FA-3404_21877_CA_LSA_20000927

I:;-COOPER ENVIRONMENTAL a;., ENGINEERS • GEOLOGISTS • SCIENTISTS September 27, 2000 Mr. Zahid M. Baloch NCDENR, UST Section Raleigh Regional Office 3800 Barrett Drive, Suite 101 Raleigh, North Carolina 27609 Re: Phase ILSA Report City of Sanford Water Treatment Plant 7 441 Poplar Springs Church Road ·. =~:-:.:::: ;:,._:_::)?'.-'. ?~?~?-'-:,,:"fi'.:'.:~ •--•-,,--,.., n• • ~ _j) :Z,l O 'fi t,D Lee County, North Carolina ~.11 CEI Project No. 20172 <j;,,,v . 1 Dear: Mr. Baloch: On behalf of the city of Sanford, Cooper Environmental, Inc. (CEI) is submitting the Phase I Limited Site Assessment (LSA) for the city water treatment plant. If you have questions or comments, please contact me at [phone]. Sincerely, COO ER ENVI,,ONMENTAL, INC. . prmdJ cc: Phillip (Hal) Hegwer, City of Sanford Engineering Department dlp\c\projects\20172-Sanford\LSACover ncdenr 2300 SARDIS ROAD NORTH, SUITE Q, CHARLOTTE, NORTH CAROLINA 28227 [phone] •FAX [phone] I • www.coopereng.com
I I I I I I I I I I I I I I I I I I I I LIMITED SITE ASSESSMENT REPORT CITY OF SANFORD SANFORD CITY WATER TREATMENT PLANT 7 441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, NORTH CAROLINA SEPTEMBER 2000 CEI PROJECT NO. 20172 FACILITY ID#: 0-017257 NCDENR GROUND WATER INCIDENT NO. TBD PREPARED FOR CITY OF SANFORD, ENGINEERING DEPARTMENT PO BOX3729 225 EAST WEATHERSPOON STREET SANFORD, NORTH CAROLINA 27331-3729 : •. PREPARED BY COOPER ENVIRONMENTAL, INC. 2300 SARDIS ROAD NORTH, SUITE Q CHARLOTTE, NORTH CAROLINA 28227
I I I I I I I I I I I I I I I I I I I I SUMMARY INFORMATION SANFORD CITY WATER TREATMENT PLANT 7 441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, SANFORD, NORTH CAROLINA CEI PROJECT NO. 20172 FACILITY ID#: 0-017257 DATE OF REPORT: SEPTEMBER 2000 OWNER OF SITE: CI1Y OF SANFORD ·po BOX 3729 225 EAST WEATHERSPOON STREET SANFORD, NORTH CAROLINA 27331-3729 CURRENT PROPERTY OWNER, ADDRESS, AND TELEPHONE NUMBER: CI1Y OF SANFORD PO BOX3729 225 EAST WEATHERSPOON STREET SANFORD, NORTH CAROLINA 27331-3729 [phone] CONSULTANT, ADDRESS, AND TELEPHONE NUMBER: COOPER ENVIRONMENTAL, INC. 2300 SARDIS ROAD NORTH, SUITE Q CHARLOTIE, NORTH CAROLINA 28227 [phone]
I I I I I .I I I I I I I I I I I I I I SUMMARY INFORMATION (PAGE 2) RELEASE DISCOVERY DATE: OCTOBER 1999 ESTIMATED QUANTITY OF RELEASE: UNKNOWN CAUSE OF RELEASE: SUSPECTED LEAKING UST SOURCE OF RELEASE: LEAKING 5,000-GALLON DIESEL UST SIZE AND CONTENTS OF UST FROM WHICH RELEASE OCCURRED: 5,000-GALLON DIESEL UST LATITUDE/LONGITUDE: NORTH 35° 32' 08" /WEST 79° 02' 51" THIS REPORT WAS PREPARED BY COOPER ENVIRONMENTAL, INC. 1, ,· '' .... . .:, ROBERT S. HIROt.P:·G< c ,', ·.: . · .< · ·:' ~~/).::..,' C. •:•, •• ,~ • .• .• • • -._:': \: •,••~ / • VICE PRESIDENT, GEO~d"Bot:R¥!J,~\91f· NORTH CAROLINA LICENSED GEOLOGIST NO. 1247
I I I I I I I I I I I I I I I I I I I TABLE OF CONTENTS 1.0 SITE HISTORY 2.0 RISK CHARACTERIZATION 3.0 RECEPTOR INFORMATION 3.1 Water Supply Wells 3.2 Public Water Supplies 3 .3 Surface Water 3. 4 Wellhead Protection Areas 3.5 Deep Aquifers in the Coastal Plain Physiographic Region 3.6 Subsurface Structures 3.7 Land Use 3.8 Property Owners and Occupants 4.0 SITE GEOLOGY AND HYDROGEOLOGY 5.0 PHASE I INVESTIGATION 6.0 SAMPLING RESULTS 7 .0 CONCLUSIONS AND RECOMMENDATIONS 8.0 REMARKS 9.0 REFERENCES
I I I I I I I I I I I I I I I I I I I Table 1: Table 2: Table 3: Table 4: Figure 1: Figure 2: Figure 3: TABLES Adjacent Property Ownership Information LSA Results for Volatile and Semi-Volatile Analyses LSA Results for Volatile and Extractable Petroleum Hydrocarbons Analyses LSA Ground Water Analytical Results FIGURES Topographic Location Map UST Closure Sampling Location Map Phase I LSA Sampling Location Map APPENDICES Appendix A: Tax Records Appendix B: LSA Risk Classification and Land Use Form Appendix C: Soil Boring Log Appendix D: Well Construction Record Appendix E: Soil Laboratory Analytical Results Appendix F: Ground Water Laboratory Analytical Results
I I I I I I I I I I I I I I I I I I I 1.0 SITE HISTORY Cooper Environmental, Inc. (CEI) was contracted on behalf of the City of Sanford (Sanford) to conduct a Phase I Limited Site Assessment (LSA) Report associated with a release of petroleum from a leaking underground storage tank (UST). The subject site is located at 7441 Poplar Springs Church Road in Lee County near Sanford, North Carolina. See Figure 1 for the Topographic Location Map. Petroleum-impacted soils were encountered during the removal of one 5,000-gallon diesel UST on October 18, 1999. Soil samples collected beneath the UST confirmed the presence of petroleum impacted soils. Approximately 200 tons of petroleum-impacted soil was transported to Soil Reclaiming Inc. (Lee Brick) in Sanford, North Carolina for treatment. Environmental Answers, LLC summarized the removal operations in the UST Closure Report dated November 1999. Figure 2 is included which illustrates the UST closure sampling locations with laboratory results. The North Carolina Department of Environment, Health and Natural Resources (NCDENR) issued a Notice of Regulatory Requirements (NORR) letter to the City of Sanford dated June 2, 2000. This report contains results of the Phase I LSA, which CEI conducted on August 8, and September 5, 2000. CEI used an excerpt for the LSA from the NCDENR's Groundwater Section Guidelines for the Investigation and Remediation of Soil and Groundwater dated January 2, 1998 as a guide. 2.0 RISK CHARACTERIZATION CEI gathered information concerning the risk and land use required to characterize the site. CEI reconnoitered the area within 1,500 feet of the site. CEI looked for water supply wells, surface waters, and other pertinent features during this reconnaissance. CEI did not identify any active water supply wells within 1,500 feet of the site. CEI reviewed tax records and zoning status files for the subject site and surrounding properties at the City of Sanford Engineering Department. The tax map and records are included in Appendix A. The zoning review indicates that the subject
I I I I I I I I I I I I I I I I I I I site and all the immediate surrounding properties are zoned as residential agricultural (RA). CEI completed the "Limited Site Assessment Ris.k Classification and Land Use Form" which is included in NCDENR guidelines dated January 2, 1998. The completed form may be found in Appendix B. 3.0 RECEPTOR INFORMATION 3.1 Water Supply Wells CEI conducted a water supply well search of the area within a 1,500-foot radius of the subject site during the Phase I LSA activities. CEI did not identify water supply wells located within the search area. 3.2 Public Water Supplies CEI did a visual search for public water supplies within 1,500 feet of the subject site. There are no public water supply source areas within 1,500 feet of the site. The source for the municipal water supply for the Sanford Water Treatment Plant is the Cape Fear River located approximately 1 ½ miles northeast of the subject site. CEI also reviewed city water maps for the subject site and surrounding properties. The subject site and surrounding properties are connected or have access to the municipal potable water system for consumptive use. 3.3 Surface Water An intermittent surface water stream is illustrated on the Moncure, North Carolina USGS topographic quadrangle map approximately 1,000 feet northwest of the subject site. However, CEI did not observe water flowing in this unnamed surface water body during the reconnaissance. 2
I I I I I I I I I I I I I I I I I I I 3.4 Wellhead Protection Areas CEI contacted Mr. John Maloy of the NCDENR, Raleigh Regional Office about the wellhead protection areas. CEI was informed that there are currently no wellhead protection areas located within Lee County. 3.5 Deep Aquifers in the Coastal Plain Physiographic Area The site is located in the Piedmont Physiographic range, which is located west of the Coastal Plain Physiographic area. 3.6 Subsurface Structures The pump building facility has a basement containing large pumps used to pump water to the distribution system. Water distribution lines are located throughout the water treatment plant and in front of the facility along Highway 42. The source area petroleum impacted soils were excavated and removed during the UST closure. The area over the former UST is covered by a concrete pad, w;b.ich should eliminate vapors that could cause a threat to human health or the environment. 3.7 Land Use The subject site, which is the city water treatment plant, is zoned as residential agricultural (RA). The properties located to the immediate north, south, east and west are also zoned RA. Current and projected future use of the subject site and the immediate surrounding properties should remain as residential agricultural. 3.8 Property Owners and Occupants CEI obtained names through the City of Sanford GIS system to gather the names and addresses of property owners contiguous to the subject site. Please refer to Table 1 for the adjacent property ownership and Appendix A for tax map and tax records. 3
I I I I I I I I I I I I I I I I I I I 4.0 SITE GEOLOGY AND HYDROLOGY The subject property is situated within the Sanford Formation of the Triassic Basin of the Piedmont Physiographic province. Based on CEI's review of the North Carolina Geologic Map dated 1985, the underlying bedrock at the site consists of conglomerate, sandstone and mudstone of Triassic age. The overburden soils consist of unconsolidated regolith consisting of red-brown, silty clay, which grade in depth to dark red-brown, tight clay. Intercalated layers of highly weathered saprolitic bedrock also exist at intermittent intervals in the regolith. 5.0 PHASE I INVESTIGATION On August 9, 2000, CE! observed American Environmental Drilling Service (AEDS) advance one soil boring near the southeast corner of the pump building near the former location of the diesel UST. Due to the presence of an underground electric line and a new concrete pad with above ground storage tanks (ASTs), the soil boring was placed as close as possible to the former UST location. See Figure 3 for the soil boring location. AEDS utilized an Ingersol Rand mobile drilling rig utilizing hollow stem auger (HSA) drilling technique. The purpose of the soil boring labeled SB-1 was to collect soil samples every five feet in the unsaturated zone between land surface and the water table and visually describe soil cuttings. Competent bedrock was encountered at 24 feet below grade level (BGL) and the hollow stem auger would not penetrate further. Refer to Appendix C for the Soil Boring Log. Petroleum-impacted soils were previously excavated to a reported depth of 15 feet BGL and subsequently backfilled with clean soils and crush and run. Upon completion of soil sampling, a permanent monitoring well was inserted into soil boring SB-1. Monitoring well MW-1 was constructed of two-inch inside diameter (ID) PVC screen and riser pipe. The monitoring well was screened from 24 to 9 feet BGL with 0.010-inch slotted screen. A two-inch ID riser pipe was attached to the well screen and extended to land surface. A gravel sand pack was placed from 24 to 7 feet BGL with a two-foot overlying bentonite seal. The remaining annular space was cement grouted to grade level. The well head was finished flush to grade with a steel manhole cover and bolt down lid. Soil cuttings generated during the installation 4
I I I I I I I I I I I I I I I I I ·I I I of the monitoring well thin spread onto an adjacent grassy area. Appendix D contains a copy of the well construction record. Based upon visual observation during drilling activities, the water table appeared to be at approximately 20 feet BGL. Therefore, the well was set to 24 feet BGL. However, ground water failed to enter the monitoring well for a period of one to two weeks. CEI submitted soil samples from the 5, 10, 15 and 20 intervals for laboratory analysis. Since ground water appeared to be at a depth greater than 25 feet BGL, CEI instructed the laboratory to not analyze the 10-foot soil sample. CEI intended to analyze soil samples at ten-foot centers, however there was no recovery at 25 feet BGL. Therefore, CEI instructed the laboratory to analyze soil samples at 5, 15 and 20 feet BGL in order to fulfill the NCDENR sampling requirements. CEI submitted the soil samples by chain of custody procedure to Pace Analytical Services (Pace). Pace is a North Carolina certified environmental laboratory. CEI instructed Pace to analyze each soil sample for volatile organic compounds (VOCs), semi-volatile organic compounds (SVOCs), volatile petroleum hydrocarbons (VPH) and extractable petroleum hydrocarbons (EPH) in accordance with US EPA Methods 8260 and 8270 and the Massachusetts Department of Environmental Protection (MADEP) methodologies. CEI intended to drill a monitoring well using air hammer technique in order to penetrate the competent bedrock. Prior to mobilization, CEI contacted with the City Water Treatment personnel to check MW-1 for ground water. Sanford personnel reported ground water at approximately 20 feet BGL on August 31, 2000. CEI measured the static water level at 19.83 feet on September 5, 2000. This would suggest that the formation that the shallow aquifer is in tightly compacted above the weathered and competent bedrock interface and is slow to recharge. The accumulation of ground water appears to allow the advection of addition ground water to the monitoring well. On September 5, 2000 CEI purged three well volumes prior to collecting a representative ground water sample. The ground water sample was then withdrawn from MW-1 with a polypropylene disposable bailer. The ground water sample was submitted to Pace for analyses for purgeable halocarbons and aromatics following EPA Method 602 including xylenes, base/neutral/ acids to include the ten 5
I I I I I I I I I I I I I I I I I I I highest tentatively identified compounds (TICs) in accordance with EPA Method 625, and VPH and EPH by the MADEP Methodologies. 6.0 SAMPLING RESULTS The Pace Analytical report did not indicate the presence of petroleum constituents in the soil samples collected at the 5 and 15-foot intervals. The soil sample collected at the 20-foot interval reported VPH concentrations of 43 milligrams per kilogram (mg/kg) in the CS-C8 aliphatic range and 23 mg/kg in the C9-C10 aromatic range. The 20-foot soil sample was collected at the capillary fringe and may not be representative of soil impact. The reported concentrations are below the NCDENR soil-to-groundwater, residential and industrial\commercial exposure scenarios. The analytical report did not indicate the presence of any other petroleum constituents in the soil samples analyzed. Laboratory results for the soil samples are summarized in Tables 2 and 3. The Pace soil laboratory analytical results are included as Appendix E. The Pace analytical report did not indicate petroleum concentrations in the ground water sample collected on September 5, 2000. Therefore, the ground water quality sample does not exceed any of the North Carolina Administrative Code (NCAC), subchapter 2L reporting standards (!SA NCAC 2L). No constituent analyzed for from the ground water sample were above the most restrictive soil-to-groundwater standard. The ground water laboratory report for the September 5, 2000 sampling event is attached as Appendix F. Analytical results for the ground water sample collected during the Phase ILSA are summarized in Table 4. 7.0 CONCLUSIONS AND RECOMMENDATIONS Environmental Answers, LLC reported that 200 tons of petroleum impacted soils were removed at the time of the UST removal. Based on the amount of impacted soil removed at the time of UST closure, it appears that the majority of the source area has been removed. The former excavation has been backfilled with crush and run rock and a concrete pad with ASTs covers the former excavation. Therefore, human exposure to petroleum-impacted soil or accumulation of vapors is unlikely. 6
I I I I I I I I I I I I I I I I I I I The laboratory reported soil concentrations are below the most restrictive soil-to-groundwater standard. The laboratory reported ground water concentrations are below the 15A NCAC 2L ground water standards. Based on the Phase I LSA investigation, the site should be classified as low risk. Based upon the aforementioned information, CEI recommends a low risk classification for the subject site. To that extent, CEI recommends NCDENR issue a "no further action" letter and close the site. 8.0 REMARKS The analyses contained in this report represents CEI's professional opinions and are based upon the finding of its investigation. These opinions were developed in accordance with currently accepted hydrogeologic and engineering practices at this time and location and no warranties or guarantees are intended or implied. Many of the opinions in this report are based upon the work and statements of others, including but not limited to laboratory reports. CEI assumes this work and these statements are accurate. 9.0 REFERENCES Environmental Answers, LLC, Underground Storage Tank Closure Report, November 17, 1999, City of Sanford Water Treatment Plant, 7 441 Poplar Springs Church Road, Sanford, North Carolina, unpublished professional report. Brown, P.M., Chief Compiler, 1985, Geologic Map of North Carolina, North Carolina Geologic Survey, Raleigh, North Carolina, scale 1:500,000. North Carolina Administrative Code, Title 15A, Subchapter 2L. Sections .0106 to .0115. North Carolina Department of Environment and Natural Resources, January 2, 1998, Ground Water Section Guidelines for the Investigation and Remediation of Soils and Groundwater, Raleigh, North Carolina, 195 pp. DLP\bmh \c\projects\20172-Sanford Water Plant\ Water Plant-LSA.doc 7
I I I I I I I I I TABLES I I I I I I I I ·1 I : I .. . --~. --
- - - - -- - --TA.M -- -----MAP !ADDRESS OF PROPERTY # (COMMENT) 7441 POPLAR SPRINGS CHURCH ROAD 1 CITY WATER TREATMENT PLANT POPLAR SPRINGS CHURCH ROAD 2 CITY WATER TREATMENT PLANT POPLAR SPRINGS CHURCH ROAD 3AND4 POPLAR SPRINGS CHURCH ROAD 5 AND 6 POPLAR SPRINGS CHURCH ROAD 7 RA = RESIDENTIAL AGRICULTURAL ADJACENT PROPERTY OWNERSHIP INFORMATION CITY OF SANFORD· WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD SANFORD, NORTH CAROLINA CEI PROJECT NO. 20172 PAGE 1 OF 1 OWNER OF RECORD ZONING COMMENTS CITY OF SANFORD RA SUBJECT SITE PO BOX 3729 TAX CARD INFORMATION: SANFORD, NC 27331 PARCEL ID# 9685-60-0468-00 CITY OF SANFORD RA PROPERTY LOCATED IMMEDIATELY WEST OF SUBJECT PO BOX 3729 SITE. SANFORD, NC 27331 TAX CARD INFORMATION; PARCEL ID# 9684-58-5867-00 CAROLINA POWER AND RA PROPERTIES LOCATED NORTH AND SOUTHWEST OF LIGHT COMPANY SUBJECT SITE POBOX1551 TAX CARD INFORMATION: SANFORD, NC 27330 PARCEL 10#9685-76-8443-00 and 9685-76-8443-00 CITY OF SANFORD RA PROPERTIES LOCATED IMMEDIATELY SOUTH OF PO BOX 3729 SUBJECT SITE SANFORD, NC 27331 TAX CARD INFORMATION: PARC EL I 0#96 84-58-5 8 6 7-00 and 96 84-6 9-2 2 3 5-00 BRODIE, TL (HEIRS) RA PRO PEATY LO CA TED IMM EDI A TEL Y EA ST OF SU BJ ECT C/0 DR. E.G. BRODIE SITE SANFORD,NC TAX CARD INFORMATION: PARCEL 1D #9684-79-1 201 -00 --
--------~ffl---------RESULTS FOR VOLATILE AND SEMI-VOLATILE ORGANICS ANALYSES SOIL SAMPLE SB-1A (5') COMPOUND BENZENE ETHYLBENZENE TOLUENE m&p-XYLENES o-XYLENES NAPHTHALENE(8260) NAPHTHALENE (8270) METHYL TERT BUTYL ETHER ISOPROPYL ETHER METHYLENE CHLORIDE SOIL SAMPLE SB-1C (15'} COMPOUND BENZENE ETHYLBENZENE TOLUENE m&p-XYLENES o-XYLENES NAPHTHALENE(8260) NAPHTHALENE(8270) METHYL TERT BUTYL ETHER ISOPROPYL ETHER METHYLENE CHLORIDE SOIL SAMPLING CITY OF SANFORD -WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD SANFORD, NORTH CAROLINA CEI PROJECT NO. 20172 PAGE 1 OF 2 DETECTED MAXIMUM SOIL CONTAMINANT CONCENTRATIONS (MSCCs) CONCENTRATION FOR VARIOUS EXPOSURE SCENARIOS (mg/kg) (mg/kg) SOIL TO GROUND WATER RESIDENTIAL INDUSTRIAL/COMMERCIAL <0.006 0.0056 22 200 <0.006 0.24 1,560 40,000 <0.006 7.00 3,200 82,000 <0,012 5.00 32,000 200,000 <0.006 5.00 32,000 200,000 <0.006 0.58 63 1,635 <0.400 0.58 63 1,635 <0.006 0.92 156 4,088 <0.006 0.37 156 4,088 <0.006 NE NE NE DETECTED MAXIMUM SOIL CONTAMINANT CONCENTRATIONS (MSCCs) CONCENTRATION FOR VARIOUS EXPOSURE SCENAR!OS (mg/kg) (mq/kq) SOIL TO GROUND WATER RESIDENTIAL <0.0058 0.0056 22 <0.0058 0.24 1,560 <0.0058 7.00 3,200 <0.0120 5.00 32,000 <0.0058 5.00 32,000 <0.0058 0.58 63 <0.3800 0.58 63 <0.0058 0.92 156 <0.0058 0.37 156 <0.0058 NE NE SOIL SAMPLES COLLECTED ON AUGUST 9, 2000 mg/kg -MILLIGRAMS PER KILOGRAM. NE -NOT ESTABLISHED. INDUSTRIAL/COMMERCIAL 200 40,000 82,000 200,000 200,000 1,635 1,635 4,088 4,088 NE
-------------------TABLE 2 RESULTS FOR VOLATILE AND SEMI-VOLATILE ORGANICS ANALYSES SOIL SAMPLING SOIL SAMPLE SB-1 D (20'} COMPOUND BENZENE ETHYLBENZENE TOLUENE m&p-XYLENES o-XYLENES NAPHTHALENE (8260) NAPHTHALENE (8270) METHYL TERT BUTYL ETHER ISOPROPYL ETHER METHYLENE CHLORIDE CITY OF SANFORD· WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD SANFORD, NORTH CAROLINA CEI PROJECT NO. 20172 PAGE 2 OF 2 DETECTED MAXIMUM SOIL CONTAMINANT CONCENTRATIONS {MSCCs) CONCENTRATION FOR VARIOUS EXPOSURE SCENARIOS (mg/kg) (mq/kq) SOIL TO GROUND WATER RESIDENTIAL <0.0056 0.0056 22 <0.0056 0.24 1,560 <0.0056 7.00 3,200 <0.0110 5.00 32,000 <0.0056 5.00 32,000 <0.0056 0.58 63 <0.3700 0.58 63 <0.0056 0.92 156 <0.0063 0.37 156 <0.0056 NE NE SOIL SAMPLES COLLECTED ON AUGUST 9, 2000 mg/kg -MILLIGRAMS PER KILOGRAM. NE -NOT ESTABLISHED. INDUSTR IAUCOMMERCIAL 200 40,000 82,000 200,000 200,000 1,635 1,635 4,088 4,088 NE
- ---TOXICOLOGICALL Y DEFINED HYDROCARBON FRACTION C5-CB ALIPHATICS C9 -C18 ALIPHA TICS C 19 -C36 ALIPHATICS C9 • C22 AROMATICS TOXICOLOGICALL Y DEFINED HYDROCARBON FRACTION cs -ca ALIPHATICS C9-C18 ALIPHATICS C19-C36 ALIPHATICS C9 -C22 AROMATICS TOXICOLOGICALL Y DEFINED HYDROCARBON FRACTION cs -ca ALIPHATICS C9 • C18 ALIPHATICS C19 -C36 ALIPHATICS C9 -C22 AROMATICS - ----TA6"' - -RESULTS FOR VPH ANO EPH ANALYSES PHASE ILSA SOIL SAMPLING CITY OF SANFORD -WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD SANFORD, NORTH CAROLINA CEI PROJECT 2017 2 - -- - ---SOIL SAMPLE SB-1A (5') "" SUIL GUN I I tVI I IVI\I;:. (MSCCS) FOR VARIOUS EXPOSURE SCENARIOS CONCENTRATION SUM OF ANALYTICAL DETECTED BY VPH AND EPH HYDROCARBON ANALYTICAL LABORATORY CONCENTRATIONS FRACTION METHOD (mg/kg) (mg/kg) C5 -ca AUPHATICS VPH <12 <12 C9-C12 ALIPHATICS VPH <12 < 24 C9-C18 ALIPHATICS EPH <12 C19-C36 ALIPHATIC$ EPH <12 <12 C9 - C 10 AROMA TICS VPH <12 <24 C11 • C22 AROMATICS EPH <12 SOIL SAMPLE SB-1C (15') CON CE NTRA TION SUM OF ANALYTICAL DETECTED BY VPHAND EPH HYDROCARBON ANALYTICAL LABORATORY CONG ENTRATI ONS FRACTION METHOD {mg/kg) (mg/kg) C5 -ca ALIPHATICS VPH <12 <12 C9-C12 ALIPHATJCS VPH <12 < 24 C9-C18 ALIPHATICS EPH <12 C19-C36 ALIPHATICS EPH <12 <12 C9 • C10 AROMATICS VPH <12 <24 C 11 -C22 AROMA TICS EPH <12 SOIL SAMPLE SB-1D (20') CONCENTRATION SUM OF ANALYTICAL DETECTED BY VPH AND EPH HYDROCARBON ANALYTICAL LABORATORY CONCENTRATIONS FRACTION METHOD (mg/kg) (mg/kg) CS -CB ALIPHATICS VPH 43 <53 C9-C12ALIPHATICS VPH <11 <22 C9-C18 ALIPHATICS EPH <11 C19-C36 ALIPHATICS EPH <11 <11 C9-C10AROMATICS VPH 23 <34 C11 -C22 AROMA TICS EPH <11 SOIL SAMPLES COLLECTED AUGUST 9, 2000 mg/kg· MILLIGRAMS PER KILOGRAM fmolko) SOIL TO GROUND WATER RESIDENTIAL INDUSTRIAL/COMMERCIAL 72 939 24,528 3,255 9,386 245,280 CONSIDERED IMMOBILE 93860 HEAL TH-BASED ST ANDA RO ;, 100% 34 469 12,264 MAXIMUM SOIL CONTAMINANT CONCENTRATIONS (MSCCs) FOR VARIOUS EXPOSURE SCENARIOS (mg/kQ) SOIL TO GROUND WATER RESIDENTIAL INDUSTRIAL/COMMERCIAL 72 939 24,528 3,255 9,386 245,280 CONSIDERED IMMOBILE 93,860 HEAL TH-BASED ST ANOARO > 1 DO¾ 34 469 12,264 MAXIMUM SOIL CONTAMINANT CONCENTRATIONS (MSCCs) FOR VARIOUS EXPOSURE SCENARIOS (mg/kg} SOIL TO GROUND WATER RESIDENTIAL INDUS TR IAUCOMME RC IA L 72 939 24,528 3,255 9,386 245,280 CONSIDERED IMMOBILE 93,860 HEAL HI-RASE[) STNJOARD -· lfJO'J. 34 469 12,264 VPH -VOLATILE PETROLEUM HYDROCARBONS. EPH -EXTRACTABLE PETROLEUM HYDROCARBONS
----------- - --Well No. IU i:: ~ m IU i:: V ~ IU i:: ~ V :9 5 hl TABLE4 LSA GROUND WATER LABORATORY ANALYTICAL RESULTS CITY OF SANFORD -WATER TREATMENT PLANT (I) ~ V ~ k El "' V 5 7441 POPLAR SPRINGS CHURCH ROAD SANFORD, NORTH CAROLINA .... V ~ ], ::s ,!J t: V -;' CEI Project No. 20172 ~ ,s ~ ..... ,.., V ~ V V i:: V fi .c: IU i:: V 'iil ,s ~ ~ V ~ 8 g. "' "" I fJ' i:: V ~ 0 i:: 11.) ~ ,.q §' z Q .g 1 ~ ' co ::r: y p_. I() :>o .g ] ~N ' ,-; ::r: y P.. °' >O .g <;$ a 0 -<o ,,-; :l!Y P.. °' _:::.__ o - - - -u ·zi (lj .a P. ~ co ~Q P.. 0, hl O u ·-g ..c: P. ~~ ,O ::r: d, P.. .... WO .::: ~ a 0 -< :;: ,0 ::r: ...'.. P.. ...... !!l 0 V i:: IU .... ;:l 0 G; MW-1 <l <l <1 <l <l <l <l <5 <5 <5 <5 I <100 I <100 I <100 I <100 I <100 I <100 I <5 NCAC 2L Standards I 1.0 I 1,000 29 530 530 200 70 I 0.19 I o.0004 I 300 21 420 14,200 I 210 I 4,200142,000 I 210 Gross Con tarnination Level 5,0001257,500129,000I 87,500187,5001200,000170,0001 NE 50 NE 15,500 NE GROUND WATER SAMPLE COLLECTED ON SEPTEMBER 5, 2000. CONCENTRATIONS IN MICROGRAMS PER LITER (ug/L). NE NE NE NE NE 15 15,000 -
I I I I I I I I I FIGURES I I I .I I I I I I I I -. -···-~-· ~-, ,. ,
I I I I I I I I I I I I I I I I I I I I Ql:IAORANGLE LOCATION , 20100• HORIZONTAL SCALE SOURCE; PORTION OF U$.G.S. 7.5 MINUTE· TOPOGRAPHIC MAP MONCURE NORTH CAROUNA UADRANGLE IJ'!!A;CODPER ENVIRONMENTAL ..., ·ENGINEERS GEOLOGISTS SCIENTISTS TOPOGRAPHIC LOCATION MAP CITY OF SANFORD WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, NORTH CAROLINA PROJECT NO: .20172 SCALE: l" = 2000' DATE: 09/08/00 FIGURE: 1
I I I I I I I I I I I I I I I I I I I I .fWE BUTI,DING GRASS LINE GR0:28.6 mg/kg DR0:146 mg/KG APPROXIMATE LOCATION OF r---fST EXCAVATION (12'x27.5') I INORTH END I r - --./T"GR0:212 mg/kg DR0:527 mg/kg 'I I 11 e I I FORMER 5,000-GALLON : : ~IESEL UST (7'x16.5') II I I : I •-+--l.som'H END IL __ .J I GR0:744 mg/kg DR0:5,070 mg/kg I I L-----r-------,----..r--L.-==--=d_ -E--E---E LEGEND UST CLOSURE SAMPLE e COLLECTED BY ENVIRONMENTAL ANSWERS, U..C (10-18-99) -E-BURIED ELECTRIC LINE ASPHALT CHLORINATOR BUILDING ~ COOPER ENVIRONMENTAL ..., ENGINEERS GEOLOGISTS SCIENTISTS UST SAMPLING LOCATION MAP CITY OF SANFORD WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, NORTH CAROLINA PROJECT NO: 20172 SCALE: 1" = 20' DATE: 08/31/00 FIGURE: 2
I I I I I I I I I I I I I I I I I I I I GRASS PUYP BUILDING APPROXIMATE LOCATION OF r---fST EXCAVATION (12':x:27.5') I / , / 1r -4~ J, . 0 ON I / • _,,, / FORMER 5,0 0-GALL :: __ :~'iJIESEL UST (7'x16.5') 11 //-·I/ 11 // (I r' I ,. , / I I /-/ I --1/ ,,___~NEW CONCRETE IL ..:_...,_J /I / -PAD WITH ASTs I / / y_/ I L..-.----r--------,,------'~-L-=-=.-==:L -E--E---E ) ~ +'-_ss-1\ YW-1 -------LEGEND son. BORING LOCATION MONITORING WELL LOCATION -E -BURIED ELECTRIC LINE ASPHALT CHLQRINATOR RlITLDING -=-o· HORIZONTAL SCALE ~ COOPER ENVIRONMENTAL ... ENGINEERS GEOLOGISTS SCIENTISTS PHASE I I.SA SAMPLlNG LOCATION MAP CITY OF SANFORD WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, NORTH CAROLINA PROJECT NO: 20172 I SCALE: 1-= 20' DATE: 08/31/00 I FIGURE: 3
I I I I I I I I I APPENDIX A I TAX RECORDS I I I I I I I I I I ,. ___ ·--. -· -
I I I I I I I I I I I I I I I I I I I r I I \ I ~ I/ ~ ~ l PO BOX 1551 TAX DEPT C. OLINA POWER ANO LIGHT COMPA 9685-76-8443-00 9685-76-8443.00 PO BOX 1551 TAX DEPT 2 CAROLINA POWER AND LIGHT COMPA PO BOX0042 HAIR, STUART A 9684-37-4793-00 4 PO SOX 1551 TAX DEPT CAROLINA POWER AND LIGHT COM PA 9685-76-8443.00 PO BOX 3729 SANFORD, CITY OF 9685-60-0468-00 1 PO BOX 3729 ANFORO. CITY 684-'9-2235-0 PO BOX372 SANFORD, CITY F 6 3 7 % DR E G BRODIE BRODIE, T L(HEIRS) 9684-79•1201-00 9684-79-% DRE BRODIE, T 7351 COLO 2425 AVENTS FERRY RO YARBOROUGH, ELOUISE 9685-92-5992-00 % OR E G BRODIE 9684-QS-5867-00,l.L'_-------✓ ,~~---....J BRODIE, TL (HEIRS) 5 7351 COLONIAL AVE 9684-88-5486-00 2425 AVENTS FERRY RO YARBOROUGH, ELOUISE 9684.a7-3830-00 ~ COOPER ENVIRONMENTAL ... ENGINEERS GEOLOGISTS SCIENTISTS TAX MAP CITY OF SANFORD WATER TREATMENT PLANT 7441 POPLAR SPRINGS CHURCH ROAD LEE COUNTY, NORTH CAROLINA SOURCE: PORTION OF CITY OF SANFORD GIS MAPPING DEPARTMENT PROJECT NO: 20172 DATE: 09/08/00 SCALE: NTS TAX MAP
I I I I I I I I I I I I I I I I I I I I -FAX-Date q. 8·00 Number of pages including cover sheet __2_ To: Doy P,c ro+t, Ph011e 1DJ./-8 J../5-2000 From: ENGINEER.ING DEPARTMENT CITY OF SANFORD P. 0. BOX 3729 SANFORD, NC 27331-3729 -1eonno-l-k +fosser PhOM _9l q-175-830I Fax PhOM _ q,q-'71'1-8/'79 I REMARKS: : . 0 Urgent O For your review D Reply ASAP 0 Please comment ~ouq, /he5e /JIU mt:.. OJJL'I ADD'2€S5GS We }/AVG_ lTNe/2.£ 1s SoMf. tJE'uJ 1N,::o'e.J1/11fuv) /JLL DF ,NeSt Pl2.DP€r2..TIES A Re Z.oNGO RA -' fZ.f5/P ~,Jil AL A6/2..IClJLTU/2:tJL'
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I I I I I I I I I I I I I I I I I I I ■ APPENDIXB LSA RISK CLASSIFICATION AND LAND USE FORM
I I I I I I I I I I I I I I I I I I I L Limited Site Assessment Risk Classification and Land Use Form Part I -Groundwater/Surface waterN apor Impacts High Risk 1. Has the discharge or release contaminated any water supply well including any us~r non-drinking purposes? YES 0 Ifyes,explain. To our knowledge, the petroleum release has not contaminated any water supply well. 2. Is a water supply well used for drinking water located within 1000 feet of the sourc~a the discharge or release? YES~ To our knowledge, a water supply well is not located within 1,000 feet of the source area. 3. Is a water supply well used for any purpose ( e.g., irrigation, washing cars, industrial cooling water, filling swimming pools) located within 250 feet of the source area ~e release or discharge? YES~ None ·observed, city water serves all areas. 4. Does groundwater within 500 feet of the source area of the discharge or release have the potential for future use in that there is no other source of water supply other th~e groundwater? . . YES~ Explain. The area is served hy the City Water Peoactmeor wbi cb receives its supply from the Cape Fear River. 5. Do vapors from the discharge or release pose a threat of explosion because of accumulation of the vapors in a confined space or pose any other serious threat to p~c health, public safety or the environment? YES-t!9) If yes, explain. To our kn ow 1 e d g e , t h er e a r e no con f i n e d s pa c es that would allow for an accumulation of vapors. 6. Are there any other factors that would cause the discharge or release to pose an ~t danger to public health, public safety, or the environment? YES~ If yes, explain. To o u r know 1 e d g e , t her e a r e no o t her fa c t or s t ha t would pose an imminent danger to public health, public safety, or the environment. 139 January 2, 1998
I I I I I I I I I I I I I I I I Intermediate Risk 7. Is a surface water body located within 500 feet of the source area of the disch~r release? YE~ ~one observed within 500 feet of the source area. If yes, does the maximum groundwater contaminant concentration exceed the surface water quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 1~~ YE~ 8. Is the source area of the discharge or release located within a designated ~e~ protection area as defined in 42 USC 300h-7(e)? YE~ If yes, explain. ________________________ _ 9. Is the discharge or release located in the Coastal Plain physiographic region as designated on a map entitled "Geology of North Carolina" published by the Department in 19!~ YE~ If yes, is the source area of the discharge or release located in an area in which there is recharge to an unconfined or semi-confined deeper aquifer that is being used or may be used as a source of drinking water? YES/NO If yes, explain. ________________________ _ 10. Do the levels of groundwater contamination for any contaminant exceed the ~s contamination levels established (see Table 7) by the Department. YES~ 140 January 2, 1998
I I I I I I I I I I I I I I I I I I I I ~ ::::::essmem epon Part II -Land Use Property Containing Source Area of Discharge or Release The questions below pertain to the property containing the source area of the release. 1. Does the property contain one or more primary or secondary residences (perm8:1~r temporary)? YE~ Explain. The subject site is the city water treatment facility. 2. Does the property contain a school, daycare center, hospital, playground, park, re~r~n area, church, nursing home, or other place of public assembly? YE~ Explain. __________________________ _ 3. Does the property contain a commercial ( e.g., retail, warehouse, office/business space, etc.) or industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum bulk storage, etc.) enterprise, an inactive commercial ~:::trial enterprise, or is the land undeveloped? ~NO Explain. Ci t y Water Treatment fa c i 1 it v 4. Do children visit the property? YEs@ Explain. __________________________ _ 5. Is access to the property reliably restricted consistent with its use (e.g., by fences, se~ personnel or both)? YES~ Explain. Property is reliably restricted to city employees. 6. Do pavement, buildings, or other structures cap the contaminated soil? @No Explain. _________________________ _ If yes, what mechanisms are in place or can be put into place to ensure that the contaminated soil will remain capped in the foreseeable future? ________ _ The bulk of the petroleum-impacted soil was removed at closure and a concrete pad covers the backfilled area. 141 January 2, 1998
I I I-I I I I I I I I I I I I 7. What is the zoning si:arus of the property? Res i d en t i a 1 -Ag r i c u 1 t u r a 1 ( RA ) 8. Is the use of the property likely to change in the next 20 years? YES@ Explain. __________________________ _ Propertv Surroundin2: Source Area of Discharize or Release The questions below pertain to the area within 1500 feet of the source area of the discharge or release (excludes property containing source area of the release): 11. What is the distance from the source area of the release to the nearest primary or secondary residence (pennanent or temporary)? None observed within 1,500 feet. 12. What is the distance from the source area of the release to the nearest school, daycare center, hospital, playground, park, recreation area, church, nursing home or other place of publicassembly? There is no place of public assembly located within 1,500 feet. 13. What is the zoning status of properties in the surrounding area? ________ _ Residential-Agricultural (RA) 14. Briefly characterize the use and activities of the land in the surrounding area. ___ _ The subject site is a large parcel and is surrounded by wooded and vacant lots. 142 January 2, 1998
I I I I I I I I I APPENDIXC I SOIL BORING LOG I I 1. I I ·1 I I I I
I I I I I I I I I I I I I I I I I I I I COOPER ENVIRONMENTAL Boring Log: SB-I (MW-I) Project: SANFORD ESGIXEERS GEOLOGISTS SCIENTISTS Date: 08/09/00 Project No: 20172 2300 Sardis Road North Drilling Cont. American Env. Drilling Suite Q Prepared By: D. Amen County: LEE Charlotte, North Carolina 28227 Address: 7441 Poplar Springs Total Depth 24 feet Church Road Telephone: [phone] Sanford, North Carolina Hole Diameter: 8 1/4 in. Fax: [phone] Lgth Coring Device: 2 feet Dis. Core NA Device: Boring Methods Groundwater Observations Drilling r-.kthod: HSA Hollow Stem Auger GW Encountered at: Drilling Fluid: None Hand Auger GW After Completion: 18.83 Driller: Kelly Other : Geoprobe GW After: NA Hammer Weight: 130 lb. GWVolumes: NA Hammer Drop: 40inch Penetra. Blow Per Sample Depth Soil Description Remarks 6" Type (FT) 0.0 Grass and topsoil ss 4-6' Red soft sand, grading to a sandy silt Soil sample (8260, 8270, VPH&EPH) ss 9-10' Red silt grading to a gray-olive sandy clay ss 14-16' Red, green sandy clay Soil sample (8260, 8270, VPH&EPH) ss 19-21' Dark red clay, moist Soil sample (8260, 8270, VPH&EPH) ss 24' No recovery, competent TD=24' Set 2" diameter well 15 foot screened Water sample: 602, 625, interval VPH&EPH SS -Split Spoon ST -Shelby Tube AS -Power Auger Sample WS -Wash Sample BS -Misc. Bag or Bottle Sample NR -No Recovery RB -Rock Bit CT -Continuous Core HA -Hand Auger Sample RC -Rock Core
I I I I I I I I I I I I I I I I I I I .......... -·--. ----------·-.. .. --···-APPENDIXD WELL CONSTRUCTION RECORD
I I I I I I I I I HORTH CAAOUkA DEPARTl.ENT 0, NATUIAL RESOURCES ANO COW.U;iTY OEVELON.ENT Ol\'ISI011 OF t1rvmo11t.£NT~.L ~WIAO':.MF.tlT -onOUTIOWAlER flfCllOtl FOR OFFICE USE ONLY P.O. oox 21eo1 -0.\1..EIOl~llC, 27011, PIiot!!: (Q 111)733-3221 I. WELL LOCAllON: (Show &ketch ol the location bolow} tlea1es1 Town: f/1,,-J TOIL V /1.,-":'"c. PofL.,1;c sz-a+,.vG,; Ile£ llk><Hl, Commu11ity, or Subdivision and Loi No.) 2. mmEn f /},,v 'ro [<./J 1-J fTZ. /l T 8,, CA17l-'lc./ C ADDness 7y'-/ 1 Po,? (_/f /l. f..&2:/\/G" f /?,, d. (Street or Route No.) ..J --I /V r:-.:, :,1, p /1-.c.. , 3. DA l C: DntLLEO City j,! Town Slate Zip Coda r-WJ ··00 USE OF WELL ··"111 u/✓X:rOit 4. TOTAL DEPnl ;J <;/ / CUTTINGS COLLEClED O Yes S-No • S. DOES WELL REPLACE EXISTING WELL? 0 Yes [hfo 6. STATIC WATER LEVEL: FT. 0 above TOP OF CASING, D below TOP OF CASING IS ____ FT. ABOVE LAND SURF ACE. 7. YIELD (gpm): METHOD OF TEST ______ _ Qu!ld. No. ______ Se1lal No. __ Lal. _________ Long. ____ Pc Minor 611i;in __________ _ 8Ml11 Cod:, __________ _ ll('l"titr F.nl. ______ ------·-·--GW-1 En!. __ _ s111Jr: wr-:u. c(it1:.nnuo11<.1it PF.llMIT l!IJl.lf.lEll: -·-----------I££..-Counly: _ _:l..::;._ ____________ _ .r IQ /J lo 5 Qo :,..J onn. Lll-1O I. OG l ' OCI( 1 .... \ l. WA TEA ZONES (deplh): '_) 9. CHLOAINA TION: I 10. CASING: From I From From I t t. GROUT: From ·7 From J I 12. SCREEN: I From 2.1./' From I From 13. GRAVEL PACK: Type Depth To To To Depth To s To -, f' Depth To 2. To To Depth Amounl Wall Thickness Diameter or Weight/Ft. Material Ft. __ _ Ft ___ _ Fl.----Material Method Ft. JJ,>yrp,il_rrc pn1 6 A ; fl. j/CftCC....,_<:.vr e D L(it. Diameter Slot Size J.. ,. Ft._~_ 1n. l> I Q In. Material pvC Fl. ___ ln. ___ ln. __ _ Ft. In. In. ---Size Material ti addlUonal space Is needed use back ol form. LOCATION SKETCH (Show direction and distance from al least two Slate Aoall,. or other map reference points) I From 2 I/ To 7 -\ From. ____ To. ___ Ft .. _____ _ :IJ. 11 tJ:1 G~A/cl · __ .,). ReMARKS:-----------------------------------------1 t DO HEREBY CERTIFY THAT THIS WELL WAS CONSTRUCTED IN ACCORDANCE WITH 15 NCAC 2C. WELL CONSTRUCTION ST AN>AAOS, AN) THAT A COPY OF THIS RECORD HA$ ~~VIDEO TO 1l£ WELL OWNER. J-_ ,fl _ 7( ~-.,,,,(,,,4,.._ · .:::,:. 0 0 I SIGNA ~ OF C TRACTOR OR AGENT DATE GW•t Revised 6/88 Submit orlglnal to DIYlalon of Envtronmental Management and copr lo w1U ownw.
I I I I I I I I I I I I I I I I I I I I APPENDIXE SOIL LABORATORY ANALYTICAL RESULTS
I~ •( ~ceAnalyticar I I I I I August 22, 2000 Mr. Doug Pierotti Cooper Environmental, Inc. 2300 Sardis Road North Suite Q Charlotte, NC 28227 RE: Pace Project Number: 9216237 Client Project ID: Sanford Dear Mr. Pierotti: Pace Analylical Services. Inc. 9800 l<inc:=., ~venue S~ L~-~ Hu:;;f(SV!lle NL ":,, .; Pnone. 10.Js-:5:;o;~' Fax. 704875.<:091 I Enclosed are the analytical results for safll>le(s) received by the laboratory on August 10,2000. If you have any questions concerning this report, please feel free to contact me. I I I I I I I I I Sincerely, Kristi Tart Project Manager Enclosures ILaboratorv Certjfication IDs NC Wastewater 12 NC Drinking Water 37706 15c 99005 ■ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I Cooper Environmental, Inc. 2300 Sardis Road North luite Q harlotte, NC 28227 ltn: Mr. Doug Pierotti one: (704)845·2000 Pace Analytical Services. Inc. ~160(1 ,. ·-_-:-. ..: . ~--:ue. :; .... -: -_-_--_ ... -~-~-·:~.NC_·::-:· ::-_,,,~-70-IS-: :_-~: ;:2,. 704.67: ;:;-DATE: 08/22/00 PAGE: 1 Pace Project Number: 9216237 Client Project ID: Sanford Solid results are reported on a dry weight basis ce sa~le No: lient Sample 10: Parameters 921140430 SB·1A 1--·-············---·-·-·-···-·· t Chemistry I Percent Moisture Percent Moisture GC Volatiles I VPH in Soil by Mass. Method Aliphatic (C05·C08) Aliphatic (C09·C12) Aromatic (C09·C10) I 2,5-Dibromotoluene (FID)(S) 2,5-Dibromotoluene (PID)(S) CC Semivolatiles I EPH in Soil by Mass. Method Aliphatic (C09-C18) Aliphatic (C19·C36) Aromatic (C11·C22) I 2-Fluorobiphenyl (S) 2-Bromonaphthalene (S) Nonatriacontane (S) o·Terphenyl CS) I Date Extracted /MS Volati Les 1 GC/Ms voe, by 8260, low level I I abor tor Certificati n IDs NC Wastewater 12 ,tc Drinking Water 37706 re 99006 I Results Units Method:% Moisture 16.8 % Method: VPH NO mg/kg ND mg/kg NO mg/kg 106 ¾ 74 % Date Collected: 08/09/00 08/10/00 Date Received: PRL Analyzed Analyst CAS# 12 12 12 Prep Method: 08/14/00 COE Prep Method: 08/19/00 Rt.IS 08/19/00 Rt.IS 08/19/00 Rt.IS VPH 08/19/00 RWS 615-59-8 08/19/00 RWS 615-59·8 Matrix: Soil Footnotes Method: EPH Prep Method: EPA 3550 NO ND ND 63 59 61 89 mg/kg 12 08/15/00 Rt.IS mg/kg 12 08/15/00 RWS mg/kg 12 08/15/00 Rt.IS % 08/15/00 Rt.IS 321·60·8 % 08/15/00 Rt.IS 580-13-2 ¾ 08/15/00 Rt.IS 7194·86·7 % 08/15/00 RWS 84·15·1 08/14/00 Method: EPA 8260 Prep Method: EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ~~; I //p£ce Analytical I Pace Analytical Services. Inc. ,::JO l<inceJ ~1_,r.L'e Sc·:= /00 Huniers1 ;1/c NC ~-5078 Phone. 704.S.-"5.9092 Fax: [phone] I I II I Pace sample No: 921140430 SB·1A ll ient Sample ID: arameters I Dichlorodifluoromethane Chloromethane Vinyl Chloride Bromomethane Chloroethane I Methyl·tert-butyl Ether Trichlorofluoromethane lsopropyl Ether 1,1-Dichloroethene I Methylene Chloride trans-1,2-Dichloroethene 1,1-Dichloroethane cis-1,2-Dichloroethene I 2,2-Dichloropropane Chloroform Bromochloromethane 1,1,1-Trichloroethane 1,1-Dichloropropene I 1,2-0ichloroethane Carbon Tetrachloride Benzene Trichloroethene I 1,2-Dichloropropane Dibromomethane Bromodichloromethane Toluene 1,1,2-Trichloroethane I 1,3-Dichloropropane Dibromochloromethane Tetrachloroethene 1,2-Dibromoethane I Chlorobenzene 1, 1, 1,2-Tetrachloroethane Ethyl benzene m&p·Xylene I Styrene o·Xylene C1,2·Dimethylbenzene) Bromoform 1,1,2,2-Tetrachloroethane lsopropylbenzene (Cunene> I I I ILabor~tor~ Certification ID~ NC Wastewater 12 INC Drinking Water 37706 SC 99006 I DATE: 08/22/00 PAGE: 2 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: 08/09/00 Matrix: Soil Date Received: 08/10/00 Results Units PRL Analyzed Analyst CAS# Footnotes ND ND ND NO NO ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ····-------------··-.............. ................... ug/kg 12 08/10/00 JRS 75-71·8 ug/kg 12 08/10/00 JRS 74-87·3 ug/kg 12 08/10/00 JRS 75-01 ·4 ug/kg 12 08/10/00 JRS 74-83-9 ug/kg 12 08/10/00 JRS 75-00-3 ug/kg 6 08/10/00 JRS 1634-04·4 ug/kg 6 08/10/00 JRS 75-69·4 ug/kg 6 08/10/00 JRS 108·20-3 ug/kg 6 08/10/00 JRS 75-35-4 ug/kg 6 08/10/00 JRS 75-09·2 ug/kg 6 08/10/00 JRS 156-60-5 ug/kg 6 08/10/00 JRS 75-34·3 ug/kg 6 08/10/00 JRS 156-59-2 ug/kg 6 08/10/00 JRS 594·20·7 ug/kg 6 08/10/00 JRS 67·66·3 ug/kg 6 08/10/00 JRS 74·97·5 ug/kg 6 08/10/00 JRS 71-55·6 Ug/kg 6 08/10/00 JRS 563-58-6 ug/kg 6 08/10/00 JRS 107-06-2 ug/kg 6 08/10/00 JRS 56-23-5 ug/kg 6 08/10/00 JRS 71-43-2 ug/kg 6 08/10/00 JRS 79-01-6 ug/kg 6 08/10/00 JRS 78-87·5 ug/kg 6 08/10/00 JRS 74-95·3 ug/kg 6 08/10/00 JRS 75-27-4 ug/kg 6 08/10/00 JRS 108-88·3 ug/kg 6 08/10/00 JRS 79·00·5 Ug/kg 6 08/10/00 JRS 142-28-9 ug/kg 6 08/10/00 JRS 124-48·1 ug/kg 6 08/10/00 JRS 127·18-4 ug/kg 6 08/10/00 JRS 106·93-4 ug/kg 6 08/10/00 JRS 108-90-7 ug/kg 6 08/10/00 JRS 630-20-6 ug/kg 6 08/10/00 JRS 100-41·4 ug/kg 12 08/10/00 JRS 7816·60·0 ug/kg 6 08/10/00 JRS 100-42·5 ug/kg 6 08/10/00 JRS 95-47·6 u9/k9 6 08/10/00 JRS 75-25-2 ug/kg 6 08/10/00 JRS 79·34-5 ug/kg 6 08/10/00 JRS 98·82-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. ·---------Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I.~ 1 /.,,Pace Analyticar Pace Analytical Services, Inc. ,=::'.·LJ ,\,ncey ,~, :· _c Suite 10c' Hunters. = NC 280,-:,: Phone -o..i.875.9092 Fax ,-:-(14.875.9097 I Pace Sample No: 921140430 SB· 1A IL i ent Sample ID: arameters I 1,2,3·Trichloropropane Bromobenzene n·Propylbenzene 2·Chlorotoluene 4·Chlorotoluene I 1,3,5·Trimethylbenzene tert·Butylbenzene 1,2,4·Trimethylbenzene sec·Butylbenzene I 1,3·Dichlorobenzene p·Isopropyltoluene 1,4-Dichlorobenzene 1,2-Dichlorobenzene n-Butylbenzene I 1,2-Dibromo-3-Chloropropane 1,2,4-Trichlorobenzene Naphthalene Hexachloro-1,3-butadiene I 1,2,3-Trichlorobenzene Dibromofluoromethane CS) 1,2-Dichloroethane-d4 CS) Toluene·c:18 CS) I 4-Bromofluorobenzene CS) /MS Semivolatiles Semivolatile Organics I bis(2-Chloroethyl)ether Phenol 2-Chlorophenol 1,3-Dichlorobenzene I 1,4-Dichlorobenzene 1,2-Dichlorobenzene Benzyl Alcohol bis(2·Chloroisopropyl)ether 2-Methylphenol I Hexachloroethane N·Nitroso·di·n·propylamine 3&4·Methylphenol Nitrobenzene I I I ILaboratory Certification IDs NC Wastewater 12 tNC Drinking Water 37706 C 99006 ■ Date Collected: Date Received: DATE: 08/22/00 PAGE: 3 Pace Project Nunber: 9216237 Client Project ID: Sanford 08/09/00 08/10/00 Matrix: Soil Results Units PRL Analyzed Analyst CAS# Footnotes ----------... ~--·---~ • .. -• * ...... - -.................. _____ ........ -.. -.......... ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND 110 107 95 88 ND ND ND ND ND ND ND ND ND ND ND ND ND ug/kg 6 08/10/00 JRS 96-18-4 ug/kg 6 08/10/00 JRS 108·86·1 ug/kg 6 08/10/00 JRS 103-65·1 ug/kg 6 08/10/00 JRS 95-49-8 ug/kg 6 08/10/00 JRS 106-43-4 ug/kg 6 08/10/00 JRS 108-67·8 ug/kg 6 08/10/00 JRS 98·06·6 ug/kg 6 08/10/00 JRS 95-63-6 ug/kg 6 08/10/00 JRS 135·98·8 ug/kg 6 08/10/00 JRS 541-73-1 ug/kg 6 08/10/00 JRS 99·87·6 ug/kg 6 08/10/00 JRS 106-46-7 ug/kg 6 08/10/00 JRS 95-50-1 ug/kg 6 08/10/00 JRS 104-51·8 ug/kg 6 08/10/00 JRS 96·12·8 ug/kg 6 08/10/00 JRS 120-82-1 ug/kg 6 08/10/00 JRS 91-20-3 ug/kg 6 08/10/00 JRS ug/kg 6 08/10/00 JRS 87-61-6 % 08/10/00 JRS 1868-53-7 % 08/10/00 JRS 17060-07·0 % 08/10/00 JRS 2037-26·5 % 08/10/00 JRS 460-00·4 Method: EPA 8270 Prep Method: EPA 3550 ug/kg 400 08/11/00 DHJ 111-44-4 ug/kg 400 08/11/00 DHJ 108-95-2 ug/kg 400 08/11/00 DHJ 95·57·8 ug/kg 400 08/11/00 OHJ 541-73·1 ug/kg 400 08/11/00 DHJ 106-46-7 ug/kg 400 08/11/00 DHJ 95-50-1 ug/kg 790 08/11/00 DHJ 100-51-6 ug/kg 400 08/11/00 DHJ 39638-32·9 ug/kg 400 08/11/00 DHJ 95-48-7 ug/kg 400 08/11/00 DHJ 67-72·1 ug/kg 400 08/11/00 DHJ 621-64-7 Ug/kg 400 08/11/00 DHJ ug/kg 400 08/11/00 DHJ 98-95·3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I Pace Sample No: 921140430 S8·1A llient Sample ID: arameters I I I I I I I I I I I I lsophorone 2-N i trophenol 2,4-Dimethylphenol bis(2·Chloroethoxy)methane Benzoic Acid 2,4-Dichlorophenol 1,2,4-Trichlorobenzene Naphthalene 4-Chloroaniline Hexachloro-1,3-butadiene 4-Chloro-3-methylphenol 2-Methylnaphthalene Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Acenaphthylene Dimethylphthalate 2,6-Dinitrotoluene Acenaphthene 3-Nitroanil ine 2,4-Dinitrophenol Dibenzofuran 2,4-Dinitrotoluene 4-Nitrophenol Fluorene 4-Chlorophenyl-phenylether Diethylphthalate 4-Nitroaniline 1,2-Diphenylhydrazine 4,6·Dinitro·2-methylphenol N·Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene Anthracene Di·n·butylphthalate Fluoranthene llaboratory Certification IDs NC Wastewater 12 INC Drinking Water 37706 SC 99006 ■ Pace Analytical Services. Inc. 9800 K0:=i ~venue :_ -c 100 i--i~ ·~i2rsville :._-~3018 P1one· 704 c.-:9092 Fax 704 c:-:9097 DATE: 0B/22/00 PAGE: 4 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: Date Received: 08/09/00 08/10/00 Results Units PRL Analyzed Analyst CAS# -----------------------------------------·-··-.. ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO NO ND ND ND ND ug/kg 400 08/11/00 DHJ 78-59-1 ug/kg 400 08/11/00 DHJ 88-75-5 ug/kg 400 08/11/00 OHJ 105-67·9 ug/kg 400 08/11/00 DHJ 111-91-1 ug/kg 2000 08/11/00 DHJ 65-85-0 ug/kg 400 08/11/00 DHJ 120-83-2 ug/kg 400 08/11/00 DHJ 120·82·1 ug/kg 400 08/11/00 DHJ 91-20·3 ug/kg 790 08/11/00 DHJ 106-47-8 ug/kg 400 08/11/00 DHJ ug/kg 790 08/11/00 DHJ 59-50·7 ug/kg 400 08/11/00 DHJ 91-57·6 ug/kg 400 08/11/00 DHJ n-47·4 ug/kg 400 08/11/00 DHJ 88-06-2 ug/kg 400 08/11/00 DHJ 95-95·4 ug/kg 400 08/11/00 DHJ 91-58·7 ug/kg 2000 08/11/00 DHJ 88-74-4 ug/kg 400 08/11/00 DHJ 208-96-8 ug/kg 400 08/11/00 DHJ 131·11-3 ug/kg 400 08/11/00 DHJ 606-20-2 ug/kg 400 08/11/00 DHJ 83-32-9 ug/kg 2000 08/11/00 DHJ 99-09-2 ug/kg 2000 08/11/00 DHJ 51-28·5 ug/kg 400 08/11/00 OHJ 132-64-9 ug/kg 400 08/11/00 DHJ 121-14-2 ug/kg 2000 08/11/00 DHJ 100-02-7 Ug/kg 400 08/11/00 DHJ 86·73-7 ug/kg 400 08/11/00 DHJ 7005-72·3 ug/kg 400 08/11/00 DHJ 84-66-2 ug/kg 2000 08/11/00 OHJ 100-01-6 Ug/kg 400 08/11/00 OHJ 122-66-7 ug/kg 400 08/11/00 DHJ 534-52-1 ug/kg 400 08/11/00 DHJ 86-30-6 ug/kg 400 08/11/00 DHJ 101·55·3 ug/kg 400 08/11/00 DHJ 118-74·1 ug/kg 2000 . 08/11/00 DHJ 87-B6·5 ug/lcg 400 08/11/00 DHJ 85-01 ·8 ug/kg 400 08/11/00 DHJ 120-12-7 ug/kg 400 08/11/00 DHJ 84-74-2 ug/kg 400 08/11/00 DHJ 206-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. without the written consent of Pace Analytical Services. Inc. Matrix: Soil Footnotes ----------Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
: /:2:eAna&(icar II Pace Analytical Services, Inc. -~ :·oo Kince: ~. :we. Suite 7VG Hur;~::·.o.iile NC 28073 P/;:.~:c. 704.815.9092 F3.x: 704.815.9097 DATE: 08/22/00 PAGE: 5 I Pace Sample No: 921140430 SB-1A lient Sample ID: rameters I I I I I I I I I I I I ■ Pyrene Butylbenzylphthalate 3,3'-0ichlorobenzidine Benzo(a)anthracene Chrysene bis(2·Ethylhexyl)phthalate Di·n·octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene 2·Fluorophenol (S) Phenol·d6 CS) Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) 2,4,6-Tribromophenol CS) Terphenyl-d14 (S) Date Extracted Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: Date Received: 08/09/00 08/10/00 Results Units PRL Analyzed Analyst CAS# --··-----------···· ---............ ........ --------------ND ND ND ND ND ND ND ND ND ND ND ND ND 35 41 37 33 43 72 ug/kg 400 08/11/00 DHJ 129-00-0 ug/lcg 400 08/11/00 OHJ 85·68·7 ug/lcg 790 08/11/00 DHJ 91-94·1 ug/lcg 400 08/11/00 DHJ 56-55·3 ug/kg 400 08/11/00 OHJ 218-01-9 ug/kg 400 08/11/00 DHJ 117-81-7 ug/kg 400 08/11/00 DHJ 117·84·0 ug/lcg 400 08/11/00 DHJ 205-99-2 ug/kg 400 08/11/00 DHJ 207·08·9 ug/lcg 400 08/11/00 DHJ 50-32-8 ug/kg 400 08/11/00 DHJ 193-39-5 ug/lcg 400 08/11/00 DHJ 53·70-3 ug/kg 400 08/11/00 DHJ 191-24·2 % 08/11/00 DHJ 367-12-4 % 08/11/00 DHJ 13127-88-3 % 08/11/00 DHJ 4165-60-0 % 08/11/00 DHJ 321·60·8 % 08/11/00 DHJ 118· 79·6 % 08/11/00 DHJ 1718·51·0 08/11/00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Matrix: Soil Footnotes --.......... -Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
: /~eAnalyticar Pace Analytical Services, Inc. ;300 Kincey A,enue Suite 100 Hunters,. ille. NC 280i8 Phone [phone] Fax. [phone] I I Pace Sample No: llient Sample ID: arameters It Chemistry Percent Moisture Percent Moisture I Volatiles 921140463 SB·1C VPH in Soil by Mass. Method I AL iphatic (C05·C08) Aliphatic (C09·C12) Aromatic (C09·C10) 2,5-Dibromotoluene (FID)(S) I 2,5-Dibromotoluene (PID)(S) Semivolatiles EPH in Soil by Mass. Method I AL iphatic; (C09·C18) Aliphatic (C19·C36) Aromatic (C11·C22) 2·Fluorobiphenyl (S) I 2·Bromonaphthalene CS) Nonatriacontane (S) o·Terphenyl (S) Date Extracted I/MS Volatiles GC/MS voes by 8260, low level Dichlorodifluoromethane I Chloromethane Vinyl Chloride Bromomethane Chloroethane I Methyl-tert·butyl Ether Trichlorofluoromethane lsopropyl Ether 1,1-0ichloroethene Methylene Chloride I I I ■ Date Collected: Date Received: DATE: 08/22/00 PAGE: 6 Pace Project Number: 9216237 Client Project ID: Sanford 08/09/00 08/10/00 Matrix: Soil Results Units PRL Analyzed Analyst CAS# Footnotes 13.2 ND ND ND 118 88 ND ND ND 76 70 74 84 ND ND ND ND ND ND ND ND ND ND Method:% Moisture Prep Method: % 08/14/00 COE Method: VPH Prep Method: VPH mg/kg 12 08/12/00 SRR mg/kg 12 08/12/00 SRR mg/kg 12 08/12/00 SRR % 08/12/00 SRR 615-59-8 % 08/12/00 SRR 615-59·8 Method: EPH Prep Method: EPA 3550 mg/kg 12 08/15/00 RIJS mg/kg 12 08/15/00 RIJS mg/kg 12 08/15/00 RIJS % 08/15/00 RllS 321-60·8 % 08/15/00 RIJS 580·13·2 % 08/15/00 RllS 7194-86-7 % 08/15/00 RIJS 84-15·1 08/14/00 Method: EPA 8260 Prep Method: EPA 8260 ug/kg 12 08/10/00 JRS 75-71-8 ug/kg 12 08/10/00 JRS 74-87-3 ug/kg 12 08/10/00 JRS 75-01-4 ug/kg 12 08/10/00 JRS 74-83·9 ug/kg 12 08/10/00 JRS 75-00-3 ug/kg 5.8 08/10/00 JRS 1634-04-4 ug/kg 5.8 08/10/00 JRS 75-69-4 ug/kg 5.8 08/10/00 JRS 108·20-3 ug/kg 5.8 08/10/00 JRS 75·35·4 ug/kg 5.8 08/10/00 JRS 75-09-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I~ Pace Analytical Services. Inc. I 1~ceAnalyticar .( ~:_·_-,fncey Avenue. Suite 100 Huntersville. NC 28078 Phone. 10.J 8159092 Fax [phone] I Pace sample No: 921140463 SB·1C llient Sample ID: arameters I trans-1,2-Dichloroethene 1,1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Chloroform I Bromochloromethane 1,1,1-Trichloroethane 1,1-Dichloropropene 1,2-Dichloroethane I Carbon Tetrachloride Benzene Trichloroethene 1,2-0ichloropropane I Dibromomethane Bromodichloromethane Toluene 1,1,2-Trichloroethane 1,3-Dichloropropane I Oibromochloromethane Tetrachloroethene 1,2-Dibromoethane Chlorobenzene I 1,1,1,2-Tetrachloroethane Ethyl benzene m&p-Xylene Styrene o-Xylene (112-Dimethylbenzene) I Bromoform 1, 1,2,2-Tetrachloroethane lsopropylbenzene (Cunene) 1,2,3-Trichloropropane I Bromobenzene n-Propylbenzene 2-Chlorotoluene 4-Chlorotoluene I 1,3,5-Trimethylbenzene tert·Butylbenzene 1,2,4-Trimethylbenzene sec-Butyl benzene 1,3-Dichlorobenzene I I I laboratQ[Y: Certification ID~ NC Wastewater 12 f C Drinking Water 37706 C 99006 DATE: 08/22/00 PAGE: 7 Pace Project N1.J11ber: 9216237 Client Project ID: Sanford Date Collected: 08/09/00 Matrix: Soil Date Received: 08/10/00 Results units PRL Analyzed Analyst CAS# Footnotes ND ND ND ND ND ND ND ND ND NO ND ND NO ND ND ND ND ND ND NO NO ND NO NO NO ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND --. -... ---------------------·-----·--ug/kg 5.8 08/10/00 JRS 156-60-5 ug/kg 5.8 08/10/00 JRS 75-34-3 u9/k9 5.8 08/10/00 JRS 156-59·2 ug/kg 5.8 08/10/00 JRS 594-20-7 ug/kg 5.8 08/10/00 JRS 67-66-3 ug/kg 5.8 08/10/00 JRS 74-97-5 ug/kg 5.8 08/10/00 JRS 71·55-6 ug/kg 5.8 08/10/00 JRS 563-58-6 ug/kg 5.8 08/10/00 JRS 107-06-2 ug/kg 5.8 08/10/00 JRS 56-23-5 ug/kg 5.8 08/10/00 JRS 71-43-2 ug/kg 5.8 08/10/00 JRS 79-01-6 ug/kg 5.8 08/10/00 JRS 78-87-5 ug/lcg 5.8 08/10/00 JRS 74-95-3 ug/kg 5.8 08/10/00 JRS 75-27-4 ug/lcg 5.8 08/10/00 JRS 108-88-3 ug/lcg 5.8 08/10/00 JRS 79-00-5 ug/kg 5.8 08/10/00 JRS 142-28-9 ug/kg 5.8 08/10/00 JRS 124-48·1 ug/kg 5.8 08/10/00 JRS 127-18-4 ug/kg 5.8 08/10/00 JRS 106-93-4 ug/kg 5.8 08/10/00 JRS 108-90·7 ug/kg 5.8 08/10/00 JRS 630-20-6 ug/kg 5.8 08/10/00 JRS 100-41-4 ug/lcg 12 08/10/00 JRS 7816-60-0 ug/kg 5.8 08/10/00 JRS 100-42-5 ug/kg 5.8 08/10/00 JRS 95·47·6 ug/kg 5.8 08/10/00 JRS 75-25-2 ug/kg 5.8 08/10/00 JRS 79-34-5 ug/kg 5.8 08/10/00 JRS 98-82-8 ug/kg 5.8 08/10/00 JRS 96-18-4 us/kg 5.8 08/10/00 JRS 108-86-1 ug/kg 5.8 08/10/00 JRS 103-65· 1 ug/kg 5.8 08/10/00 JRS 95-49·8 ug/lcg 5.8 08/10/00 JRS 106-43-4 ug/kg 5.8 08/10/00 JRS 108·67·8 ug/kg 5.8 08/10/00 JRS 98-06-6 ug/kg 5.8 08/10/00 JRS 95-63·6 ug/kg 5.8 08/10/00 JRS 135-98-8 ug/kg 5.8 08/10/00 JRS 541-73-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. ·----------Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ace Analyticar· Pace Analytical Services. Inc. 980C· --_-c, Jvenue. Sc.:c · )J -_ ~-c·-sville. NC :_3_·-:-3 :::-::.w: 104 s,-5; :92 :::ax· 7048,-5=:g1 DATE: 08/22/00 PAGE: 8 I Pace Project Number: 9216237 Client Project ID: Sanford :..Pa_c_e-Sa-mp-le_N_o_: ____ 92_1_1_4_04_6_3 ___________ D_a_te_C_o'"'ll""'.'e-c-te_d,..:---=-o'::"'a1-.o=-=9-;o::-:o=-------:M-:-a,..t-r7ix_:_s=-o--:i,-;-l--------ll ient sample ID: SB·1C Date Received: 08/10/00 arameters Results Units PRL Analyzed Analyst CAS# Footnotes I I I p-lsopropyltoluene 1,4·0ichlorobenzene 1,2-Dichlorobenzene n-Butylbenzene 1,2·0ibromo·3-Chloropropane 1,2,4-Trichlorobenzene Naphthalene Hexachloro-1,3-butadiene 1,2,3-Trichlorobenzene Dibromofluoromethane CS) 1,2-0ichloroethane-d4 (S) Toluene-dB CS) 4-Bromofluorobenzene CS) IC/MS Semivolatiles Semivolatile Organics bis(2·Chloroethyl)ether Phenol I 2·Chlorophenol 1,3-Dichlorobenzene 1,4·Dichlorobenzene 1,2·Dichlorobenzene I Benzyl Alcohol bis(2·Chloroisopropyl)ether 2·Methylphenol Hexachloroethane I N·Nitroso-di-n-propylamine 3&4·Methylpheno l Nitrobenzene lsophorone 2·Nitrophenol I 2,4·Dimethylphenol bis(2·Chloroethoxy)methane Benzoic Acid 2,4-Dichlorophenol I 1,2,4-Triehlorobenzene Naphthalene 4·Chloroaniline Hexachloro-1,3-butadiene I I I I Laboratory Certification IDs NC Wastewater 12 NC Drinking Water 37706 I SC 99006 ■ ·-··--·--· . --......... . . . . ... . . . --.. -....... -... -----···-· ----------NO ND ND ND ND ND ND ND ND 102 97 96 98 ND ND ND ND ND ND ND ND ND NO ND ND ND ND ND ND ND ND ND ND ND ND ND ug/kg 5.8 08/10/00 JRS 99-87·6 ug/kg 5.8 08/10/00 JRS 106-46·7 ug/kg 5.8 08/10/00 JRS 95-50·1 ug/kg 5.8 08/10/00 JRS 104·51-8 ug/kg 5.8 08/10/00 JRS 96-12·8 ug/kg 5.8 08/10/00 JRS 120·82·1 ug/kg 5.8 08/10/00 JRS 91-20-3 Ug/kg 5.8 08/10/00 JRS Ug/kg 5.8 08/10/00 JRS 87-61 ·6 % 08/10/00 JRS 1868·53·7 % 08/10/00 JRS 17060·07·0 % 08/10/00 JRS 2037·26·5 % 08/10/00 JRS 460·00·4 Method: EPA 8270 Prep Method: EPA 3550 Ug/kg 380 08/14/00 DHJ 111·44·4 ug/kg 380 08/14/00 DHJ 108-95·2 ug/kg 380 08/14/00 DHJ 95-57·8 ug/kg 380 08/14/00 DHJ 541 • 73· 1 Ug/kg 380 08/14/00 DHJ 106-46·7 ug/kg 380 08/14/00 DHJ 95-50·1 ug/kg 760 08/14/00 OHJ 100·51·6 ug/kg 380 08/14/00 DHJ 39638·32·9 ug/kg 380 08/14/00 DHJ 95·48·7 ug/kg 380 08/14/00 DHJ 67-72-1 ug/kg 380 08/14/00 DHJ 621·64·7 ug/kg 380 08/14/00 DHJ ug/kg 380 08/14/00 DHJ 98-95-3 ug/kg 380 08/14/00 DHJ 78·59·1 ug/kg 380 08/14/00 DHJ 88·75·5 ug/kg 380 08/14/00 DHJ 105·67·9 ug/kg 380 08/14/00 DHJ 111·91·1 ug/kg 1900 08/14/00 DHJ 65·85·0 ug/kg 380 08/14/00 DHJ 120·83·2 ug/kg 380 08/14/00 DHJ 120·82·1 ug/kg 380 08/14/00 DHJ 91·20·3 Ug/kg 760 08/14/00 DHJ 106·47·8 Ug/kg 380 08/14/00 DHJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I _:~·_,,,;•'"'::,i) I -;0ace Analyticar Pace Analytical Services. Inc. c\3()0/{irt'c'', "·'.,::'/Uc s_. :2 ._-_' P-:,e. 70.:;s;'5gc~; F~x 70.JS:'590~; I Pace Sample No: 921140463 SB-1C lient Sample ID: rameters I I I 4-Chloro-3-methylphenol 2-Methylnaphthalene Hexachlorocyclopentadiene 2,4,6·Trichlorophenol 2,4,S·Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Acenaphthylene Dimethylphthalate 2,6·Dinitrotoluene Acenaphthene 3-Nitroaniline 2,4·Dinitrophenol Dibenzofuran I 2,4-Dinitrotoluene 4-Nitrophenol Fluorene I 4-Chlorophenyl·phenylether Diethylphthalate 4-Nitroaniline 1,2-Diphenylhydrazine 4,6-Dinitro-2-methylphenol I N·Nitrosodiphenylamine 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene I Anthracene Di·n·butylphthalate Fluoranthene Pyrene I Butylbenzylphthalate 3,31-Dichlorobenzidine Benzo(a)anthracene Chrysene I bi sC2-Ethylhexyl )phthalate Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene I I I n IDs NC Waste1:1ater 12 .:}CC Drinking Water 37706 I' 99006 ■ DATE: 08/22/00 PAGE: 9 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: Date Received: 08/09/00 08/10/00 Results Units PRL Analyzed Analyst CAS# ..... _______ .... -.. --.... -·-·---------------·--------ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ug/kg 760 08/14/00 DHJ 59-50-7 ug/kg 380 08/14/00 DHJ 91-57-6 ug/kg 380 08/14/00 OHJ 77-47·4 ug/kg 380 08/14/00 DHJ 88-06-2 ug/kg 380 08/14/00 DHJ 95·95-4 ug/kg 380 08/14/00 DHJ 91-58·7 ug/kg 1900 08/14/00 DHJ 88-74-4 ug/kg 380 08/14/00 DHJ 208-96-8 ug/kg 380 08/14/00 DHJ 131·11·3 ug/kg 380 08/14/00 DHJ 606-20-2 ug/kg 380 08/14/00 DHJ 83-32-9 ug/kg 1900 08/14/00 DHJ 99-09-2 ug/kg 1900 08/14/00 OHJ 51-28-5 ug/kg 380 08/14/00 DHJ 132-64·9 ug/kg 380 08/14/00 OHJ 121-14·2 ug/kg 1900 08/14/00 OHJ 100-02-7 ug/kg 380 08/14/00 DHJ 86-73-7 ug/kg 380 08/14/00 DHJ 7005·72-3 ug/kg 380 08/14/00 OHJ 84-66-2 ug/kg 1900 08/14/00 OllJ 100-01-6 Ug/kg 380 08/14/00 DHJ 122·66·7 ug/kg 380 08/14/00 OHJ 534·52·1 ug/kg 380 08/14/00 DHJ 86·30·6 ug/kg 380 08/14/00 OHJ 101-55-3 ug/kg 380 08/14/00 OHJ 118-74-1 ug/kg 1900 08/14/00 DHJ 87-86-5 ug/kg 380 08/14/00 DHJ 85-01·8 Ug/kg 380 08/14/00 DHJ 120-12-7 ug/kg 380 08/14/00 OHJ 84-74·2 ug/kg 380 08/14/00 OHJ 206-44-0 ug/kg 380 08/14/00 OHJ 129-00-0 ug/kg 380 08/14/00 DHJ 85-68·7 ug/kg 760 08/14/00 DHJ 91-94-1 ug/kg 380 08/14/00 OHJ 56-55-3 ug/kg 380 08/14/00 OHJ 218·01·9 ug/kg 380 08/14/00 DHJ 117-81-7 ug/kg 380 08/14/00 OHJ 117-84-0 ug/kg 380 08/14/00 OHJ 205-99·2 ug/kg 380 08/14/00 DHJ 207-08·9 ug/kg 380 08/14/00 DHJ 50-32·8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services. Inc. Matrix: Soil Footnotes ···----·-· Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I -/;;::~) 0 / l/~ce Analytical Pace Analytical Services. Inc. 9800 i<incer ~, :··. :' 5,_;,[;; -_-_, Huntc.:5. ~ ·;c 2sc,-: Phone -:.: 375 90~ ~-Fa ·o.: S759c;; • I Pace Sample No: lient Sample ID: rameters 921140463 SB-1C I Indeno(1,2,3·cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene 2-Fluorophenol (S) Phenol-d6 (S) I Nitrobenzene·dS (S) 2-Fluorobiphenyl CS) 2,4,6-Tribromophenol (S) Terphenyl-d14 CS) 1 Date Extracted I I I I I I I I I NC Drinking Water 37706 IC 99006 DATE: 08/22/00 PAGE: 10 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: Date Received: 08/09/00 08/10/00 Results Units PRL Analyzed Analyst CAS# ---------------.-... ·------------------··--·-·-· ND ND ND 34 38 33 32 39 35 ug/ks 380 08/14/00 DHJ 193-39-5 Ug/kg 380 08/14/00 DHJ 53-70-3 ug/kg 380 08/14/00 OHJ 191-24-2 % 08/14/00 DHJ 367-12·4 % 08/14/00 DHJ 13127·88·3 % 08/14/00 DHJ 4165-60-0 % 08/14/00 DHJ 321·60·8 % 08/14/00 DHJ 118-79-6 % 08/14/00 DHJ 1718-51-0 08/11/00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Matrix: Soil Footnotes ....... -. --.. -Laboratory Certification IDs KY Drinking Water 90090 TN UST list VA Drinking Water 213
I ~~""--~) .:~ ,-1 , _ :_,,,Pice Analytical Pcce Analytical Services_. Inc. .~:.-o.~ -_-"_ ~\·er1ue. Suite 100 -_ :::o·sville. NC 28078 ::----~:) 704.815.9092 ::dX-704.875.9091 I I Pace Sa111Jle No: lient Sample ID: rameters It Chemistry Percent Moisture Percent Moisture I Volati Les 921140471 SB-1D VPH in Soil by Mass. Method Aliphatic (C05·C08) I Aliphatic CC09-C12) Aromatic CC09-C10) 2,S·Dibromotoluene {FID){S) 2,S·Dibromotoluene {PID){S) I Semivolatiles EPH in Soil by Mass. Method I Aliphatic (C09-C18) Aliphatic CC19-C36) Aromatic CC11-C22) 2-Fluorobiphenyl CS) 2-Bromonaphthalene CS) I Nonatriacontane (S) o-Terphenyl {S) Date Extracted IMS Volatiles C/MS voes by 8260, low level Dichlorodifluoromethane Chloromethane I Vinyl Chloride Bromomethane Chloroethane Methyl•tert-butyl Ether I Trichlorofluoromethane I sopropyl Ether 1,1-Dichloroethene Methylene Chloride I I I ab rato ertific tion IDs C Wastewater 12 NC Drinking Water 37706 IC 99006 ■ Date Collected: Date Received: DATE: 08/22/00 PAGE: 11 Pace Project Number: 9216237 Client Project ID: Sanford 08/09/00 08/10/00 Matrix: Soil Results Units PRL Analyzed Analyst CAS# Footnotes 10.6 43 ND 23 82 81 ND ND ND 46 54 48 58 ND ND ND ND ND ND ND ND NO ND Method: % Moisture Prep Method: % 08/14/00 COE Method: VPH Prep Method: VPH mg/kg 11 08/12/00 SRR mg/kg 11 08/12/00 SRR mg/kg 11 08/12/00 SRR % 08/12/00 SRR 615-59-8 % 08/12/00 SRR 615-59·8 Method: EPH Prep Method: EPA 3550 mg/kg 11 08/15/00 RIJS mg/kg 11 08/15/00 RIJS mg/kg 11 08/15/00 RIJS % 08/15/00 RIJS 321-60-8 % 08/15/00 RIJS 580-13-2 % 08/15/00 RIJS 7194-86-7 % 08/15/00 RIJS 84-15-1 08/14/00 Method: EPA 8260 Prep Method: EPA 8260 ug/kg 11 08/10/00 JRS 75· 71-8 ug/kg 11 08/10/00 JRS 74·87·3 ug/kg 11 08/10/00 JRS 75-01 -4 ug/kg 11 08/10/00 JRS 74·83·9 ug/kg 11 08/10/00 JRS 75-00-3 ug/kg 5.6 08/10/00 JRS 1634-04·4 Ug/kg 5.6 08/10/00 JRS 75-69-4 ug/kg 5.6 08/10/00 JRS 108-20-3 ug/kg 5.6 08/10/00 JRS 75-35-4 ug/kg 5.6 08/10/00 JRS 75-09-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc_ Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
~""' Pace Analytical Services. Inc. I /~----_;; I /~ __ ,,Pace Analytical 9500 liinc2~ .J: 2:'ue Su1/2 : _-_-HU1itrrs~.'i!e. NC 25D-2 Phor:2· 704 815.90:l F~1 704.815.90~; 11 I Pace Sample No: 921140471 SB-10 lient Sample ID: rameters trans-1,2-Dichloroethene I 1, 1-Dichloroethane cis-1,2-Dichloroethene 2,2-Dichloropropane Chloroform I Bromochloromethane 1, 1, 1-Trichloroethane 1,1-Dichloropropene 1,2-Dichloroethane I Carbon Tetrachloride Benzene Trichloroethene 1,2-Dichloropropane Dibromomethane I Bromodichloromethane Toluene 1,1,2-Trichloroethane 1,3-Dichloropropane I Dibromochloromethane Tetrachloroethene 1,2-0ibromoethane Chlorobenzene 1, 1, 1,2-Tetrachloroethane I Ethyl benzene rn&p-Xylene Styrene o-Xylene (1,2-Dimethylbenzene) I Bromoform 1,1,2,2-Tetrachloroethane lsopropylbenzene (Cumene) 1,2,3-Trichloropropane Bromobenzene I n-Propylbenzene 2-Chlorotoluene 4-Chlorotoluene 1,3,5-Trimethylbenzene I tert-Butylbenzene 1,2,4-Trimethylbenzene sec-Butyl benzene 1,3-Dichlorobenzene I I I Labo rat · Ce ificati n I Os NC Wastewater 12 NC Drinking Water 37706 re 99006 DATE: 08/22/00 PAGE: 12 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: 08/09/00 Matrix: Soil Date Received: 08/10/00 Results Units PRL Analyzed Analyst CAS# Footnotes ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND NO ND ND ND ND ..... _ .. ____ -------------.......... ----------ug/kg 5.6 08/10/00 JRS 156-60-5 ug/lcg 5.6 08/10/00 JRS 75·34·3 ug/kg 5.6 08/10/00 JRS 156-59·2 ug/kg 5,6 08/10/00 JRS 594-20-7 ug/kg 5.6 08/10/00 JRS 67-66-3 ug/lcg 5.6 08/10/00 JRS 74-97-5 ug/kg 5.6 08/10/00 JRS 71-55-6 ug/kg 5.6 08/10/00 JRS 563-58-6 ug/lcg 5.6 08/10/00 JRS 107·06·2 ug/lcg 5.6 08/10/00 JRS 56·23-5 ug/lcg 5.6 08/10/00 JRS 71-43-2 ug/kg 5.6 08/10/00 JRS 79-01-6 ug/kg 5.6 08/10/00 JRS 78-87-5 ug/kg 5.6 08/10/00 JRS 74-95-3 ug/kg 5.6 08/10/00 JRS 75·27·4 ug/kg 5.6 08/10/00 JRS 108-88-3 ug/kg 5.6 08/10/00 JRS 79-00·5 ug/kg 5.6 08/10/00 JRS 142-28-9 ug/kg 5.6 08/10/00 JRS 124·48·1 ug/kg 5.6 08/10/00 JRS 127-18-4 ug/kg 5.6 08/10/00 JRS 106-93-4 ug/kg 5.6 08/10/00 JRS 108-90-7 ug/lcg 5.6 08/10/00 JRS 630-20·6 ug/lcg 5.6 08/10/00 JRS 100·41·4 ug/kg 11 08/10/00 JRS 7816-60-0 ug/kg 5.6 08/10/00 JRS 100-42-5 Ug/kg 5,6 08/10/00 JRS 95-47-6 ug/kg 5.6 08/10/00 JRS 75-25-2 ug/kg 5.6 08/10/00 JRS 79-34·5 ug/kg 5.6 08/10/00 JRS 98·82·8 ug/kg 5.6 08/10/00 JRS 96-18-4 ug/kg 5.6 08/10/00 JRS 108-86-1 ug/kg 5.6 08/10/00 JRS 103-65·1 ug/lcg 5.6 08/10/00 JRS 95·49-8 ug/lcg 5.6 08/10/00 JRS 106-43-4 ug/kg 5.6 08/10/00 JRS 108-67·8 ug/kg 5.6 08/10/00 JRS 98-06-6 ug/kg 5.6 08/10/00 JRS 95·63-6 ug/lcg 5.6 08/10/00 JRS 135-98·8 ug/kg 5.6 08/10/00 JRS 541-73·1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. ----------Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I Ice Sample No: ient sa~le ID: rameters I p-Isopropyl toluene 1,4·Dichlorobenzene 1,2·0ichlorobenzene n-Butylbenzene 921140471 SB-1D I 1,2-Dibromo-3-Chloropropane 1,2,4-Trichlorobenzene Naphthalene Hexachloro-1,3·butadiene 1,2,3-Trichlorobenzene I Dibromofluoromethane (S) 1,2-Dichloroethane-d4 CS) Toluene-dB (S) 4-Bromofluorobenzene (S) I/MS Semivolatiles Semivolatile Organics bis(2-Chloroethyl)ether I Phenol 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene I 1,2-0ichlorobenzene Benzyl Alcohol bis(2-Chloroisopropyl)ether 2·Methylphenol Hexachloroethane I N·Nitroso-di-n-propylamine 3&4-Methylphenol Nitrobenzene lsophorone I 2-Nitrophenol 2,4·Dimethylphenol bis(2-Chloroethoxy)methane Benzoic Acid I 2,4-Dichlorophenol 1,2,4-Trichlorobenzene Naphthalene 4-Chloroaniline I Hexachloro-1,3-butadiene I I borator Certifi ation IDs NC Wastewater 12 ltC Drinking Water 37706 .c 99006 ■ Date Collected: Date Received: Pace Anaiytical Services. Inc. }800/-i ·-·~ .. ~-~·we. S:. :,: ·.'o ----~-~·.i1ie. NC :~.--s DATE: 08/22/00 PAGE: 13 ::-.-~=· 704.Bi: ::92 ::3x 704.875 :c)91 Pace Project Number: 9216237 Client Project ID: Sanford 08/09/00 08/10/00 Matrix: Soil Results units PRL Analyzed Analyst CAS# Footnotes -·---------------------------. .... -.... -... ................... ........ 40 .. - -ND ND ND ND ND ND NO ND ND 102 97 95 91 ND ND ND ND ND ND ND ND NO NO ND ND ND ND ND NO ND ND ND ND ND ND ND ug/kg 5.6 08/10/00 JRS 99-87-6 ug/kg 5.6 08/10/00 JRS 106-46-7 ug/kg 5.6 08/10/00 JRS 95-50-1 ug/kg 5.6 08/10/00 JRS 104-51-8 ug/kg 5.6 08/10/00 JRS 96-12-8 ug/kg 5.6 08/10/00 JRS 120-82-1 ug/kg 5.6 08/10/00 JRS 91-20-3 ug/kg 5.6 08/10/00 JRS ug/kg 5.6 08/10/00 JRS 87-61-6 % 08/10/00 JRS 1868-53-7 % 08/10/00 JRS 17060-07-0 % 08/10/00 JRS 2037-26-5 % 08/10/00 JRS 460-00·4 Method: EPA 8270 Prep Method: EPA 3550 ug/kg 370 08/14/00 DHJ 111-44-4 ug/kg 370 08/14/00 DHJ 108·95-2 ug/kg 370 08/14/00 DHJ 95-57-8 ug/kg 370 08/14/00 OHJ 541-73-1 ug/kg 370 08/14/00 DHJ 106-46-7 ug/kg 370 08/14/00 DHJ 95-50-1 Ug/kg 740 08/14/00 DHJ 100-51-6 ug/kg 370 08/14/00 OHJ 39638-32-9 ug/kg 370 08/14/00 DHJ 95-48-7 ug/kg 370 08/14/00 OHJ 67-72-1 ug/kg 370 08/14/00 DHJ 621-64-7 ug/kg 370 08/14/00 DHJ ug/kg 370 08/14/00 DHJ 98-95-3 ug/kg 370 08/14/00 OHJ 78-59-1 ug/kg 370 08/14/00 DHJ 88-75-5 ug/kg 370 08/14/00 DHJ 105-67-9 ug/kg 370 08/14/00 OHJ 111-91-1 ug/kg 1800 08/14/00 OHJ 65-85-0 Ug/kg 370 08/14/00 DHJ 120-83-2 ug/kg 370 08/14/00 DHJ 120-82-1 ug/kg 370 08/14/00 OHJ 91-20·3 ug/kg 740 08/14/00 DHJ 106-47-8 ug/kg 370 08/14/00 DHJ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I,; I 1<,,,,Pace Analytical ,1 Pace Analytical Services, Inc. :300 ~. ---~) ~-~--~ S~1te 100 -:. ;,2:s. ::. '.'C 28076 Pi7C(5 -_'._; 575.9092 Fc.1 -)J 3?5.9097 I Pace Sample No: ■lient Sample ID: 921140471 SB-10 '3rameters 4-Chloro·3·methylphenol I 2-Methylnaphthalene Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol I 2-Chloronaphthalene 2-Nitroaniline Acenaphthylene Dimethylphthalate 2,6-Dinitrotoluene I Acenaphthene 3-Nitroaniline 2,4-Dinitrophenol Dibenzofuran I 2,4·Dinitrotoluene 4-Nitrophenol Fluorene 4-Chlorophenyl•phenylether I Diethylphthalate 4-Nitroaniline 1,2-Diphenylhydrazine 4,6·Dinitro-2-methylphenol N-Nitrosodiphenylamine I 4-Bromophenyl-phenylether Hexachlorobenzene Pentachlorophenol Phenanthrene I Anthracene Di-n-butylphthalate Fluoranthene Pyrene Butylbenzylphthalate I 3,3'-Dichlorobenzidine Benzo(a)anthracene Chrysene bis(2-Ethylhexyl)phthalate I Di-n-octylphthalate Benzo(b)fluoranthene Benzo(k)fluoranthene Benzo(a)pyrene I I I I Laboratory CertificaUon IDs NC Wastewater 12 NC Drinking Water 37706 1sc 9900s ■ DATE: 08/22/00 PAGE: 14 Pace Project Number: 9216237 Client Project ID: Sanford Date Collected: Date Received: 08/09/00 08/10/00 Results Units PRL Analyzed Analyst CAS# --------------------·---------.. ----------------ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ug/kg 740 08/14/00 DHJ 59-50-7 us/kg 370 08/14/00 DHJ 91-57-6 ug/kg 370 08/14/00 DHJ 77-47-4 ug/kg 370 08/14/00 DHJ 88-06-2 ug/kg 370 08/14/00 DHJ 95-95-4 ug/kg 370 08/14/00 DHJ 91-58-7 ug/kg 1800 08/14/00 DHJ 88-74-4 ug/kg 370 08/14/00 DHJ 208-96-8 ug/kg 370 08/14/00 DHJ 131-11-3 ug/kg 370 08/14/00 DHJ 606-20-2 ug/kg 370 08/14/00 DHJ 83-32-9 ug/kg 1800 08/14/00 DHJ 99-09-2 ug/kg 1800 08/14/00 DHJ 51-28-5 ug/kg 370 08/14/00 DHJ 132-64-9 ug/kg 370 08/14/00 DHJ 121-14-2 ug/kg 1800 08/14/00 DHJ 100-02-7 ug/kg 370 08/14/00 DHJ 86-73-7 Ug/kg 370 08/14/00 DHJ 7005-72-3 ug/kg 370 08/14/00 DHJ 84-66-2 ug/kg 1800 08/14/00 DHJ 100-01-6 ug/kg 370 08/14/00 DHJ 122-66·7 ug/kg 370 08/14/00 DHJ 534-52-1 ug/kg 370 08/14/00 DHJ 86-30-6 ug/kg 370 08/14/00 DHJ 101-55-3 ug/kg 370 08/14/00 DHJ 118-74-1 ug/kg 1800 08/14/00 DHJ 87-86-5 ug/kg 370 08/14/00 DHJ 85-01-8 ug/kg 370 08/14/00 DHJ 120-12-7 ug/kg 370 08/14/00 DHJ 84-74-2 ug/kg 370 08/14/00 DHJ 206-44-0 Ug/kg 370 08/14/00 DHJ 129·00-0 ug/kg 370 08/14/00 DHJ 85-68-7 ug/kg 740 08/14/00 DHJ 91-94-1 Ug/kg 370 08/14/00 DHJ 56-55·3 ug/kg 370 08/14/00 DHJ 218-01-9 ug/kg 370 08/14/00 DHJ 117-81-7 ug/kg 370 08/14/00 OHJ 117-84-0 ug/kg 370 08/14/00 DHJ 205-99-2 ug/kg 370 08/14/00 OHJ 207-08-9 ug/kg 370 08/14/00 DHJ 50-32-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Matrix: Soil Footnotes ....... ----Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I ace Analyticar· Pace Analytical Services, Inc. 9S00 K1nce1 :'!venue. Suite · _·_· Huntersville NC 2E~'.-.: Phone [phone]~2 Fax: [phone]~7 I DATE: 08/22/00 PAGE: 15 Pace Project Number: 9216237 Client Project ID: Sanford -Pa_c_e_S_a_m-pl-e-No_: ____ 9_21_1_4_04_7_1 __________ D_at_e_Co_l_l-ec-t-ed-:--0-8/_0_9_/0_0 _____ M-at_r_i_x_: -So_i,..,.l ______ _ ICli ent Sample ID: SB· 1D Date Received: 08/10/00 arameters Results Units PRL Analyzed Analyst CAS# I I I I I I I I I I I I lndeno(1,2,3·cd)pyrene Dibenz(a,h)anthracene Benzo(g,h,i)perylene 2·Fluorophenol (S) Phenol·d6 CS) Nitrobenzene·dS (S) 2-Fluorobiphenyl CS) 2,4,6-Tribromophenol (S) Terphenyl•d14 (S) Date Extracted Laboratory Certification I Os NC Wastewater 12 NC Drinking Water 37706 I SC 99006 -------------------------------------_____ ......... ND ND NO 47 50 45 48 55 47 ug/kg 370 08/14/00 DHJ 193·39·5 ug/kg 370 08/14/00 DHJ 53·70·3 ug/kg 370 08/14/00 DHJ 191·24·2 % 08/14/00 OHJ 367-12-4 % 08/14/00 OHJ 13127-88·3 % 08/14/00 DHJ 4165-60·0 % 08/14/00 DHJ 321-60-8 % 08/14/00 DHJ 118-79·6 % 08/14/00 DHJ 1718-51-0 08/11/00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Footnotes .......... ., -... Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I Pace Analytical Services. Inc . . : :':JO Kt!IC:'' ~.:: "' .. -:. Si;,::' . _-. Hur::·;. :.NC~'c·_--_: p--_· -~ ~.._:-! 81-E ~-·:::_· •=,: I 7rJ~ 375,~ .. -~ • DATE; 08/22/00 PAGE: 16 Pace Project Number: 9216237 Client Project ID: Sanford -----------------------------------------PAR AME TE R FOOTNOTES 1~ PRL IS) I I I I I I I I I I I Not Detected Not Calculable Pace Reporting Limit Surrogate llaboratory Certification IDs NC Wastewater 12 INC Drinking Water 37706 C 99006 ---, REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written cons~nt of Pace Analytical Services, Inc. Laboratory Certification -IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I Cooper Environmental, Inc. 2300 Sardis Road North luite Q harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: (704)845·2000 QUALITY CONTROL DATA QC Batch Method: EPA 8260 Pace r1natyiical Services. Inc. ··.:~l ~; :-= .. ~ ~~.':"2 ;[\! PiJc0.-:: -_-.: 3.~5909~-F2.1 -_-.:375_909; DATE: 08/22/00 PAGE: 17 Pace Project Number: 9216237 Client Project ID: Sanford Analysis Description: GC/MS voes by 8260, low level QC Batch ID: 30088 .tnalysis Method: EPA 8260 .ssociated Pace Samples: 921140430 921140463 921140471 METHOD BLANK: 921144341 lssociated Pace Samples: 921140430 Units ~--------~------4--------·---larameter ichlorodifluoromethane Chloromethane Vinyl Chloride -romomethane hloroethane ethyl·tert-butyl Ether Trichlorofluoromethane lsopropyl Ether ,1-Dichloroethene ethylene Chloride trans·1,2-Dichloroethene 1, 1-Dichloroethane -is-1,2-Dichloroethene ,2-Dichloropropane hloroform Bromochloromethane 1,1,l·Trichloroethane , 1-Dichloropropene ,2-Dichloroethane Carbon Tetrachloride -enzene richloroethene ,2-Dichloropropane Dibromomethane Bromodichloromethane I I I Laborator Certification IDs NC Wastewater 12 w!C Drinking Water 37706 re 99006 ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg 921140455 921140463 921140471 Method Blank Result PRL Footnotes -··-·-------·-------·---------ND 10 ND 10 ND 10 ND 10 ND 10 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 NO 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the ·:✓ritten consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I METHOO BLANK: 921144341 lssociated Pace Samples: 921140430 -arameter -----------------------------oluene 1, 1,2-Trichloroethane 1,3-Dichloropropane libromochloromethane etrachloroethene ,2-Dibromoethane Chlorobenzene li1,1,2·Tetrachloroethane hylbenzene p·Xylene Styrene o·Xylene (1,2·Dimethylbenzene) -romoform , 1,2,2·Tetrachloroethane sopropylbenzene (Cumene) 1,2,3-Trichloropropane lromobenzene •Propylbenzene ·Chlorotoluene 4-Chlorotoluene 1,3,S·Trimethylbenzene ert·Butylbenzene ,2,4-Trimethylbenzene sec·Butylbenzene 1,3-Dichlorobenzene l·Isopropyltoluene ,4·Dichlorobenzene ,2·Dichlorobenzene n·Butylbenzene i,2·Dibromo·3·Chloropropane ,2,4-Trichlorobenzene aphthalene Hexachloro·1,3·butadiene 1,2,3-Trichlorobenzene libromofluoromethane (S) ,2·Dichloroethane·d4 CS) oluene·d8 CS) 4-Bromofluorobenzene (S) I I I llaborator11 Certification IDs NC Wastewater 12 NC Drinking Water 37706 1sc 99006 --, Units ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/lcg ug/kg ug/kg ug/lcg ug/lcg ug/kg ug/kg ug/kg ug/kg ug/kg % % % % QUALITY CONTROL DATA Pace Anatytic3/ Services. In,;. 98UU i\:' .:.01 ~tell,'::'.,'. :~ :cii} Pi;,,ne· 70.:/.5-: ::L:9~' Fax· 70-1.S.: :~D91 DATE: 08/22/00 PAGE: 18 Pace Project Nuni::er: 9216237 Client Project ID: Sanford 921140455 921140463 921140471 Method Blank Result PRL Footnotes ------------------------------ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 10 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 100 100 98 99 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I .s:,..._.-14' ... ~~~-.. :l ! I race 14naly-iica/ I QUALITY CONTROL DATA I Pace Project Number: Client Project ID: MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 921139408 921139416 Matrix Matrix larameter ---------·-·---------•+------1, 1-Dichloroethene -enzene richloroethene oluene Chlorobenzene Dibromofluoromethane (S) -,2-Dichloroethane-d4 (S) oluene-d8 (S) -Bromofluorobenzene (S) Uni ts --------~-ug/kg ug/kg ug/kg ug/kg ug/kg Spike 921135810 cone. ----------0 56.32 0 56.32 0 56.32 1 .132 56.32 0 56.32 Spike Spike Sp. Dup. Result % Rec Result ++------------------62.72 111 59.77 61.93 11 o 59.94 62.28 111 58.73 61.09 106 57.91 59.90 106 57.36 98 98 100 98 IABORATORY CONTROL SAMPLE: 921139382 Spike LCS Spike Parameter -ichlorodifluoromethane hloromethane inyl Chloride Bromomethane lhloroethane ethyl•tert-butyl Ether richlorofluoromethane Isopropyl Ether -,1-Dichloroethene ethylene Chloride rans·1,2-Dichloroethene , 1-Dichloroethane cis-1,2-Dichloroethene 1,2-Dichloropropane hloroform romochloromethane 1,1, 1-Trichloroethane i,1·Dichloropropene ,2-Dichloroethane arbon Tetrachloride Benzene Trichloroethene -,2·Dichloropropane ibromomethane romodichloromethane Toluene I I I I Laboratorv Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 Units Cone. Result % Rec Footnotes -.. ________ ------------·-------ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg 50 31.38 62.8 50 35.23 70.5 50 44.72 89.4 50 42.95 85.9 50 41.89 83.8 so 46.41 92.8 so 46.76 93.5 50 46.02 92.0 50 49.28 98.6 50 41.62 83.2 50 49.24 98.5 50 49.24 98.5 so 50.04 100 so 47.97 95.9 so 48.52 97.0 50 51 .69 103 50 47.95 95.9 so 49.43 98.9 50 48.60 97.2 so 50.28 101 50 49.22 98.4 50 49.55 99. 1 so 48.80 97.6 50 49.30 98.6 50 49.62 99.2 50 49.19 98.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Pace Anaiyrical Services. Inc. ' . ' · -~. -·, Cf'::c-:..~ ... _·-: --. ·---~·ie1//~ _',-~-C0c:_--: :-::;= 70--i .:.---:: ,~_-,:~ "1.1 ;;o-r::.-::c:· DATE: 08/22/00 PAGE: 19 9216237 Sanford Spike Dup % Rec RPO Footnotes ------·---106 5 106 3 104 6 101 5 102 4 98 96 100 96 Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ~-✓-I /J ace Analyticar Pace Analyiic:il Services i,7c ,:·,)1 ":fl\ . ·.:. ~. ~-·~;C ~~ ·~ -. :>:·~ -o~3-:~:::_· =.,. 701r·: ~--~: I I LABORATORY CONTROL SAMPLE: 921139382 1~~:~::=~---------------------1, 1,2-Trichloroethane 1,3-Dichloropropane ibromochloromethane etrachloroethene 1,2-Dibromoethane Chlorobenzene 11,1,2-Tetrachloroethane hylbenzene p-Xylene Styrene I-Xylene (1,2-Dimethylbenzene) romoform ,1,2,2·Tetrachloroethane Isopropylbenzene (Cumene) 1,2,3-Trichloropropane -romobenzene ·Propylbenzene -Chlorotoluene 4-Chlorotoluene 1,3,S·Trimethylbenzene ert·Butylbenzene ,2,4-Trimethylbenzene sec-Butyl benzene -,3·Dichlorobenzene ·lsopropyltoluene ,4-Dichlorobenzene ,2-Dichlorobenzene n·Butylbenzene 1,2-Dibromo-3-Chloropropane ,2,4·Trichlorobenzene aphthalene Hexachloro-1,3-butadiene 1,2,3-Trichlorobenzene ibromofluoromethane (S) ,2-Dichloroethane·d4 (S) Toluene-dB (S) .-Bromofluorobenzene CS) I I I I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 ----, Uni ts ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg QUALITY CONTROL DATA DATE: 08/22/00 PAGE: 20 Pace Project Number: 9216237 Client Project ID: Sanford Spike Cone. 50 50 50 50 50 50 so so 100 50 50 so so 50 50 50 so so 50 50 50 50 so so 50 50 so 50 so 50 50 so so LCS Result -----·----SO. 12 49.44 49.73 51.43 51.52 49.21 50.61 50.07 102.2 50.76 50.01 47.24 50. 12 51,25 50.37 47.17 50.19 49.04 49.96 50.08 49.47 49.73 50,46 50.61 50.16 49.10 49.24 49.53 47.06 50,40 49.37 51. 16 50.20 Spike % Rec Footnotes --·-------100 98.9 99.5 103 103 98.4 101 100 102 102 100 94.5 100 103 101 94.3 100 98.1 99.9 100 98.9 99.5 101 101 100 98.2 98.5 99. 1 94.1 101 98.7 102 100 102 107 102 102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laborator1 Certification I Os KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I SAMPLE DUPLICATE: 921139390 farameter -----·-----------------------Dichlorodifluoromethane -hloromethane inyl Chloride romomethane Chloroethane Trichlorofluoromethane 1,1-Dichloroethene ethylene Chloride rans-1,2-Dichloroethene 1,1-Dichloroethane lis-1,2-Dichloroethene ,2-Dichloropropane hloroform Bromochloromethane •• 1,1-r,;chlo,oeth•n• ,1-Dichloropropene ,2-Dichloroethane arbon Tetrachloride Benzene lrichloroethene ,2-Dichloropropane ibromomethane Bromodichloromethane loluene ,1,2-Trichloroethane ,3-Dichloropropane Oibromochloromethane Tetrachloroethene ,,2-Dibromoethane hlorobenzene ,1,1,2-Tetrachloroethane Ethyl benzene fp-Xylene yrene Xylene (1,2-Dimethylbenzene) Bromoform 1,1,2,2-Tetrachloroethane -sopropylbenzene (Cumene) ,2,3-Trichloropropane romobenzene n-Propylbenzene I I I I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 ' QUALITY CONTROL DATA oup. Units 921135802 Result RPO Pace Anslyiica/ Services. Inc. ·.-~: ·hc=r .. ~ .. .:: ... -~ 1Ll0 ..... "!iefS~ I:,~ ·. -~ _~3),.-S :'':one .-:·.: :· -: ,:092 Fax :-:'.: :-.~ ~091 DATE: 08/22/00 PAGE: 21 Pace Project Number: 9216237 Client Project JD; Sanford Footnotes ---------.-____ ,.. _____ ·-------·-ug/kg ug/kg Ug/kg Ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC ND NO NC ND ND NC 44.00 47.00 6 ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC ND NO NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ,,,,,-··-·) -~--/ i I Pace Analyticar· Face Analytical Services. Inc. ·, 1.\li1C2J ..:. ~ ·_,'; ~-:·:"2 \\: l-h:,;:~·:. : .','C 280.~d I I SAMPLE DUPLICATE: 921139390 lararneter _____________________ 2·Chlorotoluene 1·Chlorotoluene ,3,5-Trirnethylbenzene ert·Butylbenzene 1,2,4·Trimethylbenzene -•c·Butylb,n,,o, ,3·Dichlorobenzene ·lsopropyltoluene ,4-Dichlorobenzene 1,2-Dichlorobenzene 1·Butylbenzene ,2·Dibromo-3-Chloropropane ,2,4-Trichlorobenzene Naphthalene -exachloro·1,3-butadiene ,2,3-Trichlorobenzene ibromofluoromethane (S) 1,2-Dichloroethane·d4 CS) Toluene-dB (S) 1-Bromofluorobenzene CS) I I I I I I I I QUALITY CONTROL DATA Oup. Units 921135802 Result RPO P/Jc.·~ -J.: 375.9092 FE· -l;.;,575.9091 DATE: 08/22/00 PAGE: 22 Pace Project Number: 9216237 Client Project ID: Sanford Footnotes ------------------·-----··----ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg % % % % ND ND NC ND ND NC 29.00 47.00 47 ND ND NC 56.00 91.00 48 9.900 16.00 46 ND ND NC 8.300 13.00 42 ND ND NC ND NO NC ND ND NC ND ND NC ND ND NC 13.00 18.00 32 ND NO NC ND NO NC 95 95 0 92 89 0 99 98 0 98 97 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services. Inc. Laboratory Certification IDs KY Drinking Water 90090 HI UST List VA Drinking Water 213
I I I I Cooper Environmental, Inc. 2300 Sardis Road North luite Q harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: (704)845·2000 -QC Batch ID: 30122 QUALITY CONTROL DATA QC Batch Method: EPA 3550 PJce Anaiy[lcai Ser,ices. Inc. ~:_..:~'{' ;,·J':L-~ -. ~ -_.7 SL.'.1:·c= . _-. H:. ··.-~ ; . " .VC ~'f --.-p-_· -~ -~~-!.875.~.·:::-· :-:;. , -J-! 575~:,~;-DATE: 08/22/00 PAGE: 23 Pace Project Number: 9216237 Client Project ID: Sanford Analysis Description:·Semivolatile Organics Analysis Method: EPA 8270 lssociated Pace Samples: 921140430 921140463 921140471 METHOD BLANK: 921140539 lssociated Pace Samples: 921140430 Units ---------------·-------------iarameter is(2-Chloroethyl)ether Phenol 2-Chlorophenol 1,3-0ichlorobenzene ,4-0ichlorobenzene ,2-0ichlorobenzene Benzyl Alcohol 's(2-Chloroisopropyl)ether Methylphenol xachloroethane N-Nitroso·di·n·propylamine 3&4-Methylphenol 'trobenzene ophorone Nitrophenol 2,4-Dimethylphenol ls(2·Chloroethoxy)methane nzoic Acid ,4-0ichlorophenol 1,2,4-Trichlorobenzene fphthalene Ch l oroani line xachloro-1,3-butadiene Chloro-3-methylphenol 2-Methylnaphthalene I I I ILaboratorv Certification IDs NC Wastewater 12 t~JC Drinking Water 37706 C 99006 I ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/lcg ug/kg ug/kg ug/kg ug/kg 921140455 Method Blank Result PRL Footnotes .. __________ ........... --------·· NO 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 660 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 NO 1600 ND 330 ND 330 NO 330 NO 660 ND 330 NO 660 NO 330 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
./-~·.·,t ,:~-/i I I .-Pace 1~na1yticar P1ca ,~nalytica/ Sarvices. Inc . . -I\,::.·..:, ..:.. ; ---~ ~,.:_i_r-3 • ----' ~~-., ... QUALITY CONTROL DATA I DATE: 08/22/00 PAGE: 24 Pace Project Number: 9216237 Client Project ID: Sanford _-,j,~·.:'~ .--~ -----------------------------------------METHOD BLANK: 921140539 lssociated Pace Samples: 921140430 l;~~:!:~~~~~l~~~~;;di~~~-----Uni ts ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol l·Chloronaphthalene ·Nitroaniline cenaphthylene Dimethylphthalate -,6-Dinitrotoluene cenaphthene -Nitroaniline 2,4-Dinitrophenol Oibenzofuran ,,4-Dinitrotoluene ·Nitrophenol luorene 4-Chlorophenyl-phenylether liethylphthalate -Nitroani line ,2-Diphenylhydrazine 4,6·Dinitro·2-methylphenol -·Nitrosodiphenylamine ·Bromophenyl-phenylether exachlorobenzene entachlorophenol Phenanthrene lthracene -n·butylphthalate uoranthene Pyrene ftylbenzylphthalate 31-Dichlorobenzidine nzo(a)anthracene Chrysene bis(2-Ethylhexyl)phthalate 1-n-octylphthalate nzo(b)fluoranthene nzoCk)fluoranthene Benzo(a)pyrene I I I llaboratory Certification IDs NC Wastewater 12 NC Drinking Water 37706 1sc 99005 I 921140455 Method Blank Result PRL Footnotes ------·-·----------· ----------ND 330 ND 330 ND 330 ND 330 ND 1600 ND 330 ND 330 ND 330 ND 330 ND 1600 ND 1600 ND 330 ND 330 ND 1600 ND 330 ND 330 ND 330 ND 1600 ND 330 ND 330 ND 330 ND 330 ND 330 ND 1600 NO 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 660 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 ND 330 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laborator, Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 2i 3
I .·~·· I Pace Analytical Pcce Analy/JcJJ Services. Inc. ,:300 li1c~ ~. :''1Ue. Su;::3 ·.·' h. ·:: , . illr.. NC ~-f_. -_: r:-.--': 704875~,.-,:~-.::-3· ... 704.875.:<:~i I I IIETHOD BLANK: 921140539 1ssociated Pace Samples: 921140430 l~~~~~~~~--------------··-----ndeno(1,2,3-cd)pyrene Dibenz(a,h)anthracene Units ug/kg ug/kg ug/kg % -enzo(g,h,i)perylene -Fluorophenol CS) henol-d6 (S) Nitrobenzene-d5 CS) 2-Fluorobiphenyl (S) 1,4,6-Tribromophenol (S) erphenyl ·d14 (S) IETHOO BLANK: 921143723 ssociated Pace Samples: % % % % % 921140463 Units -arameter -----······-----·-~·---------is(2·Chloroethyl)ether Phenol 1-Chlorophenol ,3-Dichlorobenzene ,4-Dichlorobenzene 1,2-Dichlorobenzene •enzyl Alcohol is(2·Chloroisopropyl)ether -Methyl phenol exachloroethane N·Nitroso-di-n·propylamine 1!4-Methylphenol trobenzene ophorone 2-N it roph eno l *4·Dimethylphenol s(2-Chloroethoxy)methane nzoic Acid 2,4-Dichlorophenol .,2,4-Trichlorobenzene I I I Laboratorv Certification IDs NC Wastewater 12 INC Drinking Water 37706 SC 99006 ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg QUALITY CONTROL DATA DATE: 08/22/00 PAGE: 25 Pace Project Number: 9216237 Client Project ID: Sanford 921140455 Method Blank Result ND ND ND 51 58 67 70 47 81 921140471 Method Blank Result ----------ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND PRL 330 330 330 PRL ·-·----·---330 330 330 330 330 330 660 330 330 330 330 330 330 330 330 330 330 1600 330 330 Footnotes Footnotes ----------REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. without the written consent of Pace Analytical Services, Inc, Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I .~/-"-~:) I . -Pc.1ceAna/J'iicar· Pace A11aly/ical Services. Inc. ~~~::.)Li l\:(h~~t ~ . ..: · .. .--.: ·..: . -I fTHOD BLANK: 921143723 sociated Pace Samples: 921140463 Units lrameter ---·-------··----------~----phthalene 4-Chloroaniline fxachloro-1,3-butadiene Chloro-3-methylphenol Methylnaphthalene Hexachlorocyclopentadiene 2,4,6·Trichlorophenol 14,5-Trichlorophenol Chloronaphthalene Nitroaniline Acenaphthylene l·methylphthalate 6·Dinitrotoluene enaphthene 3-Nitroaniline 2,4-Dinitrophenol lbenzofuran 4-0initrotoluene -Nitrophenol Fluorene IChlorophenyl·phenylether ethylphthalate Ni t roan i l i ne 1,2-Diphenylhydrazine *6-Dinitro-2-methylphenol Nitrosodiphenylamine Bromophenyl·phenylether Hexachlorobenzene Pentachlorophenol lenanthrene thracene ·n-butylphthalate Fluoranthene Irene tylbenzylphthalate 3'·0ichlorobenzidine Benzo(a)anthracene jrysene I I llaboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 re 99006 I ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg QUALITY CONTROL DATA DATE: 08/22/00 PAGE; 26 Pace Project Number: 9216237 Client Project ID: Sanford 921140471 Method Blank Result PRL Footnotes --------------··-· .. ----------· ND 330 ND 660 NO 330 ND 660 NO 330 ND 330 NO 330 ND 330 ND 330 ND 1600 NO 330 ND 330 ND 330 ND 330 ND 1600 ND 1600 ND 330 ND 330 ND 1600 ND 330 ND 330 ND 330 ND 1600 ND 330 ND 330 ND 330 ND 330 NO 330 ND 1600 ND 330 ND 330 ND 330 NO 330 NO 330 NO 330 NO 660 ND 330 ND 330 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
Pace Anaiyucal Services. Inc. I I ,,--Pace Analyticar >_·1113· 10~ :-: qo92 "ax. 70h-:.9091 I I METHOD BLANK: 921143723 lsociated Pace Samples: 92114D463 l~~~~::~---------------------s(2-Ethylhexyl)phthalate Units ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg % Di-n-octylphthalate 'nzoCb)fluoranthene nzo(k)fluoranthene nzoCa)pyrene ndenoC1,2,3-cd)pyrene Dibenzca,h)anthracene .nzoCg,h,i)perylene Fl uoropheno l CS) enol-d6 CS) Nitrobenzene-d5 CS) IFluorobiphenyl CS) 4,6-Tribromophenol CS) rphenyl-d14 CS) % % % % % QUALITY CONTROL DATA 921140471 Method Blank Result ND ND ND NO ND ND ND ND 34 42 36 36 34 38 PRL 330 330 330 330 330 330 330 330 DATE: D8/22/00 PAGE: 27 Pace Project Number: 9216237 Client Project ID: Sanford Footnotes ITRIX SPIKE & MATRIX SPIKE DUPLICATE: 921140661 921140679 rameter Units Spike 921140000 Cone. Matrix Matrix Spike Spike Spike Sp. Dup. Dup Result % Rec Result % Rec RPO Footnotes lenol Chlorophenol 4-Dichlorobenzene N-Nitroso-di-n-propylamine 1 2,4-Trichlorobenzene IChloro-3-methylphenol enaphthene ,4-Dinitrotoluene 4-Nitrophenol lntachlorophenol rene Fluorophenol (S) Phenol-d6 CS) *·trobenzene-d5 CS) Fluorobiphenyl CS) 4,6-Tribromophenol CS) erphenyl -d14 ( S) I I I laboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 .c 99006 • ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ----------....... _____ ----------0 2004 846.5 42.2 986.8 0 2004 891.4 44.5 964.2 0 2004 869.3 43.4 941.2 0 2004 842.3 42.0 932.0 0 2004 950.6 47.4 1017 0 2004 944.3 47. 1 1085 98.08 2004 961.5 43. 1 ,on 0 2004 876.5 43.7 778.2 0 2004 914.1 45.6 1041 0 2004 970.7 48.4 1065 109.0 2004 1179 53,4 1343 43 45 41 50 50 57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. ----------49.2 15 48. 1 8 47.0 8 46.5 10 50.7 7 54. 1 14 48.9 13 38.8 12 52,0 13 53. 1 9 61.6 14 45 48 35 54 57 66 Laboratory Certification I Os KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I LABORATORY CONTROL SAMPLE: 921140562 lrameter ----------------------------bis(2-Chloroethyl)ether lenol Chlorophenol -3-Dichlorobenzene 1,4-0ichlorobenzene 1,2-Dichlorobenzene lnzyl Alcohol s(2-Chloroisopropyl)ether Methyl phenol Hexachloroethane INitroso-di-n-propylamine 4-Methylphenol trobenzene Isophorone 2-Nitrophenol 14-0imethylphenol s(2-Chloroethoxy)methane nzoic Acid 2,4-Dichlorophenol 12,4-Trichlorobenzene phthalene Chloroani line Hexachloro-1,3-butadiene 'Chloro-3-methylphenol Methylnaphthalene xachlorocyclopentadiene ,4,6-Trichlorophenol 2,4,5-Trichlorophenol IChloronaphthalene Ni troanil ine enaphthyl ene Dimethylphthalate i6-Dinitrotoluene enaphthene Nitroani line 2,4-Dinitrophenol Dibenzofuran 14-Dinitrotoluene Nitrophenol uorene 4-Chlorophenyl-phenylether I I I aborator Certificati n IDs NC Wastewater 12 NC Drinking Water 37706 tc 99006 ■ Units ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Spike Cone. 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 QUALITY CONTROL DATA LCS Spike Result % Rec ----------849.5 51.0 876.5 52.6 883.7 53.0 880.9 52.9 852.0 51. 1 860.6 51.6 867.9 52. 1 985.0 59.1 862.1 51.7 866.8 52.0 859.6 51.6 874.1 52.4 910.6 54.6 912.2 54.7 865.6 51.9 886.6 53.2 905.2 54.3 165.6 9.94 908.3 54.5 940.1 56.4 928.8 55.7 890.0 53.4 904.5 54.3 915.8 55.0 955.2 57.3 946.3 56.8 890.6 53.4 841.9 50.5 940.8 56.4 940.1 56.4 3406 204 971.5 58.3 971.0 58.3 923.8 55.4 954.6 57.3 219.2 13.2 972.2 58.3 1026 61.5 898.2 53.9 965.0 57.9 996.2 59.8 Pace Project Number: Client Project ID: Footnotes ----------2 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full. without the written consent of Pace Analytical Services. Inc. Pac2 .4nalytical Services, Inc. ~:: _- _-. ., ·:;cey .-4~ ~:~:.. :'. Su/ti; \.t Hunt21st ; 1:. NC 2Bo;:·s PlwrE -o.J.87S.9092 fa, ,-i):/81590!)1 DATE: 08/22/00 PAGE: 28 9216237 Sanford Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I LABORATORY CONTROL SAMPLE: 921140562 1~~:~::=~---··----------------Diethylphthalate I-Ni troani line ,2-0iphenylhydrazine ,6-0initro-2-methylphenol N-Nitrosodiphenylamine 4-Bromophenyl·phenylether lxachlorobenzene ntach lorophenol enanthrene Anthracene l·-n·butylphthalate uoranthene rene Butylbenzylphthalate 3,31-0ichlorobenzidine lnzo(a)anthracene rysene s(2-Ethylhexyl)phthalate Oi-n-octylphthalate lnzo(b)fluoranthene nzo(k)fluoranthene nzo(a)pyrene Indeno(1,2,3·cd)pyrene 'benz(a,h)anthracene nzo(g,h,i)perylene Fluorophenol CS) enol·d6 CS) Nitrobenzene-d5 CS) IFluorobiphenyl CS) 4,6·Tribromophenol CS) rphenyl-d14 CS) IMPLE DUPLICATE: 921143731 Parameter ls(2-Chloroethyl)ether enol Ch l orophenol 1,3-Dichlorobenzene I I I llaboratory Certification IDs NC Wastewater 12 NC Drinking Water 37706 1sc 9900s ■ Units ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg us/kg ug/kg Ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg Units ug/kg ug/kg ug/kg ug/kg QUALITY CONTROL DATA Pace Analytical Services. Inc. ·~~:.:_: ~l t?llLE :::~_::.•:..~ :{?j .-f~_;:;·01-s1• Ille. ·. ,._~ :lSO,~S Pr.one 70--i 5T5.9092 Fax: 70--! 275.9091 DATE: 08/22/00 PAGE: 29 Pace Project Number: 9216237 Client Project ID: Sanford Spike Cone. 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 1667 LCS Result ----------957.8 950.3 960.0 655.5 978.1 1089 988.2 661.4 984.2 1009 978.8 979.6 1033 957.9 2011 1033 996.9 1021 951.3 1093 983.5 1044 1059 1144 1089 Dup. 921140570 Result ND ND ND ND ND ND ND ND Spike % Rec 57.5 57.0 57.6 39.3 58.7 65.3 59.3 39.7 59. 1 60.6 58.7 58.8 62.0 57.5 121 62.0 59.8 61.3 57. 1 65.6 59.0 62.7 63.6 68.7 65.4 49 53 56 58 58 66 Footnotes ----------RPD NC NC NC NC Footnotes REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I SAMPLE DUPLICATE: 921143731 larameter ---~·-·····------------------1,4·Dichlorobenzene 1•2·Dichlorobenzene enzyl Alcohol is(2-Chloroisopropyl)ether 2·Methylphenol ·•••chlocoethooe ·Nitroso-di-n-propylamine &4·Methylphenol itrobenzene lsophorone 1·Nitrophenol ,4-Dimethylphenol is(2-Chloroethoxy)methane Benzoic Acid _,4-o;chlo,opheool ,2,4-Trichlorobenzene aphthalene ·Chloroaniline Hexachloro·1,3-butadiene 1·Chloro·3-methylphenol -Methyl naphthalene exachlorocyclopentadiene 2,4,6-Trichlorophenol 1,4,5-Trichlorophenol ·Chloronaphthalene ·Nitroaniline Acenaphthylene Dimethylphthalate t.6·0initrotoluene enaphthene Nitroanil ine 2,4-Dinitrophenol libenzofuran ,4-Dinitrotoluene ·Nitrophenol Fluorene 'Chlocophe"Yl·pheoylethe, ethylphthalate Nitroaniline ,2-Diphenylhydrazine 4,6-Dinitro-2-methylphenol I I I llaboratory Certification IDs NC Wastewater 12 INC Drinking Water 37706 SC 99006 ■ QUALITY CONTROL DATA Dup. Units 921140570 Result RPO Face Anaiyt:cai Services. inc. ·····1·_, ~.c·_, : .. :0 _·: DATE: 08/22/00 PAGE: 30 Pace Project Number: 9216237 Client Project ID: Sanford Footnotes -----------~------------------ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg Ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC ND ND NC NO ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification I Os KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I iAMPLE DUPLICATE: 921143731 arameter ------------··---------••-----N·Nitrosodiphenylamine IBromophenyl-phenylethe, xachlorobenzene ntachlorophenol Phenanthrene -nthracene i·n-butylphthalate luoranthene Pyrene Butylbenzylphthalate 13'-Dichlorobenzidine nzo(a)anthracene rysene bis(2·Ethylhexyl)phthalate 1·n·octylphthalate nzo(b)fluoranthene nzo(k)fluoranthene Benzo(a)pyrene Indeno(1,2,3-cd)pyrene lbenz(a,h)anthracene nzo(g,h,i)perylene Fluorophenol (S) Phenol·d6 CS) ltrobenzene-d5 CS) Fluorobiphenyl CS) ,4,6-Tribromophenol (S) Terphenyl-d14 CS) I I I I I I llaboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 re 99006 QUALITY CONTROL DATA Oup. Units 921140570 Result RPO Pace ~nalyticai Services. Inc. ----.. ,..-,,:=~ ..:. :··_-?_ Su,it= :CO --/un,2,5, ; NC lic.-a P:1c,::: -.~-J 875.!?u?l F;,, -a-J.875.9091 DATE: 08/22/00 PAGE: 31 Pace Project Number: 9216237 Client Project ID: Sanford Footnotes ----------···-----------------ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg ug/kg % % % % % % ND ND NC NO ND NC NO NO NC ND ND NC ND NO NC ND ND NC ND ND NC ND NO NC ND ND NC ND ND NC ND NO NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC NO ND NC ND ND NC NO ND NC 48 38 0 53 50 0 42 36 0 29 26 0 3 52 49 0 46 42 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I QUALITY CONTROL DATA Pace Analytical Services. Inc. :)::iOLPi•.'\'2\ lc'i',.:' S .. ::' -_-,1 Nuntc,s1 ,, -~-·,:L,~ .:.:"'Ci..\-0 Phon2 ,-:-:J~ 5.;-s ~._;~ .2 F3,\, TC~ 3.~5 ~G191 DATE: 08/22/00 PAGE: 32 Cooper Environmental, Inc. 2300 Sardis Road North Pace Project Number: 9216237 Client Project ID: Sanford luite Cl harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: [phone] QC Batch Method: VPH Analysis Description: VPH in Soil by Mass. Method QC Batch ID: 30181 ~nalysis Method: VPH 1ssociated Pace Samples: 921140430 921140463 921140471 METHOD BLANK: 921143954 lssociated Pace Samples: 921140430 Units ----·--------~---------~·----larameter liphatic (C05-C08) Aliphatic (C09-C12) Aromatic (C09-C10) 1,5-Dibromotoluene (FID)CS) ,5-Dibromotoluene (PID)(S) mg/kg mg/kg mg/kg % % 921140455 Method Blank Result ND ND ND 80 121 921140463 PRL 10 10 10 921140471 Footnotes IBORATORY CONTROL SAMPLE & LCSO: 921143962 921143970 Spike LCS rameter Units Cone. Result Spike % Rec LCSD Result Spike Dup % Rec RPO Aliphatic (C05-C08) 'liphatic (C09-C12) romatic (C09-C10) ,5-Dibromotoluene CFID)(S) 2,5-Dibromotoluene CPID)(S) IMPLE DUPLICATE: 921143988 ,~::::::-(C05-C08)·----------Aliphatic (C09-C12) Aromatic (C09-C10> I I I I Laboratory Certjfication IDs NC Wastewater 12 INC Drinking Water 37706 SC 99006 mg/kg mg/kg mg/kg Units mg/kg mg/kg mg/kg 8.000 5.919 2.000 2.471 2.000 2.503 Dup. 921135802 Result 74.0 124 125 118 125 ................. ··---------9.200 10.00 21.00 20.00 85.00 85.00 -------·-· 5.924 74.0 0 2.683 134 8 2.580 129 3 91 106 RPO Footnotes -------··-10 6 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Footnotes ...... _____ 4 Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I!¥) I /~ce Analytical Pace Analytical Services. Inc. ,;soo k'iflce_:· ~ . .:''ue. SL'::•= ; 1.,'t1 Hunt2rs:. :/fc. NC 2SD,-:-~ Pt;cr;2. 7'04.875.9092 Fax i04.875.909i ,1 QUALITY CONTROL DATA I DATE: 08/22/00 PAGE: 33 Pace Project Number: 9216237 Client Project ID: Sanford -----.,,.,..,..~-=------------------------------SAMPLE DUPLICATE: 921143988 1~~~~=:=~---------------------2,5-Dibromotoluene (FID)(S) 1,5-Dibromotoluene CPID)CS) I I I I I I I I I I I ILaboratory Certification IDs NC Wastewater 12 INC Drinking Water 37706 SC 99006 • Units % % Dup. 921135802 Result 404 391 205 207 RPO 0 0 Footnotes 5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, \'/ithout the written consent of Pace Analytical Services, Inc. Laboratory Certification I Os KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I u'/J __ ..,, ./ __ /PaceAnalyticar I QUALITY CONTROL DATA 01c~. Analyticai Services. In~: ,-:_',' 1,.-,_":-.--.0-_.:!. Sw,2 1• _ i-i_ ·::-i. ~-NC ~'s:-~ DATE: 08/22/00 PAGE: 34 -u-l.875.i:O::l .-~· -:J-l875.9C;: I . Cooper Environmental, Inc, 2300 Sardis Road North Pace Project Number: 9216237 Client Project ID: Sanford ISuite c Charlotte, NC 28227 IAttn: Mr. Doug Pierotti Phone: [phone] CC Batch ID: 30232 QC Batch Method: EPA 3550 Analysis Description: EPH in Soil by Mass_ Method Analysis Method: EPH IAssociated Pace Samples: 921140430 92114D463 921140471 METHOD BLANK: 921146122 IAssociated Pace Samples: 921140430 IParameter ____________________ _ Aliphatic (C09-C18) Aliphatic (C19-C36) Units mg/kg mg/kg mg/kg % Aromatic (C11-C22) 12-Fluorobiphenyl (S) 2-Bromonaphthalene CS) Nonatriacontane (S) o-Terphenyl (S) % % % 921140455 921140463 921140471 Method Blank Result PRL Footnotes ND -10 ND 10 ND 10 61 46 52 62 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 921146130 921146148 Matrix Matrix Parameter 1----------------------------·· Aliphatic (C09-C18) Aliphatic (C19-C36) Aromatic (C11-C22) 12-Fluorobiphenyl (S) 2-Brornonaphthalene (S) Nonatriacontane (S) o-Terphenyl (S) I I I I I Laboratory Certjfication IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 ■ Units mg/kg mg/kg mg/kg Spike 921140166 Cone. 0 38.25 0 51 0 108.4 Spike Result ·---------15.41 26.30 66.99 Spike Sp. Dup. % Rec Result ----------40.3 22.25 51.6 35.83 61.8 71.20 65 28 36 58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, 1·1ithout the written consent of Pace Analytical Services, Inc. Spike Dup % Rec 58.2 70.3 65.7 58 24 46 63 RPO Footnotes 36 31 6 6,6 6 Laboratory Certification I Os KY Drinking Water 90090 TN UST List VA Drinking Water 213
QUALITY CONTROL DATA I LABORATORY CONTROL SAMPLE: 921146155 Pace Analytical Services. Inc. :1::iLh} /i:nc"c_. ~., .. -·: :·_. :c -_-_-f--:'L--~-•~:~, ~-t.f: _-Ju.-~ p,-:,--~ -J_;_s/-: 909: :::3. •. -o./ s.,5 909: DATE: 08/22/00 PAGE: 35 Pace Project Number: 9216237 Client Project ID: Sanford 1~~~~=~=~----------·····------~~~~~-----Spike LCS Spike Cone. Result % Rec Footnotes --------------------Aliphatic (C09·C18) mg/kg lliphatic CC19·C36) mg/kg romatic (C11-C22) mg/kg -Fluorobiphenyl (S) 2·Bromonaphthalene CS) Nonatriacontane CS) 1-Terphenyl (S) I I I I I I I I I I I Laboratory Certification I Os NC Wastewater 12 I NC Drinking Water 37706 SC 99006 ■ 30 12.38 41.3 40 17.64 44.1 85 65.27 76.8 69 37 6 32 6 84 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ;~~) / / I /~ __ /Pace Analyticar Pace Analytical Services. Inc. .-1C·t~:...1 /\//'l'2~ _:, ~ -~ : ... ·-:: ~ _-_-Hur:~·~. ' ..... 7 ~ - - -~ . ~ ~CL-~~ Pllorc I I Cooper Environmental, Inc. 2300 Sardis Road North luite Q harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: [phone] QC Batch ID: 30246 Analysis Method:% Moisture lssociated Pace Samples: SAMPLE DUPLICATE: 921147013 ,~~~':'.':~~~---------------------Percent Moisture IAMPLE DUPLICATE: 921147021 Parameter 1--·-···---------·------------ercent Moisture I I I I I I I I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 , SC 99006 ■ QUALITY CONTROL DATA DATE: 08/22/00 PAGE: 36 Pace Project Number: 9216237 Client Project ID: Sanford QC Batch Method: Analysis Description: Percent Moisture 921140430 921140463 921140471 Dup. Units 921145124 Result RPD Footnotes ----............ ..... -...... -...... ----·------------% 22.90 22.80 0 Dup. Units 921140950 Result RPO Footnotes -------------------------------··-···---% 22.70 23.20 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, 1.·1ithout the ·:iritten consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
~ I V / I fAce Analytical II P.1ce Analytical Services. Inc. ,:300 l<:11Y~-~. c.we Su:.·c' · _-_-H:. ··c·o,lile. NC ~-~:-3 .>:·c 704875_~::;; ~~-'-104875.~c:;: DATE: 08/22/00 PAGE: 37 I Pace Project Number: 9216237 Client Project ID: Sanford QUALITY CONTROL DATA PARAMETER FOOTNOTES lonsistent with EPA guidelines unrounded concentrations are displayed and have been used to calculate% Rec and RPO values. D Not Detected NC Not Calculable IRL PD S) [1] Pace Reporting Limit Relative Percent Difference Surrogate Duplicate analysis exceeds QC limits, indicating sample may not be homogeneous. -~~ Recovery falls outside of QC limits, however, this compound is not found in the associated salJllles. ~4] [5] surrogate recovery outside of acceptance window confirmed as a matrix effect by the analysis of a duplicate or MS/MSD on this sample. The surrogate and/or spike recovery was outside acceptance limits. The surrogate recovery was outside QC acceptance limits due to matrix interference. 16] Surrogate recovery outside of control limits. The data was accepted based on valid recovery of remaining surrogate. I I I I I I I I I I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 ■ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certifjcation IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I /:~~;{ce Analyticar· I I: I I I I I I I I I I I I I I I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the '.'tritten consent of Pace Analytical Services, Inc. Pace Analytical Services. Inc. -?300 Kincey~. c ·.2. Suite : :: Hunlf ~, ~-NC 280-3 Pile~ -:J4875.9CE;. Fi• -04815.9GE· Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I I I I I I I I I I I I I I I I I I I ■ Pace Analytical Ser1ices, Inc. • NC ID# 12 Project #: __ ...;/....::~......:-~-' 3 .... · .... ?-: __ VPH Laboratory Reporting Form Initial Calibration Date 1/rlf /co Calibration Ranges and Limits ' [----___ _-__ ---_-· _____ --:· ___ -·-7_l,?91;-_----~-;=-------\V; ---~:--··-_;:_--------:_~~----------~ r -~--l ~~a\~i:j ~ -·~ --~-:~---. \~~~~@:-:~s,'0J~ ·~ ~ ·::~4:i-J(~~~ ~fsJ: __ -◄• ~--1~(€_~~~~ :-~~~(lL__ CS -CS Aliphatics 11.29 ug/I (1 _34 mg;kg) 35.89 ug/1 (4.27 mg/kg) 100 ug/I (10 mg/kg) CS -C12 Aliphatics 9.17 Jg/I (0.67 mg:kg) 29_ 17 ug/I (2.14 mg/kg) 100 ug/1 (10 mg/kg) C9 -C10 Aromatics 4.30 ugtl (0.44 mg:i-(g) 13.69 ug/1 ( 1.40 mg/kg) 100 ug/1 (10 mg/kg) NOTE: Please include units as appraor;ate Method of Quantitation (circle one): Curie or Average Response Factor Calibration Concentration Levels [ .~ . :, , . --;~'!i'«~:\-~~~f , ; ' 1_;f;.1]t_~@ ·. · ~}_\~1iJ§, -_ ;:_· -!~\~~{£ -_; ~-------~---~·---···--~............J.~~-----------------~t.---. ~---40 ug/1 CS -C8 80 ug/1 Aliphatics 1EO ug/I (FID) 200 ug/1 q.~o 400 ua/I 800 ug/1 1 O ua/I C9 -C12 20 ug/1 (-5'-7!9-Aliphatics 40 ug/1 (FID) 50 ug/1 1 CO ua/1 2CO ug/1 i O uq/I C9 -C10 20 ug/1 Aromatics 40 ug/1 13,4o (PIO) 50 ug/1 100 ua/1 200 ug/I NOTE: Please indicate units as appropriate. Calibration Check Date S / 1 < f o o __ _;;;;_,~+-, -=-----Calibration Check ~---·-1 .. ~r--rp-rg: ----~;--~----=~~~-~~~.-------'7 ' -,_'\c< j~ -,, _J t , ,_ --, .. _--£, _-1..,1, .!:!,' ~--A~-......=... -n~ --A ~ --J.--------~~~ CS -C8 Aliphatics C9 -C12 Aliphatics C9 -C10 Aromatics MDL= Method Detection Limit ML = Mimimum Limit RL = Reportable Limit 160 ug/1 40 ug/1 40 ug/I '?(/,. o/o 9s'?o J J..:::i· 1,? RPO = Relative Percent Difference ¾RSD = Percent Relative Standard Deviation CCC = Correlation Coefficient of Curve
I I I I I I I I I I I I I I I I I I I • Pace Analytical Services, lnc.-NC 10#12 Project#: EPH Laboratory Reporting Form lnitiai Calibration Date O I ll 00 'I ' I Calibration Ranges and Limits (WATERS -ug/L / SOLIDS -mg/kg) .-:i~~J~a n g e:~¾l-2..~M D L~~~"~ I ..:~~-:~L _ M Lt;s/~--· _·/ I '. _-, . RL · _ ····· .. ~...,..,,---..,.~""'~-----·-···1 ··,N t ., s· I'd •· ., W t t·s I·d · 1 W t / c:: 1·d ~;-~:~~~:.-~~-~~=:~~~~~ -~~. a4:-.~ ' :9051 s ;• i. _-_____ a :~~s /--~ s_ .. 1 coa u::Ls; ;c~~,,,:; C19 -C36 Aliphatics I 10.: / 3.42 32.~ ! 25.8 100 u~/L ! ~Cr:-:;:'-<; C11 -C22 Aromatics/ 34.S :' 13.2 i ,~: / J2.1 100 u~/L / 1Cr:-:;:'.-<;; NOTc: Please inc!ude L.:r::s as 2ccropn2te Methcd of Quantitation (c:~:::e or'.e : Curie ::r ,;ver2~2 S.espcnse Factcr ~libration Concentraticn Levels CS -C 18 ).,iiphctics C19 -C36 ,A.liph2tics C11-C22 ,t_rom2tics 8CC :.:;::-:-:L 17CC ·:.;;;:sL ¾RS□ or CCC NOTc: P!ease indicate un:ts as 2:crocri2:e. Calibration Check Date 8 ii I-{ loo Calibration Check __ .........,_, ~,-=-=----· : ·-Range:;_ . -I CS -C18 Aliphatics I C19 -C36 Aliphatics I C11 -C22 Aromatics I MDL:: Method Detection Limit ML = Mimimum limit RL = Re;::crtable Limit Level I 300 us;/.-;;L · ! 400 :..:;iml I 850 ·.1;iml I KPU I OS9o I IS "lu 99 'ic RFD = Rei2tive Percent Difference %RSO = Percent Re!::tive Stancac Ce1i2,:cr: CCC = Ccr;"e!aticn Ccefficient of Cur,e
~ - -___ .,,,. 'ace Analytical Required Client lnformalion: Section A Compani_: _ _ . _, _ /---.: {., t'. ..... ~ _l Address ~l ·11.· _ _r ~-/ /\ \. - --Required Client lnlormalion: Report To: ., .... -l ) -l Invoice To: (' . P.O. .--,(·_,l / 1 i"-'c l !f,..-11, _ •~ )I Project 1aine: _ / {-·-. ),\_,,)r-c_____"_ I --h-,' :·_a__:__,.:__c_i Phone'-~ -__ _ ", ,. I Fax \t, ', L Project Number. ..-) .. ~·. 1 -, .....,~ ( /' -GMjlNaaf'-~TQaY /.W,alliifaWil,qljlit Qiiu'llillt -The Chain-of-Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section 8 of 557374 Section C EPage: To Be Completed by Pace Analytical and Client ,;✓,. Clfent Information (Check quote/contract): Ouole R ere rer,ce: Requested Due Date: I 'TAT: ,' } /":, Project Manage~ • Turn a ''!und limes less lhan 14 days subject lo rrojecl H: l (,-, J -~ f -, laboral<iry and cont.actual obligaUons and may result In a Q c:,,_ ..• J / Rush T~_maround Surcharge. Profile H: Tum Around Tlme (TAT) In calendar days. Requested Ana lysl s: Section D Required Client Information: Valid Malrix Codes ◄--Cl w wl-1--o· <( w a ..J a w Preservatives / /~/ /,/// .·:J\_(_ /_1/; I //// =ii: ~ w != SAMPLE ID One character per box. (A-Z, 0-9 I ,-) Sample IDs MUST BE UNIQUE -~ / I !1 I. j ~ .. -i Sealed Cooler: Samples Intact: Additional Comments: 3 MATRIX WATER SOIL OIL WIPE Alll TISSUE OTI-iER CODE WT SL OL WP All TS QT "', w a 0 0 X ii ~ ~ -' '• o-.: (.) mm/dd/yy ~~ ... wt ::;;:w i= ::! 8 hh:mm alp {._;_ .... o;c, (/) u ~ Q) ~ 2: -~ ~,01 Ml Ir 8 g.11,~u~ "'::J ::tr :r: z L L ll( 311 I -. I . I r")j i _, GtV ) . .) ''1 ';I/ I I / _, .·, I I / I I I _' _/ .. ✓ ✓ Remarks / Lab ID PRINT Name of SAMPLER: , /,-•~>~:. ~~~ ,/~r ; /;1 , /.-,--/.I // ! i SIGNATURE ol SAMPLER'.-· ::~ ,~,,..· /. ,,-;r.,,. <•~ DATE Signed: (MM I DD I YY I SEE REVERSE SIDE FOR INSTRUCTIONS , ,. -I -I I / / _. I t' __ t''~ .It. C. Pace Analytical SeNices, Inc. Form COC01 02/00
I I I I I I I I I I I I I I I I I I I APPENDIXF GROUND WATER LABORATORY ANALYTICAL RESULTS
September 21. 2000 Mr. Doug Pierotti Cooper Environmental. Inc. 2300 Sardis Road North Suite Q Charlotte. NC 28227 RE: Pace Project Number: 9216883 Client Project ID: Sanford/20172 Dear Mr. Pierotti: Pace Analytical Services, Inc. 9S0c' -::ncey Avenue. Suite 100 Huntersville. NC 28018 Phone: [phone] Fax.· 704.815.9091 I I I I I I I I I I I I I I I I I Enclosed are the analytical results for sample(s) received by the laboratory on September 6. 2000. If you have any questions concerning this report. please feel free to contact me. Sincerely. .J,e£,0({}J fit :Ja,,J fo,., Kristi Tart Project Manager Enclosures I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I --~z:.:.==r-, ~/"' / -~------•Pace Analytica(" Pace i'tnalytlcai Services. Inc_ ,:_:_·: -· ---~': ~'.;'-__ c )Uite /0/) ~ __ nrers. -; ·;c 28078 Phone -.-c'-3759092 Fa,1 -_-c'-3759091 looper Environmental. Inc. 2300 Sardis Road North .uite Q .harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: [phone] DATE: 09/21/00 PAGE: 1 Pace Project Number: 9216883 Client Project ID: Sanford/20172 olid results are reported on a dry weight basis Pace Sample No: •lient Sample ID: 921192506 MW-lA arameters le Volatiles I Purgeable Aromatics Methyl -tert-butyl Ether Isopropyl Ether I Benzene Toluene Chlorobenzene Ethyl benzene I m&p-Xylene o-Xylene (1.2-Dimethylbenzene) 1,3-Dichlorobenzene I 1,4-Dichlorobenzene 1,2-Dichlorobenzene l-Chloro-2-fluorobenzene (S) I VPH in Water by Mass. Method Aliphatic (COS-COS) Aliphatic (C09-Cl2) I Aromatic (C09-C10) 2,5-Dibromotoluene (FID)(S) 2,5-Dibromotoluene (PID)(S) le Semivolatiles EPH in Water by Mass. Method I Aliphatic (C09-Cl8) Aliphatic (Cl9-C36) Aromatic (Cll-C22) I Laborator~ Qertifi[;ation IDs NC Wastewater 12 NC Drinking Water 37706 1sc 99006 ■ Date Collected: Date Received: 09/05/00 09/06/00 Matrix: Water Results Units PRL Analyzed Analyst CAS# Footnotes Method: EPA 602 Prep Method: EPA 602 ND ug/1 1 09/13/00 PPM 1634-04-4 ND ug/1 1 09/13/00 PPM 108-20-3 ND ug/l 1 09/13/00 PPM 71-43-2 ND ug/1 1 09/13/00 PPM 108-88-3 ND ug/1 1 09/13/00 PPM 108-90-7 ND ug/l 1 09/13/00 PPM 100-41-4 ND ug/1 1 09/13/00 PPM 7816-60-0 ND ug/l 1 09/13/00 PPM 95-47-6 ND ug/l 1 09/13/00 PPM 541-73-1 ND ug/l 1 09/13/00 PPM 106-46-7 ND ug/l 1 09/13/00 PPM 95-50-1 88 % 09/13/00 PPM 348-51-6 Method: VPH Prep Method: VPH ND ug/1 100 09/12/00 RWS ND ug/1 100 09/12/00 RWS ND ug/1 100 09/12/00 RWS 83 % 09/12/00 RWS 615-59-8 71 % 09/12/00 RWS 615-59-B Method: EPH Prep Method: EPA 3510 ND ug/1 100 09/21/00 SRR ND ug/1 100 09/21/00 SRR ND ug/l 100 09/21/00 SRR REPORT OF LABORATORY ANALYSIS LabQratory: CertificatiQn IDs KY Drinking Water 90090 This report shall not be reproduced. except in full, TN UST List without the written consent of Pace Analytical Services, Inc_ VA Drinking Water 213
~-I I I . -Pace Analyticar· Pace Analytical Services. ir.c. :?ii..\) !\,:"t .. :=: _:. -:-~_,'2. s .. :-? -.• -h .. --::" c, -.c. NC _·3_--~ P.:c··~ -:-o4875.9C:~ F:..:. 704.875.9Li:" DATE: 09/21/00 PAGE: 2 Pace Project Number: 9216883 I Client Project ID: Sanford/20172 '!....___ __________ _ Pace Sample No: llient Sample ID: Parameters 921192506 MW·lA I ... ;:~~~~~~~~~~~~~~.;~; .... -----2-Bromonaphthalene (S) Nonatriacontane (S) I o-Terphenyl CS) Date Extracted IC/MS Semivolatiles Extractables in Water by 625 I I N-Nitrosodimethylamine bis(2-Chloroethyl)ether Phenol 2-Chlorophenol 1.3-Dichlorobenzene 1.4-Dichlorobenzene 1.2·Dichlorobenzene I bis(2-Chloroisopropyl)ether Hexachloroethane N-Nitroso-di-n·propylamine I I Nitrobenzene Isophorone 2-Nitrophenol 2.4-Dimethylphenol bis(2-Chloroethoxy)methane 2.4-Dichlorophenol 1,2.4-Trichlorobenzene I Naphthalene Hexachloro-1.3-butadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene I 2,4,6-Trichlorophenol 2-Chloronaphthalene Acenaphthylene I Dimethylphthalate 2.6-Dinitrotoluene Acenaphthene I 2.4-Dinitrophenol 2,4-Dinitrotoluene 4-Nitrophenol Fluorene ILaboratory Certificatjon IDs NC Wastewater 12 1fi:C Drinking Water 37706 re 99006 • Date Co 11 ected: 09/05/00 Matrix: Water Date Received: 09/06/00 Results Units PRL Analyzed Analyst CAS# Footnotes ------· --------·-·· ------·· .. ········ ----------··-····---51 % 09/21/00 SRR 321-60-8 44 % 09/21/00 SRR 580-13-2 36 % 09/21/00 SRR 7194-86-7 1 57 % 09/21/00 SRR 84-15-1 09/12/00 Method: EPA 625 Prep Method: EPA 625 SF ND ug/1 5 09/13/00 DHJ 62-75-9 ND ug/l 5 09/13/00 DHJ 111-44-4 ND ug/1 5 09/13/00 DHJ 108-95·2 ND ug/1 5 09/13/00 DHJ 95-57-8 ND ug/1 5 09/13/00 DHJ 541-73-1 ND ug/1 5 09/13/00 DHJ 106-46-7 ND ug/1 5 09/13/00 DHJ 95-50-1 ND ug/1 5 09/13/00 DHJ 39638·32-9 ND ug/l 5 09/13/00 DHJ 67-72-1 ND ug/1 5 09/13/00 DHJ 621-64-7 ND ug/1 5 09/13/00 DHJ 98-95-3 ND ug/l 5 09/13/00 DHJ 78-59-1 ND ug/1 5 09/13/00 DHJ 88-75·5 ND ug/l 5 09/13/00 DHJ 105-67·9 ND ug/l 5 09/13/00 DHJ 111-91-1 ND ug/1 5 09/13/00 DHJ 120-83-2 ND ug/1 5 09/13/00 DHJ 120-82-1 ND ug/1 5 09/13/00 DHJ 91-20-3 ND ug/l 5 09/13/00 DHJ 87-68·3 ND ug/l 5 09/13/00 DHJ 59-50-7 ND ug/l 10 09/13/00 DHJ 77-47-4 NO ug/1 5 09/13/00 DHJ 88-06·2 ND ug/l 5 09/13/00 DHJ 91-58-7 ND ug/l 5 09/13/00 DHJ 208·96-8 ND ug/1 5 09/13/00 DHJ 131-11-3 ND ug/1 5 09/13/00 DHJ 606-20-2 ND ug/1 5 09/13/00 DHJ 83-32-9 ND ug/1 25 09/13/00 DHJ 51-28-5 ND ug/1 5 09/13/00 DHJ 121-14-2 ND ug/1 25 09/13/00 DHJ 100-02-7 ND ug/1 5 09/13/00 DHJ 86-73-7 REPORT OF LABORATORY ANALYSIS LabQrntor!l G!lctification 10:;i KY Drinking Water 90090 This report shall not be reproduced, except in full, TN UST List without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213
I __ .,;.. ... ;.:;..:.... ~-Pace Analytical Services. lac. . . I/ __ .,PaceAnalyticar ?~ .. -~~--;1 ·-~·-:. ~-~·-•. -: 5 .. :~ -_·_· .7 ... :.::=·:~•-.:= ·.,1c ... ·~:~·-:· I Pace Sample No: 921192506 MW-lA •lient Sample ID: arameters . . -. -.. -. ---------------------- - -I 4-Chlorophenyl-phenylether Diethylphthalate 4,6-Dinitro-2-methylphenol I N-Nitrosodiphenylamine 4-Bromophenyl -phenyl ether Hexachlorobenzene I Pentachlorophenol Phenanthrene Anthracene Di-n-butylphthalate I Fluoranthene Benzi dine Pyrene I Butylbenzylphthalate 3,3'-Dichlorobenzidine Benzo(a)anthracene I Chrysene bis(2·Ethylhexyl)phthalate Di-n-octylphthalate Benzo(b)fluoranthene I Benzo(k)fluoranthene Benzo(a)pyrene Indeno(l.2.3-cd)pyrene I Dibenz(a.h)anthracene Benzo(g.h,i)perylene Nitrobenzene-d5 (S) I 2-Fluorobiphenyl (5) Terphenyl-dl4 CS) Phenol-d6 CS) 2-Fluorophenol (S) I 2,4,6-Tribromophenol (S) Date Extracted I I laboratory Certification IDs NC Wastewater 12 JC Drinking Water 37706 we 99006 ■ Date Collected: Date Received: DATE: 09/21/00 PAGE: 3 Pace Project Number: 9216883 Client Project ID: Sanford/20172 09/05/00 09/06/00 Matrix: Water Results Units PRL Analyzed Analyst CAS# Footnotes ----------.......... - --- ------------------------ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 46 49 55 20 28 57 ug/l 5 09/13/00 DHJ 7005-72-3 ug/l 5 09/13/00 DHJ 84-66-2 ug/1 25 09/13/00 DHJ 534-52-1 ug/l 5 09/13/00 DHJ 86-30-6 ug/1 5 09/13/00 DHJ 101-55-3 ug/7 5 09/13/00 DHJ 118-74-1 ug/1 25 09/13/00 DHJ 87-86-5 ug/1 5 09/13/00 DHJ 85-01-8 ug/1 5 09/13/00 DHJ 120-12·7 ug/1 5 09/13/00 DHJ 84-74-2 ug/7 5 09/13/00 DHJ 206-44-0 ug/1 50 09/13/00 DHJ 92-87-5 ug/1 5 09/13/00 DHJ 129-00-0 ug/1 5 09/13/00 OHJ 85-68-7 ug/1 10 09/13/00 DHJ 91-94-1 ug/1 5 09/13/00 DHJ 56-55-3 ug/1 5 09/13/00 DHJ 218-01·9 ug/1 5 09/13/00 DHJ 117-81-7 ug/1 5 09/13/00 DHJ 117-84-0 ug/1 5 09/13/00 DHJ 205·99-2 ug/1 5 09/13/00 DHJ 207-08-9 ug/1 5 09/13/00 DHJ 50-32-8 ug/1 5 09/13/00 DHJ 193-39·5 ug/l 5 09/13/00 DHJ 53-70-3 ug/l 5 09/13/00 DHJ 191-24-2 ., 09/13/00 DHJ 4165-60-0 ,. % 09/13/00 DHJ 321-60-8 % 09/13/00 DHJ 1718-51-0 % 09/13/00 DHJ 13127-88-3 ., 09/13/00 DHJ 367-12-4 .. % 09/13/00 DHJ 118-79-6 09/11/00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. ----------Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I -~; 1 /~ce Analyticar I Pace Analytical Services. Inc. ~~~DO A,:·_-=: ~t2··~·=· Suf2 'Lt r.1 •. --~t2rsi; ::. Ne 2su.:·s P~:;r;e. .-J../ S ,75 9092 Fax ~0-1.875.9097 DATE: 09/21/00 Ii I PARAMETER FOOTNOTES -~ Not Detected Not Calculable PRL Pace Reporting Limit PAGE: 4 Pace Project Number: 9216883 Client Project ID: Sanford/20172 IS) Surrogate l] Surrogate recovery outside of control limits. The data was accepted based on valid recovery of remaining surrogate. I I I I I I I I I I I laboratory Certification IDs NC Wastewater 12 .J;!C Drinking Water 37706 re 99006 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ~~~, I /~,,,P'3ceAnalyticar I Ii QUALITY CONTROL DATA Pace Analytical Services, Inc. ::600 /(inceyA,~·.c Suite !C\: Hunters. ;. NC 280,.,.5 Phonf. -}-I 815.9092 Fax. -,)-1815.9097 DATE: 09/21/00 PAGE: 5 loper Environmental, Inc. 2300 Sardis Road North Pace Project Number: 9216883 Client Project ID: Sanford/20172 luite Q harlotte. NC 28227 ltn: Mr. Doug Pierotti one: [phone] QC Batch Method: EPA 3510 Analysis Description: EPH in Water by Mass. Method I Batch IO: 31058 alysis Method: EPH Associated Pace Samples: 921192506 'ETHOD BLANK: 921193785 .ssociated Pace Samples: 921192506 lrameter . -... ----.. ---.. --. --.. ---.. ----Aliphatic (C09-Cl8) 'iphatic (C19-C36) omatic (Cll-C22) Fluorobiphenyl (S) 2-Bromonaphthalene (S) lnatriacontane (S) Terphenyl (S) I MATRIX SPIKE: 921180121 ,~~~~~~~ .................... . Aliphatic (C09-C18) liphatic (C19-C36) omatic (Cll·C22) 2-Fluorobiphenyl (S) IBromonaphthalene (S) natriacontane (S) o-Terphenyl (S) I laboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 .c 99006 Units ug/l ug/1 ug/l % % % % Units ug/1 ug/l ug/1 Method Blank Result PRL Footnotes ----------------------·-------ND 100 ND 100 NO 100 36 1 54 70 39 2 Matrix Spike Spike Spike 921172607 Cone. Result % Rec Footnotes ............ ·-------... -----. -. --. --....... --. --0 300 135.0 45.0 0 400 327.2 81.8 0 850 221.7 26.1 1 30 1 8 1 55 31 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ~) 1 1~e Analyticar I QUALITY CONTROL C.~.TA Pace Analytical Services. lr.c. 9800Kir::= ~-=·,.2 s~ :: -.-.-H>:~-5 ... ':2 NC ~·3:-: F-:.,~ 704.s,-:-5 .::o;~· ;:E.X i04.875.EOE" DATE: 09/21/00 II I LABORATORY CONTROL SAMPLE: 921180113 larameter •liphatic (C09·Cl8) liphatic (Cl9·C36) romatic (Cll·C22) 2·Fluorobiphenyl (SJ l·Bromonaphthalene CS) onatriacontane CS) o·Terphenyl (S) I I I I I I I I I I bor tor Certif ation IDs NC Wastewater 12 tNC Drinking Water 37706 C 99006 I Units ug/1 ug/1 ug/l PAGE: 6 Pace Project Number: 9216883 c~ient Project ID: Sanford/20172 Spike LCS Cone. Result 300 180.2 400 368.2 850 216.4 Spike % Rec Footnotes 60.1 92.0 25.5 1 14 1 0 1 68 36 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I .q.,, 11~Pice Anatyticar 11 QUALITY CONTROL DATA Pace Analytical Services, Inc. 9800 K·.·:2: Avenue. Suite 100 ,'-::cinersville. NC 28078 _;:,,'lone· 704.875.9092 FEX 704.875.9091 DAE: 09/21/00 PAGC:: 7 looper Environmental, Inc. 2300 Sardis Road North Pace Project Number: 92168B3 Client Project ID: Sanforc/20172 luite Q harlotte, NC 28227 lttn: Mr. Doug Pierotti hone: (704)845·2000 QC Batch Method: VPH I Batch ID: 31370 nalysis Method: VPH Associated Pace Samples: Analysis Description: VPH in Water by Mass. Method -~ETHOD BLANK: 921191854 -ssociated Pace Samples: 921192506 921192506 Method Blank ,~~~~~~~··············--····· ~~~~~····· .. ~~~~~~ .. Aliphatic (C05·C08) ug/1 NO 'iphatic (C09·Cl2) ug/1 ND omatic (C09·Cl0) ug/1 NO .5·Dibromotoluene (FIO)(S) % 78 2,S·Oibromotoluene (PID)(S) % 72 I . LABORATORY CONTROL SAMPLE & LCSD: 921191862 921191870 Spike LCS PRL 100 100 100 lrameter Units Cone. Result •iphatic (COS·C08) iphatic (C09·C12) omatic (C09·Cl0) 2.S·Dibromotoluene (FID)(S) IS·Dibromotoluene (PID)(S) I I ug/1 ug/1 ug/1 -------------·---160 158.6 40 35.43 40 49.B8 Footnotes Spike Spike LCSD Dup % Rec Result % Rec RPD -------------·· -----99.1 144.7 90.4 9 88.6 36.93 92.3 4 125 50.16 125 0 86 91 84 81 laboratory Certification IDs NC Wastewater 12 REPORT OF LABORATORY ANALYSIS ~C Drinking Water 37706 .c 99006 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Footnotes --------. -Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I y} 1 /~ce Analyticar .( Pace Analytical Services, Inc. 9800 Kincey Avenue. Suite 100 Huntersville. NC 28078 Phone. [phone] Fax [phone] looper Environmental. Inc. 2300 Sardis Road North luite Q harlotte. NC 28227 lttn: Mr. Doug Pierotti hone: [phone] IC Batch ID: 31561 nalysis Method: EPA 625 Associated Pace Samples: 921192506 QUALITY CONTROL DATA QC Batch Method: EPA 625 SF DATE: 09/21/00 PAGE: 8 Pace Project Number: 9216883 Client Project ID: Sanford/20172 Analysis Description: Extractables in Water by 625 ~ETHOD BLANK: 921199121 -ssociated Pace Samples: 921192506 rrameter ------------... ------------... -N-Nitrosodimethylamine fs(Z-Chloroethyl)ether enol Chlorophenol 1.3-0ichlorobenzene 1.4-Dichlorobenzene _,2-Dichlorobenzene bis(2-Chloroisopropyl)ether lxachloroethane Nitroso-di-n-propylamine Nitrobenzene 'ophorone Nitrophenol .4-Dimethylphenol bis(Z-Chloroethoxy)methane 14-Di ch l oropheno 1 2,4-Trichlorobenzene Naphthalene lxachloro-1.3-butadiene Chloro•3-methylphenol Hexachlorocyclopentadiene ,4.6-Trichlorophenol Chloronaphthalene enaphthylene Dimethylphthalate laboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 lie 99006 ■ Method Blank Units Result PRL Footnotes ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/l ug/1 ug/l ug/l ug/l ug/l ug/1 ug/1 ug/1 ug/1 ug/l ug/l ug/l ug/1 ug/1 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 10 5 5 5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services. Inc. Laboratory Certificatjon IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
QUALITY CONTROL DATA Pace Analytical Services. Inc. 9800 Kincey Ai•enue. S~ :-2 100 Huntersville, NC ~5018 Phone. 704.8.~~.9092 Fax.· 104.87: 9091 DATE: 09/21/00 PAGE: 9 Pace Project Number: 9216883 I Client Project ID: Sanford/20172 '------------METHOD BLANK: 921199121 rssociated Pace Sam~les: 921192506 ,~~~~~~~~ ....... ---... --...... 2.6-0initrotoluene lcenaphthene ,4-Dinitrophenol 2.4-Dinitrotoluene ,-Nitrophenol l uorene 4-Chlorophenyl-phenylether -;ethylphthalate .6-Dinitro-2-methylphenol -Nitrosodiphenylamine 4-Bromophenyl-phenylether lexachlorobenzene entachlorophenol Phenanthrene .,thmeae i-n-butylphthalate l uoranthene ,.,,;,;,e yrene · utylbenzylphthalate 3.3'-Dichlorobenzidine lenzo(a)anthracene hrysene bis(2-Ethylhexyl)phthalate .i-n-octylphthalate enzo(b)fluoranthene enzo(k)fluoranthene Benzo(a)pyrene lndeno(l,2.3-cd)pyrene ibenz(a,h)anthracene Benzo(g.h,i)perylene litrobenzene-dS (S) • Fl uorobi phenyl (S) Terphenyl-dl4 CS) .henol -d6 CS) -Fluorophenol (S) .4,6-Tribromophenol (S) I Laboratory Certification IDs NC Wastewater 12 I NC Drinking Water 37706 SC 99006 • Method Blank Units Result PRL Footnotes & --... ---• --·-·-------·······-------------ug/1 ug/l ug/l ug/1 ug/1 ug/1 ug/l ug/1 ug/1 ug/l ug/1 ug/l ug/1 ug/1 ug/1 ug/1 ug/l ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/1 ug/l ug/l ug/l ug/l ug/1 ug/1 ¾ X X X ¾ ¾ ND 5 ND 5 ND 25 ND 5 ND 25 ND 5 ND 5 ND 5 ND 25 ND 5 ND 5 ND 5 ND 25 ND 5 ND 5 ND 5 ND 5 ND 50 ND 5 ND 5 ND 10 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 ND 5 55 56 62 23 33 63 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certificatjon IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
.:., .-, ~/ ?ace Anaiyticai Services, Inc . I 1-1 I _ Pace Analyticar· .: __ \! f\inL"'':'_1 . .:.. . ~ --· ~ ~ur~ · · Hue~-~--: 'iC ~,~_--: P/·;··; -~ .. :. 3759-..~:::~· F-3--_-,;a1s9c;-LABORATORY COITTROL SAMPLE: 921199147 lrameter Units •Nitrosodimethylamine ug/1 s(2-Chloroethyl)ethe~ ug/l enol ug/1 2-Chlorophenol ug/7 13-Dichlorobenzene ug/l 4-Dichlorobenzene ug/l 1.2-Dichlorobenzene ug/1 ls(2-Chloroisopropyllether xachloroethane N-Nitroso-di-n-propylamine 'trobenzene ophorone Nitrophenol 2,4-Dimethylphenol ls(2-Chloroethoxy)methane 4-Dichlorophenol 1.2,4-Trichlorobenzene 'phthalene xachloro-1.3-butadiene Chloro-3-methylphenol lxachlorocyclopentadiene 4.6-Trichlorophenol Chloronaphthalene Acenaphthylene lmethylphthalate 6-Dinitrotoluene Acenaphthene 14-Dinitrophenol 4-Dinitrotoluene Ni tropheno l lorene hlorophenyl-phenylether ethylphthalate 4,6-Dinitro-2-methylphenol INitrosodiphenylamine IBromophenyl-phenylether Hexachlorobenzene ltachlorophenol nanthrene hracene Di ·n-butylphthalate laboratory Certificatjon IDs NC Wastewater 12 ._ic Drinking Water 37706 lc 99006 ■ ug/1 ug/l ug/1 ug/1 ug/l ug/1 ug/1 ug/l ug/1 ug/l ug/1 ug/l ug/l ug/l ug/1 ug/1 ug/l ug/1 ug/1 ug/l ug/l ug/7 ug/1 ug/1 ug/1 ug/l ug/7 ug/1 ug/l ug/l ug/1 ug/l ug/l ug/l QUALITY CONTROL DATA DATE: 09/21/00 PAGE: 10 Pace Project Number: 9216883 Client Project ID: Sanford/20172 Spike LCS Cone. Result 50 11.37 50 25.34 SC 9,180 50 26.34 50 20,18 50 20.57 50 20.72 50 27.44 50 18.44 50 28.52 50 28.72 50 27.43 50 30.50 50 28.73 50 30.28 50 31. 79 50 23.85 50 27.12 50 20.54 50 32.00 so 19.50 50 33.15 50 28.66 50 33.65 50 35.50 50 35.68 50 30.76 50 34.46 50 39.05 50 9.795 50 33.29 50 33.67 50 35.51 50 37.37 50 34.66 50 39.53 50 35.08 50 37.67 50 34.84 50 35.56 50 35.38 Spike % Rec Footnotes 22.7 50.7 18,4 52.7 40.4 41.1 41.4 54.9 36.9 57.0 57.4 54.9 61.0 57.5 60.6 63.6 47.7 54.2 41.1 64.0 39.0 66.3 57.3 67.3 71.0 71.4 61.5 68.9 78.1 19.6 66.6 67.3 71.0 74.7 69.3 79.1 70.2 75.3 69.7 71.1 70.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc_ Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
-:. .... ~/ I I I I ,.· Pace Analyticar. LABORATORY CONTROL SAMPLE: 921199147 lrameter *uoranthene nzid1ne rene Butylbenzylphthalate 13' -Dichlorobenzidine nzo(alanthracene Chrysene ls(2·Ethylhexyl)phthalate -n-octylphthalate enzo(blfluoranthene lnzo(klfluoranthene nzo(a)pyrene deno(l,2,3-cd)pyrene Dibenz(a,h)anthracene lnzo(g.h.i)perylene trobenzene-d5 (S) 2-Fluorobiphenyl (S) 'rphenyl-dl4 (S) encl ·d6 (S) Fluorophenol (S) .4.6-Tribromophenol (S) SAMPLE DUPLICATE: 921201356 lrameter •Nitrosodimethylamine s(2-Chloroethyl)ether .3-Dichlorobenzene 1.4-0ichlorobenzene 12-Dichlorobenzene .. s(2-Chloroisopropyl )ether Hexachloroethane INitroso-di-n-propylamine trobenzene · Isophorone ls(2-Chloroethoxy)methane 2.4-Trichlorobenzene phthalene Hexachloro-1.3-butadiene Units ----------ug/1 ug/l ug/1 ug/1 ug/1 ug/1 ug/l ug/l ug/l ug/1 ug/1 ug/1 ug/l ug/1 ug/1 Units ----------ug/l ug/1 ug/l ug/l ug/1 ug/l ug/1 ug/l ug/l ug/l ug/1 ug/1 ug/1 ug/1 QUALITY CONTROL DATA Spike LCS Spike Cone. Result % Rec -. ~ ----. --50 34.64 69.3 100 126.9 127 50 35.87 71. 7 50 33.88 67.8 50 78.21 156 50 36.08 72.2 50 34.86 69.7 50 25.14 50.3 50 34.05 68.1 50 40.86 81.7 so 37.20 74.4 50 36.16 72.3 50 35.26 70.5 50 37.02 74.0 50 34.81 69.6 66 66 81 19 28 81 Dup. 921195400 Result --------------------ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 73.00 68.00 ND ND f3ce ~nalyfical Services. Inc. ·:~·-~y :., :··-~ _::_ ::?. !~~--h'Uii[C.°5. :-... L' 2S0,~~ Pl11X= .-L7../ C,-5 90~: Fa.• -o..: o,'590~-DATE: C?/21/00 PAGE: __ Pace Project Number: 9216883 Client Project ID: Sanford/20l:2 Footnotes ········--RPO Footnotes ---------· NC NC NC NC NC NC NC NC NC NC NC NC 7 NC laboratory Certification IDs NC Wastewater 12 ltC Drinking Water 37706 ,c 99006 REPORT OF LABORATORY ANALYSIS Laboratory Certification IDs KY Drinking Water 90090 This report shall not be reproduced, except in full, TN UST List without the written consent of Pace Analytical Services, Inc. VA Drinking Water 213 ■
I ~ I . _.--Pace Analyticar· Pace Analytical Services. inc. :.:_~_-_-..;\·iiCf) ~tf!lUC.S:..·::':' . ..., ... ~~ i-/uniersviilrJ. N:__' l5Ci Phone. 70.J 575.9092 Fax· 70-:/675.9097 11 I SAMPLE DUPLICATE: 921201356 larameter -------·········----·------··-_,,achlococyclopeotadieoe -Chloronaphthalene cenaphthylene Dimethylphthalate 16-D1n1trotoluene enaphthene 2.4-Dinitrotoluene 'luorene ·Chlorophenyl-phenylether iethylphthalate N-Nitrosodiphenylamine IBromophenyl-phenylether xachlorobenzene Phenanthrene lthracene -n-butylphthalate Fluoranthene lnzidine rene tylbenzylphthalate 3,3'-Dichlorobenzidine lnzo(a)anthracene rysene bisC2·Ethylhexyl)phthalate 1·n·octylphthalate nzo(blfluoranthene Benzo(k)fluoranthene .nzo(a)pyrene deno(l.2.3-cd)pyrene benz(a.h)anthracene Benzo(g,h. i)perylene ltrobenzene-d5 (S) · Fluorobiphenyl (S) Terphenyl-dl4 (S) lenol Chlorophenol 2-Nitrophenol ·4·Dimethylphenol 4-Dichlorophenol Chloro-3-methylphenol 2.4.6-Trichlorophenol NC Wastewater 12 lice Drinking Water 37706 • 99006 ■ QUALITY CONTROL DATA Dup. Units 921195400 Result RPO DATE: 09:'21/00 PAGE: 12 Pace Project Number: 9216883 Client Project ID: Sanford/20172 Footnotes ----------········--.......... ug/l ug/l ug/1 ug/l ug/1 ug/1 ug/l ug/1 ug/1 ug/l ug/1 ug/l ug/1 ug/1 ug/1 ug/l ug/1 ug/1 ug/l ug/l ug/1 ug/l ug/1 ug/l ug/l ug/l ug/l ug/l ug/l ug/1 ug/1 X X % ug/1 ug/l ug/1 ug/1 ug/1 ug/1 ug/l ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC 6.700 ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND NO NC 7.100 5.600 23 NO ND NC ND NO NC ND ND NC NO ND NC NO ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC 68 58 0 72 58 0 86 70 0 ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC ND ND NC REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I :,:?;:.:·~~~ '~/ / I 1 /~___,Pilce Analytical I Pace ,~nalyt1cal Sen·,ces, Inc. :.;,~---_--._ .. ~ . .:.,f:~-~ _: __ ,"-! !00 -~_:_·.-~-i~ti :-· .. y~ ~!5078 P,c.-2 .. -:-_-.:. :-59092 F3·c ,~:_'..:. :-59097 II I SAMPLE DUPLICATE: 921201356 larameter " T W • • ■ ■ ■ ■ ■ ■ ■ ■ ■ 0 • ~ • • • • • ■ • T T T ■ ■ ■ 2.4-Dinitrophenol 1-Nitrophenol ,6-Dinitro-2-methylphenol Pentachlorophenol lhenol-d6 (S) ·Fluorophenol (S) 2.4.6-Tribromophenol I I I I I I I I I I (S) I Laboratory Certification IDs NC Wastewater 12 NC Drinking Water 37706 1sc 9900s ■ QUALITY CONTROL DATA Dup. Units 921195400 Result RPO DATE: 09/2~/00 PAGE: 13 Pace Project Number: 9216883 Client Project ID: Sanfard/20172 Footnotes .......... -------··· ---------· ug/1 ug/1 ug/1 ug/1 % % % ND ND NC ND ND NC ND ND NC ND ND NC 21 18 0 28 24 0 81 65 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, '.'1ithout the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I looper Environmental. Inc. 2300 Sardis Road North luite Q harlotte. NC 28227 lttn: Mr. Doug Pierotti Phone: [phone] IC Batch ID: 31641 nalysis Method: EPA 602 Associated Pace Samples: I METHOD BLANK: 921202297 921192506 QUALITY CONTROL DATA QC Batch Method: EPA 602 ?ace AnalyticJ/ Services. Inc. ,: : _-__ ; :., '-'2.: ~. -c ",,2 Su::~ · _-: H:;,·~:-:.~511i!e. NC~::_·-~ P,\·--2 ?04 875.::."::c· Fe.· .. ,"'04.875.~:::· DATE: 09/21/00 PAGE: 14 Pace Project Number: 9216883 Client Project ID: Sanford/20172 Analysis Description: Purgeable Aromatics -ssociated Pace Samples: 921192506 ,~~~~~~~~ ............. -...... . Methyl-tert-butyl Ether lopropyl Ether nzene Toluene 'lorobenzene hylbenzene p·Xylene a-Xylene (1.2-Dimethylbenzene) l,3·Dichlorobenzene .4-Dichlorobenzene 1.2-Dichlorobenzene IChloro-2-fluorobenzene (S) ,TRIX SPIKE: 921202339 lrameter lthyl-tert-butyl Ether opropyl Ether Benzene 'luene 11 orobenzene hylbenzene m&p-Xylene laboratory Certification IDs NC Wastewater 12 a!C Drinking Water 37706 .,c 99006 ■ Units ug/1 ug/l ug/1 ug/l ug/l ug/1 ug/1 ug/1 ug/1 ug/l ug/l % Units Method Blank Result -.. -.. -----ND ND ND ND ND ND ND ND ND ND ND 86 93650091 PRL Footnotes --------------------1 1 1 1 1 1 1 1 1 1 1 Matrix Spike Spike Spike Cone. Result % Rec Footnotes . ---. ------·--·--------------------------------ug/1 0 20 17.37 86.8 ug/l 0 20 19.80 99.0 ug/l 0 20 18.72 93.6 ug/l 0 20 19.19 95.9 ug/l 0 20 18.63 93.2 ug/l 0 20 17.62 88.1 ug/l 0 40 35.96 89.9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc . Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
__ ,~--I I ~-----. ,::pJ~eAnalyticar Pace A11a/y/ica1 S:rvices. Inc. _~;_-.1~·111CE! -." .. "Suite:._-_-Hw;::=·,. c NC 2ST~ P/;_--0 -J.J 8159C;;_--_7.J.815.9C~-QUALITY CONTROL DATA I DATE: 09/21/00 PAGE: 15 Pace Project Number: 9216883 Client Project ID: Sanford/20172 ----------------------------------------------MATRIX SPIKE: 921202339 larameter Units --Xylene (1.2-Dimethylbenzene) ug/l .3-Dichlorobenzene ug/l .4-Dichlorobenzene ug/1 1.2-Dichlorobenzene ug/l 1-Ch1oro-2-fluorobenzene (S) rBORATORY CONTROL SAMPLE: 921202305 Parameter Units Spike 93650091 Cone. ..... --- --. --------0 20 0 20 0 20 0 20 Spike LCS Cone. Result Matrix Spike Spike Result % Rec Footnotes ----------. ----- - ---16.96 84.8 17.85 89.3 16.39 81. 9 18.55 92.7 92 Spike % Rec Footnotes -:ii~i;~i;i~~~~~~-~~~~;······· ~i~~----·-......... --------.... .............. 20 18.78 93.9 20 22.22 111 Benzene ug/l lo l uene ug/l hlorobenzene ug/1 Ethyl benzene ug/1 ~&p-Xylene ug/1 -Xylene (1.2-Dimethylbenzene) ug/1 .3-Dichlorobenzene ug/1 1.4-Dichlorobenzene ug/1 ,2-Dichlorobenzene ug/1 -Chloro-2-fluorobenzene (S) I I I I I ILaboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 .-,c 99006 20 21.38 107 20 20.97 105 20 21.26 106 20 20.46 102 40 41.13 103 20 19.65 98.3 20 20.41 102 20 19.57 97.9 20 20.79 104 91 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc . Laboratory Certifjcation IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I ~:::--.. , ~ J .,.... . . ..~ 1 /~Pace Analyticar i I 11 Pace Analytical Services. inc . :~~:_-_ ... I\J1ICC} ~ ':. ': :. ·: ---/-l!)i1if~~-~ · .... --.... '3.,_~-~ DATE: 09/21/00 PAGE: 16 I Pace Project Number: 9216883 Client Project ID: Sanford/20172 QUALITY CONTROL DATA PARAMETER FOOTNOTES lonsistent with EPA guidelines unrounced concentrations are displayed and have been used to calculate% Rec and RPO values. "D Not Detected -C Not Calculable RL Pace Reporting Limit PD Relative Percent Difference (S) Surrogate 11] The surrogate and/or spike recovery was outside acceptance limits. 2] Surrogate recovery outside of control limits. The data was accepted based on valid recovery of remaining surrogate. [3] Recovery falls outside of QC limits. however, this compound is not found in the associated samples. I I I I I I I I I I laboratory Certification IDs NC Wastewater 12 ~C Drinking Water 37706 re 99006 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc. Laboratory Certification IDs KY Drinking Water 90090 TN UST List VA Drinking Water 213
I lata File: /chem/:--;;:-nsd6.::..,'091300.o/09130005.d eport Date: 16-Se;-200C 11:30 · . I P~ce Analytical Services -Charlotte T:NTATIVELY IDENTIFIED COMPOUNDS IClient Name: COOE,:='.?_ 9.)\ (.;'3'33 Lab Smp Id: 921192506 Client SDG: 091300 Client Smp ID: MW-lA Sample Date: 03-SEP-2JOO Sample ?oint: Operator : DHJ ISamole Location: Sample Matrix: WATER Analysis Type: SV Date Received: 06-SEP-2000 00:00 Level: LOW CONCENTRATION UNITS: (ug/L or ug/KG) ug/L I Number TICs found: O 11-----------.-------------,--C AS NUMBER COMPOUND NAME RT EST. CONC. Q it===================-=======--=======-===== I I I I I I I I I I I • .. -··------· -·-
I I I I I Pace Analytical Services, Inc. -NC ID# 12 Project#: ___ _,_11..__.';)-._-;-"'"""3=--VP H Laboratory Reporting Form Ccuqur Initial Calibration Date q) 8' f 00 ,-Calibration Ranges and Limi~ ' CS -CS Aliphatics 11.29 ug/1 (1.34 mg/kg) 35.89 ug/1 (4.27 mg/kg) 100 ug/1 (1 0 mg/kg) C9 • C12 Aliphatics 9.17 ug/1 (0.67 mg/kg) 29.17 ug/1 (2.14 mg/kg) 100 ug/1 ( 10 mg/kg) C9 -C10 Aromatics 4.30 ug/1 (0.44 mg/kg) 13.69 ug/1 (1.40 mg/kg) 100 ug/1 (10 mg/kg) NOTE: Please include units as appropriate I · Method of Quantitation (circle one): Curve or Average Response Factor Calibration Concentratio'n Levels I I I I I 1· I I I I I I I ■ t .. ' . ,;t : • -_ ----~~ •-T---~-----➔~-•--•-"•~F-•,-••~•~,~-1~-:\~~J::~,~-•-~r~-.-! L •• _ ?:.:-1~~~--______ L __ ~---~~~-'rf_~-__ ---~-((-~(s:: ____ ; C5-C8 Aliphatics (FID) C9 -C12 Aliphatics (FID) C9 -C10 Aromatics (PIO) 40 ug/1 80 ug/1 160 ug/1 200 ug/1 400 u /I 800 ug/1 10 u /I 20 ug/1 40 ug/1 50 ug/1 100 u /I 200 ug/1 10 u /I 20 ug/1 40 ug/1 50 ug/1 100 u /I · 200 ug/1 NOTE: Please indicate units as appropriate. Calibration Check Date __ _,Jg4/_11+-jo_o __ _ Calibration Check ~ CS -CS Aliphatics 160 ug/1 C9 -C12 Aliphatics C9 -C10 Aromatics MOL = Method Detection limit . Ml = Mimimum limit RL = Reportable limit 40 ug/1 40 ug/1 RPO = Relative Percent Difference %RSD = Percent Relative Standard Deviation CCC = Correlation Coefficient of Curve
I I I I I Pace Analytical Services, Inc. -NC ID# 12 Project#: ___ \ _(!;~-~=2, __ VPH Laboratory Reporting Form Initial Calibration Date S/23 f o o Calibration Ranges and Liniits . . -:. --":i'dD)L -. -: ----:ll'JL .. ·~-------,c:ll ----··1 ,n,<, -•• .1,( ...tl~~-••••~•~--~• ~--~-----•~--'....~.; .. _,_~-~••~-a•~~~• •• ,::.:... -• -~ •--. ------_: .. ,'i~I"'"-_ ~ __ ,__,_,__ .......... _J •--·_-·::1~t~~>m~i-_---_ ·---,T--~,1Ji(c{~~ :i~,01~ -··--:._--_ /•.'.~l?s1~~}r/:1~ ·-·_.,: _ -__ ,.~:/~~~/, :i=Y~~i1F ____ CS -CB Aliphatics 11.29 ug/1 (1.34 mg/kg) 35.89 ug/1 (4.27 mg/kg) 100 ug/1 (10 mg/kg) C9 -C12 Aliphatics 9.17 ug/1 (0.67 mg/kg) 29.17 ug/1 (2.14 mg/kg) 100 ug/1 (10 mg/kg) C9 -C1 O Aromatics 4.30 ug/1 (0.44 mg/kg) 13.69 ug/1 (1.40 mg/kg) 100 ug/1 (10 mg/kg) NOTE: Please include ur:iits as appropriate I · Method of Quantitation (circle one): Curve or Average Response Factor Calibration Concentration Levels I I I I I I I I I I I I I r --__ •i~f,:,~It-: _____ ~:-~J:~-~-~~~;'.;~~~c~~ :_:_-~:J~.---:•lr.J;~I~ol; .. : ~--: i L - -40 ug/1 C5-C8 80 ug/1 Aliphatics 160 ug/1 1ll-11 (FID) 200 ug/1 •' 400 ug/1 800 ug/1 10 ug/1 C9 -C12 -20 ug/1 \\\~8''5 Aliphatics 40 ug/1 (FID) 50 ug/1 100 uq/1 200 ug/1 10 ug/1 C9 -C10 20 ug/1 Aromatics 40 ug/1 ~1 J (PIO) 50 ug/1 \ ~ ~ 100 ug/1 200 ug/1 NOTE: Please indicate units as appropriate. Calibration Check Date __ q.:....o.+( ~..:;...lt-'-cu __ _ Calibration Check f CS -CS Aliphatics C9 -C12 Aliphatics C9 -C10 Aromatics MDL= Method Detection Limit ML = Mimimum limit RL = Reportable Limit 160 ug/1 40 ug/1 40 ug/1 RPD = Relative Percent Difference %RSD = Percent Relative Standard Deviation ~ CCC = Correlation Coefficient of Curve
I I I I I I I I I I I I I I I I I I I • -·-Pace Analytical Services, lnc.-NC 1□#12 Project#: C/ 2 I U 'i ':l J EPH Laboratory Reporting Form ;i~~fiJ;.JUUS_rf~I§~rictJlf/9 GiJ5f.qtifi aJ_i ¢ffJDlr~J;;;0t~i~ Initial Calibration Date q}Qc:1 ) oo Calibration Ranges and Limi'ts (WATERS -ug/L / SOLIDS -mg/kg) ,~,~Ran. g~~ -~~~~.MDL~~~~;.: I . .:-:."::~,. z M L::::~1;:,~·.-_;c KL . . .: : ~-C19 -C36 Aliphatics 10.1 / 3.42 I 32.1 I 26.8 C11-C22Aromatics 34.6/~3.2 I 1101<12.1 NOTE: Please include units as 2pcropriate -Waters/ Solids 100 t..:g:L / 1 0rr.g/k~ 100 ug.'L I 1 0mgik~ 1'v1ethoc af Quantitation (circle one): Curve er Average Response Factor Calibration Concentration Levels -~:Ls~~~1;;~-t~:;t~:~;'.i~ ---;..:~-: ";--.. I ·. ¾RS□ or ~-/;~ ~:/te7~1s ·--.. CCC ·---30 ug;:.:l. I ! C9 -C18 120 ug/r;-;L I ,Jd-i A.liphatics 300 t.!£.'.:il I \~ ; 600 uc;;,::-:L i 1200 ugi;;-;L I I J.0 ug/r:-:L ! i C19 -C36 160 ugir;-;L I \\ Aliphatics 400 I )~ u9;;-;L I < 800 ug/r;-;L I 1600 ughl I 85 ugir.:L I C1 1 -C22 340 ugh-:-,L I ~<{ Aromatics 850 ug/:7:L I cg .J 1700 ug:rr.L I 3400 ug/rnl I NOTE: Please indicate units as apcropriate. Calibration Check Date ____ lJ_1 ~\ ~--Calibration Check C9 -C18 Aliphatics C19 -C36 Aliphatics C11 -C22 Aromatics MOL ::: Method Oetectfon Limit ML = Mimimum Limit RL = Reportable Limit eve 300 ug/rnl 400 ug/rnl 850 ug/rnl RPO = Relative Percent Difference %RSO = Percent Relative Standard Deviation CCC = Correlation Coefficient of Curve
' ,,,icmawn - - --Required Clienl Information: Company I Address 1_'_ I :· j • /_ [ Phone / , .. -C(.·(, Fax Section A l\:'I I, M •.. 1.1T rll ;Ji"' . ·/ Section D Required Client Information: SAMPLE ID One character per box. (A-Z, 0-9 I .-) Sample IDs MUST BE UNIQUE _.·,,,, Received on ICE: I (Y) I N Sealed Cooler: I Y / !N·:: Samples Intact: I ·y . ,Y N Additional Comments: Required Client fnlormatlon: Section B Report To: /1 fl I J {, , J,·., ,,'.'.'.\_ l!,1u-,:,-~. ,. Invoice To: (~.:OJ._ P.O. ~-:CJ/7.::J .:,mject N~0me: f /.:' )[_)......,_._ / [---·__,< .. ~ .· Project Nlll£ll,er_:_,-"") ,-~! /r ... Valid M alrix Codes ~ MATRIX WATER SOIL OIL WIPE AIR TISSUE QI!:.!fil! ;.\,\ CODE wf--SL OL WP AR TS QI -;/•/ ··-:i:· w □ 0 u X ii: ~ :E 'EN-~!~~~-~~· ~~:.naat -( Page: / of / 531909 To Be Completed by Pactl Analytical and Client Section C Quote Reference: Client fnformation (Check Requested Due Date: /-Project Manager. • Tum around times less than 14 days subject to I Project#: • · · \ / -CJ.. C) Q I laboratory and contractual obligations and may result in a r' : ' .-1,/,/ 0 D.....:> Rush Turnaround Surcharge. . Profile#: !'. l Tum Around Time (TAT) in calendar days. □ w wf--~~ o-l _J 8 □ w wf--:drl i= ::J 0 CJ Preservatives I'? -0 <ll <ll C i:: ~ 11~1cj151~ ::J I I J: PRINT Name of_~PLER: Requested Analy&I&: ,./I;·/,-/i' (. .. {---, '· SIGNAnJRE cl SA~:?.-JA: I/ . 1:-~v. / ,.t,,,,r, 1' / / /./_/4, .t ~-~-Iv"" .}!_., t;_~· ~~: -~ DATE Signed: (MM jOD/'YY) I 4/{;tZ. 3 SEE REVERSE SIDE FOR INSTRUCTIONS Pace ~nalytical Services, Inc: l=orm COC01 02/00