MO-2849_3898_CA_WSW_20220502_LITTLE

 
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

4/7/2022
Geological Resources, Inc. Scott Ball
3502 Hayes Road Monroe, NC, 28110
Ref: Analytical Testing
Lab Report Number: 22-089-0005 Client Project Description: Express Food Mart (2099)
3502 Hayes Rd. Monroe, NC 28110
Dear Scott Ball:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/30/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 22
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202237735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202299012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-089-0005
Page 2 of 22
Report Number:
Sample Summary Table
Client Project Description:
22-089-0005
Express Food Mart (2099)
3502 Hayes Rd.
Monroe, NC 28110
Lab No Client Sample ID Matrix Date Collected Date Received
03/30/2022 11:45Aqueous 97146 WSW-Little 03/30/2022 13:37
03/30/2022 11:30Aqueous 97147 Trip Blank 03/30/2022 13:37
Page 3 of 22
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-089-0005
Report Limit
Project:Express Food Mart (2099)
V 97146WSW-Little
J6.50 04/04/2022 20:166200BAcetoneµg/L 1.80
J0.229 04/04/2022 20:166200BBromodichloromethaneµg/L 0.160
2.57 04/04/2022 20:166200BChloroformµg/L 0.220
J0.433 04/04/2022 20:166200B1,2-Dichloroethane µg/L 0.150
V 97147Trip Blank
J2.40 04/04/2022 18:396200BAcetoneµg/L 1.80
Page 4 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:WSW-Little
97146 Matrix:
3/30/2022 11:45
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<0.00342 µg/L 0.00342 0.02071,2-Dibromoethane 1 04/07/22 15:06 EPA-504.1JC1
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 5 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:WSW-Little
97146 Matrix:
3/30/2022 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
6.50 J µg/L 1.80 10.0Acetone 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500Benzene 1 04/04/22 20:16 V17003JLB
0.229 J µg/L 0.160 0.500Bromodichloromethane 1 04/04/22 20:16 V17003JLB
<1.50 µg/L 1.50 5.00Bromoform 1 04/04/22 20:16 V17003JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 04/04/22 20:16 V17003JLB
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 04/04/22 20:16 V17003JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500
Carbon Tetrachloride 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 04/04/22 20:16 V17003JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 04/04/22 20:16 V17003JLB
2.57 µg/L 0.220 0.500Chloroform 1 04/04/22 20:16 V17003JLB
<0.220 µg/L 0.220 0.500Chloromethane 1 04/04/22 20:16 V17003JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 04/04/22 20:16 V17003JLB
<0.200 µg/L 0.200 0.500
4-Chlorotoluene 1 04/04/22 20:16 V17003JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 04/04/22 20:16 V17003JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 04/04/22 20:16 V17003JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 04/04/22 20:16 V17003JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 04/04/22 20:16 V17003JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 04/04/22 20:16 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 6 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:WSW-Little
97146 Matrix:
3/30/2022 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 04/04/22 20:16 V17003JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 04/04/22 20:16 V17003JLB
0.433 J µg/L 0.150 0.5001,2-Dichloroethane 1 04/04/22 20:16 V17003JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 04/04/22 20:16 V17003JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 04/04/22 20:16 V17003JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 04/04/22 20:16 V17003JLB
<0.150 µg/L 0.150 0.500
trans-1,3-Dichloropropene 1 04/04/22 20:16 V17003JLB
<42.0 µg/L 42.0 200Ethanol 1 04/04/22 20:16 V17003JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 04/04/22 20:16 V17003JLB
<0.059 µg/L 0.059 10.0Ethyl Tertiary Butyl Ether (ETBE)1 04/04/22 20:16 V17003JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 04/04/22 20:16 V17003JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 04/04/22 20:16 V17003JLB
<0.089 µg/L 0.089 0.500
4-Isopropyl toluene 1 04/04/22 20:16 V17003JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 04/04/22 20:16 V17003JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 04/04/22 20:16 V17003JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 04/04/22 20:16 V17003JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 04/04/22 20:16 V17003JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 04/04/22 20:16 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 7 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:WSW-Little
97146 Matrix:
3/30/2022 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<0.220 µg/L 0.220 0.500Styrene 1 04/04/22 20:16 V17003JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 04/04/22 20:16 V17003JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 04/04/22 20:16 V17003JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 04/04/22 20:16 V17003JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 04/04/22 20:16 V17003JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 04/04/22 20:16 V17003JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 04/04/22 20:16 V17003JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 04/04/22 20:16 V17003JLB
<0.220 µg/L 0.220 0.500
Toluene 1 04/04/22 20:16 V17003JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 04/04/22 20:16 V17003JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 04/04/22 20:16 V17003JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 04/04/22 20:16 V17003JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 04/04/22 20:16 V17003JLB
<0.190 µg/L 0.190 0.500
1,2,4-Trimethylbenzene 1 04/04/22 20:16 V17003JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 04/04/22 20:16 V17003JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 04/04/22 20:16 V17003JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 04/04/22 20:16 V17003JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 04/04/22 20:16 V17003JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 04/04/22 20:16 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:WSW-Little
97146 Matrix:
3/30/2022 11:45
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 04/04/22 20:16 V17003
Surrogate: 4-Bromofluorobenzene 105 Limits: 70-130%04/04/22 20:161 JLB V17003
Surrogate: Dibromofluoromethane 98.6 Limits: 70-130%04/04/22 20:161 JLB V17003
Surrogate: 1,2-Dichloroethane - d4 99.2 Limits: 70-130%04/04/22 20:161 JLB V17003
Surrogate: Toluene-d8 104 Limits: 70-130%04/04/22 20:161 JLB V17003
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97147 Matrix:
3/30/2022 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
2.40 J µg/L 1.80 10.0Acetone 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500Benzene 1 04/04/22 18:39 V17003JLB
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 04/04/22 18:39 V17003JLB
<1.50 µg/L 1.50 5.00Bromoform 1 04/04/22 18:39 V17003JLB
<0.280 µg/L 0.280 1.00Bromomethane 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 04/04/22 18:39 V17003JLB
<0.200 µg/L 0.200 0.500sec-Butyl benzene 1 04/04/22 18:39 V17003JLB
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500
Carbon Tetrachloride 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.500Chlorobenzene 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 04/04/22 18:39 V17003JLB
<0.430 µg/L 0.430 1.00Chloroethane 1 04/04/22 18:39 V17003JLB
<0.220 µg/L 0.220 0.500Chloroform 1 04/04/22 18:39 V17003JLB
<0.220 µg/L 0.220 0.500Chloromethane 1 04/04/22 18:39 V17003JLB
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 04/04/22 18:39 V17003JLB
<0.200 µg/L 0.200 0.500
4-Chlorotoluene 1 04/04/22 18:39 V17003JLB
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 04/04/22 18:39 V17003JLB
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 04/04/22 18:39 V17003JLB
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 04/04/22 18:39 V17003JLB
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 04/04/22 18:39 V17003JLB
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 04/04/22 18:39 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97147 Matrix:
3/30/2022 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 04/04/22 18:39 V17003JLB
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 04/04/22 18:39 V17003JLB
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 04/04/22 18:39 V17003JLB
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 04/04/22 18:39 V17003JLB
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500trans-1,2-Dichloroethene 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 04/04/22 18:39 V17003JLB
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 04/04/22 18:39 V17003JLB
<0.150 µg/L 0.150 0.500
trans-1,3-Dichloropropene 1 04/04/22 18:39 V17003JLB
<42.0 µg/L 42.0 200Ethanol 1 04/04/22 18:39 V17003JLB
<0.170 µg/L 0.170 0.500Ethylbenzene 1 04/04/22 18:39 V17003JLB
<0.059 µg/L 0.059 10.0Ethyl Tertiary Butyl Ether (ETBE)1 04/04/22 18:39 V17003JLB
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 04/04/22 18:39 V17003JLB
<0.380 µg/L 0.380 1.002-Hexanone 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 04/04/22 18:39 V17003JLB
<0.089 µg/L 0.089 0.500
4-Isopropyl toluene 1 04/04/22 18:39 V17003JLB
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 04/04/22 18:39 V17003JLB
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 04/04/22 18:39 V17003JLB
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 04/04/22 18:39 V17003JLB
<0.330 µg/L 0.330 2.00Methylene Chloride 1 04/04/22 18:39 V17003JLB
<0.470 µg/L 0.470 1.00Naphthalene 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 04/04/22 18:39 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97147 Matrix:
3/30/2022 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<0.220 µg/L 0.220 0.500Styrene 1 04/04/22 18:39 V17003JLB
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 04/04/22 18:39 V17003JLB
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 04/04/22 18:39 V17003JLB
<1.90 µg/L 1.90 10.0tert-Amyl Alcohol (TAA)1 04/04/22 18:39 V17003JLB
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 04/04/22 18:39 V17003JLB
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 04/04/22 18:39 V17003JLB
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 04/04/22 18:39 V17003JLB
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 04/04/22 18:39 V17003JLB
<0.220 µg/L 0.220 0.500
Toluene 1 04/04/22 18:39 V17003JLB
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 04/04/22 18:39 V17003JLB
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 04/04/22 18:39 V17003JLB
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500Trichloroethene 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 04/04/22 18:39 V17003JLB
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 04/04/22 18:39 V17003JLB
<0.190 µg/L 0.190 0.500
1,2,4-Trimethylbenzene 1 04/04/22 18:39 V17003JLB
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 04/04/22 18:39 V17003JLB
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 04/04/22 18:39 V17003JLB
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 04/04/22 18:39 V17003JLB
<0.210 µg/L 0.210 0.500o-Xylene 1 04/04/22 18:39 V17003JLB
<0.420 µg/L 0.420 1.00m,p-Xylene 1 04/04/22 18:39 V17003JLB
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 22
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28110
22-089-0005
00087
Geological Resources, Inc.
3502 Hayes Road
Scott Ball
Monroe Monroe, NC 28110
Danyale Love
Project Manager
3502 Hayes Rd.Received : 03/30/2022
Express Food Mart (2099)
Report Date : 04/07/2022
Sample ID :
Lab No :
Sampled:Trip Blank
97147 Matrix:
3/30/2022 11:30
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V17002 04/04/22 09:00
<0.21 µg/L 0.210 0.500Xylene (Total)1 04/04/22 18:39 V17003
Surrogate: 4-Bromofluorobenzene 103 Limits: 70-130%04/04/22 18:391 JLB V17003
Surrogate: Dibromofluoromethane 99.6 Limits: 70-130%04/04/22 18:391 JLB V17003
Surrogate: 1,2-Dichloroethane - d4 103 Limits: 70-130%04/04/22 18:391 JLB V17003
Surrogate: Toluene-d8 103 Limits: 70-130%04/04/22 18:391 JLB V17003
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
Associated Lab Samples: 97146, 97147
LRB-V17002 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/04/22 12:1110.01.80<1.80µg/LAcetone
04/04/22 12:110.5000.180<0.180µg/LBenzene
04/04/22 12:110.5000.160<0.160µg/LBromodichloromethane
04/04/22 12:115.001.50<1.50µg/LBromoform
04/04/22 12:111.000.280<0.280µg/LBromomethane
04/04/22 12:110.5000.180<0.180µg/Ln-Butylbenzene
04/04/22 12:110.5000.200<0.200µg/Lsec-Butyl benzene
04/04/22 12:112.000.920<0.920µg/Ltert-Butyl benzene
04/04/22 12:110.5000.180<0.180µg/LCarbon Tetrachloride
04/04/22 12:110.5000.190<0.190µg/LChlorobenzene
04/04/22 12:110.5000.190<0.190µg/LChlorodibromomethane
04/04/22 12:111.000.430<0.430µg/LChloroethane
04/04/22 12:110.5000.220<0.220µg/LChloroform
04/04/22 12:110.5000.220<0.220µg/LChloromethane
04/04/22 12:110.5000.200<0.200µg/L2-Chlorotoluene
04/04/22 12:110.5000.200<0.200µg/L4-Chlorotoluene
04/04/22 12:110.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
04/04/22 12:112.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
04/04/22 12:110.5000.200<0.200µg/L1,2-Dibromoethane
04/04/22 12:110.5000.220<0.220µg/L1,2-Dichlorobenzene
04/04/22 12:110.5000.190<0.190µg/L1,3-Dichlorobenzene
04/04/22 12:110.5000.210<0.210µg/L1,4-Dichlorobenzene
04/04/22 12:115.001.20<1.20µg/LDichlorodifluoromethane
04/04/22 12:110.5000.240<0.240µg/L1,1-Dichloroethane
04/04/22 12:110.5000.150<0.150µg/L1,2-Dichloroethane
04/04/22 12:110.5000.150<0.150µg/L1,1-Dichloroethene
04/04/22 12:110.5000.200<0.200µg/Lcis-1,2-Dichloroethene
Page 1 of 7Date:04/07/2022 05:13 PM
Page 14 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
Associated Lab Samples: 97146, 97147
LRB-V17002 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/04/22 12:110.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
04/04/22 12:110.5000.190<0.190µg/L1,2-Dichloropropane
04/04/22 12:110.5000.210<0.210µg/Lcis-1,3-Dichloropropene
04/04/22 12:110.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
04/04/22 12:1120042.0<42.0µg/LEthanol
04/04/22 12:110.5000.170<0.170µg/LEthylbenzene
04/04/22 12:1110.00.059<0.059µg/LEthyl Tertiary Butyl Ether (ETBE)
04/04/22 12:113.000.350<0.350µg/LHexachlorobutadiene
04/04/22 12:111.000.380<0.380µg/L2-Hexanone
04/04/22 12:110.5000.180<0.180µg/LIsopropylbenzene
04/04/22 12:110.5000.089<0.089µg/L4-Isopropyl toluene
04/04/22 12:115.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
04/04/22 12:111.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
04/04/22 12:111.000.078<0.078µg/L4-Methyl-2-Pentanone
04/04/22 12:112.000.330<0.330µg/LMethylene Chloride
04/04/22 12:111.000.470<0.470µg/LNaphthalene
04/04/22 12:110.5000.190<0.190µg/Ln-Propylbenzene
04/04/22 12:110.5000.220<0.220µg/LStyrene
04/04/22 12:1110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
04/04/22 12:1110.00.350<0.350µg/Ltert-Butyl formate (TBF)
04/04/22 12:1110.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
04/04/22 12:1110.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
04/04/22 12:110.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
04/04/22 12:110.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
04/04/22 12:110.5000.220<0.220µg/LTetrachloroethene
04/04/22 12:110.5000.220<0.220µg/LToluene
04/04/22 12:110.5000.310<0.310µg/L1,2,4-Trichlorobenzene
Page 2 of 7Date:04/07/2022 05:13 PM
Page 15 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
Associated Lab Samples: 97146, 97147
LRB-V17002 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
04/04/22 12:110.5000.160<0.160µg/L1,1,1-Trichloroethane
04/04/22 12:110.5000.096<0.096µg/L1,1,2-Trichloroethane
04/04/22 12:110.5000.180<0.180µg/LTrichloroethene
04/04/22 12:110.5000.180<0.180µg/LTrichlorofluoromethane
04/04/22 12:110.5000.270<0.270µg/L1,2,3-Trichloropropane
04/04/22 12:110.5000.190<0.190µg/L1,2,4-Trimethylbenzene
04/04/22 12:110.5000.180<0.180µg/L1,3,5-Trimethylbenzene
04/04/22 12:115.001.00<1.00µg/LVinyl Acetate
04/04/22 12:110.5000.170<0.170µg/LVinyl Chloride
04/04/22 12:110.5000.210<0.210µg/Lo-Xylene
04/04/22 12:111.000.420<0.420µg/Lm,p-Xylene
04/04/22 12:114-Bromofluorobenzene (S)105 70-130
04/04/22 12:11Dibromofluoromethane (S)100 70-130
04/04/22 12:111,2-Dichloroethane - d4 (S)101 70-130
04/04/22 12:11Toluene-d8 (S)102 70-130
LCS-V17002 LCSD-V17002Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
50.5 12612851.240.0µg/LAcetone 40-160 1.3 20.0
20.9 10510621.120.0µg/LBenzene 70-130 0.9 20.0
20.3 10210621.120.0µg/LBromodichloromethane 70-130 3.8 20.0
21.1 10610821.520.0µg/LBromoform 70-130 1.8 20.0
24.4 12211222.420.0µg/LBromomethane 60-140 8.5 20.0
22.8 11411222.420.0µg/Ln-Butylbenzene 70-130 1.7 20.0
22.6 11311222.420.0µg/Lsec-Butyl benzene 70-130 0.8 20.0
Page 3 of 7Date:04/07/2022 05:13 PM
Page 16 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
LCS-V17002 LCSD-V17002Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.3 11211022.020.0µg/Ltert-Butyl benzene 70-130 1.3 20.0
20.8 10410721.320.0µg/LCarbon Tetrachloride 70-130 2.3 20.0
21.7 10910721.320.0µg/LChlorobenzene 70-130 1.8 20.0
21.1 10611022.020.0µg/LChlorodibromomethane 70-130 4.1 20.0
19.7 98.596.519.320.0µg/LChloroethane 60-140 2.0 20.0
20.6 10310420.720.0µg/LChloroform 70-130 0.4 20.0
21.8 10911022.020.0µg/LChloromethane 60-140 0.9 20.0
20.1 10111021.920.0µg/L2-Chlorotoluene 70-130 8.5 20.0
22.7 11411322.520.0µg/L4-Chlorotoluene 70-130 0.8 20.0
22.4 11211523.020.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.6 20.0
22.0 11011723.420.0µg/L1,2-Dibromo-3-Chloropropane 70-130 6.1 20.0
21.5 10811122.120.0µg/L1,2-Dibromoethane 70-130 2.7 20.0
22.1 11111022.020.0µg/L1,2-Dichlorobenzene 70-130 0.4 20.0
22.5 11311022.020.0µg/L1,3-Dichlorobenzene 70-130 2.2 20.0
22.4 11211222.320.0µg/L1,4-Dichlorobenzene 70-130 0.4 20.0
24.3 12212524.920.0µg/LDichlorodifluoromethane 60-140 2.4 20.0
21.0 10510721.420.0µg/L1,1-Dichloroethane 70-130 1.8 20.0
21.0 10510921.820.0µg/L1,2-Dichloroethane 70-130 3.7 20.0
20.5 10310921.720.0µg/L1,1-Dichloroethene 70-130 5.6 20.0
21.5 10810821.520.0µg/Lcis-1,2-Dichloroethene 70-130 0.0 20.0
20.7 10410821.520.0µg/Ltrans-1,2-Dichloroethene 70-130 3.7 20.0
20.9 10510721.320.0µg/L1,2-Dichloropropane 70-130 1.8 20.0
21.4 10710821.520.0µg/Lcis-1,3-Dichloropropene 70-130 0.4 20.0
21.4 10710821.520.0µg/Ltrans-1,3-Dichloropropene 70-130 0.4 20.0
539 108113567500µg/LEthanol 60-140 5.0 20.0
21.1 10610621.120.0µg/LEthylbenzene 70-130 0.0 20.0
Page 4 of 7Date:04/07/2022 05:13 PM
Page 17 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
LCS-V17002 LCSD-V17002Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
46.4 11611947.740.0µg/LEthyl Tertiary Butyl Ether (ETBE)70-130 2.7 20.0
23.3 11711322.620.0µg/LHexachlorobutadiene 70-130 3.0 20.0
22.4 11211523.020.0µg/L2-Hexanone 60-140 2.6 20.0
22.7 11411122.120.0µg/LIsopropylbenzene 70-130 2.6 20.0
23.1 11611322.520.0µg/L4-Isopropyl toluene 70-130 2.6 20.0
23.0 11511923.820.0µg/LMethyl Ethyl Ketone (MEK)60-140 3.4 20.0
21.6 10811322.620.0µg/LMethyl tert-butyl ether (MTBE)70-130 4.5 20.0
19.1 95.510621.120.0µg/L4-Methyl-2-Pentanone 60-140 9.9 20.0
21.6 10811122.220.0µg/LMethylene Chloride 70-130 2.7 20.0
21.7 10911823.620.0µg/LNaphthalene 70-130 8.3 20.0
23.0 11511222.320.0µg/Ln-Propylbenzene 70-130 3.0 20.0
21.7 10911021.920.0µg/LStyrene 70-130 0.9 20.0
41.2 10399.239.740.0µg/Ltert-Butyl Alcohol (TBA)60-140 3.7 20.0
43.1 10812148.340.0µg/Ltert-Butyl formate (TBF)60-140 11.3 20.0
23.4 11711322.520.0µg/Ltert-Amyl Alcohol (TAA)60-140 3.9 20.0
44.3 11111546.140.0µg/Ltert-Amyl Methyl Ether (TAME)60-140 3.9 20.0
21.2 10610721.320.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.4 20.0
21.4 10711222.320.0µg/L1,1,2,2-Tetrachloroethane 70-130 4.1 20.0
20.7 10410621.120.0µg/LTetrachloroethene 70-130 1.9 20.0
20.4 10210420.820.0µg/LToluene 70-130 1.9 20.0
22.7 11411723.320.0µg/L1,2,4-Trichlorobenzene 70-130 2.6 20.0
20.4 10210420.820.0µg/L1,1,1-Trichloroethane 70-130 1.9 20.0
20.3 10210821.520.0µg/L1,1,2-Trichloroethane 70-130 5.7 20.0
20.5 10310520.920.0µg/LTrichloroethene 70-130 1.9 20.0
21.3 10710621.220.0µg/LTrichlorofluoromethane 60-140 0.4 20.0
21.9 11011623.220.0µg/L1,2,3-Trichloropropane 70-130 5.7 20.0
Page 5 of 7Date:04/07/2022 05:13 PM
Page 18 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V17003QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V17002
LCS-V17002 LCSD-V17002Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.7 11411222.320.0µg/L1,2,4-Trimethylbenzene 70-130 1.7 20.0
22.7 11411122.220.0µg/L1,3,5-Trimethylbenzene 70-130 2.2 20.0
21.9 11011122.220.0µg/LVinyl Acetate 60-140 1.3 20.0
21.9 11011022.020.0µg/LVinyl Chloride 60-140 0.4 20.0
21.5 10810821.620.0µg/Lo-Xylene 70-130 0.4 20.0
45.4 11411445.540.0µg/Lm,p-Xylene 70-130 0.2 20.0
1031034-Bromofluorobenzene (S)70-130
99.2102Dibromofluoromethane (S)70-130
1011061,2-Dichloroethane - d4 (S)70-130
104103Toluene-d8 (S)70-130
Page 6 of 7Date:04/07/2022 05:13 PM
Page 19 of 22
Quality Control Data
22-089-0005Report No:
Project Description:
Client ID:Geological Resources, Inc.
Express Food Mart (2099)
QC Prep Batch Method:
EDB and DBCP by Microextraction GC/ECD
EPA-504.1
V17135QC Analytical Batch(es):
Analysis Method:
Analysis Description:
EPA-504.1(PREP)
QC Prep:V17121
Associated Lab Samples: 97146
LRB-V17121 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
04/07/22 14:050.02000.00330<0.00330µg/L1,2-Dibromoethane
LCS-V17121 LCSD-V17121Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
0.263 10589.20.2230.250µg/L1,2-Dibromoethane 70-130 16.4 20.0
V 97599-DUP-V17121Duplicate
Max RPD
Parameter
AnalyzedRPDDUP
Result
Result
Units
20.0 04/07/22 16:060.0<0.0205< 0.0205µg/L1,2-Dibromoethane
V 97146-MS-V17121Matrix Spike
MS Result
Parameter
Max
RPD
MS
%Rec
MSD
Result
MSD
Spike
Conc.
MS Spike
Conc.ResultUnits
%Rec
Limits
0.261 1000.260< 0.00343µg/L1,2-Dibromoethane 70-130
Page 7 of 7Date:04/07/2022 05:13 PM
Page 20 of 22
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-089-0005
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 2.2C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Sarah J. Locklear Date & Time:03/30/2022 14:01:25
Special precautions or instructions included?
Comments:
Page 21 of 22
Page 22 of 22