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HomeMy WebLinkAbout4101_Guilford_CityHighPoint_Riverdale_MSWLF_Seaboard_FiveYearReport_FID1773672_20230227FIRST FIVE-YEAR REVIEW REPORT FORMER SEABOARD CHEMICAL CORPORATION FACILITY AND RIVERDALE DRIVE LANDFILL SITE JAMESTOWN, NORTH CAROLINA EPA ID No. NCD071574164 Prepared by SEABOARD REMEDIAL ACTION TRUST c/o de maximis, inc. 1550 POND ROAD, SUITE 120 ALLENTOWN, PA 18103 2/27/2023 R. Craig Coslett, Project Coordinator Date Table of Contents LIST OF ABBREVIATIONS & ACRONYMS......................................................................................... 2 I. INTRODUCTION................................................................................................................................... 3 SiteBackground...................................................................................................................................... 3 FIVE-YEAR REVIEW SUMMARY FORM......................................................................................... 4 II. RESPONSE ACTION SUMMARY...................................................................................................... 5 ResponseActions.................................................................................................................................... 5 SiteRelated............................................................................................................................................. 6 ICSummary Table.................................................................................................................................. 6 Collection/Treatment System.................................................................................................................. 6 CollectionSystem(s)........................................................................................................................... 7 TreatmentSystem(s)........................................................................................................................... 7 IrrigationControls................................................................................................................................... 9 Statusof Implementation........................................................................................................................ 9 Systems Operations/Operation & Maintenance(O&M)....................................................................... 10 Inspections............................................................................................................................................ 11 III. PROGRESS SINCE THE LAST REVIEW....................................................................................... 11 IV. FIVE-YEAR REVIEW PROCESS.................................................................................................... 12 DataReview.......................................................................................................................................... 12 GroundwaterData................................................................................................................................. 12 SurfaceWater Data............................................................................................................................... 13 OperationalData................................................................................................................................... 15 SiteInspection....................................................................................................................................... 25 V. TECHNICAL ASSESSMENT............................................................................................................ 25 QUESTIONA....................................................................................................................................... 25 QUESTIONB....................................................................................................................................... 26 QUESTIONC....................................................................................................................................... 27 VI. ISSUES/RECOMMENDATIONS..................................................................................................... 27 VII. PROTECTIVENESS STATEMENT................................................................................................ 29 VIII. NEXT REVIEW.............................................................................................................................. 29 APPENDIX A — Reference List........................................................................................................... 30 APPENDIX B — Sample Copy of Weekly Log Checklist.................................................................... 31 FIGURE1 — Site Location Map........................................................................................................... 32 FIGURE2 — Site Features Map............................................................................................................ 33 FIGURE 3 — Process Flow Diagram..................................................................................................... 34 FIGURE4 — VOC Trend Graphs.......................................................................................................... 35 FIGURE 5 — 1,4-Dioxane Trend Graphs.............................................................................................. 36 1 LIST OF ABBREVIATIONS & ACRONYMS 2017 CCR 2017 Construction Completion Report AOC Administrative Order of Consent ARAR Applicable or Relevant and Appropriate Requirement CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CFR Code of Federal Regulations COC Constituent of Concern DB Pg Deed Book and Page DEQ North Carolina Department of Environmental Quality EPA United States Environmental Protection Agency GC ROD Guilford County Register of Deeds GPM Gallons Per Minute FYR Five -Year Review HMI Human Machine Interface ICs Institutional Controls LCHT Leachate LS Lift Station LUR Land Use Restriction NCP National Oil and Hazardous Substances Pollution Contingency Plan NIS Northern Intermittent Stream NPL National Priorities List O&M Operation and Maintenance PB Pg Plat Book and Page PC Project Coordinator PE Profession Engineer PG Professional Geologist PLC Programmable Logic Controller PRP Potentially Responsible Party RAO Remedial Action Objectives RCRA Resource ROD Record of Decision RPM Remedial Project Manager RW Recovery Well SITE Seaboard Chemical / Former Riverdale Drive Landfill SIS Southern Intermittent Stream SRM Soil Residue Mound TBC To be considered TM# Technical Memorandum (numbered 1 through 11) VOC Volatile Organic Compound I. INTRODUCTION As provided in Paragraph F of the Statement of Work, Exhibit A to the Declaration and Order (Docket # 08-SF-249), attached to the Remedial Action Settlement Agreement (RASA) dated December 29, 2008, for the Former Seaboard Chemical and Riverdale Drive Landfill Site, the purpose of a Five -Year Review (FYR) is to evaluate the effectiveness of the Approved Remedy and to assess whether the Approved Remedy remains effective and is protective of human health and the environment. This FYR has been prepared in substantial compliance with the United States Environmental Protection Agency's (EPA's) Comprehensive Five -Year Review Guidance and provided to the Division within 180 days of the end of each five-year reporting period, with the first reporting period commencing on the date the system was placed into operation. de maximis, inc., Babb and Associates, and Glover Engineering, PLLC have prepared this five-year review on behalf of the Settling Remediators to the RASA (the City of High Point, Seaboard Group Il and the Work Parties), pursuant to the paragraph F of the Statement of Work and in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) Section 121, consistent with the National Contingency Plan (NCP)(40 CFR Section 300.430(f)(4)(ii)), and considering EPA policy. This is the first FYR for the Former Seaboard Chemical Corporation Facility and Riverdale Drive Landfill Site. The triggering action for this review is the August 25, 2017 notice of System Operation. The FYR has been prepared due to the fact that hazardous substances, pollutants, or contaminants remain at the site above levels that allow for unlimited use and unrestricted exposure (UU/UE). The Former Seaboard Chemical Facility and Riverdale Drive Landfill Site Five -Year Review was led by R. Craig Coslett, Project Coordinator, Gary Babb, PG, and Rich Glover, PE. The relevant entities including the PRPs and NCDEQ representatives were notified of the initiation of the five-year review. The review covers the period of August 2017 through August 2022. Site Background The general vicinity and Site location are shown on Figure 1. The Site consists of two properties as shown in Figure 2, the former Seaboard Chemical facility property located at 5899 Riverdale Drive, Jamestown, NC and the adjacent Riverdale Drive Landfill, a closed municipal solid waste landfill. The former Seaboard Chemical property is approximately 10 acres, while the Riverdale Drive Landfill consists of approximately 102 acres and bounds the former Seaboard facility on three sides. Between 1974 and 1989, Seaboard Chemical Corporation operated solvent recovery and fuel blending processes at the facility. The facility was granted Interim Status under the Resource Conservation and Recovery Act ("RCRA") as a treatment, storage, and disposal facility in 1982. The facility was divided into 13 operating areas that included, among other things, distillation, fractionation, and condensation of organic solvent wastes. In addition, three unlined surface impoundments were in service at the facility during the time that Seaboard Chemical was in operation. The corporation declared bankruptcy and was not able to fund the cost of performing the necessary site closure and remediation. Removal activities were conducted during 1990 and 1992 to remove all remaining waste materials and certain tanks and equipment from the Seaboard Chemical property. A Removal Action was conducted by the Seaboard Group I, formed by parties that may have used the services of Seaboard Chemical Corporation in the past. The Seaboard Chemical property was administered as an asset of the bankruptcy estate of Seaboard Chemical Corporation by J. Brooks Reitzel, Jr., bankruptcy trustee. The Trustee was not able to dispose of the 3 property in the course of the bankruptcy proceedings, and ownership is believed to have reverted to the dissolved Seaboard Chemical Corporation by operation of law. Seaboard Group II and the City of High Point have a recorded perpetual easement to perform remedial activities on the property. The closed Riverdale Drive Landfill (Landfill) was operated, using customary methods in general use at the time, from the 1950's until October 1993. The Landfill was permitted by the NCDEQ Solid Waste Section in 1979. During Landfill operations sections of the two tributary streams that dissect the landfill property were piped so that the landfill could be expanded, and solid waste was used to fill the drainage valleys. From approximately 1966 until 1970, Landfill operations also included the disposal and open burning of spent solvents. The burn pits were periodically cleaned of residue which was accumulated in a mound located near the former burn pits. Presently this residue mound consists of approximately 600 cubic yards of contaminated soil and is referred to as the "soil residue mound". The soil residue mound has been capped with an impermeable synthetic liner and stabilized with a vegetative cover. In 1989, a leachate collection system was added to control leachate seeps along the slopes of the Landfill. Leachate collection lines were also installed beneath the landfill parallel to the Southern Intermittent Stream piped section to intercept leachate flow in the filled stream valley. The leachate from this collection system is accumulated in concrete storage tanks. The closed Landfill is now capped with a minimum of two feet of native soil and a vegetative cover. After the Removal Action, the Seaboard Group II (Group) was formed to perform a remedial investigation and to prepare a baseline risk assessment/feasibility study for the former Seaboard site. As recommended by the NC Division of Waste Management, the Group and the City entered into an agreement to jointly perform a remedial investigation, because the close proximity of the Landfill and former Seaboard facility made joint investigation of the two properties (Site) advantageous for both the City and the Group. The Parties then entered into an Administrative Order on Consent (AOC) dated January 30, 1996 with the State to perform the remedial investigation. The feasibility study was conducted under a separate AOC dated July 22, 1997. FIVE-YEAR REVIEW SUMMARY FORM 4 Author name (Project Coordinator): R. Craig Coslett I Author affiliation: de maximis, inc. I Review period: 8/1/2017 — 8/1/2022 I Date of site inspection: 2/15/2023 I Type of review: Policy I Review number: 1 I Triggering action date: 8/25/2017 I Due date eve years after triggering action date): 2/25/2023 I II. RESPONSE ACTION SUMMARY Response Actions Remedial investigations conducted at the Site have documented the presence of chlorinated and non - chlorinated hydrocarbon compounds in soils, landfill leachate, groundwater (shallow and deep), and surface water. The remedial investigation results also indicated the presence of dense non -aqueous -phase liquids in the fractured bedrock aquifer underlying the Site. The Remedy Recommendation Document, approved by the Division of Waste Management on September 27, 2005, presents a protective remedial strategy for the impacted media based on the results of the remedial investigation, baseline risk assessment, and feasibility study. The remedial action consists of groundwater extraction and treatment in combination with institutional controls including site access control, recorded land use restrictions, and restriction of water supply well construction. The remedy was designed and constructed to prevent movement of COCs into Randleman Reservoir and the Southern Intermittent Stream, as well as to prevent exposure to impacted soils and groundwater at the Site. The objectives of remedial action at the Site as listed in the Remedy Recommendation Document include the following: • Contain the contaminated soils at the source areas to prevent direct contact by potential human and environmental receptors, reduce percolation and intrusion of storm water and reduce migration of compounds of concern ("COCs") into the groundwater, • Control migration of landfill leachate to prevent discharge to surface water at the Site, • Control migration of contaminated groundwater at the site to prevent offsite migration and unacceptable impacts to surface water, • Achieve compliance with North Carolina surface water quality standards for the COCs in the surface water of the onsite streams, • Achieve compliance with North Carolina groundwater quality standards for the COCs in the groundwater beneath the Site, and • Restrict future Site uses that could present potentially unacceptable exposure risks (e.g., residential development, use of impacted groundwater, etc.). For ease in description and comparison to the remedial objectives the components of the Remedial Action have been broken out into the following categories: Site Related and Collection/Treatment Systems. 5 Site Related As previously mentioned, the Site consists of two properties, the 10-acre former Seaboard Chemical facility property located at 5899 Riverdale Drive, Jamestown, NC and the adjacent 102-acre Riverdale Drive Landfill. Both properties have been closed consistent with local, state and federal requirements and have met the goals of the remedial action objectives by restricting future Site uses that could present potentially unacceptable exposure risks, including: • Have been secured in a manner that restricts unauthorized access (fencing). • Are subject to recorded land use restrictions (LURs) on future development and groundwater usage. • Each property has been closed pursuant to approved closure plans. (Seaboard February 1993 letter approval, April 1994 Riverdale Drive Landfill Post Closure Plan) • Are inspected on an approved schedule to ensure protectiveness. In addition, in a letter dated January 8, 2021the NCDEQ issued its satisfactory 5-year review of the hazardous waste management permit for the Seaboard Chemical facility. IC Summary Table Media, engineered ICs Called Title of IC controls, and areas that do ICs for in the Impacted IC Instrument not support UU/UE based Needed Decision Parcel(s) Objective Implemented and on current conditions Documents Date (orplanned) Guilford Restrict all uses of Declaration of Seaboard Chemical County property other agency Perpetual Land Property — 10.323ac Yes Yes Parcel approved activities. Use Restrictions, Number Remedial Activities GC ROD P.B. 158477 have been approved 179 Pg. 17, 2010 Guilford Restrict all uses of Land Use Materials Recycling County property other agency Restrictions, GC Facility (MRF) — Yes Yes Parcel approved activities. ROD P.B. 186 11.657ac Number Remedial Activities Pg. 80, D.B 7588 209709 have been approved P . 2202, 2014 Guilford Restrict all uses of Land Use Riverdale Drive Landfill County property other agency Restrictions, GC — 101.779ac Yes Yes Parcel approved activities. ROD P.B. 185 Number Remedial Activities Pg. 21, DB 7588 209705 have been approved P . 2191, 2013 Collection/Treatment System Construction of the collection/treatment system is documented in the April 2017 Construction Completion Report (2017 CCR) which was approved by NCDEQ on July 25, 2017. This 2017 CCR documents the final status of the remediation systems as constructed and includes modifications made to the components of the system after submittal of the January 15, 2014 Remedial Monitoring and Effectiveness Evaluation Plan. Additional modifications implemented during the current reporting period are provided in the Status of Implementation below. The constructed elements of the Collection/Treatment systems documented in the 2017 CCR include: Con Collection System(s) A network of 8 (eight) groundwater recovery wells are utilized for extraction of affected groundwater. These wells include 1 (one) deep well, PWDR1, and 7 (seven) shallow wells, RW- SIS 1, RW-SIS2, RW-SIS3, RW-SIS4, RW-LFS 1, RW-LFS2, and RW-NIS. In addition, 5 (five) leachate collection tanks, and the NIS sump (2 pumps) accumulate landfill leachate at the perimeter of the landfill in select locations and from the Northern and Southern Intermittent Stream discharge areas. The locations of the recovery wells and leachate collection tanks are shown in Figure 2. Flows from recovery wells RW-SIS 1, RW-LFS 1, RW-LFS2, and RW-NIS are combined with the flows from the leachate tanks in Lift Station 1 (LS-1). The discharge from LS-1 is pumped to Lift Station 2 (LS-2) where the flow is combined with the flows from PWDR-1, RW-SIS2, RW-SIS3, and RW-SIS4. Treatment System(s) The components of the treatment systems are physically located on both properties with the majority of the components being located on the former landfill property. The SCADA control system, LS-2, filter building, and the clarifier are located on the former Seaboard property. The description of the Treatment System is broken down between the Mechanical Treatment System (Mechanical System) and the Natural Treatment System (Natural System). All collected water (groundwater and leachate) is processed through the mechanical system to remove the majority of constituents of concern (COCs) prior to processing through the natural system to address the remaining constituents. Mechanical Treatment System The Mechanical System refers to the equipment and processes in the extraction well network, leachate collection network, LS-1, clarifier system, sludge handling system, filter building, LS- 2, and the irrigation network up to the node control panels (See Figure 3 — Process Flow Diagram). The node control panels separate these components and their associated treatment equipment from those used in the Natural System. The division between the Mechanical System and the Natural System is at the node control panel buildings on the Landfill's East and West Lobes. Within each node control building there is a large electrical control panel that contains the data loggers and multiplexers, as well as the translation interfaces for the SCADA control system. The Mechanical System is comprised of the following major components: • Lift Station 1 — This is a single enclosure used to collect and transfer the recovered groundwater and the leachate from most of the sources and pump it to the inlet manifold in Lift Station 2 (LS-2). This includes flow from the five leachate collection tank pumps, the NIS leachate sump (two pumps), and recovery wells RWNIS-1, RWSIS-1, RWLFS- 1, and RWLFS-2. LS-1 is located nearly 80 feet (vertically) below the elevation of LS-2 near the Landfill perimeter road. LS-1 contains the pneumatic controls for most of the shallow groundwater recovery wells and all the leachate pumps, and the inlet header from the leachate and shallow groundwater recovery well networks. • Lift Station 2 — LS-2 consists of seven enclosures used to regulate the inlet flow to the clarifier, provide pneumatic control for the remaining shallow groundwater recovery wells, and store and transfer the process flow from the Mechanical System to the irrigation network in the Natural System. The LS-2 inlet manifold contains the proportioning and shutoff valves used to regulate the system flow into the clarifier, then into the filter building, and from the filter building into the settling vat. It also receives the treated process flow from the settling vat proportioning manifold and controls the 7 flow to the discharge networks. • Clarifier System — The clarifier is a vertical wall cylindrical clarifier system which is approximately 15 feet tall and 18 feet in internal diameter. It receives all the flow from all sources in LS-1 and LS-2 and performs the initial treatment to remove mineral salts by pH adjustment, flocculation and settling. • Sludge Handling System — The sludge from the bottom of the clarifier is pumped to one of two sludge dewatering boxes (referred to as tipper boxes). These two dewatering boxes are mounted on elevated stands to allow them to be tipped to empty the dewatered sludge. A polymer is added to the sludge in the line between the clarifier and the tipper boxes to enhance dewatering. Sludge is directed to one of the tipper boxes until it is full. At that time, flow is directed to the idle tipper box, and the full box drains any free water to a sump that is pumped into the clarifier equalization tank. Once the sludge is dried sufficiently, the box is emptied, and the solids disposed on -site. • Filter Building — The filter building receives flow from the clarifier including LS-1 and the shallow bedrock recovery wells RWSIS-2, RWSIS-3, RWSIS-4, and deep groundwater pumping well PWDR-1. It provides filtering to 25-microns+/-, addition of a sequestrant, and polishing in a 6-tray air stripper. It is then passed through to the settling vat in the effluent treatment system. • Maintenance Building — The maintenance building is located near the filter building and contains the lime and ferric chloride storage tanks, chemical feed pumps, air compressors and other appurtenances associated with the clarifier chemical feed systems. It is also used for storage of spare parts and equipment. Natural Treatment System The Natural System is a 32±-acre tree stand consisting of a variety of conifer tree species first planted in 2007 located entirely on the former landfill property. An irrigation system for the tree stand is divided into 16 approximately two -acre zones that can be activated sequentially to dispense water at approximately 50 gpm per zone. The Natural System is comprised of the following components, including irrigation control: • The tree stand, first planted in 2007, occupies 22 acres on the west lobe of the landfill and about 10 acres on the east lobe; o The tree species include loblolly pine, Virginia, and Japanese Black pine as well as eastern red cedar. o The trees are arranged in rows 10 feet apart, and trees within a row are roughly on 10- foot centers (approximately 435 trees per acre). • The irrigation system for the tree stand is divided into 16 approximately two -acre zones that can be activated sequentially to dispense water at about 50 gpm (0.055 inches per hour). • Each irrigation zone has multiple drip lines. • Liquid fertilizer can be dispensed to the tree stand via the drip lines (fertigation). A fertilizer tank that can be filled with liquid nutrients is connected to a pump, solenoid valve and a flow meter. Nutrient solution can be injected, at a specific dilution factor, into the irrigation water. N. Irrigation Controls In each of the zones, the drip -irrigation system is monitored to prevent over -irrigation and excessive drainage below the root zones of the trees. Each irrigation zone is instrumented with sensors that provide data to the PLC that provides the operator with information needed to manage the volume of irrigation being used in each of the zones. • Irrometer Watermark sensors measure resistance to the flow of electricity expressed in kohms (kD)• • Soil temperature sensors. On each lobe of the landfill, in one of the nests of soil moisture sensors, three soil temperature sensors were installed at the same depth as the moisture sensors. A fourth sensor in each nest was installed at approximately 4-inches below grade to monitor freezing at the drip line elevation. Operating decisions for the irrigation system are documented on the weekly logs and verified in the field. Status of Implementation Following construction completion of the collection and treatment system, the Mechanical System and Natural System were subject to testing procedures to prove the system was operating as designed. This "prove -out" testing is presented in detail in the Construction Completion Report and documented that different components of the constructed elements could meet the design requirements that were established to address the Remedial Action Objectives for the system. Throughout the operation period, the system continued to be optimized to address inefficiencies identified. The following provides a summary of items completed during this reporting period. • Installation of surge suppressors — lightning strikes and electric surges affected equipment causing extended down time on more than one occasion following startup. Surge suppression has been installed throughout the electrical components. • Sparge Tank Addition — To optimize treatment, a 200-gallon sparge tank was installed as the initial phase of treatment. The sparge tank provides a number of benefits as the initial treatment step including; balances flow (minimizes peaks of COCs entering the clarifier), increases pH, and mixes the influent coming from the different extractions points prior to chemical additions and further mixing in the clarifier unit. • Abandonment of Monitoring Wells — In a letter dated May 2018 a list of 26 existing monitoring wells were proposed for abandonment as they were determined to be not needed for future monitoring at the Site. In a letter dated June 5, 2018, DEQ provided approval of the recommended abandonment work which was completed in the summer of 2018. • PLC/HMI Update — In a letter dated April 18, 2019, a proposal to replace the PLC/HMI control system to eliminate electronic issues that stemmed from obsolete equipment was submitted to DEQ. The proposed work included installation of new hardware (valves and controllers) to replace equipment that was no longer available, wiring of new equipment and installation of new programmable control logic. The proposal also included complete removal of the equipment associated with the AOP+ system that was non-functional. This work was approved by DEQ in a letter dated May 6, 2019. • Remedial Monitoring and Effectiveness Evaluation Report — In April 2020, the Seaboard Group II and City of High Point (Parties) submitted the Remedial Monitoring and Effectiveness Evaluation Report that documented operations, maintenance and monitoring of the Extraction and Treatment systems for the Former Seaboard Chemical and Riverdale Drive Landfill Sites for the initial 2 years following DEQ approval of the Remedial Action construction. A recommendation that came out of the April I 2020 Report was to evaluate the shallow groundwater interactions within the Southern Intermittent Stream (SIS) area. Additional Monitoring Well Installation — During the Spring and Summer of 2021, an evaluation of the existing extraction system, COC source areas, and capacity of the current treatment system (mechanical and natural) was conducted to determine if modifications would increase the effectiveness of the remedial system and improve the removal of COC mass. These efforts included the installation and sampling of additional assessment monitoring wells in the SIS basin area, drawdown tests of the existing extraction wells at the SIS basin, and yield testing of select existing wells at the Seaboard Property near the former Pond 3 area. This work led to the submittal of Technical Memorandum 11. Technical Memorandum 11 (TM-11) — On February 3, 2022, TM -II was submitted to DEQ to evaluate the effectiveness of adding select wells in the vicinity of the SIS basin and near the former Pond 3 Area of the Seaboard property to the extraction system. TM -I I was conditionally approved by DEQ in a letter dated February 18, 2022. The conditions of the approval (IE additional monitoring) were addressed. Work associated with TM -I I is being conducted currently with the initial quarterly report being submitted to DEQ on January 17, 2023. Systems Operations/Operation & Maintenance (O&M) Operation, Maintenance, and Monitoring of the system has been conducted by Piedmont Industrial Services since start-up. As previously presented, following construction completion of the collection and treatment system, the mechanical and natural systems were subjected to testing procedures to prove the system was operating as designed. "Prove -out" testing documented that different components of the constructed elements could meet the design requirements that were established to address the Remedial Action Objectives for the system. The Operation and Maintenance (O&M) plan was developed to outline data collection and monitoring requirements in addition to operation requirements to run the collection and treatment systems. The physical data collection and monitoring activities are documented on a weekly basis by the O&M contractor following the weekly log checklist. A sample copy of the weekly log checklist is provided as Appendix B. The collected information is then used to prepare summaries of Site activities that are submitted to NCDEQ as Quarterly Progress Reports. Data collected weekly and used to prepare the Quarterly Progress Reports includes: • Meter Readings — Weekly flow information from various locations including leachate collection system, groundwater extraction wells, discharge to natural treatment areas, compressor run times, and pump counter information from individual extraction locations (wells and sumps). • Chemical Levels — Tank levels are tracked showing chemical usage of the various chemicals employed in operating the system (lime slurry, flocculant, sulfuric acid, sequestrant, and sodium hydroxide). • In -House Lab Samples — Weekly tests are run on the effluent in order to check for changes prior to the monthly sampling. The weekly tests are run on -site for iron, total suspended solids, pH, oxidation- reduction potential, conductivity, and total dissolved solids. Changes in effluent parameters alert the operator of issues so that the necessary actions can be taken to resolve any potential problems. • Contract Lab Samples — Monthly samples are collected from the raw influent water, prior to the Air Stripper, and effluent water prior to discharge to the Natural System. These samples are analyzed by a NC Certified Laboratory for volatile organic compounds, inorganics, hardness, pH, total dissolved and suspended solids, and 1,4-dioxane. These samples evaluate the effectiveness of the metals removal process and air stripper operation prior to distribution to the Natural System. 10 • Well Transducer Readings — Weekly well levels are recorded in the observation wells that are equipped with level transducers. These levels confirm the drawdown by the recovery wells and offer evidence of the capture zone. • Comments — Specific details on run time, alarms, tasks completed, inspections, shutdowns, and resolutions. Further detail is provided by the operator in the transmittal of the weekly logs. • Checklist — The check list is composed of dozens of items that need to be checked or serviced for preventative maintenance. The checklist items are broken into categories of bi-weekly, weekly, monthly, and quarterly. Inspections Inspections of the Site and operations are conducted on a weekly basis as noted on the Weekly Log Checklist. Inspections are conducted during routine operations and are documented in the daily logbook when issues are identified. Sitewide inspections are also conducted on a quarterly basis and issues are identified in the Site logbook and reported in quarterly reports. If issues are identified, a narrative summary of the issues and the corrective measures taken are provided. The Landfill is also monitored separately by the City on a quarterly basis for the presence of methane/explosive gases at the waste boundary. These monitoring events are conducted by a third -party contractor and the results are submitted to NCDEQ quarterly. In addition to the routine site inspections of the natural treatment areas, weekly inspections are conducted by City personnel to identify any post - closure issues involving erosion control, site security, leachate seepage, etc. Inspections are also conducted after significant rainfall events to assure site erosion control measures remain effective. III. PROGRESS SINCE THE LAST REVIEW This is the 1st FYR for the Seaboard Chemical/Former Riverdale Drive Landfill Site. The Remedy for the Site has been constructed as designed with approved revisions documented in Technical Memoranda # 1 through # 10. Additional extraction as documented in Technical Memorandum #11 is currently being evaluated. The constructed remedy has been effective at addressing the Remedial Action Objectives as listed in the Remedy Recommendation Document as follows: • Contain the contaminated soils at the source areas to prevent direct contact by potential human and environmental receptors, reduce percolation and intrusion of storm water and reduce migration of compounds of concern ("COCs") into the groundwater. COMPLETED — through the approved Closure Activities on the Seaboard Site and Former Riverdale Drive Landfill. Seaboard Group I conducted closure activities at the Facility in 1990 and 1992, during which time the waste materials in surface tanks and equipment, as well as the empty tanks and process equipment, were cleaned and removed from the property. In February 1993 NDEQ Hazardous waste division issued approval of Phase I of the Site Closure. The approved Post Closure Plan for the Riverdale Drive Landfill is dated April 1994. • Control migration of landfill leachate to prevent discharge to surface water at the Site. ONGOING — Active leachate collection is part of the extraction and treatment systems. • Control migration of contaminated groundwater at the site to prevent offsite migration and unacceptable impacts to surface water. ONGOING — The remedy has been designed to reduce migration of impacted groundwater and to collect contaminated groundwater from strategic locations 11 to prevent migration off Site and/or discharge to surface water. The work identified in TM- 11 is being evaluated as a means to further support this corrective action. Achieve compliance with North Carolina surface water quality standards for the COCs in the surface water of the onsite streams. ONGOING — Fluctuations in COCs concentrations in surface water samples has led to additional corrective measures and further evaluation of additional extraction locations. Achieve compliance with North Carolina groundwater quality standards for the COCs in the groundwater beneath the Site. ONGOING — Progress has been made, but additional evaluation and implementation of the remedial process is necessary to achieve this objective. Restrict future Site uses that could present potentially unacceptable exposure risks (e.g., residential development, use of impacted groundwater, etc.). COMPLETED — Land Use Restrictions (LURs) are in place for the three properties; Seaboard Chemical, Riverdale Drive Landfill, and the Materials Recycling Facility (MRF). Annual Certifications are provided confirming details of the LURs are in place. IV. FIVE-YEAR REVIEW PROCESS Data Review The FYR included a review of relevant Site documents, monitoring data, and operational data with a focus on operational data collected in the five-year period from August 2017 through August 2022. A review of findings and data trends for groundwater are included in this section. Time -series graphs showing monitoring data trends in wells are discussed below. Surface water data for this reporting period is tabulated below. The groundwater and surface water data were collected and summarized in annual monitoring reports previously submitted to NCDEQ. Operational data generated as part of on -going long- term remedial action activities were summarized and included in progress reports submitted on a quarterly basis. The Remedy was designed to capture and extract contaminated groundwater and leachate from select locations along the northern portion of the Site (referred to collectively herein as the "extraction network"). As reported in the 2022 Groundwater Monitoring Report, the collection system has been successful in retaining contaminated groundwater on Site. Analytical data indicate the extraction and treatment systems are effective at controlling groundwater contamination migration from the Site. A review of groundwater and surface water monitoring results over the past five years indicates a declining trend in COC concentrations. The contaminant trends in groundwater have been plotted for the past ten years to show this trend and establish the background COC concentrations prior to full-time operation of the treatment system. Note that the treatment system was in operation on an intermittent basis beginning in 2013/2014 prior to the official startup date in August 2017. The effect of this earlier extraction operation is evident from the trend graph plots. A discussion of this data for each of the media types is provided below: Groundwater Data Groundwater analytical data for the past ten years have been summarized for total volatile organic compounds (VOC) and 1,4-dioxane. The COC trend graphs for these compounds are provided in Figures 4 and 5. Please note the variation in the scale of the y-axis for these graphs, which is significant at some locations. 12 VOC Trend Graphs The concentration trend of VOCs on Figure 4 indicates significant COC reduction in monitoring wells MW-3C, PW-5D, PW15D, and PW-16D. These monitoring wells are all within the capture zone of the primary extraction well PW-DR1. These trends indicate the capture zone created by the PW-DR1 is controlling groundwater flow and preventing further off -site COC migration. The noted reduction in COC concentration is related to dewatering of the shallow bedrock aquifer and the introduction of less contaminated water. The VOC contaminant trend in monitoring well W-4A, located downgradient of the former Seaboard Site, shows a similar COC reduction from groundwater extraction operations. Shallow extraction well RW-SIS2 is located immediately adjacent to monitoring well W-4A and has lowered the groundwater elevation by 10' since operation began. Groundwater monitoring well MW-15A is located immediately downgradient of the Soil Residue Mound (SRM) and is outside of the influence of any of the extraction wells. The VOC trend in this monitoring well shows an overall downward trend confirming the remedial approach to cap the SRM in 2010. The synthetic cap was installed to reduce rainfall infiltration and the generation of leachate from the waste mass. The VOC data plot for monitoring well PW-3D does not show a clear trend. This well, located between the former Seaboard Site and the Landfill, has been outside of the influence of the groundwater extraction system until the recent TM- I I work which is currently being evaluated. This well is also located hydraulically downgradient of the former Pond 3. 1,4-Dioxane Trend Graphs The COC data graphs for 1,4-dioxane follow a similar trend noted with the VOC graphs (Figure 5). The COC concentrations in the monitoring wells near the primary extraction well PW-DR1 show a significant reduction in 1,4-dioxane concentration. This data indicates dewatering of the shallow bedrock. Monitoring well W-4A has also shown a decreasing 1,4-dioxane trend due to its proximity to groundwater extraction well RW-SIS2. The continued operation of the expanded extraction associated with TM -I I should also assist to improve the groundwater quality at this location. The 1,4-dioxane trend in monitoring well MW-15A, located downgradient of the SRM, shows a steady decrease in COC concentration. As discussed earlier, this is likely due to the installation of the synthetic cap which serves to reduce rainfall infiltration and the generation of leachate. The 1,4-dioxane concentration trend in PW-31) is increasing, however, the overall 1,4-dioxane concentration is relatively low and it is anticipated that the continued operation of the TM -I I extraction wells located immediately upgradient of PW-31) should improve this trend. Surface Water Data Surface water samples are collected annually at several locations across the Site and on Randleman Lake (Figure 2). The surface water samples collected on Randleman Lake are collected at two discrete depths: 1' below the surface and V above the bottom of the Lake. A brief description of the sample locations is provided below: 13 Northern Intermittent Stream (NIS) — Samples SW-1 and SW-2 Southern Intermittent Stream (SIS) — Samples SW-3, SW-4, and SW-5 Randleman Lake — Samples SW-6, SW-DRP2, SW-7, and SW-DRPI I Surface Water VOC Data The laboratory analytical data for surface water samples collected from the Northern Intermittent Stream (NIS) and Randleman Lake (surface and bottom samples) did not identify appreciable concentrations of VOCs over the initial 5 years of remedial system operation. Note that the NIS has a limited watershed area, and the sample locations are frequently dry. The upper SIS samples have shown occasional single -digit detections of VOCs, especially in surface water sample SW-3. The SW-3 surface water sample location is hydraulically downgradient of the former Seaboard Site. The VOC concentrations in these samples are significantly lower than observed prior to the operation of the remedial system. Pre -remedial VOC concentrations at the SW-3 location ranged from 100 ug/l to 200 ug/l prior to operation of the shallow extraction wells at the upper SIS area. The VOC results for the lower SIS sample (SW-4) has shown a highly variable COC concentration over the past 5 years. This variation is attributed to rainfall patterns and groundwater contribution to the SIS. Surface Water Samples - 1.4-Dioxane Concentrations Sample ID 10/2017 11/2018 9/2019 10/2020 10/2021 10/2022 Northern Intermittent Stream Samples SW-1 Dry 12 ug/1 BQL Dry Dry Dry SW-2 BQL 22 ug/1 BQL Dry Dry 14 ug/1 Randleman Lake Samples SW-6(S)* 13 ug/1 BQL 1.6 ug/1 BQL BQL BQL SW-6(B)* 14 ug/1 BQL BQL BQL BQL BQL SW-DRP2(S) 19 ug/1 BQL 1.4 ug/1 0.83 ug/1 BQL BQL SW-DRP2(B) 21 ug/1 BQL BQL BQL BQL BQL SW-7(S) 26 ug/1 BQL BQL BQL BQL BQL SW-7(B) 20 ug/1 BQL BQL BQL BQL BQL SW-DRP11(S) 31 ug/1 BQL 1.3 ug/1 BQL 1.4 ug/1 1.0 ug/1 SW-DRPI I(B) 31 ug/1 BQL BQL BQL 1.2 ug/1 BQL Upper Southern Intermittent Stream Samples SW-5 14 ug/1 23 ug/1 5.8 ug/1 3.5 ug/1 2.2 ug/l 1.6 ug/1 14 SW-3 9.7 ug/1 13 ug/t 1.7 ug/1 3.9 ug/l 4.6 ug/1 2.1 ug/1 Lower Southern Intermittent Stream Sample SW-4 1,700 ug/l 48 ug/l 1,800 ug/l 79 ug/l 1,500 ug/l 14 ug/l Randleman Lake Samples: (S)=Shallow sample; (B)=Bottom sample * Upgradient background samples Surface Water 1,4-Dioxane Data The laboratory analytical data for surface water samples collected from the NIS reported detectable concentrations of 1,4-dioxane in samples collected in 2018 and 2022. These detections appear to be attributed to above -average rainfall and runoff from the phytoremediation zones at the time of sample collection. The surface water samples from Randleman Lake (1' below surface and 1' above bottom samples) reported concentrations of 1,4-dioxane in all samples during the initial startup of operations (2017). Since that time, the concentrations have been minor and may be attributed to background sources. Note that surface water sample SW-6 is located 3,500' upstream of the Site and provides background surface water quality. Randleman Lake surface water sample SW-DRP 11 is located 4,100' downstream of the Site at the confluence of Richland Creek. At least two known sources of 1,4-dioxane in surface water are located on Richland Creek upstream of this confluence. The upper SIS samples have shown a significant reduction in the 1,4-dioxane concentration over the initial 5-year operational period. The operation of the three shallow extraction wells (RW- SIS2, RW-SIS3, and RW-SIS4) along the upper SIS has resulted in an improvement of surface water quality. The 1,4-dioxane results for the lower SIS sample (SW-4) have shown a highly variable contaminant concentration over the past 5 years of operation. This variation is attributed to rainfall patterns and groundwater contribution from the SIS drainage channel. Operational Data The information provided in this report includes five years of monitoring following the NCDEQ's approval of the construction of the remedy, August 25, 2017 through August 2022. This information is essentially a summary of the data that has been previously reported to the department in the form of Quarterly Progress Reports, including the 3rd Quarter 2017 through the 3rd Quarter 2022. Several operational issues were encountered that required modifications to the system throughout this five-year period. Summaries are provided below: • February 2018 — Hazen & Sawyer re-evaluated Mechanical System, recommended additional air sparging prior to clarifier and chemical dosing modifications. • Spring 2018 —New air sparge tank installed prior to clarifier to enhance metals removal. Installed surge suppressors to protect treatment system components from lightning strikes and other 15 electrical spikes. • December 2018 — Replaced fiber optics cable from LS-1 to primary treatment building. • Summer 2019 — Removed AOP+ (PhotoCat) system from LS-2 treatment enclosure for recycling. • October through December 2019 — Major upgrade of PLC/HMI control systems. • Summer 2020- Spring 2021 — Evaluated the SIS corridor by way of video, pump tests, dye tracing, new monitoring well installations. • Summer 2020 — Summer 2021 — Continued fertigation of the entire phyto system along with tissue sampling to ensure proper nutrient levels within the Natural System. • September 2021 — Hazen & Sawyer re-evaluated the mechanical treatment system for the addition of the new extraction wells along the SIS corridor as described in TM-11. New chemical dosing setpoints were recommended along with the installation of a soda ash feed system. • Fall 2021 — Winter 2022 — A new plug was installed at the upper end of the NIS collection pipe along with regrading of areas of ponding water along the route to reduce inflow and infiltration of clean surface water into the collection system. • Fall 2021 — Planted 400 additional trees to fill in bare areas of the phyto zones and other areas of seepage. • Fall 2021 — Replaced and repositioned two lysimeters. • Spring 2022 — Installed new soda ash feed system per Hazen recommendations. • Summer 2022 — Plumbed in two new wells and two existing wells along the SIS corridor into the extraction system per TM-11. • Summer 2022 — Rovisys integrated the soda ash feed system and new wells into the PLC system and added priority programming for source points. • Summer 2022 - Fall 2022 — Redesigned the twenty-four miles of drip lines and purchased materials for the wholesale replacement of existing lines. Installation is scheduled to be done in the Winter of 2022-2023. • Summer 2022-Winter 2022 — Evaluated and tested a new radio network for transmitting well transducer levels to the PLC. Installation is in progress. • Ongoing — Replacement of collection system pumps to higher capacity pumps. The majority of extraction pumps have been changed to higher capacity pumps based on monitoring activities, mostly because of higher precipitation and leachate collection. In addition, there were many shorter duration modifications / optimizations completed throughout the 5- year reporting period. These modifications are presented on the following table: Issues Encountered Date Resolution Frozen chemical feed lines and Added heat trace and/or insulation to • irrigation control valves 18-Jan lines • Electrically damaged communication 18-Feb Added surge suppression on low I/O cards voltage lines • Intermittent power failures 18-Feb Added low voltage UPS devices • Scaling of pumps and process lines 18-Mar Modified chemical feed rates and se uestrant type per Hazen report • Scaling of pumps and process lines 18-May Installed air sparge tank prior to clarifier • Intermittent communication loss 18-Dec Replaced fiber optic cable from LS-2 to LS-1 and the node buildings 16 Scaling of pump lines from LS-1 and Re -piped the force mains in LS-1 to 0 LS-2 18-Dec allow individual citric washes while in operation LS-1 compressor failed due to water Replaced LS-1 compressor and wired 0 build-up from unloading 18-Dec LS-2 compressor for temporary back- up • Intermittent communication loss 19-Jan Replaced Profibus connections 0 Pressure loss at LS-1 compressor 19-Jun Replaced pneumatic pumps, valves, and regulators a Clogged sludge lines 19-Oct Replaced sludge pumps and re -piped manifolds • Continual communication losses and 19-Oct Replaced all drives, communication lack of replacement parts I/O racks, HMI's and PLC • Filter Building (FB) compressor 20-May Tied air lines to LS-2 compressor and frequent failures eliminated small FB compressor • Replaced pump and motor with one PWDR-1 motor failure 21-Jul more properly sized for current operational parameters • Ongoing issues with LS-1 and LS-2 22-Feb Installed oil -mist separators and purge compressors lines to increase load time • Replace hydraulic seals, installed Sludge drying box hydraulics failure 22-May additional grease fittings, increased pressures 0 Clarifier cone and chemical feed failure 22-Aug Replaced supports and fee connections with higher resistance materials • Replaced screens and placed additional Sludge drying box loss of efficiency 22-Aug cleanings on an annual maintenance schedule As presented, modifications were implemented throughout this reporting period. With the difficulties encountered, the overall system run time has been calculated to be 74% during this reporting period. System run time has increased significantly following completion of the ongoing modifications listed above. As shown below: 17 100.0% 90.0% 80.0% 70.0% a 60.0% 30.0% 20.0% 10.0% 0.0% System Run-time % & Average Flow r- n 00 CO CO CO 07 07 Q7 Q7 O O O O N N N N N N N N N N N N N 0 C 0 0 0 C 0 CD 0 0 O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N ro t rl N M It r-I N ro -It 1-1 N rn �* 1- N ro It N M a a Cr a a a Cr a a a a a a a a a a a a a a 50.0 45.0 40.0 35.0 7. a 30.0 U 15.0 Q 10.0 5.0 0.0 fRun-time(%) fAverageFlow (GPM) ......••• Linear (Run-time(%)j ......••• Linear (AverageHow (GPM)) The trend for the run-time percentage has continued upward over the 5-year period. Dips in the runtime are due to system modifications such as the PLC control network replacement in Q4 2019. The trend for the average system flow has stayed steady over the review period. As contaminated aquifers are de - watered, extraction levels have been lowered and additional source points have been brought online to maximize the system resources. The influent flows have varied over the course of the review period. Variations in the flow are due to seasonal changes such as rainfall, operating efficiencies, and de -watering of certain areas. Due to increased efficiencies of the system, larger extraction pumps, and additional flow sources, the amount of water processed has generally increased. The chart below illustrates the total processed flow vs. the various extraction sources: 5,000,000 = 4,500,000 w Q 4,000,000 3,500,000 LL w N 3,000,000 z O 2,500,000 2,000,000 1,500,000 1,000,000 500,000 0 Flow Comparison r- r- c0 00 00 00 a) a] a) 07 O O O O r-I r-I r-I r-I N N N r-I r-I r-I r i r-I r-I r-I rl r-I r-I N N N N N rIj N N N N rIj O O O O O O O O O O O O O O O O O O O O O N N N N rIj N N N N rIj N N N N N rq N N N N rIj ro �t rl N rn �t r-I N rf) * r-I N M �t 1- rIj M �* 1- N M a a a a a a a a a a Cr Cr Cr a a Cr a a a a Cr f LEACHATE (GALLONS) f LS1-RWs (GALLONS) --&-- PWDR1 (GALLONS) f SIS-RWs (GALLONS) —0— PHYTO DISCH. (GALLONS) ......••• Linear (LEACHATE (GALLONS)) ......••• Linear (LS1-RWs (GALLONS)) ........ Linear (PWDR1 (GALLONS)) ......••• Linear [SIS-RWs (GALLONS)] ......••• Linear (PHYTO DISCH. (GALLONS)} The processed water from the shallow recovery wells at LS 1 and SIS has increased during the entire period due to larger extraction pumps, additional sources, higher run-times, and increased precipitation. The amount of leachate processed has increased due to larger extraction pumps, higher run-times, and increased precipitation. PWDR-1 production has decreased over the review period, even though pumping elevations have been lowered, as the aquifer is dewatered. The overall result shows a general increase in total production through the system. 19 A breakdown of the amount of flow from each of the individual source points over the 5-year review period is detailed in the table below: MATED INDIVIDUAL SOURCE VOLUMES (2017-2022) TOTAL AVG. GALLONS % OF TOTAL % OF GALLONS PER MINUTE FLOW GROUP PWDR1 24,952,443 10.7 34.4% % OF GROUP LCHT-1* 203,501 0.1 0.3% 1% LCHT-2 4,787,621 2.1 6.6% 18% LCHT-3 563,432 0.2 0.8% 2% LCHT-4 1,694,953 0.7 2.3% 6% LCHT-5 6,315,118 2.7 8.7% 24% LCHT-NIS1 6,815,507 2.9 9.4% 26% LCHT-NIS2 5,860,026 2.5 8.1% 22% 26,240,158 11.3 36.1% 100% RW-NIS 8,051,605 3.5 11.1% 55% RW-LFS1* 3,566,640 1.5 4.9% 24% RW-LFS2 2,188,461 0.9 3.0% 15% RW-SIS1* 949,128 0.4 1.3% 6% 14,755,834 6.3 20.3% 100% RW-SIS2 1,885,197 0.8 2.6% 31% RW-SIS3 2,373,984 1.0 3.3% 39% RW-SIS4 1,778,122 0.8 2.4% 29% 6,037,303 2.6 8.3% 100% CITRIC/RAIN/TANK FILL 179,908 0.1 0.2% BACKWASH 442,062 0.2 0.6% 621,970 0.3 0.9% * INOPERATIVE PUMP COUNTERS SKEW SOME RESULTS 72, 607, 708 31.2 100% 20 Influent concentrations to the system gradually decreased over the 5-year review period indicating an effective remedy in the areas of treatment. In order to further prevent COC migration through the SIS corridor, recovery wells RW-SIS7, RW-SIS8, R-1, and PWSF-1 were brought online in the summer of 2022 as detailed in TM-11. The resulting influent COC concentrations increased immediately. These events are illustrated in the chart below (note the 1 Ox concentration difference between the left and right vertical axis): VOCs & 1,4-D Concentrations 22,500 20,000 17,500 15,000 o� 12,500 z w J 10,000 z 7,500 5,000 7..500 _ 0 - 61 IV �O .tip T ti0 y0 ti� 1ti 1ti IV 1� 1� T IV tiV T T ti0 �O ti61ti 6? C� Cti Cti 03 C� Cv 01 0 C� C~ 01 C3 Coy Cti OV C3 C3 f1NFLUENTVOCs(ug/L) fEFFLUENTVOCs(ug/Q 21 2,500 2,250 2,000 J 1,750 nod 1,500 Q c-i 1,250 H 1,000 z LU 750 LL U- w 500 250 0 —0--1,4-DIOXANE (ug/L) Due to the increase in the amount of water processed, the increase in run-time, and the increase in removal efficiency, the total VOC mass destruction from the Mechanical System has generally increased as well over the review period, even though influent concentration decreased over that same time. Once the additional recovery wells were brought online in the summer of 2022, the mass destruction rate increased dramatically. The total mass of VOCs removed by the Mechanical System during the initial 5-year operating period is 1346 Kg (2967 lbs). The results are illustrated in the chart below: 300.0 275.0 250.0 d 225.0 200.0 a Z 175.0 �a 150.0 0 0 E 125.0 a� N 100.0 N 2 75.0 50.0 25.0 0.0 Mechanical System - VOC Mass & % Removal rn rn m m co 0o rn m rn rn O o O O 14 14 1-4 14 1l �A �A rA r A 1l N N N N N N N N O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N rn rl N rn -t N M �t N n1 -* r A N rn tll a d d a d a a a a a a Or d a d d t MECHANICAL MA55 VOC RE MOVAL (kg) --0— MECHANICAL VOC REMOVAL % ......••• Linear (MECHANICAL VOC REMOVAL %) N N N O 0 0 N N N N rn a Cr Cr 100% 99% 98% 97% 96% 95% 0 94% E 93% y M 92% 91% 90% 89% 88% The Natural System received and processed approximately 72 million gallons of irrigation water from the Mechanical System. The irrigation system consists of 16 individual zones which comprise a total of 32.5 acres. The mass of VOCs and 1,4-dioxane removed by the Natural System is determined by a comparison of the influent concentration from the Mechanical System and the effluent concentrations determined from samples collected from the lysimeters installed in various irrigation zones. The total mass of additional VOCs and 1,4-dioxane removed during the initial 5-year operating period is 18 kg (40 lbs.) and 179 kg (395 lbs) respectively. 22 The percent of COC removal is based on the calculated water balance for the natural treatment area which takes into account the following parameters: • Irrigation water applied to the 32.5 acre treatment area • Daily rainfall measurements • Rate of water use by the tree stand • Interception (rainfall caught by the needles of the trees and evaporated) • Overland Flow or Runoff The Natural System has shown a consistent removal pattern over the 5-year review period. The remaining VOC's removal by the Natural System results in a 99.97% total overall removal for the entire 5-year period. The Natural System has also been able to achieve over a 94.3% 1,4-dioxane removal during the same period. These results are illustrated in the charts and table below: 100 90 80 (V r- 7,0 m ti 60 Y 5.0 0 4.0 VI M 3.0 20 1,0 00 Natural System - VOC Mass Removal & Total System - VOC % Removal I� r• CO CO CO Co a) 07 G7 a) C O C O -4 N N N rl rl N N N N N N N N N N N O C C O O O O O O O C O O C C C C O C O O N N N N N N N N N N N N N N N N N N N N N M �r ri N M -t r-1 N M It r-1 N M �t ri N M It ri N M f NAT. SYSTEM MASS VOC REMOVAL ft) ♦TOTAL SYSTEM VOC % REMOVAL ......••• Linear (TOTAL SYSTEM VOC %REMOVAL) 23 100,0% 99.9% 99.8% F 99.7% 0 99.6% VI 99.5% 99.4% y a 99.3% 99.2% 0 99.1% 99.0% Natural System - 1,4-Dioxane Mass & % Removal 20 100.0% 18 ........... 90 0% 16 80.0% 14 70.0% m e 12 60.0% bb Y 0 Fa 10 50 0% E > 0 o 8 40.0% rc y y 6 — 30.0% 4 20.0% 2 10 0% 0 0.0 % 1, n 00 CO 00 00 07 07 Q7 Q7 O O O O N N N rl O CD O rl O CD O CD O rl O CD O CD O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N M rl N fM zt rA N fM -zt .--I N rn rl N fM rl N M cr cr a a a cr cr cr cr cr a ct a a cr cr a a a rr a f 1,4-❑IOXANE MASS REMOVAL (kg) f 1,4-❑IOXANE REMOVAL % ......••• Linear (1,4-DIOXANE REMOVAL %) MASS DESTRUCTION DETAILS (2017 Q3 - 2022 Q3) MASS REMOVAL REMOVED (kg) EFFICIENCY (%) VOC's MECHANICAL SYSTEM 1346 98.7% NATURAL SYSTEM 18 97.5% TOTAL VOC's 1364 99.97% 1,4-DIOXANE NATURAL SYSTEM 179 94.3% OVERALL SYSTEM TOTAL 1543 99.3% WE Site Inspection The inspection of the Site was conducted on 2/15/2023. In attendance were Eric Aufderhaar, Joshua Hanks, and Dan Girdner, NCDEQ, Robby Stone, Melinda King, and Mike Spencer City of High Point, and Gary Babb, Babb and Associates, Rich Glover, Glover Engineering, Craig Coslett, de maximis, and Bruce Braswell, Trustee. The purpose of the inspection was to assess the protectiveness of the remedy. Participants of the Inspection met at the Treatment facility located at Recovery Way before Inspecting the various components of the Remedy using vehicles to traverse the Site. The FYR Inspection included the routine annual site inspection conducted by the NC Hazardous Waste Section due to the former Seaboard Chemical's status as a treatment, storage, or disposal facility. V. TECHNICAL ASSESSMENT QUESTION A: Is the remedy functioning as intended by the decision documents? YES - The remedial actions summarized above in Section II — Response Action Summary have been fully implemented and operate on a continuous basis. Numerous upgrades to the system have been evaluated and incorporated into the treatment system as described in the Status of Implementation section of this report. Surface water COC levels have been reduced due to the operation of the extraction system and contaminant levels are consistently at or near standards and or target values. Groundwater COC levels have also been significantly reduced as the extraction systems have outpaced COC recharge from the source areas. Further expansion of the extraction system, as provided by TM-11, will enhance containment of COC migration and improve mass removal near the source areas. The capture zones created by the extraction systems are controlling the majority of the contaminant plume in the SIS watershed. Additional evaluation is ongoing to determine the effectiveness of the expanded shallow aquifer extraction system at the SIS Basin Area and the shallow bedrock extraction system at the Pond 3 Area. These two new extraction areas are being evaluated quarterly for 1 year. The first two quarterly evaluation reports of these systems had been submitted to the NC DEQ at the time the 5YR Report submittal. Improvements are also underway to replace the irrigation lines in the phytoremediation zones which will better balance flow to each zone, tailor the irrigation flow based on past operational observations, and allow for easier inspection and maintenance of the irrigation system. The institutional controls implemented at the Site, primarily security fencing around the entire site and land use restrictions, have been effective in preventing exposure to contaminated soil, waste residues, and treatment operations. No unauthorized access to the Site has been reported during the 5-year operational period. 25 QUESTION B: Are the exposure assumptions, toxicity data, cleanup levels, and remedial action objectives (RAOs) used at the time of the remedy selection still valid? YES - The exposure criteria at the Site have not changed significantly over the 5-year operating timeframe. The COCs have not varied from the original assessment work performed at the Site; however, the concentration of the COCs has decreased during the 5-year operational period. This overall reduction in COC concentrations improves the exposure potential for workers at the Site. Also, the institutional controls implemented prior to full operation of the treatment system have prevented exposure from unauthorized personnel. Regulatory standards and guidance have changed since the effective date of the RASA in 2008. Both groundwater and surface water standards are periodically updated based on the most recent available toxicological data. The most recent update to these standards occurred in 2022. A summary of the updated groundwater and surface water regulatory standards for the COCs at the Site is provided below: Comparison of Groundwater Standards Compound Name Original Standard * Current Standard ** 1,1,2-Trichloroethane No Standard 0.6 a /l 1, 1 -Dichloroethane 700 a/1 6 u /1 1,1-Dicloroethene 7 u /1 350 a/1 1,2-Dichloroethane 0.38 u /1 0.4 u /1 1,2-Dichloro ro ane 0.56 u /1 0.6 u /1 1,4-Dioxane 7 u /1 3 u /1 Acetone 700 a/1 6,000 u l Chloroethane 2,800 u 1 3,000 u 1 Chloroform 0.19 u /1 70 u /1 Eth lbenzene 29 u /1 600 u /1 Toluene 1,000 u 1 600 a/1 trans-1,2-Dichloroethene 70 a/1 100 a/1 Trichloroethene 2.8 u /1 3 u /1 Vinyl Chloride 0.015 u 1 0.03 u /1 X lenes (Total) 530 a /1 500 a/1 * Standard at the time of signing RASA (2008) ** As of January 2023 Comparison of Surface Water Standards Compound Name 7-original Standard * Current Standard ** 1,1,2-Trichloroethane 200 a/1 2,500 u 1 1, 1 -Dichloroethane 42 u /1 6 u /1 1, 1 -Dicloroethene 0.057 u 1 300 u /1 1,2-Dichloroethane 0.38 a/1 9.9 a/1 1,4-Dioxane 3 u /1 0.35 u /l *** Acetone 350 u /1 3,100 u 1 Chloroethane 860 u /1 NE cis-1,2-Dichloroethene 33 u /1 60 u /1 Methylene Chloride 4.7 a/1 11,000 a/1 Tetrachloroethene 0.8 a/1 0.7 a/1 trans-1,2-Dichloroethene 700 u /1 290 u /1 Trichloroethene 3.08 u /1 2.5 u /1 Vin l Chloride 2 u /1 0.025 u 1 26 X lenes Total 88.5 a /l 6,200 u 1 2-Butanone 2,090 u 1 20,000 u /1 NE — Not Established * Standard at the time of signing RASA (2008) ** As of January 2023 *** Not a regulatory standard but an In -Stream Target Value While several of these updated standards represent significant changes, they are not expected to affect the current remedial action at the Site. The Mechanical System and Natural System have been designed to address the concentration of VOCs and 1,4-dioxane present at the Site. As this is a containment remedy, continued groundwater and surface water monitoring is necessary to evaluate the effectiveness of the groundwater extraction systems. Continued monitoring, evaluation and modification (when applicable) to the extraction and treatment systems will improve the efficacy of the remediation and further improve water quality at the Site. QUESTION C: Has any other information come to light that could call into question the protectiveness of the remedy? NO - As provided in this report, frequent modifications/improvements to the mechanical and natural treatment systems, extraction systems, groundwater and surface water monitoring, and operation/maintenance have occurred over the 5-year operational period. These modifications/improvements were implemented to increase the effectiveness of the overall remedial system to meet the objectives of the RASA. Any limitation identified in the remedial system has been proactively addressed in a timely manner. VI. ISSUES/RECOMMENDATIONS Issues and Recommendations Identified in the Five -Year Review: Issue Category: Monitoring Issue: Detectible COC concentrations in on Site Surface water (NIS) during periods of heavy precipitation. Recommendation: Increase monitoring to quarterly to evaluate NIS surface water conditions following replacement of irrigation lines in the phytoremediation areas. Affect Current Affect Future Party Oversight Party Milestone Date Protectiveness Protectiveness Responsible Yes Yes PRPs State l/l/2025 The laboratory analytical data for surface water samples collected from the NIS reported detectable concentrations of 1,4-dioxane in samples collected in 2018 and 2022. These detections appear to be attributed to above -average rainfall and runoff from the phytoremediation zones at the time of sample collection. 27 Replacement and balancing of the irrigation lines in the phytoremediation zones is scheduled to be completed in 2023. It is anticipated that this work will minimize runoff. Issue Category: Monitoring Issue: Fluctuating COC concentrations in on Site Surface water (SIS) Recommendation: Complete TM-11 Evaluation / Increase monitoring of select surface water locations in the SIS to quarterly. Affect Current Protectiveness Affect Future Protectiveness Party Responsible Oversight Party Milestone Date Yes Yes PRPs State 1/1 /2024 The upper SIS samples have shown a significant reduction in the 1,4-dioxane concentration over the initial 5-year operational period. The operation of the three shallow extraction wells (RW-SIS2, RW-SIS3, and RW-SIS4) along the upper SIS has resulted in an improvement of surface water quality. However, the 1,4-dioxane results for the lower SIS sample (SW-4) has shown a highly variable COC concentration over the past 5 years of operation. This variation is attributed to rainfall patterns and resultant flow in the SIS. The impact of additional extraction wells located in SIS basin on surface water quality at the SW-4 location is currently being evaluated as part of the TM -I I study. Quarterly monitoring and evaluation of the SW-3 and SW-4 locations is recommended to supplement that study. Issue Category: Monitoring Issue: Potential Impacts from other sources. Recommendation: Eliminate downgradient surface water sample collection from SW-DRPII locations from future sampling events Affect Current Protectiveness Affect Future Protectiveness Party Responsible Oversight Party Milestone Date No No PRPs State 8/31/2023 Surface Water monitoring station S W-DRP 11 is located 4,100' downstream of surface water monitoring station SW-7 at the confluence of Randleman Lake and Richland Creek. There are two known sources of 1,4-dioxane surface water contamination in the Richland Creed watershed, located between 2 and 3 miles upstream from the Randleman Lake confluence. Surface water concentrations of 1,4-dioxane as high as 21 ug/l have been documented downstream of these two known sources. The collection of surface water samples at the SW-DRP1 Ilocation does not provide representative samples of water quality downstream of the Seaboard/Riverdale Drive Landfill Site. Issue Category: Remedy Performance Issue: COCs in groundwater below the Site Recommendation: Continue Implementing the Remedial Action Affect Current Protectiveness Affect Future Protectiveness Party Responsible Oversight Party Milestone Date Yes Yes PRPs State 2/29/2028 The selected remedy is operating as designed and as demonstrated by the data collected over the initial 5 years of system operation is effective at controlling the migration of Site COCs downgradient of the Site. Evaluation of COCs in groundwater below the Site will continue. VII. PROTECTIVENESS STATEMENT Protectiveness Determination: Protective Planned Addendum Completion Date: N/A Protectiveness Statement: The Remedy is protective of human health and the environment. The immediate threats were addressed through separate removal and closure activities at the Seaboard Chemical Property and Former Riverdale Drive Landfill Sites. Effective measures to address the remedial action objectives have been constructed and are currently being implemented and monitored. VIII. NEXT REVIEW The next five-year review report for the Seaboard Chemical/Former Riverdale Drive Landfill Site is required five years from the completion date of this review and is anticipated to be February 2028. 29 APPENDIX A — Reference List • 2017 Construction Completion Report • Remedial Recommendation Document • Remedial Monitoring and Effectiveness Evaluation Report, 2022 • Quarterly Progress Reports (2017 through 2022) • Weekly O&M Log Reports • Annual Groundwater and Surface Water Monitoring Reports, (2018, 2019, 2020, 2021, and 2022) kro APPENDIX B — Sample Copy of Weekly Log Checklist 31 WEEKLY LOG WEEK: TO SEABOARD GROUP II & THE CITY OF HIGH POINT METER READINGS: LS1 LEACHATE LS1 RWs PWDR1 SIS RWs PHYTO DISCH. POTW DISCH. AIR STRIPPER LS1 COMPR. (d1) LS1 COMPR. (d4) LS2 COMPR. (d1) LS2 COMPR. (d4) ELECT. METER WATER METER BACKWASH SPARGE BLOWER RAIN GAUGE (WEEKLY READING) CHEMICAL LEVELS SULFURIC ACID SODIUM HYD. WATER-WORX FLOCCULANT LIME SLURRY FERRIC CHLORIDE CITRIC ACID (LBS.) SODA ASH (LBS.) SODA ASH (GAL.) ID FIT-122 FIT-123 FIT-212 FIT-213 FIT-400C FIT-400 D B-605 AC-120 AC-120 AC-200 AC-200 HP-EM HP-WM FIT-603 B-600 RG GALLONS): T-303 T-304 T-614 T-615 T-711 T-712 WARE. WARE. T-713 SOURCE WATER: (CIRCLE APPLICABLE SOURCES) COMMENTS: READING UNITS GAL GAL GAL GAL GAL GAL RUN HRS RUN HRS LOAD HRS RUN HRS LOAD HRS EFFLUENT LAB SAMPLE PWDR-1 SIS RWs LS1 RWs LS1 LCHT DATE BY WELL LEVELS OWDR-4 OWDR-2 PWDR-1 OWDR-3 PW-6D OWLFS-2 PW-16D PW-15D LAKE PUMP LCHT-1 LC H T-2 LCHT-3 LC H T-4 LCHT-5 LCHT-NIS1 LCHT-NIS2 RW-NIS RW-LFS1 RW-LSF2 RW-SIS7 RW-SIS8 RW-SIS2 RW-SIS3 RW-SIS4 R-1 PWSF-1 (DATE, TIME ARRIVED, TIME DEPARTED, PERSONNEL ON SITE, TASKS COMPLETE, ISSUES) CHECKLIST: (INITIAL ALL THAT APPLY) (DATE) (2 TIMES PER WEEK) MON TUES WED THUR FRI SAT SUN CHECK FLOC QUALITY (2X PER TRIP) SKIM CLARIFIER REPLACE LS2 FILTER BAGS CHECK ELECTRIC PUMPS CHECK PNEUMATIC PUMPS (1 TIME PER WEEK) CHECK CALIBRATION TUBES CHECK CHEMICAL STORAGE AREAS TIP DRYING BOX MOVE DUMPED SLUDGE CHECK PUMP COUNTERS REPLACE FB FILTER BAG CLEAN RAIN BUCKET (NO WATER) CHECK GAUGES & METERS CHECK VALVES CHECK GATES/LOCKS (MONTHLY) SAMPLE INF., EFF., & PRE A.S. GREASE BLOWER (2X PER MONTH) CHECK BLOWER OIL CHECK AIR COMPRESSOR OIL CHECK FIRE EXTINGUISHERS CHECK EYE WASH STATIONS PEST CONTROL IN JBZs & BUILDINGS MOW & LIMB CRITICAL PATHS, BLDGS. CALIBRATE pH PROBES CALIBRATE METHANE DETECTORS CHANGE CITY WATER FILTER FLUSH HYDRANT AND YARD HYDS. CHECK FENCE INTEGRITY CHECK FOR STRESSED VEGETATION CHECK FOR PONDING WATER CHECK IRR. CONTROL BOXES (QUARTERLY) CHECK FOR CAP SUBSIDENCE CHECK FOR SLOPE EROSION CHECK CAP EROSION CHECK SLOPE DRAINS CHECK FOR LEACHATE BREAKOUTS VACUUM PANELS MOW ALL AREAS CHECK EACH ZONE FOR LEAKS SAMPLE TCLP & 8270 (ANNUALLY) CHANGE AIR FILTERS CLEAN EXHAUST FANS INVENTORY SPARE PARTS CHECK FOR NIS SCOUR COMMENTS: FIGURE 1 — Site Location Map 32 - Greensboro are I r" i, wIJ44 l I ++rr High Point r" - � ea a-oard/ rverdaLI Land-61 Site..` f e y 4 ;.. -- - Site Location .I I f Figure 1 — Site Location Map Seaboard Group II Former Seaboard/Riverdale Drive Landfill Site and 5899 Riverdale Drive The City of High Point Jamestown, North Carolina Scale- Prep. By. Rev. By- Date. 1" = 1.5 miles G. Babb G. Babb February 2023 FIGURE 2 — Site Features Map 33 SW-1 Phyto Zones 1-11 SW-6 .. Located Upstream �At Kivett Dr. Bridge SW-2 RW-NIS ENIS Sump MW-12A!„�� Ob MW-12B MW-12D PW-14D SW-DRP2 Igh lop, PW-131 MW-3C "POW-DR2 Soil 'd; .LCHT3 Residue PW-5D , •PW-DR1 M anical Treatment Mound System LS-2 .................� ORW-slss and ORW-SIS7 LCHT5E ' SW-4 LCHT4 s�SP MW-15A SW-3 W-4A191h SW-5 •RW-SIS2 Igh RW-SIS4� •-SIS3 �� Ai Phyto PW-SF10 PW-3D PW-41 Zones 12-16 R-1 r .�"''r' • N ,k PW-16D mr PW-15D :D PW-6D PW-61 LCHT2 RW-LFS20 OW-LFS2 71--1. PW-10IAOIhMW-10 go Rw-LFs1 �, PW-10D LCHT1 SW-7 Q; Groundwater Monitoring Well Surface Water Monitoring Location Leachate Collection Tank/Sump Shallow Groundwater Recovery Well Deep Groundwater Recovery Well -, SW-DRP11 Located Downstream At The Confluence O Richland Creek FIGURE 3 — Process Flow Diagram 34 ll —L— IT 1 I F -Li F Lori LCKr.3 Lcur-a U"-& U>rm ►m,&U.A LFArMTE OO LECTM TANK8 I 1I -Ltna RW4191 kW4-F92 aw-ml Rw-ml 44tAuI 4 7 F C" GRCMNOWATER RECOVERY WELLS PP-Cf41 fmui (—Law) MHkLOM { VAL!LO p M N O N L �i cu L • O CD LL O cz LIFT STATION 2 V IJME FaM FILTER SUILDiNG L -2 T-am T-001 Fk44 O L > ouALLZA_ � ID� � 0 4-0 CIMRER (� ( r-791 €c :} TANK ^, W A l rags ') ��1J EF-0U�S-: V J d WAYLA Vo.QI SURGE DR � TAM m BOXER1 F#qR r � rum+ r-xaz N LIFT 4rrATKM2 FINIYFi !..ti FIlllgaI LS-2 WAWkiER 'A TAM TAW TINE{ > EO1F{{F '0 V m Q G4T1 '- U) �y FLOW DIAGRAM Y' FORMER SEABOARD CKEMICAL FAC) ..# 1 # I FORMER � k SALE DRIVE LANDFILL WE co ova 4F14TORE}1EA1f,7104 M � IRRMTM E L E > co VJ 0 Z� `� L N 0 Z �co U) C6 (TS U M d O (0 L (n Z LL 0 co LL U) cl) Figure 3 FIGURE 4 — VOC Trend Graphs 35 FIGURE 5 — IA-Dioxane Trend Graphs 36