70 51-130
Di-n-butylphthalate ug/kg 12401660 75 46-130
Di-n-octylphthalate ug/kg 13201660 80 45-130
Dibenz(a,h)anthracene ug/kg 14701660 89 48-130
Dibenzofuran ug/kg 10401660 63 10-130
Diethylphthalate ug/kg 12101660 73 48-130
Dimethylphthalate ug/kg 11701660 70 48-130
Fluoranthene ug/kg 11501660 69 48-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 20 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3900091LABORATORY CONTROL SAMPLE:
LCSSpike
Fluorene ug/kg 10901660 66 48-130
Hexachloro-1,3-butadiene ug/kg 9211660 56 39-130
Hexachlorobenzene ug/kg 11201660 67 47-130
Hexachlorocyclopentadiene ug/kg 9691660 59 17-130
Hexachloroethane ug/kg 9781660 59 40-130
Indeno(1,2,3-cd)pyrene ug/kg 15601660 94 50-130
Isophorone ug/kg 11201660 67 41-130
N-Nitroso-di-n-propylamine ug/kg 10801660 65 36-130
N-Nitrosodimethylamine ug/kg 10101660 61 34-130
N-Nitrosodiphenylamine ug/kg 11501660 70 48-130
Naphthalene ug/kg 10101660 61 46-130
Nitrobenzene ug/kg 9871660 60 39-130
Pentachlorophenol ug/kg 20503310 62 42-130
Phenanthrene ug/kg 11901660 72 50-130
Phenol ug/kg 11101660 67 42-130
Pyrene ug/kg 12301660 74 50-130
Pyridine ug/kg 9201660 56 26-130
2,4,6-Tribromophenol (S)%75 10-131
2-Fluorobiphenyl (S)%68 10-130
2-Fluorophenol (S)%66 10-130
Nitrobenzene-d5 (S)%68 10-130
Phenol-d6 (S)%68 10-130
Terphenyl-d14 (S)%75 10-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3900092MATRIX SPIKE SAMPLE:
MSSpike
Result
92646210004
1,2,4-Trichlorobenzene ug/kg 8652300 38 16-130ND
1,2-Dichlorobenzene ug/kg 9422300 41 19-130ND
1,3-Dichlorobenzene ug/kg 8902300 39 19-130ND
1,4-Dichlorobenzene ug/kg 9092300 39 20-130ND
1-Methylnaphthalene ug/kg 9752300 42 19-130ND
2,2'-Oxybis(1-chloropropane)ug/kg 11302300 49 10-130ND
2,4,5-Trichlorophenol ug/kg 10702300 46 19-130ND
2,4,6-Trichlorophenol ug/kg 9942300 43 18-130ND
2,4-Dichlorophenol ug/kg 9212300 40 16-130ND
2,4-Dimethylphenol ug/kg 12802300 55 10-130ND
2,4-Dinitrophenol ug/kg 425011500 37 10-143ND
2,4-Dinitrotoluene ug/kg 12602300 55 19-130ND
2,6-Dinitrotoluene ug/kg 11602300 50 22-130ND
2-Chloronaphthalene ug/kg 9542300 41 18-130ND
2-Chlorophenol ug/kg 10402300 45 20-130ND
2-Methylnaphthalene ug/kg 9162300 40 18-130ND
2-Methylphenol(o-Cresol)ug/kg 10802300 47 13-130ND
2-Nitroaniline ug/kg 26304610 57 18-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 21 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3900092MATRIX SPIKE SAMPLE:
MSSpike
Result
92646210004
2-Nitrophenol ug/kg 10302300 45 19-130ND
3&4-Methylphenol(m&p Cresol)ug/kg 10602300 46 13-130ND
3,3'-Dichlorobenzidine ug/kg 24404610 53 10-130ND
3-Nitroaniline ug/kg 24404610 53 22-130ND
4,6-Dinitro-2-methylphenol ug/kg 28204610 61 10-144ND
4-Bromophenylphenyl ether ug/kg 10502300 46 18-130ND
4-Chloro-3-methylphenol ug/kg 20804610 45 16-130ND
4-Chloroaniline ug/kg 19404610 42 17-130ND
4-Chlorophenylphenyl ether ug/kg 9592300 42 17-130ND
4-Nitroaniline ug/kg 28004610 61 21-130ND
4-Nitrophenol ug/kg 708011500 61 13-131ND
Acenaphthene ug/kg 10402300 45 20-130ND
Acenaphthylene ug/kg 10502300 46 21-130ND
Aniline ug/kg 9812300 43 10-130ND
Anthracene ug/kg 11802300 51 19-130ND
Benzo(a)anthracene ug/kg 13202300 57 17-130ND
Benzo(a)pyrene ug/kg 15702300 68 14-130ND
Benzo(b)fluoranthene ug/kg 15002300 65 11-134ND
Benzo(g,h,i)perylene ug/kg 16502300 72 12-130ND
Benzo(k)fluoranthene ug/kg 15402300 67 15-130ND
Benzoic Acid ug/kg ND M111500310-130ND
Benzyl alcohol ug/kg 19704610 43 20-130ND
bis(2-Chloroethoxy)methane ug/kg 10502300 46 16-130ND
bis(2-Chloroethyl) ether ug/kg 12102300 52 18-130ND
bis(2-Ethylhexyl)phthalate ug/kg 14802300 64 11-130ND
Butylbenzylphthalate ug/kg 13502300 59 10-130ND
Chrysene ug/kg 13302300 58 17-130ND
Di-n-butylphthalate ug/kg 13902300 60 16-130ND
Di-n-octylphthalate ug/kg 14702300 64 16-130ND
Dibenz(a,h)anthracene ug/kg 16102300 70 13-130ND
Dibenzofuran ug/kg 9882300 43 19-130ND
Diethylphthalate ug/kg 13902300 60 22-130ND
Dimethylphthalate ug/kg 12802300 56 23-130ND
Fluoranthene ug/kg 13202300 57 14-130ND
Fluorene ug/kg 10602300 46 19-130ND
Hexachloro-1,3-butadiene ug/kg 8042300 35 12-130ND
Hexachlorobenzene ug/kg 10902300 47 17-130ND
Hexachlorocyclopentadiene ug/kg 8142300 35 10-130ND
Hexachloroethane ug/kg 9652300 42 14-130ND
Indeno(1,2,3-cd)pyrene ug/kg 16302300 71 13-130ND
Isophorone ug/kg 11202300 49 17-130ND
N-Nitroso-di-n-propylamine ug/kg 11202300 48 10-130ND
N-Nitrosodimethylamine ug/kg 1070 v123004716-130ND
N-Nitrosodiphenylamine ug/kg 12102300 53 19-130ND
Naphthalene ug/kg 9922300 43 18-130ND
Nitrobenzene ug/kg 10602300 46 15-130ND
Pentachlorophenol ug/kg 23204610 50 10-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 22 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3900092MATRIX SPIKE SAMPLE:
MSSpike
Result
92646210004
Phenanthrene ug/kg 13002300 56 17-130ND
Phenol ug/kg 11502300 50 15-130ND
Pyrene ug/kg 12002300 52 31-130ND
Pyridine ug/kg 869 v123003810-130ND
2,4,6-Tribromophenol (S)%60 10-131
2-Fluorobiphenyl (S)%35 10-130
2-Fluorophenol (S)%49 10-130
Nitrobenzene-d5 (S)%54 10-130
Phenol-d6 (S)%51 10-130
Terphenyl-d14 (S)%36 10-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646210007
3900093SAMPLE DUPLICATE:
1,2,4-Trichlorobenzene ug/kg ND 30ND
1,2-Dichlorobenzene ug/kg ND 30ND
1,3-Dichlorobenzene ug/kg ND 30ND
1,4-Dichlorobenzene ug/kg ND 30ND
1-Methylnaphthalene ug/kg ND 30ND
2,2'-Oxybis(1-chloropropane)ug/kg ND 30ND
2,4,5-Trichlorophenol ug/kg ND 30ND
2,4,6-Trichlorophenol ug/kg ND 30ND
2,4-Dichlorophenol ug/kg ND 30ND
2,4-Dimethylphenol ug/kg ND 30ND
2,4-Dinitrophenol ug/kg ND 30ND
2,4-Dinitrotoluene ug/kg ND 30ND
2,6-Dinitrotoluene ug/kg ND 30ND
2-Chloronaphthalene ug/kg ND 30ND
2-Chlorophenol ug/kg ND 30ND
2-Methylnaphthalene ug/kg ND 30ND
2-Methylphenol(o-Cresol)ug/kg ND 30ND
2-Nitroaniline ug/kg ND 30ND
2-Nitrophenol ug/kg ND 30ND
3&4-Methylphenol(m&p Cresol)ug/kg ND 30ND
3,3'-Dichlorobenzidine ug/kg ND 30ND
3-Nitroaniline ug/kg ND 30ND
4,6-Dinitro-2-methylphenol ug/kg ND 30ND
4-Bromophenylphenyl ether ug/kg ND 30ND
4-Chloro-3-methylphenol ug/kg ND 30ND
4-Chloroaniline ug/kg ND 30ND
4-Chlorophenylphenyl ether ug/kg ND 30ND
4-Nitroaniline ug/kg ND 30ND
4-Nitrophenol ug/kg ND 30ND
Acenaphthene ug/kg ND 30ND
Acenaphthylene ug/kg ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 23 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646210007
3900093SAMPLE DUPLICATE:
Aniline ug/kg ND 30ND
Anthracene ug/kg ND 30ND
Benzo(a)anthracene ug/kg ND 30ND
Benzo(a)pyrene ug/kg ND 30ND
Benzo(b)fluoranthene ug/kg ND 30ND
Benzo(g,h,i)perylene ug/kg ND 30ND
Benzo(k)fluoranthene ug/kg ND 30ND
Benzoic Acid ug/kg ND 30ND
Benzyl alcohol ug/kg ND 30ND
bis(2-Chloroethoxy)methane ug/kg ND 30ND
bis(2-Chloroethyl) ether ug/kg ND 30ND
bis(2-Ethylhexyl)phthalate ug/kg ND 30ND
Butylbenzylphthalate ug/kg ND 30ND
Chrysene ug/kg ND 30ND
Di-n-butylphthalate ug/kg ND 30ND
Di-n-octylphthalate ug/kg ND 30ND
Dibenz(a,h)anthracene ug/kg ND 30ND
Dibenzofuran ug/kg ND 30ND
Diethylphthalate ug/kg ND 30ND
Dimethylphthalate ug/kg ND 30ND
Fluoranthene ug/kg ND 30ND
Fluorene ug/kg ND 30ND
Hexachloro-1,3-butadiene ug/kg ND 30ND
Hexachlorobenzene ug/kg ND 30ND
Hexachlorocyclopentadiene ug/kg ND 30ND
Hexachloroethane ug/kg ND 30ND
Indeno(1,2,3-cd)pyrene ug/kg ND 30ND
Isophorone ug/kg ND 30ND
N-Nitroso-di-n-propylamine ug/kg ND 30ND
N-Nitrosodimethylamine ug/kg ND v130ND
N-Nitrosodiphenylamine ug/kg ND 30ND
Naphthalene ug/kg ND 30ND
Nitrobenzene ug/kg ND 30ND
Pentachlorophenol ug/kg ND 30ND
Phenanthrene ug/kg ND 30ND
Phenol ug/kg ND 30ND
Pyrene ug/kg ND 30ND
Pyridine ug/kg ND v130ND
2,4,6-Tribromophenol (S)%5351
2-Fluorobiphenyl (S)%3841
2-Fluorophenol (S)%4043
Nitrobenzene-d5 (S)%4854
Phenol-d6 (S)%4345
Terphenyl-d14 (S)%4755
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 24 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749471
MADEP EPH
MADEP EPH
MADEP EPH NC Soil
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92646404001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3896174
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
Aliphatic (C09-C18)mg/kg ND 10.1 N201/17/23 09:4110.1
Aliphatic (C19-C36)mg/kg ND 10.1 N201/17/23 09:4110.1
Aromatic (C11-C22)mg/kg ND 10.1 N201/17/23 09:4110.1
1-Chlorooctadecane (S)%45 40-140 01/17/23 09:41
2-Bromonaphthalene (S)%105 40-140 01/17/23 09:41
2-Fluorobiphenyl (S)%98 40-140 01/17/23 09:41
o-Terphenyl (S)%78 40-140 01/17/23 09:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3896175LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
3896176
Aliphatic (C09-C18)mg/kg ND N210.1 60 40-14052ND 50
Aliphatic (C19-C36)mg/kg 10.6 N213.5 79 40-14072ND 50
Aromatic (C11-C22)mg/kg 20.0 N228.6 70 40-1408724.7 21 50
1-Chlorooctadecane (S)%77 40-14067
2-Bromonaphthalene (S)%58 40-140108
2-Fluorobiphenyl (S)%58 40-140106
o-Terphenyl (S)%56 40-14084
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 25 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
749374
SW-846
SW-846
Dry Weight/Percent Moisture
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92646404001
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646660001
3895599SAMPLE DUPLICATE:
Percent Moisture %20.6 N212520.8
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92646665001
3895614SAMPLE DUPLICATE:
Percent Moisture %7.3 N21257.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 26 of 31
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
1989171
SM 2540 G
SM 2540G
Total Solids 2540 G-2011
Laboratory:Pace National - Mt. Juliet
Associated Lab Samples:92646404001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:R3881606-1
Associated Lab Samples:92646404001
Matrix:Solid
AnalyzedMDL
Total Solids %0.00100 01/16/23 14:30
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
R3881606-2LABORATORY CONTROL SAMPLE:
LCSSpike
Total Solids %50.050.0 100 85.0-115
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
L1575866-17
R3881606-3SAMPLE DUPLICATE:
Total Solids %82.1 0.128 1082.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 27 of 31
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Analysis conducted outside the EPA method holding time.H1
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.N2
Data does not meet all conditions for compliance monitoring due to use of soil jars.u8
The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.v1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 28 of 31
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92646404
R22-64 SHAMROCK SPILL PINEVILL
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92646404001 749471 749721SS-3-2 MADEP EPH MADEP EPH
92646404001 1989609 1989609SS-3-2 MADEPV MADEP VPH
92646404001 750377 750639SS-3-2 EPA 3546 EPA 8270E
92646404001 751446 751609SS-3-2 EPA 5035A/5030B EPA 8260D
92646404001 749374SS-3-2 SW-846
92646404001 1989171 1989171SS-3-2 SM 2540 G SM 2540G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 05:43 PM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 29 of 31
Page 30 of 31
Page 31 of 31