1119_DukeAsheville_GWMR_Sept2022_FID1767696_20230113

(� DUKE
ENERGY
January 13, 2023
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. Highway 70
Swannanoa, NC 28778
Attn: Ms. Sarah Moutos (submitted electronically)
Re: Semiannual Water Quality Monitoring Report — September 2022
CCR Landfill
Permit No. 1119-INDUS-2020
Asheville Steam Electric Plant
Buncombe County, North Carolina
Dear Ms. Moutos:
526 South Church St.
Charlotte, NC 28202
Mailing Address
P.O. Box 1006
Mail Code EC 13K.
Charlotte, NC 28201-1006
Duke Energy is providing the results of the September 2022 semiannual water quality monitoring for the Duke
Energy Progress Asheville CCR Landfill (1119-INDUS), located in Arden, Buncombe County, North Carolina.
Sampling was conducted on September 26, 2022, in accordance with the approved Water Quality Monitoring
Plan (WQMP). The September 2022 monitoring event included samples from nine groundwater monitoring
wells, two surface water locations, and one sample of composite leachate. Three surface water locations and
one seep location are designated in the WQMP, however surface water sample LF-SW-1 and seep sample
DP-4 were not sampled during the September 2022 sampling event because of dry conditions.
The groundwater analytical results are compared to the groundwater standards found in Title 15A NCAC 02L
.0202 (02L Standards). The surface water and seep analytical results are compared to the surface water
standards found in Title 15A NCAC 02B .0211 (02B Standard) for Class C waters. Leachate analytical results
are not compared to groundwater or surface water quality standards.
Duke Energy personnel sample designated locations for groundwater, surface water, and leachate at the
Asheville CCR Landfill semiannually during March and September. The next water quality monitoring event for
the CCR Landfill is planned for March 2023 with a report of monitoring results to follow.
If you have any questions or concerns with this submittal, please do not hesitate to contact me at
Ashley. Healv(o)duke-energv.com or [phone].
Respectfully submitted,
j4VAi
Ashley Healy, P.G.
Environmental Services
Attachments: Semiannual Water Quality Monitoring Report — September 2022 Sampling Event; SynTerra,
January 2023
www.duke-energy.com Page 1 of 2

cc (via e-mail): Claire Osborn, NCDEQ
Elizabeth Werner, NCDEQ
Sherri Stanley, NCDEQ
Ed Mussler, NCDEQ
Joe Wilson, Duke Energy
John Toepfer, Duke Energy
Connor Zahora, Duke Energy
Nathan Grant, Duke Energy
Teresa Williams, Duke Energy
Tyler Hardin, Duke Energy
Kelly Ferri, SynTerra
Craig Eady, SynTerra
www.duke-energy.com Page 2 of 2

DENR USE ONLY ❑Paper Report [-]Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
SynTerra Corporation (Consultant)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Kelly Ferri Phone: [phone]
E-mail: kferri(cDsvnterracorp.com
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 20-24, 2006)
Duke Energy Progress 46 Duke Energy Lane 11119-INDUS-2020 1.0500 Se tember 26, 2022
Asheville Steam Electric Plant Arden, NC 28704
CCR Landfill
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Craig D. Eady
Project Manager
Facility Representative Name (Print) Title
1 /11 /2023
Signature 6. Date
148 River Street, Suite 220, Greenville, SC 29601
Facility Representative Address
C-1478 / North Carolina Geological Corporation Number C-387
[phone]
(Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
`h CAROf r
\ +•• S •tj I'
+ SEAL
i�i ' •;COI, pCa��;+' �i�:
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

REPORT VERIFICATION
PROJECT: SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
CCR LANDFILL
PERMIT NO. 1119-INDUS-2020
TITLE: SEPTEMEBR 2022 SAMPLING EVENT
This document has been reviewed for accuracy and quality commensurate with the intended
application.
Prepared by: F Date
Approved by: `� Date
Project Manager: Craig Eady, G
1/11/2023
1/11/2023
Licensed Geologist Seal:
4L�t1tiCArR{ff{!
:7
SEAL
g • q
�fO u�p��
SynTerra
148 River Street, Suite 220
Greenville, SC 29601
North Carolina Geological Corporation Number C-387

17
Terra Science &Engineering Consultants
synsynterracorp.com
SEMIANNUAL
WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
CCR LANDFILL
PERMIT NO. 1119-INDUS-2020)
ASHEVILLE STEAM ELECTRIC PLANT
46 DUKE ENERGY LANE
ARDEN, NORTH CAROLINA 28704
JANUARY 12, 2023
PREPARED FOR
DUKE
ENERGY.:
PROGRESS
DUKE ENERGY PROGRESS, LLC
t
Crai ady, NC L.G. # 99 Ryan Badum
enior Peer Revi4er Project Scientist
Kelly Ferri
Project Manager

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLE OF CONTENTS
SECTION PAGE
1.0 INTRODUCTION AND BACKGROUND..........................................................................1-1
1.1 Site and Landfill Information......................................................................................1-1
1.2 Hydrogeologic Setting................................................................................................1-1
1.3 Landfill Semiannual Monitoring Program...................................................................1-2
2.0 METHODS.................................................................................................................. 2-1
2.1 Sampling and Analysis Methods.................................................................................2-1
2.2 Regulatory Criteria.....................................................................................................2-1
2.3 Statement of Work.....................................................................................................2-1
3.0 RESULTS.....................................................................................................................3-1
3.1 Site Groundwater Flow...............................................................................................3-1
3.2 Historical Range Data.................................................................................................3-1
3.3 Analytical Results.......................................................................................................3-2
3.4 Quality Assurance/Quality Control.............................................................................3-2
4.0 REFERENCES...............................................................................................................4-1
LIST OF FIGURES
Figure 1 Site Location Map
Figure 2 Sample Locations
Figure 3A Groundwater Level Map — Surficial and Transition Flow Zones
Figure 3B Groundwater Level Map — Bedrock Flow Zone
LIST OF TABLES
Table 1 Well Construction Summary
Table 2 Groundwater, Surface Water, and Leachate Monitoring Parameters
Table 3 Field Data Parameters
Table 4 Groundwater Seepage Velocities
Table 5 Groundwater Field Results and Analytical Detections
Table 6 Field and Analytical Results that Equal or Exceed Groundwater Quality Standards
Table 7 Surface Water Field Results and Analytical Detections
Table 8 Leachate Field Results and Analytical Detections
LIST OF APPENDICES
Appendix A Field Sampling Forms
Appendix B Laboratory Report and Chain -of -Custody Forms
January 2023 Page i
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
LIST OF ACRONYMS
02L
Title 15A, NCAC 02L .0202(g) Groundwater Quality Standards
02B
Title 15A, NCAC 02B .0200 Surface Water and Wetland standards
Asheville Plant
Asheville Steam Electric Plant
CAMA
Coal Ash Management Act
CCR
coal combustion residuals
Duke Energy
Duke Energy Progress, LLC
DWM
Division of Waste Management
EDD
electronic data deliverable
Landfill
Asheville CCR Landfill
MSE
mechanically stabilized earth
NCAC
North Carolina Administrative Code
NCDEQ
North Carolina Department of Environmental Quality
Site
Asheville Steam Electric Plant
SWLF
Solid Waste Landfill
SWS
Solid Waste Section
TDS
total dissolved solids
USEPA
U.S. Environmental Protection Agency
WQMP
Water Quality Monitoring Plan
January 2023 Page H
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
f��>• I ►19.1611111I4111 9 IQ ► I_10 1113Uffel KC11:191110 L7
This semiannual report pertains to the Duke Energy Progress, LLC (Duke Energy) Asheville
Steam Electric Plant (Asheville Plant, Site) Coal Combustion Residual (CCR) Landfill (Landfill;
Permit No. 1119-INDUS-2020) and documents the results of the September 2022 groundwater,
surface water, seep, and leachate monitoring event.
Monitoring results show that groundwater constituents greater than comparison criteria are
attributable to natural variation and not the CCR Landfill, except sulfate concentrations in one
monitoring well (LMW-3B). Additional monitoring and data are needed to determine the cause
and significance of the sulfate concentration greater than historical background concentrations.
1.1 Site and Landfill Information
Duke Energy owns and operates the Asheville Steam Electric Plant, located on approximately
786 acres, addressed at 46 Duke Energy Lane in Arden, Buncombe County, North Carolina.
(Figure 1).
The Asheville Plant began operations in 1964 with construction of two coal-fired power -
generating units to generate electricity. Throughout the period of coal-fired generation, CCR
was managed and stored on -Site in the 1964 and 1982 Ash Basins. The Asheville Plant ceased
burning coal in January 2020, and the coal-fired units were replaced with a natural gas
combined cycle station for electricity generation; thus, the facility no longer generates CCR.
Excavation of the 1982 Ash Basin was completed in September 2016, and excavation of the
1964 Ash Basin was completed in June 2022.
Development and construction activities for the on -Site double lined CCR Landfill began in
February 2020 and were completed in March 2021. The CCR Landfill was constructed in an area
previously developed as a laydown yard, located north of and adjacent to the 1964 Ash Basin
(Figure 1). The CCR Landfill was constructed to support the last phase of ash excavation from
the 1964 Ash Basin. The Landfill received a Permit Approval to Operate from the North Carolina
Department of Environmental Quality (NCDEQ) on April 1, 2021, and initial placement of CCR
material in the Landfill occurred on the same day. The Landfill Operations Plan (Geosyntec,
2021) and Landfill Permit outline a variety of landfill -approved wastes; however, the primary
waste disposed of in the Landfill is CCR (fly ash and bottom ash). Landfill closure was initiated in
September 2022. Closure is expected to be complete in early 2023.
1.2 Hydrogeologic Setting
The Asheville Plant is located within the Blue Ridge physiographic province, where soil overlying
the bedrock has formed from the in -place weathering of bedrock. Groundwater at the Site
typically occurs in three interconnected flow zones. The shallowest groundwater flow zone —
the surficial flow zone — occurs in the residual soil and/or the upper section of saprolite.
Beneath the surficial flow zone, the transition zone flow zone occurs in the lower portions of
the saprolite and partially weathered bedrock and is the most permeable part of the Site
January 2023 Page 1-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
hydrogeologic system. Bedrock underlies the transition zone and comprises the least
permeable flow zone of the Site's hydrogeologic system, where groundwater flow occurs
predominantly along fractures, joints, and faults. Groundwater is usually encountered in the
surficial flow zone; however, as the hydrogeologic units above the bedrock thin to the west and
northwest, groundwater is encountered only within the lower hydrogeologic unit(s).
Groundwater flow direction at the Landfill is generally to the west toward an unnamed stream,
and to the northwest toward a wetland area and several unnamed streams, which converge
into Powell Creek. The wetland area and streams act as groundwater discharge zones
downgradient of the Landfill. Those surface waters are classified as Class C under Title 15A of
the North Carolina Administrative Code (NCAC), Subchapter 02B, Surface Water and Standards
(02B standards). Flow from those surface water features eventually reaches the French Broad
River, located to the west.
1.3 Landfill Semiannual Monitoring Program
The Water Quality Monitoring Plan (WQMP), Revision 2 (Geosyntec, 2019) for the CCR Landfill
was submitted to NCDEQ on October 31, 2019, and approved on February 7, 2020. The Landfill
semiannual monitoring program, described in detail in the WQMP, consists of 9 groundwater, 3
surface water, 1 seep, and 1 leachate monitoring locations summarized in the following table.
The monitoring locations are shown on Figure 2. A summary of monitoring well construction
information is presented in Table 1 and analytical parameters for the Landfill semiannual
groundwater monitoring program is summarized in Table 2.
January 2023 Page 1-2
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
MONITORING WELLS
MEDIA
COMMENTS
OR SAMPLE LOCATIONS
Background
CB-9, CB-9SL, CB-9BR
Groundwater
LMW-1S, LMW-1B
See Table 1 Well Construction
Summary for monitoring well
LMW-2T, LMW-2B,
construction information.
Downgradient Groundwater
LWM-313, LMW-4B
Three surface water monitoring
locations in two streams located west
and north-northwest, adjacent, and
LF-SW-1, LF-SW-2, LF-SW-3
downgradient of the Landfill (sampled
if flow is present during semiannual
monitoring).
Surface Water
Drainpipe for groundwater seepage
from the northwest portion of the
DP-4
Landfill's mechanically stabilized earth
(MSE) berm (sampled if flow is present
during semiannual monitoring).
Leachate sample, representing
leachate from the entire Landfill, was
Leachate
LCS-1
collected from an in -line sampling
point along the forcemain conveying
leachate from the Landfill to the
Leachate Storage Tank.
Notes:
1. The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised to differentiate between other Site
monitoring program surface water locations.
2. The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sample collection.
3. Two additional groundwater monitoring wells (LMW-1T and LMW-2S) were included as proposed monitoring wells in the WQMP but were
not installed. Monitoring well LMW-1T was proposed to be screened in the transition zone; however, no transition zone was observed
during drilling. Monitoring well LMW-2S was not installed because the surficial aquifer was not present at the proposed location.
January 2023 Page 1-3
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
2.0 METHODS
2.1 Sampling and Analysis Methods
Groundwater, surface water, seep, and leachate sampling was conducted by Duke Energy
personnel (Duke Energy North Carolina Field Certification #5193) on September 26, 2022, in
accordance with the North Carolina Solid Waste Management Guidelines. Copies of the field
sampling forms are included in Appendix A. Duke Energy Analytical Laboratory (North Carolina
Laboratory Certification #248) and Pace Analytical Laboratory (North Carolina Laboratory
Certification #40) analyzed the reported parameters and constituents. The laboratory report
and chain -of -custody forms are included in Appendix B.
The samples were analyzed for the list of parameters and constituents outlined in the WQMP
and guidance from the NCDEQ Division of Waste Management (DWM), Solid Waste Section
(SWS). The monitoring parameters, along with the U.S. Environmental Protection Agency
(USEPA) Solid Waste (SW)-846 analytical methods, Title 15A, NCAC, Subchapter 02L .0202(g),
Groundwater Quality Standards (02L standards), and 15A NCAC 02B .0200 Surface Water and
Wetland standards (0213 standards) for Class C waters are present in Table 2.
2.2 Regulatory Criteria
Evaluation of the semiannual monitoring analytical results are compared to the following
regulatory criteria:
Groundwater
• 02L standards
Surface Water/Seep
• 02B standards
2.3 Statement of Work
The following tasks were completed for semiannual water quality monitoring:
• Groundwater, surface water, and leachate were collected on September 26, 2022.
(Duke personnel completed this task.)
• Compared groundwater analytical results to 02L standards and historical concentration
ranges.
• Compared surface water analytical results to 02B standards and historical concentration
ranges.
• Developed generalized groundwater contour maps using groundwater elevation data
collected during the September 2022 groundwater monitoring event.
• Calculated groundwater flow velocities based on groundwater elevations at wells
perpendicular to groundwater flow.
January 2023 Page 2-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
• Converted the laboratory provided electronic data deliverable (EDD) to the format
requirements of the NCDEQ DWM EDD template and submitted copies of the EDDs to
the NCDEQ DWM with this report.
• Prepared and submitted this Semiannual Water Quality Monitoring Report.
January 2023 Page 2-2
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
3.1 Site Groundwater Flow
Groundwater flow in the aquifer beneath the Landfill footprint flows generally to the west
toward an unnamed stream, and to the northwest toward a wetland area and several unnamed
streams, which converge into Powell Creek.
Generalized groundwater elevation contours and groundwater flow direction arrows in the
vicinity of the CCR Landfill are shown on Figure 3A for the surficial and transition flow zones,
and Figure 313 for the bedrock flow zone. These contours were developed by calculating
groundwater elevations in each monitoring well using the depth -to -water -level measurements
taken during the September 2022 monitoring event. In addition, water -level measurements
from nearby groundwater monitoring wells included in other Site groundwater monitoring
programs were used. Depth -to -water measurements and calculated groundwater elevations
are presented in Table 3. Calculated groundwater flow velocities are presented in Table 4.
Calculated groundwater elevations based on depth -to -water measurements gauged during the
September 2022 monitoring event indicate groundwater at the Landfill generally flows to the
west and northwest, consistent with historical Site observations.
3.2 Historical Range Data
Newly Installed Landfill Groundwater Monitoring Wells
The WQMP included collecting four groundwater samples from each new Landfill monitoring
well prior to the Landfill becoming operational (baseline samples). The four baseline monitoring
events occurred between September 2020 and January 2021, with samples collected from each
well approximately once every 30 days. The baseline monitoring included measuring
groundwater field parameters, gauging depth -to -water in the wells, and analysis of the
collected groundwater samples for the list of parameters and constituents outlined in the
WQMP (same parameter list sampled and analyzed for in the Landfill semiannual monitoring
program). The results of the four baseline sampling events were submitted in the Groundwater
Monitoring Report Baseline Sampling Events #1 Through #4 — CCR Landfill (Baseline Report)
(SynTerra, 2021). For each newly installed monitoring well, historical ranges of constituent
concentrations were calculated using the analytical results from the four baseline monitoring
events.
Existing Wells Incorporated into the Landfill Monitoring Program
Monitoring wells CB-9, CP-9SL, and CP-9BR existed at the Site prior to Landfill development but
are incorporated into the Landfill monitoring program. Those three wells were not sampled
during baseline sampling events for the newly installed wells. Rather, data from these wells,
collected as part of other regulatory sampling programs well in advance of Landfill operations,
were used to satisfy the initial baseline sampling requirements. Historical concentration ranges
January 2023 Page 3-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
for existing wells were established using all available data collected prior to initiation of Landfill
operations (November 2012 to January 2021).
3.3 Analytical Results
A summary of the groundwater, surface water, and leachate field data is presented in Table 3.
The analytical results and reference comparisons discussed below are summarized in Tables 5
through 8. Sample locations are depicted on Figure 2.
Groundwater Results
Field and analytical results for the collected downgradient and background groundwater
samples are presented in Table 5. Groundwater analytical results are compared with 02L
standards. Constituent concentrations equal to or greater than their 02L standard are noted in
Table 5 in bold font. The laboratory analytical reports are included as Appendix B.
A summary of the downgradient groundwater field and analytical results that are equal to or
greater than applicable comparison criteria are presented in Table 6.
The groundwater concentrations in Table 6, which are identified as being equal to or greater
than the 02L standard, are attributable to natural variation, except for sulfate in LMW-313. The
sulfate concentration in LMW-313 is only slightly greater than the 02L standard and greater than
historical background concentrations for the first time; therefore, a cause and significance
cannot be determined at this time.
Surface Water
Field and analytical results for surface water samples are presented in Table 7. The sample
locations are shown on Figure 2. Analytical results for surface water and seep samples, as
available, are compared with applicable 02B Class C surface water standards. Surface water
sample LF-SW-1 and seep location DP-4 were not sampled during the September 2022 sampling
event because of dry conditions. No surface water samples collected during the September
2022 sampling event were greater than or equal to applicable 02B Class C surface water
standards.
Leachate
A leachate sample (LCS-1) was collected from the leachate collection discharge pipe on the
west side of the Landfill. Analytical results are presented in Table 8. Leachate analytical results
are not compared to groundwater (02L standards) or surface water (0213 standards) quality
standards and are provided for informational purposes only.
3.4 Quality Assurance/Quality Control
Field -performed quality assurance and quality control (QA/QC) consisted of the collection and
analysis of two field blanks (one on each day of sampling) to evaluate if possible impacts were
imparted to the samples by the sample container, preservative, or other exogenous sources. A
field duplicate sample was also collected to estimate sampling and laboratory precision. Iron
January 2023 Page 3-2
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Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
was detected in the field blank at a concentration greater than the method detection limit.
However, all data were validated and deemed usable.
Select samples were diluted, as is normal laboratory practice, to bring samples within the
calibrated range of the analysis. Specifics regarding the samples that were diluted, including the
dilution amount, are reported in the lab report. Additional QA/QC data, laboratory analyses,
and chain -of -custody forms are included in Appendix B.
January 2023 Page 3-3
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
Geosyntec. (2019). Water Quality Monitoring Plan Revision Z Asheville Steam Electric Plant CCR
Landfill, October 2019.
Geosyntec. (2021). Operations Plan, Asheville Steam Electric Plant, CCR Landfill (1119-INDUS)
Rev. Z February 19, 2021.
SynTerra. (2021). Groundwater Monitoring Report Baseline Sampling Events #1 Through #4 —
CCR Landfill, Asheville Steam Electric Plant. April 2021.
January 2023 Page 4-1
Project: 00.0069.34.07.02

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
FIGURES
L7
synTerra
Science & Engineering Consultants

1964 ASH BASIN WA
BOUNDARY
. r �
0 ♦
r-
.'/0
I - RETIRED ASHEVILLE
I I STEAM ELECTRIC
♦ r ;
I `
•
1982 ASH BASIN
- - -
WASTE BOUNDARY
,r
♦
'';
l i • `
- - '
DUKE ENERGY PROGRESS
PROPERTY BOUNDARY
�>
ASHEVILLE COMBINED
CYCLE STATION
NOTES:
1. ALL BOUNDARIES ARE APPROXIMATE.
2. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
3. USGS TOPOGRAPHIC MAP OBTAINED FROM ESRI ONLINE,
LAST UPDATED AUGUST 2021.
DUKE
ENERGY It BUNCOMBE
COUNTY �
PROGRESS
r
ASHEVILLEA
FIGURE 1
SITE LOCATION MAP
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
IRLOTTE
ARDEN, NORTH CAROLINA
DRAWN BY: B. MCGANN
DATE: 12/08/2021
GRAPHIC SCALE
REVISED BY KING DATE: 12/21/2022
CHECKED BY: R. BADUM DATE: 12/21/2022
APPROVED BY: K. FERRI DATE: 12/21/2022
PROJECT MANAGER_ K. FERRI
1,000 0 1,000 2000,
)IN FEET)

LEGEND
SURFACE WATER SAMPLE LOCATION
�® _- -
-- LEACHATE SAMPLE LOCATION
f..
DRAINPIPE SEEP SAMPLE LOCATION
000,
� DOWNGRADIENT MONITORING WELL
BACKGROUND MONITORING WELL
LEACHATE FORCEMAIN
L `� LANDFILL LIMIT OF WASTE
LMW-2T \� ��` \\\� LANDFILL REVIEW BOUNDARY
-
/ -- LANDFILL COMPLIANCE BOUNDARY
)► STREAM (TWT)
WETLANDS (TWT)
NOTES:
1. LF-SW-1, LF-SW-2, AND LF-SW-3 SAMPLE IDS HAVE BEEN REVISED FROM THE WQMP
IN ORDER TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING PROGRAM
SURFACE WATER SAMPLES WITH THE SAME SAMPLE IDS AS PRESENTED IN THE WQMP.
LEACHATE SAMPLE _CS-1 IS IDENTIFIEDAS L-1 IN THE WQMP.
2. WQMP - WATER QUALITY MONITORING PLAN
t
0000 ` 3. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
4. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USACE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION
DP-4 SAW 2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF
LMW-1 B, THE FEATURES.
5. ALL BOU NDARI ES ARE APPROXI MATE.
LMW-1 S I 6. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
/ LMW-4B _ - I 7. LANDFILLAERIAL SURVEY AND TOPOGRAPHY COLLECTED ON NOVEMBER 30, 2021
BY WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOOGLE
EARTH ON APRIL 27, 2022. IMAGE DATED APRIL 2022.
LANDFILL LIMIT 8. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINASTATE PLANE
OF WASTE COORDINATE SYSTEM RIPS 3200 (NAD83)
1. 0
LEACHATE FORCEMAIN CB-9SL CB-9�
31
f — '� �: v MW-13D
1000,
�. DUKE
}d-r ENERGY
\ PROGRESS
synTerra
LANDFILL REVIEW BOUNDARY
(APPROXIMATELY 80' FROM ' =s
LIMIT OF WASTE) /4
r
LANDFILL COMPLIANCE
BOUNDARY (APPROXIMATELY
160' FROM LIMIT OF WASTE) ,
..vim-
GRAPHIC SCALE
75 0 75 150 FIGURE 2
SAMPLE LOCATIONS
(IN FEET) CCR LANDFILL
DRAWN BY e MCGANN DATE iz/os/zozi SEMIANNUAL WATER QUALITY MONITORING REPORT
REUSED BY T KING DATE 01/11/2023 SEPTEMBER 2022 SAMPLING EVENT
AH PROVED
R eADUM DATE 01/11/2023 ASHEVILLE STEAM ELECTRIC PLANT
APPROVED BY K. FERRI DATE_01/11/2023
PROJECTMANAGER:K-FERRI ARDEN, NORTH CAROLINA
www.synterracorp.com

I
1)
1-� i��o_-
/ ti MW 13D"
2123.85 z17
loep
I
o
LANDFILL LIMI
OF WASTE
I
�o
LANDFILL REVIEW BOUNDAF
(APPROXIMATELY 80' FROM
LIMIT OF WASTE)
C6 '
2144.948
c
3-9SL /
44.82
LANDFILL COMPLIANCE
BOUNDARY (APPROXIMATEL'
160' FROM LIMIT OF WASTE)
2170 - -'
LEGEND
SURFACE WATER SAMPLE LOCATION
LEACHATE SAMPLE LOCATION
O DRAINPIPE SEEP SAMPLE LOCATION
BACKGROUND MONITORING WELL
DOWNGRADIENT MONITORING WELL
GROUNDWATER FLOW DIRECTION
-- INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
LANDFILL LIMIT OF WASTE
LANDFILL REVIEW BOUNDARY
-- LANDFILL COMPLIANCE BOUNDARY
►— STREAM (TWT)
WETLANDS (TWT)
TOPOGRAPHIC CONTOUR (10' INTERVAL)
NOTES:
1. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
.'.C; IDENTIFIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE
.,k COLLECTION.
2. * - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
FOR GROUNDWATER ELEVATION DATA ONLY.
3. W.E. - WATER ELEVATION (APPROXIMATE).
4. WQMP - WATER QUALITY MONITORING PLAN
5. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
�f} 6. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USAGE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION SAW
2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF THE
FEATURES.
7. ALL BOUNDARIES ARE APPROXIMATE.
8. PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
<9. LANDFILLAERIAL SURVEYAND TOPOGRAPHY COLLECTED ON NOVEMBER 30, 2021 BY
WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOOGLE EARTH ON
APRIL 27, 2022. IMAGE DATED APRIL 2022.
10. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
- _ COORDINATE SYSTEM RIPS 3200 (NAD83).
11. GROUNDWATER ELEVATIONS BASED ON WATER LEVELS COLLECTED SEPTEMBER 26,
2022.
DUKE 75 GRAPHIC SCALE FIGURE 3A
0 75 150
ENERGY (IN FEET) GROUNDWATER LEVEL MAP
PROGRESS SURFICIAL AND TRANSITION FLOW ZONES
DRAWN BY. B. MCGANN DATE-12/08/2021 SEMIANNUAL WATER QUALITY MONITORING REPORT
REVISED BY T KING DATE_ 12/21/2022
VIP
CHECKED BY R. BADUM DATE: 12/21/2022 SEPTEMBER 2022 SAMPLING EVENT
APPROVED BY. K. FERRI DATE_ 12/21/2022
PROJECT MANAGER: K-FERRI ASHEVILLE STEAM ELECTRIC PLANT
synTerra www.synterracorp.com ARDEN, NORTH CAROLINA

�-
��
' I I LMW-2B �
2056.39
1 OADi
2.
2�y0
//
I/
LMW-4B
I/ II 2079.87
O
LEAC MW 13BR*
•T
ef 5maigmt ` 2124.02 z17
2160
2120
CB-8BR* ,.;
2092.05
II
I
I
r LEGEND
SURFACE WATER SAMPLE LOCATION
\A LEACHATE SAMPLE LOCATION
_MW-1B ` / �I 0 DRAINPIPE SEEP SAMPLE LOCATION
BACKGROUND MONITORING WELL
DOWNGRADIENT MONITORING WELL
LANDFILL LIMIT GROUNDWATER FLOW DIRECTION
OF WASTE
INFERRED WATER ELEVATION CONTOUR (20' INTERVAL)
I LANDFILL LIMIT OF WASTE
I LANDFILL REVIEW BOUNDARY
'� -- LANDFILL COMPLIANCE BOUNDARY
C +( STREAM (TWT)
WETLANDS (TWT)
LANDFILL REVIEW BOUNDARY TOPOGRAPHIC CONTOUR (10' INTERVAL)
` (APPROXIMATELY 80' FROM
LIMIT OF WASTE) NOTES:
1. THE WQMP IDENTIFIES THE SURFACE WATER SAMPLES AS SW-1, SW-2, AND SW-3.
IDENTIFIFICATION WAS REVISED TO DIFFERENTIATE BETWEEN OTHER SITE MONITORING
I - PROGRAM SURFACE WATER LOCATIONS. THE WQMP IDENTIFIES THE LEACHATE
COLLECTION SAMPLE AS L-1. IDENTIFICATION WAS REVISED IN THE FIELD DURING SAMPLE
COLLECTION.
\ CB-9BR' 2. * - MONITORING WELL PART OF ANOTHER REGULATORY SAMPLE PROGRAM AND USED
... 2129.56 FOR GROUNDWATER ELEVATION DATA ONLY.
3. W.E. - WATER ELEVATION (APPROXIMATE).
2 80
4. WQMP -WATER QUALITY MONITORING PLAN
f 5. ALL SAMPLE LOCATIONS ARE APPROXIMATE.
z1s0 /- _ Irk 6. THE DEPICTED STREAMS AND WETLANDS DATA WERE APPROVED BY THE US ARMY
CORPS OF ENGINEERS (USACE) ON MAY 19, 2016 - JURISDICTIONAL DETERMINATION SAW
2014-00189. TAYLOR WISEMAN AND TAYLOR (TWT) PERFORMED THE SURVEY OF THE
LANDFILL COMPLIANCE FEATURES.
7. ALL BOUNDARIES ARE APPROXIMATE.
BOUNDARY (APPROXIMATELY
' \" <160' FROM LIMIT OF WASTE) 8 PROPERTY BOUNDARY PROVIDED BY DUKE ENERGY PROGRESS.
- / 9 LANDFILL AERIAL SURVEY AND TOPOGRAPHY COLLECTED ON NOVEMBER 30 2021 BY
w, WASTE MANAGEMENT. ADDITIONAL AERIAL IMAGERY OBTAINED FROM GOOGLE EARTH ON
APRIL 27, 2022. IMAGE DATED APRIL 2022.
- - 10. DRAWING HAS BEEN SET WITH A PROJECTION OF NORTH CAROLINA STATE PLANE
- - COORDINATE SYSTEM RIPS 3200 (NAD83).
"T 11. GROUNDWATER ELEVATIONS BASED ON WATER LEVELS COLLECTED SEPTEMBER 26,
2022.
DUKE GRAPHIC SCALE FIGURE 3B
75 0 75 150
ENERGY (IN FEET) GROUNDWATER LEVEL MAP
PROGRESS BEDROCK FLOW ZONE
DRAWN Br. B. MCGANN DATE 12/08/2021 SEMIANNUAL WATER QUALITY MONITORING REPORT
REVISED BY T KING DATE_ 01/09/2023
VIP
CHECKED BY R. BADUM DATE: 01/09/2023 SEPTEMBER 2022 SAMPLING EVENT
APPROVED BY. K. FERRI DATE_ 01/09/2023
PROJECT MANAGER: K-FERRI ASHEVILLE STEAM ELECTRIC PLANT
synTerra www.synterracorp.com ARDEN, NORTH CAROLINA

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
TABLES
L7
synTerra
Science & Engineering Consultants

TABLE 1
WELL CONSTRUCTION SUMMARY
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Well ID
Date
Installed
Flow Zone
Material
Diameter
(Inches)
Latitude
(degrees)
Longitude
(degrees)
Well Depth
(Ft, BTOC)
Screened
Interval
(Ft, BGS)
Measuring Point TOC
(Ft, NAVD 88)
Ground Surface
(Ft, NAVD 88)
Groundwater
Elevation
(Ft NAVD 88)
Depth to Water
(Ft BTOC)
CB-9*
10/8/2012
Surficial
PVC
2
35.4720450
-82.5467520
65.60
52-62
2182.08
2178.86
2144.48
37.60
CB-9BR*
4/21/2015
Bedrock
PVC
2
35.4720311
-82.5467707
97.85
83-93
2181.11
2178.15
2129.56
51.55
CB-9SL*
4/21/2015
Saprolite
PVC
2
35.4720577
-82.5467646
78.10
69-74
2181.42
2178.17
2144.82
36.60
LMW-1B*
9/11/2020
Bedrock
PVC
2
35.4732130
-82.5469693
103.20
91-101
2169.67
2169.53
2146.64
23.03
LMW-1ST
8/31/2020
Surficial
PVC
2
35.4731733
-82.5469538
66.60
55-65
2169.73
2169.58
2143.50
26.23
LMW-2B
9/11/2020
Bedrock
PVC
2
35.4740577
-82.5491559
110.30
100.5-110.5
2121.16
2120.84
2056.39
64.77
LMW-2T
9/11/2020
Transition
PVC
2
35.4741121
-82.5491312
87.00
76-86
2123.11
2123.20
2058.31
64.80
LMW-3B
9/11/2020
Bedrock
PVC
2
35.4734715
-82.5496049
45.30
33-43
2102.89
2102.80
2069.26
33.63
LMW-4B
9/11/2020
Bedrock
PVC
2
35.4729336
-82.5506071
49.25
39-49
2102.67
2102.57
2079.87
22.80
Notes:
* - Indicates background groundwater monitoring well.
Groundwater elevations are based on data collected during the September 2022 sampling event.
BGS - below ground surface
BTOC - below top of casing
CCR - coal combustion residual
Ft - feet
NAD 83 - Horizontal coordinates based on the North American Datum of 1983.
NAVD 88 - Vertical elevations in feet based on North American Vertical Datum of 1988
NM - not measured
PVC - polyvinylchloride
TOC - top of casing
Prepared by: RSB Checked by: KCO
Page 1 of 1

TABLE 2
GROUNDWATER, SURFACE WATER, AND LEACHATE MONITORING PARAMETERS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Field Parameters
Analytical Methods
Units
15A NCAC
1
02L Standard
15A NCAC 02B
2
(Class C)
pH
Multi -Parameter Water Quality Meter
S.U.
6.5 - 8.5
6.0 - 9.0
Temperature
Multi -Parameter Water Quality Meter
degrees Celsius
NE
:529
Specific Conductance
Multi -Parameter Water Quality Meter
µmhos/cm
NE
NE
Dissolved Oxygen
Multi -Parameter Water Quality Meter
mg/L
NE
>_4
Oxidation Reduction Potential
Multi -Parameter Water Quality Meter
millivolts
NE
NE
Turbidity
Turbidimeter
NTU
NE
:550
Water Level
Water Level Meter
ft
NE
NE
Laboratory Parameters
Analytical Methods
Units
15A NCAC
t
02L Standard
15A NCAC 02B
2
(Class C)
Antimony
EPA 200.8/EPA 6020B
µg/L
1
NE
Arsenic
EPA 200.8/EPA 6020E
µg/L
10
NE
Barium
EPA 200.7/EPA 6010D
µg/L
700
NE
Beryllium
EPA 200.7/EPA 6010D
µg/L
4
NE
Boron
EPA 200.7/EPA 6010D
µg/L
700
7300*
Cadmium
EPA 200.8/EPA 6020E
µg/L
2
NE
Chloride
EPA 300.0/EPA 9056A
mg/L
250
230
Chromium
EPA 200.8/EPA 6020E
µg/L
10
NE
Cobalt
EPA 200.8/EPA 6020B
µg/L
1
NE
Copper
EPA 200.7/EPA 6010D
µg/L
1,000
NE
Fluoride
EPA 300.0/EPA 9056A
mg/L
2
1.8
Iron
EPA 200.7/EPA 6010D
µg/L
300
NE
Lead
EPA 200.8/EPA 6020B
µg/L
15
NE
Manganese
EPA 200.7/EPA 6010D
µg/L
50
NE
Mercury
EPA 7470A
µg/L
1
0.012
Nickel
EPA 200.7/EPA 6010D
µg/L
100
NE
Nitrate
EPA 300.0/EPA 9056A
mg-N/L
10
NE
Selenium
EPA 200.8/EPA 6020E
µg/L
20
NE
Silver
EPA 200.8/EPA 6020B
µg/L
20
NE
Sulfate
EPA 300.0/EPA 9056A
mg/L
250
NE
Thallium
EPA 200.8/EPA 6020B
µg/L
2
NE
Total Dissolved Solids
SM 2540C
mg/L
500
NE
Vanadium
EPA 200.8/EPA 6020B
µg/L
7
NE
Zinc
EPA 200.7/EPA 6010D
µg/L
1,000
NE
Prepared by: KHF Checked by: TCP
Notes:
1- 15A NCAC 02L Standards for groundwater - North Carolina groundwater quality standards (effective April 1, 2022).
z - 15A NCAC 02B Standards for Class C surface waters - North Carolina surface water and wetland standards (effective September 1, 2022).
In -stream target value established per the language in 15A NCAC 02B .0202 and .0208.
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
EPA - US Environmental Protection Agency
ft- feet
mg/L- milligrams per liter
my
- millivolts
NE -
not established
NTU
- nephelometric turbidity units
S.U.
- standard units
Page 1 of 1

TABLE 3
Id � � _�l_\l_1:T_1►�iL�hJ:��
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Sample ID
Sample
Date
Appearance
Odor
Purge
Method
Average
Pump Rate
(mL/min)
Temp
(Deg C)
Specific
Conductance
(µmhos/cm)
pH
(S.U.)
ORP
(mV)
Dissolved
Oxygen
(mg/L)
Turbidity
(NTU)
Groundwater
Elevation
(Ft NAVD 88)
Depth
to Water
(Ft BTOC)
Groundwater Parameters
C13-9
9/26/2022
Clear
None
Low Flow
180
19
29
4.9
348
2.45
4.3
2144.48
37.60
C13-913R
9/26/2022
Clear
None
Low Flow
300
18
84
5.9
289
0.29
7.3
2129.56
51.55
CB-9SL
9/26/2022
Clear
None
Low Flow
110
19
46
5.5
339
3.64
6.5
2144.82
36.60
LMW-113
9/26/2022
Clear
None
Low Flow
250
19
104
6.2
277
0.27
6.1
2146.64
23.03
LMW-1S
9/26/2022
Clear
None
Low Flow
300
18
62
5.9
413
2.14
4.3
2143.50
26.23
LMW-213
9/26/2022
Clear
None
Low Flow
300
19
69
6.5
269
1.92
4.0
2056.39
64.77
LMW-2T
9/26/2022
Clear
None
Low Flow
180
19
61
7.0
396
4.08
4.7
2058.31
64.80
LMW-313
9/26/2022
Clear
None
Low Flow
180
16
476
6.9
334
1.29
3.4
2069.26
33.63
LMW-413
9/26/2022
Clear
None
Low Flow
350
15
396
6.2
204
0.24
7.7
2079.87
22.80
Surface Water Parameters
LF-SW-1*
Dry, not sampled.
LF-SW-2*
9/26/2022
Clear
None
NA
NA
17
98
8.1
445
8.49
6.5
NA
NA
LF-SW-3*
9/26/2022
Clear
None
NA
NA
19
59
7.7
374
8.13
7.1
NA
NA
DP-4
Dry, not sampled.
Leachate Collection Parameters
LCS-1**
1 9/26/2022
Clear
None
NA
NA
21
1509
6.7
401
7.12
19.0
NA
NA
Notes:
The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised to differentiate between other Site monitoring program surface water locations.
** - The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sampling collection.
µmhos/cm - micromhos per centimeter
BTOC - below top of casing
Deg C - degrees Celsius
ft - feet
mg/L - milligrams per liter
mL/min - milliliters per minute
mV - millivolts
NA - not applicable
NAVD88 - North American Vertical Datum of 1988
NTU - Nephelometric turbidity units
ORP - oxidation reduction potential
S.U. - standard units
Prepared by: RSB Checked by: KCO
WQMP - Water Quality Monitoring Plan
Page 1 of 1

TABLE 4
GROUNDWATER SEEPAGE VELOCITIES
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Surficial and Transition Flow Zone
Upgradient
Downgradient
Seepage
Groundwater
Groundwater
K
Ah
Distance
Well ID
Effective Porosity
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)
(Ft NAVD 88)
(Ft NAVD 88)
LMW-1S to LMW-2T
2143.50
2058.31
0.33
85.20
733
0.2
0.192
Bedrock Flow Zone
Upgradient
Downgradient
Seepage
Well ID
Groundwater
Groundwater
K
Oh
Distance
Effective Porosity
Velocity
Elevation
Elevation
1
(ft/day)
(ft)
(ft)
(ft/day)Z
(Ft NAVD 88)
(Ft NAVD 88)
LMW-113 to LMW-26
2146.64
2056.39
1.96
90.24
720
0.001
245.7
C13-96R to LMW-36
2129.56
2069.26
1.96
60.30
993
0.001
119.0
Notes:
1- Hydraulic conductivity values taken from slug test performed on monitoring wells with in each flow zone.
Z - Value represents an estimate of the velocity of groundwater through bedrock fractures.
Groundwater elevations are based on water level data collected on September 26, 2022.
Monitoring wells are not listed where groundwater contour information is unavailable to calculate velocity.
Hydraulic gradients and groundwater velocities are approximate.
Effective porosity taken from the Updated Groundwater Flow and Transport Modeling Report for Asheville Steam Electric Plant, Arden, NC - September 2022.
ft - feet
ft/day - feet per day
NAVD 88 - North American Vertical Datum 1988
Prepared By: RSB Checked By: KHF
Page 1 of 1

TABLE 5
GROUNDWATER FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Monitoring Wells
MDL
SW GWPS
15A NCAC 02L Standard
CB-9
CB-9BR
CB-9SL
LMW-1B
LMW-1S
LMW-2B
LMW-2T
LMW-3B
LMW-4B
pH
320
S.U.
4.9
5.9
5.5
6.2
5.9
6.5
7.0
6.9
6.2
NE
6.5-8.5
Temperature
325
Deg C
19
18
19
19
18
19
19
16
15
NE
NE
Specific Conductance
323
µmhos/cm
29
84
46
104
62
69
61
476
396
NE
NE
Dissolved Oxygen
-
mg/L
2.45
0.29
3.64
0.27
2.14
1.92
4.08
1.29
0.24
NE
NE
Oxidation Reduction Potential
336
mV
348
289
339
277
413
269
396
334
204
NE
NE
Eh
-
mV
553
494
544
482
618
474
601
539
409
NE
NE
Turbidity
330
NTU
4.3
7.3
6.5
6.1
4.3
4.0
4.7
3.4
7.7
-
NE
NE
Antimony
13
µg/L
<1
<1
0.135 JB
<1
<1
<1
<1
<1
0.133 JB
0.104
NE
1
Arsenic
14
µg/L
0.15 J
<1
<1
0.117 J
0.122 J
<1
<1
0.341 J
0.375 J
0.111
NE
10
Barium
15
µg/L
27
25
44
27
41
46
31
77
28
2
NE
700
Beryllium
23
µg/L
<5
<S
<5
<S
<5
<S
<5
<S
<5
2
NE
4
Boron
428
µg/L
6J
<50
<50
<50
<50
12J
26J
12J
44J
5
NE
700
Cadmium
34
µg/L
<1
0.048 J
<1
<1
<1
<1
0.043 J
<1
<1
0.032
NE
2
Chloride
301
mg/L
6.5
7.7
7.8
8.1
6.2
7.9
9.9
3.2
7.6
0.0154
NE
250
Chromium
51
µg/L
0.275 J
<1
0.49 J
0.238 J
0.769 J
0.364 J
<1
0.269 J
<1
0.185
NE
10
Cobalt
53
µg/L
0.9 J
0.084 J
<1
<1
0.674 J
0.286 J
0.404 J
0.384 J
25.8
0.077
NE
1
Copper
54
µg/L
<5
<5
<5
<5
<5
<5
<5
<5
<5
1
NE
1,000
Fluoride
312
mg/L
<0.1
0.05 J
<0.1
<0.1
<0.1
<0.1
<0.1
<0.2
0.45 J
0.0479
NE
2
Iron
340
µg/L
381
50J
131
39J
236
44J
95J
181
11100
4
NE
300
Lead
131
µg/L
<1
0.055 J
0.045 J
<1
0.06 J
0.093 J
0.06 J
0.069 J
<1
0.037
NE
15
Manganese
342
µg/L
31
51
2J
31
71
12
22
300
6140
1
NE
50
Mercury
132
µg/L
0.02 JB
0.01 JB
0.01 JB
0.05 BJ
0.01 JB
0.01 JB
0.01 JB
0.02 JB
0.01 JB
0.01
NE
1
Nickel
152
µg/L
<5
<5
<5
<5
2 J
<5
<5
<5
8
1
NE
100
Nitrate (as N)
303
mg-N/L
0.22
0.02
0.21
0.05
0.62
0.31
3.5
0.4
0.47 J
0.002
NE
10
Selenium
183
µg/L
<1
<1
<1
<1
<1
<1
<1
0.2161
<1
0.193
NE
20
Silver
184
µg/L
0.385 J
0.048 J
0.246 J
<1
<1
0.036 J
<1
0.466 J
<1
0.035
NE
20
Sulfate
315
mg/L
0.12
1.7
0.26
0.33
0.27
2.9
4.6
260
120
0.0428
NE
250
Thallium
194
µg/L
0.08 J
<0.2
<0.2
0.05 J
<0.2
<0.2
<0.2
<0.2
<0.2
0.041
NE
2
Total Dissolved Solids
311
mg/L
26
84
47
85
51
65
51
473
315
25
NE
500
Vanadium
209
µg/L
0.261 JB
0.277 JB
0.318 BJ
0.627 BJ
0.524 BJ
0.743 BJ
0.435 BJ
0.332 BJ
0.142 JB
0.114
NE
7
Zinc
213
µg/L
9
<5
8
<5
6
<5
<5
<5
<5
4
NE
1,000
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of 11/18/2022.
Bold concentrations are equal to or greater than the 15A NCAC 02L Standard (for pH bold indicates a measurement less than or greater than the indicated range).
' - 15A NCAC 02L Standards for groundwater- North Carolina groundwater quality standards (effective April 1, 2022).
CB-9/BR/SL and LMW-1B/S are background groundwater monitoring wells.
Samples collected by Duke personnel on September 26, 2022.
B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank. Analyte concentration in sample could be due to blank contamination.
"C - degrees Celsius
1 - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
my - millivolts
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L- milligrams per liter
mg-N/L- milligrams nitrogen per liter
NCAC- North Carolina Administrative Code
NE - not established
NTU - nephelometric turbidity units
S.U. - standard units
SW GWPS - Solid Waste Groundwater Protection Standard
SWS ID -Solid Waste Section Identification Number
µmhos/cm - micromhos per centimeter
µg/L - micrograms per liter
<- Concentration not detected at or above the adjusted reporting limit.
Prepared by RSB Checked by: KCO
Page 1 of 1

TABLE 6
FIELD AND ANALYTICAL RESULTS THAT EQUAL OR EXCEED GROUNDWATER QUALITY STANDARDS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
September
15A NCAC
Historical
Parameter
Sample ID
2022
Units
02L
Concentration
Cause and Significance
Concentration
Standard'
Range
pH
LMW-413
6.2
S.U.
6.5 - 8.5
6.4 - 6.6
Natural variation, within background concentration range (5.7 - 6.4).3
Cobalt
LMW-413
25.8
µg/L
1
56.7 - 75.6
Natural variation, less than historical concentration range.
Iron
LMW-413
11,100
µg/L
300
20,800 - 27,400
Natural variation, less than historical concentration range.
LMW-313
300
299 - 774
Natural variation, within historical concentration range.
Manganese
µg/L
50
LMW-413
6,140
10,000 - 13,800
Natural variation, less than historical concentration range.
First occurrence greater than historical concentration range; therefore, cause and
Sulfate
LMW-313
260
mg/L
250
75 - 230
significance cannot be determined at this time. Continue monitoring.
Prepared by: RSB Checked by: KCO
Notes:
1 - 15A NCAC 02L Standards for groundwater - North Carolina groundwater quality standards (effective April 1, 2022).
z - Historical concentration ranges are based on data from the four baseline monitoring events that occurred between September 2020 and January 2021, prior to waste placement in the CCR Landfill.
3 - The background concentration range is based on data collected from updgradient bedrock monitoring wells during Landfill compliance sampling events (September 2020 through September 2022).
µg/L - micrograms per liter
mg/L - milligrams per liter
S.U. -standard units
Page 1 of 1

TABLE 7
SURFACE WATER FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Surface Water Sample ID
MDL
15A NCAC 02B
(Class C)Z
LF-SW-2'
LF-SW-3'
pH
320
S.U.
8.1
7.7
6.0 - 9.0
Temperature
325
Deg C
17
19
<_29
Specific Conductance
323
µmhos/cm
98
59
NE
Dissolved Oxygen
-
mg/L
8.49
8.13
>_4
Oxidation Reduction Potential
336
mV
445
374
NE
Eh
-
mV
650
579
NE
Turbidity
330
NTUs
6.5
7.1
-
<_50
Antimony
13
µg/L
<1
0.145 JB
0.104
NE
Arsenic
14
µg/L
0.119 J
0.157 J
0.111
NE
Barium
15
µg/L
15
16
2
NE
Beryllium
23
µg/L
<5
<5
2
NE
Boron
428
µg/L
24 J
251
5
7300*
Cadmium
34
µg/L
0.103 J
<1
0.032
NE
Chloride
301
mg/L
9
9.8
0.0154
230
Chromium
51
µg/L
0.317 J
<1
0.185
NE
Cobalt
53
µg/L
0.295 J
0.1361
0.077
NE
Copper
54
µg/L
<5
<5
1
NE
Fluoride
312
mg/L
0.06J
<0.5
0.0479
1.8
Iron
340
µg/L
205
153
4
NE
Lead
131
µg/L
<1
0.082 J
0.037
NE
Manganese
342
µg/L
198
17
1
NE
Mercury
132
µg/L
0.011E
0.01JB
0.01
0.012
Nickel
152
µg/L
<5
<5
1
NE
Nitrate (as Nitrogen)
303
mg-N/L
0.08
0.07
0.002
NE
Selenium
183
µg/L
<1
<1
0.193
NE
Silver
184
µg/L
<1
<1
0.035
NE
Sulfate
315
mg/L
9.5
4.4
0.0428
NE
Thallium
194
µg/L
0.07 J
<0.2
0.041
NE
Total Dissolved Solids
311
mg/L
50
42
25
NE
Vanadium
209
µg/L
0.3 BJ
0.351 BJ
0.114
NE
Zinc
213
µg/L
<5
<5
4
NE
Prepared by: RSB Checked by: KCO
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of 11/18/2022.
Bold concentrations are equal to or greater than the 15A NCAC 02B Standards for Class C surface waters (for pH, bold indicates a measurement less than or greater than the indicated range).
' The WQMP identifies the surface water samples as SW-1, SW-2, and SW-3. Identification was revised in order to differentiate between other Site monitoring program surface water
locations.
15A NCAC 02B Standards for Class C surface waters. North Carolina surface water and wetland standards (effective September 1, 2022)
Samples collected by Duke Energy personnel on September 26, 2022.
Surface water sample location LF-SW-1' was not sampled due to dry conditions.
- In -stream target value established per the language in 15A NCAC 026 .0202 and .0208.
-- no relevant information.
<- Concentration not detected at or greater than the adjusted reporting limit.
B -Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the method blank.
Analyte concentration in sample could be due to blank contamination.
"C - degrees Celsius
µg/L- micrograms per liter
µmhos/cm - micromhos per centimeter
1- estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL)
MDL - laboratory method detection limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg/L - milligrams per liter
mg-N/L - milligrams nitrogen per liter
my - millivolts
NE - Not established per 15A NCAC 02B.
NTU - nephelometric turbidity units
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
Page 1 of 1

TABLE 8
LEACHATE FIELD RESULTS AND ANALYTICAL DETECTIONS
SEMIANNUAL WATER QUALITY MONITORING REPORT
SEPTEMBER 2022 SAMPLING EVENT
ASHEVILLE STEAM ELECTRIC PLANT
DUKE ENERGY PROGRESS, LLC, ARDEN, NC
Parameter
SWS ID
Units
Leachate Collection Sample
MDL
LCS-11, 2
pH
320
S.U.
6.7
Specific Conductance
323
µmhos/cm
1,509
Temperature
325
Deg C
21
Dissolved Oxygen
-
mg/L
7.12
Oxidation Reduction Potential
336
mV
401
Eh
-
mV
606
Turbidity
330
NTUs
19.0
-
Antimony
13
µg/L
1.67
0.104
Arsenic
14
µg/L
6.06
0.111
Barium
15
µg/L
61
2
Beryllium
23
µg/L
<5
2
Boron
428
µg/L
8,880
5
Cadmium
34
µg/L
0.126 J
0.032
Chloride
301
mg/L
39
0.0154
Chromium
51
µg/L
1.42
0.185
Cobalt
53
µg/L
1.42
0.077
Copper
54
µg/L
3J
1
Fluoride
312
mg/L
1.1 J
0.0479
Iron
340
µg/L
1050
4
Lead
131
µg/L
1.04
0.037
Manganese
342
µg/L
2,880
1
Mercury
132
µg/L
0.02 JB
0.01
Nickel
152
µg/L
5
1
Nitrate (as N)
303
mg-N/L
0.26
0.002
Selenium
183
µg/L
46
0.193
Silver
184
µg/L
<1
0.035
Sulfate
315
mg/L
700
0.0428
Thallium
194
µg/L
0.223
0.041
Total Dissolved Solids
311
mg/L
1,470
25
Vanadium
209
µg/L
5.32
0.114
Zinc
213
µg/L
1 11
4
Prepared by: RSB Checked by: KCO
Notes:
Analytical data presented in this table reflect the Duke Energy Biological Analytical Data Storage System as of 11/18/2022.
Sample collected by SynTerra and Duke personnel on September 26, 2022.
1- Comparative criteria are not applied to leachate collection samples.
2 - The WQMP identifies the leachate collection sample as L-1. Identification was revised in the field during sampling collection.
< - Concentration not detected at or greater than the adjusted reporting limit.
B - Target analyte detected in method blank at or above the reporting limit. Target analyte concentration in sample is less than 10X the concentration in the
method blank. Analyte concentration in sample could be due to blank contamination.
°C - degrees Celsius
µg/L - micrograms per liter
µmhos/cm - micromhos per centimeter
1 - Estimated concentrations equal to or greater than the MDL but less than the laboratory's method reporting limit (MRL).
MDL - Laboratory Method Detection Limit; MDL values presented are for samples not diluted by the laboratory during analysis.
mg N/L- milligrams nitrogen per liter
mg/L - milligrams per liter
my - millivolts
NTU - Nephelometric turbidity unit
S.U. - standard units
SWS ID - Solid Waste Section Identification Number
WQMP - Water Quality Monitoring Plan
Page 1 of 1

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant— CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
APPENDIX A
FIELD SAMPLING FORMS
L7
synTerra
Science & Engineering Consultants

CAMA 4_CCR `Landfill �NPDES F—j DGW❑ASW ❑LRB SPECIAL STUDY
FIELD SAMPLING LOG % DUKE
le ENERGI
Site: Well/SW ID• — Date:�-
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: WEATHER: I )SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAI SNO AIR TEMP:a �°F
COMPANY: DUKE ENERGY T FIELD METER TYPE/ SERIAL M
Liq
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #:
START PURGE TIME: S SAMPLE COLLECTION TIME: '. (
PUMPITUBING INTAKE D%TH: 00 DEPTH TO WATER: . (tt) MULT FACTOR *: 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETq `V (in) HEIGHT OF WC: (ft) WELL VOLUME: (gap
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
°
(Psi) I (sec) I (sec)
Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
Specific Conductance t 5% In pS/cm
DO f 0.2 mgiL
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
U
(mmin)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
(syO
t b
0-0
K
b
0-
a -�
2�
-a
a
i
a. S
a
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES �NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? KIYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? K]YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 — (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH one Minor Strong
ADDITIONAL NOTES: APPEARANCE lea, Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOQ
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

CAMA CCR ! Landfill NPDES �' DGWI ASW LRB ll SPECIAL STUDY,
;ita• Well/SW ID:
/,,, DUKE
C ' ENERG'
Date:
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
LEVEL
RATE
REMOVED
VC)
(mg/L)
(PS/cm)
(Su)
(mv)
(NTU)
(FT)
(x_xx1
(mUmin)
(x)
(gallons OR ML)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

CAMA CCR! �Landfill NPDES DGW❑ASW ELRB SPECIAL STUDY.
FIELD SAMPLING LOG % DUKE
Ir ENERGY
Site:Well/SW ID: C g - I got. Date:
GROUNDWATER SAMPLE "SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: WEATHER: SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ SN RAIN OW AIR TEMP:��°F
COMPANY: DU ENERGY FIELD METER TYPE/ SERIAL #:
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 3
START PURGE TIME: 41,6 SAMPLE COLLECTION TIME: !
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: MULT FACTOR *: 0.163 [*(radius/12)2.3.14`7.48]
WELL DIAMETER: U (in) HEIGHT OF WC:� (ft) WELL VOLUME: I)
WELL DEPTH: (ft) TOTAL VOLUME PURGED. h
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
(Psi) I (se°: I (Sec) I Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
• Specific Conductance t 5% in pS/cm
DO t 0.2 mg/L
• Turbidity less than 1n NTI Is
®®
., •-
®(ww
(x.xx)
0,01
49
mom
OF M,
rL-r-marmarr-rt i u I Mr mAL n up- I Ml5 JMtt I It I Mt GMAK I ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES N NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE ES NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUP ICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
—••
DETECTED ODOR one 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH NUA Minor Strong
ADDITIONAL NOTES: APPEARANCE le Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

CAMA J CCR Landfill NPDES 7 DGW� ! ASW LRB SPECIAL STUDY.
"itp.
Well/SW ID: Date:
(�. DUKE
" ENERG'
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
PH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mUmin)
(gallons OR mL)
(°C)
(mglL)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
W
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA NCCRLjAl Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑SPECIAL STUDY
FIELD SAMPLING LOG
4 1 , DUKE
�C'' ENERGY
Site: Aaa�'k`� Well/SW ID: C gzl,-0j Si_ Date: I' Qqf - I z
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF:
COMPANY: DU ENERGY
❑ OTHER:
WEATHER:
SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST []RAIN ❑SNOW AIR TEMP-]_S-_-F
FIELD METER TYPE/ SERIAL M M6 f1 7_ U
TURBIDIMETER TYPE/ SERIAL M
START PURGE TIME: S SAMPLE COLLECTION TIME: t Yll,
PUMP/TUBING INTAKE DEPTH: 0(ft) DEPTH TO WATER: - G (ft) MULT FACTOR ": 0.163 ["(radius/12)2'3.14'7.48[
WELL DIAMETER: Q .(3 (in) HEIGHT OF WC: a `-A)a (ft) WELL VOLUME: y"C2 a (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: 0 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
\
SAMPLING METHOD:
PUMP SETTING:
R
R
D
(psi) (sec) (sec)
Low Flow Sampling Stabilization Criteria
pH f 0.1 standard unit
Specific Conductance f 5% in pS/cm
DO f 0.2 mg/L
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
(IC)
(x)
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
15
l(
0�o:?-
0
5. ►
y
(.0.01
ti
q- 10
0 I�.,
i
.(A
. s
Gro,
1,Jk--
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? []YES NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES?NYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? YES ❑ NO DUPLICATE 1 _— (NTU) DUPLIC4IE - (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR on 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH o Minor Strong
ADDITIONAL NOTES: APPEARANCE le Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

ECAMA FjCCRFjLandfiill F�NPDES❑DGW❑ASW 7LRBF-] SPECIAL STUDY
Site:
Well/SW ID:
Date:
,tom DUKE
�' ENERGY
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mL/min)
I
(gallons OR mL)
VC)
(mg/L)
I
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
W
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
W
Version 1.0 Revised 12/17/2018 RDP

ECAMA F-]CCR�iLandfill [—]NPDES [—]DGWF—]ASW F—]LRB[—] SPECIAL STUDY
Site: AcJvml�-
FIELD SAMPLING LOG
Well/SW ID: bP-q
Date: 9 Z6-ZZ
DUKE
ENERGY
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE[:] LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: Ci!2-
COMPANY: ❑/ DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑ PARTLY CLOUDY []OVERCAST []RAIN []SNOW AIR TEMP: *F
FIELD METER TYPE/ SERIAL M 763511f
TURBIDIMETER TYPE/ SERIAL M 3 51M
START PURGE TIME: 1215 SAMPLE COLLECTION TIME:
PUMPITUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR *: 0.163 [*(radius/12)2*3.14*7.481
WELL DIAMETER: (in) HEIGHT OF WC: — (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( J.RA )
PURGE METHOD:
SAMPLING METHOD:
i
PUMP SETTING:
P
R
D
(psi) (sec) (sec)
4? MY , no woLtv flow
Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
Specific Conductance t 5% In pS/cm
DO t 0.2 mg/L
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(IC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? []YES []NO
IS A TURBIDITY METER DUPLICATE REQUIRED? [—]YES[ I NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑i YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

E]CAMA [—]CCRF]Landfill F]NPDES U DGWF]ASW 7]LRB ❑ SPECIAL STUDY,
Site:
Well/SW ID: Date:
�•� DUKE
' ENERGY
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
TIME
LEVEL
RATE
REMOVED
CONDUCTANCE
(FT)
(mL/min)
(gallons OR mL)
(°C)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

7CAMA 7CCR 7Landfiill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING LOG
RM
Site: A"ot&- Well/SW ID: LGS-( Date: 916-U-
GROUNDWATER SAMPLE [:]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE D WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 67L
COMPANY Q DUKE ENERGY
❑ OTHER:
WEATHER: •QSUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN []SNOW AIR TEMP:ZZ 'F
FIELD METER TYPE/ SERIAL #: 70$"71C
TURBIDIMETER TYPE/ SERIAL M 3379'
START PURGE TIME: 12t)5 SAMPLE COLLECTION TIME: IZ t O
PUMPITUBING INTAKE DEPTH: — (ft) DEPTH TO WATER: (ft) MULT FACTOR*: 0.163 [*(radius/12)2.3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: r (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
F
R
°
(Pso I (see) I (sec) Low How Sampling Stabilization Criteria
• PH f 0.1 standard unit
• Specific Conductance t 5% in NS/cm
• DO f 0.2 mg/1
Twhirlihr ices fl- An urTrr.,
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
PH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR nnL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x )
l ?,ifs
-
500 -t
N 0.50
21
7 ► 2
1509
•65
Kul
N. a
ri-mmoc rccrr=r% i v i mr 6At m Vt' I Nis snit I It- I tit CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? AYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑AYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR t2p, 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH &—e Minor Strong
ADDITIONAL NOTES: APPEARANCE tv12 Cloudy Turbid Red/Iron Film on Surface Sheen FrnA Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

[—]CAMA [—]CCR❑Landfill F—]NPDES ❑ DGWF]ASW FLRB ❑ SPECIAL STUDY
Site: Well/SW ID:
Date:
e
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA ❑CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: As6v-k
FIELD SAMPLING LOG
Well/SW ID: LF-5W-
PDUKE
ENERGY
Date: 4-a-2z
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO WELL DEVELOPMENT
FIELD STAFF: C!'� WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST [—]RAIN ❑SNOW AIR TEMP: °F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL #: 705V
❑ OTHER: TURBI DIMETER TYPE/ SERIAL M 331,ci
START PURGE TIME: 1100 SAMPLE COLLECTION TIME: •—
PUMP/TUBING INTAKE DEPTH: (ft) DEPTH TO WATER: (ft) MULT FACTOR *: 0.163 [`(radius/12)2*3.14*7.48]
WELL DIAMETER: (in) HEIGHT OF WC: (ft) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( &IZ46 )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
o
(Peo (sec) (sec) Low Flow Sampling Stabilization Criteria
• pH t 0.1 standard unit
TRY , no Sqmf(c t "44 Specific Conductance t 5% In NS/cm
• DO t 0.2 mg/t
• Turbidltv less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(Sul
(x.xx)
(mv)
W
(NTU)
(x.x)
I'LEASt Ktt-tK I U I HE 13AUK OF THI5 5HEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[:] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES [:]NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑ YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑YES F,� NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR None 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH None Minor Strong
ADDITIONAL NOTES: APPEARANCE Clear Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

DCAMA F—]CCR ❑Landfill F—]NPDES DGW[—] ASWFILRB ❑ SPECIAL STUDY
Site:
Well/SW ID:
Date:
,.I � DUKE
�'' ENERGY
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA ❑CCR gLandfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
FIELD SAMPLING LOG
Site: /lstuvt& Well/SW ID: L.F-Sw-Z Date: 9-74-z,L
❑i GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 0 7- WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN [:jSNOW AIR TEMP: °F
COMPANY: ❑ DUKE ENERGY FIELD METER TYPE/ SERIAL #: 7I SS %f
❑ OTHER: TURBIDIMETER TYPE/ SERIAL#: 33211
START PURGE TIME: Yl /� SAMPLE COLLECTION TIME: It is
PUMP/TUBING INTAKE DEPTH: (ft)' DEPTH TO WATER: (h) MULT FACTOR *: 0.163 [`(radius/12)2*3.14'7.48j
WELL DIAMETER: (in) HEIGHT OF WC: _ (h) WELL VOLUME: (gal)
WELL DEPTH: (ft) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( 6,R40 )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
P
R
D
(Psi) I (Sec) I (Sec) I LOW rlow Sampling Stabilization Criteria
pH t 0.1 standard unit
• Specific Conductance t 5% in pS/cm
• DO t 0.2 mg/1
• Turbidity less than in MT1 Ic
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(nnUmin)
(x)
(gallons OR nnL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/CM)
(x)
(Su)
(x.xx)
(mV)
W
(NTU)
(x.x)
Itt3
--
5*6 nn fkIA1—
$,`lq
g$
9.01
YKS
6•5
rLtHat Ktrt=K I U I Ht bAL;K Ut I HIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES ❑ NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑YES [:]NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ❑YES ® NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 _ (NTU) DUPLICATE 2 (NTU'
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR a 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH 12rMinor Strong
ADDITIONAL NOTES: APPEARANCE &ar Cloudy Turbid Red/Iron Film on Surface Sheen 9' 00
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE P/
GOOD
BAD
NONE
GOOD
BAD
NONE
GOODI
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
i
Version 1.0 Revised 1>1 1) .:zt t1F

nCAMA nCCRnLandfill nNPDES [-] DGW❑ASW F-]LRB ❑SPECIAL STUDY.
Site:
V ot DU KE
ENERGY
Well/SW ID: Date:
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
N
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA F-]CCR Landfill ❑NPDES ❑ DGW❑ASW F-]LRB ❑ SPECIAL STUDY.
FIELD SAMPLING LOG
Site: A *4 Well/SW ID: s$ LF 5tv-3 Date:
❑GROUNDWATER SAMPLE [—]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G77 WEATHER: ❑SUNNY El PARTLY CLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIR TEMP: °F
COMPANY: ❑i DUKE ENERGY FIELD METER TYPE/ SERIAL #: ?6NA,
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 13A
START PURGE TIME: 1325 SAMPLE COLLECTION TIME: 13,70
PUMPITUBING INTAKE DEPTH: — (tt) DEPTH TO WATER: r' (ft) MULT FACTOR *• 0.163 ['(radius/12)2'3,14'7.481
WELL DIAMETER: — (in) HEIGHT OF WC: — (n) WELL VOLUME: — (gal)
WELL DEPTH: (tt) TOTAL VOLUME PURGED: (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
y
SAMPLING METHOD:
PUMP SETTING:
P
R
6948
(PSD I (sec) I (sec) I Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
Specific Conductance t 5% in pS/cm
• DO t 0.2 mg/€
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
t32g
—
gfnccm
w --t
1 a
3,13
5 9
7. 6 b
3?lf
7
VLtwst KtFtK I U I HE IJAGK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? [:]YES[:] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? A YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES ❑ NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? DYES 2 NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE Fe
r Cloudy Turbid Red/Iron Film on Surface Sheen /r s Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

F-]CAMA 7CCR Landfill F-]NPDES 7 DGW❑ASW F�LRB ❑ SPECIAL STUDY.
Site: Well/SW ID:
Date:
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(us/cm)
(x)
(su)
(x.xx)
(mv)
N
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA [--]CCRLandfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: 464wlll
FIELD SAMPLING LOG
Well/SW ID: LMW- )Q
Date: 9 28-vL
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G)2
COMPANY: M DUKE ENERGY
❑ OTHER:
WEATHER: ❑SUNNY OPARTLYCLOUDY ❑OVERCAST DRAIN ❑SNOW AIRTEMP:73 °F
FIELD METER TYPE/ SERIAL M 763374
TURBIDIMETER TYPE/ SERIAL #: 33"
START PURGE TIME: (52.7 SAMPLE COLLECTION TIME: (50
PUMP/TUBING INTAKE DEPTH: q$ (h) DEPTH TO WATER: 2>•03 (n) MULT FACTOR *• 0.163 ["(radius/12)2'3.14"7.48]
WELL DIAMETER: 2•0 (in) HEIGHT OF WC: 8&, l'i (ft) WELL VOLUME: 1..07 (gal)
WELL DEPTH: (05.71 (ft) TOTAL VOLUME PURGED: a• 1V (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
(psi) I (Se.) I (S.C) I Low 1-low Sampling Stabilization Criteria
pH t 0.1 standard unit
• Specific Conductance f 5% In pS/cm
• DO t 0.2 mg/I
• Turbidity less than 9n NTlts
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(nnUmin)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
(550
2 .Iy
750
0.30
Z7
1,
11
6.0r.
3Y2.
22.a
(533
21.16
2So
v,s5
o.3K
R°I
&(Z
719I'•5
)S36
23.(4
G.?
Z">
2
(01
`.rK
2ty
&�
1�3°i
Z3�(6
2110
0,1S
I.Ct
6.21
sK
G•c�
Z7'j
�.r
rLMAZ& KtttK I I tit bAGK OF I HIb SHEE T IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? []YES Q NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ElYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES Q NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ©YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR o 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH ne Minor Strong
ADDITIONAL NOTES: APPEARANCE ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

[-]CAMA FCCR❑Landfill FNPDES ❑ DGW❑ASW FLRB ❑ SPECIAL STUDY
Site:
Well/SW ID:
Date:
b
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
FT
( )
(mUmin)
(gallons OR mL)
C
(° )
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.xx)
(x)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA ❑CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
Site: &gA
FIELD SAMPLING LOG
Well/SW ID: LM,W- I S
Date: 9-7d-�2
��•� DUKE
�' ENERGY
GROUNDWATER SAMPLE [—]SURFACE WATER SAMPLE ❑LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: 6%. WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST DRAIN SNOW AIRTEMP: °F
COMPANY: ❑/ DUKE ENERGY FIELD METER TYPE/ SERIAL M 76 I-7y
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M -n2l
START PURGE TIME: SAMPLE COLLECTION TIME: IS1S
PUMPITUBING INTAKE DEPTH: 615 (ft) DEPTH TO WATER: 2643 (ft) MULT FACTOR *: 0.163 C(radius/12)2.3.14.7.48I
WELL DIAMETER: / Zo (in) HEIGHT OF WC: No. 37 (ft) WELL VOLUME: G •58 (gal)
WELL DEPTH: t;. & (ft) TOTAL VOLUME PURGED: /• S' (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
/
PUMP SETTING:
P
R
p
Ps;) 5eC SeG Low Flow Sampling Stabilization Criteria
pH f 0.1 standard unit
Specific Conductance f 5% in pS/cm
• DO t 0.2 mg/L
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
FT ( )
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/CM)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
IhoZ
A..-N
300
a •2S
Z►
3. q N
5'6
L • U
39 2
t 7 'L
4%5
21G1 IS 15
3uD
o. SS
l 5
2.71
57
9•c,'7
1 Y
(Z I
ISOV
?U.65
300
Olen
(g
p (G
6 (
5"t$
V 16
G.
6I(
19-'K
I3rN
I, to
11S
-zoo/
5.14
%0Z
L•o
ISIh74.65
I.KS
[£s
2.ty
L2
S.dJy
Y11
tl3
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES [;� NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ©YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES F_� NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 _ (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR 13),e 1­12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH � e Minor Strong
ADDITIONAL NOTES: APPEARANCE ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

DCAMA F-] CCR F] Landfill FNPDES ❑ DGW❑ASW F]LRB ❑ SPECIAL STUDY.
Site:
Well/SW ID:
(•.. DUKE
V " ENERGY
Date:
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mUmin)
W
(gallons OR mL)
(x.xx)
CC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA [--]CCR ❑Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY
Site: 1751UIAA
FIELD SAMPLING LOG
Well/SW ID: L^1-26
•t� DUKE
� ENERGY
Date: 1-74-ZZ
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF:
COMPANY: ❑ DUKE ENERGY
❑ OTHER:
WEATHER: []SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN SNOW AIRTEMP: *F
FIELD METER TYPE/ SERIAL #: ?
TURBIDIMETER TYPE/ SERIAL #: 33?l
START PURGE TIME: I T % SAMPLE COLLECTION TIME: los
PUMP/TUBING INTAKE DEPTH: SUS (ft) DEPTH TO WATER: A 7? (ft) MULT FACTOR ": 0.163 [*(radius/12)2*3.14*7.48]
WELL DIAMETER: ' (in) HEIGHT OF WC: Y5,53 (ft) WELL VOLUME: 7.48 (gal)
WELL DEPTH: TOTAL VOLUME PURGED: 155 (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other( )
PURGE METHOD:
SAMPLING METHOD:
/
PUMP SETTING:
P
R
o
cP�i) (sec) (Sec) Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
Specific Conductance f 5% in pS/cm
• DO f 0.2 mg/L
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mV)
(x)
(NTU)
(x.x)
Mw
65.12
300
0.10
1,6
5•54
15
6•b6)
3sl•
Y.
140
65.7,0
3w
0.63
22
3.5D
62.
6.156
300
K.0
I 'b6
f, 5.4V
300
O A
2,01
6,. $ I
Z-86
5.1
ijjA
641W
I 3D
1.25
11
1.6A
27
-Fs
Wit
6 ,9
3,0
1.55
t-1
1.012
A°►
b9,61
y.o
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE 15 FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES j NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? ❑A YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES [ZNO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? ®YES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR o 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE r Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

F—]CAMA F—]CCR❑Landfill F—]NPDES ❑ DGWF—]ASW [—]LRB ❑ SPECIAL STUDY
Site: Well/SW ID:
Date:
.(� DUKE
�' ENERGY
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mUmin)
W
(gallons OR mL)
(x.xx)
(°C)
W
(mg/L)
(x.xx)
(PS/cm)
W
(Su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑CAMA F-1CCR Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY.
Site: 4S�ttA,
FIELD SAMPLING LOG
Well/SW ID: GMV-2T
.J� DUKE
� ENERGY
Date: '1- 26-7Z
10 GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO [:]WELL DEVELOPMENT
FIELD STAFF: t! 71- WEATHER: [:]SUNNY❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN SNOW AIR TEMP: °F
COMPANY: © DUKE ENERGY FIELD METER TYPE/ SERIAL #: %6 A
❑ OTHER: TURBIDIMETER TYPE/ SERIAL #: 337A
START PURGE TIME: 1343 SAMPLE COLLECTION TIME:
PUMP/TUBING INTAKE DEPTH: 66 (ft) DEPTH TO WATER: h'r � (ft) MULT FACTOR *: 0.163 [•(radius/12)2.3.14.7.48j
WELL DIAMETER: 7.0 (in) HEIGHT OF WC: ZN•Z (ft) WELL VOLUME: 3.g K (gal)
WELL DEPTH: 810 (ft) TOTAL VOLUME PURGED: 0.3; (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
'
SAMPLING METHOD:
PUMP SETTING:
P
RI
11
(psi) (sec) (sec)
Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
Specific Conductance t 5% in pS/cm
DO f 0.2 mg/L
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
W
(gallons OR mL)
(x.xx)
(IC)
W
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
13K6
5.ti'L
/so
0. w
Zo
7A o
5,7
Z LIS
3t
Fs.'Z
13K11
GS• o
I 110
t all
5.11
ao
7 2$
7 p 7S.S
tI52
.3 k
160
0. 6D
l q
4.16
61
7.0q
368
'4 K
( SS
b5.3k
l %D
0.
lot
14,04
1 6S
7.oK
3,99
it,
1356
65-$t
Ito
0.1gs
19
1
7-OZ
*3qt
It
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES 0 NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? DYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES 0 NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? QYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 _ (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR N e H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH a Minor Strong
ADDITIONAL NOTES: APPEARANCE ar Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

[—] CAMAF—]CCRF—]Landfill F7NPDES ❑ DGWF—]ASW [—]LRB ❑ SPECIAL STUDY.
Site:
Well/SW ID:
Date:
��� DUKE
�' ENERGI
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
TIME
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
W
(NTU)
(x.x)
Version 1.0 Revised 12/17/2018 RDP

❑LAMA �CCRFj Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
FIELD SAMPLING LOG
Site: 11S�wl t Well/SW ID: tMkJ-30
MM
Date: 9-9-n
❑i GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF`: 6-It
COMPANY: ❑i DUKE ENERGY
❑ OTHER:
WEATHER: SUNNY ❑PARTLYCLOUDY ❑OVERCAST ❑RAIN ❑SNOW AIR TEMP: ?S °F
FIELD METER TYPE/ SERIAL M Mik
TURBIDIMETER TYPE/ SERIAL M M-91
START PURGE TIME: iZ N2 SAMPLE COLLECTION TIME: 1100
PUMPITUBING INTAKE DEPTH: DEPTH TO WATER: *33.63 (ft) MULT FACTOR *• 0:163 [*(radius/12)2"3.14*7,48]
WELL DIAMETER: ZO (in) HEIGHT OF WC: 11.67 (ft) WELL VOLUME: /•90, (gal)
WELL DEPTH: K5.30 If) TOTAL VOLUME PURGED: 0-ST (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
SAMPLING METHOD:
PUMP SETTING:
F
ft
D
(psi (see) (se D) Low Flow Sampling Stabilization Criteria
pH t 0.1 standard unit
• Specific Conductance t 5% In pS/cm
• DO f 0.2 mg/1
• Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mL/min)
W
(gallons OR mL)
(x.xx)
VC)
(x)
(mg/L)
(x.xx)
(NS/cm)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
1
31.0tD
lso
0-to
I
qu
K14
.cg
21q
8.0
It"
33.011
l bo
0,15
IL
2,64
1.11t7
7.07
6.2
ttiSt
3.ct°d
tfso
o,
lb
-3�
N60
1v
�,o
?.v
125
33•01$
I W
p, 7D
16
1.3
"71
88
331
218
t25'1
3
1�
Ike
1,
7
Sb
3
PLEASE REFER TO THE BACK OF THIS SHEET IF THE CHART ABOVE IS FULL
IS REDEVELOPMENTNEEDED (>10 NTUS)? ❑ YES [�] NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? EYES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES [�] NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? EYES ❑ NO
IS THE TURBIDITY METER DUPLICATE TAKEN, WITHIN 15%? ❑ YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE (NTU)
FINAL SAMPLE OBSERVATIONS: ��-,
DETECTED ODOR . 1-12S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES`: APPEARANCE I a r Cloudy Turbid Red/Iron Film on Surface Sheen Fines Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
w
i
Version 1,0 Revised 12/1712018 RDP

[—]CAMA 7CCR7Landfill 7NPDES ❑ DGW❑ASW FLRB ❑ SPECIAL STUDY,
Site:
Well/SW ID:
V ,ot DUKE
„R.
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(mUmin)
(x)
(gallons OR mL)
(x.xx)
(°C)
(x)
(mg/L)
(x.xx)
(PS/cm)
(x)
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
Version 1.0 Revised 12/17/201'8 RDP

❑CAMA F,-]CCR7Landfiill [:]NPDES 7DGW7ASW ❑LRB❑ SPECIAL STUDY.
FIELD SAMPLING LOG
Site: AsWle Well/SW ID: LA4W`g8
Date: ? ZZ-7 Z
GROUNDWATER SAMPLE ❑SURFACE WATER SAMPLE ❑ LEACHATE SAMPLE ❑ WLO ❑ WELL DEVELOPMENT
FIELD STAFF: G%L WEATHER: /❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW AIR TEMP: 67 -F
COMPANY: [7] DUKE ENERGY FIELD METER TYPE/ SERIAL M 7435z1
❑ OTHER: TURBIDIMETER TYPE/ SERIAL M 73ut
START PURGE TIME: (l2Z SAMPLE COLLECTION TIME: 11$3
PUMP/TUBING INTAKE DEPTH: q4 (ft) DEPTH TO WATER: Z2IS0 (ft) MULT FACTOR ": 0.163 ['(radius/12)2'3.14'7.48]
WELL DIAMETER: Z.o (in) HEIGHT OF WC: Z6•N5 (ft) WELL VOLUME: y 31 (gal)
WELL DEPTH: Kq.15 (ft) TOTAL VOLUME PURGED: Z. rS (gal)
TYPE OF PUMP:
Bladder
Peristaltic
12 Volt
Grundfos
Other ( )
PURGE METHOD:
I
SAMPLING METHOD:
PUMP SETTING:
P
R
o
(Ps) (Sec) (sec)
Aft+ oA
Low Flow Sampling Stabilization Criteria
pH f 0.1 standard unit
Specific Conductance f 5% in pS/cm
DO t 0.2mg11
Turbidity less than 10 NTUs
TIME
WATER
LEVEL
FLOW
RATE
VOLUME
REMOVED
TEMPERATURE
DO
SPECIFIC
CONDUCTANCE
pH
ORP
TURBIDITY
(FT)
(x.xx)
(nnL/min)
W
(gallons OR mL)
(x.xx)
VC)
W
(mg/L)
(x.xx)
(PS/cm)
W
(su)
(x.xx)
(mv)
(x)
(NTU)
(x.x)
1126
23.11
3V
0.0
$
2.00
430
6-11H
31Z
Z011.
1124
z .tZ
300 ►KW
0'61/
16
0.65
3111
6. 38
Z140
188
(tL o
ZI 6
50
1.05
15
0.38
3ti
. ?
3VI
tk'ls
24.v1
1150
1AS
ts
0, ?
`1b
4.21z
Z0.1
!K.►
1(4%
24.01
3SP
1.to
1s
OILS
3915
6.19
206
12.q
I(S(
21wt
SO
2.1 S
1
o,2N
q
6<I %
2
7,7
PLEASE REFER TO THE BACK OF THIS SHEET 1F THE CHART ABOVE IS FULL
IS REDEVELOPMENT NEEDED (>10 NTUS)? ❑ YES Q NO WERE ALL SAMPLES ON ICE WITHIN 15 MINUTES? © YES ❑ NO
IS A TURBIDITY METER DUPLICATE REQUIRED? ❑YES L�NO IS THE LOCATION FIELD VEHICLE ACCESSIBLE? [`EYES ❑ NO
IS THE TURBIDITY METER DUPLICATE' TAKEN, WITHIN 15%? ❑YES ❑ NO DUPLICATE 1 (NTU) DUPLICATE 2 (NTU)
FINAL SAMPLE OBSERVATIONS:
DETECTED ODOR T'-'
H2S Petroleum Earthy Musty Undetermined
ODOR STRENGTH Minor Strong
ADDITIONAL NOTES: APPEARANCE Cloudy Turbid Red/Iron Film on Surface Sheen ngs Floc
WELL TAG
PROTECTIVE CASING
LOCK
DUST CAP
CONCRETE PAD
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
GOOD
BAD
NONE
Version 1.0 Revised 12/17/2018 RDP

F-]CAMA F-]CCR❑Landfill F-]NPDES ❑ DGWFJASW ❑LRB ❑ SPECIAL STUDY,
Site:
Well/SW ID:
Date:
s
WATER
FLOW
VOLUME
TEMPERATURE
DO
SPECIFIC
pH
ORP
TURBIDITY
LEVEL
RATE
REMOVED
CONDUCTANCE
TIME
(FT)
(mUmin)
(gallons OR mL)
VC)
(mg/L)
(PS/cm)
(su)
(mv)
(NTU)
(x.xx)
(x)
(x.xx)
W
(x.xx)
(x)
(x.xx)
(x)
(x:x)
Version 1.0 Revised 12/17/2018 RDP

❑LAMA ❑CCR❑j Landfill ❑NPDES ❑ DGW❑ASW ❑LRB ❑ SPECIAL STUDY,
DAILY CALIBRATION LOG
Site: ASV Date:
R-Z6-�L
DUKE
ENER
FIELD PERSONNEL: G31
WEATHER: ❑SUNNY ❑ PARTLY CLOUDY ❑ OVERCAST ❑ RAIN ❑SNOW TEMPERATURE (APPROX):
INSITU SERIAL M 763574 F
21000 SERIAL #: 3311
pH
Time: 1�3o
Lot Number
Expiration
p
Buffer
Temperature
p
(°C)
Chart
pH
(Su)
Meter
.Reading
(su)
Within ±
0.1 su?
7.00 su
Zt;oZ311
oq-30-Z L
Zuti 50
7.02
7,08
(n� N
10.01 su
260230
o3.31—Z3
Za.S`t
(o,06
IQ/o
N
4.01 su
260263
04.10-23
Zo•Iq
ttco
K-02
N
Check of 7.00 su as Live Reading
260231I
oq-3o-2Z I
&/• Sb
710Z
7,0?
N
Post Calibration- Date: Time: i015
Within
0.2 SO
7.00 su
26623�1
pq-3o-2Z
16-o2
7.65
7.07
J N
10.01 su
11
(6•03
(0.12
10.1(
( N
4.01 su
260263
66.30-Z3
16.0&
3,q 1
14.01-
N
Specific Conductivitv
Time: 1o35
Lot Number =
Expiration
Buffer
Temperature (°C)
Meter
Reading (ps)
Within ±
10%°?
Standard Value: 1 to ps
If -to
I`07•0
N
Calibration Check of
2Z'] Ps as Live Reading
a
18•q
226,K
(J N
Post Calibration- Date: ci-27.22 Time: (a(
I�t�o ps
gt;KogK
r<<<r23
16.22
I�tc t.6
N
ORP
Buffer
Adjusted
Meter
Time: Ins
Lot Number
Expiration
Temperature
Value
Reading
Within ±
20%?
(°C)
(mV)
(mV)
42a my
t 3�8t�-
(g.90
�(Y3
yY3, K
N
Post Calibration- Date: -
Time:
wm mV
g.010
N
Revised 12/18/2018 K

1--]CAMA F�CCR7Landfill nNPDES ❑ DGW❑ASW nLRB ❑ SPECIAL STUDY
DUKE
ENERGY,
DAILY CALIBRATION LOG
Site: Date: 9-24-2-1- Field Personnel: viz
Barometric
Meter
Dissolved Oxygen
Temperature
Pressure
Chart DO
Reading
% Saturation
Within # 0.5?
Time:.
(°C)
(mg/L)
(%Sat)
fo 35
(mmHg)
(mg/L)
1&61
204• 35
6.7
8.71
100,cld C
05 N
Calibration Check as Live
lts.65
7a'4•3c
' •b.7
' &'71
ivr,oz�
�Y N
Reading
e
Post Calibration -
Date: �%-Z?
Ib•66
7o3. li .
S-C(i
N
Time: fy Zy
Turbidity
Time: fDYU
Standard (NTU)
Acceptance_
Range,(NTU) .
Meter Reading
(NTU)
Within +
5%?
10.0
± .5
+U-o
(y N
Post Calibration -
Date: 01-27
N
Time: 10,0
Daily Turbidity Meter BLANK
DI Water (NTU)
Less than 0.10 NTU?
Date: q-26•Z2
N
0',
(VtO
Time:
Revised 12/18/2018 KKH

Semiannual Water Quality Monitoring Report — September 2022 Sampling Event
Asheville Steam Electric Plant — CCR Landfill (Permit No. 1119-INDUS-2020)
Arden, North Carolina
r
APPENDIX B
LABORATORY REPORT AND
CHAIN -OF -CUSTODY FORMS
1610
synTerra
Science & Engineering Consultants

Analytical Data Review Checklist - Aqueous
Facility/Site
Asheville Steam Electric Plant
State
INC
Location/Sample IDs
CB-9, CB-91311, CB-9SL, LCS-1, LF-SW-2, LF-SW-3, LMW-1B, LMW-1S, LMW-213, LMW-2T,
LMW-3B, LMW-4B
References:
- ELN/A
❑v 1 ❑
Duke Central Lab, Pace Analytical Services
Lab Report ID Sample Date Sample Receipt Date Analysis Complete Date ❑ Groundwater
/22090472 9/26/2022 9/27/2022 10/12/2022 ❑ Surface Water
❑ Other
National Functional Guidelines for Inorganic Superfund Methods Data Review (USEPA 2020)
Guidance on Environmental Data Verification and Data Validation (USEPA 2002)
Radiochemical Data Verification and Validation (MARLAP 2004)
� Sample Receipt and Chain of Custody
1) Do the sample IDs and laboratory analyses recorded on the Chain of Custody match the sample IDs and analyses listed in the laboratory package?
❑�
❑
❑
la) Do the dates and times of sampling listed on the Chain of Custody match the laboratory report?
0
❑
❑
❑
❑
❑�
2) Is the sample temperature upon receipt at the laboratory recorded on the Chain of Custody form less than 6 degrees Celsius? If NO, then:
2a) Was the presence of wet ice noted in the cooler? OR
❑
❑
❑�
2b) Were the samples collected less than two hours prior to receipt at the lab?
❑�
❑
❑
3) Was the proper sample preservation checked and documented on the Chain of Custody or sample receipt form?
❑
❑�
❑
4) Are there any special notes, exceptions, and/or anomalies listed either on the Chain of Custody or sample receipt form?
❑
❑v
❑
15) Was the transfer of custody of the samples properly documented and traceable through signature, date, and time by all persons who relinquished and/or received
custody of the samples?
❑
7❑�❑
❑ ❑�
®®Batch
6) Do the values for the field parameters listed on the Chain of Custody match the values entered in the lab report?
eAssurance/Quality
7) Was the holding time for preparation and/or analysis met for each parameter?
❑
❑�
7a) Total Alkalinity, Bicarbonate Alkalinity, Carbonate Alkalinity: Analyzed within 14 days of collection
❑
❑
7b) Bromide, Chloride, Fluoride, and Sulfate (Anions): Analyzed within 28 days of collection
❑
❑
l]
7c) Sulfide: Analyzed within 7 days of collection
0
❑
❑
7d) TOC and Nitrate -Nitrite: Analyzed within 28 days of collection
❑
❑
l]
7e) Total Phosphorus (TP) and Dissolved TP: Analyzed within 28 days of collection
❑
❑
(]
7f) Hexavalent Chromium: Analyzed Within 24 hours (unpreserved) / 28 days (preserved) of collection
0
❑
❑
7g) Mercury and Dissolved Mercury: Analyzed within 28 days of collection (preserved)
0
❑
❑
7h) Total and Dissolved Metals: Analyzed within 180 days of collection
0
❑
71) TSS and TDS: Analyzed within 7 days of collection
❑
❑
0
7J) Radionuclides: Analyzed within 180 days of collection
❑
❑
❑
❑
I]
0
7k) Methane: Analyzed within 14 days (preserved) / 7 days (unpreserved) of collection
71) Oil and Grease: Analyzed within 28 days of collection
❑�
❑
❑
8) Are there any qualifiers assigned by the laboratory and if so, are the qualifier definitions provided?
❑�
❑
9) Method Blank- Were any parameters detected in the method blank(s)?
❑�
❑
9a) If YES, were any target analyses detected in the samples at concentrations less than ten times the method blank concentration?
❑
❑
❑�
❑
❑
)]
10) Laboratory Control Sample - Were any parameters flagged by the lab as being outside the limits of control in the associated laboratory control sample (LCS)?
1 Do) If YES, was the parameter recovery less than 50 percent or greater than 150 percent?
❑
❑
2
10b) Were the some parameters detected in the samples?
❑�
❑
❑
11) Matrix Spike Sample - Did the laboratory provide matrix spike results (MS/MSD)? If so, then:
❑�
❑
❑
111a) Was the original sample spiked a project sample? If so, then:
❑
❑�
❑
11 b) Were any parameters flagged by the lab as being outside the limits of control in the associated matrix spike sample?

Batch
70!Assurance/Quality
0 ❑ ❑ 12) Laboratory Duplicate Sample - Did the laboratory provide lab duplicate sample results? If so, then:
❑ ❑ 12a) Was the sample analyzed as a laboratory duplicate a project sample? If so, then:
❑ 0 ❑ 12b) Were any parameters flagged by the lab as being outside the limits of control in the laboratory duplicate sample?
0 ❑ ❑ 13) Field Duplicate Sample - Is the relative percent difference between the parent and field duplicate sample results greater than 35 percent?
0 ❑ ❑ 14) Field/Equipment/Trip Blanks - Were any parameters detected in the associated field, equipment, and/or trip blanks?
0 ❑ ❑ 14a) If yes, were any target analytes detected in the samples at a concentration less than ten times the Field/Equipment/T(p Blank concentration?
❑v
❑ ❑ 15) Were initial and continuing calibration blank information within acceptable criteria per the lab report?
❑
❑� ❑ 16) Were any reporting limits for diluted, non -detect results greater than the screening criteria?
❑ ❑ 17) Radionuclides: Are quality control sample results provided?
❑ ❑� 17a) Are any results flagged or qualified?
❑ ❑ ❑° 17b) Are Uncertainty, MDC, Tracer/ and/or Carrier7 provided for each sample?
The questions on this checklist refer to basic review of laboratory analytical reports for completeness and accuracy of data. Any responses requiring follow up action with the analytical lab or field personnel must be
noted in the summary section at the end of this form before the data can be approved for use by technical leads.
Lab Qualifiers:
B (Duke) -Target analyte detected in the Method/Prep Blank at or above the reporting limit; target analyte concentration in sample is less than 10x the concentration in the Method/Prep
Blank.
B1(Duke) -Target analyte was detected in Method/Prep Blank at or above the reporting limit; target analyte concentration in sample is below the reporting limit or greater than lox the
concentration of the target analyte detected in the Method/Prep Blank.
J (Duke) -Analyte detected above the MDL, but below the RL; analyte concentration should be considered an estimate.
U (Duke) -Analyte was analyzed for, but not detected above the MDL.
Validation Qualifiers:
R- Result is unusable. The sample result is rejected due to serious deficiencies in meeting quality control criteria; the analyte may or may not be present in the sample.
J - Value is estimated. The result is below the reporting limit or potentially biased based on data validation.
U-Analyte was analyzed form but not detected above the minimum detectable concentration (MDC) or method detection limit (MDL).
B -Target analyte detected in the method blank an in the sample at a concentration less than 10x the blank concentration.
• Mercury (0.024 ug/L) was detected in the Method Blanks; Mercury was also detected in the samples at concentrations less than 10x the blank concentrations.
• Antimony (0.12 ug/L) and Vanadium (0.374 ug/L) (B, B,1) were detected in the Method Blank; Antimony and Vanadium were also detected in the samples at concentrations less than lOx the
blank concentrations.
• The RPD between LMW-413 and the field duplicate is greater than 35% for Nitrate (2.1/0.21 mg/L) and Nitrate as N (0.47/0.05 mg/L).
• Mercury (0.01 ug/L), Iron (0.012 mg/L), and Vanadium (0.18 ug/L) were detected in the Field Blank; Mercury, Iron, and Vanadium were also detected in the samples at concentrations less than
lox the blank concentrations.
Review Determination: ❑ Usable 0 Usable with Required Actions ❑ Unusable
Signatures: Date:
Data Quality Reviewer REB 10/27/2022
Technical Lead KHF 1/11/2023

DUE Analytical Laboratory
ENERGY
Y
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
Order Number: J22090472
Project Name: ASHEVILLE - ASHEVILLE STATE LF DETECTION MONITORING
Task Code: LF
Customer Name(s): Ashley Healy,B Moeller, D Obrien,J Stowe,C Zahora
Customer Address: Asheville Steam Station
200 CP and L Drive
Arden,NC 28704
Lab Contact: Peggy Kendall Phone: [phone]
Report Authorized By: A, &-. mate: 10/12/2022
(Signature)
Peggy Mdall
Program Comments:
QC Note: Iron (0.012 mg/L) was detected in the field blank.
Data Flags & Calculations:
Page 1 of 53
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Page 2 of 53
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2022025315
ASHEVILLE
26-Sep-22
11:15
AM
Connor Zahora
ASV_LF-SW-2
2022025316
ASHEVILLE
26-Sep-22
11:55
AM
Connor Zahora
ASV_LMW-4B
2022025317
ASHEVILLE
26-Sep-22
12:10
PM
Connor Zahora
ASV_LCS-1
2022025318
ASHEVILLE
26-Sep-22
1:00
PM
Connor Zahora
ASV_LMW-3B
2022025319
ASHEVILLE
26-Sep-22
1:30
PM
Connor Zahora
ASV_LF-SW-3
2022025320
ASHEVILLE
26-Sep-22
2:00
PM
Connor Zahora
ASV_LMW-2T
2022025321
ASHEVILLE
26-Sep-22
2:35
PM
Connor Zahora
ASV_LMW-2B
2022025322
ASHEVILLE
26-Sep-22
3:15
PM
Connor Zahora
ASV_LMW-1S
2022025323
ASHEVILLE
26-Sep-22
3:40PM
Connor Zahora
ASV_LMW-1B
2022025324
ASHEVILLE
26-Sep-22
2:49
PM
Haley Seaton
ASV_CB-9BR
2022025325
ASHEVILLE
26-Sep-22
3:22
PM
Haley Seaton
ASV_CB-9SL
2022025326
ASHEVILLE
26-Sep-22
3:49
PM
Haley Seaton
ASV—CB-9
2022025327
ASHEVILLE
26-Sep-22
Connor Zahora
ASV_FD
-20220926-1
2022025328
ASHEVILLE
26-Sep-22
2:00
PM
Connor Zahora
ASV_FB-20220926-1400
14 Total Samples

Page 3 of 53
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals❑ Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes❑ No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
d❑ Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑ Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: Peggy Kendall Date: 10/12/2022

Certificate of Laboratory Analysis Page 4 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LF-SW-2
Sample #:
2022025315
Collection Date: 09/26/2022 11:15 AM
Loc code: ASV LF-SW-2
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
9.0
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 13:13
GHUTCHI
Fluoride
0.06 J
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 13:13
GHUTCHI
Nitrate
0.35
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 13:13
GHUTCHI
Nitrate as N
0.08
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 13:13
GHUTCHI
Sulfate
9.5
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 13:13
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 12:50 JAA5429
Barium (Ba)
0.015
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.024 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.205
mg/L
0.01
0.004
Manganese (Mn)
0.198
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.119 J
ug/L
1
Cadmium (Cd)
0.103 J
ug/L
1
Chromium (Cr)
0.317 J
ug/L
1
Cobalt (Co)
0.295 J
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.07 J
ug/L
0.2
Vanadium (V) Low Level
0.3 J
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 6010D
09/28/2022 12:44
CELL106
1 SW 601OD
09/28/2022 12:44
CELL106
0.104
1
SW 6020B
10/04/2022 17:09
MHALL3
0.111
1
SW 6020B
10/04/2022 17:09
MHALL3
0.032
1
SW 6020B
10/04/2022 17:09
MHALL3
0.185
1
SW 6020B
10/04/2022 17:09
MHALL3
0.077
1
SW 6020B
10/04/2022 17:09
MHALL3
0.037
1
SW 6020B
10/04/2022 17:09
MHALL3
0.193
1
SW 6020B
10/04/2022 17:09
MHALL3
0.035
1
SW 6020B
10/04/2022 17:09
MHALL3
0.041
1
SW 6020B
10/04/2022 17:09
MHALL3
0.114
1
SW 6020B
10/04/2022 17:09
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 5 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-4B
Sample #:
2022025316
Collection Date: 09/26/2022 11:55 AM
Loc code: ASV LMW-4B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
7.6
mg/L
0.5
0.0154
5
EPA 9056A
09/27/2022 13:28
GHUTCHI
Fluoride
0.45 J
mg/L
0.5
0.0479
5
EPA 9056A
09/27/2022 13:28
GHUTCHI
Nitrate
2.1
mg/L
0.5
0.0209
5
EPA 9056A
09/27/2022 13:28
GHUTCHI
Nitrate as N
0.47
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 13:28
GHUTCHI
Sulfate
120
mg/L
5
0.0428
50
EPA 9056A
09/27/2022 13:28
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:02 JAA5429
Barium (Ba)
0.028
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.044 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
11.1
mg/L
0.01
0.004
Manganese (Mn)
6.14
mg/L
0.005
0.001
Nickel (Ni)
0.008
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.133 J
ug/L
1
Arsenic (As)
0.375 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
25.8
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.142 J
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 6010D
09/28/2022 12:57
CELL106
1 SW 601OD
09/28/2022 12:57
CELL106
0.104
1
SW 6020B
10/04/2022 16:28
MHALL3
0.111
1
SW 6020B
10/04/2022 16:28
MHALL3
0.032
1
SW 6020B
10/04/2022 16:28
MHALL3
0.185
1
SW 6020B
10/04/2022 16:28
MHALL3
0.077
1
SW 6020B
10/04/2022 16:28
MHALL3
0.037
1
SW 6020B
10/04/2022 16:28
MHALL3
0.193
1
SW 6020B
10/04/2022 16:28
MHALL3
0.035
1
SW 6020B
10/04/2022 16:28
MHALL3
0.041
1
SW 6020B
10/04/2022 16:28
MHALL3
0.114
1
SW 6020B
10/04/2022 16:28
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 6 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LCS-1
Sample #:
2022025317
Collection Date: 09/26/2022 12:10 PM
Loc code: ASV LCS-1
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride 39
mg/L
2
0.0154
20
EPA 9056A
09/27/2022 13:43
GHUTCHI
Fluoride 1.1 J
mg/L
2
0.0479
20
EPA 9056A
09/27/2022 13:43
GHUTCHI
Nitrate 1.2 J
mg/L
2
0.0209
20
EPA 9056A
09/27/2022 13:43
GHUTCHI
Nitrate as N 0.26
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 13:43
GHUTCHI
Sulfate 700
mg/L
20
0.0428
200
EPA 9056A
09/27/2022 13:43
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.02 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:09 JAA5429
Barium (Ba)
0.061
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
8.88
mg/L
0.05
0.005
Copper (Cu)
0.003 J
mg/L
0.005
0.001
Iron (Fe)
1.05
mg/L
0.01
0.004
Manganese (Mn)
2.88
mg/L
0.005
0.001
Nickel (Ni)
0.005
mg/L
0.005
0.001
Zinc (Zn)
0.011
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
1.67
ug/L
1
Arsenic (As)
6.06
ug/L
1
Cadmium (Cd)
0.126 J
ug/L
1
Chromium (Cr)
1.42
ug/L
1
Cobalt (Co)
1.42
ug/L
1
Lead (Pb)
1.04
ug/L
1
Selenium (Se)
46.0
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.223
ug/L
0.2
Vanadium (V) Low Level
5.32
ug/L
B1, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 6010D
09/28/2022 13:02
CELL106
1 SW 601OD
09/28/2022 13:02
CELL106
0.104
1
SW 6020B
10/04/2022 17:18
MHALL3
0.111
1
SW 6020B
10/04/2022 17:18
MHALL3
0.032
1
SW 6020B
10/04/2022 17:18
MHALL3
0.185
1
SW 6020B
10/04/2022 17:18
MHALL3
0.077
1
SW 6020B
10/04/2022 17:18
MHALL3
0.037
1
SW 6020B
10/04/2022 17:18
MHALL3
0.193
1
SW 6020B
10/04/2022 17:18
MHALL3
0.035
1
SW 6020B
10/04/2022 17:18
MHALL3
0.041
1
SW 6020B
10/04/2022 17:18
MHALL3
0.114
1
SW 6020B
10/04/2022 17:18
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 7 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-3B
Sample #:
2022025318
Collection Date: 09/26/2022 01:00 PM
Loc code: ASV LMW-3B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
3.2
mg/L
0.2
0.0154
2
EPA 9056A
09/27/2022 13:58
GHUTCHI
Fluoride
0.0479 U
mg/L
0.2
0.0479
2
EPA 9056A
09/27/2022 13:58
GHUTCHI
Nitrate
1.8
mg/L
0.2
0.0209
2
EPA 9056A
09/27/2022 13:58
GHUTCHI
Nitrate as N
0.40
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 13:58
GHUTCHI
Sulfate
260
mg/L
5
0.0428
50
EPA 9056A
09/27/2022 13:58
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.02 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:11 JAA5429
Barium (Ba)
0.077
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.012 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.181
mg/L
0.01
0.004
Manganese (Mn)
0.300
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.341 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.269 J
ug/L
1
Cobalt (Co)
0.384 J
ug/L
1
Lead (Pb)
0.069 J
ug/L
1
Selenium (Se)
0.216 J
ug/L
1
Silver (Ag)
0.466 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.332
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 6010D
09/28/2022 13:06
CELL106
1 SW 601OD
09/28/2022 13:06
CELL106
0.104
1
SW 6020B
10/04/2022 17:26
MHALL3
0.111
1
SW 6020B
10/04/2022 17:26
MHALL3
0.032
1
SW 6020B
10/04/2022 17:26
MHALL3
0.185
1
SW 6020B
10/04/2022 17:26
MHALL3
0.077
1
SW 6020B
10/04/2022 17:26
MHALL3
0.037
1
SW 6020B
10/04/2022 17:26
MHALL3
0.193
1
SW 6020B
10/04/2022 17:26
MHALL3
0.035
1
SW 6020B
10/04/2022 17:26
MHALL3
0.041
1
SW 6020B
10/04/2022 17:26
MHALL3
0.114
1
SW 6020B
10/04/2022 17:26
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 8 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LF-SW-3
Sample #:
2022025319
Collection Date: 09/26/2022 01:30 PM
Loc code: ASV LF-SW-3
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
9.8
mg/L
0.5
0.0154
5
EPA 9056A
09/27/2022 14:13
GHUTCHI
Fluoride
0.0479 U
mg/L
0.5
0.0479
5
EPA 9056A
09/27/2022 14:13
GHUTCHI
Nitrate
0.29 J
mg/L
0.5
0.0209
5
EPA 9056A
09/27/2022 14:13
GHUTCHI
Nitrate as N
0.07
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 14:13
GHUTCHI
Sulfate
4.4
mg/L
0.5
0.0428
5
EPA 9056A
09/27/2022 14:13
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:14 JAA5429
Barium (Ba)
0.016
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.025 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.153
mg/L
0.01
0.004
Manganese (Mn)
0.017
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.145 J
ug/L
1
Arsenic (As)
0.157 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.136 J
ug/L
1
Lead (Pb)
0.082 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.351
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 6010D
09/28/2022 13:11
CELL106
1 SW 601OD
09/28/2022 13:11
CELL106
0.104
1
SW 6020B
10/04/2022 17:34
MHALL3
0.111
1
SW 6020B
10/04/2022 17:34
MHALL3
0.032
1
SW 6020B
10/04/2022 17:34
MHALL3
0.185
1
SW 6020B
10/04/2022 17:34
MHALL3
0.077
1
SW 6020B
10/04/2022 17:34
MHALL3
0.037
1
SW 6020B
10/04/2022 17:34
MHALL3
0.193
1
SW 6020B
10/04/2022 17:34
MHALL3
0.035
1
SW 6020B
10/04/2022 17:34
MHALL3
0.041
1
SW 6020B
10/04/2022 17:34
MHALL3
0.114
1
SW 6020B
10/04/2022 17:34
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 9 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-2T
Sample #:
2022025320
Collection Date: 09/26/2022 02:00 PM
Loc code: ASV LMW-2T
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
9.9
mg/L
0.1
0.0154
1
EPA 9056A
09/28/2022 09:07
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/28/2022 09:07
GHUTCHI
Nitrate
16
mg/L
0.5
0.0209
5
EPA 9056A
09/28/2022 09:07
GHUTCHI
Nitrate as N
3.5
mg-N/L
0.023
0.002
1
EPA 9056A
09/28/2022 09:07
GHUTCHI
Sulfate
4.6
mg/L
0.1
0.0428
1
EPA 9056A
09/28/2022 09:07
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:16 JAA5429
Barium (Ba)
0.031
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.026 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.095
mg/L
0.01
0.004
Manganese (Mn)
0.022
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.043 J
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.404 J
ug/L
1
Lead (Pb)
0.06 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.435
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 6010D
09/28/2022 13:15
CELL106
1 SW 601OD
09/28/2022 13:15
CELL106
0.104
1
SW 6020B
10/04/2022 17:43
MHALL3
0.111
1
SW 6020B
10/04/2022 17:43
MHALL3
0.032
1
SW 6020B
10/04/2022 17:43
MHALL3
0.185
1
SW 6020B
10/04/2022 17:43
MHALL3
0.077
1
SW 6020B
10/04/2022 17:43
MHALL3
0.037
1
SW 6020B
10/04/2022 17:43
MHALL3
0.193
1
SW 6020B
10/04/2022 17:43
MHALL3
0.035
1
SW 6020B
10/04/2022 17:43
MHALL3
0.041
1
SW 6020B
10/04/2022 17:43
MHALL3
0.114
1
SW 6020B
10/04/2022 17:43
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 10 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-2B
Sample #:
2022025321
Collection Date: 09/26/2022 02:35 PM
Loc code: ASV LMW-2B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
7.9
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 14:43
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 14:43
GHUTCHI
Nitrate
1.4
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 14:43
GHUTCHI
Nitrate as N
0.31
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 14:43
GHUTCHI
Sulfate
2.9
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 14:43
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:19 JAA5429
Barium (Ba)
0.046
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.012 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.044
mg/L
0.01
0.004
Manganese (Mn)
0.012
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.364 J
ug/L
1
Cobalt (Co)
0.286 J
ug/L
1
Lead (Pb)
0.093 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.036 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.743
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 6010D
09/28/2022 13:20
CELL106
1 SW 601OD
09/28/2022 13:20
CELL106
0.104
1
SW 6020B
10/04/2022 17:51
MHALL3
0.111
1
SW 6020B
10/04/2022 17:51
MHALL3
0.032
1
SW 6020B
10/04/2022 17:51
MHALL3
0.185
1
SW 6020B
10/04/2022 17:51
MHALL3
0.077
1
SW 6020B
10/04/2022 17:51
MHALL3
0.037
1
SW 6020B
10/04/2022 17:51
MHALL3
0.193
1
SW 6020B
10/04/2022 17:51
MHALL3
0.035
1
SW 6020B
10/04/2022 17:51
MHALL3
0.041
1
SW 6020B
10/04/2022 17:51
MHALL3
0.114
1
SW 6020B
10/04/2022 17:51
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 11 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-lS
Sample #:
2022025322
Collection Date: 09/26/2022 03:15 PM
Loc code: ASV LMW-lS
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
6.2
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 12:27
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 12:27
GHUTCHI
Nitrate
2.7
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 12:27
GHUTCHI
Nitrate as N
0.62
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 12:27
GHUTCHI
Sulfate
0.27
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 12:27
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:21 JAA5429
Barium (Ba)
0.041
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.236
mg/L
0.01
0.004
Manganese (Mn)
0.071
mg/L
0.005
0.001
Nickel (Ni)
0.002 J
mg/L
0.005
0.001
Zinc (Zn)
0.006
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.122 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.769 J
ug/L
1
Cobalt (Co)
0.674 J
ug/L
1
Lead (Pb)
0.06 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.524
ug/L
B, 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 6010D
09/28/2022 13:24
CELL106
1 SW 601OD
09/28/2022 13:24
CELL106
0.104
1
SW 6020B
10/04/2022 18:00
MHALL3
0.111
1
SW 6020B
10/04/2022 18:00
MHALL3
0.032
1
SW 6020B
10/04/2022 18:00
MHALL3
0.185
1
SW 6020B
10/04/2022 18:00
MHALL3
0.077
1
SW 6020B
10/04/2022 18:00
MHALL3
0.037
1
SW 6020B
10/04/2022 18:00
MHALL3
0.193
1
SW 6020B
10/04/2022 18:00
MHALL3
0.035
1
SW 6020B
10/04/2022 18:00
MHALL3
0.041
1
SW 6020B
10/04/2022 18:00
MHALL3
0.114
1
SW 6020B
10/04/2022 18:00
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 12 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV LMW-1 B
Sample #:
2022025323
Collection Date: 09/26/2022 03:40 PM
Loc code: ASV LMW-1 B
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
8.1
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 15:14
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 15:14
GHUTCHI
Nitrate
0.21
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 15:14
GHUTCHI
Nitrate as N
0.05
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 15:14
GHUTCHI
Sulfate
0.33
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 15:14
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.05 ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:24 JAA5429
Barium (Ba)
0.027
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.039
mg/L
0.01
0.004
Manganese (Mn)
0.003 J
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.117 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.238 J
ug/L
1
Cobalt (Co)
0.077 U
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.035 U
ug/L
1
Thallium (TI) Low Level
0.05 J
ug/L
0.2
Vanadium (V) Low Level
0.627
ug/L
B 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 6010D
09/28/2022 13:29
CELL106
1 SW 601OD
09/28/2022 13:29
CELL106
0.104
1
SW 6020B
10/04/2022 18:33
MHALL3
0.111
1
SW 6020B
10/04/2022 18:33
MHALL3
0.032
1
SW 6020B
10/04/2022 18:33
MHALL3
0.185
1
SW 6020B
10/04/2022 18:33
MHALL3
0.077
1
SW 6020B
10/04/2022 18:33
MHALL3
0.037
1
SW 6020B
10/04/2022 18:33
MHALL3
0.193
1
SW 6020B
10/04/2022 18:33
MHALL3
0.035
1
SW 6020B
10/04/2022 18:33
MHALL3
0.041
1
SW 6020B
10/04/2022 18:33
MHALL3
0.114
1
SW 6020B
10/04/2022 18:33
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 13 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV CB-9BR
Sample #:
2022025324
Collection Date: 09/26/2022 02:49 PM
Loc code: ASV CB-9BR
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride 7.7
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 15:29
GHUTCHI
Fluoride 0.05 J
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 15:29
GHUTCHI
Nitrate 0.11
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 15:29
GHUTCHI
Nitrate as N 0.02
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 15:29
GHUTCHI
Sulfate 1.7
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 15:29
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:26 JAA5429
Barium (Ba)
0.025
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.050
mg/L
0.01
0.004
Manganese (Mn)
0.051
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.048 J
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
0.084 J
ug/L
1
Lead (Pb)
0.055 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.048 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.277 J
ug/L
B 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 6010D
09/28/2022 13:33
CELL106
1 SW 601OD
09/28/2022 13:33
CELL106
0.104
1
SW 6020B
10/04/2022 18:41
MHALL3
0.111
1
SW 6020B
10/04/2022 18:41
MHALL3
0.032
1
SW 6020B
10/04/2022 18:41
MHALL3
0.185
1
SW 6020B
10/04/2022 18:41
MHALL3
0.077
1
SW 6020B
10/04/2022 18:41
MHALL3
0.037
1
SW 6020B
10/04/2022 18:41
MHALL3
0.193
1
SW 6020B
10/04/2022 18:41
MHALL3
0.035
1
SW 6020B
10/04/2022 18:41
MHALL3
0.041
1
SW 6020B
10/04/2022 18:41
MHALL3
0.114
1
SW 6020B
10/04/2022 18:41
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 14 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV CB-9SL
Sample #:
2022025325
Collection Date: 09/26/2022
03:22 PM
Loc code: ASV CB-9SL
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
7.8
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 16:29
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 16:29
GHUTCHI
Nitrate
0.94
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 16:29
GHUTCHI
Nitrate as N
0.21
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 16:29
GHUTCHI
Sulfate
0.26
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 16:29
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:29 JAA5429
Barium (Ba)
0.044
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.005 U
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.013
mg/L
0.01
0.004
Manganese (Mn)
0.002 J
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.008
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.135 J
ug/L
1
Arsenic (As)
0.111 U
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.49 J
ug/L
1
Cobalt (Co)
0.077 U
ug/L
1
Lead (Pb)
0.045 J
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.246 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.318
ug/L
B 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 6010D
09/28/2022 13:46
CELL106
1 SW 601OD
09/28/2022 13:46
CELL106
0.104
1
SW 6020B
10/04/2022 18:50
MHALL3
0.111
1
SW 6020B
10/04/2022 18:50
MHALL3
0.032
1
SW 6020B
10/04/2022 18:50
MHALL3
0.185
1
SW 6020B
10/04/2022 18:50
MHALL3
0.077
1
SW 6020B
10/04/2022 18:50
MHALL3
0.037
1
SW 6020B
10/04/2022 18:50
MHALL3
0.193
1
SW 6020B
10/04/2022 18:50
MHALL3
0.035
1
SW 6020B
10/04/2022 18:50
MHALL3
0.041
1
SW 6020B
10/04/2022 18:50
MHALL3
0.114
1
SW 6020B
10/04/2022 18:50
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 15 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV CB-9
Sample #:
2022025326
Collection Date: 09/26/2022 03:49 PM
Loc code: ASV-CB-9
Matrix:
GW RCRA
Analyte Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride 6.5
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 16:44
GHUTCHI
Fluoride 0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 16:44
GHUTCHI
Nitrate 0.98
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 16:44
GHUTCHI
Nitrate as N 0.22
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 16:44
GHUTCHI
Sulfate 0.12
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 16:44
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.02 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:36 JAA5429
Barium (Ba)
0.027
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.006 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
0.038
mg/L
0.01
0.004
Manganese (Mn)
0.031
mg/L
0.005
0.001
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
Zinc (Zn)
0.009
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.15 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.275 J
ug/L
1
Cobalt (Co)
0.9 J
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.385 J
ug/L
1
Thallium (TI) Low Level
0.08 J
ug/L
0.2
Vanadium (V) Low Level
0.261 J
ug/L
B 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 6010D
09/28/2022 13:51
CELL106
1 SW 601OD
09/28/2022 13:51
CELL106
0.104
1
SW 6020B
10/04/2022 18:58
MHALL3
0.111
1
SW 6020B
10/04/2022 18:58
MHALL3
0.032
1
SW 6020B
10/04/2022 18:58
MHALL3
0.185
1
SW 6020B
10/04/2022 18:58
MHALL3
0.077
1
SW 6020B
10/04/2022 18:58
MHALL3
0.037
1
SW 6020B
10/04/2022 18:58
MHALL3
0.193
1
SW 6020B
10/04/2022 18:58
MHALL3
0.035
1
SW 6020B
10/04/2022 18:58
MHALL3
0.041
1
SW 6020B
10/04/2022 18:58
MHALL3
0.114
1
SW 6020B
10/04/2022 18:58
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 16 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV_FD-20220926-1
Duplicate
Sample #:
2022025327
Collection Date: 09/26/2022
Loc code: ASV FD
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
7.7
mg/L
0.5
0.0154
5
EPA 9056A
09/27/2022 17:14
GHUTCHI
Fluoride
0.46 J
mg/L
0.5
0.0479
5
EPA 9056A
09/27/2022 17:14
GHUTCHI
Nitrate
0.21 J
mg/L
0.5
0.0209
5
EPA 9056A
09/27/2022 17:14
GHUTCHI
Nitrate as N
0.05
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 17:14
GHUTCHI
Sulfate
120
mg/L
5
0.0428
50
EPA 9056A
09/27/2022 17:14
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg) 0.01 J ug/L 0.05
TOTAL RECOVERABLE METALS BY ICP - Q22090328
0.01 1 EPA 7470A 10/04/2022 13:43 JAA5429
Barium (Ba)
0.027
mg/L
0.005
0.002
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
Boron (B)
0.038 J
mg/L
0.05
0.005
Copper (Cu)
0.001 U
mg/L
0.005
0.001
Iron (Fe)
10.6
mg/L
0.01
0.004
Manganese (Mn)
5.89
mg/L
0.005
0.001
Nickel (Ni)
0.007
mg/L
0.005
0.001
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
Arsenic (As)
0.326 J
ug/L
1
Cadmium (Cd)
0.032 U
ug/L
1
Chromium (Cr)
0.185 U
ug/L
1
Cobalt (Co)
26.2
ug/L
1
Lead (Pb)
0.037 U
ug/L
1
Selenium (Se)
0.193 U
ug/L
1
Silver (Ag)
0.097 J
ug/L
1
Thallium (TI) Low Level
0.041 U
ug/L
0.2
Vanadium (V) Low Level
0.114 U
ug/L
B 0.3
TOTAL DISSOLVED SOLIDS
- (Analvsis Performed by
Pace Laboratories)
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 6010D
09/28/2022 13:55
CELL106
1 SW 601OD
09/28/2022 13:55
CELL106
0.104
1
SW 6020B
10/04/2022 19:07
MHALL3
0.111
1
SW 6020B
10/04/2022 19:07
MHALL3
0.032
1
SW 6020B
10/04/2022 19:07
MHALL3
0.185
1
SW 6020B
10/04/2022 19:07
MHALL3
0.077
1
SW 6020B
10/04/2022 19:07
MHALL3
0.037
1
SW 6020B
10/04/2022 19:07
MHALL3
0.193
1
SW 6020B
10/04/2022 19:07
MHALL3
0.035
1
SW 6020B
10/04/2022 19:07
MHALL3
0.041
1
SW 6020B
10/04/2022 19:07
MHALL3
0.114
1
SW 6020B
10/04/2022 19:07
MHALL3
Vendor Parameter Complete Vendor Method V_PACE

Certificate of Laboratory Analysis Page 17 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Site: ASV FB-20220926-1400
Field Blank
Sample #:
2022025328
Collection Date: 09/26/2022 02:00 PM
Loc code: ASV QA
Matrix:
GW RCRA
Analyte
Result
Units
Qualifiers RDL
MDL
DF
Method
Analysis Date/Time
Analyst
INORGANIC IONS BY IC - Q22090338
Chloride
0.0154 U
mg/L
0.1
0.0154
1
EPA 9056A
09/27/2022 17:29
GHUTCHI
Fluoride
0.0479 U
mg/L
0.1
0.0479
1
EPA 9056A
09/27/2022 17:29
GHUTCHI
Nitrate
0.0209 U
mg/L
0.1
0.0209
1
EPA 9056A
09/27/2022 17:29
GHUTCHI
Nitrate as N
0.002 U
mg-N/L
0.023
0.002
1
EPA 9056A
09/27/2022 17:29
GHUTCHI
Sulfate
0.0428 U
mg/L
0.1
0.0428
1
EPA 9056A
09/27/2022 17:29
GHUTCHI
MERCURY (COLD VAPOR) IN WATER - Q22100044
Mercury (Hg)
0.01 J
ug/L
0.05
0.01
1
EPA 7470A
10/04/2022 13:45
JAA5429
TOTAL RECOVERABLE METALS BY ICP - Q22090328
Barium (Ba)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
09/28/2022 14:00
CELL106
Beryllium (Be)
0.002 U
mg/L
0.005
0.002
1
SW 6010D
09/28/2022 14:00
CELL106
Boron (B)
0.005 U
mg/L
0.05
0.005
1
SW 6010D
09/28/2022 14:00
CELL106
Copper (Cu)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
09/28/2022 14:00
CELL106
Iron (Fe)
0.012
mg/L
0.01
0.004
1
SW 6010D
09/28/2022 14:00
CELL106
Manganese (Mn)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
09/28/2022 14:00
CELL106
Nickel (Ni)
0.001 U
mg/L
0.005
0.001
1
SW 6010D
09/28/2022 14:00
CELL106
Zinc (Zn)
0.004 U
mg/L
0.005
0.004
1
SW 601 OD
09/28/2022 14:00
CELL106
TOTAL RECOVERABLE METALS BY ICP-MS - Q22090330
Antimony (Sb)
0.104 U
ug/L
1
0.104
1
SW 6020B
10/04/2022 19:15
MHALL3
Arsenic (As)
0.111 U
ug/L
1
0.111
1
SW 6020B
10/04/2022 19:15
MHALL3
Cadmium (Cd)
0.032 U
ug/L
1
0.032
1
SW 6020B
10/04/2022 19:15
MHALL3
Chromium (Cr)
0.185 U
ug/L
1
0.185
1
SW 6020B
10/04/2022 19:15
MHALL3
Cobalt (Co)
0.077 U
ug/L
1
0.077
1
SW 6020B
10/04/2022 19:15
MHALL3
Lead (Pb)
0.037 U
ug/L
1
0.037
1
SW 6020B
10/04/2022 19:15
MHALL3
Selenium (Se)
0.193 U
ug/L
1
0.193
1
SW 6020B
10/04/2022 19:15
MHALL3
Silver (Ag)
0.035 U
ug/L
1
0.035
1
SW 6020B
10/04/2022 19:15
MHALL3
Thallium (TI) Low Level
0.041 U
ug/L
0.2
0.041
1
SW 6020B
10/04/2022 19:15
MHALL3
Vanadium (V) Low Level
0.18 J
ug/L
B 0.3
0.114
1
SW 6020B
10/04/2022 19:15
MHALL3
Qualifiers:
B Target analyte detected in Method/Prep Blank at or above the reporting limit. Target analyte concentration in sample is less
than 10X the concentration in the Method/Prep Blank. Analyte concentration in sample could be due to contamination.
B1 Target analyte was detected in Method/Prep Blank at or above the reporting limit. Target analyte concentration in sample is
below the reporting limit or greater than 10X the concentration of the target analyte detected in the Method/Prep Blank.
Analyte concentration in sample is not affected by contamination.
J Analyte detected above the MDL, but below the RL. Analyte concentration should be considered an estimate.

Certificate of Laboratory Analysis Page 18 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22090338 Dionex INORGANIC IONS BY IC
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Chloride
0
0
mg/L
1
0.0154
0.1
< MDL
Fluoride
0
0
mg/L
1
0.0479
0.1
< MDL
Nitrate
0
0
mg/L
1
0.0209
0.1
< MDL
Sulfate
0
0
mg/L
1
0.0428
0.1
< MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
1.96
1.96
mg/L
1
0.0154
5
98
80
120
Fluoride
2
2
mg/L
1
0.0479
5
100
80
120
Nitrate
1.98
1.98
mg/L
1
0.0209
5
98.8
80
120
Sulfate
2.03
2.03
mg/L
1
0.0428
5
101
80
120
MS # 1
Parent Sample:
J22090472 -- 2022025322
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL
Qualifier
Chloride
8.15
8.15
mg/L
1
0.0154
2
96.7
80
120
Fluoride
2.04
2.04
mg/L
1
0.0479
2
100
80
120
Nitrate
4.77
4.77
mg/L
1
0.0209
2
102
80
120
Sulfate
2.29
2.29
mg/L
1
0.0428
2
101
80
120
MSD # 1
Parent Sample:
J22090472 -- 2022025322
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
8.2
8.2
mg/L
1
0.0154
2
99.5
80
120
2.91
Fluoride
2.1
2.1
mg/L
1
0.0479
2
103
80
120
2.65
Nitrate
4.82
4.82
mg/L
1
0.0209
2
105
80
120
2.62
Sulfate
2.37
2.37
mg/L
1
0.0428
2
105
80
120
3.54

Certificate of Laboratory Analysis Page 19 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22100044 HG 7470 MERCURY (COLD VAPOR) IN WATER
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.009
0.009
ug/L
1
0.01
0.05
< MDL
Blank # 2
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.01
0.01
ug/L
1
0.01
0.05
= MDL
Blank # 3
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.011
0.011
ug/L
1
0.01
0.05
> MDL
Blank # 4
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.012
0.012
ug/L
1
0.01
0.05
> MDL
Blank # 5
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.012
0.012
ug/L
1
0.01
0.05
> MDL
Blank # 6
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.023
0.023
ug/L
1
0.01
0.05
> MDL
Blank # 7
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.024
0.024
ug/L
1
0.01
0.05
> MDL
Blank # 8
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Qualifier
Mercury (Hg)
0.022
0.022
ug/L
1
0.01
0.05
> MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
alAke
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
2.02
2.02
ug/L
1
0.01
2
101
85
115
LCS # 2
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
2.01
2.01
ug/L
1
0.01
2
101
85
115
LCS # 3
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL Qualifier
Mercury (Hg)
2.01
2.01
ug/L
1
0.01
2
100
85
115

Certificate of Laboratory Analysis Page 20 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
022100044 HG 7470 MERCURY (COLD VAPOR) IN WATER
LCS # 4
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
2.02
2.02
ug/L
1
0.01
2
101
85 115
MS # 1
Parent Sample:
J22080352 -- 2022021555
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.997
0.997
ug/L
1
0.01
1
98.5
75 125
MSD # 1
Parent Sample:
J22080352 -- 2022021555
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
99.3
75 125 0.809
MS # 2
Parent Sample:
J22080352 -- 2022021566
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
101
75 125
MSD # 2
Parent Sample:
J22080352 -- 2022021566
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
101
75 125 0.495
MS # 3
Parent Sample:
J22090389 -- 2022024811
Parameter
Measured
Final
Units
Di
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.06
1.06
ug/L
1
0.01
1
105
75 125
MSD # 3
Parent Sample:
J22090389 -- 2022024811
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
100
75 125 4.2
MS # 4
Parent Sample:
J22090389 -- 2022024821
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
99.9
75 125
MSD # 4
Parent Sample:
J22090389 -- 2022024821
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.996
0.996
ug/L
1
0.01
1
98.2
75 125 1.72
MS # 5
Parent Sample:
J22090472 -- 2022025316
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
0.969
0.969
ug/L
1
0.01
1
95.8
75 125
MSD # 5
Parent Sample:
J22090472 -- 2022025316
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
0.966
0.966
ug/L
1
0.01
1
95.5
75 125 0.314

Certificate of Laboratory Analysis Page 21 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22100044 HG 7470 MERCURY (COLD VAPOR) IN WATER
MS # 6
Parent Sample:
J22090472 -- 2022025326
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1.02
1.02
ug/L
1
0.01
1
101
75 125
MSD # 6
Parent Sample:
J22090472 -- 2022025326
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.03
1.03
ug/L
1
0.01
1
101
75 125 0.892
MS # 7
Parent Sample:
J22090473 -- 2022025336
Parameter
Measured
Final
Units
Dil
MDL
52ike
% Recovery
LCL UCL
Qualifier
Mercury (Hg)
1
1
ug/L
1
0.01
1
99.4
75 125
MSD # 7
Parent Sample:
J22090473 -- 2022025336
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL UCL RPD
Qualifier
Mercury (Hg)
1.01
1.01
ug/L
1
0.01
1
99.6
75 125 0.201

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22090328 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Barium (Ba)
-0.000257
-0.000257
mg/L
1
0.002
0.005
< MDL
Beryllium (Be)
0
mg/L
1
0.002
0.005
< MDL
Boron (B)
0.00165
0.00165
mg/L
1
0.005
0.05
< MDL
Copper (Cu)
0.000046
0.000046
mg/L
1
0.001
0.005
< MDL
Iron (Fe)
0.00266
0.00266
mg/L
1
0.004
0.01
< MDL
Manganese (Mn)
0.000053
0.000053
mg/L
1
0.001
0.005
< MDL
Nickel (Ni)
-0.000388
-0.000388
mg/L
1
0.001
0.005
< MDL
Zinc (Zn)
0.000255
0.000255
mg/L
1
0.004
0.005
< MDL
LCS # 1
Page 22 of 53
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.15
5.15
mg/L
1
0.002
5
103
80
120
Beryllium (Be)
4.87
mg/L
1
0.002
5
97.3
80
120
Boron (B)
4.76
4.76
mg/L
1
0.005
5
95.2
80
120
Copper (Cu)
4.81
4.81
mg/L
1
0.001
5
96.1
80
120
Iron (Fe)
4.69
4.69
mg/L
1
0.004
5
93.9
80
120
Manganese (Mn)
4.83
4.83
mg/L
1
0.001
5
96.5
80
120
Nickel (Ni)
4.63
4.63
mg/L
1
0.001
5
92.6
80
120
Zinc (Zn)
4.85
4.85
mg/L
1
0.004
5
97
80
120
MS # 1
Parent Sample:
J22090472
-- 2022025315
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL
Barium (Ba)
5.27
5.27
mg/L
1
0.002
5
105
75
125
Beryllium (Be)
5.05
mg/L
1
0.002
5
101
75
125
Boron (B)
5.01
5.01
mg/L
1
0.005
5
99.8
75
125
Copper (Cu)
5
5
mg/L
1
0.001
5
99.9
75
125
Iron (Fe)
5.17
5.17
mg/L
1
0.004
5
99.2
75
125
Manganese (Mn)
5.21
5.21
mg/L
1
0.001
5
100
75
125
Nickel (Ni)
4.95
4.95
mg/L
1
0.001
5
98.9
75
125
Zinc (Zn)
5.04
5.04
mg/L
1
0.004
5
101
75
125
MSD # 1
Parent Sample:
J22090472
-- 2022025315
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
RPD
Barium (Ba)
5.25
5.25
mg/L
1
0.002
5
105
75
125
0.38
Beryllium (Be)
4.93
mg/L
1
0.002
5
98.6
75
125
2.39
Boron (B)
4.88
4.88
mg/L
1
0.005
5
97
75
125
2.77
Copper (Cu)
4.9
4.9
mg/L
1
0.001
5
98
75
125
2
Iron (Fe)
4.99
4.99
mg/L
1
0.004
5
95.7
75
125
3.43
Manganese (Mn)
5.11
5.11
mg/L
1
0.001
5
98.2
75
125
2.03
Nickel (Ni)
4.73
4.73
mg/L
1
0.001
5
94.6
75
125
4.42
Qualifier
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 23 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22090328 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1 Parent Sample: J22090472 -- 2022025315
Parameter Measured Final Units Dil MDL Spike % Recovery LCL UCL RPD Qualifier
Zinc (Zn) 4.92 4.92 mg/L 1 0.004 5 98.3 75 125 2.43

Certificate of Laboratory Analysis Page 24 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22090330 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units
Dil
MDL
RDL
Relative Concentration
Antimony (Sb)
0.12
0.12
ug/L
1
0.104
1
> MDL
Arsenic (As)
0.099
0.099
ug/L
1
0.111
1
< MDL
Cadmium (Cd)
0.027
0.027
ug/L
1
0.032
1
< MDL
Chromium (Cr)
0.034
0.034
ug/L
1
0.185
1
< MDL
Cobalt (Co)
0.041
0.041
ug/L
1
0.077
1
< MDL
Lead (Pb)
0.036
0.036
ug/L
1
0.037
1
< MDL
Selenium (Se)
0.04
0.04
ug/L
1
0.193
1
< MDL
Silver (Ag)
0.019
0.019
ug/L
1
0.035
1
< MDL
Thallium (TI) Low Level
0.022
0.022
ug/L
1
0.041
0.2
< MDL
Vanadium (V) Low Level
0.374
0.374
ug/L
1
0.114
0.3
> MDL
LCS # 1
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
51.8
51.8
ug/L
1
0.104
50
104
80
120
Arsenic (As)
52.2
52.2
ug/L
1
0.111
50
104
80
120
Cadmium (Cd)
50.8
50.8
ug/L
1
0.032
50
102
80
120
Chromium (Cr)
50.6
50.6
ug/L
1
0.185
50
101
80
120
Cobalt (Co)
52.1
52.1
ug/L
1
0.077
50
104
80
120
Lead (Pb)
51.3
51.3
ug/L
1
0.037
50
103
80
120
Selenium (Se)
48.7
48.7
ug/L
1
0.193
50
97.5
80
120
Silver (Ag)
51.6
51.6
ug/L
1
0.035
50
103
80
120
Thallium (TI) Low Level
48.7
48.7
ug/L
1
0.041
50
97.3
80
120
Vanadium (V) Low Level
50.7
50.7
ug/L
1
0.114
50
101
80
120
MS # 1
Parent Sample:
J22090472 -- 2022025316
Parameter
Measured
Final
Units
Dil
MDL
S ike
% Recovery
LCL
UCL
Antimony (Sb)
51.9
51.9
ug/L
1
0.104
50
104
75
125
Arsenic (As)
52
52
ug/L
1
0.111
50
103
75
125
Cadmium (Cd)
50.4
50.4
ug/L
1
0.032
50
101
75
125
Chromium (Cr)
51.3
51.3
ug/L
1
0.185
50
103
75
125
Cobalt (Co)
76.6
76.6
ug/L
1
0.077
50
102
75
125
Lead (Pb)
51.2
51.2
ug/L
1
0.037
50
102
75
125
Selenium (Se)
48.9
48.9
ug/L
1
0.193
50
97.8
75
125
Silver (Ag)
51.5
51.5
ug/L
1
0.035
50
103
75
125
Thallium (TI) Low Level
47.2
47.2
ug/L
1
0.041
50
94.4
75
125
Vanadium (V) Low Level
52.1
52.1
ug/L
1
0.114
50
104
75
125
MSD # 1
Parent Sample:
J22090472 -- 2022025316
Parameter
Measured
Final
Units
Dil
MDL
Spike
% Recovery
LCL
UCL RPD
Antimony (Sb)
53.2
53.2
ug/L
1
0.104
50
106
75
125 2.54
Qualifier
B,B1
Qualifier
Qualifier
Qualifier

Certificate of Laboratory Analysis Page 25 of 53
This report shall not be reproduced, except in full.
Order # J22090472
Level II QC Summary
Q22090330 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MSD # 1
Parent Sample: J22090472 -- 2022025316
Parameter Measured Final Units
Dil MDL Spike % Recovery LCL
UCL
RPD
Arsenic (As) 51.4 51.4 ug/L
1 0.111 50 102 75
125
1.23
Cadmium (Cd) 50.8 50.8 ug/L
1 0.032 50 102 75
125
0.915
Chromium (Cr) 51.8 51.8 ug/L
1 0.185 50 104 75
125
0.98
Cobalt (Co) 76.8 76.8 ug/L
1 0.077 50 102 75
125
0.289
Lead (Pb) 51.4 51.4 ug/L
1 0.037 50 103 75
125
0.39
Selenium (Se) 49.1 49.1 ug/L
1 0.193 50 98.2 75
125
0.465
Silver (Ag) 50.9 50.9 ug/L
1 0.035 50 102 75
125
1.25
Thallium (TI) Low Level 48.2 48.2 ug/L
1 0.041 50 96.4 75
125
2.06
Vanadium (V) Low Level 53 53 ug/L
1 0.114 50 106 75
125
1.64
Qualifiers:
B Target analyte detected in Method/Prep Blank
at or above the reporting limit. Target analyte concentration in
sample is less than 10X the concentration in
the Method/Prep Blank. Analyte concentration in sample could
be due to contamination.
B1 Target analyte was detected in Method/Prep Blank at or above the reporting limit. Target analyte
concentration in sample is below the reporting
limit or greater than 10X the concentration of the target
analyte detected in the Method/Prep Blank.
Analyte concentration in sample is not affected by
contamination.
Qualifier

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
og8� ��-6 f&Ie. Suite 100
��JJ Huntersville, NC 28078
[phone]
October 04, 2022
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg.7405 MG30A2
Huntersville, NC 28078
RE: Project: J22090472 ASV LF
Pace Project No.: 92627920
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on September 27, 2022. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
%D'a6-
Nicole D'Oleo
nicole.d'[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 27

leAnalyiical
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Pace Analytical Services, LLC
og8� ' le. Suite 100
��JJ Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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SAMPLE SUMMARY
Project: J22090472 ASV LF
Pace Project No.: 92627920
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92627920001
LF-SW-2
Water
09/26/2211:15
09/27/22 14:20
92627920002
LMW-4B
Water
09/26/2211:55
09/27/22 14:20
92627920003
LCS-1
Water
09/26/2212:10
09/27/22 14:20
92627920004
LMW-3B
Water
09/26/2213:00
09/27/22 14:20
92627920005
LF-SW-3
Water
09/26/22 13:30
09/27/22 14:20
92627920006
LMW-2T
Water
09/26/2214:00
09/27/22 14:20
92627920007
LMW-213
Water
09/26/2214:35
09/27/22 14:20
92627920008
LMW-1S
Water
09/26/2215:15
09/27/22 14:20
92627920009
LMW-1B
Water
09/26/2215:40
09/27/22 14:20
92627920010
C13-913R
Water
09/26/2214:49
09/27/22 14:20
92627920011
C13-9SL
Water
09/26/2215:22
09/27/22 14:20
92627920012
C13-9
Water
09/26/2215:49
09/27/22 14:20
92627920013
ASV FD-20220926-1
Water
09/26/22 00:00
09/27/22 14:20
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
J22090472 ASV LF
92627920
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92627920001
LF-SW-2
SM 2540C-2015
CS1
1
PASI-A
92627920002
LMW-413
SM 2540C-2015
CS1
1
PASI-A
92627920003
LCS-1
SM 2540C-2015
CS1
1
PASI-A
92627920004
LMW-313
SM 2540C-2015
CS1
1
PASI-A
92627920005
LF-SW-3
SM 2540C-2015
CS1
1
PASI-A
92627920006
LMW-2T
SM 2540C-2015
CS1
1
PASI-A
92627920007
LMW-213
SM 2540C-2015
CS1
1
PASI-A
92627920008
LMW-1S
SM 2540C-2015
CS1
1
PASI-A
92627920009
LMW-1B
SM 2540C-2015
CS1
1
PASI-A
92627920010
C13-913R
SM 2540C-2015
CS1
1
PASI-A
92627920011
C13-9SL
SM 2540C-2015
CS1
1
PASI-A
92627920012
C13-9
SM 2540C-2015
CS1
1
PASI-A
92627920013
ASV FD-20220926-1
SM 2540C-2015
CS1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
REPORT OF LABORATORY ANALYSIS
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SUMMARY OF DETECTION
Project:
Pace Project No.:
J22090472 ASV LF
92627920
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92627920001
LF-SW-2
SM 2540C-2015
Total Dissolved Solids
50.0
mg/L
25.0
09/29/22 09:21
92627920002
LMW-46
SM 2540C-2015
Total Dissolved Solids
315
mg/L
25.0
09/29/22 09:21
92627920003
LCS-1
SM 2540C-2015
Total Dissolved Solids
1470
mg/L
50.0
09/29/22 09:21
92627920004
LMW-36
SM 2540C-2015
Total Dissolved Solids
473
mg/L
25.0
09/29/22 09:21
92627920005
LF-SW-3
SM 2540C-2015
Total Dissolved Solids
42.0
mg/L
25.0
09/29/22 09:22
92627920006
LMW-2T
SM 2540C-2015
Total Dissolved Solids
51.0
mg/L
25.0
09/29/22 09:22
92627920007
LMW-26
SM 2540C-2015
Total Dissolved Solids
65.0
mg/L
25.0
09/29/22 09:22
92627920008
LMWA S
SM 2540C-2015
Total Dissolved Solids
51.0
mg/L
25.0
09/29/22 09:22
92627920009
LMW-1B
SM 2540C-2015
Total Dissolved Solids
85.0
mg/L
25.0
09/29/22 09:22
92627920010
C13-96R
SM 2540C-2015
Total Dissolved Solids
84.0
mg/L
25.0
09/29/22 09:22
92627920011
CB-9SL
SM 2540C-2015
Total Dissolved Solids
47.0
mg/L
25.0
09/30/22 09:50
92627920012
C13-9
SM 2540C-2015
Total Dissolved Solids
26.0
mg/L
25.0
09/30/22 09:50
92627920013
ASV FD-20220926-1
SM 2540C-2015
Total Dissolved Solids
305
mg/L
25.0
09/30/22 09:50
REPORT OF LABORATORY ANALYSIS
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PROJECT NARRATIVE
Project: J22090472 ASV LF
Pace Project No.: 92627920
Method: SM 2540C-2015
Description: 2540C Total Dissolved Solids
Client: Duke Energy
Date: October 04, 2022
General Information:
13 samples were analyzed for SM 254OC-2015 by Pace Analytical Services Asheville. All samples were received in acceptable
condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached
at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LF-SW-2 Lab ID: 92627920001 Collected: 09/26/22 11:15 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 50.0 mg/L 25.0 25.0 1 09/29/22 09:21
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-413 Lab ID: 92627920002 Collected: 09/26/22 11:55 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 254OC-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 315 mg/L 25.0 25.0 1 09/29/22 09:21
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LCS-1 Lab ID: 92627920003 Collected: 09/26/22 12:10 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 1470 mg/L 50.0 50.0 1 09/29/22 09:21
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-313 Lab ID: 92627920004 Collected: 09/26/22 13:00 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 473 mg/L 25.0 25.0 1 09/29/22 09:21
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LF-SW-3 Lab ID: 92627920005 Collected: 09/26/22 13:30 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 42.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-2T Lab ID: 92627920006 Collected: 09/26/22 14:00 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 51.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-213 Lab ID: 92627920007 Collected: 09/26/22 14:35 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 65.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-1S Lab ID: 92627920008 Collected: 09/26/22 15:15 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 51.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: LMW-113 Lab ID: 92627920009 Collected: 09/26/22 15:40 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 85.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: C13-913R Lab ID: 92627920010 Collected: 09/26/22 14:49 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 84.0 mg/L 25.0 25.0 1 09/29/22 09:22
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: C13-9SL Lab ID: 92627920011 Collected: 09/26/22 15:22 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 47.0 mg/L 25.0 25.0 1 09/30/22 09:50
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: C13-9 Lab ID: 92627920012 Collected: 09/26/22 15:49 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 26.0 mg/L 25.0 25.0 1 09/30/22 09:50
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J22090472 ASV LF
Pace Project No.: 92627920
Sample: ASV_FD-20220926-1 Lab ID: 92627920013 Collected: 09/26/22 00:00 Received: 09/27/22 14:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
Total Dissolved Solids 305 mg/L 25.0 25.0 1 09/30/22 09:50
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J22090472 ASV LF
Pace Project No.: 92627920
QC Batch: 726459 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92627920001, 92627920002, 92627920003, 92627920004, 92627920005, 92627920006, 92627920007,
92627920008,92627920009,92627920010
METHOD BLANK: 3783682 Matrix: Water
Associated Lab Samples: 92627920001, 92627920002, 92627920003, 92627920004, 92627920005, 92627920006, 92627920007,
92627920008,92627920009,92627920010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 25.0 09/29/22 09:19
LABORATORY CONTROL SAMPLE:
3783683
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
250 100
90-110
SAMPLE DUPLICATE: 3783684
92627917001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
312
310
1 25
SAMPLE DUPLICATE: 3783685
92627920001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
Total Dissolved Solids
mg/L
50.0
52.0
4 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J22090472 ASV LF
Pace Project No.: 92627920
QC Batch: 726983 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92627920011, 92627920012, 92627920013
METHOD BLANK: 3785993
Matrix:
Water
Associated Lab Samples: 92627920011, 92627920012,
92627920013
Blank
Reporting
Parameter
Units
Result
Limit
Total Dissolved Solids
mg/L
ND
25.0
LABORATORY CONTROL SAMPLE:
3785994
Spike
LCS
Parameter
Units
Conc.
Result
Total Dissolved Solids
mg/L
250
258
SAMPLE DUPLICATE: 3785995
92627920011 Dup
Parameter Units Result Result
Total Dissolved Solids mg/L 47.0 44.0
MDL Analyzed Qualifiers
25.0 09/30/22 09:50
LCS % Rec
% Rec Limits Qualifiers
103 90-110
Max
RPD RPD Qualifiers
7 25
SAMPLE DUPLICATE: 3785996
92628383003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L ND ND 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J22090472 ASV LF
Pace Project No.: 92627920
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J22090472 ASV LF
Pace Project No.: 92627920
Lab ID Sample ID QC Batch Method QC Batch
92627920001
LF-SW-2
SM
2540C-2015
726459
92627920002
LMW-4B
SM
2540C-2015
726459
92627920003
LCS-1
SM
2540C-2015
726459
92627920004
LMW-3B
SM
2540C-2015
726459
92627920005
LF-SW-3
SM
2540C-2015
726459
92627920006
LMW-2T
SM
2540C-2015
726459
92627920007
LMW-2B
SM
2540C-2015
726459
92627920008
LMW-1S
SM
2540C-2015
726459
92627920009
LMW-1 B
SM
2540C-2015
726459
92627920010
CB-9BR
SM
2540C-2015
726459
92627920011
CB-9SL
SM
254OC-2015
726983
92627920012
CB-9
SM
254OC-2015
726983
92627920013
ASV FD-20220926-1
SM
254OC-2015
726983
Date: 10/04/2022 12:01 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical Method
Analytical
Batch
Page 23 of 27

DG# Title: ENV-FRM-HUN�1-0083 v0'1_Sle Condition Upon Receipt
f ar e arnpPage 49 of 53
Effective Date: 05/121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood [] Huntersvilleo//Raleigh❑ Mechanicsville❑ Atlantan KernersvilleF-1
Sample Condition Client Name: Upon Receipt Project WO# : 92627920
I] IlJ 1
Courier: VeE ❑UPS 5 5 ❑Client❑ Commercial / ❑Ot er: 111 ! 1 III
/ 92627920
Custody Seal Present? ❑Yes ❑No Seals Intact? []Yes No
Date/initials Person Examining Contents:
X/�
Packing Material: ❑Bubble Wrap ❑Bubble Bags ne ❑ Other Biological Tissue Froze
Thermometer:
Gun ID: qZ
Type of Ice:
Z ; 1 Correction Factor:
Cooler Temp: V Add/Subtract (°C)
Cooler Temp Corrected ('C): `.
USDA Regulated Sail (water sample)
Did samples originate in a quarantine zone within the United States: i
(check maps)? MYes MNo
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (c72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes
is Matrix: L/"
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Prpjr ct hlartager SRE Review: -
[]Yes ❑No
�Olue None
NY, or SC
No
Yes
No
J ❑N/A
6.
❑Yes
❑N/A❑N/A
s
[--]No
❑N/A
7.
❑Yes
Na
A
S.
s
[IN.
❑N/A
9.
❑Na
/A
10.
[]Yes
[]Yes
❑No
koXfA
11.
Temp should be above freezing to 6'C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rico)? ❑Yes []No
Comments/Discrenancv:
Field Data Required? ❑Yes ❑No
Lot ID of split containers:
Date/Time:
Date:
Date: -
Page 24 of 27
Qualtrax ID: 69614 Page 1 of 2

aee u(X—Title: ENV-FRM-HUN1-0083 v0l -Sample Condition Upon Receipt
Page 50 of 53
Effective Date: 05/121202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and prof WO# : 92627920
within the acceptance range for preservation samples. PM: HMG
Exceptions: VOA, Coliform, TOC, oil and Grease, DRO/8015 (waterl DOC, ttfig Du! Date:
: le/fa4/22
*"Bottom half of box is to list number of bottles CLIENT: 92—Duke Ener
***Check all unpreserved Nitrates for chlorine
V z CU
0 U u a V z
Z z Z = U 0 .J y = 2 t\
v a Z N N M c z N *v V d 2 ro M rim 2 �o
v
N v y Q 0. ? Z N x Cci
Q ro 0 ¢i
CL a c v O p ¢ m a a p a m a z = ? N v v
Q z 0 Lo a c O +� O N S N '3 `
u V IV
� u N 2 N ' N S C. 2 N 4 0 a N O C M M ; . u c n. a
lv v m'^ A a D w = Z 2 = Y W y U m m 7
a a a m ° Q m ro o E E E E a Q ¢ a Q = = = a
a CL C FL Ja E E E d E ¢ ¢ 0 o 0 D p a a' a E u E
E E E u E E E E v W v E ¢ E E 1 Ln ¢
N o - LM uQi N 3 = o °' o o E E E E m E E E E E E
# ~ N tp .-i rl r-4 r-i ry .-4 M N �0 O 0 L 0 0 O O G
E R M r ✓1 � N m LL N fv`I N Q
N N V rtl C V Ur M rl M N M 01 Gl O~i T P1 C� Y
m m m m aan m m m E7 t, 0 l9 [7 l7 Q l7 t7 0 M v FM 0 On CR
m Q ? o
a a a a a o o a 0 7
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8
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1
10
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PH Adjustment Log for Preserved Samples
Sample to Type of Preservative pH upon receipt Rate preservation adjusted Time preservation Amount of Preservative tat p
adJusted added
Note:'Wheriever there is a discrepancy affecting North Carolina compliance samples, a COPY of this form will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out Of temp, incorrect containers.
Qualtrax ID: 69614 Page 2 of 2 Page 25 of 27

Pace -vuuU V J i vaa IIVIU l4Vt lilt t l till UPUIt MUCBIP1
". Page 51 of 53
Effective Date: 05112/202205/12/2022 —
*Check mark top half of box if pH and/or dechlorination is verified and Project it
within the acceptance range for preservation samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) !]OC, Wig
"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
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PH Adjustment Log for Preserved Samples
Sample lD Type of Preservative pH upon receipt Date preservation adjusted::Trime:preservallon Amount of Preservative Lot#
justed added
Note:-WhtrTrev6rttm?,M; a tllscrepancy aT ec mg ort Nina conrplsance samples, a copy of this form will he seat to the NortirCarolina l)Et�R Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Qualtrax ID: 69614 Page 2of2 Page 26 of 27

CHAIN OF CI ISTnnV lZr-i- 1Rn Anln ANAL vcie oC'rii it=e-rcnDae
02 Zt
DUKE DukoEnegyAnalylicaiLatloratory .i._------------------------------- .--------- I.. —Anal .....a..... .....`:_._._._.__._._._._._._._._._._._.�...._._._._._._._._._._._._._._ i rclyt: oc UI O0
.4!LnMaII COG MaO]yt 18u Wi,0Mrl 'Order fl
N
ENERGY ,,.,:, sarN. Rtl i �
Malrlx WATER
e.mr —OyWmq r.a
NC Page_7_of _7
�_
! DISTRIBUTION
0
HOMuavlllr, N.C. irWl
C-7
Fagrrra24s i ilap& d BY
Date Tlma
i ORIGINAL
N
P.+: Lseraafs.gose ! !
SAMPLE PROGRAM
to LAB, COPY 10 CLIENT
__ _ _
Project Nam* ASHEVILLE STATE LF DETECTION PM1OO. Nao ive ar
MONITORING i
Client ASHLEY HEALY , BRYAN MOELLER, 13EE ip0
O'BRIEN, JOSH STOWE, CONNOR ZAHORA Pace - i
Cb61erT P�CL _
-...._.._.._.._.._. _.._.
Filtration (OAS um)
Ground
0dnkin
._.._........_.._......_........
Lt
Water _X_
Water
RCRA Waste_
_..........................................
lJntlltered
NPDES
UST_
_ i - - -
21271207,2
`----'
II Flterod
M
d
Operating UnN: AE00 P{ ----:NGRDWTR Account: _— (
Projecu AAE000315 Activity 10: Facility ID:ASV PO ` P # 9172711
Preservative
ICE ICE
Container Volume ImL]
son 300
500
Pmgnm 1 EOuiS Task Code:ASV LF Sub-Progm;P ask Cade:
Container Type
vEr PET
NDPE
— }
�
ANIONS by
Malale prep-6010b
TRM: Ba, Be, a, Cu,
c
m
Customer to complete aft appmprlafe non shaded areas. w
Sample Description Or ID '^ d
Cl.F, 9086A:
TDB 03-N(46-Hr
N
Fe, Mn, Ni, Zn
6020B IMS: Sb, As,
SAMPLEcollection Infarma0on
i
u n1,,
Hold Tlme),
504
Cd, Cr, Cc, Pb, Se,
_
1d
ER
i Date Time Printed Name
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Ag, VILL). VILL),
and Ho 747OA
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STATE EDD REQUIRED ! EQUIS REQUIRED
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' Add. Cost Will App}y
U

CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM
,Zp2 21
---------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
Duke Energy Analytical Laboratory i Analytical LaboratoryUse Onlyi Page 53 of 53
A DUKE MintCw MG03A2(Building7106) '•Order# � Matrix WATER NC_X_ Page _1 of 1_
ENERGY. 13339 Hager6 Fw yRd Mn p1i O1p1nitln°"O° SC— DISTRIBUTION
Hunler°vltle, N.C. 20070 ;Log ed By Dates Tlme SAMPLE PROGRAM ORIGINAL to LAB, COPY to CLIENT
(7") 07iZ C
F.. L741 �6ae�e ._______.__! ! Ground Water X_ NPDES
-.----- ------------.. - F..
Name ASHEVILLE STATE LF DETECTION Ph. -No: c Drinking Water_ UST
MONITORING .._.. _.._.. .._.._. Cer T�fn.P1!±1.._.._ ._.._.._.._.._.._.._.._.._.._. RCRA Waste -..............................
Client ASHLEY HEALY , BRYAN MOELLER, DEE i PO a
O'BRIEN, JOSH STOWE, CONNOR ZAHORA Pace Filtration (0.45 um) d Unfiltered b Filtered
Operating Unit: AE00 Process:NGRDWTR Account: Preservative ICE ICE
!._.._.. PO # 9171711 .._.._.._.. ! �) ._...
Project: AAE000315 Activity ID: Facility ID:ASV Container Volume mL 500 300 600
TEST R�811
Program i EQuiS Task COde:ASV LF Sub-Program/Task Code: Container Type PET PET HDPE
Metals Prep-6010D
ANIONS by
5 TRM: Be' Be, B, Cu, -
9056A: Cl, F, Fe, Mn, Ni, Zn y
Customer to complete all appropriate non -shaded areas. in . o TDS NO3-N 48-Hr U
_ Sample Description or ID 6020B IMS: Sb, As,
SAMPLE ID Collection Information Hold Time), Ctl, Cr, Co, Pb, L),
SO4 pg, TILL), VILL), e
NUMBER Data Time Printed Name Signature and Hg 7470A
Too
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_ELF SW-2
26-Z2
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7 Days
Comments
E
'Other
STATE EDD REQUIRED I EQUIS REQUIRED
•Add. Cost Will Apply
0
0
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