8106_CCPLF_SemiAnnualReport_FID1772864_20230213

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Scott Spinner Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Duke Energy Carolinas, LLC 573 Duke Power Road 8106 .0500 October 19-20, 2022
Roger's Energy Complex Mooresboro, North Carolina
Cliffside Steam Station
CCP Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ® Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Scott Spinner Project Manager [phone]
Facility Re esentative Name (Print) Title (Area Code) Telephone Number
20 2/9/2023 Affix NC Licensed/ Professional Geologist Seal
Signature Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
NC PE Firm License Number (if applicable effective May 1, 2009
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
OCTOBER 2022 SAMPLING EVENT
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
CCP LANDFILL PHASES I THROUGH IV
f]:11N Moil MIMI181-1
TITLE: OCTOBER 2022 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: — --- Date: February 9, 2023
David Avard
Approved by: �`( Date: February 9, 2023
Scott Spinner
Project Manager: Scott Spinner, NC LG
Licensed Geologist Seal:
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

17
Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
OCTOBER 2022 SAMPLING EVENT
CCP LANDFILL PHASES I THROUGH IV
PERMIT No. 8106)
CLEVELAND AND RUTHERFORD COUNTIES
ROGERS ENERGY COMPLEX — CLIFFSIDE STEAM STATION
573 DUKE POWER ROAD
MOORESBORO, NORTH CAROLINA
FEBRUARY 15, 2023
PREPARED FOR
r� DUKE
ENERGY,:
CAROLINAS
DUKE ENERGY CAROLINAS, LLC
�� - "A -
Kathryn W. Webb
Senior Peer Reviewer
s`
G David Avard
Project Scientist
Scott Spinner, NC LG #2243
Project Manager

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0
INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1
Site and Landfill Information......................................................................................1-1
1.2
Hydrogeologic Setting................................................................................................1-1
1.3
Landfill Semiannual Monitoring Program...................................................................1-2
2.0
METHODS..................................................................................................................
2-1
2.1
Sampling and Analysis Methods.................................................................................2-1
2.2
Regulatory Criteria.....................................................................................................2-1
2.3
Statement of Work.....................................................................................................2-1
3.0
RESULTS.....................................................................................................................3-1
3.1
Site Groundwater Flow...............................................................................................3-1
3.2
Analytical Results.......................................................................................................3-1
3.3
Quality Assurance/Quality Control.............................................................................3-2
4.0
REFERENCES...............................................................................................................4-1
February 2023 Page i
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Groundwater Monitoring System
Figure 3 Water -level Map — Shallow Flow Zone — October 2022
Figure 4 Water -level Map — Bedrock Flow Zone — October 2022
LIST OF TABLES
Table 1 Monitoring Location Summary Table
Table 2 Well Construction Summary
Table 3 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 4 Groundwater Seepage Velocities
Table 5 Field Data Parameters
Table 6 Leachate Field Results and Analytical Detections
Table 7 Groundwater Field Results and Analytical Detections
Table 8 Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Table 9 Surface Water Field Results and Analytical Detections
Table 10 Field and Analytical Results that Equal or Exceed Surface Water Quality
Standards
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
February 2023 Page H
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
LIST OF ACRONYMS
02L
Title 15A NCAC 02L .0202(g) Groundwater Quality Standards
02B
Title 15A NCAC 02B .0200 Surface Water and Wetland standards
CCP
Coal Combustion Products
CCR
Coal Combustion Residuals
Cliffside
Cliffside Steam Station
Duke Energy
Duke Energy Carolinas, LLC
Division
Division of Waste Management
HDPE
High -density polyethylene
landfill
CCP Landfill Phases I through IV
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
QA
Quality Assurance
QC
Quality Control
Site
Cliffside Steam Station
SW
Solid Waste
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
February 2023 Page iii
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
"KIMI►1f :1�]1�I� [�]►I_1 Ll:�_1�l:t�l:%1�1►L
This semiannual report pertains to the Duke Energy Carolinas, LLC (Duke Energy) Rogers Energy
Complex — Cliffside Steam Station (Cliffside, Site) Coal Combustion Products (CCP) Landfill
(landfill) and documents the results of the October 2022 groundwater, surface water, and
leachate monitoring event.
1.1 Site and Landfill Information
Duke Energy owns and operates Cliffside, located at 573 Duke Power Road in Mooresboro,
North Carolina (Figure 1).
The CCP Landfill has been developed in four Phases (Phases I through IV) and comprises a total
area of approximately 71.7 acres. The CCP Landfill currently accepts coal combustion residual
(CCR) material generated during coal fired power generation and other CCR disposal needs for
the Site, which includes excavated CCR materials from the on -Site ash basins. The landfill
includes a liner system consisting of two geosynthetic barrier components (a 60-mil High -
density polyethylene (HDPE) geomembrane and a geosynthetic clay liner) between waste and
the groundwater beneath the landfill (SynTerra, 2022).
1.2 Hydrogeologic Setting
The Site is located in the Inner Piedmont Belt of the Piedmont Physiographic Province. The
Piedmont Physiographic Province in North Carolina is characterized by gentle to steep, hilly
terrain with small quantities of alluvium. The Inner Piedmont is bounded on the northwest by
the Brevard Fault zone, on the southeast by the Kings Mountain Belt, and by the faults and
shear zones that define the central Piedmont structure.
As typical in the Piedmont region, groundwater is present within the residuum, saprolite,
partially weathered rock, and fractured bedrock beneath the CCP Landfill. In general, surface
drainage from the CCP Landfill flows from the west to the north towards Duke Power Road, and
to the south and east towards Suck Creek. The highest elevations at the landfill are along the
western edge of the landfill.
Two streams are near the CCP Landfill. Suck Creek is located approximately 1,200 feet
southeast of the landfill and flows north to the Broad River. An unnamed tributary to the Broad
River is located approximately 1,100 feet west of the landfill. Surface waters draining to the
Broad River are classified as WS-IV per NC 15A NCAC Subchapter 02B. Based on evaluation of
local topography, shallow groundwater beneath the landfill liner is expected to discharge to
Suck Creek and the unnamed tributary.
The landfill and surrounding topographic and physiographic features are shown on Figure 2.
February 2023 Page 1-1
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
1.3 Landfill Semiannual Monitoring Program
The October 2022 sampling event and this Semiannual Water Quality Monitoring Report
comply with the Water Quality Monitoring Plan (WQMP), Revision 0 (SynTerra, 2022) submitted
to the North Carolina Department of Environmental Quality (NCDEQ) Division of Waste
Management (Division), Solid Waste Section on March 31, 2022. The landfill semiannual
monitoring program, described in detail in the WQMP, consists of 17 groundwater, 3 surface
water, and 2 leachate monitoring locations listed on Table 1 and shown on Figure 2. A summary
of monitoring well construction information is presented in Table 2 and analytical parameter
coverage for the landfill semiannual groundwater, surface water, and leachate monitoring
program is summarized in Table 3.
February 2023 Page 1-2
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Groundwater, surface water, and leachate sampling was performed by Pace Analytical Services
personnel (Pace Analytical, North Carolina Field Certification #5342) on October 19 and 20,
2022, in accordance with the North Carolina Solid Waste Management Guidelines. Copies of the
field sampling forms are included in Appendix A. Duke Energy Analytical Laboratory (North
Carolina Laboratory Certification #248) and Pace Analytical (North Carolina Laboratory
Certification #40) analyzed the reported parameters and constituents. The laboratory report
and chain -of -custody forms are included in Appendix B.
The samples were analyzed for the list of parameters and constituents outlined in the WQMP
and guidance from the NCDEQ Division of Waste Management, Solid Waste Section. The
monitoring parameters, along with the U.S. Environmental Protection Agency (USEPA) Solid
Waste (SW)-846 analytical methods, and applicable groundwater and surface water standards
are presented in Table 3.
2.2 Regulatory Criteria
Evaluation of the semiannual monitoring analytical results are compared to the following
regulatory criteria:
Groundwater
• 15A NCAC 02L .0202(g) Groundwater Quality standards (02L)
Surface Water
• 15A NCAC 02B .0200 Surface Water and Wetland standards (02B)
Leachate
• Not compared to water quality standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Collected groundwater, surface water, and leachate samples on October 19 and 20,
2022.
• Reviewed the laboratory analytical results pertaining to the parameters listed in Table 3.
• Compared groundwater analytical results to 02L and historical concentration ranges.
• Compared surface water analytical results to 02B and historical concentration ranges.
• Developed generalized groundwater surface contour maps using groundwater elevation
data supplied by Duke Energy.
February 2023 Page 2-1
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
February 2023 Page 2-2
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
0311=3*119W
3.1 Site Groundwater Flow
The predominant direction of groundwater flow at the Site is north toward the Broad River,
with a portion of groundwater in the central part of the Site flowing toward Suck Creek and
then north to the Broad River.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCP Landfill are shown on Figure 3 for the surficial flow zone (shallow and deep
flow zones), and Figure 4 for the bedrock flow zone. These contours were developed by
calculating groundwater elevations in each monitoring well using the depth -to -water -level
measurements taken during the October 2022 monitoring event. Depth -to -water
measurements and calculated groundwater elevations are presented in Table 2. Calculated
groundwater seepage velocities are presented in Table 4. Calculated groundwater elevations,
based on depth -to -water measurements gauged during the October 2022 monitoring event,
indicate groundwater at the landfill generally flows to the east/southeast, consistent with
historical Site observations.
3.2 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table 5.
Analytical results and reference comparisons discussed below are summarized in Table 6
through Table 10. Sample locations are depicted on Figure 2.
Leachate
Leachate samples were collected from two discharge points (CCP-Leachate and CCP-Leachate-
34) located at the leachate pond. Analytical results are presented in Table 6. Leachate analytical
results are not compared to groundwater (02L) or surface water (02B) quality standards and are
provided for informational purposes only.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 7. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than 02L standards are noted in
Table 7 by bold font. The laboratory analytical reports are included as Appendix B. A summary
of the downgradient groundwater field and analytical results that are equal to or greater than
comparison criteria are presented in Table 8. Groundwater samples were not collected from
monitoring wells CCP-CCRBG-1D, CCPMW-3S, CCPMW-8S, or CCPTW-2 due to insufficient water
volume in the wells. Those wells will be attempted to be sampled during the next monitoring
event and will be evaluated for abandonment and/or replacement if they remain unviable.
Constituent concentrations in Table 7 which are identified as being equal or greater than their
applicable comparative criteria are not attributed to a release from the CCP Landfill.
February 2023 Page 3-1
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
Surface Water
Field and analytical results for surface water samples are presented in Table 9. The sample
locations are depicted on Figure 2. Analytical results for surface water samples are compared
with applicable 02B Class WS-IV surface water standards. Constituent concentrations greater
than 02B are noted in Table 9 by bold font.
A summary of surface water analytical results equal to or greater than applicable comparison
criteria is presented in Table 10.
3.3 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of a field blank to evaluate if contamination was imparted to the samples by the
sample container, preservative, or other exogenous sources. A field duplicate sample was also
collected from CCP-SW1 on October 19, 2022, to estimate sampling and laboratory precision.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the lab report. Additional QA/QC data, laboratory analyses,
and chain -of -custody forms are included in Appendix B.
February 2023 Page 3-2
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
L'111=1.44=4401"i
SynTerra. (Rev 0, 2022). Water Quality Monitoring Plan, Rogers Energy Complex — Cliffside
Steam Station CCP Landfill Phases I Through IV, March 2022.
February 2023 Page 4-1
Project: 00.0092.59.02

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
FIGURES
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SITE LOCATION MAP
SEMIANNUAL GROUNDWATER MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA
DRAWN BY: C. WYATT DATE: 06/15/2022 GRAPHIC SCALE
REVISED BY: L. FOREMAN DATE: 08/08/2022 0 500 1,000 2,000
CHECKED BY: D. AVARD DATE: 08/08/2022
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SEMIANNUAL GROUNDWATER MONITORING REPORT
DRAWN BY: C. WYATT DATE: 06/15/2022
CCP LANDFILL PHASES I THROUGH IV
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REVISED BY: E. ORDEMANN DATE: 02/08/2023
CHECKED BY: D. AVARD DATE: 02/08/2023
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
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APPROVED BY: D. AVARD DATE: 02/08/2023
MOORESBORO, NORTH CAROLINA
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4. ALL BOUNDARIES ARE APPROXIMATE
5. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS.
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6. AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLER AERIAL
_
PHOTOGRAPHY COLLECTED ON OCTOBER 25, 2022 AND GOOGLE EARTH AERIAL
IMAGERY COLLECTED ON SEPTEMBER 4, 2021.
-
7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE
.
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FIGURE 3
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WATER LEVEL MAP
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SEMIANNUAL GROUNDWATER MONITORING REPORT
DRAWN BY: C. WYATT DATE: 06/15/2022
REVISED BY: E. ORDEMANN DATE: 02/08/2023
CCP LANDFILL PHASES I THROUGH IV
CHECKED BY: D. AVARD DATE: 02/08/2023
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
APPROVED BY: D. AVARD DATE: 02/08/2023
PROJECT MANAGER: S. SPINNER
MOORESBORO, NORTH CAROLINA

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41
Qo 815.53 1
r0 \ 850 �♦ \
CCPMW 4 .M6� . �♦ ♦.
860 CCPMW 6D
812.86
♦
1 f.'
] r
� ■ 836 �6i . � . � • • ♦
DUKE PO :ER RD • • �►
yr, -. �F• ¢-. 's 1 ■ •�i.� � ��. ._ •�
CCPMW-1D41
o ?— ♦ _ •.
[r
ti
LEGEND
GROUNDWATER MONITORING WELL
..F
' � � % � 1 '��\ � $ � --• INFERRED GROUNDWATER ELEVATION CONTOUR
10 GROUNDWATER FLOW DIRECTION
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
■
+t 1 — - — • LANDFILL COMPLIANCE BOUNDARY
�m $' 0°1�, �✓ 1 1,. r. \ DUKE ENERGY CAROLINAS PROPERTY BOUNDARY
.>.
R-CCPBG-1BR
.67
4
86\ 8/
06
0
90Y
+ I STREAM (AMEC NRTR)
0000�-` \ WETLANDS (AMEC NRTR)
TOPOGRAPHIC CONTOUR (10INTERVAL)
NOTES:
f r rJ CCPMW-3D� r- '`� - ! 1. WATER LEVELS WERE COLLECTED OCTOBER 19 AND 20, 2022.
?' 790.45
'"' • �0 2. ELEVATIONS ARE REFERENCED TO THE NORTH AMERICAN VERTICAL DATUM OF
'g36-CCPMW-ZD i - • - i90 1988 (NAVD 88).
799.16 . �f • 3. THE WATERS OF THE US DELINEATION HAS NOT BEEN APPROVED BY THE
US ARMY CORPS OF ENGINEERS AT THE TIME OF THE MAP CREATION. THIS MAP
_ IS NOTTO BE USED FOR JURISDICTIONAL DETERMINATION PURPOSES. THE
WETLANDS AND STREAMS BOUNDARIES WERE OBTAINED FROM STREAM AND
. +r J w■� WETLAND DELINEATION CONDUCTED BY AMEC FOSTER WHEELER
L .. ENVIRONMENTAL AND INFRASTRUCTURE, INC. JUNE 2015.
as a� :Y - g -. • ,
(' DUKE 225 GRAPHIC SCALE
0 225 450
ENERGY. N FEET
CAROLINAS
DRAWN BY: C. WYATT DATE: 06/15/2022
REVISED BY: E. ORDEMANN DATE: 02/08/2023
L�
CHECKED BY: D. AVARD DATE: 02/08/2023
APPROVED BY: D. AVARD DATE: 02/08/2023
Terra
PROJECT MANAGER: S. SPINNER
www.synterracorp.com
4. ALL BOUNDARIES ARE APPROXIMATE.
5. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY CAROLINAS
6.AERIAL IMAGERY IS A COMBINATION OF DUKE ENERGY PROPELLER AERIAL
PHOTOGRAPHY COLLECTED ON OCTOBER 25, 2022 AND GOOGLE EARTH AERIAL
IMAGERY COLLECTED ON SEPTEMBER 4, 2021.
7. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE
PLANE COORDINATE SYSTEM FIPS 3200 (NAD83).
FIGURE 4
WATER LEVEL MAP
BEDROCK FLOW ZONE
SEMIANNUAL GROUNDWATER MONITORING REPORT
CCP LANDFILL PHASES I THROUGH IV
ROGERS ENERGY COMPLEX - CLIFFSIDE STEAM STATION
MOORESBORO, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
TABLES
L7
synTerra
Science & Engineering Consultants

TABLE 1
MONITORING LOCATION SUMMARY TABLE
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Media
Monitoring Location ID
Comments
CCR-CCPBG-1BR
CCR-CCPBG-1BR was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCR-CCPBG-1D
CCR-CCPBG-1D was installed to monitor background groundwater and is located southwest and upgradient of the landfill.
CCPMW-1S
CCPMW-1S was installed to monitor background groundwater and is located west and upgradient of the landfill.
CCPMW-1D
CCPMW-1D was installed to monitoring background ground water and is located west and upgradient of the landfill.
CCPMW-2S
CCPMW-2S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-2D
CCPMW-2D was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3S
CCPMW-3S was installed for assessment, is located south and downgradient of the landfill.
CCPMW-3D
CCPMW-3D was installed for assessment, is located south and downgradient of the landfill.
Groundwater
CCPMW-4
CCPMW-4 was installed for assessment, is located northwest and downgradient of the landfill.
CCPMW-5
CCPMW-S was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6S
CCPMW-6S was installed for assessment, is located north and downgradient of the landfill.
CCPMW-6D
CCPMW-6D was installed for assessment, is located north and downgradient of the landfill.
CCPMW-7
CCPMW-7 was installed for assessment, is located north and downgradient of the landfill.
CCPMW-8
CCPMW-8 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-10
CCPMW-10 was installed for assessment, is located south and downgradient of the landfill.
CCPMW-11
CCPMW-11 was installed for assessment, is located southeast and downgradient of the landfill.
CCPTW-2
CCPTW-2 was installed for assessment, is located south and downgradient of the landfill.
CCPSW-1
CCPSW-1 surface water monitoring location is south and upgradient of the landfill.
Surface Water
CCPSW-2
CCPSW-2 surface water monitoring location is south and downgradient of the landfill.
CCPSW-3
CCPSW-3 surface water monitoring location is west and downgradient of the landfill.
CCP-Leachate
Leachate sample, representing leachate from the entire landfill, collected from an in -line sampling point south and
downgradient of the landfill.
Leachate
CCP-Leachate-34
Leachate sample, representing leachate from the entire landfill, collected from an in -line sampling point south and
down radient of the landfill.
Note:
See Table 2 Well Construction Summary for monitoring well construction information.
Prepared By: DAA Checked By: MRC SAS
Page 1 of 1

TABLE 2
WELL CONSTRUCTION SUMMARY
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(Ft, BTOQ
Screened
Interval
(Ft, BGS)
Measuring
Point TOC
(Ft, NAVD 88)
Ground
Surface
(Ft, NAVD 88)
Groundwater
1
Elevation
(Ft, NAVD 88)
Depth
i
to Water
(Ft, BT0Q
CCR-CCPBG-1BR
7/23/2020
Bedrock
PVC
2
35.203831869
-81.775968852
98.52
91.0 - 96.0
889.02
886.52
832.67
56.35
CCR-CCPBG-1D
7/17/2020
Deep
PVC
2
35.203856335
-81.775968875
50.51
43.0 - 48.0
889.28
886.26
839.42
49.86
CCPMW-1S
2/23/2010
Deep
PVC
2
35.206700000
-81.774300000
42.45
30.0 - 40.0
875.58
873.24
BTOP
BTOP
CCPMW-1D
2/24/2010
Bedrock
PVC
2
35.206710000
-81.774300000
56.95
49.0 - 54.0
875.89
873.33
834.62
41.27
CCPMW-2S
2/24/2010
Shallow
PVC
2
35.203550000
-81.772740000
49.30
32.0 - 42.0
842.24
840.26
BTOP
BTOP
CCPMW-2D
2/24/2010
Bedrock
PVC
2
35.203550000
-81.772720000
72.80
65.0 - 70.0
842.35
840.20
799.16
43.19
CCPMW-3S
6/27/2007
Shallow
PVC
2
35.203410000
-81.771020000
16.90
9.0 - 14.0
811.56
809.30
796.53
15.03
CCPMW-3D
7/16/2007
Bedrock
PVC
2
35.203410000
-81.771000000
35.41
26.0 - 31.0
811.74
810.47
790.45
21.29
CCPMW-4
10/26/2015
Bedrock
PVC
2
35.208930000
-81.774820000
68.31
50.0 - 65.0
845.95
843.29
814.80
31.15
CCPMW-5
10/23/2015
Bedrock
PVC
2
35.209930000
-81.772850000
75.42
62.5 - 72.5
858.63
855.87
815.53
43.10
CCPMW-6S
10/21/2015
Deep
PVC
2
35.208670000
-81.771120000
46.79
33.5 - 43.5
854.35
851.48
812.72
41.63
CCPMW-6D
10/26/2015
Bedrock
PVC
2
35.208650000
-81.771100000
63.00
50.0 - 60.0
854.38
851.45
812.86
41.52
CCPMW-7
7/20/2020
Shallow
PVC
2
35.207790000
-81.769440000
51.07
37.0 - 47.0
855.49
852.63
BTOP
BTOP
CCPMW-8
7/6/2020
Shallow
PVC
2
35.203720000
-81.769460000
49.05
35.0 - 45.0
831.52
828.24
783.27
48.25
CCPMW-10
7/7/2020
Shallow
PVC
2
35.203380000
-81.768420000
45.38
32.0 - 42.0
812.98
810.45
777.53
35.45
CCPMW-11
7/1/2020
Shallow
PVC
2
35.203810000
-81.766750000
33.75
20.0 - 30.0
803.32
800.24
778.24
25.08
CCPTW-2
2/25/2010
Shallow
PVC
2
1 35.203860000
1 -81.770430000
1 47.63
35.0 - 45.0
841.72
839.62
BTOP
BTOP
Notes:
1Groundwater elevations are based on depth to water gauged during the October 19 and 20, 2022 sampling event.
BGS - Below ground surface
BTOC - Below top of casing
BTOP - Water level is below top of pump and not gauged.
Ft - Feet
NAD 83 - Horizontal coordinates based on the North American Datum of 1983.
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988
NM - Not measured
PVC - Polyvinylchloride
TOC - Top of casing
Prepared by: TWL Checked by: DAA
Page 1 of 1

TABLE 3
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
CCP LANDFILL PHASES I - IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Field Parameters
Analytical Methods
Units
15A NCAC
t
02L Standard
15A NCAC 02B
(Class WS-IV)
pH
Multi -Parameter Water Quality Meter
S.U.
6.5-8.5
6.0-9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
:529
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
>A
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
NE
NE
Turbidity
Turbidimeter
NTU
NE
<_50
Water Level
Water Level Meter
ft
NE
NE
Laboratory Parameters
Analytical Methods
Units
15A NCAC
1
02L Standard
15A NCAC 02B
2
(Class WS-IV)
Antimony
EPA 200.8/EPA 6020B
µg/L
1
N E t
Arsenic
EPA 200.8/EPA 6020B
µg/L
10
10
Barium
EPA 200.7/EPA 6010D
µg/L
700
1000
Beryllium
EPA 200.7/EPA 6010D
µg/L
4
NA#
Boron
EPA 200.7/EPA 6010D
µg/L
700
NE
Cadmium
EPA 200.8/EPA 6020B
µg/L
2
NA
Chloride
EPA 300.0/EPA 9056A
mg/L
250
250
Chromium
EPA 200.8/EPA 6020B
µg/L
10
NA*'#
Cobalt
EPA 200.8/EPA 6020B
µg/L
1
NE
Copper
EPA 200.7/EPA 6010D
µg/L
1000
NA.
Fluoride
EPA 300.0/EPA 9056A
mg/L
2
1.8
Iron
EPA 200.7/EPA 6010D
µg/L
300
NE
Lead
EPA 200.8/EPA 6020B
µg/L
15
NAB
Manganese
EPA 200.7/EPA 6010D
µg/L
50
NE
Mercury
EPA 7470A
µg/L
1
0.012
Nickel
EPA 200.7/EPA 6010D
µg/L
100
25
Nitrate
EPA 300.0/EPA 9056A
mg-N/L
10
10
Selenium
EPA 200.8/EPA 6020B
µg/L
20
NA^
Silver
EPA 200.8/EPA 6020B
µg/L
20
NA*'#
Sulfate
EPA 300.0/EPA 9056A
mg/L
250
250
Thallium
EPA 200.8/EPA 6020B
µg/L
2
NE
Total Dissolved Solids
SM 2540C
mg/L
500
500
Vanadium
EPA 200.8/EPA 6020B
µg/L
7
NE
Zinc
EPA 200.7/EPA 6010D
/L
1000
NAB
Prepared by: DAA Checked by: SAS
Notes:
1- 15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
Z - 15A NCAC 02B Standards for Class WS-IV surface waters. Water quality standards applicable to Class C waters also apply to Class WS-IV waters.
North Carolina surface water and wetland standards (effective June 1, 2022).
NE - Not established per 15A NCAC 02B
NA - Not applicable
t - Constituent does not have an established 15A NCAC 02B standard. An in -stream target value is provided in the Division of Water Resources (DWR)
"North Carolina In -Stream Target Values for Surface Waters" table.
* - Hardness -dependent dissolved metal standard not applicable to sampling method.
# - Non hardness -dependent dissolved metal standard not applicable to sampling method.
A -Total metal standard not applicable to sampling method.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
EPA - US Environmental Protection Agency
ft- feet
mg/L - milligrams per liter
mg-N/L - Milligrams nitrogen per liter
my - millivolts
NTU - nephelometric turbidity units
S.U. - Standard Units
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Well ID
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
Effective PorosityZ
Velocity
(ft/day)
(Ft NAVD 88)
(Ft NAVD 88)
CCPMW-8 to CCPMW-10
1 783.27
1 777.53
1 1.02
1 5.74
1 336
1 0.20
1 0.087
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Ah
Distance
Effective PorosityZ
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)3
(Ft NAVD 88)
(Ft NAVD 88)
CCPMW-1D to CCPMW-3D
834.62
790.45
1.30
44.17
1555
0.05
0.739
CCPMW-1D to CCPMW-6D
834.62
812.86
1.30
21.76
1188
0.05
0.476
Prepared By: TWL Checked By: DAA
Notes:
1- Values used are a calculated Geomean of hydraulic conductivities in paired wells. Hydraulic conductivity values are derived from slug test data presented in the Groundwater Monitoring Well
Installation Report (SynTerra, April 2021).
Z - Value taken from Updated Groundwater Flow and Transport Modeling Report for Cliffside Steam Station, Mooresboro, NC, December 2019 (SynTerra) .
a - Value represents an estimate of the velocity of groundwater through bedrock fractures.
ft - feet
ft/day - feet per day
Groundwater elevations are based on water level data collected in October 2022.
Hydraulic gradients and groundwater velocities are approximate.
NAVD 88 - North American Vertical Datum of 1988
Page 1 of 1

TABLE 5
FIELD DATA PARAMETERS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Sample ID
Sample Date
Appearance
Odor
Purge Method
Average Pump Rate
mL min
( / )
Temp
De C
(Deg )
Specific
Conductance
(µmhos/cm)
pH
S.U.
( )
ORP
mV
( )
Dissolved Oxygen
m L
( g/)
Turbidity
NTU
( )
Groundwater
Elevation
(Ft, NAVD 88)
Depth to Water
Ft, BTOC
( )
Groundwater Parameters
CCR-CCPBG-1D
10/19/2022
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
839.42
49.86
CCR-CCPBG-1BR
10/19/2022
Clear
None
Bladder Pump
280
17
1,264
7.6
86
1.50
1.9
832.67
56.35
CCPMW-1S
10/19/2022
Clear
None
Bladder Pump
60
13
31
5.4
57
7.60
2.7
BTOP
BTOP
CCPMW-1D
10/19/2022
Clear
None
Bladder Pump
150
15
54
5.4
35
5.60
2.4
834.62
41.27
CCPMW-2S
10/19/2022
Clear
None
Bladder Pump
50
18
59
5.6
139
7.30
0.1
BTOP
BTOP
CCPMW-2D
10/19/2022
Clear
None
Bladder Pump
100
16
143
9.7
193
3.20
0.7
799.16
43.19
CCPMW-3S
10/19/2022
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
796.53
15.03
CCPMW-3D
10/19/2022
Clear
None
Bladder Pump
300
17
117
5.5
42
4.90
2.1
790.45
21.29
CCPMW-4
10/19/2022
Clear
None
Bladder Pump
100
18
184
8.2
72
1.70
0.1
814.80
31.15
CCPMW-5
10/19/2022
Clear
None
Bladder Pump
150
17
392
11.0
-81
4.40
1.9
815.53
43.10
CCPMW-6S
10/19/2022
Clear
None
Bladder Pump
50
13
96
5.5
105
3.10
4.7
812.72
41.63
CCPMW-6D
10/19/2022
Clear
None
Bladder Pump
80
16
51
5.4
86
7.50
0.7
812.86
41.52
CCPMW-7
10/19/2022
Clear
None
Bladder Pump
100
17
72
5.2
80
5.60
7.1
BTOP
BTOP
CCPMW-8
10/19/2022
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
783.27
48.25
CCPMW-10
10/19/2022
Clear
None
Bladder Pump
200
17
45
5.0
218
5.30
8.2
777.53
35.45
CCPMW-11
10/20/2022
Clear
None
Mega Monsoon
40
19.9
68
5.4
138
4.60
9.7
778.24
25.08
CCPTW-2
10/19/2022
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
BTOP
BTOP
Surface Water Parameters
CCPSW-1
10/19/2022
Clear
None
Grab
NA
10
71
5.7
113
7.70
4.5
NA
NA
CCPSW-2
10/19/2022
Clear
None
Grab
NA
9
55
6.0
75
6.70
5.7
NA
NA
CCPSW-3
10/19/2022
NS
NS
NS
NA
NS
NS
NS
NS
NS
NS
NA
NA
Leachate Collection Parameters
CCP-Leachate
10/19/2022
Clear
None
Grab
NA
18
39,311
4.6
160
4.10
3.1
NA
NA
CCP-Leachate-34
10/19/2022
Clear
None
Grab
NA
20
4,103
4.4
100
3.10
0.1
NA
NA
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023.
Water level data collected October 19 and 20, 2022.
µmhos/cm - micromhos per centimeter
BTOC - Below top of casing
BTOP - Below top of PUMP
Deg C - Degrees Celsius
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - Not Applicable
NAVD88 - North American Vertical Datum of 1988
NS - Not Sampled
NTU - Nephelometric Turbidity Units
ORP - Oxidation Reduction Potential
S.U. - Standard units
Prepared by: TWL Checked by: DAA
Page 1 of 1

TABLE 6
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Leachate Sample ID
MDL
CCP-Leachate
CCP-Leachate-34
pH
320
S.U.
4.6
4.4
Temperature
325
Deg C
18
20
Specific Conductance
323
µmhos/cm
39
4,103
Dissolved Oxygen
-
mg/L
4.10
3.10
-
Oxidation Reduction Potential
336
mV
159.8
100.3
-
Eh
-
mV
360
300
-
Turbidity
330
NTUs
3.1
0.1
-
Antimony
13
µg/L
0.748 J
0.112 J
0.104
Arsenic
14
µg/L
12.1
7.06
0.111
Barium
15
µg/L
469
50
2
Beryllium
23
µg/L
1.21
10.8
0.249
Boron
428
µg/L
14,200
6,940
5
Cadmium
34
µg/L
2.62
3.51
0.032
Chloride
301
mg/L
15,000
600
0.0154
Chromium
51
µg/L
0.443 J
1.37
0.185
Cobalt
53
µg/L
742
472
0.077
Copper
54
µg/L
54
166
1
Fluoride
312
mg/L
1.2 J
0.91 J
0.0479
Iron
340
µg/L
406
123
4
Lead
131
µg/L
135
26
0.037
Manganese
342
µg/L
15,900
17,300
1
Mercury
132
µg/L
< 0.05
< 0.05
0.01
Nickel
152
µg/L
128
557
1
Nitrate (as N)
303
mg/L
5.1
3.8
0.002
Selenium
183
µg/L
88.4
7.99
0.193
Silver
184
µg/L
0.407 J
0.083 J
0.035
Sulfate
315
mg/L
830
1,700
0.0428
Thallium
194
µg/L
11.8
3.95
0.041
Total Dissolved Solids
311
mg/L
26,900
3,520
25
Vanadium
209
µg/L
2.09
0.153 J
0.114
Zinc
213
µg/L
1 178
1 484
4
Prepared By: TWL Checked By: DAA
Notes:
Samples collected by Pace Analytical on October 19, 2022.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023.
< - Concentration not detected at or above the adjusted reporting limit.
°C - degrees Celsius
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MOIL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L- milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - Millivolts
NTUs - Nephelometric Turbidity Units
S.U. -Standard Units
SWS ID - Solid Waste Section Identification Number
Page 1 of 1

TABLE 7
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW
GWPS
15A NCAC
02L Standard
CCPMW-1S
CCPMW-1D
CCPMW-2S
CCPMW-2D
CCPMW-3S
CCPMW-3D
CCPMW-4
CCPMW-5
CCPMW-6S
CCPMW-6D
CCPMW-7
CCPMW-8
CCPMW-10
CCPMW-11
CCPTW-2
CCR-CCPBG-1D
CCR-CCPBG-1BR
pH
320
S.U.
5.4
5.4
5.6
9.7
NS
5.5
8.2
11.0
5.5
5.4
5.2
NS
5.0
5.4
NS
NS
7.6
-
NE
6.5-8.5
Temperature
325
1 Deg C
13
15
18
16
NS
17
18
17
13
16
17
NS
17
20
NS
NS
17
-
NE
NE
Specific Conductance
323
µmhos/cm
31
54
59
143
NS
117
184
392
1 96
51
72
NS
45
68
NS
NS
1,264
-
NE
NE
Dissolved Oxygen
-
mg/L
7.60
5.60
7.30
3.20
NS
4.90
1.70
4.40
3.10
7.50
5.60
NS
5.30
4.60
NS
NS
1.50
-
NE
NE
Oxidation Reduction Potential
336
mV
56.9
35.4
138.7
192.5
NS
42.3
72.0
-80.6
104.9
86.0
79.9
NS
218.3
138.3
NS
NS
85.8
-
NE
NE
Eh
-
mV
256.9
235.4
338.7
392.5
NS
242.3
272
119
304.9
286
279.9
NS
418.3
338.3
NS
NS
285.8
-
NE
NE
Turbidity
330
NTUs
2.7
2.4
0.1
0.7
NS
2.1
0.1
1.9
4.7
0.7
7.1
NS
8.2
9.7
NS
NS
1.9
-
NE
NE
Antimony
13
µg/L
< 1
< 1
< 1
< 1
NS
< 1
< 1
0.223 J
< 1
< 1
< 1
NS
< 1
0.115 J
NS
NS
0.216 J
0.104
NE
1
Arsenic
14
µg/L
< 1
0.121 J
0.48 J
0.777 J
NS
< 1
0.806 J
1.87
0.173 J
< 1
< 1
NS
< 1
0.13 J
NS
NS
0.841 J
0.111
NE
10
Barium
15
µg/L
25
17
49
9
NS
38
8
< 5
59
30
38
NS
51
34
NS
NS
9
2
NE
700
Beryllium
23
µg/L
<1
<1
0.273J
<1
NS
<1
<1
<1
<1
<1
<1
NS
<1
<1
NS
NS
<1
0.249
NE
4
Boron
428
µg/L
< 50
6 J
91
< 50
NS
60
9 J
9 J
< 50
< 50
< 50
NS
6 J
8 J
NS
NS
15 J
5
NE
700
Cadmium
34
µg/L
<1
0.046J
<1
<1
NS
<1
<1
<1
0.168J
<1
0.048J
NS
<1
<1
NS
NS
<1
0.032
NE
2
Chloride
301
mg/L
4.7
7.7
2.9
5.4
NS
13
1.7
4.5
5
5.4
10
NS
5.2
4.9
NS
NS
160
0.0154
NE
250
Chromium
51
µg/L
0.263 J
< 1
3.4
1.94
NS
1.1
< 1
5.85
10.8
1.14
0.508 J
NS
2.26
2.98
NS
NS
1.2
0.185
NE
10
Cobalt
53
µg/L
2.93 J
0.377 J
2.59 J
< 1
NS
0.374 J
< 1
< 1
5.23 J
0.782 J
1.28 J
NS
1.20 J
0.362 J
NS
NS
0.368 J
0.077
NE
1
Copper
54
µg/L
<5
1J
2J
<5
NS
<5
<5
<5
2J
<5
<5
NS
1J
1J
NS
NS
<5
1
NE
1,000
Fluoride
312
mg/L
< 0.1
< 0.1
< 0.1
0.05 J
NS
< 0.1
0.2
0.12
0.06 J
< 0.1
< 0.1
NS
< 0.1
< 0.1
NS
NS
0.14 J
0.0479
NE
2
Iron
340
µg/L
85
11
1,310
6 J
NS
5 J
44
< 10
244
13
24
NS
237
447
NS
NS
6 J
4
NE
300
Lead
131
µg/L
0.116 J
0.055 J
1.29
< 1
NS
< 1
< 1
< 1
0.246 J
0.04 J
< 1
NS
0.23 J
0.436 J
NS
NS
0.041 J
0.037
NE
15
Manganese
342
µg/L
39
8
92
< 5
NS
12
20
< 5
288
16
46
NS
22
29
NS
NS
62
1
NE
50
Mercury
132
µg/L
< 0.05
< 0.05
0.02 J
< 0.05
NS
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
< 0.05
NS
0.02 J
< 0.05
NS
NS
< 0.05
0.01
NE
1
Nickel
152
µg/L
0.823 J
1.13 J
5.15 J
< 1
NS
< 1
2.96 J
< 1
20.1
0.551 J
1.04 J
NS
1.19 J
2.23
NS
NS
2.97 J
1
NE
100
Nitrate (as N)
303
mg-N/L
0.19
0.69
1.6
1.3
NS
1.2
0.02
1
0.66
2.4
1.8
NS
1.7
1.7
NS
NS
0.23
0.002
NE
10
Selenium
183
µg/L
<1
<1
0.491J
<1
NS
0.274J
<1
<1
<1
<1
<1
NS
<1
<1
NS
NS
<1
0.193
NE
20
Silver
184
µg/L
<1
<1
<1
<1
NS
<1
<1
<1
<1
<1
<1
NS
<1
<1
NS
NS
<1
0.035
NE
20
Sulfate
315
mg/L
0.24
1.6
6
6.4
NS
20
13
23
24
0.37
0.43
NS
0.24
1.8
NS
NS
230
0.0428
NE
250
Thallium
194
µg/L
0.065 J
0.077 J
0.095 J
< 0.2
NS
0.057 J
< 0.2
< 0.2
0.33
0.069 J
0.063 J
NS
0.143 J
0.154 J
NS
NS
< 0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
< 25.0
33
34
97
NS
86
114
136
1 70
40
54
NS
44
61
NS
NS
704
25
NE
500
Vanadium
209
µg/L
0.206 J
< 0.3
3.06
5.44
NS
0.151 J
0.116 J
17.1
0.449
< 0.3
0.17 J
NS
0.475
0.697
NS
NS
0.842
0.114
NE
7
Zinc
213
µg/L
<5
<5
1 <5
1 <5
1 NS
1 <5
1 <5
<5
6
1 <5
1 <5
1 NS
5J
6
NS
NS
<5
4
NE
1,000
Notes:
Bold and Grey concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH, greater than or less than the 02L Standard range).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L. 0202 Groundwater Quality Standards, last amended on April 1, 2022.
CCPMW-1S/D and CCR-CCPBG-1D/BR are background groundwater monitoring wells.
Samples collected by Pace Analytical personnel on October 19 and 20, 2022.
< - concentration not detected at or above the adjusted reporting limit.
°C - degrees Celsius
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
mV - Millivolts
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
NCAC - North Carolina Administrative Code
NE - Not Established
NS - Not Sampled
NTUs - Nephelometric Turbidity Units
S.U. - Standard Units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
µmhos/cm - micromhos per centimeter
µg/L - micrograms per liter
Prepared by: I WL Checked by: UAA
Page 1 of 1

TABLE 8
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
Sample ID
October 2022
Concentration
Units
1SA NCAC
02L Standard
Historical
Concentration Range*
Cause and Significance
pH
CCPMW-1S
5.4
S.U.
6.5 - 8.5
4.4 - 6.6
pH is consistent with the range of historical concentrations at CCPMW-1S
CCPMW-1D
5.4
4.4 - 9.7
pH is consistent with the range of historical concentrations at CCPMW-1D
CCPMW-2S
5.6
4.4 - 6.4
pH is consistent with the range of historical concentrations at CCPMW-2S
CCPMW-2D
9.7
8.4 - 10.5
pH is consistent with the range of historical concentrations at CCPMW-2D
CCPMW-3D
5.5
4.7 - 5.5
pH is consistent with the range of historical concentrations at CCPMW-3D
CCPMW-5
11.0
8.1 - 10.7
pH is greater than the range of historical concentrations at CCPMW-5
CCPMW-6S
5.5
4.7 - 5.8
pH is consistent with the range of historical concentrations at CCPMW-6S
CCPMW-6D
5.4
5.1 - 5.4
pH is consistent with the range of historical concentrations at CCPMW-6D
CCPMW-7
5.2
4.7 - 5.7
pH is consistent with the range of historical concentrations at CCPMW-7
CCPMW-10
5.0
4.5 - 5.2
pH is consistent with the range of historical concentrations at CCPMW-10
CCPMW-11
5.4
5.3 - 5.5
pH is consistent with the range of historical concentrations at CCPMW-11
Chromium
CCPMW-6S
10.8
µg/L
10
<1- 4.94
Chromium is greater than the range of historical concentrations at CCPMW-6S
Cobalt
CCPMW-1S
2.93
µg/L
1
0.6 - 10.7
Cobalt is consistent with the range of historical concentrations at CCPMW-1S
CCPMW-2S
2.59
0.424 - 4.08
Cobalt is consistent with the range of historical concentrations at CCPMW-2S
CCPMW-6S
5.23
1.95 - 10.3
Cobalt is consistent with the range of historical concentrations at CCPMW-6S
CCPMW-7
1.28
0.189 - 7.6
Cobalt is consistent with the range of historical concentrations at CCPMW-7
CCPMW-10
1.2
0.84 - 2.5
Cobalt is consistent with the range of historical concentrations at CCPMW-10
Iron
CCPMW-2S
1,310
µg/L
300
4.05 - 450
Iron is greater than the range of historical concentrations at CCPMW-2S
CCPMW-11
447
58 - 497
Iron is consistent with the range of historical concentrations at CCPMW-11
Manganese
CCPMW-2S
92
µg/L
50
5 - 41
Manganese is greater than the range of historical concentrations at CCPMW-2S
CCPMW-6S
288
43 - 2910
Manganese is consistent with the range of historical concentrations at CCPMW-6S
CCR-CCPBG-1BR
62
25 - 32.3
Manganese is greater than the range of historical concentrations at CCR-CCPBG-1BR
TDS
CCR-CCPBG-1BR
704
mg/L
500
165 - 1090
TDS is consistent with the range of historical concentrations at CCR-CCPBG-1BR
Notes:
* - Historical ranges are based on data in Duke Energy Carolinas, LLC (Duke Energy) analytical results database and previous reporting. Historical ranges exclude sample data with turbidity values greater than 10 NTUs.
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023.
15A NCAC 02L Standard refers to Class GA Standards as found in 15A NCAC 02L .0202 Groundwater Quality Standards, last amended on April 1, 2022.
µg/L - micrograms per liter
mg/L - milligrams per liter
S.U. - Standard Units
TDS - total dissolved solids
NTUs - Nephelometric Turbidity Units
Prepared by: DAA Checked by: TWL
Page 1 of 1

TABLE 9
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
Parameter
SWS ID
Units
Surface Water Sample ID
MDL
15A NCAC 02B
(Class WS-IV)1
CCPSW-1
CCPSW-2
CCPSW-3
pH
320
S.U.
5.7
6.0
NS
6.0-9.0
Temperature
325
°C
10
9
NS
:529
Specific Conductance
323
µmhos/cm
70
55
NS
NE
Dissolved Oxygen
-
mg/L
7.70
6.70
NS
>_4
Oxidation Reduction Potential
336
mV
113
75
NS
NE
Eh
-
mV
313
275
NS
NE
Turbidity
330
NTUs
4.5
5.7
NS
<_50
Antimony
13
µg/L
< 1
< 1
NS
0.104
NE
Arsenic
14
µg/L
0.245 J
0.283 J
NS
0.111
10
Barium
15
µg/L
21
23
NS
2
1,000
Beryllium
23
µg/L
< 1
< 1
NS
0.249
NA#
Boron
428
µg/L
11.1
10.1
NS
5
NE
Cadmium
34
µg/L
< 1
< 1
NS
0.032
NAB
Chloride
301
mg/L
4.1
4.2
NS
0.0154
250
Chromium
51
µg/L
0.279 J
0.336 J
NS
0.185
NE
Cobalt
53
µg/L
0.487 J
0.756 J
NS
0.077
NE
Copper
54
µg/L
1 J
11
NS
1
1,300'
Fluoride
312
mg/L
< 0.1
< 0.1
NS
0.0479
1.8
Iron
340
µg/L
1,260
1,270
NS
4
NE
Lead
131
µg/L
0.188 J
0.226 J
NS
0.037
NAB
Manganese
342
µg/L
27
36
NS
1
NE
Mercury
132
µg/L
< 0.05
< 0.05
NS
0.01
0.012
Nickel
152
µg/L
0.63 J
0.812 J
NS
0.256
25
Nitrate (as N)
303
mg-N/L
0.13
0.11
NS
0.002
10
Selenium
183
µg/L
< 1
< 1
NS
0.193
170'
Silver
184
µg/L
< 1
< 1
NS
0.035
NAB'#
Sulfate
315
mg/L
0.82
1.6
NS
0.0428
250
Thallium
194
µg/L
0.114 J
0.054 J
NS
0.041
NE
Total Dissolved Solids
311
mg/L
38
44
NS
25
500
Vanadium
209
µg/L
0.355
0.489
NS
0.114
NE
Zinc
213
µg/L
< 5
< 5
NS
4
NAB
Notes:
Bold and Grey concentrations are equal to or greater than the 15A NCAC 02B Standard (for pH, greater than or less than the 02B Standard range).
Samples collected by Pace Analytical personnel on October 19, 2022.
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023.
A field duplicate was collected from CCPSW-1 on 10/19/2022
1 - 15A NCAC 02B Standards for Class WS-IV surface water. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina
surface water and wetland standards (effective September 1, 2022).
t - Constituent does not have an established 15A NCAC 02B standard. An in -stream target value is provided in the Division of Water Resources (DWR) "North
Carolina In -Stream Target Values for Surface Waters" table.
* - Hardness -dependent dissolved metal standard not applicable to sampling method.
# - Non hardness -dependent dissolved metal standard not applicable to sampling method.
EPA National Recommended Water Quality Criteria for Aquatic Life and Human Health.
<- Concentration not detected at or above the adjusted reporting limit.
°C - degrees Celsius
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
mV - Millivolts
NE - Not established per 15A NCAC 02B
NA - Not applicable
NCAC - North Carolina Administrative Code
NS- not sampled, insufficient water to sample
S.U. - Standard Units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID - Solid Waste Section Identification Number
Prepared by DAA Checked by: TWL
Page 1 of 1

TABLE 10
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED SURFACE WATER QUALITY STANDARDS
CCP LANDFILL PHASES I THROUGH IV
SEMIANNUAL WATER QUALITY MONITORING REPORT
CLIFFSIDE STEAM STATION
DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC
1SA NCAC 02B
Historical
Parameter
Sample ID
October 2022
Units
Standard
Concentration
Cause and Significance
Concentration
(Class WS-IV)1
Range
pH is less than the range of historical concentrations at CCPSW-1.
pH
CCPSW-1
5.7
S.U.
6.0 - 9.0
5.8 - 7.4
Surface water sample location CCPSW-1 is the background
sample location in Suck Creek.
Prepared by: DAA Checked by: TWL
Notes:
1- 15A NCAC 02B Standards for Class WS-IV surface waters. Water quality standards applicable to Class C waters also apply to Class WS-IV waters. North Carolina surface water and wetland
standards (effective September 1, 2022).
Analytical data presented in this table reflects the Duke Energy Biological Analytical Data Storage System (BASS) as of 01/27/2023
NCAC - North Carolina Administrative Code
S.U. - Standard Units
Page 1 of 1

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
L7
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Science & Engineering Consultants

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Regulatory AgenOy:NCDENR1OWm-SWSectidn STATE EDD I EQUIS REQUIRED I PERMIT#81-06
SAMPLE PROGRAM
GmundWaler X_
NPDES
Dunking Watery_
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... ......... _-._..-.._._-_._.._.____._.._._.._.._.__..
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ICE
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300
No
HOPE
PET
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CI, F,
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Page l_of_2_
DISTRIBUTION
ORIGINAL to LAB, COW 0 CLIEW
6 Filtered
V
Requested Turnaround
De1elRma
u a
21 Days
Datemme
a c
n c
14 Days
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CHAIN OF CUSTODY RECORD AND
DUKE Nre enwgyAnildical Laboratory-
N.4 ,MDW tag">"
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------ .--_._.__
ANAL T 010 KtUIJhJT
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SAMPLE PROGRAM
DISTRIBUTION
I ORIGINAL to TAB, COW to CLIENT
LANDFILL PERMD#6,-06
=Client
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on 0
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NPUE
RYANCZOP,BRYAN MOELLER,
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:' Preservative
ICE
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Filtered
PwBmm /Epul3 Taak Catle: TESTSVSu"ragram?aek Catle:
COS
Container Volume(ML)
500
300
CCP/LF
500
500
Container Type
HDPE
pt,,
PET
HDPE
J�
(Mrtaw Prep - A6010DRM)
CI,F,
Cualomer
to compkae all appwpdele nonahedeEmeas
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U

DOeuntent Name: Field dah Sheet
Date Issued: I4 alth 8, 2Q't9
At1 641_-al.
pafie: I off
Docpmeat Number F=CAR-FID-MI-rex63
Qh'S Ruth°eitp;Pace-Hunt¢°=vilYe QualCty .
Office .
��
Name and Affiliation
Name and Affiliation (Iruspeetar)::
Well Information
Wellm C C Vnkl- 0
Well Diameter: _,a-"
Total Well Depth: Lis ft
State Water Levee: TO_Pft
Height of Water Column: ft
> I /LProject #rf CGP I( fill pm%0 S" 11
%field Data Sheet Review-
d01%9YP_a 5pw
ate. 2-D- g '
Well Locked E NO / Flmhmount )
Construction: (&/Steel/Stahrless Steel)
Multi Factor*, • I Co3 (•(Rad1usf12)2 x3.14 x?.181
Casing Volume: gallons
Cal.3'Volumesi gallons
Pump intake; . qQQ'�- ft
Purl+eInformation p J\
Date Purged: 1 V / � _( / a� Start : r0S_ Fluish:10 Iry I i n .'n
1�'Pnrge Rate: � A
Purging Method Tic d Zl ci,9d er _ _. Total Volume Purged: (`j C) cD (gallons (Q/L
Sampling Information
Date Collected:10 /i9 /'a ` Time Collected o ' aG/pra)
Sampling, Equipment Used�cl (3 jQdd-Qr Instrument ID:_ I �l l 7 (a�1Pi U Is (2
r—
Bottle Type Preservation Analysis Required
FI-
Field Measurements/Observations
Sample Temp (eC): I A • CO
Time:
Specific.Cond. (uS): C Time:
Sample pH (s.u.): • J Time:
ReDox (mV): 5Q -4 Time:
ReDox (EH value):YSI ProPlus e200mV_
General/Weather Observations:
1055_ _ Turbidity (ntu): �i Time: I lD s S
Fe2+mg/L: AM Tame:1065
Res. Cl (mg/L)j(µg/'L): " Time: —
Odcr: t4 0 Tirne: I 06L
------ Appearance: CCu
$<� Other: Time: `
un _. /cloudy/rainy) Temp YJ_(°F) Wind S (mph)
Sampler Signature. Date: fU ,!21ol
Stabilization Test
Time
Temp.
Diss Oxy.
Spec.
pH (s.u.)
ReDox
Turbidity
o ume
removed
Water
Purged
CC)
(mg/I)
(us)
(mV)
(ntu)
(gallons/
level (ft)
Other
L
lLpo
( ,0
(�
t.f
CD
DAP
f . (D
-O
a- w
5.1-0
JJ
• 18
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5s,�
5
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Document Name:
Field Data Sheet.
Document Issued: March 8, T019
FagAof-1,
t
Document Number:
F-CARFLD-001.rev.03
Issueing Authority:
Pace HuntersvitleQuality office -
Client: T VV, eGY�4--t`1�7
Location:. tVio(Dre-)b(r-(-.o NC
Project: C L S _
WelliD: U-hn03-I3
Reviewed Date and By: I O r/Z V Z-2—' ? N
Stabilization Test 141ai, � � QyL.-
1•VeH Diameter
Multiplication Factor"
1
0.0403
1.2
0.0918
1.625
0.1080
2
0.1630
3
0,3670
4
0.6530
6
1.4680'
8
2.6100
Time
Purged
g
Temp.
°
(C)
Di Oxy.
(mg/L)
Spec.
Cone.
(u5)
pH (s.u.)
ReDox (mV)
Turbidity
(ntu )
Volume R moved
{gallons m /L)
circle one
Water level
(ft)
other
IUsc�
la•i�
]:lv
��:
5.LI
53.E
S
1150
—

Document Name. Field dala Sheet
Date lumeT Marclvg, �20494
PAge-, I of
Document NumtTv F-CAR-001-mv.03
I
leaulkg. Aethwity., Pace HawArsvfilp Quality`
00ke
, NC Protect#: CLS cc f 1-4,W I/
Name and Affillation (Sampler(s)LIAL:
1L �Tj_ VC. �C,_, Field Data Sheet Review:
Name and Affiliation (Inspector):.
iol�AWRa 7-1) D
Well Information
Date-. f 0 G 2 Wf a By: S NO
Well ID.. 6 r PMW
Well Locked: ((Y_� / NO / Nushmount)
Well Diameter- 1,
Constructiont, 065t/Stepi/stalrdesssteet)
Total Well Depth: SEUAS7 ft
muitiFactor-: 0463 r(_RdiuS(12)2x3.14x7A8j
Static Water Level. .4 �13 -1 it
Casing Volume; I . 5'tp gallons
Height of Water Coltm-m._L51 U 9 ft
Cal. 3,Volumes: 7 •(P9 gallons
Pump Intake: q it
Purge Information
rL
Date Purged: __LLj_jj_/jX Start: 102-o KIM: IQqQ Purge Rate., I
Purging Method: NrAle,- pvmr Total Volume Purged: -3 0 (gallons/ (PIL)
Date Collected: 10 J-tj/ Time CoJ.lected:J_(_)45_
Sampling Equipment Used: bIJJz,- FOA-,P Instrument ID: IS 1 6 *?-04 /TrI., ls-bu
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (`C): _—J-49—Time: i (NSr -Turbidity (ntu). 2, I Time: 104 S­
Diss OXY (mg/4 5-, t 0
Time.
Ii5'
Fc2+mg/L,,N_D
Time; 0 'A 5-
Specific Cond. (uS): 5- 1 el
Time:
WA5'
Res, d(mg/L)/4tg/L):
— 'rime:
Sample pl-1. (sat.): -Time:
_1045'
odor:__j
ND Time:., 104s
ReDox (mV): 35-4
Time:
t _0`t 5'
Appearance:
rime: 104s-
ReDox (EH value):YSI ProPlus +20.0mv_
�35, i
Other:
Time:
General/Weather Observations!
LL.4;
_F13 Acil-P
kz,-e-
Sampler Signature: f::::: ate: 10-19- 22-
Stabilization Testz, �
Time
Temp,
Diss OxT
Spec.
Cond.
pH (s.u-)
VoluTrTL
removed
Water
Other
Purged
CC)
(mg/L)
(us)
(gallons//Lo/
level (ft)
_U5
Q
10 Z.157
14.1
17-5,1)
4 1, OD
.9
10.5
0,1
24-S
Z3. 1
—
1
5-1 4
5-15
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q-3tSua
q Z-0 -L
100
N I U
22�_()
qj, gx
I o +0
L 14'. Y
3•u
53.5
5 q
1 35,3
3ovp

Document Name: Fielddata Sheet
Date Issued: March 8, 2019
flC6FVk7/yIIC°4/
Page: Luf 1
Document Number, F CAR FLIP-001-rev,49
Issuing Authority: Nee Htuacrsville: Quality
"
Office
Field Data Sheet
Client: Cn o. ._Location:_ M_w�QAv v .mac Project #: L L S_ C'c
Name and Affiliation (Sampler(s): &4`/n/'n Field Data Sheet Review:
Name and Affiliation (inspector): rv/Q lo/dg/a3
Dater By:
Well Information (jG2 yZ
Well ID; ('C (�lln W - Z S Well Locke {i YE / NO / Flushmount )
Well Diameter; 7 Construction: kjj2/Stee1/Stainless Steel)
Total Well Depth: �(4;3Q-----ftMulti Factor*: 0,lC3 r(Radius/12)2x314x7.48l
Static Water Level: Q J UIJ ft Casing Volume: gallons
Height of Water Column;_mq...__ ft Cal. 3 Volumes: gallons
Pump Intake: ft
Purge Information
Date Purged._b_n/j�__/?Z _start:—z 30 -Finish:: i25O Purge Rate:
Purging Method: ui` Total Volume Purged: l000 .(ga1lons/ji9P/`L)
Samuiine Information
Date Collected:_! / L 9 / i z ` Tlme Collected: 12-5S.S _ (am&D
Sampling Equipment Used: �i .� ��I Instrument ID:
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (eC): _ 1 S
I'hne:
12 SS
Turbidity (ntu): O. I
-rime:
I ZSS
Diss Oxy (mg/L): ,3
Time:
i -L SS
Fe 2+ mg/L: tJ , D,
Time:
i z 5F
Specific Cond. (us): 59
Time:
11 S:S
Res. Cl
Sample PH (s.u.)s ^. S , �
Time:
_ 1 i SS'
Odor:_ tJ 0 Ae
_Jime:
_L ti 5-r
ReDox (mV); 1 3 $,
Time:
l SS
Appearance: Clec.-
Time:
lzSs
ReDox (EH value):YSi ProPlus +200nrV
33 S
Other: L,-9
Tine:
Wind 7' f (mph)
Sampler Signature: �4/
Stabilization Test
Spec.
Volume
Time
Temp.
Diss Oxy.
Cond.
pH (s.u:)
ReDox
Turbidity
removed
Water
Other
Purged
(C;)
(mg/L)
( )
(mV)
(ntu)
(gallons/4—'s/
level (ft)
L
DU P
6tN
Sq
6L
ill+)
6,3
-4,
59.4
S.a.
132,E
u,l
�pO
B.lo
1ZqSI
1 ,V
z 15q,7
S,6
h_3S,2j
011
1 _-So I
izSo
I i7.c
- .3 159
o
1 5,6 1
138,
11©00
clasp

AO
'�
oPaaeArrnlyticbt"
Document Name: Field data Sheet
Date Issued: March 8, 2019:
2
Page: 1062
Dmument Number: F-CAR-Ft.D-001-mv.03
Issuing Authority: Pace Huntersville Quality
Office
tall
Name -and Affiliation
Name and Affiliation
Well Information Well ID: C Mw — 0
Well Diameter: �LIV\
Total Well Depth:_71• W ft
Static Water Level• 113,19 / ift
Height of Water Column: )g.61 It
i.vacaaneec
un(p566M. /V(, n u. LLS
I Date:
Well Locked:
Construction: (/Steel/Stainless Steel)
Multi Factor`: (`1163 ruiadius/12)2 x ,14 x 7.�481
Casing Volume: H <<63 gallons
Cal.3 Volumes: 192E gallons
Pump Intake: r% 70,5 It
By:
L61 I
7,>D .
Purge Information
Date Purged. 10 /_ —U 2f — Start* -30 Finish: 1355 Purge Rate: L"
Purging Method:AGtC Qt— &Wkf Total Volume Purged: S (gallons/ sls L)
Sampling Information
Date Cotjected:_tip 1 Time Collected: 400 (am/ in
Sampling Equipment Used: 151G(Ud21 PUMV lnstrumentID: 61 0 M_41565
Battle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (°C): I h %•Ui Time:,
Diss Oxy (mg/L), 3. oL Time:
Specific Cond. (uS):_ Time:
Sample pi -I (s.u.): Time:
ReDox (mV): 19 Time:
ReDox (EH value):YSI ProPtus +200mV_
Sampler Signature
Stabilization Test
Turbidity (ntu): r' Vj Time:
Fe 2+ mg/ L: f V Time: Q
Res. CI (ing/L)``/,(µg/L): ' 'rime:
Odor:
Appearatice: Ueaf— Time: I 0
Other: Time: —
FOTM fi
9,75m. due
Time
Temp:
Diss Oxy.
Spec
Cond.
P H(} su.
ReDox
Turbidity
o uine
removed
Water
Other
Purged
(°C)
(nig/L)
(us)
(mV)
(ntu)
(gallons misy
L
level (ft)
I a3
1'
(o
15.3
7.
I:
,-7
500
Ll T—OT
15.'7
5.q
I a3.
20'),S
0, 6,
U
'-ICI. 0
UQP
16.-7S
121a
00,()
20 . (o
U.
—
a�1,3
0
5,6
to,
a90.
,(0
1 3000
--

Document Name:
Field Data Sheet
Document Issued March 8, 2019
Pageiof 4
df 4/�I1�7�}�liCri�•
l�
Document Number:
F-CAR-FLD-00l.rev.03
Issueing Authority:
Pace Huntecsville Quality Office
Client: TiLAI�Q Cii,e��y
Location: MOO &d {& `i � C
Protect: CV / CC P L ma- i l ` I �(�I'1Ni1 �gdVl pli Rj
Well ID: w��Iv1�nY —2V
is/a /aa no
Reviewed Date and By:
Stabilization Test � � e z� l P tA)
'f�trell BiaEn t r ,.
-hIwljhplicakiazt Facbox" '
1 1_G25
i
0!.1.080
I
0.1,63- 0
0.3-6 s0
4
0.6wo
6,
1..4680
3
2.,6100
• •
.
•.
(ntu)
circle one
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Doeunient Name: Field data Sheet
Date lbsued: March B, 2014
Pp e: }of_
.. BGEAtk?IyliC2/
-
Document Number; F-CAR-FI.6-Q01-rev.03
issuing A4tlusrity: Pace l-Itmtersville Quality
Office
Field Data SheeE•
CIient: Ev-u5, 4_ Loeatian: MoorzSboryfjVC Project#:f LS CCP LA.a�`I1 err +Ss .PI;n�
Name and Affiliation (Sampler(s): Mc- 12
73 D " 64 ct
Field Data Sheet Review:
Name and Affiliation (Inspector): NA
TJD
Date:/6Y931A• By-
Well Information
Well ID: Gc P M W - 3 lb
Well Locked: ( i? / NO / Flushmoui t ).
Well Diameters a
Construction: ('V /Steel/Stainless Steel)
Total Well. Depth: 3 5' k t ft
Multi Factor*: 0 • 3 (*(Radius/12)2 x 3.14 x 7 48]
Static Water Level: 21.21
Casing Volume: '2- 10 _ gallons
Height of Water Column: t a, f 2 ft
Cal. 3 Volumes 1v l 0 gallons
Pump Intake: ^ 3 3 ft
Purge Information r/L
" L1.x1
Date.Puiged; r o Ad Start:
i 3si� ; Piu sh tit Purge Rate: 3 a 0 n
Purging Method: b lkj&,� F-I,,
Total Volume Purged: (sco c) (gallons /L)
Sampling Information
Date Collected: 10 /1-1/ a,
Time Collected:' 14 2 p (am/@ )
Samplingd; , Equipment Use. b (a A &4- P
v M tP nt InstrumeID: `1 S t o 2\\y 4 j TPw , Yuu
Bottle Type
Preservation Analysis Required.
Field Measurements/Observations
SampleTemp0q: t-I,j Time: i10 Turbidity(ntu): a•1 Time: 1410
Diss Oxy (mg/L): y • q Time: I y 2a Fe 2+ mg/L � Time: t i 27
Specific Cond. (u5): ((l e.S Time: 014 Res. C1(mg/L)/(µg/L): —nn Tune: —
Sample pH (s u.): Time: 1 ` 2-D Odor: � J Time: 14 20
ReDox (mV): 41, 3 Time: 142D Appearance: Dime:
ReDox (EH value)NSI ProPlus +20(ImV 2 N 2' 3 Other: Time:
/rainy) Temp. 5f0.ff) Wind 3 (mph)
to-I`i- 22
Stabilization Test
Spec.
Volume
Time
Purged
Temp.
(C)e
Diss Oxy:
(mg/L)
Cond.
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
removed
(gallons/os/
Water
level (ft)
Amer
(us)
s(oD
tl• Z
5-,Z
12 -
<S'
35- Q
Z, 2
f S-D
7j. 35
(405'
ITT
S,o
i1 a,3
5.5
-34.0
W7
3ov©
21.35
—
141t,
17.a_.
1.9
11-7.q
1 5,5
I yl.oL
Q•\
qS-oo
21.35
—
t`i1S"
IT-X
y-
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1 5.5
1 4a. aL
1 D,H
1 t0000
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or
Dtilument Name. Field data Sheet
Date Issued: March g, 2019
If
.- dABArtalytiCttl�
t
Pa e: 1 of Z
Document Number, &CAR FLl)-D01-rev.D3
Issuing Authority. Pace Hu
ntersviile:Quality
Field Data Sheet
Name and Affiliation (Sainpler(s):
Field Data Sheet Review:
Name and Affiliation (Inspector): /
io/mma)- nD
Well Information
Date: By:
f f $7 S P
Well IQ: CC/� /%tv
Well Locked: E / NO j Flushmount)
y.
Well Diameter:
/ Construction: (ALCSteel/Stainless Steel)
p
Total Well Qepth:... �o , a Lft
Multi Factor*; 0• 1G 3' ["(Radius/12)2x3.14 x 7.4lq
Static Water Level: 3�' fS. Et
Casing Volume: G 0 r gallons
Height of Water Column: -2 l G it
Cal. 3 Volumes: ) - gallons
Pump Intake V i it
Purge Information
Date Purged:1(� f / Z Z _ Start:
j 3S Finish; Purge Rate:
Purging Method:, i�l4� Y /ham
U
Total Volume Purged: y S O O _ (gallons/L)
Sampling Information
Date Collected:_/ 0 /L4j, Z z
Time Collected: )S 2 5- (am/E
Sampling Equipment Used; !S%,� /
:'� Instrmnent ID: % `r ; ��
Bottle Type
` Preservation Analysis Required
4wt, 41 f
Field Measurements/Observations
Sample Temp (aC):
S
Time:
S Z S
Turbidity;(ntu): Q 'Time:
1 S ZS
Diss Oxy(mg/L):
) ` }
Time:
I S ZS
Fe 2+ mg/L:
Specific Cond. (uS)t
18 LI ,2�
Time:
IsZ S
Res. Cl (mg/L)/(Rg/L): = Tlme:
Sample pH (s.u.):
`a Z
Times.
{S Z.SS
Odor: N)ane Time:
I s Z S
ReDox (mV):
Z .O
Time:
I SZS
Appearance Oew Time:
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ReDox(EHvalue):YS1ProPlus+200mV _ 1 ? .0
Other: N4A Time:
General/Weather Observations:
onn cloudy/rainy) Temp.GC/ (°F) Wind 0 S (mph)
Sampler Signature
Stabilization Test
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Time
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Document Name:
Document Issued: March 3, 2019
.,. ,2ceAfk7tytieW
Field Data Sheet
Pagel of Z
Document Number:
F-CAR-FLD-001.rev.03
fssueing Authority:
Mace Huntersville Quality Office
Client:
rn�r5,� FVell Diameter Multiplication
p�. VC
Location: /Vlbor2sbaIerNc 1.2 0-0918
1.625 0.1080
Project: C L S _ LC PPrM (!I{ 2 0.1630
Well ID: ccpN\\O _L, 3 0.3670
r ,.. _ ..,. 4 0.6530
Reviewed Date and By: 6 1.46$0
Stabilization Test �tzq' t z, r 3 2.6100
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d
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--( C)
(B/�}
Cond.
(US)
pH jTu.j
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DosumentName: Field data Sheet Date Wued: March &, 2019:
eAnahZical I Page: 1 of Z
DacumeSt Number: F-CAR-6id)-Oo7-rev.Q`S umg:Authoxify Pace:Huntergville 4uality`
Client; 7A-t ��r��_LoeahomM_norrc�o.-o f� Project# LLS ccl' �u
Name and Affiliation (Sampler(s);: i" 1 E✓L TJf) - Pk Le. jDa:he.
ldData Sheet Review:
Name and Affiliation (Inspector): Al A 10/121v4ka -F) 0
By.
Well Information� u�! 2
01)
Well ID: �PM'S� Well Locked: (NOfFIushmount)
t �� .,
Well Diameter: Construction: l."1`'/Steel/Stainless Steel)
Total Well Depth: S W ft Multi Factor* 0 ((D 3 p(F d us/12)2 x s 14 x 7.4e1
Static Water Level:__ ) 0_ft CasingVhlume: gallons
Height of Water Column: 3 2. 3 -)'ft Cal. 3 Volumes: i 5 gallons
Pump Intake; '� l 3 ft
Purge Wormatian
Date Purged: 1 0 / 1 /: Start : I SS l7 Finish: l la 3 0 purge
Purging Method: r31 e.Acl IPv t, Total Volume Purged: -_ 5 Z 50 (gallons/§/L)
Sampling Information
Date Collected: 1 /�/� Time Collected:: I fo_ 3 _ (am/ r�)
Sampling, Equipment Used: N a J- a�, strument ID: Y S t
Bottle Type Preservation
Field Measurements/Observations
Analysis Required
V3 v Kt k-L--
Sample Temp (°C): 1 -7• 3 Time: 1(r 3 � _ Turbidity (ntu): 1-7 Time: I (n 3 5-
Diss OXY (mg/L,): `i, i Time: I to 35 Fe 2+ mg/L: N•O Time, I k 3 S
Specific Cond. (us): 3 12. L Time; t V 35 Res. CI in L g ) ( g/ �(Ft /L c Time:
Sample pH (s.u.): Time: I U 35 Odor:
ReDox (mV); _�D (p Titne< (U'?5 Appearance: < 12 c; r
Pp Time: _ 1 LP 3 $
ReDox (EH value):YSi PcoPlus +200mV I I I . H Other: Time:
General/Weather Observations: S a w e i t ct I. (, 1' H av e }b i1 D 5, g n: °«, j d b w hwe rd_
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are
Sampler Signature
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Document Name: Decument Issued: March 8, Wig
AtTslij✓ilC�7f Field Data Sheet page zof _ 2
e1GB
Document Number: Issuemg Authority::
F-CAR-FLD-M.xev.03 Dace ffuntersviHe Quality Office
Diameter-multmplici
Client: l7v{'—e En.ew�,u
1 p,
Location: Moores6ortz /V( 1.2 0.1
t625 p
Project: US CC f� L�a�t+lt �2✓n .r�/n{ 2 n•
Well ID- C LEmw - ,'j 3 0.3670
TJD IG%14 /2 a 4 0.030
Reviewed Date and By: Fr 1,4630
Stabilization Test �. (� bV l C) / 21z
2.6100
Time
Purged
Temp.
a
(C)
DNs Oxy.
(mg/C}
Spec.
Cond.
(US)
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(ntu)
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(gellonsr(9/L}
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Document Name: Field data Sheet
Date Issued:: March &, 2019
Page; I of Z
Document Number: F-CAWFI D-001 rev.03
lssubigAuthority: Pace Huntersvitle Quality
Office
meld Luata. Sheet..
Client: 1)U K e L-n Qf � Location: 0 *nU' Nc
Name and Affiliation (Sampier(s): Rm5-ZQ�,M - rc� c a SEND
d Data Sheet Review: )
Name and Affiliation (Inspector): NDate.
l00'@/9"a' iJt7
Well Information tt 10 (�G �By: .a S
Well ID: CC(-5tv\Qj - lJ J Well Locked: / Flushmount)'
Well Diameter: Z Construction: &/Steel/StainlessS Steel)
Total Well Depth: Ll G.19 ft Multi Factor*: C7, I G 5 r(Radius/I2)2 x3; is x 7.481
Static Water Level: +0,G3 ft Casing, Volume: gallons
Heightof Water Column; Si I G ft Cal. 3 Volumes: Z S' gallons
Pump Intake, 1-1 S ft
Purge Information
Date Purged; 1 J 15 / ZI Start: QISS Finish, 10 SO Purge Rake: Sy n J M
Purging Method: E&<� Ag- _Total Volume Purged: 31�0' (gallons/L)
SamplingSAmpling Information
Date Coilected: 10 19 Z2 1 OJT
J_/ Time Collected:_ -_.-- 8t Pin)
Sampling Equipment Used: Rn Instrument ID: qSl i�7i }rt4 TbW
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp (oq: (2 • G Time: (OSS .._4_Tvxbidity
(ntu) Ll jir
Time: �oSs
l
Diss Oxy (mg/L): 3 t I Time: l ©3T'
Fe 2+ mgf L 9' !�)'
Time: IdSS
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Rea Cl (ing/L)/(Itg/L)- ---'rime:
Sample pH (s.u.): -S' S ,Time:. 1o)SS
Odor: Nan e ...._--_----Time:
ReDox (mV); LOLI 'c) Time: tIS
Appearance: (Z\e�w-
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Time: IoSs
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Fsi
/cloudy/rainy) Temp)-\O
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Document Name:
Document Issued: March 8, 2019
aceArtaJyticai
Field Data Sheet
Page2-of Z
Document Number:
F-CAR-FI.D-001.rev.03
Issueing Authority:
Face Huntersville Quality Office
Client: Dusk: c—Z))
Location: rn oaroS i N
Project: C lS_ CC P '1= -
Well ID: CCPIV) W — Gs -
Reviewed Date and By10/"J2.3N T-3U
Stabilization Test J p r 2'kt 2 2 5 r Cq
lVell Diameter
Multiplication Factor"
1
0.0408
1.2
0.0913
1.625
0.1080
2 .
0.1630
3
0.3670
4
0.6530
6
1.4650
8
2.6100
Time
Purged
Temp.
(oC)
DissOxy.
(mg/L)
Spec.
Cord.
(US)
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(ntu)
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Document Name: Field data Sheet
Date Issued: March 11, 2019:
Page: I of 1
Document Number. FCAR-CAR-(JOI-cev:0
Issuing Authority. Face Huntersville Quality
Office
Name and Affiliation
Name and Affiliation
Well. ID:
/1� Well Locked:
Well Diameter: 0- Idt
Total Well Depths V 3 Et
Static Water Level: q . 5oZ ft
Height of Water Column: Algz__ft
Construction
)I lV C- Project#,CL5 CU J[ch
(Field Data Sheet Review:
lolgel?la
Date: 10 / Z 912 9 By. S "
Steel)
Multi Factor*:AJO ["(Radius/12)20.14x7,481
Casing Volume: 3,50 gallons
-
CaL 3 Volumes; , r7O gallons
Pumpintake: N 60,5 ft
Purge Information fl�L
Date Purged:/�/_� Start :-i,� Finish:� Purge Rate. ---SO oir\
Purging Method:W[ ' 'tit Total Volume Purged: D-COO (gallons/ n s I,)
Sampling Information
Doke Collected: /iq/_ Time Collected: —to —
Sampling Equipment Used:..6k A/AN 1=_NInstrument ID: S P Tf 1t
56 ri
Bottle Type Preservation Analysis Required
Field Measurements/Observ
ations
Sample Temp "Cc I b, Time:—JQXTMTurbidity (ntu): �7 _ Time:
Diss Oxy (mg/L):�lFe 2+ mg/L: N V Tune: )Q
Specific Cond: (uS): 5 Time: Lvov _Res. CI (mg/L)/(µg/L)--'time:
Sample pH (s,u.): S —_-- Time:, J QZ Odor:_.._-p..__._ Time:._
ReDox (mV): Time: I OX Appearance: C-((? t1
ReDox (EH value):YSI ProPlus +200mV Other: Time:
General/Weather Observations: 41/(? l I ID' CCPMK --6 D
Sampler Signature
Stabilization Test
Time
Purged
Tamp.
(C)
Diss Oxy.
(mg/L)
Spec.
Cond.
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/m1 /
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level (ft)
Other
(u5)
L
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Document Name: Field data Sheet
Field Data Sheet
Name and Affiliation (Sampler(s)�. bv I @ Cte ° Field Data Sheet Review:
Name and Affiliation (Inspector)
i a �
Datet Well Informati ons �' t17 Ik(�?, s
'C F
SPty
ByPW
1
�G
Well ID: C P M.,t�/ 7 WellLocked: (' Y( / NO / Ftushmount )
Well Diameter: at
_ Construction: (P/Steel,tStainless Steel)
Total Well Depth: '9l 3 it Multi Factor,-!q /63 r(Radius/12)2x3a4x7.4111
Static Water Level:j4a�` ft Casing Volume: gallons
Height of Water Column; =ft Cal. 3 Volumes: gallons
Punip Intake: � Ct 'i (, it
Pure In€orm tion
Date Purged.-D i � _ ^ ,
�/>—_/ Start: � Flnishfl urge Rate; G (i GhGS (� • �
Purging Method:_ D2AA t P, Total Volume Purged: 361 (gallons/t s/L)
Samptinginformation
Date Collected:_ a /_a/ 2, Time Collected;—1 3 � Z (am/&)
Sampling Equipment Used: I a / Instrument
Bottle Type Preservation Analysis Required 5 t'iV
Field MeasurementstObservations
Sample Temp Cq:_L r __Time: _Turbidity
(ntu) �7 i f Time:
Diss Oxy (mg/L): rL, Q,_ Time:
Fe 2+ mg/ L: `T C n C f Time: d 3 5 d
Specific Cond. (u5): _ Time:t�Appearance:
Res. d
Sample pH (s:u.);_.--Time:
--.
ReDox (mV): � � a� Time:
G I ea p 'rime., 1'3 5D
ReDox (EH value):YSI ProPlus +20omV —zlq_r�Other:
— Time: —�
General/Weather Observations;
(A/cloudy/rainy) Temp. ? (°I) windC-5- (mph)
Sampler Signature: i Date: �, ✓�% j C{ /'� 2
Stabilization Test
Time
Temp:
Diss Oxy
SpeC
pH (s.u.)
ReDox
Turbidity
o unte
remove
Water
Purged
(aC)
(mg/L)
(US)
(US)
mV
()
(ntu)
(g allons/ /
level (ft)
Other
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la
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Document Name: Field data Shell
Date f am& March 11, 2019'
Page:.1 of 2
Document Number; F-CAR-171.13-001-rev.S
lssuing,Authority: Pace Huntersville Quality'
Office
Field Data Sheef
Name and Affiliation (Sampler(s): AL44 /53 Z -Xice_
Name and Affiliation (Inspector): Ae� A/kA
Well Information /pltgly.L
Well ID: CLR-Mu - 10 Well Locked:
Llx �eIWJ
Field Data Sheet Review:
Date:(C/ io)AI3faa & 7�
32.�CZ� y 8011„
Well Diameter: 2" Construction: (V /Steel/Stainless Steel)
Total Well Depth: � KSl it Multi'Factoe: Q. L3 r(Radius/12)2 x 3.14 x 7,481
Static Water Level: j5 `15 ft Casing Volume: !• G 2 gallons
Height of Water Column: 7 ft Cal, 3 Volumes; `/ • 96 gallons
Pump Intake: It
Purge Information
Date Purged: 16 Start: INSU Finish: iSJy Purge Rate: 260,4
Purging Method: 66uMlAr Pot M Total Volume Purged: Coo() (gallons m)s/L)
Sampling Information
Date Collected: 14 /_LL/ 2 2 Time Collected;._._„ _ (am/l&
Sampling Equipment Used: 6W.,( _PL� Instrument ID: Y`003 m I % Pw.o! 00 _.-.._
Bottle Type Preservation Analysis Required.
_ ._.....__ L%w11 " (L: r ..........._-----
Field Measurements/Observations
Sample Temp (aC): !(7 I Time: 15 a:5____Turbidity (ntu): 9•)- _ Time: 1515-
Diss Oxy{mg/L)r % 3 Time: Fe 2+ mg/Lf (JTime: ) D-s
Specific Cond. (uS): Time: Res. Cl (mg/L)&g/L): Time:
Sample PH(s.u,):_---------- Time: Odor:_________-�anx Tirne: lSJS
ReDox (mV): 213.3 Time: Appearance: C (ecl- rime: 15J S
ReDox (EH value)NSI ProPlus.+200mV CO3- 3 Other: Time:
fun y/cloudy/rainy)
Sampler Signature
Stabilization Test
Wind T (mph)
Time
Temp,
Diss Oxy.
Spec
Cond.pH
(s.u.)
ReDox
Turbidity
Volume
removed
Water
Queer
Purged
CC)
(mg/L)
(mV)
(ntu)
(gallons/( /
level (ff)
L
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Document Nm v:.
Document Issued: Mardi 8, 2019
���pi i36 3f{fiallyllCs7�
Field Data Sheet
Page$ of,l
r
DocumetrtNumber:
IssueingAutharity:
j
F-CARFLD001.rev.03
Pace Himtemille Quality Office.
Client: _ bloke¢— G✓1Ut'
Location:_ Mex[Gkoj o,/JC
Project: CLS CCP (Y PF 1 54)�
Well ID: CU-Mw"10
Reviewed Date and By:
Stabilization Test`
l-Vell Diameter
'Multiplication Factoe
1
0.0408
1.2
0.0918
1.625
0.1080
2
0.1630
3
0.3670
4
0.6530
6
1.4680
8
2:6100
Time
Purged g'
Pur
Temp.
aG)
(,
Diss Oxy.
(mgJL)
Spec.
Cond
(u5)
pH (s.u.)
ReDox (mv)
Turbidity
(ntu}
Volume Removed
(gallons/&L)
circle one
Water level
Eft)
Other
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Document Name: Field data Sheet
Date Issued: March 8, 2019
Pa e: 1 of
- aceFNk?I)rficaTa
Document Number: F-CAR-FLD-001-rev.03
Issuing Authority: Pace Huntersville Quality,
.
Office
Field Data Sheet
.ae,CJAI
Name and Affiliation (Sampler(s):_<S17_j ALAA, p ILC4 I
ield Data Sheet Review:
Name and Affiliation (Inspector): NI A (0/Lf /ZZ
Well Information
Date: /0%�'q� By 7-JD
Well ID: . L0 - Let c; mkl Well-LoCl�d. -YES-/- dGV_Eushmount 1
Well Diameter:
Total Well Depth:
Static Water Level: — Et
Height of Water Column: ft
Gen.9tfuetiep -(VV4 /SMMj5tainless Steel)
Multi Factor": r(Radius/12)2 x 3.14 x 7.481.
Casing Volume: gallons.
Cal. 3 Volumes: gallons
Pump Intake: ft
Purge Information
Date Purged: / — / — Start: — Finish: .� Purge Rate:
Purging Method: Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected: 1 L1_ /Lv a -a Time Collected: ) O C) am pm)
Sampling Equipment Used: Instrument ID:
Bottle Type Preservation Analysis Required
C (P rt
Field Measuremerfts/Observations
Sample Temp (eC): . I1 .3 Time: ) Turbidity (ntu):_ Time:I Cll
Dig s Oxy (mg/L): 4 . �_ Time: 1030 Fe 2+ mg/L: Time:" ) 0'3 C )
Specific Cond. (uS): — Time: _ �0"',0 Res. Cl (mg/L)/(µg/L): Time:.
Sample pH (s.u.): LATime: ViO Odor: f�J% Time: I Q30
ReDox (mV): ( Time: Q?;, Appearance: CTime: 1 Q`�(7
ReDox (EH value):YSI ProPlus +200mV 3 � Other: Time:
General/Weather Observations:
Temp._q4')t:(°F) Wmd_'-�__(mph)
Sampler Signature
Stabilization Test
Time
Purged
Temp.
CC)
Digs Oxy.
(mg/L)
Spec.
(us, •
PH (s'u')
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
Water
level (ft)
Other
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731"Al
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ff+Il
Document Name: Field data Sheet
Date Issued: March 8, 2019
Page: 1 of 1
.Document Number: P•CAR-CAR-001-rev.03
Issuing Authority: Pare Huntmville Quality,
Office -.
Field Data Sheet
Name and Affiliation (Sampler(s): T -Z-- ) A LM - P6, eA Field Data Sheet Review:
Name and Affiliation (Inspector): /U l ij 10/2i /2-- W4-
Well Information Date: /U/1)M000% BY: rJD
WellID: .0 05l,t 1 -- � W.e11-Leeke&--(-YES JT7U7TIu'shmnunt )
Well Diameter: —
Total Well Depth:
Static Water Level: ft
Height of Water Column: _ ft
Const4,uetitm:•—(PVe jSCM7Stairdess Steel)
Multi Factor*: _
_ i*(Radius/12)2x3.14x7.481,
Casing Volume:
— gallons.
Cal. 3 Volumes:
— gallons
Pump Intake:
— ft
Purge Information
Date Purged: / / Start: Finish: Purge Rate:
Purging Method: Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected:- Z . /J /_ Time Collected: (;m m)
Sampling Equipment Used: G -A InstrumentlD: Sy 0 co,QUAC ti na-n�(Ml�,: u+'I-V44 3C�� i
Bottle Type
Preservation
Analysis Required
C-0 �t r
Field Measurements/Observations
Sample Temp (°C): Time:OS30 Turbidity (ntu): y Time: O`l 3 n
Dias Oxy (mg/L): Time: C �'� it Fe 2+ mg/L: t 1) Time: R g 3O
Specific Cond. (uS): Time: n. q-5 O Res. Cl (mg/LY(µg/L): Time:. ---`
Sample pH (s.u.): S Time: Q4 -� (1 . Odor: NI) Time: a' 3 p
ReDox (mV): ) Time: a� 3 O Appearance: C 14 c r Time: 0 g 3 O
ReDox (EH value):YSI ProPlus +200mV 3 , k Othec Time:
General/Weather Observations: i' k S'rennlorl 1Vnt1 G 6 ton(-'7(i-Ss`li.(
Sampler Signature
Stabilization Test
Time
Purged
Temp.
CC)
Diss Oxy.
(mg/L)
Spec.
(US)
PH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
Water
level (ft)
Other
1
,A
q
i� .
b,n
a
« X3

.rdCe`?/k1/yFlEa/•5
t
Document Name: data Field dtSheet
Date Issued: March 8, 2019
Pa e: lof_ (
-
.Document NumbAr. P•CAR-CAR-001-rev.03
Issuing Authority: Pace Huntersville Quality,
Office
Name and Affiliation (Sampler(s):�
Name and Affiliation (Inspector):_
Well Information
Well ID: . r CPS.Lo oZ
Well Diameter: '
Field Data Sheet
I l✓ ( 0-YL /vl --KCt. Ct_ Field Data Sheet Review:
/V li4 WLI172
Date:/�/���� By:
Total Well Depth: ft
Static Water Level: _ it
Height of Water Column: — ft
Purge Information
NIe1l-io hmount }
Cbastmetiew—(i'i�C�/9leelf5tainless Steel)
Multi Factor*: ["(Radius/12)2x3.140.48].
Casing Volume: gallons
Cal. 3 Volumes: — gallons
Pump Intake: Jt
P �M^PTnnS
Date Purged: Start : Finish: -_Purge Rate: '—
Purging Method: Tot al Volume Purged: s (gallons/mis/L)
Samviine Information
Date Collected: (C1. /l�v IL Time Collected: Cl (a pm)
Sampling Equipment Used: G cab Instrument ID:
Bottle Type Preservation Analysis Required j
Field Measurements/Observations
Sample Temp (°C): . � • S Time: I Q Q 0 Turbidity (ntu): Time: �i C
DissOxy(mg/L): (?•-+ Time: C) Fe2+mg/L:�J� Timer %(lCl(�
Specific Cond. (uS): 5` k Time: ci Q 0 Res. Ct (mg/LY(µg/L): Time:. --
Sample pH (s.u.): �9 .O Time: Q t Odor: ND Time: ) ()Q D
ReDox (mV): �i s ti Time: 10 Q 0 Appearance: CI-t� Time:) Q Q C)
ReDox (EH value):YSI ProPlus +200mV -� Other: Time:
General/WeatherObservations: (BPS371a,3.1TA-),-'X:°j4'S 633'W
Sampler Signature
Stabilization Test
W
/ray)
Time
Purged
Temp.
(°C)
Diss Oxy.
(mg/L)
Speer
(,
PH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
Water
level (ft)
Other

e
r�/�
�/ HCefllklfyEdCdT1
f1111
Document Name: Field data Sheet
Date Issued: March 8, 2019
Page: 1 of j
-
.Document Number: F-CAR-FLD-001-rev.03
lssuing Authority: Pace Rmtersville Quality.
Office .
Field Uata hheet
Client: 3)tAA Er\.e Location: MnckrnNL Project
Name and Affiliation (Sampler(s): TTI PaL,,, Field Data Sheet Review:
Name and Affiliation (Inspector):&LA t o/v//4'2
Well Information Date: f 61,0\0/ P
Well TD: . G L S _ . li _ \ We1LL litlsed: �( XBSa-P](� /-Flushmount-)
Well Diameter:
Total Well Depth: _ ft
Static Water Level: ft
Height of Water Column: ft
Cons#--ueKow— PVCJ to ess Steel)
Multi Factor*: — [•(Radius/12)2 x 3.14 x 7.48].
Casing Volume: gallons
Cal. 3 Volumes: gallons
Pump Intake: ft
Perrvu F 3o4,0 '- 7
By:1' aD
Purge Information
cdw\)r
Date Purged: Start : Finish: Purge Rate:
Purging Method: Total VolumePurged: (gallons/mis/L)
Samniinir Information
Date Collecfed: t 0 /LCij Time Collected: (a /pm)
Sampling Equipment Used: Vrawb Instrument ID: �/STQronIn St# oa-� �(vscr�rPw#3n�.
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Turbidity (ntu): Time:
Diss Oxy (mg/L): Time: �Fa.2+ Ln/�L.
Specific Cond. (uS): Time Res. Cl (mg/
Sample pH (s.u.): Time:odor
ReDox (mV):—Pim�e:- Appearance:
ReDox (E ltae . I ProPlus +20omV Other:
Gtl l _ i r,cnc, , i
Sampler Signature
Stabilization Test
Time:
Wind 1 _(mph)
NMI
�®

Document Na me: Niald data Sheet
Date Issued: March &, 2M
Page: tot_ t
�eArw4 t7eat'
Issui'ng Attthnrity:Facet-tuntemvil%Quatfty-
Dgcument Numher: F CAR-FC.f3-UU1-rev:03
t)ftice
Client: �V� �v ery 1 Location 41o0n
Name and Affiliation (Sampler(s). MEP-'Tjb - P 4 Q
Name and Affiliation (hispector) _ 1J A
Well Information
Weil ID.. c t_ s _ F $ Locked;
bo✓o t rv" Project #: LL S '-e
Field Data Sheet Review:
t��tf3/e�
Date:
( YES / NO / Flushmount )
(PVC/Steel/Stainless Steel)
Total Well ft Multi Factor*; i"(Ra4ius/12)2x3:140i481
Static Water Level: ft Casing Volume: gallons
Height of water CQlumn: ft Cal. 3 Volumes. ga
Pump Intake: ft
Date
Lri J4,11 Pie, i%
UD
Ey� 5 P
Purging Method, Total Volume Purger-::�— teallor../mis/1
Sam-linglnformation
DateCoilected: t0 /j`�/ a� Time Collected: lOtd a(@i/pm)
Sampling, Equipment Used: f7rab lnstrumentID-
Bottle Type. Preservation Analysis Required
Sam Temp (aC):
Time:
__Turbidity (ntu):
Time:
Diss Oxy (mg/
Time:
Fe 2+ mg/L
Time:
Specific Cond. (uS):
7riiine.
Res. Cl (rng/L)/(µg/L):
' hue:
Sam le pH (s a ):
Tinge:
P -- -
ReDox (mV); Time: Appearance:
ReDox (EH value);YST ProPlus,+2Q0mV OtheV
r- ..o t/AFnathar('lhaarvatinnnt f oti t-J-tk ci(-(t��l^� —
Sappier Sign
Con Ail t��t...n
In - TjI -tL
i 1(OF) Wind--3 —(mph)
Purged
CC)
—Dju—oxyl.
(mg/l.)
Spec,
ond.
(u5)
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level (ft)
Other

Document Name: Field data Sheet
Date Issued: March 8, 2019
- Pa 1
J CEr'F/k1fIE31y
of
ePa:
Document Number. F-CAR-FLD-001-rev.03
- Issuing Authority: ce Huntersvilfe Quality.
t
.
Office
Field Data Sheet
�' GercwS��=N�(rkr
Name and Affiliation (Sampler(s): CA- Field Data Sheet Review:
Name and Affiliation (Inspector): n�\ /� f0/Qi/2 2 1 VT''T
Well Information Date:1011t0A By:1�b
Well ID: CC\ - L2G1L�V0-�C'2Jy us oun
Well Diameter: — on tee /Sta' es Steel)
Total Well Depth: ft Multi Factor": [+(Radius/12)2 x 3.14 X 7.481,
Static Water Level: _ ft Casing Volume: gallons.
Height of Water Column: ft Cal. 3 Volumes: gallons
Pump Intake: ft
Puree Information
Date Purged: / '-/ . Start: Finish: Purge Rate:
Purging Method: Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected: 10 /JW A— Time Collected: \y� (am/(m
Sampling Equipment Used: limb Instrument ID: qSTL&L*(1(r-ev i>TeL-jit, -30,
Bottle Type Preservation Analysis Required
CU? �rj-
Field Measurements/Observations
Sample Temp (0q: l`t .g Time: M (O Turbidity (ntu): Q ` Time: C ) I n
Digs Oxy (mg/L): Time: I` l 10 Fe 2+ mg/L: M1) Time:
Specific Cond. (uS):Time:. (] \Q Res. Cl (mg/L)/(µg/L): Time:.
Sample pH (s.u.): 'k,'A Time: 1 l . Odor: lvih Time: I` ( l
ReDox (mV): \ U -; Timer\ O Appearance: Utr Time: I `O
ReDox (EH value):YSI ProPlus +2001riV �0Other: Time:
General/Weather Observations:
Wind-/o_(mph)
Sampler Signature
Stabilization Test
Time
Purged
Temp.
(C)
Diss Oxy.
(mg/L)
Spec.
Spec.Cond
()
pH (s.u.)jReD�xTurbidity
(ntu)
Volume
removed
(gallons/mis/
Water
level (ft)
Other
0.

i/ �.t�aceAnalyticAl `
r
Name and Affiliation
Name and Affiliation
WeI1 Information
well ID:CLR,-6iPIQ(�.
a..
Well Diameter:
Total Well Depth:
Static Water Level: . 1 5 ft
Height of Water Column: LI a•1-i 0 ft
Domment-Name Fiord date Shoo
document Number.F-CAR-F[D-0 1-rev:03
fra tR Field Data Sheet Review:
Date:. ,
l ofz!�rG-,7_
Well Locked:
Construction: (/Steel/Stainless5teel)
Multi Factor*; DA0 [`(Radius/12)2x3:14x7A8j
Casing Volume: tI • q I gallons
Cal. 3 Volumes; Do • _7 3 gallons
cee, 1-4".9vt Ae'r;�,i'�_
T)Z
By. 5 P W
Rump lntake.___'L t0 it
Purge Information
Date Purged: \ 3 f 1 .f a s Start : k �'1'-X O finish: 1 5 2 D Purge Irate: 230
Purging Method: _ 13i a__ AAx-,-r . y � P Total Volume Purged: 1 1 2 D 0 (gallons/ Is L)
Samplinglnformation
Date Collected: 1 �J f1 j/ " 1 Time Collected: i 5-2 5 (a @n)
Sampling; Equipment Used:_Q l Qll r p� +� nstrmnent ID: `l 5 l 0104 ) T-?w i S is &
Bottle Type Preservation Analysis Required•
0 V 14 k-,+
Field Mea&urements/Observations
Sample Temp CC): 4 Tame:
1 5 2 S'
Turbidity (ntu): I • r( Time: I S 2 5-
Diss Oxy (mg/4
)' S Time:
1 S 2 S
Fe 2+ mg/L:- - Time: I $ -L S
Specific Cond. (uS): 1 Z U 4 Time:
15 2 S
Res. Cl {iilg/L)f(Ftgf L): Time: —
Sample pH (s.u.): 1,U Time!
1 S 2-7
Odor: Nh Time:. i S' Z 5
ReDox (mV): gS. -e Time:
1575
Appearance: t (e a'_ Time: 1 5 2_5
ReDox (EH value):YSI ProRlus +200mV
2 %5. `3
other; — Time:
General/Weather Observations:
Sampler Sign
Stabilization
Time
Temp.
Digs Oxy.
Spec.
Cond.
pH
ReDox
Turbidity
Vo ume
removed
Water
Purged
(eC}
(mgfL)
(u
{mV)
(ntu)
(gallonsfyf
level (ft)
Omer
ly�ts
i I.ti
�,
2.U,
L ''
ti,LI
1,
oiD
74
12i,,.3
—
—
i`lT-0
17,
l$(!
-114
1264
a2'0
ggoJ
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i`i55-
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t.
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a•c�
y2a�
S7,
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7,t
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F aeeAatalwical'
i
Client: . �'J
Document Name:
Document Number:
F-CAR.FLD-M,rev.03
Location: M Do fe s 6 o rC3N C
Project:. e L S C C P Lc,W1,11 Pu "+ 4 Sc.' p 1;;,1
Well ID: (—(Br—
/
a CC'aC7-i
Reviewed
Date and By10/l8/X-A T)p
Stabilization Test 1 G Z C I� 2L '5p �v
PageLof:_Z
Issueing Authority;
Pace HuntersviHe Quahty office
NItrltipiication Factor"o.04oa
M
0.0918
0.10&0
0.1630
3
0.3670
0.6530
6
8
EE16t1DE0
Time
Pur ad
g
Temp
�
(0
Diss Oxy.
(mg/L)
Spec.
Cond.
(US)
pH (s.u.)
ReDox (mV).
Turbidity
(ntu)
Volume Removed
(gallons(' I L
circle one 1
Water level
t )
Other
IS-os
11.1
1.3
(3U
-7.0
of,
3.1
oap
SI,SS
15-(D
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Document Nance: Field data Sheet Date tssuediMarch 6, 2019:
aCeAn,�lyti ,11 + Page:: I of 1
_T:
i
iJm D;a mt Number: F-CAR-ELn-0obrev.03. wing Authority: Pare Ru tersville Quality
Office
CL-S—Cc P I andFi It perms
Name and Affiliation (Sampler(s): ---D ttt
p-- ?Qr0 Field Data Sheet Review;
Name and Affiliation (Inspector):
10 / Z IIZ2, IOU)
Well Information
Date: By;
In �
Well ID. l MW -3S
c�i�
Well Locked; YE / NO / Fiushmount )
Well Diameter: a1/
Construction.. Steel/Stainless Steel)
Total Well Depth: f s` a� ft
Multi Factork:0A3 !`(Radius/ 12A 0.14 x T.;#s1
Static Water Level: 1 o P ft
Casing Volume: — gallons
Height of Water Column}`'—`' ft
—
TJD to iq
Cal. 3 Volumes: gallons
Pumpintake: �� t/" ft
Pure Infemiation
Date Purged: // Start :
Finish: Purge Rate:
Purging Method:
Total Volume Purged: (gallons/mis/L)
Sampling Information
Date Collected: /_/
T ollected: _ (am/pm)
Sampling, Equipment Used:
Ins ent ID:
Bottle Type
Preservation Analysis Required.
t Q ie-� Uy.A �y � . — ---
Sample Temp (C):
Tim .. Turbidity (ntu):
Diss Oxy (mg/L):
Time.
+ mg/L:_
Specific Cond. (uS):
Time:
Res. Cl (mg
Sample PFl. (s.u.): __.Time:
Odor:_
ReDox (mV):
Time:
Appearance:
ReDox (EH value):YSI ProPlus +200mV
Other:
General/WeatherObservatio�s:
' �,r
`jZL)W ).J)C�.ttt Rcyt-p
}n cpi.
;atll iaini.ly� Bunn /cloudy/rain
Sampler Signature: _Date: J 01W
Stabilization oeST--
Tune:
Time.
Time:
C#41 Sb2tic, wris 15•03�t
Temp.:�S-_(°F) Wind U (mph)
Time
Purged
Temp,
(°C}
Diss.Oxy.
(mg/I•)
(us)
P
ReDox
V)
Turbidity
(ntu)
Vo unie
removed
(gallons/mis/
L
Water
level (ft)
Other

2seFlixrlylical.
Document -Name: Field data Shell
Date [ssued:March S, 2019'
Page: 1of�
Document Number. F-CAR-FLD-001-rev:63
lssuingAuthority: Pace Hwuersville Quality'.
Office
Field Data Sheef
Client: l.'('_ f%^1`i Location: Nuan_C,6 !Je
�Ti � � Project#:
Name and Affiliation (Sampler(s): 6CM J i 1 ? -pare Field Data Sheet R+
Name and Affiliation (Inspector):; (ilk IU�/�
Well Information Date
4
u-s ca c."9P) (&�'q S pL j
T)J
By: e ,.
Well ID: (LP 4Mu 8 Well Locked: YY / NO / Flushmount)
Well Diameter: d Construction: C//Steel/Stainless Steel)
Total Well Depth; ft Multi Factor*: c 1 r(Radius/12)2 x 3.14 x 7.481
Static Water Level:'(s A ft Casing Volume: 0' 13 gallons
Height of Water Column:6A ft Cal. 3 Volumes 31 gallons
Pump Intake:
Pum Information Co
Date Pux ed: U Iq 2,2
g �-1/ Start: .%yi Finish:, Purge Rate: `i'�1^4 t�
qc.K ioll4b,
Purging Method: ) 1 V Total Volume Purged: 01 t1 (gallons/ rl&/L)
Sampling Information
Date Collected: '-/ Time Collected,:----._ _ (am/pm)
Sampling Equipment Used: Instrument ID: --'�
Bottle Type Preservation Analysis Required
Field Measurements/Observations
Sample Temp rC):
Time:_
-_Turbidity (ntu):
Time:
Diss Oxy (mg/L):
Time.
Fe2+ mg/L
Time:
Specific Cond. (US):
Time: _
19
`lime:
Sample pifi (sa.);
trr .
Odor:_--
ReDox (mV),.
Thne:
Appearance:
Time:
ReDox (EH value):YSI ProPlus +200mV
Other:
Time:
Temp,(-F) Wind 3 (mph)
Stabilization Test
Spec
Volume
Time
Telnp.
Diss Oxy:
Cond.
p 'u')
ReDox
Turbidity
removed
Water
Omer
Purged
CC)
(mg/L)
(us)'
(mV)
(ntu)
(gallons/ r�si /
,level (ft)
L
Diu
4_(
(v
1`i.4
i
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Dmument Name
Document Issued: March 8,2019
r�ceArkllyticaf°
Field Data Sheet
Page�fof a-
.�.
r
Document Number:
Issneing:Authority:
t
F-CAR-FI.D-001.rev.03
Pace Huntersville Quality Office.
Client:. ]) cc 6✓ SqH
Location: /I' &73a sbcvu ,0(-
Project:_CJ—S GI—P LFPe)"J St�!e�
Well ID: 00 - AkW -8
Reviewed Date and By: jUL" aa. no
Stabilization Test to' / Z / 2t
tVeil Diameter
Multiplication Factor"
1
0.0408
1.2
0:0918
1.625
0.1080
2
0.1630
3
0,3670
4
0.6330
6
1.4680
a
2,6100
Time
Purged
g
Temp.
o
(C)
DissOxy.
(mg/L)
Spec.
Cond.
(US)
pH (s.u.)
ReDox (mV)
Turbidity
(ntu)
Volume Removed
(gallonse/1.)
circle one
Water level
(tt)
Other
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Document blame: N04 data sheetEWLSSuhigg
tssuedrMarch S, 2019
2CBAnatytiC�i!' Pu e:. 1 of'�
Document Numttac F-CAR-FLD-00l-rev.03 itpPace Himtersvitfa Quality
Office
Field Data shee C G S C C F (. F P eq, W
.,r ca.,• -s , \ ri ti i ) S" .. Location: i v 1 ' r
Name and Affiliation (Sampler(s): 4° t / p n (=o Pield Data Sheet Review: S
Name and Affiliation (Inspector):. �— _e /y 2 ti )MAr jc
Well Information Dater By:
k0 '3
Well ID: [C N1 - i f
Well Locked: ( / NO / Ploshmount )
WeIlDiameter: Consiruetron: (V /Steel/Staitiless Steel)
Total Well Depth: 53, 7 Fi tt Multi Factor*:li ( r(Radius/12)2x3:14z7.48l
Static Water Level.' ft Casing Volume:.I U ,3gallons
Height of Water Column: l L 16 ft Cal. 3 Volumes; iq gaUons
Pump Intake: It
Pure In€ormi tion
Date Purged: i ©p/- Lq�/`Z: Start,, Pinish: �a ��C' r�Pu/rge Rate: C � i
Purging Method:_ 15 (q t) C Let Total Volume Purged: - I I!J dt 1 (gallons/tfil�/L)
Sampling Information
Date Collected:_i-3 -/LCt/_s. 'rime Collected: _ (am/pm) Sampling Equipment Used: f Q:1 A 2 J, Instrument ID: � 2 Z 1 y �,/ r p tv PA
Bottle Type Preservation Analysis Required
i
L-
Sample Temp ( Time: Turbidity (ntu):
Diss Oxy (mg/L): i Fe 2+ 3g J r!
SpecifcCond. (uS): T (mg/L)/,
Sample pH (s, Time: Odar: _
ReDox ); Time,
Appearance:
ReDeS (EH value)NS'll ProPlus t-200mV Other:
General%WeatherObservations: `4 M4
Sampler Signature
Stabilization Test
Time:
_(°F) Wind�_(mph)
Time
Temp.
Diss Oxy:
Spec.
P
Cond.
pI-I (s.u.)
ReDox
Turbidity
Vo ume
removed
Water
Purged
(1C)-
(mg(L)
(uS
(rrrV)
(ntu)
(gallons/r&
level (ft)
Other
4C)
;.
a
Top-
aU
s
rJ`
Wz.
Z

��-CeAnalyftal$
Document Name:
Field Data Sheet.
Document Number:
F-CAR-FLD-M,rev:03
Client: -
Location;..
CG P IF Peggy i'+
Project: G L Cj c
Well JD; _. G G { S 5 Pw 1661
Reviewed Date and By: _10 5/VL rrM,4-
Stabilization Test q l a a ovz
Time Temp. Diss Oxy. Spec.
Purged (°C) fmgiL) Cond.
(us)
pH (s.u.) I ReDox (mV)
Page4f Z
Issueing Authority:
Pace Huntersville. Quality ofilee:
0.3670
4 O:6530
6 1.4680
3 "t,n
Turbidity Volume Removed
(gallons] I VL) Water level
{ntu) circle one I
(ft)
Other

,1d1�— BeA'nalyt/Ca!'
1
Document Name: Field data Sheet
I
Date Issued:Mareh &, 2Q19
I Page. Iof )
Document Number. F•CAR-171 D-0Q1-mv.63
issuing.Authority: Pace Huntersville Quality
Office
Field Data Sheet
/&W-Uitgf.r,: N( T
.J
Name and Affiliation (Sampler(s)i AL.M j 3"2
Name and Affiliation (Inspector): N//j:
Well Information
WeIJID: tAAVTW-). Well Locked:
Well Diameter: j„ Construction:
1d Data Sheet Review:
l�Ia�1�.a ray
Date: _ By: .
Steel)
Total Well Depth: ft Multi Factor*: 1(Radius/12)2 x 3.14x 7.481
Static Water Level: ` 1p1ft Casing Volume: gallons
Height of Water Colutnni _ ft Cal, 3 Volumes. gallons
Pump lntake-.N` 3 ft
Pure Information
Date Purged: i- J J d2 Start: Finish: — Purge Rate:
Purging Method: Total Volume Purged: (gallons/ails/L)
Sampling Inforlinatiott
Date Collected': Time Collected:_ _ (am/pm)
Sampling Equipment Used: Instrument ID:
Bottle Type Preservation Analysis Required
"� /. 3i (-.l LL)—u
Field Measurements/Observations
Sample Temp (°C): Time: _Turbidity
(ntu):
Time:
Diss Oxy (mgJL): Time:
Fe 2+ mg/L:'
Time:
Specific Cond. (uS): Time:
�Rg��jL�-u(]tg/L):
Time:
Sample pH (s tt.): ^ _._ e: ,
Odor:__— —
_._Time:
ReDox (mV); Time:
Appearance:
'rime:
ReDox (E value):YSI ProrIns +20QmV
Other:
Time:
Temp.--�;7S.(OF) Wind 3 (mph)
Sampler Signature
Stabilization Test
Time
Purged
Temp.
(a
Diss Oxy:
(mgJt.)
Spec. ond
CC)
(us)
)
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
o ume
removed
(gallons/mis(
L
Water
level (ft)
Other

Document Name: Field data Sheet
Date Issued: Marth 8, 2(ng
gage;
BArkRlyl%C8/
1 of
Document Number; F-CAR-FT.D-001-rev:OS
,..
Issuing: Autltonty!Pace HuntersviliaQuality
1.
ice
Name and Affiliation (Sampler(s):: J 1t, A nD
Name and Affiliation (inspector): NA
Well Information \
Well ID: _ L L P S w- 3 W&,ocked:
W ametera ConsteuchDn;
IC Project cu V e r1'4 5&'w f 11,113
ld Data Sheet Reviews
Date:10/a 01va TJD
. P17cz4i 1, By: 2Z, ';Pto
( YES / NO-/ Riushmount.
(PVC/Steel/Stainless Steel)
Total Well it Multi Factor*: r(Radius/12)2x314x7,481
Static Water Level: ft Casing Volume: gallons
Height of Water Column: ft Cal.3 Volumes: g ns
Pump Intake: fE
Ini
firm _
Date Purged: /�/ `Star- t--- '-Ph Pur e Rate:_
Purging Method: Total Volume Purged:
Cam in r information
Date Collected: /_/
Sampling; Equipment Used, Instrument
Bottle Type Preservation
Analysis Required
Field Measurements/Observations
Sa ` Temp (' : Time: ____Turbidity (rntu): Time:
Diss Oxy (mg/L}: Time: Fe 2+ mg/L: Time:
Specific Cond. (uS): 3TJbnneT—Res. Cl (rag/L)/(µg/L): TvneiSample pH (s.u.): m: ___—_ Time:
ReDox (mV); Tim: Appeararn
ReDox (EH value):YSI ProPlus +200mV Other:
GeneraVWeather Observations: S
3VX :5'531o3.a1 Sloq,'33.Z55"6=s cloud
( �i y
Sampler Signature
Stabilization Test
�i CR t✓4{e,. ��
/rainy) Temp.3 9 .(°A) Wind —_(mph)
Purged
Temp.
(
Diss Oxy.
Spec.
Cond.
(US)
pH (s.u.)
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level(ft)
Omer

At ek?lylkai"
Document Name! Fluid data Sheet
Date Issued: March S, 2(n9
Page: Iofj
Document Number: F-CAR-FI:D-001-rev.03
wing Authociiy: Pace Htmtersvitle Quility
office
Name and Affiliation (Sampler(s)-DD Field Data Sheet Review:
Name and Affiliation (Inspeetar): t Q ( 28
Well Information Date:.
-t_c I Q� a-8(')-�
CC Well ID: 'P- Q ` I D Well Locked; (LEY/ NO / Flushmount)
Well Diameter: 'a Construction: /Steel/Stasnless Steel)
Total WellDepth:5x 7 ft Multi Pactor*:�D Pt{Q
j'(,adius(12)2x3.14x7.48j
Static Water Level.'T 16(9ft Casing Volume Qdj gallons
Height of Water Column: 0. ft Cal. 3 Volurr 4 `{ a gallons
By:
cre-
Pumpintake:!`C3t!- ft
Purge IInformattio-n C
Date Purged: 10 /, 0 1 /�a_ Start., finish: purge Bate:
PurgingMethod: 1 f� �' e5L%' mansoO-) Total Volume Purged: - (gallons/mis/L)
Sampling, Equipment
Bottle Type
Field Measurements/Observations
Diss Oxy (mg/L):
Time:
Specific Cond. (US):
Time:
Sample pH (%u.):
__Time:
ReDox (mV); Time:
ReDox (EH value):YSI ProPlus.+200mV_
Time Collected:--- (am/pm)
Preservation
Analysis Required
Turbidity (ntu): Time:
Fe 2+ mg/L: Time: _
Cl (u g/L)/(gg/L): 'rime:
Appearance:
Other:
General/Weather Observations: W)(eC.d badk"rxjyvapf• Nncyn
} -�� r , ✓ I h s� .�r i^t (sunny/cloudy/rainy)
Sampler Signature: ✓
Stabilization Test
Time:
Wind_-�-_(mph)
Time
Purged
Temp.
(oC)
D` ss`Qx
(mg/l,)
Spec.
-Cazd
(uS)
H s.u.
P ( )
ReDox
(mV)
Turbidity
(ntu)
Volume
removed
(gallons/mis/
L
Water
level (ft)
Outer

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Container Volume (mL)
Sao
300
500
Coalalner Type
HOPE
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PET
(Metals PMP-TRM)
Cl, F,
Cualomer Ineompla, all appropriate noaeeded areas J,
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(ICP-EPA6010D)Ba,
B, Ca, Ca, Fe, MB, Me,
NO3-N
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Document Name: Field data Sheet
Date Issued: March 8, 2019
Page: 1 �--
BAn<?lytiCtll
of
Document Number: p-CAR-FhI}rti01-cev.03
lasuing Authority: Pace Huntersville Quality
Office
Field Data Sheet
Client:���e°l Location! n��ek Project# LLS «G�"f%
saCo��C
Name and Affiliation (Sampler(s):� - ?2ce_ Field Data Sheet Review:
Name and Affiliation (Inspector): N I A
'- f0 n) 9-1,' r J%
Date:
Well Information -
Well ID: i_( Pc n ln➢ - 1
Well Locked: YF / NO / Flushmount)
Well Diameter:
Construction: (V�/Steel/Stainless Steel)
Total Well Depth: 33 ft
Multi Factor*:'Q (»(Radius/12)2x3.14x7481
Static Water Level- 3 (YZ it
Casing Volume: gallons
Height of Water Columm-5 65 It
Cal, 3 Volumes: gallons
Pump Intake: of it
Purge Information
Date Purged:._ 10 /_20 /�aa Start :1 L,= Finish: 1 Purge Rate: Li 0 mLl cn tC�
Purging Method: mem MO nSoo -a
—Total Volume Purged: 3I-300 (gallons/(11 /L)
Sampling; Information
Date Collected: I O j� n/
Time CoilectedA Q _ (auto
Sampling Equipment Used: m6c nt.onsnc
n Instrument ID:
Bottle Type
Preservation AnalysisRequired
C (.2 . .
Field Measurements/Observations
.1` = Sample Temp (°C):l=1_Time:
Turbidity (ntu): Time:
Digs Oxy (mg/L): 6 Time:
' 1 t'LkO Fe 2+ mg/L: Tune:
Specific Cond. (uS): 6 _ Time:
1 bkQ Res. Cl (mg/L)/(gg/L): Time:
Sample pH (s.u.):_...._ _Time:
I bkQ _ Odor:_,_ /_Time:
ReDox (mv} 13� .'j Time:
( 6 -LO_ Appearance: Time: b�CO
ReDox (EH value):YSI ProPlus +20011,V 'J 5 � Other: Time:
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sun/cloudy/rainy) Temp.(*F) Wind G3 (mph) nitx '
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of

Semiannual Water Quality Monitoring Report — October 2022 Sampling Event
Rogers Energy Complex — Cliffside Steam Station — CCP Landfill Phases I through IV (Permit No. 8106)
Mooresboro, North Carolina
r
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
L7
synTerra
Science & Engineering Consultants

Analytical Data Review Checklist - Aqueous
Facility/Site
"liftd.arnStation
State
NC
Location/Sample IDs
CCP-LEACHATE, CCP-LEACHATE-34, CCPMW-1D, CCPMW-1S, CCPMW-2D, CCPMW-2S,
CCPMW-3D, CCPMW-4, CCPMW-5, CCPMW-6D, CCPMW-6S, CCPMW-7, CCPMW-10,
CCPMW-11, CCPSW-1, CCPSW-2, CCR-CCPBG-1BR
References:
- ELN/A
❑v 1 ❑
Duke Central Lab, Pace Analytical Services kw Matrix
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date ❑ Groundwater
J22090222 10/19-20/2022 10/20-21/2022 11/8/2022 ❑ Surface Water
❑ Other
National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
� Sample Receipt and Chain of Custody
1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
❑�
❑
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
❑�
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
❑�
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑�
1 ❑
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
❑
0
❑
15) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
7❑�❑�
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
0
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
0
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
0
7f) Hexavalent Chromium: Analyzed Within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
[21
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑
0
9) Method Blank- Were any parameters detected in the method blank(s)?
❑
❑
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
❑
)]
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
1 Do) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
2
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
111a) Was the original sample spiked a project sample? If so, then:
❑
❑�
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
70!Assurance/Quality
0 ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
❑ ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
❑ 0 ❑ 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
0 ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
0 ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/Mia Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑
❑� ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier% provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
J (Duke) -Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
U (Duke) -Analyte was analyzed for, but not detected above the MDL. 7
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than lox the blank concentration.
• At the request of the Duke SME, hardness calculation was added to locations CCPSW-1 and CCPSW-2.
• CCPMW-35, CCPMW-8, CCPTW-2 - insufficient volume, CCPSW-3 - dry.
• The RPD between CCPSW-1 and the field duplicate is greater than 35%for Nickel (0.63/1.12 ug/L).
• Dissolved Chromium (0.257 ug/L), Cobalt (0.81 ug/L), Lead (0.086 ug/L), and Nickel (0.669 ug/L) were detected in the 10/19/2022 Field Blank; Dissolved Chromium, Cobalt, Lead, and Nickel
were also detected in the samples at concentrations less than lox the blank concentrations.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 12/16/2022
Technical Lead SAS 2/9/2023

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J22090222
Project Name: CLIFFSIDE - GW CCP LANDFILL
Task Code: LF
Customer Name(s): Bill Wylie,Bryan Moeller,Dee O Brien,Josh Stowe
Customer Address: Cliffside Steam Station
573 Duke Power Rd
Mail Code: Clliffside Steam Station
Mooresboro, NC 28024
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: pate: 11/8/2022
(Signature)
AWnd
Program Comments:
Note: At the request of the Duke SME, hardness calculation was added to locations CCPSW-1 and CCPSW-2.
Data Flags & Calculations:
Page 1 of 91
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 91
Sample ID
Plant/Station
Collection
Date and Time
Collected By
Sample Description
2022023959
CLIFFSIDE
19-Oct-22
10:55 AM
MER TJD
CLS CCPMW-1S
2022023960
CLIFFSIDE
19-Oct-22
10:45 AM
MER TJD
CLS CCPMW-1 D
2022023961
CLIFFSIDE
19-Oct-22
12:55 PM
BMS JCM
CLS CCPMW-2S
2022023962
CLIFFSIDE
19-Oct-22
2:00 PM
BMS JCM
CLS CCPMW-2D
2022023964
CLIFFSIDE
19-Oct-22
2:20 PM
MER TJD
CLS CCPMW-3D
2022023965
CLIFFSIDE
19-Oct-22
3:25 PM
BMS JCM
CLS CCPMW-4
2022023966
CLIFFSIDE
19-Oct-22
4:35 PM
MER TJD
CLS CCPMW-5
2022023967
CLIFFSIDE
19-Oct-22
10:55 AM
BMS JCM
CLS CCPMW-6S
2022023968
CLIFFSIDE
19-Oct-22
10:20 AM
BMS JCM
CLS CCPMW-6D
2022023969
CLIFFSIDE
19-Oct-22
1:50 PM
SPW
CLS CCPMW-7
2022023971
CLIFFSIDE
19-Oct-22
3:25 PM
JJZ ALM
CLS CCPMW-10
2022023972
CLIFFSIDE
20-Oct-22
4:40 PM
JJZ
CLS CCPMW-11
2022023974
CLIFFSIDE
19-Oct-22
10:30 AM
JJZ ALM
CLS CCP-Leachate
2022023975
CLIFFSIDE
19-Oct-22
2:10 PM
JJZ ALM
CLS CCP-LEACHATE-34
2022023976
CLIFFSIDE
19-Oct-22
9:30 AM
JJZ ALM
CLS CCPSW-1
2022023977
CLIFFSIDE
19-Oct-22
10:00 AM
JJZ ALM
CLS CCPSW-2
2022023979
CLIFFSIDE
19-Oct-22
JJZ ALM
CLS FD-20221019-1
2022023981
CLIFFSIDE
19-Oct-22
10:10 AM
MER TJD
CLS FB-20221019-1010
2022023983
CLIFFSIDE
19-Oct-22
3:25 PM
MER TJD
CLS CCR-CCPBG-1BR
19 Total Samples

Page 3 of 91
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 11/8/2022

Certificate of Laboratory Analysis Page 4 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-lS
Sample #: 2022023959
Collection Date: 10/19/2022 10:55 AM
Loc code: CLS CCPMW-1 S
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
2.22 J
mg/L
5
1.7
1 SM 2320B4d
10/25/2022 12:32
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
4.7
mg/L
0.1
0.0154
1 EPA 9056A
10/20/2022 08:34
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/20/2022 08:34
BGN9034
Nitrate
0.85
mg/L
0.1
0.0209
1 EPA 9056A
10/20/2022 08:34
BGN9034
Nitrate as N
0.19
mg-N/L
0.023
0.002
1 EPA 9056A
10/20/2022 08:34
BGN9034
Sulfate
0.24
mg/L
0.1
0.0428
1 EPA 9056A
10/20/2022 08:34
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/25/2022 11:28
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Barium (Ba)
0.025
mg/L
0.005
0.002
1 SW 6010D
10/24/2022 17:20
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1 SW 6010D
10/24/2022 17:20
CELL106
Calcium (Ca)
0.332
mg/L
0.05
0.012
1 SW 6010D
10/24/2022 17:20
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:20
CELL106
Iron (Fe)
0.085
mg/L
0.01
0.004
1 SW 601OD
10/24/2022 17:20
CELL106
Magnesium (Mg)
0.859
mg/L
0.02
0.008
1 SW 6010D
10/24/2022 17:20
CELL106
Manganese (Mn)
0.039
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:20
CELL106
Potassium (K)
1.01
mg/L
0.1
0.031
1 SW 6010D
10/24/2022 17:20
CELL106
Sodium (Na)
1.69
mg/L
0.05
0.017
1 SW 6010D
10/24/2022 17:20
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/24/2022 17:20
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/24/2022 13:02
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1 SW 6020B
10/24/2022 13:02
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/24/2022 13:02
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/24/2022 13:02
MHALL3
Chromium (Cr)
0.263 J
ug/L
1
0.185
1 SW 6020B
10/24/2022 13:02
MHALL3
Cobalt (Co)
2.93
ug/L
1
0.077
1 SW 6020B
10/24/2022 13:02
MHALL3
Lead (Pb)
0.116 J
ug/L
1
0.037
1 SW 6020B
10/24/2022 13:02
MHALL3
Nickel (Ni)
0.823 J
ug/L
1
0.256
1 SW 6020B
10/24/2022 13:02
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/24/2022 13:02
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/24/2022 13:02
MHALL3
Thallium (TI) Low Level
0.065 J
ug/L
0.2
0.041
1 SW 6020B
10/24/2022 13:02
MHALL3
Vanadium (V) Low Level
0.206 J
ug/L
0.3
0.114
1 SW 6020B
10/24/2022 13:02
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 5 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-1 D
Sample #: 2022023960
Collection Date: 10/19/2022 10:45 AM
Loc code: CLS CCPMW-1 D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
5.17
mg/L
5
1.7
1 SM 2320B4d
10/25/2022 12:44
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
7.7
mg/L
0.1
0.0154
1 EPA 9056A
10/20/2022 09:53
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/20/2022 09:53
BGN9034
Nitrate
3.0
mg/L
0.1
0.0209
1 EPA 9056A
10/20/2022 09:53
BGN9034
Nitrate as N
0.69
mg-N/L
0.023
0.002
1 EPA 9056A
10/20/2022 09:53
BGN9034
Sulfate
1.6
mg/L
0.1
0.0428
1 EPA 9056A
10/20/2022 09:53
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/25/2022 11:35
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Barium (Ba)
0.017
mg/L
0.005
0.002
1 SW 6010D
10/24/2022 17:33
CELL106
Boron (B)
0.006 J
mg/L
0.05
0.005
1 SW 6010D
10/24/2022 17:33
CELL106
Calcium (Ca)
2.77
mg/L
0.05
0.012
1 SW 6010D
10/24/2022 17:33
CELL106
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:33
CELL106
Iron (Fe)
0.011
mg/L
0.01
0.004
1 SW 601OD
10/24/2022 17:33
CELL106
Magnesium (Mg)
1.45
mg/L
0.02
0.008
1 SW 6010D
10/24/2022 17:33
CELL106
Manganese (Mn)
0.008
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:33
CELL106
Potassium (K)
1.41
mg/L
0.1
0.031
1 SW 6010D
10/24/2022 17:33
CELL106
Sodium (Na)
2.86
mg/L
0.05
0.017
1 SW 6010D
10/24/2022 17:33
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/24/2022 17:33
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/24/2022 13:10
MHALL3
Arsenic (As)
0.121 J
ug/L
1
0.111
1 SW 6020B
10/24/2022 13:10
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/24/2022 13:10
MHALL3
Cadmium (Cd)
0.046 J
ug/L
1
0.032
1 SW 6020B
10/24/2022 13:10
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1 SW 6020B
10/24/2022 13:10
MHALL3
Cobalt (Co)
0.377 J
ug/L
1
0.077
1 SW 6020B
10/24/2022 13:10
MHALL3
Lead (Pb)
0.055 J
ug/L
1
0.037
1 SW 6020B
10/24/2022 13:10
MHALL3
Nickel (Ni)
1.13
ug/L
1
0.256
1 SW 6020B
10/24/2022 13:10
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/24/2022 13:10
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/24/2022 13:10
MHALL3
Thallium (TI) Low Level
0.077 J
ug/L
0.2
0.041
1 SW 6020B
10/24/2022 13:10
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1 SW 6020B
10/24/2022 13:10
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 6 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-2S
Sample #: 2022023961
Collection Date: 10/19/2022 12:55 PM
Loc code: CLS CCPMW-2S
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
4.54 J
mg/L
5
1.7
1 SM 2320B4d
10/25/2022 12:57
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
2.9
mg/L
0.1
0.0154
1 EPA 9056A
10/20/2022 10:13
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1 EPA 9056A
10/20/2022 10:13
BGN9034
Nitrate
7.3
mg/L
0.1
0.0209
1 EPA 9056A
10/20/2022 10:13
BGN9034
Nitrate as N
1.6
mg-N/L
0.023
0.002
1 EPA 9056A
10/20/2022 10:13
BGN9034
Sulfate
6.0
mg/L
0.1
0.0428
1 EPA 9056A
10/20/2022 10:13
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1 EPA 7470A
10/25/2022 11:38
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Barium (Ba)
0.049
mg/L
0.005
0.002
1 SW 6010D
10/24/2022 17:38
CELL106
Boron (B)
0.009 J
mg/L
0.05
0.005
1 SW 6010D
10/24/2022 17:38
CELL106
Calcium (Ca)
3.12
mg/L
0.05
0.012
1 SW 6010D
10/24/2022 17:38
CELL106
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:38
CELL106
Iron (Fe)
1.31
mg/L
0.01
0.004
1 SW 601OD
10/24/2022 17:38
CELL106
Magnesium (Mg)
1.98
mg/L
0.02
0.008
1 SW 6010D
10/24/2022 17:38
CELL106
Manganese (Mn)
0.092
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:38
CELL106
Potassium (K)
2.18
mg/L
0.1
0.031
1 SW 6010D
10/24/2022 17:38
CELL106
Sodium (Na)
1.69
mg/L
0.05
0.017
1 SW 6010D
10/24/2022 17:38
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/24/2022 17:38
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/24/2022 12:19
MHALL3
Arsenic (As)
0.48 J
ug/L
1
0.111
1 SW 6020B
10/24/2022 12:19
MHALL3
Beryllium (Be)
0.273 J
ug/L
1
0.249
1 SW 6020B
10/24/2022 12:19
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/24/2022 12:19
MHALL3
Chromium (Cr)
3.40
ug/L
1
0.185
1 SW 6020B
10/24/2022 12:19
MHALL3
Cobalt (Co)
2.59
ug/L
1
0.077
1 SW 6020B
10/24/2022 12:19
MHALL3
Lead (Pb)
1.29
ug/L
1
0.037
1 SW 6020B
10/24/2022 12:19
MHALL3
Nickel (Ni)
5.15
ug/L
1
0.256
1 SW 6020B
10/24/2022 12:19
MHALL3
Selenium (Se)
0.491 J
ug/L
1
0.193
1 SW 6020B
10/24/2022 12:19
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/24/2022 12:19
MHALL3
Thallium (TI) Low Level
0.095 J
ug/L
0.2
0.041
1 SW 6020B
10/24/2022 12:19
MHALL3
Vanadium (V) Low Level
3.06
ug/L
0.3
0.114
1 SW 6020B
10/24/2022 12:19
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 7 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-2D
Sample #: 2022023962
Collection Date: 10/19/2022 02:00 PM
Loc code: CLS CCPMW-2D
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
45.4
mg/L
5
1.7
1 SM 2320B4d
10/25/2022 13:10
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
5.4
mg/L
0.1
0.0154
1 EPA 9056A
10/20/2022 10:32
BGN9034
Fluoride
0.05 J
mg/L
0.1
0.0479
1 EPA 9056A
10/20/2022 10:32
BGN9034
Nitrate
5.7
mg/L
0.1
0.0209
1 EPA 9056A
10/20/2022 10:32
BGN9034
Nitrate as N
1.3
mg-N/L
0.023
0.002
1 EPA 9056A
10/20/2022 10:32
BGN9034
Sulfate
6.4
mg/L
0.1
0.0428
1 EPA 9056A
10/20/2022 10:32
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1 EPA 7470A
10/25/2022 11:40
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Barium (Ba)
0.009
mg/L
0.005
0.002
1 SW 6010D
10/24/2022 17:42
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1 SW 6010D
10/24/2022 17:42
CELL106
Calcium (Ca)
16.9
mg/L
0.05
0.012
1 SW 6010D
10/24/2022 17:42
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:42
CELL106
Iron (Fe)
0.006 J
mg/L
0.01
0.004
1 SW 601 OD
10/24/2022 17:42
CELL106
Magnesium (Mg)
0.545
mg/L
0.02
0.008
1 SW 6010D
10/24/2022 17:42
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1 SW 6010D
10/24/2022 17:42
CELL106
Potassium (K)
6.17
mg/L
0.1
0.031
1 SW 6010D
10/24/2022 17:42
CELL106
Sodium (Na)
6.56
mg/L
0.05
0.017
1 SW 6010D
10/24/2022 17:42
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1 SW 6010D
10/24/2022 17:42
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1 SW 6020B
10/24/2022 13:19
MHALL3
Arsenic (As)
0.777 J
ug/L
1
0.111
1 SW 6020B
10/24/2022 13:19
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1 SW 6020B
10/24/2022 13:19
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1 SW 6020B
10/24/2022 13:19
MHALL3
Chromium (Cr)
1.94
ug/L
1
0.185
1 SW 6020B
10/24/2022 13:19
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1 SW 6020B
10/24/2022 13:19
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1 SW 6020B
10/24/2022 13:19
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1 SW 6020B
10/24/2022 13:19
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1 SW 6020B
10/24/2022 13:19
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1 SW 6020B
10/24/2022 13:19
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1 SW 6020B
10/24/2022 13:19
MHALL3
Vanadium (V) Low Level
5.44
ug/L
0.3
0.114
1 SW 6020B
10/24/2022 13:19
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 8 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-3D Sample #: 2022023964
Collection Date: 10/19/2022 02:20 PM Loc code: CLS CCPMW-3D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 6.55 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
13
mg/L
0.5
0.0154 5
Fluoride
0.0479 U
mg/L
0.1
0.0479 1
Nitrate
5.5
mg/L
0.1
0.0209 1
Nitrate as N
1.2
mg-N/L
0.023
0.002 1
Sulfate
20
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 13:18 CELL106
EPA
9056A
10/20/2022 10:52
BGN9034
EPA
9056A
10/20/2022 10:52
BGN9034
EPA
9056A
10/20/2022 10:52
BGN9034
EPA
9056A
10/20/2022 10:52
BGN9034
EPA
9056A
10/20/2022 10:52
BGN9034
EPA
7470A
10/25/2022 11:42
JAA5429
Barium (Ba)
0.038
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 17:47
CELL106
Boron (B)
0.060
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 17:47
CELL106
Calcium (Ca)
11.7
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 17:47
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:47
CELL106
Iron (Fe)
0.005 J
mg/L
0.01
0.004
1
SW 601 OD
10/24/2022 17:47
CELL106
Magnesium (Mg)
2.86
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 17:47
CELL106
Manganese (Mn)
0.012
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:47
CELL106
Potassium (K)
1.88
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 17:47
CELL106
Sodium (Na)
2.57
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 17:47
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 17:47
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/24/2022 13:27
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/24/2022 13:27
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 13:27
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 13:27
MHALL3
Chromium (Cr)
1.10
ug/L
1
0.185
1
SW 6020B
10/24/2022 13:27
MHALL3
Cobalt (Co)
0.374 J
ug/L
1
0.077
1
SW 6020B
10/24/2022 13:27
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/24/2022 13:27
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/24/2022 13:27
MHALL3
Selenium (Se)
0.274 J
ug/L
1
0.193
1
SW 6020B
10/24/2022 13:27
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 13:27
MHALL3
Thallium (TI) Low Level
0.057 J
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 13:27
MHALL3
Vanadium (V) Low Level
0.151 J
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 13:27
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-4
Collection Date: 10/19/2022 03:25 PM Loc code: CLS CCPMW-4
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 71.4 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
1.7
mg/L
0.1
0.0154 1
Fluoride
0.20
mg/L
0.1
0.0479 1
Nitrate
0.11
mg/L
0.1
0.0209 1
Nitrate as N
0.02
mg-N/L
0.023
0.002 1
Sulfate
13
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Sample #: 2022023965
Matrix: GW RCRA
Page 9 of 91
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 13:24 CELL106
EPA
9056A
10/20/2022 11:12
BGN9034
EPA
9056A
10/20/2022 11:12
BGN9034
EPA
9056A
10/20/2022 11:12
BGN9034
EPA
9056A
10/20/2022 11:12
BGN9034
EPA
9056A
10/20/2022 11:12
BGN9034
EPA
7470A
10/25/2022 11:45
JAA5429
Barium (Ba)
0.008
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 17:51
CELL106
Boron (B)
0.009 J
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 17:51
CELL106
Calcium (Ca)
21.4
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 17:51
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:51
CELL106
Iron (Fe)
0.044
mg/L
0.01
0.004
1
SW 601OD
10/24/2022 17:51
CELL106
Magnesium (Mg)
0.977
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 17:51
CELL106
Manganese (Mn)
0.020
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:51
CELL106
Potassium (K)
8.24
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 17:51
CELL106
Sodium (Na)
11.0
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 17:51
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 17:51
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/24/2022 13:36
MHALL3
Arsenic (As)
0.806 J
ug/L
1
0.111
1
SW 6020B
10/24/2022 13:36
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 13:36
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 13:36
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
10/24/2022 13:36
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
10/24/2022 13:36
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/24/2022 13:36
MHALL3
Nickel (Ni)
2.96
ug/L
1
0.256
1
SW 6020B
10/24/2022 13:36
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/24/2022 13:36
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 13:36
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 13:36
MHALL3
Vanadium (V) Low Level
0.116 J
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 13:36
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-5
Collection Date: 10/19/2022 04:35 PM Loc code: CLS CCPMW-5
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 81.7 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
4.5
mg/L
0.1
0.0154 1
Fluoride
0.12
mg/L
0.1
0.0479 1
Nitrate
4.5
mg/L
0.1
0.0209 1
Nitrate as N
1.0
mg-N/L
0.023
0.002 1
Sulfate
23
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Sample #: 2022023966
Matrix: GW RCRA
Page 10 of 91
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 13:33 CELL106
EPA
9056A
10/20/2022 11:31
BGN9034
EPA
9056A
10/20/2022 11:31
BGN9034
EPA
9056A
10/20/2022 11:31
BGN9034
EPA
9056A
10/20/2022 11:31
BGN9034
EPA
9056A
10/20/2022 11:31
BGN9034
EPA
7470A
10/25/2022 11:47
JAA5429
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 17:56
CELL106
Boron (B)
0.009 J
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 17:56
CELL106
Calcium (Ca)
27.3
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 17:56
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:56
CELL106
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 601OD
10/24/2022 17:56
CELL106
Magnesium (Mg)
0.203
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 17:56
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 17:56
CELL106
Potassium (K)
2.20
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 17:56
CELL106
Sodium (Na)
9.97
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 17:56
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 17:56
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.223 J
ug/L
1
0.104
1
SW 6020B
10/24/2022 13:44
MHALL3
Arsenic (As)
1.87
ug/L
1
0.111
1
SW 6020B
10/24/2022 13:44
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 13:44
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 13:44
MHALL3
Chromium (Cr)
5.85
ug/L
1
0.185
1
SW 6020B
10/24/2022 13:44
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
10/24/2022 13:44
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/24/2022 13:44
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/24/2022 13:44
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/24/2022 13:44
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 13:44
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 13:44
MHALL3
Vanadium (V) Low Level
17.1
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 13:44
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 11 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-6S Sample #: 2022023967
Collection Date: 10/19/2022 10:55 AM Loc code: CLS CCPMW-6S Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 2.82 J mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
5.0
mg/L
0.1
0.0154 1
Fluoride
0.06 J
mg/L
0.1
0.0479 1
Nitrate
2.9
mg/L
0.1
0.0209 1
Nitrate as N
0.66
mg-N/L
0.023
0.002 1
Sulfate
24
mg/L
0.5
0.0428 5
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 13:48 CELL106
EPA
9056A
10/20/2022 12:10
BGN9034
EPA
9056A
10/20/2022 12:10
BGN9034
EPA
9056A
10/20/2022 12:10
BGN9034
EPA
9056A
10/20/2022 12:10
BGN9034
EPA
9056A
10/20/2022 12:10
BGN9034
EPA
7470A
10/25/2022 11:49
JAA5429
Barium (Ba)
0.059
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 18:00
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 18:00
CELL106
Calcium (Ca)
3.05
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 18:00
CELL106
Copper (Cu)
0.002 J
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:00
CELL106
Iron (Fe)
0.244
mg/L
0.01
0.004
1
SW 601OD
10/24/2022 18:00
CELL106
Magnesium (Mg)
2.56
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 18:00
CELL106
Manganese (Mn)
0.288
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:00
CELL106
Potassium (K)
5.15
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 18:00
CELL106
Sodium (Na)
5.26
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 18:00
CELL106
Zinc (Zn)
0.006
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 18:00
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/24/2022 13:52
MHALL3
Arsenic (As)
0.173 J
ug/L
1
0.111
1
SW 6020B
10/24/2022 13:52
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 13:52
MHALL3
Cadmium (Cd)
0.168 J
ug/L
1
0.032
1
SW 6020B
10/24/2022 13:52
MHALL3
Chromium (Cr)
10.8
ug/L
1
0.185
1
SW 6020B
10/24/2022 13:52
MHALL3
Cobalt (Co)
5.23
ug/L
1
0.077
1
SW 6020B
10/24/2022 13:52
MHALL3
Lead (Pb)
0.246 J
ug/L
1
0.037
1
SW 6020B
10/24/2022 13:52
MHALL3
Nickel (Ni)
20.1
ug/L
1
0.256
1
SW 6020B
10/24/2022 13:52
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/24/2022 13:52
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 13:52
MHALL3
Thallium (TI) Low Level
0.330
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 13:52
MHALL3
Vanadium (V) Low Level
0.449
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 13:52
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 12 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-6D Sample #: 2022023968
Collection Date: 10/19/2022 10:20 AM Loc code: CLS CCPMW-6D Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 5.96 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100329
Chloride
5.4
mg/L
0.1
0.0154 1
Fluoride
0.0479 U
mg/L
0.1
0.0479 1
Nitrate
11
mg/L
0.5
0.0209 5
Nitrate as N
2.4
mg-N/L
0.115
0.002 5
Sulfate
0.37
mg/L
0.1
0.0428 1
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 13:54 CELL106
EPA
9056A
10/20/2022
09:33
BGN9034
EPA
9056A
10/20/2022
09:33
BGN9034
EPA
9056A
10/20/2022
09:33
BGN9034
EPA
9056A
10/20/2022
09:33
BGN9034
EPA
9056A
10/20/2022
09:33
BGN9034
EPA
7470A
10/25/2022
11:52
JAA5429
Barium (Ba)
0.030
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 18:05
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 18:05
CELL106
Calcium (Ca)
1.95
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 18:05
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:05
CELL106
Iron (Fe)
0.013
mg/L
0.01
0.004
1
SW 601OD
10/24/2022 18:05
CELL106
Magnesium (Mg)
1.57
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 18:05
CELL106
Manganese (Mn)
0.016
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:05
CELL106
Potassium (K)
1.64
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 18:05
CELL106
Sodium (Na)
3.09
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 18:05
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 18:05
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/24/2022 14:01
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/24/2022 14:01
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 14:01
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 14:01
MHALL3
Chromium (Cr)
1.14
ug/L
1
0.185
1
SW 6020B
10/24/2022 14:01
MHALL3
Cobalt (Co)
0.782 J
ug/L
1
0.077
1
SW 6020B
10/24/2022 14:01
MHALL3
Lead (Pb)
0.04 J
ug/L
1
0.037
1
SW 6020B
10/24/2022 14:01
MHALL3
Nickel (Ni)
0.551 J
ug/L
1
0.256
1
SW 6020B
10/24/2022 14:01
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/24/2022 14:01
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 14:01
MHALL3
Thallium (TI) Low Level
0.069 J
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 14:01
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 14:01
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-7
Collection Date: 10/19/2022 01:50 PM Loc code: CLS CCPMW-7
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 7.35 mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
10
mg/L
0.5
0.0154 5
Fluoride
0.0479 U
mg/L
0.1
0.0479 1
Nitrate
8.0
mg/L
0.1
0.0209 1
Nitrate as N
1.8
mg-N/L
0.023
0.002 1
Sulfate
0.43
mg/L
0.1
0.0428 1
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01 1
TOTAL RECOVERABLE METALS BY ICP - Q22100363
Sample #: 2022023969
Matrix: GW RCRA
Page 13 of 91
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 14:03 CELL106
EPA
9056A
10/20/2022 10:13
BGN9034
EPA
9056A
10/20/2022 10:13
BGN9034
EPA
9056A
10/20/2022 10:13
BGN9034
EPA
9056A
10/20/2022 10:13
BGN9034
EPA
9056A
10/20/2022 10:13
BGN9034
EPA
7470A
10/25/2022 11:54
JAA5429
Barium (Ba)
0.038
mg/L
0.005
0.002
1
SW 6010D
10/24/2022 18:09
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/24/2022 18:09
CELL106
Calcium (Ca)
4.40
mg/L
0.05
0.012
1
SW 6010D
10/24/2022 18:09
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:09
CELL106
Iron (Fe)
0.024
mg/L
0.01
0.004
1
SW 601OD
10/24/2022 18:09
CELL106
Magnesium (Mg)
1.75
mg/L
0.02
0.008
1
SW 6010D
10/24/2022 18:09
CELL106
Manganese (Mn)
0.046
mg/L
0.005
0.001
1
SW 6010D
10/24/2022 18:09
CELL106
Potassium (K)
2.45
mg/L
0.1
0.031
1
SW 6010D
10/24/2022 18:09
CELL106
Sodium (Na)
3.72
mg/L
0.05
0.017
1
SW 6010D
10/24/2022 18:09
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/24/2022 18:09
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100373
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/24/2022 14:09
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/24/2022 14:09
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/24/2022 14:09
MHALL3
Cadmium (Cd)
0.048 J
ug/L
1
0.032
1
SW 6020B
10/24/2022 14:09
MHALL3
Chromium (Cr)
0.508 J
ug/L
1
0.185
1
SW 6020B
10/24/2022 14:09
MHALL3
Cobalt (Co)
1.28
ug/L
1
0.077
1
SW 6020B
10/24/2022 14:09
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/24/2022 14:09
MHALL3
Nickel (Ni)
1.04
ug/L
1
0.256
1
SW 6020B
10/24/2022 14:09
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/24/2022 14:09
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 14:09
MHALL3
Thallium (TI) Low Level
0.063 J
ug/L
0.2
0.041
1
SW 6020B
10/24/2022 14:09
MHALL3
Vanadium (V) Low Level
0.17 J
ug/L
0.3
0.114
1
SW 6020B
10/24/2022 14:09
MHALL3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 14 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-10
Sample #: 2022023971
Collection Date: 10/19/2022 03:25 PM
Loc code: CLS CCPMW-10
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
3.5 J
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:09
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
5.2
mg/L
0.1
0.0154
1
EPA 9056A
10/20/2022 09:27
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/20/2022 09:27
BGN9034
Nitrate
7.4
mg/L
0.1
0.0209
1
EPA 9056A
10/20/2022 09:27
BGN9034
Nitrate as N
1.7
mg-N/L
0.023
0.002
1
EPA 9056A
10/20/2022 09:27
BGN9034
Sulfate
0.24
mg/L
0.1
0.0428
1
EPA 9056A
10/20/2022 09:27
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.02 J
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:01
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.051
mg/L
0.005
0.002
1
SW 6010D
10/27/2022 15:04
CELL106
Boron (B)
0.006 J
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 15:04
CELL106
Calcium (Ca)
1.65
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 15:04
CELL106
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:04
CELL106
Iron (Fe)
0.237
mg/L
0.01
0.004
1
SW 601OD
10/27/2022 15:04
CELL106
Magnesium (Mg)
1.71
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 15:04
CELL106
Manganese (Mn)
0.022
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:04
CELL106
Potassium (K)
1.62
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 15:04
CELL106
Sodium (Na)
2.17
mg/L
0.05
0.017
1
SW 6010D
10/27/2022 15:04
CELL106
Zinc (Zn)
0.005 J
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 15:04
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2022 12:19
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2022 12:19
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 12:19
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 12:19
MHALL3
Chromium (Cr)
2.26
ug/L
1
0.185
1
SW 6020B
10/25/2022 12:19
MHALL3
Cobalt (Co)
1.20
ug/L
1
0.077
1
SW 6020B
10/25/2022 12:19
MHALL3
Lead (Pb)
0.23 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 12:19
MHALL3
Nickel (Ni)
1.19
ug/L
1
0.256
1
SW 6020B
10/25/2022 12:19
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 12:19
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 12:19
MHALL3
Thallium (TI) Low Level
0.143 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 12:19
MHALL3
Vanadium (V) Low Level
0.475
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 12:19
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 15 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPMW-11
Sample #: 2022023972
Collection Date: 10/20/2022 04:40 PM
Loc code: CLS CCPMW-11
Matrix: GW
RCRA
Analyte
Result
Units Qualifiers
RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
13.8
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:16
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100360
Chloride
4.9
mg/L
0.1
0.0154
1
EPA 9056A
10/21/2022 08:37
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/21/2022 08:37
BGN9034
Nitrate
7.6
mg/L
0.1
0.0209
1
EPA 9056A
10/21/2022 08:37
BGN9034
Nitrate as N
1.7
mg-N/L
0.023
0.002
1
EPA 9056A
10/21/2022 08:37
BGN9034
Sulfate
1.8
mg/L
0.1
0.0428
1
EPA 9056A
10/21/2022 08:37
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:09
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.034
mg/L
0.005
0.002
1
SW 6010D
10/27/2022 14:50
CELL106
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 14:50
CELL106
Calcium (Ca)
2.27
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 14:50
CELL106
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 14:50
CELL106
Iron (Fe)
0.447
mg/L
0.01
0.004
1
SW 601OD
10/27/2022 14:50
CELL106
Magnesium (Mg)
1.50
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 14:50
CELL106
Manganese (Mn)
0.029
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 14:50
CELL106
Potassium (K)
4.28
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 14:50
CELL106
Sodium (Na)
6.07
mg/L
0.05
0.017
1
SW 6010D
10/27/2022 14:50
CELL106
Zinc (Zn)
0.006
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 14:50
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.115 J
ug/L
1
0.104
1
SW 6020B
10/25/2022 13:19
MHALL3
Arsenic (As)
0.13 J
ug/L
1
0.111
1
SW 6020B
10/25/2022 13:19
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 13:19
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 13:19
MHALL3
Chromium (Cr)
2.98
ug/L
1
0.185
1
SW 6020B
10/25/2022 13:19
MHALL3
Cobalt (Co)
0.362 J
ug/L
1
0.077
1
SW 6020B
10/25/2022 13:19
MHALL3
Lead (Pb)
0.436 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 13:19
MHALL3
Nickel (Ni)
2.23
ug/L
1
0.256
1
SW 6020B
10/25/2022 13:19
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 13:19
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 13:19
MHALL3
Thallium (TI) Low Level
0.154 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 13:19
MHALL3
Vanadium (V) Low Level
0.697
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 13:19
MHALL3
TOTAL DISSOLVED SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
Vendor Method
V_PACE

Certificate of Laboratory Analysis Page 16 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCP-Leachate Sample #: 2022023974
Collection Date: 10/19/2022 10:30 AM Loc code: CLS CCP-Leachate Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1 SM 232064d 10/25/2022 14:22 CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
15000
mg/L
200
0.0154
2000
Fluoride
1.2 J
mg/L
20
0.0479
200
Nitrate
23
mg/L
20
0.0209
200
Nitrate as N
5.1
mg-N/L
4.6
0.002
200
Sulfate
830
mg/L
20
0.0428
200
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.469
mg/L
0.005
0.002
1
Boron (B)
14.2
mg/L
0.05
0.005
1
Calcium (Ca)
9110
mg/L
5
0.012
100
Copper (Cu)
0.054
mg/L
0.005
0.001
1
Iron (Fe)
0.406
mg/L
0.01
0.004
1
Magnesium (Mg)
57.8
mg/L
0.02
0.008
1
Manganese (Mn)
15.9
mg/L
0.005
0.001
1
Potassium (K)
712
mg/L
1
0.031
10
Sodium (Na)
516
mg/L
0.5
0.017
10
Zinc (Zn)
0.178
mg/L
0.005
0.004
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.748 J
ug/L
1
0.104 1
Arsenic (As)
12.1
ug/L
1
0.111 1
Beryllium (Be)
1.21
ug/L
1
0.249 1
Cadmium (Cd)
2.62
ug/L
1
0.032 1
Chromium (Cr)
0.443 J
ug/L
1
0.185 1
Cobalt (Co)
742
ug/L
10
0.077 10
Lead (Pb)
135
ug/L
1
0.037 1
Nickel (Ni)
128
ug/L
1
0.256 1
Selenium (Se)
88.4
ug/L
1
0.193 1
Silver (Ag)
0.407 J
ug/L
1
0.035 1
Thallium (TI) Low Level
11.8
ug/L
0.2
0.041 1
Vanadium (V) Low Level
2.09
ug/L
0.3
0.114 1
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
EPA 9056A
10/20/2022 10:43
BGN9034
EPA 9056A
10/20/2022 10:43
BGN9034
EPA 9056A
10/20/2022 10:43
BGN9034
EPA 9056A
10/20/2022 10:43
BGN9034
EPA 9056A
10/20/2022 10:43
BGN9034
EPA 7470A
10/25/2022 12:11
JAA5429
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 601OD
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6010D
10/27/2022 15:08
CELL106
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
SW 6020B
10/25/2022 13:27
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCP-LEACHATE-34
Collection Date: 10/19/2022 02:10 PM Loc code: CLS CCP-LEACHATE-34
Analyte Result Units Qualifiers RDL MDL DF
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 1.7 U mg/L 5 1.7 1
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
600
mg/L
20
0.0154
200
Fluoride
0.91 J
mg/L
2
0.0479
20
Nitrate
17
mg/L
2
0.0209
20
Nitrate as N
3.8
mg-N/L
0.46
0.002
20
Sulfate
1700
mg/L
20
0.0428
200
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.050
mg/L
0.005
0.002
1
Boron (B)
6.94
mg/L
0.05
0.005
1
Calcium (Ca)
739
mg/L
0.5
0.012
10
Copper (Cu)
0.166
mg/L
0.005
0.001
1
Iron (Fe)
0.123
mg/L
0.01
0.004
1
Magnesium (Mg)
115
mg/L
0.2
0.008
10
Manganese (Mn)
17.3
mg/L
0.005
0.001
1
Potassium (K)
50.2
mg/L
1
0.031
10
Sodium (Na)
52.8
mg/L
0.05
0.017
1
Zinc (Zn)
0.484
mg/L
0.005
0.004
1
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.112 J
ug/L
1
0.104
1
Arsenic (As)
7.06
ug/L
1
0.111
1
Beryllium (Be)
10.8
ug/L
1
0.249
1
Cadmium (Cd)
3.51
ug/L
1
0.032
1
Chromium (Cr)
1.37
ug/L
1
0.185
1
Cobalt (Co)
472
ug/L
1
0.077
1
Lead (Pb)
26.0
ug/L
1
0.037
1
Nickel (Ni)
557
ug/L
10
0.256
10
Selenium (Se)
7.99
ug/L
1
0.193
1
Silver (Ag)
0.083 J
ug/L
1
0.035
1
Thallium (TI) Low Level
3.95
ug/L
0.2
0.041
1
Vanadium (V) Low Level
0.153 J
ug/L
0.3
0.114
1
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by Pace Laboratories)
Sample #: 2022023975
Matrix: GW RCRA
Page 17 of 91
Method Analysis Date/Time Analyst
SM 232064d 10/25/2022 14:29 CELL106
EPA 9056A
10/20/2022 10:28
BGN9034
EPA 9056A
10/20/2022 10:28
BGN9034
EPA 9056A
10/20/2022 10:28
BGN9034
EPA 9056A
10/20/2022 10:28
BGN9034
EPA 9056A
10/20/2022 10:28
BGN9034
EPA 7470A
10/25/2022 12:13
JAA5429
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 601OD
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6010D
10/27/2022 15:13
CELL106
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
SW 6020B
10/25/2022 13:02
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 18 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPSW-1
Sample #:
2022023976
Collection Date: 10/19/2022 09:30 AM
Loc code: CLS CCPSW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
14.6
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:37
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
4.1
mg/L
0.1
0.0154
1
EPA 9056A
10/20/2022 08:11
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/20/2022 08:11
BGN9034
Nitrate
0.56
mg/L
0.1
0.0209
1
EPA 9056A
10/20/2022 08:11
BGN9034
Nitrate as N
0.13
mg-N/L
0.023
0.002
1
EPA 9056A
10/20/2022 08:11
BGN9034
Sulfate
0.82
mg/L
0.1
0.0428
1
EPA 9056A
10/20/2022 08:11
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:16
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22100367
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 13:22
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.021
mg/L
0.005
0.002
1
SW 601OD
10/27/2022 15:17
CELL106
Boron (B)
0.011 J
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 15:17
CELL106
Calcium (Ca)
2.99
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 15:17
CELL106
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:17
CELL106
Iron (Fe)
1.26
mg/L
0.01
0.004
1
SW 6010D
10/27/2022 15:17
CELL106
Magnesium (Mg)
1.54
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 15:17
CELL106
Manganese (Mn)
0.027
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:17
CELL106
Potassium (K)
2.75
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 15:17
CELL106
Sodium (Na)
2.81
mg/L
0.05
0.017
1
SW 601OD
10/27/2022 15:17
CELL106
Total Hardness (Ca and Mg)
13.8
mg/L
0.19
1
SW 6010D
10/27/2022 15:17
CELL106
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 15:17
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22100368
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 18:15
MHALL3
Chromium (Cr)
0.404 J
ug/L
1
0.185
1
SW 6020B
10/24/2022 18:15
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/24/2022 18:15
MHALL3
Lead (Pb)
0.106 J
ug/L
1
0.037
1
SW 6020B
10/24/2022 18:15
MHALL3
Nickel (Ni)
0.45 J
ug/L
1
0.256
1
SW 6020B
10/24/2022 18:15
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 18:15
MHALL3

Certificate of Laboratory Analysis Page 19 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPSW-1
Sample #:
2022023976
Collection Date: 10/19/2022 09:30 AM
Loc code: CLS CCPSW-1
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2022 13:10
MHALL3
Arsenic (As)
0.245 J
ug/L
1
0.111
1
SW 6020B
10/25/2022 13:10
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 13:10
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 13:10
MHALL3
Chromium (Cr)
0.279 J
ug/L
1
0.185
1
SW 6020B
10/25/2022 13:10
MHALL3
Cobalt (Co)
0.487 J
ug/L
1
0.077
1
SW 6020B
10/25/2022 13:10
MHALL3
Lead (Pb)
0.188 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 13:10
MHALL3
Nickel (Ni)
0.63 J
ug/L
1
0.256
1
SW 6020B
10/25/2022 13:10
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 13:10
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 13:10
MHALL3
Thallium (TI) Low Level
0.114 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 13:10
MHALL3
Vanadium (V) Low Level
0.355
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 13:10
MHALL3
TOTAL DISSOLVED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 20 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPSW-2
Sample #:
2022023977
Collection Date: 10/19/2022 10:00 AM
Loc code: CLS CCPSW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
15.2
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:44
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
4.2
mg/L
0.1
0.0154
1
EPA 9056A
10/20/2022 09:42
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/20/2022 09:42
BGN9034
Nitrate
0.47
mg/L
0.1
0.0209
1
EPA 9056A
10/20/2022 09:42
BGN9034
Nitrate as N
0.11
mg-N/L
0.023
0.002
1
EPA 9056A
10/20/2022 09:42
BGN9034
Sulfate
1.6
mg/L
0.1
0.0428
1
EPA 9056A
10/20/2022 09:42
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:18
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22100367
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 13:36
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.023
mg/L
0.005
0.002
1
SW 601OD
10/27/2022 15:22
CELL106
Boron (B)
0.01 J
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 15:22
CELL106
Calcium (Ca)
3.32
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 15:22
CELL106
Copper (Cu)
0.001 J
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:22
CELL106
Iron (Fe)
1.27
mg/L
0.01
0.004
1
SW 6010D
10/27/2022 15:22
CELL106
Magnesium (Mg)
1.66
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 15:22
CELL106
Manganese (Mn)
0.036
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:22
CELL106
Potassium (K)
2.86
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 15:22
CELL106
Sodium (Na)
2.84
mg/L
0.05
0.017
1
SW 601OD
10/27/2022 15:22
CELL106
Total Hardness (Ca and Mg)
15.1
mg/L
0.19
1
SW 6010D
10/27/2022 15:22
CELL106
(CaCO3)
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 15:22
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22100368
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 17:49
MHALL3
Chromium (Cr)
0.44 J
ug/L
1
0.185
1
SW 6020B
10/24/2022 17:49
MHALL3
Copper (Cu)
0.787 J
ug/L
1
0.787
1
SW 6020B
10/24/2022 17:49
MHALL3
Lead (Pb)
0.092 J
ug/L
1
0.037
1
SW 6020B
10/24/2022 17:49
MHALL3
Nickel (Ni)
0.414 J
ug/L
1
0.256
1
SW 6020B
10/24/2022 17:49
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 17:49
MHALL3

Certificate of Laboratory Analysis Page 21 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCPSW-2
Sample #:
2022023977
Collection Date: 10/19/2022 10:00 AM
Loc code: CLS CCPSW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2022 13:35
MHALL3
Arsenic (As)
0.283 J
ug/L
1
0.111
1
SW 6020B
10/25/2022 13:35
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 13:35
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 13:35
MHALL3
Chromium (Cr)
0.336 J
ug/L
1
0.185
1
SW 6020B
10/25/2022 13:35
MHALL3
Cobalt (Co)
0.756 J
ug/L
1
0.077
1
SW 6020B
10/25/2022 13:35
MHALL3
Lead (Pb)
0.226 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 13:35
MHALL3
Nickel (Ni)
0.812 J
ug/L
1
0.256
1
SW 6020B
10/25/2022 13:35
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 13:35
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 13:35
MHALL3
Thallium (TI) Low Level
0.054 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 13:35
MHALL3
Vanadium (V) Low Level
0.489
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 13:35
MHALL3
TOTAL DISSOLVED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 22 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS_FD-20221019-1 Duplicate
Sample #:
2022023979
Collection Date: 10/19/2022
Loc code: CLS
FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
14.6
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:51
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
4.1
mg/L
0.1
0.0154
1
EPA 9056A
10/20/2022 08:57
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/20/2022 08:57
BGN9034
Nitrate
0.57
mg/L
0.1
0.0209
1
EPA 9056A
10/20/2022 08:57
BGN9034
Nitrate as N
0.13
mg-N/L
0.023
0.002
1
EPA 9056A
10/20/2022 08:57
BGN9034
Sulfate
0.83
mg/L
0.1
0.0428
1
EPA 9056A
10/20/2022 08:57
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:20
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22100367
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 13:41
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.021
mg/L
0.005
0.002
1
SW 601OD
10/27/2022 15:26
CELL106
Boron (B)
0.008 J
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 15:26
CELL106
Calcium (Ca)
2.99
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 15:26
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:26
CELL106
Iron (Fe)
1.29
mg/L
0.01
0.004
1
SW 6010D
10/27/2022 15:26
CELL106
Magnesium (Mg)
1.54
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 15:26
CELL106
Manganese (Mn)
0.028
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:26
CELL106
Potassium (K)
2.73
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 15:26
CELL106
Sodium (Na)
2.81
mg/L
0.05
0.017
1
SW 601OD
10/27/2022 15:26
CELL106
Zinc (Zn)
0.005
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 15:26
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22100368
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 18:24
MHALL3
Chromium (Cr)
0.395 J
ug/L
1
0.185
1
SW 6020B
10/24/2022 18:24
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/24/2022 18:24
MHALL3
Lead (Pb)
0.103 J
ug/L
1
0.037
1
SW 6020B
10/24/2022 18:24
MHALL3
Nickel (Ni)
0.331 J
ug/L
1
0.256
1
SW 6020B
10/24/2022 18:24
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 18:24
MHALL3

Certificate of Laboratory Analysis Page 23 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS_FD-20221019-1 Duplicate
Sample #:
2022023979
Collection Date: 10/19/2022
Loc code: CLS
FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2022 13:44
MHALL3
Arsenic (As)
0.246 J
ug/L
1
0.111
1
SW 6020B
10/25/2022 13:44
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 13:44
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 13:44
MHALL3
Chromium (Cr)
0.299 J
ug/L
1
0.185
1
SW 6020B
10/25/2022 13:44
MHALL3
Cobalt (Co)
0.878 J
ug/L
1
0.077
1
SW 6020B
10/25/2022 13:44
MHALL3
Lead (Pb)
0.224 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 13:44
MHALL3
Nickel (Ni)
1.12
ug/L
1
0.256
1
SW 6020B
10/25/2022 13:44
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 13:44
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 13:44
MHALL3
Thallium (TI) Low Level
0.045 J
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 13:44
MHALL3
Vanadium (V) Low Level
0.347
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 13:44
MHALL3
TOTAL DISSOLVED SOLIDS - (Analvsis Performed by
Pace Laboratories)
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 24 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS FB-20221019-1010 Field Blank
Sample #:
2022023981
Collection Date: 10/19/2022 10:10 AM
Loc code: CLS QA
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
LOW LEVEL ALKALINITY (FIXED END POINT)
- Q22100422
Total Alkalinity as CaCO3
1.7 U
mg/L
5
1.7
1
SM 2320B4d
10/25/2022 14:57
CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
0.0154 U
mg/L
0.1
0.0154
1
EPA 9056A
10/20/2022 07:54
BGN9034
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
10/20/2022 07:54
BGN9034
Nitrate
0.0209 U
mg/L
0.1
0.0209
1
EPA 9056A
10/20/2022 07:54
BGN9034
Nitrate as N
0.002 U
mg-N/L
0.023
0.002
1
EPA 9056A
10/20/2022 07:54
BGN9034
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
10/20/2022 07:54
BGN9034
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg)
0.01 U
ug/L
0.05
0.01
1
EPA 7470A
10/25/2022 12:23
JAA5429
TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
- Q22100367
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 13:46
CELL106
TOTAL RECOVERABLE METALS BY ICP - Q22100394
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 601OD
10/27/2022 15:31
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
10/27/2022 15:31
CELL106
Calcium (Ca)
0.012 U
mg/L
0.05
0.012
1
SW 6010D
10/27/2022 15:31
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:31
CELL106
Iron (Fe)
0.004 U
mg/L
0.01
0.004
1
SW 6010D
10/27/2022 15:31
CELL106
Magnesium (Mg)
0.008 U
mg/L
0.02
0.008
1
SW 6010D
10/27/2022 15:31
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
10/27/2022 15:31
CELL106
Potassium (K)
0.031 U
mg/L
0.1
0.031
1
SW 6010D
10/27/2022 15:31
CELL106
Sodium (Na)
0.017 U
mg/L
0.05
0.017
1
SW 601OD
10/27/2022 15:31
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 6010D
10/27/2022 15:31
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED) - Q22100368
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/24/2022 18:32
MHALL3
Chromium (Cr)
0.257 J
ug/L
1
0.185
1
SW 6020B
10/24/2022 18:32
MHALL3
Copper (Cu)
0.787 U
ug/L
1
0.787
1
SW 6020B
10/24/2022 18:32
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/24/2022 18:32
MHALL3
Nickel (Ni)
0.256 U
ug/L
1
0.256
1
SW 6020B
10/24/2022 18:32
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/24/2022 18:32
MHALL3

Certificate of Laboratory Analysis Page 25 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS FB-20221019-1010
Field Blank
Sample #:
2022023981
Collection Date: 10/19/2022 10:10 AM
Loc code: CLS QA
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/25/2022 13:52
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/25/2022 13:52
MHALL3
Beryllium (Be)
0.249 U
ug/L
1
0.249
1
SW 6020B
10/25/2022 13:52
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/25/2022 13:52
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
10/25/2022 13:52
MHALL3
Cobalt (Co)
0.81 J
ug/L
1
0.077
1
SW 6020B
10/25/2022 13:52
MHALL3
Lead (Pb)
0.086 J
ug/L
1
0.037
1
SW 6020B
10/25/2022 13:52
MHALL3
Nickel (Ni)
0.669 J
ug/L
1
0.256
1
SW 6020B
10/25/2022 13:52
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/25/2022 13:52
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/25/2022 13:52
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/25/2022 13:52
MHALL3
Vanadium (V) Low Level
0.114 U
ug/L
0.3
0.114
1
SW 6020B
10/25/2022 13:52
MHALL3

Certificate of Laboratory Analysis Page 26 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Site: CLS CCR-CCPBG-1 BR Sample #: 2022023983
Collection Date: 10/19/2022 03:25 PM Loc code: CLS CCR-CCPBG-1 BR Matrix: GW RCRA
Analyte Result Units Qualifiers RDL MDL DF Method Analysis Date/Time Analyst
LOW LEVEL ALKALINITY (FIXED END POINT) - Q22100422
Total Alkalinity as CaCO3 84.6 mg/L 5 1.7 1 SM 232064d 10/25/2022 15:02 CELL106
(CaCO3)
INORGANIC IONS BY IC - Q22100331
Chloride
160
mg/L
2.5
0.0154 25
Fluoride
0.14 J
mg/L
0.5
0.0479 5
Nitrate
1.0
mg/L
0.5
0.0209 5
Nitrate as N
0.23
mg-N/L
0.115
0.002 5
Sulfate
230
mg/L
2.5
0.0428 25
MERCURY (COLD VAPOR) IN WATER - Q22100425
Mercury (Hg) 0.01 U ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22100394
0.01 1
Barium (Ba)
0.009
mg/L
0.005
0.002
Boron (B)
0.015 J
mg/L
0.05
0.005
Calcium (Ca)
52.6
mg/L
0.05
0.012
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.006 J
mg/L
0.01
0.004
Magnesium (Mg)
4.47
mg/L
0.02
0.008
Manganese (Mn)
0.062
mg/L
0.005
0.001
Potassium (K)
69.5
mg/L
1
0.031
Sodium (Na)
4.83
mg/L
0.5
0.017
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22100393
Antimony (Sb)
0.216 J
ug/L
1
Arsenic (As)
0.841 J
ug/L
1
Beryllium (Be)
0.249 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
1.20
ug/L
1
Cobalt (Co)
0.368 J
ug/L
1
Lead (Pb)
0.041 J
ug/L
1
Nickel (Ni)
2.97
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.842
ug/L
0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
EPA
9056A
10/20/2022
09:58
BGN9034
EPA
9056A
10/20/2022
09:58
BGN9034
EPA
9056A
10/20/2022
09:58
BGN9034
EPA
9056A
10/20/2022
09:58
BGN9034
EPA
9056A
10/20/2022
09:58
BGN9034
EPA
7470A
10/25/2022
12:25
JAA5429
1 SW 6010D
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
1 SW 601OD
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
10 SW 6010D
10/27/2022 15:35
CELL106
10 SW 6010D
10/27/2022 15:35
CELL106
1 SW 6010D
10/27/2022 15:35
CELL106
0.104
1
SW 6020B
10/25/2022 14:01
MHALL3
0.111
1
SW 6020B
10/25/2022 14:01
MHALL3
0.249
1
SW 6020B
10/25/2022 14:01
MHALL3
0.032
1
SW 6020B
10/25/2022 14:01
MHALL3
0.185
1
SW 6020B
10/25/2022 14:01
MHALL3
0.077
1
SW 6020B
10/25/2022 14:01
MHALL3
0.037
1
SW 6020B
10/25/2022 14:01
MHALL3
0.256
1
SW 6020B
10/25/2022 14:01
MHALL3
0.193
1
SW 6020B
10/25/2022 14:01
MHALL3
0.035
1
SW 6020B
10/25/2022 14:01
MHALL3
0.041
1
SW 6020B
10/25/2022 14:01
MHALL3
0.114
1
SW 6020B
10/25/2022 14:01
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 27 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Qualifiers:
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 28 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100422 ALK_LL_Fix LOW LEVEL ALKALINITY (FIXED END POINT)
Duplicate # 1
Parameter
Measured
Final
Total Alkalinity as CaCO3
5.23
Duplicate # 2
Parameter
Measured
Final
Total Alkalinity as CaCO3
4.59
Duplicate # 3
Parameter
Measured
Final
Total Alkalinity as CaCO3
45.2
LCS # 1
Parameter
Measured
Final
Total Alkalinity as CaCO3
40.3
LCS # 2
Parameter Measured Final
Total Alkalinity as CaCO3 38.3
LCS # 3
Parameter Measured Final
Total Alkalinity as CaCO3 38
Parent Sample:
J22090222 -- 2022023960
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
1.15
Parent Sample:
J22090222 -- 2022023961
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
1.1
Parent Sample:
J22090222 -- 2022023962
Units
Dil
MDL
RPD
Qualifier
mg/L
1
1.7
0.397
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
41.4
97.2
85 115
(CaCO3)
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
41.4
92.5
85 115
(CaCO3)
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
mg/L
1
1.7
41.4
91.9
85 115
(CaCO3)

Certificate of Laboratory Analysis Page 29 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100329 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
2
2
mg/L
1
0.0154
2
99.8
80
120
Fluoride
2.03
2.03
mg/L
1
0.0479
2
102
80
120
Nitrate
2.02
2.02
mg/L
1
0.0209
2
101
80
120
Sulfate
2.12
2.12
mg/L
1
0.0428
2
106
80
120
MS # 1
Parent Sample:
J22090222 -- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Qualifier
Chloride
6.72
6.72
mg/L
1
0.0154
2
100
80
120
Fluoride
2.06
2.06
mg/L
1
0.0479
2
103
80
120
Nitrate
2.96
2.96
mg/L
1
0.0209
2
106
80
120
Sulfate
2.42
2.42
mg/L
1
0.0428
2
109
80
120
MSD # 1
Parent Sample:
J22090222 -- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
6.71
6.71
mg/L
1
0.0154
2
100
80
120
0.449
Fluoride
2.06
2.06
mg/L
1
0.0479
2
102
80
120
0.341
Nitrate
2.96
2.96
mg/L
1
0.0209
2
105
80
120
0.237
Sulfate
2.42
2.42
mg/L
1
0.0428
2
109
80
120
0.183

Certificate of Laboratory Analysis Page 30 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100331 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
2.05
2.05
mg/L
1
0.0154
2
102
80
120
Fluoride
2.1
2.1
mg/L
1
0.0479
2
105
80
120
Nitrate
2.07
2.07
mg/L
1
0.0209
2
103
80
120
Sulfate
2.07
2.07
mg/L
1
0.0428
2
104
80
120
MS # 1
Parent Sample:
J22090222 -- 2022023976
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Qualifier
Chloride
5.96
5.96
mg/L
1
0.0154
2
95
80
120
Fluoride
2.02
2.02
mg/L
1
0.0479
2
99
80
120
Nitrate
2.56
2.56
mg/L
1
0.0209
2
99.7
80
120
Sulfate
2.73
2.73
mg/L
1
0.0428
2
95.5
80
120
MSD # 1
Parent Sample:
J22090222 -- 2022023976
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
5.96
5.96
mg/L
1
0.0154
2
95.3
80
120
0.315
Fluoride
2.03
2.03
mg/L
1
0.0479
2
99.7
80
120
0.705
Nitrate
2.56
2.56
mg/L
1
0.0209
2
99.7
80
120
0
Sulfate
2.74
2.74
mg/L
1
0.0428
2
95.9
80
120
0.418

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100360 Dionex INORGANIC IONS BY IC
Blank # 1
LCS # 1
MS # 1
MSD # 1
MS # 2
MSD # 2
Page 31 of 91
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
2.1
2.1
mg/L
1
0.0154
2
105
90
110
Fluoride
2.15
2.15
mg/L
1
0.0479
2
107
90
110
Nitrate
2.12
2.12
mg/L
1
0.0209
2
106
90
110
Sulfate
2.13
2.13
mg/L
1
0.0428
2
106
90
110
Parent Sample:
J22090222 -- 2022023972
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Chloride
6.81
6.81
mg/L
1
0.0154
2
95.2
80
120
Fluoride
2.04
2.04
mg/L
1
0.0479
2
100
80
120
Nitrate
9.46
9.46
mg/L
1
0.0209
2
92
80
120
Sulfate
3.71
3.71
mg/L
1
0.0428
2
96.3
80
120
Parent Sample:
J22090222 -- 2022023972
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Chloride
6.8
6.8
mg/L
1
0.0154
2
94.8
80
120
0.316
Fluoride
2.03
2.03
mg/L
1
0.0479
2
99.8
80
120
0.45
Nitrate
9.46
9.46
mg/L
1
0.0209
2
91.8
80
120
0.272
Sulfate
3.71
3.71
mg/L
1
0.0428
2
96.2
80
120
0.156
Parent Sample:
J22100407 -- 2022027594
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Chloride
2.99
29.9
mg/L
10
0.0154
20
99
80
120
Fluoride
2.51
2.51
mg/L
1
0.0479
2
105
80
120
Nitrate
Not Tested
mg/L
1
0.0209
2
80
120
Sulfate
6.3
63
mg/L
10
0.0428
20
94.3
80
120
Parent Sample:
J22100407 -- 2022027594
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Chloride
2.98
29.8
mg/L
10
0.0154
20
98.4
80
120
0.608
Fluoride
2.52
2.52
mg/L
1
0.0479
2
105
80
120
0.238
Nitrate
Not Tested
mg/L
1
0.0209
2
80
120
Sulfate
6.3
63
mg/L
10
0.0428
20
94.3
80
120
0.037'
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 32 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100425 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.007
-0.007
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.004
-0.004
ug/L
1
0.01
0.05
< MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.003
-0.003
ug/L
1
0.01
0.05
< MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.007
-0.007
ug/L
1
0.01
0.05
< MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.012
-0.012
ug/L
1
0.01
0.05
< MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
-0.01
-0.01
ug/L
1
0.01
0.05
< MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0
0
ug/L
1
0.01
0.05
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
2.02
2.02
ug/L
1
0.01
2
101 85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
2.02
2.02
ug/L
1
0.01
2
101 85
115
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
2.04
2.04
ug/L
1
0.01
2
102 85
115
MS # 1
Parent Sample: J22090222 -- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery LCL
UCL
Qualifier
Mercury (Hg)
1.05
1.05
ug/L
1
0.01
1
105 75
125

Certificate of Laboratory Analysis Page 33 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
022100425 HG 7470 MERCURY (COLD VAPOR) IN WATER
MSD # 1
Parent Sample:
J22090222 -- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.04
1.04
ug/L
1
0.01
1
104
75 125 0.573
MS # 2
Parent Sample:
J22090222 -- 2022023971
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.1
1.1
ug/L
1
0.01
1
108
75 125
MSD # 2
Parent Sample:
J22090222 -- 2022023971
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.08
1.08
ug/L
1
0.01
1
106
75 125 1.22
MS # 3
Parent Sample:
J22100329 -- 2022027207
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
100
75 125
MSD # 3
Parent Sample:
J22100329 -- 2022027207
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
101
75 125 1.09
MS # 4
Parent Sample:
J22100329 -- 2022027217
Parameter
Measured
Final
Units
Di
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
102
75 125
MSD # 4
Parent Sample:
J22100329 -- 2022027217
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.773
0.773
ug/L
1
0.01
1
77.3
75 125 27.1
MS # 5
Parent Sample:
J22100406 -- 2022027584
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.994
0.994
ug/L
1
0.01
1
99.4
75 125
MSD # 5
Parent Sample:
J22100406 -- 2022027584
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.811
0.811
ug/L
1
0.01
1
81.1
75 125 20.3
MS # 6
Parent Sample:
J22100439 -- 2022027726
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.787
0.787
ug/L
1
0.01
1
78.7
75 125
MSD # 6
Parent Sample:
J22100439 -- 2022027726
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
Not Tested
ug/L
1
0.01
1
75 125

Certificate of Laboratory Analysis Page 34 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100367 ICP_DIS_TRM TOTAL RECOVERABLE METALS BY ICP (DISSOLVED)
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Zinc (Zn)
-0.000269
-0.000269
mg/L
1
0.004
0.005
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.12
5.12
mg/L
1
0.004
5
102
80
120
MS # 1
Parent Sample:
J22090222 -- 2022023976
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Zinc (Zn)
5.12
5.12
mg/L
1
0.004
5
102
70
130
MSD # 1
Parent Sample:
J22090222 -- 2022023976
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Zinc (Zn)
5.11
5.11
mg/L
1
0.004
5
102
70
130 0.117
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100363 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.00104
-0.00104
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000216
0.000216
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00145
0.00145
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
-0.000116
-0.000116
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.000915
0.000915
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.0022
0.0022
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000301
0.000301
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.000203
-0.000203
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.00183
0.00183
mg/L
1
0.017
0.05
< MDL
Zinc (Zn)
-0.00114
-0.00114
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 35 of 91
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.15
5.15
mg/L
1
0.002
5
103
80
120
Boron (B)
4.83
4.83
mg/L
1
0.005
5
96.6
80
120
Calcium (Ca)
5.19
5.19
mg/L
1
0.012
5
104
80
120
Copper (Cu)
5.18
5.18
mg/L
1
0.001
5
104
80
120
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
101
80
120
Magnesium (Mg)
4.87
4.87
mg/L
1
0.008
5
97.4
80
120
Manganese (Mn)
5.1
5.1
mg/L
1
0.001
5
102
80
120
Potassium (K)
5.14
5.14
mg/L
1
0.031
5
103
80
120
Sodium (Na)
5.05
5.05
mg/L
1
0.017
5
101
80
120
Zinc (Zn)
4.88
4.88
mg/L
1
0.004
5
97.5
80
120
MS # 1
Parent Sample:
J22090222
-- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.18
5.18
mg/L
1
0.002
5
103
75
125
Boron (B)
4.76
4.76
mg/L
1
0.005
5
95
75
125
Calcium (Ca)
5.46
5.46
mg/L
1
0.012
5
103
75
125
Copper (Cu)
5.13
5.13
mg/L
1
0.001
5
103
75
125
Iron (Fe)
5.06
5.06
mg/L
1
0.004
5
99.6
75
125
Magnesium (Mg)
5.62
5.62
mg/L
1
0.008
5
95.3
75
125
Manganese (Mn)
5.07
5.07
mg/L
1
0.001
5
101
75
125
Potassium (K)
6.14
6.14
mg/L
1
0.031
5
103
75
125
Sodium (Na)
6.78
6.78
mg/L
1
0.017
5
102
75
125
Zinc (Zn)
4.79
4.79
mg/L
1
0.004
5
95.8
75
125
MSD # 1
Parent Sample:
J22090222
-- 2022023959
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.1
5.1
mg/L
1
0.002
5
101
75
125 1.6
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 36 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100363 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Boron (B)
4.87
4.87
mg/L
1
0.005
Calcium (Ca)
5.47
5.47
mg/L
1
0.012
Copper (Cu)
5.14
5.14
mg/L
1
0.001
Iron (Fe)
5.14
5.14
mg/L
1
0.004
Magnesium (Mg)
5.73
5.73
mg/L
1
0.008
Manganese (Mn)
5.09
5.09
mg/L
1
0.001
Potassium (K)
6.08
6.08
mg/L
1
0.031
Sodium (Na)
6.67
6.67
mg/L
1
0.017
Zinc (Zn)
4.87
4.87
mg/L
1
0.004
Parent Sample:
J22090222 -- 2022023959
Spike
% Recovery
LCL
UCL
RPD
5
97.2
75
125
2.31
5
103
75
125
0.165
5
103
75
125
0.0779
5
101
75
125
1.45
5
97.3
75
125
1.82
5
101
75
125
0.433
5
101
75
125
1.13
5
99.6
75
125
1.58
5
97.3
75
125
1.57
Qualifier

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100394 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000527
-0.000527
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.000808
0.000808
mg/L
1
0.005
0.05
< MDL
Calcium (Ca)
0.00517
0.00517
mg/L
1
0.012
0.05
< MDL
Copper (Cu)
0.000362
0.000362
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00197
0.00197
mg/L
1
0.004
0.01
< MDL
Magnesium (Mg)
0.00265
0.00265
mg/L
1
0.008
0.02
< MDL
Manganese (Mn)
0.000184
0.000184
mg/L
1
0.001
0.005
< MDL
Potassium (K)
-0.0111
-0.0111
mg/L
1
0.031
0.1
< MDL
Sodium (Na)
0.00508
0.00508
mg/L
1
0.017
0.05
< MDL
Zinc (Zn)
0.000819
0.000819
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 37 of 91
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.16
5.16
mg/L
1
0.002
5
103
80
120
Boron (B)
5.05
5.05
mg/L
1
0.005
5
101
80
120
Calcium (Ca)
5.06
5.06
mg/L
1
0.012
5
101
80
120
Copper (Cu)
5.06
5.06
mg/L
1
0.001
5
101
80
120
Iron (Fe)
5.05
5.05
mg/L
1
0.004
5
101
80
120
Magnesium (Mg)
4.95
4.95
mg/L
1
0.008
5
99
80
120
Manganese (Mn)
5.05
5.05
mg/L
1
0.001
5
101
80
120
Potassium (K)
5.02
5.02
mg/L
1
0.031
5
100
80
120
Sodium (Na)
4.97
4.97
mg/L
1
0.017
5
99.4
80
120
Zinc (Zn)
5.07
5.07
mg/L
1
0.004
5
101
80
120
MS # 1
Parent Sample:
J22090222
-- 2022023972
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Barium (Ba)
5.17
5.17
mg/L
1
0.002
5
103
75
125
Boron (B)
4.97
4.97
mg/L
1
0.005
5
99.3
75
125
Calcium (Ca)
7.25
7.25
mg/L
1
0.012
5
99.5
75
125
Copper (Cu)
5
5
mg/L
1
0.001
5
99.9
75
125
Iron (Fe)
5.42
5.42
mg/L
1
0.004
5
99.4
75
125
Magnesium (Mg)
6.36
6.36
mg/L
1
0.008
5
97.4
75
125
Manganese (Mn)
5.02
5.02
mg/L
1
0.001
5
99.9
75
125
Potassium (K)
9.23
9.23
mg/L
1
0.031
5
98.9
75
125
Sodium (Na)
10.9
10.9
mg/L
1
0.017
5
97
75
125
Zinc (Zn)
5.02
5.02
mg/L
1
0.004
5
100
75
125
MSD # 1
Parent Sample:
J22090222
-- 2022023972
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Barium (Ba)
5.22
5.22
mg/L
1
0.002
5
104
75
125 0.963
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 38 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100394 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
Boron (B)
5.03
5.03
mg/L
1
0.005
Calcium (Ca)
7.29
7.29
mg/L
1
0.012
Copper (Cu)
5.04
5.04
mg/L
1
0.001
Iron (Fe)
5.46
5.46
mg/L
1
0.004
Magnesium (Mg)
6.4
6.4
mg/L
1
0.008
Manganese (Mn)
5.07
5.07
mg/L
1
0.001
Potassium (K)
9.27
9.27
mg/L
1
0.031
Sodium (Na)
11
11
mg/L
1
0.017
Zinc (Zn)
5.06
5.06
mg/L
1
0.004
Parent Sample:
J22090222 -- 2022023972
Spike
% Recovery
LCL
UCL
RPD
5
101
75
125
1.24
5
100
75
125
0.619
5
101
75
125
0.956
5
100
75
125
0.699
5
98.1
75
125
0.611
5
101
75
125
0.852
5
99.8
75
125
0.476
5
97.9
75
125
0.429
5
101
75
125
0.913
Qualifier

Certificate of Laboratory Analysis Page 39 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100368 IMS_DIS_TRM TOTAL RECOVERABLE METALS BY ICP-MS (DISSOLVED)
Blank # 1
LCS # 1
MS # 1
MSD # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Cadmium (Cd)
0.002
0.002
ug/L
1
0.032
1
< MDL
Chromium (Cr)
-0.025
-0.025
ug/L
1
0.185
1
< MDL
Copper (Cu)
-0.03
-0.03
ug/L
1
0.787
1
< MDL
Lead (Pb)
0.001
0.001
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.003
-0.003
ug/L
1
0.256
1
< MDL
Silver (Ag)
-0.001
-0.001
ug/L
1
0.035
1
< MDL
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Cadmium (Cd)
50.6
50.6
ug/L
1
0.032
50
101
80
120
Chromium (Cr)
51
51
ug/L
1
0.185
50
102
80
120
Copper (Cu)
51.6
51.6
ug/L
1
0.787
50
103
80
120
Lead (Pb)
51.7
51.7
ug/L
1
0.037
50
103
80
120
Nickel (Ni)
51.2
51.2
ug/L
1
0.256
50
102
80
120
Silver (Ag)
51
51
ug/L
1
0.035
50
102
80
120
Parent Sample:
J22090222 -- 2022023977
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
102
75
125
Chromium (Cr)
52
52
ug/L
1
0.185
50
103
75
125
Copper (Cu)
51.4
51.4
ug/L
1
0.787
50
101
75
125
Lead (Pb)
52.1
52.1
ug/L
1
0.037
50
104
75
125
Nickel (Ni)
50.8
50.8
ug/L
1
0.256
50
101
75
125
Silver (Ag)
51
51
ug/L
1
0.035
50
102
75
125
Parent Sample:
J22090222 -- 2022023977
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
RPD
Cadmium (Cd)
51.2
51.2
ug/L
1
0.032
50
102
75
125
0.888
Chromium (Cr)
51.9
51.9
ug/L
1
0.185
50
103
75
125
0.13
Copper (Cu)
52.1
52.1
ug/L
1
0.787
50
103
75
125
1.39
Lead (Pb)
51.9
51.9
ug/L
1
0.037
50
104
75
125
0.549
Nickel (Ni)
51.1
51.1
ug/L
1
0.256
50
101
75
125
0.704
Silver (Ag)
51.4
51.4
ug/L
1
0.035
50
103
75
125
0.613
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 40 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100373 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.006
0.006
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.007
0.007
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0
0
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
0.003
0.003
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.04
0.04
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.004
0.004
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.005
0.005
ug/L
1
0.037
1
< MDL
Nickel (Ni)
-0.002
-0.002
ug/L
1
0.256
1
< MDL
Selenium (Se)
0.094
0.094
ug/L
1
0.193
1
< MDL
Silver (Ag)
-0.003
-0.003
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.006
-0.006
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.024
0.024
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
50.7
50.7
ug/L
1
0.104
50
101
80
120
Arsenic (As)
51
51
ug/L
1
0.111
50
102
80
120
Beryllium (Be)
50
50
ug/L
1
0.249
50
100
80
120
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
51
51
ug/L
1
0.185
50
102
80
120
Cobalt (Co)
51.7
51.7
ug/L
1
0.077
50
103
80
120
Lead (Pb)
52
52
ug/L
1
0.037
50
104
80
120
Nickel (Ni)
52.1
52.1
ug/L
1
0.256
50
104
80
120
Selenium (Se)
50.7
50.7
ug/L
1
0.193
50
101
80
120
Silver (Ag)
50.8
50.8
ug/L
1
0.035
50
102
80
120
Thallium (TI) Low Level
49.2
49.2
ug/L
1
0.041
50
98.4
80
120
Vanadium (V) Low Level
51.2
51.2
ug/L
1
0.114
50
102
80
120
MS # 1
Parent Sample:
J22090222 -- 2022023961
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
48.6
48.6
ug/L
1
0.104
50
97.1
75
125
Arsenic (As)
50.2
50.2
ug/L
1
0.111
50
99.5
75
125
Beryllium (Be)
51.1
51.1
ug/L
1
0.249
50
102
75
125
Cadmium (Cd)
50.5
50.5
ug/L
1
0.032
50
101
75
125
Chromium (Cr)
53.9
53.9
ug/L
1
0.185
50
101
75
125
Cobalt (Co)
52.6
52.6
ug/L
1
0.077
50
100
75
125
Lead (Pb)
52.4
52.4
ug/L
1
0.037
50
102
75
125
Nickel (Ni)
57.6
57.6
ug/L
1
0.256
50
105
75
125
Selenium (Se)
49.5
49.5
ug/L
1
0.193
50
98
75
125
Silver (Ag)
50.6
50.6
ug/L
1
0.035
50
101
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 41 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100373 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
48.6
48.6
ug/L
Vanadium (V) Low Level
53.5
53.5
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
48.3
48.3
ug/L
Arsenic (As)
50.9
50.9
ug/L
Beryllium (Be)
49.6
49.6
ug/L
Cadmium (Cd)
50.5
50.5
ug/L
Chromium (Cr)
54.9
54.9
ug/L
Cobalt (Co)
53.3
53.3
ug/L
Lead (Pb)
53.3
53.3
ug/L
Nickel (Ni)
56.4
56.4
ug/L
Selenium (Se)
50.6
50.6
ug/L
Silver (Ag)
50.4
50.4
ug/L
Thallium (TI) Low Level
49.2
49.2
ug/L
Vanadium (V) Low Level
54.5
54.5
ug/L
Parent Sample:
J22090222 -- 2022023961
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
97.1
75
125
1
0.114
50
101
75
125
Parent Sample:
J22090222
-- 2022023961
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
96.6
75
125
0.465
1
0.111
50
101
75
125
1.23
1
0.249
50
98.7
75
125
2.93
1
0.032
50
101
75
125
0.17
1
0.185
50
103
75
125
2.03
1
0.077
50
102
75
125
1.52
1
0.037
50
104
75
125
1.67
1
0.256
50
103
75
125
2.21
1
0.193
50
100
75
125
2.23
1
0.035
50
101
75
125
0.337
1
0.041
50
98.2
75
125
1.16
1
0.114
50
103
75
125
2
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 42 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100393 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.004
0.004
ug/L
1
0.104
1
< MDL
Arsenic (As)
0.023
0.023
ug/L
1
0.111
1
< MDL
Beryllium (Be)
0.009
0.009
ug/L
1
0.249
1
< MDL
Cadmium (Cd)
-0.001
-0.001
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.031
0.031
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0
0
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.002
0.002
ug/L
1
0.037
1
< MDL
Nickel (Ni)
0.018
0.018
ug/L
1
0.256
1
< MDL
Selenium (Se)
-0.062
-0.062
ug/L
1
0.193
1
< MDL
Silver (Ag)
0
0
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
-0.004
-0.004
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.025
0.025
ug/L
1
0.114
0.3
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
50.7
50.7
ug/L
1
0.104
50
101
80
120
Arsenic (As)
51.3
51.3
ug/L
1
0.111
50
103
80
120
Beryllium (Be)
50.2
50.2
ug/L
1
0.249
50
100
80
120
Cadmium (Cd)
50.4
50.4
ug/L
1
0.032
50
101
80
120
Chromium (Cr)
50.3
50.3
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
51.8
51.8
ug/L
1
0.077
50
104
80
120
Lead (Pb)
51.4
51.4
ug/L
1
0.037
50
103
80
120
Nickel (Ni)
51.4
51.4
ug/L
1
0.256
50
103
80
120
Selenium (Se)
49.9
49.9
ug/L
1
0.193
50
99.9
80
120
Silver (Ag)
50.6
50.6
ug/L
1
0.035
50
101
80
120
Thallium (TI) Low Level
48.9
48.9
ug/L
1
0.041
50
97.7
80
120
Vanadium (V) Low Level
50.7
50.7
ug/L
1
0.114
50
101
80
120
MS # 1
Parent Sample:
J22090222 -- 2022023971
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Antimony (Sb)
50.1
50.1
ug/L
1
0.104
50
100
75
125
Arsenic (As)
50
50
ug/L
1
0.111
50
99.9
75
125
Beryllium (Be)
50.2
50.2
ug/L
1
0.249
50
100
75
125
Cadmium (Cd)
50.4
50.4
ug/L
1
0.032
50
101
75
125
Chromium (Cr)
52.5
52.5
ug/L
1
0.185
50
100
75
125
Cobalt (Co)
51.6
51.6
ug/L
1
0.077
50
101
75
125
Lead (Pb)
51.5
51.5
ug/L
1
0.037
50
103
75
125
Nickel (Ni)
52
52
ug/L
1
0.256
50
102
75
125
Selenium (Se)
48.9
48.9
ug/L
1
0.193
50
97.7
75
125
Silver (Ag)
50.2
50.2
ug/L
1
0.035
50
100
75
125
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 43 of 91
This report shall not be reproduced, except in full.
Order # J22090222
Level II QC Summary
Q22100393 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MS # 1
Parameter
Measured
Final
Units
Thallium (TI) Low Level
48.4
48.4
ug/L
Vanadium (V) Low Level
50.6
50.6
ug/L
MSD # 1
Parameter
Measured
Final
Units
Antimony (Sb)
50
50
ug/L
Arsenic (As)
49.6
49.6
ug/L
Beryllium (Be)
50.4
50.4
ug/L
Cadmium (Cd)
49.9
49.9
ug/L
Chromium (Cr)
52.6
52.6
ug/L
Cobalt (Co)
51
51
ug/L
Lead (Pb)
51.2
51.2
ug/L
Nickel (Ni)
51.8
51.8
ug/L
Selenium (Se)
48.8
48.8
ug/L
Silver (Ag)
49.6
49.6
ug/L
Thallium (TI) Low Level
48
48
ug/L
Vanadium (V) Low Level
50.7
50.7
ug/L
Parent Sample:
J22090222 -- 2022023971
Dil
MDL
Spike
% Recovery
LCL
UCL
1
0.041
50
96.5
75
125
1
0.114
50
100
75
125
Parent Sample:
J22090222
-- 2022023971
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
1
0.104
50
100
75
125
0.174
1
0.111
50
99.1
75
125
0.838
1
0.249
50
101
75
125
0.389
1
0.032
50
99.9
75
125
0.971
1
0.185
50
101
75
125
0.191
1
0.077
50
99.6
75
125
1.26
1
0.037
50
102
75
125
0.565
1
0.256
50
101
75
125
0.323
1
0.193
50
97.5
75
125
0.184
1
0.035
50
99.2
75
125
1.3
1
0.041
50
95.7
75
125
0.797
1
0.114
50
100
75
125
0.112
Qualifier
Qualifier

leAnalyiical
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October 25, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on October 20, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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CERTIFICATIONS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92632312001
CCPMW-1S
Water
10/19/2210:55
10/20/22 14:23
92632312002
CCPMW-1D
Water
10/19/2210:45
10/20/22 14:23
92632312003
CCPMW-2S
Water
10/19/2212:55
10/20/22 14:23
92632312004
CCPMW-2D
Water
10/19/2214:00
10/20/22 14:23
92632312005
CCPMW-3D
Water
10/19/2214:20
10/20/22 14:23
92632312006
CCPMW-4
Water
10/19/2215:25
10/20/22 14:23
92632312007
CCPMW-5
Water
10/19/2216:35
10/20/22 14:23
92632312008
CCPMW-6S
Water
10/19/2210:55
10/20/22 14:23
92632312009
CCPMW-6D
Water
10/19/2210:20
10/20/22 14:23
92632312010
CCPMW-7
Water
10/19/2213:50
10/20/22 14:23
92632312011
CCPMW-10
Water
10/19/2215:25
10/20/22 14:23
92632312012
CCP-LEACHATE
Water
10/19/2210:30
10/20/22 14:23
92632312013
CCPSW-1
Water
10/19/22 09:30
10/20/22 14:23
92632312014
CCPSW-2
Water
10/19/2210:00
10/20/22 14:23
92632312015
CLS FD-20221019-1
Water
10/19/22 00:00
10/20/22 14:23
92632312016
CCP-LEACHATE-34
Water
10/19/2214:10
10/20/22 14:23
92632312017
CCR-CCPBG-1BR
Water
10/19/2215:25
10/20/22 14:23
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J22090222 CLS CCP/LF
92632312
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92632312001
CCPMW-1S
SM 2540C-2015
CS1
1
PASI-A
92632312002
CCPMW-1D
SM 2540C-2015
CS1
1
PASI-A
92632312003
CCPMW-2S
SM 2540C-2015
CS1
1
PASI-A
92632312004
CCPMW-2D
SM 2540C-2015
CS1
1
PASI-A
92632312005
CCPMW-3D
SM 2540C-2015
CS1
1
PASI-A
92632312006
CCPMW-4
SM 2540C-2015
CS1
1
PASI-A
92632312007
CCPMW-5
SM 2540C-2015
CS1
1
PASI-A
92632312008
CCPMW-6S
SM 2540C-2015
CS1
1
PASI-A
92632312009
CCPMW-6D
SM 2540C-2015
CS1
1
PASI-A
92632312010
CCPMW-7
SM 2540C-2015
CS1
1
PASI-A
92632312011
CCPMW-10
SM 2540C-2015
CS1
1
PASI-A
92632312012
CCP-LEACHATE
SM 2540C-2015
CS1
1
PASI-A
92632312013
CCPSW-1
SM 2540C-2015
CS1
1
PASI-A
92632312014
CCPSW-2
SM 2540C-2015
CS1
1
PASI-A
92632312015
CLS FD-20221019-1
SM 2540C-2015
CS1
1
PASI-A
92632312016
CCP-LEACHATE-34
SM 2540C-2015
CS1
1
PASI-A
92632312017
CCR-CCPBG-1BR
SM 2540C-2015
CS1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J22090222 CLS CCP/LF
92632312
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92632312002
CCPMW-1 D
SM 2540C-2015
Total Dissolved Solids
33.0
mg/L
25.0
10/21/22 13:28
92632312003
CCPMW-2S
SM 2540C-2015
Total Dissolved Solids
34.0
mg/L
25.0
10/21/22 13:28
92632312004
CCPMW-2D
SM 2540C-2015
Total Dissolved Solids
97.0
mg/L
25.0
10/21/22 13:28
92632312005
CCPMW-3D
SM 2540C-2015
Total Dissolved Solids
86.0
mg/L
25.0
10/21/22 13:28
92632312006
CCPMW-4
SM 2540C-2015
Total Dissolved Solids
114
mg/L
25.0
10/21/22 13:28
92632312007
CCPMW-5
SM 2540C-2015
Total Dissolved Solids
136
mg/L
25.0
10/21/22 13:29
92632312008
CCPMW-6S
SM 2540C-2015
Total Dissolved Solids
70.0
mg/L
25.0
10/21/22 13:29
92632312009
CCPMW-6D
SM 2540C-2015
Total Dissolved Solids
40.0
mg/L
25.0
10/21/22 13:29
92632312010
CCPMW-7
SM 2540C-2015
Total Dissolved Solids
54.0
mg/L
25.0
10/21/22 13:29
92632312011
CCPMW-10
SM 2540C-2015
Total Dissolved Solids
44.0
mg/L
25.0
10/21/22 13:29
92632312012
CCP-LEACHATE
SM 2540C-2015
Total Dissolved Solids
26900
mg/L
625
10/21/22 13:29
92632312013
CCPSW-1
SM 2540C-2015
Total Dissolved Solids
38.0
mg/L
25.0
10/21/22 13:29
92632312014
CCPSW-2
SM 2540C-2015
Total Dissolved Solids
44.0
mg/L
25.0
10/21/22 13:29
92632312015
CLS FD-20221019-1
SM 2540C-2015
Total Dissolved Solids
36.0
mg/L
25.0
10/21/22 13:29
92632312016
CCP-LEACHATE-34
SM 2540C-2015
Total Dissolved Solids
3520
mg/L
125
10/21/22 13:29
92632312017
CCR-CCPBG-1 BR
SM 2540C-2015
Total Dissolved Solids
704
mg/L
50.0
10/21/22 13:29
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: October 25, 2022
General Information:
17 samples were analyzed for SM 254OC-2015 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-1S Lab ID: 92632312001 Collected: 10/19/22 10:55 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids ND mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-1D Lab ID: 92632312002 Collected: 10/19/22 10:45 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 33.0 mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-2S Lab ID: 92632312003 Collected: 10/19/22 12:55 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 34.0 mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-2D Lab ID: 92632312004 Collected: 10/19/22 14:00 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 97.0 mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-3D Lab ID: 92632312005 Collected: 10/19/22 14:20 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 86.0 mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 11 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-4 Lab ID: 92632312006 Collected: 10/19/22 15:25 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 114 mg/L 25.0 25.0 1 10/21/22 13:28
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 12 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-5 Lab ID: 92632312007 Collected: 10/19/22 16:35 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 136 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 13 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-6S Lab ID: 92632312008 Collected: 10/19/22 10:55 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 70.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 14 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-6D Lab ID: 92632312009 Collected: 10/19/22 10:20 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 40.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 15 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-7 Lab ID: 92632312010 Collected: 10/19/22 13:50 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 54.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPMW-10 Lab ID: 92632312011 Collected: 10/19/22 15:25 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 44.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 17 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCP-LEACHATE Lab ID: 92632312012 Collected: 10/19/22 10:30 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 26900 mg/L 625 625 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPSW-1 Lab ID: 92632312013 Collected: 10/19/22 09:30 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 38.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 31

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[phone]
ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCPSW-2 Lab ID: 92632312014 Collected: 10/19/22 10:00 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 44.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 31

leAnalyiical
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CLS_FD-20221019-1 Lab ID: 92632312015 Collected: 10/19/22 00:00 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 36.0 mg/L 25.0 25.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 31

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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCP-LEACHATE-34 Lab ID: 92632312016 Collected: 10/19/22 14:10 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 3520 mg/L 125 125 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 22 of 31

leAnalyiical
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ANALYTICAL RESULTS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Sample: CCR-CCPBG-1BR Lab ID: 92632312017 Collected: 10/19/22 15:25 Received: 10/20/22 14:23 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 704 mg/L 50.0 50.0 1 10/21/22 13:29
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 31

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QUALITY CONTROL DATA
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
QC Batch: 732004 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92632312001, 92632312002, 92632312003, 92632312004, 92632312005, 92632312006, 92632312007,
92632312008,92632312009,92632312010,92632312011,92632312012,92632312013,92632312014,
92632312015,92632312016,92632312017
METHOD BLANK: 3810603 Matrix: Water
Associated Lab Samples: 92632312001, 92632312002, 92632312003, 92632312004, 92632312005, 92632312006, 92632312007,
92632312008,92632312009,92632312010,92632312011,92632312012,92632312013,92632312014,
92632312015,92632312016,92632312017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 10/21/22 13:28
LABORATORY CONTROL SAMPLE: 3810604
Spike LCS
Parameter Units Conc. Result
Total Dissolved Solids mg/L 250 246
SAMPLE DUPLICATE: 3810605
92632087008 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 119 117
LCS % Rec
% Rec Limits Qualifiers
98 90-110
Max
RPD RPD Qualifiers
2 25
SAMPLE DUPLICATE: 3810606
92632312008 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 70.0 68.0 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 10/25/2022 12:51 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 31

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QUALIFIERS
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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Date: 10/25/2022 12:51 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 31

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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22090222 CLS CCP/LF
Pace Project No.: 92632312
Lab ID Sample ID QC Batch Method QC Batch
92632312001
CCPMW-1S
SM
2540C-2015
732004
92632312002
CCPMW-1D
SM
2540C-2015
732004
92632312003
CCPMW-2S
SM
2540C-2015
732004
92632312004
CCPMW-2D
SM
2540C-2015
732004
92632312005
CCPMW-3D
SM
2540C-2015
732004
92632312006
CCPMW-4
SM
2540C-2015
732004
92632312007
CCPMW-5
SM
2540C-2015
732004
92632312008
CCPMW-6S
SM
2540C-2015
732004
92632312009
CCPMW-6D
SM
2540C-2015
732004
92632312010
CCPMW-7
SM
2540C-2015
732004
92632312011
CCPMW-10
SM
2540C-2015
732004
92632312012
CCP-LEACHATE
SM
2540C-2015
732004
92632312013
CCPSW-1
SM
2540C-2015
732004
92632312014
CCPSW-2
SM
2540C-2015
732004
92632312015
CLS_FD-20221019-1
SM
2540C-2015
732004
92632312016
CCP-LEACHATE-34
SM
2540C-2015
732004
92632312017
CCR-CCPBG-1BR
SM
2540C-2015
732004
Date: 10/25/2022 12:51 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 26 of 31

„jC UC#_Title: ENV-FRM-HUN1-0083 vOZ_Sample Condition Upon Receipt
s_',�_ Page 70 of 91
Effective Date: 05112/202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsvillef-1 ntlantal—ISample Condition
Upon Receipt Client Name: Project #: WO# 92632312
Courier: ❑Fed Ex ❑UPS ❑0 ❑Client
her; II � III II I IIIII I � �� I III
❑ Commercial ❑pace
92632312
Custody Seal Present? ❑Yes ❑No Seals Intact? Dyes ❑fqo
Packing Material, ❑Bubble Wrap ❑Bubble Bags ❑None ❑ Other
Thermometer:
❑ IR Gun ID:
Type of Ice: ” ❑Wet ❑clue []None
Correction Factor:
Choler Temp; I� �: s Add/Subtract (°C) `
Cooler Temp Corrected (°C): � J i t�. J, .
USDA Regulated Soil If] N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
(check maps)? ❑Yes ❑No
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match CDC?
-includes Date/Time/ID/Analysis Matrix: 11\/
Headspace in VOA Vials (>S-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
LJYes
LINO
LIN/A
1,
©Yes
❑No
❑N/A
2.
❑Yes
[:]No
❑N/A
3.
❑Yes
❑Na
bN/A
4.
'[]Yes
❑No
❑N/A
5.
Des
❑No
❑N/A
6,
❑Yes
[:]No
❑N/A
❑Yes
[]No
❑N/A
7.
❑Yes
[:]No
❑N/A
$•
,)Yes
RNo
[I N/A
9-
TJ511vl9,djX1
❑Yes
❑No
QN/A
10.
❑Yes
❑No
ON/A
11.
--t +•-rt , _
Date/Initials Person Examining Contents: fJup
Biological Tissue Frozen?
❑Yes ❑No ❑N/A
Temp should be above freezing to 6°C
❑samples out oftemp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rico)? ❑Yes i]No
Field Data Required? ❑Yes []NO
!� r7- UL
CLIENT NOTIFICATION/RESOLUTION Lot ID of split containers:
Person contacted:
Project Manager SCURF Review:
—Project Manager SRE Review:
Date/Time:
Date:
Date: - - - -
Qualtrax ID; 69614 Page 1 of 2 Page 27 of 31

vvv.i vv ,,Cllllf,Jlt2 l.UrIt'll tiviI UIJUft Mucelpi
Effective Data: 051121202205/12/2022 —
*Check mark top half of box if pH and/or dechlorinatlon is verified and
within the acceptance range for preservation satrapies.
Exceptions: VOA, Coliform, TOC, Oil and Grease, oRO/8015 (water) DOC, lltfg
"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Page 71 of 91
Project It WO# : 92632312
PM: NMG Rue Cate: 10/27/22
CLIENT: 92-Duke Ener
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PH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adJusted Time preservation Amount of Preservative lot #
adjusted added
*Vote -WherrtsvgrtltercTii a dlscrepancyaife�ling NottFCarolini crimp lam samples, a copy of this form will be sent tothe NorthCaralina DENRCertif
Out of hold, incorrect preservative, out of temp, incorrect containers. icationOfiice (i,e.
Qualtrax ID: 69614 Page 2 of 2 Page 28 of 31

Q r ❑❑ ..i•'-vvv.p ry r UArrrt it: k+uflullfult Upuft McCUIPT
,,: ,..,
Effectivo Date: 051121202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coiiform, TOC, Oil and Grease, DRO/8015 (water) DOC, Wig
ig
"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Page 72 of 91
Project It WO# : 92632312
PM: NMG Due Date: 10/27/22
CLIENT: 92—Duke Ener
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Page 29 of 31
Qualtrax ID: 69614 Page 2 of 2

Page 73 of 91
C
DUKE Oukr Energy pnalytFc.l Laboratory
/r urlcad. uaoa4z
DUKE
CHAIN OF CUSTODY RECORD AND ANA_LYSIS_REQUEST FORM
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Page 30 of 31

Page 74 of 91
CHAIN OF CUSTODY RECORD AND ANALYSIS_ REQUEST FORM
Duk•Energy AnalytFcal Lahoralory.._._.___._._._._._._.._._._.__._._._�._._._.__._.._._._._._.__._,.,._.__._ __ .............. — —----- ._...__._._._._._._._._.......... — ------- .__,-------
DUKE Analytical Laboratory Ua• Only
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Page _2_ of 2_
DISTRIBUTION
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Page 31 of 31

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
Og8�t�inffte. Suite 100
�J Huntersville, NC 28078
[phone]
October 27, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22090222 CCP LF
Pace Project No.: 92632460
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on October 21, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 14

leAnalyiical
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Pace Analytical Services, LLC
0gO�I ,6foe. Suite 100
�J Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: J22090222 CCP LF
Pace Project No.: 92632460
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 14

leAnalyiical
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Pace Analytical Services, LLC
OgO�I� 6ffte. Suite 100
�J Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: J22090222 CCP LF
Pace Project No.: 92632460
Lab ID Sample ID Matrix Date Collected Date Received
92632460001 CCPMW-11 Water 10/20/2216:40 10/21/2212:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 14

leAnalyiical
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Pace Analytical Services, LLC
Og8onffte. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: J22090222 CCP LF
Pace Project No.: 92632460
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92632460001 CCPMW-11
PASI-A = Pace Analytical Services - Asheville
SM 2540C-2015
REPORT OF LABORATORY ANALYSIS
CS1
PAS I -A
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 14

leAnalyiical
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Pace Analytical Services, LLC
Og8onffte. Suite 100
Huntersville, NC 28078
[phone]
Project: J22090222 CCP LF
Pace Project No.: 92632460
Lab Sample ID
Method
92632460001
SM 2540C-2015
Client Sample ID
Parameters
CCPMW-11
Total Dissolved Solids
SUMMARY OF DETECTION
Result
Units
Report Limit
Analyzed Qualifiers
61.0
mg/L
25.0
10/25/22 09:02
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 14

leAnalyiical
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Pace Analytical Services, LLC
og8nnffte. Suite 100
�J Huntersville, NC 28078
[phone]
PROJECT NARRATIVE
Project: J22090222 CCP LF
Pace Project No.: 92632460
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: October 27, 2022
General Information:
1 sample was analyzed for SM 2540C-2015 by Pace Analytical Services Asheville. All samples were received in acceptable condition
with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end
of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 14

leAnalyiical
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Pace Analytical Services, LLC
0g8oinlc6roe. Suite 100
�J Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: J22090222 CCP LF
Pace Project No.: 92632460
Sample: CCPMW-11 Lab ID: 92632460001 Collected: 10/20/22 16:40 Received: 10/21/22 12:37 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 61.0 mg/L 25.0 25.0 1 10/25/22 09:02
Date: 10/27/2022 04:15 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 14

leAnalyiical
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Pace Analytical Services, LLC
Og8nnffte. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: J22090222 CCP LF
Pace Project No.: 92632460
QC Batch: 732525 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92632460001
METHOD BLANK: 3812918
Associated Lab Samples: 92632460001
Parameter
Units
Total Dissolved Solids
mg/L
LABORATORY CONTROL SAMPLE:
3812919
Parameter
Units
Total Dissolved Solids
mg/L
SAMPLE DUPLICATE: 3812920
Parameter
Units
Total Dissolved Solids
mg/L
Matrix: Water
Blank Reporting
Result Limit MDL Analyzed Qualifiers
ND 25.0 25.0 10/25/22 08:57
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
250 256 102 90-110
92632351015 Dup Max
Result Result RPD RPD Qualifiers
570 558 2 25
SAMPLE DUPLICATE: 3812921
92632351025 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 206 206
Max
RPD RPD Qualifiers
0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/27/2022 04:15 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 14

leAnalyiical
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Pace Analytical Services, LLC
0g8oiscsroe. Suite 100
��JJ Huntersville, NC 28078
[phone]
QUALIFIERS
Project: J22090222 CCP LF
Pace Project No.: 92632460
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/27/2022 04:15 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 14

leAnalyiical
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Pace Analytical Services, LLC
OgO�I� '6ffte. Suite 100
�J Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22090222 CCP LF
Pace Project No.: 92632460
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92632460001 CCPMW-11 SM 2540C-2015 732525
Date: 10/27/2022 04:15 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 10 of 14

;�pp UG#_Title: ENV-FRM-HUN1-0083 v01_Sample Condition Upon Receipt
f�uC� Page 85 of 91
I,: r 7t' •.::, ."
Effective Date: 051121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville FC] Raleigh[] Mechanicsville❑ Atlanta❑ Kernersville❑
ConditionSample Client Name: wog : 92632460
Upon Receipt Project #:
/9 11y l II! f r
Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client
❑ Commercial [Pace ❑0ther, 92632460
Custody Seal Present? ']Yes ❑No Seals Intact? QYes ❑No
Date/initials Person Examining Contents:
Packing Material: ❑Bubble Wrap ❑Bubble Bags QNone ❑ Other
Thermometer:
IR Gun ID: �'� b Type of Ice: [] Wet
%r�� Correction Factor:
Cooler Temp: V-� Add/Subtract (°C)
Cooler Temp Corrected (°C):
USDA Regulated Sail ([ N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
(check mansl? I]Yes F1N0
❑blue ❑None
Biological Tissue Frozen?
❑Yes ❑No [�JN/A
Temp should be above freezing to VC
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
Comments/Discrepancy: u
Chain of Custody Present?
(Dyes
❑ND
❑N/A
1.
Samples Arrived within Hold Time?
DYes
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
Dyes
j]No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
. Na
❑N/A
4.
Sufficient Volume?
(Dyes
❑No
❑N/A
S.
Correct Containers Used?
mYes
❑Na
❑N/A
i
6.
-Pace Containers Used?
Yes
❑No
❑N/A
Containers Intact?
QYes
[-]No
❑N/A
?.
Dissolved analysis: Samples field Filtered?
❑Yes
[]No
®N/A
81
Sample Labels Match COC?
fDYes
[]No
[-]N/A
9.
-Includes Date/Time/ID/Analysls Matrix:
Headspace in VOA Vials (>5-6mm)?
❑Yes
[]No
NN/A
10,
Trip Blank Present?
❑Yes
QNo
[]N/A
11.
Trip Blank Custody Seals Present?
❑Yes
[]No
-©N/A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
l'roject..Manager SRF Review:
Lot ID of split containers:
Date/Time:
Date:
Date:
Field Data Required? ❑Yes ❑No
Page 11 of 14
Qualtrax ID: 69614 Page 1 of 2

1�a'Ce UC:#_Title: ENV-FRM-HUN1-0083 01_Sample Condition Upon Receipt
Effective Date: 051121202205/1.2/2022
Page 86 of 91
*Check mark top half of box if pH and/or dechlorination is verified and project H
within the acceptance range for preservation samples.
Exceptions: VOA, Coli€orm, TOC, Oil and Grease, DRO/9015 (water) DOC, Mig
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Wa# : 926324A
PM: NMG Due Date: 10/28/22
CLIENT: 92-Duke Ener
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PH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot 4
Note: whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 12 of 14
Qualtrax ID: 69614 Page 2 of 2

Duke Energy Analytical LahorA
DUKEMil Cad. Men3e; (aulldlna 7w51
``�'r ENERGY ,a1]* N, N ay Rd
HunWvlM, x. C. rb
purl a7ssxcs
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Nam- ROGERS CLIFFSIOE CCP
LANDFILL PERMIT# 81-08
Ilent RYAN CZOP, BRYAN MOELLER,
EE O'BRIEN, JOSH STOWE
Sample Description or ID
SAMPLE ID
I NUMBER
20210253061
. 2021p 397
2021025388
2021025389 E
202i�90
2021025391
2027025392 j
12021025393
20210253434 1
2021
20270253961;
I
2021025397 I
12021� 025398
i 2021025399 it
2021025400
20210�25401 1
i
i
CHAIN OF CUSTODY RECORD AND APage 87 of 91
ANALYSIS REQUEST UEST FORM -�An------ l La6an[ory ... Only.___._._._._.__._.__._._.___ti-_._.___._._._�._._._._._._._._._.._-i
0 J210 13196 Matrix WATER s.M._n .,•�,..r,.. NC_X_ i Page _1_o! 2
Deta47lm* SC-- DISTRIBUTION
t„Dr SAMPLE PROGRAM i ORIGINAL to LAD. COPY to CLIENT
ro Gund Water_X_ NPDES_
Drinking Water_ UST
R1q
c°el*r i•m C
RCRAWnste
PO# 9172712
Flltrat[On 10.45 umf
0
Unfiltered
10E
Container Volume (ml-)
Soo
300
500
Container Type
HOPE
PET
PET
m o
} �
(Metal* Prop. TR.)
(ICP - EPA 60106) Ba,
Cl. F,
Cdatomer to complaro elfappmprlete non•shadod
areas.
zz a
B. Ca, Cu, Fa, Mg, Mn,
NO3-1,1
(48-Hr
K. No. Zn (10)1 Hg
(EPA7470A)((IMS-
Hold
TITS
Coll*cllon informatlen
EPA 602013) Sh, Aa,
Time),
e.
Ba, Cd, Cr, Co, Pb, NJ,
SO4,
.to
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Prinlod Nam*
Signature
o
E
Se, All, TI(LL), V(LL)
F_ALK
u
m
12
4-5
x
1
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x
+
1
1
x
+
1
t
x
+
1
1
x
+
1
1
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x
+
1
1
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+
1
1
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+
1
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TOTAL N CONTAINERS
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78
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16
18
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Regulatory Agency: NCDENRfDVYM - SW Section STATE EDD f EQUIS REQUIRED f PERMIT 4 81.06 0
/ V
P'q 16 f 1r
a
8 Filtered
D 1 D 1 o n 1 o 1 0 48
Requested Turnaround Total 48
21 Days
14 Days X_ /,_ r
_T—o
•7 Days
'Other
• Add. COSI Will Apply
A

``� DUKE ar ..na,p,ca, t.acOraP
3\r1�I1 Ced. Y�PW aMM+P Ysa)
'ENERGY
ENERGY
Pa" arsuu
c4.n Name w ROQERS CUFFSIDE CCP
LANDFILL PERMIT# 0146
Rent RYAN CZOP, BRYAN 11lllELLfJi,
=E C'BRIEN, JOSH STOWE
I
ReGnaalan.tl ay
Sample Description cr ID
ba`larTlm•
iV(�7�RL � irft.!
CHAIN OF CUSTODY RECORD AND ANALYSIS
jam.^......`.
Po # 9172112 Fitratlan (OAS
Prese-3
����+ Container Volume I
Ccmalnor 1
CYs10rrlrr f0 complete all "PPmprfnU non-ihbtlntl ama5,
CalfeeHon Inrorm.O:On
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Reg4WOry Agency: NCDENRTIWm-SW Section STAT460I EQUIS REQUIRED lPERMIT # 8i c6
TOTAL N CDRTAINER9
x
Page 88 of 91
FORM
DISTRIBUTION
SAMPLE PROGRAM ORIGINAL to LAe. COPY In CLICNT
G11 ,6 W*w X_ NPDFS
D atml W.I., USr
ACn. wow.
---
B Unlitlerpd - d
Filtered
I(.F
rcE
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506
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in rimmu u
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__
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EPA 60206$ SE, Ai,
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a., Ctl. Cr, Cc, Ph, W.
SO4,
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—
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" Days - -- .—X�-f�
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m�
E '171har _
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Page 89 of 91
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DUKEAnalytical
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SAMPLE PROGRAM
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ELANDFILL PERMIT#
.2am;
Ground Water _X
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i
`-4RYAN
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ICE
ICE
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300
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PET
PET
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>
_ ._.._.._.._.._._.
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to complete all appropriate non -shaded
areas.
a
a
B, Ca, Cu. Fe, Mg, Mn,
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)
o
Date
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CHAIN OF CUSTODY RFCORn ONn At -JAI vSIS Rl=nl IGQT rnoae
Page 90 of 91
a01c13'r
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Laboratory Use Only
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ORIGINAL to LAB, COPY to CLIENT
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LANDFILL PERMIT# 81.06 i
Pace
4 Client RYAN CZOP, BRYAN MOELLER, `
D
;-.._.._.._....._._co°�er i.mC.I�)._.._...._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._.._..
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Page 91 of 91
CHAIN OF CUSTODY RFCnRn OMn AMAI vslc P=f)l I=QT cneaa
Duke Energy Analytical Laboratory------------------'-----'-'-'-""-'-'-"-'-'--'-"'-"---AnalyticalLaboratory Use Only
-- ' '-- ' '-' '-' '--- '-'----' '-' -- '-' -- '--
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o LANDFILL PERMIT# 81-06 i
RCRA Waste
Client RYAN CZOP, BRYAN MOELLER, 'a`D �' era A!'['0 ._.._.._.._. ,cooler 7amP_1c1._.._. _.._.._.._.._.._.._.._.._._.._.._.._.._.._.._..—_.._.._.._.._.._.._.._.._.._..
a' DEE O'BRIEN, JOSH STOWE t ` Filtration (0.45 um) Z'- Unfiltered Il Filtered
ating Unit: CS56 NGRDWTR Account: L�__ritPreservativeICE
r®#917Z
�.J.ct:ICE
�Activlty
AC5580062 D: Facility ID: CLS "-"-"-"-"-"-" . ,.r.
T ContajVolumeML) 500 300 500
Program I EQUIS Task Code: CLS Sub-Programfcask Code:CCPILF
ype HDPE PET PET
(Metals Prep - TRM)CI, F,
L(ICP-EPA
6010D)Be, NO3-NCustomer
to complete ell appro riate non- w 8, Ca, Cu, Fe, Mg, Mn, (48-Hr
p shaded areas.
-_- K, Na, Zn (10) I Hg E
-""'-""' Sample Description or ID Hold 2
P P (EPA 7470A) I TDS `o
Collection Information b, As, Time),
SAMPLE ID EPA 6020B) Sb, As, �
NUMBER Be, Cd, Cr, Co, Pb, Ni, SO4, a
i c Se, All, TILL), VILL) F_ALK m
r--� Date Time Printed Name Signature
0o D 12 (4.5)
2021025386
'. 2021025387
GL.&_66PMW!9
t;t8 CCPMVp 1p
x
1
1
1
3
x
1
1
1
3
is 2021025388 is
5L,-CC2MW.9t
_
x
1
1
1
!. 2021025389 !
66A-eePMYWPB
3
x
1
t
1
3
2021025390
C1:6_66PMW96,
2021025391 ;
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x
1
1
t
3
3
2021025392
6L�-6CPMYV.r
x
1
1
1
X
1
1
1
3
i 2021 93
Gt1-eePWW-S,
i 2021025394i
S 66SCRMW-69
x
1
1
1
3
20210253951
CQ- -21111 D
x
1
1
1
3
x
t
1
1
! 2021025396 is
61S_GCPMWy
3
3
X
t
! 2021025397 1
6LS-CLAMyV.B
x
1
2021025398
6t6�6PMW{g
x
1
1
3
99 j
CLS_CCPMW-11 !7
1004-4
164o
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1
3
3
2021025400
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JJ
1
1
1
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i 20210
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0
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l i
TOTAL ,00"T Nl '.
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a
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"A''q'.;
a
ustomer o Man date a ow
-
0
.,o
�0�.`:"48
Relinquished By DateRime
Accepted DateRime
,..
Requested Turnaround
,
Total E
Relinquished By DateRime
Acce d y: DateRime
o
C
w a
T
21 Days
Rellnilulsh.d By Dat./Tim. Accepted
By: DateRime
-
�J
/�
0
c
14 Days X
Se DateRime Sealedl1-ock
Opened By DateRime
r 3
a
r
z Z
°o. �_'
'7 Days
Comments
v
w
Regulatory Agency: NCDENRIDWm - SW Section STATE EDD I EQUIS REQUIRED I PERMIT # 81-06
0
•Other
U
' Add. Cost Will Apply