HomeMy WebLinkAbout20010_Sonrise Industrial_LSA Addendum_20220726Mid Atlantic
Engineering & Environmental Solutions
July 26, 2022
Mr. Tirence Horne
Upper Coastal Plain Council of Governments
121 West Nash Street
Wilson, North Carolina 27893
409 Rogers View CourC
Raleigh, NC 276 10
office 919.250,9918
facsimile 919.250.9950
MAAONLINE.COM
Subject: ADDENDUM TO LIMITED ENVIRONMENTAL SITE ASSESSMENT
REPORT
SONRISE INDUSTRIAL CENTER
(FORMER WEST POINT STEVENS ROSEMARY COMPLEX)
1200 HENRY STREET
ROANOKE RAPIDS, HALIFAX COUNTY, NORTH CAROLINA
EPA BROWNFIELDS GRANT: BF-01 D12820-0
MID -ATLANTIC JOB NO. R3641.00 T40034
Dear Mr. Horne:
We are pleased to present this Addendum to Limited Environmental Site Assessment
Report for the above -referenced site. We appreciate the opportunity to provide
environmental services to the Upper Coastal Plain Council of Governments. Please
contact me at 919-250-9918 if any questions arise or if we may be of further service.
Sincerely,
MID -ATLANTIC ASSOCIATES, INC.
Darin M. McClure, PE
Principal Engineer
Enclosure
EXPERIENCE❑ CUSTOMER FOCUSED INNOVATIVE
SONRISE INDUSTRIAL CENTER
(FORMER WEST POINT
STEVENS ROSEMARY COMPLEX)
1200 HENRY STREET
ROANOKE RAPIDS, HALIFAX COUNTY, NC
EPA BROWNFIELDS GRANT: BF-01 D12820-0
Prepared For:
Mr. Tirence Horne
Upper Coastal Plain Council of Governments
121 West Nash Street
Wilson, North Carolina 27893
Prepared By:
Mid -Atlantic Associates, Inc.
409 Rogers View Court
Raleigh, North Carolina 27610
Mid -Atlantic Job No. R3641.00 T40034
July 26, 2022
4 Atlantic
Mid Atlantic
Engineering & Environmental Solutions
409 Rogers View Court
Raleigh, NC 27610
office 9I9.250.9918
facsimile 919.250.9950
MAAONLINE.COM
SONRISE INDUSTRIAL CENTER
(FORMER WEST POINT STEVENS ROSEMARY COMPLEX)
1200 HENRY STREET
ROANOKE RAPIDS, HALIFAX COUNTY, NORTH CAROLINA
EPA BROWNFIELDS GRANT: BF-01 D12820-0
Mid -Atlantic Associates Job No. R3641.00 T40034
Prepared For:
Mr. Tirence Horne
Upper Coastal Plain Council
Of Governments
121 West Nash Street
Wilson, North Carolina 27893
July 26, 2022
Prepared By:
MID -ATLANTIC ASSOCIATES, I
i
Darin M. McClure, P.E.
Principal Engineer
-- - — - EXPERIENCED CUSTOMER FOCUSED INNOVATIVE
TABLE OF CONTENTS
DISTRIBUTION LIST
1.0 INTRODUCTION............................................................................................................... 1
2.0 SUMMARY OF FIELD ACTIVITIES.................................................................................. 1
2.1 Groundwater Assessment.................................................................................... 2
2.2 Indoor Air Sample Collection................................................................................ 2
2.3 Soil Gas SamDlina Activities.................................................................................2
2.3.1 Vapor Implant Installation Procedures............................................................ 2
2.3.2 Helium Leak Check Procedures...................................................................... 3
2.3.3 Sample Collection Procedures........................................................................ 3
3.0 SUMMARY OF LABORATORY TEST RESULTS............................................................ 3
3.1 Sub -Slab Soil Gas and Indoor Air Sample Results ............................................... 3
3.2 Risk Evaluation Methodology and Results...........................................................4
3.4 Summary and Discussion.....................................................................................5
4.0 QUALITY ASSURANCE................................................................................................... 5
4.1 Property -Specific Corrective Actions.................................................................... 5
4.2 Quality Control Parameters.................................................................................. 5
4.2.1 Precision and Accuracy............................................................................... 6
4.2.2 Representativeness.................................................................................... 6
4.2.3 Completeness............................................................................................. 7
4.2.4 Comparability.............................................................................................. 7
4.2.5 Sensitivity....................................................................................................7
4.3 Laboratory Data Evaluation.................................................................................. 7
4.3.1 Qualitative Data — Level A........................................................................... 8
4.3.2 Quantitative Data — Level B......................................................................... 8
5.0 SUMMARY AND CONCLUSIONS.................................................................................... 9
DRAWINGS
Drawing 1 Topographic Site Map
Drawing 2 Site Map and Historical Sample Locations
Drawing 3 Groundwater Table Elevation Contour Map (6/22/2022)
Drawing 4 Sample Location Map
TABLES
Table 1 Summary of Well Casing and Water Table Elevations
Table 2 Chemical Constituents Analyzed in Indoor Air and Risk Calculations
Table 3 Chemical Constituents Analyzed in Sub -Slab Soil Gas and Risk
Calculations
Table 4 Indoor Air Sample/Sample Duplicate Comparison "IA-1" and "IA-DUP"
Table 5 Soil Gas Sample/Sample Duplicate Comparison "SG-9" and "SG-
DUP"
1% Mid Atlantic
TABLE OF CONTENTS — continued
APPENDICES
Appendix A Laboratory Analytical Reports and Chain -of -Custody Records
Appendix B Risk Calculations
1% Mid Atlantic
DISTRIBUTION LIST
The following personnel will receive a copy of this report:
Agency
Number of Copies
Sara Janovitz, Brownfields Project Manager
United States Environmental Protection Agency (EPA)
Region 4, Atlanta Federal Building
Waste Management Division
1
61 Forsyth Street SW
Atlanta, GA 30303
Phone: (404) 562-9870
Email: 'anovitz.sara e a. ov
Sara Janovitz, EPA Designated Approving Official (DAO)
EPA - Region 4, Atlanta Federal Building
61 Forsyth Street Southwest
1
Atlanta, GA 30303
Phone: (404) 562-9870
Email: janovitz.sara(a�epa.gov
Sharon Eckard, Eastern District Supervisor
NC Brownfields Program, Division of Waste
Management
1
217 West Jones Street, Raleigh, North Carolina 27603
Phone: (919) 77-8294
Email: Sharon.eckard ncdenr. ov
Tirence Horne, Regional Planner
Upper Coastal Plain Council of Governments
121 W. Nash Street
1
Wilson, NC 27894
Phone: (252) 234-5966
Email: rtownle uc co .or
Darin M. McClure, Project Manager
Mid -Atlantic Associates, Inc.
409 Rogers View Court
1
Raleigh, NC 27610
Phone: (919) 250-9918
Email: dmcclure(a_maaonline.com
Daniel H. Nielsen, QA/QC Officer
Mid -Atlantic Associates, Inc.
409 Rogers View Court
Raleigh, NC 27610
1
Phone: (919) 250-9918
Email: dnielsenC@rnaaonline.com
1% Mid Atlantic
1.0 INTRODUCTION
In accordance with the Generic Quality Assurance Project Plan (QAPP) dated December 17,
2020, the Site Specific QAPP Addendum A-1 (SSQAPP) dated February 8, 2021, and the
Work Plan and Addendum to Site -Specific Quality Assurance Project Plan (Work Plan) dated
June 16, 2022, Mid -Atlantic Associates, Inc. (Mid -Atlantic) has prepared this Addendum to
Limited Environmental Site Assessment Report for the Sonrise Industrial Center site located
at 1200 Henry Street in Roanoke Rapids, North Carolina (the subject site). The Sonrise
Industrial Warehouse site contains the former WestPoint Stevens Rosemary Complex and
consists of nine contiguous parcels (54.13 acres) located between W. 10t" Street to the north,
Roanoke Avenue to the east, and W. 131" Street to the south (Drawings 1 and 2). A
recreational complex containing baseball fields is located to the west of the subject site. The
current owner of the subject site is Sonrise Reclamation, LLC (Sonrise) of Indianola,
Mississippi.
Mid -Atlantic completed a Phase I Environmental Assessment (PESA) on the subject site dated
September 30, 2014. The September 30, 2014 PESA report documented site conditions from a
visit on August 13, 2014. Three textile mills, a finishing plant, fabrication warehouse and
distribution warehouse occupied the site and were referred collectively by the last
owner/occupant (WestPoint Stevens) as the "Rosemary Complex". At the time of the most
recent field activities discussed in this report (June 2022), the subject site was vacant.
The September 30, 2014 PESA report prepared by Mid -Atlantic identified multiple Recognized
Environmental Conditions (RECs) which were investigated as described in the March 7, 2016
Limited Environmental Site Assessment (2016 LSA) and July 8, 2021 Limited Environmental
Site Assessment Report dated (2021 LSA).
Both assessments identified environmental impacts to groundwater including the presence of
chlorinated solvents 1, 1, 1 -Trichloroethane (TCA), perch loroethylene (PCE), and their respective
degradation compounds. The 2021 LSA notes that these compounds have been detected at
concentrations above their respective NC Groundwater Quality Standard (NCGQS), Residential
Vapor Intrusion Screening Levels (VISLs) and/or Non -Residential VISLs at multiple locations.
Historical sampling locations are shown on Drawing 2.
Because multiple residences/receptors are located adjacent to the subject site, the NC
Brownfields Program requested that the groundwater monitoring network at the subject site be
evaluated to confirm groundwater flow conditions at the site. In addition, the NC Brownfields
Program requested that a paired indoor air and sub -slab soil gas sample be collected in a former
machine shop area located inside the former distribution warehouse located adjacent to
monitoring well MW-8.
2.0 SUMMARY OF FIELD ACTIVITIES
To confirm groundwater flow conditions at the subject site and assess indoor air and sub -slab
soil gas, Mid -Atlantic gauged depth to water at the wells comprising the monitoring well
network and collected a paired indoor air and sub -slab soil gas sample in the former machine
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shop. The location of the former machine shop was confirmed using signage inside the former
distribution warehouse and photographs collected during the Phase I.
2.1 Groundwater Assessment
Mid -Atlantic personnel surveyed the top of casing (TOC) elevations relative to wells as part
of the 2016 and 2021 LSAs. Prior to measuring depth to groundwater in the monitoring wells,
Mid -Atlantic removed the well caps and allowed groundwater levels to equilibrate for 1-2
hours. Depth to groundwater was measured on June 22, 2022 and groundwater was
encountered at depths ranging from approximately 11 to 30 feet BLS (Table 1). Using the
survey elevations and water level measurements from June 22, 2022 an estimated
groundwater table elevation contour map was prepared for the site and is provided as Drawing
3. As shown, the estimated groundwater flow direction at the site was determined to be
generally to the south-southeast, towards a dry valley shown on the topographic map with
Chockoyotte Creek located further south (Drawing 1).
2.2 Indoor Air Sample Collection
An 8-hour indoor air sample (IA-1) and duplicate (IA-DUP) were collected inside the former
machine shop. The approximate sample location is shown on Drawing 4. The indoor air sample
and duplicate were placed on boxes so the sample was collected approximately four feet above
the ground. The samples were collected in general accordance with the DWM Vapor Intrusion
Guidance dated March 2018 and the aforementioned QAPPs. The samples were collected on
June 22, 2022 using individually -certified 6-liter stainless steel Summa canisters at a maximum
flow rate of 8-10 ml/min. Outdoor temperatures were in the mid-70s (F) at the start of the
sampling and peaked in the mid-90s (F). The skies were mostly sunny and there was a light
breeze. After collection, the indoor air samples were provided to a courier affiliated with Waypoint
under proper chain of custody for analysis. The canisters were analyzed for VOCs in accordance
with EPA Method TO-15.
2.3 Soil Gas Sampling Activities
2.3.1 Vapor Implant Installation Procedures
Following indoor air sample collection, Mid -Atlantic installed and sampled an interior sub -slab
soil gas sampling point and duplicate (SG-9 and SG-DUP) to evaluate soil gas quality beneath
the former machine shop. To create a sub -slab sampling port, a rotary -impact drill equipped with
a decontaminated spline drill bit was utilized to drill a 5/8-inch diameter hole through the concrete
slabs. The concrete slab was approximately 6 to 8 inches thick. Mid -Atlantic observed what
appeared to be soil after puncturing through the concrete slab. Upon completion, a vapor
sampling probe was established using a new "Vapor Pin TM" which utilizes a brass barb fitting
with a silicone sleeve to create a seal with the concrete when inserted using an
installation/extraction tool. The vapor pin was then fitted with'/4-inch outer diameter Teflon -lined
tubing to complete the vapor sampling probe assembly.
1% Mid Atlantic
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2.3.2 Helium Leak Check Procedures
Upon completion of sample point construction activities, the points were purged and a leak
check was performed at each probe location using a plastic shroud, helium gas, and a portable
helium gas detector. A plastic shroud was placed over the entire sampling train of each soil gas
sampling location. Helium was released into the shroud via tubing from the cylinder into the
shroud, and a grab sample was collected by filling a Tedlar bag using the exhaust port of the
purge syringe. Helium was not detected within the Tedlar bag at a concentration exceeding
DEQ's acceptable guideline of ten percent of the helium concentration under the plastic shroud
at the sampling locations. As such, leaks were not detected prior to soil gas sample collection.
The results of Mid -Atlantic's helium leak checks at each sample location are as follows:
Helium Concentration Under
ium Concentration
Sample ID
Shroud
in Tedlar Bag
SG-9
31.0 %
0 PPM
SG-DUP
22.9 %
0 PPM
Note: 1 % = 10,000 PPM
2.3.3 Sample Collection Procedures
Sub -slab soil gas samples SG-9 and SG-DUP were collected using a 1-liter stainless steel
canister at a maximum flow rate of 200 milliliters per minute (ml/min) after performing the helium
leak check. Upon collection, the soil gas samples were provided to a courier affiliated with
Waypoint under proper chain of custody for analysis of VOCs according to EPA Method TO-
15.
3.0 SUMMARY OF LABORATORY TEST RESULTS
The laboratory analytical report and chain -of -custody records for the sub slab soil gas and indoor
air samples collected at the site are provided in Appendix A. Laboratory results from indoor air
and soil gas samples are summarized in Tables 2 and 3, respectively.
3.1 Sub -Slab Soil Gas and Indoor Air Sample Results
Indoor air and sub slab soil gas sample results were compared to the Soil Gas Screening
Levels (SGSLs) and Indoor Air Screening Levels (IASLs) January 2022 tables respectively.
As summarized on Table 2, two constituents, chloroform and naphthalene, were detected
above their respective Residential and Non -Residential IASLs in indoor air at estimated
concentrations. Other indoor air constituents were detected above their MDLs, but not at
concentrations above their respective Residential/Non-Residential IASLs.
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As summarized in Table 3, soil gas constituents were not detected at concentrations
exceeding Residential and/or Non -Residential SGSLs.
3.2 Risk Evaluation Methodology and Results
The cumulative risk is calculated by entering the maximum concentrations of all contaminants
detected at each established exposure unit (EU) into the DEQ Risk Calculator. An EU is a
defined area of a site represented by a specific set of land use(s), receptors, contaminant
concentrations, and exposure pathways.' The soil gas sample and indoor air sample (and their
respective duplicates) were treated as their own EU. Information regarding the specific EUs is
described in the table below:
SG-9 and SG-DUP Machine Shop Soil Gas
IA-1 and IA-DUP Machine Shop Indoor Air
The DEQ Risk Calculator determines the cancer risk sum for all carcinogens and the cumulative
hazard index for all non -carcinogens. The DWM allows a maximum cancer risk sum for all
carcinogens of 1.0E-04 and a maximum non -carcinogenic hazard index of 1.0E+00. The hazard
index is the sum of the hazard quotient (HQs) calculated for each compound detected. The
NCDEQ risk calculations for the subject site are included in Appendix B. As noted in Section
4.2.5, eight analytes in IA-1 and IA-DUP had MDLs above their respective SGSLs/IASLs. As
such, risk calculations for soil gas and indoor air included the MDL of the analyte in undiluted
samples.
The results of the risk evaluations for IA-1/IA-DUP are summarized on Table 2. Under a
residential exposure scenario, the non -carcinogenic hazard index was above the target value at
1.4E+00 while the target value for the cancer risk sum (1.0E-04) was not exceeded at 6.3E-05.
Under a non-residential exposure scenario, neither the non -carcinogenic hazard index or the
cancer risk sum were exceeded. When the eight compounds with MDLs above their respective
IASLs are not considered in risk calculations, the non -carcinogenic hazard index becomes 1.6E-
05 and the cancer risk sum was 6.6E-01, both of which are below their respective target values
under a residential exposure scenario.
The results of the risk evaluations for soil gas samples are summarized on Table 3. Under a
residential exposure scenario, the non -carcinogenic hazard index was below the target value
(1.0E+00) at 4.1 E-02 and the target value for the cancer risk sum (1.0E-04) was not exceeded
at 1.0E-06. Under a non-residential exposure scenario, neither the non -carcinogenic hazard
index or the cancer risk sum were exceeded. Risk calculations are provided in Appendix B.
NCDEQ Technical Guidance for Risk -Based Environmental Remediation of Sites. March 2017. Page 40
Mid Atlantic
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1200 Henry Street
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3.4 Summary and Discussion
Depth to groundwater measurements collected as part of this assessment and the estimated
groundwater flow direction are consistent with the findings of the 2016 and 2021 LSAs with a
dominant southward component to groundwater flow. Based on the analytical results from
soil gas and indoor air testing, there is no evidence of a release to the environment originating
at the machine shop or an exposure risk to vapors in a non-residential scenario. However,
historical groundwater sampling at well MW-8 (located directly downgradient of the machine
shop) in 2016 exhibited a concentration of PCE just below its NC Groundwater Quality
Standard (0.7 ug/L versus a detection of 0.68 ug/L).
4.0 QUALITY ASSURANCE
The QAPP and the SSQAPP set forth the procedures and methods for data collection, and
defined the specific procedures and adjustments necessary to maintain data quality to support
the project decision. This Addendum to Limited Environmental Site Assessment (ESA) requires
both field and laboratory checks to monitor conformance to project quality limits.
4.1 Property -Specific Corrective Actions
The investigation field methods were reviewed during the data verification audit discussed in the
next paragraph. The field methods used were consistent with the EPAs guidelines included in
Appendices D and E of the QAPP (note that the SSQAPP referenced the QAPP for field
procedures) with the following exceptions:
• Field equipment was calibrated by the rental equipment supplier prior to use by Mid -
Atlantic personnel.
Data verification and data validation audits were completed by Mid -Atlantic before this report
was prepared. In addition to the items listed above, the following deficiencies were discovered
that were related to the laboratory testing program:
The method detection limits for the indoor air exceeded the Residential and/or Non -
Residential IASLs for eight indoor air constituents not detected in indoor air. These
include benzyl chloride, bromodichloromethane, 1,3-butadiene, 1,2-dichloroethane, 1,2-
dibromoethane, hexachlorobutadiene, 1,1,2,2-tetrachloroethane, 1,1,2-trichloroethane.
4.2 Quality Control Parameters
To assess whether quality assurance objectives for this project have been achieved, the
following QC parameters were considered: precision, accuracy, representativeness,
comparability, completeness and sensitivity.
Mid Atlantic
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4.2.1 Precision and Accuracy
As described in the QAPP, precision is evaluated using the relative percent difference (RPD)
between an actual sample and a duplicate sample. In accordance with the SSQAPP Addendum,
a duplicate indoor air sample and a sub -slab soil gas sample were collected during field
activities. A comparison of the detected concentrations for the primary sample and the
associated duplicate sample was made to evaluate the reproducibility of the sample results
based on the laboratory analysis and sample collection and transportation procedures. The
variability of the results for the primary and duplicates sample were evaluated by calculating the
RPD and percent ratio for each analyte among the duplicate pair using the formula below
RPD = [(x,-xjlx]X100% Where:
x, = concentration of sample 1 of pair,
x2 = concentration of sample 2 of pair, and
x = average of sample 1 and sample 2.
RPD percentages <35% indicate "good/acceptable" variability, a %RPD >35% but < 50%
indicated that the variability was "slightly high", and a %RPD >50% indicated a "high" degree of
variability.
Soil Gas/Indoor Air Samples
Of the 13 indoor air constituents detected in primary indoor air sample IA-1 and/or its duplicate,
IA-DUP, three were detected above their respective RLs in both samples (acetone,
dichlorodifluoromethane, and tetrachloroethylene). Precision was determined to be acceptable
for the indoor air constituents detected in IA-1 and IA-DUP (Table 4).
Of the 26 indoor air constituents detected in primary soil gas sample SG-9 and/or its duplicate,
SG-DUP, nine were detected above their respective RLs in both samples (acetone, 2-butanone,
dichlorodifluoromethane, heptane, isopropanol, propene, tetrachloroethylene, toluene, and m&p
xylene). Precision was determined to be acceptable for six of the compounds, slightly high for
two of the compounds (2-butanone and heptane), and high for propene (Table 5).
Accu racy
Accuracy is evaluated using a percent recovery measured in spiked and unspiked samples.
Accuracy is a function of the laboratory method, and parameters regarding accuracy are
included in the lab reports provided in Appendix A.
4.2.2 Representativeness
Mid -Atlantic has evaluated the representativeness of the limited ESA activities to document the
degree to which the sample data accurately and precisely represents a characteristic of a
Mid Atlantic
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population, parameter variations at a sampling point, or an environmental condition. Review of
field methods and procedures indicated that sample collection, handling and transportation were
conducted in accordance with the QAPP and SSQAPP. Review of analytical results indicates
that the analytical data is generally uniform and consistent between sampling points.
4.2.3 Completeness
Soil Gas/Indoor Air: A total of 4 soil gas/indoor air samples were submitted for analysis for
VOCs by EPA Compendium Method TO-15 in accordance with the Work Plan. Completeness
for the testing specified in the Work Plan was 100% for VOCs.
4.2.4 Comparability
To produce comparable data, the units specified for analytical results obtained during the field
activities are consistent throughout this project. The soil gas and indoor air concentrations used
in the report tables are similar to the units included in the State and EPA action level tables that
are used for comparison. Standardized analytical methods have been used for each parameter.
4.2.5 Sensitivity
Laboratory quantitation limits (the reporting limit and/or MDL) for soil gas and indoor air samples
were sufficient to report concentrations below the action levels in undiluted samples. Exceptions
to this are noted below:
Indoor Air
The method detection limits for the indoor air exceeded the Residential IASLs for eight indoor
air constituents that were not detected. These include benzyl chloride, bromodichloromethane,
1,3-butadiene, 1,2-dibromoethane, 1,2-dichloroethane, hexachlorobutadiene, 1,1,2,2-
tetrachloroethane, and 1,1,2-trichloroethane. One of these compounds, 1,2-dibromoethane, had
an MDL that exceeded its Non -Residential IASL. For the purpose of risk evaluation and
comparison, risk calculations were performed with, and without, the MDLs of the compounds
above.
4.3 Laboratory Data Evaluation
The laboratories completed validation and verification of laboratory processes and data, and
delivered laboratory reports to the Mid -Atlantic Project Manager. The laboratory reports and the
QC information contained therein documents compliance to the QAPP.
The following qualifiers were used by the laboratories in the reports when presenting data for
the samples and QA/QC samples collected by Mid -Atlantic:
"J" — Result is an estimated concentration (J-Flag).
Mid Atlantic
Addendum to Limited Environmental Site Assessment Report July 26, 2022
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"<" — Not detected at or above the method detection limit (MDL).
Data usability determination is also a part of data evaluation. After data validity has been
assessed, that is, the analytical data has been reviewed and qualifier codes have been applied,
these data were individually identified and assessed for usability. Sample data (both with and
without qualifier codes) may be generally spoken of as either qualitative (Level A), quantitative
(Level B), or unusable. Within any matrix it is likely certain samples may have parameters that
require qualifier codes. A discussion of these qualifier codes for each level is provided below.
4.3.1 Qualitative Data — Level A
Qualitative data are often referred to as Level A data. All screening data is considered Level A
data. Screening data may not be considered as Level B data and cannot be used to make site
management decisions. Data in this level also include "J" coded data. These data are considered
to be an estimated quantity, i.e., a presence or absence value. Data having been given a "J"
code were not automatically classified as qualitative data only; these data were considered as
Level B (quantitative) data depending on bias, and were evaluated on a case by case basis.
Data reported with a "NY code or marked with a "<" symbol can also be classified as Level B
data provided the detection limit was not above an applicable regulatory action level for that
analyte. All analytical data received as part of the analytical package for this site were accepted
as Level A data.
Some results for indoor air analytes with MDLs above applicable action levels and listed as not
detected must be considered as Level A data. These analytes are listed in Section 4.2.5.
4.3.2 Quantitative Data — Level B
Data at this level are referred to as Level B data. Only data meeting all field and analytical data
usability requirements may be classified as Level B data. This means all quality assurance
parameters have been satisfied, including quality control and quality assessment. Only data
that were found to be analytically valid and passed all criteria for Level A were considered for
classification at Level B. These data are considered definitive and may be used for any purpose.
Based on information provided in the laboratory reports, laboratory tests were performed within
the appropriate holding times. Except for items noted in Section 4.3.1, detected analytes in all
samples which were both above the MDL and RL and are accepted as Level B data.
In reviewing the laboratory reports, multiple analytes were reported as detections with "J" data
qualifiers, indicating the reported value is an estimate. These compounds (J value) were
detected above the MDL, but below the RL. The MDL is the lowest concentration at which an
analyte can be detected in a sample by the particular laboratory method used. "Detected"
indicates that the analyte can be distinguished from the blank with reasonable certainty. The
RL is approximately five times the MDL or the lower calibration standard, whichever is higher.
Results above the RL can be distinguished from the blank and fall within applicable standard
Mid Atlantic
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curves. For the purposes of this assessment, "J value" qualified data are considered acceptable
for making site management decisions as these data are not the sole determinant of "clean."
These data are accepted as Level B data.
5.0 SUMMARY AND CONCLUSIONS
Sonrise Reclamation, LLC owns the subject property and may sell the property in the future
to a potential buyer. The objective of this assessment was to further assess the historical use
of the subject site and to assess whether contaminants are present at levels that may be an
impediment to future redevelopment. Mid -Atlantic offers the following conclusions based on
the results of this assessment as they pertain to redevelopment:
Groundwater flow below the site is to the south-southeast towards a topographic low
area of the property and a "dry" stream valley that has been backfilled over time on
the Sonrise Industrial Center and the adjacent Panda co -generation facility (Dominion
Power) site. A perennial steam, Chockoyotte Creek, is located approximately 1,500
feet to the south. This groundwater flow direction is consistent with historical
assessments performed at the site.
Soil gas constituents were not detected above their Residential and/or Non -
Residential SGSLs. This suggests that a release has not occurred in the vicinity of
the former machine shop.
Indoor air sample IA-1 and its duplicate (IA-DUP) did not exhibit detectable
constituents at concentrations that exceeded their respective residential or non-
residential IASLs. Because the MDLs for these samples exceeded the IASL for
multiple constituents, a set of risk calculations were performed that included the MDLs
of these compounds (i.e. considered these compounds to be present at their MDLs
as a very conservative measure and compounds reported at estimated
concentrations). With these compounds included at concentrations equal to their
respective MDLs, the cancer risk sum and non -carcinogenic hazard index were
exceeded under a residential scenario, but not in a non-residential scenario. When
these compounds are not assumed present, neither the cancer risk sum or non -
carcinogenic hazard index are exceeded in either scenario.
Based on the data collected to date, it does not appear that contaminants present at the site
pose an unacceptable risk for a non-residential redevelopment/use. Additional assessment,
remedial action, and/or engineering/institutional controls may be necessary to facilitate a
more sensitive use (i.e. residential, etc.). Mid -Atlantic recommends that a copy of this report
be submitted to the NCBP for their review as they prepare the draft Brownfields Agreement
for this site.
Mid Atlantic
DRAWINGS
1% Mid Atlantic
a
REFERENCES:
1. PROPERTY LINES FROM HALIFAX CO. GIS, MAY 2013.
2. ROANOKE RAPIDS, NC DIGITAL RASTER GRAPHIC, USGS. SCANNED FROM
1:24,000-SCALE ROANOKE RAPIDS, NC TOPOGRAPHIC MAP, 2013, USGS.
3. INSET MAP DIGITAL DATA FROM BUREAU OF TRANSPORTATION 0
STATISTICS, WASHINGTON, D.C.
SCALE: 1:12,000
500 1,000
Feet
2,000
TOPOGRAPHIC SITE MAP DRAWN DATE:
SONRISE INDUSTRIAL CENTER BY: FEBRUARY2016
Ift
DRAFT JOB NO:
Mid Atlantic (FORMER WESTPOINT STEVENS CHECK: R2298.02 T4115
Englneering& Enrirvnmencal Svlucivns ROSEMARY COMPLEX ENG. GIS NO:
ROANOKE RAPIDS, CHECK: 1G-R2298.02T4115-5
NORTH CAROLINA APPROVAL: UEA I DWG NO: 1
Y
i rl; Alit 1
fix
I
411
.
MILL 144,
'c
Mw-10
ST014G
SG-6-*
El®
OFFICE
SS-2 SS-1/MW-11
O
CS-1
ZZ
/d �►;
A ,•� _
'�
(Dup-2)
x .
MW-9
/
-
B1/MW-1 '
w
a
a. MILL 5 r
Ej
DELTA 4 ❑
'"' "'FIINISHING PLANT SS-7
MILL 3 B2/MW-2
❑mwf,1,3 r
`....i SG-8
IA7 owl
SS-13/
'FABRICATING MW._1,7.(Dup-1) SS-9
DISTRIBUTION PLANT I
< � B5/MW-5
~- WARE HO E—>� MILL 2
:.. SG-1 SG-5
9
jj& (Dup-2) ❑
SS-8 SG-7
FABRICATING; ss-6
PLANT ANNEX (Dup-1) �_! 1, J ❑ SS-4 i
SG-V` L/MW-4
SS-5
SG-2 k_mv
14eSS-12.
�_. B6/MW-6 .
r - B8/MW-8 B3/Mw-3
SG-3` '` SW-1 (Dup-2)
SS-10/ v►� l�
\' = MW-16
I_ r
01
} I r 1
LEGEND-
_. - REFERENCES:
MONITORING WELL 1. BUILDING REFERENCES (IN YELLOW) FROM STORM WATER POLLUTION
❑ SOIL SAMPLE LOCATION
} PREVENTION PLAN, THE BIBB COMPANY ROSEMARY COMPLEX,
FEBRUARY 1996.
❑ SURFACE WATER AND SEDIMENT SAMPLE LOCATION 2. 1970s FACILITY PLAN FROM WESTPOINT STEVENS.
f 3.1997 FINISHING PLANT RENOVATION DRAWINGS FROM WESTPOINT
® SOIL AND GROUNDWATER SAMPLE LOCATIONS STEVENS.
- HISTORICAL SOIL GAS SAMPLE LOCATION 4. HISTORICAL SAMPLING LOCATIONS FROM LIMITED ENVIRONMENTAL
SITE ASSESSMENT REPORTS FOR SONRISE INDUSTRIAL WAREHOUSE BY
❑ PCB SAMPLE LOCATION MID -ATLANTIC. DATED MARCH 7, 2016 AND JULY 8, 2021
O CRAWLSPACE SAMPLE LOCATION 0 Feet
ROSEMARY COMPLEX BUILDINGS (1996) 0 200 400 600 800
C SUBJECT SITE SCALE: 101,800
�NCC,rNC9�11 Board
DRAWN DATE:
SITE MAP AND HISTORICAL SAMPLE LOCATIONS BY: KRC JULY 2022
SONRISE INDUSTRIAL CENTER DRAFT JOB NO:
Mid Atlantic ROANOKE RAPIDS CHECK: DMM R3641.00
Engineering &Environmental Solutions �
NORTH CAROLINA ENG. GIS NO:
CHECK: DMM 03G-R3641.00-2
APPROVAL: DMM DWG NO: 2
'1
M� r
id
N 4 AW—'
1�
f• ` `. A
T -41
- � MW-9
, wr
7.
MW-10 74.0 ,�
(74.44) ti f
(7,415)
MW-1
(74.10)
-M
(r73.70>
r MW-13 r it
MW-17
(73.84) ,rq
MW;5 73.0
% • (7312)
(
�_ � � 73.41)
, 1 i. 7r25 q
_ (73.20) MW-12
MW-8 — — _ I T.. (72165)
'< (73.28) MW-3 j
MW-7 — (72.76)t
=! MAW-15 (72.76j `
�• y:►�,
.95
73,4 y�
Ak
.i r`. r ,�► t A,s1►�:.,� ;72.5 y / � � •r •'„wf�' � , � , • .
(72.13) • A
� � ;1 • • 1 x• r n. � r
`) r�,�+��,,,,��••���► +I � r'i ��Ir ;,�y r •� fit: •�` y� r '�As; � - - �r. � �.. I� � !
it rtr •� "t . I r` Jj� . � �,.
t
it
Ath
mo
It
' a Feet
0 200 400 600 800
SCALE: 1:1)800
Source: Esri, M �rt= ar, EaGeographics, and the rGIS User Comrn'ianity
DRAWN DATE:
GROUNDWATER TABLE ELEVATION BY: KRC JUNE 2022
Mid Atlantic
Engineering & Environmental Solutions
CONTOUR MAP (6/22/2022)
SONRISE INDUSTRIAL CENTER
ROANOKE RAPIDS,
NORTH CAROLI NA
9
�^ r4
am -
I
DISTRIBUTION
WAREHOUSE
R
VIA** 11
FINISHING PLANT
iBRICATING
PLANT
SG-10
��� =ram• �/
. I
FABRICATING .
PLANT ANNEX
LEGEND
0 PAIRED INDOOR AIR AND SUB -SLAB SOIL GAS SAMPLE
Q HISTORICAL SOIL GAS SAMPLE LOCATION
MONITORING WELL
ROSEMARY COMPLEX BUILDINGS (1996)
E SUBJECT SITE
Mid Atlantic
Engineering & Environmental Solutions
AN5
I
SG-30
FORM WATER POLLUTION
EMARY COMPLEX,
I LUI \lJ ll1 \ I I JJu.
2. 1970s FACILITY PLAN FROM WESTPOINT STEVENS.
3.1997 FINISHING PLANT RENOVATION DRAWINGS FROM WESTPOINT
STEVENS.
4. HISTORICAL SAMPLING LOCATIONS FROM LIMITED ENVIRONMENTAL
SITE ASSESSMENT REPORTS FOR SONRISE INDUSTRIAL WAREHOUSE BY
MID -ATLANTIC. DATED MARCH 7, 2016 AND JULY 8, 2021
SAMPLE LOCATION MAP
SONRISE INDUSTRIAL CENTER
ROANOKE RAPIDS,
NORTH CAROLI NA
Feet
0 50 100 150 200
SCALE: 1:600
NCCGIA, NC911 Board
DRAWN DATE:
BY: KRC J U LY 2022
DRAFT JOB NO:
CHECK: DMM R3641.00
ENG. GIS NO:
CHECK: DMM 03G-R3641.00-IA
APPROVAL: DMM DWG NO: 4
TABLES
1% Mid Atlantic
TABLE 1
SUMMARY OF WELL CASING AND WATER TABLE ELEVATIONS
SONRISE INDUSTRIAL CENTER
1200 HENRY STREET
ROANOKE RAPIDS, NORTH CAROLINA
MID -ATLANTIC JOB NO. R3641.00 T40034
WELL ID
TOC ELEVATION
(FEET)
DEPTH TO WATER
JUNE 22, 2022 (FEET
BELOW TOC)
GROUNDWATER
TABLE ELEVATION
JUNE 22, 2022
MW-1
103.71
29.61
74.10
MW-2
101.89
28.19
73.70
MW-3
103.05
30.29
72.76
MW-4
95.00
21.59
73.41
MW-5
99.02
25.60
73.42
M W -6
84.74
11.54
73.20
MW-7
88.50
15.23
73.27
MW-8
95.60
22.32
73.28
MW-9
100.78
26.14
74.64
MW-10
104.27
29.83
74.44
MW-11
103.35
29.20
74.15
MW-12
99.48
26.83
72.65
MW-13
98.77
25.01
73.76
MW-14
88.15
16.02
72.13
MW-15
93.62
20.67
72.95
MW-16
90.15
17.39
72.76
MW-17
96.46
22.62
73.84
Notes:
BLS - Below Land Surface
TOC - Top of Casing
TABLE 2
CHEMICAL CONSTITUENTS ANALYZED IN INDOOR AIR AND RISK CALCULATIONS
SONRISE INDUSTRIAL CENTER
1200 HENRY STREET
ROANOKE RAPIDS, NORTH CAROLINA
MID -ATLANTIC JOB NO. R3641.00
Sample ID
IA-1
IA-DUP
Greatest
Concentration
NCDEQ DWM Residential Indoor
Air
Screening Levels
January 2022 (ug/m3)
NCDEQ DWM Non -Residential
Indoor Air
Screening Levels
January 2022 (ug/m3)
Sampling Date
6/22/2022
6/22/2022
Acetone
5.75
4.97
5.75
NE
NE
Benzene
0.310 J
0.323 J
0.323 J
0.36
1.6
Benzyl Chloride*
<0.148
<0.148
0.148
0.057
0.25
Bromodichloromethane*
<0.150
<0.150
0.150
0.076
0.33
Bromoform
<0.153
<0.153
ND
2.6
11
Bromomethane
<0.115
<0.115
ND
1.0
4.4
1,3-Butadiene*
<0.328
<0.328
0.328
0.094
0.41
2-Butanone (MEK)
1.02 J
0.958 J
1.02 J
1000
4400
Carbon Disulfide
0.504 J
<0.0608
0.504 J
150
610
Carbon Tetrachloride
<0.155
<0.155
ND
0.47
2.0
Chlorobenzene
<0.107
<0.107
ND
10
44
Chloroethane
<0.164
<0.164
NO
830
3500
Chloroform
0.718 J
<0.0864
0.718 J
0.12
0.53
Chloromethane
<0.0673
<0.0673
ND
19
79
Cyclohexane
<0.161
<0.161
ND
1300
5300
Dibromochloromethane
<0.208
<0.208
ND
NE
NE
1,2-Dibromoethane (EDB)*
<0.151
<0.151
0.151
0.0047
0.02
1,2-Dichlorobenzene
<0.0963
<0.0963
ND
42
180
1,3-Dichlorobenzene
<0.174
<0.174
ND
NE
NE
1,4-Dichlorobenzene
<0.186
<0.186
ND
0.26
1.1
Dichlorodifluoromethane (Freon
121
2.70
2.60
2.70
21
88
1,1-Dichloroethane
<0.101
<0.101
ND
1.8
7.7
1,2-Dichloroethane*
<0.129
<0.129
0.129
0.11
0.47
1,1-Dichloroethylene
<0.107
<0.107
ND
42
180
cis-1,2-Dichloroethylene
0.333 J
<0.0955
0.333 J
NE
NE
trans-1,2-Dichloroethylene
<0.108
<0.108
ND
8.3
35
1,2-Dichloropropane
<0.205
<0.205
ND
0.76
3.3
cis-1,3-Dichloropropene
<0.178
<0.178
ND
NE
NE
trans-1,3-Dichloropropene
<0.178
<0.178
ND
NE
NE
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (Freon 114)
<0.623
<0.623
ND
NE
NE
1,4-Dioxane
<0.435
<0.435
ND
0.56
2.5
Ethyl Acetate
<0.136
<0.136
ND
15
61
Ethylbenzene
<0.106
<0.106
ND
1.1
4.9
4-Ethyltoluene
<0.128
<0.128
ND
NE
NE
Heptane
<0.143
<0.143
ND
83
350
Hexachlorobutadiene*
<0.330
<0.330
0.330
0.13
0.56
Hexane
<0.0472
<0.0472
ND
150
610
2-Hexanone (MBK)
<0.285
<0.285
NO
6.3
26
Isopropanol
<0.139
0.846 J
0.846 J
42
180
Methyl tert-Butyl Ether (MTBE)
<0.0336
<0.0336
NO
11
47
Methylene Chloride
0.580 J
0.493 J
0.580 J
100
530
4-Methyl-2-pentanone (MIBK)
<0.121
<0.121
ND
630
2600
Naphthalene
0.598 J
0.571 J
0.598 J
0.083
0.36
Propene
<0.242
<0.242
NO
630
2600
Styrene
<0.124
<0.124
ND
210
880
1,1,2,2-Tetrachloroethane*
<0.104
<0.104
0.104
0.048
0.21
Tetrachloroethylene
6.61
4.00
6.61
8.3
35
Tetrahydrofuran
<0.107
<0.107
ND
420
1800
Toluene
1.30 J
1.10 J
1.30 J
1000
4400
1,2,4-Trichlorobenzene
<0.209
<0.209
NO
0.42
1.8
1,1,1-Trichloroethane
<0.144
<0.144
NO
1000
4400
1,1,2-Trichloroethane*
<0.0877
<0.0877
0.0877
0.042
0.18
Trichloroethylene
0.537 J
<0.199
0.537 J
0.42
1.8
Trichlorofluoromethane (Freon
11)
1.84 J
1.84 J
1.84 J
NE
NE
1,1,2-Trichloro-1,2,2-
trifluoroethane (Freon 113)
<0.561
<0.561
NO
1000
4400
1,2,4-Trimethylbenzene
<0.110
<0.110
NO
13
53
1,3,5-Trimethylbenzene
<0.236
<0.236
NO
13
53
Vinyl Acetate
<0.224
<0.224
NO
42
180
Vinyl Chloride
<0.127
<0.127
ND
0.17
2.8
m&p-Xylene
<0.217
<0.217
ND
21
88
o-Xylene
<0.157
<0.157
ND
21
88
RESIDENTIAL RISK CALCULATIONS SUMMARY
Acceptable Carcinogenic
Sum Risk Range and Maximum Non -Cancer Hazard Index
Calculated Sample Cancer Risk
Sum
6.2E-05
1.0 E-04
Calculated Sample Non-
Carcinogenic Hazard Index
1.4E+00
HI=1
NON-RESIDENTIAL RISK CALCULATIONS SUMMARY
Acceptable Carcinogenic
Sum Risk Range and Maximum Non -Cancer Hazard Index
Calculated Sample Cancer Risk
Sum
1.4E-05
1.0 E-04
Calculated Sample Non-
Carcinogenic Hazard Index
2.4E-01
HI=1
Notes:
Concentration units; ug/m3
J = Estimated Concentration
NE = Not Established
* = Compound was not detected, but had a lab method detection limit over the Residential SGSL. For the purpose of risk evaluation, concentrations of this
compound equal to its MDL were assumed.
Bolded concentrations exceed the Residential Indoor Air Screeninq Level
Shaded concentrations exceed the Non -Residential Indoor Air Screening Level
<0.34 = Not detected above the lab method detection limit
TABLE 3
CHEMICAL CONSTITUENTS ANALYZED IN SUB -SLAB SOIL GAS AND RISK CALCULATIONS
SONRISE INDUSTRIAL CENTER
1200 HENRY STREET
ROANOKE RAPIDS, NORTH CAROLINA
MID -ATLANTIC JOB NO. R3641.00
Sample ID
SG-9
SG-DUP
Greatest
Concentration
NCDEQ DWM Residential Soil
Gas
Screening Levels
January 2022 (ug/m3)
NCDEQ DWM Non -Residential Soil
Gas
Screening Levels
January 2022 (ug/m3)
Sampling Date
6/22/2022
6/22/2022
Acetone
65.3
51.0
65.3
NE
NE
Benzene
1.92
1.34 J
1.92
12
160
Benzyl Chloride
<0.148
<0.148
ND
1.9
25
Bromodichloromethane
<0.150
<0.150
ND
2.5
33
Bromoform
<0.153
<0.153
ND
85
1100
Bromomethane
<0.115
<0.115
ND
35
440
1,3-Butadiene
0.785 J
<0.328
0.785 J
3.1
41
2-Butanone (MEK)
9.75
7.01
9.75
35000
440000
Carbon Disulfide
1.35 J
1.80 J
1.80 J
4900
61000
Carbon Tetrachloride
<0.155
<0.155
ND
16
200
Chlorobenzene
<0.107
<0.107
ND
350
4400
Chloroethane
<0.164
<0.164
ND
28000
350000
Chloroform
1.16 J
1.00 J
1.16 J
4.1
53
Chloromethane
<0.0673
<0.0673
ND
630
7900
Cyclohexane
<0.161
<0.161
ND
42000
530000
Dibromochloromethane
<0.208
<0.208
ND
NE
NE
1,2-Dibromoethane (EDB)
<0.151
<0.151
ND
0.16
2.0
1,2-Dichlorobenzene
<0.0963
<0.0963
ND
1400
18000
1,3-Dichlorobenzene
0.577 J
0.535 J
0.577 J
NE
NE
1,4-Dichlorobenzene
<0.186
<0.186
ND
8.5
110
Dichlorodifluoromethane (Freon
12)
2.90
3.11
3.11
700
8800
1,1-Dichloroethane
<0.101
<0.101
ND
58
770
1,2-Dichloroethane
<0.129
<0.129
ND
3.6
47
1,1-Dichloroethylene
<0.107
<0.107
ND
1400
18000
cis-1,2-Dichloroethylene
<0.0955
<0.0955
ND
NE
NE
trans-1,2-Dichloroethylene
<0.108
<0.108
ND
280
3500
1,2-Dichloropropane
<0.205
<0.205
ND
25
330
cis-1,3-Dichloropropene
<0.178
<0.178
ND
NE
NE
trans-1,3-Dichloropropene
<0.178
<0.178
ND
NE
NE
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (Freon 114)
<0.623
<0.623
ND
NE
NE
1,4-Dioxane
<0.435
<0.435
ND
19
250
Ethyl Acetate
<0.136
<0.136
ND
490
6100
Ethylbenzene
1.67 J
2.01 J
2.01 J
37
490
4-Ethyltoluene
0.629 J
0.929 J
0.929 J
NE
NE
Heptane
4.73
2.37
4.73
2800
35000
Hexachlorobutadiene
<0.330
<0.330
ND
4.3
56
Hexane
8.00
3.03
8.00
4900
61000
2-Hexanone (MBK)
1.79 J
1.20 J
1.79 J
210
2600
Isopropanol
19.9
16.4
19.9
1400
18000
Methyl tert-Butyl Ether (MTBE)
<0.0336
<0.0336
ND
360
4700
Methylene Chloride
1.09 J
1.02 J
1.09 J
3400
53000
4-Methyl-2-pentanone (MIBK)
1.20 J
0.733 J
1.20 J
21000
260000
Naphthalene
0.587 J
0.550 J
0.587 J
2.8
36
Propene
13.0
5.85
13.0
21000
260000
Styrene
0.515 J
0.477 J
0.515 J
7000
88000
1,1,2,2-Tetrachloroethane
<0.104
<0.104
ND
1.6
21
Tetrachloroethylene
13.6
15.8
15.8
280
3500
Tetrahydrofuran
<0.107
0.310 J
0.310 J
14000
180000
Toluene
7.95
8.00
8.00
35000
440000
1,2,4-Trichlorobenzene
<0.209
<0.209
ND
14
180
1,1,1-Trichloroethane
0.475 J
0.464 J
0.475 J
35000
440000
1,1,2-Trichloroethane
<0.0877
<0.0877
ND
1.4
18
Trichloroethylene
<0.199
<0.199
ND
14
180
Trichlorofluoromethane (Freon
11)
2.76 J
2.77 J
2.77 J
NE
NE
1,1,2-Tdchloro-1,2,2-
trifluoroethane (Freon 113)
<0.561
0.728 J
0.728 J
35000
440000
1,2,4-Trimethylbenzene
1.94 J
2.86
2.86
420
5300
1,3,5-Trimethylbenzene
0.487 J
0.659 J
0.659 J
420
5300
Vinyl Acetate
<0.224
<0.224
ND
1400
18000
Vinyl Chloride
<0.127
<0.127
ND
5.6
280
m&p-Xylene
5.99
7.19
7.19
700
8800
o-Xylene
1.74 J
2.37
2.37
700
8800
RESIDENTIAL RISK CALCULATIONS
SUMMARY
Acceptable Carcinogenic
Sum Risk Range and Maximum Non -Cancer Hazard Index
Calculated Sample Cancer Risk
Sum
1.0E-06
1.0 E-04
Calculated Sample Non-
Carcinogenic Hazard Index
4.1E-02
HI=1
NON-RESIDENTIAL RISK CALCULATIONS
SUMMARY
Acceptable Carcinogenic
Sum Risk Range and Maximum Non -Cancer Hazard Index
Calculated Sample Cancer Risk
Sum
7.7E-08
1.0 E-04
Calculated Sample Non-
Carcinogenic Hazard Index
3.3E-03
HI=1
Notes:
Concentration units; ug/m3
J = Estimated Concentration
ND = Not Detected
NE =Not Established
Bolded concentrations exceed the Residential Soil Gas Screening Level
Bolded risk calculations exceed the Carcinogenic Risk and/or Non-Carcinoqenic Hazard Quotient target values
Shaded concentrations exceed the Non -Residential Soil Gas Screening Level
<0.34 = Not detected above the lab method detection limit
TABLE 4
INDOOR AIR SAMPLE/SAMPLE DUPLICATE COMPARISON: "IA-1" AND "IA-DUP"
SONRISE INDUSTRIAL CENTER
1200 HENRY STREET
ROANOKE RAPIDS, NORTH CAROLINA
MID -ATLANTIC JOB NO. R3641.00 T40034
PRIMARY SAMPLE:
IA-1
DUPLICATE SAMPLE:
IA-DUP
Absolute
Difference or
AVG. of
Results for
Absolute
Difference
% RPD (Note 2)
Variability
(See Note 2 if based on %RPD)
SAMPLING DATE:
6/22/2022
SAMPLING DATE:
6/22/2022
Parameter
Method
Units
Result
Qualif
RL
Parameter
Method
Units
Result
Qualif
RL
% RPD (Note
1)
RPD Calc.
between
Results
[((x1-x2)/AVG) "
100]
(See Note 3 if based on Absolute Difference)
VOCs Method
TO-15
Acetone
TO-15
uQ/m3
5.75
4.75
Acetone
TO-15
UCl/M3
4.97
4.75
ABS
0.78
Acceptable
Benzene
TO-15
u /m3
0.310
J
1.60
Benzene
TO-15
u /m3
0.323
J
1.60
NC - J Value
2-Butanone (MEK)
TO-15
ug/m3
1.02
J
1.47
2-Butanone (MEK)
TO-15
ug/m3
0.958
J
1.47
NC - J Value
Carbon Disulfide
TO-15
u /m3
0.504
J
6.23
Carbon Disulfide
TO-15
u /m3
ND
6.23
NC - Only 1
Chloroform
TO-15
ug/m3
0.718
J
2.44
Chloroform
TO-15
ug/m3
ND
2.44
NC - Only 1
Dichlorodifluoromethane
Freon 12
TO-15
u /m3
1 2.70
2.47
Dichlorodifluoromethane Freon 12
TO-15
u /m3
2.60
2.47
ABS
0.10
Acceptable
cis-1,2-Dichloroethylene
TO-15
ug/m3
0.333
J
1.98
cis-1,2-Dichloroethylene
TO-15
ug/m3
ND
1.98
NC - Only 1
Methylene Chloride
TO-15
u /m3
0.580
J
1.74
Methylene Chloride
TO-15
u /m3
0.493
J
1.74
NC - J Value
Naphthalene
TO-15
ug/m3
0.598
J
2.62
Naphthalene
TO-15
ug/m3
0.571
J
2.62
NC - J Value
Tetrachloroeth lene
TO-15
u /m3
6.61
3.39
Tetrachloroeth lene
TO-15
u /m3
4.00
3.39
ABS
2.61
Acceptable
Toluene
TO-15
ug/m3
1.30
J
1.88
Toluene
TO-15
ug/m3
1.10
J
1.88
NC - J Value
Trichloroeth lene
TO-15
u /m3
0.537
J
2.15
ITrichloroethylene
I TO-15
u /m3
ND
2.15
NC - Only 1
Trichlorofluoromethane
Freon 11
TO-15
u /m3
1.84
1 J
2.81
ITrichlorofluoromethane Freon 11
TO-15
u /m3
1.84
J
2.81
1
NC - J Value
Notes:
Note 1 = If duplicate or sample results is less than 5 times the reporting limit (RL), then the comparison is made by the absolute difference (ABS) between results. If ABS is less
than the higher
reporting limit, precision is considered acceptable.
If duplicate or sample result is greater than 5 times the RL, then the comparison is assessed by the RPD (Note 2)
Note 2 = The relative percent difference (RPD) and percent ratio were calculated for each pair (see formulas in column headings). Variability
was evaluated based on % RPD:
Good/Acceptable (<35%), Slightly High (>35% but <50%) and High
(%50).
Note 3 = ABS less than the magnitude of the RL are considered acceptable. ABS within two times the magnitude of the RL are considered "slightly high".
ABS greater than two times the RL are considered "High".
Blank Cells = Consituent not detected, or below the method detection limit (MDL).
NT = Constituent not tested for.
J = Detected, but below the Reporting Limit; therefore, result is an estimated concentration
ND = Constituent not detected above the method detection limit (MDL), which is lower than the reporting limit (RL).
NC - J Value = Variability not determined because one or both results are "estimated" concentrations (J-values) below the reporting limit.
NC - Only 1 = Variability not determined because the analyte was not detected in both the primary and duplicate sample
TABLES
SOIL GAS SAMPLE/SAMPLE DUPLICATE COMPARISON: "SG-9" AND "SG-DUP"
SONRISE INDUSTRIAL CENTER
1200 HENRY STREET
ROANOKE RAPIDS, NORTH CAROLINA
MID -ATLANTIC JOB NO. R3641.00 T40034
PRIMARY SAMPLE:
SG-9
DUPLICATE SAMPLE:
SG-DUP
Absolute
Difference or
% RPD (Note
1)
AVG. of
Results for
RPD Calc.
Absolute
Difference
between
Results
% RPD (Note 2)
[((x1-x2)/AVG)
100]
Variability
(See Note 2 if based on %RPD)
(See Note 3 if based on Absolute Difference)
SAMPLING DATE:
6/22/2022
SAMPLING DATE:
6/22/2022
Parameter
Method
Units
Result
Qualif
RL
Parameter
Method
Units
Result
Qualif
RL
VOCs Method
TO-15
Acetone
TO-15
UCl/M3
65.3
0.202
Acetone
TO-15
uq/m3
51.0
0.202
%RPD
58.2
14.3
24.6
Acceptable
Benzene
TO-15
u /m3
1.92
0.0733
Benzene
TO-15
u /m3
1.34
J
0.0733
NC - J Value
1,3-Butadiene
TO-15
uq/m3
0.785
J
1.11
1,3-Butadiene
TO-15
ua/rn3
ND
0.328
NC - Only 1
2-Butanone MEK
TO-15
u /m3
9.75
1.47
2-Butanone MEK
TO-15
u /m3
7.01
1.47
%RPD
8.4
2.74
32.7
Slightly High
Carbon Disulfide
TO-15
uq/m3
1.35
J
6.23
Carbon Disulfide
TO-15
uq/m3
1.80
J
6.23
NC - J Value
Chloroform
TO-15
u /m3
1.16
J
2.44
Chloroform
TO-15
u /m3
1 1.00
J
2.44
NC - J Value
1,3-Dichlorobenzene
TO-15
uq/m3
0.577
J
12.0
1,3-Dichlorobenzene
TO-15
uq/m3
0.54
J
12.0
NC - J Value
Dichlorodifluoromethane Freon 12
TO-15
u /m3
2.90
2.47
Dichlorodifluoromethane Freon 12
TO-15
u /m3
3.11
2.47
ABS
0.21
Acceptable
Ethylbenzene
TO-15
uq/m3
1.67
J
2.17
Ethylbenzene
TO-15
ua/rn3
2.01
J
2.17
NC - J Value
4-Eth (toluene
TO-15
u /m3
0.629
J
2.46
4-Eth (toluene
TO-15
u /m3
2.01
J
2.46
NC - J Value
Heptane
TO-15
uq/m3
4.73
2.05
Heptane
TO-15
uq/m3
2.37
2.05
ABS
2.36
Slightly High
Hexane
TO-15
u /m3
8.00
1.76
Hexane
TO-15
u /m3
3.03
1.76
NC - J Value
2-Hexanone (MBK)
TO-15
uq/m3
1.79
J
2.05
2-Hexanone (MBK)
TO-15
ua/rn3
1.20
J
2.05
NC - J Value
Iso ro anol
TO-15
u /m3
19.9
4.92
Iso ro anol
TO-15
u /m3
16.4
4.92
ABS
3.50
Acceptable
Methylene Chloride
TO-15
uq/m3
1.09
J
1.74
Methylene Chloride
TO-15
uq/m3
1.02
J
1.74
NC - J Value
4-Meth I-2- entanone MIBK
TO-15
u /m3
1.20
J
2.05
4-Meth I-2- entanone MIBK
TO-15
u /m3
0.733
J
2.05
NC - J Value
Naphthalene
TO-15
uq/m3
0.587
J
1 2.62
Naphthalene
TO-15
uq/m3
0.550
J
2.62
NC - J Value
Propene
TO-15
u /m3
13.0
0.861
Propene
TO-15
u /m3
5.85
0.861
%RPD
9.4
7.15
75.9
High
Styrene
TO-15
uq/m3
0.515
J
2.13
Styrene
TO-15
ua/rn3
0.477
J
2.13
NC - J Value
Tetrachloroeth (ene
TO-15
u /m3
13.6
3.39
Tetrachloroeth lene
TO-15
u /m3
15.8
3.39
%RPD
14.7
2.2
15.0
Acceptable
Tetrahydrofuran
TO-15
uq/m3
ND
1.47
Tetrahydrofuran
TO-15
uq/m3
0.310
J
1.47
NC - Non -Detection
Toluene
TO-15
u /m3
7.95
1.88
Toluene
TO-15
u /m3
8.00
1.88
%RPD
8.0
0.05
0.6
Acceptable
1,1,1-Trichloroethane
TO-15
uq/m3
0.475
J
1 2.73
1,1,1-Trichloroethane
TO-15
ua/rn3
0.464
J
2.73
NC - J Value
Trichlorofluoromethane Freon 11
TO-15
u /m3
2.76
J
2.81
Trichlorofluoromethane Freon 11
TO-15
u /m3
2.770
J
2.81
NC - J Value
1,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
TO-15
ug/m3
ND
3.83
1,1,2-Trichloro-1,2,2-trifluoroethane
(Freon 113)
TO-15
ug/m3
0.728
J
3.83
NC - Only 1
1,2,4-Trimeth (benzene
TO-15
u /m3
1.94
J
2.46
1,2,4-Trimeth (benzene
TO-15
u /m3
2.86
1
2.46
NC - J Value
1,3,5-Trimethylbenzene
TO-15
uq/m3
0.487
1 J
2.46
1,3,5-Trimethylbenzene
TO-15
uq/rn3
0.659
J
1 2.46
NC - J Value
m& -X (ene
TO-15
u /m3
5.99
1 5.65
m& -X lene
TO-15
u /m3
7.19
1 5.651
ABS
1.20
Acceptable
o-X lene
TO-15
3
1.74
J
2.17
o-X lene
TO-15
3
2.37
1 2.17
NC - J Value
Notes:
Note 1 = If duplicate or sample results is less than 5 times the reporting limit (RL), then the comparison is made by the absolute difference (ABS) between results. If ABS is less than the higher reporting limit, precision is considered acceptable.
If duplicate or sample result is greater than 5 times the RL, then the comparison is assessed by the RPD (Note 2)
Note 2 = The relative percent difference (RPD) and percent ratio were calculated for each pair (see formulas in column headings). Variability was evaluated based on % RPD: Good/Acceptable (<35%), Slightly High (>35% but <50%) and High (%50).
Note 3 = ABS less than the magnitude of the RL are considered acceptable. ABS within two times the magnitude of the RL are considered "slightly high". ABS greater than two times the RL are considered "High".
Blank Cells = Consituent not detected, or below the method detection limit (MDL).
NT = Constituent not tested for.
J = Detected, but below the Reporting Limit; therefore, result is an estimated concentration
ND = Constituent not detected above the method detection limit (MDL), which is lower than the reporting limit (RL).
NC - J Value = Variability not determined because one or both results are "estimated" concentrations (J-values) below the reporting limit.
NC - Only 1 = Variability not determined because the analyte was not detected in both the primary and duplicate sample
APPENDIX A
LABORATORY ANALYTICAL REPORTS
AND CHAIN -OF -CUSTODY RECORDS
1% Mid Atlantic
Waypointo
ANALYTICAL
7/14/2022
Mid -Atlantic Associates, Inc. - Raleigh
Kevin Clay
409 Rogers View Court
Raleigh, NC, 27610
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Revised Lab Report Number: 22-175-9007 (Original Report 22-175-0007)
Client Project Description: R3641.00
Dear Kevin Clay:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 6/24/2022 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a'_1
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 31
Waypoint.0
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2022
North Carolina
State Program
402
12/31/2022
South Carolina
State Program
99012
07/31/2022
South Carolina
State Program
99012
12/31/2022
Page 1 of 1 00016/22-175-9007
Page 2 of 31
Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Sample Summary Table
Report Number: 22-175-9007
Client Project Description: R3641.00
Lab No Client Sample ID Matrix Date Collected Date Received
92995
IA-DUP
Air
06/22/2022
07:31
06/24/2022
14:59
92996
IA-1
Air
06/22/2022
07:31
06/24/2022
14:59
92997
SG-DUP
Air
06/22/2022
16:35
06/24/2022
14:59
92998
SG-9
Air
06/22/2022
16:10
06/24/2022
14:59
Page 3 of 31
Waypoint.
(2) 449 Springbrook
Rd, Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.waypointana lyti ca I som
Summary of Detected Analytes
Project:
R3641.00
Report Number: 22-175-9007
Client Sample ID Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
IA-DUP
V 92995
TO-15
Acetone
4.97
pg/m3
0.202
06/28/2022 01:40
TO-15
Benzene
0.323
pg/m3
0.0733
06/28/2022 01:40
J
TO-15
Dichlorodifluoromethane
2.60
pg/m3
0.134
06/28/2022 01:40
TO-15
Isopropyl Alchohol
0.846
pg/m3
0.139
06/28/2022 01:40
J
TO-15
Methyl Ethyl Ketone (MEK)
0.958
pg/m3
0.224
06/28/2022 01:40
J
TO-15
Methylene Chloride
0.493
pg/m3
0.489
06/28/2022 01:40
J
TO-15
Naphthalene
0.571
pg/m3
0.183
06/28/2022 01:40
J
TO-15
Tetrachloroethene
4.00
pg/m3
0.181
06/28/2022 01:40
TO-15
Toluene
1.10
pg/m3
0.0901
06/28/2022 01:40
J
TO-15
Trichlorofluoromethane
1.84
pg/m3
0.130
06/28/2022 01:40
J
IA-1
V 92996
TO-15
Acetone
5.75
pg/m3
0.202
06/28/2022 02:25
TO-15
Benzene
0.310
pg/m3
0.0733
06/28/2022 02:25
J
TO-15
Carbon Disulfide
0.504
pg/m3
0.0608
06/28/2022 02:25
J
TO-15
Chloroform
0.718
pg/m3
0.0864
06/28/2022 02:25
J
TO-15
Dichlorodifluoromethane
2.70
pg/m3
0.134
06/28/2022 02:25
TO-15
cis-1,2-Dichloroethene
0.333
pg/m3
0.0955
06/28/2022 02:25
J
TO-15
Methyl Ethyl Ketone (MEK)
1.02
pg/m3
0.224
06/28/2022 02:25
J
TO-15
Methylene Chloride
0.580
pg/m3
0.489
06/28/2022 02:25
J
TO-15
Naphthalene
0.598
pg/m3
0.183
06/28/2022 02:25
J
TO-15
Tetrachloroethene
6.61
pg/m3
0.181
06/28/2022 02:25
TO-15
Toluene
1.30
pg/m3
0.0901
06/28/2022 02:25
J
TO-15
Trichloroethene
0.537
pg/m3
0.199
06/28/2022 02:25
J
TO-15
Trichlorofluoromethane
1.84
pg/m3
0.130
06/28/2022 02:25
J
SG-DUP
V 92997
TO-15
Acetone
51.0
pg/m3
0.202
06/30/202212:01
TO-15
Benzene
1.34
pg/m3
0.0733
06/30/202212:01
J
TO-15
Carbon Disulfide
1.80
pg/m3
0.0608
06/30/2022 12:01
J
TO-15
Chloroform
1.00
pg/m3
0.0864
06/30/202212:01
J
TO-15
1,3-Dichlorobenzene
0.535
pg/m3
0.174
06/30/202212:01
J
TO-15
Dichlorodifluoromethane
3.11
pg/m3
0.134
06/30/202212:01
TO-15
Ethylbenzene
2.01
pg/m3
0.106
06/30/202212:01
J
TO-15
4-Ethyltoluene
0.929
pg/m3
0.128
06/30/202212:01
J
TO-15
1,1,2-Trichloro-1,2,2-trifluoroethane 0.728
pg/m3
0.561
06/30/202212:01
J
TO-15
Heptane
2.37
pg/m3
0.143
06/30/202212:01
TO-15
n-Hexane
3.03
pg/m3
0.0472
06/30/202212:01
Page 4 of 31
Waypoint.(2)
ANALYTICAL
Project: R3641.00
Report Number: 22-175-9007
Client Sample ID Lab Sample ID
Method Parameters
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
Summary of Detected
Result Units Report Limit Analyzed
SG-DUP
V 92997
TO-15
2-Hexanone
1.20
pg/m3
0.285
06/30/2022 12:01
TO-15
Isopropyl Alchohol
16.4
pg/m3
0.139
06/30/2022 12:01
TO-15
Methyl Ethyl Ketone (MEK)
7.01
pg/m3
0.224
06/30/2022 12:01
TO-15
4-Methyl-2-Pentanone
0.733
pg/m3
0.121
06/30/2022 12:01
TO-15
Methylene Chloride
1.02
pg/m3
0.489
06/30/2022 12:01
TO-15
Naphthalene
0.550
pg/m3
0.183
06/30/2022 12:01
TO-15
Propene
5.85
pg/m3
0.242
06/30/2022 12:01
TO-15
Styrene
0.477
pg/m3
0.124
06/30/2022 12:01
TO-15
Tetrachloroethene
15.8
pg/m3
0.181
06/30/2022 12:01
TO-15
Tetrahydrofuran
0.310
pg/m3
0.107
06/30/2022 12:01
TO-15
Toluene
8.00
pg/m3
0.0901
06/30/2022 12:01
TO-15
1,1,1-Trichloroethane
0.464
pg/m3
0.144
06/30/2022 12:01
TO-15
Trichlorofluoromethane
2.77
pg/m3
0.130
06/30/2022 12:01
TO-15
1,2,4-Trimethyl benzene
2.86
pg/m3
0.110
06/30/2022 12:01
TO-15
1,3,5-Trimethyl benzene
0.659
pg/m3
0.236
06/30/2022 12:01
TO-15
o-Xylene
2.37
pg/m3
0.157
06/30/2022 12:01
TO-15
m,p-Xylene
7.19
pg/m3
0.217
06/30/2022 12:01
TO-15
Xylene (Total)
9.56
pg/m3
0.157
06/30/2022 12:01
SG-9
V 92998
TO-15
Acetone
65.3
pg/m3
0.202
06/30/2022 12:53
TO-15
Benzene
1.92
pg/m3
0.0733
06/30/2022 12:53
TO-15
1,3-Butadiene
0.785
pg/m3
0.328
06/30/2022 12:53
TO-15
Carbon Disulfide
1.35
pg/m3
0.0608
06/30/2022 12:53
TO-15
Chloroform
1.16
pg/m3
0.0864
06/30/2022 12:53
TO-15
1,3-Dichlorobenzene
0.577
pg/m3
0.174
06/30/2022 12:53
TO-15
Dichlorodifluoromethane
2.90
pg/m3
0.134
06/30/2022 12:53
TO-15
Ethylbenzene
1.67
pg/m3
0.106
06/30/2022 12:53
TO-15
4-Ethyltoluene
0.629
pg/m3
0.128
06/30/2022 12:53
TO-15
Heptane
4.73
pg/m3
0.143
06/30/2022 12:53
TO-15
n-Hexane
8.00
pg/m3
0.0472
06/30/2022 12:53
TO-15
2-Hexanone
1.79
pg/m3
0.285
06/30/2022 12:53
TO-15
Isopropyl Alchohol
19.9
pg/m3
0.139
06/30/2022 12:53
TO-15
Methyl Ethyl Ketone (MEK)
9.75
pg/m3
0.224
06/30/2022 12:53
TO-15
4-Methyl-2-Pentanone
1.20
pg/m3
0.121
06/30/2022 12:53
TO-15
Methylene Chloride
1.09
pg/m3
0.489
06/30/2022 12:53
TO-15
Naphthalene
0.587
pg/m3
0.183
06/30/2022 12:53
Qualifiers
J
J
J
J
J
J
J
J
J
I
I
0
I
Page 5 of 31
Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Summary of Detected Analytes
Project: R3641.00
Report Number: 22-175-9007
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
SG-9
V 92998
TO-15
Propene
13.0
Ng/m3
TO-15
Styrene
0.515
Ng/m3
TO-15
Tetrachloroethene
13.6
Ng/m3
TO-15
Toluene
7.95
lag/m3
TO-15
1,1,1-Trichloroethane
0.475
Ng/m3
TO-15
Trichlorofluoromethane
2.76
lag/m3
TO-15
1,2,4-Trimethyl benzene
1.94
Ng/m3
TO-15
1,3,5-Trimethyl benzene
0.487
Ng/m3
TO-15
o-Xylene
1.74
lag/m3
TO-15
m,p-Xylene
5.99
lag/m3
TO-15
Xylene (Total)
7.73
Ng/m3
0.242 06/30/2022 12:53
0.124
06/30/2022 12:53 J
0.181
06/30/2022 12:53
0.0901
06/30/2022 12:53
0.144
06/30/2022 12:53 J
0.130
06/30/2022 12:53 J
0.110
06/30/2022 12:53 J
0.236
06/30/2022 12:53 J
0.157
06/30/2022 12:53 J
0.217
06/30/2022 12:53
0.157
06/30/2022 12:53 J
Page 6 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92995
Matrix: Air
Sample ID: IA-DUP
Sampled:
6/22/2022
7:31
Analytical Method: TO-15
Prep Batch(es):
V20612
06/27/22 09:00
Prep Method: TO-15
Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
4.97
Ng/m3
0.202
4.75
1
06/28/22 01:40
ENM
V20630
Benzene
0.3233
ug/m3
0.0733
1.60
1
06/28/22 01:40
ENM
V20630
Benzyl Chloride
<0.148
Ng/m3
0.148
10.4
1
06/28/22 01:40
ENM
V20630
Bromodichloromethane
<0.150
ug/m3
0.150
3.35
1
06/28/22 01:40
ENM
V20630
Bromoform
<0.153
Ng/m3
0.153
5.17
1
06/28/22 01:40
ENM
V20630
Bromomethane
<0.115
ug/m3
0.115
1.94
1
06/28/22 01:40
ENM
V20630
1,3-Butadiene
<0.328
Ng/m3
0.328
1.11
1
06/28/22 01:40
ENM
V20630
Carbon Disulfide
<0.0608
ug/m3
0.0608
6.23
1
06/28/22 01:40
ENM
V20630
Carbon Tetrachloride
<0.155
N9/m3
0.155
3.15
1
06/28/22 01:40
ENM
V20630
Chlorobenzene
<0.107
ug/m3
0.107
2.30
1
06/28/22 01:40
ENM
V20630
Chlorodibromomethane
<0.208
N9/m3
0.208
4.26
1
06/28/22 01:40
ENM
V20630
Chloroethane
<0.164
ug/m3
0.164
1.32
1
06/28/22 01:40
ENM
V20630
Chloroform
<0.0864
N9/m3
0.0864
2.44
1
06/28/22 01:40
ENM
V20630
Chloromethane
<0.0673
ug/m3
0.0673
1.03
1
06/28/22 01:40
ENM
V20630
Cyclohexane
<0.161
N9/m3
0.161
3.44
1
06/28/22 01:40
ENM
V20630
1,2-Dibromoethane
<0.151
ug/m3
0.151
3.84
1
06/28/22 01:40
ENM
V20630
1,2-Dichlorobenzene
<0.0963
N9/m3
0.0963
3.01
1
06/28/22 01:40
ENM
V20630
1,3-Dichlorobenzene
<0.174
ug/m3
0.174
12.0
1
06/28/22 01:40
ENM
V20630
1,4-Dichlorobenzene
<0.186
N9/m3
0.186
3.01
1
06/28/22 01:40
ENM
V20630
Dichlorodifluoromethane
2.60
ug/m3
0.134
2.47
1
06/28/22 01:40
ENM
V20630
1,1-Dichloroethane
<0.101
N9/m3
0.101
2.02
1
06/28/22 01:40
ENM
V20630
1,2-Dichloroethane
<0.129
ug/m3
0.129
2.02
1
06/28/22 01:40
ENM
V20630
Qualifiers/ DF
Dilution Factor
I
Estimated value
Definitions MQL
Method Quantitation Limit
Page 7 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92995
Matrix: Air
Sample ID: IA-DUP
Sampled:
6/22/2022
7:31
Analytical Method: TO-15
Prep Batch(es):
V20612
06/27/22 09:00
Prep Method: TO-15 Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethene
<0.107
Ng/m3
0.107
1.98
1
06/28/22 01:40
ENM
V20630
cis- 1,2-Dich loroethene
<0.0955
ug/m3
0.0955
1.98
1
06/28/22 01:40
ENM
V20630
trans-1,2-Dichloroethene
<0.108
Ng/m3
0.108
1.98
1
06/28/22 01:40
ENM
V20630
1,2-Dichloropropane
<0.205
pg/m3
0.205
2.31
1
06/28/22 01:40
ENM
V20630
1,2-Dichlorotetrafluoroethane
<0.623
Ng/m3
0.623
3.50
1
06/28/22 01:40
ENM
V20630
cis- 1,3-Dich loropropene
<0.178
ug/m3
0.178
2.27
1
06/28/22 01:40
ENM
V20630
trans-1,3-Dichloropropene
<0.178
Ng/m3
0.178
2.27
1
06/28/22 01:40
ENM
V20630
1,4-Dioxane
<0.435
ug/m3
0.435
1.80
1
06/28/22 01:40
ENM
V20630
Ethyl Acetate
<0.136
Ng/m3
0.136
1.80
1
06/28/22 01:40
ENM
V20630
Ethylbenzene
<0.106
ug/m3
0.106
2.17
1
06/28/22 01:40
ENM
V20630
4-Ethyltoluene
<0.128
Ng/m3
0.128
2.46
1
06/28/22 01:40
ENM
V20630
1,1,2-Trichloro-1,2,2-trifluoroethane
<0.561
ug/m3
0.561
3.83
1
06/28/22 01:40
ENM
V20630
Heptane
<0.143
Ng/m3
0.143
2.05
1
06/28/22 01:40
ENM
V20630
Hexachlorobutadiene
<0.330
ug/m3
0.330
5.33
1
06/28/22 01:40
ENM
V20630
n-Hexane
<0.0472
Ng/m3
0.0472
1.76
1
06/28/22 01:40
ENM
V20630
2-Hexanone
<0.285
ug/m3
0.285
2.05
1
06/28/22 01:40
ENM
V20630
Isopropyl Alchohol
0.8463
Ng/m3
0.139
4.92
1
06/28/22 01:40
ENM
V20630
Methyl Ethyl Ketone (MEK)
0.9581
ug/m3
0.224
1.47
1
06/28/22 01:40
ENM
V20630
Methyl tert-butyl ether (MTBE)
<0.0336
Ng/m3
0.0336
1.80
1
06/28/22 01:40
ENM
V20630
4-Methyl-2-Pentanone
<0.121
ug/m3
0.121
2.05
1
06/28/22 01:40
ENM
V20630
Methylene Chloride
0.4933
Ng/m3
0.489
1.74
1
06/28/22 01:40
ENM
V20630
Naphthalene
0.571 J
ug/m3
0.183
2.62
1
06/28/22 01:40
ENM
V20630
Qualifiers/ DF Dilution Factor
I
Estimated value
Definitions MQL Method Quantitation Limit
Page 8 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92995 Matrix: Air
Sample ID: IA-DUP Sampled: 6/22/2022 7:31
Analytical Method: TO-15 Prep Batch(es): V20612 06/27/22 09:00
Prep Method: TO-15 Prep
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Propene
<0.242
N9/m3
0.242
0.861
1
06/28/22 01:40
ENM
V20630
Styrene
<0.124
pg/m3
0.124
2.13
1
06/28/22 01:40
ENM
V20630
1,1,2,2-Tetrachloroethane
<0.104
N9/m3
0.104
3.43
1
06/28/22 01:40
ENM
V20630
Tetrachloroethene
4.00
pg/m3
0.181
3.39
1
06/28/22 01:40
ENM
V20630
Tetrahydrofuran
<0.107
N9/m3
0.107
1.47
1
06/28/22 01:40
ENM
V20630
Toluene
1.103
pg/m3
0.0901
1.88
1
06/28/22 01:40
ENM
V20630
1,2,4-Trichlorobenzene
<0.209
N9/m3
0.209
3.71
1
06/28/22 01:40
ENM
V20630
1,1,1-Trichloroethane
<0.144
pg/m3
0.144
2.73
1
06/28/22 01:40
ENM
V20630
1, 1, 2-Trich loroetha ne
<0.0877
N9/m3
0.0877
2.73
1
06/28/22 01:40
ENM
V20630
Trichloroethene
<0.199
pg/m3
0.199
2.15
1
06/28/22 01:40
ENM
V20630
Trichlorofluoromethane
1.843
N9/m3
0.130
2.81
1
06/28/22 01:40
ENM
V20630
1,2,4-Trimethyl benzene
<0.110
pg/m3
0.110
2.46
1
06/28/22 01:40
ENM
V20630
1,3,5-Trimethyl benzene
<0.236
N9/m3
0.236
2.46
1
06/28/22 01:40
ENM
V20630
Vinyl Acetate
<0.224
pg/m3
0.224
1.76
1
06/28/22 01:40
ENM
V20630
Vinyl Chloride
<0.127
N9/m3
0.127
1.28
1
06/28/22 01:40
ENM
V20630
o-Xylene
<0.157
pg/m3
0.157
2.17
1
06/28/22 01:40
ENM
V20630
m,p-Xylene
<0.217
N9/m3
0.217
5.65
1
06/28/22 01:40
ENM
V20630
Xylene (Total)
<0.157
pg/m3
0.157
2.17
1
06/28/22 01:40
V20630
Surrogate: 4-13romofluorobenzene
98.0
Limits: 70-130%
1 06/28/22 01:40 ENM
V20630
Qualifiers/ DF
Dilution Factor
I
Estimated value
Definitions MQL
Method Quantitation Limit
Page 9 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92996
Matrix: Air
Sample ID: IA-1
Sampled:
6/22/2022
7:31
Analytical Method: TO-15
Prep Batch(es):
V20612
06/27/22 09:00
Prep Method: TO-15
Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
5.75
pg/m3
0.202
4.75
1
06/28/22 02:25
ENM
V20630
Benzene
0.3103
pg/m3
0.0733
1.60
1
06/28/22 02:25
ENM
V20630
Benzyl Chloride
<0.148
pg/m3
0.148
10.4
1
06/28/22 02:25
ENM
V20630
Bromodichloromethane
<0.150
pg/m3
0.150
3.35
1
06/28/22 02:25
ENM
V20630
Bromoform
<0.153
pg/m3
0.153
5.17
1
06/28/22 02:25
ENM
V20630
Bromomethane
<0.115
pg/m3
0.115
1.94
1
06/28/22 02:25
ENM
V20630
1,3-Butadiene
<0.328
pg/m3
0.328
1.11
1
06/28/22 02:25
ENM
V20630
Carbon Disulfide
0.504 3
pg/m3
0.0608
6.23
1
06/28/22 02:25
ENM
V20630
Carbon Tetrachloride
<0.155
pg/m3
0.155
3.15
1
06/28/22 02:25
ENM
V20630
Chlorobenzene
<0.107
pg/m3
0.107
2.30
1
06/28/22 02:25
ENM
V20630
Chlorodibromomethane
<0.208
pg/m3
0.208
4.26
1
06/28/22 02:25
ENM
V20630
Chloroethane
<0.164
pg/m3
0.164
1.32
1
06/28/22 02:25
ENM
V20630
Chloroform
0.7183
pg/m3
0.0864
2.44
1
06/28/22 02:25
ENM
V20630
Chloromethane
<0.0673
pg/m3
0.0673
1.03
1
06/28/22 02:25
ENM
V20630
Cyclohexane
<0.161
pg/m3
0.161
3.44
1
06/28/22 02:25
ENM
V20630
1,2-Dibromoethane
<0.151
pg/m3
0.151
3.84
1
06/28/22 02:25
ENM
V20630
1,2-Dichlorobenzene
<0.0963
pg/m3
0.0963
3.01
1
06/28/22 02:25
ENM
V20630
1,3-Dichlorobenzene
<0.174
pg/m3
0.174
12.0
1
06/28/22 02:25
ENM
V20630
1,4-Dichlorobenzene
<0.186
pg/m3
0.186
3.01
1
06/28/22 02:25
ENM
V20630
Dichlorodifluoromethane
2.70
pg/m3
0.134
2.47
1
06/28/22 02:25
ENM
V20630
1,1-Dichloroethane
<0.101
pg/m3
0.101
2.02
1
06/28/22 02:25
ENM
V20630
1,2-Dichloroethane
<0.129
pg/m3
0.129
2.02
1
06/28/22 02:25
ENM
V20630
Qualifiers/ DF
Dilution Factor
I
Estimated value
Definitions MQL
Method Quantitation Limit
Page 10 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92996
Matrix: Air
Sample ID: IA-1
Sampled:
6/22/2022
7:31
Analytical Method: TO-15
Prep Batch(es):
V20612
06/27/22 09:00
Prep Method: TO-15 Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethene
<0.107
Ng/m3
0.107
1.98
1
06/28/22 02:25
ENM
V20630
cis- 1,2-Dich loroethene
0.3333
ug/m3
0.0955
1.98
1
06/28/22 02:25
ENM
V20630
trans-1,2-Dichloroethene
<0.108
Ng/m3
0.108
1.98
1
06/28/22 02:25
ENM
V20630
1,2-Dichloropropane
<0.205
ug/m3
0.205
2.31
1
06/28/22 02:25
ENM
V20630
1,2-Dichlorotetrafluoroethane
<0.623
Ng/m3
0.623
3.50
1
06/28/22 02:25
ENM
V20630
cis- 1,3-Dich loropropene
<0.178
ug/m3
0.178
2.27
1
06/28/22 02:25
ENM
V20630
trans-1,3-Dichloropropene
<0.178
Ng/m3
0.178
2.27
1
06/28/22 02:25
ENM
V20630
1,4-Dioxane
<0.435
ug/m3
0.435
1.80
1
06/28/22 02:25
ENM
V20630
Ethyl Acetate
<0.136
Ng/m3
0.136
1.80
1
06/28/22 02:25
ENM
V20630
Ethylbenzene
<0.106
ug/m3
0.106
2.17
1
06/28/22 02:25
ENM
V20630
4-Ethyltoluene
<0.128
Ng/m3
0.128
2.46
1
06/28/22 02:25
ENM
V20630
1,1,2-Trichloro-1,2,2-trifluoroethane
<0.561
ug/m3
0.561
3.83
1
06/28/22 02:25
ENM
V20630
Heptane
<0.143
Ng/m3
0.143
2.05
1
06/28/22 02:25
ENM
V20630
Hexachlorobutadiene
<0.330
ug/m3
0.330
5.33
1
06/28/22 02:25
ENM
V20630
n-Hexane
<0.0472
Ng/m3
0.0472
1.76
1
06/28/22 02:25
ENM
V20630
2-Hexanone
<0.285
ug/m3
0.285
2.05
1
06/28/22 02:25
ENM
V20630
Isopropyl Alchohol
<0.139
Ng/m3
0.139
4.92
1
06/28/22 02:25
ENM
V20630
Methyl Ethyl Ketone (MEK)
1.02 J
u9/m3
0.224
1.47
1
06/28/22 02:25
ENM
V20630
Methyl tert-butyl ether (MTBE)
<0.0336
Ng/m3
0.0336
1.80
1
06/28/22 02:25
ENM
V20630
4-Methyl-2-Pentanone
<0.121
u9/m3
0.121
2.05
1
06/28/22 02:25
ENM
V20630
Methylene Chloride
0.580 J
Ng/m3
0.489
1.74
1
06/28/22 02:25
ENM
V20630
Naphthalene
0.598 J
ug/m3
0.183
2.62
1
06/28/22 02:25
ENM
V20630
Qualifiers/ DF Dilution Factor
I
Estimated value
Definitions MQL Method Quantitation Limit
Page 11 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92996
Matrix: Air
Sample ID: IA-1
Sampled:
6/22/2022
7:31
Analytical Method: TO-15
Prep Batch(es):
V20612
06/27/22 09:00
Prep Method: TO-15 Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Propene
<0.242
Ng/m3
0.242
0.861
1
06/28/22 02:25
ENM
V20630
Styrene
<0.124
ug/m3
0.124
2.13
1
06/28/22 02:25
ENM
V20630
1,1,2,2-Tetrachloroethane
<0.104
Ng/m3
0.104
3.43
1
06/28/22 02:25
ENM
V20630
Tetrachloroethene
6.61
ug/m3
0.181
3.39
1
06/28/22 02:25
ENM
V20630
Tetrahydrofuran
<0.107
Ng/m3
0.107
1.47
1
06/28/22 02:25
ENM
V20630
Toluene
1.303
ug/m3
0.0901
1.88
1
06/28/22 02:25
ENM
V20630
1,2,4-Trichlorobenzene
<0.209
Ng/m3
0.209
3.71
1
06/28/22 02:25
ENM
V20630
1,1,1-Trichloroethane
<0.144
ug/m3
0.144
2.73
1
06/28/22 02:25
ENM
V20630
1, 1, 2-Trich loroetha ne
<0.0877
Ng/m3
0.0877
2.73
1
06/28/22 02:25
ENM
V20630
Trichloroethene
0.537 J
ug/m3
0.199
2.15
1
06/28/22 02:25
ENM
V20630
Trichlorofluoromethane
1.84 J
Ng/m3
0.130
2.81
1
06/28/22 02:25
ENM
V20630
1,2,4-Trimethyl benzene
<0.110
ug/m3
0.110
2.46
1
06/28/22 02:25
ENM
V20630
1,3,5-Trim ethyl benzene
<0.236
Ng/m3
0.236
2.46
1
06/28/22 02:25
ENM
V20630
Vinyl Acetate
<0.224
ug/m3
0.224
1.76
1
06/28/22 02:25
ENM
V20630
Vinyl Chloride
<0.127
Ng/m3
0.127
1.28
1
06/28/22 02:25
ENM
V20630
o-Xylene
<0.157
ug/m3
0.157
2.17
1
06/28/22 02:25
ENM
V20630
m,p-Xylene
<0.217
Ng/m3
0.217
5.65
1
06/28/22 02:25
ENM
V20630
Xylene (Total)
<0.157
ug/m3
0.157
2.17
1
06/28/22 02:25
V20630
Surrogate: 4-13romofluorobenzene
95.3
Limits: 70-130%
1 06/28/22 02:25 ENM
V20630
Qualifiers/ DF Dilution Factor
I
Estimated value
Definitions MQL Method Quantitation
Limit
Page 12 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92997
Matrix: Air
Sample ID: SG-DUP
Sampled:
6/22/2022
16:35
Analytical Method: TO-15
Prep Batch(es):
V20769
06/30/22 09:00
Prep Method: TO-15
Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
51.0
Ng/m3
0.202
4.75
1
06/30/22 12:01
ENM
V20770
Benzene
1.343
ug/m3
0.0733
1.60
1
06/30/22 12:01
ENM
V20770
Benzyl Chloride
<0.148
Ng/m3
0.148
10.4
1
06/30/22 12:01
ENM
V20770
Bromodichloromethane
<0.150
ug/m3
0.150
3.35
1
06/30/22 12:01
ENM
V20770
Bromoform
<0.153
Ng/m3
0.153
5.17
1
06/30/22 12:01
ENM
V20770
Bromomethane
<0.115
ug/m3
0.115
1.94
1
06/30/22 12:01
ENM
V20770
1,3-Butadiene
<0.328
Ng/m3
0.328
1.11
1
06/30/22 12:01
ENM
V20770
Carbon Disulfide
1.803
ug/m3
0.0608
6.23
1
06/30/22 12:01
ENM
V20770
Carbon Tetrachloride
<0.155
Ng/m3
0.155
3.15
1
06/30/22 12:01
ENM
V20770
Chlorobenzene
<0.107
ug/m3
0.107
2.30
1
06/30/22 12:01
ENM
V20770
Chlorodibromomethane
<0.208
Ng/m3
0.208
4.26
1
06/30/22 12:01
ENM
V20770
Chloroethane
<0.164
ug/m3
0.164
1.32
1
06/30/22 12:01
ENM
V20770
Chloroform
1.003
Ng/m3
0.0864
2.44
1
06/30/22 12:01
ENM
V20770
Chloromethane
<0.0673
ug/m3
0.0673
1.03
1
06/30/22 12:01
ENM
V20770
Cyclohexane
<0.161
Ng/m3
0.161
3.44
1
06/30/22 12:01
ENM
V20770
1,2-Dibromoethane
<0.151
u9/m3
0.151
3.84
1
06/30/22 12:01
ENM
V20770
1,2-Dichlorobenzene
<0.0963
Ng/m3
0.0963
3.01
1
06/30/22 12:01
ENM
V20770
1,3-Dichlorobenzene
0.5351
ug/m3
0.174
12.0
1
06/30/22 12:01
ENM
V20770
1,4-Dichlorobenzene
<0.186
Ng/m3
0.186
3.01
1
06/30/22 12:01
ENM
V20770
Dichlorodifluoromethane
3.11
ug/m3
0.134
2.47
1
06/30/22 12:01
ENM
V20770
1,1-Dichloroethane
<0.101
Ng/m3
0.101
2.02
1
06/30/22 12:01
ENM
V20770
1,2-Dichloroethane
<0.129
ug/m3
0.129
2.02
1
06/30/22 12:01
ENM
V20770
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 13 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92997 Matrix: Air
Sample ID: SG-DUP Sampled: 6/22/2022 16:35
Analytical Method: TO-15 Prep Batch(es): V20769 06/30/22 09:00
Prep Method: TO-15 Prep
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
1,1-Dichloroethene
<0.107
p9/m3
0.107
1.98
1
06/30/22 12:01
ENM
V20770
cis- 1,2-Dich loroethene
<0.0955
p9/m3
0.0955
1.98
1
06/30/22 12:01
ENM
V20770
trans-1,2-Dichloroethene
<0.108
p9/m3
0.108
1.98
1
06/30/22 12:01
ENM
V20770
1,2-Dichloropropane
<0.205
p9/m3
0.205
2.31
1
06/30/22 12:01
ENM
V20770
1,2-Dichlorotetrafluoroethane
<0.623
p9/m3
0.623
3.50
1
06/30/22 12:01
ENM
V20770
cis- 1,3-Dich loropropene
<0.178
p9/m3
0.178
2.27
1
06/30/22 12:01
ENM
V20770
trans-1,3-Dichloropropene
<0.178
p9/m3
0.178
2.27
1
06/30/22 12:01
ENM
V20770
1,4-Dioxane
<0.435
p9/m3
0.435
1.80
1
06/30/22 12:01
ENM
V20770
Ethyl Acetate
<0.136
p9/m3
0.136
1.80
1
06/30/22 12:01
ENM
V20770
Ethylbenzene
2.011
pg/m3
0.106
2.17
1
06/30/22 12:01
ENM
V20770
4-Ethyltoluene
0.9293
p9/m3
0.128
2.46
1
06/30/22 12:01
ENM
V20770
1,1,2-Trichloro-1,2,2-trifluoroethane
0.726 J
pg/m3
0.561
3.83
1
06/30/22 12:01
ENM
V20770
Heptane
2.37
pg/m3
0.143
2.05
1
06/30/22 12:01
ENM
V20770
Hexachlorobutadiene
<0.330
pg/m3
0.330
5.33
1
06/30/22 12:01
ENM
V20770
n-Hexane
3.03
pg/m3
0.0472
1.76
1
06/30/22 12:01
ENM
V20770
2-Hexanone
1.20 J
pg/m3
0.285
2.05
1
06/30/22 12:01
ENM
V20770
Isopropyl Alchohol
16.4
pg/m3
0.139
4.92
1
06/30/22 12:01
ENM
V20770
Methyl Ethyl Ketone (MEK)
7.01
pg/m3
0.224
1.47
1
06/30/22 12:01
ENM
V20770
Methyl tert-butyl ether (MTBE)
<0.0336
pg/m3
0.0336
1.80
1
06/30/22 12:01
ENM
V20770
4-Methyl-2-Pentanone
0.733 J
pg/m3
0.121
2.05
1
06/30/22 12:01
ENM
V20770
Methylene Chloride
1.02 J
pg/m3
0.489
1.74
1
06/30/22 12:01
ENM
V20770
Naphthalene
0.550 J
pg/m3
0.183
2.62
1
06/30/22 12:01
ENM
V20770
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 14 of 31
WavDdibnto
ANALYTICAL
01139
Mid -Atlantic Associates, Inc. - Raleigh
Kevin Clay
409 Rogers View Court
Raleigh , NC 27610
Report Number : 22-175-9007
Project R3641.00
Information :
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
REPORT OF ANAL YSIS
Original Report Date : 07/01/2022
Revised Report Date: 07/14/2022
Received : 06/24/2022
Lab No : 92997 Matrix: Air
Sample ID: SG-DUP Sampled: 6/22/2022 16:35
Analytical Method: TO-15 Prep Batch(es): V20769 06/30/22 09:00
Prep Method: TO-15 Prep
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Propene
5.85
pg/m3
0.242
0.861
1
06/30/22 12:01
ENM
V20770
Styrene
0.4773
pg/m3
0.124
2.13
1
06/30/22 12:01
ENM
V20770
1,1,2,2-Tetrachloroethane
<0.104
pg/m3
0.104
3.43
1
06/30/22 12:01
ENM
V20770
Tetrachloroethene
15.8
pg/m3
0.181
3.39
1
06/30/22 12:01
ENM
V20770
Tetrahydrofuran
0.3103
pg/m3
0.107
1.47
1
06/30/22 12:01
ENM
V20770
Toluene
8.00
pg/m3
0.0901
1.88
1
06/30/22 12:01
ENM
V20770
1,2,4-Trichlorobenzene
<0.209
pg/m3
0.209
3.71
1
06/30/22 12:01
ENM
V20770
1,1,1-Trichloroethane
0.4643
pg/m3
0.144
2.73
1
06/30/22 12:01
ENM
V20770
1, 1, 2-Trich loroetha ne
<0.0877
pg/m3
0.0877
2.73
1
06/30/22 12:01
ENM
V20770
Trichloroethene
<0.199
pg/m3
0.199
2.15
1
06/30/22 12:01
ENM
V20770
Trichlorofluoromethane
2.773
pg/m3
0.130
2.81
1
06/30/22 12:01
ENM
V20770
1,2,4-Trimethyl benzene
2.86
pg/m3
0.110
2.46
1
06/30/22 12:01
ENM
V20770
1,3,5-Trimethyl benzene
0.6593
pg/m3
0.236
2.46
1
06/30/22 12:01
ENM
V20770
Vinyl Acetate
<0.224
pg/m3
0.224
1.76
1
06/30/22 12:01
ENM
V20770
Vinyl Chloride
<0.127
pg/m3
0.127
1.28
1
06/30/22 12:01
ENM
V20770
o-Xylene
2.37
pg/m3
0.157
2.17
1
06/30/22 12:01
ENM
V20770
m,p-Xylene
7.19
pg/m3
0.217
5.65
1
06/30/22 12:01
ENM
V20770
Xylene (Total)
9.56
pg/m3
0.157
2.17
1
06/30/22 12:01
V20770
Surrogate:4-Bromofluorobenzene
104
Limits:70-130%
1 06/30/22 12:01 ENM
V20770
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 15 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92998 Matrix: Air
Sample ID: SG-9 Sampled: 6/22/2022 16:10
Analytical Method: TO-15 Prep Batch(es): V20769 06/30/22 09:00
Prep Method: TO-15 Prep
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Acetone
65.3
pg/m3
0.202
4.75
1
06/30/22 12:53
ENM
V20770
Benzene
1.92
pg/m3
0.0733
1.60
1
06/30/22 12:53
ENM
V20770
Benzyl Chloride
<0.148
pg/m3
0.148
10.4
1
06/30/22 12:53
ENM
V20770
Bromodichloromethane
<0.150
pg/m3
0.150
3.35
1
06/30/22 12:53
ENM
V20770
Bromoform
<0.153
pg/m3
0.153
5.17
1
06/30/22 12:53
ENM
V20770
Bromomethane
<0.115
pg/m3
0.115
1.94
1
06/30/22 12:53
ENM
V20770
1,3-Butadiene
0.7853
pg/m3
0.328
1.11
1
06/30/22 12:53
ENM
V20770
Carbon Disulfide
1.35 J
pg/m3
0.0608
6.23
1
06/30/22 12:53
ENM
V20770
Carbon Tetrachloride
<0.155
pg/m3
0.155
3.15
1
06/30/22 12:53
ENM
V20770
Chlorobenzene
<0.107
pg/m3
0.107
2.30
1
06/30/22 12:53
ENM
V20770
Chlorodibromomethane
<0.208
pg/m3
0.208
4.26
1
06/30/22 12:53
ENM
V20770
Chloroethane
<0.164
pg/m3
0.164
1.32
1
06/30/22 12:53
ENM
V20770
Chloroform
1.163
pg/m3
0.0864
2.44
1
06/30/22 12:53
ENM
V20770
Chloromethane
<0.0673
pg/m3
0.0673
1.03
1
06/30/22 12:53
ENM
V20770
Cyclohexane
<0.161
pg/m3
0.161
3.44
1
06/30/22 12:53
ENM
V20770
1,2-Dibromoethane
<0.151
pg/m3
0.151
3.84
1
06/30/22 12:53
ENM
V20770
1,2-Dichlorobenzene
<0.0963
pg/m3
0.0963
3.01
1
06/30/22 12:53
ENM
V20770
1,3-Dichlorobenzene
0.5771
p9/m3
0.174
12.0
1
06/30/22 12:53
ENM
V20770
1,4-Dichlorobenzene
<0.186
pg/m3
0.186
3.01
1
06/30/22 12:53
ENM
V20770
Dichlorodifluoromethane
2.90
pg/m3
0.134
2.47
1
06/30/22 12:53
ENM
V20770
1,1-Dichloroethane
<0.101
pg/m3
0.101
2.02
1
06/30/22 12:53
ENM
V20770
1,2-Dichloroethane
<0.129
pg/m3
0.129
2.02
1
06/30/22 12:53
ENM
V20770
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 16 of 31
Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01139
Mid -Atlantic Associates, Inc. - Raleigh Project R3641.00 Original Report Date : 07/01/2022
Kevin Clay Revised Report Date: 07/14/2022
409 Rogers View Court Information : Received : 06/24/2022
Raleigh , NC 27610
Report Number : 22-175-9007 REPOR T OF A NA L YSIS
Lab No : 92998 Matrix: Air
Sample ID: SG-9 Sampled: 6/22/2022 16:10
Analytical Method: TO-15 Prep Batch(es): V20769 06/30/22 09:00
Prep Method: TO-15 Prep
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
1,1-Dichloroethene
<0.107
p9/m3
0.107
1.98
1
06/30/22 12:53
ENM
V20770
cis- 1,2-Dich loroethene
<0.0955
p9/m3
0.0955
1.98
1
06/30/22 12:53
ENM
V20770
trans-1,2-Dichloroethene
<0.108
p9/m3
0.108
1.98
1
06/30/22 12:53
ENM
V20770
1,2-Dichloropropane
<0.205
p9/m3
0.205
2.31
1
06/30/22 12:53
ENM
V20770
1,2-Dichlorotetrafluoroethane
<0.623
p9/m3
0.623
3.50
1
06/30/22 12:53
ENM
V20770
cis- 1,3-Dich loropropene
<0.178
p9/m3
0.178
2.27
1
06/30/22 12:53
ENM
V20770
trans-1,3-Dichloropropene
<0.178
p9/m3
0.178
2.27
1
06/30/22 12:53
ENM
V20770
1,4-Dioxane
<0.435
p9/m3
0.435
1.80
1
06/30/22 12:53
ENM
V20770
Ethyl Acetate
<0.136
p9/m3
0.136
1.80
1
06/30/22 12:53
ENM
V20770
Ethylbenzene
1.671
pg/m3
0.106
2.17
1
06/30/22 12:53
ENM
V20770
4-Ethyltoluene
0.6293
p9/m3
0.128
2.46
1
06/30/22 12:53
ENM
V20770
1,1,2-Trichloro-1,2,2-trifluoroethane
<0.561
pg/m3
0.561
3.83
1
06/30/22 12:53
ENM
V20770
Heptane
4.73
p9/m3
0.143
2.05
1
06/30/22 12:53
ENM
V20770
Hexachlorobutadiene
<0.330
p9/m3
0.330
5.33
1
06/30/22 12:53
ENM
V20770
n-Hexane
8.00
p9/m3
0.0472
1.76
1
06/30/22 12:53
ENM
V20770
2-Hexanone
1.79 J
pg/m3
0.285
2.05
1
06/30/22 12:53
ENM
V20770
Isopropyl Alchohol
19.9
p9/m3
0.139
4.92
1
06/30/22 12:53
ENM
V20770
Methyl Ethyl Ketone (MEK)
9.75
pg/m3
0.224
1.47
1
06/30/22 12:53
ENM
V20770
Methyl tert-butyl ether (MTBE)
<0.0336
pg/m3
0.0336
1.80
1
06/30/22 12:53
ENM
V20770
4-Methyl-2-Pentanone
1.20 J
pg/m3
0.121
2.05
1
06/30/22 12:53
ENM
V20770
Methylene Chloride
1.09 J
pg/m3
0.489
1.74
1
06/30/22 12:53
ENM
V20770
Naphthalene
0.587 J
pg/m3
0.183
2.62
1
06/30/22 12:53
ENM
V20770
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 17 of 31
WavDdibnto
ANALYTICAL
01139
Mid -Atlantic Associates, Inc. - Raleigh
Kevin Clay
409 Rogers View Court
Raleigh , NC 27610
Report Number : 22-175-9007
Project R3641.00
Information :
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lytica Isom
REPORT OF ANAL YSIS
Original Report Date : 07/01/2022
Revised Report Date: 07/14/2022
Received : 06/24/2022
Lab No : 92998
Matrix: Air
Sample ID: SG-9
Sampled:
6/22/2022
16:10
Analytical Method: TO-15
Prep Batch(es):
V20769
06/30/22 09:00
Prep Method: TO-15 Prep
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Propene
13.0
pg/m3
0.242
0.861
1
06/30/22 12:53
ENM
V20770
Styrene
0.5153
pg/m3
0.124
2.13
1
06/30/22 12:53
ENM
V20770
1,1,2,2-Tetrachloroethane
<0.104
pg/m3
0.104
3.43
1
06/30/22 12:53
ENM
V20770
Tetrachloroethene
13.6
pg/m3
0.181
3.39
1
06/30/22 12:53
ENM
V20770
Tetrahydrofuran
<0.107
pg/m3
0.107
1.47
1
06/30/22 12:53
ENM
V20770
Toluene
7.95
pg/m3
0.0901
1.88
1
06/30/22 12:53
ENM
V20770
1,2,4-Trichlorobenzene
<0.209
pg/m3
0.209
3.71
1
06/30/22 12:53
ENM
V20770
1,1,1-Trichloroethane
0.475 J
pg/m3
0.144
2.73
1
06/30/22 12:53
ENM
V20770
1,1,2-Trichloroethane
<0.0877
pg/m3
0.0877
2.73
1
06/30/22 12:53
ENM
V20770
Trichloroethene
<0.199
pg/m3
0.199
2.15
1
06/30/22 12:53
ENM
V20770
Trichlorofluoromethane
2.76 J
pg/m3
0.130
2.81
1
06/30/22 12:53
ENM
V20770
1,2,4-Trimethyl benzene
1.943
pg/m3
0.110
2.46
1
06/30/22 12:53
ENM
V20770
1,3,5-Trimethyl benzene
0.487 J
pg/m3
0.236
2.46
1
06/30/22 12:53
ENM
V20770
Vinyl Acetate
<0.224
pg/m3
0.224
1.76
1
06/30/22 12:53
ENM
V20770
Vinyl Chloride
<0.127
pg/m3
0.127
1.28
1
06/30/22 12:53
ENM
V20770
o-Xylene
1.74 J
pg/m3
0.157
2.17
1
06/30/22 12:53
ENM
V20770
m,p-Xylene
5.99
pg/m3
0.217
5.65
1
06/30/22 12:53
ENM
V20770
Xylene (Total)
7.73 J
pg/m3
0.157
2.17
1
06/30/22 12:53
V20770
Surrogate:4-Bromofluorobenzene
104
Limits:70-130%
1 06/30/22 12:53 ENM
V20770
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation
Limit
Page 18 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20612
QC Prep Batch Method: TO-15 Prep
QC Analytical Batch(es): V20630
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
Lab Reagent Blank LRB-V20612 Matrix: AIR
Associated Lab Samples: 92995, 92996
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/m3
<0.202
0.202
4.75
06/27/22 13:34
Benzene
pg/m3
<0.0733
0.0733
1.60
06/27/22 13:34
Benzyl Chloride
pg/m3
<0.148
0.148
10.4
06/27/22 13:34
Bromodichloromethane
pg/m3
<0.150
0.150
3.35
06/27/22 13:34
Bromoform
pg/m3
<0.153
0.153
5.17
06/27/22 13:34
Bromomethane
pg/m3
<0.115
0.115
1.94
06/27/22 13:34
1,3-Butadiene
pg/m3
<0.328
0.328
1.11
06/27/22 13:34
Carbon Disulfide
pg/m3
<0.0608
0.0608
6.23
06/27/22 13:34
Carbon Tetrachloride
pg/m3
<0.155
0.155
3.15
06/27/22 13:34
Chlorobenzene
pg/m3
<0.107
0.107
2.30
06/27/22 13:34
Chlorodibromomethane
pg/m3
<0.208
0.208
4.26
06/27/22 13:34
Chloroethane
pg/m3
<0.164
0.164
1.32
06/27/22 13:34
Chloroform
pg/m3
<0.0864
0.0864
2.44
06/27/22 13:34
Chloromethane
pg/m3
<0.0673
0.0673
1.03
06/27/22 13:34
Cyclohexane
pg/m3
<0.161
0.161
3.44
06/27/22 13:34
1,2-Dibromoethane
pg/m3
<0.151
0.151
3.84
06/27/22 13:34
1,2-Dichlorobenzene
pg/m3
<0.0963
0.0963
3.01
06/27/22 13:34
1,3-Dichlorobenzene
pg/m3
<0.174
0.174
12.0
06/27/22 13:34
1,4-Dichlorobenzene
pg/m3
<0.186
0.186
3.01
06/27/22 13:34
Dichlorodifluoromethane
pg/m3
<0.134
0.134
2.47
06/27/22 13:34
1,1-Dichloroethane
pg/m3
<0.101
0.101
2.02
06/27/22 13:34
1,2-Dichloroethane
pg/m3
<0.129
0.129
2.02
06/27/22 13:34
1,1-Dichloroethene
pg/m3
<0.107
0.107
1.98
06/27/22 13:34
cis- 1,2-Dichloroethene
pg/m3
<0.0955
0.0955
1.98
06/27/22 13:34
trans-1,2-Dichloroethene
pg/m3
<0.108
0.108
1.98
06/27/22 13:34
1,2-Dichloropropane
pg/m3
<0.205
0.205
2.31
06/27/22 13:34
1,2-Dichlorotetrafluoroethane
pg/m3
<0.623
0.623
3.50
06/27/22 13:34
Date:
07/14/2022 02:22 PM
Page 1 of 10
Page 19 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20612
QC Prep Batch Method: TO-15 Prep
QC Analytical Batch(es): V20630
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
Lab Reagent Blank LRB-V20612 Matrix: AIR
Associated Lab Samples: 92995, 92996
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
cis-1,3-Dichloropropene
pg/m3
<0.178
0.178
2.27
06/27/22 13:34
trans-1,3-Dichloropropene
pg/m3
<0.178
0.178
2.27
06/27/22 13:34
1,4-Dioxane
pg/m3
<0.435
0.435
1.80
06/27/22 13:34
Ethyl Acetate
pg/m3
<0.136
0.136
1.80
06/27/22 13:34
Ethylbenzene
pg/m3
<0.106
0.106
2.17
06/27/22 13:34
4-Ethyltoluene
pg/m3
<0.128
0.128
2.46
06/27/22 13:34
1,1,2-Trichloro-1,2,2-trifluoroethane
pg/m3
<0.561
0.561
3.83
06/27/22 13:34
Heptane
pg/m3
<0.143
0.143
2.05
06/27/22 13:34
Hexachlorobutadiene
pg/m3
<0.330
0.330
5.33
06/27/22 13:34
n-Hexane
pg/m3
<0.0472
0.0472
1.76
06/27/22 13:34
2-Hexanone
pg/m3
<0.285
0.285
2.05
06/27/22 13:34
Isopropyl Alchohol
pg/m3
<0.139
0.139
4.92
06/27/22 13:34
Methyl Ethyl Ketone (MEK)
pg/m3
<0.224
0.224
1.47
06/27/22 13:34
Methyl tert-butyl ether (MTBE)
pg/m3
<0.0336
0.0336
1.80
06/27/22 13:34
4-Methyl-2-Pentanone
pg/m3
<0.121
0.121
2.05
06/27/22 13:34
Methylene Chloride
pg/m3
<0.489
0.489
1.74
06/27/22 13:34
Naphthalene
pg/m3
<0.183
0.183
2.62
06/27/22 13:34
Propene
pg/m3
<0.242
0.242
0.861
06/27/22 13:34
Styrene
pg/m3
<0.124
0.124
2.13
06/27/22 13:34
1,1,2,2-Tetrachloroethane
pg/m3
<0.104
0.104
3.43
06/27/22 13:34
Tetrachloroethene
pg/m3
<0.181
0.181
3.39
06/27/22 13:34
Tetrahydrofuran
pg/m3
<0.107
0.107
1.47
06/27/22 13:34
Toluene
pg/m3
<0.0901
0.0901
1.88
06/27/22 13:34
1,2,4-Trichlorobenzene
pg/m3
<0.209
0.209
3.71
06/27/22 13:34
1,1,1-Trichloroethane
pg/m3
<0.144
0.144
2.73
06/27/22 13:34
1,1,2-Trichloroethane
pg/m3
<0.0877
0.0877
2.73
06/27/22 13:34
Trichloroethene
pg/m3
<0.199
0.199
2.15
06/27/22 13:34
Date:
07/14/2022 02:22 PM
Page 2 of 10
Page 20 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Mid -Atlantic Associates, Inc. - Raleigh
Project Description:
R3641.00
Report No:
22-175-9007
QC Prep:
V20612
QC Analytical Batch(es): V20630
QC Prep Batch Method:
TO-15 Prep
Analysis Method:
TO-15
Analysis Description:
Volatile Organic
Compounds in Air- GC/MS
Lab Reagent Blank
LRB-V20612
Matrix: AIR
Associated Lab Samples:
92995, 92996
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
Trichlorofluoromethane
pg/m3
<0.130
0.130
2.81
06/27/22 13:34
1,2,4-Trimethyl benzene
pg/m3
<0.110
0.110
2.46
06/27/22 13:34
1,3,5-Trimethyl benzene
pg/m3
<0.236
0.236
2.46
06/27/22 13:34
Vinyl Acetate
pg/m3
<0.224
0.224
1.76
06/27/22 13:34
Vinyl Chloride
pg/m3
<0.127
0.127
1.28
06/27/22 13:34
o-Xylene
pg/m3
<0.157
0.157
2.17
06/27/22 13:34
m,p-Xylene
pg/m3
<0.217
0.217
5.65
06/27/22 13:34
4-Bromofluorobenzene (S)
06/27/22 13:34
99.7 70-130
Laboratory Control Sample
LCS-V20612
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Acetone
pg/m3
11.9
11.2
94.1
70-130
Benzene
pg/m3
16.0
15.9
99.3
70-130
Benzyl Chloride
pg/m3
25.9
28.0
108
70-130
Bromodichloromethane
pg/m3
33.5
33.7
101
70-130
Bromoform
pg/m3
51.7
54.4
105
70-130
Bromomethane
pg/m3
19.4
19.7
102
70-130
1,3-Butadiene
pg/m3
11.1
11.4
103
70-130
Carbon Disulfide
pg/m3
15.6
16.3
104
70-130
Carbon Tetrachloride
pg/m3
31.5
30.5
96.8
70-130
Chlorobenzene
pg/m3
23.0
23.6
103
70-130
Chlorodibromomethane
pg/m3
42.6
43.9
103
70-130
Chloroethane
pg/m3
13.2
12.8
96.9
70-130
Chloroform
pg/m3
24.4
24.2
99.1
70-130
Chloromethane
pg/m3
10.3
10.4
101
70-130
Cyclohexane
pg/m3
17.2
16.5
95.9
70-130
Date: 07/14/2022 02:22 PM
Page 3 of 10
Page 21 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20612
QC Prep Batch Method: TO-15 Prep
Laboratory Control Sample
Parameter
QC Analytical Batch(es): V20630
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
LCS-V20612
Spike LCS LCS %Rec % Rec
Units Conc. Result Limits
1,2-Dibromoethane
pg/m3
38.4
39.5
103
70-130
1,2-Dichlorobenzene
pg/m3
30.1
30.0
99.6
70-130
1,3-Dichlorobenzene
pg/m3
30.1
29.6
98.3
70-130
1,4-Dichlorobenzene
pg/m3
30.1
28.6
95.0
70-130
Dichlorodifluoromethane
pg/m3
24.7
24.6
99.5
70-130
1,1-Dichloroethane
pg/m3
20.2
20.7
102
70-130
1,2-Dichloroethane
pg/m3
20.2
20.2
100
70-130
1,1-Dichloroethene
pg/m3
19.8
21.0
106
70-130
cis-1,2-Dichloroethene
pg/m3
19.8
20.6
104
70-130
trans-1,2-Dichloroethene
pg/m3
19.8
20.9
106
70-130
1,2-Dichloropropane
pg/m3
23.1
23.2
100
70-130
1,2-Dichlorotetrafluoroethane
pg/m3
35.0
33.4
95.4
70-130
cis-1,3-Dichloropropene
pg/m3
22.7
23.1
102
70-130
trans-1,3-Dichloropropene
pg/m3
22.7
23.1
102
70-130
1,4-Dioxane
pg/m3
18.0
16.1
89.4
70-130
Ethyl Acetate
pg/m3
18.0
17.9
99.4
70-130
Ethylbenzene
pg/m3
21.7
22.4
103
70-130
4-Ethyltoluene
pg/m3
24.6
26.1
106
70-130
1,1,2-Trichloro-1,2,2-trifluoroethane
pg/m3
38.3
38.3
100
70-130
Heptane
pg/m3
20.5
21.4
104
70-130
Hexachlorobutadiene
pg/m3
53.3
52.0
97.5
70-130
n-Hexane
pg/m3
17.6
18.0
102
70-130
2-Hexanone
pg/m3
20.5
18.6
90.7
70-130
Isopropyl Alchohol
pg/m3
12.3
12.6
102
70-130
Methyl Ethyl Ketone (MEK)
pg/m3
14.8
14.5
97.9
70-130
Methyl tert-butyl ether (MTBE)
pg/m3
18.0
17.4
96.6
70-130
4-Methyl-2-Pentanone
pg/m3
20.5
19.4
94.6
70-130
Date: 07/14/2022 02:22 PM Page 4 of 10
Page 22 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20612
QC Prep Batch Method: TO-15 Prep
Laboratory Control Sample
Parameter
QC Analytical Batch(es): V20630
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
LCS-V20612
Spike LCS LCS %Rec % Rec
Units Conc. Result Limits
Methylene Chloride
pg/m3
17.4
16.7
95.9
70-130
Naphthalene
pg/m3
26.2
29.9
114
70-130
Propene
pg/m3
8.61
8.54
99.1
70-130
Styrene
pg/m3
21.3
23.2
109
70-130
1,1,2,2-Tetrachloroethane
pg/m3
34.3
35.5
103
70-130
Tetrachloroethene
pg/m3
33.9
34.2
101
70-130
Tetrahydrofuran
pg/m3
14.7
14.8
101
70-130
Toluene
pg/m3
18.8
19.5
104
70-130
1,2,4-Trichlorobenzene
pg/m3
37.1
37.9
102
70-130
1,1,1-Trichloroethane
pg/m3
27.3
26.4
96.7
70-130
1,1,2-Trichloroethane
pg/m3
27.3
27.6
101
70-130
Trichloroethene
pg/m3
26.9
26.1
97.0
70-130
Trichlorofluoromethane
pg/m3
28.1
29.1
104
70-130
1,2,4-Trimethyl benzene
pg/m3
24.6
25.8
105
70-130
1,3,5-Trimethyl benzene
pg/m3
24.6
26.7
109
70-130
Vinyl Acetate
pg/m3
17.6
18.9
107
70-130
Vinyl Chloride
pg/m3
12.8
12.3
96.0
70-130
o-Xylene
pg/m3
21.7
22.6
104
70-130
m,p-Xylene
pg/m3
43.4
44.0
101
70-130
4-Bromofluorobenzene (S)
99.4
70-130
Date: 07/14/2022 02:22 PM Page 5 of 10
Page 23 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20769
QC Prep Batch Method: TO-15 Prep
QC Analytical Batch(es): V20770
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
Lab Reagent Blank LRB-V20769 Matrix: AIR
Associated Lab Samples: 92997, 92998
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/m3
<0.202
0.202
4.75
06/30/22 11:05
Benzene
pg/m3
<0.0733
0.0733
1.60
06/30/22 11:05
Benzyl Chloride
pg/m3
<0.148
0.148
10.4
06/30/22 11:05
Bromodichloromethane
pg/m3
<0.150
0.150
3.35
06/30/22 11:05
Bromoform
pg/m3
<0.153
0.153
5.17
06/30/22 11:05
Bromomethane
pg/m3
<0.115
0.115
1.94
06/30/22 11:05
1,3-Butadiene
pg/m3
<0.328
0.328
1.11
06/30/22 11:05
Carbon Disulfide
pg/m3
<0.0608
0.0608
6.23
06/30/22 11:05
Carbon Tetrachloride
pg/m3
<0.155
0.155
3.15
06/30/22 11:05
Chlorobenzene
pg/m3
<0.107
0.107
2.30
06/30/22 11:05
Chlorodibromomethane
pg/m3
<0.208
0.208
4.26
06/30/22 11:05
Chloroethane
pg/m3
<0.164
0.164
1.32
06/30/22 11:05
Chloroform
pg/m3
<0.0864
0.0864
2.44
06/30/22 11:05
Chloromethane
pg/m3
<0.0673
0.0673
1.03
06/30/22 11:05
Cyclohexane
pg/m3
<0.161
0.161
3.44
06/30/22 11:05
1,2-Dibromoethane
pg/m3
<0.151
0.151
3.84
06/30/22 11:05
1,2-Dichlorobenzene
pg/m3
<0.0963
0.0963
3.01
06/30/22 11:05
1,3-Dichlorobenzene
pg/m3
<0.174
0.174
12.0
06/30/22 11:05
1,4-Dichlorobenzene
pg/m3
<0.186
0.186
3.01
06/30/22 11:05
Dichlorodifluoromethane
pg/m3
<0.134
0.134
2.47
06/30/22 11:05
1,1-Dichloroethane
pg/m3
<0.101
0.101
2.02
06/30/22 11:05
1,2-Dichloroethane
pg/m3
<0.129
0.129
2.02
06/30/22 11:05
1,1-Dichloroethene
pg/m3
<0.107
0.107
1.98
06/30/22 11:05
cis- 1,2-Dichloroethene
pg/m3
<0.0955
0.0955
1.98
06/30/22 11:05
trans-1,2-Dichloroethene
pg/m3
<0.108
0.108
1.98
06/30/22 11:05
1,2-Dichloropropane
pg/m3
<0.205
0.205
2.31
06/30/22 11:05
1,2-Dichlorotetrafluoroethane
pg/m3
<0.623
0.623
3.50
06/30/22 11:05
Date:
07/14/2022 02:22 PM
Page 6 of 10
Page 24 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20769
QC Prep Batch Method: TO-15 Prep
QC Analytical Batch(es): V20770
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
Lab Reagent Blank LRB-V20769 Matrix: AIR
Associated Lab Samples: 92997, 92998
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
cis-1,3-Dichloropropene
pg/m3
<0.178
0.178
2.27
06/30/22 11:05
trans-1,3-Dichloropropene
pg/m3
<0.178
0.178
2.27
06/30/22 11:05
1,4-Dioxane
pg/m3
<0.435
0.435
1.80
06/30/22 11:05
Ethyl Acetate
pg/m3
<0.136
0.136
1.80
06/30/22 11:05
Ethylbenzene
pg/m3
<0.106
0.106
2.17
06/30/22 11:05
4-Ethyltoluene
pg/m3
<0.128
0.128
2.46
06/30/22 11:05
1,1,2-Trichloro-1,2,2-trifluoroethane
pg/m3
<0.561
0.561
3.83
06/30/22 11:05
Heptane
pg/m3
<0.143
0.143
2.05
06/30/22 11:05
Hexachlorobutadiene
pg/m3
<0.330
0.330
5.33
06/30/22 11:05
n-Hexane
pg/m3
<0.0472
0.0472
1.76
06/30/22 11:05
2-Hexanone
pg/m3
<0.285
0.285
2.05
06/30/22 11:05
Isopropyl Alchohol
pg/m3
0.211
0.139
4.92
06/30/22 11:05
Methyl Ethyl Ketone (MEK)
pg/m3
<0.224
0.224
1.47
06/30/22 11:05
Methyl tert-butyl ether (MTBE)
pg/m3
<0.0336
0.0336
1.80
06/30/22 11:05
4-Methyl-2-Pentanone
pg/m3
<0.121
0.121
2.05
06/30/22 11:05
Methylene Chloride
pg/m3
<0.489
0.489
1.74
06/30/22 11:05
Naphthalene
pg/m3
<0.183
0.183
2.62
06/30/22 11:05
Propene
pg/m3
<0.242
0.242
0.861
06/30/22 11:05
Styrene
pg/m3
<0.124
0.124
2.13
06/30/22 11:05
1,1,2,2-Tetrachloroethane
pg/m3
<0.104
0.104
3.43
06/30/22 11:05
Tetrachloroethene
pg/m3
<0.181
0.181
3.39
06/30/22 11:05
Tetrahydrofuran
pg/m3
<0.107
0.107
1.47
06/30/22 11:05
Toluene
pg/m3
<0.0901
0.0901
1.88
06/30/22 11:05
1,2,4-Trichlorobenzene
pg/m3
<0.209
0.209
3.71
06/30/22 11:05
1,1,1-Trichloroethane
pg/m3
<0.144
0.144
2.73
06/30/22 11:05
1,1,2-Trichloroethane
pg/m3
<0.0877
0.0877
2.73
06/30/22 11:05
Trichloroethene
pg/m3
<0.199
0.199
2.15
06/30/22 11:05
Date:
07/14/2022 02:22 PM
Page 7 of 10
Page 25 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Mid -Atlantic Associates, Inc. - Raleigh
Project Description:
R3641.00
Report No:
22-175-9007
QC Prep:
V20769
QC Analytical Batch(es): V20770
QC Prep Batch Method:
TO-15 Prep
Analysis Method:
TO-15
Analysis Description:
Volatile Organic
Compounds in Air- GC/MS
Lab Reagent Blank
LRB-V20769
Matrix: AIR
Associated Lab Samples:
92997, 92998
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
Trichlorofluoromethane
pg/m3
<0.130
0.130
2.81
06/30/22 11:05
1,2,4-Trimethyl benzene
pg/m3
<0.110
0.110
2.46
06/30/22 11:05
1,3,5-Trimethyl benzene
pg/m3
<0.236
0.236
2.46
06/30/22 11:05
Vinyl Acetate
pg/m3
<0.224
0.224
1.76
06/30/22 11:05
Vinyl Chloride
pg/m3
<0.127
0.127
1.28
06/30/22 11:05
o-Xylene
pg/m3
<0.157
0.157
2.17
06/30/22 11:05
m,p-Xylene
pg/m3
<0.217
0.217
5.65
06/30/22 11:05
4-Bromofluorobenzene (S)
06/30/22 11:05
106 70-130
Laboratory Control Sample
LCS-V20769
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Acetone
pg/m3
11.9
11.1
93.2
70-130
Benzene
pg/m3
16.0
18.8
118
70-130
Benzyl Chloride
pg/m3
25.9
31.8
123
70-130
Bromodichloromethane
pg/m3
33.5
38.9
116
70-130
Bromoform
pg/m3
51.7
60.4
117
70-130
Bromomethane
pg/m3
19.4
21.7
112
70-130
1,3-Butadiene
pg/m3
11.1
12.0
108
70-130
Carbon Disulfide
pg/m3
15.6
17.8
114
70-130
Carbon Tetrachloride
pg/m3
31.5
35.4
112
70-130
Chlorobenzene
pg/m3
23.0
26.5
115
70-130
Chlorodibromomethane
pg/m3
42.6
47.8
112
70-130
Chloroethane
pg/m3
13.2
14.0
106
70-130
Chloroform
pg/m3
24.4
28.2
116
70-130
Chloromethane
pg/m3
10.3
10.8
105
70-130
Cyclohexane
pg/m3
17.2
20.0
116
70-130
Date: 07/14/2022 02:22 PM
Page 8 of 10
Page 26 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20769
QC Prep Batch Method: TO-15 Prep
Laboratory Control Sample
Parameter
QC Analytical Batch(es): V20770
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
LCS-V20769
Spike LCS LCS %Rec % Rec
Units Conc. Result Limits
1,2-Dibromoethane
pg/m3
38.4
44.6
116
70-130
1,2-Dichlorobenzene
pg/m3
30.1
32.6
108
70-130
1,3-Dichlorobenzene
pg/m3
30.1
32.4
108
70-130
1,4-Dichlorobenzene
pg/m3
30.1
31.3
104
70-130
Dichlorodifluoromethane
pg/m3
24.7
26.3
106
70-130
1,1-Dichloroethane
pg/m3
20.2
22.3
110
70-130
1,2-Dichloroethane
pg/m3
20.2
23.1
114
70-130
1,1-Dichloroethene
pg/m3
19.8
21.9
111
70-130
cis-1,2-Dichloroethene
pg/m3
19.8
22.4
113
70-130
trans-1,2-Dichloroethene
pg/m3
19.8
22.2
112
70-130
1,2-Dichloropropane
pg/m3
23.1
26.6
115
70-130
1,2-Dichlorotetrafluoroethane
pg/m3
35.0
37.3
107
70-130
cis-1,3-Dichloropropene
pg/m3
22.7
26.8
118
70-130
trans-1,3-Dichloropropene
pg/m3
22.7
26.8
118
70-130
1,4-Dioxane
pg/m3
18.0
18.9
105
70-130
Ethyl Acetate
pg/m3
18.0
18.9
105
70-130
Ethylbenzene
pg/m3
21.7
26.1
120
70-130
4-Ethyltoluene
pg/m3
24.6
29.9
122
70-130
1,1,2-Trichloro-1,2,2-trifluoroethane
pg/m3
38.3
42.4
111
70-130
Heptane
pg/m3
20.5
23.4
114
70-130
Hexachlorobutadiene
pg/m3
53.3
57.9
109
70-130
n-Hexane
pg/m3
17.6
20.0
114
70-130
2-Hexanone
pg/m3
20.5
20.3
99.0
70-130
Isopropyl Alchohol
pg/m3
12.3
13.1
107
70-130
Methyl Ethyl Ketone (MEK)
pg/m3
14.8
15.2
103
70-130
Methyl tert-butyl ether (MTBE)
pg/m3
18.0
19.7
109
70-130
4-Methyl-2-Pentanone
pg/m3
20.5
21.7
106
70-130
Date: 07/14/2022 02:22 PM Page 9 of 10
Page 27 of 31
Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Mid -Atlantic Associates, Inc. - Raleigh
Project Description: R3641.00
Report No: 22-175-9007
QC Prep: V20769
QC Prep Batch Method: TO-15 Prep
Laboratory Control Sample
Parameter
QC Analytical Batch(es): V20770
Analysis Method: TO-15
Analysis Description: Volatile Organic Compounds in Air- GC/MS
LCS-V20769
Spike LCS LCS %Rec % Rec
Units Conc. Result Limits
Methylene Chloride
pg/m3
17.4
16.9
97.1
70-130
Naphthalene
pg/m3
26.2
30.9
118
70-130
Propene
pg/m3
8.61
8.84
103
70-130
Styrene
pg/m3
21.3
26.4
124
70-130
1,1,2,2-Tetrachloroethane
pg/m3
34.3
40.3
117
70-130
Tetrachloroethene
pg/m3
33.9
39.2
116
70-130
Tetrahydrofuran
pg/m3
14.7
15.8
107
70-130
Toluene
pg/m3
18.8
23.0
122
70-130
1,2,4-Trichlorobenzene
pg/m3
37.1
43.0
116
70-130
1,1,1-Trichloroethane
pg/m3
27.3
31.1
114
70-130
1,1,2-Trichloroethane
pg/m3
27.3
31.2
114
70-130
Trichloroethene
pg/m3
26.9
31.0
115
70-130
Trichlorofluoromethane
pg/m3
28.1
30.9
110
70-130
1,2,4-Trimethyl benzene
pg/m3
24.6
29.2
119
70-130
1,3,5-Trimethyl benzene
pg/m3
24.6
30.4
124
70-130
Vinyl Acetate
pg/m3
17.6
21.0
119
70-130
Vinyl Chloride
pg/m3
12.8
13.5
105
70-130
o-Xylene
pg/m3
21.7
26.1
120
70-130
m,p-Xylene
pg/m3
43.4
53.0
122
70-130
4-Bromofluorobenzene (S)
106
70-130
Date: 07/14/2022 02:22 PM Page 10 of 10
Page 28 of 31
WayPAoint.
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01139
Customer Name: Mid -Atlantic Associates, Inc. - Raleigh
Report Number: 22-175-0007
Shipping Method
0 Fed Ex 0 US Postal 0 Lab 0 Other:
0 UPS 0 Client # Courier Thermometer ID: N/A
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
U Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
U Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F Low concentration EnCore samplers (48 hr)
Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Angelo Norvell Date & Time: 06/24/2022 15:55:06
Page 29 of 31
I
Waypoint_
Q)
ANALYTICAL
T015 Air Analysis
Chain of Custody
449 Springbrook Rd
Charlotte, NC 29217
Office: (704) 529-6364
Company Name:
voice to:
Project Name:
Contact Name: ✓1,?
voice Contact:
Site Name: 171
Address: �—jpCry�Cw G� p ,�
I— F
Invoice Address:
Site Location:
Project Number: 34:-r I oa
Iz 7 ,(/G
16�G
Phone #: G'a
<'
Tnvoice Phone #:
Purchase Order #:
Email: �G� Q
Invoice Email:
Quote M
Sampler's Name (Print):
Sampler's Signature:
Turn Around Time:
�� Day(s)
Page: Of
"Mow Controller and
Lab Use Only
Client Sampling Information
Canister Certification batch:
Sampling Start Information
Sampling Stop Information
Canister rust be used
togewaras
designated"
Initial Canister
Final
Stop Tine
Sample
Type
Comments
WPA
�
tab
lab
Flow Controller
GI Flow
Canes ID.
Outgoing
Receiving
Start Date
Start Time Pressure
Stop Date (24hr Canister
Code
ikM aciftonN information
ID#:
Client Sample ID
ID:
(vjmin)
v,
ter
Canister
Whr clock)
(in Mg)
Pressure
clock)
ate the site)
Pressure
Pressure
(in Hill)
La
L4
--7
..per
.3]4
6
E�1/"'�
6
-30
--
Z
-1q.5
�
?yu
2)
-
37a,�
L4
aq
-jDz
473r
.Zq`�
CYLL
Is3�
6
'T
3
fL A� (�
Z
L4
4)
6
Sample Type Codes: AA= Indoor/Ambient Air SG= Soil Gas LV= Landfill/Vent Gas OT= Other _
Relinquish
Date / Time:
Reced:
Date / Time:
� z,/ z'z2w
Relinquished:
Date Time:
ed:
Date/Time:
` �z-17Sa007
1�1�1 I�h l�1�lII��I 11�II�IN�fl�� � =Z
RAid Atf®nlicAswcvates. Inc. Rak"oh 15:43:30
R3641.00
Relinquished:
Date / Time:
Received:
to / Tlme:
1'f Ks�
Rev. 0 9122120
Page 30 of 31
449 Springbrook Rd
Waypoint T015 Air Analysis Charlotte, NC 28217
ANALYTICAL Chain of Custody Office: (704) 529-6364
Company Name:
Invoice to:
Project Name:
Contact Name:
Invoice Contact:
Site Name:
Address:
i^
.�.- I
Invoice Address:.
Site Location:
Project Number:
Phone f1:
Invoice Phone M:
Purchase Order q:
Email:
Invoice Email:
Quote M:
Sampler's Name (Print):
r
&e
Sampler's Signature:
Turn Around Time:
Page: Of
I/
� -
Day(s)
"Plow Casrtrvikr and
Lab Use Only
Client Sampling Information
Canister Certification Batch:
Sampling Start Information
Sampling Stop Information
C6nhw AVOW be used
r
de*nated"
In" Canis
Final
Stop Time
Sample
Type
Comments
WPA
lab
Lab
Flow Controller
Cal Flow
Canister ID:
=
outsokq
Receiving
Start Date
Start Time
lrrswe
Canister
Stop Date (24hr
Code
(Arrr addkumal information
IDO:
Client Sample ID
ID:
(cc/min)
Canister
Canister
(2Ahr clocki (lo Hill
dock) Preswre
about the ske)
Pnaasare
Pressure
(in Hs)
s
i +�a 3�
al5
l 700
1.4
6
- �
-
z
rd�s
��-7 s
%�
104
--5
M
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13�
6
z)
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143,11
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-0
_
�r2Zl
16��
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q2z
(b �
3)
Zit
Z/C
L4
4)
6
Sample Type Codes: AA= Indoor/Ambient Air SG= Soil Gas LV= Landfill/Vent Gas OT= Other i
Relinquished:
Date / Time:
Received:
Date / Time:/
L
Relinquished:
zz- Date
Date /Time:
tved:
j
Date /Time:
11�nN�1l1111 �IIIInII�I 01139
! 11111111! i� � oa�2tr:
Nid /itiwrtic Asa;ciaies. Inc. Rakrioh 15:43:30
Relinquished:
Date /rime:
Received:
Date / Time:
R3641.00
Zz ry
PAv. 0 9/22/20
Page 31 of
APPENDIX B
RISK CALCUATIONS
Mid Atlantic
North Carolina Department of Environmental Quality
Risk Calculator
Version Date:
January 2022
Basis:
November 2021 EPA RSL Table
Site Name:
Sonrise Industrial Warehouse
Site Address:
1200 Henry Street
DEQ Section:
Site ID:
Exposure Unit ID:
Submittal Date:
7/6/2022
Prepared By:
Maddie Hook
Kevin Clay
Reviewed By:
North Carolina DEQ Risk Calculator
IDEO Risk Calculator - Vapor Intrusion - Resident Indoor Air
Version Date: January 2022
Basis: November 2021 EPA RSL Table
Site ID:
Exposure Unit ID: &AMEMEMS"A
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic
risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
All concentrations are in uQ/m3
CAS #
Chemical Name:
Indoor Air
Concentration
3
(ug/m)
Target Indoor
Au Conc. for
Carcinogens @
TCR = 1 E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
5.75
71-43-2
Benzene
0.323
3.6E-01
6.3E+00
9.0E-07
1.0E-02
100-44-7
Benzyl Chloride
0.148
5.7E-02
2.1E-01
2.6E-06
1.4E-01
75-27-4
Bromodichloromethane
0.15
7.6E-02
2.0E-06
106-99-0
Butadiene, 1,3-
0.328
9.4E-02
4.2E-01
3.5E-06
1.6E-01
75-15-0
Carbon Disulfide
0.504
1.5E+02
6.9E-04
67-66-3
Chloroform
0.718
1.2E-01
2.0E+01
5.9E-06
7.0E-03
106-93-4
Dibromoethane, 1,2-
0.151
4.7E-03
1.9E+00
3.2E-05
1.6E-02
75-71-8
Dichlorodifluoromethane
2.7
2.1E+01
2.6E-02
107-06-2
Dichloroethane, 1,2-
0.129
1.1E-01
1.5E+00
1.2E-06
1.8E-02
156-59-2
Dichloroethylene, cis-1,2-
0.333
87-68-3
Hexachlorobutadiene
0.33
1.3E-01
2.6E-06
67-63-0
Isopropanol
0.846
4.2E+01
4.1E-03
78-93-3
Methyl Ethyl Ketone (2-Butanone)
1.02
1.0E+03
2.0E-04
75-09-2
Methylene Chloride
0.58
1.0E+02
1.3E+02
5.7E-09
9.3E-04
91-20-3
-Naphthalene
0.598
8.3E-02
6.3E-01
7.2E-06
1.9E-01
79-34-5
Tetrachloroethane, 1,1,2,2-
0.104
4.8E-02
2.1E-06
127-18-4
Tetrachloroethylene
6.61
1.1E+01
8.3E+00
6.1E-07
1.6E-01
108-88-3
Toluene
1.3
1.0E+03
2.5E-04
79-00-5
Trichloroethane, 1,1,2-
0.0877
1.8E-01
4.2E-02
5.0E-07
4.2E-01
79-01-6
Trichloroethylene
0.537
4.8E-01
4.2E-01
1.1E-06
2.6E-01
75-69-4
Trichlorofluoromethane
1.84
Cumulative: I 6.3E-05 I1.4E+00
North Carolina DEQ Risk Calculator
IDEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air r
Version Date: January 2022
Basis: November 2021 EPA RSL Table
ID:
Unit ID:
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic
risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are
likely not associated with vapor intrusion.
All concentrntion- are in nn/m3
CAS #
Chemical Name:
Indoor Air
Concentration
3
(ug/m)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non -
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
5.75
71-43-2
Benzene
0.323
1.6E+00
2.6E+01
2.1E-07
2.5E-03
100-44-7
Benzyl Chloride
0.148
2.5E-01
8.8E-01
5.9E-07
3.4E-02
75-27-4
Bromodichloromethane
0.15
3.3E-01
4.5E-07
106-99-0
Butadiene, 1,3-
0.328
4.1E-01
1.8E+00
8.0E-07
3.7E-02
75-15-0
Carbon Disulfide
0.504
6.1E+02
1.6E-04
67-66-3
Chloroform
0.718
5.3E-01
8.6E+01
1.3E-06
1.7E-03
106-934
Dibromoethane, 1,2-
0.151
2.0E-02
7.9E+00
7.4E-06
3.8E-03
75-71-8
Dichlorodifluoromethane
2.7
8.8E+01
6.2E-03
107-06-2
Dichloroethane, 1,2-
0.129
4.7E-01
6.1E+00
2.7E-07
4.2E-03
156-59-2
Dichloroeth lene, cis-1,2-
0.333
-
87-68-3
Hexachlorobutadiene
0.33
5.6E-01
5.9E-07
67-63-0
Iso ro anol
0.846
1.8E+02
9.7E-04
78-93-3
Methyl Eth 1 Ketone 2-Butanone
1.02
4.4E+03
4.7E-05
75-09-2
Methylene Chloride
0.58
1.2E+03
5.3E+02
4.7E-10
2.2E-04
91-20-3
-Naphthalene
0.598
3.6E-01
2.6E+00
1.7E-06
4.6E-02
79-34-5
Tetrachloroethane, 1,1,2,2-
0.104
2.1E-01
4.9E-07
127-184
Tetrachloroeth lene
6.61
4.7E+01
3.5E+01
1.4E-07
3.8E-02
108-88-3
Toluene
1.3
4.4E+03
5.9E-05
79-01-6
Trichloroeth lene
0.537
3.0E+00
1.8E+00
1.8E-07
6.1E-02
75-694
1 Trichlorofluoromethane
1.84
Cumulative: I 1.4E-05 2.4E-Ol
North Carolina DEQ Risk Calculator
Risk Calculator - Vapor Intrusion - Resident Indoor Air
ersion Date: January 2022
asis: November 2021 EPA RSL Table
to ID:
xnosure Unit ID:
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic
risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals
are likely not associated with vapor intrusion.
All concentrations are in uQ/m3
CAS #
Chemical Name:
Indoor Air
Concentration
3
(ug/m)
Target Indoor
Air Cone. for
Carcinogens @
TCR = 1 E-06
Target Indoor Air
Cone. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
5.75
71-43-2
Benzene
0.323
3.6E-01
6.3E+00
9.0E-07
1.0E-02
75-15-0
Carbon Disulfide
0.504
1.5E+02
6.9E-04
67-66-3
Chloroform
0.718
1.2E-01
2.0E+01
5.9E-06
7.0E-03
75-71-8
Dichlorodifluoromethane
2.7
2.1E+01
2.6E-02
156-59-2
Dichloroethylene, cis-1,2-
0.333
67-63-0
Isopropanol
0.846
1 4.2E+01
4.1E-03
78-93-3
Methyl Ethyl Ketone (2-Butanone)
1.02
1.0E+03
2.0E-04
75-09-2
Methylene Chloride
0.58
1.0E+02
1.3E+02
5.7E-09
9.3E-04
91-20-3
-Naphthalene
0.598
8.3E-02
6.3E-01
7.2E-06
1.9E-01
127-18-4
Tetrachloroethylene
6.61
1.1E+01
8.3E+00
6.1E-07
1.6E-01
108-88-3
Toluene
1.3
1.0E+03
2.5E-04
79-01-6
Trichloroethylene
0.537
4.8E-01
4.2E-01
1.1E-06
2.6E-01
75-69-4
1 Trichlorofluoromethane
1.84
Cumulative: I 1.6E-05 I6.6E-01
North Carolina DEQ Risk Calculator
IDEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Indoor Air r
Version Date: January 2022
Basis: November 2021 EPA RSL Table
ID:
Unit ID:
** - Note that the EPA has no consensus on reference dose or cancer slope factor values for lead, therefore it is not possible to calculate carcinogenic
risk or hazard quotient. Lead concentrations are compared to the National Ambient Air Quality Standard of 0.15 µg/m3.
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Risks are calculated for these values if
indoor air concentrations are entered and indoor air screening levels have been established, but it should be noted that detections of these chemicals are
likely not associated with vapor intrusion.
All concentrations are in no/m3
CAS #
Chemical Name:
Indoor Air
Concentration
3
(ug/m)
Target Indoor
Conc. for
Carcinogens
cinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non-
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
5.75
7143-2
Benzene
0.323
1.6E+00
2.6E+01
2.1E-07
2.5E-03
75-15-0
Carbon Disulfide
0.504
6.1E+02
1.6E-04
67-66-3
Chloroform
0.718
5.3E-01
8.6E+01
1.3E-06
1.7E-03
75-71-8
Dichlorodifluoromethane
2.7
8.8E+01
6.2E-03
156-59-2
Dichloroeth lene, cis-1,2-
0.333
67-63-0
Iso ro anol
0.846
1.8E+02
9.7E-04
78-93-3
Methyl Ethyl Ketone 2-Butanone
1.02
4.4E+03
4.7E-05
75-09-2
Methylene Chloride
0.58
1.2E+03
5.3E+02
4.7E-10
2.2E-04
91-20-3
-Naphthalene
0.598
3.6E-01
2.6E+00
1.7E-06
4.6E-02
127-184
Tetrachloroeth lene
6.61
4.7E+01
3.5E+01
1.4E-07
3.8E-02
108-88-3
Toluene
1.3
4.4E+03
5.9E-05
79-01-6
Trichloroeth lene
0.537
3.0E+00
1.8E+00
1.8E-07
6.1E-02
75-694
Trichlorofluoromethane
1.84
Cumulative: I 3.5E-06 1.6E-01
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air K911TIM11 WITFIR
Version Date: January 2022
Basis: November 2021 EPA RSL Table
Site ID:
Exposure Unit ID: ANION
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
All concentrations are in ue/m3
CAS #
Chemical Name:
Soil Gas
Concentration
3
(ug/m)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non -
Carcinogens @
T'HQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
65.3
1.959
71-43-2
Benzene
1.92
0.0576
3.6E-01
6.3E+00
1.6E-07
1.8E-03
106-99-0
Butadiene, 1,3-
0.785
0.02355
9.4E-02
4.2E-01
2.5E-07
1.1E-02
75-15-0
Carbon Disulfide
1.8
0.054
1.5E+02
7.4E-05
67-66-3
Chloroform
1.16
0.0348
1.2E-01
2.0E+01
2.9E-07
3.4E-04
75-71-8
Dichlorodifluoromethane
3.11
0.0933
2.1E+01
8.9E-04
100-41-4
Eth lbenzene
2.01
0.0603
1.1E+00
2.1E+02
5.4E-08
5.8E-05
109-99-9
-Tetrah drofuran
0.31
0.0093
4.2E+02
4.5E-06
142-82-5
Heptane, N-
4.73
0.1419
8.3E+01
3.4E-04
110-54-3
Hexane, N-
8
0.24
1.5E+02
3.3E-04
591-78-6
Hexanone, 2-
1.79
0.0537
6.3E+00
1.7E-03
67-63-0
Iso ro anol
19.9
0.597
4.2E+01
2.9E-03
78-93-3
Methyl Ethyl Ketone 2-Butanone
9.75
0.2925
1.0E+03
5.6E-05
108-10-1
Methyl Isobutyl Ketone 4-meth 1-2- entanone)
1.2
0.036
6.3E+02
1.2E-05
75-09-2
Methylene Chloride
1.09
0.0327
1.0E+02
1.3E+02
3.2E-10
5.2E-05
91-20-3
-Naphthalene
0.587
0.01761
1 8.3E-02
6.3E-01
2.1E-07
5.6E-03
115-07-1
Propylene
13
0.39
6.3E+02
1.2E-04
10042-5
Styrene
0.515
0.01545
2.1E+02
1.5E-05
127-18-4
Tetrachloroeth lene
15.8
0.474
1.1E+01
8.3E+00
4.4E-08
1.1E-02
108-88-3
Toluene
8
0.24
1.0E+03
4.6E-05
76-13-1
Trichloro-1,2,2-trifluoroethane, 1,1,2-
0.728
0.02184
1.0E+03
4.2E-06
71-55-6
Trichloroethane, 1,1,1-
0.475
0.01425
1.0E+03
2.7E-06
75-69-4
Trichlorofluoromethane
2.77
0.0831
95-63-6
Trimeth lbenzene, 1,2,4-
2.86
0.0858
1.3E+01
1.4E-03
108-67-8
Trimeth lbenzene, 1,3,5-
0.659
0.01977
1.3E+01
3.2E-04
1330-20-7
1 Xylenes
9.56
0.2868
2.1E+01
2.8E-03
Cumulative: I 1.0E-06 I 4.1E-02
North Carolina DEQ Risk Calculator
DEQ Risk Calculator - Vapor Intrusion - Non -Residential Worker Soil Gas to Indoor Air 1
Version Date: January 2022
Basis: November 2021 EPA RSL Table
Site ID:
Exposure Unit ID:
Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion
risk, no risk values are calculated for these chemicals.
All concentrations are in ue/m3
CAS #
Chemical Name:
Soil Gas
Concentration
s
(ug/m)
Calculated
Indoor Air
Concentration
(ug/m3)
Target Indoor
Air Conc. for
Carcinogens @
TCR = 1E-06
Target Indoor Air
Conc. for Non -
Carcinogens @
THQ = 0.2
Calculated
Carcinogenic
Risk
Calculated
Non -
Carcinogenic
Hazard
Quotient
67-64-1
Acetone
65.3
0.653
71-43-2
Benzene
1.92
0.0192
1.6E+00
2.6E+01
1.2E-08
1.5E-04
106-99-0
Butadiene, 1,3-
0.785
0.00785
4.1E-01
1.8E+00
1.9E-08
9.0E-04
75-15-0
Carbon Disulfide
1.8
0.018
6.1E+02
5.9E-06
67-66-3
Chloroform
1.16
0.0116
5.3E-01
8.6E+01
2.2E-08
2.7E-05
75-71-8
Dichlorodifluoromethane
3.11
0.0311
8.8E+01
7.1E-05
100-41-4
Eth lbenzene
2.01
0.0201
4.9E+00
8.8E+02
4.1E-09
4.6E-06
109-99-9
-Tetrah drofuran
0.31
0.0031
1.8E+03
3.5E-07
142-82-5
He tare, N-
4.73
1 0.0473
3.5E+02
2.7E-05
110-54-3
Hexane, N-
8
0.08
6.1E+02
2.6E-05
591-78-6
Hexanone, 2-
1.79
0.0179
2.6E+01
1.4E-04
67-63-0
Iso ro anol
19.9
0.199
1.8E+02
2.3E-04
78-93-3
Methyl Ethyl Ketone (2-Butanone)
9.75
0.0975
4.4E+03
4.5E-06
108-10-1
Methyl Isobutyl Ketone (4-meth 1-2- entanone)
1.2
0.012
2.6E+03
9.1E-07
75-09-2
Methylene Chloride
1.09
0.0109
1.2E+03
5.3E+02
8.9E-12
4.1E-06
91-20-3
-Naphthalene
0.587
0.00587
3.6E-01
2.6E+00
1.6E-08
4.5E-04
115-07-1
Propylene
13
0.13
-
2.6E+03
9.9E-06
100-42-5
Styrene
0.515
0.00515
8.8E+02
1.2E-06
127-18-4
Tetrachloroethylene
15.8
0.158
4.7E+01
3.5E+01
3.3E-09
9.0E-04
108-88-3
Toluene
8
0.08
4.4E+03
3.7E-06
76-13-1
Trichloro-1,2,2-trifluoroethane, 1,1,2-
0.728
0.00728
4.4E+03
3.3E-07
71-55-6
Trichloroethane, 1,1,1-
0.475
0.00475
4.4E+03
2.2E-07
75-69-4
Trichlorofluoromethane
2.77
0.0277
95-63-6
Trimeth lbenzene, 1,2,4-
2.86
0.0286
5.3E+01
1.1E-04
108-67-8
Trimeth lbenzene, 1,3,5-
0.659
0.00659
5.3E+01
2.5E-05
1330-20-7
Xylenes
9.56
0.0956
8.8E+01
2.2E-04
Cumulative: I 7.7E-08 I 3.3E-03
North Carolina DEQ Risk Calculator