FA-29367_48524_CA_MRP_20221222

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]

December 22, 2022

Ms. Liz Price
NCDEQ-UST Section
Wilmington Regional Office
127 Cardinal Drive Extension
Wilmington, NC 28405

Re: Ground water Monitoring Report
December 2022
5110 Market Cafe
5110 NC Highway 96
Selma, Johnston County
North Carolina
Facility ID Number: 0-00-0000014259
Incident Number: 48524
GRI Project Number: 6008

Dear Ms. Price,

Please find enclosed the referenced report, for the abovementioned site.
If you have any questions, please contact Scott Driscoll at 704-845-4010.

Sincerely,
Geological Resources, Inc.

Leslie Maxtone-Graham
Administrative Assistant

Enclosure

Cc: Mr. Vivek B. Patel; Jai Umiya LLC, file

3502 Hayes Road • Monroe, North Carolina 28110
113 West Firetower Road, Suite G • Winterville, North Carolina 28590
Phone [phone] • [phone] • Fax [phone]
Engineering Certification: C-2727 • Geology Certification: C-127
Ground Water Monitoring Report
December 2022
5110 Market & Cafe
5110 NC Highway 96
Selma, Johnston County
North Carolina
Facility ID Number: 0-00-0000014259
Incident Number: 48524
GRI Project Number: 6008

Prepared for:

Mr. Vivek B. Patel
Jai Umiya, LLC
304 Trolley Car Way
Morrisville, North Carolina 27560

December 22, 2022

Scott Driscoll
Project Manager
Xavier Farmer
Staff Scientist

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
i
EXECUTIVE SUMMARY

5110 Market & Cafe is located at 5110 NC Highway 96 in Selma, Johnston County, North Carolina. The
site is currently owned and operated by Jai Umiya, LLC as a convenience store and grill which stores and
resells petroleum fuels from USTs. Currently, five underground storage tanks are operated at the site to
sell unleaded gasoline, diesel fuel and dyed off-road diesel fuel. The site and surrounding area are a
mixture of small business and residential properties. The site contains one building and is primarily capped
with asphalt, concrete and grass. The overall topography at the site relatively flat.

One previous incident (NCDEQ No. 7058) was reported at the site in September 1991, and the incident
was closed under the name Stop & Shop with an NFA on March 14, 2006. The current incident (NCDEQ
48524) was a result of a Site Check investigation requested by NCDEQ in response to a failed UST
compliance inspection. A Phase II LSA report was issued October 11, 2022, which detailed the results of
additional soil and ground water sampling at the site. During LSA activities, twenty-eight water supply
wells were identified within 1,500 feet of the site. Based on the LSA information, the site was classified
as high risk and an additional sampling event was requested by NCDEQ.

On November 29, 2022, five Type II monitoring wells (GMW-1 through GMW-4 and EMW-1) were gauged,
purged and/or sampled in accordance with the NCDEQ guidelines. The onsite inactive water supply well
(WSW-28) was also sampled.

Concentrations of individual petroleum constituents were reported above the MACs in four of the five
ground water monitoring wells at the site. No concentrations of detected analytes were reported above
the GCLs.

Based on this information, the risk classification for the site should remain high due to the the proximity
of water supply wells identified during assessment activities in combination with the MAC exceedances.
Further assessment should be warranted for this site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
ii
SITE INFORMATION
1. Site Identification
 5110 Market & Cafe (Facility ID 0-00-0000014259)
 Incident Number 48524 – High Risk (H250D)
 Location of Source Area: 5110 NC Highway 96
Selma, NC 28677
Johnston County
35.605178°N, 78.295568°W (Topographical Map)

2. Information about Contacts Associated with the Leaking UST System

UST Owner
Jai Umiya, LLC
5110 NC Hwy 96 North
Selma, NC 27576-6187
Email Unknown
919-965-3665

UST Operator
Vivek B. Patel
5110 NC Hwy 96 North
Selma, NC 27576-6187
Email Unknown
919-965-3665

Property Owner
Jai Umiya, LLC
5110 NC Hwy 96 North
Selma, NC 27576-6187
Email Unknown
919-965-3665

Property Occupant
5110 Market Cafe
5110 NC Hwy 96 North
Selma, NC 27576-6187
Email Unknown
919-965-3665

Consultant/Contractor
Geological Resources, Inc.
3502 Hayes Road
Monroe, NC 28110
[e-mail]
704-845-4010

Analytical Laboratory
Waypoint Analytical, LLC
449 Springbrook Road
Charlotte, NC 28217
NC Certification No. 37735 and 402
704-529-6364

3. Information about Release
 Release was discovered on September 9, 2022
 An unknown amount of product was released from beneath the ULSD and off-road diesel fuel
islands and potentially the gasoline USTs.
 One 12,000-gallon compartmentalized (8,000/4,000-gallon split) gasoline, one 4,000-gallon
gasoline, and one 4,000-gallon compartmentalized (2,000-gallon split) diesel fuel USTs containing
diesel fuel and dyed off-road diesel fuel are currently in use at the site.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
iii
ACRONYMS
ACM: Asbestos Containing Materials
AFVR: Aggressive Fluid-Vapor Recovery
ARR: Acknowledgement of Report Receipt
AS: Air Sparging
AST: Aboveground Storage Tank
ASTM: American Society for Testing and
Materials
BGS: Below Ground Surface
CAP: Corrective Action Plan
CFR: Code of Federal Regulations
CSA: Comprehensive Site Assessment
DPE: Dual Phase Extraction
DRO: Total Petroleum Hydrocarbons Diesel
Range Organics
DWM: Division of Waste Management
DWR: Department of Water Resources
EPA: Environmental Protection Agency
EPH: Extractible Petroleum Hydrocarbons
ESA: Environmental Site Assessment
GCL: Gross Contamination Level
GRI: Geological Resources, Inc.
GRO: Total Petroleum Hydrocarbons
Gasoline Range Organics
HERR: HAZMAT Emergency Response and
Remediation, Inc.
LSA: Limited Site Assessment
MAC: Maximum Allowable Concentration as
specified in T15A NCAC 2L.0202
MADEP: Massachusetts Department of
Environmental Protection
MCC: Maximum Contaminant Concentrations
MMPE: Mobile Multi-Phase Extraction
NAPL: Non-Aqueous Phase Liquid, “Free
Product”
NCDEQ: North Carolina Department of
Environmental Quality
NCDOT: North Carolina Department of
Transportation
NFA: Notice of No Further Action
NORR: Notice of Regulatory Requirements
NOV: Notice of Violation
NPDES: National Pollutant Discharge
Elimination System
NRP: Notice of Residual Petroleum
O&M: Operation and Maintenance
PAHs: Polynuclear Aromatic Hydrocarbons
PCA: Pre-Construction Assessment
RAL: Regulatory Action Level
SCLs: Soil Cleanup Level
SPCC: Spill Prevention Control and
Countermeasures
SVE: Soil Vapor Extraction
SVOCs: Semi-Volatile Organic Compounds
SWPPP: Stormwater Pollution Prevention Plan
TCLP: Toxicity Characteristic Leaching
Procedure (EPA Method SW-846 1311)
TOC: Top of Casing
TPH: Total Petroleum Hydrocarbons
ULSD: Ultra-Low Sulfur Diesel
USGS: United States Geological Survey
UST: Underground Storage Tank
UVF: Ultraviolet Fluorescence
VOCs: Volatile Organic Compounds
VPH: Volatile Petroleum Hydrocarbons

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
TABLE OF CONTENTS
EXECUTIVE SUMMARY ....................................................................................................................... i
SITE INFORMATION ............................................................................................................................ ii
ACRONYMS ....................................................................................................................................... iii
1.0 SITE HISTORY AND CHARACTERIZATION ...................................................................................1
2.0 CURRENT SITE INFORMATION/ COMPARISON TO HISTORICAL ASSESSMENT INFORMATION .....2
3.0 FREE PRODUCT REMOVAL ........................................................................................................3
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS ................................ 43
5.0 CONCLUSIONS .........................................................................................................................4
6.0 LIMITATIONS ......................................................................................................................... 45
7.0 STATEMENTS AND CERTIFICATION ...........................................................................................5

FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: Site Vicinity Map
Figure 4: Water Table Surface Map
Figure 5: Ground Water Quality Map

TABLES
Table 1: UST Owner and Operator Information
Table 2: UST System Information
Table 3: Well/Receptor Information
Table 4: Adjacent Property Owner Information
Table 5: Well Construction and Gauging Information
Table 6: Summary of Ground Water Sample Analytical Results

APPENDICES
Appendix A: NCDEQ Correspondence
Appendix B: Laboratory Report – Ground Water Samples

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
1
1.0 SITE HISTORY AND CHARACTERIZATION
GRI presents the results of the November 2022 ground water sampling event at the 5110 Market & Cafe
site; located at 5110 NC Highway 96 in Selma, Johnston County, North Carolina (Figure 1). These activities
were conducted in accordance with GRI Proposal No. 22-815, which was submitted to NCDEQ on
November 11, 2022, and was approved as Task Authorization No. 48524-2 on November 15, 2022. NCDEQ
correspondence has been included as Appendix A.

The site is currently owned by Jai Umiya, LLC and is operated by Vivek B. Patel as a convenience store and
grill which stores and sells petroleum fuels for resale. Currently, one 12,000-gallon compartmentalized
gasoline (8,000/4,000-gallon split), one 4,000-gallon gasoline and one 4,000-gallon compartmentalized
diesel fuel USTs (2,000-gallon split) are in service at the site. The NCDEQ Registered Tank Report for the
site is shown below:

UST owner/operator information and UST system information are included as Tables 1 and 2, respectively.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
2
The site and surrounding area are a mixture of small business and residential properties. The site contains
one building and is primarily capped with asphalt, concrete, and grass. The overall topography at the site
relatively flat.

One previous incident (NCDEQ No. 7058) was reported at the site in September 1991. A diesel fuel UST
was reported to have taken on water due to a hole in a suction line. The tank was removed on October
25, 1991, and soil samples were collected during the removal. The TPH concentrations reported in the
sample(s) were less than the action levels, and the incident was closed under the name Stop & Shop with
an NFA on March 14, 2006.

The current incident (NCDEQ 48524) was a result of a Site Check investigation requested by NCDEQ in
response to a failed UST compliance inspection. The site check was conducted at the site in June 2022
and confirmed a release of petroleum to ground water was confirmed. An LSA was required to be
performed by the UST owner.

A Phase II LSA report was issued October 11, 2022, which detailed the results of additional soil and ground
water sampling at the site. During LSA activities, twenty-eight water supply wells were identified within
1,500 feet of the site. One inactive well (WSW-28) is located onsite and one water supply well (WSW-14)
is located within 250 feet of the source area. Fourteen potable wells are located between 250 feet and
1,000 feet of the site. Municipal water is available to the site and surrounding properties. There is one
low-lying area and pond identified approximately 325 feet north of the site. A site vicinity map is included
as Figure 2 which depicts surrounding properties and locations of the water supply wells. Receptor
information gathered during LSA activities is provided in Table 3. Adjacent property owner information
is presented in Table 4.

Five Type II monitoring wells (GMW-1 through GMW-4, and EMW-1) have been installed at the site during
previous ground water assessment activities. A Site Map showing the locations of the monitoring wells
and the structures on-site has been included as Figure 3.

Based on this information, the site was classified as high risk and an additional sampling event was
requested by NCDEQ.
2.0 CURRENT SITE INFORMATION/ COMPARISON TO HISTORICAL ASSESSMENT INFORMATION
On November 29, 2022, five Type II monitoring wells (GMW-1 through GMW-4 and EMW-1) were gauged,
purged and/or sampled in accordance with the NCDEQ guidelines. The onsite inactive water supply well
(WSW-28) was also sampled. Free product was not observed in any of the monitoring wells. Depths to
ground water in the Type II monitoring wells ranged from 3.35 feet to 4.24 feet below the tops of well
casings. Ground water elevations in the Type II monitoring wells ranged from 95.42 feet to 96.30 feet.
Ground water flow was generally to the north/northeast with a horizontal gradient of less than 0.01 feet
per foot. Well construction and gauging information is presented in Table 5. A Water Table Surface Map

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
3
based on the Type II monitoring wells is included as Figure 4. A summary of the current ground water
gauging data is shown below:
Well ID
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free
Product
Thickness
(ft.)
Ground
Water
Elevation
(ft.)
GWM-1 5 - 15 15 100.00 4.24 --- 95.76
EMW-1 3 - 15 15 99.87 4.14 --- 95.73
GMW-2 5 - 15 15 100.46 4.16 --- 96.30
GMW-3 5 - 15 15 100.05 4.09 --- 95.96
GMW-4 5 - 15 15 98.77 3.35 --- 95.42

Ground water samples collected from the five monitoring wells and inactive water supply well were
submitted for laboratory analyses of VOCs plus 5 oxygenates using EPA Method 6200B and VPH using the
MADEP Method. Concentrations of benzene, MTBE, naphthalene, tert-Amyl alcohol, tert-Butyl alcohol,
isopropylbenzene, C5-C8 aliphatics, C9-12 aliphatics and/or C9-C10 aromatics that exceeded the MACs
were reported in the ground water samples collected from GMW-1 through GMW-3 and EMW-1. No
concentrations of detected analytes were reported above the GCLs. A summary of the analytical results
for ground water samples collected on November 28, 2022, is presented in Table 6. A Ground Water
Quality Map based on the October 2022 data is included as Figure 5. The complete report of laboratory
analyses of the ground water samples collected from the monitoring wells is included as Appendix B. An
abbreviated summary of the current ground water analytical data is shown below:

Contaminant of
Concern  Benzene Toluene Ethylbenzene Xylenes MTBE Naphthalene Well ID
MACs (μg/l) 1 600 600 500 20 6
GCL (μg/l) 5,000 260,000 80,000 50,000 20,000 6,000
Trip Blank <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
GMW-1 549 1.38 5.44 4.27 34.8 87.4
GMW-2 30.6 0.513 8.64 2.48 J <0.140 2.23
GMW-3 430 5.72 104 13.9 13.8 19.5
GMW-4 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470
EMW-1 0.850 <0.220 0.427 J <0.210 22.8 <0.470
WSW-28 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470

According to the 1985 Geologic Map of North Carolina, the site is situated in the Coastal Plain
Physiographic Province of North Carolina. The surficial aquifer is underlain by terrace deposits and upland
sediment deposits, which can be 30 to 40 feet thick in the area. The surficial aquifer is underlain by
bedrock. The water table has a seasonal high depth to water of approximately two to four feet BGS.
3.0 FREE PRODUCT REMOVAL
No free product has been detected in any of the onsite wells.

___________________________________________________________________________________________
Prepared by: Geological Resources, Inc. Ground Water Monitoring Report
Prepared on: December 22, 2022 5110 Market & Cafe
Project Manager: Scott Driscoll GRI Project No. 6008
4
4.0 NATURAL ATTENUATION / NATURAL SOURCE ZONE DEPLETION STATUS
No natural attenuation monitoring plan is currently in place at the site.
5.0 CONCLUSIONS
 On November 28, 2022, five Type II monitoring wells were gauged, purged and/or sampled. The
onsite inactive water supply well (WSW-28) was also sampled. Free product was not found in any
of the wells onsite. Ground water flow was generally to the north/northeast with a horizontal
gradient of less than 0.01 feet per foot.
 Concentrations of benzene, MTBE, naphthalene, tert-Amyl alcohol, tert-Butyl alcohol,
isopropylbenzene, C5-C8 aliphatics, C9-12 aliphatics and/or C9-C10 aromatics that exceeded the
MACs were reported in the ground water samples collected from GMW-1, GMW-2, GMW-3 and
EMW-1. No concentrations of detected analytes were reported above the GCLs.
 A receptor survey was conducted within 1,500 feet of the site in August 2022 during LSA activities.
Public water is available to the subject site and surrounding properties through the Johnston
County East Public Utilities (JCEPU); PWS ID NC4051018. Twenty-eight water supply wells were
identified within 1,500 feet of the site. Two water supply wells, one confirmed to be inactive,
were identified within a 250-foot radius of the site. A total of fourteen potable water supply wells
were located within 1,000 feet of the site. The site is not located in a designated wellhead
protection area. One unidentified pond is located 325 feet northeast of the site.
 It is noted here that many water meters were witnessed at properties where water wells were
identified. JCEPU, stating privacy concerns, would not allow GRI to cross reference address and
ownership information to determine if any of the properties were connected to their water
system. One inactive well (WSW-28), which was sampled as part of this investigation is located
on the site. It is verified that the well is inactive, and the site is connected to the public water
system.
 Based on this information, the risk classification for the site should remain high due to the
proximity of water supply wells identified during assessment activities in combination with the
MAC exceedances. Further assessment should be warranted for this site.
6.0 LIMITATIONS
This report has been prepared for the exclusive use of Jai Umiya, LLC for specific application to the
referenced site in Johnston County, North Carolina. The assessment was conducted based on the scope
of work and level of effort desired by the NCDEQ and with resources adequate only for that scope of work.
Our findings have been developed in accordance with generally accepted standards of environmental
practices in the State of North Carolina, available information, and our professional judgment. No other
warranty is expressed or implied.

The data that are presented in this report are indicative of conditions that existed at the precise locations
sampled and at the time the samples were collected. In addition, the data obtained from samples would
be interpreted as being meaningful with respect to parameters indicated in the laboratory report. No
additional information can logically be inferred from these data.

FIGURES
SITE LOCATION
Figure 1
Site Location
5110 Market & Cafe
5110 NC Highway 96
Selma, North Carolina
Johnston County
Incident No. N/A
GRI Project No. 6008
500 M
2000 FT
Date: 04/10/2022 Location: 35.605178°N -78.295568°W
D
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d
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"J
"J
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"J
"J
"J
"J SITE
260700-95-2475
261701-06-5377
261700-04-1833
261701-05-4194
260700-95-0890
260700-95-5604
260700-84-5907 261701-05-3210260700-95-4853
260700-96-1528
260700-96-2382
260700-86-9678
260700-97-0146 260700-97-2131
260700-96-3782
260700-96-2809
260700-94-4409
260700-96-3541
260700-86-3102
260700-86-4215
260700-95-5051260700-86-7812
260700-97-4078
260700-95-6744260700-96-4932
260700-94-3810 260700-95-8757260700-95-9679260700-95-1278
260700-95-1158
WSW-9
WSW-8
WSW-7
WSW-6WSW-5
WSW-4
WSW-3
WSW-2
WSW-1
WSW-28
WSW-27
WSW-26
WSW-25
WSW-24
WSW-23
WSW-22
WSW-21
WSW-20
WSW-19
WSW-18
WSW-17
WSW-16 WSW-15
WSW-14
WSW-13
WSW-12
WSW-11
WSW-10
LITTLE DIVINE RD
NC HWY 96 NHOWARD RDSULL IVAN RDCEDAR LNLIVE OAK CHURCH RDSOUTH TRLFIGURE 2A: SITE VICINITY MAP5110 MARKET & CAFE5110 NC HIGHWAY 96SELMA, JOHNSTON COUNTYNORTH CAROLINAINCIDENT NO. 48524GRI NO. 6008
PREPARED BY:GEOLOGICAL RESOURCES, INC.AUGUST 27, 20221,500-FOOT RADIUS
1,000-FOOT RADIUS
250-FOOT RADIUS
500-FOOT RADIUS
³
0 300150Feet
1 inch = 300 feet
LEGEND
"J Water Supply Well
Street Centerlines
Hydrology
Well Owners and Adjacent Properties
Johnston County NC parcels_2020
X
X
XXXXXXXXXX
X
X
XXXXXXXXXX
X
X
XXXXXXXXXX
X
X
XXXXXXXXXX

TABLES
UST ID Number A1/A2B, A2, A3/A3B Facility ID Number
Owner or Operator?
Owner
UST ID Number A1/A2B, A2, A3/A3B Facility ID Number
Owner or Operator?
Owner
UST ID Number A1/A2B, A2, A3/A3B Facility ID Number
Owner or Operator?
Owner
UST ID Number A1/A2B, A2, A3/A3B Facility ID Number
Owner or Operator?
Owner
UST ID Number 1-5 Facility ID Number
Owner or Operator?
Owner
UST ID Number 6 Facility ID Number
Owner or Operator?
Owner
UST ID Number 1-6 Facility ID Number
Owner or Operator?
Owner
Address Telephone Number
Unknown Unknown
00-0-0000014259
Name of Owner Dates of Ownership
Unknown 05/08/1981 - 05/09/1986
Edith Parrish and Lorna B. Harris 05/09/1986 - 10/25/91
Address Telephone Number
Unknown Unknown
Unknown Unknown
00-0-0000014259
Name of Owner Dates of Ownership
Name of Owner Dates of Ownership
Edith Parrish and Lorna B. Harris 05/09/1986 - 10/31/1993
Address Telephone Number
Address Telephone Number
Unknown Unknown
00-0-0000014259
00-0-0000014259
Name of Owner Dates of Ownership
Edith Parrish and Lorna B. Harris 10/31/1993 - 04/17/1996
Edith Parrish 04/17/1996 - 03/03/2005
Address Telephone Number
Unknown Unknown
Unknown Unknown
00-0-0000014259
Name of Owner Dates of Ownership
Name of Owner Dates of Ownership
Edith Parrish and Anthony & Beverly Southerland 03/03/2005 - 01/15/2010
Address Telephone Number
00-0-0000014259
Unknown5110 NC Highway 96 North, Selma, NC 27576-6187
TABLE 1
UST OWNER/OPERATOR INFORMATION
5110 MARKET & CAFE (INCIDENT NO. 48066)
Address Telephone Number
Name of Owner Dates of Ownership
00-0-0000014259
JAI Umiya LLC 01/15/2010 - Current
Page 1 of 1
Date: 05/23/2022 Facility ID #: 00-0-0000014259
Was Release
Associated
with UST
System?
(Yes / No)
A1 Gasoline 8,000
A2B Gasoline 4,000
A2 Gasoline 4,000 10/31/1993 Single Wall Steel Unknown Single Wall FRP Current No
A3 Kerosene 2,000 No
A3B Diesel 2,000 Yes
1 Diesel 6,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/25/1991)Yes
2 Gasoline 6,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/31/1993)No
3 Gasoline 3,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/31/1993)No
4 Kerosene 4,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/31/1993)No
5 Kerosene 4,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/31/1993)No
6 Diesel 4,000 05/08/1981 Single Wall Steel Unknown SW Steel Removed
(10/31/1993)No
No
CurrentSingle Wall FRPSingle Wall Steel10/31/1993 Unknown
CurrentSingle Wall Steel10/31/1993 Unknown Single Wall FRP
UST
ID
No.
TABLE 2
UST SYSTEM INFORMATION
5110 MARKET & CAFE (INCIDENT NO. 48066)
Tank
Dimensions
Description of
Associated
Product Piping
and
Pumps
Status
of
UST
Current
or Most
Recent
Contents
Capacity
(gallons)
Date
Installed
Construction
Details
Page 1 of 1
Facility ID # : 00-0-0000014259
Well ID.Parcel ID No.Owner Mailing Address Well Address Adjoining
Property
Well Status
(Active/In-
Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
WSW-1 260700-96-1528 Odilon Quezada 1487 Little Devine Rd
Selma NC 27576
1487 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~750 NW
WSW-2 260700-86-4215 Pamela Maynor 1434 Little Devine Rd
Selma, NC 27576
1434 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~1,100 NW
WSW-3 260700-86-3102 Steven Stallings 1350 Thorne Road
Selma, NC 27576
1350 Thorne Rd
Selma, NC 27576 No Active Potable Yes No ~1,100 NW
WSW-4 260700-86-7812 Pedro Reyes 101 South Trail
Selma, NC 27576
101 South Trail
Selma, NC 27576 No Active Potable Yes No ~1,300 N
WSW-5 260700-97-0146 Virginia Staley 107 South Trail
Selma, NC 27576
107 South Trail
Selma, NC 27576 No Active Potable Yes No ~1,300 N
WSW-6 260700-97-2131 Stephen Anderson 108 South Trail
Selma, NC 27576
108 South Trail
Selma, NC 27576 No Active Potable Yes No ~1,300 N
WSW-7 260700-96-2809 Warren Curran 102 South Trail
Selma, NC 27576
102 South Trail
Selma, NC 27576 No Active Potable Yes No ~1,200 N
WSW-8 260700-86-9678 Linda Klein 1457 Little Devine
Selma, NC 27576
1457 Little Devine
Selma, NC 27576 No Active Potable Yes No ~750 N
WSW-9 260700-96-2382 Anthony Artis 5187 NC HWY 96 N
Selma, NC 27576
5187 NC HWY 96 N
Selma, NC 27576 Yes Active Non-Potable Yes Yes ~400 N
WSW-10 260700-96-3541 Wayne Stewart 5217 NC HWY 96
Selma, NC 27576
5217 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes Yes ~750 N
WSW-11 260700-96-3782 Paul Askew 5247 NC HWY 96 N
Selma, NC 27576
5247 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes No ~950 N
WSW-12 260700-96-4932 Susan Humprhies 5283 NC HWY 96 N
Selma, NC 27576
5283 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes No ~1300 N
WSW-13 260700-97-4078 Jeffrey Thayer 5309 NC HWY 96 N
Selma, NC 27576
5309 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes No ~1400 N
WSW-14 260700-95-0890 Connie Moore 467 Gor An Farm Rd
Selma, NC 27576
5075 NC HWY 96 N
Selma, NC 27576 Yes Active Potable Yes No ~250 SW
WSW-15 260700-04-1833 Norwood Norris 5014 NC HWY 96 N
Selma, NC 27576
5014 NC HWY 96 Nx
Selma, NC 27576 No Active Potable Yes Yes ~950 S
WSW-16 260700-95-5051 Anthony Pleasnt 5016 NC HWY 96 N
Selma, NC 27576
5016 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes Yes ~950 S
WSW-17 260700-95-2475 Randy Taylor 5028 NC HWY 96 N
Selma, NC 27576
5028 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes No ~40"S
WSW-18 260700-95-1278 John Molokach 5000 NC HWY 96 N
Selma, NC 27576
5000 NC HWY 96 N
Selma, NC 27576 No Active Potable Yes No ~750 S
WSW-19 260700-84-5907 Live Oak Baptist Church 1555 Live Oak Church Rd
Selma, NC 27576
1555 Live Oak Church Rd
Selma, NC 27576 No Active Potable Yes No ~1,200 SW
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
TABLE 3
RECEPTOR INFORMATION
5110 MARKET & CAFE (INCIDENT NO. 48066)
Date: 9/29/2022
Well Construction
Details
(Depth, Screened
Interval, Type of
Well, etc.)
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Page 1 of 3
Facility ID # : 00-0-0000014259
Well ID.Parcel ID No.Owner Mailing Address Well Address Adjoining
Property
Well Status
(Active/In-
Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
TABLE 3
RECEPTOR INFORMATION
5110 MARKET & CAFE (INCIDENT NO. 48066)
Date: 9/29/2022
Well Construction
Details
(Depth, Screened
Interval, Type of
Well, etc.)
WSW-20 260700-94-3810 April Brantley 4906 NC Highway 96 N
Selma, NC 27576
4906 NC Highway 96 N
Selma, NC 27576 No Active Potable Yes No ~750 S
WSW-21 260700-94-4409 Larry Holland 4852 NC Highway 96 N
Selma, NC 27576
4852 NC Highway 96 N
Selma, NC 27576 No Active Potable Yes No ~1,250 S
WSW-22 260700-95-1158 Edgar Santos-Rubio 4974 NC Highway 96 N
Selma, NC 27576
4974 NC Highway 96 N
Selma, NC 27576 No Active Potable Yes No ~850 S
WSW-23 260700-95-6744 Israel Borjas 1640 Little Devine Rd
Selma, NC 27576
1640 Little Devine Rd
Selma, NC 27576 Yes Active Potable Yes No ~350 E
WSW-24 260700-95-8757 Elaine Langdon 1660 Little Devine RdS
elma, NC 27576
1660 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~400 E
WSW-25 260700-95-9679 Susie B. Johnson Life
Estate
1682 Little Devine Rd
Selma, NC 27576
1682 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~600 E
WSW-26 261701-05-3210 George Richardson 1776 Little Devine RdSelma, NC
27576
1776 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~1,100 E
WSW-27 261701-05-4194 John Sykes 1808 Little Devine Rd
Selma, NC 27576
1808 Little Devine Rd
Selma, NC 27576 No Active Potable Yes No ~1,250 E
WSW-28 260700-95-4853 Jai Umiya LLC 5110 NC Highway 96 N
Selma, NC 27576
5110 NC Highway 96 N
Selma, NC 27576 Site Inactive Out of Service Yes Yes ~75 S
Adjoining 261701-06-5377 Paul H. Howard Jr.221 W Woodlawn Drive
Smithfield, NC 27577 NA Yes NA NA NA NA ~350 N
Adjoining 260700-95-5604 Margaret D Tyndall,
Estate
5076 NC Highway 96 N
Selma, NC 27576 NA Yes NA NA NA NA ~300 N
Unknown
Unknown
Unknown
NA
NA
Unknown
Unknown
Unknown
Unknown
Unknown
Unknown
Page 2 of 3
Facility ID # : 00-0-0000014259
Well ID.Parcel ID No.Owner Mailing Address Well Address Adjoining
Property
Well Status
(Active/In-
Active)
Well Use
(Potable / Non-
Potable
etc.)
Municpal
Water
Available
Yes/No
Connected
to
Municipal
Water
Yes/No
Distance
from source
area of
release
(ft.)
TABLE 3
RECEPTOR INFORMATION
5110 MARKET & CAFE (INCIDENT NO. 48066)
Date: 9/29/2022
Well Construction
Details
(Depth, Screened
Interval, Type of
Well, etc.)
Receptor ID
Latitude/
Longitude of
Any
Significant
Points
Distance
from
the source
area
of release
(ft.)
n/a Yes n/a ~350 N
n/a No n/a ~750 W
n/a No n/a ~1400 SW
n/a No n/a ~1000 S
Notes:
• Receptors and property boundaries are shown on Figure 3.
• n/a: not applicable.
Pond 4880 NC Highway 96 N n/a -
Pond 1434 Little Devine Rd n/a -
Pond 4901 Live Oak Church Rd n/a -
Description Location Contact/Phone Number Usage
Pond 273 Howard Road n/a -
Page 3 of 3
Date: 12/06/2022 Facility ID # : 00-0-0000014259
Well ID
Date
Installed
(m/dd/yy)
Date Water
Level
Measured
(m/dd/yy)
Well
Casing
Depth
(ft. BGS)
Screened
Interval
(x to y ft.
BGS)
Bottom
of Well
(ft. BGS)
Top of
Casing
Elevation
(ft.)
Depth to
Water from
Top of Casing
(feet)
Free Product
Thickness
(ft.)
Ground
Water
Elevation (ft.)
Comments
05/10/22 NM 4.77 ---NM
08/23/22 3.96 ---96.04
11/29/22 4.24 ---95.76
05/10/22 NM 5.49 ---NM
08/23/22 NM ---NM
11/29/22 4.14 ---95.73
08/23/22 3.91 ---96.55
11/29/22 4.16 ---96.30
08/23/22 3.74 ---96.31
11/29/22 4.09 ---95.96
08/23/22 3.41 ---95.36
11/29/22 3.35 ---95.42
Notes:
GMW-2
GMW-4
EMW-1
98.77155 - 1558/17/2022
155 - 15
99.87153 - 1531/6/2010
58/17/2022
8/17/2022
• Elevation relative to mean sea level.
• ft BGS : feet below ground surface.
• NM : Not measured.
TABLE 4
WELL CONSTRUCTION AND GAUGING INFORMATION
5110 MARKET CAFÉ (INCIDENT NO. 48066)
155 - 15
100.05GMW-3
505/10/22GMW-1 100.00
100.46155 - 155
Page 1 of 1
Date: 10/04/22 Facility ID #: 00-0-0000014259
Sample IDDate Collected (mm/dd/yy)Sample Depth(ft-BGS)Gasoline-Range TPHDiesel-Range TPHBenzeneTolueneEthylbenzeneXylenesMTBENaphthaleneC5 - C8 AliphaticsC9-C12 Aliphaticsc9-C10 AromaticsC9-C18 AliphaticsC19-C36 AliphaticsC11-C22 Aromatics50 100 NA NA NA NA NA NA NA NA NA NA NA NA
NE NE 0.0056 4.3 4.9 4.6 0.085 0.2 68 540 31 540 NE 31
NE NE 18 1,200 1,560 3,129 156 5.5 625 1,560 469 1,560 31,200 469
SS-1-4 05/10/22 4 NR NR 0.098 0.004 J 0.004 J 0.124 J <0.0007 0.004 J <9.10 11.4 <9.10 <56.9 <56.9 <56.9
GMW-2 08/18/22 4 <20 <4 NR NR NR NR NR NR NR NR NR NR NR NR
GMW-3 08/18/22 4 <20 <4 NR NR NR NR NR NR NR NR NR NR NR NR
GMW-4 08/18/22 4 <20 <4 NR NR NR NR NR NR NR NR NR NR NR NR
Notes:
• Results reported in mg/kg (milligrams per kilograms)
• ft-BGS: feet below ground surface
• < : Less than the method detection limit specified in the laboratory report
• MCCs: Maximum Contaminant Concentrations (soils)
• SCLs: Soil Cleanup Levels.
• Concentrations in bold face type exceed the soil-to-water MCC
• Concentrations in italic type exceed the residential SCL
• NE: Not Established
• NR: Not Requested
• NA: Not Applicable/Not Analyzed
Soil to Water MCC (mg/kg)
Residential SCLs (mg/kg)
Analytical Method MADEP VPH/EPH
RAL (Regulatory Action Level)
UVF
TABLE 5
SUMMARY OF SOIL SAMPLE ANALYTICAL RESULTS
5110 MARKET CAFÉ (INCIDENT NO. 48066)
EPA 8260B
Page 1 of 1
Date: 12/13/2022 Facility ID # : 00-0-0000014259
EPA
504.1
EPA
6010
Well
ID
Sample Date
(mm/dd/yy)
1 600 600 500 20 6 70 40 10 70 0.02 400 700 200 700 10,000 200 15
5,000 260,000 80,000 50,000 20,000 6,000 70,000 40,000 10,000 30,500 50 NE NE NE NE NE NE 1,500
11/29/22 549 1.38 5.44 4.27 34.8 87.4 13.3 4.69 J 134 74.7 NR 833 701 2,490 NR NR NR NR
11/29/22 0.850 <0.220 0.427 J <0.210 22.8 <0.470 13.9 3.52 J 177 <0.409 J NR 86.9 87.6 300 NR NR NR NR
11/29/22 30.6 0.513 8.64 2.48 J <0.140 2.23 <0.500 790 J 52.0 3.0 NR 790 71.5 181 NR NR NR NR
11/29/22 430 5.72 104 13.9 13.8 19.5 8.47 <1.90 276 J 11.00 NR 1,690 499 1,160 NR NR NR NR
11/29/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.500 <1.90 <1.6 <0.180 NR <11.5 <25.8 <4.02 NR NR NR NR
WSW-28 11/29/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.500 <1.90 1.74 J <0.180 NR <11.5 <25.8 <4.02 NR NR NR NR
11/29/22 <0.180 <0.220 <0.170 <0.210 <0.140 <0.470 <0.500 NR NR <0.180 NR NR NR NR NR NR NR NR
Notes:
• Results reported in micrograms per liter (µg/l).
• MAC: Maximum Allowable Concentration as specified in T15A NCAC 2L.0202.
• Concentrations in bold face type exceed the MAC
• GCL: Gross contamination level.
• Concentrations in italic type exceed the GCL
• < : Less than the method detection limit specified in the laboratory report.
• J: Estimated value.
• NR: Not requested.
• Refer to laboratory report for other detectable concentrations which did not exceed the MACs.
• Concentrations of n-propylbenzene of 101ug/l sampled on August 23, 2022. Refer to full lab report.
Trip Blank
GMW-1
EMW-1
GMW-2
GMW-3
GMW-4
TABLE 6
SUMMARY OF GROUND WATER SAMPLE ANALYTICAL RESULTS - 11/29/22
5110 MARKET CAFÉ (INCIDENT NO. 48066)
Analytical Method MADEP VPH
C9-C18 AliphaticsC19-C36 AliphaticsC5-C8 AliphaticsC9-C12 AliphaticsLead1,2 Dibromomethane(EDB)C11-C22 AromaticsMADEP EPH
C9-C10 AromaticsMAC (μg/l)
GCL (μg/l)MTBENaphthaleneEPA 602/6200B
Contaminant of Concern
BenzeneTolueneEthylbenzeneXylenesIsopropylbenzeneDi-isopropyl ethertert-Amyl alcoholtert-Butyl alcoholPage 1 of 1

APPENDICES

APPENDIX A
NCDEQ Correspondence
NCDEQ Incident Report
RP/Company JAI UMIYA, LLC
RPAddress 304 TROLLEY CAR WAY
RPCity MORRISVILLE
Contact VIVEK B. PATEL
RPState NC
TELEPHONE
IncidentNumber 48524 USTNum FA-29367
IncidentName 5110 MARKET & CAFÉ
FacilID 00-0-0000014259
Address 5110 NC HIGHWAY 96
CityTown SELMA State
ZipCode 27576-6187
DateOccurred 12/2 /2021
DateReported 6 /11/2022
ConfRisk H
CloseOut
COMMENT
RptType Rcvd Rvwd Appvd
Incident Mgr LEPLongitude-78.295335 Latitude 35.605205
County JOHNS
SCH 6/14/2022 6/23/2022
GW above 2L, soil above soil-to GW, pea gravel. LSA required.
LSA2 10/11/2022 11/3/2022
soil above soil-to-GW MSCCs but below residential MSCCs; GW above 2L;
On-Site WSW
Tuesday, December 6, 2022 Page 1 of 1
NCDEQ Registered Tank Report
Facility Name 5110 MARKET & CAFE
Facility Id 00-0-0000014259
Address 5110 NC HIGHWAY 96 NORTH
City SELMA State NC
Zip 27576
Tank Owner JAI UMIYA LLC
Address 5110 NC HIGHWAY 96 NORTH
City SELMA
State NC Zip 27576-6187
County Johnston
Latitude 35.60500 Longitude -78.29541
Tank Information
Tank Id CapacityProduct Name Installation Date Perm Close Date Tank Construction Piping Construction Spill Protection Tank Status OverFill Protection
1 6000Gasoline, Gas Mix 5/8/1981 10/31/1993 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
2 6000Gasoline, Gas Mix 5/8/1981 10/31/1993 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
3 3000Gasoline, Gas Mix 5/8/1981 10/31/1993 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
4 4000Kerosene, Kero
Mix
5/8/1981 10/31/1993 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
5 4000Kerosene, Kero
Mix
5/8/1981 10/31/1993 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
6 4000Diesel 5/8/1981 10/25/1991 Single Wall Steel Single Wall Steel Unknown RemovedUnknown
A1 8000Gasoline, Gas Mix 10/31/1993 Single Wall Steel Single Wall FRP Catchment Basin CurrentAuto Shutoff Device
A2 4000Gasoline, Gas Mix 10/31/1993 Single Wall Steel Single Wall FRP Catchment Basin CurrentBall Float Valve
Tuesday, December 6, 2022 Page 1 of 2
Facility Name 5110 MARKET & CAFE
Facility Id 00-0-0000014259
Address 5110 NC HIGHWAY 96 NORTH
City SELMA State NC
Zip 27576
Tank Owner JAI UMIYA LLC
Address 5110 NC HIGHWAY 96 NORTH
City SELMA
State NC Zip 27576-6187
County Johnston
Latitude 35.60500 Longitude -78.29541
Tank Information
A2B 4000Gasoline, Gas Mix 10/31/1993 Single Wall Steel Single Wall FRP Catchment Basin CurrentBall Float Valve
A3 2000Kerosene, Kero
Mix
10/31/1993 Single Wall Steel Single Wall FRP Catchment Basin CurrentAuto Shutoff Device
A3B 2000Diesel 10/31/1993 Single Wall Steel Single Wall FRP Catchment Basin CurrentBall Float Valve
Tuesday, December 6, 2022 Page 2 of 2

APPENDIX B
Laboratory Report – Ground Water Samples

Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.

12/8/2022
Geological Resources, Inc. Scott Driscoll
113 W. Firetower Road, Suite G Winterville, NC, 28590
Ref: Analytical Testing
Lab Report Number: 22-334-0002 Client Project Description: Market Cafe
GRI #6008
Dear Scott Driscoll:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 11/30/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as-
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Danyale Love Project Manager
Page 1 of 65
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State Program Lab ID Expiration Date
07/31/202337735State ProgramNorth Carolina
12/31/2022402State ProgramNorth Carolina
07/31/202399012State ProgramSouth Carolina
12/31/202299012State ProgramSouth Carolina
Page 1 of 1 00016/22-334-0002
Page 2 of 65
Report Number:
Sample Summary Table
Client Project Description:
22-334-0002
Market Cafe
GRI #6008
Lab No Client Sample ID Matrix Date Collected Date Received
11/29/2022 08:57Aqueous 94300 Trip Blank 11/30/2022 10:15
11/29/2022 09:39Aqueous 94301 GMW-1 11/30/2022 10:15
11/29/2022 09:54Aqueous 94302 GMW-2 11/30/2022 10:15
11/29/2022 10:12Aqueous 94303 GMW-3 11/30/2022 10:15
11/29/2022 10:27Aqueous 94304 GMW-4 11/30/2022 10:15
11/29/2022 10:42Aqueous 94305 EMW-1 11/30/2022 10:15
11/29/2022 11:06Aqueous 94306 WSW-28 11/30/2022 10:15
Page 3 of 65
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-334-0002
Report Limit
Project:Market Cafe
V 94301GMW-1
549 12/02/2022 19:086200BBenzeneµg/L 18.0
3.81 12/01/2022 17:356200Bn-Butylbenzene µg/L 0.180
2.68 12/01/2022 17:356200Bsec-Butyl benzene µg/L 0.200
13.3 12/01/2022 17:356200BDi-Isopropyl Ether (DIPE)µg/L 0.500
5.44 12/01/2022 17:356200BEthylbenzeneµg/L 0.170
74.7 12/01/2022 17:356200BIsopropylbenzeneµg/L 0.180
34.8 12/01/2022 17:356200BMethyl tert-butyl ether (MTBE)µg/L 0.140
87.4 12/01/2022 17:356200BNaphthaleneµg/L 0.470
57.7 12/01/2022 17:356200Bn-Propylbenzene µg/L 0.190
134 12/01/2022 17:356200Btert-Butyl Alcohol (TBA)µg/L 1.60
J4.69 12/01/2022 17:356200Btert-Amyl Alcohol (TAA)µg/L 1.90
J2.79 12/01/2022 17:356200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
1.38 12/01/2022 17:356200BTolueneµg/L 0.220
2.14 12/01/2022 17:356200B1,2,4-Trimethylbenzene µg/L 0.190
0.831 12/01/2022 17:356200B1,3,5-Trimethylbenzene µg/L 0.180
0.627 12/01/2022 17:356200Bo-Xylene µg/L 0.210
3.64 12/01/2022 17:356200Bm,p-Xylene µg/L 0.420
4.27 12/01/2022 17:356200BXylene (Total)µg/L 0.210
283 11/30/2022 18:13CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
2490 11/30/2022 18:13CALCULATIONAromatic C9-C10 (Adjusted)µg/L 40.2
833 11/30/2022 18:13MADEP-VPH Aliphatic C5-C8 µg/L 115
701 11/30/2022 18:13MADEP-VPH Aliphatic C9-C12 µg/L 258
2490 11/30/2022 18:13MADEP-VPH Aromatic C9-C10 µg/L 40.2
V 94302GMW-2
30.6 12/06/2022 15:566200BBenzeneµg/L 0.180
J0.310 12/06/2022 15:566200Bsec-Butyl benzene µg/L 0.200
8.64 12/06/2022 15:566200BEthylbenzeneµg/L 0.170
3.00 12/06/2022 15:566200BIsopropylbenzeneµg/L 0.180
J0.394 12/06/2022 15:566200B4-Isopropyl toluene µg/L 0.089
2.23 12/06/2022 15:566200BNaphthaleneµg/L 0.470
2.04 12/06/2022 15:566200Bn-Propylbenzene µg/L 0.190
52.0 12/06/2022 15:566200Btert-Butyl Alcohol (TBA)µg/L 1.60
J79012/07/2022 18:216200Btert-Amyl Alcohol (TAA)µg/L 190
0.513 12/06/2022 15:566200BTolueneµg/L 0.220
3.44 12/06/2022 15:566200B1,2,4-Trimethylbenzene µg/L 0.190
3.86 12/06/2022 15:566200B1,3,5-Trimethylbenzene µg/L 0.180
Page 4 of 65
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-334-0002
Report Limit
Project:Market Cafe
V 94302GMW-2
1.49 12/06/2022 15:566200Bo-Xylene µg/L 0.210
J0.987 12/06/2022 15:566200Bm,p-Xylene µg/L 0.420
J2.48 12/06/2022 15:566200BXylene (Total)µg/L 0.210
759 11/30/2022 17:49CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
181 11/30/2022 17:49CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
790 11/30/2022 17:49MADEP-VPH Aliphatic C5-C8 µg/L 11.5
71.5 11/30/2022 17:49MADEP-VPH Aliphatic C9-C12 µg/L 25.8
181 11/30/2022 17:49MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 94303GMW-3
430 12/02/2022 19:316200BBenzeneµg/L 18.0
1.52 12/01/2022 17:586200Bn-Butylbenzene µg/L 0.180
1.15 12/01/2022 17:586200Bsec-Butyl benzene µg/L 0.200
8.47 12/01/2022 17:586200BDi-Isopropyl Ether (DIPE)µg/L 0.500
104 12/02/2022 19:316200BEthylbenzeneµg/L 17.0
11.0 12/01/2022 17:586200BIsopropylbenzeneµg/L 0.180
0.633 12/01/2022 17:586200B4-Isopropyl toluene µg/L 0.089
13.8 12/01/2022 17:586200BMethyl tert-butyl ether (MTBE)µg/L 0.140
19.5 12/01/2022 17:586200BNaphthaleneµg/L 0.470
12.1 12/01/2022 17:586200Bn-Propylbenzene µg/L 0.190
J27612/02/2022 19:316200Btert-Butyl Alcohol (TBA)µg/L 160
5.72 12/01/2022 17:586200BTolueneµg/L 0.220
17.7 12/01/2022 17:586200B1,2,4-Trimethylbenzene µg/L 0.190
19.1 12/01/2022 17:586200B1,3,5-Trimethylbenzene µg/L 0.180
3.94 12/01/2022 17:586200Bo-Xylene µg/L 0.210
10.0 12/01/2022 17:586200Bm,p-Xylene µg/L 0.420
13.9 12/01/2022 17:586200BXylene (Total)µg/L 0.210
1250 11/30/2022 19:01CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 115
1160 12/01/2022 10:08CALCULATIONAromatic C9-C10 (Adjusted)µg/L 8.04
1690 11/30/2022 19:01MADEP-VPH Aliphatic C5-C8 µg/L 115
499 12/01/2022 10:08MADEP-VPH Aliphatic C9-C12 µg/L 51.6
1160 12/01/2022 10:08MADEP-VPH Aromatic C9-C10 µg/L 8.04
V 94304GMW-4
0.910 12/01/2022 16:246200BChloroformµg/L 0.220
J0.409 12/01/2022 16:246200B4-Isopropyl toluene µg/L 0.089
Page 5 of 65
Summary of Detected Analytes
QualifiersAnalyzedUnitsResult
Report Number:
Client Sample ID
Method Parameters
Lab Sample ID
22-334-0002
Report Limit
Project:Market Cafe
V 94305EMW-1
0.850 12/01/2022 16:486200BBenzeneµg/L 0.180
J0.340 12/01/2022 16:486200Bsec-Butyl benzene µg/L 0.200
0.858 12/01/2022 16:486200BChloromethaneµg/L 0.220
13.9 12/01/2022 16:486200BDi-Isopropyl Ether (DIPE)µg/L 0.500
J0.427 12/01/2022 16:486200BEthylbenzeneµg/L 0.170
J0.409 12/01/2022 16:486200BIsopropylbenzeneµg/L 0.180
22.8 12/01/2022 16:486200BMethyl tert-butyl ether (MTBE)µg/L 0.140
0.917 12/01/2022 16:486200Bn-Propylbenzene µg/L 0.190
177 12/02/2022 16:016200Btert-Butyl Alcohol (TBA)µg/L 16.0
J3.52 12/01/2022 16:486200Btert-Amyl Alcohol (TAA)µg/L 1.90
J1.48 12/01/2022 16:486200Btert-Amyl Methyl Ether (TAME)µg/L 0.280
86.1 11/30/2022 17:01CALCULATIONAliphatic C5-C8 (Adjusted)µg/L 11.5
300 11/30/2022 17:01CALCULATIONAromatic C9-C10 (Adjusted)µg/L 4.02
86.9 11/30/2022 17:01MADEP-VPH Aliphatic C5-C8 µg/L 11.5
87.6 11/30/2022 17:01MADEP-VPH Aliphatic C9-C12 µg/L 25.8
300 11/30/2022 17:01MADEP-VPH Aromatic C9-C10 µg/L 4.02
V 94306WSW-28
J0.220 12/01/2022 17:116200BChloromethaneµg/L 0.220
J1.74 12/01/2022 17:116200Btert-Butyl Alcohol (TBA)µg/L 1.60
Page 6 of 65

Client: Geological Resources, Inc. CASE NARRATIVE
Project: Market Cafe Lab Report Number: 22-334-0002
Date: 12/8/2022
Volatile Organic Compounds - GC/MS Method 6200B Analyte: 1,1,1,2-Tetrachloroethane QC Batch No: V27418/V27187
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 2-Butanone QC Batch No: V27188/V27187
Relative Percent Difference (RPD) for the duplicate analysis was outside of the allowable QC limits.
Analyte: Carbon Tetrachloride QC Batch No: V27418/V27187
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Analyte: 1,2-Dibromo-3-chloropropane QC Batch No: V27418/V27187
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be acceptable.
Analyte: tert-Amyl alcohol QC Batch No: V27188/V27187
Recovery for the LCS exceeded the upper acceptance limit. However, all sample results associated with the batch are below the MQL, so this high bias had no impact upon the client data. The results are considered to be
acceptable.
Page 7 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
94300 Matrix:
11/29/2022 8:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500Benzene 1 12/01/22 15:15 V27188MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 15:15 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 15:15 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 15:15 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 15:15 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 15:15 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 15:15 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 15:15 V27188MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/01/22 15:15 V27188MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 15:15 V27188MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 15:15 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 15:15 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 15:15 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 8 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
94300 Matrix:
11/29/2022 8:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 15:15 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 15:15 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 15:15 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 15:15 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 15:15 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 15:15 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 15:15 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 15:15 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 15:15 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 15:15 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 15:15 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 15:15 V27188MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 12/01/22 15:15 V27188MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 15:15 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 15:15 V27188MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 15:15 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 15:15 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 9 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
94300 Matrix:
11/29/2022 8:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 15:15 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 15:15 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 15:15 V27188MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 15:15 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 15:15 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 15:15 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 15:15 V27188MSA
<0.220 µg/L 0.220 0.500
Tetrachloroethene 1 12/01/22 15:15 V27188MSA
<0.220 µg/L 0.220 0.500Toluene 1 12/01/22 15:15 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 15:15 V27188MSA
<0.310 µg/L 0.310 0.5001,2,4-Trichlorobenzene 1 12/01/22 15:15 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 15:15 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.500
Trichlorofluoromethane 1 12/01/22 15:15 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 15:15 V27188MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 15:15 V27188MSA
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 15:15 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 15:15 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 15:15 V27188MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 12/01/22 15:15 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 10 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:Trip Blank
94300 Matrix:
11/29/2022 8:57
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.420 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 15:15 V27188MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 12/01/22 15:15 V27188
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%12/01/22 15:151 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 15:151 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 96.4 Limits: 70-130%12/01/22 15:151 MSA V27188
Surrogate: Toluene-d8 99.6 Limits: 70-130%12/01/22 15:151 MSA V27188
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 11 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/01/22 17:35 6200BMSA
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 98.2 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: Toluene-d8 101 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: Toluene-d8 96.6 Limits: 70-130%12/02/22 19:08100 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 12 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 17:35 V27188MSA
549 µg/L 18.0 50.0Benzene 100 12/02/22 19:08 V27277MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 17:35 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 17:35 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 17:35 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 17:35 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 17:35 V27188MSA
3.81 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 17:35 V27188MSA
2.68 µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 17:35 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 17:35 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 17:35 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 17:35 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 17:35 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 17:35 V27188MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/01/22 17:35 V27188MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 12/01/22 17:35 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 17:35 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 17:35 V27188MSA
13.3 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 17:35 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 17:35 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 17:35 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 17:35 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 13 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 17:35 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 17:35 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 17:35 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 17:35 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 17:35 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 17:35 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 17:35 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 17:35 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 17:35 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 17:35 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 17:35 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 17:35 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 17:35 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 17:35 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 17:35 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 17:35 V27188MSA
5.44 µg/L 0.170 0.500Ethylbenzene 1 12/01/22 17:35 V27188MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 17:35 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 17:35 V27188MSA
74.7 µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 17:35 V27188MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 17:35 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 17:35 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 14 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
34.8 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 17:35 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 17:35 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 17:35 V27188MSA
87.4 µg/L 0.470 1.00Naphthalene 1 12/01/22 17:35 V27188MSA
57.7 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 17:35 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 17:35 V27188MSA
134 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 12/01/22 17:35 V27188MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/01/22 17:35 V27188MSA
4.69 J
µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 12/01/22 17:35 V27188MSA
2.79 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/01/22 17:35 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 17:35 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 17:35 V27188MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/01/22 17:35 V27188MSA
1.38 µg/L 0.220 0.500Toluene 1 12/01/22 17:35 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 17:35 V27188MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/01/22 17:35 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 17:35 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 17:35 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 17:35 V27188MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/01/22 17:35 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 17:35 V27188MSA
2.14 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 17:35 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 15 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
0.831 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 17:35 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 17:35 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 17:35 V27188MSA
0.627 µg/L 0.210 0.500o-Xylene 1 12/01/22 17:35 V27188MSA
3.64 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 17:35 V27188MSA
4.27 µg/L 0.210 0.500Xylene (Total)1 12/01/22 17:35 V27188KCC
Surrogate: 4-Bromofluorobenzene 97.8 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 98.2 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: Toluene-d8 101 Limits: 70-130%12/01/22 17:351 MSA V27188
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%12/02/22 19:08100 MSA V27277
Surrogate: Toluene-d8 96.6 Limits: 70-130%12/02/22 19:08100 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 16 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-1
94301 Matrix:
11/29/2022 9:39
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
283 µg/L 115 500Aliphatic C5-C8 (Adjusted)1 11/30/22 18:13
<258 µg/L 258 500Aliphatics C9-C12 (Adjusted)10 11/30/22 18:13
2490 µg/L 40.2 500Aromatic C9-C10 (Adjusted)10 11/30/22 18:13
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
833 µg/L 115 500Aliphatic C5-C8 10 11/30/22 18:13 V27071TBL
701 µg/L 258 500Aliphatic C9-C12 10 11/30/22 18:13 V27071TBL
2490 µg/L 40.2 500Aromatic C9-C10 10 11/30/22 18:13 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)78.4 Limits: 70-130%11/30/22 18:1310 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)80.8 Limits: 70-130%11/30/22 18:1310 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 17 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/06/22 15:56 6200BMSA
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: 1,2-Dichloroethane - d4 96.8 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: Toluene-d8 98.0 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: Dibromofluoromethane 101 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: Toluene-d8 97.4 Limits: 70-130%12/07/22 18:21100 ANG V27487
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 18 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27417 12/06/22 09:00 V27486 12/07/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/06/22 15:56 V27418MSA
30.6 µg/L 0.180 0.500Benzene 1 12/06/22 15:56 V27418MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/06/22 15:56 V27418MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/06/22 15:56 V27418MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/06/22 15:56 V27418MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/06/22 15:56 V27418MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/06/22 15:56 V27418MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 12/06/22 15:56 V27418MSA
0.310 J
µg/L 0.200 0.500
sec-Butyl benzene 1 12/06/22 15:56 V27418MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/06/22 15:56 V27418MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/06/22 15:56 V27418MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/06/22 15:56 V27418MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/06/22 15:56 V27418MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/06/22 15:56 V27418MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/06/22 15:56 V27418MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 12/06/22 15:56 V27418MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/06/22 15:56 V27418MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/06/22 15:56 V27418MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/06/22 15:56 V27418MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/06/22 15:56 V27418MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/06/22 15:56 V27418MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/06/22 15:56 V27418MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 19 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27417 12/06/22 09:00 V27486 12/07/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/06/22 15:56 V27418MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/06/22 15:56 V27418MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/06/22 15:56 V27418MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/06/22 15:56 V27418MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/06/22 15:56 V27418MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/06/22 15:56 V27418MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/06/22 15:56 V27418MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/06/22 15:56 V27418MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/06/22 15:56 V27418MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/06/22 15:56 V27418MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/06/22 15:56 V27418MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/06/22 15:56 V27418MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/06/22 15:56 V27418MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/06/22 15:56 V27418MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/06/22 15:56 V27418MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/06/22 15:56 V27418MSA
8.64 µg/L 0.170 0.500Ethylbenzene 1 12/06/22 15:56 V27418MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/06/22 15:56 V27418MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/06/22 15:56 V27418MSA
3.00 µg/L 0.180 0.500Isopropylbenzene 1 12/06/22 15:56 V27418MSA
0.394 J µg/L 0.089 0.5004-Isopropyl toluene 1 12/06/22 15:56 V27418MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/06/22 15:56 V27418MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 20 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27417 12/06/22 09:00 V27486 12/07/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/06/22 15:56 V27418MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/06/22 15:56 V27418MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/06/22 15:56 V27418MSA
2.23 µg/L 0.470 1.00Naphthalene 1 12/06/22 15:56 V27418MSA
2.04 µg/L 0.190 0.500n-Propylbenzene 1 12/06/22 15:56 V27418MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/06/22 15:56 V27418MSA
52.0 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 12/06/22 15:56 V27418MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/06/22 15:56 V27418MSA
790 J
µg/L 190 1000
tert-Amyl Alcohol (TAA)100 12/07/22 18:21 V27487ANG
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/06/22 15:56 V27418MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/06/22 15:56 V27418MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/06/22 15:56 V27418MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/06/22 15:56 V27418MSA
0.513 µg/L 0.220 0.500Toluene 1 12/06/22 15:56 V27418MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/06/22 15:56 V27418MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/06/22 15:56 V27418MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/06/22 15:56 V27418MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/06/22 15:56 V27418MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/06/22 15:56 V27418MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/06/22 15:56 V27418MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/06/22 15:56 V27418MSA
3.44 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/06/22 15:56 V27418MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 21 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27417 12/06/22 09:00 V27486 12/07/22 09:00
3.86 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/06/22 15:56 V27418MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/06/22 15:56 V27418MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/06/22 15:56 V27418MSA
1.49 µg/L 0.210 0.500o-Xylene 1 12/06/22 15:56 V27418MSA
0.987 J µg/L 0.420 1.00m,p-Xylene 1 12/06/22 15:56 V27418MSA
2.48 J µg/L 0.210 0.500Xylene (Total)1 12/06/22 15:56 V27418
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: 1,2-Dichloroethane - d4 96.8 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: Toluene-d8 98.0 Limits: 70-130%12/06/22 15:561 MSA V27418
Surrogate: 4-Bromofluorobenzene 100 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: Dibromofluoromethane 101 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: 1,2-Dichloroethane - d4 97.0 Limits: 70-130%12/07/22 18:21100 ANG V27487
Surrogate: Toluene-d8 97.4 Limits: 70-130%12/07/22 18:21100 ANG V27487
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 22 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-2
94302 Matrix:
11/29/2022 9:54
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
759 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 11/30/22 17:49
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 11/30/22 17:49
181 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 11/30/22 17:49
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
790 µg/L 11.5 50.0Aliphatic C5-C8 1 11/30/22 17:49 V27071TBL
71.5 µg/L 25.8 50.0Aliphatic C9-C12 1 11/30/22 17:49 V27071TBL
181 µg/L 4.02 50.0Aromatic C9-C10 1 11/30/22 17:49 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)81.3 Limits: 70-130%11/30/22 17:491 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)89.7 Limits: 70-130%11/30/22 17:491 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 23 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/01/22 17:58 6200BMSA
Surrogate: 4-Bromofluorobenzene 98.4 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: Toluene-d8 99.2 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: Dibromofluoromethane 102 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: Toluene-d8 99.2 Limits: 70-130%12/02/22 19:31100 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 24 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 17:58 V27188MSA
430 µg/L 18.0 50.0Benzene 100 12/02/22 19:31 V27277MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 17:58 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 17:58 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 17:58 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 17:58 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 17:58 V27188MSA
1.52 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 17:58 V27188MSA
1.15 µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 17:58 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 17:58 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 17:58 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 17:58 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 17:58 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 17:58 V27188MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/01/22 17:58 V27188MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 12/01/22 17:58 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 17:58 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 17:58 V27188MSA
8.47 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 17:58 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 17:58 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 17:58 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 17:58 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 25 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 17:58 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 17:58 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 17:58 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 17:58 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 17:58 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 17:58 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 17:58 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 17:58 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 17:58 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 17:58 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 17:58 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 17:58 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 17:58 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 17:58 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 17:58 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 17:58 V27188MSA
104 µg/L 17.0 50.0Ethylbenzene 100 12/02/22 19:31 V27277MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 17:58 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 17:58 V27188MSA
11.0 µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 17:58 V27188MSA
0.633 µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 17:58 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 17:58 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 26 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
13.8 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 17:58 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 17:58 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 17:58 V27188MSA
19.5 µg/L 0.470 1.00Naphthalene 1 12/01/22 17:58 V27188MSA
12.1 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 17:58 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 17:58 V27188MSA
276 J µg/L 160 1000tert-Butyl Alcohol (TBA)100 12/02/22 19:31 V27277MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/01/22 17:58 V27188MSA
<1.90 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 12/01/22 17:58 V27188MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/01/22 17:58 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 17:58 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 17:58 V27188MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/01/22 17:58 V27188MSA
5.72 µg/L 0.220 0.500Toluene 1 12/01/22 17:58 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 17:58 V27188MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/01/22 17:58 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 17:58 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 17:58 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 17:58 V27188MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/01/22 17:58 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 17:58 V27188MSA
17.7 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 17:58 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 27 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
19.1 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 17:58 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 17:58 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 17:58 V27188MSA
3.94 µg/L 0.210 0.500o-Xylene 1 12/01/22 17:58 V27188MSA
10.0 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 17:58 V27188MSA
13.9 µg/L 0.210 0.500Xylene (Total)1 12/01/22 17:58 V27188KCC
Surrogate: 4-Bromofluorobenzene 98.4 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: Toluene-d8 99.2 Limits: 70-130%12/01/22 17:581 MSA V27188
Surrogate: 4-Bromofluorobenzene 97.4 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: Dibromofluoromethane 102 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 95.4 Limits: 70-130%12/02/22 19:31100 MSA V27277
Surrogate: Toluene-d8 99.2 Limits: 70-130%12/02/22 19:31100 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 28 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-3
94303 Matrix:
11/29/2022 10:12
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
1250 µg/L 115 500Aliphatic C5-C8 (Adjusted)1 11/30/22 19:01
<51.6 µg/L 51.6 100Aliphatics C9-C12 (Adjusted)2 12/01/22 10:08
1160 µg/L 8.04 100Aromatic C9-C10 (Adjusted)2 12/01/22 10:08
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
1690 µg/L 115 500Aliphatic C5-C8 10 11/30/22 19:01 V27071TBL
499 µg/L 51.6 100Aliphatic C9-C12 2 12/01/22 10:08 V27071TBL
1160 µg/L 8.04 100Aromatic C9-C10 2 12/01/22 10:08 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)79.6 Limits: 70-130%11/30/22 19:0110 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)107 Limits: 70-130%11/30/22 19:0110 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)78.1 Limits: 70-130%12/01/22 10:082 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)101 Limits: 70-130%12/01/22 10:082 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 29 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/01/22 16:24 6200BMSA
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: Dibromofluoromethane 102 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 96.4 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: Toluene-d8 99.8 Limits: 70-130%12/01/22 16:241 MSA V27188
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 30 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500Benzene 1 12/01/22 16:24 V27188MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 16:24 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 16:24 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 16:24 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 16:24 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 16:24 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 16:24 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 16:24 V27188MSA
0.910 µg/L 0.220 0.500Chloroform 1 12/01/22 16:24 V27188MSA
<0.220 µg/L 0.220 0.500
Chloromethane 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 16:24 V27188MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 16:24 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 16:24 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 16:24 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 31 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 16:24 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 16:24 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 16:24 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 16:24 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 16:24 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 16:24 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 16:24 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 16:24 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 16:24 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 16:24 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 16:24 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 16:24 V27188MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 12/01/22 16:24 V27188MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 16:24 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 16:24 V27188MSA
0.409 J µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 16:24 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 16:24 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 32 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 16:24 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 16:24 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 16:24 V27188MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 16:24 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 16:24 V27188MSA
<1.60 µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 12/01/22 16:24 V27188MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/01/22 16:24 V27188MSA
<1.90 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 12/01/22 16:24 V27188MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/01/22 16:24 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 16:24 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 16:24 V27188MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/01/22 16:24 V27188MSA
<0.220 µg/L 0.220 0.500Toluene 1 12/01/22 16:24 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 16:24 V27188MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/01/22 16:24 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 16:24 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 16:24 V27188MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/01/22 16:24 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 16:24 V27188MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 16:24 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 33 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 16:24 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 16:24 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 16:24 V27188MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 12/01/22 16:24 V27188MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 16:24 V27188MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 12/01/22 16:24 V27188
Surrogate: 4-Bromofluorobenzene 99.8 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: Dibromofluoromethane 102 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 96.4 Limits: 70-130%12/01/22 16:241 MSA V27188
Surrogate: Toluene-d8 99.8 Limits: 70-130%12/01/22 16:241 MSA V27188
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 34 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:GMW-4
94304 Matrix:
11/29/2022 10:27
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 11/30/22 16:37
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 11/30/22 16:37
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 11/30/22 16:37
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 11/30/22 16:37 V27071TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 11/30/22 16:37 V27071TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 11/30/22 16:37 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)76.6 Limits: 70-130%11/30/22 16:371 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)96.2 Limits: 70-130%11/30/22 16:371 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 35 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/01/22 16:48 6200BMSA
Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: Toluene-d8 98.8 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 95.8 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: Toluene-d8 98.4 Limits: 70-130%12/02/22 16:0110 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 36 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 16:48 V27188MSA
0.850 µg/L 0.180 0.500Benzene 1 12/01/22 16:48 V27188MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 16:48 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 16:48 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 16:48 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 16:48 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 16:48 V27188MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 16:48 V27188MSA
0.340 J
µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 16:48 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 16:48 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 16:48 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 16:48 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 16:48 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 16:48 V27188MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/01/22 16:48 V27188MSA
0.858 µg/L 0.220 0.500
Chloromethane 1 12/01/22 16:48 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 16:48 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 16:48 V27188MSA
13.9 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 16:48 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 16:48 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 16:48 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 16:48 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 37 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 16:48 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 16:48 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 16:48 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 16:48 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 16:48 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 16:48 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 16:48 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 16:48 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 16:48 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 16:48 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 16:48 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 16:48 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 16:48 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 16:48 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 16:48 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 16:48 V27188MSA
0.427 J µg/L 0.170 0.500Ethylbenzene 1 12/01/22 16:48 V27188MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 16:48 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 16:48 V27188MSA
0.409 J µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 16:48 V27188MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 16:48 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 16:48 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 38 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
22.8 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 16:48 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 16:48 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 16:48 V27188MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 12/01/22 16:48 V27188MSA
0.917 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 16:48 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 16:48 V27188MSA
177 µg/L 16.0 100tert-Butyl Alcohol (TBA)10 12/02/22 16:01 V27277MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/01/22 16:48 V27188MSA
3.52 J
µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 12/01/22 16:48 V27188MSA
1.48 J µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/01/22 16:48 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 16:48 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 16:48 V27188MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/01/22 16:48 V27188MSA
<0.220 µg/L 0.220 0.500Toluene 1 12/01/22 16:48 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 16:48 V27188MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/01/22 16:48 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 16:48 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 16:48 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 16:48 V27188MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/01/22 16:48 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 16:48 V27188MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 16:48 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 39 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00 V27276 12/02/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 16:48 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 16:48 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 16:48 V27188MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 12/01/22 16:48 V27188MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 16:48 V27188MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 12/01/22 16:48 V27188KCC
Surrogate: 4-Bromofluorobenzene 95.8 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 101 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: Toluene-d8 98.8 Limits: 70-130%12/01/22 16:481 MSA V27188
Surrogate: 4-Bromofluorobenzene 102 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: Dibromofluoromethane 105 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: 1,2-Dichloroethane - d4 95.8 Limits: 70-130%12/02/22 16:0110 MSA V27277
Surrogate: Toluene-d8 98.4 Limits: 70-130%12/02/22 16:0110 MSA V27277
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 40 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:EMW-1
94305 Matrix:
11/29/2022 10:42
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
86.1 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 11/30/22 17:01
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 11/30/22 17:01
300 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 11/30/22 17:01
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
86.9 µg/L 11.5 50.0Aliphatic C5-C8 1 11/30/22 17:01 V27071TBL
87.6 µg/L 25.8 50.0Aliphatic C9-C12 1 11/30/22 17:01 V27071TBL
300 µg/L 4.02 50.0Aromatic C9-C10 1 11/30/22 17:01 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)80.9 Limits: 70-130%11/30/22 17:011 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)83.1 Limits: 70-130%11/30/22 17:011 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 41 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Test Results Units MDL MQL By Analytical
Method
Date / Time
Analyzed
DF
<1.00 µg/L 1.00 10.03,3-Dimethyl-1-butanol 1 12/01/22 17:11 6200BMSA
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: Dibromofluoromethane 101 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: Toluene-d8 102 Limits: 70-130%12/01/22 17:111 MSA V27188
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 42 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<1.80 µg/L 1.80 10.0Acetone 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500Benzene 1 12/01/22 17:11 V27188MSA
<0.210 µg/L 0.210 0.500Bromobenzene 1 12/01/22 17:11 V27188MSA
<0.420 µg/L 0.420 1.00Bromochloromethane 1 12/01/22 17:11 V27188MSA
<0.160 µg/L 0.160 0.500Bromodichloromethane 1 12/01/22 17:11 V27188MSA
<1.50 µg/L 1.50 5.00Bromoform 1 12/01/22 17:11 V27188MSA
<0.280 µg/L 0.280 1.00Bromomethane 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500n-Butylbenzene 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.500
sec-Butyl benzene 1 12/01/22 17:11 V27188MSA
<0.920 µg/L 0.920 2.00tert-Butyl benzene 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500Carbon Tetrachloride 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.500Chlorobenzene 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.500Chlorodibromomethane 1 12/01/22 17:11 V27188MSA
<0.430 µg/L 0.430 1.00Chloroethane 1 12/01/22 17:11 V27188MSA
<0.220 µg/L 0.220 0.500Chloroform 1 12/01/22 17:11 V27188MSA
0.220 J
µg/L 0.220 0.500
Chloromethane 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.5002-Chlorotoluene 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.5004-Chlorotoluene 1 12/01/22 17:11 V27188MSA
<0.500 µg/L 0.500 0.500Di-Isopropyl Ether (DIPE)1 12/01/22 17:11 V27188MSA
<1.10 µg/L 1.10 2.001,2-Dibromo-3-Chloropropane 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.5001,2-Dibromoethane 1 12/01/22 17:11 V27188MSA
<0.230 µg/L 0.230 0.500Dibromomethane 1 12/01/22 17:11 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 43 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.220 µg/L 0.220 0.5001,2-Dichlorobenzene 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.5001,3-Dichlorobenzene 1 12/01/22 17:11 V27188MSA
<0.210 µg/L 0.210 0.5001,4-Dichlorobenzene 1 12/01/22 17:11 V27188MSA
<1.20 µg/L 1.20 5.00Dichlorodifluoromethane 1 12/01/22 17:11 V27188MSA
<0.240 µg/L 0.240 0.5001,1-Dichloroethane 1 12/01/22 17:11 V27188MSA
<0.150 µg/L 0.150 0.5001,2-Dichloroethane 1 12/01/22 17:11 V27188MSA
<0.150 µg/L 0.150 0.5001,1-Dichloroethene 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.500cis-1,2-Dichloroethene 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500
trans-1,2-Dichloroethene 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.5001,2-Dichloropropane 1 12/01/22 17:11 V27188MSA
<0.130 µg/L 0.130 0.5001,3-Dichloropropane 1 12/01/22 17:11 V27188MSA
<0.210 µg/L 0.210 2.002,2-Dichloropropane 1 12/01/22 17:11 V27188MSA
<0.200 µg/L 0.200 0.5001,1-Dichloropropene 1 12/01/22 17:11 V27188MSA
<0.210 µg/L 0.210 0.500cis-1,3-Dichloropropene 1 12/01/22 17:11 V27188MSA
<0.150 µg/L 0.150 0.500trans-1,3-Dichloropropene 1 12/01/22 17:11 V27188MSA
<42.0 µg/L 42.0 200
Ethanol 1 12/01/22 17:11 V27188MSA
<0.170 µg/L 0.170 0.500Ethylbenzene 1 12/01/22 17:11 V27188MSA
<0.350 µg/L 0.350 3.00Hexachlorobutadiene 1 12/01/22 17:11 V27188MSA
<0.380 µg/L 0.380 1.002-Hexanone 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500Isopropylbenzene 1 12/01/22 17:11 V27188MSA
<0.089 µg/L 0.089 0.5004-Isopropyl toluene 1 12/01/22 17:11 V27188MSA
<0.710 µg/L 0.710 5.00Methyl Ethyl Ketone (MEK)1 12/01/22 17:11 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 44 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.140 µg/L 0.140 1.00Methyl tert-butyl ether (MTBE)1 12/01/22 17:11 V27188MSA
<0.078 µg/L 0.078 1.004-Methyl-2-Pentanone 1 12/01/22 17:11 V27188MSA
<0.330 µg/L 0.330 2.00Methylene Chloride 1 12/01/22 17:11 V27188MSA
<0.470 µg/L 0.470 1.00Naphthalene 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.500n-Propylbenzene 1 12/01/22 17:11 V27188MSA
<0.220 µg/L 0.220 0.500Styrene 1 12/01/22 17:11 V27188MSA
1.74 J µg/L 1.60 10.0tert-Butyl Alcohol (TBA)1 12/01/22 17:11 V27188MSA
<0.350 µg/L 0.350 10.0tert-Butyl formate (TBF)1 12/01/22 17:11 V27188MSA
<1.90 µg/L 1.90 10.0
tert-Amyl Alcohol (TAA)1 12/01/22 17:11 V27188MSA
<0.280 µg/L 0.280 10.0tert-Amyl Methyl Ether (TAME)1 12/01/22 17:11 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1,2-Tetrachloroethane 1 12/01/22 17:11 V27188MSA
<0.160 µg/L 0.160 0.5001,1,2,2-Tetrachloroethane 1 12/01/22 17:11 V27188MSA
<0.220 µg/L 0.220 0.500Tetrachloroethene 1 12/01/22 17:11 V27188MSA
<0.220 µg/L 0.220 0.500Toluene 1 12/01/22 17:11 V27188MSA
<0.380 µg/L 0.380 0.5001,2,3-Trichlorobenzene 1 12/01/22 17:11 V27188MSA
<0.310 µg/L 0.310 0.500
1,2,4-Trichlorobenzene 1 12/01/22 17:11 V27188MSA
<0.160 µg/L 0.160 0.5001,1,1-Trichloroethane 1 12/01/22 17:11 V27188MSA
<0.096 µg/L 0.096 0.5001,1,2-Trichloroethane 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500Trichloroethene 1 12/01/22 17:11 V27188MSA
<0.180 µg/L 0.180 0.500Trichlorofluoromethane 1 12/01/22 17:11 V27188MSA
<0.270 µg/L 0.270 0.5001,2,3-Trichloropropane 1 12/01/22 17:11 V27188MSA
<0.190 µg/L 0.190 0.5001,2,4-Trimethylbenzene 1 12/01/22 17:11 V27188MSA
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 45 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
6200 PT
6200B Prep Batch(es):V27187 12/01/22 09:00
<0.180 µg/L 0.180 0.5001,3,5-Trimethylbenzene 1 12/01/22 17:11 V27188MSA
<1.00 µg/L 1.00 5.00Vinyl Acetate 1 12/01/22 17:11 V27188MSA
<0.170 µg/L 0.170 0.500Vinyl Chloride 1 12/01/22 17:11 V27188MSA
<0.210 µg/L 0.210 0.500o-Xylene 1 12/01/22 17:11 V27188MSA
<0.420 µg/L 0.420 1.00m,p-Xylene 1 12/01/22 17:11 V27188MSA
<0.21 µg/L 0.210 0.500Xylene (Total)1 12/01/22 17:11 V27188
Surrogate: 4-Bromofluorobenzene 101 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: Dibromofluoromethane 101 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: 1,2-Dichloroethane - d4 97.4 Limits: 70-130%12/01/22 17:111 MSA V27188
Surrogate: Toluene-d8 102 Limits: 70-130%12/01/22 17:111 MSA V27188
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Method Quantitation LimitMQL
Page 46 of 65
,
REPORT OF ANALYSISReport Number :
Project
Information :
NC 28590
22-334-0002
00087
Geological Resources, Inc.
113 W. Firetower Road, Suite G
Scott Driscoll
Winterville
Danyale Love
Project Manager
GRI #6008 Received : 11/30/2022
Market Cafe
Report Date : 12/08/2022
Sample ID :
Lab No :
Sampled:WSW-28
94306 Matrix:
11/29/2022 11:06
Aqueous
Analytical Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
CALCULATION
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 (Adjusted)1 11/30/22 17:25
<25.8 µg/L 25.8 50.0Aliphatics C9-C12 (Adjusted)1 11/30/22 17:25
<4.02 µg/L 4.02 50.0Aromatic C9-C10 (Adjusted)1 11/30/22 17:25
Analytical Method:
Prep Method:
Test Results Units MDL MQL By Analytical
Batch
Date / Time
Analyzed
DF
MAVPH (Prep)
MADEP-VPH Prep Batch(es):V27070 11/30/22 08:00
<11.5 µg/L 11.5 50.0Aliphatic C5-C8 1 11/30/22 17:25 V27071TBL
<25.8 µg/L 25.8 50.0Aliphatic C9-C12 1 11/30/22 17:25 V27071TBL
<4.02 µg/L 4.02 50.0Aromatic C9-C10 1 11/30/22 17:25 V27071TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (FID)77.8 Limits: 70-130%11/30/22 17:251 TBL
MADEP-VPHSurrogate: 2,5-Dibromotoluene (PID)97.6 Limits: 70-130%11/30/22 17:251 TBL
Qualifiers/
Definitions
Estimated valueJDilution FactorDF
Page 47 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
Associated Lab Samples: 94300, 94301, 94303, 94304, 94305, 94306
LRB-V27187 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/01/22 14:2810.01.80<1.80µg/LAcetone
12/01/22 14:280.5000.180<0.180µg/LBenzene
12/01/22 14:280.5000.210<0.210µg/LBromobenzene
12/01/22 14:281.000.420<0.420µg/LBromochloromethane
12/01/22 14:280.5000.160<0.160µg/LBromodichloromethane
12/01/22 14:285.001.50<1.50µg/LBromoform
12/01/22 14:281.000.280<0.280µg/LBromomethane
12/01/22 14:280.5000.180<0.180µg/Ln-Butylbenzene
12/01/22 14:280.5000.200<0.200µg/Lsec-Butyl benzene
12/01/22 14:282.000.920<0.920µg/Ltert-Butyl benzene
12/01/22 14:280.5000.180<0.180µg/LCarbon Tetrachloride
12/01/22 14:280.5000.190<0.190µg/LChlorobenzene
12/01/22 14:280.5000.190<0.190µg/LChlorodibromomethane
12/01/22 14:281.000.430<0.430µg/LChloroethane
12/01/22 14:280.5000.220<0.220µg/LChloroform
12/01/22 14:280.5000.220<0.220µg/LChloromethane
12/01/22 14:280.5000.200<0.200µg/L2-Chlorotoluene
12/01/22 14:280.5000.200<0.200µg/L4-Chlorotoluene
12/01/22 14:280.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
12/01/22 14:282.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
12/01/22 14:280.5000.200<0.200µg/L1,2-Dibromoethane
12/01/22 14:280.5000.230<0.230µg/LDibromomethane
12/01/22 14:280.5000.220<0.220µg/L1,2-Dichlorobenzene
12/01/22 14:280.5000.190<0.190µg/L1,3-Dichlorobenzene
12/01/22 14:280.5000.210<0.210µg/L1,4-Dichlorobenzene
12/01/22 14:285.001.20<1.20µg/LDichlorodifluoromethane
12/01/22 14:280.5000.240<0.240µg/L1,1-Dichloroethane
Page 1 of 16Date:12/08/2022 04:16 PM
Page 48 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
Associated Lab Samples: 94300, 94301, 94303, 94304, 94305, 94306
LRB-V27187 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/01/22 14:280.5000.150<0.150µg/L1,2-Dichloroethane
12/01/22 14:280.5000.150<0.150µg/L1,1-Dichloroethene
12/01/22 14:280.5000.200<0.200µg/Lcis-1,2-Dichloroethene
12/01/22 14:280.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
12/01/22 14:280.5000.190<0.190µg/L1,2-Dichloropropane
12/01/22 14:280.5000.130<0.130µg/L1,3-Dichloropropane
12/01/22 14:282.000.210<0.210µg/L2,2-Dichloropropane
12/01/22 14:280.5000.200<0.200µg/L1,1-Dichloropropene
12/01/22 14:280.5000.210<0.210µg/Lcis-1,3-Dichloropropene
12/01/22 14:280.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
12/01/22 14:2820042.0<42.0µg/LEthanol
12/01/22 14:280.5000.170<0.170µg/LEthylbenzene
12/01/22 14:283.000.350<0.350µg/LHexachlorobutadiene
12/01/22 14:281.000.380<0.380µg/L2-Hexanone
12/01/22 14:280.5000.180<0.180µg/LIsopropylbenzene
12/01/22 14:280.5000.089<0.089µg/L4-Isopropyl toluene
12/01/22 14:285.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
12/01/22 14:281.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
12/01/22 14:281.000.078<0.078µg/L4-Methyl-2-Pentanone
12/01/22 14:282.000.330<0.330µg/LMethylene Chloride
12/01/22 14:281.000.470<0.470µg/LNaphthalene
12/01/22 14:280.5000.190<0.190µg/Ln-Propylbenzene
12/01/22 14:280.5000.220<0.220µg/LStyrene
12/01/22 14:2810.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
12/01/22 14:2810.00.350<0.350µg/Ltert-Butyl formate (TBF)
12/01/22 14:2810.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
12/01/22 14:2810.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
Page 2 of 16Date:12/08/2022 04:16 PM
Page 49 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
Associated Lab Samples: 94300, 94301, 94303, 94304, 94305, 94306
LRB-V27187 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/01/22 14:280.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
12/01/22 14:280.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
12/01/22 14:280.5000.220<0.220µg/LTetrachloroethene
12/01/22 14:280.5000.220<0.220µg/LToluene
12/01/22 14:280.5000.380<0.380µg/L1,2,3-Trichlorobenzene
12/01/22 14:280.5000.310<0.310µg/L1,2,4-Trichlorobenzene
12/01/22 14:280.5000.160<0.160µg/L1,1,1-Trichloroethane
12/01/22 14:280.5000.096<0.096µg/L1,1,2-Trichloroethane
12/01/22 14:280.5000.180<0.180µg/LTrichloroethene
12/01/22 14:280.5000.180<0.180µg/LTrichlorofluoromethane
12/01/22 14:280.5000.270<0.270µg/L1,2,3-Trichloropropane
12/01/22 14:280.5000.190<0.190µg/L1,2,4-Trimethylbenzene
12/01/22 14:280.5000.180<0.180µg/L1,3,5-Trimethylbenzene
12/01/22 14:285.001.00<1.00µg/LVinyl Acetate
12/01/22 14:280.5000.170<0.170µg/LVinyl Chloride
12/01/22 14:280.5000.210<0.210µg/Lo-Xylene
12/01/22 14:281.000.420<0.420µg/Lm,p-Xylene
12/01/22 14:2810.01.00<1.00µg/L3,3-Dimethyl-1-butanol
12/01/22 14:284-Bromofluorobenzene (S)101 70-130
12/01/22 14:28Dibromofluoromethane (S)106 70-130
12/01/22 14:281,2-Dichloroethane - d4 (S)98.6 70-130
12/01/22 14:28Toluene-d8 (S)98.8 70-130
Page 3 of 16Date:12/08/2022 04:16 PM
Page 50 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
LCS-V27187Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
203*40.620.0µg/Ltert-Amyl Alcohol (TAA)40-140
LCS-V27187 LCSD-V27187Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
33.0 82.585.234.140.0µg/LAcetone 40-160 3.2 20.0
19.8 99.099.519.920.0µg/LBenzene 70-130 0.5 20.0
18.6 93.091.518.320.0µg/LBromobenzene 70-130 1.6 20.0
21.4 10710420.720.0µg/LBromochloromethane 70-130 3.3 20.0
21.9 11010220.320.0µg/LBromodichloromethane 70-130 7.5 20.0
23.0 11511523.020.0µg/LBromoform 70-130 0.0 20.0
19.5 97.586.517.320.0µg/LBromomethane 60-140 11.9 20.0
18.8 94.091.518.320.0µg/Ln-Butylbenzene 70-130 2.6 20.0
17.8 89.085.017.020.0µg/Lsec-Butyl benzene 70-130 4.5 20.0
17.8 89.087.517.520.0µg/Ltert-Butyl benzene 70-130 1.6 20.0
23.6 11811322.520.0µg/LCarbon Tetrachloride 70-130 4.7 20.0
19.4 97.097.519.520.0µg/LChlorobenzene 70-130 0.5 20.0
21.9 11010821.620.0µg/LChlorodibromomethane 70-130 1.3 20.0
18.4 92.088.017.620.0µg/LChloroethane 60-140 4.4 20.0
20.0 10099.519.920.0µg/LChloroform 70-130 0.5 20.0
18.1 90.588.517.720.0µg/LChloromethane 60-140 2.2 20.0
18.8 94.091.018.220.0µg/L2-Chlorotoluene 70-130 3.2 20.0
18.0 90.086.017.220.0µg/L4-Chlorotoluene 70-130 4.5 20.0
18.4 92.096.519.320.0µg/LDi-Isopropyl Ether (DIPE)70-130 4.7 20.0
22.1 11111022.020.0µg/L1,2-Dibromo-3-Chloropropane 70-130 0.4 20.0
22.6 11311021.920.0µg/L1,2-Dibromoethane 70-130 3.1 20.0
Page 4 of 16* QC Fail Date:12/08/2022 04:16 PM
Page 51 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
LCS-V27187 LCSD-V27187Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.0 10510320.520.0µg/LDibromomethane 70-130 2.4 20.0
19.2 96.096.519.320.0µg/L1,2-Dichlorobenzene 70-130 0.5 20.0
19.5 97.596.519.320.0µg/L1,3-Dichlorobenzene 70-130 1.0 20.0
18.7 93.592.018.420.0µg/L1,4-Dichlorobenzene 70-130 1.6 20.0
18.5 92.587.017.420.0µg/LDichlorodifluoromethane 60-140 6.1 20.0
18.6 93.099.019.820.0µg/L1,1-Dichloroethane 70-130 6.2 20.0
19.5 97.597.519.520.0µg/L1,2-Dichloroethane 70-130 0.0 20.0
18.9 94.591.018.220.0µg/L1,1-Dichloroethene 70-130 3.7 20.0
19.2 96.094.018.820.0µg/Lcis-1,2-Dichloroethene 70-130 2.1 20.0
18.9 94.592.018.420.0µg/Ltrans-1,2-Dichloroethene 70-130 2.6 20.0
19.6 98.098.519.720.0µg/L1,2-Dichloropropane 70-130 0.5 20.0
19.2 96.098.519.720.0µg/L1,3-Dichloropropane 70-130 2.5 20.0
20.3 10298.019.620.0µg/L2,2-Dichloropropane 70-130 3.5 20.0
21.0 10510220.320.0µg/L1,1-Dichloropropene 70-130 3.3 20.0
21.8 10910420.820.0µg/Lcis-1,3-Dichloropropene 70-130 4.6 20.0
22.0 11011222.420.0µg/Ltrans-1,3-Dichloropropene 70-130 1.8 20.0
485 97.096.8484500µg/LEthanol 60-140 0.2 20.0
19.1 95.592.518.520.0µg/LEthylbenzene 70-130 3.1 20.0
21.2 10610420.820.0µg/LHexachlorobutadiene 70-130 1.9 20.0
18.7 93.591.518.320.0µg/L2-Hexanone 60-140 2.1 20.0
18.9 94.590.518.120.0µg/LIsopropylbenzene 70-130 4.3 20.0
18.9 94.592.018.420.0µg/L4-Isopropyl toluene 70-130 2.6 20.0
24.2 12170.014.020.0µg/LMethyl Ethyl Ketone (MEK)60-140 53.4*20.0
19.8 99.010120.120.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.5 20.0
19.8 99.010220.420.0µg/L4-Methyl-2-Pentanone 60-140 2.9 20.0
19.3 96.595.519.120.0µg/LMethylene Chloride 70-130 1.0 20.0
Page 5 of 16* QC Fail Date:12/08/2022 04:16 PM
Page 52 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
LCS-V27187 LCSD-V27187Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
22.5 11310621.120.0µg/LNaphthalene 70-130 6.4 20.0
18.0 90.088.017.620.0µg/Ln-Propylbenzene 70-130 2.2 20.0
20.0 10093.018.620.0µg/LStyrene 70-130 7.2 20.0
39.0 97.590.536.240.0µg/Ltert-Butyl Alcohol (TBA)40-140 7.4 20.0
45.3 11311345.340.0µg/Ltert-Butyl formate (TBF)40-140 0.0 20.0
41.0 10310441.440.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 0.9 20.0
23.0 11511523.020.0µg/L1,1,1,2-Tetrachloroethane 70-130 0.0 20.0
23.4 11711522.920.0µg/L1,1,2,2-Tetrachloroethane 70-130 2.1 20.0
19.3 96.592.018.420.0µg/LTetrachloroethene 70-130 4.7 20.0
19.0 95.094.518.920.0µg/LToluene 70-130 0.5 20.0
21.6 10810520.920.0µg/L1,2,3-Trichlorobenzene 70-130 3.2 20.0
20.8 10410220.420.0µg/L1,2,4-Trichlorobenzene 70-130 1.9 20.0
21.5 10810621.220.0µg/L1,1,1-Trichloroethane 70-130 1.4 20.0
21.4 10710320.620.0µg/L1,1,2-Trichloroethane 70-130 3.8 20.0
19.1 95.595.519.120.0µg/LTrichloroethene 70-130 0.0 20.0
19.2 96.090.518.120.0µg/LTrichlorofluoromethane 60-140 5.8 20.0
19.6 98.097.519.520.0µg/L1,2,3-Trichloropropane 70-130 0.5 20.0
18.1 90.589.017.820.0µg/L1,2,4-Trimethylbenzene 70-130 1.6 20.0
18.5 92.587.517.520.0µg/L1,3,5-Trimethylbenzene 70-130 5.5 20.0
22.8 11410320.620.0µg/LVinyl Acetate 60-140 10.1 20.0
18.1 90.595.019.020.0µg/LVinyl Chloride 60-140 4.8 20.0
19.1 95.593.018.620.0µg/Lo-Xylene 70-130 2.6 20.0
39.4 98.595.538.240.0µg/Lm,p-Xylene 70-130 3.0 20.0
22.3 11210020.020.0µg/L3,3-Dimethyl-1-butanol 70-130 10.8 20.0
98.697.64-Bromofluorobenzene (S)70-130
109112Dibromofluoromethane (S)70-130
Page 6 of 16Date:12/08/2022 04:16 PM
Page 53 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27188QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27187
LCS-V27187 LCSD-V27187Laboratory Control Sample & LCSD
LCSD
ResultParameter
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
1031041,2-Dichloroethane - d4 (S)70-130
99.4100Toluene-d8 (S)70-130
Page 7 of 16Date:12/08/2022 04:16 PM
Page 54 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27277QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27276
Associated Lab Samples: 94301, 94303, 94305
LRB-V27276 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/02/22 13:410.5000.180<0.180µg/LBenzene
12/02/22 13:410.5000.170<0.170µg/LEthylbenzene
12/02/22 13:4110.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
12/02/22 13:414-Bromofluorobenzene (S)101 70-130
12/02/22 13:41Dibromofluoromethane (S)108 70-130
12/02/22 13:411,2-Dichloroethane - d4 (S)99.2 70-130
12/02/22 13:41Toluene-d8 (S)99.2 70-130
LCS-V27276 LCSD-V27276Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.0 10010120.120.0µg/LBenzene 70-130 0.4 20.0
18.8 94.098.519.720.0µg/LEthylbenzene 70-130 4.6 20.0
34.5 86.292.236.940.0µg/Ltert-Butyl Alcohol (TBA)40-140 6.7 20.0
99.495.84-Bromofluorobenzene (S)70-130
110109Dibromofluoromethane (S)70-130
1011021,2-Dichloroethane - d4 (S)70-130
97.4100Toluene-d8 (S)70-130
Page 8 of 16Date:12/08/2022 04:16 PM
Page 55 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
Associated Lab Samples: 94302
LRB-V27417 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 15:3310.01.80<1.80µg/LAcetone
12/06/22 15:330.5000.180<0.180µg/LBenzene
12/06/22 15:330.5000.210<0.210µg/LBromobenzene
12/06/22 15:331.000.420<0.420µg/LBromochloromethane
12/06/22 15:330.5000.160<0.160µg/LBromodichloromethane
12/06/22 15:335.001.50<1.50µg/LBromoform
12/06/22 15:331.000.280<0.280µg/LBromomethane
12/06/22 15:330.5000.180<0.180µg/Ln-Butylbenzene
12/06/22 15:330.5000.200<0.200µg/Lsec-Butyl benzene
12/06/22 15:332.000.920<0.920µg/Ltert-Butyl benzene
12/06/22 15:330.5000.180<0.180µg/LCarbon Tetrachloride
12/06/22 15:330.5000.190<0.190µg/LChlorobenzene
12/06/22 15:330.5000.190<0.190µg/LChlorodibromomethane
12/06/22 15:331.000.430<0.430µg/LChloroethane
12/06/22 15:330.5000.220<0.220µg/LChloroform
12/06/22 15:330.5000.220<0.220µg/LChloromethane
12/06/22 15:330.5000.200<0.200µg/L2-Chlorotoluene
12/06/22 15:330.5000.200<0.200µg/L4-Chlorotoluene
12/06/22 15:330.5000.500<0.500µg/LDi-Isopropyl Ether (DIPE)
12/06/22 15:332.001.10<1.10µg/L1,2-Dibromo-3-Chloropropane
12/06/22 15:330.5000.200<0.200µg/L1,2-Dibromoethane
12/06/22 15:330.5000.230<0.230µg/LDibromomethane
12/06/22 15:330.5000.220<0.220µg/L1,2-Dichlorobenzene
12/06/22 15:330.5000.190<0.190µg/L1,3-Dichlorobenzene
12/06/22 15:330.5000.210<0.210µg/L1,4-Dichlorobenzene
12/06/22 15:335.001.20<1.20µg/LDichlorodifluoromethane
12/06/22 15:330.5000.240<0.240µg/L1,1-Dichloroethane
Page 9 of 16Date:12/08/2022 04:16 PM
Page 56 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
Associated Lab Samples: 94302
LRB-V27417 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 15:330.5000.150<0.150µg/L1,2-Dichloroethane
12/06/22 15:330.5000.150<0.150µg/L1,1-Dichloroethene
12/06/22 15:330.5000.200<0.200µg/Lcis-1,2-Dichloroethene
12/06/22 15:330.5000.180<0.180µg/Ltrans-1,2-Dichloroethene
12/06/22 15:330.5000.190<0.190µg/L1,2-Dichloropropane
12/06/22 15:330.5000.130<0.130µg/L1,3-Dichloropropane
12/06/22 15:332.000.210<0.210µg/L2,2-Dichloropropane
12/06/22 15:330.5000.200<0.200µg/L1,1-Dichloropropene
12/06/22 15:330.5000.210<0.210µg/Lcis-1,3-Dichloropropene
12/06/22 15:330.5000.150<0.150µg/Ltrans-1,3-Dichloropropene
12/06/22 15:3320042.0<42.0µg/LEthanol
12/06/22 15:330.5000.170<0.170µg/LEthylbenzene
12/06/22 15:333.000.350<0.350µg/LHexachlorobutadiene
12/06/22 15:331.000.380<0.380µg/L2-Hexanone
12/06/22 15:330.5000.180<0.180µg/LIsopropylbenzene
12/06/22 15:330.5000.089<0.089µg/L4-Isopropyl toluene
12/06/22 15:335.000.710<0.710µg/LMethyl Ethyl Ketone (MEK)
12/06/22 15:331.000.140<0.140µg/LMethyl tert-butyl ether (MTBE)
12/06/22 15:331.000.078<0.078µg/L4-Methyl-2-Pentanone
12/06/22 15:332.000.330<0.330µg/LMethylene Chloride
12/06/22 15:331.000.470<0.470µg/LNaphthalene
12/06/22 15:330.5000.190<0.190µg/Ln-Propylbenzene
12/06/22 15:330.5000.220<0.220µg/LStyrene
12/06/22 15:3310.01.60<1.60µg/Ltert-Butyl Alcohol (TBA)
12/06/22 15:3310.00.350<0.350µg/Ltert-Butyl formate (TBF)
12/06/22 15:3310.00.280<0.280µg/Ltert-Amyl Methyl Ether (TAME)
12/06/22 15:330.5000.160<0.160µg/L1,1,1,2-Tetrachloroethane
Page 10 of 16Date:12/08/2022 04:16 PM
Page 57 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
Associated Lab Samples: 94302
LRB-V27417 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/06/22 15:330.5000.160<0.160µg/L1,1,2,2-Tetrachloroethane
12/06/22 15:330.5000.220<0.220µg/LTetrachloroethene
12/06/22 15:330.5000.220<0.220µg/LToluene
12/06/22 15:330.5000.380<0.380µg/L1,2,3-Trichlorobenzene
12/06/22 15:330.5000.310<0.310µg/L1,2,4-Trichlorobenzene
12/06/22 15:330.5000.160<0.160µg/L1,1,1-Trichloroethane
12/06/22 15:330.5000.096<0.096µg/L1,1,2-Trichloroethane
12/06/22 15:330.5000.180<0.180µg/LTrichloroethene
12/06/22 15:330.5000.180<0.180µg/LTrichlorofluoromethane
12/06/22 15:330.5000.270<0.270µg/L1,2,3-Trichloropropane
12/06/22 15:330.5000.190<0.190µg/L1,2,4-Trimethylbenzene
12/06/22 15:330.5000.180<0.180µg/L1,3,5-Trimethylbenzene
12/06/22 15:335.001.00<1.00µg/LVinyl Acetate
12/06/22 15:330.5000.170<0.170µg/LVinyl Chloride
12/06/22 15:330.5000.210<0.210µg/Lo-Xylene
12/06/22 15:331.000.420<0.420µg/Lm,p-Xylene
12/06/22 15:3310.01.00<1.00µg/L3,3-Dimethyl-1-butanol
12/06/22 15:334-Bromofluorobenzene (S)99.6 70-130
12/06/22 15:33Dibromofluoromethane (S)109 70-130
12/06/22 15:331,2-Dichloroethane - d4 (S)98.8 70-130
12/06/22 15:33Toluene-d8 (S)97.8 70-130
LCS-V27417Laboratory Control Sample
Parameter
LCS %RecLCS
Result
Spike
Conc.Units
% Rec
Limits
11923.820.0µg/L1,2-Dibromo-3-Chloropropane 70-130
Page 11 of 16Date:12/08/2022 04:16 PM
Page 58 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
LCS-V27417 LCSD-V27417Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
32.5 81.280.032.040.0µg/LAcetone 40-160 1.5 20.0
21.4 10711222.420.0µg/LBenzene 70-130 4.5 20.0
19.9 99.510821.520.0µg/LBromobenzene 70-130 7.7 20.0
21.1 10612124.120.0µg/LBromochloromethane 70-130 13.2 20.0
24.8 12412925.720.0µg/LBromodichloromethane 70-130 3.5 20.0
22.2 11111923.820.0µg/LBromoform 70-130 6.9 20.0
17.9 89.593.518.720.0µg/LBromomethane 60-140 4.3 20.0
20.9 10510821.520.0µg/Ln-Butylbenzene 70-130 2.8 20.0
19.2 96.010220.420.0µg/Lsec-Butyl benzene 70-130 6.0 20.0
19.4 97.010521.020.0µg/Ltert-Butyl benzene 70-130 7.9 20.0
25.3 127132*26.420.0µg/LCarbon Tetrachloride 70-130 4.2 20.0
20.4 10211022.020.0µg/LChlorobenzene 70-130 7.5 20.0
23.3 11712124.120.0µg/LChlorodibromomethane 70-130 3.3 20.0
19.2 96.010220.320.0µg/LChloroethane 60-140 5.5 20.0
20.6 10310921.820.0µg/LChloroform 70-130 5.6 20.0
18.2 91.095.519.120.0µg/LChloromethane 60-140 4.8 20.0
20.2 10110821.520.0µg/L2-Chlorotoluene 70-130 6.2 20.0
19.5 97.510520.920.0µg/L4-Chlorotoluene 70-130 6.9 20.0
20.6 10310621.220.0µg/LDi-Isopropyl Ether (DIPE)70-130 2.8 20.0
23.1 11612124.120.0µg/L1,2-Dibromoethane 70-130 4.2 20.0
21.8 10911021.920.0µg/LDibromomethane 70-130 0.4 20.0
20.8 10410621.220.0µg/L1,2-Dichlorobenzene 70-130 1.9 20.0
21.3 10711021.920.0µg/L1,3-Dichlorobenzene 70-130 2.7 20.0
20.1 10110821.520.0µg/L1,4-Dichlorobenzene 70-130 6.7 20.0
17.6 88.094.518.920.0µg/LDichlorodifluoromethane 60-140 7.1 20.0
20.9 10511422.820.0µg/L1,1-Dichloroethane 70-130 8.6 20.0
Page 12 of 16* QC Fail Date:12/08/2022 04:16 PM
Page 59 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
LCS-V27417 LCSD-V27417Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
20.7 10411022.020.0µg/L1,2-Dichloroethane 70-130 6.0 20.0
21.1 10611022.020.0µg/L1,1-Dichloroethene 70-130 4.1 20.0
20.3 10210921.720.0µg/Lcis-1,2-Dichloroethene 70-130 6.6 20.0
21.0 10511222.420.0µg/Ltrans-1,2-Dichloroethene 70-130 6.4 20.0
20.5 10311021.920.0µg/L1,2-Dichloropropane 70-130 6.6 20.0
20.2 10110621.120.0µg/L1,3-Dichloropropane 70-130 4.3 20.0
22.4 11211523.020.0µg/L2,2-Dichloropropane 70-130 2.6 20.0
22.8 11411522.920.0µg/L1,1-Dichloropropene 70-130 0.4 20.0
22.9 11512224.320.0µg/Lcis-1,3-Dichloropropene 70-130 5.9 20.0
24.1 12112525.020.0µg/Ltrans-1,3-Dichloropropene 70-130 3.6 20.0
516 10388.4442500µg/LEthanol 60-140 15.4 20.0
20.1 10110520.920.0µg/LEthylbenzene 70-130 3.9 20.0
22.7 11411923.720.0µg/LHexachlorobutadiene 70-130 4.3 20.0
18.1 90.590.518.120.0µg/L2-Hexanone 60-140 0.0 20.0
20.6 10311022.020.0µg/LIsopropylbenzene 70-130 6.5 20.0
20.9 10510821.520.0µg/L4-Isopropyl toluene 70-130 2.8 20.0
15.0 75.072.014.420.0µg/LMethyl Ethyl Ketone (MEK)60-140 4.0 20.0
20.8 10410621.220.0µg/LMethyl tert-butyl ether (MTBE)70-130 1.9 20.0
20.8 10499.019.820.0µg/L4-Methyl-2-Pentanone 60-140 4.9 20.0
20.4 10210821.520.0µg/LMethylene Chloride 70-130 5.2 20.0
22.7 11410821.520.0µg/LNaphthalene 70-130 5.4 20.0
20.0 10010521.020.0µg/Ln-Propylbenzene 70-130 4.8 20.0
20.2 10110721.320.0µg/LStyrene 70-130 5.3 20.0
38.3 95.793.737.540.0µg/Ltert-Butyl Alcohol (TBA)40-140 2.1 20.0
45.7 11412248.940.0µg/Ltert-Butyl formate (TBF)40-140 6.7 20.0
42.2 10611044.140.0µg/Ltert-Amyl Methyl Ether (TAME)40-140 4.4 20.0
Page 13 of 16Date:12/08/2022 04:16 PM
Page 60 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27418QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27417
LCS-V27417 LCSD-V27417Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
24.9 12512424.820.0µg/L1,1,2,2-Tetrachloroethane 70-130 0.4 20.0
19.6 98.011021.920.0µg/LTetrachloroethene 70-130 11.0 20.0
20.5 10310821.620.0µg/LToluene 70-130 5.2 20.0
22.1 11111122.120.0µg/L1,2,3-Trichlorobenzene 70-130 0.0 20.0
21.4 10711122.120.0µg/L1,2,4-Trichlorobenzene 70-130 3.2 20.0
24.4 12212224.420.0µg/L1,1,1-Trichloroethane 70-130 0.0 20.0
21.8 10911322.620.0µg/L1,1,2-Trichloroethane 70-130 3.6 20.0
20.8 10411222.320.0µg/LTrichloroethene 70-130 6.9 20.0
19.4 97.010320.620.0µg/LTrichlorofluoromethane 60-140 6.0 20.0
20.0 10099.519.920.0µg/L1,2,3-Trichloropropane 70-130 0.5 20.0
19.8 99.010420.820.0µg/L1,2,4-Trimethylbenzene 70-130 4.9 20.0
19.9 99.510621.220.0µg/L1,3,5-Trimethylbenzene 70-130 6.3 20.0
25.0 12510721.420.0µg/LVinyl Acetate 60-140 15.5 20.0
18.8 94.096.019.220.0µg/LVinyl Chloride 60-140 2.1 20.0
19.8 99.010621.120.0µg/Lo-Xylene 70-130 6.3 20.0
41.0 10310943.640.0µg/Lm,p-Xylene 70-130 6.1 20.0
21.8 10910020.020.0µg/L3,3-Dimethyl-1-butanol 70-130 8.6 20.0
10299.24-Bromofluorobenzene (S)70-130
111114Dibromofluoromethane (S)70-130
10099.41,2-Dichloroethane - d4 (S)70-130
97.298.0Toluene-d8 (S)70-130
Page 14 of 16Date:12/08/2022 04:16 PM
Page 61 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Volatile Organic Compounds - GC/MS
6200B
V27487QC Analytical Batch(es):
Analysis Method:
Analysis Description:
6200 PT
QC Prep:V27486
Associated Lab Samples: 94302
LRB-V27486 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
12/07/22 13:4010.01.90<1.90µg/Ltert-Amyl Alcohol (TAA)
12/07/22 13:404-Bromofluorobenzene (S)102 70-130
12/07/22 13:40Dibromofluoromethane (S)107 70-130
12/07/22 13:401,2-Dichloroethane - d4 (S)97.2 70-130
12/07/22 13:40Toluene-d8 (S)98.6 70-130
LCS-V27486 LCSD-V27486Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
21.8 10910220.420.0µg/Ltert-Amyl Alcohol (TAA)40-140 6.6 20.0
1041014-Bromofluorobenzene (S)70-130
113113Dibromofluoromethane (S)70-130
10098.81,2-Dichloroethane - d4 (S)70-130
10099.4Toluene-d8 (S)70-130
Page 15 of 16Date:12/08/2022 04:16 PM
Page 62 of 65
Quality Control Data
22-334-0002Report No:
Project Description:
Client ID:Geological Resources, Inc.
Market Cafe
QC Prep Batch Method:
Massachusetts VPH
MADEP-VPH
V27071QC Analytical Batch(es):
Analysis Method:
Analysis Description:
MAVPH (Prep)
QC Prep:V27070
Associated Lab Samples: 94301, 94302, 94303, 94304, 94305, 94306
LRB-V27070 Matrix: AQULab Reagent Blank
Parameter
AnalyzedMQLMDLBlank
ResultUnits
%
Recovery
% Rec
Limits
11/30/22 16:1350.011.5<11.5µg/LAliphatic C5-C8
11/30/22 16:1350.025.8<25.8µg/LAliphatic C9-C12
11/30/22 16:1350.04.02<4.02µg/LAromatic C9-C10
11/30/22 16:132,5-Dibromotoluene (FID) (S)78.1 70-130
11/30/22 16:132,5-Dibromotoluene (PID) (S)105 70-130
LCS-V27070 LCSD-V27070Laboratory Control Sample & LCSD
LCSD
ResultParameter Max
RPD
LCSD
% Rec
LCS
%Rec
LCS
Result
Spike
Conc.Units
% Rec
Limits RPD
304 10197.6293300µg/LAliphatic C5-C8 70-130 3.6 50.0
374 125121362300µg/LAliphatic C9-C12 70-130 3.2 50.0
93.5 93.5110110100µg/LAromatic C9-C10 70-130 16.2 50.0
76.779.02,5-Dibromotoluene (FID) (S)70-130
1041062,5-Dibromotoluene (PID) (S)70-130
Page 16 of 16Date:12/08/2022 04:16 PM
Page 63 of 65
Fed Ex
UPS
US Postal
Client
Lab
Courier
Other :
Shipment Receipt Form
Customer Number:
Customer Name:
Report Number:22-334-0002
Geological Resources, Inc.
00087
Shipping Method
Shipping container/cooler uncompromised?
Thermometer ID:IRT-15 1.7C
Chain of Custody (COC) present?Yes No
Yes No Not Present
Yes No Not Present
Yes No
COC agrees with sample label(s)? Yes No
COC properly completed
Samples in proper containers?
Sample containers intact?
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
Cooler temperature in compliance?
Yes No
Yes No
Yes No
Yes No
Yes No
Yes NoCooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
Yes No
Yes No N/A
Yes No N/A
Yes No N/ASoil VOA method 5035 – compliance criteria met
Water - Sample containers properly preserved
Water - VOA vials free of headspace Yes No N/A
Trip Blanks received with VOAs
Low concentration EnCore samplers (48 hr)
High concentration pre-weighed (methanol -14 d) Low conc pre-weighed vials (Sod Bis -14 d)
High concentration container (48 hr)
Custody seals intact on shipping container/cooler?
Custody seals intact on sample bottles?
Number of coolers/boxes received
Yes No
1
Signature:Angelo Norvell Date & Time:11/30/2022 10:45:15
Special precautions or instructions included?
Comments:
Page 64 of 65
Page 65 of 65