3902_Granville_Butner_MSWLF_Sept22GW_FID1771894_20230201

hart 'L hickman
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Via E-Mail
[e-mail]
January 26, 2023
Garrett & Moore, Inc.
1029 West South Street
Raleigh, NC 27603
sbray(&,Barrett-moore. com
Attn: Mr. Stefan Bray, PE
Re: Water Quality Monitoring Report — September 2022
Granville County Butner Landfill
Butner, Granville County, NC
Facility Permit No. 39-02
H&H Job No. GMI-003
Dear Stefan:
Hart & Hickman, PC (H&H) is submitting the attached Water Quality Monitoring Report —
September 2022 documenting sample results for the Butner Landfill for the second semi-annual
sampling event of 2022. H&H appreciates the opportunity to work with you on this project. If
you have any questions or require additional information, please do not hesitate to contact us at
704-586-0007.
Very truly yours,
Hart & Hickman, PC
Jason Soban, PG
Project Manager
Jeffrey 011ison
Project Environmental Scientist
2923 South Tryon Street, Suite 100
Charlotte, NC 28203
704_S86.0007 main
3921 Sunset Ridge Rd, Suite 301
Raleigh, NC 27607 www.harthickman.com
919.847.4241 main

b 5E—NR USE ONLY: I ❑Paper Re ort ❑Electronic Data - Email CD (data loaded: Yes / No Y Doc/Event #:
NC DENR I rEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1 As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i)
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information _
Name of entity submitting data (laboratory, consultant, facility owner):
Garrett & Moore, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Stefan
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # ( 0500 or .1600) October 20-24, 2006)
,Granville County State Road 1004
Butner Landfill Butner. NC 27565 E02 1600 September 28-29, 2022
Environmental Status: (Check all that apply) _
❑ Initial/Background Monitoring ❑ Detection Monitoring :X] Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Methane gas monitoring data
Groundwater monitoring data from private water supply wells
❑X Corrective action data (specify)
Leachate monitoring data
❑ Other(specify)
Surface water monitoring data
MNA Parameters
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Jason Soban, PG Consultant for Facility [phone]
Facility Representative Name (Print) Title (Area Code) Telephone Number
26' Z 1" Affix NC Licensed/ Professional Geologist Seal
Signature f Date
2923 S Tryon Street, Suite 100, Charlotte, NC 28203
Facility Representative Address
C-1269 (Engineering) 245 (Geology)
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
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Water Quality Monitoring Report
September 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
January 26, 2023
GARRETT
&MOOREEP22
Engineering for the POMF and WasN Industries
-.411
hart 'ti• hickman
■
SMARTER ENVIRONMENTAL SOLUTIONS
2923 South Tryon Street, Suite 100 3921 Sunset Ridge Rd , Suite 301
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919,847.4241 main

Water Quality Monitoring Report — September 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
Table of Contents
Section Paj4e
1.0 Introduction.................................................................................................................I
1.1
Site Information........................................................................................................1
1.2
Regulatory Status......................................................................................................1
1.3
Groundwater Monitoring Program...........................................................................2
1.4
Surface Water Monitoring Program.........................................................................3
2.0 Water Quality Monitoring Activities........................................................................5
2.1
Water Level Measurements......................................................................................5
2.2
Groundwater Sampling Methods..............................................................................5
2.3
Surface Water Sampling Methods............................................................................6
2.4
Sample Equipment Management..............................................................................6
2.5
Sample Handling and Laboratory Analyses.............................................................7
3.0 Water Quality Monitoring Results............................................................................8
3.1
Groundwater Flow and Hydraulic Gradient.............................................................8
3.2
Groundwater Analytical Results...............................................................................9
3.3
Surface Water Analytical Results...........................................................................10
3.4
Quality Assurance/Quality Control Results............................................................11
4.0 Corrective
Action Evaluation..................................................................................13
4.1
Monitored Natural Attenuation Parameters............................................................13
4.2
Phytoremediation....................................................................................................13
4.3
Evaluation of Plume Stability and Trends..............................................................14
5.0 Conclusions
................................................................................................................17
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List of Tables
Table 1
Summary of Well Construction Details
Table 2
Summary of Groundwater Elevations
Table 3
Summary of Field Parameters
Table 4
Summary of Groundwater Flow Velocity
Table 5
Summary of Constituent Detections
Table 6
Summary of Monitored Natural Attenuation Parameters
List of Figures
Figure 1 Site Location Map
Figure 2 Site Plan
Figure 3 Groundwater Potentiometric Map (September 28, 2022)
Figure 4 Phytoremediation Survey Map
List of Appendices
Appendix A
Groundwater and Surface Water Sampling Records
Appendix B
Laboratory Analytical Reports
Appendix C
Summary of Historical Groundwater Elevations
Appendix D
Summary of Historical Constituents in Groundwater
Appendix E
Summary of Historical Constituents in Surface Water
Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
Appendix G
Phytoremediation Tree and Flora Inspection Logs
Appendix H
Concentration vs. Time Charts
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Water Quality Monitoring Report — September 2022
Granville County Butner Landfill
Butner, North Carolina
Permit No. 39-02
H&H Job No. GMI-003
1.0 Introduction
This Water Quality Monitoring Report (Report) has been prepared by Hart & Hickman, PC (H&H)
to document the methods and results of semi-annual groundwater and surface water monitoring
activities conducted at the Butner Landfill located off State Route 1004 near the Town of Butner,
Granville County, North Carolina. A site location map is included as Figure 1. Water quality
monitoring at the site was performed in general accordance with the Water Quality Monitoring
Program as described in the Corrective Action Plan (May 2014), which was approved by the North
Carolina Department of Environmental Quality (DEQ) Solid Waste Section (SWS).
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the Town of Butner, Granville County, North Carolina. The Butner facility started receiving
solid waste prior to May 1973. Permit Number 39-02 was issued by the State of North Carolina
on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the present, a
small recycling center and transfer station are operated by the County of Granville at the entrance
of the closed landfill. A site layout map that depicts the facility features is included as Figure 2.
1.2 Regulatory Status
The Butner Landfill entered an Assessment Monitoring Program in December of 1997 because of
detections of volatile organic compounds (VOCs) and pesticides above the North Carolina 2L
Groundwater Standards (2L Standards). An Assessment of Corrective Measures (ACM) was
initiated in 2003, and then suspended by DEQ since there had been no more 2L Standard
exceedances. The Nature and Extent Study (NES) and ACM were recommenced in 2007 when
apparent VOC exceedances of the 2L Standard began to appear; however, they were again
Ad
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suspended when it was determined that the apparent exceedances were not statistically significant
increases (SSIs) above background. An ACM was reinitiated after an exceedance of benzene in
monitoring well MW-2R in December 2012 and was submitted to DEQ in May 2013. Approval
of the ACM was granted in a letter from DEQ dated June 27, 2013. A Corrective Action Plan
(CAP) for monitored natural attenuation (MNA) plus phytoremediation was submitted to DEQ on
May 23, 2014, and was approved by DEQ on June 18, 2014.
The site is currently in an Assessment Monitoring Program and Corrective Action Monitoring
Program. Groundwater and surface water samples are collected semi-annually and analyzed in
accordance with the approved CAP. An overview of the monitoring program is provided in the
following sections.
1.3 Groundwater Monitoring Program
The groundwater monitoring program at the Butner Landfill consists of the following seven
monitoring wells: MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring
well MW-1R is located northwest and upgradient of the landfill and serves as a background
location. The compliance network consists of monitoring wells MW-2R, MW-3R, MW-4, MW-
5, and MW-6, which are situated cross -gradient and downgradient of the landfill. Compliance
monitoring wells MW-2R and MW-3R are located at the southern downgradient side of the landfill
and also serve as CAP performance wells. Monitoring well NES-1 is located downgradient of
MW-2R and MW-3R and serves as a CAP sentry well. The monitoring well locations and other
site features are identified on Figure 2. A summary of well construction details is provided in
Table 1.
Groundwater samples are collected semi-annually for select analyses per the CAP. Sample
analyses includes North Carolina Solid Waste Management Rules Appendix I or Appendix II
constituents (hereafter referred to as Appendix I constituents and Appendix II constituents,
respectively), and/or constituents of concern (COCs; i.e., 1,4-dioxane benzene, and cobalt).
During the first half semi-annual event compliance well analysis for Appendix I and Appendix II
constituents is completed. During the second half semi-annual event compliance well analysis for
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Appendix I and detected Appendix II constituents is completed. As required by DEQ in their
August 3, 2018 letter, tin and any new Appendix II detections are analyzed during each semi-
annual event. A summary of the well locations and sample analyses for the semi-annual sampling
events is provided below.
Select MNA parameters (alkalinity, biochemical oxygen demand [BOD], chemical oxygen
demand [COD], chloride, ferrous iron, sulfate, methane, nitrate, total organic carbon [TOC], pH,
temperature, and specific conductance) are analyzed on a semi-annual basis for MW-2R and MW-
3R, and annually for NES-1 and MW-1R. As required by DEQ in their January 13, 2021 letter,
six additional MNA parameters (dissolved hydrogen, sulfide, volatiles fatty acids, dissolved
carbon dioxide, ethene, and ethane) are to be sampled for two times every five years corresponding
to the two events immediately preceding the CAER (i.e., second half event 2024 and first half
event 2025).
Well ID
Classification
First Half Analyses
Second Half Analyses
MW-lR
Background
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane, Select MNA
Dioxane
MW-2R
Compliance
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane, MNA
Dioxane, MNA
MW-3R
Compliance
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane, MNA
Dioxane, MNA
MW-4
Compliance
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
MW-5
Compliance
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
MW-6
Compliance
App. I + App.
II,
1,4-
App. I + App. II Det., 1,4-
Dioxane
Dioxane
NES-1
Sentry
COCs, MNA
COCs
1.4 Surface Water Monitoring Program
The surface water monitoring program at the Butner Landfill consists of collecting samples from
two locations (SW-1 and SW-2) along an unnamed tributary to Picture Creek which is situated
along the southern downgradient boundary of the site. Picture Creek is classified as a Class IV
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(Water Supply) stream. The surface water sampling points are located downgradient of the facility
at upstream (SW-1) and downstream (SW-2) locations. The locations of the surface water
monitoring points are identified on Figure 2. Surface water samples are collected semi-annually
and analyzed for Appendix I constituents plus 1,4-dioxane.
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2.0 Water Quality Monitoring Activities
2.1 Water Level Measurements
On September 28, 2022, H&H measured depth -to -water and total depths in monitoring wells MW-
1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Depth -to -water measurements were
collected from the top -of -casing utilizing a decontaminated electronic water level indicator.
Depth -to -water measurements were made after the wells were opened for a sufficient period of
time to allow water levels to equilibrate with atmospheric pressure. Water level measurements
and calculated groundwater elevations are presented in Table 2.
2.2 Groundwater Sampling Methods
On September 28 and 29, 2022, H&H collected groundwater samples from site monitoring wells
MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. Monitoring well MW-1R serves
as the upgradient background well for the facility, and monitoring wells MW-2R, MW- 3R, MW-
4, MW-5, MW-6, and NES-1 serve as compliance monitoring wells. The groundwater samples
were collected and handled in accordance with the sampling protocols included in the site Water
Quality Monitoring Plan as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface
Water Sampling document.
The monitoring wells were purged utilizing a peristaltic pump or submersible pump under low
flow (< 200 milliliters/minute) conditions. Water levels were recorded during the purging process
to ensure the pump rate did not cause significant drawdown of the water column, and samples were
collected following stabilization of field parameters over three consecutive readings. Field
measurements of pH, temperature, specific conductance, oxygen reduction potential (ORP), and
dissolved oxygen (DO) were measured using a YSI Pro Plus water quality meter. Turbidity was
measured using a HF Scientific MicroTPI turbidity meter. A summary of the final field parameters
recorded prior to sample collection is presented in Table 3. Copies of groundwater sampling forms
containing pertinent information recorded in the field during purging and sampling at each
monitoring well are presented in Appendix A.
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The results of the field -measured water quality parameters indicate that the values measured in
groundwater collected from site monitoring wells were within applicable stabilization criteria.
Groundwater at the site is acidic based on the pH values measured in the field (4.88 to 6.96
Standard Units). Specific conductance values in site groundwater ranged from 77.9 (MW-1 R) to
2,016 (MW-2R) microsiemens per centimeter (µS/cm) with higher values measured at well
locations immediately downgradient of the landfill. Turbidity values ranged from <0.02 (MW-
2R, MW-3R, and MW-6) to 10.8 (MW-1R) nephelometric turbidity units (NTUs). The collected
groundwater sample from MW-1R exhibited a turbidity slightly above the target level of 10 NTU;
however, the turbidity level in the well was stable at the time of collection.
2.3 Surface Water Sampling Methods
On September 28, 2022, H&H attempted to collect surface water samples from sample locations
SW-1 and SW-2 (Figure 2). During the sampling event, a surface water sample was collected
from downstream location SW-2; however, consistent with prior seasonal conditions the upstream
surface water sample location SW-2 was dry and a sample was not collected from this location.
Surface water samples were collected in general accordance with the site Water Quality
Monitoring Plan as well as the DEQ SWS Guidelines for Groundwater, Soil, and Surface Water
Sampling document. Field parameters were measured during sample collection and a copy of the
surface water sampling form is provided in Appendix A. A summary of field parameters recorded
prior to sample collection is provided in Table 3.
2.4 Sample Equipment Management
Reusable sampling equipment (e.g., water level indicator, bladder pump) was properly
decontaminated between sampling locations with a non -phosphate soap and water wash, followed
by multiple rinses with distilled water. New disposable nitrile or latex gloves were worn during
sampling activities. Disposable sampling equipment/material was discarded after each use.
0
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2.5 Sample Handling and Laboratory Analyses
Upon sample collection, samples for laboratory analysis were placed directly into dedicated
laboratory -supplied sample bottles, labeled, and placed into ice -filled coolers. A chain -of -custody
record was completed and included sample description, analyses required, matrix, sample
container information, and date and time of sample collection. The samples were transported on
ice, under standard chain -of -custody protocol, to Pace Analytical Services, Inc. (Pace) in
Huntersville, North Carolina. Pace is a North Carolina -certified laboratory. The laboratory
analytical report and chain -of -custody record for the September 2022 sampling event are included
in Appendix B. A summary of samples collected during the subject reporting period is provided
below.
The groundwater samples from monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5 and
MW-6 were analyzed for Appendix I constituents and Appendix II constituents detected during
the first monitoring event of 2022 (i.e., naphthalene and tin), plus 1,4-dioxane. The groundwater
samples from monitoring wells MW-2R and MW-3R were also analyzed for MNA parameters.
Additionally, the groundwater sample from monitoring well NES-1 was analyzed for benzene, 1,4-
dioxane, and cobalt as COCs. The surface water sample from SW- 2 was analyzed for Appendix
I constituents plus 1,4-dioxane.
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3.0 Water Quality Monitoring Results
Groundwater and surface water monitoring activities were conducted at the site on September 28
and 29, 2022. Groundwater and surface water samples were collected and analyzed in accordance
with the DEQ approved CAP and changes to the CAP documented in DEQ approved Corrective
Action Evaluation Reports (CAER; December 2016 and December 2020). The monitoring results
are discussed in the following sections.
3.1 Groundwater Flow and Hydraulic Gradient
A summary of monitoring well gauging and water level elevation data is provided in Table 2.
Historical groundwater elevation data is provided in Appendix C. Groundwater flow direction,
average hydraulic gradient, and average interstitial flow velocity were derived from water -level
measurements recorded during the September 2022 sampling event. A potentiometric map
generated from the September 28, 2022 gauging event is provided as Figure 3. The September
2022 water levels measured at downgradient wells are on average slightly higher than the February
2022 event, but similar to historical seasonal fluctuations. Consistent with historical trends, the
overall direction of shallow groundwater flow at the site is south to southeast towards the unnamed
tributary to Picture Creek.
The hydraulic gradient in the vicinity of each well was derived by dividing the elevation difference
between water table elevations measured at the monitoring wells and proximal potentiometric
contour lines, by the perpendicular horizontal distance between the wells and potentiometric
contours (Figure 3 and Table 4). The potentiometric contours indicate an average hydraulic
gradient of approximately 0.044 ft./ft. Results of in -situ slug testing reported by others (LaBella,
2021) indicate an average hydraulic conductivity value in the shallow surficial aquifer of 6.18 x
10-2 feet/day (approximately 22.6 feet/year). Using the horizontal hydraulic gradient
measurements, the individual estimate of hydraulic conductivity, and an assumed effective
porosity of 0.18 (LaBella, 2021), the range of average interstitial groundwater flow velocities for
the shallow surficial aquifer was calculated using the following equation: VX = (K/ne) x dh/dl.
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Where:
VX = average interstitial groundwater flow velocity;
K = hydraulic conductivity;
ne = effective porosity; and,
dh/d1= horizontal hydraulic gradient
Average linear flow velocities are estimated to range between approximately 3.07 to 7.29 feet/year
(0.008 to 0.020 feet/day), with a geometric mean of 5.45 feet/year (0.015 feet/day). These values
are consistent with prior monitoring events. Table 4 summarizes the data used to calculate the
average interstitial groundwater flow velocity in the vicinity of each monitoring well.
3.2 Groundwater Analytical Results
Semi-annual groundwater sampling consisted of collecting samples from seven site monitoring
wells. A summary of groundwater constituent detections from the September 2022 sampling event
is provided in Table 5. Historical analytical results are presented in Appendix D. Consistent with
the CAP and subsequent changes documented in DEQ approved CAERs (December 2016 and
December 2020), the primary COCs for the site include benzene, 1,4-dioxane, and cobalt. A
summary of groundwater results for site COCs and other exceedances is provided below.
Organic Analyses
The analytical results indicate VOCs benzene, chlorobenzene, 1,2-dichlorobenzene, 1,4-dioxane,
naphthalene, trichlorofluoromethane, and vinyl chloride were detected at concentrations above
laboratory method detection limits (MDLs) in one or more wells during the September 2022
sampling event. Benzene was detected at a concentration above its 2L Standard (1 µg/L) in MW-
2R (1.9 µg/L). The concentration of benzene detected in MW-2R is consistent with historical data
and has been addressed in the ACM (approved in June 2013) and the CAP (approved in June
2014). 1,4-Dioxane (up to 98.7 µg/L) was detected at concentrations above its 2L Standard (3
µg/L) in monitoring wells MW-2R, MW-3R, MW-4, and MW-5, and concentrations are consistent
with historical detections. Vinyl chloride was detected at an estimated J-flag concentration above
its 2L Standard (0.03 µg/L) in MW-3R (0.72 J µg/L), and the concentration is consistent with
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historical detections at this location. No other organic constituents were detected above 2L
Standards during the September 2022 sampling event.
Inorganic Anal
The analytical results indicate metals barium, cadmium, cobalt, nickel, selenium, and tin were
detected at concentrations above MDLs in one or more wells during the September 2022 sampling
event. Cobalt (up to 37.9 µg/L) was detected at concentrations above its 2L Standard (1 µg/L) in
MW-2R, MW-3R, MW-4, and MW-5, and current concentrations are comparable to historical
detections. Nickel (101 µg/L) was detected at a concentration slightly above its 2L Standard (100
µg/L) in MW-2R. Historic concentrations of nickel have fluctuated above and below 2L Standards
in MW-2R, and the current concentration is comparable to historical detections at this location.
No other inorganic constituents were detected above 2L Standards during the September 2022
sampling event.
3.3 Surface Water Analytical Results
During the September 2022 sampling event, a surface water sample was collected from
downstream location SW-2; however, consistent with prior seasonal conditions the upstream
surface water sample location SW-2 was dry and a sample was not collected from this location. A
summary of surface water constituent detections from the September 2022 sampling event is
provided in Table 5. Historical analytical results are presented in Appendix E. A discussion of
the results of the September 2022 sampling event is provided below.
The analytical results indicate four constituents (1,4-dioxane, barium, cobalt, and nickel) were
detected above the MDL in the sample collected from downstream location SW-2. The detected
concentration of barium does not exceed the North Carolina 2B Surface Water Standards (2B
Standard). However, nickel (46.6 µ/L) was detected above its 2B Standard (25 µg/L). With regard
to 1,4-dioxane and cobalt North Carolina has not established 213 Surface Water Standards. Results
of the surface water sampling indicate 1,4-dioxane was detected in downstream sample SW-2 (54.5
µg/L) at a concentration above the North Carolina In -Stream Target Value for Surface Water
(ISTV; 0.35 µg/L); and cobalt was detected in downstream sample SW-2 (10.7 µg/L) at a
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concentration above the ISTV (3 µg/L). Review of historic data indicates concentrations of nickel,
1,4-dioxane, and cobalt are comparable to historical detections at SW-2 which have fluctuated
above and below applicable surface water standards. No other constituents were reported above
the applicable surface water standards during the September 2022 sampling event.
3.4 Quality Assurance/Quality Control Results
Quality assurance procedures and protocols for sampling activities were conducted in general
accordance with the DEQ-approved CAP. Quality assurance samples included the collection of a
trip blank and field blank sample. Samples were received by the lab in good condition and met
holding times and preservation requirements. Based upon a review of the data packages, no
significant quality assurance/quality control (QA/QC) issues were identified for the laboratory
analyses. In summary, the QA/QC results indicate that the data collected during the semiannual
monitoring event is suitable for its intended purpose.
Trip Blanks
Laboratory -filled trip blanks accompanied the sampling team during sampling and the transport of
VOC samples to the laboratory. The trip blank samples serve as a QC check on potential external
contamination and/or cross -contamination between VOC water samples during shipping and
storage. The trip blank samples were analyzed for Appendix I VOCs and 1,4-dioxane. The results
indicate no constituents were detected above laboratory MDLs, with the exception of an estimated
J-flag concentration of acetone detected in the trip blank sample dated September 29, 2022.
Review of the laboratory analytical report indicates that acetone was not detected above the
laboratory MDL in the sample that was submitted with this trip blank sample. Acetone is a
common laboratory contaminant and the low detection in the trip blank sample may be a result of
laboratory cleaning processes
Field Blanks
A field blank sample was collected in the field by exposing laboratory -supplied deionized water
to the sampling environment. The field blank is used to evaluate the potential for contamination
of a sample by site contaminants from a source not associated with the samples collected. The
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field blank sample was analyzed for the same constituent that groundwater samples were analyzed
for (Appendix I constituents, select Appendix II constituents, and 1,4-dioxane). The results
indicate no constituents were detected above laboratory MDLs.
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4.0 Corrective Action Evaluation
4.1 Monitored Natural Attenuation Parameters
Groundwater samples collected during the September 2022 sampling event from monitoring wells
MW-2R, and MW-3R were analyzed for MNA parameters. The groundwater MNA parameter
results for the current sampling event are summarized in Table 6. Historical groundwater MNA
parameter results are provided as Appendix F. A summary of the MNA parameters collected
from the above locations is provided below:
• MNA Field Parameters: temperature, pH, conductivity, ORP, turbidity, DO, and ferrous
iron.
• MNA Laboratory Parameters: alkalinity, biological oxygen demand (BOD), chemical
oxygen demand (COD), chloride, methane, nitrogen/nitrate, sulfate, and total organic
carbon (TOC).
Based on the January 13, 2021 response from DEQ to the CAER dated December 21, 2020,
additional parameters including dissolved carbon dioxide, dissolved hydrogen, sulfide, volatile
fatty acids, dissolved methane, ethene, and ethane will be analyzed for two events every five years,
corresponding to the two events immediately preceding each CAER. The next CAER is due after
the second half semi-annual sampling event of 2025. The current results will supplement the above
mentioned future MNA sampling and the comprehensive results as they relate to the evaluation of
MNA as the remedy for this site will be discussed in detail in the next CAER.
4.2 Phytoremediation
On August 29, 2022, a phytoremediation tree survey for the Butner Landfill was conducted in
accordance with the CAP. The CAP requires completion of an annual phytoremediation tree
survey including surveys of tree species, tree health, and tree maturity within the plume area. The
results of August 2022 phytoremediation tree survey indicated flora in the phytoremediation areas
are relatively unchanged since the previous survey and flora appear healthy. Phytoremediation
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Tree and Flora Inspection Logs are included as Appendix G and a figure depicting the
phytoremediation areas is included as Figure 4. The next phytoremediation survey will be
scheduled for summer 2023.
4.3 Evaluation of Plume Stability and Trends
As required by the CAP, this Water Quality Monitoring Report includes an evaluation of plume
stability and contaminant concentration trends based on analytical results obtained from
performance wells MW-2R and MW-3R. In addition, constituent exceedances at other compliance
monitoring wells (i.e., MW-4 and MW-5) are discussed in this section. The September 2022
results indicate organic compounds benzene, 1,4-dioxane, and vinyl chloride, and inorganic
compounds cobalt and nickel, are the only constituents detected in site groundwater at
concentrations above 2L Standards. Charts that depict constituent concentrations versus time for
site COCs (benzene, 1,4-dioxane, and cobalt) are provided in Appendix H. A discussion of the
concentration trends in site groundwater is provided below.
Ra"_a"P
Chart 1 presents a plot of benzene concentrations for monitoring wells with previous detections
(MW-2R, MW-3R, and MW-4). Historical results indicate there were no benzene detections in
site groundwater prior to December 2006; however, from December 2006 to present,
concentrations of benzene in MW-2R were detected above its 2L Standard (1.0 µg/L) with
concentrations ranging between 1.2 µg/L and 2.1 µg/L. During prior monitoring events, benzene
was also detected in MW-3R (up to 0.73J µg/L) and MW-4 (up to 0.44J µg/L) at estimated J-flag
concentrations below its 2L Standard. The benzene concentrations from the September 2022
sampling event are consistent within historical detections at the site.
Site monitoring results indicate benzene detections and exceedances are localized and limited to
three compliance monitoring wells. Since there have been no detections of benzene in samples
collected from surface water or sentinel well NES-1, there is no indication that the plume is
migrating toward the property boundary. This COC will continue to be monitored during future
semi-annual sampling events.
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1,4-Dioxane
As required by the DEQ Solid Waste Section, beginning in 2018 groundwater and surface water
samples collected at the site have been analyzed for 1,4-dioxane. Chart 2 presents a plot of 1,4-
dioxane concentrations for monitoring wells with previous detections (MW-2R, MW-3R, MW-4,
and MW-5). The results of the September 2022 sampling event indicate 1,4-dioxane was detected
above its 2L Standard in compliance monitoring wells MW-2R, MW-3R, MW-4, and MW-5. As
shown on the chart, the 1,4-dioxane concentrations are generally stable and current concentrations
are consistent with historical detections at the site. This COC will continue to be monitored during
future semiannual sampling events.
Surface water results indicate 1,4-dioxane was detected in the downstream sample collected from
SW-2 at a concentration of 54.5 µg/L and above its ISTV. No sample was collected from upstream
location SW-1 due to seasonally dry conditions at the time of the sampling event. 1,4-Dioxane
concentrations in surface water have historically fluctuated between non -detect and 26.0 µg/L. The
September 2022 detection of 1,4-dioxane at SW-2 is the highest detection to date in surface water
sampled at the site.
Based on the available data collected since 2018, 1,4-dioxane concentrations in groundwater
appear to be relatively stable, while detections in surface water have fluctuated to varying degrees.
This COC will continue to be monitored during future semi-annual sampling events.
Vinyl Chloride
The September 2022 sample results indicate vinyl chloride was detected at an estimated J-flag
concentration (0.72J µg/L) above its 2L Standard (0.03 µg/L) in compliance monitoring well MW-
3R. The exceedance is consistent with historical detections at this location which have ranged
from non -detect to 1.1 µg/L since 2006. Recent vinyl chloride detections in site groundwater
appear to be limited to MW-3R and will be monitored during future semi-annual sampling events.
Cobalt
Chart 3 presents a plot of the cobalt concentrations versus time for select monitoring wells where
it has consistently been detected in exceedance of its 2L Standard of 1 µg/L (MW-2R and MW-
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5). Cobalt in MW-2R has ranged between non -detect and 38.0 µg/L, but has been consistently
between 7.4 and 17.0 µg/L since August 2014. Cobalt in MW-5 has fluctuated between non -detect
and 251 µg/L, but has been consistently between 11.4 and 172 µg/L since August 2014. This COC
will continue to be monitored during future semiannual sampling events.
Ni rkal
The September 2022 sample results indicate nickel was detected slightly above its 2L Standard in
compliance monitoring well MW-2R. Historically, concentrations of nickel have fluctuated above
and below 2L Standards in MW-2R, and the current concentrations are comparable to prior
detections.
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5.0 Conclusions
Semi-annual water quality monitoring activities were conducted at the site in September 2022.
The groundwater results indicate the landfill monitoring well network remains adequate to monitor
the site. Review of plume stability and concentration trends indicate that the selected remedies of
natural attenuation and phytoremediation are adequately controlling the plume. Based on the
September 2022 results, site COCs remain consistent with the prior sampling event, and the facility
will continue work in the Assessment Monitoring and Corrective Action programs. A summary
of the results is provided below.
• Consistent with historical trends, the overall direction of groundwater flow at the site is
south to southeast towards the unnamed tributary to Picture Creek.
• Benzene (MW-2R), 1,4-dioxane (MW-2R, MW-3R, MW-4, and MW-5), and vinyl
chloride (MW-3R) were detected in groundwater at concentrations above their 2L
Standards. The benzene, 1,4-dioxane, and vinyl chloride concentrations are consistent with
historical concentrations detected at each location. No other organic constituents were
detected above 2L Standards.
• Cobalt (MW-2R, MW-3R, MW-4, and MW-5), and nickel (MW-2R) were detected in
groundwater at concentrations above their 2L Standards. The cobalt and nickel
concentrations are consistent with historical concentrations detected at each location. No
other inorganic constituents were detected above 2L Standards.
• Nickel was detected in the downstream surface water sample (SW-2) at a concentration
above its 2B Standard. Cobalt and 1,4-dioxane were detected in SW-2 at a concentration
above their respective ISTV. The nickel and cobalt concentrations are consistent with
historical concentrations at this location. The 1,4-dioxane concentration is the highest
detection to date since monitoring for this compound began in 2018. The upstream surface
water sample location (SW-1) was dry and not sampled during September 2022.
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Table 1
Summary of Well Construction Details
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Ground
TOC
Top of
Top of
Bottom of
Total Well
Depth to
Geologic
Well ID
Latitude
Longitude
Elevation
Elevation
Casing
Screen
Screen
Depth
Bedrock
Unit
(ft AMSL)
(ft AMSL)
(ft AGS)
(ft BTOC)
(ft BTOC)
(ft BTOC)
(ft BTOC)
Fractured
MW-1 R
N 36° 09' 55.49"
W 78° 45' 37.80"
461.01
460.51
0.00
41.00
56.00
56.00
30.00
Bedrock
Weathered
MW-2R
N 36° 09' 38.57"
W 78° 45' 34.97"
326.60
331.60
2.34
3.85
18.85
18.85
13.00
Bedrock
Fractured
MW-3R
N 36° 09' 38.58"
W 78° 45' 34.85"
328.77
330.96
2.18
25.83
35.83
35.83
13.00
Bedrock
Fractured
MW-4
N 36° 09' 38.93"
W 78° 45' 30.15"
338.97
340.80
1.95
16.43
31.43
31.43
13.00
Bedrock
Fractured
MW-5
N 36' 09' 39.35"
W 78' 45' 23.77"
341.88
343.88
2.12
8.52
23.52
23.52
17.00
Bedrock
Fractured
MW-6
N 36° 09' 47.00"
W 78° 45' 25.47"
360.80
362.53
2.00
17.63
32.63
32.63
21.20
Bedrock
Fractured
NES-1
N 36° 09' 35.65"
W 78° 45' 31.59"
326.22
328.40
2.50
15.00
32.80
32.80
26.00
Bedrock
Notes:
Well information obtained from LaBella 2021 Water Quality Monitoring Report
ft = feet; AMSL = above mean sea level
AGS = above ground surface
BTOC = below top of casing
Table 1 (Page 1 of
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Table 2
Summary of Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Total Depth
ft BTOC
( )
TOC Elevation
ft AMSL
( )
September 28, 2022
Depth to
Groundwater
(ft BTOC)
Groundwater Elevation
(ft AMSL)
MW-1 R
56.00
460.51
46.31
414.20
MW-2R
18.85
331.60
3.12
328.48
MW-3R
35.83
330.96
3.53
327.43
MW-4
31.43
340.80
9.68
331.12
MW-5
23.52
343.88
16.26
327.62
MW-6
32.63
362.53
14.94
347.59
N ES-1
32.80
328.40
20.86
307.54
Notes:
ft = feet; AMSL = above mean sea level
BTOC = Feet below top of casing
Table 2 (Page 1 of 1)
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Table 3
Summary of Field Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Sample ID
Sample Date
Field Parameter
Result
Unit
Groundwater
MW-1R
9/29/2022
pH
5.98
S.U.
Temperature
Conductivity
15.9
°C
77.9
PS/cm
Turbidity
10.8
NTU
Dissolved Oxygen
4.72
mg/L
ORP
206.1
mV
MW-2R
9/28/2022
pH
6.38
S.U.
Temperature
17.8
°C
Conductivity
2,016
PS/cm
Turbidity
<0.02
NTU
Dissolved Oxygen
0.29
mg/L
ORP
-84.7
mV
MW-3R
9/28/2022
pH
6.70
S.U.
Temperature
17.8
°C
Conductivity
1,590
PS/cm
Turbidity
<0.02
NTU
Dissolved Oxygen
0.18
mg/L
ORP
-52.2
mV
MW-4
9/28/2022
pH
6.36
S.U.
Temperature
17.77
°C
Conductivity
1,667
PS/cm
Turbidity
0.05
NTU
Dissolved Oxygen
0.50
mg/L
ORP
40.8
mV
MW-5
9/28/2022
pH
6.96
S.U.
Temperature
17.23
°C
Conductivity
1,391
PS/cm
Turbidity
7.51
NTU
Dissolved Oxygen
0.30
mg/L
ORP
-42.1
mV
MW-6
9/28/2022
pH
6.95
S.U.
Temperature
17.2
°C
Conductivity
684
PS/cm
Turbidity
<0.02
NTU
Dissolved Oxygen
0.47
mg/L
ORP
41.6
mV
NES-1
9/28/2022
pH
4.88
S.U.
Temperature
16.69
°C
Conductivity
184
PS/cm
Turbidity
4.66
NTU
Dissolved Oxygen
0.51
mg/L
ORP
139.1
mV
Surface Water
SW-1
9/28/2022
Not Sampled (DRY)
SW-2
9/28/2022
pH
7.34
S.U.
Temperature
17.0
°C
Conductivity
1,708
NS/cm
Turbidity
8.56
NTU
Dissolved Oxygen
1.50
mg/L
ORP
10.2
mV
Notes:
S.U. = standard units; °C = degrees Celsius; pS/cm = microsiemens per centimeter
NTU = nephelometric turbidity unit; mg/L = milligrams per liter; mV = millivolts
ORP = oxidation reduction potential
Table 3 (Page 1 of 1)
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Table 4
Summary of Groundwater Flow Velocity
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Hydraulic
Conductivity (ft/day)
Groundwater
Elevation
(ft AMSL)
Reference
Elevation
(ft AMSL)
Delta
Elevation
(ft)
Map Length
(ft)
Hydraulic
Gradient (ft/ft)
Effective
Porosity ��>
Groundwater
Flow Velocity
(ft/day)
Groundwater
Flow Velocity
(ft/year)
MW-1 R
6.18E-02
414.20
400.00
14.20
251.80
0.056
0.18
0.019
7.07
MW-2R
6.18E-02
328.48
320.00
8.48
160.67
0.053
0.18
0.018
6.61
MW-3R
6.18E-02
327.43
320.00
7.43
155.72
0.048
0.18
0.016
5.98
MW-4
6.18E-02
331.12
320.00
11.12
205.07
0.054
0.18
0.019
6.80
MW-5
6.18E-02
327.62
340.00
12.38
461.62
0.027
0.18
0.009
3.36
MW-6
6.18E-02
347.59
340.00
7.59
1 309.40
0.025
0.18
0.008
3.07
NES-1
6.18E-02
307.54
320.00
12.46
214.11
0.058
0.18
0.020
7.29
Minimum
--
--
--
--
0.025
--
0.008
3.07
Maximum
--
--
--
--
0.058
--
0.020
7.29
Geometric Mean
--
--
--
--
0.044
--
0.015
5.45
Notes:
1) Hydraulic conductivity and porosity values used from Labella Associates Water Quality Monitoring Report - February 2021 Event.
ft = feet; ft/day = feet per day; ft/year = feet per year
AMSL = feet above mean sea level; -- = not applicable
Vx = (K/ne) x dh/dl
Vx = groundwater flow velocity
K = hydraulic conductivity
ne = effective porosity
dh/dl = hydraulic gradient
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Table 5
Summary of Constituent Detections
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter I')
Result (µg/L)
Standard
(Ng/L)
Source )2 & 3)
Groundwater
MW-1R
9/29/2022
No Constituents Detected
MW-2R
9/28/2022
1 ,2-Dichlorobenzene
1.2
20
INC 2L
1,4-Dioxane
rBarium
98.7
3
INC 2L
110
700
INC 2L
Benzene
1.9
1
INC 2L
Cadmium
0.54 J
2
INC 2L
Chlorobenzene
15.4
50
INC 2L
Cobalt
17.0
1
INC 2L
Naphthalene
3.6
6
INC 2L
Nickel
101
100
INC 2L
Selenium
4.9 J
20
INC 2L
Tin
52.1
2,000
INC 2L
Trichlorofluoromethane
1.4
2,000
INC 2L
MW-3R
9/28/2022
1,2-Dichlorobenzene
1.3
20
INC 2L
1,4-Dioxane
59.0
3
INC 2L
Barium
79.5
700
INC 2L
Benzene
0.47 J
1
INC 2L
Chlorobenzene
17.7
50
INC 2L
Cobalt
7.7
1
INC 2L
Nickel
31.0
100
INC 2L
Tin
34.8
2,000
INC 2L
Vinyl chloride
0.72 J
0.03
INC 2L
MW-4
9/28/2022
1,4-Dioxane
40.7
3
INC 2L
Benzene
0.37 J
1
INC 2L
Cadmium
0.67 J
2
INC 2L
Cobalt
11.8
1
INC 2L
Nickel
15.2
100
INC 2L
Tin
20.8
2,000
INC 2L
MW-5
9/28/2022
1,4-Dioxane
7.8
3
INC 2L
Barium
42.5
700
INC 2L
Cadmium
0.94 J
2
INC 2L
Cobalt
37.9
1
INC 2L
Nickel
10.9
100
INC 2L
Tin
14.6
2,000
INC 2L
MW-6
9/28/2022
Tin
11.6
2,000
INC 2L
NES-1
9/28/2022
1,4-Dioxane
0.92 J
3
INC 2L
Surface Water
SW-1
9/28/2022
Not Sampled (DRY)
SW-2
9/28/2022
1,4-Dioxane
54.5
0.35
ISTV�4)
Barium
144
1,000
INC 2B
Cobalt
10.7
3
ISTV �4)
Nickel
46.6
25
INC 2B
Hardness
789,000
100,000
INC 2B
Notes:
1. VOCs analyzed by EPA Methods 8260/8260 SIM and metals analyzed by EPA Methods 6010/6020
2. INC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022.
3. 15A NCAC 213 Water Quality Standards (26 Standards) for Surface Water (Class WS IV,
nutrient sensitive waters [NSW]) dated July 26, 2021.
4. No 2B Standard established, value shown is North Carolina In -Stream Target Value for Surface Water (ISTV).
Bold concentrations exceed the INC 2L Standard for groundwater or INC 2B Standard for surface water.
VOCs = volatile organic compounds; SIM = select ion monitoring
pg/L = micrograms per liter; -- = not applicable
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Table 6
Summary of Monitored Natural Attenuation Parameters
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Well ID
Sample Date
Parameter
Result
(µ9/L)
Standard
(µ9/L)
MW-2R
9/28/2022
Chloride
191,000
250,000
MW-3R
9/28/2022
150,000
250,000
MW-2R
9/28/2022
Sulfate
<1,000
250,000
MW-3R
9/28/2022
<1,000
250,000
MW-2R
9/28/2022
Nitrogen, Nitrate
<100
10,000
MW-3R
9/28/2022
<100
10,000
MW-2R
9/28/2022
Methane
2,300
NE
MW-3R
9/28/2022
270
NE
MW-2R
9/28/2022
Alkalinity
864,000
NE
MW-3R
9/28/2022
792,000
NE
MW-2R
9/28/2022
Ferrous Iron
7,000
NE
MW-3R
9/28/2022
500
NE
MW-2R
9/28/2022
Biological Oxygen Demand
(5 Day)
6,100 B3
NE
MW-3R
9/28/2022
<2,000
NE
MW-2R
9/28/2022
Chemical Oxygen Demand
119,000
NE
MW-3R
9/28/2022
49,300
NE
MW-2R
9/28/2022
Total Organic Carbon
26,400
NE
MW-3R
9/28/2022
8,300
NE
Notes:
1. NC 2L Standards are the Title 15A NCAC 02L .0202 Groundwater Standards dated April 1, 2022
ug/L = micrograms per liter; NS = Not Sampled; ND = Not Detected; Not Established
B3 = The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L.
Table 6 (Page 1 of 1)
Hart & Hickman, PC
https://harthick.sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Tables 1-6

PROPERTY BOUNDARY
APPROXIMATE
LIMITS OF WASTE
USGS-The National Map: National Boundaries Dataset, 3DEP Elevation
Program, Geographic Names Information System, National Hydrography
Dataset, National Land Cover Database, National Structures Dataset, and
National Transportation Dataset; USGS Global Ecosystems; U.S. Census
Bureau TIGER/Line data; USFS Road Data; Natural Earth Data; U.S.
Department of State Humanitarian Information Unit; and NOAA National
Centers for Environmental Information, U.S. Coastal Relief Model.• Data
refreshed August, 2021.
0 2,000 4,000
Niiii
SCALE IN FEET
U.S.G.S. QUADRANGLE MAP
LAKE MICHIE, NORTH CAROLINA 2019
3 QUADRANGLE
7.5 MINUTE SERIES (TOPOGRAPHIC)

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Appendix A
Groundwater and Surface Water Sampling Records
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Job No: . M i • Q 3
Well ID: M
Well Location: t5 yfy'k y-r r/L
Facility Name: W Y t-aOA6\ j Date: 91Z9122
Top of Casing Elevation (ft msl): Casing Material: Pvc, Volume of Water Per Well Volume: gallons
Total Well Depth (ftTOC): 5 Depth to Water (ftTOC):_�q �0. 3 Well Diameter: L
Sampling Personnel: H.WcklsScreen Interval (ftTOC):
Type of Pump,.. P tit Tubing Material: D , Pump/Tubing set at: '" �� ft
Weather Conditions: M U . (-r" F NOTES: 1� co I cum) tgC
�L �fn1YlC,_ `V )(('DELL[.j, 1�l�15
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +1- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
Water Volume Pumping DO Temp.
Level Pumped Rate -ir
lCsDO 00 �1 L t;i%t,I1-1
� q
Vi �11� I la .
L. 1'7 Lo4D tw.l. s i In �55
l� -� it 5? I{�I�.0
/ LO 7 )15 i0 S
ISZS tom"L 110377I If.,�
IIS5�r,] ML
to N IQ PAL 16),% `}.�Z IS•q
Cw�i� I,q��l' TtAt'btc�l�
Other Sample Parameters:
S. Cond.
pH
ORP
Turbidity
(US/cm)
(§U)
mV
NTU
71• 1
5•
7 6
)q?"
) 7i
7-
I fa
-A&
jY7
15.0
5
1c1c1q. U
Z
es
r �
� 5
`15• ��
177 1
97. !
?5, S
5. R
G
Z-Q 13
54 . s
1,
5j.
77-H
17.9
r
9.0510
En. f
CfI_.01
Sampled at: 11 71; Parameters taken with: � `> I I ;Aci
Sample Delivered to:--? �� C_.E ALLY1i EQ Y 1 11 f by at
Field Filtration: Q Yes E) No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): a[ j
'S:IBBB Master TemplatesTorms- 2022 FormslLow Flow Groundwater Sampling Form.pdr' Stabilization crileria guidelines from the EPA SESD Operating
Last Updated: 2/1412022 Procedure for Groundwater Sampling, dated April 26, 2017.
:4

_ Stabilization Criteria
hart ?"=J hickman
Primary: Secondary:
`y
+/- 0.1 DO
7� �� 3
pH unit +/- 0.2 mg/L
Job No: •
SMARTER ENVIRONMENTAL SOLUTIONS S. Cond. +/- 5% ORP +/- 20 mV
LOW -FLOW GROUNDWATER Turb. +/- 10% (<10 NTUs for metals)
Well ID: el.) Z
Water Level: slight or stable
SAMPLING RECORD drawdown during purging
Well Location: -5L-Ar.v K2C.
Facility Name: &' Vi, [ � �—Cry
Date: SA/-Zz
Top of Casing Elevation (ft msl): Casing Material: QVC, Volume of Water Per Well Volume:
gallons
Total Well Depth (ftTOC): 1 %p' ( -0 "4*!13tdth to Water (ftTOC): �. �
Well Diameter: 2u
Sampling Personnel: cj7V4 _4__7
Screen Interval (ftTOC): 1.1 -
Type of Pump: �CIk.�I Tubing Material: a�i�!%L
Pump/Tubing set at:
ft
Weather Conditions: C/e.L . ,,-7o"
NOTES: /°1A­'0U1t,A IS MI L65—
e
0jrL
GROUNDWATER SAMPLING PARAMETERS
Water Volume Pumping DO Temp.
S. Cond. pH ❑RP
Turbidity
Time Level Pumped Rate (mo fll(US/cm)
(SU) Ll
(NT_U)
1S11\ l -7 t /6 LIVn 1.-77 17. r3
2, v -, Z "g7 - 97, FS
,
k SnUQ�7z"On.L f 1. /s /8,o
Z.030 G,.3IT -&.e,
1�3 �•�7 1S-� 6.4% 17.q
2,:,-�� �.3 -135'.'-
6.atS
o- 7 7 .L��
� a� _ 911f. 9
L CAL �� " f3. ? 17. I;r
7, o16 ,6a," - 911.:
le Parameters:
Other Sam �� ._iro n _
Sampled at: rZ//
1_1 i0 __ Parameters taken with: S'� � . ��;
+ "a,." -tea �.,rL,+` ; sty
Ltt,!4
Sample Delivered to:_F&_G N k by RQiw
at
Field Filtration: Q Yes Q No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives). flocs
F
L'x
J J G� �'Worti L fl r.0 •V n A
EEC VL+b BrV t_
"SMBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

Sty
sex9•�r�.�
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Facility Name: f Zr'n.,r {"J-r- tf
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Job No: 6/h ! . 0o'3
Turb. +/- 10% (<10 NTUs for metals) Well ID: A W — � 1\
Water Level: slight or stable
drawdown during purging Well Location: •}- - /[J c
Date:
Top of Casing Elevation (ft msi):
Casing Material: 1. lll.� Volume of Water Per Well Volume:
gallons
Total Well Depth (ftTOC): 3s' (:9-7 tqj'A epth to Water (ftTOC): • ,53
Well Diameter:
IL
Sampling Personnel: C
I
Screen Interval (ftTOC): 2
3T—
Type of Pump: F�'tk. , ] �
Tubing Material: t. PFF
Pump/Tubing set at:
ft
Weather Conditions: 4_ow, ^'
v�
NOTES: 1 eeLGJ ; �'n �.,Pf1
�'f �- ���..�4-i
GROUNDWATER SAMPLING PARAMETERS
Water Volume
Pumping DO Temp.
S. Cond. pH
ORP
Turbidity
Time Level Pumped
Rate {m m °C°C]Gkslcm
5U
I 7
mV
(NTU)
r.�912- - [' -L,
GrI
05 r;- C�'
ISL't. s��Q +Zv0.
[S7_7 5. 37 t7so
17.6
/-1•
r, 'T7z 71
I. "z
11.
3
c c
6.
CA
5.. 2276c,
for� 1
. "76
- IL
Other Sample Parameters: +V6�J.I1`
Sampled at: Parameters taken with: t- PM-4- ICJ°" `f;JL.- �ro
Sample Delivered to:!"I.,e, NlUc✓4M- by F at
Field Filtration: o Yes Q No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): oocs x Y/€tGl ltc s d'
hs'o-L Pa)v "'Vft41 &4'4 _ [ tgtc VAS te- (& v..s, rk.c . t.,;I) 1M 0L &,k,, %,xr-6)i
aJt �_ �.�ldk� ,_., 7 s�t� [�� l; (.�/�t. JviY
"S:\BBB Master Templates\Fors - 2022 Forms\Low Flow Groundwater Sampling For.pdr'
Last Updated: 2/1412022
Stabilization cntena guiceimes from rile LFA btsu uperanng
Procedure for Groundwater Sampling, dated April 26. 2017.

__ M.
Stabilization Criteria
hart ` =may hickman
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
Job No: Glhr• D,n
zK
SMARTER ENVIRONMENTAL SOLUTIONS
S. Cond. +/- 5% ORP +/- 20 mV
-
LOW -FLOW GROUNDWATER
Turb. +/- 10% (<10 NTUs for metals)
Well ID: rA y
SAMPLING RECORD
Water Level: slight or stable
drawdown during purging
Well Location: Sip P-r
NC
Facility Name:
Date: 9/'Z
Top of Casing Elevation (ft msl).
Casing Material: P4C Volume of Water Per Well Volume:
gallons
Total Well Depth (ftTOC): 3a, DFi
Depth to Water (ftTOC): Ice
Well Diameter:
02
Sampling Personnel:. M
Screen Interval (ftTOC):
Type of Pump:
Tubing Material: LDPE
Pump/Tubing set at
�' 30. 0 ft
Weather Conditions: .io jv rog6 F
NOTES:
GROUNDWATER SAMPLING PARAMETERS
Water Volume
Pumping DO Temp.
S. Cond. pH
ORP Turbidity
Time Level Pumped
Rate (rr gr� �C)
uSlcm (SU)
(MV) NNTU)
IS - 5
15; 5Q p.S L
"'� n 1_ Ig. R.4
163
3.3�
0ID.5'7—
: s.110IDR.
15 5 � 4 1 4 L
a 0' - W" a Q7 1V oT
BSI 6. 30
77,.� _ �. qC
14: ob I I SR L6 L
iop MVq, O• f �f: 03
ISSs 3 _
6a-
;per IiZ,12 20 L
o O_G1 17.g6
j6ciz 6.3q
SP-2 �9�1
I6; to WA 1
17V
_ [6" -�1,35
'45'. 1 I. al
EC, 1S 13.42r 3.QL
100 "` wr'n 0-.5 17,177
IF97 36--
40.0
Other Sample Parameters: N` R
Sampled aL 1c: 15
Parameters taken with. r 5
!K,r_r0-FP\4
T rdr is
Sample Delivered to,
_ by _ -
at
Field Filtration: QYes O No If yes, which sample parameters were field filtered:
-N/A
Sample Parameter Containers (Types, Number of Containers, Preservatives): MAJ&
by 40 [JD I r rnL_ Cleo, Poi I D-z P �
►�! - ' ox 6� '�D
G4 G� �'s .
�n
G tSd60 3 �e� G C� 4G VD H F
.S:\BBB Master TemplatesTorms - 2022 Farms\Law Flow Groundwater Sampling Form pdf' Stabilization criteria guidelines from the EVA StSU Uperating
Last Updated: 2114/2022 Procedure for Groundwater Sampling, dated April 26. 2017.

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
,lob No: GMT, pD3
Well ID: Mw-S
Well Location: JtVt f f
FacilityName: &An-er "Pill
Top of Casing Elevation (ft msl):
Total Well Depth (ftTOC):
Sampling Personnel_ tT''fTM
Type of Pump: i�p iJo1TZC., _
Weather Conditions: a
Date: 1AS, Az
Casing Material: P►G Volume of Water Per Well Volume:
Depth to Water (ftTOC): Well Diameter: e2 ;AC�grS
Screen Interval (ftTOC):
Tubing Material:_ �DP� _ Pump/Tubing set at: ^'
NOTES:
gallons
ft
GROUNDWATER SAMPLING PARAMETERS
Water Volume
Pumping ❑O Temp.
S. Cond. pH
ORP
Turbidity
Time Level Pumped
Pumped
Rate {mgllj �
([is/cm)(SU)
(mom
LMTU�
VI D . a b Q L-
r —
^
--�
0:4 I 5 C.5 L
IDo OIL Z97 I7LIu _
,�3
f
1T7;S5 16.{d I Is L
Iccoo L
loh n -w D.46 _ 17.21E
12,91 GAS
_go`
. D
: CO M'� 13 ¢. s i-
100 ,n) p, 4 3 I . .2-3
8"53
4� �. 9s
o
C1 � qO_
1 _
14S;1a 1�1,�c 3.fl
0'0 -k 17. l a
tt*
1340 —G.
LIZ s
71
»ark Q.3�— 1`7�R3
13g1_ C.96
— 2..1
Other Sample Parameters: al .._ _
Sampled at:
Parameters taken with: YSS S-6c
Mt'S M� r'---rr'^r
Turbtdt er
Sample Delivered to:
by
at
Field Filtration: OYes O No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number
of Containers, Preservative`sr)+: Nj
[ L
{{ Ncy6n' 1JT �►Z�❑ l3 5C �ml_
rlr� r CAI,, VDA5 14CL P142j,
� iXs �tj & 40 f 3 xA,b
t4g:ss VLY'l-<
CI, pt�S)
"5:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS
LOW -FLOW GROUNDWATER
SAMPLING RECORD
Job No: A-r - © 03
Well ID: e�1�,)
Well Location:
Facility Name: Buk , r- Date: 2,28/-7 -7-
Top of Casing Elevation (ft msl): Casing Material: WC, _ Volume of Water Per Well Volume: gallons
i L(
Total Well Depth (ftTOC): -` ••1. �� pia De h to Water (ftTOC):. ` 1 Well Diameter: 2
Sampling Personnel: L- C "I Screen Interval (ftTOC): % 1, 7 - 2 i. 7
Type of Pump: T z-N-t'43\;., I Tubing Material: Pump/Tubing set at: Z 3 ft
Weather Conditions: C A.L. 7Ly NOTES: a
Stabilization Criteria
Primary: Secondary:
pH +1- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Turb. +/- 10% (<10 NTUs for metals)
Water Level: slight or stable
drawdown during purging
GROUNDWATER SAMPLING PARAMETERS
Water Volume Pumping DO Temp. S. Cond. pH ORP Turbidity
Time� Level Pumped Rate LTC tll 5/cm (SU) (MV) NTUJ
' I S• I riGnLIK.. 3� 1-;�.11 &17 G. 27 � �' `4 d5. Cd
Other Sample Parameters:
Sampled at: Parameters taken with: "0/,;. � � 2 'w '`fi�•aT �H�t+
Sample Delivered to 4,0U' by r5f A at
Field Filtration: ()Yes No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): (� �� r � 14o It Lf Aw,-, l3Y Vra„s A,-t
Afz'w S Lsu I%k w-7 W-k>3)
"S:\BBB Master Templates\Forms - 2022 Forms\Low Flow Groundwater Sampling Form.pdf' Staomzanon criteria guaeones trom the erH beau uperaung
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

A
hart i-= hickman
1.
SMARTER ENVIRONMENTAL SOLUTIONS
Stabilization Criteria
Primary: Secondary:
pH +/- 0.1 unit DO +/- 0.2 mg/L
S. Cond. +/- 5% ORP +/- 20 mV
Job No: 00
LOW -FLOW GROUNDWATER Turb. +/- 10% (<10 NTLIs for metals) Well ID: NES _ J
Water Level: slight or stable
SAMPLING RECORD drawdown during purging Well Location: RAI-Pr NC,
Facility Name: 1 Date: C� /� �.ZD t.
Top of Casing Elevation (isl): Casing Materlal: PVC, Volume of Water Per Well Volume. gallons
Total Well Depth (ftTOC). fP-.If- 33.IDDepth to Water (ftTOC):_ Well Diameter: 02 AC6 -
Sampling Personnel: Z:5 m _ Screen Interval (ftTOC): /S 33_ I'B
Type of Pump: p i53a��t� Tubing Material: L-DP� Pump/Tubing set at: ^' 3D-0 ft
Weather Conditions:pts�v ra� l= NOTES:
GROUNDWATER SAMPLING PARAMETERS
Water
Volume
Pumping DO
Temp,
S. Cond.
pH
❑RP
Turbidity
Time Level
Pumped
Rate m 11
C-C)
LtS/cm
SSU1
(rnV)
N( _TUB
13.E u�
❑L
13 1(, 091
O.S L
JD❑ rr n I.�1
I`7.(1
�1�
��
3
[ -ys
h3,25 , v7
1. D L
Irmo
116
$!
6-0. 3
u _
1� 34 2
f.S L
loa ""1' W1 [)-a�6.?6
�85
t
—
13� 2 ;3 oCi _ 35
2-0 �-
/DD M nin f j
I(0.6C
I`
3: 0 At'4Z_
�
I Da �"'� 5l -
16. 61k
[F�q
4.i€18r
134, t
q L CG
Other Sample Parameters:- __tJ-%il!
Sampled at:_
Parameters taken with.
YS-T S-SIG
MP5 l R't'
Ic —Fp\j
7rbj nllitr
016
Sample Delivered to:
by
at
Field Filtration: ©Yes O
No If yes, which sample parameters were field filtered:
fU
Sample Parameter Containers
(Types, Number of Containers, Preservatives): Mejo15 by
CD10 / x
oZ5D M� i
f�NO �
4-Diox�ne D
3 u4�
L r I HC.1-
a6�
3"it
C�css
-CG
"SABBB Master Templateffonns - 2022 Forms\Low Flow Groundwater Sampling Form pdr' Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

Stabilization Criteria
hart hickman
Primary: Secondary:
®a
pH +/- 0.1 unit DO +/- 0.2 mg/L
Job No:�®
SMARTER ENVIRONMENTAL SOLUTIONS
S. Cond. +/- 5% ORP +/- 20 mV
LOW -FLOW GROUNDWATER
Turb. +/- 10% (<10 NTUs for metals)
Well ID:��_
fJcr, Sc,.�LGS
SAMPLING RECORD
Water Level: slight or stable
drawdown during purging
Well Location:
/U
Facility Name: r ;k� U
Date:
? 2
Top of Casing Elevation (ft msl):
Casing Material — . _ _ _ _ Volume
of Water Per Well Volume: gallons
Total Well Depth (ftTOC): Depth to Water (ftTOC): Well Diameter:
Sampling Personnel: Screen Interval (ftTOC): - —
Type of Pump: Tubing Material: Pump/Tubing set at: ft
Weather Conditions: 6 m,. " '7vaF NOTES:
Y
GROUNDWATER SAMPLING PARAMETERS
-Jil~ Volume Pumping DO Temp. S. Cond. pH ❑RP Turbidity
Time _LeV9 Pumped Rate (mQ/1) CC)(US/cm LSD (MV) ��
Other Sample Parameters:
Sampled at: Parameters taken with: �`1 Z �� �I..3 [ +u �, _r Tf.1 ftt)
Sample Delivered to: C.f'g L0, by _ �F� at
Field Filtration: © Yes 0 No If yes, which sample parameters were field filtered:
Sample Parameter Containers (Types, Number of Containers, Preservatives): Veems (, 5"<, 1.-4IAL f, I- A-u SKyrA , C t
_V NJIIA�11 � 1"4b NL vi:1,, wy'7al
"SABBB Master TemplateslForms - 2022 Forms\Low Flow Groundwater Sampling Form.pdr, Stabilization criteria guidelines from the EPA SESD Operating
Last Updated: 2/14/2022 Procedure for Groundwater Sampling, dated April 26, 2017.

Appendix B
Laboratory Analytical Reports
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 01, 2022
Jeffrey 011ison
Hart & Hickman
3921 Sunset Ridge Rd.
Ste. 301
Raleigh, NC 27607
RE: Project: GM1.003
Pace Project No.: 92628331
Dear Jeffrey 011ison:
Enclosed are the analytical results for sample(s) received by the laboratory on September 29, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
A revised laboratory report is being submitted on 11/1/22 to report MDLs and applicable J values, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Taylor M Cannon
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
r
e
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: GM1.003
Pace Project No.: 92628331
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification #: 6429-01
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification #: 618
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: GM1.003
Pace Project No.: 92628331
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92628331001
MW-2R
Water
09/28/2213:46
09/29/22 10:30
92628331002
MW-3R
Water
09/28/2215:37
09/29/22 10:30
92628331003
MW-4
Water
09/28/2216:15
09/29/22 10:30
92628331004
MW-5
Water
09/28/2218:10
09/29/22 10:30
92628331005
MW-6
Water
09/28/22 18:29
09/29/22 10:30
92628331006
SW-2
Water
09/28/2211:55
09/29/22 10:30
92628331007
FIELD BLANK
Water
09/28/22 19:15
09/29/22 10:30
92628331008
TRIP BLANK
Water
09/28/22 00:00
09/29/22 10:30
92628331009
TRIP BLANK
Water
09/28/22 00:00
09/29/22 10:30
92628331010
NES-1
Water
09/28/2213:40
09/29/22 10:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
GM1.003
92628331
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92628331001
MW-2R
RSK-175
LMB
1
GCLA
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 5210B-2011
TFD
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
3
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92628331002
MW-3R
RSK-175
LMB
1
GCLA
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 5210B-2011
TFD
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
3
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 5310B-2014
MJP
1
PASI-A
92628331003
MW-4
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92628331004
MW-5
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92628331005
MW-6
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92628331006
SW-2
EPA 6010D
DEC, RDT,
15
PASI-A
SBW
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
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lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: GM1.003
Pace Project No.: 92628331
Analytes
Lab lD Sample ID
Method
Analysts
Reported
Laboratory
92628331007 FIELD BLANK
EPA 6010D
DEC, RDT
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
SAS
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92628331008 TRIP BLANK
EPA 8260D
SAS
51
PASI-C
92628331009 TRIP BLANK
EPA 8260D Mod.
LMB
3
PASI-C
92628331010 NES-1
EPA 6010D
DEC, RDT
14
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
LMB
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
GCLA = Pace Analytical Gulf Coast
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-2R
Lab ID:
92628331001
Collected:
09/28/22 13:46
Received: 09/29/22 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Biodegradation Indicator Gases
Analytical
Method: RSK-175
Pace Analytical
Gulf Coast
Methane
2300
ug/L
5.0
2.0
1
10/05/22 08:38
74-82-8
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method:
EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2218:42
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:26
7440-38-2
Barium
110
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2218:42
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2218:42
7440-41-7
Cadmium
0.54J
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2218:42
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/05/2218:42
7440-47-3
Cobalt
17.0
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2218:42
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2218:42
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 20:26
7439-92-1
Nickel
101
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2218:42
7440-02-0
Selenium
4.9J
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:26
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2218:42
7440-22-4
Tin
52.1
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2218:42
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2218:42
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2218:42
7440-66-6
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND ug/L 2.4 0.25 5 10/04/22 09:27 10/05/22 01:54 7440-28-0 D3
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
1.9
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
15.4
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
1.2
ug/L
1.0
5.1
1
10/01/22 05:34
67-64-1
1.8
1
10/01/22 05:34
107-13-1
0.34
1
10/01/22 05:34
71-43-2
0.47
1
10/01/22 05:34
74-97-5
0.31
1
10/01/22 05:34
75-27-4
0.34
1
10/01/22 05:34
75-25-2
1.7
1
10/01/22 05:34
74-83-9
4.0
1
10/01/22 05:34
78-93-3
0.36
1
10/01/22 05:34
75-15-0
0.33
1
10/01/22 05:34
56-23-5
0.28
1
10/01/22 05:34
108-90-7
0.65
1
10/01/22 05:34
75-00-3
0.43
1
10/01/22 05:34
67-66-3
0.54
1
10/01/22 05:34
74-87-3
0.34
1
10/01/22 05:34
96-12-8
0.36
1
10/01/22 05:34
124-48-1
0.27
1
10/01/22 05:34
106-93-4
0.39
1
10/01/22 05:34
74-95-3
0.34
1
10/01/22 05:34
95-50-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,v1
Page 6 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-2R Lab ID: 92628331001 Collected: 09/28/22 13:46 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.33
1
10/01/22 05:34
106-46-7
ND
ug/L
1.0
0.56
1
10/01/22 05:34
110-57-6
ND
ug/L
1.0
0.37
1
10/01/22 05:34
75-34-3
ND
ug/L
1.0
0.32
1
10/01/22 05:34
107-06-2
ND
ug/L
1.0
0.35
1
10/01/22 05:34
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 05:34
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 05:34
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 05:34
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 05:34
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 05:34
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 05:34
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 05:34
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 05:34
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 05:34
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 05:34
108-10-1
3.6
ug/L
1.0
0.64
1
10/01/22 05:34
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 05:34
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 05:34
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 05:34
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 05:34
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 05:34
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 05:34
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 05:34
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 05:34
79-01-6
1.4
ug/L
1.0
0.30
1
10/01/22 05:34
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 05:34
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 05:34
108-05-4
ND
ug/L
1.0
0.39
1
10/01/22 05:34
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 05:34
1330-20-7
97
%
70-130
1
10/01/22 05:34
460-00-4
112
%
70-130
1
10/01/22 05:34
17060-07-0
108
%
70-130
1
10/01/22 05:34
2037-26-5
Analytical
Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
98.7
ug/L
2.0
0.86
1
09/30/2212:24
123-91-1
88
%
70-130
1
09/30/2212:24
17060-07-0
100
%
70-130
1
09/30/2212:24
2037-26-5
Analytical
Method: SM 2320B-2011
Pace Analytical Services
-Asheville
864
mg/L
5.0
5.0
1
10/01/2218:54
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 7 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-2R
Lab ID: 92628331001 Collected:
09/28/22 13:46
Received: 09/29/22 10:30 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
6.1 mg/L 2.0
2.0
1
09/29/22 19:13 10/04/22 12:58
B3
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
191 mg/L 4.0
2.4
4
09/29/2216:49
16887-00-6
Nitrate as N
ND mg/L 0.10
0.060
1
09/29/22 15:50
14797-55-8
Sulfate
ND mg/L 1.0
0.50
1
09/29/2215:50
14808-79-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
119 mg/L 25.0
12.5
1
09/30/22 14:33 09/30/22 17:38
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
26.4 mg/L 1.0
0.50
1
10/03/22 16:40
7440-44-0
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 54

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-3R
Lab ID:
92628331002
Collected:
09/28/22 15:37
Received: 09/29/22 10:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Biodegradation Indicator Gases
Analytical
Method: RSK-175
Pace Analytical
Gulf Coast
Methane
270
ug/L
5.0
2.0
1
10/05/22 08:49
74-82-8
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method:
EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:03
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:40
7440-38-2
Barium
79.5
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:03
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:03
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:03
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 20:40
7440-47-3
Cobalt
7.7
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:03
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:03
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 20:40
7439-92-1
Nickel
31.0
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:03
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:40
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:03
7440-22-4
Tin
34.8
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2219:03
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:03
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:03
7440-66-6
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND ug/L 0.47 0.050 1 10/04/22 09:27 10/07/22 00:09 7440-28-0
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
10.0
0.47J
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
17.7
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
1.3
ug/L
1.0
5.1
1
10/01/22 05:52
67-64-1
1.8
1
10/01/22 05:52
107-13-1
0.34
1
10/01/22 05:52
71-43-2
0.47
1
10/01/22 05:52
74-97-5
0.31
1
10/01/22 05:52
75-27-4
0.34
1
10/01/22 05:52
75-25-2
1.7
1
10/01/22 05:52
74-83-9
4.0
1
10/01/22 05:52
78-93-3
0.36
1
10/01/22 05:52
75-15-0
0.33
1
10/01/22 05:52
56-23-5
0.28
1
10/01/22 05:52
108-90-7
0.65
1
10/01/22 05:52
75-00-3
0.43
1
10/01/22 05:52
67-66-3
0.54
1
10/01/22 05:52
74-87-3
0.34
1
10/01/22 05:52
96-12-8
0.36
1
10/01/22 05:52
124-48-1
0.27
1
10/01/22 05:52
106-93-4
0.39
1
10/01/22 05:52
74-95-3
0.34
1
10/01/22 05:52
95-50-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK
Page 9 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-3R Lab ID: 92628331002 Collected: 09/28/22 15:37 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.33
1
10/01/22 05:52
106-46-7
ND
ug/L
1.0
0.56
1
10/01/22 05:52
110-57-6
ND
ug/L
1.0
0.37
1
10/01/22 05:52
75-34-3
ND
ug/L
1.0
0.32
1
10/01/22 05:52
107-06-2
ND
ug/L
1.0
0.35
1
10/01/22 05:52
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 05:52
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 05:52
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 05:52
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 05:52
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 05:52
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 05:52
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 05:52
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 05:52
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 05:52
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 05:52
108-10-1
ND
ug/L
1.0
0.64
1
10/01/22 05:52
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 05:52
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 05:52
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 05:52
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 05:52
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 05:52
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 05:52
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 05:52
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 05:52
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 05:52
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 05:52
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 05:52
108-05-4
0.72.11
ug/L
1.0
0.39
1
10/01/22 05:52
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 05:52
1330-20-7
96
%
70-130
1
10/01/22 05:52
460-00-4
115
%
70-130
1
10/01/22 05:52
17060-07-0
106
%
70-130
1
10/01/22 05:52
2037-26-5
Analytical
Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
59.0
ug/L
2.0
0.86
1
09/30/2212:43
123-91-1
101
%
70-130
1
09/30/2212:43
17060-07-0
101
%
70-130
1
09/30/2212:43
2037-26-5
Analytical
Method: SM 2320B-2011
Pace Analytical Services
-Asheville
792
mg/L
5.0
5.0
1
10/01/22 19:04
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-3R
Lab ID: 92628331002 Collected:
09/28/22 15:37
Received: 09/29/22 10:30 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND mg/L 2.0
2.0
1
09/29/22 19:13 10/04/22 13:03
B3
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
150 mg/L 3.0
1.8
3
09/29/2217:04
16887-00-6
Nitrate as N
ND mg/L 0.10
0.060
1
09/29/22 16:05
14797-55-8
Sulfate
ND mg/L 1.0
0.50
1
09/29/2216:05
14808-79-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
49.3 mg/L 25.0
12.5
1
09/30/22 14:33 09/30/22 17:38
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
8.3 mg/L 1.0
0.50
1
10/03/22 18:16
7440-44-0
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-4 Lab ID: 92628331003 Collected: 09/28/22 16:15 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:06
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:43
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:06
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:06
7440-41-7
Cadmium
0.67J
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:06
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 20:43
7440-47-3
Cobalt
11.8
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:06
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:06
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 20:43
7439-92-1
Nickel
15.2
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:06
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:43
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:06
7440-22-4
Tin
20.8
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2219:06
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:06
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:06
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1
10/04/22 09:27
10/07/22 00:13
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/01/22 06:10
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/01/22 06:10
107-13-1
Benzene
0.37J
ug/L
1.0
0.34
1
10/01/22 06:10
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/01/22 06:10
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/01/22 06:10
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/01/22 06:10
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/01/22 06:10
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/01/22 06:10
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/01/22 06:10
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/01/22 06:10
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/01/22 06:10
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/01/22 06:10
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/01/22 06:10
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/01/22 06:10
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/01/22 06:10
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/01/22 06:10
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/01/22 06:10
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/01/22 06:10
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/01/22 06:10
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/01/22 06:10
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/01/22 06:10
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/01/22 06:10
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/01/22 06:10
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 12 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-4 Lab ID: 92628331003 Collected: 09/28/22 16:15 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/01/22 06:10
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 06:10
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 06:10
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 06:10
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 06:10
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 06:10
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 06:10
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 06:10
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 06:10
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 06:10
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 06:10
108-10-1
ND
ug/L
1.0
0.64
1
10/01/22 06:10
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 06:10
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 06:10
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 06:10
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 06:10
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 06:10
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 06:10
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 06:10
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 06:10
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 06:10
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 06:10
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 06:10
108-05-4
ND
ug/L
1.0
0.39
1
10/01/22 06:10
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 06:10
1330-20-7
96
%
70-130
1
10/01/22 06:10
460-00-4
108
%
70-130
1
10/01/22 06:10
17060-07-0
106
%
70-130
1
10/01/22 06:10
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
40.7
ug/L
2.0
0.86
1
09/30/2213:02
123-91-1
102
%
70-130
1
09/30/2213:02
17060-07-0
88
%
70-130
1
09/30/2213:02
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-5 Lab ID: 92628331004 Collected: 09/28/22 18:10 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:10
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:51
7440-38-2
Barium
42.5
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:10
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:10
7440-41-7
Cadmium
0.94J
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:10
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 20:51
7440-47-3
Cobalt
37.9
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:10
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:10
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 20:51
7439-92-1
Nickel
10.9
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:10
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:51
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:10
7440-22-4
Tin
14.6
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2219:10
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:10
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:10
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1
10/04/22 09:27
10/07/22 00:17
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/01/22 06:28
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/01/22 06:28
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/01/22 06:28
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/01/22 06:28
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/01/22 06:28
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/01/22 06:28
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/01/22 06:28
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/01/22 06:28
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/01/22 06:28
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/01/22 06:28
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/01/22 06:28
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/01/22 06:28
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/01/22 06:28
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/01/22 06:28
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/01/22 06:28
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/01/22 06:28
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/01/22 06:28
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/01/22 06:28
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/01/22 06:28
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/01/22 06:28
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/01/22 06:28
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/01/22 06:28
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/01/22 06:28
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 14 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-5 Lab ID: 92628331004 Collected: 09/28/22 18:10 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/01/22 06:28
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 06:28
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 06:28
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 06:28
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 06:28
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 06:28
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 06:28
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 06:28
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 06:28
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 06:28
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 06:28
108-10-1
ND
ug/L
1.0
0.64
1
10/01/22 06:28
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 06:28
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 06:28
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 06:28
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 06:28
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 06:28
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 06:28
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 06:28
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 06:28
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 06:28
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 06:28
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 06:28
108-05-4
ND
ug/L
1.0
0.39
1
10/01/22 06:28
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 06:28
1330-20-7
99
%
70-130
1
10/01/22 06:28
460-00-4
118
%
70-130
1
10/01/22 06:28
17060-07-0
108
%
70-130
1
10/01/22 06:28
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
7.8
ug/L
2.0
0.86
1
09/30/2213:21
123-91-1
111
%
70-130
1
09/30/2213:21
17060-07-0
112
%
70-130
1
09/30/2213:21
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-6 Lab ID: 92628331005 Collected: 09/28/22 18:29 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:13
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:55
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:13
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:13
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:13
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 20:55
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:13
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:13
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 20:55
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:13
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 20:55
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:13
7440-22-4
Tin
11.6
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2219:13
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:13
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:13
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1
10/04/22 09:27
10/07/22 00:21
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/01/22 06:46
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/01/22 06:46
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/01/22 06:46
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/01/22 06:46
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/01/22 06:46
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/01/22 06:46
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/01/22 06:46
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/01/22 06:46
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/01/22 06:46
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/01/22 06:46
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/01/22 06:46
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/01/22 06:46
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/01/22 06:46
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/01/22 06:46
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/01/22 06:46
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/01/22 06:46
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/01/22 06:46
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/01/22 06:46
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/01/22 06:46
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/01/22 06:46
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/01/22 06:46
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/01/22 06:46
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/01/22 06:46
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 16 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: MW-6 Lab ID: 92628331005 Collected: 09/28/22 18:29 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/01/22 06:46
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 06:46
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 06:46
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 06:46
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 06:46
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 06:46
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 06:46
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 06:46
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 06:46
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 06:46
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 06:46
108-10-1
ND
ug/L
1.0
0.64
1
10/01/22 06:46
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 06:46
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 06:46
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 06:46
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 06:46
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 06:46
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 06:46
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 06:46
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 06:46
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 06:46
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 06:46
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 06:46
108-05-4
ND
ug/L
1.0
0.39
1
10/01/22 06:46
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 06:46
1330-20-7
95
%
70-130
1
10/01/22 06:46
460-00-4
115
%
70-130
1
10/01/22 06:46
17060-07-0
107
%
70-130
1
10/01/22 06:46
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
0.86
1
09/30/2213:41
123-91-1
92
%
70-130
1
09/30/2213:41
17060-07-0
97
%
70-130
1
09/30/2213:41
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: SW-2 Lab ID: 92628331006 Collected: 09/28/22 11:55 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:16
7440-36-0
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:05
7440-38-2
144
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:16
7440-39-3
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:16
7440-41-7
ND
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:16
7440-43-9
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 21:05
7440-47-3
10.7
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:16
7440-48-4
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:16
7440-50-8
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 21:05
7439-92-1
46.6
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:16
7440-02-0
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:05
7782-49-2
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:16
7440-22-4
789000
ug/L
3310
655
5
10/04/22 11:42
10/07/2219:31
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:16
7440-62-2
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:16
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1 10/04/22 09:27
10/07/22 00:24
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/01/22 07:04
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/01/22 07:04
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/01/22 07:04
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/01/22 07:04
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/01/22 07:04
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/01/22 07:04
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/01/22 07:04
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/01/22 07:04
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/01/22 07:04
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/01/22 07:04
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/01/22 07:04
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/01/22 07:04
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/01/22 07:04
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/01/22 07:04
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/01/22 07:04
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/01/22 07:04
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/01/22 07:04
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/01/22 07:04
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/01/22 07:04
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/01/22 07:04
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/01/22 07:04
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/01/22 07:04
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/01/22 07:04
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 18 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: SW-2 Lab ID: 92628331006 Collected: 09/28/22 11:55 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/01/22 07:04
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 07:04
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 07:04
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 07:04
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 07:04
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 07:04
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 07:04
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 07:04
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 07:04
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 07:04
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 07:04
108-10-1
ND
ug/L
1.0
0.29
1
10/01/22 07:04
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 07:04
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 07:04
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 07:04
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 07:04
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 07:04
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 07:04
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 07:04
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 07:04
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 07:04
96-18-4
ND
ug/L
2.0
1.3
1
10/01/22 07:04
108-05-4
ND
ug/L
1.0
0.39
1
10/01/22 07:04
75-01-4
ND
ug/L
1.0
0.34
1
10/01/22 07:04
1330-20-7
98
%
70-130
1
10/01/22 07:04
460-00-4
114
%
70-130
1
10/01/22 07:04
17060-07-0
108
%
70-130
1
10/01/22 07:04
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
54.5
ug/L
2.0
0.86
1
09/30/2214:00
123-91-1
107
%
70-130
1
09/30/2214:00
17060-07-0
105
%
70-130
1
09/30/2214:00
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: FIELD BLANK Lab ID: 92628331007 Collected: 09/28/22 19:15 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:20
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:09
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:20
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:20
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:20
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 21:09
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:20
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:20
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 21:09
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:20
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:09
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:20
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
10/04/22 11:42
10/05/2219:20
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:20
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:20
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1
10/04/22 09:27
10/07/22 00:48
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/02/22 19:41
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/02/22 19:41
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/02/22 19:41
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/02/22 19:41
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/02/22 19:41
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/02/22 19:41
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/02/22 19:41
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/02/22 19:41
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/02/22 19:41
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/02/22 19:41
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/02/22 19:41
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/02/22 19:41
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/02/22 19:41
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/02/22 19:41
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/02/22 19:41
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/02/22 19:41
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/02/22 19:41
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/02/22 19:41
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/02/22 19:41
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/02/22 19:41
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/02/22 19:41
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/02/22 19:41
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/02/22 19:41
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
IK
Page 20 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: FIELD BLANK Lab ID: 92628331007 Collected: 09/28/22 19:15 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/02/2219:41
75-35-4
ND
ug/L
1.0
0.38
1
10/02/2219:41
156-59-2
ND
ug/L
1.0
0.40
1
10/02/2219:41
156-60-5
ND
ug/L
1.0
0.36
1
10/02/2219:41
78-87-5
ND
ug/L
1.0
0.36
1
10/02/22 19:41
10061-01-5
ND
ug/L
1.0
0.36
1
10/02/2219:41
10061-02-6
ND
ug/L
1.0
0.30
1
10/02/2219:41
100-41-4
ND
ug/L
5.0
0.48
1
10/02/2219:41
591-78-6
ND
ug/L
20.0
9.7
1
10/02/2219:41
74-88-4
ND
ug/L
5.0
2.0
1
10/02/2219:41
75-09-2
ND
ug/L
5.0
2.7
1
10/02/2219:41
108-10-1
ND
ug/L
1.0
0.64
1
10/02/2219:41
91-20-3
ND
ug/L
1.0
0.29
1
10/02/2219:41
100-42-5
ND
ug/L
1.0
0.31
1
10/02/2219:41
630-20-6
ND
ug/L
1.0
0.22
1
10/02/2219:41
79-34-5
ND
ug/L
1.0
0.29
1
10/02/2219:41
127-18-4
ND
ug/L
1.0
0.48
1
10/02/2219:41
108-88-3
ND
ug/L
1.0
0.33
1
10/02/2219:41
71-55-6
ND
ug/L
1.0
0.32
1
10/02/2219:41
79-00-5
ND
ug/L
1.0
0.38
1
10/02/2219:41
79-01-6
ND
ug/L
1.0
0.30
1
10/02/2219:41
75-69-4
ND
ug/L
1.0
0.26
1
10/02/2219:41
96-18-4
ND
ug/L
2.0
1.3
1
10/02/2219:41
108-05-4
ND
ug/L
1.0
0.39
1
10/02/2219:41
75-01-4
ND
ug/L
1.0
0.34
1
10/02/2219:41
1330-20-7
96
%
70-130
1
10/02/2219:41
460-00-4
117
%
70-130
1
10/02/2219:41
17060-07-0
109
%
70-130
1
10/02/2219:41
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
0.86
1
09/30/2212:05
123-91-1
97
%
70-130
1
09/30/2212:05
17060-07-0
98
%
70-130
1
09/30/2212:05
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: TRIP BLANK Lab ID: 92628331008 Collected: 09/28/22 00:00 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
10/01/22 01:22
67-64-1
ND
ug/L
10.0
1.8
1
10/01/22 01:22
107-13-1
ND
ug/L
1.0
0.34
1
10/01/22 01:22
71-43-2
ND
ug/L
1.0
0.47
1
10/01/22 01:22
74-97-5
ND
ug/L
1.0
0.31
1
10/01/22 01:22
75-27-4
ND
ug/L
1.0
0.34
1
10/01/22 01:22
75-25-2
ND
ug/L
2.0
1.7
1
10/01/22 01:22
74-83-9
ND
ug/L
5.0
4.0
1
10/01/22 01:22
78-93-3
ND
ug/L
2.0
0.36
1
10/01/22 01:22
75-15-0
ND
ug/L
1.0
0.33
1
10/01/22 01:22
56-23-5
ND
ug/L
1.0
0.28
1
10/01/22 01:22
108-90-7
ND
ug/L
1.0
0.65
1
10/01/22 01:22
75-00-3
ND
ug/L
1.0
0.43
1
10/01/22 01:22
67-66-3
ND
ug/L
1.0
0.54
1
10/01/22 01:22
74-87-3
ND
ug/L
2.0
0.34
1
10/01/22 01:22
96-12-8
ND
ug/L
1.0
0.36
1
10/01/22 01:22
124-48-1
ND
ug/L
1.0
0.27
1
10/01/22 01:22
106-93-4
ND
ug/L
1.0
0.39
1
10/01/22 01:22
74-95-3
ND
ug/L
1.0
0.34
1
10/01/22 01:22
95-50-1
ND
ug/L
1.0
0.33
1
10/01/22 01:22
106-46-7
ND
ug/L
1.0
0.56
1
10/01/22 01:22
110-57-6
ND
ug/L
1.0
0.37
1
10/01/22 01:22
75-34-3
ND
ug/L
1.0
0.32
1
10/01/22 01:22
107-06-2
ND
ug/L
1.0
0.35
1
10/01/22 01:22
75-35-4
ND
ug/L
1.0
0.38
1
10/01/22 01:22
156-59-2
ND
ug/L
1.0
0.40
1
10/01/22 01:22
156-60-5
ND
ug/L
1.0
0.36
1
10/01/22 01:22
78-87-5
ND
ug/L
1.0
0.36
1
10/01/22 01:22
10061-01-5
ND
ug/L
1.0
0.36
1
10/01/22 01:22
10061-02-6
ND
ug/L
1.0
0.30
1
10/01/22 01:22
100-41-4
ND
ug/L
5.0
0.48
1
10/01/22 01:22
591-78-6
ND
ug/L
20.0
9.7
1
10/01/22 01:22
74-88-4
ND
ug/L
5.0
2.0
1
10/01/22 01:22
75-09-2
ND
ug/L
5.0
2.7
1
10/01/22 01:22
108-10-1
ND
ug/L
1.0
0.64
1
10/01/22 01:22
91-20-3
ND
ug/L
1.0
0.29
1
10/01/22 01:22
100-42-5
ND
ug/L
1.0
0.31
1
10/01/22 01:22
630-20-6
ND
ug/L
1.0
0.22
1
10/01/22 01:22
79-34-5
ND
ug/L
1.0
0.29
1
10/01/22 01:22
127-18-4
ND
ug/L
1.0
0.48
1
10/01/22 01:22
108-88-3
ND
ug/L
1.0
0.33
1
10/01/22 01:22
71-55-6
ND
ug/L
1.0
0.32
1
10/01/22 01:22
79-00-5
ND
ug/L
1.0
0.38
1
10/01/22 01:22
79-01-6
ND
ug/L
1.0
0.30
1
10/01/22 01:22
75-69-4
ND
ug/L
1.0
0.26
1
10/01/22 01:22
96-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IN
Page 22 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: TRIP BLANK
Parameters
Lab ID:
Results
92628331008
Units
Collected:
Report
Limit
09/28/22 00:00
MDL DF
Received: 09/29/22 10:30 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Vinyl acetate
ND
ug/L
2.0
1.3 1
10/01/22 01:22
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39 1
10/01/22 01:22
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34 1
10/01/22 01:22
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
95
%
70-130
1
10/01/22 01:22
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
10/01/22 01:22
17060-07-0
Toluene-d8 (S)
106
%
70-130
1
10/01/22 01:22
2037-26-5
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: TRIP BLANK
Lab ID: 92628331009 Collected:
09/28/22 00:00
Received: 09/29/22 10:30 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
0.86 1
09/30/22 11:46
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98 % 70-130
1
09/30/22 11:46
17060-07-0
Toluene-d8 (S)
110 % 70-130
1
09/30/22 11:46
2037-26-5
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: NES-1 Lab ID: 92628331010 Collected: 09/28/22 13:40 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/04/22 11:42
10/05/2219:23
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:12
7440-38-2
Barium
131
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:23
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/04/22 11:42
10/05/2219:23
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
10/04/22 11:42
10/05/2219:23
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/04/22 11:42
10/06/22 21:12
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
10/04/22 11:42
10/05/2219:23
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/04/22 11:42
10/05/2219:23
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/04/22 11:42
10/06/22 21:12
7439-92-1
Nickel
7.0
ug/L
5.0
3.5
1
10/04/22 11:42
10/05/2219:23
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/04/22 11:42
10/06/22 21:12
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/04/22 11:42
10/05/2219:23
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
10/04/22 11:42
10/05/2219:23
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/04/22 11:42
10/05/2219:23
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
0.12J
ug/L
0.47
0.050
1
10/04/22 09:27
10/07/22 00:51
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/04/22 16:07
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/04/22 16:07
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/04/22 16:07
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/04/22 16:07
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/04/22 16:07
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/04/22 16:07
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
10/04/22 16:07
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/04/22 16:07
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/04/22 16:07
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/04/22 16:07
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/04/22 16:07
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/04/22 16:07
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/04/22 16:07
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/04/22 16:07
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/04/22 16:07
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/04/22 16:07
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/04/22 16:07
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/04/22 16:07
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/04/22 16:07
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/04/22 16:07
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/04/22 16:07
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/04/22 16:07
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/04/22 16:07
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
10/04/22 16:07
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
v2
Page 25 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: GM1.003
Pace Project No.: 92628331
Sample: NES-1 Lab ID: 92628331010 Collected: 09/28/22 13:40 Received: 09/29/22 10:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:07 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.38
1
10/04/2216:07
156-59-2
ND
ug/L
1.0
0.40
1
10/04/2216:07
156-60-5
ND
ug/L
1.0
0.36
1
10/04/2216:07
78-87-5
ND
ug/L
1.0
0.36
1
10/04/22 16:07
10061-01-5
ND
ug/L
1.0
0.36
1
10/04/2216:07
10061-02-6
ND
ug/L
1.0
0.30
1
10/04/2216:07
100-41-4
ND
ug/L
5.0
0.48
1
10/04/2216:07
591-78-6
ND
ug/L
20.0
9.7
1
10/04/2216:07
74-88-4
ND
ug/L
5.0
2.0
1
10/04/2216:07
75-09-2
ND
ug/L
5.0
2.7
1
10/04/2216:07
108-10-1
ND
ug/L
1.0
0.29
1
10/04/2216:07
100-42-5
ND
ug/L
1.0
0.31
1
10/04/2216:07
630-20-6
ND
ug/L
1.0
0.22
1
10/04/2216:07
79-34-5
ND
ug/L
1.0
0.29
1
10/04/2216:07
127-18-4
ND
ug/L
1.0
0.48
1
10/04/2216:07
108-88-3
ND
ug/L
1.0
0.33
1
10/04/2216:07
71-55-6
ND
ug/L
1.0
0.32
1
10/04/2216:07
79-00-5
ND
ug/L
1.0
0.38
1
10/04/2216:07
79-01-6
ND
ug/L
1.0
0.30
1
10/04/2216:07
75-69-4
ND
ug/L
1.0
0.26
1
10/04/2216:07
96-18-4
ND
ug/L
2.0
1.3
1
10/04/2216:07
108-05-4
ND
ug/L
1.0
0.39
1
10/04/2216:07
75-01-4
ND
ug/L
1.0
0.34
1
10/04/2216:07
1330-20-7
100
%
70-130
1
10/04/2216:07
460-00-4
103
%
70-130
1
10/04/2216:07
17060-07-0
102
%
70-130
1
10/04/2216:07
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
0.92J
ug/L
2.0
0.86
1
09/30/2214:19
123-91-1
91
%
70-130
1
09/30/2214:19
17060-07-0
98
%
70-130
1
09/30/2214:19
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 751162 Analysis Method: RSK-175
QC Batch Method: RSK-175 Analysis Description: Biodegradation Indicator Gases
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 2403704 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Methane ug/L ND 5.0 2.0 10/05/22 06:10
LABORATORY CONTROL SAMPLE & LCSD: 2403705 2403706
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Methane ug/L 380 330 330 87 87 70-130 0 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 27 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727679 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331007,
92628331010
METHOD BLANK: 3789283 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331007,
92628331010
Parameter
Units
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Cadmium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Hardness, Total(SM 2340B)
ug/L
Lead
ug/L
Nickel
ug/L
Selenium
ug/L
Silver
ug/L
Tin
ug/L
Vanadium
ug/L
Zinc
ug/L
LABORATORY CONTROL SAMPLE: 3789284
Parameter
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
5.0
3.0
10/05/2218:34
ND
10.0
4.7
10/06/22 20:19
ND
5.0
3.5
10/05/2218:34
ND
1.0
0.70
10/05/2218:34
ND
1.0
0.40
10/05/2218:34
ND
5.0
3.7
10/05/2218:34
ND
5.0
3.6
10/05/2218:34
ND
5.0
4.3
10/05/2218:34
ND
662
131
10/05/2218:34
ND
5.0
4.5
10/06/22 20:19
ND
5.0
3.5
10/05/2218:34
ND
10.0
4.7
10/06/22 20:19
ND
5.0
2.5
10/05/2218:34
ND
5.0
4.7
10/05/2218:34
ND
5.0
3.9
10/05/2218:34
ND
10.0
9.5
10/05/2218:34
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
ug/L
500
512
102
80-120
ug/L
500
493
99
80-120
ug/L
500
500
100
80-120
ug/L
500
515
103
80-120
ug/L
500
513
103
80-120
ug/L
500
514
103
80-120
ug/L
500
521
104
80-120
ug/L
500
528
106
80-120
ug/L
33100
34000
103
80-120
ug/L
500
505
101
80-120
ug/L
500
531
106
80-120
ug/L
500
504
101
80-120
ug/L
250
238
95
80-120
ug/L
500
528
106
80-120
ug/L
500
553
111
80-120
ug/L
500
518
104
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 28 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
MATRIX SPIKE & MATRIX SPIKE
Parameter
DUPLICATE: 3789285
MS
92628331001 Spike
Units Result Conc.
MSD
Spike
Conc.
3789286
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Antimony
ug/L
ND
500
500
495
502
99
100
75-125
1
20
Arsenic
ug/L
ND
500
500
500
503
99
100
75-125
1
20
Barium
ug/L
110
500
500
584
591
95
96
75-125
1
20
Beryllium
ug/L
ND
500
500
490
496
98
99
75-125
1
20
Cadmium
ug/L
0.54J
500
500
501
506
100
101
75-125
1
20
Chromium
ug/L
ND
500
500
464
476
92
95
75-125
3
20
Cobalt
ug/L
17.0
500
500
495
498
96
96
75-125
1
20
Copper
ug/L
ND
500
500
488
502
98
100
75-125
3
20
Hardness, Total(SM 2340B)
ug/L
801000
33100
33100
816000
840000
46
118
75-125
3
20
Lead
ug/L
ND
500
500
461
465
92
93
75-125
1
20
Nickel
ug/L
101
500
500
577
585
95
97
75-125
1
20
Selenium
ug/L
4.9J
500
500
519
519
103
103
75-125
0
20
Silver
ug/L
ND
250
250
225
230
90
92
75-125
2
20
Tin
ug/L
52.1
500
500
548
553
99
100
75-125
1
20
Vanadium
ug/L
ND
500
500
514
526
102
105
75-125
2
20
Zinc
ug/L
ND
500
500
483
490
96
98
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 29 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727646 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331007,
92628331010
METHOD BLANK: 3789148 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331007,
92628331010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.47 0.050 10/05/22 01:46
LABORATORY CONTROL SAMPLE: 3789149
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 25 25.3 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789150 3789151
MS MSD
92628331001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 25 25 25.9 25.2 103 101 75-125 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 30 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727117 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331008
METHOD BLANK: 3786678 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
10/01/22 00:46
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
10/01/22 00:46
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
10/01/22 00:46
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
10/01/22 00:46
1,1-Dichloroethane
ug/L
ND
1.0
0.37
10/01/22 00:46
1,1-Dichloroethene
ug/L
ND
1.0
0.35
10/01/22 00:46
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
10/01/22 00:46
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
10/01/22 00:46
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
10/01/22 00:46
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
10/01/22 00:46
1,2-Dichloroethane
ug/L
ND
1.0
0.32
10/01/22 00:46
1,2-Dichloropropane
ug/L
ND
1.0
0.36
10/01/22 00:46
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
10/01/22 00:46
2-Butanone (MEK)
ug/L
ND
5.0
4.0
10/01/22 00:46
2-Hexanone
ug/L
ND
5.0
0.48
10/01/22 00:46
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
10/01/22 00:46
Acetone
ug/L
ND
25.0
5.1
10/01/22 00:46
Acrylonitrile
ug/L
ND
10.0
1.8
10/01/22 00:46
Benzene
ug/L
ND
1.0
0.34
10/01/22 00:46
Bromochloromethane
ug/L
ND
1.0
0.47
10/01/22 00:46
Bromodichloromethane
ug/L
ND
1.0
0.31
10/01/22 00:46
Bromoform
ug/L
ND
1.0
0.34
10/01/22 00:46
Bromomethane
ug/L
ND
2.0
1.7
10/01/22 00:46
Carbon disulfide
ug/L
ND
2.0
0.36
10/01/22 00:46
Carbon tetrachloride
ug/L
ND
1.0
0.33
10/01/22 00:46
Chlorobenzene
ug/L
ND
1.0
0.28
10/01/22 00:46
Chloroethane
ug/L
ND
1.0
0.65
10/01/22 00:46
Chloroform
ug/L
ND
1.0
0.43
10/01/22 00:46
Chloromethane
ug/L
ND
1.0
0.54
10/01/22 00:46
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
10/01/22 00:46
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/01/22 00:46
Dibromochloromethane
ug/L
ND
1.0
0.36
10/01/22 00:46
Dibromomethane
ug/L
ND
1.0
0.39
10/01/22 00:46
Ethylbenzene
ug/L
ND
1.0
0.30
10/01/22 00:46
lodomethane
ug/L
ND
20.0
9.7
10/01/22 00:46
Methylene Chloride
ug/L
ND
5.0
2.0
10/01/22 00:46
Naphthalene
ug/L
ND
1.0
0.64
10/01/22 00:46
Styrene
ug/L
ND
1.0
0.29
10/01/22 00:46
Tetrachloroethene
ug/L
ND
1.0
0.29
10/01/22 00:46
Toluene
ug/L
ND
1.0
0.48
10/01/22 00:46
IK
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
METHOD BLANK: 3786678 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
10/01/22 00:46
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/01/22 00:46
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
10/01/22 00:46
Trichloroethene
ug/L
ND
1.0
0.38
10/01/22 00:46
Trichlorofluoromethane
ug/L
ND
1.0
0.30
10/01/22 00:46
Vinyl acetate
ug/L
ND
2.0
1.3
10/01/22 00:46
Vinyl chloride
ug/L
ND
1.0
0.39
10/01/22 00:46
Xylene (Total)
ug/L
ND
1.0
0.34
10/01/22 00:46
1,2-Dichloroethane-d4 (S)
%
106
70-130
10/01/22 00:46
4-Bromofluorobenzene (S)
%
98
70-130
10/01/22 00:46
Toluene-d8 (S)
%
107
70-130
10/01/22 00:46
LABORATORY CONTROL SAMPLE:
Parameter
3786679
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.5
109
70-130
1,1,1-Trichloroethane
ug/L
50
52.1
104
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
53.9
108
70-130
1,1,2-Trichloroethane
ug/L
50
51.6
103
70-130
1,1-Dichloroethane
ug/L
50
50.4
101
70-130
1,1-Dichloroethene
ug/L
50
52.2
104
70-130
1,2,3-Trichloropropane
ug/L
50
52.6
105
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
54.7
109
70-131
1,2-Dibromoethane (EDB)
ug/L
50
53.6
107
70-130
1,2-Dichlorobenzene
ug/L
50
51.8
104
70-130
1,2-Dichloroethane
ug/L
50
50.7
101
70-130
1,2-Dichloropropane
ug/L
50
50.8
102
70-130
1,4-Dichlorobenzene
ug/L
50
49.5
99
70-130
2-Butanone (MEK)
ug/L
100
104
104
70-134
2-Hexanone
ug/L
100
108
108
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
100
104
104
70-130
Acetone
ug/L
100
97.2
97
70-133
Acrylonitrile
ug/L
250
260
104
70-130
Benzene
ug/L
50
47.2
94
70-130
Bromochloromethane
ug/L
50
51.0
102
70-130
Bromodichloromethane
ug/L
50
51.0
102
70-130
Bromoform
ug/L
50
50.5
101
70-130
Bromomethane
ug/L
50
46.8
94
45-151
Carbon disulfide
ug/L
50
46.9
94
70-130
Carbon tetrachloride
ug/L
50
50.1
100
70-130
Chlorobenzene
ug/L
50
51.7
103
70-130
Chloroethane
ug/L
50
58.8
118
39-152 IK
Chloroform
ug/L
50
51.6
103
70-130
Chloromethane
ug/L
50
48.6
97
58-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
LABORATORY CONTROL SAMPLE:
Parameter
3786679
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
cis-1,2-Dichloroethene
ug/L
50
52.7
105
70-130
cis-1,3-Dichloropropene
ug/L
50
53.1
106
70-130
Dibromochloromethane
ug/L
50
52.1
104
70-130
Dibromomethane
ug/L
50
46.4
93
70-130
Ethylbenzene
ug/L
50
52.3
105
70-130
lodomethane
ug/L
100
103
103
53-141
Methylene Chloride
ug/L
50
51.4
103
66-130
Naphthalene
ug/L
50
53.9
108
70-130
Styrene
ug/L
50
51.5
103
70-130
Tetrachloroethene
ug/L
50
49.7
99
70-130
Toluene
ug/L
50
49.4
99
70-130
trans-1,2-Dichloroethene
ug/L
50
51.4
103
70-130
trans- 1,3-Dichloropropene
ug/L
50
52.6
105
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
49.5
99
57-185
Trichloroethene
ug/L
50
49.3
99
70-130
Trichlorofluoromethane
ug/L
50
46.0
92
62-130
Vinyl acetate
ug/L
100
108
108
70-144
Vinyl chloride
ug/L
50
53.9
108
62-130
Xylene (Total)
ug/L
150
154
103
70-130
1,2-Dichloroethane-d4 (S)
%
104
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3786680
MS
92628331001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3786681
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.7
25.5
109
128
70-141
16
30
1,1,1-Trichloroethane
ug/L
ND
20
20
23.4
26.5
117
133
70-150
12
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.7
25.7
109
128
69-142
17
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.8
24.4
104
122
70-138
16
30
1,1-Dichloroethane
ug/L
ND
20
20
23.0
25.6
115
128
70-150
11
30
1,1-Dichloroethene
ug/L
ND
20
20
24.6
28.0
123
140
70-156
13
30
1,2,3-Trichloropropane
ug/L
ND
20
20
19.6
24.3
98
121
70-140
21
30
1,2-Dibromo-3-
ug/L
ND
20
20
21.1
24.0
105
120
68-146
13
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.5
24.0
108
120
70-138
11
30
1,2-Dichlorobenzene
ug/L
1.2
20
20
22.0
24.0
104
114
70-141
9
30
1,2-Dichloroethane
ug/L
ND
20
20
22.5
26.4
112
132
69-143
16
30
1,2-Dichloropropane
ug/L
ND
20
20
22.1
24.8
110
124
68-156
12
30
1,4-Dichlorobenzene
ug/L
ND
20
20
21.6
23.9
108
119
70-142
10
30
2-Butanone (MEK)
ug/L
ND
40
40
41.1
49.4
99
120
60-157
18
30
2-Hexanone
ug/L
ND
40
40
44.2
52.7
111
132
68-146
17
30
4-Methyl-2-pentanone
ug/L
ND
40
40
41.2
49.6
103
124
70-141
19
30
(MIBK)
Acetone
ug/L
ND
40
40
45.9
55.0
115
137
58-157
18
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3786680
3786681
MS
MSD
92628331001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acrylonitrile
ug/L
ND
100
100
109
127
109
127
69-147
15
30
Benzene
ug/L
1.9
20
20
21.9
25.2
100
116
70-142
14
30
Bromochloromethane
ug/L
ND
20
20
21.4
24.9
107
124
70-146
15
30
Bromodichloromethane
ug/L
ND
20
20
21.3
24.7
107
124
70-139
15
30
Bromoform
ug/L
ND
20
20
19.0
22.9
95
114
64-140
19
30
Bromomethane
ug/L
ND
20
20
21.7
22.5
109
113
28-192
4
30
Carbon disulfide
ug/L
ND
20
20
22.2
25.0
111
125
70-151
12
30
Carbon tetrachloride
ug/L
ND
20
20
22.3
25.0
112
125
70-148
11
30
Chlorobenzene
ug/L
15.4
20
20
37.9
40.5
112
126
70-141
7
30
Chloroethane
ug/L
ND
20
20
30.5
32.3
152
161
58-191
6
30 IK,v1
Chloroform
ug/L
ND
20
20
22.7
26.3
114
131
70-148
15
30
Chloromethane
ug/L
ND
20
20
23.2
26.3
116
132
43-162
12
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
23.0
26.4
115
132
68-151
14
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.9
25.2
109
126
70-139
14
30
Dibromochloromethane
ug/L
ND
20
20
21.0
24.7
105
124
70-144
16
30
Dibromomethane
ug/L
ND
20
20
18.5
21.3
92
106
70-139
14
30
Ethylbenzene
ug/L
ND
20
20
22.4
25.4
112
127
70-143
13
30
lodomethane
ug/L
ND
40
40
42.8
49.0
107
122
35-171
13
30
Methylene Chloride
ug/L
ND
20
20
20.9
24.2
105
121
62-149
15
30
Naphthalene
ug/L
3.6
20
20
25.6
29.3
110
129
67-147
13
30
Styrene
ug/L
ND
20
20
20.8
24.5
104
122
70-143
16
30
Tetrachloroethene
ug/L
ND
20
20
19.6
23.2
98
116
70-145
17
30
Toluene
ug/L
ND
20
20
20.8
23.8
104
119
70-142
13
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
23.9
26.7
119
134
70-151
11
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.9
25.9
109
129
70-139
17
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
17.4
20.4
87
102
51-159
16
30
Trichloroethene
ug/L
ND
20
20
20.6
24.1
103
121
62-146
16
30
Trichlorofluoromethane
ug/L
1.4
20
20
23.4
26.0
110
123
63-153
11
30
Vinyl acetate
ug/L
ND
40
40
43.6
51.7
109
129
61-162
17
30 v1
Vinyl chloride
ug/L
ND
20
20
24.6
27.4
123
137
61-163
11
30
Xylene (Total)
ug/L
ND
60
60
66.3
74.2
111
124
70-143
11
30
1,2-Dichloroethane-d4 (S)
%
112
112
70-130
4-Bromofluorobenzene (S)
%
100
103
70-130
Toluene-d8 (S)
%
102
102
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 34 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727360 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628331007
METHOD BLANK: 3787851
Associated Lab Samples: 92628331007
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
10/02/22 18:47
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
10/02/22 18:47
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
10/02/22 18:47
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
10/02/22 18:47
1,1-Dichloroethane
ug/L
ND
1.0
0.37
10/02/22 18:47
1,1-Dichloroethene
ug/L
ND
1.0
0.35
10/02/22 18:47
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
10/02/22 18:47
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
10/02/22 18:47
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
10/02/22 18:47
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
10/02/22 18:47
1,2-Dichloroethane
ug/L
ND
1.0
0.32
10/02/22 18:47
1,2-Dichloropropane
ug/L
ND
1.0
0.36
10/02/22 18:47
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
10/02/22 18:47
2-Butanone (MEK)
ug/L
ND
5.0
4.0
10/02/22 18:47
2-Hexanone
ug/L
ND
5.0
0.48
10/02/22 18:47
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
10/02/22 18:47
Acetone
ug/L
ND
25.0
5.1
10/02/22 18:47
Acrylonitrile
ug/L
ND
10.0
1.8
10/02/22 18:47
Benzene
ug/L
ND
1.0
0.34
10/02/22 18:47
Bromochloromethane
ug/L
ND
1.0
0.47
10/02/22 18:47
Bromodichloromethane
ug/L
ND
1.0
0.31
10/02/22 18:47
Bromoform
ug/L
ND
1.0
0.34
10/02/22 18:47
Bromomethane
ug/L
ND
2.0
1.7
10/02/22 18:47
Carbon disulfide
ug/L
ND
2.0
0.36
10/02/22 18:47
Carbon tetrachloride
ug/L
ND
1.0
0.33
10/02/22 18:47
Chlorobenzene
ug/L
ND
1.0
0.28
10/02/22 18:47
Chloroethane
ug/L
ND
1.0
0.65
10/02/22 18:47
Chloroform
ug/L
ND
1.0
0.43
10/02/22 18:47
Chloromethane
ug/L
ND
1.0
0.54
10/02/22 18:47
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
10/02/22 18:47
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/02/22 18:47
Dibromochloromethane
ug/L
ND
1.0
0.36
10/02/22 18:47
Dibromomethane
ug/L
ND
1.0
0.39
10/02/22 18:47
Ethylbenzene
ug/L
ND
1.0
0.30
10/02/22 18:47
lodomethane
ug/L
ND
20.0
9.7
10/02/22 18:47
Methylene Chloride
ug/L
ND
5.0
2.0
10/02/22 18:47
Naphthalene
ug/L
ND
1.0
0.64
10/02/22 18:47
Styrene
ug/L
ND
1.0
0.29
10/02/22 18:47
Tetrachloroethene
ug/L
ND
1.0
0.29
10/02/22 18:47
Toluene
ug/L
ND
1.0
0.48
10/02/22 18:47
IK
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 35 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
METHOD BLANK: 3787851
Matrix:
Water
Associated Lab Samples: 92628331007
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
10/02/22 18:47
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/02/22 18:47
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
10/02/22 18:47
Trichloroethene
ug/L
ND
1.0
0.38
10/02/22 18:47
Trichlorofluoromethane
ug/L
ND
1.0
0.30
10/02/22 18:47
Vinyl acetate
ug/L
ND
2.0
1.3
10/02/22 18:47
Vinyl chloride
ug/L
ND
1.0
0.39
10/02/22 18:47
Xylene (Total)
ug/L
ND
1.0
0.34
10/02/22 18:47
1,2-Dichloroethane-d4 (S)
%
118
70-130
10/02/22 18:47
4-Bromofluorobenzene (S)
%
96
70-130
10/02/22 18:47
Toluene-d8 (S)
%
111
70-130
10/02/22 18:47
LABORATORY CONTROL SAMPLE: 3787852
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.3
109
70-130
1,1,1-Trichloroethane
ug/L
50
54.3
109
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
54.7
109
70-130
1,1,2-Trichloroethane
ug/L
50
53.1
106
70-130
1,1-Dichloroethane
ug/L
50
53.0
106
70-130
1,1-Dichloroethene
ug/L
50
54.3
109
70-130
1,2,3-Trichloropropane
ug/L
50
54.7
109
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
53.7
107
70-131
1,2-Dibromoethane (EDB)
ug/L
50
52.8
106
70-130
1,2-Dichlorobenzene
ug/L
50
52.3
105
70-130
1,2-Dichloroethane
ug/L
50
55.6
111
70-130
1,2-Dichloropropane
ug/L
50
50.9
102
70-130
1,4-Dichlorobenzene
ug/L
50
51.2
102
70-130
2-Butanone (MEK)
ug/L
100
106
106
70-134
2-Hexanone
ug/L
100
114
114
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
100
108
108
70-130
Acetone
ug/L
100
106
106
70-133
Acrylonitrile
ug/L
250
272
109
70-130
Benzene
ug/L
50
47.2
94
70-130
Bromochloromethane
ug/L
50
52.1
104
70-130
Bromodichloromethane
ug/L
50
52.5
105
70-130
Bromoform
ug/L
50
52.3
105
70-130
Bromomethane
ug/L
50
45.0
90
45-151
Carbon disulfide
ug/L
50
48.1
96
70-130
Carbon tetrachloride
ug/L
50
51.6
103
70-130
Chlorobenzene
ug/L
50
52.6
105
70-130
Chloroethane
ug/L
50
57.6
115
39-152 IK
Chloroform
ug/L
50
53.6
107
70-130
Chloromethane
ug/L
50
50.0
100
58-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
LABORATORY CONTROL SAMPLE:
Parameter
3787852
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
cis-1,2-Dichloroethene
ug/L
50
54.6
109
70-130
cis-1,3-Dichloropropene
ug/L
50
55.1
110
70-130
Dibromochloromethane
ug/L
50
55.1
110
70-130
Dibromomethane
ug/L
50
45.3
91
70-130
Ethylbenzene
ug/L
50
52.4
105
70-130
lodomethane
ug/L
100
107
107
53-141
Methylene Chloride
ug/L
50
54.0
108
66-130
Naphthalene
ug/L
50
58.4
117
70-130
Styrene
ug/L
50
52.3
105
70-130
Tetrachloroethene
ug/L
50
49.5
99
70-130
Toluene
ug/L
50
49.0
98
70-130
trans-1,2-Dichloroethene
ug/L
50
53.8
108
70-130
trans- 1,3-Dichloropropene
ug/L
50
55.4
111
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
55.3
111
57-185
Trichloroethene
ug/L
50
49.4
99
70-130
Trichlorofluoromethane
ug/L
50
46.1
92
62-130
Vinyl acetate
ug/L
100
115
115
70-144
Vinyl chloride
ug/L
50
51.9
104
62-130
Xylene (Total)
ug/L
150
158
105
70-130
1,2-Dichloroethane-d4 (S)
%
111
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
100
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787853
MS
92628486006 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3787854
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
20.6
21.6
103
108
70-141
5
30
1,1,1-Trichloroethane
ug/L
ND
20
20
26.5
25.3
132
126
70-150
5
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.5
22.2
108
111
69-142
3
30
1,1,2-Trichloroethane
ug/L
ND
20
20
23.5
22.1
118
110
70-138
6
30
1,1-Dichloroethane
ug/L
ND
20
20
24.9
24.0
125
120
70-150
4
30
1,1-Dichloroethene
ug/L
ND
20
20
26.5
26.0
132
130
70-156
2
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.4
20.3
107
102
70-140
5
30
1,2-Dibromo-3-
ug/L
ND
20
20
22.1
22.3
111
112
68-146
1
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.3
22.9
107
114
70-138
7
30
1,2-Dichlorobenzene
ug/L
ND
20
20
20.3
22.0
102
110
70-141
8
30
1,2-Dichloroethane
ug/L
ND
20
20
24.8
23.4
124
117
69-143
6
30
1,2-Dichloropropane
ug/L
ND
20
20
23.0
23.6
115
118
68-156
3
30
1,4-Dichlorobenzene
ug/L
ND
20
20
20.4
20.4
102
102
70-142
0
30
2-Butanone (MEK)
ug/L
ND
40
40
47.1
43.1
118
108
60-157
9
30
2-Hexanone
ug/L
ND
40
40
45.2
46.2
113
115
68-146
2
30
4-Methyl-2-pentanone
ug/L
ND
40
40
41.4
43.2
104
108
70-141
4
30
(MIBK)
Acetone
ug/L
ND
40
40
48.4
45.8
121
115
58-157
5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
Date: 11/01/2022 12:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 37 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787853
3787854
MS
MSD
92628486006
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acrylonitrile
ug/L
ND
100
100
123
117
123
117
69-147
4
30
Benzene
ug/L
ND
20
20
21.5
21.1
108
106
70-142
2
30
Bromochloromethane
ug/L
ND
20
20
25.0
23.7
125
118
70-146
6
30
Bromodichloromethane
ug/L
ND
20
20
23.5
22.2
117
111
70-139
6
30
Bromoform
ug/L
ND
20
20
20.4
20.5
102
103
64-140
0
30
Bromomethane
ug/L
ND
20
20
23.8
21.8
119
109
28-192
9
30
Carbon disulfide
ug/L
ND
20
20
24.0
23.2
120
116
70-151
4
30
Carbon tetrachloride
ug/L
ND
20
20
26.3
25.3
131
127
70-148
4
30
Chlorobenzene
ug/L
ND
20
20
21.6
22.4
108
112
70-141
4
30
Chloroethane
ug/L
ND
20
20
31.9
29.4
159
147
58-191
8
30 IK,v1
Chloroform
ug/L
ND
20
20
25.1
23.8
125
119
70-148
5
30
Chloromethane
ug/L
ND
20
20
25.1
23.9
125
119
43-162
5
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
25.7
24.6
128
123
68-151
4
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
23.4
23.4
117
117
70-139
0
30
Dibromochloromethane
ug/L
ND
20
20
22.5
21.1
112
106
70-144
6
30
Dibromomethane
ug/L
ND
20
20
19.0
19.5
95
97
70-139
2
30
Ethylbenzene
ug/L
ND
20
20
22.6
22.8
113
114
70-143
1
30
lodomethane
ug/L
ND
40
40
49.1
46.0
123
115
35-171
6
30
Methylene Chloride
ug/L
ND
20
20
23.3
22.9
117
114
62-149
2
30
Naphthalene
ug/L
ND
20
20
21.7
20.9
108
104
67-147
4
30
Styrene
ug/L
ND
20
20
20.8
21.4
104
107
70-143
3
30
Tetrachloroethene
ug/L
ND
20
20
19.5
20.9
97
104
70-145
7
30
Toluene
ug/L
ND
20
20
21.3
21.8
107
109
70-142
2
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
26.0
24.5
130
122
70-151
6
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
23.7
23.3
119
116
70-139
2
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
18.8
18.8
94
94
51-159
0
30
Trichloroethene
ug/L
ND
20
20
22.0
22.6
110
113
62-146
3
30
Trichlorofluoromethane
ug/L
ND
20
20
24.3
23.8
121
119
63-153
2
30
Vinyl acetate
ug/L
ND
40
40
50.1
46.7
125
117
61-162
7
30 v1
Vinyl chloride
ug/L
ND
20
20
27.2
26.3
136
132
61-163
3
30
Xylene (Total)
ug/L
ND
60
60
65.0
66.8
108
111
70-143
3
30
1,2-Dichloroethane-d4 (S)
%
122
111
70-130
4-Bromofluorobenzene (S)
%
99
99
70-130
Toluene-d8 (S)
%
100
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727685 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628331010
METHOD BLANK: 3789304
Associated Lab Samples: 92628331010
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
10/04/22 23:46
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
10/04/22 23:46
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
10/04/22 23:46
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
10/04/22 23:46
1,1-Dichloroethane
ug/L
ND
1.0
0.37
10/04/22 23:46
1,1-Dichloroethene
ug/L
ND
1.0
0.35
10/04/22 23:46
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
10/04/22 23:46
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
10/04/22 23:46
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
10/04/22 23:46
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
10/04/22 23:46
1,2-Dichloroethane
ug/L
ND
1.0
0.32
10/04/22 23:46
1,2-Dichloropropane
ug/L
ND
1.0
0.36
10/04/22 23:46
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
10/04/22 23:46
2-Butanone (MEK)
ug/L
ND
5.0
4.0
10/04/22 23:46
2-Hexanone
ug/L
ND
5.0
0.48
10/04/22 23:46
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
10/04/22 23:46
Acetone
ug/L
ND
25.0
5.1
10/04/22 23:46
Acrylonitrile
ug/L
ND
10.0
1.8
10/04/22 23:46
Benzene
ug/L
ND
1.0
0.34
10/04/22 23:46
Bromochloromethane
ug/L
ND
1.0
0.47
10/04/22 23:46
Bromodichloromethane
ug/L
ND
1.0
0.31
10/04/22 23:46
Bromoform
ug/L
ND
1.0
0.34
10/04/22 23:46
Bromomethane
ug/L
ND
2.0
1.7
10/04/22 23:46
Carbon disulfide
ug/L
ND
2.0
0.36
10/04/22 23:46
Carbon tetrachloride
ug/L
ND
1.0
0.33
10/04/22 23:46
Chlorobenzene
ug/L
ND
1.0
0.28
10/04/22 23:46
Chloroethane
ug/L
ND
1.0
0.65
10/04/22 23:46
Chloroform
ug/L
ND
1.0
0.43
10/04/22 23:46
Chloromethane
ug/L
ND
1.0
0.54
10/04/22 23:46 v2
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
10/04/22 23:46
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/04/22 23:46
Dibromochloromethane
ug/L
ND
1.0
0.36
10/04/22 23:46
Dibromomethane
ug/L
ND
1.0
0.39
10/04/22 23:46
Ethylbenzene
ug/L
ND
1.0
0.30
10/04/22 23:46
lodomethane
ug/L
ND
20.0
9.7
10/04/22 23:46
Methylene Chloride
ug/L
ND
5.0
2.0
10/04/22 23:46
Styrene
ug/L
ND
1.0
0.29
10/04/22 23:46
Tetrachloroethene
ug/L
ND
1.0
0.29
10/04/22 23:46
Toluene
ug/L
ND
1.0
0.48
10/04/22 23:46
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
10/04/22 23:46
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
METHOD BLANK: 3789304
Associated Lab Samples: 92628331010
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/04/22 23:46
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
10/04/22 23:46
Trichloroethene
ug/L
ND
1.0
0.38
10/04/22 23:46
Trichlorofluoromethane
ug/L
ND
1.0
0.30
10/04/22 23:46
Vinyl acetate
ug/L
ND
2.0
1.3
10/04/22 23:46
Vinyl chloride
ug/L
ND
1.0
0.39
10/04/22 23:46
Xylene (Total)
ug/L
ND
1.0
0.34
10/04/22 23:46
1,2-Dichloroethane-d4 (S)
%
95
70-130
10/04/22 23:46
4-Bromofluorobenzene (S)
%
97
70-130
10/04/22 23:46
Toluene-d8 (S)
%
102
70-130
10/04/22 23:46
LABORATORY CONTROL SAMPLE:
Parameter
3789305
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.3
105
70-130
1,1,1-Trichloroethane
ug/L
50
46.8
94
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.6
99
70-130
1,1,2-Trichloroethane
ug/L
50
50.2
100
70-130
1,1-Dichloroethane
ug/L
50
44.9
90
70-130
1,1-Dichloroethene
ug/L
50
44.1
88
70-130
1,2,3-Trichloropropane
ug/L
50
48.4
97
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
52.3
105
70-131
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
50.6
101
70-130
1,2-Dichloroethane
ug/L
50
43.0
86
70-130
1,2-Dichloropropane
ug/L
50
48.1
96
70-130
1,4-Dichlorobenzene
ug/L
50
48.7
97
70-130
2-Butanone (MEK)
ug/L
100
96.9
97
70-134
2-Hexanone
ug/L
100
106
106
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
100
99.0
99
70-130
Acetone
ug/L
100
96.5
97
70-133
Acrylonitrile
ug/L
250
249
99
70-130
Benzene
ug/L
50
45.5
91
70-130
Bromochloromethane
ug/L
50
47.5
95
70-130
Bromodichloromethane
ug/L
50
48.1
96
70-130
Bromoform
ug/L
50
54.0
108
70-130
Bromomethane
ug/L
50
46.7
93
45-151
Carbon disulfide
ug/L
50
45.7
91
70-130
Carbon tetrachloride
ug/L
50
50.4
101
70-130
Chlorobenzene
ug/L
50
49.4
99
70-130
Chloroethane
ug/L
50
45.6
91
39-152
Chloroform
ug/L
50
45.0
90
70-130
Chloromethane
ug/L
50
42.6
85
58-130 v3
cis-1,2-Dichloroethene
ug/L
50
45.2
90
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
LABORATORY CONTROL SAMPLE:
Parameter
3789305
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
cis-1,3-Dichloropropene
ug/L
50
51.5
103
70-130
Dibromochloromethane
ug/L
50
51.2
102
70-130
Dibromomethane
ug/L
50
48.5
97
70-130
Ethylbenzene
ug/L
50
48.7
97
70-130
lodomethane
ug/L
100
101
101
53-141
Methylene Chloride
ug/L
50
46.9
94
66-130
Styrene
ug/L
50
52.0
104
70-130
Tetrachloroethene
ug/L
50
49.1
98
70-130
Toluene
ug/L
50
45.8
92
70-130
trans-1,2-Dichloroethene
ug/L
50
47.0
94
70-130
trans- 1,3-Dichloropropene
ug/L
50
50.9
102
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
44.7
89
57-185
Trichloroethene
ug/L
50
50.8
102
70-130
Trichlorofluoromethane
ug/L
50
42.6
85
62-130
Vinyl acetate
ug/L
100
102
102
70-144
Vinyl chloride
ug/L
50
46.5
93
62-130
Xylene (Total)
ug/L
150
148
99
70-130
1,2-Dichloroethane-d4 (S)
%
88
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
97
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306
MS
92628588001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3789307
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
26.1
26.0
131
130
70-141
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
25.1
24.7
126
124
70-150
2
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
25.1
25.4
125
127
69-142
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
25.2
23.3
126
116
70-138
8
30
1,1-Dichloroethane
ug/L
ND
20
20
23.3
23.2
117
116
70-150
0
30
1,1-Dichloroethene
ug/L
ND
20
20
24.1
23.7
120
118
70-156
2
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.7
23.0
123
115
70-140
7
30
1,2-Dibromo-3-
ug/L
ND
20
20
26.6
26.7
133
133
68-146
0
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
26.1
25.6
130
128
70-138
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.0
25.0
125
125
70-141
0
30
1,2-Dichloroethane
ug/L
ND
20
20
22.5
22.9
112
114
69-143
2
30
1,2-Dichloropropane
ug/L
ND
20
20
24.7
24.3
124
121
68-156
2
30
1,4-Dichlorobenzene
ug/L
ND
20
20
25.1
25.2
125
126
70-142
0
30
2-Butanone (MEK)
ug/L
ND
40
40
53.5
47.9
134
120
60-157
11
30
2-Hexanone
ug/L
ND
40
40
54.4
52.6
136
131
68-146
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
49.7
46.5
124
116
70-141
7
30
(MIBK)
Acetone ug/L
ND 40 40 56.6 51.2 142 128 58-157 10
30
Acrylonitrile ug/L
ND 100 100 129 124 129 124 69-147 4
30
Benzene ug/L
ND 20 20 23.6 22.4 118 112 70-142 5
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM
without the written consent of Pace Analytical Services, LLC.
Page 41 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306
MS
92628588001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3789307
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Bromochloromethane
ug/L
ND
20
20
25.7
24.8
128
124
70-146
4
30
Bromodichloromethane
ug/L
ND
20
20
25.2
24.3
126
122
70-139
4
30
Bromoform
ug/L
ND
20
20
26.8
25.7
134
128
64-140
4
30
Bromomethane
ug/L
ND
20
20
24.2
23.0
121
115
28-192
5
30 v3
Carbon disulfide
ug/L
ND
20
20
22.5
22.4
113
112
70-151
0
30
Carbon tetrachloride
ug/L
ND
20
20
26.2
25.6
131
128
70-148
2
30
Chlorobenzene
ug/L
ND
20
20
25.6
26.4
126
129
70-141
3
30
Chloroethane
ug/L
ND
20
20
24.2
24.1
121
121
58-191
0
30 v3
Chloroform
ug/L
2.1
20
20
25.2
24.6
116
113
70-148
2
30
Chloromethane
ug/L
ND
20
20
23.7
22.9
118
114
43-162
3
30 v3
cis-1,2-Dichloroethene
ug/L
ND
20
20
23.9
23.8
120
119
68-151
0
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
26.0
24.7
130
123
70-139
5
30
Dibromochloromethane
ug/L
ND
20
20
26.5
26.3
132
131
70-144
1
30
Dibromomethane
ug/L
ND
20
20
26.1
24.4
131
122
70-139
7
30
Ethylbenzene
ug/L
ND
20
20
25.1
25.0
126
125
70-143
1
30
lodomethane
ug/L
ND
40
40
48.9
47.1
122
118
35-171
4
30
Methylene Chloride
ug/L
ND
20
20
24.9
24.4
125
122
62-149
2
30
Styrene
ug/L
ND
20
20
26.3
25.9
132
130
70-143
2
30
Tetrachloroethene
ug/L
ND
20
20
24.2
24.7
121
123
70-145
2
30
Toluene
ug/L
ND
20
20
24.4
23.1
122
116
70-142
5
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
24.2
24.6
121
123
70-151
2
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
26.2
25.2
131
126
70-139
4
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.1
19.6
80
98
51-159
20
30
Trichloroethene
ug/L
ND
20
20
26.2
24.8
131
124
62-146
6
30
Trichlorofluoromethane
ug/L
ND
20
20
22.5
23.1
112
115
63-153
3
30
Vinyl acetate
ug/L
ND
40
40
50.9
47.5
127
119
61-162
7
30
Vinyl chloride
ug/L
ND
20
20
25.4
25.2
127
126
61-163
1
30
Xylene (Total)
ug/L
ND
60
60
75.1
75.4
125
126
70-143
0
30
1,2-Dichloroethane-d4 (S)
%
97
94
70-130
4-Bromofluorobenzene (S)
%
100
102
70-130
Toluene-d8 (S)
%
99
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727091 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628331001, 92628331002, 92628331003, 92628331004, 92628331005, 92628331006, 92628331007,
92628331009,92628331010
METHOD BLANK: 3786436
Matrix:
Water
Associated Lab Samples:
92628331001, 92628331002, 92628331003,
92628331004, 92628331005, 92628331006, 92628331007,
92628331009,92628331010
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 09/30/22 11:27
1,2-Dichloroethane-d4 (S)
%
100
70-130
09/30/22 11:27
Toluene-d8 (S)
%
101
70-130
09/30/22 11:27
LABORATORY CONTROL SAMPLE: 3786437
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 19.5 98 70-130
1,2-Dichloroethane-d4 (S) % 94 70-130
Toluene-d8 (S) % 100 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3786438
3786439
MS
MSD
92628331010 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 0.92J 20
20 19.1 20.5
91
98
63-136
7 30
1,2-Dichloroethane-d4 (S)
%
98
106
70-130
30
Toluene-d8 (S)
%
100
100
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727323 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 3787752 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 mg/L ND 5.0 5.0 10/01/22 14:58
LABORATORY CONTROL SAMPLE: 3787753
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 50.3 101 80-120
LABORATORY CONTROL SAMPLE: 3787754
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 mg/L 50 51.0 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787755 3787756
MS MSD
92628237001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 26.3 50 50 75.1 74.5 98 96 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3787757 3787758
MS MSD
92628237002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 mg/L 26.0 50 50 78.3 77.9 105 104 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 44 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 726875 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 3785640 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day mg/L ND 2.0 2.0 10/04/22 12:44 B3
LABORATORY CONTROL SAMPLE: 3785641
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
BOD, 5 day mg/L 198 198 100 84.6-115
SAMPLE DUPLICATE: 3785642
92628076007 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
BOD, 5 day mg/L ND ND 25 B3,H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 726840 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 3785487 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride mg/L ND 1.0 0.60 09/29/2215:03
Nitrate as N mg/L ND 0.10 0.060 09/29/22 15:03
Sulfate mg/L ND 1.0 0.50 09/29/2215:03
LABORATORY CONTROL SAMPLE: 3785488
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 47.6 95 90-110
Nitrate as N mg/L 2.5 2.3 93 90-110
Sulfate mg/L 50 49.4 99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3785489
3785490
MS
MSD
92628331002 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
Chloride mg/L
150 50
50
198
198
95
96
90-110
0 10
Nitrate as N mg/L
ND 2.5
2.5
2.3
2.3
93
94
90-110
1 10
Sulfate mg/L
ND 50
50
50.0
50.5
99
100
90-110
1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 46 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727063 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 3786260 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand mg/L ND 25.0 12.5 09/30/22 17:36
LABORATORY CONTROL SAMPLE: 3786261
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 736 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3786262 3786263
MS MSD
92628039001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 21100 100 100 23900 23900 2770 2770 90-110 0 3 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3786264 3786265
MS MSD
92628199001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand mg/L 10100 100 100 11100 11000 1040 961 90-110 1 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 47 of 54

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: GM1.003
Pace Project No.: 92628331
QC Batch: 727455 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628331001, 92628331002
METHOD BLANK: 3788250 Matrix: Water
Associated Lab Samples: 92628331001, 92628331002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 0.50 10/03/22 14:28
LABORATORY CONTROL SAMPLE: 3788251
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 25.1 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3788252 3788253
MS MSD
92628331001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 26.4 25 25 49.2 49.2 91 91 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3788255 3788256
MS MSD
92627463004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND 25 25 25.3 25.2 101 100 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:07 PM without the written consent of Pace Analytical Services, LLC.
Page 48 of 54

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: GM1.003
Pace Project No.: 92628331
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L.
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
H3 Sample was received or analysis requested beyond the recognized method holding time.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
GM1.003
Pace Project No.:
92628331
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92628331001
MW-2R
RSK-175
751162
92628331002
MW-3R
RSK-175
751162
92628331001
MW-2R
EPA 3010A
727679
EPA 6010D
727785
92628331002
MW-3R
EPA 3010A
727679
EPA 6010D
727785
92628331003
MW-4
EPA 3010A
727679
EPA 6010D
727785
92628331004
MW-5
EPA 3010A
727679
EPA 6010D
727785
92628331005
MW-6
EPA 3010A
727679
EPA 6010D
727785
92628331006
SW-2
EPA 3010A
727679
EPA 6010D
727785
92628331007
FIELD BLANK
EPA 3010A
727679
EPA6010D
727785
92628331010
NES-1
EPA 3010A
727679
EPA 6010D
727785
92628331001
MW-2R
EPA 3010A
727646
EPA 6020B
727752
92628331002
MW-3R
EPA 3010A
727646
EPA 6020B
727752
92628331003
MW-4
EPA 3010A
727646
EPA 6020B
727752
92628331004
MW-5
EPA 3010A
727646
EPA 6020B
727752
92628331005
MW-6
EPA 3010A
727646
EPA 6020B
727752
92628331006
SW-2
EPA 3010A
727646
EPA 6020B
727752
92628331007
FIELD BLANK
EPA 3010A
727646
EPA 6020B
727752
92628331010
NES-1
EPA 3010A
727646
EPA 6020B
727752
92628331001
MW-2R
EPA 8260D
727117
92628331002
MW-3R
EPA 8260D
727117
92628331003
MW-4
EPA 8260D
727117
92628331004
MW-5
EPA 8260D
727117
92628331005
MW-6
EPA 8260D
727117
92628331006
SW-2
EPA 8260D
727117
92628331007
FIELD BLANK
EPA 8260D
727360
92628331008
TRIP BLANK
EPA 8260D
727117
92628331010
NES-1
EPA 8260D
727685
92628331001
MW-2R
EPA 8260D Mod.
727091
92628331002
MW-3R
EPA 8260D Mod.
727091
92628331003
MW-4
EPA 8260D Mod.
727091
92628331004
MW-5
EPA 8260D Mod.
727091
92628331005
MW-6
EPA 8260D Mod.
727091
92628331006
SW-2
EPA 8260D Mod.
727091
92628331007
FIELD BLANK
EPA 8260D Mod.
727091
92628331009
TRIP BLANK
EPA 8260D Mod.
727091
92628331010
NES-1
EPA 8260D Mod.
727091
92628331001
MW-2R
SM 2320B-2011
727323
92628331002
MW-3R
SM 2320B-2011
727323
92628331001
MW-2R
SM 521 OB-2011
726875
SM 521 OB-2011
726934
92628331002
MW-3R
SM 521 OB-2011
726875
SM 521 OB-2011
726934
92628331001
MW-2R
EPA 300.0 Rev 2.1 1993
726840
92628331002
MW-3R
EPA 300.0 Rev 2.1 1993
726840
92628331001
MW-2R
SM 5220D-2011
727063
SM 5220D-2011
727217
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
GM1.003
92628331
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92628331002
MW-3R
SM 5220D-2011
727063 SM 5220D-2011 727217
92628331001
MW-2R
SM 531OB-2014
727455
92628331002
MW-3R
SM 531OB-2014
727455
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:07 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 54

DC#Jitio ENV-FRM-HUN14003 vpi_8am0is Gondition Upon Receipt
LIIUfu45u1,S fS - - - -
Effeolive Rate; 091.1212022
`Laboratory r ceiving samples:
Asheville M. Ede-hO GreenwoodO .Huntersville ❑ Rale)gh❑ MechanicsvilleE] Atlanta0 Kernersville❑
Sample c6nditioll Cllent.Na.mel WO# : 9Z6283�
0c Lry►�
Project st: ' 31
Couriers �ped � lJe5 p� he f: ❑Cl.lent
�] Coptrner4lal + 1111)
926281331
'
Custo.dyseQl:Present7 I]Yes= ,(Na Seals'Intact? []ves. A
0
Date)fnitlals Person Ekamining Contents:
Pack)ne Materlal, ZBubble Wrap P
ubbfe Bags []None L] other Biological Tissue Frozen?
7herinometer: ❑'lies []No❑NIA
[� tRGun IQ: Z 7/ Type of Ice: Mvht ❑Pipe ❑Kane
0rrectiorifsoor:
CoolerTemp;� r�u Add/Subtract.Vc) C7 Temp should be above freeiing co VC
❑samplesout of temp crlierEa Samples o.n,ice, caoling.prpcess
Cooler Temp Garrecteii (°CI: �. d hasbegen
USDA Regulated Soli ( [NA, water sartf)w
Dld sampie s-or iglnete;Ima. -quarentfne zone within the United.Sta,tes; CA;4r SC Ofd samples originate from a foreign source {internatlan_ally,
(check reaps]? []Yes []NO IntlWPM HaWail and.Puerto. Rico)? []Yes ❑No
Cammmots/Dlscr�panty:
Cha10of6stod Present?
et
❑No
❑NIA
1,
ssnlples,Arrived within Hold Tirne?
es.
No
N/A
2.
Short Hold Tirne.Analysis (r72 hr.)?
es
QlNljA
3.
Rush7'urn;AraundTime Requested?
Yes
o
N/A
A.
5ufficielnt Volume?UYes
[]No
❑N/A
S.
Corrett.Contafners Used!
f0are.Cantalners Used?
Yes.
Yes
❑Na
El No
dN/A
EINIA
6.
Gu tainor§ I0aet7
Yes
❑No
❑N/A.
7.
Dtssolv6d anal Sic; Sampla Field Filtered?
byO,
o
❑N/A
s.
Sample -La bets' maEsh,eQC7
Includes Oate/Time/ID/Analysis Matrix:
[Yes.
[]NO
❑N%A
9,
Heads ace In VOA Vials t>5.6mm)7
❑Yes
No
❑N/A
W,
Trip elank Present?
Trip Vila nkCustody Seals Present?
KYes
Wes
❑No
ONO
❑NIA;
❑NIA
11,
COMMENT5JSAMPLE iDJSCE1l�PAN0
/I
Lot ID of spllt,conta€nets;
CLIENT NOTIFICATION/RESOLLITION
Person contacted;
Project Manager SCURF Revlevl:
's
Pate/Tiros:
Date:
Field Data Required? ❑Yes ❑No
Qualtrax ID; 69814
peg$- 1 O`'2 Pane 52 of Gd

f ace,
DC# Title: ENV-I=RM-HUN1-0U84 v01 Tech Spec Sample Condition
Upon Receipt
(-WZV119uOVKn
Effective Date:0511212022
*Check mark top half of box If pH and/or dechlorination
is verified and within the acceptance range For
preservation samples,
Exceptions: VOA, Ccliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHE
**Bottorn half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
r—
Project VWQ ; 92628331
PM: TIT Due Date: 10/06722
CLIENT: 92-Hart_Ral
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservatlon
adjusted
amount of Preservative
added
Lot tt
Note: Whenever there i5 a dis'crepanry affecting North Carolina compliance samples, a copy of this form will be sent td the North Carolina DEHNR Certification Office (I.e.
Out of hold, Incorrect preservative, out of temp, incorrect containers)
Quallrax Document ID: 70677 Page 2 of 2
Page 53 of 54

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P- Fd of 54

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
November 01, 2022
Jeffrey 011ison
Hart & Hickman
3921 Sunset Ridge Rd.
Ste. 301
Raleigh, NC 27607
RE: Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Dear Jeffrey 011ison:
Enclosed are the analytical results for sample(s) received by the laboratory on October 03, 2022. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
A revised laboratory report is being submitted on 11/1/22 to report MDLs and applicable J values, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
—1$� &-I—
Taylor M Cannon
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
r
e
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 27

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92628841001
92628841002
MW-1R
TRIP BLANK
Water
Water
09/29/22 17:35
09/29/22 00:00
10/03/22 07:30
10/03/22 07:30
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 27

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92628841001 MW-1R
EPA 6010D
SBW
15
PASI-A
EPA6020B
DBB1
1
PASI-A
EPA 8260D
LMB
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92628841002 TRIP BLANK
EPA 8260D
LMB
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 27

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Sample: MWAR
Lab ID:
92628841001
Collected:
09/29/22
17:35
Received: 10/03/22 07:30 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Antimony
ND
ug/L
5.0
3.0
1
10/07/22 01:45
10/07/22 18:45
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
10/07/22 01:45
10/07/22 18:45
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
10/07/22 01:45
10/07/22 18:45
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
10/07/22 01:45
10/07/22 18:45
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
10/07/22 01:45
10/07/22 18:45
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
10/07/22 01:45
10/07/22 18:45
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
10/07/22 01:45
10/07/22 18:45
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
10/07/22 01:45
10/07/22 18:45
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
10/07/22 01:45
10/07/22 18:45
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
10/07/22 01:45
10/07/22 18:45
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
10/07/22 01:45
10/07/22 18:45
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
10/07/22 01:45
10/07/22 18:45
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
10/07/22 01:45
10/07/22 18:45
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
10/07/22 01:45
10/07/22 18:45
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
10/07/22 01:45
10/07/22 18:45
7440-66-6
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3010A
Pace Analytical
Services
-Asheville
Thallium
ND
ug/L
0.47
0.050
1
10/11/22 15:06
10/11/22 23:08
7440-28-0
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
10/06/22 18:26
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
10/06/22 18:26
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
10/06/22 18:26
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
10/06/22 18:26
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
10/06/22 18:26
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
10/06/22 18:26
75-25-2 IK
Bromomethane
ND
ug/L
2.0
1.7
1
10/06/22 18:26
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
10/06/22 18:26
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
10/06/22 18:26
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
10/06/22 18:26
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
10/06/22 18:26
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
10/06/22 18:26
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
10/06/22 18:26
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
10/06/22 18:26
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
10/06/22 18:26
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
10/06/22 18:26
124-48-1 IK
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
10/06/22 18:26
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
10/06/22 18:26
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
10/06/22 18:26
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
10/06/22 18:26
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
10/06/22 18:26
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
10/06/22 18:26
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
10/06/22 18:26
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 27

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Sample: MWAR Lab ID: 92628841001 Collected: 09/29/22 17:35 Received: 10/03/22 07:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/01/2022 12:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.35
1
10/06/2218:26
75-35-4
ND
ug/L
1.0
0.38
1
10/06/2218:26
156-59-2
ND
ug/L
1.0
0.40
1
10/06/2218:26
156-60-5
ND
ug/L
1.0
0.36
1
10/06/2218:26
78-87-5
ND
ug/L
1.0
0.36
1
10/06/2218:26
10061-01-5 v1
ND
ug/L
1.0
0.36
1
10/06/2218:26
10061-02-6
ND
ug/L
1.0
0.30
1
10/06/2218:26
100-41-4
ND
ug/L
5.0
0.48
1
10/06/2218:26
591-78-6
ND
ug/L
20.0
9.7
1
10/06/2218:26
74-88-4
ND
ug/L
5.0
2.0
1
10/06/2218:26
75-09-2
ND
ug/L
5.0
2.7
1
10/06/2218:26
108-10-1
ND
ug/L
1.0
0.64
1
10/06/2218:26
91-20-3
ND
ug/L
1.0
0.29
1
10/06/2218:26
100-42-5
ND
ug/L
1.0
0.31
1
10/06/2218:26
630-20-6 IK
ND
ug/L
1.0
0.22
1
10/06/2218:26
79-34-5
ND
ug/L
1.0
0.29
1
10/06/2218:26
127-18-4
ND
ug/L
1.0
0.48
1
10/06/2218:26
108-88-3
ND
ug/L
1.0
0.33
1
10/06/2218:26
71-55-6
ND
ug/L
1.0
0.32
1
10/06/2218:26
79-00-5
ND
ug/L
1.0
0.38
1
10/06/2218:26
79-01-6
ND
ug/L
1.0
0.30
1
10/06/2218:26
75-69-4
ND
ug/L
1.0
0.26
1
10/06/2218:26
96-18-4
ND
ug/L
2.0
1.3
1
10/06/2218:26
108-05-4 IK
ND
ug/L
1.0
0.39
1
10/06/2218:26
75-01-4
ND
ug/L
1.0
0.34
1
10/06/2218:26
1330-20-7
91
%
70-130
1
10/06/2218:26
460-00-4
85
%
70-130
1
10/06/2218:26
17060-07-0
108
%
70-130
1
10/06/2218:26
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
0.86
1
10/04/22 06:00
123-91-1
113
%
70-130
1
10/04/22 06:00
17060-07-0
105
%
70-130
1
10/04/22 06:00
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 27

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Sample: TRIP BLANK Lab ID: 92628841002 Collected: 09/29/22 00:00 Received: 10/03/22 07:30 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Naphthalene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Date: 11/01/2022 12:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
10.6J
ug/L
25.0
5.1
1
10/04/2215:49
67-64-1
ND
ug/L
10.0
1.8
1
10/04/2215:49
107-13-1
ND
ug/L
1.0
0.34
1
10/04/2215:49
71-43-2
ND
ug/L
1.0
0.47
1
10/04/2215:49
74-97-5
ND
ug/L
1.0
0.31
1
10/04/2215:49
75-27-4
ND
ug/L
1.0
0.34
1
10/04/2215:49
75-25-2
ND
ug/L
2.0
1.7
1
10/04/2215:49
74-83-9
ND
ug/L
5.0
4.0
1
10/04/2215:49
78-93-3
ND
ug/L
2.0
0.36
1
10/04/2215:49
75-15-0
ND
ug/L
1.0
0.33
1
10/04/2215:49
56-23-5
ND
ug/L
1.0
0.28
1
10/04/2215:49
108-90-7
ND
ug/L
1.0
0.65
1
10/04/2215:49
75-00-3
ND
ug/L
1.0
0.43
1
10/04/2215:49
67-66-3
ND
ug/L
1.0
0.54
1
10/04/2215:49
74-87-3
ND
ug/L
2.0
0.34
1
10/04/2215:49
96-12-8
ND
ug/L
1.0
0.36
1
10/04/2215:49
124-48-1
ND
ug/L
1.0
0.27
1
10/04/2215:49
106-93-4
ND
ug/L
1.0
0.39
1
10/04/2215:49
74-95-3
ND
ug/L
1.0
0.34
1
10/04/2215:49
95-50-1
ND
ug/L
1.0
0.33
1
10/04/2215:49
106-46-7
ND
ug/L
1.0
0.56
1
10/04/2215:49
110-57-6
ND
ug/L
1.0
0.37
1
10/04/2215:49
75-34-3
ND
ug/L
1.0
0.32
1
10/04/2215:49
107-06-2
ND
ug/L
1.0
0.35
1
10/04/2215:49
75-35-4
ND
ug/L
1.0
0.38
1
10/04/2215:49
156-59-2
ND
ug/L
1.0
0.40
1
10/04/2215:49
156-60-5
ND
ug/L
1.0
0.36
1
10/04/2215:49
78-87-5
ND
ug/L
1.0
0.36
1
10/04/22 15:49
10061-01-5
ND
ug/L
1.0
0.36
1
10/04/2215:49
10061-02-6
ND
ug/L
1.0
0.30
1
10/04/2215:49
100-41-4
ND
ug/L
5.0
0.48
1
10/04/2215:49
591-78-6
ND
ug/L
20.0
9.7
1
10/04/2215:49
74-88-4
ND
ug/L
5.0
2.0
1
10/04/2215:49
75-09-2
ND
ug/L
5.0
2.7
1
10/04/2215:49
108-10-1
ND
ug/L
1.0
0.64
1
10/04/2215:49
91-20-3
ND
ug/L
1.0
0.29
1
10/04/2215:49
100-42-5
ND
ug/L
1.0
0.31
1
10/04/2215:49
630-20-6
ND
ug/L
1.0
0.22
1
10/04/2215:49
79-34-5
ND
ug/L
1.0
0.29
1
10/04/2215:49
127-18-4
ND
ug/L
1.0
0.48
1
10/04/2215:49
108-88-3
ND
ug/L
1.0
0.33
1
10/04/2215:49
71-55-6
ND
ug/L
1.0
0.32
1
10/04/2215:49
79-00-5
ND
ug/L
1.0
0.38
1
10/04/2215:49
79-01-6
ND
ug/L
1.0
0.30
1
10/04/2215:49
75-69-4
ND
ug/L
1.0
0.26
1
10/04/2215:49
96-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 7 of 27

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Sample: TRIP BLANK
Parameters
Lab ID: 92628841002 Collected:
Report
Results Units Limit
09/29/22 00:00
MDL DF
Received: 10/03/22 07:30 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl acetate
ND ug/L 2.0
1.3
1
10/04/22 15:49
108-05-4
Vinyl chloride
ND ug/L 1.0
0.39
1
10/04/22 15:49
75-01-4
Xylene (Total)
ND ug/L 1.0
0.34
1
10/04/22 15:49
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
10/04/22 15:49
460-00-4
1,2-Dichloroethane-d4 (S)
97 % 70-130
1
10/04/22 15:49
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
10/04/22 15:49
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
0.86
1
10/03/22 21:23
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
104 % 70-130
1
10/03/22 21:23
17060-07-0
Toluene-d8 (S)
104 % 70-130
1
10/03/22 21:23
2037-26-5
Date: 11/01/2022 12:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 27

lV11.1 Analytical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 728585 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628841001
METHOD BLANK: 3794442
Associated Lab Samples: 92628841001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.0
10/07/2218:07
Arsenic
ug/L
ND
10.0
4.7
10/07/2218:07
Barium
ug/L
ND
5.0
3.5
10/07/2218:07
Beryllium
ug/L
ND
1.0
0.70
10/07/2218:07
Cadmium
ug/L
ND
1.0
0.40
10/07/2218:07
Chromium
ug/L
ND
5.0
3.7
10/07/2218:07
Cobalt
ug/L
ND
5.0
3.6
10/07/2218:07
Copper
ug/L
ND
5.0
4.3
10/07/2218:07
Lead
ug/L
ND
5.0
4.5
10/07/2218:07
Nickel
ug/L
ND
5.0
3.5
10/07/2218:07
Selenium
ug/L
ND
10.0
4.7
10/07/2218:07
Silver
ug/L
ND
5.0
2.5
10/07/2218:07
Tin
ug/L
ND
5.0
4.7
10/07/2218:07
Vanadium
ug/L
ND
5.0
3.9
10/07/2218:07
Zinc
ug/L
ND
10.0
9.5
10/07/2218:07
LABORATORY CONTROL SAMPLE:
Parameter
3794443
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
502
100
80-120
Arsenic
ug/L
500
501
100
80-120
Barium
ug/L
500
517
103
80-120
Beryllium
ug/L
500
510
102
80-120
Cadmium
ug/L
500
514
103
80-120
Chromium
ug/L
500
514
103
80-120
Cobalt
ug/L
500
506
101
80-120
Copper
ug/L
500
517
103
80-120
Lead
ug/L
500
516
103
80-120
Nickel
ug/L
500
514
103
80-120
Selenium
ug/L
500
505
101
80-120
Silver
ug/L
250
243
97
80-120
Tin
ug/L
500
514
103
80-120
Vanadium
ug/L
500
554
111
80-120
Zinc
ug/L
500
510
102
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
BUTNER LANDFILL GM1.003
92628841
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3794444
3794445
MS
MSD
92628749001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
483
493
97
99
75-125
2
20
Arsenic
ug/L
ND
500
500
488
496
97
98
75-125
2
20
Barium
ug/L
30.0
500
500
519
526
98
99
75-125
1
20
Beryllium
ug/L
ND
500
500
494
503
99
101
75-125
2
20
Cadmium
ug/L
ND
500
500
488
496
98
99
75-125
2
20
Chromium
ug/L
ND
500
500
491
499
97
99
75-125
2
20
Cobalt
ug/L
ND
500
500
482
491
96
98
75-125
2
20
Copper
ug/L
20.7
500
500
509
512
98
98
75-125
1
20
Lead
ug/L
ND
500
500
494
502
98
99
75-125
2
20
Nickel
ug/L
ND
500
500
493
501
98
99
75-125
2
20
Selenium
ug/L
ND
500
500
501
513
100
102
75-125
2
20
Silver
ug/L
ND
250
250
233
237
93
95
75-125
2
20
Tin
ug/L
ND
500
500
487
495
97
99
75-125
2
20
Vanadium
ug/L
10.8
500
500
541
550
106
108
75-125
2
20
Zinc
ug/L
69.0
500
500
552
560
97
98
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 729379 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92628841001
METHOD BLANK: 3798239
Matrix:
Water
Associated Lab Samples: 92628841001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Thallium
ug/L
ND
0.47
0.050 10/11/22 20:54
LABORATORY CONTROL SAMPLE:
3798240
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Thallium
ug/L
25
26.1
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3798241 3798242
MS MSD
92628841001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 25 25 25.7 26.2 103 105 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 727685 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628841002
METHOD BLANK: 3789304
Associated Lab Samples: 92628841002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
10/04/22 23:46
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
10/04/22 23:46
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
10/04/22 23:46
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
10/04/22 23:46
1,1-Dichloroethane
ug/L
ND
1.0
0.37
10/04/22 23:46
1,1-Dichloroethene
ug/L
ND
1.0
0.35
10/04/22 23:46
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
10/04/22 23:46
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
10/04/22 23:46
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
10/04/22 23:46
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
10/04/22 23:46
1,2-Dichloroethane
ug/L
ND
1.0
0.32
10/04/22 23:46
1,2-Dichloropropane
ug/L
ND
1.0
0.36
10/04/22 23:46
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
10/04/22 23:46
2-Butanone (MEK)
ug/L
ND
5.0
4.0
10/04/22 23:46
2-Hexanone
ug/L
ND
5.0
0.48
10/04/22 23:46
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
10/04/22 23:46
Acetone
ug/L
ND
25.0
5.1
10/04/22 23:46
Acrylonitrile
ug/L
ND
10.0
1.8
10/04/22 23:46
Benzene
ug/L
ND
1.0
0.34
10/04/22 23:46
Bromochloromethane
ug/L
ND
1.0
0.47
10/04/22 23:46
Bromodichloromethane
ug/L
ND
1.0
0.31
10/04/22 23:46
Bromoform
ug/L
ND
1.0
0.34
10/04/22 23:46
Bromomethane
ug/L
ND
2.0
1.7
10/04/22 23:46
Carbon disulfide
ug/L
ND
2.0
0.36
10/04/22 23:46
Carbon tetrachloride
ug/L
ND
1.0
0.33
10/04/22 23:46
Chlorobenzene
ug/L
ND
1.0
0.28
10/04/22 23:46
Chloroethane
ug/L
ND
1.0
0.65
10/04/22 23:46
Chloroform
ug/L
ND
1.0
0.43
10/04/22 23:46
Chloromethane
ug/L
ND
1.0
0.54
10/04/22 23:46 v2
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
10/04/22 23:46
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/04/22 23:46
Dibromochloromethane
ug/L
ND
1.0
0.36
10/04/22 23:46
Dibromomethane
ug/L
ND
1.0
0.39
10/04/22 23:46
Ethylbenzene
ug/L
ND
1.0
0.30
10/04/22 23:46
lodomethane
ug/L
ND
20.0
9.7
10/04/22 23:46
Methylene Chloride
ug/L
ND
5.0
2.0
10/04/22 23:46
Naphthalene
ug/L
ND
1.0
0.64
10/04/22 23:46
Styrene
ug/L
ND
1.0
0.29
10/04/22 23:46
Tetrachloroethene
ug/L
ND
1.0
0.29
10/04/22 23:46
Toluene
ug/L
ND
1.0
0.48
10/04/22 23:46
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 27

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
METHOD BLANK: 3789304
Matrix:
Water
Associated Lab Samples: 92628841002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
10/04/22 23:46
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/04/22 23:46
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
10/04/22 23:46
Trichloroethene
ug/L
ND
1.0
0.38
10/04/22 23:46
Trichlorofluoromethane
ug/L
ND
1.0
0.30
10/04/22 23:46
Vinyl acetate
ug/L
ND
2.0
1.3
10/04/22 23:46
Vinyl chloride
ug/L
ND
1.0
0.39
10/04/22 23:46
Xylene (Total)
ug/L
ND
1.0
0.34
10/04/22 23:46
1,2-Dichloroethane-d4 (S)
%
95
70-130
10/04/22 23:46
4-Bromofluorobenzene (S)
%
97
70-130
10/04/22 23:46
Toluene-d8 (S)
%
102
70-130
10/04/22 23:46
LABORATORY CONTROL SAMPLE: 3789305
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.3
105
70-130
1,1,1-Trichloroethane
ug/L
50
46.8
94
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.6
99
70-130
1,1,2-Trichloroethane
ug/L
50
50.2
100
70-130
1,1-Dichloroethane
ug/L
50
44.9
90
70-130
1,1-Dichloroethene
ug/L
50
44.1
88
70-130
1,2,3-Trichloropropane
ug/L
50
48.4
97
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
52.3
105
70-131
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
50.6
101
70-130
1,2-Dichloroethane
ug/L
50
43.0
86
70-130
1,2-Dichloropropane
ug/L
50
48.1
96
70-130
1,4-Dichlorobenzene
ug/L
50
48.7
97
70-130
2-Butanone (MEK)
ug/L
100
96.9
97
70-134
2-Hexanone
ug/L
100
106
106
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
100
99.0
99
70-130
Acetone
ug/L
100
96.5
97
70-133
Acrylonitrile
ug/L
250
249
99
70-130
Benzene
ug/L
50
45.5
91
70-130
Bromochloromethane
ug/L
50
47.5
95
70-130
Bromodichloromethane
ug/L
50
48.1
96
70-130
Bromoform
ug/L
50
54.0
108
70-130
Bromomethane
ug/L
50
46.7
93
45-151
Carbon disulfide
ug/L
50
45.7
91
70-130
Carbon tetrachloride
ug/L
50
50.4
101
70-130
Chlorobenzene
ug/L
50
49.4
99
70-130
Chloroethane
ug/L
50
45.6
91
39-152
Chloroform
ug/L
50
45.0
90
70-130
Chloromethane
ug/L
50
42.6
85
58-130 v3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
LABORATORY CONTROL SAMPLE:
Parameter
3789305
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
cis-1,2-Dichloroethene
ug/L
50
45.2
90
70-130
cis-1,3-Dichloropropene
ug/L
50
51.5
103
70-130
Dibromochloromethane
ug/L
50
51.2
102
70-130
Dibromomethane
ug/L
50
48.5
97
70-130
Ethylbenzene
ug/L
50
48.7
97
70-130
lodomethane
ug/L
100
101
101
53-141
Methylene Chloride
ug/L
50
46.9
94
66-130
Naphthalene
ug/L
50
58.8
118
70-130
Styrene
ug/L
50
52.0
104
70-130
Tetrachloroethene
ug/L
50
49.1
98
70-130
Toluene
ug/L
50
45.8
92
70-130
trans-1,2-Dichloroethene
ug/L
50
47.0
94
70-130
trans- 1,3-Dichloropropene
ug/L
50
50.9
102
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
44.7
89
57-185
Trichloroethene
ug/L
50
50.8
102
70-130
Trichlorofluoromethane
ug/L
50
42.6
85
62-130
Vinyl acetate
ug/L
100
102
102
70-144
Vinyl chloride
ug/L
50
46.5
93
62-130
Xylene (Total)
ug/L
150
148
99
70-130
1,2-Dichloroethane-d4 (S)
%
88
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
97
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306
MS
92628588001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3789307
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
26.1
26.0
131
130
70-141
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
25.1
24.7
126
124
70-150
2
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
25.1
25.4
125
127
69-142
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
25.2
23.3
126
116
70-138
8
30
1,1-Dichloroethane
ug/L
ND
20
20
23.3
23.2
117
116
70-150
0
30
1,1-Dichloroethene
ug/L
ND
20
20
24.1
23.7
120
118
70-156
2
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.7
23.0
123
115
70-140
7
30
1,2-Dibromo-3-
ug/L
ND
20
20
26.6
26.7
133
133
68-146
0
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
26.1
25.6
130
128
70-138
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.0
25.0
125
125
70-141
0
30
1,2-Dichloroethane
ug/L
ND
20
20
22.5
22.9
112
114
69-143
2
30
1,2-Dichloropropane
ug/L
ND
20
20
24.7
24.3
124
121
68-156
2
30
1,4-Dichlorobenzene
ug/L
ND
20
20
25.1
25.2
125
126
70-142
0
30
2-Butanone (MEK)
ug/L
ND
40
40
53.5
47.9
134
120
60-157
11
30
2-Hexanone
ug/L
ND
40
40
54.4
52.6
136
131
68-146
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
49.7
46.5
124
116
70-141
7
30
(MIBK)
Acetone
ug/L
ND
40
40
56.6
51.2
142
128
58-157
10
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
Date: 11/01/2022 12:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3789306
3789307
MS
MSD
92628588001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acrylonitrile
ug/L
ND
100
100
129
124
129
124
69-147
4
30
Benzene
ug/L
ND
20
20
23.6
22.4
118
112
70-142
5
30
Bromochloromethane
ug/L
ND
20
20
25.7
24.8
128
124
70-146
4
30
Bromodichloromethane
ug/L
ND
20
20
25.2
24.3
126
122
70-139
4
30
Bromoform
ug/L
ND
20
20
26.8
25.7
134
128
64-140
4
30
Bromomethane
ug/L
ND
20
20
24.2
23.0
121
115
28-192
5
30 v3
Carbon disulfide
ug/L
ND
20
20
22.5
22.4
113
112
70-151
0
30
Carbon tetrachloride
ug/L
ND
20
20
26.2
25.6
131
128
70-148
2
30
Chlorobenzene
ug/L
0.51J
20
20
25.6
26.4
126
129
70-141
3
30
Chloroethane
ug/L
ND
20
20
24.2
24.1
121
121
58-191
0
30 v3
Chloroform
ug/L
2.1
20
20
25.2
24.6
116
113
70-148
2
30
Chloromethane
ug/L
ND
20
20
23.7
22.9
118
114
43-162
3
30 v3
cis-1,2-Dichloroethene
ug/L
ND
20
20
23.9
23.8
120
119
68-151
0
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
26.0
24.7
130
123
70-139
5
30
Dibromochloromethane
ug/L
ND
20
20
26.5
26.3
132
131
70-144
1
30
Dibromomethane
ug/L
ND
20
20
26.1
24.4
131
122
70-139
7
30
Ethylbenzene
ug/L
ND
20
20
25.1
25.0
126
125
70-143
1
30
lodomethane
ug/L
ND
40
40
48.9
47.1
122
118
35-171
4
30
Methylene Chloride
ug/L
ND
20
20
24.9
24.4
125
122
62-149
2
30
Naphthalene
ug/L
ND
20
20
27.3
26.1
136
130
67-147
4
30
Styrene
ug/L
ND
20
20
26.3
25.9
132
130
70-143
2
30
Tetrachloroethene
ug/L
ND
20
20
24.2
24.7
121
123
70-145
2
30
Toluene
ug/L
ND
20
20
24.4
23.1
122
116
70-142
5
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
24.2
24.6
121
123
70-151
2
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
26.2
25.2
131
126
70-139
4
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.1
19.6
80
98
51-159
20
30
Trichloroethene
ug/L
ND
20
20
26.2
24.8
131
124
62-146
6
30
Trichlorofluoromethane
ug/L
ND
20
20
22.5
23.1
112
115
63-153
3
30
Vinyl acetate
ug/L
ND
40
40
50.9
47.5
127
119
61-162
7
30
Vinyl chloride
ug/L
ND
20
20
25.4
25.2
127
126
61-163
1
30
Xylene (Total)
ug/L
ND
60
60
75.1
75.4
125
126
70-143
0
30
1,2-Dichloroethane-d4 (S)
%
97
94
70-130
4-Bromofluorobenzene (S)
%
100
102
70-130
Toluene-d8 (S)
%
99
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 728441 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628841001
METHOD BLANK: 3793557
Associated Lab Samples: 92628841001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
10/06/22 13:48
IK
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
10/06/22 13:48
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
10/06/22 13:48
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
10/06/22 13:48
1,1-Dichloroethane
ug/L
ND
1.0
0.37
10/06/22 13:48
1,1-Dichloroethene
ug/L
ND
1.0
0.35
10/06/22 13:48
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
10/06/22 13:48
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
10/06/22 13:48
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
10/06/22 13:48
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
10/06/22 13:48
1,2-Dichloroethane
ug/L
ND
1.0
0.32
10/06/22 13:48
1,2-Dichloropropane
ug/L
ND
1.0
0.36
10/06/22 13:48
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
10/06/22 13:48
2-Butanone (MEK)
ug/L
ND
5.0
4.0
10/06/22 13:48
2-Hexanone
ug/L
ND
5.0
0.48
10/06/22 13:48
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
10/06/22 13:48
Acetone
ug/L
ND
25.0
5.1
10/06/22 13:48
Acrylonitrile
ug/L
ND
10.0
1.8
10/06/22 13:48
Benzene
ug/L
ND
1.0
0.34
10/06/22 13:48
Bromochloromethane
ug/L
ND
1.0
0.47
10/06/22 13:48
Bromodichloromethane
ug/L
ND
1.0
0.31
10/06/22 13:48
Bromoform
ug/L
ND
1.0
0.34
10/06/22 13:48
IK
Bromomethane
ug/L
ND
2.0
1.7
10/06/22 13:48
v2
Carbon disulfide
ug/L
ND
2.0
0.36
10/06/22 13:48
Carbon tetrachloride
ug/L
ND
1.0
0.33
10/06/22 13:48
Chlorobenzene
ug/L
ND
1.0
0.28
10/06/22 13:48
Chloroethane
ug/L
ND
1.0
0.65
10/06/22 13:48
Chloroform
ug/L
ND
1.0
0.43
10/06/22 13:48
Chloromethane
ug/L
ND
1.0
0.54
10/06/22 13:48
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
10/06/22 13:48
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/06/22 13:48
v1
Dibromochloromethane
ug/L
ND
1.0
0.36
10/06/22 13:48
IK
Dibromomethane
ug/L
ND
1.0
0.39
10/06/22 13:48
Ethylbenzene
ug/L
ND
1.0
0.30
10/06/22 13:48
lodomethane
ug/L
ND
20.0
9.7
10/06/22 13:48
Methylene Chloride
ug/L
ND
5.0
2.0
10/06/22 13:48
Naphthalene
ug/L
ND
1.0
0.64
10/06/22 13:48
Styrene
ug/L
ND
1.0
0.29
10/06/22 13:48
Tetrachloroethene
ug/L
ND
1.0
0.29
10/06/22 13:48
Toluene
ug/L
ND
1.0
0.48
10/06/22 13:48
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 27

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
METHOD BLANK: 3793557
Matrix:
Water
Associated Lab Samples: 92628841001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
10/06/22 13:48
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
10/06/22 13:48
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
10/06/22 13:48
Trichloroethene
ug/L
ND
1.0
0.38
10/06/22 13:48
Trichlorofluoromethane
ug/L
ND
1.0
0.30
10/06/22 13:48
Vinyl acetate
ug/L
ND
2.0
1.3
10/06/22 13:48 IK
Vinyl chloride
ug/L
ND
1.0
0.39
10/06/22 13:48
Xylene (Total)
ug/L
ND
1.0
0.34
10/06/22 13:48
1,2-Dichloroethane-d4 (S)
%
84
70-130
10/06/22 13:48
4-Bromofluorobenzene (S)
%
92
70-130
10/06/22 13:48
Toluene-d8 (S)
%
117
70-130
10/06/22 13:48
LABORATORY CONTROL SAMPLE: 3793558
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
47.0
94
70-1301K
1,1,1-Trichloroethane
ug/L
50
61.3
123
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.3
103
70-130
1,1,2-Trichloroethane
ug/L
50
59.1
118
70-130
1,1-Dichloroethane
ug/L
50
55.4
111
70-130
1,1-Dichloroethene
ug/L
50
56.0
112
70-130
1,2,3-Trichloropropane
ug/L
50
51.9
104
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
53.5
107
70-131
1,2-Dibromoethane (EDB)
ug/L
50
56.9
114
70-130
1,2-Dichlorobenzene
ug/L
50
50.9
102
70-130
1,2-Dichloroethane
ug/L
50
56.9
114
70-130
1,2-Dichloropropane
ug/L
50
58.7
117
70-130
1,4-Dichlorobenzene
ug/L
50
50.1
100
70-130
2-Butanone (MEK)
ug/L
100
115
115
70-134
2-Hexanone
ug/L
100
112
112
70-131
4-Methyl-2-pentanone (MIBK)
ug/L
100
110
110
70-130
Acetone
ug/L
100
99.6
100
70-133
Acrylonitrile
ug/L
250
280
112
70-130
Benzene
ug/L
50
53.9
108
70-130
Bromochloromethane
ug/L
50
55.1
110
70-130
Bromodichloromethane
ug/L
50
57.8
116
70-130
Bromoform
ug/L
50
45.7
91
70-1301K
Bromomethane
ug/L
50
53.2
106
45-151 v3
Carbon disulfide
ug/L
50
54.7
109
70-130
Carbon tetrachloride
ug/L
50
58.8
118
70-130
Chlorobenzene
ug/L
50
50.9
102
70-130
Chloroethane
ug/L
50
61.1
122
39-152
Chloroform
ug/L
50
56.8
114
70-130
Chloromethane
ug/L
50
58.7
117
58-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
LABORATORY CONTROL SAMPLE:
Parameter
3793558
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
cis-1,2-Dichloroethene
ug/L
50
55.7
111
70-130
cis-1,3-Dichloropropene
ug/L
50
62.5
125
70-130 v1
Dibromochloromethane
ug/L
50
48.3
97
70-1301K
Dibromomethane
ug/L
50
51.6
103
70-130
Ethylbenzene
ug/L
50
53.4
107
70-130
lodomethane
ug/L
100
124
124
53-141
Methylene Chloride
ug/L
50
51.3
103
66-130
Naphthalene
ug/L
50
55.7
111
70-130
Styrene
ug/L
50
55.1
110
70-130
Tetrachloroethene
ug/L
50
49.0
98
70-130
Toluene
ug/L
50
50.1
100
70-130
trans-1,2-Dichloroethene
ug/L
50
57.5
115
70-130
trans- 1,3-Dichloropropene
ug/L
50
62.4
125
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
69.8
140
57-185
Trichloroethene
ug/L
50
61.0
122
70-130
Trichlorofluoromethane
ug/L
50
52.2
104
62-130
Vinyl acetate
ug/L
100
101
101
70-144 IK
Vinyl chloride
ug/L
50
55.6
111
62-130
Xylene (Total)
ug/L
150
162
108
70-130
1,2-Dichloroethane-d4 (S)
%
108
70-130
4-Bromofluorobenzene (S)
%
104
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE SAMPLE:
Parameter
3793560
Units
92629433012
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.4
107
70-141
1,1,1-Trichloroethane
ug/L
ND
20
20.9
105
70-150
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.6
103
69-142
1,1,2-Trichloroethane
ug/L
ND
20
21.8
109
70-138
1,1-Dichloroethane
ug/L
ND
20
18.3
92
70-150
1,1-Dichloroethene
ug/L
ND
20
19.9
100
70-156
1,2,3-Trichloropropane
ug/L
ND
20
19.8
99
70-140
1,2-Dibromo-3-chloropropane
ug/L
ND
20
22.0
110
68-146
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.0
105
70-138
1,2-Dichlorobenzene
ug/L
ND
20
20.9
105
70-141
1,2-Dichloroethane
ug/L
ND
20
18.3
92
69-143
1,2-Dichloropropane
ug/L
ND
20
20.1
101
68-156
1,4-Dichlorobenzene
ug/L
ND
20
20.7
104
70-142
2-Butanone (MEK)
ug/L
ND
40
40.9
102
60-157
2-Hexanone
ug/L
ND
40
43.1
108
68-146
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40.3
101
70-141
Acetone
ug/L
ND
40
42.2
106
58-157
Acrylonitrile
ug/L
ND
100
106
106
69-147
Benzene
ug/L
ND
20
19.8
99
70-142
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
MATRIX SPIKE SAMPLE:
Parameter
3793560
Units
92629433012
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromochloromethane
ug/L
ND
20
21.6
108
70-146
Bromodichloromethane
ug/L
ND
20
20.8
104
70-139
Bromoform
ug/L
ND
20
20.7
103
64-140
Bromomethane
ug/L
ND
20
16.7
84
28-192 v3
Carbon disulfide
ug/L
ND
20
19.5
97
70-151
Carbon tetrachloride
ug/L
ND
20
21.7
109
70-148
Chlorobenzene
ug/L
ND
20
21.3
106
70-141
Chloroethane
ug/L
ND
20
20.8
104
58-191
Chloroform
ug/L
ND
20
20.2
99
70-148
Chloromethane
ug/L
ND
20
18.2
91
43-162
cis-1,2-Dichloroethene
ug/L
ND
20
19.6
98
68-151
cis-1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-139
Dibromochloromethane
ug/L
ND
20
21.1
106
70-144
Dibromomethane
ug/L
ND
20
21.9
109
70-139
Ethylbenzene
ug/L
ND
20
20.8
104
70-143
lodomethane
ug/L
ND
40
39.4
98
35-171
Methylene Chloride
ug/L
ND
20
19.0
95
62-149
Naphthalene
ug/L
ND
20
23.2
116
67-147
Styrene
ug/L
ND
20
20.4
102
70-143
Tetrachloroethene
ug/L
21.3
20
39.3
90
70-145
Toluene
ug/L
ND
20
20.1
100
70-142
trans-1,2-Dichloroethene
ug/L
ND
20
19.5
98
70-151
trans- 1,3-Dichloropropene
ug/L
ND
20
21.0
105
70-139
trans-1,4-Dichloro-2-butene
ug/L
ND
20
13.5
67
51-159
Trichloroethene
ug/L
11.2
20
34.9
118
62-146
Trichlorofluoromethane
ug/L
ND
20
19.6
98
63-153
Vinyl acetate
ug/L
ND
40
40.6
102
61-162
Vinyl chloride
ug/L
ND
20
21.4
107
61-163
Xylene (Total)
ug/L
ND
60
62.4
104
70-143
1,2-Dichloroethane-d4 (S)
%
94
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 3793559
92629433015
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
SAMPLE DUPLICATE: 3793559
Parameter
Units
92629433015
Result
Dup
Result
1,2-Dichlorobenzene
ug/L
ND
ND
1,2-Dichloroethane
ug/L
ND
ND
1,2-Dichloropropane
ug/L
ND
ND
1,4-Dichlorobenzene
ug/L
ND
ND
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
3.4
3.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Naphthalene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
57.1
52.8
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
9.4
10.4
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
86
96
4-Bromofluorobenzene (S)
%
88
100
Toluene-d8 (S)
%
107
100
Max
RPD RPD
I.7
8
HE
30
30
30
30
30
30
30
30
30
30
30
30
30
30 v2
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 727582 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628841002
METHOD BLANK: 3788970
Matrix:
Water
Associated Lab Samples: 92628841002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 10/03/22 20:45
1,2-Dichloroethane-d4 (S)
%
106
70-130
10/03/22 20:45
Toluene-d8 (S)
%
104
70-130
10/03/22 20:45
LABORATORY CONTROL SAMPLE: 3788971
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 18.2 91 70-130
1,2-Dichloroethane-d4 (S) % 107 70-130
Toluene-d8 (S) % 105 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3788972
3788973
MS
MSD
92628726016 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 18.9 19.3
95
97
63-136
2 30
1,2-Dichloroethane-d4 (S)
%
114
118
70-130
30
Toluene-d8 (S)
%
104
104
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 27

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
QC Batch: 727584 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92628841001
METHOD BLANK: 3788974
Matrix:
Water
Associated Lab Samples: 92628841001
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 10/03/22 21:04
1,2-Dichloroethane-d4 (S)
%
103
70-130
10/03/22 21:04
Toluene-d8 (S)
%
104
70-130
10/03/22 21:04
LABORATORY CONTROL SAMPLE: 3788975
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 17.8 89 70-130
1,2-Dichloroethane-d4 (S) % 106 70-130
Toluene-d8(S) % 104 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3788976
3788977
MS
MSD
92628726017 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 1.5J 20
20 19.9 19.6
92
90
63-136
2 30
1,2-Dichloroethane-d4 (S)
%
119
121
70-130
30
Toluene-d8(S)
%
104
106
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /01 /2022 12:16 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 27

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/01/2022 12:16 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: BUTNER LANDFILL GM1.003
Pace Project No.: 92628841
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
Batch
92628841001
MWA R
EPA 3010A
728585 EPA 6010D
728598
92628841001
MWA R
EPA 3010A
729379 EPA 6020B
729465
92628841001
MWA R
EPA 8260D
728441
92628841002
TRIP BLANK
EPA 8260D
727685
92628841001
MWA R
EPA 8260D Mod.
727584
92628841002
TRIP BLANK
EPA 8260D Mod.
727582
Date: 11/01/2022 12:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 27

uta- t itie: t=NV-t-KlV1-HUN1-UUtf3 vU'i Sample Condition Upon Receipt
Effective Date: 05/121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville 0 Raleigh❑ Mechanicsville❑ Atlanta[—] Kernersville❑
SampleClient Name: W01 . 92,6288141
" P _L �� Project Courier; ❑Fed Ex ❑UPS ❑USPS ❑Client
❑ III
III
IIII
11111111J�1Commercial .[\ace ❑Other:
P
1 92626341
Custody Seal Present? ❑Yes No seals Intact? ❑Yes EJNo
Date/initials Person Examining Contents:
Packing Material: ❑Bubble Wrap dBubbie Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: /� ❑Yes []No RN/A
'Q'IRGunID: ga7-07['
Type of Ice: [Wet ❑Blue ❑Nave
Correction factor:
Cooler Temp: Add/Subtract ('C) I Temp should be above freezing to 6°C
Cooler Temp Corrected (°C): ' 7 ❑Samples out of temp criteria. Sampteson ice, cooling process
has tegun
USDA Regulated Soil (Q N/A, water sample)
Did samples originate i� a quarantine zone within the united States: CA, NY, or SC Did samples originate from a foreign source (internationally,
(check maos)? I—iYes 1-1No a. 1'� r IV , r-i.._
Comments/Discrepancy:
Crain of Custody Present?
❑Yes
[]No❑N/A
1.
Samples Arrived within Hold Time?
❑Yes
[]No
❑N/A
2.
Short hold Time Analysis (<72 hr.)?
❑Yes
❑No
[]N/A
I
Rush Turn Around Time Requested?
Dyes
[IN a
❑N/A
4,
Sufficient Volume?
C]Yes
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
❑Yes
Ely es
❑No
❑No
El N/A
❑N/A
6.
Containers Intact?
Oissolved analysis; Samples Field Filtered?
❑Yes
❑Yes
I]No
❑Na
❑N/A
❑N/A
7.
S.
Sample Labels Match CDC?
includes Date/Time/ID/Analysis Matrix:
❑Yes
[:]No
❑N/A
9,
HeadspaceinVDAVials (>5-6mm)?
[]Yes
❑No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
[:]No
[-]No
❑N/A
[-]N/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
r'r�1C:tManagcr�ftF F c.: � ...
Lot ID of splitcontainers:
Date/Time:
Date:
Field Data Required? ❑Yes ❑Na
QLtaltrax ID: 69614 Page 1 of 2 Page 25 of 27

ace u,�- %1111e: MNv-rrcm-Iyl. NI-UUtSJ VU'I -Sample Condition Upon Receipt
Effectjve Date: 05/12120220S/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and prof, Wo #2V8141 —
within the acceptance range for preservation samples. r1,1C Due Date: 1p/10/22
Exceptions: VOA, Coliform, TOC, oil and Grease, oR0/8015 {water) DOC, LLHg CLIENT: gZ"Ha�t _Rai
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
U
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CL
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative
adjusted added
Lot p
note: whenever there Fs a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (Le,
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID. 69614 Page 2 of 2 Page 26 of 27

;,0 m to Y 0 X (n
N
=. a m co •i m 0 A to N
+
ITEM #
d. o y 9 0 n
N � w
a o A
Ll
co
o
0, �
b
V W (n
_
�
_6 nLLLIVVVn`►►►
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to O w
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MATRIX CODE (sec valid codes to IeFI)
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SAMPLE TYPE (G-GRAB C=CCI51P)
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Page 27 of 27

Appendix C
Summary of Historical Groundwater Elevations
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix C
Summary of Historical Groundwater Elevations
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Groundwater Elevations (ft AMSL)
Background
Downgradient
Date
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
8/21/99
418.68
329.13
328.06
330.50
330.83
352.10
NI
11/16/99
419.75
325.38
324.51
331.53
334.33
352.97
NI
5/10/00
424.53
329.60
328.83
334.15
334.49
355.72
NI
10/26/00
419.21
329.26
328.15
331.33
330.94
352.78
NI
4/18/01
418.76
329.42
328.63
333.57
334.36
354.22
NI
10/26/01
412.53
329.04
327.94
330.57
330.23
350.92
NI
6/13/02
413.70
328.38
327.41
330.21
330.29
351.04
NI
11/19/02
413.40
329.25
328.35
331.57
337.17
350.94
NI
06/27/03
423.61
329.57
328.93
334.24
333.99
355.21
NI
12/29/03
420.23
329.70
329.11
334.49
334.78
354.92
NI
06/30/04
418.81
329.38
328.48
332.26
331.39
353.10
NI
12/28/04
418.02
329.50
328.91
333.45
334.14
355.14
NI
06/29/05
418.81
329.10
329.26
331.62
330.90
352.76
NI
12/29/05
413.38
329.29
328.71
332.78
334.27
351.52
NI
06/27/06
414.75
329.17
328.40
332.18
333.56
353.43
NI
12/28/06
415.54
329.40
328.86
333.57
335.24
354.02
NI
07/12/07
438.64
328.69
327.97
331.31
330.52
352.30
NI
12/18/07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
07/08/08
414.52
329.20
326.00
331.46
330.85
351.03
NM
12/17/08
412.79
329.39
328.84
333.15
335.03
350.82
NM
07/09/09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
12/16/29
418.11
329.55
329.09
334.57
336.94
352.87
NM
06/24/10
422.42
329.41
328.77
333.65
333.15
353.62
NM
12/13/10
415.96
329.49
328.85
332.81
330.34
350.08
NM
06/20/11
416.00
328.95
328.18
336.77
331.38
351.83
NM
12/05/11
412.94
329.31
328.65
332.32
329.51
349.87
NM
06/12/11
414.56
329.10
328.35
332.52
331.33
351.75
312.5
12/12/12
412.83
329.19
328.36
331.67
330.35
349.48
NM
05/01/13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
08/05/13
417.97
329.02
328.41
333.32
332.83
353.01
NM
02/24/14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
08/11/14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
03/10/15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
08/17/15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
02/17/16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
08/09/16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
02/13/17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
08/22/17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
02/05/18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
08/14/18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
02/04/19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
08/06/19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
02/12/20
417.43
329.75
329.30
335.65
336.08
352.38
317.67
08/27/20
418.84
329.18
328.55
333.42
330.48
351.34
310.90
02/11/21
421.71
329.93
329.62
336.59
336.17
355.52
318.10
08/19/21
420.22
329.50
328.71
333.67
330.13
351.84
310.29
02/15/22
415.99
329.57
329.00
334.15
330.53
350.12
312.55
09/28/22
414.20
328.48
327.43
331.12
327.62
347.59
307.54
Notes:
Groundwater elevations from August 1999 through February 2021 obtained from LaBella Associates Water Quality
Monitoring Report - February 2021 Event.
Groundwater elevations from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August
2021 Event.
ft AMSL = ft above mean sea level
NM = water level not measure
NI = well not yet installed
Appendix C (Page 1 of 1)
https:/Iharthick.sharepoint.com/sites/MasterF!Ies-1/Shared Documents/AAA-Masler Projects/Garrett & Moore/GMI-003 - Granville Go. Butner LF/2022 Second Half GW M/
Butner Historic Tables.xlsx Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
1,1-Dichloroethane
12/01/97
---
ND
ND
1
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=6µg/L
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
0.36
0.52
ND
ND
---
12/19/07
---
ND
ND
ND
0.57
ND
ND
ND
07/08/08
---
ND
ND
ND
0.6
ND
ND
---
12/17/08
0.32
ND
ND
ND
0.51
ND
ND
---
07/09/09
0.32
ND
ND
ND
0.84
ND
ND
ND
12/16/09
0.32
ND
ND
ND
0.73
ND
ND
---
06/24/10
0.32
ND
ND
ND
0.53
ND
ND
---
12/13/10
0.32
ND
ND
ND
0.6
ND
ND
---
06/20/11
0.32
ND
ND
ND
0.63
ND
ND
---
12/05/11
0.32
ND
ND
ND
0.67
ND
ND
ND
06/11/12
0.32
ND
ND
ND
ND
ND
ND
---
12/12/12
0.32
ND
ND
ND
1.61
ND
ND
ND
05/01/13
0.32
ND
ND
ND
1.62
ND
ND
--
05/08/13
0.32
ND
ND
ND
0.53
ND
ND
ND
02/24/14
0.32
ND
ND
ND
0.5
ND
ND
ND
08/12/14
0.32
ND
ND
ND
0.47
ND
ND
ND
03/10/15
0.32
ND
ND
ND
0.5
ND
ND
--
08/18/15
0.32
ND
ND
ND
0.49
ND
ND
ND
02/16/16
0.32
ND
ND
ND
0.45
ND
ND
--
08/09/16
0.32
ND
ND
ND
0.34
ND
ND
---
02/13/17
0.32
ND
ND
ND
0.33
ND
ND
--
08/22/17
0.32
ND
ND
ND
1.37
ND
ND
---
02/05/18
0.32
ND
ND
ND
1.38
ND
ND
--
08/13/18
0.32
ND
ND
ND
0.37
ND
ND
---
02/04/19
0.27
ND
ND
ND
0.36
ND
ND
---
08/07/19
0.27
ND
ND
ND
ND
ND
ND
---
02/12/20
0.27
ND
ND
ND
0.33
ND
ND
---
08/27/20
0.27
ND
ND
ND
ND
ND
ND
---
02/11/21
0.27
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.37
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.37
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
1,2-Dichlorobenzene
12/01/97
---
ND
3
2
1
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=20µg/L
11/19/98
---
ND
2.4
2.3
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
--
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
--
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
1.5
2.3
ND
ND
ND
---
07/12/07
---
ND
1.4
1.7
0.31
ND
ND
---
12/19/07
--
ND
1.6
2
0.37
ND
ND
ND
07/08/08
---
ND
1.6
2
0.39
ND
ND
---
12/17/08
0.3
ND
1.4
1.9
ND
ND
ND
---
07/09/09
0.3
ND
1.6
2
0.36
ND
ND
ND
12/16/09
0.3
ND
0.96
2
0.33
ND
ND
---
06/24/10
0.3
ND
1.9
1.7
0.31
ND
ND
---
12/13/10
0.3
ND
1.9
1.9
0.43
ND
ND
---
06/20/11
0.3
ND
1.5
1.7
0.37
ND
ND
---
12/05/11
0.3
ND
1.3
1.6
ND
ND
ND
---
06/11/12
0.3
ND
1
1.5
ND
ND
ND
ND
12/12/12
0.3
ND
1.3
1.7
ND
ND
ND
---
05/01/13
0.3
ND
1.2
1.6
ND
ND
ND
ND
08/05/13
0.3
ND
1.2
1.6
0.3
ND
ND
---
02/24/14
0.3
ND
1.4
0.64
ND
ND
ND
ND
08/12/14
0.3
ND
1.2
1.5
ND
ND
ND
ND
03/10/15
0.3
ND
1.1
1.1
ND
ND
ND
ND
08/18/15
0.3
ND
0.88
1.3
ND
ND
ND
---
02/16/16
0.3
ND
1.1
1.4
ND
ND
ND
ND
08/09/16
0.3
ND
1.2
1.4
ND
ND
ND
---
02/13/17
0.3
ND
1.2
1.4
ND
ND
ND
---
08/22/17
0.3
ND
1.2
1.5
ND
ND
ND
---
02/05/18
0.3
ND
1
1.4
ND
ND
ND
---
08/13/18
0.3
ND
1.2
1.6
ND
ND
ND
---
02/04/19
0.29
ND
1
ND
ND
ND
ND
---
08/07/19
0.29
ND
0.62
1.2
ND
ND
ND
---
02/12/20
0.29
ND
0.82
0.71
ND
ND
ND
---
08/27/20
0.29
ND
1.2
1.3
ND
ND
ND
---
02/11/21
0.29
ND
1.1
0.83
ND
ND
ND
---
08/19/21
0.29
ND
1.1
1.1
ND
ND
ND
ND
02/16/22
0.34
ND
0.61
ND
ND
ND
ND
NA
9/28/22'
0.34
<1.0
1.2
1.3
<1.0
<1.0
<1.0
NA
Appendix D (Page 1 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
1,2-Dichloroethane
12/17/08
0.12
ND
ND
0.15
ND
ND
ND
---
07/09/09
0.12
ND
ND
ND
ND
ND
ND
ND
NC21-=0.4µg/L
12/16/09
0.12
ND
ND
0.14
ND
ND
ND
---
06/24/10
0.12
ND
ND
ND
ND
ND
ND
---
12/13/10
0.12
ND
ND
ND
ND
ND
ND
---
06/20/11
0.12
ND
ND
ND
ND
ND
ND
--
12/05/11
0.12
ND
ND
ND
ND
0.18
ND
---
06/11/12
0.12
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.12
ND
ND
ND
ND
-0.2
ND
---
05/01/13
0.12
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.12
ND
ND
ND
ND
ND
ND
---
02/24/14
0.12
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.12
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.12
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.24
ND
ND
0.33
0.29
0.36
ND
---
02/16/16
0.24
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.24
ND
ND
ND
ND
ND
ND
---
02/13/17
0.24
ND
ND
ND
ND
ND
ND
---
08/22/17
0.24
ND
ND
ND
ND
ND
ND
---
02/05/18
0.24
0.25
ND
0.37
ND
0.43
ND
---
08/13/18
0.24
ND
ND
ND
ND
ND
ND
---
02/04/19
0.34
ND
ND
ND
ND
ND
ND
---
08/07/19
0.34
ND
ND
ND
ND
ND
ND
---
02/12/20
0.34
ND
ND
ND
ND
ND
ND
---
08/27/20
0.34
ND
ND
ND
ND
ND
ND
---
02/11/21
0.34
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.32
ND
ND
ND
ND
ND
ND
NA
9/28/221
0.32
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
1,4-Dichlorobenzene
09/08/94
---
ND
ND
5
ND
ND
ND
---
12/01/94
---
ND
ND
5
ND
ND
ND
---
NC21-=6µg/L
02/09/95
---
ND
8
6
ND
ND
ND
---
03/02/95
---
ND
7
6
ND
ND
ND
---
11/15/95
--
ND
7
6
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
--
ND
ND
ND
ND
ND
ND
--
06/17/97
---
ND
7.6
6.2
ND
ND
ND
---
12/01/97
--
ND
6
5
4
ND
ND
---
05/20/98
---
ND
7.6
ND
ND
ND
ND
---
11/19/98
--
ND
3.7
2.8
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
5
6
ND
ND
ND
---
04/18/01
---
ND
ND
5
6
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
--
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
3
3.3
ND
ND
ND
---
02/23/07
---
--
3.2
3.3
---
---
---
---
07/12/07
--
ND
3.3
2.9
0.31
ND
ND
---
12/19/07
---
ND
3
2.7
ND
ND
ND
ND
07/08/08
---
ND
3
2.4
ND
ND
ND
---
12/17/08
0.33
ND
2.9
2.5
ND
ND
ND
---
07/09/09
0.33
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.33
ND
2.8
2.2
ND
ND
ND
---
06/24/10
0.33
ND
1.6
ND
ND
ND
ND
---
12/13/10
0.33
ND
3.1
1.9
ND
ND
ND
---
06/20/11
0.33
ND
2.7
1.6
ND
ND
ND
---
12/05/11
0.33
ND
2.2
1.4
ND
ND
ND
---
06/11/12
0.33
ND
1.8
1.4
ND
ND
ND
ND
12/12/12
0.33
ND
2.4
1.3
ND
ND
ND
---
05/01/13
0.33
ND
2.1
1.2
ND
ND
ND
ND
08/05/13
0.33
ND
2
1.3
ND
ND
ND
---
02/24/14
0.33
ND
2.2
1.8
ND
ND
ND
ND
08/12/14
0.33
ND
2.4
1.3
ND
ND
ND
ND
03/10/15
0.33
ND
2.2
1.1
ND
ND
ND
ND
08/18/15
0.33
ND
1.5
1.1
ND
ND
ND
---
02/16/16
0.33
ND
2
1
ND
ND
ND
ND
08/09/16
0.33
ND
1.9
1
ND
ND
ND
---
02/13/17
0.33
ND
1.9
0.9
ND
ND
ND
--
08/22/17
0.33
ND
1.9
0.96
ND
ND
ND
---
02/05/18
0.33
ND
1.6
1.1
ND
ND
ND
--
08/13/18
0.33
ND
1.9
1.1
ND
ND
ND
---
02/04/19
0.26
ND
ND
ND
ND
ND
ND
--
08/07/19
0.26
ND
ND
ND
ND
ND
ND
---
02/12/20
0.26
ND
ND
ND
ND
ND
ND
--
08/27/20
0.26
ND
2.1
1.4
ND
ND
ND
---
02/11/21
0.26
ND
1.9
0.8
ND
ND
ND
--
08/19/21
0.33
ND
2.0
1.1
ND
ND
ND
ND
02/16/22
0.33
ND
0.8
ND
ND
ND
ND
NA
9/28/22'
0.33
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
1,4-Dioxane(p-Dioxane)
08/13/18
1.9
ND
88.0
53.1
40.7
2.0
ND
---
02/04/19
1.9
ND
132
49.6
49.8
ND
ND
ND
NC21-=3µg/L
08/07/19
1.2
ND
98.1
51.7
32.7
3.1
ND
---
02/12/20
1.2
ND
98.2
44.4
36
ND
ND
---
08/27/20
1.2
ND
113
50.0
39.3
3.0
ND
ND
02/11/21
1.2
ND
118
53.1
40.6
1.8
ND
---
08/19/21
1.2
ND
89.7
52.8
39.8
5.2
ND
ND
02/16/22
1.7
ND
107
50.3
37.4
5.5
ND
0.92
9/28/22'
0.86
<2.0
98.7
59.0
40.7
7.8
<2.0
0.921
Appendix D (Page 2 of 22)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
2,4-D
06/27/03
---
---
5.9
ND
ND
ND
---
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
NC21-=70µg/L
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
--
12/29/05
--
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
--
12/29/06
--
ND
ND
ND
ND
ND
ND
--
07/12/07
---
ND
ND
ND
ND
ND
ND
--
12/19/07
--
ND
ND
ND
ND
ND
ND
ND
04/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
--
ND
ND
ND
ND
ND
ND
--
07/09/09
---
ND
ND
ND
ND
ND
ND
--
12/16/09
0.11
ND
ND
ND
ND
ND
ND
--
06/24/10
0.23
ND
ND
ND
ND
ND
ND
--
12/10/10
0.22
ND
ND
ND
ND
ND
ND
---
06/20/11
0.22
ND
ND
ND
ND
ND
ND
---
12/05/11
0.22
ND
ND
ND
ND
ND
ND
---
06/11/12
0.22
ND
ND
ND
ND
ND
ND
---
12/12/12
0.22
ND
ND
ND
ND
ND
ND
---
05/01/13
0.22
ND
ND
ND
ND
ND
ND
---
08/05/13
0.22
ND
ND
ND
ND
ND
ND
---
02/24/14
0.22
ND
ND
ND
ND
ND
ND
---
08/12/14
0.22
ND
ND
ND
--
---
---
---
03/10/15
0.24
ND
ND
ND
---
---
---
---
08/18/15
0.24
ND
ND
ND
--
--
--
---
02/16/16
0.23
ND
ND
ND
---
---
---
---
08/09/16
0.24
ND
ND
ND
--
--
--
---
02/13/17
0.22
ND
ND
ND
---
---
---
---
08/22/17
0.24
ND
ND
ND
--
---
--
---
02/05/18
0.24
ND
ND
ND
---
---
---
---
02/04/19
1.6
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/20
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
2-Butanone (MEK)
12/17/08
0.96
ND
ND
ND
ND
1.2
ND
---
07/09/09
0.96
ND
ND
ND
ND
ND
ND
ND
NC21-=4,000µg/L
12/16/09
0.96
ND
ND
ND
ND
ND
ND
---
06/24/10
0.96
ND
ND
ND
ND
ND
ND
---
12/13/10
0.96
ND
ND
ND
ND
ND
ND
---
06/20/11
0.96
ND
ND
ND
ND
ND
ND
---
12/05/11
0.96
ND
ND
ND
ND
ND
ND
---
06/11/12
0.96
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.96
ND
ND
ND
ND
ND
ND
---
05/01/13
0.96
ND
ND
ND
ND
ND
ND
ND
05/08/13
0.96
ND
ND
ND
ND
ND
ND
---
02/24/14
0.96
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.96
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.96
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.96
ND
ND
ND
ND
ND
ND
---
02/16/16
0.96
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.96
ND
ND
ND
ND
ND
ND
---
02/13/17
0.96
ND
ND
ND
ND
ND
ND
---
08/22/17
0.96
ND
ND
ND
ND
ND
ND
---
02/05/18
0.96
ND
ND
ND
ND
ND
ND
---
08/13/18
0.96
ND
ND
ND
ND
ND
ND
---
02/04/19
3.3
ND
ND
ND
ND
ND
ND
---
08/07/19
3.3
ND
ND
ND
ND
ND
ND
---
02/12/20
3.3
ND
ND
ND
ND
ND
ND
---
08/27/20
3.3
ND
ND
ND
ND
ND
ND
---
02/11/21
3.3
ND
ND
ND
ND
ND
ND
---
08/19/21
4
ND
4.91
ND
ND
ND
ND
ND
02/16/22
4
ND
ND
ND
ND
ND
ND
NA
9/28/22'
4.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
2-Methyl naphthalene
06/24/10
5.1
ND
38.9
ND
ND
ND
ND
---
08/12/10
4.2
---
ND
---
---
---
---
---
NC21- = 30 µg/L
12/13/10
---
---
---
---
---
---
---
---
06/20/11
0.3
ND
ND
ND
ND
ND
ND
---
12/05/11
---
---
---
---
---
---
---
---
06/11/12
0.28
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.28
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
0.28
ND
ND
ND
ND
ND
ND
---
08/12/14
---
---
---
---
---
---
---
---
03/10/15
1
N D
N D
N D
---
---
---
---
02/16/16
0.3
N D
N D
N D
---
---
---
---
02/13/17
0.3
N D
N D
N D
--
--
---
---
08/22/17
1.4
ND
ND
ND
---
---
---
---
02/05/18
1.5
N D
N D
N D
---
---
---
---
02/04/19
2.8
N D
N D
N D
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
1.7
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Appendix D (Page 3 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-S
MW-6
NES-1
4,4'-DDD
06/11/12
0.05
ND
ND
0.13
ND
ND
ND
---
07/19/12
0.05
---
---
ND
---
---
---
---
NC21-=0.1pg/L
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
--
08/05/13
---
---
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
---
---
---
---
---
---
---
---
03/10/15
0.05
ND
ND
ND
--
---
---
---
02/16/16
0.05
ND
ND
ND
---
---
---
---
02/13/17
0.05
ND
ND
ND
--
--
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
--
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
2/11/2021
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.015
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
4,4'DDT
06/11/12
0.05
ND
ND
0.1
ND
ND
ND
---
07/19/12
0.05
---
---
0.063
---
---
---
---
NC21-=0.1µg/L
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
---
---
---
---
03/10/15
0.05
ND
ND
ND
---
---
---
---
02/16/16
0.05
ND
ND
ND
---
--
---
---
02/13/17
0.05
ND
ND
ND
---
---
---
---
02/05/18
0.052
ND
ND
ND
--
---
---
---
02/04/19
0.05
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Acetone
10/27/01
---
244
109
ND
130
128
476
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
NC2L=6,000µg/L
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
20
ND
ND
ND
ND
ND
ND
---
07/09/09
20
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.2
ND
ND
ND
ND
ND
ND
---
06/24/10
2.2
ND
18.5
6.5
ND
2.2
ND
---
12/13/10
2.2
ND
ND
ND
ND
ND
ND
---
06/20/11
2.2
ND
ND
ND
ND
ND
2.4
---
12/05/11
2.2
ND
2.3
ND
ND
ND
ND
---
06/11/12
2.2
ND
3.5
ND
ND
ND
ND
ND
12/12/12
10
ND
ND
ND
ND
ND
ND
---
05/01/13
10
ND
ND
ND
ND
ND
ND
ND
08/05/13
10
ND
ND
ND
ND
ND
ND
---
02/24/14
10
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
ND
ND
ND
ND
ND
ND
ND
03/10/15
10
ND
ND
ND
ND
ND
ND
ND
08/18/15
10
ND
ND
ND
ND
ND
ND
ND
02/16/16
10
ND
ND
ND
ND
ND
ND
ND
08/09/16
10
ND
ND
ND
ND
ND
ND
---
02/13/17
10
ND
ND
ND
ND
ND
ND
---
08/22/17
10
ND
ND
ND
ND
ND
ND
---
02/05/18
10
ND
ND
ND
ND
ND
ND
---
08/13/18
10
ND
ND
ND
ND
ND
ND
---
02/04/19
6.2
ND
ND
ND
ND
ND
ND
---
08/07/19
6.2
ND
ND
ND
ND
ND
ND
---
02/12/20
6.2
ND
ND
ND
ND
ND
ND
---
08/27/20
6.2
ND
ND
ND
ND
ND
ND
---
02/11/21
6.2
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
5.1
ND
ND
ND
ND
ND
ND
NA
9/28/22'
5.1
<25.0
<25.0
<25.0
<25.0
<25.0
<25.0
NA
Appendix D (Page 4 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Antimony
09/08/94
---
ND
ND
ND
ND
ND
ND
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=1µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
--
03/02/95
---
ND
ND
ND
ND
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
ND
ND
ND
ND
ND
--
06/17/97
--
ND
ND
ND
ND
ND
ND
--
12/01/97
---
ND
ND
ND
ND
ND
ND
--
05/20/98
--
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
80
38
32
33
31
--
10/26/00
---
30
ND
ND
ND
ND
ND
--
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
--
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
06/30/04
--
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
--
06/29/05
--
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
--
06/28/06
--
ND
ND
ND
ND
ND
ND
--
12/29/06
---
ND
ND
ND
ND
ND
ND
--
07/12/07
--
ND
ND
ND
ND
ND
ND
--
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
2.6
ND
ND
ND
ND
ND
ND
---
07/09/09
2.6
ND
ND
ND
ND
ND
ND
ND
12/16/09
2.6
ND
ND
ND
ND
ND
ND
---
06/24/10
2.6
ND
ND
ND
2.9
ND
ND
---
12/13/10
2.6
ND
ND
3.0
ND
2.8
ND
---
06/20/11
5
ND
ND
ND
ND
6.0
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
---
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
ND
ND
ND
ND
---
02/24/14
5
8.8
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
10.5
8.0
ND
ND
ND
---
03/10/15
3.8
ND
7.1
6.5
3.9
ND
ND
---
08/18/15
3.8
ND
6.2
4.8
4.1
ND
ND
---
02/16/16
3.8
ND
9.9
6.5
4.3
ND
ND
---
08/09/16
3.8
ND
7.7
ND
ND
ND
ND
---
02/13/17
3.9
ND
ND
ND
ND
ND
ND
---
08/22/17
3.9
ND
ND
ND
ND
ND
ND
---
02/05/18
3.9
ND
ND
ND
ND
ND
ND
---
08/13/18
3.9
ND
ND
ND
ND
ND
ND
---
02/04/19
3.9
ND
ND
ND
ND
ND
ND
---
08/07/19
3
ND
ND
ND
ND
ND
ND
---
02/12/20
3
ND
ND
ND
ND
ND
ND
---
08/27/20
3
ND
ND
ND
ND
ND
ND
---
02/11/21
3
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
3
ND
ND
ND
ND
ND
ND
NA
9/28/22'
3.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Arsenic
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-=10µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
--
ND
ND
ND
ND
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
--
ND
ND
ND
ND
ND
ND
---
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
--
6.0
15.0
ND
ND
ND
ND
---
12/01/97
---
ND
5.0
ND
ND
ND
ND
---
05/20/98
--
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
2.0
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
4.1
ND
ND
ND
ND
ND
07/08/08
---
ND
4.9
ND
ND
ND
ND
---
12/17/08
2.7
ND
ND
ND
ND
ND
ND
---
07/09/09
2.7
ND
13.5
10.9
5.6
ND
4.0
ND
12/16/09
2.7
ND
10.6
6.4
5.0
ND
3.6
---
06/24/10
2.7
ND
11.8
8.1
8.2
3.3
3.1
---
08/12/10
2.7
--
---
7.2
---
---
---
---
08/31/10
2.7
--
15.4
---
--
---
---
---
12/13/10
2.7
ND
4.9
2.7
5.4
ND
ND
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
5.4
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
---
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
5.6
ND
ND
ND
---
02/24/14
5
ND
6.4
ND
ND
ND
ND
ND
08/12/14
5
ND
ND
ND
ND
ND
ND
---
03/10/15
2.5
4.1
5.4
ND
ND
3.1
3.2
---
08/18/15
2.5
ND
5.1
ND
ND
ND
ND
---
02/16/16
2.5
ND
ND
ND
ND
ND
ND
---
08/09/16
2.5
ND
ND
ND
ND
ND
ND
---
02/13/17
5
ND
ND
ND
ND
ND
ND
---
08/22/17
5
ND
ND
ND
ND
ND
ND
---
02/05/18
5
ND
ND
ND
ND
ND
ND
---
08/13/18
5
ND
5.4
ND
ND
ND
ND
---
02/04/19
5
ND
5.7
ND
ND
ND
ND
---
08/07/19
4.7
ND
ND
ND
ND
ND
ND
---
02/12/20
4.7
ND
ND
ND
ND
ND
ND
---
08/27/20
4.7
ND
ND
ND
ND
ND
ND
---
02/11/21
4.7
4.9
10
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
4.7
ND
11.5
11.2
9.0
5.2
5.9
NA
9/28/22'
4.7
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
Appendix D (Page 5 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Barium
09/08/94
---
ND
270
ND
ND
830
860
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=700µg/L
02/09/95
---
ND
ND
ND
ND
510
ND
--
03/02/95
---
ND
ND
ND
ND
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
82
30
ND
15
ND
--
06/17/97
--
200
320
37
17
210
31
--
12/01/97
---
61
180
43
46
220
33
--
05/20/98
--
30
150
45
13
180
22
--
11/19/98
---
48
120
42
ND
380
12
--
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
ND
ND
ND
ND
ND
--
04/18/01
---
ND
ND
ND
ND
ND
ND
--
10/26/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
--
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
06/30/04
--
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
5.2
120
64.9
1.5
64.1
1.8
---
07/12/07
--
2.5
129
65.7
1.1
77
1.3
---
12/19/07
---
2.8
99.2
50
1.4
49.6
1.7
87.8
07/08/08
---
5.8
102
58.4
1.1
57.9
1.2
--
12/17/08
0.2
2.7
92.9
53.1
1.2
55.5
1.1
---
07/09/09
0.2
4.6
121
63.4
0.37
81.4
0.94
72.4
12/16/09
0.2
2.9
108
62.8
0.61
56.8
0.87
---
06/24/10
0.2
2.5
115
61.1
1.6
93.5
1.4
---
12/13/10
0.2
4.3
122
67.9
1.3
90.6
1.5
---
06/20/11
5
ND
108
70.7
ND
84.7
ND
---
12/05/11
5
ND
118
73
ND
90.6
ND
---
06/11/12
5
ND
138
65.2
ND
76.4
ND
61.3
12/12/12
5
ND
113
64.7
ND
73.6
ND
---
05/01/13
5
ND
118
69.1
ND
84.2
ND
81.2
08/05/13
5
ND
111
65.1
ND
95.6
ND
---
02/24/14
5
ND
93.8
44.8
ND
139
ND
ND
08/12/14
5
ND
125
66.4
ND
121
ND
---
03/10/15
2.5
3.0
109
61.8
ND
116
ND
---
08/18/15
2.5
4.4
119
63.1
ND
81.3
ND
---
02/16/16
2.5
5.2
123
72.7
3.0
126
ND
---
08/09/16
2.5
4.5
123
73.3
ND
109
ND
---
02/13/17
2.5
7.8
112
68.3
ND
151
5.6
---
08/22/17
2.5
ND
102
64.5
ND
99.9
ND
---
02/05/18
2.5
8.0
117
73.5
ND
161
ND
---
08/13/18
2.5
3.8
116
67.6
ND
103
ND
---
02/04/19
2.5
ND
104
44.3
ND
110
ND
---
08/07/19
1
5.4
113
73.8
1.2
95.1
1.9
---
02/12/20
1
3.6
110
56.2
2.5
147
1.6
---
08/27/20
3.5
4.5
127
83.2
ND
128
ND
---
02/11/21
3.5
5.3
116
74.4
ND
161
ND
---
08/19/21
3.5
6.2
119
72.7
ND
131
ND
72.3
02/16/22
3.5
4.4
111
61.2
ND
78.3
ND
NA
9/28/22'
3.5
<5.0
110
79.5
<5.0
42.5
<5.0
NA
Benzene
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-=1µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
--
ND
ND
ND
ND
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
--
ND
ND
ND
ND
ND
ND
---
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
--
ND
ND
ND
ND
ND
ND
---
12/01/97
---
ND
ND
ND
ND
ND
ND
---
05/20/98
--
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
1.5
ND
ND
ND
ND
---
02/23/07
--
--
1.2
---
---
---
---
---
07/12/07
---
ND
1.9
ND
ND
ND
ND
---
12/19/07
--
ND
1.8
0.48
0.26
ND
ND
ND
07/08/08
---
ND
1.4
0.51
0.32
ND
ND
---
12/17/08
0.25
ND
1.7
0.54
ND
ND
ND
---
07/09/09
0.25
ND
1.7
0.34
ND
ND
ND
ND
12/16/09
0.25
ND
1.7
0.60
0.29
ND
ND
--
06/24/10
0.25
ND
0.77
0.49
0.33
ND
ND
---
12/13/10
0.25
ND
1.8
0.59
0.37
ND
ND
---
02/08/11
0.25
--
1.4
---
---
---
---
---
06/20/11
0.25
ND
1.7
0.6
0.39
ND
ND
---
12/05/11
0.25
ND
1.4
0.69
0.40
ND
ND
---
06/11/12
0.25
ND
ND
0.51
ND
ND
ND
ND
12/12/12
0.25
ND
1.6
0.73
0.32
ND
ND
---
01/10/13
0.25
ND
1.4
---
---
---
ND
ND
05/01/13
0.25
ND
1.3
0.56
0.27
ND
ND
ND
08/05/13
0.25
ND
1.6
0.64
0.44
ND
ND
--
02/24/14
0.25
ND
1.4
ND
ND
ND
ND
ND
08/12/14
0.25
ND
1.7
0.61
0.25
ND
ND
ND
03/10/15
0.25
ND
1.3
0.54
ND
ND
ND
ND
08/18/15
0.25
ND
1.5
0.66
0.32
ND
ND
---
02/16/16
0.25
ND
1.3
0.56
ND
ND
ND
ND
08/09/16
0.25
ND
1.4
0.53
0.29
ND
ND
ND
02/13/17
0.25
ND
1.2
0.61
ND
ND
ND
ND
08/22/17
0.25
ND
1.3
0.54
ND
ND
ND
ND
02/05/18
0.25
ND
1.2
0.67
ND
ND
ND
ND
08/13/18
0.25
ND
1.3
0.61
0.29
ND
ND
ND
02/04/19
0.15
ND
1.6
ND
ND
ND
ND
ND
08/07/19
0.15
ND
1.7
0.54
0.30
ND
ND
ND
02/12/20
OAS
ND
1.5
ND
ND
ND
ND
ND
08/27/20
0.15
ND
1.9
0.49
ND
ND
ND
ND
02/11/21
0.15
ND
1.8
ND
ND
ND
ND
---
08/19/21
0.30
ND
2.1
0.491
ND
0.381
ND
ND
02/16/22
0.34
ND
1.5
ND
ND
ND
ND
ND
9/28/22'
1.0
<1.0
1.9
0.471
0.371
<1.0
<1.0
<1.0
Appendix D (Page 6 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Benzo(g,h,i)perylene
06/20/11
0.4
ND
ND
ND
ND
ND
1.4
--
12/05/11
---
---
---
---
NC2L=200µg/L
06/11/12
0.38
ND
ND
ND
ND
ND
ND
--
12/12/12
---
---
---
---
05/01/13
0.38
ND
ND
ND
ND
ND
ND
--
08/05/13
---
---
---
---
02/24/14
0.38
ND
ND
ND
ND
ND
ND
--
08/12/14
---
---
---
---
03/10/15
0.5
ND
ND
ND
---
---
---
--
02/16/16
0.4
ND
ND
ND
--
--
--
---
02/13/17
0.4
ND
ND
ND
---
---
---
---
08/22/17
2.1
ND
ND
ND
--
--
--
---
02/05/18
2.2
ND
ND
ND
---
---
---
---
02/04/19
1.8
ND
ND
ND
--
--
--
--
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Beryllium
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
4
ND
---
NC21-=4µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
ND
ND
ND
N D
2
N D
---
11/15/95
--
ND
ND
ND
ND
ND
ND
--
05/28/96
---
ND
ND
ND
N D
6
ND
---
11/22/96
--
ND
ND
ND
ND
3
ND
---
06/17/97
---
2
3
ND
N D
1
ND
---
12/01/97
--
ND
ND
ND
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
--
ND
ND
ND
ND
2
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
12
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
--
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
0.1
ND
ND
ND
ND
0.14
ND
---
07/09/09
0.1
ND
0.18
0.22
0.17
ND
ND
0.23
12/16/09
0.1
ND
0.15
0.17
0.15
0.25
ND
---
06/24/10
0.1
ND
ND
0.27
0.16
ND
ND
---
12/13/10
0.1
ND
ND
ND
ND
ND
ND
---
06/20/11
1
ND
ND
ND
ND
ND
ND
---
12/05/11
1
ND
ND
ND
ND
ND
ND
---
06/11/12
1
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
ND
ND
ND
ND
ND
ND
---
05/01/13
1
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
ND
ND
ND
ND
ND
ND
---
02/24/14
1
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
ND
ND
ND
ND
ND
ND
---
03/10/15
0.5
ND
ND
ND
ND
ND
ND
---
08/18/15
0.5
ND
ND
ND
ND
ND
ND
---
02/16/16
0.5
ND
ND
ND
ND
ND
ND
---
08/09/16
0.5
ND
ND
ND
ND
ND
ND
---
02/13/17
0.5
ND
ND
ND
ND
0.57
ND
---
08/22/17
0.5
ND
ND
ND
ND
ND
ND
---
02/05/18
0.5
ND
ND
ND
ND
ND
ND
---
08/13/18
0.5
ND
ND
ND
ND
ND
ND
---
02/04/19
0.5
ND
ND
ND
ND
ND
ND
---
08/07/19
0.2
ND
ND
ND
ND
ND
ND
---
02/12/20
0.2
0.27
ND
ND
ND
ND
0.21
---
08/27/20
0.7
ND
ND
ND
ND
ND
ND
---
02/11/21
0.7
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.7
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.7
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Beta-BHC
06/11/12
0.05
ND
ND
0.16
ND
ND
ND
---
07/19/12
0.05
---
---
ND
---
---
---
---
NC2L=0.02µg/L
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
---
---
---
---
02/24/14
0.05
ND
0.052
ND
ND
ND
ND
---
04/15/14
0.05
---
ND
---
---
---
---
---
08/12/14
---
---
---
03/10/15
0.1
ND
ND
ND
---
---
---
---
02/16/16
0.1
ND
ND
ND
--
--
---
---
02/13/17
0.1
ND
ND
ND
---
---
---
---
02/05/18
0.1
ND
ND
ND
--
--
---
---
02/04/19
0.1
ND
ND
ND
---
---
---
---
08/07/19
0.1
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.044
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Bis(2-Ethylhexl)phtha late
02/24/14
0.79
2.6
ND
ND
ND
ND
ND
ND
04/15/14
0.79
ND
ND
ND
ND
ND
ND
ND
NC21-=3µg/L
08/12/14
---
---
---
---
---
---
---
---
03/10/15
0.5
ND
ND
ND
--
--
---
---
02/16/16
0.9
ND
ND
ND
---
---
---
---
02/13/17
0.9
ND
ND
ND
--
--
---
---
08/22/17
2.3
ND
ND
ND
---
---
---
---
02/05/18
2.4
ND
ND
ND
---
---
---
---
02/04/19
1.4
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Appendix D (Page 7 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Bromomethane
12/17/08
0.29
ND
ND
0.58
ND
ND
ND
---
07/09/09
0.29
ND
ND
ND
ND
ND
ND
ND
NC21-=10µg/L
12/16/09
0.29
ND
ND
ND
ND
ND
ND
---
06/24/10
0.29
ND
ND
ND
ND
ND
ND
---
12/13/10
0.29
ND
ND
ND
ND
ND
ND
---
06/20/11
0.29
ND
ND
ND
ND
ND
ND
--
12/05/11
0.29
ND
ND
ND
ND
ND
ND
ND
06/11/12
0.29
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.29
ND
ND
ND
ND
ND
ND
--
05/01/13
0.29
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.29
ND
ND
ND
ND
ND
ND
--
02/24/14
0.29
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.29
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.29
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.29
ND
ND
ND
ND
ND
ND
---
02/16/16
0.29
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.29
ND
ND
ND
ND
ND
ND
---
02/13/17
0.29
ND
ND
ND
ND
ND
ND
---
08/22/17
0.29
ND
ND
ND
ND
ND
ND
---
02/05/18
0.29
ND
ND
ND
ND
ND
ND
---
08/13/18
0.29
ND
ND
ND
ND
ND
ND
---
02/04/19
0.62
ND
ND
ND
ND
ND
ND
---
08/07/19
0.62
ND
ND
ND
ND
ND
ND
---
02/12/20
0.62
ND
ND
ND
ND
ND
ND
---
08/27/20
0.62
ND
ND
ND
ND
ND
ND
---
02/11/21
0.62
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
1.7
ND
ND
ND
ND
ND
ND
NA
9/28/22'
2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
NA
Cadmium
09/08/94
---
ND
ND
ND
ND
ND
4
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-=2µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
--
ND
ND
ND
ND
ND
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
ND
ND
ND
ND
ND
---
06/17/97
--
ND
3
1
ND
ND
ND
--
12/01/97
---
ND
2
ND
ND
ND
ND
---
05/20/98
--
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
3
3
ND
2
ND
---
05/10/00
--
5
ND
ND
ND
ND
ND
---
10/26/00
---
ND
2
ND
ND
ND
ND
---
04/18/01
---
ND
11
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
2
ND
ND
ND
ND
---
11/19/02
---
2
2
ND
ND
2
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
1
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
0.5
ND
ND
ND
ND
ND
ND
---
07/09/09
0.5
ND
1.4
ND
ND
ND
ND
ND
12/16/09
0.5
ND
ND
ND
ND
ND
ND
---
06/24/10
0.5
ND
ND
ND
ND
ND
ND
---
12/13/10
0.5
ND
ND
ND
ND
ND
ND
---
06/20/11
1
ND
ND
ND
ND
ND
ND
---
12/05/11
1
ND
ND
ND
ND
ND
ND
---
06/11/12
1
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
ND
ND
ND
ND
ND
ND
---
05/01/13
1
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
ND
ND
ND
ND
ND
ND
---
02/24/14
1
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
ND
ND
ND
ND
ND
ND
---
03/10/15
0.5
ND
ND
ND
ND
ND
ND
---
08/18/15
0.5
ND
ND
ND
ND
ND
ND
---
02/16/16
0.5
ND
ND
ND
ND
ND
ND
---
08/09/16
0.5
ND
ND
ND
ND
ND
ND
---
02/13/17
0.5
ND
ND
ND
ND
ND
ND
---
08/22/17
0.5
ND
ND
ND
ND
ND
ND
---
02/05/18
0.5
ND
ND
ND
ND
ND
ND
---
08/13/18
0.5
ND
ND
ND
ND
ND
ND
---
02/04/19
0.5
ND
ND
ND
ND
ND
ND
---
08/07/19
0.4
ND
ND
ND
0.48
ND
ND
---
02/12/20
0.4
ND
ND
ND
0.69
ND
ND
---
08/27/20
0.4
ND
ND
ND
ND
ND
ND
---
02/11/21
0.4
ND
0.7
0.7
1.1
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.4
ND
0.46
ND
0.43
0.47
ND
---
9/28/22'
0.4
<1.0
0.541
<1.0
0.671
0.941
<1.0
NA
Appendix D (Page 8 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Carbon disulfide
06/17/97
---
ND
64
ND
ND
ND
ND
--
12/01/97
---
ND
5
8
ND
ND
ND
--
NC21-=700µg/L
05/20/98
---
ND
7.5
6.2
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
07/21/99
---
ND
ND
ND
ND
ND
ND
--
11/16/99
--
ND
ND
ND
ND
ND
ND
--
05/10/00
---
ND
ND
ND
ND
ND
ND
--
10/26/00
--
ND
ND
ND
ND
ND
ND
--
04/18/01
---
ND
ND
ND
ND
ND
ND
--
10/27/01
--
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
--
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
--
12/30/03
--
ND
ND
ND
ND
ND
ND
--
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
--
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
--
12/29/06
--
ND
ND
ND
ND
ND
ND
--
07/12/07
---
ND
ND
ND
ND
ND
ND
--
12/19/07
--
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
1.2
ND
ND
ND
ND
ND
ND
--
07/09/09
1.2
ND
ND
ND
ND
ND
ND
ND
12/16/09
1.2
ND
ND
ND
ND
ND
ND
---
06/24/10
1.2
ND
ND
ND
ND
ND
ND
---
12/13/10
1.2
ND
ND
ND
ND
ND
ND
---
06/20/11
1.2
ND
ND
ND
ND
ND
ND
---
12/05/11
1.2
ND
ND
ND
ND
ND
ND
---
06/11/12
1.2
ND
ND
ND
ND
ND
ND
ND
12/12/12
1.2
ND
ND
ND
ND
ND
ND
---
05/01/13
1.2
ND
ND
ND
ND
ND
ND
ND
08/05/13
1.2
ND
ND
ND
ND
ND
ND
---
02/24/14
1.2
ND
ND
ND
ND
ND
ND
ND
08/12/14
1.2
ND
ND
ND
ND
ND
ND
ND
03/10/15
1.2
ND
ND
ND
ND
ND
ND
ND
08/18/15
1.2
ND
ND
ND
ND
ND
ND
---
02/16/16
1.2
ND
ND
ND
ND
ND
ND
ND
08/09/16
1.2
ND
ND
ND
ND
ND
ND
---
02/13/17
1.2
ND
ND
ND
ND
ND
ND
---
08/22/17
1.2
ND
ND
ND
ND
ND
ND
---
02/05/18
1.2
ND
ND
ND
ND
ND
ND
---
08/13/18
1.2
ND
ND
ND
ND
ND
ND
---
02/04/19
0.4
ND
ND
ND
ND
ND
ND
---
08/07/19
0.4
ND
ND
ND
ND
ND
ND
---
02/12/20
0.4
ND
ND
ND
ND
ND
ND
---
08/27/20
0.4
ND
ND
ND
ND
ND
ND
---
02/11/21
0.4
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.73
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.36
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
NA
Chlorobenzene
09/08/94
---
ND
10
7
ND
ND
ND
---
12/01/94
---
ND
ND
7
ND
ND
ND
---
NC2 L= 50 µg/L
02/09/95
---
ND
13
8
6
ND
ND
---
03/02/95
--
ND
12
9
ND
ND
ND
---
11/15/95
---
ND
14
8
9
ND
ND
---
05/28/96
--
ND
15
9
10
ND
ND
---
11/22/96
---
ND
15
ND
11
ND
ND
---
06/17/97
--
ND
19
11
14
ND
ND
---
12/01/97
---
ND
17
9
14
ND
ND
---
05/20/98
--
ND
20
8.6
12
ND
ND
---
11/19/98
---
ND
17.2
9.2
10
ND
ND
---
07/21/99
--
ND
14
10
11
ND
ND
---
11/16/99
---
ND
16
10
8
ND
ND
---
05/10/00
--
ND
17
11
10
ND
ND
---
10/26/00
---
ND
16
12
9
ND
ND
---
04/18/01
---
ND
16
13
6
ND
ND
---
10/27/01
---
ND
17
12
9
ND
ND
---
06/13/02
--
ND
16
11
8
ND
ND
---
11/19/02
---
ND
18
15
9
ND
ND
---
06/27/03
--
ND
17.7
13.3
7.4
ND
ND
---
12/30/03
---
ND
20
15
6.1
ND
ND
---
06/30/04
--
ND
18
15
9.9
ND
ND
---
12/29/04
---
ND
19
16
9.4
ND
ND
---
06/29/05
--
ND
15
13
8
ND
ND
---
12/29/05
---
ND
18
16
5
ND
ND
---
06/28/06
--
ND
16.5
10.8
7.8
ND
ND
---
12/29/06
---
ND
17.0
17.0
4.2
ND
ND
---
07/12/07
--
ND
17.0
16.0
ND
ND
ND
---
12/19/07
---
ND
17.3
16.9
4.7
ND
ND
ND
07/08/08
---
ND
17.2
17.4
6.5
ND
ND
---
12/17/08
0.23
ND
15.9
15.6
2.6
ND
ND
---
07/09/09
0.23
ND
16.1
17.2
6.1
ND
ND
ND
12/16/09
0.23
ND
15.5
17.7
4.8
ND
ND
---
06/24/10
0.23
ND
8.3
15.7
6.3
ND
ND
---
12/13/10
0.23
ND
17.7
18.2
6.4
ND
ND
---
06/20/11
0.23
ND
16.3
17.2
6.7
ND
ND
---
12/05/11
0.23
ND
14.2
17.0
5.8
ND
ND
---
06/11/12
0.23
ND
12.0
14.8
4.4
ND
ND
ND
12/12/12
0.23
ND
15.8
17.9
4.5
ND
ND
---
05/01/13
0.23
ND
14.0
16.6
3.0
ND
ND
ND
08/05/13
0.23
ND
14.4
15.9
4.6
ND
ND
---
02/24/14
0.23
ND
16.3
2.5
1.4
ND
ND
ND
08/12/14
0.23
ND
15.6
18.3
3.6
ND
ND
ND
03/10/15
0.23
ND
16
17
2.1
ND
ND
ND
08/18/15
0.23
ND
12.8
17.6
4.3
ND
ND
---
02/16/16
0.23
ND
13.5
16.4
1.5
ND
ND
ND
08/09/16
0.23
ND
13.5
16.9
4.2
ND
ND
---
02/13/17
0.23
ND
13.6
18
1.3
ND
ND
---
08/22/17
0.23
ND
14.2
19.9
1.2
ND
ND
---
02/05/18
0.23
ND
13.5
17.3
0.54
ND
ND
---
08/13/18
0.23
ND
14.5
22.2
3.4
ND
ND
---
02/04/19
0.23
ND
13.6
0.35
1.3
ND
ND
---
08/07/19
0.23
ND
10.2
16.9
ND
ND
ND
---
02/12/20
0.23
ND
ND
ND
2.0
0.32
ND
---
08/27/20
0.23
ND
16.1
17.5
4.1
ND
ND
---
02/11/21
0.23
ND
15.1
7.3
2.2
ND
ND
---
08/19/21
0.30
ND
15.4
15.7
4.2
ND
ND
ND
02/16/22
0.28
ND
11.4
4.5
1.3
0.49
ND
NA
9/28/22'
0.28
11.0
15.4
17.7
<1.0
<1.0
<1.0
NA
Appendix D (Page 9 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Chloroethane
12/01/97
---
ND
S
2
2
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=3,000kg/L
11/19/98
---
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
2.2
1.9
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
1.9
1.9
1.5
ND
ND
ND
07/08/08
---
ND
2.2
2.5
1.8
ND
ND
---
12/17/08
0.54
ND
1.6
ND
ND
ND
ND
---
07/09/09
0.54
ND
ND
ND
3.8
ND
ND
ND
12/16/09
0.54
ND
ND
2.2
2.0
ND
ND
---
06/24/10
0.54
ND
ND
2.1
2.0
ND
ND
--
12/13/10
0.54
ND
1.8
2.0
1.7
ND
ND
---
06/20/11
0.54
ND
1.2
2.2
2
ND
ND
---
12/05/11
0.54
ND
1.3
2.0
1.7
ND
ND
---
06/11/12
0.54
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.54
ND
ND
ND
ND
ND
ND
---
05/01/13
0.54
ND
ND
1.9
2.7
ND
ND
ND
08/05/13
0.54
ND
ND
2.0
2.2
ND
ND
---
02/24/14
0.54
ND
1.1
0.82
ND
ND
ND
ND
08/12/14
0.54
ND
1.1
1.5
1.1
ND
ND
ND
03/10/15
0.54
ND
1
1.8
0.81
ND
ND
ND
08/18/15
0.54
ND
1.2
2
3.7
ND
ND
---
02/16/16
0.54
ND
1.1
1.8
0.79
ND
ND
ND
08/09/16
0.54
ND
0.68
2.4
1.5
ND
ND
---
02/13/17
0.54
ND
0.76
1.6
1.1
ND
ND
--
08/22/17
0.54
ND
1.3
2.0
1.6
ND
ND
---
02/05/18
0.54
ND
1.7
1.7
0.68
ND
ND
--
08/13/18
0.54
ND
1.2
2.4
1.4
ND
ND
---
02/04/19
0.49
ND
1.3
ND
0.79
ND
ND
---
08/07/19
0.49
ND
0.94
1.9
1.3
ND
ND
---
02/12/20
0.49
ND
1.6
1.3
1.5
ND
ND
---
08/27/20
0.49
ND
0.87
1.5
1.1
ND
ND
---
02/11/21
0.49
ND
1.2
1
1.3
ND
ND
---
08/19/21
0.70
ND
0.921
1.4
1.2
ND
ND
ND
02/16/22
0.65
ND
1.6
1.4
1.5
ND
ND
NA
9/28/22'
0.65
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Chloromethane
07/09/09
0.11
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.11
ND
ND
ND
ND
ND
ND
---
NC21-=3µg/L
06/24/10
0.11
ND
ND
ND
ND
ND
0.11
---
12/13/10
0.11
ND
ND
ND
ND
ND
ND
---
06/20/11
0.11
ND
ND
ND
ND
ND
ND
---
12/05/11
0.11
ND
ND
ND
ND
ND
ND
---
06/11/12
0.11
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.11
ND
ND
ND
ND
ND
ND
---
05/01/13
0.11
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.11
ND
ND
ND
ND
ND
ND
--
02/24/14
0.11
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.11
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.11
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.11
ND
ND
ND
ND
ND
ND
--
02/16/16
0.11
ND
ND
ND
ND
ND
ND
---
08/09/16
0.11
ND
ND
ND
ND
ND
ND
---
02/13/17
0.11
0.2
ND
0.22
0.23
0.19
0.32
---
08/22/17
0.11
ND
ND
ND
ND
ND
ND
---
02/05/18
0.11
ND
ND
ND
ND
ND
ND
---
08/13/18
0.11
ND
ND
ND
ND
ND
ND
---
02/04/19
0.39
ND
ND
ND
ND
ND
ND
---
08/07/19
0.39
ND
ND
ND
ND
ND
ND
---
02/12/20
0.39
ND
ND
ND
ND
ND
ND
---
08/27/20
0.39
ND
ND
ND
ND
ND
ND
---
02/11/21
0.39
ND
ND
ND
ND
ND
ND
ND
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.54
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.54
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Appendix D (Page 10 of 22)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Chromium
09/08/94
---
8
44
ND
6
48
80
---
12/01/94
---
14
ND
ND
ND
18
ND
---
NC21-= 10 µg/L
02/09/95
---
14
ND
ND
10
ND
ND
---
03/02/95
---
ND
ND
ND
ND
ND
ND
---
11/15/95
---
13
13
ND
ND
ND
ND
---
05/28/96
--
33
ND
ND
ND
ND
ND
---
11/22/96
---
3
ND
ND
ND
ND
3
---
06/17/97
--
57
43
ND
3
2
6
--
12/01/97
---
29
ND
ND
ND
ND
ND
---
05/20/98
--
10
3
N D
N D
12
ND
---
11/19/98
---
17
3
ND
ND
5
ND
---
07/21/99
--
ND
ND
ND
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
---
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
12
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
2.0
ND
ND
ND
ND
1.1
07/08/08
--
ND
0.54
0.58
ND
ND
ND
---
12/17/08
0.4
0.73
1.8
0.96
ND
0.96
0.7
---
07/09/09
0.4
1.2
2.4
1.1
1.6
0.68
0.53
4.8
12/16/09
0.4
1.3
ND
ND
ND
0.95
ND
---
06/24/10
0.4
1.1
3.5
2.8
2.4
1.2
1.4
---
12/13/10
0.4
2.5
1.3
1.8
0.69
0.57
1.2
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
S
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
8.6
ND
ND
ND
ND
ND
12/12/12
S
ND
5.2
ND
ND
ND
ND
---
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
S
ND
ND
ND
ND
ND
ND
---
02/24/14
5
ND
ND
ND
ND
ND
ND
ND
08/12/14
S
ND
ND
ND
ND
ND
ND
---
03/10/15
2.5
ND
ND
ND
ND
ND
ND
---
08/18/15
2.5
ND
2.7
ND
ND
ND
6.7
---
02/16/16
2.5
ND
ND
ND
ND
ND
ND
---
08/09/16
2.5
2.8
2.8
ND
ND
ND
ND
---
02/13/17
2.5
ND
2.6
ND
ND
ND
ND
---
08/22/17
2.5
ND
ND
ND
ND
ND
ND
---
02/05/18
2.5
ND
ND
ND
ND
ND
ND
---
08/13/18
2.5
ND
ND
ND
ND
ND
ND
---
02/04/19
2.5
ND
ND
ND
ND
ND
ND
---
08/07/19
1
ND
ND
ND
ND
ND
ND
---
02/12/20
1
1.5
ND
ND
1.1
ND
ND
---
08/27/20
3.7
ND
ND
ND
ND
ND
ND
---
02/11/21
3.7
4.1
4.0
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
3.7
ND
ND
ND
ND
ND
ND
NA
9/28/22'
3.7
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Cobalt
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
11
ND
13
16
22
ND
---
NC21-=1µg/L
02/09/95
---
20
14
ND
48
39
ND
---
03/02/95
--
16
21
ND
29
121
ND
---
11/15/95
---
20
21
N D
N D
27
N D
---
05/28/96
--
30
16
ND
ND
122
ND
---
11/22/96
---
6
13
ND
4.7
93
ND
---
06/17/97
--
130
38
ND
6
45
3
---
12/01/97
---
32
21
ND
12
36
4
---
05/20/98
--
15
16
2
9
100
3
---
11/19/98
---
21
16
2
7
180
3
---
07/21/99
--
ND
16
ND
ND
100
ND
---
11/16/99
---
ND
15
ND
ND
38
ND
---
05/10/00
--
ND
17
ND
ND
61
ND
--
10/26/00
---
ND
15
ND
ND
ND
ND
---
04/18/01
---
ND
27
ND
ND
74
ND
---
10/27/01
---
ND
12
ND
ND
47
ND
---
06/13/02
--
ND
14
ND
ND
251
ND
--
11/19/02
---
ND
10
ND
ND
57
ND
---
06/27/03
--
ND
15
ND
ND
75
ND
--
12/30/03
---
ND
17
ND
ND
52
ND
---
06/30/04
--
ND
16
ND
ND
31
ND
---
12/29/04
---
ND
11
ND
ND
46
ND
---
06/29/05
--
ND
11
ND
ND
43
ND
---
12/29/05
---
ND
12
ND
ND
30
ND
---
06/28/06
--
ND
ND
ND
ND
72.5
ND
---
12/29/06
---
ND
11.4
ND
ND
37.5
ND
---
07/12/07
--
ND
11.8
ND
2.7
58.4
ND
---
12/19/07
---
2.5
ND
ND
2.0
103
2.6M
8.0M
07/08/08
---
10.3
12.1
2.00
9.0
130
4.82
---
12/17/08
0.6
2.1
11.8
2.30
3.6
43.7
1.60
---
07/09/09
0.6
ND
6.2
ND
ND
100
ND
2.22
12/16/09
0.6
ND
4.7
ND
ND
6.6
ND
---
06/24/10
0.6
ND
16.3
ND
ND
25.0
ND
---
12/13/10
0.6
2.5
15.5
ND
ND
129
ND
---
06/20/11
5
ND
14.2
ND
ND
81.8
ND
--
12/05/11
S
ND
12.7
ND
ND
146
ND
---
01/25/12
5
--
---
--
--
47.5
---
--
06/11/12
S
ND
14.2
ND
ND
101
ND
ND
12/12/12
5
ND
11.3
ND
ND
113
ND
--
OS/01/13
S
ND
24.3
ND
ND
34.0
ND
ND
08/05/13
5
ND
24.7
ND
ND
50.9
ND
--
02/24/14
5
ND
18.4
ND
ND
9.6
ND
ND
08/12/14
5
ND
9.4
ND
ND
46.3
ND
--
03/10/15
2.5
ND
8.7
ND
ND
39.2
ND
---
08/18/15
2.5
ND
9.3
ND
ND
116
ND
---
02/16/16
2.5
ND
10.0
ND
ND
13.1
ND
---
08/09/16
2.5
ND
10.0
ND
ND
144
ND
---
02/13/17
2.5
ND
8.3
ND
ND
78.7
ND
---
08/22/17
2.5
ND
7.4
ND
ND
51.1
ND
--
02/05/18
2.5
ND
8.3
ND
ND
172
ND
---
08/13/18
2.5
ND
10.7
ND
ND
97.7
ND
--
02/04/19
2.5
ND
9.9
ND
ND
24
ND
---
08/07/19
1.1
ND
11.3
ND
ND
127
ND
ND
02/12/20
1.1
ND
7.5
ND
ND
11.4
ND
1.10
08/27/20
3.6
ND
9.7
ND
ND
88.7
ND
ND
02/11/21
3.6
ND
10.8
ND
ND
18.6
ND
3.80
08/19/21
3.6
ND
11.1
ND
ND
91.0
ND
ND
02/16/22
3.6
ND
16.2
6.2
7.6
40.2
3.8
0.26
9/28/22'
3.6
<5.0
17.0
7.7
11.8
37.9
<5.0
<5.0
Appendix D (Page 11 of 22)
Hart & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Copper
09/08/94
---
ND
ND
ND
ND
ND
660
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=I,000µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
--
03/02/95
---
ND
ND
ND
ND
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
ND
32
13
100
ND
--
06/17/97
--
34
350
13
37
28
77
--
12/01/97
---
19
72
14
88
15
34
--
05/20/98
--
12
48
380
41
53
28
--
11/19/98
---
10
ND
410
28
53
14
--
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
11.3
5.500
10.4
1.900
---
07/12/07
--
ND
ND
13.4
7.9
2.60
ND
---
12/19/07
---
2
ND
8.6
3.80
7.00
0.73
5.80
07/08/08
---
0.64
ND
12.1
3.70
8.50
ND
---
12/17/08
0.3
0.8
13.6
10.2
3.90
11.9
0.37
---
07/09/09
0.3
ND
ND
6.3
ND
5.7©
ND
8.8©
12/16/09
0.3
ND
ND
9.2
1.60
5.70
ND
---
06/24/10
0.3
ND
ND
10
1.20
SAM
ND
---
12/13/10
0.3
1.1
ND
13.6
5.80
5.60
0.59
---
06/20/11
5
ND
ND
15.3
8.10
8.7©
ND
---
12/05/11
5
ND
ND
16.9
10.00
TO
ND
---
06/11/12
5
ND
10.7
12.2
6.31a
7AM
ND
ND
12/12/12
5
ND
ND
11.6
8.50
10.4
ND
---
05/01/13
5
ND
ND
13.6
5.8©
9.6©
ND
ND
08/05/13
5
ND
ND
14.3
ND
10.2
ND
---
02/24/14
5
ND
ND
12.2
ND
5.10
ND
ND
08/12/14
5
ND
ND
10.5
ND
ND
ND
---
03/10/15
2.5
ND
ND
8.70
ND
15.5
ND
---
08/18/15
2.5
ND
ND
6.70
5.60
10.1
ND
---
02/16/16
2.5
ND
ND
7.80
ND
5.1
ND
---
08/09/16
2.5
ND
ND
SAM
ND
7.8
ND
---
02/13/17
2.5
ND
ND
6.80
4.30
14.5
9.40
---
08/22/17
2.5
ND
ND
6.50
ND
5.7
4.40
---
02/05/18
2.5
ND
6.5
9.00
5.50
12.4
2.60
---
08/13/18
2.5
ND
5.5
12.2
3.70
48.8
ND
---
02/04/19
2.5
ND
3.0
5.4
8.0
4.3
ND
---
08/07/19
2.1
ND
3.5
6.0
7.2
4.4
2.3
---
02/12/20
2.1
ND
ND
9.8
12.7
3.3
ND
---
08/27/20
4.3
ND
ND
5.3
13.5
5.6
ND
---
02/11/21
4.3
ND
ND
84.8
9.6
ND
ND
---
08/19/21
4.3
13.7
ND
ND
ND
ND
ND
ND
02/16/22
4.3
7.9
ND
ND
ND
ND
ND
NA
9/28/22'
4.3
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Cyanide
07/09/09
5
ND
ND
ND
ND
46.9
ND
ND
09/28/09
5
--
---
---
---
ND
---
---
NC21- = 70 µg/L
12/16/09
---
--
---
---
---
---
---
---
06/24/10
5
ND
ND
ND
ND
ND
ND
---
12/13/10
---
---
---
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
---
--
---
---
06/11/12
5
ND
6.40
ND
ND
8.7
ND
---
12/12/12
---
--
---
---
---
---
---
---
05/01/13
5
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
02/24/14
5
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
ND
ND
ND
ND
ND
ND
03/10/15
5
9.5
7.50
8.50
8.8
11.8
6.60
---
02/16/16
4
ND
ND
ND
---
---
---
---
02/13/17
4
ND
ND
ND
---
---
---
---
08/22/17
4
ND
ND
ND
---
---
---
---
02/05/18
4
ND
ND
ND
--
--
---
---
02/04/19
6
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Delta-BHC
06/11/12
0.05
ND
ND
0.09
ND
ND
ND
---
07/19/12
0.05
---
---
ND
---
---
---
---
NC21-=NE
12/12/12
---
---
---
---
---
---
---
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
---
---
---
---
---
---
---
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
---
---
---
---
---
---
---
---
03/10/15
0.05
ND
ND
ND
--
--
---
---
02/16/16
0.05
ND
ND
ND
---
---
---
---
02/13/17
0.05
ND
ND
ND
--
--
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
--
---
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.013
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Appendix D (Page 12 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dibenz(a,h)anthracene
06/20/11
0.55
ND
ND
ND
ND
ND
1.5
--
12/05/11
---
---
---
---
NC2L=0.005µg/L
06/11/12
0.55
ND
ND
ND
ND
ND
ND
--
12/12/12
---
---
---
---
05/01/13
0.55
ND
ND
ND
ND
ND
ND
--
08/05/13
---
---
---
---
02/24/14
0.55
ND
ND
ND
ND
ND
ND
--
08/12/14
---
---
---
---
03/10/15
0.5
ND
ND
ND
---
---
---
---
02/16/16
0.6
ND
ND
ND
--
--
--
---
02/13/17
0.6
ND
ND
ND
---
---
---
---
08/22/17
2
ND
ND
ND
--
--
--
---
02/05/18
2.1
ND
ND
ND
---
---
---
---
02/04/19
1.9
ND
ND
ND
--
--
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.7
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Dichlorodifluoromethane
02/05/18
0.21
ND
0.36
ND
---
---
---
---
02/04/19
0.23
ND
ND
ND
---
---
---
---
NC21-=1,000WL
02/11/21
0.23
ND
ND
ND
---
---
---
---
02/16/22
0.35
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Diethyl phthalate
02/04/19
2
ND
7.1
ND
---
---
---
---
NC21-=6,000M/L
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Dinoseb
03/10/15
0.061
ND
ND
0.11
---
---
---
---
02/16/16
0.058
ND
ND
ND
---
---
---
---
NC21-=7µg/L
02/13/17
0.057
ND
ND
ND
---
---
---
---
08/22/17
0.062
ND
ND
ND
--
--
---
---
02/05/18
0.061
ND
ND
ND
---
---
---
---
02/04/19
1.2
ND
ND
ND
--
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
NA
NA
NA
NA
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Endosulfan 1
02/04/19
0.05
---
0.078
0.19
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
NC2L=40µg/L
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/20
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.016
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Endrin aldehyde
06/11/12
0.05
ND
ND
0.14
ND
ND
ND
---
12/12/12
0.05
ND
ND
ND
ND
ND
ND
---
NC2L=2µg/L
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
0.05
ND
ND
ND
ND
ND
ND
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
0.05
ND
ND
ND
---
---
---
---
03/10/15
0.05
ND
ND
ND
--
--
--
---
08/18/15
0.05
ND
ND
ND
---
---
---
---
02/16/16
0.05
ND
ND
ND
--
--
--
---
08/09/16
0.05
ND
ND
ND
---
---
---
---
02/13/17
0.05
ND
ND
ND
--
--
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
--
---
---
---
8/7/2019
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.015
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Ethylbenzene
12/17/08
0.3
ND
0.31
ND
ND
ND
ND
---
07/09/09
0.3
ND
ND
ND
ND
ND
ND
ND
NC2L=600µg/L
12/16/09
0.3
ND
ND
ND
ND
ND
ND
---
06/24/10
0.3
ND
ND
ND
ND
ND
ND
---
12/13/10
0.3
ND
ND
ND
ND
ND
ND
---
06/20/11
0.3
ND
ND
ND
ND
ND
ND
---
12/05/11
0.3
ND
ND
ND
ND
ND
ND
---
06/11/12
0.3
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.3
ND
ND
ND
ND
ND
ND
---
05/01/13
0.3
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.3
ND
ND
ND
ND
ND
ND
---
02/24/14
0.3
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.3
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.3
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.3
ND
ND
ND
ND
ND
ND
---
02/16/16
0.3
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.3
ND
ND
ND
ND
ND
ND
---
02/13/17
0.3
ND
ND
ND
ND
ND
ND
---
08/22/17
0.3
ND
ND
ND
ND
ND
ND
---
02/05/18
0.3
ND
ND
ND
ND
ND
ND
---
08/13/18
0.3
ND
ND
ND
ND
ND
ND
---
02/04/19
0.26
ND
ND
ND
ND
ND
ND
---
08/07/19
0.26
ND
ND
ND
ND
ND
ND
---
02/12/20
0.26
ND
ND
ND
ND
ND
ND
---
08/27/20
0.26
ND
ND
ND
ND
ND
ND
---
02/11/21
0.26
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.3
ND
0.4
0.57
ND
ND
ND
NA
9/28/22'
0.3
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Appendix D (Page 13 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Fluorene
06/24/10
3.8
ND
4.3
ND
ND
ND
ND
--
08/12/10
3.1
---
ND
---
---
---
---
--
NC21- = 300 µg/L
12/13/10
---
---
---
---
---
---
---
--
06/20/11
0.2
ND
ND
ND
ND
ND
ND
--
12/05/11
---
---
---
06/11/12
0.21
ND
ND
ND
ND
ND
ND
--
12/12/12
---
---
---
05/01/13
0.21
ND
ND
ND
ND
ND
ND
--
08/05/13
---
---
---
--
02/24/14
0.21
ND
ND
ND
ND
ND
ND
--
08/12/14
---
---
---
---
---
---
---
---
03/10/15
1
ND
ND
ND
--
--
---
---
02/16/16
0.2
ND
ND
ND
---
---
---
---
02/13/17
0.2
ND
ND
ND
--
--
--
---
08/22/17
1.6
ND
ND
ND
---
---
---
---
02/05/18
1.6
ND
ND
ND
--
---
---
---
02/04/19
3
ND
ND
ND
---
---
---
---
02/16/22
1.9
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
gamma-BHC(Lindane)
06/27/03
---
ND
0.085
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
NC2L=0.03µg/L
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
0.05
ND
ND
ND
ND
ND
ND
---
07/09/09
0.05
ND
ND
ND
ND
ND
ND
---
12/16/09
0.01
ND
ND
ND
ND
ND
ND
---
06/24/10
0.00021
ND
ND
0.052
ND
ND
ND
---
08/12/10
0.0002
---
---
ND
---
---
---
---
12/13/10
0.0002
ND
ND
0.013
ND
ND
ND
---
06/20/11
0.0002
ND
ND
0.066
ND
ND
ND
---
07/28/11
0.0002
---
---
ND
--
---
---
---
12/05/11
0.05
ND
ND
ND
ND
ND
ND
---
06/11/12
0.05
ND
ND
ND
ND
ND
ND
---
12/12/12
0.05
ND
ND
ND
ND
ND
ND
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
0.05
ND
ND
ND
ND
ND
ND
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
0.05
ND
ND
ND
---
---
---
---
03/10/15
0.05
ND
ND
ND
--
--
---
---
08/18/15
0.05
ND
ND
ND
---
---
---
---
02/16/16
0.05
ND
ND
ND
--
--
---
---
08/09/16
0.05
ND
ND
ND
---
---
---
---
02/13/17
0.05
ND
ND
ND
---
---
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
--
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.011
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Heptachlor
06/27/03
---
ND
0.03
0.17
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
NC21-=0.008µg/L
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
0.05
ND
ND
ND
ND
ND
ND
---
07/09/09
0.05
ND
ND
ND
ND
ND
ND
---
12/16/09
0.02
ND
ND
ND
ND
ND
ND
---
06/24/10
0.0015
ND
ND
ND
ND
ND
ND
---
12/13/10
0.05
ND
ND
ND
ND
ND
ND
---
06/20/11
0.05
ND
ND
ND
ND
ND
ND
---
12/05/11
0.05
ND
0.062
ND
ND
ND
ND
---
01/25/12
0.05
---
ND
---
--
---
---
---
06/11/12
0.05
ND
ND
ND
ND
ND
ND
---
12/12/12
0.05
ND
ND
ND
ND
ND
ND
---
05/01/13
0.05
ND
ND
ND
ND
ND
ND
---
08/05/13
0.05
ND
ND
ND
ND
ND
ND
---
02/24/14
0.05
ND
ND
ND
ND
ND
ND
---
08/12/14
0.05
ND
ND
ND
--
--
---
---
03/10/15
0.05
ND
ND
ND
---
---
---
---
08/18/15
0.05
ND
ND
ND
--
--
---
---
02/16/16
0.05
ND
ND
ND
---
---
---
---
08/09/16
0.05
ND
ND
ND
--
--
---
---
02/13/17
0.05
ND
ND
ND
---
---
---
---
02/05/18
0.052
ND
ND
ND
---
---
---
---
02/04/19
0.05
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.018
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Appendix D (Page 14 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Indeno(1,2,3-cd)pyrene
06/20/11
0.29
ND
ND
ND
ND
ND
1.3
--
12/05/11
---
---
---
---
NC2L=0.05µg/L
06/11/12
0.29
ND
ND
ND
ND
ND
ND
--
12/12/12
---
---
---
---
05/01/13
0.29
ND
ND
ND
ND
ND
ND
--
08/05/13
---
---
---
---
02/24/14
0.29
ND
ND
ND
ND
ND
ND
--
08/12/14
---
---
---
---
03/10/15
0.5
ND
ND
ND
---
---
---
---
02/16/16
0.3
ND
ND
ND
--
--
--
---
02/13/17
0.3
ND
ND
ND
---
---
---
---
08/22/17
2
ND
ND
ND
--
--
--
---
02/05/18
2.1
ND
ND
ND
---
---
---
---
02/04/19
1.7
ND
ND
ND
--
--
--
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Isobutanol
06/24/10
35
ND
59
ND
ND
ND
ND
---
12/13/10
---
---
---
---
NC21-=NE
06/20/11
35
ND
39.5
ND
ND
ND
ND
---
12/05/11
---
---
---
---
---
---
---
ND
06/11/12
35
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
---
---
---
---
---
---
05/01/13
35
ND
ND
ND
ND
ND
ND
---
08/05/13
---
ND
---
---
---
---
---
---
02/24/14
35
ND
ND
ND
ND
ND
ND
---
08/12/14
35
ND
ND
ND
ND
ND
ND
---
03/10/15
35
ND
ND
ND
--
---
---
---
02/16/16
35
ND
42.5
ND
---
---
---
---
02/13/17
35
ND
ND
ND
--
--
--
---
08/22/17
35
ND
ND
ND
---
---
---
---
02/05/18
35
ND
ND
ND
--
---
---
---
02/04/19
66.4
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
66.4
ND
ND
ND
---
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
52.3
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Lead
09/08/94
---
ND
13
ND
ND
30
36
---
12/01/94
---
11
ND
ND
ND
36
ND
---
NC21-=15µg/L
02/09/95
---
ND
ND
ND
10
37
ND
---
03/02/95
--
ND
ND
ND
ND
44
ND
---
11/15/95
---
ND
ND
ND
ND
ND
ND
---
05/28/96
--
ND
ND
ND
ND
42
ND
---
11/22/96
---
ND
ND
ND
ND
13
ND
---
06/17/97
--
20
29
ND
ND
13
ND
---
12/01/97
---
8
14
ND
5
14
ND
---
05/20/98
--
ND
6
ND
6
21
ND
---
11/19/98
---
5
ND
ND
ND
58
ND
---
07/21/99
--
ND
12
14
ND
ND
ND
---
11/16/99
---
ND
ND
ND
ND
ND
ND
---
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
--
11
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
12
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
2.1
---
07/12/07
--
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
--
ND
ND
ND
ND
ND
ND
---
12/17/08
4
ND
ND
ND
ND
ND
ND
---
07/09/09
4
ND
ND
ND
ND
ND
ND
ND
12/16/09
4
ND
ND
ND
ND
ND
ND
---
06/24/10
4
ND
ND
ND
ND
ND
ND
---
12/13/10
4
ND
ND
ND
ND
ND
ND
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
---
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
ND
ND
ND
ND
---
02/24/14
5
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
ND
ND
ND
ND
ND
---
03/10/15
2.5
ND
ND
ND
ND
ND
ND
---
08/18/15
2.5
ND
ND
ND
ND
ND
ND
---
02/16/16
2.5
ND
ND
ND
ND
ND
ND
---
08/09/16
2.5
ND
5.10
ND
ND
ND
ND
---
02/13/17
2.5
ND
ND
ND
ND
ND
ND
---
08/22/17
2.5
ND
2.80
ND
ND
ND
ND
---
02/05/18
2.5
ND
ND
ND
ND
ND
ND
---
08/13/18
2.5
ND
ND
ND
ND
4.6
ND
---
02/04/19
2.5
ND
ND
ND
ND
ND
ND
---
08/07/19
1.6
ND
2
ND
ND
ND
ND
---
02/12/20
1.6
1.9
2.1
2.1
2.8
3.1
2.3
---
08/27/20
4.5
ND
ND
ND
ND
ND
ND
---
02/11/21
4.5
ND
ND
ND
ND
ND
ND
---
08/19/21
4.5
ND
4.71
ND
ND
ND
ND
ND
02/16/22
4.5
ND
6.6
5.4
6.4
ND
ND
NA
9/28/22'
4.5
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Appendix D (Page 15 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Mercury
12/01/97
---
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
NC21-=1µg/L
11/16/99
---
ND
0.59
0.65
0.65
0.76
ND
--
05/10/00
---
--
ND
ND
ND
ND
---
--
10/26/00
---
--
ND
ND
ND
ND
---
--
04/18/01
--
-
ND
ND
ND
ND
---
---
06/13/02
---
--
ND
ND
ND
ND
---
---
06/27/03
--
-
ND
ND
ND
ND
---
---
12/30/03
---
---
---
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
--
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
--
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
--
---
07/12/07
---
ND
ND
ND
ND
ND
ND
--
12/19/07
---
--
---
---
---
---
---
N D
07/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
---
---
---
--
07/09/09
0.07
ND
ND
ND
ND
ND
ND
--
12/16/09
---
---
---
---
06/24/10
0.07
ND
ND
ND
ND
ND
0.098
---
12/13/10
---
---
---
---
06/20/11
0.1
ND
ND
ND
ND
ND
ND
---
12/05/11
---
--
---
---
---
---
---
---
06/11/12
0.1
ND
ND
ND
ND
ND
ND
ND
12/12/12
---
--
---
---
---
---
---
---
05/01/13
0.1
ND
ND
ND
ND
ND
ND
---
08/05/13
---
--
---
---
---
---
---
---
02/24/14
0.1
ND
ND
ND
ND
ND
ND
ND
08/12/14
---
--
---
---
---
---
---
---
03/10/15
0.1
ND
ND
ND
---
---
---
---
02/16/16
0.1
ND
ND
ND
---
---
---
---
02/13/17
0.1
ND
ND
ND
--
--
---
---
08/22/17
0.1
ND
ND
ND
---
---
---
---
02/05/18
0.1
ND
ND
ND
--
--
---
---
02/04/19
0.1
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
0.12
ND
ND
ND
---
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.12
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Methylene Chloride
07/09/09
0.97
ND
ND
ND
ND
ND
ND
ND
12/16/09
0.97
ND
ND
ND
ND
ND
ND
---
NC21-=5µg/L
06/24/10
0.97
ND
19
ND
ND
ND
ND
---
08/12/10
0.97
---
ND
---
---
---
---
---
12/13/10
0.97
ND
ND
ND
ND
ND
ND
--
06/20/11
0.97
ND
ND
ND
ND
ND
ND
---
12/05/11
0.97
ND
ND
ND
ND
ND
ND
---
06/11/12
0.97
ND
ND
---
ND
ND
ND
ND
12/12/12
0.97
ND
ND
ND
ND
ND
ND
---
05/01/13
0.97
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.97
ND
ND
ND
ND
ND
ND
---
02/24/14
0.97
1.0
ND
ND
ND
ND
ND
ND
08/12/14
0.97
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.97
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.97
1.3
1.1
1.6
ND
ND
ND
ND
02/16/16
0.97
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.97
ND
ND
1.0
ND
ND
ND
---
02/13/17
0.97
ND
ND
ND
ND
ND
ND
---
08/22/17
0.97
ND
ND
ND
ND
ND
ND
---
02/05/18
0.97
ND
ND
ND
ND
ND
ND
---
08/13/18
0.97
ND
ND
ND
ND
ND
ND
---
02/04/19
3.7
ND
ND
ND
ND
ND
ND
---
08/07/19
3.7
ND
ND
ND
ND
ND
ND
---
02/12/20
3.7
ND
ND
ND
ND
ND
ND
---
08/27/20
3.7
ND
ND
ND
ND
ND
ND
--
02/11/21
3.7
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
2
ND
ND
ND
ND
ND
ND
NA
9/28/22'
2.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Naphthalene
07/08/08
---
ND
3.8
ND
ND
ND
---
---
12/17/08
---
---
---
---
NC2L=6µg/L
07/09/09
0.24
ND
2.4
ND
ND
ND
---
---
12/16/09
---
---
---
---
06/24/10
0.24
ND
7.4
ND
ND
ND
---
---
12/13/10
---
---
---
---
06/20/11
0.24
ND
4.6
ND
ND
ND
---
---
12/05/11
---
---
---
---
06/11/12
0.2
ND
4.6
ND
ND
ND
ND
ND
12/12/12
---
---
---
---
05/01/13
0.24
ND
5.1
ND
ND
ND
---
---
08/05/13
---
---
---
---
02/24/14
0.24
ND
5.8
ND
ND
ND
---
---
08/12/14
---
---
---
---
03/10/15
0.2
ND
5.4
ND
---
---
---
---
02/16/16
0.2
ND
5.7
ND
---
---
---
---
02/13/17
0.2
ND
6.1
ND
---
---
---
---
08/22/17
0.2
ND
7.0
0.45
--
--
---
---
02/05/18
0.2
ND
5.7
ND
---
---
---
---
02/04/19
0.4
ND
4.2
ND
--
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
0.4
ND
3.7
ND
---
---
---
---
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
0.12
ND
ND
ND
NA
NA
NA
NA
9/28/22'
0.64
<1.0
3.6
<1.0
<1.0
<1.0
<1.0
NA
Appendix D (Page 16 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Nickel
09/08/94
---
ND
ND
ND
ND
ND
ND
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=100µg/L
02/09/95
---
ND
72
ND
ND
ND
ND
--
03/02/95
---
ND
100
ND
ND
ND
ND
--
11/15/95
---
ND
61
ND
ND
ND
ND
--
05/28/96
--
ND
85
ND
ND
ND
ND
--
11/22/96
---
ND
72
ND
ND
ND
ND
--
06/17/97
--
75
98
ND
ND
ND
ND
--
12/01/97
---
ND
89
ND
ND
ND
ND
--
05/20/98
--
ND
91
ND
ND
ND
ND
--
11/19/98
---
ND
83
ND
ND
ND
ND
--
07/21/99
--
ND
109
ND
ND
ND
ND
--
11/16/99
---
ND
122
ND
ND
ND
ND
--
05/10/00
--
ND
104
ND
ND
ND
ND
--
10/26/00
---
ND
93
ND
ND
ND
ND
---
04/18/01
--
ND
107
ND
ND
ND
ND
---
10/27/01
---
ND
92
ND
ND
ND
ND
---
06/13/02
---
ND
98
ND
ND
ND
ND
---
11/19/02
---
ND
74
ND
ND
ND
ND
---
06/27/03
--
ND
85
ND
ND
ND
ND
---
12/30/03
---
ND
100
ND
ND
ND
ND
---
06/30/04
--
ND
120
ND
ND
ND
ND
---
12/29/04
---
ND
100
ND
ND
ND
ND
---
06/29/05
--
ND
150
ND
ND
ND
ND
---
12/29/05
---
ND
96.0
ND
ND
ND
ND
---
06/28/06
--
ND
88.7
ND
ND
ND
ND
---
12/29/06
---
ND
94.7
30.1
14.2
8.9
ND
---
07/12/07
--
ND
99.0
30.60
13.9
13.7
ND
---
12/19/07
---
ND
83.4
23.7
11
18.3
ND
11.4
07/08/08
---
ND
76.0
28.10
11.5
27
ND
---
12/17/08
1.7
ND
75.5
27.80
12.2
11.0
ND
---
07/09/09
1.7
2.2
93.5
29.40
11.7
23.2
ND
13.1
12/16/09
1.7
ND
81.2
28.20
11.8
2.6
ND
---
06/24/10
1.7
NO
76.3
19.70
9.0
7.0
4.50
---
12/13/10
1.7
ND
83.0
23.50
6.8
20.7
ND
---
06/20/11
5
NO
78.8
30.10
11.2
15.3
ND
---
12/05/11
5
ND
89.1
32.80
11.7
24.3
ND
---
06/11/12
5
ND
91.8
28.90
10.0
17.3
ND
ND
12/12/12
5
ND
91.8
29.20
9.3
21.1
ND
---
05/01/13
5
ND
89.6
31.90
10.4
5.7
ND
ND
08/05/13
5
ND
87.9
28.10
9.0
8.4
ND
---
02/24/14
5
ND
83.1
16.7©
10.4
ND
ND
ND
08/12/14
5
ND
97.9
29.00
12.9
13.2
ND
---
03/10/15
2.5
ND
91.9
32.90
12.3
8.2
ND
---
08/18/15
2.5
ND
98.0
28.01a
11.9
26.2
SAM
---
02/16/16
2.5
ND
92.0
35.41d
12.7
3.7
ND
---
08/09/16
2.5
3.3
88.9
29.00
12.2
30.7
ND
---
02/13/17
2.5
NO
89.6
30.411
13.5
16.2
NO
---
08/22/17
2.5
ND
84.2
28.20
12.3
13.5
ND
---
02/05/18
2.5
ND
87.6
29.811
11.7
28.5
ND
---
08/13/18
2.5
ND
88.9
29.00
12.3
21.9
ND
---
02/04/19
2.5
ND
85.7
17.4
10.7
5.5
ND
---
08/07/19
0.9
ND
92.6
27.8
11.7
18.7
ND
---
02/12/20
0.9
1.1
89.9
20.5
13.2
3.4
ND
---
08/27/20
3.5
ND
99.1
19.5
12.2
18.1
ND
---
02/11/21
3.5
ND
91.8
21.4
13.5
3.9
ND
---
08/19/21
3.5
3.5 J
100
24.8
15.1
15.9
N D
7.1
02/16/22
3.5
4.8
99.3
19.9
16.2
9.1
ND
NA
9/28/22'
3.5
<5.0
101
31.0
15.2
10.9
<5.0
NA
N-N itroso-d i-n-butylamine
02/24/14
7.5
ND
ND
ND
8.6
ND
ND
ND
08/12/14
---
---
---
---
---
---
---
---
NC2L= NE
03/10/15
1.3
ND
ND
ND
---
---
---
---
02/16/16
2.2
ND
ND
ND
---
---
---
---
02/13/17
2.2
ND
ND
ND
---
--
---
---
08/22/17
1.6
ND
ND
ND
---
---
---
---
02/05/18
1.6
ND
ND
ND
---
--
---
---
02/04/19
2.2
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Phorate
04/18/01
---
---
3.2
ND
ND
ND
---
---
10/27/01
---
ND
8.1
ND
ND
ND
ND
---
NC21-=1µg/L
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
---
---
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
---
---
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
--
---
---
---
---
---
---
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
---
---
---
---
07/09/09
6.6
ND
ND
ND
ND
ND
ND
---
12/16/09
---
---
---
---
06/24/10
6.5
ND
ND
ND
ND
ND
ND
---
12/13/10
---
---
---
---
06/20/11
5.4
ND
ND
ND
ND
ND
ND
---
12/05/11
---
---
---
---
06/11/12
5.4
ND
ND
ND
ND
ND
ND
---
12/12/12
---
---
---
---
05/01/13
5.4
ND
ND
ND
ND
ND
ND
---
08/05/13
---
--
---
---
02/24/14
5.4
---
ND
ND
ND
ND
ND
---
08/12/14
---
--
---
---
03/10/15
0.8
ND
ND
ND
---
---
---
---
02/16/16
1.1
ND
---
ND
--
--
---
---
02/13/17
1.1
ND
ND
ND
---
---
---
---
08/22/17
1.7
ND
ND
ND
---
---
---
---
02/05/18
1.8
ND
ND
ND
---
---
---
---
02/04/19
1.1
ND
ND
ND
---
---
---
---
08/07/19
NA
NA
NA
NA
NA
NA
NA
NA
02/12/20
NA
NA
NA
NA
NA
NA
NA
NA
08/27/20
NA
NA
NA
NA
NA
NA
NA
NA
02/11/21
NA
NA
NA
NA
NA
NA
NA
NA
08/19/21
NA
NA
NA
NA
NA
NA
NA
NA
02/16/22
2.6
ND
ND
ND
NA
NA
NA
NA
9/28/22'
NA
NA
NA
NA
NA
NA
NA
NA
Appendix D (Page 17 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Selenium
09/08/94
---
ND
ND
ND
ND
ND
ND
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=20µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
--
03/02/95
---
ND
ND
ND
ND
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
ND
ND
ND
ND
ND
--
06/17/97
--
ND
ND
ND
ND
ND
ND
--
12/01/97
---
ND
ND
ND
ND
ND
ND
--
05/20/98
--
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
07/21/99
--
ND
ND
ND
ND
36
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
--
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
--
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
06/30/04
--
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
ND
ND
ND
ND
ND
--
06/29/05
--
ND
ND
ND
ND
ND
ND
--
12/29/05
---
ND
ND
ND
ND
ND
ND
--
06/28/06
--
ND
ND
ND
ND
ND
ND
--
12/29/06
---
ND
ND
ND
ND
ND
ND
--
07/12/07
--
ND
ND
ND
ND
ND
ND
--
12/19/07
---
ND
11.5
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
--
12/17/08
3.8
4.8
5.1
4.80
ND
ND
ND
--
07/09/09
3.8
ND
ND
4.20
ND
ND
ND
ND
12/16/09
3.8
ND
ND
ND
5.1
ND
ND
---
06/24/10
3.8
ND
ND
ND
ND
ND
ND
---
12/13/10
3.8
ND
ND
ND
ND
ND
ND
---
06/20/11
10
ND
ND
ND
ND
ND
ND
---
12/05/11
10
ND
ND
ND
ND
ND
ND
---
06/11/12
10
ND
ND
ND
ND
ND
ND
ND
12/12/12
10
ND
ND
ND
ND
ND
ND
---
05/01/13
10
ND
ND
ND
ND
ND
ND
ND
08/05/13
10
ND
ND
ND
ND
ND
ND
---
02/24/14
10
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
ND
ND
ND
ND
ND
ND
---
03/10/15
5
ND
ND
ND
ND
ND
ND
---
08/18/15
5
ND
ND
ND
ND
ND
ND
---
02/16/16
5
ND
ND
ND
ND
ND
ND
---
08/09/16
5
ND
ND
ND
ND
ND
ND
---
02/13/17
5
ND
ND
ND
ND
ND
ND
---
08/22/17
5
ND
ND
ND
ND
ND
ND
---
02/05/18
5
ND
ND
ND
ND
ND
ND
---
08/13/18
5
ND
ND
ND
ND
ND
ND
---
02/04/19
5
ND
ND
ND
ND
ND
ND
---
08/07/19
4.7
ND
ND
ND
ND
ND
ND
---
02/12/20
4.7
ND
ND
ND
ND
ND
ND
---
08/27/20
4.7
ND
ND
ND
ND
ND
ND
---
02/11/21
4.7
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
4.7
ND
7.7
ND
5.8
ND
ND
NA
9/28/22'
4.7
<10.0
4.9.1
<10.0
<10.0
<10.0
<10.0
NA
Silver
09/08/94
---
ND
ND
ND
ND
ND
ND
---
12/01/94
---
ND
ND
ND
ND
ND
ND
---
NC21-=20µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
---
03/02/95
---
ND
ND
ND
ND
ND
ND
---
11/15/95
--
ND
ND
ND
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
--
ND
ND
ND
ND
ND
ND
---
06/17/97
---
ND
ND
ND
ND
ND
ND
---
12/01/97
--
ND
8
ND
ND
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
--
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
15
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
0.57
0.6
0.55
ND
0.33
ND
07/08/08
---
ND
2.7
2.3
1.1
0.22
0.69
---
12/17/08
0.1
0.13
1.8
1.4
0.85
0.12
0.51
---
07/09/09
0.1
ND
0.84
0.63
0.45
ND
0.11
ND
12/16/09
0.1
0.12
2.0
1.6
1.0
0.12
0.52
---
06/24/10
0.1
ND
0.38
0.33
0.35
ND
ND
---
12/13/10
0.1
0.15
1.3
0.99
0.45
ND
ND
---
06/20/11
5
ND
ND
ND
ND
ND
ND
---
12/05/11
5
ND
ND
ND
ND
ND
ND
---
06/11/12
5
ND
ND
ND
ND
ND
ND
ND
12/12/12
5
ND
ND
ND
ND
ND
ND
---
05/01/13
5
ND
ND
ND
ND
ND
ND
ND
08/05/13
5
ND
ND
ND
ND
ND
ND
---
02/24/14
5
ND
ND
ND
ND
ND
ND
ND
08/12/14
5
ND
ND
ND
ND
ND
ND
---
03/10/15
2.5
ND
ND
ND
ND
ND
ND
---
08/18/15
2.5
ND
ND
ND
ND
ND
ND
---
02/16/16
2.5
ND
ND
ND
ND
ND
ND
---
08/09/16
2.5
ND
ND
ND
ND
ND
ND
---
02/13/17
2.5
ND
ND
ND
ND
ND
ND
---
08/22/17
2.5
ND
ND
ND
ND
ND
ND
---
02/05/18
2.5
ND
ND
ND
ND
ND
ND
---
08/13/18
2.5
ND
ND
ND
ND
ND
ND
---
02/04/19
2.5
ND
ND
ND
ND
ND
ND
---
08/07/19
2.5
ND
ND
ND
ND
ND
ND
---
02/12/20
2.5
ND
ND
ND
ND
ND
ND
---
08/27/20
2.5
ND
ND
ND
ND
ND
ND
---
02/11/21
2.5
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
2.5
ND
ND
ND
ND
ND
ND
NA
9/28/22'
2.5
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Appendix D (Page 18 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Thallium
09/08/94
---
ND
ND
ND
ND
ND
ND
--
12/01/94
---
ND
ND
ND
ND
ND
ND
--
NC21-=2µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
--
03/02/95
---
ND
ND
ND
ND
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
ND
ND
ND
ND
ND
ND
--
11/22/96
---
ND
ND
ND
ND
ND
ND
--
06/17/97
--
ND
3
ND
ND
ND
ND
--
12/01/97
---
ND
ND
ND
ND
ND
ND
--
05/20/98
--
ND
ND
ND
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
--
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/27/01
---
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
---
ND
ND
ND
ND
ND
ND
--
06/27/03
--
ND
ND
ND
ND
ND
ND
--
12/30/03
---
ND
ND
ND
ND
ND
ND
--
06/30/04
--
ND
ND
ND
ND
ND
ND
--
12/29/04
---
ND
30
ND
ND
ND
ND
--
06/29/05
--
ND
22
13
ND
ND
ND
--
12/29/05
---
ND
23
20
ND
ND
ND
--
06/28/06
--
ND
25.7
12.6
ND
ND
ND
--
12/29/06
---
ND
ND
ND
ND
ND
ND
--
07/12/07
--
ND
ND
ND
ND
ND
ND
--
12/19/07
---
ND
4.0
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
ND
ND
ND
ND
---
12/17/08
3
ND
3.2
3.2
ND
ND
ND
---
07/09/09
3
ND
ND
ND
4.1
ND
ND
ND
12/16/09
3
ND
ND
ND
ND
ND
ND
---
06/24/10
3
ND
ND
5.2
3.1
ND
ND
---
12/13/10
3
ND
ND
7.7
ND
ND
ND
---
06/20/11
5.4
ND
ND
ND
ND
ND
ND
---
12/05/11
5.4
ND
ND
ND
ND
ND
ND
---
06/11/12
5.4
ND
ND
ND
ND
ND
ND
ND
12/12/12
5.4
ND
ND
ND
ND
ND
ND
---
05/01/13
5.4
ND
ND
ND
ND
ND
ND
ND
08/05/13
5.4
ND
ND
ND
ND
ND
ND
---
02/24/14
5.4
ND
ND
ND
ND
ND
ND
ND
08/12/14
5.4
ND
ND
ND
ND
ND
ND
---
03/10/15
5
ND
ND
ND
ND
ND
ND
---
08/18/15
5
ND
ND
ND
ND
ND
ND
---
02/16/16
5
ND
ND
ND
ND
ND
ND
---
08/09/16
5
ND
ND
ND
ND
ND
ND
---
02/13/17
0.02
0.023
0.04
ND
ND
0.035
ND
---
08/22/17
0.02
ND
ND
ND
ND
0.033
ND
---
02/05/18
0.03
ND
ND
ND
ND
0.047
ND
---
08/13/18
0.02
ND
ND
ND
ND
0.037
ND
---
02/04/19
0.06
ND
ND
ND
ND
ND
ND
---
08/07/19
0.06
ND
ND
ND
ND
ND
ND
---
02/12/20
0.06
ND
ND
ND
ND
ND
ND
---
08/27/20
0.05
ND
ND
ND
ND
ND
ND
---
02/11/21
0.05
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
0.069.1
02/16/22
0.05
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.05
<0.47
<2.4
<0.47
<0.47
<0.47
<0.47
NA
Tin
12/01/97
---
ND
ND
ND
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=2,000Vg/L
11/16/99
---
ND
ND
ND
ND
ND
ND
---
10/26/00
---
--
ND
ND
ND
ND
---
---
04/18/01
--
-
ND
ND
ND
ND
---
---
10/27/01
---
--
---
---
06/13/02
--
ND
ND
ND
ND
ND
ND
---
11/19/02
---
--
---
---
06/27/03
--
ND
149
127
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
41.1
14.4
3.2
ND
ND
---
07/12/07
---
ND
35.2
13.9
5.2
ND
ND
---
12/19/07
---
ND
33.6
7.4
ND
ND
ND
ND
07/08/08
---
4.4
28.6
15.1
5.4
3
3.6
---
12/17/08
1.8
ND
22.5
9.2
ND
ND
ND
---
07/09/09
1.8
ND
21.4
8.6
ND
ND
ND
---
12/16/09
1.8
ND
26.3
10.7
ND
ND
ND
---
06/24/10
1.8
ND
23.4
10.7
3.2
2.2
1.9
---
12/13/10
1.8
ND
30.3
12.1
5.8
ND
ND
---
06/20/11
5
ND
26.8
13.8
ND
ND
ND
---
12/05/11
5
ND
25.8
13.9
ND
ND
ND
---
06/11/12
5
ND
22.2
9
ND
ND
ND
ND
12/12/12
5
ND
30.0
13.2
ND
ND
ND
---
05/01/13
5
ND
25.8
12.2
ND
ND
ND
---
08/05/13
5
ND
22.7
12.5
ND
ND
ND
---
02/24/14
5
ND
26.7
11.7
9.8
ND
ND
ND
08/12/14
5
ND
30.7
8.2
ND
ND
ND
---
03/10/15
2.5
ND
28.7
11.1
ND
ND
ND
---
08/18/15
2.5
ND
27.7
7.5
ND
ND
ND
---
02/16/16
2.5
ND
28.6
10.4
---
--
---
---
08/09/16
2.5
ND
20.9
5.4
---
---
---
---
02/13/17
2.5
ND
25.5
7.8
---
--
---
---
08/22/17
2.5
ND
17.2
5.3
---
---
---
---
02/05/18
2.5
ND
20.3
9.5
--
--
--
--
08/13/18
2.5
ND
22.2
7.4
---
---
ND
---
02/04/19
2.5
ND
24.8
5.5
--
--
--
--
08/07/19
1.6
ND
29.3
9.7
---
---
---
---
02/12/20
1.6
ND
26.0
5.8
--
--
--
--
08/27/20
4.7
ND
27.6
5.1
---
---
---
---
02/11/21
4.7
ND
30.1
8.0
---
---
---
---
08/19/21
4.7
ND
26.2
6.5
ND
---
ND
---
02/16/22
4.7
ND
28.2
11.2
NA
NA
NA
NA
9/28/22'
4.7
<5.0
52.1
34.8
20.8
14.6
11.6
NA
Appendix D (Page 19 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt& Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Toluene
05/20/98
---
ND
ND
8.1
ND
ND
ND
--
11/19/98
---
ND
ND
ND
ND
ND
ND
--
NC21-=600µg/L
07/21/99
---
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
---
ND
ND
ND
ND
ND
ND
--
04/18/01
--
ND
ND
ND
ND
ND
ND
--
10/26/01
---
ND
ND
ND
ND
ND
ND
--
10/27/01
--
ND
ND
ND
ND
ND
ND
--
06/13/02
---
ND
ND
ND
ND
ND
ND
--
11/19/02
--
ND
ND
ND
ND
ND
ND
--
06/27/03
---
ND
ND
ND
ND
ND
ND
--
12/30/03
--
ND
ND
ND
ND
ND
ND
--
06/30/04
---
ND
ND
ND
ND
ND
ND
--
12/29/04
--
ND
ND
ND
ND
ND
ND
--
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
---
ND
0.49
ND
ND
ND
ND
---
12/19/07
--
ND
0.51
ND
ND
ND
ND
ND
07/08/08
---
ND
0.39
ND
ND
1.3
ND
---
12/17/08
0.26
1.4
1.6
ND
ND
11.7
ND
---
07/09/09
0.26
ND
0.46
ND
ND
ND
ND
ND
12/16/09
0.26
ND
0.42
ND
ND
ND
ND
---
06/24/10
0.26
ND
ND
ND
ND
ND
ND
---
12/13/10
0.26
ND
0.54
ND
ND
ND
ND
---
06/20/11
0.26
ND
0.34
ND
ND
ND
ND
---
12/05/11
0.26
ND
0.28
ND
ND
0.3
ND
---
06/11/12
0.26
ND
0.28
ND
ND
ND
ND
ND
12/12/12
0.26
ND
0.29
ND
ND
0.36
ND
---
05/01/13
0.26
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.26
ND
0.29
ND
ND
ND
ND
---
02/24/14
0.26
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.26
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.26
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.26
ND
ND
ND
ND
ND
ND
---
02/16/16
0.26
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.26
ND
0.33
ND
ND
ND
ND
---
02/13/17
0.26
ND
ND
ND
ND
ND
ND
---
08/22/17
0.26
ND
ND
ND
ND
ND
ND
--
02/05/18
0.26
ND
ND
ND
ND
ND
ND
---
08/13/18
0.26
ND
ND
ND
ND
0.44
ND
--
02/04/19
0.24
ND
ND
ND
ND
ND
ND
---
08/07/19
0.24
ND
ND
ND
ND
ND
ND
--
02/12/20
0.24
ND
ND
ND
ND
ND
ND
---
08/27/20
0.24
ND
ND
ND
ND
ND
ND
---
02/11/21
0.24
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.48
ND
1.1
1.9
ND
ND
ND
NA
9/28/22'
0.48
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
trans-1,4-Dichloro-2-butene
05/20/98
---
ND
ND
5.1
ND
ND
ND
---
11/19/98
---
ND
ND
ND
ND
ND
ND
---
NC21-=NE
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
--
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
---
ND
ND
ND
ND
ND
ND
---
07/12/07
--
ND
ND
ND
ND
ND
ND
--
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
--
ND
ND
ND
ND
ND
ND
--
12/17/08
1
ND
ND
ND
ND
ND
ND
---
07/09/09
1
ND
ND
ND
ND
ND
ND
ND
12/16/09
1
ND
ND
ND
ND
ND
ND
---
06/24/10
1
ND
ND
ND
ND
ND
ND
---
12/13/10
1
ND
ND
ND
ND
ND
ND
---
06/20/11
1
ND
ND
ND
ND
ND
ND
---
12/05/11
1
ND
ND
ND
ND
ND
ND
---
06/11/12
1
ND
ND
ND
ND
ND
ND
ND
12/12/12
1
ND
ND
ND
ND
ND
ND
---
05/01/13
1
ND
ND
ND
ND
ND
ND
ND
08/05/13
1
ND
ND
ND
ND
ND
ND
---
02/24/14
1
ND
ND
ND
ND
ND
ND
ND
08/12/14
1
ND
ND
ND
ND
ND
ND
ND
03/10/15
1
ND
ND
ND
ND
ND
ND
ND
08/18/15
1
ND
ND
ND
ND
ND
ND
---
02/16/16
1
ND
ND
ND
ND
ND
ND
ND
08/09/16
1
ND
ND
ND
ND
ND
ND
---
02/13/17
1
ND
ND
ND
ND
ND
ND
---
08/22/17
1
ND
ND
ND
ND
ND
ND
---
02/05/18
1
ND
ND
ND
ND
ND
ND
---
08/13/18
1
ND
ND
ND
ND
ND
ND
---
02/04/19
0.5
ND
ND
ND
ND
ND
ND
---
08/07/19
0.54
ND
ND
ND
ND
ND
ND
---
02/12/20
0.54
ND
ND
ND
ND
ND
ND
---
08/27/20
0.54
ND
ND
ND
ND
ND
ND
---
02/11/21
0.54
ND
ND
ND
ND
ND
ND
---
08/19/21
NR
ND
ND
ND
ND
ND
ND
ND
02/16/22
0.56
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.56
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Trichlorofluoromethane
1 9/28/22
0.30
1 <1.0
1 1.4
1 <1.0
I <1.0
I <1.0
I <1.0
NA
Appendix D (Page 20 of 22)
C:\UaeraVcmckinne�1Deak[ap\Homer Historic Tables Hatt & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Vanadium
09/08/94
---
ND
ND
ND
ND
ND
130
--
12/01/94
---
63
ND
ND
45
ND
ND
--
NC21-=7µg/L
02/09/95
---
ND
ND
ND
ND
ND
ND
--
03/02/95
---
41
ND
ND
45
ND
ND
--
11/15/95
---
ND
ND
ND
ND
ND
ND
--
05/28/96
--
83
ND
ND
ND
ND
ND
--
11/22/96
---
7
17
ND
21
ND
ND
--
06/17/97
--
450
560
ND
19
ND
ND
--
12/01/97
---
62
88
ND
41
ND
10
--
05/20/98
--
25
15
ND
10
5
ND
--
11/19/98
---
33
29
5
16
9
5
--
07/21/99
--
ND
ND
ND
ND
ND
ND
--
11/16/99
---
ND
ND
ND
ND
ND
ND
--
05/10/00
--
ND
ND
ND
ND
ND
ND
--
10/26/00
---
ND
ND
ND
ND
ND
ND
---
04/18/01
--
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
---
ND
ND
ND
ND
ND
ND
---
06/27/03
--
ND
ND
ND
ND
ND
ND
---
12/30/03
---
ND
ND
ND
ND
ND
ND
---
06/30/04
--
ND
ND
ND
ND
ND
ND
---
12/29/04
---
ND
ND
ND
ND
ND
ND
---
06/29/05
--
ND
ND
ND
ND
ND
ND
---
12/29/05
---
ND
ND
ND
ND
ND
ND
---
06/28/06
--
ND
ND
ND
ND
ND
ND
---
12/29/06
---
2.7E
ND
ND
14.5
ND
1.0E
---
07/12/07
--
ND
ND
ND
19.41M
ND
ND
---
12/19/07
---
2.2E
2.2E
ND
15.71M
3
1.2E
4.00
07/08/08
---
2.6E
2.4E
ND
14.6©
1.4E
1.2E
---
12/17/08
0.2
1.9E
2.3E
ND
13.91B
2.50
1.2E
---
07/09/09
0.2
3.9E
9.7E
2.5E
18.41fl
2.9E
2.2E
8.5E
12/16/09
0.2
2.00
4.4E
1.3E
14.0E
2.20
1.5E
---
06/24/10
0.2
1.8E
4.4E
1.5E
13.3E
2.2E
1.3E
---
12/13/10
0.2
3.2E
3.6E
0.35E
16.60
1.80
1.00
---
06/20/11
5
ND
ND
ND
14.51fl
ND
ND
---
12/05/11
5
ND
ND
ND
13.51fl
ND
ND
---
06/11/12
5
ND
18.0E
ND
12.31fl
ND
ND
ND
12/12/12
5
ND
ND
ND
13.61N
ND
ND
---
05/01/13
5
ND
ND
ND
6.3E
ND
ND
ND
08/05/13
5
ND
ND
ND
10.2E
ND
ND
---
02/24/14
5
ND
ND
ND
12.9©
ND
ND
ND
08/12/14
5
ND
ND
ND
18.61fl
ND
ND
---
03/10/15
2.5
3.1E
11.60
6.2E
13.4M
ND
ND
---
08/18/15
2.5
3.4E
6.8E
3.6E
19.6E
2.80
ND
---
02/16/16
2.5
2.7E
3.3E
ND
14.0
ND
ND
---
08/09/16
2.5
2.5E
3.5E
ND
21.2E
ND
ND
---
02/13/17
2.5
4.4E
4.1E
ND
18.40
3.0E
2.9E
---
08/22/17
2.5
ND
6.6E
ND
20.60
2.6E
ND
---
02/05/18
2.5
3.6E
4.4E
ND
17.6©
ND
2.5
---
08/13/18
2.5
ND
5.3E
ND
20.4E
2.9E
ND
---
02/04/19
2.5
ND
3.5E
ND
12.0
ND
ND
---
08/07/19
1.3
2.6E
4.1E
1.9E
22.1
1.7E
2.4E
---
02/12/20
1.3
ND
ND
ND
17.0
ND
1.4E
---
08/27/20
3.9
ND
ND
ND
21.1
ND
ND
6.8
02/11/21
3.9
ND
ND
ND
13.4
ND
ND
7.2
08/19/21
3.9
ND
4.81
ND
ND
ND
ND
ND
02/16/22
3.9
ND
5.1
ND
ND
ND
ND
NA
9/28/22'
3.9
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
Vinyl chloride
09/08/94
---
ND
ND
12
ND
ND
ND
---
12/01/94
---
ND
ND
13
ND
ND
ND
---
NC2L=0.03µel-
02/09/95
---
ND
ND
15
ND
ND
ND
---
03/02/95
---
ND
ND
14
ND
ND
ND
---
11/15/95
--
ND
ND
11
ND
ND
ND
---
05/28/96
---
ND
ND
ND
ND
ND
ND
---
11/22/96
--
ND
ND
ND
ND
ND
ND
---
06/17/97
---
ND
ND
ND
ND
ND
ND
---
12/01/97
--
ND
ND
7
4
ND
ND
---
05/20/98
---
ND
ND
ND
ND
ND
ND
---
11/19/98
--
ND
ND
ND
ND
ND
ND
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
ND
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
ND
ND
ND
---
06/29/05
---
ND
ND
ND
ND
ND
ND
---
12/29/05
--
ND
ND
ND
ND
ND
ND
--
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
ND
ND
0.98
ND
ND
ND
---
02/23/07
---
--
--
1.0
--
--
--
---
07/12/07
---
ND
ND
ND
ND
ND
ND
---
12/19/07
---
ND
ND
ND
ND
ND
ND
ND
07/08/08
---
ND
ND
0.76
ND
ND
ND
---
12/17/08
0.62
ND
ND
0.76
ND
ND
ND
---
07/09/09
0.62
ND
ND
0.99
ND
ND
ND
ND
12/16/09
0.62
ND
ND
0.81
ND
ND
ND
---
06/24/10
0.62
ND
ND
0.77
ND
ND
ND
--
12/13/10
0.62
ND
ND
ND
ND
ND
ND
---
06/20/11
0.62
ND
ND
ND
ND
ND
ND
---
12/05/11
0.62
ND
ND
ND
ND
ND
ND
---
06/11/12
0.62
ND
ND
ND
ND
ND
ND
ND
12/12/12
0.62
ND
ND
ND
ND
ND
ND
---
05/01/13
0.62
ND
ND
ND
ND
ND
ND
ND
08/05/13
0.62
ND
ND
ND
ND
ND
ND
---
02/24/14
0.62
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.62
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.62
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.62
ND
ND
ND
ND
ND
ND
---
02/16/16
0.62
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.62
ND
ND
ND
ND
ND
ND
---
02/13/17
0.62
ND
ND
ND
ND
ND
ND
--
08/22/17
0.62
ND
ND
ND
ND
ND
ND
---
02/05/18
0.62
ND
ND
0.63
ND
ND
ND
---
08/13/18
0.62
ND
ND
0.72
ND
ND
ND
---
02/04/19
0.24
ND
ND
ND
ND
ND
ND
---
08/07/19
0.24
ND
ND
1.1
ND
ND
ND
---
09/04/19
0.24
--
--
ND
--
--
--
---
02/12/20
0.24
ND
ND
ND
ND
ND
ND
---
08/27/20
0.24
ND
ND
1.1
ND
ND
ND
---
09/30/20
0.24
--
--
ND
--
--
--
---
02/11/21
0.24
ND
ND
0.53
ND
ND
ND
---
08/19/21
0.39
ND
ND
0.841
ND
ND
ND
ND
02/16/22
0.39
ND
ND
ND
ND
ND
ND
NA
9/28/22'
0.39
<1.0
<1.0
0.721
<1.0
<1.0
<1.0
NA
Appendix D (Page 21 of 22)
GWaersVc-nn yM.k[ap\B -r Historic Tables Hatt & Hickman, PC

Appendix D
Summary of Historical Constituents in Groundwater
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analyte
Sample Date
MDL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Xylenes, total
12/29/06
---
ND
1.4
ND
ND
ND
ND
--
07/12/07
---
ND
1.2
ND
ND
ND
ND
--
NC2L=500µg/L
12/19/07
---
ND
2
ND
ND
ND
ND
ND
07/08/08
---
ND
1.1
ND
ND
ND
ND
--
12/17/08
0.66
1.4
2.7
ND
ND
ND
ND
--
07/09/09
0.66
ND
1.5
ND
ND
ND
ND
ND
12/16/09
0.66
ND
2.2
ND
ND
ND
ND
--
06/24/10
0.66
ND
0.73
ND
ND
ND
ND
--
12/13/10
0.66
ND
2
ND
ND
ND
ND
---
06/20/11
0.66
ND
1.4
ND
ND
ND
ND
---
12/05/11
0.66
ND
1.1
ND
ND
ND
ND
---
06/11/12
0.66
ND
0.91
ND
ND
ND
ND
ND
12/12/12
0.66
ND
0.97
ND
ND
ND
ND
---
05/01/13
0.66
ND
0.68
ND
ND
ND
ND
ND
08/05/13
0.66
ND
ND
ND
ND
ND
ND
---
02/24/14
0.66
ND
ND
ND
ND
ND
ND
ND
08/12/14
0.66
ND
ND
ND
ND
ND
ND
ND
03/10/15
0.66
ND
ND
ND
ND
ND
ND
ND
08/18/15
0.66
ND
ND
ND
ND
ND
ND
---
02/16/16
0.66
ND
ND
ND
ND
ND
ND
ND
08/09/16
0.66
ND
ND
ND
ND
ND
ND
---
02/13/17
0.66
ND
ND
ND
ND
ND
ND
---
08/22/17
0.66
ND
ND
ND
ND
ND
ND
---
02/05/18
0.66
ND
ND
ND
ND
ND
ND
---
08/13/18
0.66
ND
ND
ND
ND
ND
ND
---
02/04/19
0.63
ND
ND
ND
ND
ND
ND
---
08/07/19
0.63
ND
ND
ND
ND
ND
ND
---
02/12/20
0.63
ND
ND
ND
ND
ND
ND
---
08/27/20
0.63
ND
ND
ND
ND
ND
ND
---
02/11/21
0.63
ND
ND
ND
ND
ND
ND
---
08/19/21
0.34
ND
0.821
ND
ND
ND
0.351
ND
02/16/22
0.34
ND
2.9
3.8
ND
ND
ND
NA
9/28/22'
0.34
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
Zinc
09/08/94
---
110
160
ND
ND
320
430
---
12/01/94
---
132
N D
N D
70
164
N D
---
NC2L=1,000M/L
02/09/95
---
144
89
ND
91
79
74
---
03/02/95
---
67
N D
N D
N D
ill
N D
---
11/15/95
--
ND
50
ND
ND
ND
ND
---
05/28/96
---
136
N D
N D
N D
122
N D
---
11/22/96
--
79
48
28
ND
38
ND
---
06/17/97
---
370
410
33
39
36
69
---
12/01/97
--
140
110
11
45
34
30
---
05/20/98
---
70
63
23
31
47
34
---
11/19/98
--
61
33
21
17
53
10
---
07/21/99
---
ND
ND
ND
ND
ND
ND
---
11/16/99
--
ND
ND
ND
ND
ND
ND
---
05/10/00
---
ND
ND
ND
ND
ND
ND
---
10/26/00
--
ND
ND
ND
ND
ND
ND
---
04/18/01
---
ND
ND
ND
ND
ND
ND
---
10/27/01
---
ND
ND
ND
ND
ND
ND
---
06/13/02
---
ND
ND
ND
ND
382
ND
---
11/19/02
--
ND
ND
ND
ND
ND
ND
---
06/27/03
---
ND
ND
ND
ND
ND
ND
---
12/30/03
--
ND
ND
ND
ND
ND
ND
---
06/30/04
---
ND
ND
ND
ND
ND
ND
---
12/29/04
--
ND
ND
ND
66
ND
ND
---
06/29/05
---
N D
54
56
N D
ND
N D
---
12/29/05
--
ND
ND
ND
ND
ND
ND
---
06/28/06
---
ND
ND
ND
ND
ND
ND
---
12/29/06
--
8
N D
N D
4.1
4.32
4.1
---
07/12/07
---
9.6
ND
ND
ND
ND
ND
---
12/19/07
---
4.3
14.30
6.3
ND
ND
ND
2.4
07/08/08
---
5.9
N D
N D
N D
4.10
N D
---
12/17/08
0.4
2.4
6.3
N D
N D
4.6121
0.6
---
07/09/09
0.4
3.4
ND
ND
ND
ND
ND
6.1
12/16/09
0.4
4.6
ND
ND
ND
7.41J
ND
---
06/24/10
0.4
0.58
ND
ND
ND
ND
1.3
---
12/13/10
0.4
4.5
ND
ND
ND
ND
ND
---
06/20/11
10
ND
ND
ND
ND
ND
ND
---
12/05/11
10
ND
ND
ND
ND
ND
ND
---
06/11/12
10
ND
20.9
ND
ND
ND
ND
ND
12/12/12
10
ND
ND
ND
ND
ND
ND
---
05/01/13
10
ND
ND
ND
ND
11.8
ND
10
08/05/13
10
ND
ND
ND
ND
ND
ND
---
02/24/14
10
ND
ND
ND
ND
ND
ND
ND
08/12/14
10
ND
ND
ND
ND
16.9
ND
--
08/18/15
5
7.4
ND
ND
ND
5.2121
ND
---
02/16/16
5
14.5
16.7
17.8
46.1
5.90
ND
---
08/09/16
5
12.0
7.7
ND
ND
ND
ND
---
02/13/17
5
12.3
ND
ND
ND
9.8121
6
---
08/22/17
5
ND
6.3
ND
ND
ND
ND
---
02/05/18
5
6.7
17.9
ND
ND
ND
ND
--
08/13/18
5
ND
ND
ND
ND
8.10
ND
---
02/04/19
5
6.8
ND
5
ND
ND
ND
---
08/07/19
3.9
8.3
ND
ND
ND
ND
ND
---
02/12/20
3.9
4.3
ND
ND
ND
4.52
ND
---
08/27/20
9.5
ND
ND
ND
ND
ND
ND
---
02/11/21
9.5
12.9
ND
ND
ND
ND
ND
---
08/19/21
9.5
44.2
ND
ND
ND
ND
ND
ND
02/16/22
9.5
36.0
ND
ND
ND
ND
ND
NA
9/28/22'
9.5
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
Notes:
Analytical results from September 1994 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2021 Event. Analytical results
from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event.
NC 2L Standards are the Title 15A NCAC 02L.0202 Groundwater Standards dated April 1, 2022.
Bold concentrations exceed the NC 2L Standard.
All results are in micrograms per liter (ug/L).
1. September 2022 MW-1R sample collected on 09/29/2022.
ND = Not detected; NR = Not reported; NE = Not established; --- = Not sampled, NA = Data not available; MDL= Laboratory method detection limit
1 = Estimated concentration above the method detection limit but below the laboratory reporting limit; <values shown in the table indicate less than the laboratory
reporting limit.
Appendix D (Page 22 of12l2)
S:~-Master Projects%Garretl & Meore\GM-3 -G-11. Co. Butner LF12022 S- Half G-utner Historic Tables Hart & Hickman, ! 1.

Appendix E
Summary of Historical Constituents in Surface Water
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
INORGANICS
Arsenic
06/24/10
2.7
4.30 J
2.90 J
12/13/10
2.7
ND
ND
NC2B ' = 10 pg/L
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
3.10 B
ND
02/13/17
5.0
ND
ND
08/22/17
5.0
ND
ND
02/05/18
5.0
ND
ND
08/13/18
5.0
ND
ND
02/04/19
5.0
ND
ND
08/07/19
4.7
ND
ND
02/12/20
4.7
ND
ND
08/27/20
---
Dry
Dry
02/11/21
4.7
---
ND
08/19/21
NR
ND
ND
02/16/22
4.7
6.6 J
ND
09/28/22
4.7
Dry
<10.0
Barium
11/22/96
---
37.0
37.0
06/17/97
---
37.0
62.0
NC2B ' = 1,000 pg/L
12/01/97
---
53.0
45.0
05/20/98
---
24.0
69.0
11/19/98
---
ND
100
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
37.5
40.6
07/12/07
---
33.3 J
---
12/19/07
---
52.6 B
149.0
07/08/08
---
33.8 J
161.0
12/17/08
0.2
30.2 B
33.5 B
07/09/09
0.2
36.8 B
78.4 B
12/16/09
0.2
31.2 B
36 .2 B
06/24/10
0.2
34.5 B
71.3 B
12/13/10
0.2
36.1 B
91.0 J
06/20/11
5.0
40.3 J
93.0 J
12/05/11
5.0
32.9 J
59 .0 J
06/11/12
5.0
40.0 J
95.6 J
12/12/12
5.0
45.0 J
97.8 J
05/01/13
5.0
32.7 J
43.1 J
08/05/13
5.0
49.9 J
79.8 J
02/24/14
5.0
29.0 J
30.4 J
08/12/14
5.0
---
121
03/10/15
2.5
29.0 J
32.1 J
08/18/15
---
Dry
Dry
02/16/16
2.5
33.1 J
33 .5 J
08/09/16
2.5
43.3 J
105
02/13/17
2.5
45.3 J
60.4 J
08/22/17
2.5
39.7 J
88 .7 J
02/05/18
2.5
32.5 J
29.1 J
08/13/18
2.5
70.0 J
86 .6 J
02/04/19
2.5
29.1
33.1
08/07/19
1.0
70.0
94.4
02/12/20
1.0
27.6
30.3
08/27/20
---
Dry
Dry
02/11/21
3.5
---
31.20
08/19/21
3.5
45.1
91.90
02/16/22
3.5
41.8
27.90
09/28/22
4.7
Dry
144
Appendix E (Page 1 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Beryllium
07/08/08
---
0.32 J
ND
12/17/08
0.1
ND
ND
NC2B(') = 65
07/09/09
0.1
ND
ND
12/16/09
0.1
0.12 J
ND
06/24/10
0.1
ND
ND
12/13/10
0.1
ND
ND
06/20/11
1.0
ND
ND
12/05/11
1.0
ND
ND
06/11/12
1.0
ND
ND
12/12/12
1.0
ND
ND
05/01/13
1.0
ND
ND
08/05/13
1.0
ND
ND
02/24/14
1.0
ND
ND
08/12/14
1.0
---
ND
03/10/15
0.50
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.50
ND
ND
08/09/16
0.50
ND
ND
02/13/17
0.50
ND
ND
08/22/17
0.50
ND
ND
02/05/18
0.50
ND
ND
08/13/18
0.50
ND
ND
02/04/19
0.50
ND
ND
08/07/19
0.20
ND
ND
02/12/20
0.20
0.21 J
0.25 J
08/27/20
---
Dry
Dry
02/11/21
0.7
---
ND
08/19/21
NR
ND
ND
02/16/22
0.7
ND
ND
09/28/22
4.7
Dry
<1.0
Chromium
06/17/97
---
ND
3.00
12/01/97
---
ND
ND
NC2B ' = 3093.15 lag/L
05/20/98
---
ND
ND
NC2B = Hardness Dependent
11/19/98
---
ND
ND
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
2.20 B
2.60 B
07/08/08
---
2.50 J
2.20 J
12/17/08
0.4
1.40 J
2.60 J
07/09/09
0.4
2.6 J
1 .2 J
12/16/09
0.4
4.1 J
3.4 J
06/24/10
0.4
3.3 B
7.3 J
12/13/10
0.4
1.4 J
1.5 J
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
7.2 J
12/12/12
5.0
ND
8.2 J
05/01/13
5.0
5.7 J
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
4.4 J
3.6 J
08/18/15
---
Dry
Dry
02/16/16
2.5
4.6 J
6.8 J
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
6.9 J
7.9 J
08/13/18
2.5
5.9 J
ND
02/04/19
2.5
ND
ND
08/07/19
1.0
ND
ND
02/12/20
1.0
5.3
4.7 J
08/27/20
---
Dry
Dry
02/11/21
3.7
---
4.00 J
08/19/21
NR
ND
ND
02/16/22
3.7
ND
ND
09/28/22
4.7
Dry
<5.0
Appendix E (Page 2 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Cobalt
05/20/98
---
2.0
2.0
11/19/98
---
ND
3.0
ISTV(3) = 3 lag/L
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
22.0
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
10.0
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
4.2 B
1.20 B
07/08/08
---
4.80 B
10.5 B
12/17/08
0.6
1.70 B
1.1 B
07/09/09
0.6
ND
ND
12/16/09
0.6
ND
1.0 J
06/24/10
0.6
ND
ND
12/13/10
0.6
4.4 B
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
Resampled
01/25/12
5.0
---
---
06/11/12
5.0
ND
5.10 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
6.0 J
ND
02/04/19
2.5
ND
ND
08/07/19
1.1
2.5 J
ND
02/12/20
1.1
ND
ND
08/27/20
---
Dry
Dry
02/11/21
3.6
---
ND
08/19/21
NR
ND
ND
02/16/22
3.6
ND
ND
09/28/22
4.7
Dry
10.7
Copper
12/29/06
---
1.3 B
1.10 B
07/12/07
---
ND
---
NRWQC (2) = 1,300 lag/L
12/19/07
---
5.3 B
ND
07/08/08
---
1.7 J
4.20 J
12/17/08
0.3
1.40 J
1.50 J
07/09/09
0.3
ND
ND
12/16/09
0.3
1.90 J
2.00 J
06/24/10
0.3
ND
3.10 J
12/13/10
0.3
0.31 B
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
5.50 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
2.90 J
3.40 J
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
3.8 J
3.8 J
08/13/18
2.5
4.1 J
ND
02/04/19
2.5
ND
ND
08/07/19
2.1
3.2 J
3.3 J
02/12/20
2.1
3.9 J
3.4 J
08/27/20
---
Dry
Dry
02/11/21
4.3
---
ND
08/19/21
NR
ND
ND
02/16/22
4.3
ND
ND
09/28/22
4.7
Dry
<5.0
Appendix E (Page 3 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Lead
05/20/98
---
ND
8.00
11/19/98
---
ND
ND
NC2B"' = 554.78
07/21/99
---
ND
10.0
NC213 = Hardness Dependent
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
ND
ND
07/08/08
---
ND
ND
12/17/08
4.0
ND
ND
07/09/09
4.0
ND
ND
12/16/09
4.0
ND
ND
06/24/10
4.0
ND
ND
12/13/10
4.0
ND
ND
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
ND
ND
02/04/19
2.5
ND
ND
08/07/19
1.6
2.2 J
ND
02/12/20
1.6
ND
ND
08/27/20
---
Dry
Dry
02/11/21
4.5
---
ND
08/19/21
NR
ND
ND
02/16/22
4.5
ND
ND
09/28/22
4.7
Dry
<5.0
Nickel
12/29/04
---
ND
ND
06/29/05
---
ND
ND
NC213 ' = 25 pg/L
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
2.9 J
07/12/07
---
3.8 J
---
12/19/07
---
6.0
31.5
07/08/08
---
3.2 J
29.8 J
12/17/08
1.7
2.4 B
4.0 B
07/09/09
1.7
4.1 J
12.3 J
12/16/09
1.7
3.8 B
4.4 B
06/24/10
1.7
ND
2.0 J
12/13/10
1.7
ND
14.2 J
06/20/11
5.0
ND
7.8 J
12/05/11
5.0
ND
5.3 J
06/11/12
5.0
ND
11.0 J
12/12/12
5.0
ND
13 .8 J
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
5.6 J
02/24/14
5.0
ND
ND
08/12/14
5.0
---
20.3 J
03/10/15
2.5
3.0 J
3.8 J
08/18/15
---
Dry
Dry
02/16/16
2.5
2.9 J
4.7 J
08/09/16
2.5
3.3 J
15.2 J
02/13/17
2.5
ND
7.3 J
08/22/17
2.5
ND
16 .3 J
02/05/18
2.5
5.3 J
4.4 J
08/13/18
2.5
7.3 J
12.4 J
02/04/19
2.5
ND
2.7 J
08/07/19
0.90
8.8
14.8
02/12/20
0.90
3.1 J
4.6 J
08/27/20
---
Dry
Dry
02/11/21
3.5
---
4.40 J
08/19/21
3.5
ND
25.1
02/16/22
3.5
6.5
ND
09/28/22
4.7
Dry
46.6
Appendix E (Page 4 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Silver
07/12/07
---
2.20 J
---
12/19/07
---
ND
0.34 J
NC213 ' = 112.30 pg/L
07/08/08
---
0.35 B
1.00 J
NC213 = Hardness Dependent
12/17/08
0.1
ND
ND
07/09/09
0.1
ND
0.10 J
12/16/09
0.1
ND
0.16 J
06/24/10
0.1
ND
0.26 J
12/13/10
0.1
ND
0.28 B
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
ND
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
ND
ND
08/18/15
---
Dry
Dry
02/16/16
2.5
ND
ND
08/09/16
2.5
ND
ND
02/13/17
2.5
ND
ND
08/22/17
2.5
ND
ND
02/05/18
2.5
ND
ND
08/13/18
2.5
ND
ND
02/04/19
2.5
ND
ND
08/07/19
2.5
ND
ND
02/12/20
2.5
ND
ND
08/27/20
---
Dry
Dry
02/11/21
2.5
---
ND
08/19/21
NR
ND
ND
02/16/22
2.5
ND
ND
09/28/22
4.7
Dry
<5.0
Thallium
12/29/04
---
ND
ND
06/29/05
---
ND
ND
ISTV (3)= 2 pg/L
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
3.60 J
ND
07/08/08
---
3.40 J
ND
12/17/08
3.0
ND
ND
07/09/09
3.0
ND
ND
12/16/09
3.0
ND
ND
06/24/10
3.0
ND
ND
12/13/10
3.0
3.80 J
ND
06/20/11
5.4
ND
ND
12/05/11
5.4
ND
ND
06/11/12
5.4
ND
ND
12/12/12
5.4
ND
ND
05/01/13
5.4
ND
ND
08/05/13
5.4
ND
ND
02/24/14
5.4
ND
ND
08/12/14
5.4
---
ND
03/10/15
5.0
ND
ND
08/18/15
---
Dry
Dry
02/16/16
5.0
ND
ND
08/09/16
5.0
ND
ND
02/13/17
0.020
ND
ND
08/22/17
0.020
ND
ND
02/05/18
0.028
ND
ND
08/13/18
0.020
ND
ND
02/04/19
0.060
ND
ND
08/07/19
0.060
ND
ND
02/12/20
0.060
ND
ND
08/27/20
---
Dry
Dry
02/11/21
0.1
---
ND
08/19/21
NR
ND
ND
02/16/22
0.05
ND
ND
09/28/22
4.7
Dry
<0.47
Appendix E (Page 5 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
Vanadium
12/29/06
---
1.60 J
2.00 J
07/12/07
---
4.60 J
---
SWSL141= 25 pg/L
12/19/07
---
3.30 J
1.40 B
07/08/08
---
5.20 J
2.30 J
12/17/08
0.2
1.80 B
2.70 B
07/09/09
0.2
5.00 B
3.40 B
12/16/09
0.2
3.60 J
3.50 J
06/24/10
0.2
5.80 J
2.60 J
12/13/10
0.2
1.60 B
0.67 B
06/20/11
5.0
ND
ND
12/05/11
5.0
ND
ND
06/11/12
5.0
ND
11.5 J
12/12/12
5.0
ND
ND
05/01/13
5.0
ND
ND
08/05/13
5.0
ND
ND
02/24/14
5.0
ND
ND
08/12/14
5.0
---
ND
03/10/15
2.5
3.9 J
4.7 J
08/18/15
---
Dry
Dry
02/16/16
2.5
4.1 J
5.8 J
08/09/16
2.5
2.9 J
2.8 J
02/13/17
2.5
ND
ND
08/22/17
2.5
2.8 J
ND
02/05/18
2.5
6.6 J
5.9 J
08/13/18
2.5
8.3 J
3.1 J
02/04/19
2.5
2.9 J
2.7 J
08/07/19
1.3
1.4 J
2.3 J
02/12/20
1.3
4.5 J
5.0
08/27/20
---
Dry
Dry
02/11/21
3.9
---
ND
08/19/21
NR
ND
ND
02/16/22
3.9
ND
4.4
09/28/22
4.7
Dry
<5.0
Zinc
11/22/96
---
11.0
ND
06/17/97
---
ND
ND
NC213 ' = 674.45 pg/L
12/01/97
---
20.0
ND
NC213 = Hardness Dependent
05/20/98
---
20.0
28.0
11/19/98
---
ND
ND
07/21/99
---
ND
ND
11/16/99
---
ND
ND
05/10/00
---
ND
ND
10/26/00
---
ND
ND
04/18/01
---
ND
ND
10/27/01
---
ND
ND
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
24.6 B
ND
07/08/08
---
ND
ND
12/17/08
0.4
ND
0.89 B
07/09/09
0.4
ND
4.90 B
12/16/09
0.4
2.60 B
2.60 B
06/24/10
0.4
ND
14.9
12/13/10
0.4
ND
9.80 B
06/20/11
10.0
ND
ND
12/05/11
10.0
ND
ND
06/11/12
10.0
ND
ND
12/12/12
10.0
ND
ND
05/01/13
10.0
ND
16.80
08/05/13
10.0
ND
ND
02/24/14
10.0
ND
ND
08/12/14
10.0
---
ND
03/10/15
5.0
7.7 B
7.8 B
08/18/15
---
Dry
Dry
02/16/16
5.0
7.0 J
ND
08/09/16
5.0
ND
ND
02/13/17
5.0
ND
5.2 J
08/22/17
5.0
ND
ND
02/05/18
5.0
ND
ND
08/13/18
5.0
6.0 J
ND
02/04/19
5.0
ND
ND
08/07/19
3.9
ND
ND
02/12/20
3.9
ND
ND
08/27/20
---
Dry
Dry
02/11/21
9.5
---
ND
08/19/21
NR
ND
ND
02/16/22
9.5
ND
ND
09/28/22
4.7
Dry
<10.0
Total Hardness (SM 23406)
02/04/19
662
57.1
85.3
08/07/19
131
316
460
NC213 ' = 100,000 pg/L
02/12/20
131
18,300
60,200
08/27/20
---
---
---
02/11/21
131.0
---
70,000
09/28/22
14.7
Dry
789,000
Appendix E (Page 6 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SW-1
SW-2
ORGANICS
Acetone
10/27/01
---
168 B
337 B
06/13/02
---
---
---
ISTV (3) = 3100 pg/L
06/13/02
---
---
---
11/19/02
---
ND
ND
06/27/03
---
ND
ND
12/30/03
---
ND
ND
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
12.7 B
ND
07/08/08
---
ND
ND
12/17/08
20
ND
ND
07/09/09
20
ND
ND
12/16/09
2.2
ND
ND
06/24/10
2.2
2.80 B
ND
12/13/10
2.2
ND
3.00 J
06/20/11
2.2
ND
3.80 B
12/05/11
2.2
ND
7.20 B
06/11/12
2.2
ND
5.50 B
12/12/12
10.0
ND
ND
05/01/13
10.0
ND
ND
08/05/13
10.0
ND
ND
02/24/14
10.0
ND
ND
08/12/14
10.0
---
ND
03/10/15
10.0
ND
ND
08/18/15
---
Dry
Dry
02/16/16
10.0
ND
ND
08/09/16
10.0
ND
ND
02/13/17
10.0
ND
ND
08/22/17
10.0
ND
ND
02/05/18
10.0
ND
ND
08/13/18
10.0
ND
ND
02/04/19
6.2
ND
ND
08/07/19
6.2
ND
ND
02/12/20
6.2
ND
ND
08/27/20
---
Dry
Dry
02/11/21
6.2
---
ND
08/19/21
NR
ND
ND
02/16/22
5.1
ND
ND
09/28/22
4.7
Dry
<25.0
Chlorobenzene
06/27/03
---
ND
7.20
12/30/03
---
ND
ND
NC2B"' = 488 pg/L
06/30/04
---
ND
ND
12/29/04
---
ND
ND
06/29/05
---
ND
ND
12/29/05
---
ND
ND
06/28/06
---
ND
ND
12/29/06
---
ND
ND
07/12/07
---
ND
---
12/19/07
---
ND
ND
07/08/08
---
ND
ND
12/17/08
0.23
ND
ND
07/09/09
0.23
ND
ND
12/16/09
0.23
ND
ND
06/24/10
0.23
ND
ND
12/13/10
0.23
ND
ND
06/20/11
0.23
ND
ND
12/05/11
0.23
ND
ND
06/11/12
0.23
ND
ND
12/12/12
0.23
ND
ND
05/01/13
0.23
ND
ND
08/05/13
0.23
ND
ND
02/24/14
0.23
ND
ND
08/12/14
0.23
---
ND
03/10/15
0.23
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.23
ND
ND
08/09/16
0.23
ND
ND
02/13/17
0.23
ND
ND
08/22/17
0.23
ND
ND
02/05/18
0.23
ND
ND
08/13/18
0.23
ND
ND
02/04/19
0.23
ND
ND
08/07/19
0.23
ND
ND
02/12/20
0.23
ND
ND
08/27/20
---
Dry
Dry
02/11/21
0.2
---
ND
08/19/21
NR
ND
ND
02/16/22
0.28
ND
ND
09/28/22
4.7
Dry
<1.0
Appendix E (Page 7 of 8)
C:\Users\kmckinney\Desktop\Butner Historic Tables Hart & Hickman, PC

Appendix E
Summary of Historical Constituents in Surface Water
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Analytes
Sample Date
MDL
SWA
SW-2
Chloromethane
07/09/09
0.11
ND
0.19 J
12/16/09
0.11
ND
ND
ISTV (3) = 2.6 pg/L
06/24/10
0.11
ND
ND
12/13/10
0.11
ND
ND
06/20/11
0.11
ND
ND
12/05/11
0.11
ND
ND
06/11/12
0.11
ND
ND
12/12/12
0.11
ND
ND
05/01/13
0.11
ND
ND
08/05/13
0.11
ND
ND
02/24/14
0.11
ND
ND
08/12/14
0.11
---
ND
03/10/15
0.11
ND
ND
08/18/15
---
Dry
Dry
02/16/16
0.11
ND
ND
08/09/16
0.11
ND
ND
02/13/17
0.11
0.17 J
0.19 J
08/22/17
0.11
ND
ND
02/05/18
0.11
ND
ND
08/13/18
0.11
ND
ND
02/04/19
0.39
ND
ND
08/07/19
0.39
ND
ND
02/12/20
0.39
ND
ND
08/27/20
---
Dry
Dry
02/11/21
0.4
---
ND
08/19/21
NR
ND
ND
02/16/22
0.5
ND
ND
09/28/22
4.7
Dry
<1.0
1,4-Dioxane (p-Dioxane)
08/13/18
1.9
ND
14.1
02/04/19
1.9
ND
ND
ISTV (3)= 0-35 uo/L
08/07/19
1.2
10.50
22.3
02/12/20
1.2
ND
1.2 J
08/27/20
---
Dry
Dry
02/11/21
1.2
---
3.00
08/19/21
1.0
ND
26.0
02/16/22
0.86
6.0
ND
09/28/22
4.7
1 Dry
54.5
Methylene Chloride
08/09/16
0.97
ND
ND
02/13/17
0.97
ND
ND
NRWQC (21 = 20 pg/L
08/22/17
0.97
ND
ND
02/05/18
0.97
ND
ND
08/13/18
0.97
ND
ND
02/04/19
3.7
ND
ND
08/07/19
3.7
ND
ND
02/12/20
3.7
ND
ND
08/27/20
Dry
Dry
02/11/21
3.7
---
ND
08/19/21
NR
ND
ND
02/16/22
2.0
ND
ND
09/28/22
1 4.7
1 Dry
<5.0
Notes:
1. 15A NCAC 2B Water Quality Standards (26 Standards) for Surface Water (Class WS IV, nutrient
sensitive waters [NSW]).
2. No 2B Standard established, value shown is EPA Nationally Recommended Water Quality Criteria
(NRWQC) for Aquatic Life & Human Health.
3. No 2B Standard or NWQC established, value shown is North Carolina In -Stream Target Values for
Surface Waters (ISTV).
4. No 2B Standard, NWQC, or ISTV established, value shown is Solid Waste Section Limits (SWSL).
Analytical results from November 1996 through February 2021 obtained from LaBella Associates
Water Quality Monitoring Report - February 2021 Event.
Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring
Report - August 2021 Event.
Bold concentrations exceed the NC 2B Standard.
All concentrations are in micrograms per liter (pg/L).
J = Estimated concentration above the adjusted method detection limit and below the adjusted
method reporting limit;
MDL = laboratory method detection limit; ND = Not detected above laboratory method reporting limit
B = Blank -qualified data, result is expected to be biased high based on concentrations in the blanks
NR = Not Reported; NE= Not established; --- = Not sampled; < values shown in the table indicate
less than the laboratory reporting limit.
Appendix E (Page 8 of 8)
S:VA A -Master Projects\Garrett & Moore\GMI-003 - Granville Go. Butner LF\2022 Second Half GWM\Butner Historic Tables Hart & Hickman, PC

Appendix F
Summary of Historical Monitoring Natural Attenuation Parameters
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Temperature (FP)
12/30/03
°C
15.40
11.10
11.20
12.50
13.60
14.20
---
12/19/07
°C
12.30
12.50
13.10
14.40
14.90
14.40
13.30
05/01/13
°C
15.70
13.70
15.10
14.40
14.20
14.20
12.50
08/14/14
°C
17.80
18.00
19.20
19.40
16.80
17.20
16.00
03/10/15
°C
17.30
16.00
15.90
13.80
13.30
13.70
16.10
08/18/15
°C
16.43
17.78
17.79
17.25
16.47
16.64
16.05
02/16/16
°C
14.60
13.80
14.40
14.00
12.00
13.40
13.10
08/09/16
°C
16.40
17.30
19.40
18.20
17.10
16.80
17.90
02/13/17
°C
14.80
14.40
14.90
15.70
14.10
15.30
15.20
08/22/17
°C
17.40
17.90
17.90
17.50
17.40
16.60
17.80
02/05/18
°C
13.06
11.66
13.05
14.46
13.83
14.53
12.25
08/13/18
°C
17.40
21.10
18.20
19.30
20.60
18.40
16.60
02/04/19
°C
13.20
15.50
16.50
14.90
14.50
15.40
13.70
08/06/19
°C
17.00
22.70
17.60
19.90
17.30
18.20
16.00
08/14/19
°C
---
---
---
---
---
24.30
---
02/12/20
°C
17.20
14.30
14.80
16.50
15.10
16.40
14.80
08/27/20
°C
17.20
18.90
19.90
22.20
20.30
21.10
20.10
09/30/20
°C
---
---
19.30
---
---
---
02/11/21
°C
15.10
12.40
13.60
11.80
11.50
11.30
14.00
08/19/21
°C
19.70
19.40
19.90
25.30
19.30
22.30
17.70
02/16/22
°C
14.90
20.60
10.70
16.90
14.20
10.40
14.70
9/28/221
°C
15.9
17.8
17.8
17.77
17.23
17.2
16.69
pH (FP)
12/30/03
S.U.
7.31
6.54
6.81
6.90
7.24
7.29
---
12/19/07
S.U.
6.89
6.90
7.07
6.87
7.39
6.67
7.64
05/01/13
S.U.
7.32
6.37
6.61
6.42
6.92
7.13
6.10
08/14/14
S.U.
5.84
6.36
6.96
6.79
7.00
6.48
5.59
03/10/15
S.U.
6.11
6.37
6.56
6.30
6.25
6.55
5.68
08/18/15
S.U.
5.12
6.68
6.48
6.76
7.03
6.78
4.94
02/16/16
S.U.
6.15
6.15
6.61
6.69
7.14
6.10
6.52
08/09/16
S.U.
4.79
5.05
5.30
5.06
4.41
5.75
6.46
02/13/17
S.U.
6.10
6.55
6.76
6.78
6.24
7.37
6.23
08/22/17
S.U.
6.58
6.46
6.45
6.98
7.53
7.16
7.16
02/05/18
S.U.
7.11
6.80
7.01
7.33
7.22
7.54
5.53
08/13/18
S.U.
6.30
6.45
6.64
6.38
7.15
7.03
5.54
02/04/19
S.U.
6.17
6.44
7.16
6.87
6.07
7.02
5.13
08/06/19
S.U.
8.84
6.17
6.49
6.69
7.44
7.49
6.79
08/14/19
S.U.
---
---
---
---
---
6.47
---
02/12/20
S.U.
5.63
4.88
6.30
6.73
6.27
7.10
8.72
08/27/20
S.U.
5.08
6.13
6.42
6.45
6.71
6.73
5.48
09/30/20
S.U.
---
---
6.57
---
---
---
---
02/11/21
S.U.
5.65
6.13
6.45
5.94
6.30
6.15
4.38
08/19/21
S.U.
5.52
6.27
6.59
6.36
6.52
6.60
4.94
02/16/22
S.U.
5.64
6.29
6.77
6.41
6.73
6.62
4.95
9/28/221
S.U.
5.98
6.38
6.70
6.36
6.96
6.95
4.88
Conductivity (FP)
12/19/07
PS/cm
96.00
1964.00
1591.00
1245.00
---
---
510.00
05/01/13
PS/cm
111.00
1587.00
1357.00
1150.00
195.00
594.00
69.60
08/14/14
PS/cm
231.00
1897.00
1534.00
1413.00
522.00
565.00
172.60
03/10/15
PS/cm
90.00
996.00
1277.00
1186.00
106.00
504.00
114.00
08/18/15
PS/cm
134.00
1630.00
1680.00
1244.00
617.00
534.00
83.00
02/16/16
PS/cm
72.40
1611.00
1369.00
1234.00
164.00
474.00
78.20
08/09/16
PS/cm
100.70
1924.00
1535.00
1475.00
660.00
600.00
95.60
02/13/17
PS/cm
68.00
1535.00
1314.00
1155.00
272.00
508.00
89.60
08/22/17
PS/cm
77.10
1,752
1350.00
1446.00
755.00
560.00
175.00
02/05/18
PS/cm
80.00
1460.00
1247.00
1230.00
676.00
633.00
50.00
08/13/18
PS/cm
101.20
2013.00
1608.00
1569.00
870.00
620.00
131.20
02/04/19
PS/cm
107.90
1692.00
1266.00
1364.00
276.10
546.00
91.60
08/06/19
PS/cm
113.40
1719.00
1307.00
1287.00
775.00
545.30
98.50
08/14/19
PS/cm
---
---
---
---
---
559.00
---
02/12/20
PS/cm
94.80
1946.00
1475.00
1471.00
276.90
588.30
95.50
08/27/20
PS/cm
82.40
1601.00
1217.00
1335.00
773.00
577.00
140.50
09/30/20
PS/cm
---
---
1409.00
---
---
---
---
02/11/21
PS/cm
85.20
1251.00
1004.00
838.00
211.30
323.80
65.90
08/19/21
PS/cm
127.40
206.20
1568.00
1658.00
1044.00
630.00
125.60
02/16/22
PS/cm
91.60
2095.00
1543.00
1421.00
1056.00
604.80
81.40
9/28/221
PS/cm
77.9
2016
1590
1667
1391
684
184
Redox Potential (ORP) (FP)
12/30/03
my
257.2
76.20
207.6
212.70
187.30
123.60
---
12/19/07
my
146.00
45.00
142.00
134.00
---
---
138.00
05/01/13
my
111.70
-26.70
55.20
120.50
---
---
227.10
08/14/14
my
115.80
-37.20
86.90
---
---
---
---
03/10/15
my
87.00
0.80
56.30
---
---
---
96.70
08/18/15
my
134.70
-96.30
-68.80
-33.90
-49.90
---
182.80
02/16/16
my
111.70
-47.30
16.90
---
---
---
173.40
08/09/16
my
56.00
-43.10
-6.90
---
---
---
---
02/13/17
my
87.40
0.80
-16.50
---
---
---
---
08/22/17
my
102.90
-37.10
87.00
---
---
---
116.70
02/05/18
my
57.10
29.50
49.40
---
---
---
109.20
08/13/18
my
117.90
-60.50
-49.30
---
---
64.40
28.40
02/04/19
my
197.70
-64.30
132.20
---
9.60
---
281.20
08/06/19
my
164.70
-69.30
-33.70
171.60
188.60
232.60
231.80
08/14/19
my
---
---
---
---
---
237.60
---
02/12/20
my
336.50
33.40
22.40
254.50
299.90
282.00
245.60
08/27/20
my
242.70
-10.80
12.40
190.30
196.50
188.00
240.60
09/30/20
my
---
---
232.30
---
---
---
---
02/11/21
my
166.80
4.10
34.80
197.40
---
278.80
284.50
08/19/21
my
112.30
65.00
79.90
58.70
52.50
125.00
42.30
02/16/22
my
172.30
-48.00
-8.80
88.00
-1.50
194.70
282.80
9/28/221
my
206.1
-84.7
-52.2
40.8
-42.1
41.6
139.1
Appendix F (Page 1 of 6)
hUps://harthick,sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Tables.xlsx Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Oxygen (DO) (FP)
12/30/03
mg/L
9.49
4.84
---
---
---
---
---
12/19/07
mg/L
---
1.88
1.44
3.21
---
---
0.70
05/01/13
mg/L
4.40
1.37
1.79
4.65
---
---
2.90
08/14/14
mg/L
4.44
3.26
2.48
---
---
---
2.80
03/10/15
mg/L
3.84
1.47
1.80
---
---
---
1.85
08/18/15
mg/L
4.95
5.75
1.30
---
3.79
---
1.77
02/16/16
mg/L
4.45
3.66
2.51
---
---
---
3.72
08/09/16
mg/L
3.17
2.87
2.29
---
---
---
---
02/13/17
mg/L
5.37
3.16
2.14
---
---
---
---
08/22/17
mg/L
5.43
2.24
4.02
---
---
---
5.86
02/05/18
mg/L
8.08
6.61
9.16
---
---
---
8.36
08/13/18
mg/L
6.31
3.20
2.35
---
---
4.80
3.91
02/04/19
mg/L
1.26
1.82
4.17
---
4.17
---
1.63
08/06/19
mg/L
3.77
0.32
0.26
4.55
5.30
2.76
3.04
08/14/19
mg/L
---
---
---
---
---
1.95
---
02/12/20
mg/L
5.11
0.65
1.36
4.30
3.48
2.44
6.37
08/27/20
mg/L
0.63
0.22
0.48
5.04
6.22
4.14
3.16
09/30/20
mg/L
---
---
2.00
---
---
---
---
02/11/21
mg/L
1.75
1.05
0.40
7.40
5.41
3.23
2.18
08/19/21
mg/L
0.68
3.55
1.02
0.31
0.19
1.88
2.07
02/16/22
mg/L
2.06
0.14
0.99
0.34
0.32
3.62
2.94
9/28/221
mg/L
4.72
0.29
0.18
0.50
0.30
0.47
0.51
Dissolved CO2 (FP)
12/19/07
mg/L
25.00
365.00
175.00
295.00
---
---
60.00
05/01/13
mg/L
30.00
245.00
125.00
225.00
---
---
45.00
08/14/14
mg/L
60.00
390.00
185.00
---
---
---
75.00
03/10/15
mg/L
50.00
110.00
75.00
---
---
---
50.00
08/18/15
mg/L
30.00
275.00
125.00
---
---
---
60.00
02/16/16
mg/L
30.00
210.00
230.00
---
---
---
20.00
08/09/16
mg/L
---
185.00
210.00
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
75.00
---
130.00
---
---
---
---
08/06/19
mg/L
---
475.00
250.00
---
---
---
---
02/12/20
mg/L
---
260.00
---
---
---
---
---
08/27/20
mg/L
---
---
---
---
---
---
---
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
--
02/16/22
mg/L
---
---
---
---
---
---
---
9/28/221
mg/L
---
---
---
---
---
--
Fe, Ferrous (+2) (FP)
12/30/03
mg/L
ND
1.50
ND
ND
0.22
ND
---
12/19/07
mg/L
ND
7.20
ND
ND
---
---
0.20
05/01/13
mg/L
ND
1.00
ND
ND
---
---
ND
08/14/14
mg/L
ND
2.50
ND
---
---
---
ND
03/10/15
mg/L
ND
5.30
ND
---
---
---
ND
08/18/15
mg/L
ND
4.50
1.00
---
---
---
ND
02/16/16
mg/L
ND
4.00
1.30
---
---
---
ND
08/09/16
mg/L
---
3.10
1.00
---
---
---
---
02/13/17
mg/L
ND
3.00
1.50
---
---
---
---
08/22/17
mg/L
ND
3.50
1.50
---
---
---
ND
02/05/18
mg/L
ND
4.00
0.50
---
---
---
ND
08/13/18
mg/L
ND
5.50
0.20
---
---
---
---
02/04/19
mg/L
ND
---
ND
---
---
---
---
08/06/19
mg/L
---
3.50
0.50
---
---
---
---
02/12/20
mg/L
---
1.00
0.50
---
---
---
---
08/27/20
mg/L
---
4.50
1.00
---
---
---
---
02/11/21
mg/L
0.00
1.50
0.50
---
---
---
0.00
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
---
---
---
---
---
---
---
9/28/221
mg/L
---
7.0
0.5
---
---
---
---
Alkalinity (CaCO3)
12/30/03
mg/L
37.00
800.00
690.00
640.00
68.00
350.00
---
12/19/07
mg/L
39.00
763.00
726.00
619.00
---
---
190.00
05/01/13
mg/L
43.40
757.00
660.00
645.00
---
---
10.40
08/14/14
mg/L
41.10
784.00
661.00
---
---
---
14.50
03/10/15
mg/L
38.00
744.00
653.00
---
---
---
8.80
08/18/15
mg/L
37.80
772.00
664.00
---
---
---
10.30
02/16/16
mg/L
41.20
792.00
741.00
---
---
---
8.73
08/09/16
mg/L
---
783.00
629.00
---
---
---
---
02/13/17
mg/L
37.90
753.00
654.00
---
---
---
8.79
08/22/17
mg/L
42.40
766.00
678.00
---
---
---
10.20
02/05/18
mg/L
44.40
821.00
752.00
---
---
---
7.52
08/13/18
mg/L
---
768.00
722.00
---
---
---
---
02/04/19
mg/L
62.00
856.00
638.00
---
---
---
7.02
08/06/19
mg/L
---
839.00
754.00
---
---
---
---
02/02/20
mg/L
---
818.00
646.00
---
---
---
---
08/27/20
mg/L
47.60
909.00
735.00
---
---
---
---
02/11/21
mg/L
53.90
875.00
724.00
---
---
---
ND
08/19/21
mg/L
---
914.00
636.00
---
---
---
---
02/16/22
mg/L
35.00
820.00
630.00
---
---
---
5.00
9/28/221
mg/L
---
864
792
Appendix F (Page 2 of 6)
https:/Iharthick.shampoint.wm/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Table -lax Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Chloride
12/30/03
mg/L
3.50
280.00
170.00
82.00
13.00
44.00
---
12/19/07
mg/L
ND
13.10
297.00
89.10
---
---
7.90
05/01/13
mg/L
3.54
258.00
180.00
123.00
---
---
2.85
08/14/14
mg/L
5.53
264.00
144.00
---
---
---
5.00
03/10/15
mg/L
3.80
266.00
194.00
---
---
---
4.09
08/18/15
mg/L
4.69
267.00
178.00
---
---
---
3.90
02/16/16
mg/L
3.92
274.00
186.00
---
---
---
3.24
08/09/16
mg/L
---
269.00
191.00
---
---
---
---
02/13/17
mg/L
3.45
309.00
215.00
---
---
---
5.09
08/22/17
mg/L
3.73
318.00
214.00
---
---
---
5.86
02/05/18
mg/L
3.92
280.00
205.00
---
---
---
2.52
08/13/18
mg/L
-
221.00
165.00
---
---
---
---
02/04/19
mg/L
3.42
221.00
147.00
---
---
---
4.52
08/06/19
mg/L
---
203.00
154.00
---
---
---
---
02/12/20
mg/L
---
224.00
153.00
---
---
---
---
08/27/20
mg/L
3.84
208.00
148.00
---
---
---
5.33
02/11/21
mg/L
3.67
201.00
148.00
---
---
---
4.06
08/19/21
mg/L
---
0.217
0.157
---
---
---
---
02/16/22
mg/L
---
---
---
---
---
---
---
9/28/221
mg/L
---
191
150
---
---
---
---
Dissolved Hydrogen
05/01/13
nM
0.40
0.63
0.61
0.50
---
---
0.47
08/14/14
nM
1.40
1.60
5.40
-
---
---
1.40
03/10/15
nM
1.20
1.40
1.40
1.00
---
---
1.40
08/18/15
nM
1.70
2.20
1.70
---
---
---
1.50
02/16/16
nM
2.00
1.70
1.90
---
---
---
1.50
08/09/16
nM
---
1.50
1.60
---
---
---
---
02/13/17
nM
---
---
---
---
---
---
---
08/22/17
nM
---
---
---
---
---
---
---
02/05/18
nM
---
---
---
---
---
---
---
08/13/18
nM
---
---
---
---
---
---
---
02/04/19
nM
6.70
7.60
7.40
---
---
---
---
08/06/19
nM
---
2.00
5.40
---
---
---
6.80
02/12/20
nM
---
5.80
2.70
---
---
---
---
08/27/20
nM
---
1.0 J
1.2 J
---
---
---
---
09/10/20
nM
1.80
---
---
---
---
---
---
02/11/21
nM
---
---
---
---
---
---
2.40
08/19/21
nM
---
---
---
---
02/16/22
nM
1.2 J
1.3 J
3.2
---
---
---
2.40
9/28/221
nM
---
---
---
---
---
---
Nitrate-N
12/30/03
mg/L
0.12
ND
ND
ND
ND
0.13
---
12/19/07
mg/L
ND
ND
ND
ND
---
---
13.00
05/01/13
mg/L
0.16
ND
ND
ND
---
---
3.58
08/14/14
mg/L
.115 J
ND
ND
---
---
---
2.02 J
03/10/15
mg/L
.252 J
ND
ND
---
---
---
2.56 J
08/18/15
mg/L
.124 J
ND
ND
---
---
---
3.27 J
02/16/16
mg/L
.36 J
ND
ND
---
---
---
2.54 J
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
.248 J
.189 J
ND
---
---
---
2.63 J
08/22/17
mg/L
.118 J
.0186 J
.0451 J
---
---
---
4.06 J
02/05/18
mg/L
.310 J
ND
.0120 J
---
---
---
1.15 J
08/13/18
mg/L
---
ND
ND
---
---
---
---
02/04/19
mg/L
0.20
ND
0.11
---
---
---
6.50
08/06/19
mg/L
---
ND
ND
---
---
---
---
02/12/20
mg/L
---
0.07
0.36
---
---
---
---
08/27/20
mg/L
ND
ND
ND
---
---
---
6.34
02/11/21
mg/L
0.06
ND
0.06
---
---
---
4.65
08/19/21
mg/L
---
ND
ND
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
9/28/221
mg/L
---
<0.10
<0.10
---
---
---
---
Sulfate
12/30/03
mg/L
ND
ND
ND
2.60
9.60
9.00
---
12/19/07
mg/L
ND
ND
ND
ND
---
---
36.80
05/01/13
mg/L
ND
ND
ND
4.69
---
---
10.70
08/14/14
mg/L
1.08 J
1.2 J
ND
---
---
---
5.84 J
03/10/15
mg/L
1.52 J
1.13 J
1.52 J
---
---
---
7.04 J
08/18/15
mg/L
1.56 J
1.31 J
2.49 J
---
---
---
5.24 J
02/16/16
mg/L
1.5 J
1.7 J
1.8 J
---
---
---
10.0 J
08/09/16
mg/L
---
1.22
1.75 J
---
---
---
---
02/13/17
mg/L
1.53 J
1.59 J
1.78 J
---
---
---
11.9 J
08/22/17
mg/L
ND
ND
.626 J
---
---
---
11.2 J
02/05/18
mg/L
ND
ND
.627 J
---
---
---
7.48 J
08/13/18
mg/L
ND
ND
.630 J
---
---
---
---
02/04/19
mg/L
1.15
ND
1.10
---
---
---
6.75
08/06/19
mg/L
---
ND
.711 J
---
---
---
---
02/12/20
mg/L
---
ND
.85 J
---
---
---
---
08/27/20
mg/L
ND
ND
ND
---
---
---
5.21
02/11/21
mg/L
1.41
ND
0.82
---
---
---
5.92
08/19/21
mg/L
---
ND
ND
---
---
---
---
02/16/22
mg/L
ND
ND
0.543 J
---
---
---
6.62
9/28/221
mg/L
---
<1.0
<1.0
---
---
---
---
Sulfide
08/14/14
mg/L
ND
ND
ND
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
ND
---
---
---
1.00
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
ND
ND
ND
---
---
---
---
08/22/17
mg/L
ND
ND
ND
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
ND
ND
ND
---
---
---
ND
08/06/19
mg/L
ND
ND
---
---
---
---
02/12/20
mg/L
0.083 J
ND
---
---
---
---
08/27/20
mg/L
ND
ND
ND
---
---
---
ND
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
9/28/221
mg/L
---
---
---
---
---
---
---
Appendix F (Page 3 of 6)
hUps://harthick,sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Tables.xlsx Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-111
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Total Organic Carbon
12/19/07
mg/L
2.90
54.30
23.20
17.20
---
---
7.20
05/01/13
mg/L
2.24
29.50
30.00
19.40
---
---
5.74
08/14/14
mg/L
ND
229.00
25.50
---
---
---
8.39
03/10/15
mg/L
0.781J
34.80
9.54
---
---
---
1.88
08/18/15
mg/L
0.917J
32.90
9.86
---
---
---
27.80
02/16/16
mg/L
1.50
27.60
8.46
---
---
---
40.90
08/09/16
mg/L
---
29.40
9.53
---
---
---
---
02/13/17
mg/L
ND
28.50
9.72
---
---
---
1.36
08/22/17
mg/L
ND
29.10
9.92
---
---
---
1.71
02/05/18
mg/L
ND
25.90
11.40
---
---
---
4.24
08/13/18
mg/L
ND
25.80
10.20
---
---
---
ND
02/04/19
mg/L
ND
27.90
8.02
---
---
---
1.60
08/06/19
mg/L
---
33.30
15.10
---
---
---
---
02/12/20
mg/L
---
25.40
7.46
---
---
---
---
08/27/20
mg/L
0.689 J
29.80
8.19
---
---
---
0.916 J
02/11/21
mg/L
ND
28.20
7.68
---
---
---
1.61
08/19/21
mg/L
---
28.20
7.69
---
---
---
---
02/16/22
mg/L
ND
26.50
7.80
---
---
---
1.18
9/28/221
mg/L
---
26.4
8.3
---
---
---
---
Biochemical Oxygen Demand (BOD 5-day)
08/14/14
mg/L
ND
83.40
2.49
---
---
---
03/10/15
mg/L
2.55
10.60
ND
---
---
---
ND
08/18/15
mg/L
2.22
11.80
2.00
---
---
---
2.00
02/16/16
mg/L
ND
60.00
6.60
---
---
---
ND
08/09/16
mg/L
---
11.60
ND
---
---
---
02/13/17
mg/L
ND
9.5 J
ND
---
---
---
ND
08/22/17
mg/L
ND
ND
ND
---
---
---
ND
02/05/18
mg/L
ND
5.60
ND
---
---
---
ND
08/13/18
mg/L
ND
71.80
3.56
---
---
---
ND
02/04/19
mg/L
ND
7.50
ND
---
---
---
ND
08/06/19
mg/L
---
8.00
ND
---
---
---
---
02/12/20
mg/L
---
6.30
ND
---
---
---
---
08/27/20
mg/L
ND
9.45
ND
---
---
---
ND
02/11/21
mg/L
ND
9.87
ND
---
---
---
ND
08/19/21
mg/L
---
6.38
ND
---
---
---
02/16/22
mg/L
ND
8.00
ND
---
---
---
ND
9/28/221
mg/L
---
6.1 B3
<2.0
---
---
---
---
Chemical Oxygen Demand (COD)
08/14/14
mg/L
ND
132.00
ND
---
---
---
50.00
03/10/15
mg/L
15.0 J
235.00
96.00
---
---
---
ND
08/18/15
mg/L
25.00
110.00
756.00
---
---
---
25.00
02/16/16
mg/L
ND
295.00
50.00
---
---
---
ND
08/09/16
mg/L
-
131.00
50.00
---
---
---
-
02/13/17
mg/L
17 J
119.00
43.00
---
---
---
22 J
08/22/17
mg/L
ND
121.00
74.00
---
---
---
16 J
02/05/18
mg/L
ND
113.00
51.00
---
---
---
46.00
08/13/18
mg/L
ND
112.00
73.90
---
---
---
ND
02/04/19
mg/L
ND
101.00
26.50
---
---
---
ND
08/06/19
mg/L
123.00
45.50
---
---
---
02/12/20
mg/L
160.00
36.10
---
---
---
08/27/20
mg/L
ND
112.00
35.90
---
---
---
ND
02/11/21
mg/L
ND
108.00
38.00
---
---
---
ND
08/19/21
mg/L
-
121.00
48.20
---
---
---
02/16/22
mg/L
ND
105.00
32.10
---
---
---
ND
9/28/221
mg/L
---
119
49.3
---
---
---
---
Dissolved Ethane
12/30/03
mg/L
ND
ND
ND
---
---
---
---
12/19/07
mg/L
ND
ND
ND
ND
ND
ND
---
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
0.0036 J
ND
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
0.01
0.01
0.01
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
0.01
08/09/16
mg/L
---
1.6 J
2.6 J
---
---
---
ND
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
ND
ND
ND
ND
ND
ND
ND
08/06/19
mg/L
ND
2.0 J
---
---
---
---
ND
02/12/20
mg/L
ND
0.0026 J
---
---
---
---
ND
08/27/20
mg/L
ND
ND
---
---
---
---
ND
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
---
--
02/16/22
mg/L
---
---
---
---
---
---
---
9/28/221
mg/L
---
---
---
---
---
--
Dissolved Ethane
12/01/03
mg/L
ND
ND
ND
ND
ND
ND
---
12/19/07
mg/L
ND
ND
ND
ND
ND
---
ND
05/01/13
mg/L
ND
ND
0.0017
0.00
ND
---
ND
08/14/14
mg/L
ND
ND
ND
ND
---
---
ND
03/10/15
mg/L
ND
ND
ND
ND
---
---
ND
08/18/15
mg/L
0.01
0.01
0.01
0.01
---
---
0.01
02/16/16
mg/L
ND
ND
ND
ND
---
---
ND
08/09/16
mg/L
---
ND
ND
ND
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
02/04/19
mg/L
ND
ND
ND
ND
ND
ND
ND
08/06/19
mg/L
ND
ND
0.0016 J
.0016 J
---
---
ND
02/12/20
mg/L
ND
0.00
ND
ND
---
---
ND
08/27/20
mg/L
ND
ND
ND
ND
---
---
ND
02/11/21
mg/L
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
---
---
---
---
---
---
9/28/221
mg/L
---
---
---
---
---
--
Appendix F (Page 4 of 6)
hUps://harthick,sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Tables.xlsx Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
ND
0.66
0.13
0.01
0.00
ND
---
12/19/07
mg/L
ND
0.12
0.19
ND
---
---
ND
05/01/13
mg/L
ND
0.04
0.10
0.03
---
---
ND
08/14/14
mg/L
ND
1.29
0.28
---
---
---
ND
03/10/15
mg/L
0.01
1.00
0.16
---
---
---
ND
08/18/15
mg/L
0.00
2.16
0.32
---
---
---
0.00
02/16/16
mg/L
0.007 J
0.87
0.10
---
---
---
0.0016 J
08/09/16
mg/L
-
1.85
0.21
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
ND
27.20
ND
ND
ND
ND
ND
08/06/19
mg/L
ND
5.00
0.49
---
---
---
ND
02/12/20
mg/L
ND
4.50
0.38
---
---
---
ND
08/27/20
mg/L
ND
6.00
0.50
---
---
---
ND
02/11/21
mg/L
ND
6.66
0.52
---
---
---
ND
08/19/21
mg/L
---
7.21
0.603
---
---
---
---
02/16/22
mg/L
ND
4.61
0.397
---
---
---
ND
9/28/221
mg/L
---
2.3
0.27
---
---
---
---
Pyruvic Acid
12/19/07
mg/L
2.50
ND
1.50
2.00
---
---
1.20
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
0.41 J
0.41 J
0.41 J
---
---
---
0.41 J
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
---
---
---
---
---
---
---
08/06/19
mg/L
ND
ND
ND
---
---
---
ND
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
ND
ND
ND
ND
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
9/28/221
mg/L
---
---
---
---
---
---
---
Lactic Acid
12/19/07
mg/L
ND
5.40
11.90
3.10
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
4.2 J
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
---
---
---
---
---
---
---
08/06/19
mg/L
ND
ND
0.087 J
---
---
---
ND
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
ND
ND
ND
---
---
---
ND
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
230 J
ND
ND
---
---
---
ND
9/28/221
mg/L
---
---
---
---
---
---
---
Acetic Acid
12/19/07
mg/L
ND
ND
ND
ND
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
0.97 J
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
02/04/19
mg/L
---
---
---
---
---
---
08/06/19
mg/L
ND
0.097 J
0.34
---
---
---
ND
02/12/20
mg/L
---
---
---
---
---
---
08/27/20
mg/L
0.53
4.7 J
0.53
---
---
---
0.56
02/11/21
mg/L
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
0.13
9/28/221
mg/L
---
---
---
---
---
---
---
Propionic Acid
12/19/07
mg/L
ND
63.70
38.30
12.80
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
08/22/17
mg/L
---
---
---
---
02/13/17
mg/L
---
---
---
---
08/22/17
mg/L
---
---
---
---
02/05/18
mg/L
---
---
---
---
08/13/18
mg/L
---
---
---
---
02/04/19
mg/L
---
---
---
---
08/06/19
mg/L
---
0.0058 J
0.0045 J
---
---
---
---
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
ND
ND
ND
---
---
---
ND
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
9/28/221
mg/L
---
---
---
---
---
--
Appendix F (Page 5 of 6)
hUps://harthick,sharepoint.com/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Tables.xlsx Hart & Hickman, PC

Appendix F
Summary of Historical Monitored Natural Attenuation
Granville County Butner Landfill
Butner, North Carolina
H&H Job No. GMI-003
Parameter
Date
Units
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Butyric Acid
12/19/07
mg/L
ND
ND
ND
ND
---
---
ND
05/01/13
mg/L
ND
ND
ND
ND
---
---
ND
08/14/14
mg/L
ND
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
ND
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
---
---
02/13/17
mg/L
---
---
---
---
08/22/17
mg/L
---
---
---
---
02/05/18
mg/L
---
---
---
---
08/13/18
mg/L
---
---
---
---
02/04/19
mg/L
---
---
---
---
08/06/19
mg/L
---
0.22
ND
---
—
---
---
02/12/20
mg/L
---
---
---
---
08/27/20
mg/L
ND
ND
0.066 J
---
---
ND
02/11/21
mg/L
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
ND
ND
ND
---
---
---
ND
9/28/221
mg/L
---
---
---
---
---
---
---
Formic Acid
08/06/19
mg/L
---
1.10
1.60
---
---
---
---
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
4.90
45.00
4.80
---
---
---
5.10
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
---
02/16/22
mg/L
1.2
42
9.2
---
---
---
4
9/28/221
mg/L
---
---
---
---
---
---
---
Total Volatile Fatty Acids (sum of above 6 acids)
12/19/07
mg/L
2.50
69.10
51.70
17.90
---
---
1.20
05/01/13
mg/L
ND
ND
ND
---
---
---
ND
08/14/14
mg/L
4.2 J
ND
ND
---
---
---
ND
03/10/15
mg/L
ND
ND
ND
---
---
---
ND
08/18/15
mg/L
ND
ND
0.97 J
---
---
---
ND
02/16/16
mg/L
ND
ND
ND
---
---
---
ND
08/09/16
mg/L
---
ND
ND
---
---
02/13/17
mg/L
---
---
---
---
---
---
---
08/22/17
mg/L
---
---
---
---
---
---
---
02/05/18
mg/L
---
---
---
---
---
---
---
08/13/18
mg/L
---
---
---
---
---
---
---
02/04/19
mg/L
---
---
---
---
---
---
---
08/06/19
mg/L
---
1.32
1.94
---
---
02/12/20
mg/L
---
---
---
---
---
---
---
08/27/20
mg/L
5.43
49.70
5.40
---
---
---
5.66
02/11/21
mg/L
---
---
---
---
---
---
---
08/19/21
mg/L
---
---
---
--
---
02/16/22
mg/L
231.20
42.00
9.20
---
---
---
4.13
9/28/221
mg/L
Notes.
Analytical results from December 2003 through February 2021 obtained from La Bella Associates Water Quality Monitoring Report - February 2021 Event
Analytical results from August 2021 obtained from Garrett & Moore, Inc. Water Quality Monitoring Report - August 2021 Event
Method detection limits vary between samples for fatty acid analysis, the higher method detection limit reported for each constituent for samples collected in February 2022
1. September 2022 MW-1R sample collected on 09/29/2022.
mg/L = milligrams per liter; nanometers; --- = Not Sampled and/or Not Reported; ND = Not Detected; MDL = method detection limit;
MRL = method reporting limit; 1 = Estimated concentration above the adjusted method detection limit and below the adjustec
method reporting limit; S.U. = standard units; °C = degrees Celsius; VS/cm = microsiemens per centimeter; mV = millivolts
133 = The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L
Appendix F (Page 6 of 6)
https:/Iharthick.shampoint.wm/sites/MasterFiles-1/Shared Documents/AAA-Master Projects/Garrett & Moore/GMI-003 - Granville Co. Butner LF/2022 Second Half GWM/Butner Historic Table —lax Hart & Hickman, PC

Appendix G
Phytoremediation Tree and Flora Inspection Logs
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Phytoremediation Tree and Flora Inspection Log
Site: Date:
Personnel:
Weather Conditions:
Description of Area:
Has the ground surface been disturbed by rutting, erosion, tire tracks, settlement, etc.?
Are there any indications of vandalism or trespassing?
Is there any ponded water in the area?
Has there been any change in the number of live/dead trees in the area since the last inspection?
Do any trees exhibit signs of disease, damage, or distress (discolored leaves, damaged bark, broken limbs, etc.)?
Are there any signs of unusual animal/insect damage to the trees?
Has there been any change in the type, amount, or health of undergrowth or ground cover flora?
Has there been any change in the observed wetlands (size, maturity, health) in the area?
Please describe the prevalent tree species and give approximate percentages in the area:
COMMENTS:
SPECIES % AVERAGE MATURITY AVERAGE HEALTH
Signature of Inspector:

Phytoremediation Tree and Flora Inspection Log
Site: Date:
Personnel:
Weather Conditions:
Description of Area:
Has the ground surface been disturbed by rutting, erosion, tire tracks, settlement, etc.?
Are there any indications of vandalism or trespassing?
Is there any ponded water in the area?
Has there been any change in the number of live/dead trees in the area since the last inspection?
Do any trees exhibit signs of disease, damage, or distress (discolored leaves, damaged bark, broken limbs, etc.)?
Are there any signs of unusual animal/insect damage to the trees?
Has there been any change in the type, amount, or health of undergrowth or ground cover flora?
Has there been any change in the observed wetlands (size, maturity, health) in the area?
Please describe the prevalent tree species and give approximate percentages in the area:
COMMENTS:
SPECIES % AVERAGE MATURITY AVERAGE HEALTH
Signature of Inspector:

Phytoremediation Tree and Flora Inspection Log
Site: Date:
Personnel:
Weather Conditions:
Description of Area:
Has the ground surface been disturbed by rutting, erosion, tire tracks, settlement, etc.?
Are there any indications of vandalism or trespassing?
Is there any ponded water in the area?
Has there been any change in the number of live/dead trees in the area since the last inspection?
Do any trees exhibit signs of disease, damage, or distress (discolored leaves, damaged bark, broken limbs, etc.)?
Are there any signs of unusual animal/insect damage to the trees?
Has there been any change in the type, amount, or health of undergrowth or ground cover flora?
Has there been any change in the observed wetlands (size, maturity, health) in the area?
Please describe the prevalent tree species and give approximate percentages in the area:
COMMENTS:
SPECIES % AVERAGE MATURITY AVERAGE HEALTH
Signature of Inspector:

Appendix H
Concentration vs. Time Charts
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Chart 1
Benzene Concentrations vs. Time
M W-2 R, M W-3 R, & M W-4
2.5
2.0
F� A
ova 1.5
o MW-2R
c�
+, M W- R
c
u MW-4
u° 1 0 2L Standard (1 µg/L)
0.5
0.0
10/10/06 9/9/08 8/10/10 7/10/12 6/10/14 5/10/16 4/10/18 3/10/20 2/8/22 1/9/24
Note: Non -detect values are graphed equal to the reporting limit. Date

Chart 2
1,4-Dioxane Concentrations vs. Time
MW-2R, MW-3R, MW-4, & MW-5
140.0
120.0
100.0
J
bA
=- 80.0
1
MW-2R
0
MW-3R
c
u 60.0
c
c
MW-5
U
2L Standard (3 µg/L)
40.0
20.0
0.0
07/19/18
02/04/19 08/23/19 03/10/20 09/26/20 04/14/21 10/31/21 05/19/22 12/05/22
Note: Non -detect
values are graphed equal to the reporting limit. Date

Chart 3
Cobalt Concentrations vs. Tlme
MW-2R & MW-5
300
250
200
J
C
0
150 MW-2R
c
v
U
0 2L Standard (1 µg/L)
u
100
50
0
6/15/94 1/5/98 7/28/01 2/17/05 9/9/08 4/1/12 10/23/15 5/15/19 12/5/22
Note: Non -detect values are graphed equal to the reporting limit. Date