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HomeMy WebLinkAbout1201_Burke_KirkseyDrive_MSWLF_Nov22GW_FID1776724_20230309L�ENR W oNLYLd ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information_ Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G.V. Burbach, PhD, PG E-mail: vburbach@labellapc.com Phone: (336) 323-0092 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. - Kirksey Dr. Landfill Kirksey Drive 12-01 .0500 November 14-15, 2022 Morganton, NC Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring X❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, PhD, PG Sr. Technical Geologist (336) 323-0092 Facili a e N Print) Title (Area Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal Signature 12-D Oak Branch Dr., Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Date CAR '. SEAL 4349 r V G GF0LESS 0�,� LaBeLLa Powered by partnership. March 09, 2023 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: November 2022 Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2223529 Dear Ms. Drummond: Please find the attached November 2022 Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the November 2022 monitoring event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the EQuIS EDD. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates ro�51--tr� Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure cc: Mark Delehant, Burke County 12-D Oak Branch Drive I Greensboro, NC 27407 I p (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 4 RuxxE o 00 �T8 CAR0 Submitted by: LaBella Associates (Joyce Engineering) 12-D Oak Branch Drive Greensboro, NC 27407 (336) 323-0092 NC License No. C-0782 LaBeRa Powered by partnership. November 2022 WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 MARCH 2O23 PROJECT NO. 2223529 November 2022 Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................................................................1 1.1 Site Information................................................................................................................... 1 1.2 Site Geology......................................................................................................................... 1 1.3 Regulatory Status................................................................................................................. 1 2.0 FACILITY MONITORING PROGRAM...............................................................................................2 2.1 Groundwater Monitoring Program......................................................................................... 2 2.2 Surface Water Monitoring Program....................................................................................... 2 3.0 November 2022 MONITORING EVENT........................................................................................3 3.1 Field Work............................................................................................................................ 3 3.2 Laboratory Analysis and Quality Control................................................................................ 3 4.0 HYDROGEOLOGY..........................................................................................................................4 5.0 DATA ANALYSIS.............................................................................................................................5 5.1 Analytical Results and Comparison to Standards.................................................................. 5 5.1.1 Groundwater........................................................................................................................5 5.1.2 Surface Water.......................................................................................................................6 6.0 CONCLUSION................................................................................................................................7 7.0 REFERENCES................................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 November 2022 Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS (CONTINUED) Tables Table 1 Groundwater Elevations (November 2022) Table 2 Hydraulic Gradients and Velocities (November 2022) Table 3 Detected Constituents (November 2022) Table 4 Exceedances of Standards (November 2022) Table 5 Field Parameters (November 2022) Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map (November 2022) Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of the Inner Piedmont Belt rocks were mostly sedimentary (greywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1(background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (feet) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The INC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply WS-IV. All surface water monitoring points are monitored semiannually for the INC Appendix I list of constituents plus 1,4-dioxane. Surface Point Classification Monitoring Program Location Description SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 2 3.0 November 2022 MONITORING EVENT 3.1 Field Work On November 14, 2022, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-1, MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S and collect surface water samples from surface water monitoring points SMP-1, SMP-2, and SMP-3 (November 2022 Monitoring Event). Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the November 2022 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation- reduction potential, and turbidity were recorded in the site logbook and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a cooler. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the November 2022 Monitoring Event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity and recorded in the site logbook. Immediately after sample collection, the samples were placed on ice in a laboratory -provided cooler. Field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The November 2022 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory in good condition, properly preserved, at proper temperature, and within analysis hold times. The sampling data report was received from Pace Analytical Services on November 16, 2022. A Field Blank was collected by LaBella personnel as part of the sampling event and a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank, Trip Blank was analyzed for NC Appendix I VOCs and 1,4-dioxane. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 3 Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), 15A NCAC 2B Surface Water Standards (NC2B), or NC In -stream Target Values (ISTV); and • Detections that are above historical levels. A review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and highly fractured/weathered metamorphic rock. Beneath the regolith is fractured metamorphic rock that is typically well connected to the regolith but has less porosity and storativity. The fractured bedrock portion of the aquifer tends to be more heterogeneous and anisotropic than the regolith. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in November 2022, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the November 2022 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.046 to 0.071, with an average of approximately 0.054. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = K►/ne. Where: V = average linear velocity; K = hydraulic conductivity; i = horizontal hydraulic gradient; and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 4 The estimated linear groundwater flow velocity under the facility ranged from 274 to 427 feet/year, with an average flow velocity of approximately 321 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the November 2022 Monitoring Event are listed in Table 3. Results with quantified concentrations above their respective NC21- Standard are presented in Table 4. Field parameter data from the November 2022 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the November 2022 monitoring event, the inorganic constituents detected at quantified concentrations above the MRL in the groundwater samples included: • Barium (MW-1, MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S); • Cobalt (MW-1, MW-2, MW-3S); • Nickel (MW-2, MW-3D, MW-6S); and • Zinc (MW-1). The inorganic constituents detected at quantified concentrations in exceedance of their respective NC21- during the November 2022 Monitoring Event include: • Barium (MW-2); and • Cobalt (MW-1, MW-2, and MW-3S). The organic constituents detected in groundwater monitoring wells at quantified concentrations above the MRL in the groundwater samples included: • Acetone (MW-1); • Benzene (MW-2, MW-3D, MW-3S); • Chlorobenzene (MW-2, MW-31), MW-3S); • 1,1-Dichloroethane (MW-3D); Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 5 • 1,2-Dichlorobenzene (MW-2, MW-3S); • 1,2-Dichloropropane (MW-3D); • 1,4-Dichlorobenzene (MW-2, MW-3D); • cis-1,2-Dichlorethene (MW-3D, MW-4); • 1,4-Dioxane (MW-2, MW-3D, MW-3S); • Ethylbenzene (MW-2); • Tetrachloroethene (MW-3D, MW-4); • Trichloroethene (MW-3D); • Vinyl chloride (MW-3D); and • Xylenes (MW-2, MW-3S). The organic constituents detected at quantified concentrations in exceedance of their respective NC21- during the November 2022 Monitoring Event include: • Benzene (MW-2, MW-3D, MW-3S); • 1,4-Dichlorobenzene (MW-2, MW-3S); • 1,4-Dioxane (MW-2, MW-3D, MW-3S); • Tetrachloroethene (MW-3D); • Trichloroethene (MW-3D); and • Vinyl chloride (MW-3D). In general, these results are consistent with historical data for the site (Appendix 2, Table A2-2). 5.1.2 Surface Water Constituents detected in the surface water during the November 2022 monitoring event are presented in Table 3., and constituents detected in exceedance of their respective standard are presented in Table 4. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). Barium was detected at quantified concentrations above the MRL in all of the surface water samples during the November 2022 Monitoring Event. SW-2 also showed a quantified detections for zinc and 1,4 dioxane. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. 1,4-Dioxane was detected in exceedance of its ISTV for class WS-IV waters during this sampling event. There were no inorganic constituents detected at quantified concentrations above their respective NC2B Standards or ISTV during this sampling event. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 6 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for May 2023. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, p. 119 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2022 Water Quality Monitoring Report March 2023 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 Groundwater Elevations (November 2022) Hydraulic Gradients and Velocities (November 2022) Detected Constituents (November 2022) Exceedances of Standards (November 2021) Field Parameters (November 2022) TABLE 1: Groundwater Elevations (November 2022) Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 32.35 Saprolite 35.51 1087.47 MW-2 1077.23 26.75 Saprolite 45.25 1050.48 MW-3S 1022.76 5.77 Bedrock 26.95 1016.99 MW-3D 1021.90 0.00 Bedrock 76.15 1021.90 MW-4 1054.99 22.54 Saprolite 29.60 1032.45 MW-5 1137.43 41.12 Saprolite 50.80 1096.31 MW-6S 1065.00 9.74 Bedrock 27.56 1055.26 MW-6D 1065.00 11.7 Saprolite 63.15 1053.34 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Water Levels measured November 15, 2022 --- = well damaged, not sampled. Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 TABLE 2: Hydraulic Gradients and Velocities (November 2022) Water Levels Measured: November 15, 2022 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT ► HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1095 11 982 E 0.0713 3.28E+00 0.20 427 1025 1085 12 875 SE 0.0457 3.28E+00 0.20 274 1045 AVERAGE: 0.0536 AVERAGE: I 321 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V = Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detected Constituents (November 2022) SAMPLE ID PARAMETER RESULT METHOD MOIL I MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater Barium 159 EPA 6020B 0.67 5 700 NC21- pg/L Cobalt 9.4 EPA 6020B 0.39 5 1 NC2L pg/L Copper 3.8 J EPA 6020E 1 5 1000 NC21L pg/L Nickel 2.0 J EPA 6020E 0.71 5 100 NC21L pg/L MW-1 Zinc 47.3 EPA 6020B 7 10 1000 NC21L pg/L 11/15/2022 1,4-Dichlorobenzene 2.1 EPA 8260D 0.33 1 6 NC21L pg/L Acetone 246 EPA 8260D 5.1 25 6000 NC21L pg/L Benzene 0.89 J EPA 8260D 0.34 1 1 NC21L pg/L cis-1,2-Dichloroethene 0.72 J EPA 8260D 0.38 1 1 70 NC21L pg/L Antimony 1.1 J EPA 6020E 0.78 3 1 NC21L pg/L Barium 1400 EPA 6020B 3.4 25 700 NC2L pg/L Chromium 1.8 J EPA 6020E 1.1 5 10 NC21L pg/L Cobalt 108 EPA 6020B 0.39 5 1 IMAC pg/L Nickel 17.7 EPA 6020E 0.71 5 100 NC21L pg/L Vanadium 2.1 J EPA 6020E 1.9 10 0.3 IMAC pg/L 1,1-Dichloroethane 0.43 J EPA 8260D 0.37 1 6 NC21L pg/L MW-2 1,2-Dichlorobenzene 2.1 EPA 8260D 0.34 1 20 NC21L pg/L 11/14/2022 1,4-Dichlorobenzene 37.3 EPA 8260D 0.33 1 6 NC2L pg/L 1,4-Dioxane (p-Dioxane) 256 EPA 8260D Mod. 4.3 10 3 NC2L pg/L Benzene 7.8 EPA 8260D 0.34 1 1 NC2L pg/L Chlorobenzene 27.5 EPA 8260D 0.28 1 50 NC21L pg/L Ethylbenzene 7.1 EPA 8260D 0.3 1 600 NC21L pg/L Toluene 0.84 J EPA 8260D 0.24 1 600 NC21L pg/L Xylene (Total) 13.6 EPA 8260D 0.34 1 500 NC21L pg/L Barium 495 EPA 6020E 0.67 5 700 NC21L pg/L Cobalt 14.7 EPA 6020B 0.39 5 1 NC2L pg/L Nickel 3.4 J EPA 6020E 0.71 5 100 NC21L pg/L 1,2-Dichlorobenzene 0.53 J EPA 8260D 0.34 1 20 NC21L pg/L MW-3S 1,4-Dichlorobenzene 9.9 EPA 8260D 0.33 1 6 NC2L pg/L 11/14/2022 1,4-Dioxane (p-Dioxane) 31.9 EPA 8260D Mod. 0.86 2 3 NC2L pg/L Benzene 3.4 EPA 8260D 0.34 1 1 NC2L pg/L Chlorobenzene 30 EPA 8260D 0.28 1 50 NC21L pg/L Chloroethane 0.9 J EPA 8260D 0.65 1 3000 NC21L pg/L Xylene (Total) 25.3 EPA 8260D 0.34 1 1 500 NC21L pg/L Barium 215 EPA 6020E 0.67 5 700 NC21L pg/L Cobalt 1.1 J EPA 6020E 0.39 5 1 NC21L pg/L Copper 1.8 J EPA 6020E 1 5 1000 NC21L pg/L Nickel 28.7 EPA 6020E 0.71 5 100 NC21L pg/L 1,1-Dichloroethane 5.1 EPA 8260D 0.37 1 6 NC21L pg/L 1,2-Dichloropropane 0.67 J EPA 8260D 0.36 1 0.6 NC21L pg/L 1,4-Dichlorobenzene 3.8 EPA 8260D 0.33 1 6 NC21L pg/L MW-3D 1,4-Dioxane (p-Dioxane) 96.7 EPA 8260D Mod. 1.7 4 3 NC2L pg/L 11/14/2022 Benzene 1.4 EPA 8260D 0.34 1 1 NC2L pg/L Chlorobenzene 8.9 EPA 8260D 0.28 1 50 NC21L pg/L cis-1,2-Dichloroethene 25.3 EPA 8260D 0.38 1 70 NC21L pg/L Tetrachloroethene 8.4 EPA 8260D 0.29 1 0.7 NC2L pg/L Trichloroethene 6.2 EPA 8260D 0.38 1 1 3 NC2L pg/L Vinyl chloride 1.2 EPA 8260D 0.39 1 0.03 NC2L pg/L Barium 81.6 EPA 6020E 0.67 5 700 NC21L pg/L Chromium 1.3 J EPA 6020E 1.1 5 10 NC21L pg/L Cobalt 0.68 J EPA 6020E 0.39 5 1 NC21L pg/L Copper 1.1 J EPA 6020E 1 5 1000 NC21L pg/L MW-4 Nickel 1.6 J EPA 6020B 0.71 5 100 NC21L pg/L 11/14/2022 1,1-Dichloroethane 0.54 J EPA 8260D 0.37 1 6 NC21L pg/L 1,4-Dioxane (p-Dioxane) 1.3 J EPA 8260D Mod. 0.86 2 3 NC21L pg/L cis-1,2-Dichloroethene 4.9 EPA 8260D 0.38 1 70 NC21L pg/L Tetrachloroethene 0.47 J EPA 8260D 0.29 1 1 0.7 NC21L pg/L MW-5 Barium 25.9 EPA 6020E 0.67 5 700 NC2L pg/L 11/14/2022 Cobalt 0.63 J EPA 6020B 0.39 5 1 NC2L pg/L Barium 48.4 EPA 6020E 0.67 5 700 NC21L pg/L MW-6S Cobalt 0.99 J EPA 6020E 0.39 5 1 NC2L pg/L 11/15/2022 Nickel 8.0 EPA 6020B 0.71 5 1 100 NC2L pg/L Chloroform 1 0.81 -11 EPA 8260D 0.43 70 1 NC2L pg/L MW-6D Barium 1 14 1 EPA 6020B 0.67 5 700 1 NC21L pg/L 1 11/15/2022 Burke Co. - Kirksey Dr. Landfill Permit # 12-01 1 of 2 LaBelle Associates TABLE 3: Detected Constituents (November 2022) SAMPLE ID PARAMETER RESULT METHOD MOIL MRL STANDARD SOURCE UNITS COLLECT DATE Surface Water SW-1 Barium 36.3 EPA 6020E 0.67 5 1000 NC2B pg/L 11/14/2022 Barium 221 EPA 6020E 0.67 5 5 1000 NC2B pg/L Chromium 1.5 J EPA 6020E 1.1 23.81 NC2B* pg/L Cobalt 1.8 J EPA 6020E 0.39 5 3 ISTV pg/L SW-2 Copper 2.9 J EPA 6020E 1 5 2.74 NC2B* pg/L 11/14/2022 Nickel 3.4 J EPA 6020E 0.71 5 16.1 NC2B* pg/L Zinc 16.4 EPA 6020E 7 10 36.2 NC2B* pg/L 1,4-Dioxane (p-Dioxane) 2.3 EPA 8260D Mod. 0.86 2 0.35 ISTV pg/L SW-3 Barium 37.3 EPA 6020B 0.67 5 1000 NC2B pg/L 11/14/2022 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank -qualified data due to detections in trip, field, or method blanks. NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 NC2B = NC Surface Water Standard from15A NCAC 2B (NC213* =hardness -dependent standard) ISTV = NC In -Stream Target Values NRWQC = EPA's National Recommended Water Quality Criteria Bold = Quantified detections above the Standard Burke Go. - Kirksey Dr. Landfill Permit # 12-01 2 of 2 La Bella Associates TABLE 4: Exceedances of Standards (November 2022) SAMPLE ID PARAMETER RESULT METHOD I MOIL MRL STANDARD SOURCE UNITS COLLECT DATE Groundwater MW-1 Cobalt 9.4 EPA 6020B 0.39 5 1 NC2L pg/L 11/15/2022 Barium 1400 EPA 6020B 3.4 25 700 NC2L pg/L Cobalt 108 EPA 6020B 0.39 5 1 NC2L pg/L MW-2 1,4-Dichlorobenzene 37.3 EPA 8260D 0.33 1 6 NC2L pg/L 11/14/2022 1,4-Dioxane (p-Dioxane) 256 EPA 8260D Mod. 4.3 10 3 NC2L pg/L Benzene 7.8 EPA 8260D 0.34 1 1 NC2L pg/L Cobalt 14.7 EPA 6020B 0.39 5 1 NC2L pg/L 1,4-Dichlorobenzene 9.9 EPA 8260D 0.33 1 6 NC2L pg/L MW 3S 11/14/2022 1,4-Dioxane (p-Dioxane) 31.9 EPA 8260D Mod. 0.86 2 3 NC2L pg/L Benzene 3.4 EPA 8260D 0.34 1 1 NC2L pg/L 1,4-Dioxane (p-Dioxane) 96.7 EPA 8260D Mod. 1.7 4 3 NC2L pg/L Benzene 1.4 EPA 8260D 0.34 1 1 NC2L pg/L MW-3D Tetrachloroethene 8.4 EPA 8260D 0.29 1 0.7 NC2L pg/L 11/14/2022 Trichloroethene 6.2 EPA 8260D 0.38 1 3 NC2L pg/L Vinyl chloride 1.2 EPA 8260D 0.39 1 0.03 NC2L pg/L Surface Water SW-2 1,4-Dioxane (p-Dioxane) 2.3 EPA 8260D Mod. 1 0.86 2 0.35 ISTV pg/L 11/14/2022 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit MRL = Method Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 ISTV = NC In -Stream Target Values Burke Co. - Kirksey Dr. Landfill Permit # 12-01 LaBella Associates TABLE 5: Field Parameters (November 2022) Parameter Units Sample Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) SW-1 SW-2 SW-3 Well Depth Ft. 11/14/2022 35.51 45.25 26.95 76.15 24.60 50.8 27.56 63.15 -- -- -- pH S.U. 11/14/2022 5.37 5.6 6.37 5.65 7.18 6.70 5.60 6.00 7.30 6.80 6.80 Temperature °C 11/14/2022 13.60 15.3 15.7 15.8 14.6 14.3 14.7 13.9 10.3 9.5 10.4 Conductivity pS/cm 11/14/2022 690 2535 973 916 110.6 23.5 76.7 100.3 189.2 523.9 106.9 Dissolved Oxygen mg/L 11/14/2022 4.84 1.2 1.66 52.27 1.9 7 4.10 3.40 8.6 9.43 8.7 Oxidation Reduction Potential my 11/14/2022 54.20 -228.5 -211.8 -250.7 -211.8 -159.7 131.8 45.2 -154.0 -202 164.7 Turbidity NTU 11/14/2022 50.10 11.3 11.4 4.50 14.3 21.5 9.0 1.90 20.50 6.10 22.10 Static Water Level Ft. 11/14/2022 32.35 26.75 1 5.77 1 0.00 1 22.54 1 41.12 1 9.74 1 11.7 - - - Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet NS = Not sampled due to broken casing Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map ------ tj 16V 1000 CP APPROXIMATE LOCATION OF PROPERTY LINE i---------- rx X, IF lef' 44,0 .10410 ISSUED FOR: 03 LaBeRa GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: DRAWN BY: DATE: PROJECT NO.: SITE LOCATION MAP RVVH 02/27/19 2192621 2211 WEST MEADOW'VIEW ROAD GREENSBORO, N.C. 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL 1 labellapc.com (D 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\Pwgs\Drawhgs—rui­nt\8URKE\GW EVENT MAPS\, SITE LOCATION MAP KIRKSEY DRIVE 2020.4wg DRAWING Drawing 1 Groundwater Potentiometric Surface Map (November 2022) 1 MW-2 1050.48 SMP-2 1021.9 / / 1� I 1 I I SMP-3 0 z u') \ I ' 2\ \ 02V 1' 11101 .0000. /� � j M /I o 1 tk� O M -4 / 1032. 5 \ � MW-6S / 1055.26/ W-6D — 053.34 \� MW-1 / 10�7.4Z- \ MW_5 709S O� � / / OS� 109 1_ I Pr,pl\ln 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING 20' TOPOGRAPHIC CONTOUR ,� 080 _ _ _ GROUNDWATER SURFACE CONTOUR [FEET ABOVE MEAN SEA LEVEL (AMSL)] PROPERTY LINE GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT OSEGMENT USED FOR GRADIENT CALCULATION 1 - MW-5 ELEV O SW-2 EXISTING ROAD / GRAPHI� SCALE 0 150 / 600 / ■ (FEET) N(1TP:C 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS MEASURED ON NOVEMBER 15, 2022. CENTERLINE OF STREAM GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION 4. BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, COMPLIANCE WELL LOCATION AND TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. IDENTIFICATION WITH STATIC WATER LEVEL ELEVATION (FEET AMSL) SURFACE MONITORING POINT LOCATION AND IDENTIFICATION FLOW PATH LENGTH Z1 982 LF 12 875 LF LaBeLLa Powered by partnership. 2211 WEST MEADOWVIEW, SUITE 101 GREENSBORO, NC 27407 (336) 323-0092 labellapc.com F T 7 L T F T o 2023 Leeella Assonietis KIRKSEY DRIVE LANDFILL BURKE COUNTY, NORTH CAROLINA NO. DATE'. DESCRIPTION: Revisions PROJECT NUMBER: 2212740.00 DRAWN BY: RH REVIEWED BY: EK ISSUED FOR: GROUNDWATER REPORT DATE: 03/08/23 DRAWING NAME: PERMIT NO. 12-01 GROUNDWATER POTENTIOMETRIC SURFACE MAP NOVEMBER 15, 2022 DRAWING NUMBER: 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data Appendix 1 Field Logs and Laboratory Analytical Reports DATE: 0. LaBelLa p, vip'ie, by_Pa'aner&r„p, GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: '=362oi �Z Well ID: Ind Sampler(s): ,�,Onri DotinovAnnk Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 2 inches 32.36 feet 3�. 6l feet 3.1.0 feet [DTB-DTW] gallons —' gallons = 1 1 5 gallons Actual Amount Purged/Bailed: U • gallons Purged with: ailer Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: 3 . 3w feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials tit�3 1 1 �.� q7D 5Z1• 6 -346-5 -,- 100D �e 0.3 Date of sample: �j INZ2 Before Sampling: OV-5 13.E 6.37 M L1 A4 51A.1 60.1 Comments (weather conditions, odor, color, silt, etc.): % hoes Signature: QA/QC Sign Off: Date: 1� I U� ZZ Date: n LaBe[La DATE:I! I(q k& GROUND WATER SAMPLING LOG Project Name: . - uk, ,. L Project No. /Task No.: ZZ2352q G n & Well ID: Z Sampler(s): YkAnv) . lVovaoyomk Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) 2 inches . 715 feet ii'S 2,5 feet M . 5 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = ' M gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = q • 05 gallons Actual Amount Purged/Bailed: q . 05 gallons Purged with: ail Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: ZIP . 96 feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 5.6 271AI-0 Lk.1 -331A 3.� 3• 0 HN 0 -2b .A t9.� . b I !A ,-7 16. S 5 . °I 7_121t. 0 `. (o IT k 9.1 I�LiI j04 6.0 s�s�-D -260.6 till Date of sample: I Imlm Before Sampling: 15'l i5.3 �.(0 2�,i3O I.Z -�Z�fi•�a tl."� Comments (weather conditions, odor, color, silt, etc.):_ % 6kkki Signati CITlM Date: 12./15-I u DATE: 1 ly 22 LaBetLa ,P GROUND WATER SAMPLING LOG Project Name: 'kike Co. -VG rV6aA Pt. 4 Project No. No.: 2223521 01 Well ID: A W - 3S 13 Sampler(s): lit e,n . DorwoA Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: 2 inches 6.77 feet Z( . T 5 feet 2k, k% feet [DTB-DTW] _ •'�� gallons gallons = 10.36 gallons �� • 31v gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials 0 125� 15 . � 5.1 533.0 M . 7 3.% > . 2 <3 3 �5 I301 15..9 D 1M.0 101.r3 lesut. -?so.i 6.90 MO 6 - 1� g3Lt. 0 q 1.0 -35&t 1 15 Z lb (� V"r3 16.0 G.b 1W.0 11). -2ki.ei 'AZ.(9 Date of sample: 1l iOda Before Sampling: k��� 9"I3 l.lol� -211.`b k1.'-k Comments (weather conditions, odor, color, silt, etc.): 7 �,,,*Vs Signature: QA/QC Sign Off: Date: It L 29 l 22 Date: 12 /1 S-tZ2- P,_ LaBelLa DATE: 6t Itg I pu.,.,,?J,�fi,,,, P,,.t,u�.,;r,,;; GROUND WATER SAMPLING LOG Project Name: 'B", (.a. - Ii.; AA,l eu Dr. L-V Project No. /Task No.: 2 Well ID: MW - 3D Sampler(s): Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches TO C, feet -1f� -1- feet 1�. 6 feet [DTB-DTW] 17--M gallons _ -------gallons = 3-7 ZA gallons 37. Zk gallons Purged with: Bailer uma Other: Sampled with: Bailer Other: Depth to Water before Sampling: i feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials (� tzm 16,p �.0°I g01.0 1��•7� _gks.i 5.l`6 OP/ 12,-g1 VZov% 1 5.(0 qN.0 i6%.0 -%0 A �i %q 2-A 31. vA 130 �5.40 5.6s %-o 1.5 Date of sample: Iv - Before Sampling: Comments (weather conditions, odor, color, silt, etc.): -7 b06kk\e5 Signature: QA/QC Sign Off: Date: l\ I Vg I zZ Date: I Z I Is ILZ- f1 LaBelLa DATE: 11 A L 122. puvyes�c by P<vfni ,P GROUND WATER SAMPLING LOG Project Name: IxTIAe. Go. - Li ksex, D,. LC Project No. /Task No.: 22Z3;29 b2 Well ID: Sampler(s): 11An a noyay,� Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): inches ZZ , 6�k feet %0 feet Dig feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 1 • Z gallons For 4" Well: WCT X 0.653 = — gallons For THREE Well Volumes: WV X 3 = 3 • (o gallons Actual Amount Purged/Bailed: 3 (O gallons Purged with: Bailer Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: 22. -7(D feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials o k363 1 ,3 'A •61 tZ3.1 50. 11i -3Z1 .1 3t .2 ILAj L� 15• `b -7Z.00 -3bk.9 L9•� '3.(o kqz\ 15.0 LA,46 gk.'L 13Z.0 --W,i0 L19.6 Date of sample: t\a Before Sampling: 15 0 1 .i� Z.1� 1l0•t� �.q� -N `b 1a-1,�3 Comments (weather conditions, odor, color, silt, etc.): 7 \Da-ykkes Signatu 1,l QA/QC Sign Off: `� l `10al�P�e C 1 Deis Date: l2 /. 15` f 2Z 11 La6elLa DATE: ttk22 oy ,,, GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: zu-5529 02 Well ID: AW Sampler(s): �e�� s Dohoim-sk Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): 2 inches Lit.IZ feet 50 • '50 feet 9 - 161- feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = t gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = ''{ gallons Actual Amount Purged/Bailed: >7allons Purged with: ail Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials (� t ZOO 14. q L. , 65 11.1 I3(o.gei -V-5.3 337 � IZIk M W-0 11,13 -3i2.ti 0i Date of sample: iAlv2 Before Sampling: ��Cl� 1�l•3 �.7 23.5 to -M.3 it •6 / Comments (weather conditions, odor, color, silt, etc.): `7 ba•thes Signature: QA/QC Sign Off: Date: tL l29 I ?&Z' Date: tZ IIS IZZ n LaB( Ua DATE: 111161n by poflnershlp. GROUND WATER SAMPLING LOG Project Nam'e:``aUckZ 6o. - I,'%rk�eu pc. Project No. /Task No.: ZZ Z 3529 w Well ID: A - 65 Sampler(s): i�ar 00A Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) 2 inches q • 7' feet 21.56 : feet 0 • `62 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = 2 gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = C 7 gallons Actual Amount Purged/Bailed: gallons Purged with: ailc� er �� Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials (� N61 15.Z. 5.`b '90.t 1.7 12.0 (.�Z U,'/, -7 5.'7 "60 .9 /00.6 41, 6 5.� DIN 16,5 5.6 _M6 3.Z t1-7.2- IM-0 1,7 0 � 67 t'J .7 5 . (o 76.7 q A mk ,% 1.0 Date of sample: Itbt -t Before Sampling: sample Tm� ui��1y Comments (weather conditions, odor, color, silt, etc.): 7 64kes QA/QC Sign Off: Date: Vt I ZM L ZZ Date: M /Ia&L DATE: i t 5 / ZZ LaBeUa po"Y.e,--Id by pa, 111C'-: ,-,,; GROUNDWATER SAMPLING LOG Project Name: Otxc4 6o � rlAscu Dr. UV Project No. /Task No.: �LL35�R O z Well ID: Sampler(s): �l�.r. _06vnovMr)� Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches 0 • (D feet 67- 6 feet 6t - q'� feet [DTB-DTW] gallons gallons Z�. Z gallons gallons Purged with: Bailer 6&;p Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (OC) pH (S.U.) Cond. (pS/cm) Dis.02 (mg/L) ORP (mV) Turb. (NTU) Initials D 0s3's `b ���� 13� •°1 lad t.7 1A l (4 Oifii t'31 6 . b 1 62. 0 7, Z 25 Z 0�53 131 OVI Date of sample: t4Ibi(z-z Before�r�e Sampling: Comments (weather conditions, odor, color, silt, etc.): -7 %tyAes Signature: QA/QC Sign Off: Date: M Z� t 22 Date: ,2I I S- /7_Z DATE: 0 I'-1 1 ZZ LaBetta SURFACE WATER MONITORING LOG Project Name: 3uAk,. �.�rlhSzeJl 17�. L Project/Task No.: ZZZ'_�Za (7L QD Surface Point ID: �W-'�i Sampler(s): ti.e1,r pon��ar Location: tnp5\,c amm o� `�AQ?_ 0Y\ oaka'( ,, �)V Field Parameters: Time of Sampling: 1� pH: � Temperature: fin+ 5 (0C) Conductivity: 'L (US/CM) Turbidity: Z0. 5 (ntu) Dissolved Oxygen `� �lb (mg/L) Oxidation -Reduction Potential '" 151k. (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): P,__T, LaBetta DATE: 11 11 `I Iv, Po•arexet1b a!tnership SURFACE WATER MONITORING/LOG Project Name: LX4z (- Project/Task No.: c.�52� (U� Surface Point ID: 5W - - Sampler(s): i�.Z �o novavc� Location: one,'( MW - '6J-;V Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential g .5 C) 5Z3 1 `'I (US/CM) 6• 9,�kl (ntu) (mg/L) ZD1z 0 (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): QA/QC Sign Off: UQ g� Date: 12/1_657ILZ DATE: Iti l a P,_ LaB< tta SURFACE WATER MONITORING/LOG Project Name: &r e (o �,q�4w Qv- U_r Project/Task No.: 02 Surface Point ID: 5W - 3 Sampler(s): Location: nmc MQ '�V ) 36 Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential 1565 Vs (US/CM) (ntu) . 7 (mg/L) (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): QA/QC Sign Off: �15Q� LWQ� Date: leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 27, 2022 Mr. Van Burbach LaBella Associates, D.P.C. 12-D Oak Branch Drive Greensboro, NC 27407 RE: Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on November 17, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, LaBella Associates, DPC Kandice Estes, Labella Associates Miguel Vazquez, Joyce Engineering Elina Wright, LaBella Associates, D.P.C. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 54 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification #: 460221 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Lab ID Sample ID Matrix Date Collected Date Received 92637353001 1201-MW1 Water 11/15/22 09:25 11/17/22 11:00 92637353002 1201-MW2 Water 11/14/2215:43 11/17/22 11:00 92637353003 1201-MW3s Water 11/14/2214:55 11/17/22 11:00 92637353004 1201-MW3D Water 11/14/2213:19 11/17/22 11:00 92637353005 1201-MW4 Water 11/14/2215:30 11/17/22 11:00 92637353006 1201-MW5 Water 11/14/2216:10 11/17/22 11:00 92637353007 1201-MW6S Water 11/15/22 09:07 11/17/22 11:00 92637353008 1201-MW6D Water 11/15/22 08:53 11/17/22 11:00 92637353009 1201-SW1 Water 11/14/2215:58 11/17/22 11:00 92637353010 1201-SW2 Water 11/14/2215:15 11/17/22 11:00 92637353011 1201-SW3 Water 11/14/2215:05 11/17/22 11:00 92637353012 1201-FIELD BLANK Water 11/15/22 09:30 11/17/22 11:00 92637353013 1201-TRIP BLANK Water 11/15/22 00:00 11/17/22 11:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: BURKE CO.-KIRKSEY DRIVE 92637353 Analytes Lab lD Sample ID Method Analysts Reported Laboratory 92637353001 1201-MW1 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353002 1201-MW2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353003 1201-MW3s EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353004 1201-MW3D EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353005 1201-MW4 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353006 1201-MW5 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353007 1201-MW6S EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353008 1201-MW6D EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353009 1201-SW1 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353010 1201-SW2 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353011 1201-SW3 EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353012 1201-FIELD BLANK EPA6020B CW1 15 PASI-GA EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92637353013 1201-TRIP BLANK EPA 8260D CL 50 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Analytes Lab lD Sample ID Method Analysts Reported Laboratory EPA 8260D Mod. LMB 3 PASI-C PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: BURKE CO.-KIRKSEY DRIVE 92637353 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92637353001 1201-MW1 EPA 6020B Barium 159 ug/L 5.0 12/22/22 12:57 EPA 6020B Cobalt 9.4 ug/L 5.0 12/22/22 12:57 EPA 6020B Copper 3.8J ug/L 5.0 12/22/22 12:57 EPA 6020B Nickel 2.OJ ug/L 5.0 12/22/22 12:57 EPA 6020B Zinc 47.3 ug/L 10.0 12/22/22 12:57 EPA8260D Acetone 246 ug/L 25.0 11/19/2210:55 EPA8260D Benzene 0.891 ug/L 1.0 11/19/2210:55 EPA8260D 1,4-Dichlorobenzene 2.1 ug/L 1.0 11/19/2210:55 EPA8260D cis-1,2-Dichloroethene 0.72J ug/L 1.0 11/19/2210:55 92637353002 1201-MW2 EPA 6020B Antimony 1.1 J ug/L 3.0 12/22/22 13:21 EPA 6020B Barium 1400 ug/L 25.0 12/23/22 14:24 EPA 6020B Chromium 1.8J ug/L 5.0 12/22/22 13:21 EPA 6020B Cobalt 108 ug/L 5.0 12/22/22 13:21 EPA 6020B Nickel 17.7 ug/L 5.0 12/22/22 13:21 EPA 6020B Vanadium 2.1 J ug/L 10.0 12/22/22 13:21 EPA8260D Benzene 7.8 ug/L 1.0 11/19/2213:20 EPA8260D Chlorobenzene 27.5 ug/L 1.0 11/19/2213:20 EPA8260D 1,2-Dichlorobenzene 2.1 ug/L 1.0 11/19/2213:20 EPA8260D 1,4-Dichlorobenzene 37.3 ug/L 1.0 11/19/2213:20 EPA8260D 1,1-Dichloroethane 0.43J ug/L 1.0 11/19/2213:20 EPA8260D Ethylbenzene 7.1 ug/L 1.0 11/19/2213:20 EPA8260D Toluene 0.84J ug/L 1.0 11/19/2213:20 EPA8260D Xylene(Total) 13.6 ug/L 1.0 11/19/2213:20 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 256 ug/L 10.0 11/18/22 23:52 92637353003 1201-MW3s EPA 6020B Barium 495 ug/L 5.0 12/22/22 13:27 EPA 6020B Cobalt 14.7 ug/L 5.0 12/22/22 13:27 EPA 6020B Nickel 3AJ ug/L 5.0 12/22/22 13:27 EPA8260D Benzene 3.4 ug/L 1.0 11/19/2212:25 EPA8260D Chlorobenzene 30.0 ug/L 1.0 11/19/2212:25 EPA8260D Chloroethane 0.901 ug/L 1.0 11/19/2212:25 EPA8260D 1,2-Dichlorobenzene 0.53J ug/L 1.0 11/19/2212:25 EPA8260D 1,4-Dichlorobenzene 9.9 ug/L 1.0 11/19/2212:25 EPA8260D Xylene(Total) 25.3 ug/L 1.0 11/19/2212:25 EPA8260D Mod. 1,4-Dioxane (p-Dioxane) 31.9 ug/L 2.0 11/18/22 18:46 92637353004 1201-MW3D EPA 6020B Barium 215 ug/L 5.0 12/22/22 13:33 EPA 6020B Cobalt 1.1 J ug/L 5.0 12/22/22 13:33 EPA 6020B Copper 1.8J ug/L 5.0 12/22/22 13:33 EPA 6020B Nickel 28.7 ug/L 5.0 12/22/22 13:33 EPA8260D Benzene 1.4 ug/L 1.0 11/19/2212:43 EPA8260D Chlorobenzene 8.9 ug/L 1.0 11/19/2212:43 EPA8260D 1,4-Dichlorobenzene 3.8 ug/L 1.0 11/19/2212:43 EPA8260D 1,1-Dichloroethane 5.1 ug/L 1.0 11/19/2212:43 EPA8260D cis-1,2-Dichloroethene 25.3 ug/L 1.0 11/19/2212:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Lab Sample ID Method Client Sample ID Parameters 92637353004 1201-MW3D EPA 8260D 1,2-Dichloropropane EPA 8260D Tetrachloroethene EPA 8260D Trichloroethene EPA 8260D Vinyl chloride EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92637353005 1201-MW4 EPA 6020B Barium EPA 6020B Chromium EPA 6020B Cobalt EPA 6020B Copper EPA 6020B Nickel EPA 8260D 1,1-Dichloroethane EPA 8260D cis-1,2-Dichloroethene EPA 8260D Tetrachloroethene EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92637353006 1201-MW5 EPA 6020B Barium EPA 6020B Cobalt 92637353007 1201-MW6S EPA 6020B Barium EPA 6020B Cobalt EPA 6020B Nickel EPA 8260D Chloroform 92637353008 1201-MW6D EPA 6020B Barium 92637353009 1201-SW1 EPA 6020B Barium 92637353010 1201-SW2 EPA 6020B Barium EPA 6020B Chromium EPA 6020B Cobalt EPA 6020B Copper EPA 6020B Nickel EPA 6020B Zinc EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 92637353011 1201-SW3 EPA 6020B Barium SUMMARY OF DETECTION Result Units Report Limit Analyzed 0.67J ug/L 1.0 11/19/2212:43 8.4 ug/L 1.0 11/19/2212:43 6.2 ug/L 1.0 11/19/2212:43 1.2 ug/L 1.0 11/19/2212:43 96.7 ug/L 4.0 11/18/22 23:33 81.6 ug/L 5.0 12/22/2213:39 1.3J ug/L 5.0 12/22/2213:39 0.68J ug/L 5.0 12/22/2213:39 1.1 J ug/L 5.0 12/22/22 13:39 1.6J ug/L 5.0 12/22/2213:39 0.54J ug/L 1.0 11/19/2210:00 4.9 ug/L 1.0 11/19/2210:00 0.47J ug/L 1.0 11/19/2210:00 1.3J ug/L 2.0 11/18/2219:05 25.9 ug/L 5.0 12/22/2213:57 0.63J ug/L 5.0 12/22/2213:57 48.4 ug/L 5.0 12/22/2214:03 0.991 ug/L 5.0 12/22/2214:03 8.0 ug/L 5.0 12/22/2214:03 0.81J ug/L 1.0 11/19/2211:13 14.0 ug/L 5.0 12/22/2214:09 36.3 ug/L 5.0 12/22/2214:15 221 ug/L 5.0 12/22/2214:21 1.5J ug/L 5.0 12/22/2214:21 1.8J ug/L 5.0 12/22/2214:21 2.9J ug/L 5.0 12/22/2214:21 3AJ ug/L 5.0 12/22/2214:21 16.4 ug/L 10.0 12/22/2214:21 2.3 ug/L 2.0 11/18/22 20:03 37.3 ug/L 5.0 12/22/2214:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 7 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW1 Lab ID: 92637353001 Collected: 11/15/22 09:25 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2212:57 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2212:57 7440-38-2 Barium 159 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2212:57 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2212:57 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2212:57 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2212:57 7440-47-3 Cobalt 9.4 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2212:57 7440-48-4 Copper 3.8J ug/L 5.0 1.0 1 12/14/2213:25 12/22/2212:57 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2212:57 7439-92-1 Nickel 2.0.1 ug/L 5.0 0.71 1 12/14/2213:25 12/22/2212:57 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2212:57 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2212:57 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2212:57 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2212:57 7440-62-2 Zinc 47.3 ug/L 10.0 7.0 1 12/14/2213:25 12/22/2212:57 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 246 ug/L 25.0 5.1 1 11/19/22 10:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 10:55 107-13-1 Benzene 0.891 ug/L 1.0 0.34 1 11/19/22 10:55 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 10:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 10:55 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 10:55 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 10:55 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 10:55 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 10:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 10:55 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 10:55 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 10:55 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 10:55 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 10:55 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 10:55 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 10:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 10:55 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 10:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 10:55 95-50-1 1,4-Dichlorobenzene 2.1 ug/L 1.0 0.33 1 11/19/22 10:55 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 10:55 110-57-6 v2 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 10:55 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 10:55 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 10:55 75-35-4 cis-1,2-Dichloroethene 0.72J ug/L 1.0 0.38 1 11/19/22 10:55 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 10:55 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 10:55 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW1 Lab ID: 92637353001 Collected: 11/15/22 09:25 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 97 % 70-130 99 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 104 % 70-130 106 % 70-130 0.36 1 11 /19/22 10:55 10061-01-5 0.36 1 11 /19/22 10:55 10061-02-6 0.30 1 11 /19/22 10:55 100-41-4 0.48 1 11 /19/22 10:55 591-78-6 9.7 1 11/19/2210:55 74-88-4 2.0 1 11/19/2210:55 75-09-2 2.7 1 11 /19/22 10:55 108-10-1 0.29 1 11 /19/22 10:55 100-42-5 0.31 1 11/19/2210:55 630-20-6 0.22 1 11/19/2210:55 79-34-5 0.29 1 11 /19/22 10:55 127-18-4 0.24 1 11 /19/22 10:55 108-88-3 0.33 1 11 /19/22 10:55 71-55-6 0.32 1 11/19/2210:55 79-00-5 0.38 1 11 /19/22 10:55 79-01-6 0.30 1 11/19/2210:55 75-69-4 0.26 1 11/19/2210:55 96-18-4 1.3 1 11 /19/22 10:55 108-05-4 0.39 1 11 /19/22 10:55 75-01-4 0.34 1 11 /19/22 10:55 1330-20-7 1 11/19/2210:55 460-00-4 1 11 /19/22 10:55 17060-07-0 1 11/19/2210:55 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 20:41 123-91-1 11/18/22 20:41 17060-07-0 11/18/22 20:41 2037-26-5 Page 9 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW2 Lab ID: 92637353002 Collected: 11/14/22 15:43 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony 1.1J ug/L 3.0 0.78 1 12/14/2213:25 12/22/2213:21 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2213:21 7440-38-2 Barium 1400 ug/L 25.0 3.4 5 12/14/2213:25 12/23/2214:24 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2213:21 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2213:21 7440-43-9 Chromium 1.81 ug/L 5.0 1.1 1 12/14/2213:25 12/22/2213:21 7440-47-3 Cobalt 108 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2213:21 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2213:21 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2213:21 7439-92-1 Nickel 17.7 ug/L 5.0 0.71 1 12/14/2213:25 12/22/2213:21 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2213:21 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2213:21 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2213:21 7440-28-0 Vanadium 2.1J ug/L 10.0 1.9 1 12/14/2213:25 12/22/2213:21 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2213:21 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 13:20 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 13:20 107-13-1 Benzene 7.8 ug/L 1.0 0.34 1 11/19/22 13:20 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 13:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 13:20 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 13:20 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 13:20 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 13:20 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 13:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 13:20 56-23-5 Chlorobenzene 27.5 ug/L 1.0 0.28 1 11/19/22 13:20 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 13:20 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 13:20 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 13:20 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 13:20 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 13:20 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 13:20 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 13:20 74-95-3 1,2-Dichlorobenzene 2.1 ug/L 1.0 0.34 1 11/19/22 13:20 95-50-1 1,4-Dichlorobenzene 37.3 ug/L 1.0 0.33 1 11/19/22 13:20 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 13:20 110-57-6 1,1-Dichloroethane 0.43J ug/L 1.0 0.37 1 11/19/22 13:20 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 13:20 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 13:20 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 13:20 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 13:20 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 13:20 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW2 Lab ID: 92637353002 Collected: 11/14/22 15:43 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.36 1 11 /19/22 13:20 10061-01-5 ND ug/L 1.0 0.36 1 11/19/2213:20 10061-02-6 7.1 ug/L 1.0 0.30 1 11/19/2213:20 100-41-4 ND ug/L 5.0 0.48 1 11/19/2213:20 591-78-6 ND ug/L 20.0 9.7 1 11/19/2213:20 74-88-4 ND ug/L 5.0 2.0 1 11/19/2213:20 75-09-2 ND ug/L 5.0 2.7 1 11/19/2213:20 108-10-1 ND ug/L 1.0 0.29 1 11/19/2213:20 100-42-5 ND ug/L 1.0 0.31 1 11/19/2213:20 630-20-6 ND ug/L 1.0 0.22 1 11/19/2213:20 79-34-5 ND ug/L 1.0 0.29 1 11/19/2213:20 127-18-4 0.84.1 ug/L 1.0 0.24 1 11/19/2213:20 108-88-3 ND ug/L 1.0 0.33 1 11/19/2213:20 71-55-6 ND ug/L 1.0 0.32 1 11/19/2213:20 79-00-5 ND ug/L 1.0 0.38 1 11/19/2213:20 79-01-6 ND ug/L 1.0 0.30 1 11/19/2213:20 75-69-4 ND ug/L 1.0 0.26 1 11/19/2213:20 96-18-4 ND ug/L 2.0 1.3 1 11/19/2213:20 108-05-4 ND ug/L 1.0 0.39 1 11/19/2213:20 75-01-4 13.6 ug/L 1.0 0.34 1 11/19/2213:20 1330-20-7 96 % 70-130 1 11/19/2213:20 460-00-4 96 % 70-130 1 11/19/2213:20 17060-07-0 99 % 70-130 1 11/19/2213:20 2037-26-5 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 256 ug/L 10.0 4.3 5 11/18/22 23:52 123-91-1 97 % 70-130 5 11/18/22 23:52 17060-07-0 98 % 70-130 5 11/18/22 23:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW3s Lab ID: 92637353003 Collected: 11/14/22 14:55 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2213:27 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2213:27 7440-38-2 Barium 495 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2213:27 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2213:27 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2213:27 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2213:27 7440-47-3 Cobalt 14.7 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2213:27 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2213:27 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2213:27 7439-92-1 Nickel 3.4J ug/L 5.0 0.71 1 12/14/2213:25 12/22/2213:27 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2213:27 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2213:27 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2213:27 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2213:27 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2213:27 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 12:25 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 12:25 107-13-1 Benzene 3.4 ug/L 1.0 0.34 1 11/19/22 12:25 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 12:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 12:25 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 12:25 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 12:25 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 12:25 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 12:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 12:25 56-23-5 Chlorobenzene 30.0 ug/L 1.0 0.28 1 11/19/22 12:25 108-90-7 Chloroethane 0.901 ug/L 1.0 0.65 1 11/19/22 12:25 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 12:25 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 12:25 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 12:25 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 12:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 12:25 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 12:25 74-95-3 1,2-Dichlorobenzene 0.53J ug/L 1.0 0.34 1 11/19/22 12:25 95-50-1 1,4-Dichlorobenzene 9.9 ug/L 1.0 0.33 1 11/19/22 12:25 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 12:25 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 12:25 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 12:25 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 12:25 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 12:25 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 12:25 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 12:25 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW3s Lab ID: 92637353003 Collected: 11/14/22 14:55 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 25.3 ug/L 1.0 97 % 70-130 98 % 70-130 100 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 31.9 ug/L 2.0 79 % 70-130 96 % 70-130 0.36 1 11 /19/22 12:25 10061-01-5 0.36 1 11 /19/22 12:25 10061-02-6 0.30 1 11 /19/22 12:25 100-41-4 0.48 1 11 /19/22 12:25 591-78-6 9.7 1 11/19/2212:25 74-88-4 2.0 1 11/19/2212:25 75-09-2 2.7 1 11 /19/22 12:25 108-10-1 0.29 1 11 /19/22 12:25 100-42-5 0.31 1 11/19/2212:25 630-20-6 0.22 1 11/19/2212:25 79-34-5 0.29 1 11 /19/22 12:25 127-18-4 0.24 1 11 /19/22 12:25 108-88-3 0.33 1 11 /19/22 12:25 71-55-6 0.32 1 11/19/2212:25 79-00-5 0.38 1 11 /19/22 12:25 79-01-6 0.30 1 11/19/2212:25 75-69-4 0.26 1 11/19/2212:25 96-18-4 1.3 1 11 /19/22 12:25 108-05-4 0.39 1 11 /19/22 12:25 75-01-4 0.34 1 11 /19/22 12:25 1330-20-7 1 11/19/2212:25 460-00-4 1 11 /19/22 12:25 17060-07-0 1 11/19/2212:25 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 /18/22 18:46 123-91-1 11 /18/22 18:46 17060-07-0 11/18/2218:46 2037-26-5 Page 13 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW3D Lab ID: 92637353004 Collected: 11/14/22 13:19 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2213:33 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2213:33 7440-38-2 Barium 215 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2213:33 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2213:33 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2213:33 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2213:33 7440-47-3 Cobalt 1.1.1 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2213:33 7440-48-4 Copper 1.81 ug/L 5.0 1.0 1 12/14/2213:25 12/22/2213:33 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2213:33 7439-92-1 Nickel 28.7 ug/L 5.0 0.71 1 12/14/2213:25 12/22/2213:33 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2213:33 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2213:33 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2213:33 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2213:33 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2213:33 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 12:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 12:43 107-13-1 Benzene 1.4 ug/L 1.0 0.34 1 11/19/22 12:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 12:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 12:43 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 12:43 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 12:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 12:43 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 12:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 12:43 56-23-5 Chlorobenzene 8.9 ug/L 1.0 0.28 1 11/19/22 12:43 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 12:43 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 12:43 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 12:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 12:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 12:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 12:43 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 12:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 12:43 95-50-1 1,4-Dichlorobenzene 3.8 ug/L 1.0 0.33 1 11/19/22 12:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 12:43 110-57-6 1,1-Dichloroethane 5.1 ug/L 1.0 0.37 1 11/19/22 12:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 12:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 12:43 75-35-4 cis-1,2-Dichloroethene 25.3 ug/L 1.0 0.38 1 11/19/22 12:43 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 12:43 156-60-5 1,2-Dichloropropane 0.67J ug/L 1.0 0.36 1 11/19/22 12:43 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW3D Lab ID: 92637353004 Collected: 11/14/22 13:19 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 8.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 1.2 ug/L 1.0 ND ug/L 1.0 97 % 70-130 99 % 70-130 99 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 96.7 ug/L 4.0 99 % 70-130 99 % 70-130 0.36 1 11 /19/22 12:43 10061-01-5 0.36 1 11 /19/22 12:43 10061-02-6 0.30 1 11 /19/22 12:43 100-41-4 0.48 1 11 /19/22 12:43 591-78-6 9.7 1 11/19/2212:43 74-88-4 2.0 1 11/19/2212:43 75-09-2 2.7 1 11 /19/22 12:43 108-10-1 0.29 1 11 /19/22 12:43 100-42-5 0.31 1 11/19/2212:43 630-20-6 0.22 1 11/19/2212:43 79-34-5 0.29 1 11 /19/22 12:43 127-18-4 0.24 1 11 /19/22 12:43 108-88-3 0.33 1 11 /19/22 12:43 71-55-6 0.32 1 11/19/2212:43 79-00-5 0.38 1 11 /19/22 12:43 79-01-6 0.30 1 11/19/2212:43 75-69-4 0.26 1 11/19/2212:43 96-18-4 1.3 1 11 /19/22 12:43 108-05-4 0.39 1 11 /19/22 12:43 75-01-4 0.34 1 11 /19/22 12:43 1330-20-7 1 11/19/2212:43 460-00-4 1 11 /19/22 12:43 17060-07-0 1 11/19/2212:43 2037-26-5 1.7 2 2 2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 23:33 123-91-1 11/18/22 23:33 17060-07-0 11/18/22 23:33 2037-26-5 Page 15 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW4 Lab ID: 92637353005 Collected: 11/14/22 15:30 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2213:39 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2213:39 7440-38-2 Barium 81.6 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2213:39 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2213:39 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2213:39 7440-43-9 Chromium 1.3J ug/L 5.0 1.1 1 12/14/2213:25 12/22/2213:39 7440-47-3 Cobalt 0.68J ug/L 5.0 0.39 1 12/14/2213:25 12/22/2213:39 7440-48-4 Copper 1.1.1 ug/L 5.0 1.0 1 12/14/2213:25 12/22/2213:39 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2213:39 7439-92-1 Nickel 1.6.1 ug/L 5.0 0.71 1 12/14/2213:25 12/22/2213:39 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2213:39 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2213:39 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2213:39 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2213:39 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2213:39 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 10:00 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 10:00 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 10:00 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 10:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 10:00 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 10:00 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 10:00 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 10:00 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 10:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 10:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 10:00 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 10:00 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 10:00 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 10:00 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 10:00 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 10:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 10:00 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 10:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 10:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 10:00 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 10:00 110-57-6 1,1-Dichloroethane 0.54J ug/L 1.0 0.37 1 11/19/22 10:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 10:00 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 10:00 75-35-4 cis-1,2-Dichloroethene 4.9 ug/L 1.0 0.38 1 11/19/22 10:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 10:00 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 10:00 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW4 Lab ID: 92637353005 Collected: 11/14/22 15:30 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.47J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 96 % 70-130 96 % 70-130 99 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1.3J ug/L 2.0 82 % 70-130 100 % 70-130 0.36 1 11 /19/22 10:00 10061-01-5 0.36 1 11 /19/22 10:00 10061-02-6 0.30 1 11 /19/22 10:00 100-41-4 0.48 1 11 /19/22 10:00 591-78-6 9.7 1 11/19/2210:00 74-88-4 2.0 1 11/19/2210:00 75-09-2 2.7 1 11 /19/22 10:00 108-10-1 0.29 1 11 /19/22 10:00 100-42-5 0.31 1 11/19/2210:00 630-20-6 0.22 1 11/19/2210:00 79-34-5 0.29 1 11 /19/22 10:00 127-18-4 0.24 1 11 /19/22 10:00 108-88-3 0.33 1 11 /19/22 10:00 71-55-6 0.32 1 11/19/2210:00 79-00-5 0.38 1 11 /19/22 10:00 79-01-6 0.30 1 11/19/2210:00 75-69-4 0.26 1 11/19/2210:00 96-18-4 1.3 1 11 /19/22 10:00 108-05-4 0.39 1 11 /19/22 10:00 75-01-4 0.34 1 11 /19/22 10:00 1330-20-7 1 11/19/2210:00 460-00-4 1 11 /19/22 10:00 17060-07-0 1 11/19/2210:00 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 /18/22 19:05 123-91-1 11 /18/22 19:05 17060-07-0 11/18/2219:05 2037-26-5 Page 17 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW5 Lab ID: 92637353006 Collected: 11/14/22 16:10 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2213:57 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2213:57 7440-38-2 Barium 25.9 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2213:57 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2213:57 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2213:57 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2213:57 7440-47-3 Cobalt 0.63J ug/L 5.0 0.39 1 12/14/2213:25 12/22/2213:57 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2213:57 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2213:57 7439-92-1 Nickel ND ug/L 5.0 0.71 1 12/14/2213:25 12/22/2213:57 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2213:57 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2213:57 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2213:57 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2213:57 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2213:57 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 10:18 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 10:18 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 10:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 10:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 10:18 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 10:18 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 10:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 10:18 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 10:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 10:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 10:18 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 10:18 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 10:18 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 10:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 10:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 10:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 10:18 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 10:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 10:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 10:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 10:18 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 10:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 10:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 10:18 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 10:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 10:18 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 10:18 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW5 Lab ID: 92637353006 Collected: 11/14/22 16:10 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 98 % 70-130 96 % 70-130 99 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 90 % 70-130 106 % 70-130 0.36 1 11 /19/22 10:18 10061-01-5 0.36 1 11 /19/22 10:18 10061-02-6 0.30 1 11 /19/22 10:18 100-41-4 0.48 1 11 /19/22 10:18 591-78-6 9.7 1 11/19/2210:18 74-88-4 2.0 1 11/19/2210:18 75-09-2 2.7 1 11 /19/22 10:18 108-10-1 0.29 1 11 /19/22 10:18 100-42-5 0.31 1 11/19/2210:18 630-20-6 0.22 1 11/19/2210:18 79-34-5 0.29 1 11 /19/22 10:18 127-18-4 0.24 1 11 /19/22 10:18 108-88-3 0.33 1 11 /19/22 10:18 71-55-6 0.32 1 11/19/2210:18 79-00-5 0.38 1 11 /19/22 10:18 79-01-6 0.30 1 11/19/2210:18 75-69-4 0.26 1 11/19/2210:18 96-18-4 1.3 1 11 /19/22 10:18 108-05-4 0.39 1 11 /19/22 10:18 75-01-4 0.34 1 11 /19/22 10:18 1330-20-7 1 11/19/2210:18 460-00-4 1 11 /19/22 10:18 17060-07-0 1 11/19/2210:18 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 /18/22 19:25 123-91-1 11 /18/22 19:25 17060-07-0 11/18/2219:25 2037-26-5 Page 19 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW6S Lab ID: 92637353007 Collected: 11/15/22 09:07 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:03 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:03 7440-38-2 Barium 48.4 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:03 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:03 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:03 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:03 7440-47-3 Cobalt 0.991 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:03 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:03 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:03 7439-92-1 Nickel 8.0 ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:03 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:03 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:03 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:03 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:03 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:03 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 11:13 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 11:13 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 11:13 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 11:13 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 11:13 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 11:13 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 11:13 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 11:13 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 11:13 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 11:13 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 11:13 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 11:13 75-00-3 Chloroform 0.811 ug/L 1.0 0.43 1 11/19/22 11:13 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 11:13 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 11:13 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 11:13 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 11:13 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 11:13 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 11:13 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 11:13 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 11:13 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 11:13 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 11:13 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 11:13 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 11:13 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 11:13 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 11:13 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW6S Lab ID: 92637353007 Collected: 11/15/22 09:07 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 96 % 70-130 100 % 70-130 99 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 96 % 70-130 105 % 70-130 0.36 1 11 /19/22 11:13 10061-01-5 0.36 1 11 /19/22 11:13 10061-02-6 0.30 1 11 /19/22 11:13 100-41-4 0.48 1 11 /19/22 11:13 591-78-6 9.7 1 11/19/2211:13 74-88-4 2.0 1 11/19/2211:13 75-09-2 2.7 1 11 /19/22 11:13 108-10-1 0.29 1 11 /19/22 11:13 100-42-5 0.31 1 11/19/2211:13 630-20-6 0.22 1 11/19/2211:13 79-34-5 0.29 1 11 /19/22 11:13 127-18-4 0.24 1 11 /19/22 11:13 108-88-3 0.33 1 11 /19/22 11:13 71-55-6 0.32 1 11/19/2211:13 79-00-5 0.38 1 11 /19/22 11:13 79-01-6 0.30 1 11/19/2211:13 75-69-4 0.26 1 11/19/2211:13 96-18-4 1.3 1 11 /19/22 11:13 108-05-4 0.39 1 11 /19/22 11:13 75-01-4 0.34 1 11 /19/22 11:13 1330-20-7 1 11/19/2211:13 460-00-4 1 11 /19/22 11:13 17060-07-0 1 11/19/2211:13 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 21:00 123-91-1 11/18/22 21:00 17060-07-0 11/18/22 21:00 2037-26-5 Page 21 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW6D Lab ID: 92637353008 Collected: 11/15/22 08:53 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:09 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:09 7440-38-2 Barium 14.0 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:09 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:09 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:09 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:09 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:09 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:09 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:09 7439-92-1 Nickel ND ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:09 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:09 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:09 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:09 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:09 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:09 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 11:31 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 11:31 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 11:31 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 11:31 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 11:31 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 11:31 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 11:31 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 11:31 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 11:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 11:31 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 11:31 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 11:31 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 11:31 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 11:31 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 11:31 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 11:31 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 11:31 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 11:31 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 11:31 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 11:31 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 11:31 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 11:31 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 11:31 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 11:31 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 11:31 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 11:31 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 11:31 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-MW6D Lab ID: 92637353008 Collected: 11/15/22 08:53 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 98 % 70-130 98 % 70-130 100 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 100 % 70-130 110 % 70-130 0.36 1 11 /19/22 11:31 10061-01-5 0.36 1 11 /19/22 11:31 10061-02-6 0.30 1 11 /19/22 11:31 100-41-4 0.48 1 11 /19/22 11:31 591-78-6 9.7 1 11 /19/22 11:31 74-88-4 2.0 1 11 /19/22 11:31 75-09-2 2.7 1 11 /19/22 11:31 108-10-1 0.29 1 11 /19/22 11:31 100-42-5 0.31 1 11 /19/22 11:31 630-20-6 0.22 1 11 /19/22 11:31 79-34-5 0.29 1 11 /19/22 11:31 127-18-4 0.24 1 11 /19/22 11:31 108-88-3 0.33 1 11 /19/22 11:31 71-55-6 0.32 1 11 /19/22 11:31 79-00-5 0.38 1 11 /19/22 11:31 79-01-6 0.30 1 11 /19/22 11:31 75-69-4 0.26 1 11 /19/22 11:31 96-18-4 1.3 1 11 /19/22 11:31 108-05-4 0.39 1 11 /19/22 11:31 75-01-4 0.34 1 11 /19/22 11:31 1330-20-7 1 11 /19/22 11:31 460-00-4 1 11 /19/22 11:31 17060-07-0 1 11 /19/22 11:31 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 21:19 123-91-1 11/18/22 21:19 17060-07-0 11/18/22 21:19 2037-26-5 Page 23 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW1 Lab ID: 92637353009 Collected: 11/14/22 15:58 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:15 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:15 7440-38-2 Barium 36.3 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:15 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:15 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:15 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:15 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:15 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:15 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:15 7439-92-1 Nickel ND ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:15 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:15 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:15 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:15 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:15 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:15 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 10:36 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 10:36 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 10:36 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 10:36 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 10:36 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 10:36 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 10:36 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 10:36 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 10:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 10:36 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 10:36 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 10:36 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 10:36 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 10:36 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 10:36 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 10:36 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 10:36 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 10:36 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 10:36 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 10:36 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 10:36 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 10:36 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 10:36 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 10:36 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 10:36 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 10:36 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 10:36 78-87-5 REPORT OF LABORATORY ANALYSIS v2 This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW1 Lab ID: 92637353009 Collected: 11/14/22 15:58 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 98 % 70-130 100 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 95 % 70-130 107 % 70-130 0.36 1 11 /19/22 10:36 10061-01-5 0.36 1 11 /19/22 10:36 10061-02-6 0.30 1 11 /19/22 10:36 100-41-4 0.48 1 11 /19/22 10:36 591-78-6 9.7 1 11/19/2210:36 74-88-4 2.0 1 11/19/2210:36 75-09-2 2.7 1 11 /19/22 10:36 108-10-1 0.29 1 11 /19/22 10:36 100-42-5 0.31 1 11/19/2210:36 630-20-6 0.22 1 11/19/2210:36 79-34-5 0.29 1 11 /19/22 10:36 127-18-4 0.24 1 11 /19/22 10:36 108-88-3 0.33 1 11 /19/22 10:36 71-55-6 0.32 1 11/19/2210:36 79-00-5 0.38 1 11 /19/22 10:36 79-01-6 0.30 1 11/19/2210:36 75-69-4 0.26 1 11/19/2210:36 96-18-4 1.3 1 11 /19/22 10:36 108-05-4 0.39 1 11 /19/22 10:36 75-01-4 0.34 1 11 /19/22 10:36 1330-20-7 1 11/19/2210:36 460-00-4 1 11 /19/22 10:36 17060-07-0 1 11/19/2210:36 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 /18/22 19:44 123-91-1 11 /18/22 19:44 17060-07-0 11/18/2219:44 2037-26-5 Page 25 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW2 Lab ID: 92637353010 Collected: 11/14/22 15:15 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:21 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:21 7440-38-2 Barium 221 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:21 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:21 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:21 7440-43-9 Chromium 1.5J ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:21 7440-47-3 Cobalt 1.81 ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:21 7440-48-4 Copper 2.9.1 ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:21 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:21 7439-92-1 Nickel 3.4J ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:21 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:21 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:21 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:21 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:21 7440-62-2 Zinc 16.4 ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:21 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 09:12 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 09:12 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 09:12 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 09:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 09:12 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 09:12 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 09:12 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 09:12 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 09:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 09:12 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 09:12 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 09:12 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 09:12 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 09:12 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 09:12 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 09:12 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 09:12 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 09:12 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 09:12 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 09:12 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 09:12 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 09:12 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 09:12 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 09:12 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 09:12 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 09:12 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 09:12 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW2 Lab ID: 92637353010 Collected: 11/14/22 15:15 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 98 % 70-130 113 % 70-130 102 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 2.3 ug/L 2.0 94 % 70-130 99 % 70-130 0.36 1 11/19/22 09:12 10061-01-5 0.36 1 11/19/22 09:12 10061-02-6 0.30 1 11/19/22 09:12 100-41-4 0.48 1 11/19/22 09:12 591-78-6 9.7 1 11/19/22 09:12 74-88-4 2.0 1 11/19/22 09:12 75-09-2 2.7 1 11/19/22 09:12 108-10-1 0.29 1 11/19/22 09:12 100-42-5 0.31 1 11/19/22 09:12 630-20-6 0.22 1 11/19/22 09:12 79-34-5 0.29 1 11/19/22 09:12 127-18-4 0.24 1 11/19/22 09:12 108-88-3 0.33 1 11/19/22 09:12 71-55-6 0.32 1 11/19/22 09:12 79-00-5 0.38 1 11/19/22 09:12 79-01-6 0.30 1 11/19/22 09:12 75-69-4 0.26 1 11/19/22 09:12 96-18-4 1.3 1 11/19/22 09:12 108-05-4 0.39 1 11/19/22 09:12 75-01-4 0.34 1 11/19/22 09:12 1330-20-7 1 11/19/22 09:12 460-00-4 1 11/19/22 09:12 17060-07-0 1 11/19/22 09:12 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 20:03 123-91-1 11/18/22 20:03 17060-07-0 11/18/22 20:03 2037-26-5 Page 27 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW3 Lab ID: 92637353011 Collected: 11/14/22 15:05 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:27 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:27 7440-38-2 Barium 37.3 ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:27 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:27 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:27 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:27 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:27 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:27 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:27 7439-92-1 Nickel ND ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:27 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:27 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:27 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:27 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:27 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:27 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 09:30 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 09:30 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 09:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 09:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 09:30 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 09:30 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 09:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 09:30 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 09:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 09:30 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 09:30 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 09:30 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 09:30 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 09:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 09:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 09:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 09:30 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 09:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 09:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 09:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 09:30 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 09:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 09:30 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 09:30 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 09:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 09:30 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 09:30 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-SW3 Lab ID: 92637353011 Collected: 11/14/22 15:05 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 97 % 70-130 112 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 98 % 70-130 109 % 70-130 0.36 1 11/19/22 09:30 10061-01-5 0.36 1 11/19/22 09:30 10061-02-6 0.30 1 11/19/22 09:30 100-41-4 0.48 1 11/19/22 09:30 591-78-6 9.7 1 11/19/22 09:30 74-88-4 2.0 1 11/19/22 09:30 75-09-2 2.7 1 11/19/22 09:30 108-10-1 0.29 1 11/19/22 09:30 100-42-5 0.31 1 11/19/22 09:30 630-20-6 0.22 1 11/19/22 09:30 79-34-5 0.29 1 11/19/22 09:30 127-18-4 0.24 1 11/19/22 09:30 108-88-3 0.33 1 11/19/22 09:30 71-55-6 0.32 1 11/19/22 09:30 79-00-5 0.38 1 11/19/22 09:30 79-01-6 0.30 1 11/19/22 09:30 75-69-4 0.26 1 11/19/22 09:30 96-18-4 1.3 1 11/19/22 09:30 108-05-4 0.39 1 11/19/22 09:30 75-01-4 0.34 1 11/19/22 09:30 1330-20-7 1 11/19/22 09:30 460-00-4 1 11/19/22 09:30 17060-07-0 1 11/19/22 09:30 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/18/22 20:22 123-91-1 11/18/22 20:22 17060-07-0 11/18/22 20:22 2037-26-5 Page 29 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-FIELD BLANK Lab ID: 92637353012 Collected: 11/15/22 09:30 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Pace Analytical Services - Peachtree Corners, GA Antimony ND ug/L 3.0 0.78 1 12/14/2213:25 12/22/2214:33 7440-36-0 Arsenic ND ug/L 5.0 2.2 1 12/14/2213:25 12/22/2214:33 7440-38-2 Barium ND ug/L 5.0 0.67 1 12/14/2213:25 12/22/2214:33 7440-39-3 Beryllium ND ug/L 0.50 0.054 1 12/14/2213:25 12/22/2214:33 7440-41-7 Cadmium ND ug/L 0.50 0.11 1 12/14/2213:25 12/22/2214:33 7440-43-9 Chromium ND ug/L 5.0 1.1 1 12/14/2213:25 12/22/2214:33 7440-47-3 Cobalt ND ug/L 5.0 0.39 1 12/14/2213:25 12/22/2214:33 7440-48-4 Copper ND ug/L 5.0 1.0 1 12/14/2213:25 12/22/2214:33 7440-50-8 Lead ND ug/L 1.0 0.89 1 12/14/2213:25 12/22/2214:33 7439-92-1 Nickel ND ug/L 5.0 0.71 1 12/14/2213:25 12/22/2214:33 7440-02-0 Selenium ND ug/L 5.0 1.4 1 12/14/2213:25 12/22/2214:33 7782-49-2 Silver ND ug/L 5.0 0.44 1 12/14/2213:25 12/22/2214:33 7440-22-4 Thallium ND ug/L 1.0 0.18 1 12/14/2213:25 12/22/2214:33 7440-28-0 Vanadium ND ug/L 10.0 1.9 1 12/14/2213:25 12/22/2214:33 7440-62-2 Zinc ND ug/L 10.0 7.0 1 12/14/2213:25 12/22/2214:33 7440-66-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 5.1 1 11/19/22 08:00 67-64-1 Acrylonitrile ND ug/L 10.0 1.8 1 11/19/22 08:00 107-13-1 Benzene ND ug/L 1.0 0.34 1 11/19/22 08:00 71-43-2 Bromochloromethane ND ug/L 1.0 0.47 1 11/19/22 08:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 11/19/22 08:00 75-27-4 Bromoform ND ug/L 1.0 0.34 1 11/19/22 08:00 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 11/19/22 08:00 74-83-9 2-Butanone (MEK) ND ug/L 5.0 4.0 1 11/19/22 08:00 78-93-3 Carbon disulfide ND ug/L 2.0 0.36 1 11/19/22 08:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.33 1 11/19/22 08:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 11/19/22 08:00 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 11/19/22 08:00 75-00-3 Chloroform ND ug/L 1.0 0.43 1 11/19/22 08:00 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 11/19/22 08:00 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 11/19/22 08:00 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 11/19/22 08:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 11/19/22 08:00 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 11/19/22 08:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 11/19/22 08:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 11/19/22 08:00 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.56 1 11/19/22 08:00 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.37 1 11/19/22 08:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 11/19/22 08:00 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 11/19/22 08:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 11/19/22 08:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 11/19/22 08:00 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 11/19/22 08:00 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-FIELD BLANK Lab ID: 92637353012 Collected: 11/15/22 09:30 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 99 % 70-130 111 % 70-130 100 % 70-130 Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte ND ug/L 2.0 94 % 70-130 105 % 70-130 0.36 1 11/19/22 08:00 10061-01-5 0.36 1 11/19/22 08:00 10061-02-6 0.30 1 11/19/22 08:00 100-41-4 0.48 1 11/19/22 08:00 591-78-6 9.7 1 11/19/22 08:00 74-88-4 2.0 1 11/19/22 08:00 75-09-2 2.7 1 11/19/22 08:00 108-10-1 0.29 1 11/19/22 08:00 100-42-5 0.31 1 11/19/22 08:00 630-20-6 0.22 1 11/19/22 08:00 79-34-5 0.29 1 11/19/22 08:00 127-18-4 0.24 1 11/19/22 08:00 108-88-3 0.33 1 11/19/22 08:00 71-55-6 0.32 1 11/19/22 08:00 79-00-5 0.38 1 11/19/22 08:00 79-01-6 0.30 1 11/19/22 08:00 75-69-4 0.26 1 11/19/22 08:00 96-18-4 1.3 1 11/19/22 08:00 108-05-4 0.39 1 11/19/22 08:00 75-01-4 0.34 1 11/19/22 08:00 1330-20-7 1 11/19/22 08:00 460-00-4 1 11/19/22 08:00 17060-07-0 1 11/19/22 08:00 2037-26-5 0.86 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11 /18/22 18:08 123-91-1 11 /18/22 18:08 17060-07-0 11/18/2218:08 2037-26-5 Page 31 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-TRIP BLANK Lab ID: 92637353013 Collected: 11/15/22 00:00 Received: 11/17/22 11:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 12/27/2022 05:09 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 5.1 1 11/19/22 08:18 67-64-1 ND ug/L 10.0 1.8 1 11/19/22 08:18 107-13-1 ND ug/L 1.0 0.34 1 11/19/22 08:18 71-43-2 ND ug/L 1.0 0.47 1 11/19/22 08:18 74-97-5 ND ug/L 1.0 0.31 1 11/19/22 08:18 75-27-4 ND ug/L 1.0 0.34 1 11/19/22 08:18 75-25-2 ND ug/L 2.0 1.7 1 11/19/22 08:18 74-83-9 ND ug/L 5.0 4.0 1 11/19/22 08:18 78-93-3 ND ug/L 2.0 0.36 1 11/19/22 08:18 75-15-0 ND ug/L 1.0 0.33 1 11/19/22 08:18 56-23-5 ND ug/L 1.0 0.28 1 11/19/22 08:18 108-90-7 ND ug/L 1.0 0.65 1 11/19/22 08:18 75-00-3 ND ug/L 1.0 0.43 1 11/19/22 08:18 67-66-3 ND ug/L 1.0 0.54 1 11/19/22 08:18 74-87-3 ND ug/L 2.0 0.34 1 11/19/22 08:18 96-12-8 ND ug/L 1.0 0.36 1 11/19/22 08:18 124-48-1 ND ug/L 1.0 0.27 1 11/19/22 08:18 106-93-4 ND ug/L 1.0 0.39 1 11/19/22 08:18 74-95-3 ND ug/L 1.0 0.34 1 11/19/22 08:18 95-50-1 ND ug/L 1.0 0.33 1 11/19/22 08:18 106-46-7 ND ug/L 1.0 0.56 1 11/19/22 08:18 110-57-6 ND ug/L 1.0 0.37 1 11/19/22 08:18 75-34-3 ND ug/L 1.0 0.32 1 11/19/22 08:18 107-06-2 ND ug/L 1.0 0.35 1 11/19/22 08:18 75-35-4 ND ug/L 1.0 0.38 1 11/19/22 08:18 156-59-2 ND ug/L 1.0 0.40 1 11/19/22 08:18 156-60-5 ND ug/L 1.0 0.36 1 11/19/22 08:18 78-87-5 ND ug/L 1.0 0.36 1 11/19/22 08:18 10061-01-5 ND ug/L 1.0 0.36 1 11/19/22 08:18 10061-02-6 ND ug/L 1.0 0.30 1 11/19/22 08:18 100-41-4 ND ug/L 5.0 0.48 1 11/19/22 08:18 591-78-6 ND ug/L 20.0 9.7 1 11/19/22 08:18 74-88-4 ND ug/L 5.0 2.0 1 11/19/22 08:18 75-09-2 ND ug/L 5.0 2.7 1 11/19/22 08:18 108-10-1 ND ug/L 1.0 0.29 1 11/19/22 08:18 100-42-5 ND ug/L 1.0 0.31 1 11/19/22 08:18 630-20-6 ND ug/L 1.0 0.22 1 11/19/22 08:18 79-34-5 ND ug/L 1.0 0.29 1 11/19/22 08:18 127-18-4 ND ug/L 1.0 0.24 1 11/19/22 08:18 108-88-3 ND ug/L 1.0 0.33 1 11/19/22 08:18 71-55-6 ND ug/L 1.0 0.32 1 11/19/22 08:18 79-00-5 ND ug/L 1.0 0.38 1 11/19/22 08:18 79-01-6 ND ug/L 1.0 0.30 1 11/19/22 08:18 75-69-4 ND ug/L 1.0 0.26 1 11/19/22 08:18 96-18-4 ND ug/L 2.0 1.3 1 11/19/22 08:18 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Sample: 1201-TRIP BLANK Parameters Lab ID: 92637353013 Collected: Report Results Units Limit 11/15/22 00:00 MDL DF Received: 11/17/22 11:00 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl chloride ND ug/L 1.0 0.39 1 11/19/22 08:18 75-01-4 Xylene (Total) ND ug/L 1.0 0.34 1 11/19/22 08:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 11/19/22 08:18 460-00-4 1,2-Dichloroethane-d4 (S) 110 % 70-130 1 11/19/22 08:18 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 11/19/22 08:18 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 0.86 1 11/18/22 18:27 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 11/18/22 18:27 17060-07-0 Toluene-d8 (S) 106 % 70-130 1 11/18/22 18:27 2037-26-5 Date: 12/27/2022 05:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 QC Batch: 743354 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020 MET Laboratory: Pace Analytical Services - Peachtree Corners, GA Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009,92637353010,92637353011,92637353012 METHOD BLANK: 3867271 Matrix: Water Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009,92637353010,92637353011,92637353012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 3.0 0.78 12/22/2212:46 Arsenic ug/L ND 5.0 2.2 12/22/2212:46 Barium ug/L ND 5.0 0.67 12/22/2212:46 Beryllium ug/L ND 0.50 0.054 12/22/2212:46 Cadmium ug/L ND 0.50 0.11 12/22/2212:46 Chromium ug/L ND 5.0 1.1 12/22/2212:46 Cobalt ug/L ND 5.0 0.39 12/22/2212:46 Copper ug/L ND 5.0 1.0 12/22/2212:46 Lead ug/L ND 1.0 0.89 12/22/2212:46 Nickel ug/L ND 5.0 0.71 12/22/2212:46 Selenium ug/L ND 5.0 1.4 12/22/2212:46 Silver ug/L ND 5.0 0.44 12/22/2212:46 Thallium ug/L ND 1.0 0.18 12/22/2212:46 Vanadium ug/L ND 10.0 1.9 12/22/2212:46 Zinc ug/L ND 10.0 7.0 12/22/2212:46 LABORATORY CONTROL SAMPLE: Parameter 3867272 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 105 105 80-120 Arsenic ug/L 100 96.6 97 80-120 Barium ug/L 100 100 100 80-120 Beryllium ug/L 100 95.6 96 80-120 Cadmium ug/L 100 100 100 80-120 Chromium ug/L 100 101 101 80-120 Cobalt ug/L 100 99.3 99 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 98.5 98 80-120 Nickel ug/L 100 98.4 98 80-120 Selenium ug/L 100 99.0 99 80-120 Silver ug/L 100 103 103 80-120 Thallium ug/L 100 98.1 98 80-120 Vanadium ug/L 100 98.0 98 80-120 Zinc ug/L 100 100 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: BURKE CO.-KIRKSEY DRIVE 92637353 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3867273 3867274 MS MSD 92637353001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 109 102 109 102 75-125 6 20 Arsenic ug/L ND 100 100 102 98.5 102 99 75-125 3 20 Barium ug/L 159 100 100 271 248 112 89 75-125 9 20 Beryllium ug/L ND 100 100 85.3 81.8 85 82 75-125 4 20 Cadmium ug/L ND 100 100 101 96.7 101 97 75-125 4 20 Chromium ug/L ND 100 100 102 95.5 101 95 75-125 6 20 Cobalt ug/L 9.4 100 100 109 103 99 94 75-125 5 20 Copper ug/L 3.8J 100 100 102 96.3 99 92 75-125 6 20 Lead ug/L ND 100 100 99.0 92.6 99 92 75-125 7 20 Nickel ug/L 2.OJ 100 100 101 94.9 99 93 75-125 6 20 Selenium ug/L ND 100 100 104 101 104 101 75-125 3 20 Silver ug/L ND 100 100 98.1 92.3 98 92 75-125 6 20 Thallium ug/L ND 100 100 98.6 93.5 98 93 75-125 5 20 Vanadium ug/L ND 100 100 102 95.8 102 96 75-125 6 20 Zinc ug/L 47.3 100 100 147 139 99 91 75-125 6 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 QC Batch: 738208 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009 METHOD BLANK: 3841852 Matrix: Water Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/19/22 06:41 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/19/22 06:41 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/19/22 06:41 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/19/22 06:41 1,1-Dichloroethane ug/L ND 1.0 0.37 11/19/22 06:41 1,1-Dichloroethene ug/L ND 1.0 0.35 11/19/22 06:41 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/19/22 06:41 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/19/22 06:41 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/19/22 06:41 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/19/22 06:41 1,2-Dichloroethane ug/L ND 1.0 0.32 11/19/22 06:41 1,2-Dichloropropane ug/L ND 1.0 0.36 11/19/22 06:41 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/19/22 06:41 2-Butanone (MEK) ug/L ND 5.0 4.0 11/19/22 06:41 2-Hexanone ug/L ND 5.0 0.48 11/19/22 06:41 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/19/22 06:41 Acetone ug/L ND 25.0 5.1 11/19/22 06:41 Acrylonitrile ug/L ND 10.0 1.8 11/19/22 06:41 Benzene ug/L ND 1.0 0.34 11/19/22 06:41 Bromochloromethane ug/L ND 1.0 0.47 11/19/22 06:41 Bromodichloromethane ug/L ND 1.0 0.31 11/19/22 06:41 Bromoform ug/L ND 1.0 0.34 11/19/22 06:41 Bromomethane ug/L ND 2.0 1.7 11/19/22 06:41 Carbon disulfide ug/L ND 2.0 0.36 11/19/22 06:41 Carbon tetrachloride ug/L ND 1.0 0.33 11/19/22 06:41 Chlorobenzene ug/L ND 1.0 0.28 11/19/22 06:41 Chloroethane ug/L ND 1.0 0.65 11/19/22 06:41 Chloroform ug/L ND 1.0 0.43 11/19/22 06:41 Chloromethane ug/L ND 1.0 0.54 11/19/22 06:41 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/19/22 06:41 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/19/22 06:41 Dibromochloromethane ug/L ND 1.0 0.36 11/19/22 06:41 Dibromomethane ug/L ND 1.0 0.39 11/19/22 06:41 Ethylbenzene ug/L ND 1.0 0.30 11/19/22 06:41 lodomethane ug/L ND 20.0 9.7 11/19/22 06:41 Methylene Chloride ug/L ND 5.0 2.0 11/19/22 06:41 Styrene ug/L ND 1.0 0.29 11/19/22 06:41 Tetrachloroethene ug/L ND 1.0 0.29 11/19/22 06:41 Toluene ug/L ND 1.0 0.24 11/19/22 06:41 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 METHOD BLANK: 3841852 Matrix: Water Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/19/22 06:41 trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/19/22 06:41 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/19/22 06:41 v2 Trichloroethene ug/L ND 1.0 0.38 11/19/22 06:41 Trichlorofluoromethane ug/L ND 1.0 0.30 11/19/22 06:41 Vinyl acetate ug/L ND 2.0 1.3 11/19/22 06:41 Vinyl chloride ug/L ND 1.0 0.39 11/19/22 06:41 Xylene (Total) ug/L ND 1.0 0.34 11/19/22 06:41 1,2-Dichloroethane-d4 (S) % 96 70-130 11/19/22 06:41 4-Bromofluorobenzene (S) % 98 70-130 11/19/22 06:41 Toluene-d8 (S) % 99 70-130 11/19/22 06:41 LABORATORY CONTROL SAMPLE: 3841853 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 49.1 98 70-130 1,1,1-Trichloroethane ug/L 50 47.3 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 47.9 96 70-130 1,1,2-Trichloroethane ug/L 50 47.6 95 70-130 1,1-Dichloroethane ug/L 50 45.0 90 70-130 1,1-Dichloroethene ug/L 50 49.2 98 70-130 1,2,3-Trichloropropane ug/L 50 47.0 94 70-130 1,2-Dibromo-3-chloropropane ug/L 50 47.4 95 70-131 1,2-Dibromoethane (EDB) ug/L 50 49.1 98 70-130 1,2-Dichlorobenzene ug/L 50 48.2 96 70-130 1,2-Dichloroethane ug/L 50 47.5 95 70-130 1,2-Dichloropropane ug/L 50 48.4 97 70-130 1,4-Dichlorobenzene ug/L 50 46.5 93 70-130 2-Butanone (MEK) ug/L 100 87.0 87 70-134 2-Hexanone ug/L 100 91.9 92 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 87.5 87 70-130 Acetone ug/L 100 87.0 87 70-133 Acrylonitrile ug/L 250 238 95 70-130 Benzene ug/L 50 46.3 93 70-130 Bromochloromethane ug/L 50 49.5 99 70-130 Bromodichloromethane ug/L 50 48.0 96 70-130 Bromoform ug/L 50 48.1 96 70-130 Bromomethane ug/L 50 47.1 94 45-151 Carbon disulfide ug/L 50 48.9 98 70-130 Carbon tetrachloride ug/L 50 45.5 91 70-130 Chlorobenzene ug/L 50 47.5 95 70-130 Chloroethane ug/L 50 55.5 111 39-152 Chloroform ug/L 50 45.7 91 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 LABORATORY CONTROL SAMPLE: Parameter 3841853 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloromethane ug/L 50 48.8 98 58-130 cis-1,2-Dichloroethene ug/L 50 45.6 91 70-130 cis-1,3-Dichloropropene ug/L 50 47.5 95 70-130 Dibromochloromethane ug/L 50 48.1 96 70-130 Dibromomethane ug/L 50 50.6 101 70-130 Ethylbenzene ug/L 50 46.8 94 70-130 lodomethane ug/L 100 96.2 96 53-141 Methylene Chloride ug/L 50 46.3 93 66-130 Styrene ug/L 50 48.9 98 70-130 Tetrachloroethene ug/L 50 46.8 94 70-130 Toluene ug/L 50 46.5 93 70-130 trans-1,2-Dichloroethene ug/L 50 47.3 95 70-130 trans- 1,3-Dichloropropene ug/L 50 47.2 94 70-130 trans-1,4-Dichloro-2-butene ug/L 50 38.7 77 57-185 v3 Trichloroethene ug/L 50 51.1 102 70-130 Trichlorofluoromethane ug/L 50 46.8 94 62-130 Vinyl acetate ug/L 100 95.3 95 70-144 Vinyl chloride ug/L 50 49.1 98 62-130 Xylene (Total) ug/L 150 141 94 70-130 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: Parameter 3841855 Units 92637044009 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.9 109 70-141 1,1,1-Trichloroethane ug/L ND 20 24.0 120 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 19.7 98 69-142 1,1,2-Trichloroethane ug/L ND 20 21.5 108 70-138 1,1-Dichloroethane ug/L ND 20 20.9 105 70-150 1,1-Dichloroethene ug/L ND 20 22.4 112 70-156 1,2,3-Trichloropropane ug/L ND 20 18.9 95 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 19.7 99 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 21.6 108 70-138 1,2-Dichlorobenzene ug/L ND 20 22.5 112 70-141 1,2-Dichloroethane ug/L ND 20 19.9 100 69-143 1,2-Dichloropropane ug/L ND 20 20.3 102 68-156 1,4-Dichlorobenzene ug/L ND 20 22.3 111 70-142 2-Butanone (MEK) ug/L ND 40 31.7 79 60-157 2-Hexanone ug/L ND 40 31.7 79 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 32.8 82 70-141 Acetone ug/L ND 40 31.3 78 58-157 Acrylonitrile ug/L ND 100 93.2 93 69-147 Benzene ug/L ND 20 21.2 106 70-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 MATRIX SPIKE SAMPLE: 3841855 92637044009 Spike MS MS Parameter Units Result Conc. Result % Rec Bromochloromethane ug/L ND 20 24.2 121 Bromodichloromethane ug/L ND 20 20.7 103 Bromoform ug/L ND 20 20.4 102 Bromomethane ug/L ND 20 27.2 136 Carbon disulfide ug/L ND 20 23.2 116 Carbon tetrachloride ug/L ND 20 24.8 124 Chlorobenzene ug/L 1.1 20 23.5 112 Chloroethane ug/L ND 20 27.2 136 Chloroform ug/L ND 20 20.7 103 Chloromethane ug/L ND 20 21.6 108 cis-1,2-Dichloroethene ug/L ND 20 20.8 104 cis-1,3-Dichloropropene ug/L ND 20 20.9 104 Dibromochloromethane ug/L ND 20 21.0 105 Dibromomethane ug/L ND 20 22.3 112 Ethylbenzene ug/L ND 20 21.6 108 lodomethane ug/L ND 40 48.2 121 Methylene Chloride ug/L ND 20 16.0 80 Styrene ug/L ND 20 22.1 111 Tetrachloroethene ug/L ND 20 22.6 113 Toluene ug/L ND 20 22.0 110 trans-1,2-Dichloroethene ug/L ND 20 21.7 108 trans- 1,3-Dichloropropene ug/L ND 20 20.5 103 trans-1,4-Dichloro-2-butene ug/L ND 20 14.4 72 Trichloroethene ug/L ND 20 24.1 121 Trichlorofluoromethane ug/L ND 20 20.7 104 Vinyl acetate ug/L ND 40 33.1 83 Vinyl chloride ug/L ND 20 22.3 111 Xylene (Total) ug/L ND 60 65.9 110 1,2-Dichloroethane-d4 (S) % 88 4-Bromofluorobenzene (S) % 97 Toluene-d8 (S) % 99 SAMPLE DUPLICATE: 3841854 92637044008 Dup Max Parameter Units Result Result RPD RPD 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 % Rec Limits Qualifiers 70-146 70-139 64-140 28-192 70-151 70-148 70-141 58-191 v3 70-148 43-162 68-151 70-139 70-144 70-139 70-143 35-171 62-149 70-143 70-145 70-142 70-151 70-139 51-159 v1 62-146 63-153 v3 61-162 61-163 70-143 70-130 70-130 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 SAMPLE DUPLICATE: 3841854 Parameter Units 92637044008 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 v2 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 v1 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 v2 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 98 92 4-Bromofluorobenzene (S) % 98 100 Toluene-d8 (S) % 100 94 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 QC Batch: 738210 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92637353010, 92637353011, 92637353012, 92637353013 METHOD BLANK: 3841861 Matrix: Water Associated Lab Samples: 92637353010, 92637353011, 92637353012, 92637353013 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 11/19/22 07:05 1,1,1-Trichloroethane ug/L ND 1.0 0.33 11/19/22 07:05 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/19/22 07:05 1,1,2-Trichloroethane ug/L ND 1.0 0.32 11/19/22 07:05 1,1-Dichloroethane ug/L ND 1.0 0.37 11/19/22 07:05 1,1-Dichloroethene ug/L ND 1.0 0.35 11/19/22 07:05 1,2,3-Trichloropropane ug/L ND 1.0 0.26 11/19/22 07:05 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 11/19/22 07:05 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 11/19/22 07:05 1,2-Dichlorobenzene ug/L ND 1.0 0.34 11/19/22 07:05 1,2-Dichloroethane ug/L ND 1.0 0.32 11/19/22 07:05 1,2-Dichloropropane ug/L ND 1.0 0.36 11/19/22 07:05 1,4-Dichlorobenzene ug/L ND 1.0 0.33 11/19/22 07:05 2-Butanone (MEK) ug/L ND 5.0 4.0 11/19/22 07:05 2-Hexanone ug/L ND 5.0 0.48 11/19/22 07:05 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 2.7 11/19/22 07:05 Acetone ug/L ND 25.0 5.1 11/19/22 07:05 Acrylonitrile ug/L ND 10.0 1.8 11/19/22 07:05 Benzene ug/L ND 1.0 0.34 11/19/22 07:05 Bromochloromethane ug/L ND 1.0 0.47 11/19/22 07:05 Bromodichloromethane ug/L ND 1.0 0.31 11/19/22 07:05 Bromoform ug/L ND 1.0 0.34 11/19/22 07:05 Bromomethane ug/L ND 2.0 1.7 11/19/22 07:05 Carbon disulfide ug/L ND 2.0 0.36 11/19/22 07:05 Carbon tetrachloride ug/L ND 1.0 0.33 11/19/22 07:05 Chlorobenzene ug/L ND 1.0 0.28 11/19/22 07:05 Chloroethane ug/L ND 1.0 0.65 11/19/22 07:05 Chloroform ug/L ND 1.0 0.43 11/19/22 07:05 Chloromethane ug/L ND 1.0 0.54 11/19/22 07:05 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 11/19/22 07:05 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 11/19/22 07:05 Dibromochloromethane ug/L ND 1.0 0.36 11/19/22 07:05 Dibromomethane ug/L ND 1.0 0.39 11/19/22 07:05 Ethylbenzene ug/L ND 1.0 0.30 11/19/22 07:05 lodomethane ug/L ND 20.0 9.7 11/19/22 07:05 Methylene Chloride ug/L ND 5.0 2.0 11/19/22 07:05 Styrene ug/L ND 1.0 0.29 11/19/22 07:05 Tetrachloroethene ug/L ND 1.0 0.29 11/19/22 07:05 Toluene ug/L ND 1.0 0.24 11/19/22 07:05 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 11/19/22 07:05 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 METHOD BLANK: 3841861 Matrix: Water Associated Lab Samples: 92637353010, 92637353011, 92637353012, 92637353013 Blank Reporting Parameter Units Result Limit MDL Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 0.36 11/19/22 07:05 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.56 11/19/22 07:05 Trichloroethene ug/L ND 1.0 0.38 11/19/22 07:05 Trichlorofluoromethane ug/L ND 1.0 0.30 11/19/22 07:05 Vinyl acetate ug/L ND 2.0 1.3 11/19/22 07:05 Vinyl chloride ug/L ND 1.0 0.39 11/19/22 07:05 Xylene (Total) ug/L ND 1.0 0.34 11/19/22 07:05 1,2-Dichloroethane-d4 (S) % 112 70-130 11/19/22 07:05 4-Bromofluorobenzene (S) % 99 70-130 11/19/22 07:05 Toluene-d8 (S) % 102 70-130 11/19/22 07:05 LABORATORY CONTROL SAMPLE: Parameter 3841862 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 45.4 91 70-130 1,1,1-Trichloroethane ug/L 50 47.3 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.2 98 70-130 1,1,2-Trichloroethane ug/L 50 47.7 95 70-130 1,1-Dichloroethane ug/L 50 47.5 95 70-130 1,1-Dichloroethene ug/L 50 52.0 104 70-130 1,2,3-Trichloropropane ug/L 50 49.0 98 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.5 101 70-131 1,2-Dibromoethane (EDB) ug/L 50 48.6 97 70-130 1,2-Dichlorobenzene ug/L 50 46.8 94 70-130 1,2-Dichloroethane ug/L 50 50.3 101 70-130 1,2-Dichloropropane ug/L 50 48.6 97 70-130 1,4-Dichlorobenzene ug/L 50 45.7 91 70-130 2-Butanone (MEK) ug/L 100 104 104 70-134 2-Hexanone ug/L 100 111 111 70-131 4-Methyl-2-pentanone (MIBK) ug/L 100 105 105 70-130 Acetone ug/L 100 107 107 70-133 Acrylonitrile ug/L 250 269 108 70-130 Benzene ug/L 50 44.6 89 70-130 Bromochloromethane ug/L 50 48.3 97 70-130 Bromodichloromethane ug/L 50 47.5 95 70-130 Bromoform ug/L 50 46.9 94 70-130 Bromomethane ug/L 50 40.4 81 45-151 Carbon disulfide ug/L 50 47.2 94 70-130 Carbon tetrachloride ug/L 50 44.2 88 70-130 Chlorobenzene ug/L 50 46.3 93 70-130 Chloroethane ug/L 50 52.4 105 39-152 Chloroform ug/L 50 46.7 93 70-130 Chloromethane ug/L 50 45.6 91 58-130 cis-1,2-Dichloroethene ug/L 50 48.5 97 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 54 Pace Analytical Services, LLC lac, Analyilcal ® 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 LABORATORY CONTROL SAMPLE: Parameter 3841862 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 47.3 95 70-130 Dibromochloromethane ug/L 50 46.9 94 70-130 Dibromomethane ug/L 50 44.4 89 70-130 Ethylbenzene ug/L 50 46.2 92 70-130 lodomethane ug/L 100 81.9 82 53-141 Methylene Chloride ug/L 50 49.5 99 66-130 Styrene ug/L 50 48.6 97 70-130 Tetrachloroethene ug/L 50 42.0 84 70-130 Toluene ug/L 50 45.6 91 70-130 trans-1,2-Dichloroethene ug/L 50 49.6 99 70-130 trans- 1,3-Dichloropropene ug/L 50 48.5 97 70-130 trans-1,4-Dichloro-2-butene ug/L 50 42.8 86 57-185 Trichloroethene ug/L 50 45.0 90 70-130 Trichlorofluoromethane ug/L 50 43.9 88 62-130 Vinyl acetate ug/L 100 112 112 70-144 Vinyl chloride ug/L 50 52.4 105 62-130 Xylene (Total) ug/L 150 142 95 70-130 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8(S) % 102 70-130 MATRIX SPIKE SAMPLE: Parameter 3841864 Units 92637360005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 24.2 121 70-141 1,1,1-Trichloroethane ug/L ND 20 27.6 138 70-150 1,1,2,2-Tetrachloroethane ug/L ND 20 25.2 126 69-142 1,1,2-Trichloroethane ug/L ND 20 25.9 130 70-138 1,1-Dichloroethane ug/L ND 20 27.8 139 70-150 1,1-Dichloroethene ug/L ND 20 21.2 106 70-156 1,2,3-Trichloropropane ug/L ND 20 24.6 123 70-140 1,2-Dibromo-3-chloropropane ug/L ND 20 21.9 109 68-146 1,2-Dibromoethane (EDB) ug/L ND 20 24.8 124 70-138 1,2-Dichlorobenzene ug/L ND 20 25.1 126 70-141 1,2-Dichloroethane ug/L ND 20 26.3 131 69-143 1,2-Dichloropropane ug/L ND 20 26.9 135 68-156 1,4-Dichlorobenzene ug/L ND 20 24.9 125 70-142 2-Butanone (MEK) ug/L ND 40 47.0 117 60-157 2-Hexanone ug/L ND 40 46.5 116 68-146 4-Methyl-2-pentanone (MIBK) ug/L ND 40 48.5 121 70-141 Acetone ug/L ND 40 32.2 80 58-157 Acrylonitrile ug/L ND 100 131 131 69-147 Benzene ug/L ND 20 25.8 129 70-142 Bromochloromethane ug/L ND 20 27.4 137 70-146 Bromodichloromethane ug/L ND 20 24.9 124 70-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 MATRIX SPIKE SAMPLE: Parameter 3841864 Units 92637360005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromoform ug/L ND 20 23.1 115 64-140 Bromomethane ug/L ND 20 25.3 126 28-192 Carbon disulfide ug/L ND 20 21.8 109 70-151 Carbon tetrachloride ug/L ND 20 25.9 130 70-148 Chlorobenzene ug/L ND 20 25.7 128 70-141 Chloroethane ug/L ND 20 26.3 132 58-191 v3 Chloroform ug/L ND 20 26.3 131 70-148 Chloromethane ug/L ND 20 30.7 154 43-162 cis-1,2-Dichloroethene ug/L ND 20 27.1 135 68-151 cis-1,3-Dichloropropene ug/L ND 20 26.7 133 70-139 Dibromochloromethane ug/L ND 20 23.7 118 70-144 Dibromomethane ug/L ND 20 24.9 124 70-139 Ethylbenzene ug/L ND 20 26.2 131 70-143 lodomethane ug/L ND 40 48.1 120 35-171 Methylene Chloride ug/L ND 20 14.8 74 62-149 Styrene ug/L ND 20 26.2 131 70-143 Tetrachloroethene ug/L ND 20 25.5 127 70-145 Toluene ug/L ND 20 26.5 133 70-142 trans-1,2-Dichloroethene ug/L ND 20 20.8 104 70-151 trans- 1,3-Dichloropropene ug/L ND 20 26.5 132 70-139 trans-1,4-Dichloro-2-butene ug/L ND 20 23.5 118 51-159 v1 Trichloroethene ug/L ND 20 26.9 135 62-146 Trichlorofluoromethane ug/L ND 20 20.2 101 63-153 v3 Vinyl acetate ug/L ND 40 47.7 119 61-162 Vinyl chloride ug/L ND 20 30.5 152 61-163 Xylene (Total) ug/L ND 60 79.1 132 70-143 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 103 70-130 SAMPLE DUPLICATE: 3841863 Parameter Units 92637360004 Result Dup Result RPD Max RPD 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropene ug/L ND ND 30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 SAMPLE DUPLICATE: 3841863 Parameter Units 92637360004 Result Dup Result Max RPD RPD 1,4-Dichlorobenzene ug/L 1.1 1.2 7 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 v2 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L 1.9 1.8 7 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 v1 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 v2 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 109 87 4-Bromofluorobenzene (S) % 98 96 Toluene-d8 (S) % 101 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 QC Batch: 738214 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009,92637353010,92637353011,92637353012,92637353013 METHOD BLANK: 3841902 Matrix: Water Associated Lab Samples: 92637353001, 92637353002, 92637353003, 92637353004, 92637353005, 92637353006, 92637353007, 92637353008,92637353009,92637353010,92637353011,92637353012,92637353013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 0.86 11/18/22 17:11 1,2-Dichloroethane-d4 (S) % 89 70-130 11/18/22 17:11 Toluene-d8 (S) % 106 70-130 11/18/22 17:11 LABORATORY CONTROL SAMPLE: 3841903 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.4 92 70-130 1,2-Dichloroethane-d4 (S) % 98 70-130 Toluene-d8 (S) % 105 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3841904 3841906 Parameter 1,4-Dioxane (p-Dioxane) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) MS 92637360006 Spike Units Result Conc. ug/L 13.9 20 MSD Spike MS MSD MS MSD % Rec Max Conc. Result Result % Rec % Rec Limits RPD RPD Qual 20 31.3 34.9 87 105 63-136 11 30 99 95 70-130 30 98 102 70-130 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 54 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BURKE CO.-KIRKSEY DRIVE Pace Project No.: 92637353 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92637353001 1201-MW1 EPA 3005A 743354 EPA 6020B 743481 92637353002 1201-MW2 EPA 3005A 743354 EPA 6020B 743481 92637353003 1201-MW3s EPA 3005A 743354 EPA 6020B 743481 92637353004 1201-MW3D EPA 3005A 743354 EPA 6020B 743481 92637353005 1201-MW4 EPA 3005A 743354 EPA 6020B 743481 92637353006 1201-MW5 EPA 3005A 743354 EPA 6020B 743481 92637353007 1201-MW6S EPA 3005A 743354 EPA 6020B 743481 92637353008 1201-MW6D EPA 3005A 743354 EPA 6020B 743481 92637353009 1201-SW1 EPA 3005A 743354 EPA 6020B 743481 92637353010 1201-SW2 EPA 3005A 743354 EPA 6020B 743481 92637353011 1201-SW3 EPA 3005A 743354 EPA 6020B 743481 92637353012 1201-FIELD BLANK EPA 3005A 743354 EPA 6020B 743481 92637353001 1201-MW 1 EPA 8260D 738208 92637353002 1201-MW2 EPA 8260D 738208 92637353003 1201-MW3s EPA 8260D 738208 92637353004 1201-MW3D EPA 8260D 738208 92637353005 1201-MW4 EPA 8260D 738208 92637353006 1201-MW5 EPA 8260D 738208 92637353007 1201-MW6S EPA 8260D 738208 92637353008 1201-MW6D EPA 8260D 738208 92637353009 1201-SW1 EPA 8260D 738208 92637353010 1201-SW2 EPA 8260D 738210 92637353011 1201-SW3 EPA 8260D 738210 92637353012 1201-FIELD BLANK EPA 8260D 738210 92637353013 1201-TRIP BLANK EPA 8260D 738210 92637353001 1201-MW1 EPA 8260D Mod. 738214 92637353002 1201-MW2 EPA 8260D Mod. 738214 92637353003 1201-MW3s EPA 8260D Mod. 738214 92637353004 1201-MW3D EPA 8260D Mod. 738214 92637353005 1201-MW4 EPA 8260D Mod. 738214 92637353006 1201-MW5 EPA 8260D Mod. 738214 92637353007 1201-MW6S EPA 8260D Mod. 738214 92637353008 1201-MW6D EPA 8260D Mod. 738214 92637353009 1201-SW1 EPA 8260D Mod. 738214 92637353010 1201-SW2 EPA 8260D Mod. 738214 92637353011 1201-SW3 EPA 8260D Mod. 738214 92637353012 1201-FIELD BLANK EPA 8260D Mod. 738214 92637353013 1201-TRIP BLANK EPA 8260D Mod. 738214 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/27/2022 05:09 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 54 r uUU Effective Date: 05/121202205/12/2022 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Q Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ Sample Condition Client Name: Project ff: W�+1t ' 9Z,6373�53 �. j Courier: []Fed Ex ❑UPS CUSPS 7 ❑Client ❑ Commercial []Pace -❑other: 92637353 Custody Sea! Present? Des [^]No Seals Intact? ❑Yes HNo Date/initials Person Examining Contents: T�yl f � 11%1rno( Pa Thermometer: ❑Yes []No [IN/A Q IR Gun ID: )-TO ? C' Type of Ice: tJWet ❑Glue ❑None it Correction Factor: Cooler Temp: Add/Subtract ('C) 4 Temp should be above freezing to 6'C '7 []Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected ('C): r 7 has begun USDA Regulated Soil' (,aN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally, (check maosf? F1Yes -ElNr) ;, F..X� "'...,::.-., .:__„ n..__ Comments/Discrepancy: u Chain of Custody Present? '_]Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? -E3i'es [:]No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? []Yes ❑No -gN/A 3. Rush Turn Around Time Requested? ❑Yes ❑No QLf/A 4. SufficientWume? i4yes Elmo ❑N/A 5. Correct Containers Used? rBYes ❑No El N/A 6. Pace Containers Used? GYes ❑No ❑N/A Containers Intact? {Yes ❑No []N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ❑N/A S. Sample Labels Match COC? "❑Yes —EA}a ❑NJA 5. / w f Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? ❑Yes TSNo ❑N/A 10. Trip Blank Present? .OYes []No ❑NJA 11. Trip Blank Custody Seals Present? SYes ElNo ❑N/A COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: _._Fcoject-Manager 5RF Review:.. -. -.. -. Qualtrax ID: 69614 Lot ID of split containers: Date/Time: Field Data Required? ❑Yes ❑No Date: Date: Page 1 of 2 Page 49 of 54 -1 UGG Effective [late: 051121202205/12/2022 *Check mark top half of box if PH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) HOC, LLHg *"Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine # : 92637353 Project # PM: AI4B CLIE Due Date: 12/05/22 N'f : 92-JoYce Eng a u FF-ii v_ 7 T TM _ ¢ d '13.... v N r-I C N i* N v N _ U Q = 2 z Q c c c a C lu O O ¢ = m m a a a O O �n 'J v ¢ m p v z z N a� m w L V n c tn z V U u l'7 y c x c = of = ry Z x Z Z ry N d Q 0 a _ a i° z O C N a` (a a a L rts a ry a N IO a (6 a JC 7 a E - E ¢ M E ¢ E 4 d a E A E ¢ E E ¢ ¢ O a O a d a O LA? ¢ m y u o y E m c d n E E Ln E O E O a a+ E E J vs E d, r _ _ E 0 ¢ 6 J E J E E } J > J � J J E c. � r4 Ln J E vi J E a J E Q E u V7 J Q J f ~ N N H D rrvi Vi n 2 N N eq m 3 L=L .i 7 rt = N 7Ln _' rl N U1 N a K 0 Y 0 O V O v Y 'n ,rvl O N 0 tn 0 E E C a m a w a m a m a m a ca a m a m 3 C7 a C7 ¢ ¢ rn m m o~r m m ty in 0 3z u, N m a m 1 a Q a o a a ra o n 0. a > o 2 II f 3 4 5 - I 6 r� �Y 7 s 9 L' 10 L •� 11 Si 12 PH Adjustment Log for Preserved Samples Sample 1D Type of Preservative pH upon receipt Hate preservation adjusted Time preservation Amount of Preservative adjusted added Lot $1 Note:-Whersevei there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina OENR Certificatilon Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 50 of 54 I -YaCE L V U r '.1a„llyie t,onaition upon Keceipt 1 Effective Date. 05/12/202205/12/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg *'"Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine u zT s_ W QJ N d v ca o, M 5 ru tK 4 a N Ln r ry .wE, a a m m 1 2 3 4 S 6 7 8 4 10 11 %2 Project # IWOI$:92637353PH. A118Du CLIENT: a Date: 12/CS/22 82-Joyce Eng rn ro _ � ? Z v Q1 'N a a a E ,`a o 0 = 4 IL ry m flp x .... r E N b m _ z 4 x a E Ln m m a " nzr u m E Ln a m M ^ z d z u ra E ,n a m ? ro L E w Z7 C7 }� m N = a v W C7 a V u_ E v .=y l7 a z ° y c O N M l7 a v Q O Y m E 4 �°_ a Y 4 r n a E o Ln UY lm7 a ¢ ? z n a E o O C7 a U o J E O o ry ry z > E Ci C7 > z ° R a > E O l7 a O 4 Y o > ; O ? Q s v O = Q O > a 11f t9 Q a > :Y a a m > I ro14 b Q m m L E sn a M e r9 v 0 ry a Va PH Adjustment Log for Preserved Samples Sample ID Type of Preservative[pH upon receipt Date preservation adjusted Time preservation Amount of Preservative adjusted added -" ; 221 N c; ro K S v m N CL ? N 2 C C z o c u a Z a ¢ E J V) Q O o E E vq a o 0 ry v Lot # Note: Wherjever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to tolina DENRCerJlicaiion Office (i.e, Out of hold, incorrect preservative, Out of temp, incorrect containers. he North Car Quaftrax ID. 69614 Page 2 of 2 Page 51 of 54 — Addresses —� Order By ; Company LaBella Associates, Inc. Contact Burbach, Van Email vburbach@labellapc.com Address 12-D Oak Branch Drive Address 2 City Greensboro State NC Zip 27407 Phone (336)323-0092 Iwo Pace Container Order #1006432 Ship To: Company LaBella Associates, Inc. Contact Burbach, Van Email vburbach@labellapc.com Address 12-D Oak Branch Drive Address 2 City Greensboro State NC Zip 27407 Phone (336)323-0092 Project Name Burke Co.-Kirksey Drive Due Date 1011912022 Profile 2327 Return To: Company Pace Analytical Charlotte Contact Baioni, Angela Email angela.baioni@pacelabs.com Address 9800 Kincey Ave. Suite 100 Address 2 City Huntersville State NC Zip 28078 Phone (704)87..,-an4,2 Project Manager Baioni, Angela Return Date Carrier Courier-Huntersville 1 1lp oianKS X❑ Include Trip Blanks Return Shipping Labels El No Shipper With Shipper I tions er of Blanks rinted # of Samples Matrix Test _ Container Dome !_abets Blank Pre -Printed No Sample IDS X7 Pre -Printed With Sample IDS - Misc Quote Location NC uUmt:s Boxed Cases Individually Wrapped XI Grouped By Sample ID/Matrix Sampling Instructions Extra Bubble Wrap Custody Seal Short Hold/Rush Stickers Temp. Blanks XX DI Water 1L Liter{s) X❑ Coolers USDA Regulated Soils Syringes Total # of Lot # Notes Hazard Shipping Placard In Place : NO iample receiving hours are Mon -Fri 8:00am-6:00pm and Sat via Fedex only unless special arrangements are made LAB USE: Date ; ith your project manager. 'ace Analytical reserves the right to return hazardous, toxic, or radioactive samples to you. Prepared By: 'ace Analytical reserves the right to charge for unused bottles, as well as cost associated with sample storage/disposal. 'ayment term are net 30 days. Verified By; lease include the proposal number on the chain of custody to insure proper billing. Sample ALL-C-009-rev.00, 19Dec2016 Page 1 of 1 CLIENT USE (Optional): Date Rec'd; Received By; Verified By: Page 52 o 54 12 WT NC App I Metals 1-250mi Plastic HNO3 12 12 WT NC App I VOCs 8260 3-40m1 A Amber Glass Vials HCL 0 38 12 WT 8260 SIM-1,4-dioxane 3-46m1 Amber Glass Vials HCL 0 36 0 1 WT NC App I VOCs-trip blank 2x40ml amber vials with HCL. Di 1 WT 8260 51M-1,4-dioxane-trip blank water, custod seal 2x40m1 amber vials with HCL, DI 2 0 water, custody seal 2 0 CHAIN -OF -CUSTODY / Analytical Request Document is LEGAL DOCUMENT. All relevant fields must completed accurately. aee The Chain-ef-Custody a la Terms and Conditions found at https:Ninfo.pacebs.comlhubfslpas-standard-terms.pdf. Submitting a sample via this chain of custo constitutes acknowledgment and acceptance of the Pace [—page Section B Section C Of 2 � 2 Required Pr jest Information: Invoice Information: ent Information: ttenLon: Lali Associates. Inc. ape" To: opy To: VanBurbach ompany Name Re ulato A enc 12-D Oak Branch Drive tldress'. NC 27407 urchase O der 9: ace Quote'. State I Location irbach(Nlabellape.com roject Nam pace Project Manager. angeia.baioni@pacelabs_com, Burke Co,-Kirksey Drive NC [3361323-0042 Fax: ace Profile #: 2327 7ue Date: roject #', Re uested Analysis Filtered YIN Z O COLLECTED Preservatives >' MATRIX CODE V z _ s a o+ long w,w Dw Wamr WT Waste Ws+cr Ww — 4 N cp � n r SAMPLE ID a,I+sole aL Oo O� END C7 START ¢ `o N �- W O 1 O v One Character per box. w pc wP �„ AR wo a aroi a z 7 - F m 7, z w (A-Z, 0-9 f, -) ou,cr OT TS n r n O M a w o m Sample Ids must be unique Tissue x w � a c � w O cn 2 vi ;° r`� 4 ¢ o ¢ o d C N Q O N �_ a CJ U N U N s uQi DATE p N Z U z Z m Z d TIME DATE TIME < O = Y = z z t O ME F 4 �/ f II I Ix x 1201-Trip Blank ADDITIONAL COMMENTS RELINouisHED BY I AFFILIATION i DATE 1 TIME PLER NAME AND SIGNATURE PRINT Name of SAMPLER: SIGNATURE of SAMPLER. ACCEPTED By 1 AFFILIATION DATE TIME SAMPLE CONDITIONS Uc u m DATE Signed: F 1cm } ff�CiZ IFS/ ,ace nti z�n nF CHAIN -OF -CUSTODY ! Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. Ail relevant fields must be completed accurately. ­r,n ram ack—wied rrent and 2cce tance of the Pace Terms and Conditions found at httoS:llinfo.oacelabs-comlhubfs/pas-standard-terms.pdf �U ri ., ,g ...._...__,... ..__ Section E Section C :2:] Client Information: Required Project Information: Invoice Information: Page: 1 Of Van Burbach enlion:12-D mpany Name: LaBelle Associates. Inc RePort To Oak Branch Drive uPy To re, NC 27407 dress: [arelProfile#: Reulato Agency,burbach@labellapc.com urchase rder #� ce Quote: (336)323-0092 Fax: roject N me: Burke Co.-Kirksey Drive ce Project Manager: argela baioni pacelabs.cam, State f Location i Due Date: rojecs #: 2327 NC Requestod Analysis Filtered IN Z m o a COLLECTED Z Preservatives } — MATRIX CODE bnnking Wales pW U U O V a Warm Wr m 10 _ z Wesie Warm WW SAMPLE ID S°'ISa,d SL qi O� = _ ¢ " START END ° One Character per box. arm AP a a z a D O v (A-Z, 0.9 I , -j Otncr oT r w m 7 > '- U Sample Ids must 6e unique Tissue TS u a ..W z o p r d C ¢ ¢ o ¢ o a V1 L/k ~ T O a C N O Z _ U N N Q U U N U ry ¢ _ ran DATE TIME DATE TIME , = z z O z z m z ro 1201-MW1 N 111 ; X X X � x X D 1201-MW2 N ilt4Ll913 is x to l 1201-MW35 et m451 So . x x x E�tt 1201-M W 3D Ln 1 1r i- t fir[ x X X �` 1201-MW4 6 / 1"IrV L 530 4� X X X ✓ 1201-MWs W (A i La �� X X x !E �'11'��lY X X 1201-MW65 1(A- O 4�f 1201-MW6D W EI tL l X X X !!V 1201-SW1 N to X X x `�`%i 1201-SW2 1 t �Q `2 1201-SW3 �S lIlk L iif�i5 1 �� 1201-Field Blank ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACC£PTEDBY) AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE —" C m m u m a c PRWT Name of SAMPLER: w z } y a z , } E ? } SIGNATURE of SAMPLER: DATE Signed: -. It i► 1S/zC Z - v LO LO LO m EL � / Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Background Downgradient Location MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.51 45.25 26.95 76.15 29.60 50.80 27.56 63.15 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1089.96 1051.23 1016.22 1022.76 1036.09 1101.77 1054.90 1053.09 6-May-20 - 1051.23 1017.08 1022.76 1036.09 1101.77 1055.25 1053.38 9-Nov-20 - 1051.08 1016.18 1022.76 1036.31 1102.20 1055.16 1053.30 4-May-21 - 1051.62 1016.35 1022.76 1037.38 1105.08 1055.35 1053.67 2-Nov-21 - 1051.02 1015.61 1022.76 1032.37 1101.29 1054.75 1053.00 3-Nov-21 14-Nov-22 1084.31 1031.98 994.95 946.61 1025.39 1086.63 1037.44 1001.85 1087.47 1050.48 1016.99 1021.90 1032.45 1096.31 1055.26 1053.34 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 Fixed 2022 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 pg/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA 6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 3.9 6.0 NS ND ND ND ND ND ND ND ND IMAC = 1 pg/L 4-Dec-18 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 3.9 5.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND NC2L = 1 pg/L 4-May-21 EPA 6010D 3.0 5.0 NS 3 J ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 3.0 5.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020B 0.8 3.0 ND ND ND ND ND ND ND ND -- 14-Nov-22 EPA 6020B 0.8 3.0 ND 1.1 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC21- - 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC21- = 10 Ng/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA6010D 5.0 10.0 NS ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND - 6-May-20 EPA 6010D 4.7 10.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020B 2.2 5.0 ND ND ND ND ND ND ND ND --- 14-Nov-22 EPA 6020E 2.2 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC21- - 2,000 Ng/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC2L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 NS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1,050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1,210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1,060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1,040 388 167 82.0 J 28.0 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 NS 1,470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 NS 1,240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 NS 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 NS 1,160 507 205 82.0 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 NS 1,040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6010D 2.5 5 NS 1,370 448 219 130 46.5 35.6 17.0 --- 6-May-20 EPA 6010D 3.5 5 NS 1,160 486 194 71.2 55.4 27.2 12.8 --- 9-Nov-20 EPA 6010D 3.5 5 NS 1,390 489 200 75.3 36.6 30.0 13.9 ND 4-May-21 EPA 6010D 3.5 5 NS 1,190 478 201 91.2 121 26.5 13.4 ND 2-Nov-21 EPA 6010D 3.5 5 NS 1,550 467 202 110 46.5 26.2 13.5 ND 17-May-22 EPA 6020B 0.7 5 91.9 1,620 412 177 71.6 26.7 38.9 34.2 --- 14-Nov-22 EPA6020B 0.7 5 159.0 1,400 495 215 81.6 25.9 48.4 14.0 ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.10 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND IMAC = 4 Ng/L (10/23/07) 4-Dec-18 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.2 1.0 NS ND ND ND ND 0.23 J ND ND --- 6-May-20 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND ND l = 4 ug/L 4-May-21 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 0.7 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020E 0.1 0.5 ND ND 0.1 J ND 0.061 J 0.064 J ND ND --- 14-Nov-22 EPA 6020B 0.1 0.5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NCA = 1.75 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC2L = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 NS 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 NS 2.0 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 6010D 0.4 1.0 NS ND 0.51 J ND ND ND ND ND --- 9-Nov-20 EPA 6010D 0.4 1.0 NS ND ND 0.62 J 0.58 J ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 0.4 1.0 NS ND ND ND ND ND 0.65 J ND ND 17-May-22 EPA 6020B 0.1 0.5 ND ND 0.26 J 0.12 J ND ND ND ND --- 14-Nov-22 EPA 6020B 0.1 0.5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC21- = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.0 5.0 NS ND ND ND 5.9 1.8 J ND ND -- 6-May-20 EPA 6010D 3.7 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 3.7 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 3.7 5.0 NS ND ND ND ND 8 ND ND ND 2-Nov-21 EPA 6010D 3.7 5.0 NS ND ND ND 4.3 J ND ND ND ND 17-May-22 EPA 6020B 1.1 5.0 ND 1.5 J 1.6 J ND 1.2 J ND ND ND --- 14-Nov-22 EPA 6020B 1.1 5.0 ND 1.8 J ND ND 1.3 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS - 70 Ng/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 pg/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS 102 20.2 ND ND ND 4.2 J ND ND IMAC = 1 ug/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 NS 119 12.3 ND 1.6 J 1.3 J ND ND - 6-May-20 EPA 6010D 3.6 5.0 NS 106 16.8 ND ND ND ND ND - 9-Nov-20 EPA 6010D 3.6 5.0 NS 122 14.2 ND ND ND ND ND ND NC21- = 1 Ng/L 4-May-21 EPA 6010D 3.6 5.0 NS 95.4 13.7 ND ND 8.7 ND ND ND 2-Nov-21 EPA 6010D 3.6 5.0 NS 116 12.4 ND ND ND ND ND ND 17-May-22 EPA 6020B 0.4 5.0 9.7 114 15.8 1.1 J 0.76 J 0.47 J 0.88 J ND - 14-Nov-22 EPA6020B 0.4 5.0 9.4 108 14.7 1.1 J 0.68 J 0.63 J 0.99 J ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6010D 2.1 5.0 NS 3.3 J ND ND 4.6 J ND ND ND --- 6-May-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 6010D 4.3 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.3 5.0 NS ND ND ND ND 6.2 ND ND ND 2-Nov-21 EPA 6010D 4.3 5.0 NS ND ND ND 4.5 J ND ND ND ND 17-May-22 EPA 6020B 1.0 5.0 2.4 J ND 3.4 J ND ND ND ND ND --- 14-Nov-22 EPA 6020B 1.0 5.0 3.8 J ND ND 1.8 J 1.1 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC21- - 15 Ng/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 NS 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 NS 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 NS ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 NS 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.6 5.0 NS 5.2 2.0 J ND ND ND ND ND - 6-May-20 EPA 6010D 4.5 5.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 4.5 5.0 NS 9.3 ND ND ND ND ND ND ND 4-May-21 EPA 6010D 4.5 5.0 NS ND ND ND ND 10.4 ND ND ND 2-Nov-21 EPA 6010D 4.5 5.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020B 0.9 1.0 ND ND ND ND ND ND ND ND -- 14-Nov-22 EPA 6020B 0.9 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC2L = 100 Ng/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND INS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 INS 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 INS 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 INS 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 INS 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 INS 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6010D 0.9 5.0 INS 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND --- 6-May-20 EPA 6010D 3.5 5.0 INS 14.4 5.4 24.1 ND ND ND ND --- 9-Nov-20 EPA 6010D 3.5 5.0 INS 21.7 4.9 J 27.1 ND ND ND ND ND 4-May-21 EPA 6010D 3.5 5.0 INS 14.4 ND 26.9 ND 5.6 ND ND ND 2-Nov-21 EPA 6010D 3.5 5.0 INS 20.5 5.3 28.9 ND ND ND ND ND 17-May-22 EPA 6020E 0.7 5.0 1.9 J 18.8 4.3 J 27.0 1.7 J ND ND ND --- 14-Nov-22 EPA6020B 0.7 5.0 2 J 17.7 3.4 J 28.7 1.6 J ND 8 ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC21- - 50 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC21- = 20 Ng/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA6010D 5.0 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND - 6-May-20 EPA 6010D 4.7 10.0 NS 9.2 J ND ND ND 7.2 J ND ND -- 9-Nov-20 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA6010D 4.7 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 6020B 1.4 5.0 ND ND ND ND ND ND ND ND --- 14-Nov-22 EPA 6020E 1.4 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC21- = 17.5 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC21L = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 INS ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 INS ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 INS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND -- 6-May-20 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND -- 9-Nov-20 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND ND 4-May-21 EPA 6010D 2.5 5.0 INS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 6010D 2.5 5.0 INS 5.6 2.6 J ND ND ND ND ND ND 17-May-22 EPA 6020B 0.4 5.0 ND ND ND ND ND ND ND ND -- 14-Nov-22 EPA 6020E 0.4 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS - 0.28 Ng/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 ug/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND (4.8) J ND ND 4.0 {ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 0.0 5.5 NS ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6020B 0.03 0.1 NS ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 NS ND ND ND ND ND ND ND ND IMAC = 0.2 pg,/L (10/1/10) 4-Dec-18 EPA 6020B 0.06 0.1 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 6020B 0.06 0.1 NS ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA 6020B 0.06 0.1 NS ND ND 0.061 J 0.060 J 0.16 ND ND -- 6-May-20 EPA 6020B 0.12 0.2 NS ND ND ND ND 0.20 ND ND --- Resample-> 16-Jul-20 EPA 6020B 0.12 0.2 NS NS NS NS NS ND NS NS --- 9-Nov-20 EPA 6020B 0.05 0.1 NS ND ND ND ND 0.11 ND ND ND NC21- = 2 ug/L 4-May-21 EPA 6020E 0.05 1 NS ND ND ND 0.058 J 0.67 J ND ND ND 2-Nov-21 EPA 6020B 0.05 0.47 NS ND ND ND ND 0.15 J ND ND ND 17-May-22 EPA 6020B 0.18 1 ND ND ND ND ND ND ND ND --- 14-Nov-22 EPA 6020B 0.18 1 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS - 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 NS 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 NS 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 NS 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND IMAC = 0.3 pg/L (10/1/10) 4-Dec-18 EPA 6010D 2.5 5.0 NS ND 3.0 J ND 6.0 ND ND ND ND Resample -> 8-Feb-19 EPA 6010D 2.5 5.0 NS -- -- --- ND -- - - 6-May-19 EPA 6010D 2.5 5.0 NS 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 NS 5.3 1.8 J ND 10.0 3.8 J ND ND --- Resample -> 23-Jan-20 EPA 6010D 1.3 5.0 NS 5.1 -- -- 2.3 J -- - -- 6-May-20 EPA 6010D 3.9 5.0 NS ND ND ND ND 7.2 ND ND - Resample -> 16-Jul-20 EPA 6010D 3.9 5.0 NS NS NS NS NS ND NS NS -- 9-Nov-20 EPA 6010D 3.9 5.0 NS -- 9.5 ND ND ND ND ND ND Resample -> 27-Jan-21 EPA 6010D 3.9 5.0 NS -- ND -- -- -- - -- NC2L = 7 pg/L 4-May-21 EPA 6010D 3.9 5.0 NS 7.3 ND ND 7.9 19.4 ND ND ND 2-Nov-21 EPA 6010D 3.9 5.0 NS 59.9 23.3 ND 9.9 5.1 ND ND ND 17-May-22 EPA6020B 1.9 10.0 ND ND 2.3 J ND ND ND ND 2.5 J -- 14-Nov-22 EPA6020B 1.9 10.0 ND 2.1 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NCA = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC2L = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 NS ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 NS ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 NS 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA6010D 5.0 10.0 NS ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 NS ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA6010D 3.9 10.0 NS ND ND ND 15.4 7.5 J ND 7.0 J - 6-May-20 EPA6010D 9.5 10.0 NS ND ND ND ND 12.6 ND ND -- 9-Nov-20 EPA6010D 9.5 10.0 NS ND 14.7 ND ND ND ND ND ND 4-May-21 EPA6010D 9.5 10.0 NS ND ND ND 10.6 34.6 ND ND ND 2-Nov-21 EPA6010D 9.5 10.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA6020B 7.0 10.0 81.5 ND 7.3 J ND ND ND ND ND -- 14-Nov-22 EPA6020B 7.0 10.0 47.3 ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC21- = 700 pg/L (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC2L = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 NS ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA8260 10.0 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 10.0 100 NS 484 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 10.0 25 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 8.2 25 NS 299 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 NS 105 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 6.2 25 NS 255 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 6.2 25 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 25.6 125 NS 1160 i ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 5.1 25 15.1 J ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 5.1 25 246.0 ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC21- - 1 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA8260 0.25 1.0 NS 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA8260 0.25 1.0 NS 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA8260 0.25 1.0 NS 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA8260B 0.25 1.0 NS 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA8260D 0.20 1.0 NS 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA8260D 0.15 1.0 NS 8.3 3.4 1.3 ND ND ND ND - 6-May-20 EPA8260D 0.15 1.0 NS 9.6 3.7 1.4 ND ND ND ND - 9-Nov-20 EPA8260D 0.15 1.0 NS 10.4 3.5 1.4 ND ND ND ND ND 4-May-21 EPA8260D 0.34 1.0 NS 9.7 3.6 1.6 ND ND ND ND ND 2-Nov-21 EPA8260D 0.34 1.0 NS 8.9 3.1 1.5 ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 7.6 3.7 1.4 ND ND ND ND ND 14-Nov-22 EPA8260D 0.34 1.0 0.89 J 7.8 3.4 1.4 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte mA Collection Date JL Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC21- = 700 Ng/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 1.2 100 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 1.2 2 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.8 10 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.4 2 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.6 10 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.7 2 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.4 2 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.4 2 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA8260 0.23 3.0 NS 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA8260 0.23 3.0 NS 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA8260 0.23 3.0 NS 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.23 1.0 NS 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 NS 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 NS 22.5 32.7 7.5 ND ND 0.28 J ND -- 6-May-20 EPA 8260D 0.23 1.0 NS 26.7 32.3 8.2 ND ND ND ND -- 9-Nov-20 EPA 8260D 0.23 1.0 NS 24.7 32.7 8.0 ND ND ND ND ND 4-May-21 EPA 8260D 0.28 1.0 NS 22.1 35.9 8.7 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.28 1.0 NS 24.5 32.3 8.8 ND ND ND ND ND 17-May-22 EPA 8260D 0.28 1.0 ND 27.2 33.8 9.0 ND ND ND ND ND 14-Nov-22 EPA 8260D 0.28 1.0 ND 27.5 30.0 8.9 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 2,800 pWL (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC21- = 3,000 ug/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA8260 0.54 10.0 NS ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA8260 0.54 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.54 10.0 NS ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.54 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.52 1.0 NS ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.49 1.0 NS ND 1.6 ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.49 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 3.20 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.65 1.0 NS ND 1.7 ND ND ND ND ND ND 17-May-22 EPA 8260D 0.65 1.0 ND ND 1.1 ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.65 1.0 ND ND 0.9 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte MM Collection Date Method RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-613 Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21- = 70 Ng/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA8260 0.14 5.0 NS ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA8260 0.14 5.0 NS ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA8260 0.14 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.14 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.58 1.0 NS ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 2.30 5.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 7.80 25.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.43 1.0 NS ND ND ND ND ND 0.88 J ND ND 17-May-22 EPA 8260D 0.43 1.0 ND ND ND ND ND ND 0.89 J ND ND 14-Nov-22 EPA 8260D 0.43 1.0 ND ND ND ND ND ND 0.81 J ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 43 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte MM Collection Date Method RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-613 Blanks Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21- = 2.6 Ng/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 ug/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA8260 0.11 1.0 NS 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.11 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.11 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.39 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.54 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.54 1.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.54 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC21- = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 NS 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 NS 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 NS 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 NS 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 NS 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 2.2 0.6 J ND ND ND ND ND -- 6-May-20 EPA 8260D 0.29 1.0 NS 2.2 0.64 J ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.29 1.0 NS 2.2 0.62 J ND ND ND ND ND ND 4-May-21 EPA 8260D 1.70 5.0 NS 1.7 J 0.66 J ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 NS 2.1 0.49 J ND ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 2.2 0.54 J ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.34 1.0 ND 2.1 0.53 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte MA Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC21- - 1.4 pg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC2L = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA8260 0.33 1.0 NS 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA8260 0.33 1.0 NS 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA8260 0.33 1.0 NS 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA8260B 0.33 1.0 NS 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 NS 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA8260D 0.26 1.0 NS 38.6 10.7 4.2 0.48 J ND ND ND - 6-May-20 EPA8260D 0.26 1.0 NS 39.0 10.7 4.1 ND ND ND ND - 9-Nov-20 EPA8260D 0.26 1.0 NS 37.7 10.9 3.9 ND ND ND ND ND 4-May-21 EPA8260D 0.33 1.0 NS 38.4 10.4 3.9 ND ND ND ND ND 2-Nov-21 EPA8260D 0.33 1.0 NS 33.7 9.0 3.9 ND ND ND ND ND 17-May-22 EPA 8260D 0.33 1.0 ND 37.5 10.6 3.8 ND ND ND ND ND 14-Nov-22 EPA8260D 0.33 1.0 2.1 37.3 9.9 3.8 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte MA Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC21- - 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA8260 0.32 5.0 NS 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA8260 0.32 5.0 NS 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA8260 0.32 5.0 NS ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 NS 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA 8260D 0.41 1.0 NS 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.27 1.0 NS 0.57 J 0.43 J 4.7 1.5 ND ND ND -- 6-May-20 EPA 8260D 0.27 1.0 NS 0.61 J ND 4.8 0.48 J ND ND ND -- 9-Nov-20 EPA 8260D 0.27 1.0 NS ND ND 5.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.80 5.0 NS ND ND 5.8 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.37 1.0 NS 0.49 J ND 5.5 0.65 J ND ND ND ND 17-May-22 EPA 8260D 0.37 1.0 ND 0.38 J ND 4.4 0.39 J ND ND ND ND 14-Nov-22 EPA 8260D 0.37 1.0 ND 0.43 J ND 5.1 0.54 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte mA Collection Date Metho RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC21- = 0.4 Ng/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.24 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.67 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.34 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA8260D 0.34 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA8260D 0.34 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte mA Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC21- - 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 pg/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.56 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.56 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.72 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 NS ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND -- 9-Nov-20 EPA8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA8260D 1.70 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA8260D 0.35 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA8260D 0.35 1.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA8260D 0.35 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Collection Date Method RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B Mod. 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 2L = 3 pg/L 6-May-19 EPA 8260D Mod. 5.8 10 NS 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 EPA 8260DMod. 1.2 2 3.0 236 36.4 269 2.7 ND ND ND - 6-May-20 EPA 8260DMod. 5.8 10 NS 213 33.3 111 ND ND ND ND - 9-Nov-20 EPA 8260DMod. 1.2 2 NS 260 49.6 114 ND ND ND ND ND 4-May-21 EPA 8260DMod. 0.9 2 NS 187 41.5 110 ND ND ND ND ND 2-Nov-21 EPA 8260DMod. 0.9 2 NS 279 34.1 95.7 ND ND ND ND ND 17-May-22 EPA 8260DMod. 0.9 2 ND 275 23.2 95.9 ND ND ND ND ND 14-Nov-22 EPA 8260DMod. 0.9 2 ND 256 31.9 96.7 1.3 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC21- - 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 NS 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 NS 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 NS ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 NS 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 NS ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 NS 0.33 J ND 14.6 J 8.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 NS 0.41 J ND 16.4 2.6 ND ND ND --- 9-Nov-20 EPA 8260D 0.29 1.0 NS ND ND 21.2 3.5 ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 21.3 2.1 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 NS ND ND 22.9 5.6 ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND 22.1 2.6 ND ND ND ND 14-Nov-22 EPA 8260D 0.38 1.0 0.7 J ND ND 25.3 4.9 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents A Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC21- = 100 ug/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.49 5.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.49 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.46 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.25 1.0 NS ND ND ND ND ND ND ND - 6-May-20 EPA8260D 0.25 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA8260D 0.25 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 2.00 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA8260D 0.40 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA8260D 0.40 1.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA8260D 0.40 1.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte MM Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NCA = 0.51 ug/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC2L = 0.6 Ng/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA8260 0.27 1.0 NS ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA8260 0.27 1.0 NS ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 NS ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 NS ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 NS ND ND 0.87 J ND ND ND ND -- 6-May-20 EPA 8260D 0.19 1.0 NS ND ND 0.84 J ND ND ND ND -- 9-Nov-20 EPA 8260D 0.19 1.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 NS ND ND 0.63 J ND ND ND ND ND 2-Nov-21 EPA 8260D 0.36 1.0 NS ND ND 0.72 J ND ND ND ND ND 17-May-22 EPA 8260D 0.36 1.0 ND ND ND 0.75 J ND ND ND ND ND 14-Nov-22 EPA 8260D 0.36 1.0 ND ND ND 0.67 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC21- - 550 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC2L = 600 pg/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.30 1.0 NS 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.30 1.0 NS 10.5 ND ND ND ND ND ND ND 14-May-18 EPA8260 0.30 1.0 NS 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.45 1.0 NS 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.26 1.0 NS 12.1 ND ND ND ND ND ND - 6-May-20 EPA8260D 0.26 1.0 NS 17.0 ND ND ND ND ND ND -- 9-Nov-20 EPA8260D 0.26 1.0 NS 10.9 ND ND ND ND ND ND ND 4-May-21 EPA8260D 0.30 1.0 NS 20.3 ND ND ND ND ND ND ND 2-Nov-21 EPA8260D 0.30 1.0 NS 10.7 ND ND ND ND ND ND ND 17-May-22 EPA8260D 0.30 1.0 ND 8.4 0.42 J ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.30 1.0 ND 7.1 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS - 280 Ng/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND IMAC = 40 Ng/L 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.46 50.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.46 50.0 NS 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.46 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.89 5.0 NS 8.0 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.57 5.0 NS ND ND ND ND ND ND ND ND NCA = 40 Ng/L 4-May-21 EPA 8260D 2.40 25.0 NS 6.4 J ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.48 5.0 -- ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.48 5.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.48 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte mA Collection Date Meth RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks lodonnethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC21- = NE Ng/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.32 10.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.32 5.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.10 10.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 12.50 20.0 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 48.60 100.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 9.70 20.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 9.70 20.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 9.70 20.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 ug/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.97 1.0 INS ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA8260 0.97 1.0 INS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.97 1.0 INS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.97 1.0 INS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 INS ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA 8260D 3.70 5.0 INS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 3.70 5.0 INS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 3.70 5.0 INS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 9.80 25.0 INS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 2.00 5.0 INS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 2.00 5.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 2.00 5.0 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC21- - 4,200 Ng/L (10/23/07) 28-Nov-07 NR 100 18.0 J ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC2L = 4,000 pg/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.96 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.96 100 NS 268 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.96 5 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.20 5 NS 448 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 3.30 5 NS 14.8 ND ND ND ND ND ND - 6-May-20 EPA 8260D 3.30 5 NS 222 ND ND ND ND ND ND -- 9-Nov-20 EPA 8260D 3.30 5 NS ND ND ND ND ND ND ND ND 4-May-21 EPA 8260D 19.80 25 NS 1190 Ml ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 4.00 5 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 4.00 5 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 4.00 5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS - 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND IMAC = 100 pg/L 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.33 100 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.33 100 NS 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.33 5 NS 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.86 5 NS 311 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 4.50 5 NS 11.2 ND ND ND ND ND ND - 6-May-20 EPA 8260D 4.50 5 NS 187 ND ND ND ND ND ND - 9-Nov-20 EPA 8260D 4.50 5 NS 7.0 ND ND ND ND ND ND ND NCA = 100 pg/L 4-May-21 EPA 8260D 2.70 5 NS 616 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 2.70 5 NS 5.0 ND ND ND ND ND ND ND 17-May-22 EPA 8260D 2.70 5 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 2.70 5 ND ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 pWL (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA8260 0.46 1.0 NS ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA8260 0.46 1.0 NS ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA8260 0.46 1.0 NS ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA8260B 0.46 1.0 NS ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 NS ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 NS ND ND 6.5 1.8 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 NS ND ND 8.1 0.69 J ND ND ND --- 9-Nov-20 EPA 8260D 0.16 1.0 NS ND ND 8.5 ND ND ND ND ND 4-May-21 EPA 8260D 1.50 5.0 NS ND ND 8.7 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.29 1.0 NS ND ND 7.7 0.49 J ND ND ND ND 17-May-22 EPA 8260D 0.29 1.0 ND ND ND 9.1 ND ND ND ND ND 14-Nov-22 EPA 8260D 0.29 1.0 ND ND ND 8.4 0.47 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date JL Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC21- = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC21- = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND - 2-May-16 EPA8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.26 1.0 NS 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA8260 0.26 1.0 NS 1.1 ND ND ND ND ND ND ND 14-May-18 EPA8260 0.26 1.0 NS 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.26 1.0 NS 0.91 J ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.31 1.0 NS 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS 1.1 ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS 2.5 ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS 0.90 J ND ND ND ND ND ND ND 4-May-21 EPA 8260D 0.48 1.0 NS 6.80 ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.48 1.0 NS 1.00 ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.48 1.0 ND 1.00 ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.24 1.0 ND 0.84 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 pWL (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA8260 0.47 1.0 NS ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA8260 0.47 1.0 NS ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA8260 0.47 1.0 NS ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA8260B 0.47 1.0 NS ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 NS ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 NS ND ND 4.8 0.72 J ND ND ND - 6-May-20 EPA 8260D 0.22 1.0 NS ND ND 5.0 ND ND ND ND - 9-Nov-20 EPA 8260D 0.22 1.0 NS ND ND 5.4 ND ND ND ND ND 4-May-21 EPA 8260D 1.90 5.0 NS ND ND 6.2 ND ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 NS ND ND 5.7 ND ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND 6.4 ND ND ND ND ND 14-Nov-22 EPA 8260D 0.38 1.0 ND ND ND 6.2 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NCA = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC2L=0.03Ng/L(01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA8260 0.62 1.0 INS ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA8260 0.62 1.0 INS ND ND 1.1 ND ND ND ND ND 14-May-18 EPA8260 0.62 1.0 INS ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA8260B 0.62 1.0 INS ND ND 1.2 ND ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 INS ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 INS ND ND ND ND ND ND ND - 6-May-20 EPA 8260D 0.24 1.0 INS ND ND 0.88 J ND ND ND ND -- 9-Nov-20 EPA8260D 0.24 1.0 INS ND ND ND ND ND ND ND ND 4-May-21 EPA8260D 1.90 5.0 INS ND ND 1.1 ND ND ND ND ND 2-Nov-21 EPA8260D 0.39 1.0 INS ND ND 1.1 ND ND ND ND ND 17-May-22 EPA8260D 0.39 1.0 ND ND ND 1.1 ND ND ND ND ND 14-Nov-22 EPA8260D 0.39 1.0 ND ND ND 1.2 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 g MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC21- = 530 Ng/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC21L = 500 pg/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 INS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA8260 0.66 5.0 INS 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA8260 0.66 5.0 INS 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA8260 0.66 5.0 INS 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.66 1.0 INS 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 8260D 1.50 2.0 INS 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.63 1.0 INS 22.3 14.3 ND ND ND ND ND --- 6-May-20 EPA 8260D 0.63 1.0 INS 34.0 15.1 ND ND ND ND ND -- 9-Nov-20 EPA 8260D 0.63 1.0 INS 20.8 15.0 ND ND ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 INS 51.5 9.5 ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 INS 18.2 13.3 ND ND ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND 16.0 43.1 ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.34 1.0 ND 13.6 25.3 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 42 of 43 Labelle Associates TABLE A2-2: Historical Groundwater Constituents Analyte M Collection Date Meth RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND NS ND ND ND ND ND IMAC = 1 Ng/L 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.29 1.0 NS ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.58 2.0 NS ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.29 1.0 NS ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.59 1.0 NS ND ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 6-May-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND --- 9-Nov-20 EPA 8260D 0.24 1.0 NS ND ND ND ND ND ND ND ND NC21- - 0.6 Ng/L 4-May-21 EPA 8260D 1.60 5.0 NS ND ND ND ND ND ND ND ND 2-Nov-21 EPA 8260D 0.32 1.0 NS ND ND ND ND ND ND ND ND 17-May-22 EPA 8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND 14-Nov-22 EPA 8260D 0.32 1.0 ND ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. NA = No data available. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NR = Not reported. NC21- = North Carolina Groundwater Standards from 15A NCAC 2L.0202. NI = Not installed. GWPS = Groundwater Protection Standards established by the SWS for constituents with no listed NC21- standard (no longer used). NE = Not established. IMAC = Interim Maximum Allowable Concentration. NS = Not sampled. Bold values are greater than the NC21-, GWPS, or IMAC. Dry = Insufficient water column to sample. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 43 of 43 Labelle Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Well Depth [ft] - 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25 °C) 11-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [MS/CM] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 - 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 - 2185.0 920 875 99 25 97 114 14-May-18 - 1658.0 1117 923 131 22.2 118 59 4-Dec-18 - 1604.0 776 661 70 48 64.3 92.8 Resample-> 8-Feb-19 - - - - 55.9 - - - 6-May-19 - 1923 916 792 59.6 23.3 50.6 85.6 Resample-> 23-Jul-19 - - - 1454 - - - - 4-Nov-19 - 2225 831 853 92.1 18.3 59.3 90 6-May-20 - 2226 913 842 59 19.2 80.4 101.5 Resample-> 16-Jul-20 - - - - - 16.6 - -- 9-Nov-20 - 2044 803 752 72.8 15.8 53.5 88.5 Resample-> 27-Jan-21 - - 757 - - - - -- 4-May-21 - 1506.0 593 632.0 67.0 43.9 45.2 74.2 2-Nov-21 - 3069 931 1002 112.6 25.6 75.9 122.7 17-May-22 4420.0 2781 881 890 99.3 19.7 77.3 109.9 14-Nov-22 690.0 2535 973 916 110.6 23.5 76.7 100.3 pH 11-Jun-13 5.9 6.1 6.36 - 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 -- 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 - 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 - 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample-> 8-Feb-19 - - - - 5.64 - - -- 6-May-19 - 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample-> 23-Jul-19 - - - 6.00 - -- - -- 4-Nov-19 - 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6-May-20 - 6 6.35 6.59 5.66 5.47 5.8 6.44 Resample--> 16-Jul-20 - - - - -- 5.55 - -- 9-Nov-20 - 6.11 6.37 6.19 5.44 5.50 5.88 6.16 Resample--> 27-Jan-21 - 6.65 -- -- -- - -- 4-May-21 5.8 5.96 6.0 6.5 7.2 6.3 5.76 2-Nov-21 -- 5.14 6.12 5.05 5.77 5.89 5.85 5.96 17-May-22 5.9 5.95 6.12 6.29 6.64 6.69 6.34 6.21 14-Nov-22 5.4 5.60 6.37 5.65 7.18 6.70 5.60 6.00 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 1 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 [ ° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 - 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 - 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 - 15.3 14.6 13.9 14 14 13.3 14.5 Resample-> 8-Feb-19 - - - - 15.2 - - -- 6-May-19 - 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample-> 23-Jul-19 - - - 17.3 - -- - -- 4-Nov-19 - 15.1 13 16.4 14.7 15.3 16.4 16.4 6-May-20 - 16 16 16.7 14.6 16 13.3 14.2 Resample-> 16-Jul-20 - - - -- - 20.9 - - 9-Nov-20 - 17.0 17.4 16.6 15.9 16.2 17.5 15.1 Resample-> 27-Jan-21 - - 15.1 -- - -- - -- 4-May-21 - 16.9 14.9 16.4 15.6 16.1 13.8 15.6 2-Nov-21 - 16.8 15.7 16.4 14.2 14.9 16.1 15.0 17-May-22 16.5 17.1 16.7 16.9 16.9 17.6 14.6 15.4 14-Nov-2 2 13.6 15.3 15.7 15.8 14.6 14.3 14.7 13.9 Dissolved Oxygen 6-May-19 - 0.92 3.59 1.09 5.18 5.73 5.44 2.13 [mg/L] 23-Jul-19 - -- - 0.91 - - - - 4-Nov-19 - 1.63 1.85 4.39 3.99 4.36 3.55 2.89 6-May-20 - 5.06 4.71 5.14 6.7 1.85 5.74 4.33 Resample-> 16-Jul-20 - - - - - 7.37 - -- 9-Nov-20 - 1.65 1.29 1.21 3.66 9.03 6.00 1.19 Resample-> 27-Jan-21 - - 1.68 -- - -- - -- 4-May-21 - 1.4 1.97 1.2 7.1 10.3 9.07 0.98 2-Nov-21 - 1.06 1.87 6.52 1.73 7.57 4.31 0.90 17-May-22 5.2 2.33 1.89 5.09 7.10 9.63 7.92 1.71 14-Nov-22 4.8 1.20 1.66 52.27 1.90 7.00 4.10 3.40 Oxidation Reduction Potential 6-May-19 - 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 - - - 210.5 - - - -- 4-Nov-19 - 33.3 85.4 180.3 199 146.4 208.3 -81.6 6-May-20 - 218.2 272.5 323 192.5 300.9 192 201.5 Resample-> 16-Jul-20 - - - - - 282.3 - -- 9-Nov-20 - 0.6 -24.7 1.4 199.9 202.3 230.1 63.1 Resample-> 27-Jan-21 - - -22.8 -- - -- - -- 4-May-21 - 40.4 60.8 194.8 98.3 164.7 127.5 109.6 2-Nov-21 - -30.4 64.7 116.0 56.9 110.9 83.2 -43.1 17-May-22 163.4 76.1 51.1 62.2 116.4 121.5 138.0 115.3 14-Nov-22 54.2 -228.5 -211.8 -250.7 -211.8 -159.7 131.8 45.2 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 2 of 3 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 - 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 - 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 - 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 - 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample-> 8-Feb-19 - - - - 7.96 - - -- 6-May-19 - 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample-> 23-Jul-19 - -- - 3.12 - -- - -- 4-Nov-19 - 4.79 9 3.01 35.17 41.15 8.49 30.39 6-May-20 - 8.25 8.12 12.17 97.58 356.5 79.08 3.74 Resample-> 16-Jul-20 - - - - - 13.23 - -- 9-Nov-20 - 6.18 14.0 6.26 8.57 11.4 4.82 8.84 Resample-> 27-Jan-21 - - 8.5 - - - - - 4-May-21 - 8.7 8 4.0 30.1 91.6 20.4 5.25 2-Nov-21 - 6.93 33.7 1.55 65.5 150 18.6 2.23 17-May-22 26.1 576.00 14.7 2.54 10.3 26 7.8 2.65 14-Nov-22 50.1 11.30 11.4 4.50 14.3 21.5 9.0 1.90 Notes: °C= degrees Centigrade mg/L = milligrams per liter S.U.= Standard Units my = millivolts pS = microSemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 3 of 3 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.7 10.0 ND ND ND ND 17-May-22 EPA 6020B 2.2 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 2.2 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Barium 28 Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2,000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10.0 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.50 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.20 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.80 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.30 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.70 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 EPA 6010 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 EPA 6010 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 EPA 6010 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 EPA 6010 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 EPA 6010 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 EPA 6010 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 EPA 6010 2.5 100 38.1 J 38.0 J 301 2.50 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 EPA 6010 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 EPA 6010D 2.5 5 33.1 32.0 267 ND 6-May-19 EPA 6010D 2.5 5 26.4 26.2 239 ND 5-Nov-19 EPA 6010D 2.5 5 34.5 35.9 34.8 --- 6-May-20 EPA 6010D 3.5 5 31.9 28.7 32.3 --- 9-Nov-20 EPA 6010D 3.5 5 34.0 33.7 32.0 ND 4-May-21 EPA 6010D 3.5 5 34.1 38.6 36.1 ND 2-Nov-21 EPA 6010D 3.5 5 30.5 31.8 30.8 ND 17-May-22 EPA 6020B 0.7 5 34.2 30.9 34.2 --- 14-Nov-22 EPA 6020B 0.7 5 36.3 221.0 37.3 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28 Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 ug/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 EPA 6010 1.0 1.0 ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND Dry NA 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND NS ND 26-Jun-17 EPA 6010 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 ND ND ND ND 5-Nov-19 EPA 6010D 0.5 1.0 ND ND ND --- 6-May-20 EPA 6010D 0.4 1.0 ND ND ND --- 9-Nov-20 EPA 6010D 0.4 1.0 ND ND ND ND 4-May-21 EPA 6010D 0.4 1.0 ND ND ND ND 2-Nov-21 EPA 6010D 0.4 1.0 ND ND ND ND 17-May-22 EPA 6020B 0.1 0.5 ND ND ND --- 14-Nov-22 EPA 6020B 0.1 0.5 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.00 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.3 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.3 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 2.8 J ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.7 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.7 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.7 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.7 5.0 ND ND ND ND 17-May-22 EPA 6020B 1.1 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 1.1 5.0 ND 1.50 J ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28 Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC2B = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 6 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 3.6 J ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.6 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.6 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.6 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.6 5.0 ND ND ND ND 17-May-22 EPA 6020B 0.4 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 0.4 5.0 ND 1.80 J ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND 6.4 J ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND 3.0 J ND 2-May-16 EPA 6010 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 4.3 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.3 5.0 ND ND ND ND 4-May-21 EPA 6010D 4.3 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.3 5.0 ND ND ND ND 17-May-22 EPA 6020B 1.0 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 1.0 5.0 ND 2.90 J ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 4.1 J ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 4.5 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.5 5.0 ND ND ND ND 4-May-21 EPA 6010D 4.5 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.5 5.0 ND ND ND ND 17-May-22 EPA 6020B 0.9 1.0 ND ND ND --- 14-Nov-22 EPA 6020B 0.9 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND ND 4.6 B 2.2 J NC2B = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 EPA 6010 5.0 50.0 ND ND 10.4 J ND 19-May-15 EPA 6010 2.5 50.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 50.0 ND ND 5.1 J ND 2-May-16 EPA 6010 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 EPA 6010 2.5 50.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND 5.9 ND 6-May-19 EPA 6010D 2.5 5.0 ND ND 6.3 ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 3.5 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.5 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.5 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 3.5 5.0 ND ND ND ND 17-May-22 EPA 6020B 0.7 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 0.7 5.0 ND 3.40 J ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC2B = 5 ug/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND NS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 4.7 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 4.7 10.0 ND ND ND ND 4-May-21 EPA 6010D 4.7 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 4.7 10.0 ND ND ND ND 17-May-22 EPA 6020B 1.4 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 1.4 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC2B = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 10.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 ND ND ND --- 6-May-20 EPA 6010D 2.5 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 2.5 5.0 ND ND ND ND 4-May-21 EPA 6010D 2.5 5.0 ND ND ND ND 2-Nov-21 EPA 6010D 2.5 5.0 ND ND ND ND 17-May-22 EPA 6020B 0.4 5.0 ND ND ND --- 14-Nov-22 EPA 6020B 0.4 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 EPA 6020B 0.1 0.1 ND ND 0.077 J --- 6-May-19 EPA 6020B 0.1 0.1 ND ND 0.11 ND 5-Nov-19 EPA 6020B 0.1 0.1 ND ND ND --- 6-May-20 EPA 6020B 0.1 0.1 ND ND ND --- 9-Nov-20 EPA 6020B 0.1 0.1 ND ND ND ND 4-May-21 EPA 6020B 0.1 1.0 ND ND ND ND 2-Nov-21 EPA 6020B 0.1 0.5 ND ND ND ND 17-May-22 EPA 6020B 0.2 1.0 ND ND ND --- 14-Nov-22 EPA 6020B 0.2 1.0 ND ND ND ND Vanadium 19-Nov-03 NR 40.0 62.00 56.00 60.00 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC2B = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 EPA 6010 5.0 25.0 ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 ND ND Dry NA 7-Dec-15 EPA 6010 2.5 25.0 ND ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 EPA 6010 2.5 25.0 ND ND NS ND 26-Jun-17 EPA 6010 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 1.4 J 1.5 J 1.5 J --- 6-May-20 EPA 6010D 3.9 5.0 ND ND ND --- 9-Nov-20 EPA 6010D 3.9 5.0 ND ND ND ND 4-May-21 EPA 6010D 3.9 5.0 5.40 6.40 5.70 ND 2-Nov-21 EPA 6010D 3.9 5.0 ND ND ND ND 17-May-22 EPA 6020B 1.9 10.0 2.50 J 2.90 J 3.20 J --- 14-Nov-22 EPA 6020B 1.9 10.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 EPA 6010 10.0 10.0 ND ND 10.3 ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND 18.0 ND 19-May-15 EPA 6010 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 EPA 6010 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 EPA 6010 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 EPA 6010 5.0 10.0 ND 8.0 J INS ND 26-Jun-17 EPA 6010 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 ND ND 7.4 J ND 6-May-19 EPA 6010D 5.0 10.0 ND ND ND ND 5-Nov-19 EPA 6010D 5.0 10.0 ND ND ND --- 6-May-20 EPA 6010D 9.5 10.0 ND ND ND --- 9-Nov-20 EPA 6010D 9.5 10.0 ND ND ND ND 4-May-21 EPA 6010D 9.5 10.0 ND ND ND ND 2-Nov-21 EPA 6010D 9.5 10.0 ND ND ND ND 17-May-22 EPA 6020B 7.0 10.0 ND ND ND --- 14-Nov-22 EPA 6020B 7.0 10.0 ND 16.40 ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Beryllium 5-Nov-19 EPA 6010D 0.2 1.0 ND 0.24 J ND --- 6-May-20 EPA 6010D 0.7 1.0 ND ND ND --- 9-Nov-20 EPA 6010D 0.7 1.0 ND ND ND ND 4-May-21 EPA 6010D 0.7 1.0 ND ND ND ND 2-Nov-21 EPA 6010D 0.7 1.0 ND ND ND ND 17-May-22 EPA 6020B 0.1 0.5 ND ND ND --- 14-Nov-22 EPA 6020B 0.1 0.5 ND ND ND ND ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 EPA 8260 10.0 100 ND ND 17.6 J ND 21-Oct-14 EPA 8260 10.0 100 ND ND ND ND 19-May-15 EPA 8260 10.0 100 ND ND Dry NA 7-Dec-15 EPA 8260 10.0 100 ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 ND ND INS ND 26-Jun-17 EPA 8260 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 EPA 8260 10.0 100 ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 ND ND ND ND 6-May-19 EPA 8260D 8.2 25 ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 ND ND ND --- 6-May-20 EPA 8260D 6.2 25 ND ND ND ND 9-Nov-20 EPA 8260D 6.2 25 ND ND ND ND 4-May-21 EPA 8260D 5.1 25 ND ND ND ND 2-Nov-21 EPA 8260D 5.1 25 ND ND ND ND 17-May-22 EPA 8260D 5.1 25 ND ND ND ND 14-Nov-22 EPA 8260D 5.1 25 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 pg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.25 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.25 1.0 ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.20 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.15 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.15 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.15 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 EPA 8260 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 EPA 8260 0.29 10.0 ND ND 0.41 J ND 19-May-15 EPA 8260 0.29 10.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.29 10.0 ND ND ND ND 2-May-16 EPA 8260 0.29 10.0 ND ND ND ND 12-Dec-16 EPA 8260 0.29 10.0 ND ND NS ND 26-Jun-17 EPA 8260 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 EPA 8260 0.29 10.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.29 2.0 ND ND ND ND 6-May-19 EPA 8260D 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 EPA 8260D 0.62 2.0 ND ND ND --- 6-May-20 EPA 8260D 0.62 2.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.62 2.0 ND ND ND ND 4-May-21 EPA 8260D 1.70 2.0 ND ND ND ND 2-Nov-21 EPA 8260D 1.70 2.0 ND ND ND ND 17-May-22 EPA 8260D 1.70 2.0 ND ND ND ND 14-Nov-22 EPA 8260D 1.70 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 EPA 8260 0.23 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.23 3.0 ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND ND NS ND 26-Jun-17 EPA 8260 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.23 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.23 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.23 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.28 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.28 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.28 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.28 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14 Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.11 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 ND ND 0.19 J ND 19-May-15 EPA 8260 0.11 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.11 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.38 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.39 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.39 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.39 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.54 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.54 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.54 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.54 1.0 ND ND ND ND 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.30 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.30 5.0 ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.34 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.34 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.34 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.33 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.33 1.0 ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.33 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.58 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.26 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.26 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.26 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.33 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.33 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.33 1.0 ND ND ND ND 14-Nov-22 EPA 826OD 0.33 1.0 ND ND ND ND 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NC2B = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.32 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.32 5.0 ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND ND 4-Dec-18 EPA 826OB 0.32 1.0 ND ND ND ND 6-May-19 EPA 826OD 0.41 1.0 ND ND ND ND 5-Nov-19 EPA 826OD 0.27 1.0 ND ND ND --- 6-May-20 EPA 826OD 0.27 1.0 ND ND ND ND 9-Nov-20 EPA 826OD 0.27 1.0 ND ND ND ND 4-May-21 EPA 826OD 0.37 1.0 ND ND ND ND 2-Nov-21 EPA 826OD 0.37 1.0 ND ND ND ND 17-May-22 EPA 826OD 0.37 1.0 ND ND ND ND 14-Nov-22 EPA 826OD 0.37 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 EPA 8260 0.19 5.0 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.19 5.0 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 ND ND NS ND 26-Jun-17 EPA 8260 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.29 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.29 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.38 1.0 ND ND ND ND 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.27 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.19 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.19 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.19 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.36 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.36 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.36 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.36 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 EPA 8260B 1.90 2.0 ND ND 10.5 ND 6-May-19 EPA 8260D 1.20 2.0 ND ND 7.6 ND 5-Nov-19 EPA 8260D 1.20 2.0 ND ND ND --- 6-May-20 EPA 8260D 1.20 2.0 ND ND ND ND 9-Nov-20 EPA 8260D 1.20 2.0 ND ND ND ND 4-May-21 EPA 8260D 0.86 2.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.86 2.0 ND 1.40 J ND ND 17-May-22 EPA 8260D 0.86 2.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.86 2.0 ND 2.30 ND ND Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.46 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.78 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.16 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.16 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.16 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.29 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.29 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.29 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.29 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 19 of 21 TABLE A2-4: Historical Surface Water Constituents Analyte Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.47 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.34 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.22 1.0 ND ND ND --- 6-May-20 EPA 8260D 0.22 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.22 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.38 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.38 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.38 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.38 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 20 of 21 TABLE A2-4: Historical Surface Water Constituents Collection Date Method DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC2B = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 EPA 8260 0.62 1.0 ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND Dry NA 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND NS ND 26-Jun-17 EPA 8260 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 ND ND ND ND 6-May-19 EPA 8260D 0.60 1.0 ND ND ND ND 5-Nov-19 EPA 8260D 0.24 1.0 ND ND ND - 6-May-20 EPA 8260D 0.24 1.0 ND ND ND ND 9-Nov-20 EPA 8260D 0.24 1.0 ND ND ND ND 4-May-21 EPA 8260D 0.39 1.0 ND ND ND ND 2-Nov-21 EPA 8260D 0.39 1.0 ND ND ND ND 17-May-22 EPA 8260D 0.39 1.0 ND ND ND ND 14-Nov-22 EPA 8260D 0.39 1.0 ND ND ND ND Hardness, Total (SM 2340B) 6-May-20 EPA 6010D 131.00 662.0 25,300 22,600 25,100 Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; SWSL for December 2006 - 2017, and MRL 2017-present.). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). J = Estimated concentration less than the RL but above the DL. NA = No data available. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NR = Not reported. NC26 = 15A NCAC 2B Surface Water Standards. NS = Not sampled. Dry = Surface water point was considered to be dry and no sample collected. NE = Not established. Surface water has been classified as Water Supply IV- Highly Developed, Freshwater, Critical Area. Bold values are greater than the NC213. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 21 of 21 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25 °C) 11-Jun-13 54.4 63.2 655 [MS/cm] 29-Oct-13 78.2 67.8 - 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 - 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 - 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 6-May-20 77.0 76.8 76.8 9-Nov-20 68.4 69.6 74.5 4-May-21 61.1 54 79.8 2-Nov-21 115.4 100.0 112.0 17-May-22 92 110.3 112.9 14-Nov-22 189.2 523.9 106.9 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 - 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 - 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 6-May-20 7.5 7.43 7.43 9-Nov-20 6.32 7.09 7.18 4-May-21 6.93 6.62 6.76 2-Nov-21 7.32 6.86 6.22 17-May-22 6.99 6.99 7.10 14-Nov-22 7.30 6.80 6.80 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 1 of 3 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date sW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 - 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 - 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.07 10.6 10.7 6-May-20 14.4 17.2 17.2 9-Nov-20 16.2 17.1 17.1 4-May-21 16.2 16.2 16.5 2-Nov-21 11.6 13.6 13.9 17-May-22 20.2 19.5 19.9 14-Nov-22 10.3 9.5 10.4 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg1L) 4-Nov-19 7.23 6.56 7.27 6-May-20 5.2 4.89 4.89 9-Nov-20 7.86 7.82 6.65 4-May-21 9.35 8.79 7.62 2-Nov-21 8.52 7.23 6.88 17-May-22 6.47 7.3 6.72 14-Nov-22 8.60 9.42 8.7 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 6-May-20 326.9 214 214 9-Nov-20 219.9 37.8 7.1 4-May-21 30.1 43.9 4.7 2-Nov-21 -55.0 -17.1 -55.1 17-May-22 87.6 94.9 45.5 14-Nov-22 -154.0 -202 164.7 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 2 of 3 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 - 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 - 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 - 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 6-May-20 15.6 15.6 15.6 9-Nov-20 7.5 9.13 9.24 4-May-21 47.4 77.90 47.40 2-Nov-21 6.37 6.19 5.72 17-May-22 9.94 11.60 8.30 14-Nov-22 20.50 6.10 22.10 Notes: °C= degrees Centigrade pS/cm = microSemens per centimeter S.U.= Standard Units NTU = Nephelometric Turbidity Units my = millivolts mg/L - milligrams per liter Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 3 of 3