AS-4431_41488_CA_LAB_20230125

#=CL#
January 25, 2023
LIMS USE: FR - BRETT ENGARD
LIMS OBJECT ID: 92647670
92647670
Project:
Pace Project No.:
RE:
Brett Engard
NCDENR
2090 U.S. Hwy
Swannanoa, NC 28778
SW SAMPLING CROWN FOOD MART US
Dear Brett Engard:
Enclosed are the analytical results for sample(s) received by the laboratory on January 18, 2023. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Sara Poulson
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 21
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 21
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92647670001 TULULA CREEK -SW-13 SM 6200B 63 PASI-CCL
92647670002 TULULA CREEK -SW-12 SM 6200B 63 PASI-CCL
92647670003 TULULA CREEK -SW-14 SM 6200B 63 PASI-CCL
92647670004 TULULA CREEK -SW-11 SM 6200B 63 PASI-CCL
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-13 Lab ID:92647670001 Collected:01/18/23 12:30 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/25/23 14:24 71-43-2 M16.2 12.5
Bromobenzene ND ug/L 01/25/23 14:24 108-86-1 M16.2 12.5
Bromochloromethane ND ug/L 01/25/23 14:24 74-97-5 M16.2 12.5
Bromodichloromethane ND ug/L 01/25/23 14:24 75-27-4 M16.2 12.5
Bromoform ND ug/L 01/25/23 14:24 75-25-2 M16.2 12.5
Bromomethane ND ug/L 01/25/23 14:24 74-83-9 M162.5 12.5
n-Butylbenzene 58.1 ug/L 01/25/23 14:24 104-51-8 M16.2 12.5
sec-Butylbenzene ND ug/L 01/25/23 14:24 135-98-8 M16.2 12.5
tert-Butylbenzene ND ug/L 01/25/23 14:24 98-06-6 M16.2 12.5
Carbon tetrachloride ND ug/L 01/25/23 14:24 56-23-5 M16.2 12.5
Chlorobenzene ND ug/L 01/25/23 14:24 108-90-7 M16.2 12.5
Chloroethane ND ug/L 01/25/23 14:24 75-00-3 M112.5 12.5
Chloroform ND ug/L 01/25/23 14:24 67-66-3 M16.2 12.5
Chloromethane ND ug/L 01/25/23 14:24 74-87-3 M112.5 12.5
2-Chlorotoluene ND ug/L 01/25/23 14:24 95-49-8 M16.2 12.5
4-Chlorotoluene ND ug/L 01/25/23 14:24 106-43-4 M16.2 12.5
1,2-Dibromo-3-chloropropane ND ug/L 01/25/23 14:24 96-12-8 M112.5 12.5
Dibromochloromethane ND ug/L 01/25/23 14:24 124-48-1 M16.2 12.5
1,2-Dibromoethane (EDB)ND ug/L 01/25/23 14:24 106-93-4 M16.2 12.5
Dibromomethane ND ug/L 01/25/23 14:24 74-95-3 M16.2 12.5
1,2-Dichlorobenzene ND ug/L 01/25/23 14:24 95-50-1 M16.2 12.5
1,3-Dichlorobenzene ND ug/L 01/25/23 14:24 541-73-1 M16.2 12.5
1,4-Dichlorobenzene ND ug/L 01/25/23 14:24 106-46-7 M16.2 12.5
Dichlorodifluoromethane ND ug/L 01/25/23 14:24 75-71-8 M16.2 12.5
1,1-Dichloroethane ND ug/L 01/25/23 14:24 75-34-3 M16.2 12.5
1,2-Dichloroethane ND ug/L 01/25/23 14:24 107-06-2 M16.2 12.5
1,1-Dichloroethene ND ug/L 01/25/23 14:24 75-35-4 M16.2 12.5
cis-1,2-Dichloroethene ND ug/L 01/25/23 14:24 156-59-2 M16.2 12.5
trans-1,2-Dichloroethene ND ug/L 01/25/23 14:24 156-60-5 M16.2 12.5
1,2-Dichloropropane ND ug/L 01/25/23 14:24 78-87-5 M16.2 12.5
1,3-Dichloropropane ND ug/L 01/25/23 14:24 142-28-9 M16.2 12.5
2,2-Dichloropropane ND ug/L 01/25/23 14:24 594-20-7 M16.2 12.5
1,1-Dichloropropene ND ug/L 01/25/23 14:24 563-58-6 M16.2 12.5
cis-1,3-Dichloropropene ND ug/L 01/25/23 14:24 10061-01-5 M16.2 12.5
trans-1,3-Dichloropropene ND ug/L 01/25/23 14:24 10061-02-6 M16.2 12.5
Diisopropyl ether ND ug/L 01/25/23 14:24 108-20-3 M16.2 12.5
Ethylbenzene 171 ug/L 01/25/23 14:24 100-41-4 M16.2 12.5
Hexachloro-1,3-butadiene ND ug/L 01/25/23 14:24 87-68-3 M125.0 12.5
Isopropylbenzene (Cumene)66.1 ug/L 01/25/23 14:24 98-82-8 M16.2 12.5
Methylene Chloride ND ug/L 01/25/23 14:24 75-09-2 M125.0 12.5
Methyl-tert-butyl ether ND ug/L 01/25/23 14:24 1634-04-4 M16.2 12.5
Naphthalene 97.7 ug/L 01/25/23 14:24 91-20-3 M125.0 12.5
n-Propylbenzene 205 ug/L 01/25/23 14:24 103-65-1 M16.2 12.5
Styrene ND ug/L 01/25/23 14:24 100-42-5 M16.2 12.5
1,1,1,2-Tetrachloroethane ND ug/L 01/25/23 14:24 630-20-6 M16.2 12.5
1,1,2,2-Tetrachloroethane ND ug/L 01/25/23 14:24 79-34-5 M16.2 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-13 Lab ID:92647670001 Collected:01/18/23 12:30 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/25/23 14:24 127-18-4 M16.2 12.5
Toluene ND ug/L 01/25/23 14:24 108-88-3 M16.2 12.5
1,2,3-Trichlorobenzene ND ug/L 01/25/23 14:24 87-61-6 M125.0 12.5
1,2,4-Trichlorobenzene ND ug/L 01/25/23 14:24 120-82-1 M125.0 12.5
1,1,1-Trichloroethane ND ug/L 01/25/23 14:24 71-55-6 M16.2 12.5
1,1,2-Trichloroethane ND ug/L 01/25/23 14:24 79-00-5 M16.2 12.5
Trichloroethene ND ug/L 01/25/23 14:24 79-01-6 M16.2 12.5
Trichlorofluoromethane ND ug/L 01/25/23 14:24 75-69-4 M112.5 12.5
1,2,3-Trichloropropane 8.7 ug/L 01/25/23 14:24 96-18-4 M16.2 12.5
1,2,4-Trimethylbenzene 1650 ug/L 01/25/23 14:24 95-63-66.2 12.5
1,3,5-Trimethylbenzene 349 ug/L 01/25/23 14:24 108-67-8 M16.2 12.5
Vinyl chloride ND ug/L 01/25/23 14:24 75-01-4 M112.5 12.5
m&p-Xylene 76.8 ug/L 01/25/23 14:24 179601-23-1 M112.5 12.5
o-Xylene ND ug/L 01/25/23 14:24 95-47-6 M16.2 12.5
Surrogates
1,2-Dichloroethane-d4 (S)109 %01/25/23 14:24 17060-07-070-130 12.5
4-Bromofluorobenzene (S)100 %01/25/23 14:24 460-00-470-130 12.5
Toluene-d8 (S)101 %01/25/23 14:24 2037-26-570-130 12.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-12 Lab ID:92647670002 Collected:01/18/23 12:45 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/25/23 13:30 71-43-21.0 2
Bromobenzene ND ug/L 01/25/23 13:30 108-86-11.0 2
Bromochloromethane ND ug/L 01/25/23 13:30 74-97-51.0 2
Bromodichloromethane ND ug/L 01/25/23 13:30 75-27-41.0 2
Bromoform ND ug/L 01/25/23 13:30 75-25-21.0 2
Bromomethane ND ug/L 01/25/23 13:30 74-83-910.0 2
n-Butylbenzene 21.0 ug/L 01/25/23 13:30 104-51-81.0 2
sec-Butylbenzene 8.2 ug/L 01/25/23 13:30 135-98-81.0 2
tert-Butylbenzene ND ug/L 01/25/23 13:30 98-06-61.0 2
Carbon tetrachloride ND ug/L 01/25/23 13:30 56-23-51.0 2
Chlorobenzene ND ug/L 01/25/23 13:30 108-90-71.0 2
Chloroethane ND ug/L 01/25/23 13:30 75-00-32.0 2
Chloroform ND ug/L 01/25/23 13:30 67-66-31.0 2
Chloromethane ND ug/L 01/25/23 13:30 74-87-32.0 2
2-Chlorotoluene ND ug/L 01/25/23 13:30 95-49-81.0 2
4-Chlorotoluene ND ug/L 01/25/23 13:30 106-43-41.0 2
1,2-Dibromo-3-chloropropane ND ug/L 01/25/23 13:30 96-12-82.0 2
Dibromochloromethane ND ug/L 01/25/23 13:30 124-48-11.0 2
1,2-Dibromoethane (EDB)ND ug/L 01/25/23 13:30 106-93-41.0 2
Dibromomethane ND ug/L 01/25/23 13:30 74-95-31.0 2
1,2-Dichlorobenzene ND ug/L 01/25/23 13:30 95-50-11.0 2
1,3-Dichlorobenzene ND ug/L 01/25/23 13:30 541-73-11.0 2
1,4-Dichlorobenzene ND ug/L 01/25/23 13:30 106-46-71.0 2
Dichlorodifluoromethane ND ug/L 01/25/23 13:30 75-71-81.0 2
1,1-Dichloroethane ND ug/L 01/25/23 13:30 75-34-31.0 2
1,2-Dichloroethane ND ug/L 01/25/23 13:30 107-06-21.0 2
1,1-Dichloroethene ND ug/L 01/25/23 13:30 75-35-41.0 2
cis-1,2-Dichloroethene ND ug/L 01/25/23 13:30 156-59-21.0 2
trans-1,2-Dichloroethene ND ug/L 01/25/23 13:30 156-60-51.0 2
1,2-Dichloropropane ND ug/L 01/25/23 13:30 78-87-51.0 2
1,3-Dichloropropane ND ug/L 01/25/23 13:30 142-28-91.0 2
2,2-Dichloropropane ND ug/L 01/25/23 13:30 594-20-71.0 2
1,1-Dichloropropene ND ug/L 01/25/23 13:30 563-58-61.0 2
cis-1,3-Dichloropropene ND ug/L 01/25/23 13:30 10061-01-51.0 2
trans-1,3-Dichloropropene ND ug/L 01/25/23 13:30 10061-02-61.0 2
Diisopropyl ether ND ug/L 01/25/23 13:30 108-20-31.0 2
Ethylbenzene 20.1 ug/L 01/25/23 13:30 100-41-41.0 2
Hexachloro-1,3-butadiene ND ug/L 01/25/23 13:30 87-68-34.0 2
Isopropylbenzene (Cumene)16.0 ug/L 01/25/23 13:30 98-82-81.0 2
Methylene Chloride ND ug/L 01/25/23 13:30 75-09-24.0 2
Methyl-tert-butyl ether ND ug/L 01/25/23 13:30 1634-04-41.0 2
Naphthalene 12.2 ug/L 01/25/23 13:30 91-20-34.0 2
n-Propylbenzene 52.9 ug/L 01/25/23 13:30 103-65-11.0 2
Styrene ND ug/L 01/25/23 13:30 100-42-51.0 2
1,1,1,2-Tetrachloroethane ND ug/L 01/25/23 13:30 630-20-61.0 2
1,1,2,2-Tetrachloroethane ND ug/L 01/25/23 13:30 79-34-51.0 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-12 Lab ID:92647670002 Collected:01/18/23 12:45 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/25/23 13:30 127-18-41.0 2
Toluene 196 ug/L 01/25/23 13:30 108-88-31.0 2
1,2,3-Trichlorobenzene ND ug/L 01/25/23 13:30 87-61-64.0 2
1,2,4-Trichlorobenzene ND ug/L 01/25/23 13:30 120-82-14.0 2
1,1,1-Trichloroethane ND ug/L 01/25/23 13:30 71-55-61.0 2
1,1,2-Trichloroethane ND ug/L 01/25/23 13:30 79-00-51.0 2
Trichloroethene ND ug/L 01/25/23 13:30 79-01-61.0 2
Trichlorofluoromethane ND ug/L 01/25/23 13:30 75-69-42.0 2
1,2,3-Trichloropropane 1.5 ug/L 01/25/23 13:30 96-18-41.0 2
1,2,4-Trimethylbenzene 324 ug/L 01/25/23 13:30 95-63-61.0 2
1,3,5-Trimethylbenzene 55.5 ug/L 01/25/23 13:30 108-67-81.0 2
Vinyl chloride ND ug/L 01/25/23 13:30 75-01-42.0 2
m&p-Xylene 3.7 ug/L 01/25/23 13:30 179601-23-12.0 2
o-Xylene ND ug/L 01/25/23 13:30 95-47-61.0 2
Surrogates
1,2-Dichloroethane-d4 (S)107 %01/25/23 13:30 17060-07-070-130 2
4-Bromofluorobenzene (S)99 %01/25/23 13:30 460-00-470-130 2
Toluene-d8 (S)100 %01/25/23 13:30 2037-26-570-130 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-14 Lab ID:92647670003 Collected:01/18/23 13:00 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene ND ug/L 01/25/23 13:48 71-43-21.2 2.5
Bromobenzene ND ug/L 01/25/23 13:48 108-86-11.2 2.5
Bromochloromethane ND ug/L 01/25/23 13:48 74-97-51.2 2.5
Bromodichloromethane ND ug/L 01/25/23 13:48 75-27-41.2 2.5
Bromoform ND ug/L 01/25/23 13:48 75-25-21.2 2.5
Bromomethane ND ug/L 01/25/23 13:48 74-83-912.5 2.5
n-Butylbenzene 18.1 ug/L 01/25/23 13:48 104-51-81.2 2.5
sec-Butylbenzene ND ug/L 01/25/23 13:48 135-98-81.2 2.5
tert-Butylbenzene ND ug/L 01/25/23 13:48 98-06-61.2 2.5
Carbon tetrachloride ND ug/L 01/25/23 13:48 56-23-51.2 2.5
Chlorobenzene ND ug/L 01/25/23 13:48 108-90-71.2 2.5
Chloroethane ND ug/L 01/25/23 13:48 75-00-32.5 2.5
Chloroform ND ug/L 01/25/23 13:48 67-66-31.2 2.5
Chloromethane ND ug/L 01/25/23 13:48 74-87-32.5 2.5
2-Chlorotoluene ND ug/L 01/25/23 13:48 95-49-81.2 2.5
4-Chlorotoluene ND ug/L 01/25/23 13:48 106-43-41.2 2.5
1,2-Dibromo-3-chloropropane ND ug/L 01/25/23 13:48 96-12-82.5 2.5
Dibromochloromethane ND ug/L 01/25/23 13:48 124-48-11.2 2.5
1,2-Dibromoethane (EDB)ND ug/L 01/25/23 13:48 106-93-41.2 2.5
Dibromomethane ND ug/L 01/25/23 13:48 74-95-31.2 2.5
1,2-Dichlorobenzene ND ug/L 01/25/23 13:48 95-50-11.2 2.5
1,3-Dichlorobenzene ND ug/L 01/25/23 13:48 541-73-11.2 2.5
1,4-Dichlorobenzene ND ug/L 01/25/23 13:48 106-46-71.2 2.5
Dichlorodifluoromethane ND ug/L 01/25/23 13:48 75-71-81.2 2.5
1,1-Dichloroethane ND ug/L 01/25/23 13:48 75-34-31.2 2.5
1,2-Dichloroethane ND ug/L 01/25/23 13:48 107-06-21.2 2.5
1,1-Dichloroethene ND ug/L 01/25/23 13:48 75-35-41.2 2.5
cis-1,2-Dichloroethene ND ug/L 01/25/23 13:48 156-59-21.2 2.5
trans-1,2-Dichloroethene ND ug/L 01/25/23 13:48 156-60-51.2 2.5
1,2-Dichloropropane ND ug/L 01/25/23 13:48 78-87-51.2 2.5
1,3-Dichloropropane ND ug/L 01/25/23 13:48 142-28-91.2 2.5
2,2-Dichloropropane ND ug/L 01/25/23 13:48 594-20-71.2 2.5
1,1-Dichloropropene ND ug/L 01/25/23 13:48 563-58-61.2 2.5
cis-1,3-Dichloropropene ND ug/L 01/25/23 13:48 10061-01-51.2 2.5
trans-1,3-Dichloropropene ND ug/L 01/25/23 13:48 10061-02-61.2 2.5
Diisopropyl ether ND ug/L 01/25/23 13:48 108-20-31.2 2.5
Ethylbenzene 13.3 ug/L 01/25/23 13:48 100-41-41.2 2.5
Hexachloro-1,3-butadiene ND ug/L 01/25/23 13:48 87-68-35.0 2.5
Isopropylbenzene (Cumene)18.2 ug/L 01/25/23 13:48 98-82-81.2 2.5
Methylene Chloride ND ug/L 01/25/23 13:48 75-09-25.0 2.5
Methyl-tert-butyl ether ND ug/L 01/25/23 13:48 1634-04-41.2 2.5
Naphthalene 14.9 ug/L 01/25/23 13:48 91-20-35.0 2.5
n-Propylbenzene 38.4 ug/L 01/25/23 13:48 103-65-11.2 2.5
Styrene ND ug/L 01/25/23 13:48 100-42-51.2 2.5
1,1,1,2-Tetrachloroethane ND ug/L 01/25/23 13:48 630-20-61.2 2.5
1,1,2,2-Tetrachloroethane ND ug/L 01/25/23 13:48 79-34-51.2 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-14 Lab ID:92647670003 Collected:01/18/23 13:00 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/25/23 13:48 127-18-41.2 2.5
Toluene 16.6 ug/L 01/25/23 13:48 108-88-31.2 2.5
1,2,3-Trichlorobenzene ND ug/L 01/25/23 13:48 87-61-65.0 2.5
1,2,4-Trichlorobenzene ND ug/L 01/25/23 13:48 120-82-15.0 2.5
1,1,1-Trichloroethane ND ug/L 01/25/23 13:48 71-55-61.2 2.5
1,1,2-Trichloroethane ND ug/L 01/25/23 13:48 79-00-51.2 2.5
Trichloroethene ND ug/L 01/25/23 13:48 79-01-61.2 2.5
Trichlorofluoromethane ND ug/L 01/25/23 13:48 75-69-42.5 2.5
1,2,3-Trichloropropane ND ug/L 01/25/23 13:48 96-18-41.2 2.5
1,2,4-Trimethylbenzene 305 ug/L 01/25/23 13:48 95-63-61.2 2.5
1,3,5-Trimethylbenzene 15.2 ug/L 01/25/23 13:48 108-67-81.2 2.5
Vinyl chloride ND ug/L 01/25/23 13:48 75-01-42.5 2.5
m&p-Xylene 11.9 ug/L 01/25/23 13:48 179601-23-12.5 2.5
o-Xylene 19.5 ug/L 01/25/23 13:48 95-47-61.2 2.5
Surrogates
1,2-Dichloroethane-d4 (S)106 %01/25/23 13:48 17060-07-070-130 2.5
4-Bromofluorobenzene (S)98 %01/25/23 13:48 460-00-470-130 2.5
Toluene-d8 (S)100 %01/25/23 13:48 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-11 Lab ID:92647670004 Collected:01/18/23 13:15 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Benzene 1.6 ug/L 01/25/23 14:06 71-43-21.2 2.5
Bromobenzene ND ug/L 01/25/23 14:06 108-86-11.2 2.5
Bromochloromethane ND ug/L 01/25/23 14:06 74-97-51.2 2.5
Bromodichloromethane ND ug/L 01/25/23 14:06 75-27-41.2 2.5
Bromoform ND ug/L 01/25/23 14:06 75-25-21.2 2.5
Bromomethane ND ug/L 01/25/23 14:06 74-83-912.5 2.5
n-Butylbenzene 19.2 ug/L 01/25/23 14:06 104-51-81.2 2.5
sec-Butylbenzene ND ug/L 01/25/23 14:06 135-98-81.2 2.5
tert-Butylbenzene ND ug/L 01/25/23 14:06 98-06-61.2 2.5
Carbon tetrachloride ND ug/L 01/25/23 14:06 56-23-51.2 2.5
Chlorobenzene ND ug/L 01/25/23 14:06 108-90-71.2 2.5
Chloroethane ND ug/L 01/25/23 14:06 75-00-32.5 2.5
Chloroform ND ug/L 01/25/23 14:06 67-66-31.2 2.5
Chloromethane ND ug/L 01/25/23 14:06 74-87-32.5 2.5
2-Chlorotoluene ND ug/L 01/25/23 14:06 95-49-81.2 2.5
4-Chlorotoluene ND ug/L 01/25/23 14:06 106-43-41.2 2.5
1,2-Dibromo-3-chloropropane ND ug/L 01/25/23 14:06 96-12-82.5 2.5
Dibromochloromethane ND ug/L 01/25/23 14:06 124-48-11.2 2.5
1,2-Dibromoethane (EDB)ND ug/L 01/25/23 14:06 106-93-41.2 2.5
Dibromomethane ND ug/L 01/25/23 14:06 74-95-31.2 2.5
1,2-Dichlorobenzene ND ug/L 01/25/23 14:06 95-50-11.2 2.5
1,3-Dichlorobenzene ND ug/L 01/25/23 14:06 541-73-11.2 2.5
1,4-Dichlorobenzene ND ug/L 01/25/23 14:06 106-46-71.2 2.5
Dichlorodifluoromethane ND ug/L 01/25/23 14:06 75-71-81.2 2.5
1,1-Dichloroethane ND ug/L 01/25/23 14:06 75-34-31.2 2.5
1,2-Dichloroethane ND ug/L 01/25/23 14:06 107-06-21.2 2.5
1,1-Dichloroethene ND ug/L 01/25/23 14:06 75-35-41.2 2.5
cis-1,2-Dichloroethene ND ug/L 01/25/23 14:06 156-59-21.2 2.5
trans-1,2-Dichloroethene ND ug/L 01/25/23 14:06 156-60-51.2 2.5
1,2-Dichloropropane ND ug/L 01/25/23 14:06 78-87-51.2 2.5
1,3-Dichloropropane ND ug/L 01/25/23 14:06 142-28-91.2 2.5
2,2-Dichloropropane ND ug/L 01/25/23 14:06 594-20-71.2 2.5
1,1-Dichloropropene ND ug/L 01/25/23 14:06 563-58-61.2 2.5
cis-1,3-Dichloropropene ND ug/L 01/25/23 14:06 10061-01-51.2 2.5
trans-1,3-Dichloropropene ND ug/L 01/25/23 14:06 10061-02-61.2 2.5
Diisopropyl ether ND ug/L 01/25/23 14:06 108-20-31.2 2.5
Ethylbenzene 17.3 ug/L 01/25/23 14:06 100-41-41.2 2.5
Hexachloro-1,3-butadiene ND ug/L 01/25/23 14:06 87-68-35.0 2.5
Isopropylbenzene (Cumene)15.2 ug/L 01/25/23 14:06 98-82-81.2 2.5
Methylene Chloride ND ug/L 01/25/23 14:06 75-09-25.0 2.5
Methyl-tert-butyl ether ND ug/L 01/25/23 14:06 1634-04-41.2 2.5
Naphthalene 13.1 ug/L 01/25/23 14:06 91-20-35.0 2.5
n-Propylbenzene 46.3 ug/L 01/25/23 14:06 103-65-11.2 2.5
Styrene ND ug/L 01/25/23 14:06 100-42-51.2 2.5
1,1,1,2-Tetrachloroethane ND ug/L 01/25/23 14:06 630-20-61.2 2.5
1,1,2,2-Tetrachloroethane ND ug/L 01/25/23 14:06 79-34-51.2 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 21
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Sample:TULULA CREEK -SW-11 Lab ID:92647670004 Collected:01/18/23 13:15 Received:01/18/23 13:20 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
6200B MSV
Tetrachloroethene ND ug/L 01/25/23 14:06 127-18-41.2 2.5
Toluene 16.3 ug/L 01/25/23 14:06 108-88-31.2 2.5
1,2,3-Trichlorobenzene ND ug/L 01/25/23 14:06 87-61-65.0 2.5
1,2,4-Trichlorobenzene ND ug/L 01/25/23 14:06 120-82-15.0 2.5
1,1,1-Trichloroethane ND ug/L 01/25/23 14:06 71-55-61.2 2.5
1,1,2-Trichloroethane ND ug/L 01/25/23 14:06 79-00-51.2 2.5
Trichloroethene ND ug/L 01/25/23 14:06 79-01-61.2 2.5
Trichlorofluoromethane ND ug/L 01/25/23 14:06 75-69-42.5 2.5
1,2,3-Trichloropropane ND ug/L 01/25/23 14:06 96-18-41.2 2.5
1,2,4-Trimethylbenzene 326 ug/L 01/25/23 14:06 95-63-61.2 2.5
1,3,5-Trimethylbenzene 74.7 ug/L 01/25/23 14:06 108-67-81.2 2.5
Vinyl chloride ND ug/L 01/25/23 14:06 75-01-42.5 2.5
m&p-Xylene 24.4 ug/L 01/25/23 14:06 179601-23-12.5 2.5
o-Xylene 17.7 ug/L 01/25/23 14:06 95-47-61.2 2.5
Surrogates
1,2-Dichloroethane-d4 (S)107 %01/25/23 14:06 17060-07-070-130 2.5
4-Bromofluorobenzene (S)101 %01/25/23 14:06 460-00-470-130 2.5
Toluene-d8 (S)101 %01/25/23 14:06 2037-26-570-130 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
751699
SM 6200B
SM 6200B
6200B MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92647670001, 92647670002, 92647670003, 92647670004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3906123
Associated Lab Samples:92647670001, 92647670002, 92647670003, 92647670004
Matrix:Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/25/23 12:17
1,1,1-Trichloroethane ug/L ND 0.50 01/25/23 12:17
1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/25/23 12:17
1,1,2-Trichloroethane ug/L ND 0.50 01/25/23 12:17
1,1-Dichloroethane ug/L ND 0.50 01/25/23 12:17
1,1-Dichloroethene ug/L ND 0.50 01/25/23 12:17
1,1-Dichloropropene ug/L ND 0.50 01/25/23 12:17
1,2,3-Trichlorobenzene ug/L ND 2.0 01/25/23 12:17
1,2,3-Trichloropropane ug/L ND 0.50 01/25/23 12:17
1,2,4-Trichlorobenzene ug/L ND 2.0 01/25/23 12:17
1,2,4-Trimethylbenzene ug/L ND 0.50 01/25/23 12:17
1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/25/23 12:17
1,2-Dibromoethane (EDB)ug/L ND 0.50 01/25/23 12:17
1,2-Dichlorobenzene ug/L ND 0.50 01/25/23 12:17
1,2-Dichloroethane ug/L ND 0.50 01/25/23 12:17
1,2-Dichloropropane ug/L ND 0.50 01/25/23 12:17
1,3,5-Trimethylbenzene ug/L ND 0.50 01/25/23 12:17
1,3-Dichlorobenzene ug/L ND 0.50 01/25/23 12:17
1,3-Dichloropropane ug/L ND 0.50 01/25/23 12:17
1,4-Dichlorobenzene ug/L ND 0.50 01/25/23 12:17
2,2-Dichloropropane ug/L ND 0.50 01/25/23 12:17
2-Chlorotoluene ug/L ND 0.50 01/25/23 12:17
4-Chlorotoluene ug/L ND 0.50 01/25/23 12:17
Benzene ug/L ND 0.50 01/25/23 12:17
Bromobenzene ug/L ND 0.50 01/25/23 12:17
Bromochloromethane ug/L ND 0.50 01/25/23 12:17
Bromodichloromethane ug/L ND 0.50 01/25/23 12:17
Bromoform ug/L ND 0.50 01/25/23 12:17
Bromomethane ug/L ND 5.0 01/25/23 12:17
Carbon tetrachloride ug/L ND 0.50 01/25/23 12:17
Chlorobenzene ug/L ND 0.50 01/25/23 12:17
Chloroethane ug/L ND 1.0 01/25/23 12:17
Chloroform ug/L ND 0.50 01/25/23 12:17
Chloromethane ug/L ND 1.0 01/25/23 12:17
cis-1,2-Dichloroethene ug/L ND 0.50 01/25/23 12:17
cis-1,3-Dichloropropene ug/L ND 0.50 01/25/23 12:17
Dibromochloromethane ug/L ND 0.50 01/25/23 12:17
Dibromomethane ug/L ND 0.50 01/25/23 12:17
Dichlorodifluoromethane ug/L ND 0.50 01/25/23 12:17
Diisopropyl ether ug/L ND 0.50 01/25/23 12:17
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3906123
Associated Lab Samples:92647670001, 92647670002, 92647670003, 92647670004
Matrix:Water
Analyzed
Ethylbenzene ug/L ND 0.50 01/25/23 12:17
Hexachloro-1,3-butadiene ug/L ND 2.0 01/25/23 12:17
Isopropylbenzene (Cumene)ug/L ND 0.50 01/25/23 12:17
m&p-Xylene ug/L ND 1.0 01/25/23 12:17
Methyl-tert-butyl ether ug/L ND 0.50 01/25/23 12:17
Methylene Chloride ug/L ND 2.0 01/25/23 12:17
n-Butylbenzene ug/L ND 0.50 01/25/23 12:17
n-Propylbenzene ug/L ND 0.50 01/25/23 12:17
Naphthalene ug/L ND 2.0 01/25/23 12:17
o-Xylene ug/L ND 0.50 01/25/23 12:17
sec-Butylbenzene ug/L ND 0.50 01/25/23 12:17
Styrene ug/L ND 0.50 01/25/23 12:17
tert-Butylbenzene ug/L ND 0.50 01/25/23 12:17
Tetrachloroethene ug/L ND 0.50 01/25/23 12:17
Toluene ug/L ND 0.50 01/25/23 12:17
trans-1,2-Dichloroethene ug/L ND 0.50 01/25/23 12:17
trans-1,3-Dichloropropene ug/L ND 0.50 01/25/23 12:17
Trichloroethene ug/L ND 0.50 01/25/23 12:17
Trichlorofluoromethane ug/L ND 1.0 01/25/23 12:17
Vinyl chloride ug/L ND 1.0 01/25/23 12:17
1,2-Dichloroethane-d4 (S)%109 70-130 01/25/23 12:17
4-Bromofluorobenzene (S)%100 70-130 01/25/23 12:17
Toluene-d8 (S)%102 70-130 01/25/23 12:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3906124LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 20.420 102 60-140
1,1,1-Trichloroethane ug/L 22.920 115 60-140
1,1,2,2-Tetrachloroethane ug/L 21.620 108 60-140
1,1,2-Trichloroethane ug/L 21.920 109 60-140
1,1-Dichloroethane ug/L 23.220 116 60-140
1,1-Dichloroethene ug/L 24.620 123 60-140
1,1-Dichloropropene ug/L 24.420 122 60-140
1,2,3-Trichlorobenzene ug/L 23.520 117 60-140
1,2,3-Trichloropropane ug/L 22.220 111 60-140
1,2,4-Trichlorobenzene ug/L 23.620 118 60-140
1,2,4-Trimethylbenzene ug/L 23.920 119 60-140
1,2-Dibromo-3-chloropropane ug/L 19.120 95 60-140
1,2-Dibromoethane (EDB)ug/L 22.620 113 60-140
1,2-Dichlorobenzene ug/L 22.520 113 60-140
1,2-Dichloroethane ug/L 23.720 119 60-140
1,2-Dichloropropane ug/L 23.320 117 60-140
1,3,5-Trimethylbenzene ug/L 23.320 117 60-140
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3906124LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 22.520 113 60-140
1,3-Dichloropropane ug/L 22.920 114 60-140
1,4-Dichlorobenzene ug/L 21.520 108 60-140
2,2-Dichloropropane ug/L 23.720 118 60-140
2-Chlorotoluene ug/L 22.720 113 60-140
4-Chlorotoluene ug/L 23.120 116 60-140
Benzene ug/L 20.220 101 60-140
Bromobenzene ug/L 21.620 108 60-140
Bromochloromethane ug/L 22.320 111 60-140
Bromodichloromethane ug/L 20.120 100 60-140
Bromoform ug/L 17.320 86 60-140
Bromomethane ug/L 18.120 91 60-140
Carbon tetrachloride ug/L 19.720 99 60-140
Chlorobenzene ug/L 21.920 109 60-140
Chloroethane ug/L 25.320 127 60-140
Chloroform ug/L 22.520 112 60-140
Chloromethane ug/L 25.420 127 60-140
cis-1,2-Dichloroethene ug/L 23.620 118 60-140
cis-1,3-Dichloropropene ug/L 21.720 108 60-140
Dibromochloromethane ug/L 19.020 95 60-140
Dibromomethane ug/L 20.920 104 60-140
Dichlorodifluoromethane ug/L 23.920 119 60-140
Diisopropyl ether ug/L 23.720 118 60-140
Ethylbenzene ug/L 22.420 112 60-140
Hexachloro-1,3-butadiene ug/L 22.120 111 60-140
Isopropylbenzene (Cumene)ug/L 22.520 112 60-140
m&p-Xylene ug/L 45.940 115 60-140
Methyl-tert-butyl ether ug/L 22.820 114 60-140
Methylene Chloride ug/L 23.520 117 60-140
n-Butylbenzene ug/L 24.920 125 60-140
n-Propylbenzene ug/L 22.820 114 60-140
Naphthalene ug/L 25.120 125 60-140
o-Xylene ug/L 22.820 114 60-140
sec-Butylbenzene ug/L 23.220 116 60-140
Styrene ug/L 23.120 116 60-140
tert-Butylbenzene ug/L 18.820 94 60-140
Tetrachloroethene ug/L 21.320 106 60-140
Toluene ug/L 21.220 106 60-140
trans-1,2-Dichloroethene ug/L 24.720 123 60-140
trans-1,3-Dichloropropene ug/L 21.620 108 60-140
Trichloroethene ug/L 22.720 114 60-140
Trichlorofluoromethane ug/L 19.820 99 60-140
Vinyl chloride ug/L 22.620 113 60-140
1,2-Dichloroethane-d4 (S)%109 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3906125MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92647670001
3906126
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L M12501060-14010 0250ND25.5 25.6
1,1,1-Trichloroethane ug/L M12501160-14011 2250ND26.5 27.0
1,1,2,2-Tetrachloroethane ug/L M12501260-14012 3250ND30.3 31.2
1,1,2-Trichloroethane ug/L M12501260-14012 0250ND28.8 28.8
1,1-Dichloroethane ug/L M12501260-14012 3250ND29.4 30.3
1,1-Dichloroethene ug/L M12501160-14011 6250ND26.3 28.0
1,1-Dichloropropene ug/L M12501160-14011 3250ND27.3 28.2
1,2,3-Trichlorobenzene ug/L M12501160-14012 5250ND28.4 29.9
1,2,3-Trichloropropane ug/L M12501460-14014 12508.7 44.0 44.3
1,2,4-Trichlorobenzene ug/L M12501260-14013 12250ND29.0 32.7
1,2,4-Trimethylbenzene ug/L 250 77 60-14096 2250165018401890
1,2-Dibromo-3-chloropropane ug/L M1250960-14010 12250ND22.4 25.2
1,2-Dibromoethane (EDB)ug/L M12501160-14011 3250ND27.4 28.3
1,2-Dichlorobenzene ug/L M12501260-14013 8250ND29.8 32.4
1,2-Dichloroethane ug/L M12501260-14013 4250ND30.1 31.5
1,2-Dichloropropane ug/L M12501260-14012 1250ND28.9 29.2
1,3,5-Trimethylbenzene ug/L M12503360-14036 2250349431439
1,3-Dichlorobenzene ug/L M12501360-14013 2250ND31.3 31.9
1,3-Dichloropropane ug/L M12501260-14012 2250ND29.6 30.2
1,4-Dichlorobenzene ug/L M12501260-14012 1250ND30.5 30.3
2,2-Dichloropropane ug/L M12501160-14011 2250ND27.2 27.8
2-Chlorotoluene ug/L M12502760-14028 3250ND68.1 70.0
4-Chlorotoluene ug/L M12501360-14012 10250ND31.7 28.8
Benzene ug/L M12501160-14010 0250ND26.3 26.2
Bromobenzene ug/L M12501260-14012 2250ND30.5 31.2
Bromochloromethane ug/L M12501060-14011 10250ND26.0 28.7
Bromodichloromethane ug/L M12501160-14011 1250ND26.5 26.9
Bromoform ug/L M1250860-1408 1250ND20.1 20.3
Bromomethane ug/L M1250960-1408250ND21.4J ND
Carbon tetrachloride ug/L M1250960-14011 18250ND22.5 27.0
Chlorobenzene ug/L M12501260-14012 3250ND29.9 30.8
Chloroethane ug/L M12501160-14011 4250ND27.2 28.2
Chloroform ug/L M12501260-14012 3250ND30.3 29.5
Chloromethane ug/L M1250960-1409 3250ND22.4 22.9
cis-1,2-Dichloroethene ug/L M12501260-14013 2250ND31.0 31.5
cis-1,3-Dichloropropene ug/L M12501060-14010 1250ND24.1 24.0
Dibromochloromethane ug/L M1250960-1409 0250ND21.9 21.8
Dibromomethane ug/L M12501060-14011 5250ND25.9 27.2
Dichlorodifluoromethane ug/L M1250560-1405 6250ND12.1 12.9
Diisopropyl ether ug/L M12501260-14012 1250ND29.6 29.4
Ethylbenzene ug/L M12502360-14023 1250171230228
Hexachloro-1,3-butadiene ug/L M12501160-14012 7250ND27.2 29.0
Isopropylbenzene (Cumene)ug/L M12501860-14018 125066.1 111 111
m&p-Xylene ug/L M15001560-14015 150076.8 150 151
Methyl-tert-butyl ether ug/L M12501060-14011 4250ND26.2 27.3
Methylene Chloride ug/L M1250960-1409250NDNDND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 21
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3906125MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92647670001
3906126
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
n-Butylbenzene ug/L M12501660-14017 125058.1 99.3 101
n-Propylbenzene ug/L M12502660-14029 3250205271278
Naphthalene ug/L M12501360-14016 625097.7 130 139
o-Xylene ug/L M12501260-14012 2250ND29.9 30.4
sec-Butylbenzene ug/L M12502260-14022 1250ND54.7 55.2
Styrene ug/L M12501160-14011 2250ND28.1 28.7
tert-Butylbenzene ug/L M1250960-14011 15250ND23.1 26.8
Tetrachloroethene ug/L M12501360-14013 1250ND33.4 33.2
Toluene ug/L M12501260-14012 2250ND29.3 29.9
trans-1,2-Dichloroethene ug/L M12501160-14012 3250ND28.6 29.3
trans-1,3-Dichloropropene ug/L M12501060-14010 0250ND24.0 24.1
Trichloroethene ug/L M12501160-14011 1250ND27.4 27.0
Trichlorofluoromethane ug/L M1250860-1408 1250ND20.6 20.8
Vinyl chloride ug/L M1250860-1408 5250ND20.3 19.3
1,2-Dichloroethane-d4 (S)%107 70-130107
4-Bromofluorobenzene (S)%101 70-130100
Toluene-d8 (S)%99 70-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 21
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 21
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92647670
SW SAMPLING CROWN FOOD MART US
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92647670001 751699TULULA CREEK -SW-13 SM 6200B
92647670002 751699TULULA CREEK -SW-12 SM 6200B
92647670003 751699TULULA CREEK -SW-14 SM 6200B
92647670004 751699TULULA CREEK -SW-11 SM 6200B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/25/2023 04:45 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
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