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HomeMy WebLinkAboutAS-788_9307_CA_RMR_20200128SHEALY ENVIRONMENTAL SERVICES,INC. The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced,except in its entirety,without the written approval of Shealy Environmental Services,Inc. Shealy Environmental Services,Inc. 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax (803)791-9111 www.shealylab.com Report of Analysis ARM Environmental Services,Inc. 11164 Downs Road Pineville,NC 28134 Attention:Tim McCorkle Project Name:CCBCC-Shelby Dec 2019 Groundwater Lot Number:UL13020 Date Completed:12/20/2019 12/23/2019 3:33 PM Approved and released by: Lab Director -Greenville:Lucas Odom Page 1 of 21 SHEALY ENVIRONMENTAL SERVICES,INC. SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No:5639 Shealy Environmental Services,Inc. 106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax (803)791-9111 www.shealylab.com Case Narrative ARM Environmental Services,Inc. Lot Number:UL13020 This Report of Analysis contains the analytical result(s)for the sample(s)listed on the Sample Summary following this Case Narrative.The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt,sample analysis,and data review have been performed in accordance with the most current approved NELAC standards,the Shealy Environmental Services,Inc.("Shealy")Quality Assurance Management Plan (QAMP),standard operating procedures (SOPs),and Shealy policies.Any exceptions to the NELAC standards,the QAMP,SOPs or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. EDB by Microextraction Sample -007 has been analyzed at a 50X dilution due to a large detection of the target compound.This large dilution caused the surrogate to recover above method criteria.No corrective action is required as it is known that dilutions of 5X and greater may impact surrogate recoveries. Sample -010 has been qualified with a "P"as the relative percent difference between the two GC columns exceeds method criteria.Per SESI SOP,the lesser of the two values has been reported. Page 2 of 21 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary ARM Environmental Services, Inc. Lot Number: UL13020 Sample Number Sample ID Matrix Date Sampled Date Received 001 12/11/2019 1348MW-1 Aqueous 12/12/2019 002 12/11/2019 1403MW-1A Aqueous 12/12/2019 003 12/11/2019 1330MW-2 Aqueous 12/12/2019 004 12/11/2019 1418MW-3 Aqueous 12/12/2019 005 12/11/2019 1312MW-5 Aqueous 12/12/2019 006 12/11/2019 1255MW-6 Aqueous 12/12/2019 007 12/11/2019 1455MW-7 Aqueous 12/12/2019 008 12/11/2019 1438MW-8 Aqueous 12/12/2019 009 12/11/2019 1145MW-11R Aqueous 12/12/2019 010 12/11/2019 1226MW-12 Aqueous 12/12/2019 011 12/11/2019 1210MW-13 Aqueous 12/12/2019 012 12/11/2019 1125MW-14 Aqueous 12/12/2019 (12 samples) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 3 of 21 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary ARM Environmental Services, Inc. Lot Number: UL13020 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 MW-1 Aqueous Benzene 8260B 550 ug/L 6 001 MW-1 Aqueous Ethylbenzene 8260B 1900 ug/L 6 001 MW-1 Aqueous Toluene 8260B 14000 ug/L 6 001 MW-1 Aqueous Xylenes (total)8260B 13000 ug/L 6 001 MW-1 Aqueous 1,2-Dibromoethane (EDB)504.1 0.063 ug/L 6 002 MW-1A Aqueous Benzene 8260B 9200 ug/L 7 002 MW-1A Aqueous Ethylbenzene 8260B 1700 ug/L 7 002 MW-1A Aqueous Toluene 8260B 11000 ug/L 7 002 MW-1A Aqueous Xylenes (total)8260B 8400 ug/L 7 002 MW-1A Aqueous 1,2-Dibromoethane (EDB)504.1 0.83 ug/L 7 003 MW-2 Aqueous Benzene 8260B 150 ug/L 8 003 MW-2 Aqueous Diisopropyl ether (IPE)8260B 1.1 ug/L 8 003 MW-2 Aqueous Ethylbenzene 8260B 25 ug/L 8 003 MW-2 Aqueous Methyl tertiary butyl ether 8260B 1.3 ug/L 8 003 MW-2 Aqueous Toluene 8260B 20 ug/L 8 003 MW-2 Aqueous Xylenes (total)8260B 99 ug/L 8 004 MW-3 Aqueous Benzene 8260B 72 ug/L 9 004 MW-3 Aqueous Ethylbenzene 8260B 200 ug/L 9 004 MW-3 Aqueous Toluene 8260B 280 ug/L 9 004 MW-3 Aqueous Xylenes (total)8260B 380 ug/L 9 004 MW-3 Aqueous 1,2-Dibromoethane (EDB)504.1 0.033 ug/L 9 005 MW-5 Aqueous Benzene 8260B 42 ug/L 10 005 MW-5 Aqueous Diisopropyl ether (IPE)8260B 3.5 ug/L 10 005 MW-5 Aqueous Ethylbenzene 8260B 13 ug/L 10 005 MW-5 Aqueous Methyl tertiary butyl ether 8260B 63 ug/L 10 005 MW-5 Aqueous Toluene 8260B 1.3 ug/L 10 005 MW-5 Aqueous Xylenes (total)8260B 8.3 ug/L 10 006 MW-6 Aqueous Benzene 8260B 650 ug/L 11 006 MW-6 Aqueous Methyl tertiary butyl ether 8260B 37 ug/L 11 007 MW-7 Aqueous Benzene 8260B 19000 ug/L 12 007 MW-7 Aqueous Diisopropyl ether (IPE)8260B 350 ug/L 12 007 MW-7 Aqueous Ethylbenzene 8260B 3400 ug/L 12 007 MW-7 Aqueous Methyl tertiary butyl ether 8260B 200 ug/L 12 007 MW-7 Aqueous Toluene 8260B 38000 ug/L 12 007 MW-7 Aqueous Xylenes (total)8260B 18000 ug/L 12 007 MW-7 Aqueous 1,2-Dibromoethane (EDB)504.1 31 ug/L 12 008 MW-8 Aqueous Xylenes (total)8260B 47 ug/L 13 009 MW-11R Aqueous Benzene 8260B 2400 ug/L 14 009 MW-11R Aqueous Methyl tertiary butyl ether 8260B 92 ug/L 14 010 MW-12 Aqueous Benzene 8260B 610 ug/L 15 010 MW-12 Aqueous Ethylbenzene 8260B 2000 ug/L 15 010 MW-12 Aqueous Methyl tertiary butyl ether 8260B 290 ug/L 15 010 MW-12 Aqueous Toluene 8260B 5000 ug/L 15 010 MW-12 Aqueous Xylenes (total)8260B 15000 ug/L 15 010 MW-12 Aqueous 1,2-Dibromoethane (EDB)504.1 0.90 P ug/L 15 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 4 of 21 Detection Summary (Continued) Lot Number: UL13020 Sample Sample ID Matrix Parameter Method Result Q Units Page 011 MW-13 Aqueous Methyl tertiary butyl ether 8260B 1.1 ug/L 16 (46 detections) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 5 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-1 UL13020-001 12/11/2019 1348 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 200 12/17/2019 0600 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 550 1ug/L200 Chlorobenzene 108-90-7 8260B ND 1ug/L200 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L200 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L200 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L200 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L200 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L200 Ethylbenzene 100-41-4 8260B 1900 1ug/L200 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B ND 1ug/L200 Toluene 108-88-3 8260B 14000 1ug/L200 Xylenes (total)1330-20-7 8260B 13000 1ug/L200 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 107 70-130 Bromofluorobenzene 104 70-130 Toluene-d8 104 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1326 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 0.063 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 129 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 6 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-1A UL13020-002 12/11/2019 1403 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 100 12/17/2019 0535 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 9200 1ug/L100 Chlorobenzene 108-90-7 8260B ND 1ug/L100 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L100 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L100 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L100 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L100 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L100 Ethylbenzene 100-41-4 8260B 1700 1ug/L100 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B ND 1ug/L100 Toluene 108-88-3 8260B 11000 1ug/L100 Xylenes (total)1330-20-7 8260B 8400 1ug/L100 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 99 70-130 Bromofluorobenzene 93 70-130 Toluene-d8 97 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1338 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 0.83 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 121 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 7 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-2 UL13020-003 12/11/2019 1330 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260B 1 12/18/2019 0030 STM 39341 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 150 2ug/L1.0 Chlorobenzene 108-90-7 8260B ND 2ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 2ug/L1.0 1,2-Dichlorobenzene 95-50-1 8260B ND 2ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 2ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 2ug/L1.0 Diisopropyl ether (IPE)108-20-3 8260B 1.1 2ug/L1.0 Ethylbenzene 100-41-4 8260B 25 2ug/L1.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 1.3 2ug/L1.0 Toluene 108-88-3 8260B 20 2ug/L1.0 Xylenes (total)1330-20-7 8260B 99 2ug/L1.0 AcceptanceRun 2 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 70-130 Bromofluorobenzene 102 70-130 Toluene-d8 101 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1350 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 120 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 8 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-3 UL13020-004 12/11/2019 1418 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260B 5 12/18/2019 0746 STM 39341 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 72 2ug/L5.0 Chlorobenzene 108-90-7 8260B ND 2ug/L5.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 2ug/L5.0 1,2-Dichlorobenzene 95-50-1 8260B ND 2ug/L5.0 1,3-Dichlorobenzene 541-73-1 8260B ND 2ug/L5.0 1,4-Dichlorobenzene 106-46-7 8260B ND 2ug/L5.0 Diisopropyl ether (IPE)108-20-3 8260B ND 2ug/L5.0 Ethylbenzene 100-41-4 8260B 200 2ug/L5.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B ND 2ug/L5.0 Toluene 108-88-3 8260B 280 2ug/L5.0 Xylenes (total)1330-20-7 8260B 380 2ug/L5.0 AcceptanceRun 2 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 70-130 Bromofluorobenzene 98 70-130 Toluene-d8 100 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1402 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 0.033 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 128 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 9 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-5 UL13020-005 12/11/2019 1312 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/17/2019 0015 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 42 1ug/L1.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Diisopropyl ether (IPE)108-20-3 8260B 3.5 1ug/L1.0 Ethylbenzene 100-41-4 8260B 13 1ug/L1.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 63 1ug/L1.0 Toluene 108-88-3 8260B 1.3 1ug/L1.0 Xylenes (total)1330-20-7 8260B 8.3 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 107 70-130 Bromofluorobenzene 103 70-130 Toluene-d8 107 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1414 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.020 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 117 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 10 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-6 UL13020-006 12/11/2019 1255 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 10 12/17/2019 0307 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 650 1ug/L10 Chlorobenzene 108-90-7 8260B ND 1ug/L10 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L10 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L10 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L10 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L10 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L10 Ethylbenzene 100-41-4 8260B ND 1ug/L10 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 37 1ug/L10 Toluene 108-88-3 8260B ND 1ug/L10 Xylenes (total)1330-20-7 8260B ND 1ug/L10 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 110 70-130 Bromofluorobenzene 103 70-130 Toluene-d8 107 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1439 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 98 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 11 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-7 UL13020-007 12/11/2019 1455 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 200 12/17/2019 0625 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 19000 1ug/L200 Chlorobenzene 108-90-7 8260B ND 1ug/L200 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L200 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L200 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L200 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L200 Diisopropyl ether (IPE)108-20-3 8260B 350 1ug/L200 Ethylbenzene 100-41-4 8260B 3400 1ug/L200 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 200 1ug/L200 Toluene 108-88-3 8260B 38000 1ug/L200 Xylenes (total)1330-20-7 8260B 18000 1ug/L200 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 109 70-130 Bromofluorobenzene 106 70-130 Toluene-d8 107 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 50 12/17/2019 1652 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 31 1ug/L0.97 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane N 0.00 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 12 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-8 UL13020-008 12/11/2019 1438 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 5030B 8260B 1 12/18/2019 0319 STM 39341 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B ND 2ug/L1.0 Chlorobenzene 108-90-7 8260B ND 2ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 2ug/L1.0 1,2-Dichlorobenzene 95-50-1 8260B ND 2ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 2ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 2ug/L1.0 Diisopropyl ether (IPE)108-20-3 8260B ND 2ug/L1.0 Ethylbenzene 100-41-4 8260B ND 2ug/L1.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B ND 2ug/L1.0 Toluene 108-88-3 8260B ND 2ug/L1.0 Xylenes (total)1330-20-7 8260B 47 2ug/L1.0 AcceptanceRun 2 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 100 70-130 Bromofluorobenzene 107 70-130 Toluene-d8 103 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1503 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 105 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 13 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-11R UL13020-009 12/11/2019 1145 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 20 12/17/2019 0357 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 2400 1ug/L20 Chlorobenzene 108-90-7 8260B ND 1ug/L20 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L20 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L20 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L20 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L20 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L20 Ethylbenzene 100-41-4 8260B ND 1ug/L20 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 92 1ug/L20 Toluene 108-88-3 8260B ND 1ug/L20 Xylenes (total)1330-20-7 8260B ND 1ug/L20 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 101 70-130 Bromofluorobenzene 94 70-130 Toluene-d8 99 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1515 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.020 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 103 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 14 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-12 UL13020-010 12/11/2019 1226 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 50 12/17/2019 0510 JTH 39195 2 5030B 8260B 100 12/19/2019 1639 TML 39562 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B 610 1ug/L50 Chlorobenzene 108-90-7 8260B ND 1ug/L50 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L50 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L50 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L50 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L50 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L50 Ethylbenzene 100-41-4 8260B 2000 1ug/L50 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 290 1ug/L50 Toluene 108-88-3 8260B 5000 1ug/L50 Xylenes (total)1330-20-7 8260B 15000 2ug/L100 AcceptanceAcceptanceRun 2Run 1 Surrogate Q % Recovery Limits % Recovery LimitsQ 1,2-Dichloroethane-d4 111 70-130 103 70-130 Bromofluorobenzene 107 70-130 106 70-130 Toluene-d8 107 70-130 101 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1528 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 0.90 P 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 82 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 15 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-13 UL13020-011 12/11/2019 1210 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/17/2019 0039 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B ND 1ug/L1.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L1.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B 1.1 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 106 70-130 Bromofluorobenzene 102 70-130 Toluene-d8 103 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1540 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 106 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 16 of 21 Description:Matrix: Date Received: Client:Laboratory ID: Date Sampled: ARM Environmental Services, Inc. MW-14 UL13020-012 12/11/2019 1125 12/12/2019 Aqueous Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260B 1 12/17/2019 0104 JTH 39195 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run Benzene 71-43-2 8260B ND 1ug/L1.0 Chlorobenzene 108-90-7 8260B ND 1ug/L1.0 1,2-Dibromoethane (EDB)106-93-4 8260B ND 1ug/L1.0 1,2-Dichlorobenzene 95-50-1 8260B ND 1ug/L1.0 1,3-Dichlorobenzene 541-73-1 8260B ND 1ug/L1.0 1,4-Dichlorobenzene 106-46-7 8260B ND 1ug/L1.0 Diisopropyl ether (IPE)108-20-3 8260B ND 1ug/L1.0 Ethylbenzene 100-41-4 8260B ND 1ug/L1.0 Methyl tertiary butyl ether (MTBE)1634-04-4 8260B ND 1ug/L1.0 Toluene 108-88-3 8260B ND 1ug/L1.0 Xylenes (total)1330-20-7 8260B ND 1ug/L1.0 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 107 70-130 Bromofluorobenzene 96 70-130 Toluene-d8 103 70-130 EDB & DBCP by Microextraction Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 504.1 504.1 1 12/17/2019 1552 DAL1 12/17/2019 0855 39203 AnalyticalCAS Parameter Number Method Result Q LOQ Units Run 1,2-Dibromoethane (EDB)106-93-4 504.1 ND 1ug/L0.019 AcceptanceRun 1 Surrogate Q % Recovery Limits 1,1,1,2-Tetrachloroethane 110 57-137 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range P = The RPD between two GC columns exceeds 40%ND = Not detected at or above the LOQ N = Recovery is out of criteria H = Out of holding time W = Reported on wet weight basis 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 17 of 21 Chain of Custody and Miscellaneous Documents 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 18 of 21 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 19 of 21 SHEALY ENVIRONMENTAL SERVICES, INC. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Shealy Environmental Services, Inc. Page 20 of 21