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HomeMy WebLinkAbout1701_CaswellLandfill_ MonitoringReport_April2022_FID1741326_20220622I NtNR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): S&ME, Inc. (Consultant for Caswell County) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Edmund Q.B. Henriques Phone: 336-288-7180 E-mail: ehenriques(a)_smeinc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Caswell County Landfill Landfill Road, Yanceyville, North Carolina 17-01 .0500 April 28 and April 29, 2022 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring �x Detection Monitoring �x Assessment Monitoring Corrective Action T e of data submitted: (Check all that apply) x Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ x Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. Hx Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 21B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Edmund Q.B. Henriques, PG Senior Geologist / S&ME, Inc. 336-312-3330 Facility Representative Name (Print) Title (Area Code) Telephone Number 6/22/2022 Affix NC LicenseWjtjutessigppl Geologist Seal Signature N " Date 8646 W. Market Street, Suite 105, Greensboro NC 27409 Facility Representative Address F-0176 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 a 1216 6�4�rhf 9 d 0 &9Od @0©6�Dc� Semi -Annual Monitoring Report April 2022 Monitoring Event Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 June 23, 2022 Caswell County P.O. Box 98 Yanceyville, North Carolina 27379 Attention: Mr. AJ Fuqua Reference: Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 Dear Mr. Fuqua: S&ME Inc. (S&ME) has completed the First semi-annual monitoring event for 2022 at the closed Caswell County Landfill site. The monitoring activities were authorized by Caswell County, County Manager, Mr. Bryan Miller and were completed in general accordance with S&ME proposal 218644 Rev1 October 14, 2021. This report summarizes our understanding of the project, our field services, and the results of laboratory analyses performed on the samples collected. If you have any questions regarding this document, and our associated findings and recommendations; please contact Edmund Henriques at your convenience. Sincerely, S&ME, Inc. �A�(32. Edmund Q.B. Henriques, P.G. Project Manager/Principal Geologist NC Licensed Geologist No. 1216 Cody McMechen, G.I.T. Environmental Staff Professional S&ME, Inc. 18646 West Market Street, Suite 105 1 Greensboro, NC 27409 1 p 336.288.7180 1 www.smeinc.com Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 Table of Contents 1.0 Executive Summary..........................................................................................................2 2.0 Introduction.......................................................................................................................3 3.0 Scope of Services...............................................................................................................4 4.0 Methods Employed...........................................................................................................4 4.1 Monitoring Well Sampling............................................................................................................4 4.2 Groundwater Flow Direction.......................................................................................................5 4.3 Surface Water Sampling................................................................................................................ 5 4.4 On -Site Water Well Sampling.......................................................................................................5 5.0 Corrective Action Assessment Activities.....................................................................5 6.0 Results.................................................................................................................................6 6.1 Groundwater Analytical Results..................................................................................................6 6.1.1 Metals(8-RCRA):.............................................................................................................................6 6.1.2 Volatile Organic Compounds: ........................................................................................................... 6 6.2 Surface Water Analytical Results................................................................................................. 7 6.3 On -Site Water Supply Well Analytical Results.......................................................................... 7 6.4 Quality Control...............................................................................................................................7 6.5 Preliminary Analysis of Cause and Significance of 2L Exceedances...................................... 8 7.0 References...........................................................................................................................8 Appendices Appendix I - Figures Appendix II - Tables Appendix III - Groundwater Sampling Field Data Sheets Appendix IV - Laboratory Analytical Report June 23, 2022 Semi -Annual Monitoring Report -April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 1.0 Executive Summary Six compliance groundwater monitoring wells (MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, and five Corrective Actions Assessment monitoring wells MW-5D, MW-7, MW-8, MW-9, and MW-10 comprise the groundwater monitoring system for the closed Caswell County Landfill. Three surface water sample locations, SW-1, SW-2, and SW-3 are used to monitor surface water quality. Monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-5D, MW-6, MW-7, MW-8, MW-9 and MW-10 were sampled on April 28 and April 29, 2022. The sampling was conducted in general accordance with North Carolina Solid Waste Management Guidelines. Samples collected from monitoring wells and surface water sample locations were submitted for analysis of the North Carolina Landfill Appendix I volatile organic constituents plus eight RCRA Metals. The samples were analyzed by PACE Analytical Services, Inc., a North Carolina certified laboratory. Analytical results of the eleven groundwater samples report the following exceedances of the corresponding 15A North Carolina Administrative Code (NCAC) 2L .0200 groundwater quality standard (2L Standard) during this monitoring event: Benzene was detected in the groundwater samples collected from monitoring wells MW-2, MW-4, and MW-5 at concentrations greater than the 2L standard of 1 pg/L. 1,4-Dichlorobenzene was detected in the groundwater sample collected from monitoring well MW-5 at concentrations greater than the 2L standard of 6 pg/L. 1,4-Dioxane (p-Dioxane) was detected in monitoring wells MW-2, MW-3, MW-4, MW-5, MW-5D, and MW-7 at concentrations greater than the 2L Standard of 3 pg/L. Mercury was detected in the groundwater samples collected from monitoring wells MW-1, MW-7, MW-8, and MW-10 at concentrations greater than the 2L standard of 1 pg/L. Based on historic site data, the detection of mercury above the corresponding 2L Standard is inconsistent with historic data. Furthermore, mercury was detected in the facility's upgradient monitoring well. On this basis, it was presumed that the mercury detections were most likely a sampling or laboratory related artifact. Monitoring wells MW-2 and MW-4 are located approximately 50 feet beyond the apparent limits of waste for an older landfill unit. During this monitoring event, barium and mercury were detected at a concentration greater than the method detection limit in the three stream sample locations. Barium and mercury were detected in the up -gradient background surface water sample and the down -gradient samples at similar concentrations. The reported concentrations of barium were below the respective 15A NCAC 213 Surface Water Standard for Class C surface waters. The reported concentrations of mercury were above the respective 15A NCAC 2B Surface Water Standard for Class C surface waters. The detection of mercury in surface water samples is inconsistent with historic site data. Consistent with the anomalous detections of mercury in groundwater during this event, mercury in surface water samples is presumed to be a sampling or laboratory related artifact. It is believed that the cause of the 2L Standards exceedances for Benzene, 1,4-Dichlorobenzene and 1,4-Dioxane at the Caswell County Landfill is from percolation of landfill constituents from the waste management units into the uppermost groundwater aquifer. June 23, 2022 Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 Due to benzene and 1,4-Dioxane concentrations exceeding the 2L Standards in the compliance wells, S&ME prepared a Corrective Action Assessment Work Plan dated May 14, 2020, which was approved by North Carolina Department of Environmental Quality (NCDEQ). Monitoring wells MW-5D, MW-7 and MW-8 were installed during August 2020 to provide for additional delineation of the extent of constituents of potential concern in groundwater. These three wells were sampled during subsequent semi-annual monitoring event. Based on analytical results received, S&ME prepared a Corrective Action Assessment Work Plan dated September 15, 2021, to provide for additional delineation of the extent of constituents of potential concern in groundwater. This Work Plan involved installation of monitoring wells MW-9 and MW-10 added a third surface water sampling location (SW-3), and added the sampling of the on -site water supply well. Analytical results for the second sampling event for monitoring wells MW-9, MW-10, and surface water location SW-3 are presented in this report. 2.0 Introduction The Caswell County Landfill (Permit No. 17-01) is located at 162 Landfill Road, Yanceyville, North Carolina 27379 as depicted in Appendix I, Figure 1. The landfill is a closed facility that ceased operation in 1994, and currently monitors water quality under a Post Closure Care Plan on a semi-annual basis. The facility uses a network of eleven groundwater monitoring wells to monitor groundwater quality at the facility, as depicted in Appendix I, Figure 2. The groundwater monitoring network is made up of one up -gradient monitoring well (MW-1) and ten cross -gradient and/or down -gradient compliance monitoring wells (MW-2, MW-3, MW-4, MW-5, MW-5D, MW-6, MW-7, MW-8, MW-9, and MW-10). Monitoring wells MW-5D, MW-7 and MW-8 were installed during August 2020, in accordance with the Corrective Action Assessment Work Plan, dated May 14, 2020. Monitoring wells MW- 9 and MW-10 were installed in November 2021, as proposed in the Corrective Action Assessment Work Plan dated September 15, 2021, to provide for additional delineation of the extent of constituents of potential concern in groundwater. The latest Work Plan also included the addition of a third surface water sampling location SW-3, and sampling of the on -site water supply well. The collected groundwater samples were analyzed in accordance with 15A NCAC 13B .0500 et seq for the North Carolina Landfill Appendix I volatile organic constituent suite plus the eight RCRA metals. The monitoring wells were purged and groundwater samples collected using new a sterile peristaltic pump with new Teflon lined tubing or a non -dedicated bladder pump. The facility monitors surface water quality at the stream that crosses the down -gradient region of the facility. As conditions allow, during each semi-annual monitoring event, three surface water samples are collected from this stream at designated sampling points. Stream sampling location SW-1 is the upstream sampling location to the south of the waste management unit. Stream sampling location SW-2 is the downstream sampling location, down -gradient of monitoring well MW-5/MW-5D, new stream sample location SW-3 is further downstream and down -gradient of monitoring well MW-7. S&ME Inc. (S&ME) has completed the first semi-annual monitoring event for 2022 at the closed Caswell County Landfill site. The monitoring activities were authorized by County Manager, Mr. Bryan Miller and were completed in general accordance with S&ME proposal 218644 Rev 1, dated October 14, 2021. This report summarizes our understanding of the project, our field services, and the results of laboratory analyses performed on the samples June 23, 2022 Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 I I Yanceyville, North Carolina S&ME Project No. 1584-07-034 collected for the first semi-annual water quality monitoring event for 2022 and additional Corrective Action Assessment activities. 3.0 Scope of Services S&ME has performed semi-annual groundwater sampling of the groundwater monitoring wells and surface water samples. The groundwater monitoring wells were purged, sampled, and the groundwater samples collected from the monitoring wells were analyzed for the North Carolina Appendix I volatile organic constituents and the eight RCRA metals. This semi-annual groundwater monitoring report has been prepared to document the spring 2022 water quality monitoring event and includes: Summary Tables of the laboratory analytical data from each sampling event, Development of a current potentiometric map, A discussion of findings and results, An electronic copy of this report will be sent to the NCDEQ 4.0 Methods Employed 4.1 Monitoring Well Sampling Groundwater monitoring well sampling took place on April 28 and April 29, 2022. The monitoring well locations with respect to the facility layout are shown on Appendix I, Figure 2. Prior to sample collection each well was opened and the static water level measured relative to the top edge of the PVC well casing. The total well depth was used to determine the volume of water in the wells at the time of sampling. These data are summarized in Appendix II, Table 1 and Table 2. Monitor wells were purged using non -dedicated pumps prior to collecting the water samples. The wells were purged until field parameters stabilized or purged until the well went dry prior to the collection of the groundwater samples. The purge water was monitored for temperature, pH, conductivity, dissolved oxygen, and oxidation reduction potential. Sample turbidity measurements (quantitative) were also obtained. Appendix II Table 2 provides a summary of the measured field parameters. The field data collected during sampling was recorded on the groundwater sampling field data sheets included in Appendix III of this report. Upon collection, each groundwater sample was placed in laboratory supplied containers, place in a cooler with ice, and placed under chain -of custody. The sampling technician wore new nitrile gloves that were changed between wells to reduce the possibility of cross contamination. All groundwater samples were then sent to PACE Analytical Services, Inc. (PACE) in Huntersville, North Carolina to be analyzed for Appendix I volatile organic constituents, 1,4-Dioxane, and the eight RCRA metals. June 23, 2022 4 Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 4.2 Groundwater Flow Direction The static water levels in the monitoring wells were measured on April 28 and April 29, 2022. On the sampled dates, the depths to the water table ranged from 7.13 feet below top of well casing at MW-10 to 23.91 feet below the top of well casing at MW-8. Groundwater elevation data are presented in Appendix II, Table 1. A groundwater contour map was constructed using the calculated groundwater elevation data from the April 2022 sampling dates and is presented as Appendix I, Figure 3. Groundwater elevation data for wells MW-4 and MW- 5D were not used in the generation of the groundwater contour map. The groundwater elevation data collected during this monitoring event indicates that the shallow groundwater beneath the landfill is estimated to flow easterly toward the unnamed tributary of Bear Branch. This estimated flow direction is consistent with observations made during prior monitoring events. 4.3 Surface Water Sampling Surface water sampling took place on April 28 and April 29, 2022. Three stream samples (SW-1, SW-2, and SW-3) were collected from an unnamed tributary of Bear Branch, which flows along the eastern portion of the facility and flows toward the north away from the Landfill. Surface water sample (SW-1) was collected from an upstream position with respect to the waste management unit and SW-2 was collected downstream of the waste management unit. Stream sample SW-3 is located downstream of SW-2. The location of each stream sample location is presented on Appendix I, Figure 3. The surface water samples were collected by immersing laboratory supplied containers directly into the stream at the locations to be sampled. After collection, the surface water samples were placed in a cooler with ice and placed under chain -of -custody. All stream samples were analyzed for the North Carolina Appendix I volatile organic constituents, 1,4-Dioxane, and the 8 RCRA metals by PACE Analytical Services, Inc.; a North Carolina certified laboratory. 4.4 On -Site Water Well Sampling The on -site water supply well was not sampled during this monitoring event. 5.0 Corrective Action Assessment Activities Groundwater monitoring wells MW-9 and MW-10 were installed between November 1 and 3, 2021, in accordance with the approved Corrective Action Assessment Work Plan. Following installation, the new groundwater monitoring wells were developed to remove clay, silt, and sand particles that may have been introduced into the formation or filter pack during installation. To evaluate hydrogeological characteristics of the subsurface materials, S&ME performed in -situ permeability tests (slug tests) in new groundwater monitoring well MW-9. Monitoring well MW-10 was not slug tested due to an apparent very low yield. Data collected from slug testing will be analyzed to calculate horizontal permeabilities for well screen intervals. Horizontal permeabilities calculated from slug tests will be used to calculate groundwater flow velocities. This and other hydrogeologic information will be incorporated into a Corrective June 23, 2022 Semi -Annual Monitoring Report -April 2022 Caswell County Landfill Permit No 17-01 I I Yanceyville, North Carolina S&ME Project No. 1584-07-034 Action Assessment Report, which will be a stand-alone report, to be submitted subsequent to this first semi-annual monitoring report for 2022. 6.0 Results The following sections provide a discussion of the groundwater and surface water sampling results for the spring 2022 semi-annual monitoring event. The laboratory analytical reports are included in Appendix IV. The NCDEQ electronic data deliverable (EDD) for select field and analytical laboratory data have been submitted to NCDEQ. 6.1 Groundwater Analytical Results The results of the laboratory analyses for the groundwater monitoring well samples are summarized in Appendix II, Table 3, which also provides the corresponding 15A North Carolina Administrative Code (NCAC) 2L .0200 groundwater quality standards (21- Standard) for reference. Appendix II, Table 4 provides a summary of the constituents detected at concentrations greater than their respective 2L Standards. The following summarizes detections for the groundwater samples obtained for the eleven monitoring wells (MW-1, MW-2, MW-3, MW-4, MW-5, MW-51D, MW-6, MW-7, MW-8, MW-9, and MW-10) on April 28 and April 29, 2022. 6.1.1 Metals (8-RCRA): Arsenic was detected (at an estimated concentration) in the sample obtained from MW-51D. The arsenic concentration detected in this well was less than the corresponding 2L Standard; Barium was detected in samples collected from each monitoring well at concentrations less than its corresponding 2L Standard; Selenium was detected in the samples collected from MW-2, MW-3, and MW-7 at concentrations less than its corresponding 2L Standard. Mercury was detected in the samples collected from the facility's background well MW-1 along with compliance wells MW-7, MW-8, and MW-9 at concentrations that exceed the corresponding 2L Standard established at 1 pg/L. The analytical results for the detected metals (totals) are summarized in Appendix II, Table 3. 6.1.2 Volatile Organic Compounds: Benzene was detected in the groundwater samples collected from monitoring wells MW-2, MW-4, and MW-5 at concentrations greater than its 2L Standard established at 1 pg/L. Benzene was also detected at monitoring wells MW-3 and MW-51D at estimated concentrations less than the 2L Standard. 1,4-Dichlorobenzene was detected in the groundwater samples collected from monitoring well MW-5 at concentrations greater than the 2L standard of 6 pg/L. 1,4-Dichlorobenzene was also detected at monitoring wells MW-2, MW-3, MW-4, and MW-51D at estimated concentrations less than the 2L Standard. 1,4-Dioxane was detected in monitoring wells MW-2, MW-3, MW-4, MW-5, MW-51D, MW-7, and MW-10 at concentrations greater than its 2L Standards established at 3 pg/L. June 23, 2022 Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 Yanceyville, North Carolina S&ME Project No. 1584-07-034 Chlorobenzene, Chloroethane, 1,2-Dichlorobenzene, 1,1-Dichloroethane, Cis-1,2-Dichloroethene, Toluene, and Xylene (Total) were detected in one or more groundwater samples during this monitoring event; however, each of the reported concentrations of these constituents was less than their respective 2L Standard or an estimated concentration. No other volatile organic compounds were detected above their respective method detection limit in the monitoring wells sampled during this event. The analytical results for the detected volatile organic compounds are summarized in Appendix II, Table 3. Appendix II, Table 4 provides a summary of the constituents and concentrations which appear to exceed to the corresponding 2L standards. 6.2 Surface Water Analytical Results There were no volatile organic constituents, including 1,4-Dioxane detected above the method detection limits in stream samples SW-1, SW-2, and SW-3 collected on April 28 and April 29, 2022. Barium and mercury were detected at relatively similar concentrations in each sample. The reported concentrations of barium were below the respective 15A NCAC 2B Surface Water Standard for barium for Class C surface waters. The reported concentrations of mercury were above the respective 15A NCAC 2B Surface Water Standard for Class C surface waters. There were no other metals detected above the method detection limits in the surface water samples collected during this sampling event. The results of the surface water sample analyses are summarized on Appendix II, Table 5 and Table 6. 6.3 On -Site Water Supply Well Analytical Results The on -site water supply well was not sampled during this monitoring period. The location of the water supply well is presented in Appendix I, Figure 4. 6.4 Quality Control A qualitative review of the data was performed to verify that the detected concentrations in the laboratory report were of known quality. A formal, quantitative data validation was not performed. Laboratory -assigned data qualifiers were evaluated to verify that rejected or unsupportable data were not included in the dataset. Quality control data provided in the laboratory reports were also reviewed. No rejected or otherwise unacceptable quality data were reported from the laboratory. During this event a duplicate sample was collected from monitoring well MW-5 and the sample was analyzed for the Appendix I Volatile Organic Compounds and the 8-RCRA metals. The detected analytes and their concentrations in the sample identified as MW-5 exhibit relatively good correlation with the analytes and concentrations reported for the duplicate sample. A Trip Blank accompanied the sample kit during shipment, sample collection, and shipment of the collected samples back to the laboratory. The Trip Blank sample was analyzed for Appendix I Volatile Organic Compounds. The results of the duplicate and trip blank sample analyses are included in Appendix IV. June 23, 2022 Semi -Annual Monitoring Report —April 2022 Caswell County Landfill Permit No 17-01 I I Yanceyville, North Carolina S&ME Project No. 1584-07-034 6.5 Preliminary Analysis of Cause and Significance of 2L Exceedances It is believed that the cause of the 2L Standard exceedances reported for benzene, 1,4-dichlorobenezne, and 1,4- Dioxane within the hydrogeologic regime at the Caswell County Landfill is caused from percolation of landfill constituents from the waste management units into the uppermost groundwater aquifer. The Spring 2022 monitoring event represents third monitoring event utilizing low -flow sampling methods and the collection of quantitative measurements of sample turbidity. Mercury was detected in the groundwater samples collected from monitoring wells MW-1, MW-7, MW-8, and MW- 10 at concentrations greater than the 2L standard of 1 pg/L. Based on historic site data, the detection of mercury above the 2L Standards is inconsistent with historic data. Furthermore, mercury was detected in the facility's upgradient monitoring well. Accordingly, it was presumed mercury is most likely a sampling or laboratory artifact. As part of the Corrective Action Assessment activities, Caswell County's Environmental Health Department staff completed a survey of water supply wells located within approximately 0.5 mile of the landfill limits of waste. With one exception, the water wells identified are on opposite sides of Bear Branch. Given the documented concentrations of volatile organic compounds originating from the landfill, physical separation distances between site groundwater impacts and off -site water wells, and existence of natural hydraulic divides between impacted groundwater and the water supply wells, the potential for impacts to water supply wells appears to be low. Due to prior exceedances of the 2L Standard, Caswell County submitted to the NCDEQ Corrective Action Plan Assessment Work Plans, which were focused on delineation of extents of 2L Standard exceedances, and the collection of other data to support development of a Corrective Action Plan for the facility. Installation of new groundwater monitoring wells MW-5D, MW-7, MW-8 in August 2020 and MW-9 and MW-10 in November 2021, were key elements of these Work Plans. The analytical data for this water quality monitoring event will be incorporated into a Corrective Action Assessment report, to be prepared and submitted to NCDEQ. . 7.0 References North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Environmental Management, Subchapter 2L, Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina, Sections .0100, .0200, and .0300; from the Environmental Management Commission Raleigh, North Carolina. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Environmental Management, Subchapter 2B, Classifications and Water Quality Standards Applicable to the Surface Waters of North Carolina, Section .0200; from the Environmental Management Commission, Raleigh, North Carolina. North Carolina Administrative Code, Title 15A, Department of Environment, Health and Natural Resources, Division of Solid Waste Management, subchapter 13B, Solid Waste Management, Section .1600. June 23, 2022 8 Appendices Appendix I - Figures *KAW-10 I l I G� (517.93)un tCf 1 � M� - l LLon �B MW-7 OA * (493.29) / (�6.74 �•'� Q EXISTING Z STORMWATER/ - o J J SEDIMENT , �I I - 0 `POND f �� _ O� Q U J �\ �I ( .42) ' uil M W 6 - U � J VCLOSED LANDFILL AREA I I MVV-31 -5 / Z O PERMIT # 17-01 I (503.16) Z o w (506.Lu �z MW-Q < 4 / / (505.87) 1 1 // I I I� / �� / �� O JII I LANDFILL CLOSED I / PRIOR TO 1988 LANDFILL CLOSED (558.14) O O O / I O OI PRIOR TO 1988 MW-8 \ M W-10, / / /� (490.42) i M� V v ki Q/ / A SCALE: AS SHOWN DATE: JUNE 2022 NOTE PROJECT NUMBER GROUNDWATER MEASUREMENT FOR MONITORING WELL MW-4 AND MW-5D NOT INCLUDED IN CONTOUR CALCULATION 1584-07-034C NOTE: GROUNDWATER MEASURED ON APRIL 28 & 29, 2022 KEY FIGURE NO. MONITORING WELL LOCATION 0 150 300 — GROUNDWATER CONTOUR (558.74) - GROUNDWATER ELEVATION MEASURED IN MONITORING WELL ON 4/28-29/2022 2 -� GROUNDWATER FLOW DIRECTION GRAPHIC SCALE (IN FEET) 3 . VIT" k ;� " . .4 01 CLOSED LANDFILL AREA PERMIT# 17-01 j., LFG WELL #2 too.hh G11-1 T, GV4 +GV 6 GV-2 -V LANDFILL CLOSED D PRIOR TO 1988 mw-1 KEY SURFACE WATER SAMPLE LOCATION WATER SUPPLY WELL MONITORING WELL LOCATION + GAS VENT WELL LOCATION LANDFILL GAS WELL LOCATION IWISTREAMS 10'CONTOURS APPROXIMATE LIMITS OF SOLID WASTE UNITS CASWELL COUNTY PROPERTY BOUNDARY CASWELL COUNTY TAX PARCELS SOURCE: 2017 AERIAL PHOTOGRAPH OBTAINED FROM GOOGLE MAPS 44i 4 14' SW-3 MW-7 *MW-3MW-5 -2 * m S Wtsw D MW-6 W-2 -4 LFG mw LANDFILL CLOSED PRIOR TO 1988 vz ',ej, �r -j Z SCALE: AS SHOWN DATE: DUNE 2022 PROJECT NUMBER 1584-07-034C FIGURE NO rd Appendix II - Tables TABLE 1 WELL CONSTRUCTION AND GROUNDWATER ELEVATION DATA - APRIL 2022 PERMIT # 17-01 CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Well I im Date Installed Total Depth Well •eology (feet) (inches) Depth t Top of (feet)] Well Screen (feet bgs) of Screened Interval Latitude AD 83 Longitude NAD: Ground Elevation -• (feet msi.) Top. Elevation (feet msi.) GroundwatW (feet) Elevation (feet msl.) MW-1 6/10/1985 24.5 2 13 13 - 23 partially weather rock 36.438254 -79.371118 572 574.32 16.18 558.14 MW-2 6/10/1985 22.3 2 10.5 10.5 - 20.5 partially weather rock 36.439137 -79.367584 526 526.96 20.13 506.83 MW-3 6/10/1985 17.8 2 8 8 - 18 partially weather rock 36.439460 -79.367302 511 513.61 10.45 503.16 MW-4 3/12/1992 36.2 2 29 29 - 34 rock 36.439102 -79.367572 526 529.12 23.25 505.87 MW-5 3/16/1992 24.7 2 12.6 12.6 - 22.6 rock 36.439355 -79.366798 498 497.99 8.57 489.42 MW-5D 8/10/2020 76 2 62.6 62.6 - 72.6 rock 36.439336 -79.366791 497 499.49 8.99 490.50 MW-6 3/13/1992 16.2 2 7.8 7.8 - 17.8 rock 36.439400 -79.366397 489 490.48 7.83 482.65 MW-7 8/10/2020 39 2 11.5 11.5 - 36.5 rock 36.439917 -79.366975 510 512.67 19.38 493.29 MW-8 8/11 /2020 32.9 2 10.0 10.0 - 30.0 partially weather rock 36.438407 -79.366904 511 514.33 23.91 490.42 MW-9 11/1/2021 34.8 2 14.6 14.6 - 34.6 rock 36.439806 -79.367873 524 527.04 20.30 506.74 MW-10 11/3/2021 47.6 2 17.3 17.3 - 47.3 rock 36.440671 -79.368808 522 525.06 7.13 517.93 Top of casing elevations based on survey provided Regional Land Surveyors, Inc. in 2020, and added MW-9 & MW-10 in November 2021 Well Construction details obtained from Well Construction Records provided by Caswell County feet bgs. = feet below ground surface feet msl. = feet mean sea level Depth to Groundwater' = below top of casing elevation Groundwater Elevation = calculated groundwater elevation T:\ENV\Projects\2007\1584-07-034 Caswell County Landfill Groundwater Monitoring\2022 GW Monitoring%pring 2022\Tables\Tables_April 2022_EH.xlsx TABLE 2 SUMMARY OF GROUNDWATER SAMPLING FIELD PARAMETERS (APRIL 2022) PERMIT # 17-01 CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Date 4/29/2022 Well MW-1 Well D- 1 24.5 Depth To 16.18 Water 558.14 •.. None Pump 100 .. 1.4 .. . 0.8 No 13.2 6.43 644 • 1.4 •RP 64 Turbidity 9.2 4/28/2022 MW-2 22.3 20.13 506.83 None Pump 100 0.4 0.8 No 16.1 6.27 1,150 0.4 -64 3.0 4/28/2022 MW-3 17.8 10.45 503.16 None Pump 80 1.2 1.7 No 15 6.03 545 0.6 62 40.5 4/28/2022 MW-4 36.1 23.25 505.87 None Pump 100 2.1 0.8 No 17.8 6.33 1,197 0.7 -103 4.8 4/28/2022 MW-5 24.7 8.57 489.42 None Pump 100 2.6 1.5 No 14.1 6.3 994 0.6 -11 86.8 4/28/2022 MW-5D 75.7 8.99 490.50 None Pump 100 1 10.9 0.9 No 14.4 6.6 1,013 1.1 -37 0.4 4/28/2022 MW-6 16.2 7.83 482.65 None Pump 100 1.4 0.8 No 13.2 6.19 113 3.4 72 3.6 4/28/2022 MW-7 39.9 19.38 493.29 None Pump 100 3.3 2.9 No 17.8 6.44 568 0.5 9 54.9 4/28/2022 MW-8 32.8 23.91 490.42 None Pump 100 1.5 1.5 No 16.7 5.8 161 0.2 -1 8.1 4/29/2022 MW-9 34.8 20.30 506.74 None Pump 300 2.8 4.8 No 15.2 5.77 187 4.8 84 27.2 4/28/2022 MW-10 47.6 7.13 517.93 None Pump Grab 7.0 0.0 No 14.9 6.16 444 0.5 10 4.4 Notes: 1. TEMP = groundwater temperature, measured in degrees Celsius 2. Pump Rate, measured in milliliters/minute 3. EVAC = evacuated volume of groundwater 4. Specific Conductance, measured in ps/cm indicates micro Siemens per centimeter. 5. SU indicates Standard Units. 6. Dissolved Oxygen measured in milligram per liter 7. Oxidation Reduction Potential (ORP) measured in millivolts. 8. Turbidity measured in Nephelometric Turbidity Units (NTU) TABLE 3 SUMMARY OF GROUNDWATER ANALYSES RESULTS - DETECTIONS APRIL 2022 PERMIT # 17-01 CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Number Well ID Date Collected Detected Analytes 1W MW-1 1701-MW1 04/29/22 (p9/L) MW-2 1701-MW2 04/28/22 (p9/L) MW-3 1701-MW3 04/28/22 (p9/L) MW-4 1701-MW4 04/28/22 (p9/L)��(p9/L) Appendix MW-5 1701-MW5 04/28/22 I Volatile MW-5D 1701-MW5D 04/28/22 (p9/L) Organic Compounds Sample Locations MW-6 1701-MW6 04/28/22 (p9/L) (plus MW-7 1701-MW7 04/28/22 (p9/L) 1,4-Dioxane) MW-8 1701-MW8 04/28/22 (p9/L) MW-9 1701-MW9 04/29/22 (p9/L) MW-10 1701-MW10 04/29/22 (p9/L) WSW 1701-WSW 04/28/22 (p9/L) Duplicate 1701-Duplicate 04/28/22CAS (N9/L) itr(,ndar)d (pg/L)(pg/L) IMAC MCLsSampleID (p9/L) c CAS Number WeIIID Sample ID Date Collected Detected Analytes MW-1 1701-MW 04/29/22 (pg/L) MW-2 1701-MW2 04/28/22 (pg/L) MW-3 1701-MW3 04/28/22 (pg/L) MW-4 701-MW4 04/28/22 (pg/L) MW-5 1701-MW5 04/28/22 (pg/L) MW-5D 1701-MW5D 04/28/22 (pg/L) 8-RCRA Sample Locations MW-6 1701-MW6 04/28/22 (pg/L) Metals F MW-7 1701-MW 04/28/22 (pg/L) MW-8 1701-MW8 04/28/22 (p9/L) MW-9 1701-MW8 04/29/22 (pg/L) MW-10 1701-MW8 04/29/22 (pg/L) WSW 1701-MW8 04/28/22 (pg/L) Duplicate 1701-Duplicate 04/28/22 (pg/L) Report Limit (pg/L) NCAAA� Standard (pg/L) N� CDEQ' IMAC M (pg/L) (pg/L) pg/L = concentrations reported in micrograms per liter CAS Number = Chemical Abstracts Service Number NCAC 2L Standards = 15A North Carolina Administrative Code 2L .0200, GW Quality Standards for Class GA groundwater. concentrations in bold and yellow highlighted cells exceed the corresponding 2L Standard NCDEQ IMAC = Interim Maximum Allowed Concentration, NCDEQ Federal MCL = Maximum Contaminant Levels, USEPA NS = no NCAC 2L Standard or MCL listed (USEPA) TABLE 4 SUMMARY OF GROUNDWATER EXCEEDANCES - APRIL 2022 PERMIT # 17-01 CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Well ID MW-1 MW-2 MW-3 MW-4 MW-5 MW-5D MW-7 MW-8 MW-10 Duplicate NCAC 2L NCDEQ Fed fq9Date Sample ID 1701-MW1 1701-MW2 1701-MW3 1701-MW4 1701-MW 1701-MW5D 1701-MW7 J1701-MW8 1701-MW7 1701-Duplicate Standards IMa M Collected 04/29/22 04/28/22 04/28/22 04/28/22 04/28/22 04/28/22 04/28/22� 04/28/22 04/29/22 04/28/22 CAS Number Detected Analytes (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) ®®®®®®� 2.4 4.4®1 a µg/L = concentrations reported in micrograms per liter CAS Number = Chemical Abstracts Service Number NCAC 2L Standards = 15A North Carolina Administrative Code 2L .0200, GIN Quality Standards for Class GA groundwater. Concentration greater than the NCAC 2L Standards are shown in bold <2L = concentration reported was less than the corresponding NCAC 2L Standard NCDEQ IMAC = Interim Maximum Allowed Concentration, NCDEQ Federal MCL = Maximum Contamiant Levels, USEPA NS = no MCL listed, USEPA TABLE 5 s SUMMARY OF SURFACE WATER ANALYSES RESULTS - DETECTIONS APRIL 2022 PERMIT # 17-01 s CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Appendix I Volatile Organic Compounds Plus 1,4-Dioxane Sample Locations Report NCAC 2B Sample Location SW-1 SW-2 SW-3 Limit Standards Sample ID 1701 -SW 1 1701-SW2 1701-SW3 Date rl.cte� Collected 04/28/22 04/28/22 04/29/22 CAS Numb Analytes (µg/L) (µg/L) (µg/L) K (µg/md all target analytes so is analyte specific Sample IFE 8-RCRA Sample Location SW-1 Metals lll� Locations SW-2 SW-3 Lim! * i * NCAC 2B Standards Sample ID 1701 -SW 1 1701-SW2 1701-SW3 Date Collected 04/28/22 04/28/22 04/29/22 CAS Number Detected Analytes (µg/L) (µg/L) (µg/L) (µg/L) (µg/L) ��1 • = 1 1 111 CAS Number = Chemical Abstracts Service Number µg/L = concentrations reported in micrograms per liter TABLE 6 SUMMARY OF 2B SURFACE WATER STANDARD EXCEEDANCES APRIL 2022 PERMIT # 17-01 CASWELL COUNTY LANDFILL YANCEYVILLE, NORTH CAROLINA S&ME PROJECT NO. 1584-07-034 Appendix I VOCs and 8-RCRA Metals ow Sample Locatio SW-1 SW-2 SW-3 NCAC 2B Sample I 1701-SW1 1701-SW2 1701-SW3 Standards* Date Collected 04/28/22 04/28/22 04/29/22 Solid Waste Section IDS Detected Analytes (µg/L) (µg/L) (µg/L) (µg/L) µg/L = concentrations reported in micrograms per liter NC SWSL = North Carolina Solid Waste Section Limit * = Title 15A NCAC 2B Standards for all Water Supply Classifications Appendix III - Groundwater Sampling Field Data Sheets s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-SW1 Purge Time: 0 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 15:40 Weather: Sunny Air Temp: 75* F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Volume Purged Depth to Water Dissolved Oxygen Turbidity Start Purging Final: 15:40 15.8 6.7 97 6.9 37 2.9 End of Purging Sample Method: Bailer Sample Start Time: 15:40 Sample End Time: Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: To convert ORP to Eh, add 205 mV to ORP. Measuring Point: Top of Casing Depth to Water: ft-TOC Total Well Depth: ft-TOC Height of Water Column: feet Screen Length: feet Stickup: ft-GRD Well Volume Well Diameter 2 inch Water Volume Gal 3 *Well Volume Gal 5 *Well Volume Gal Purge Method: Peristaltic Pump Start Time: 15:40 End Time: 15:40 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: ft-TOC Water Column Above Pump Intake: feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: ft-TOC Comments: Final Volume Purged: Gallons Used YSI Pro Plus, Final Volume Purge Rate: mL/min Well Purged Dry?: No (Yes/No) Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-SW2 Purge Time: 0 Minutes Locked?: No Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 9:00 Weather: Sunny Air Temp: 60* F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Volume P urged (gal) Depth to Water (ft) INN Dissolved Oxygen (-g/L) 0 Turbidity NTU) M Start Purging Final: 09:00 11.4 7.0 117 11.1 121 2.9 End of Purging Sample Method: Bailer Sample Start Time: 09:00 Sample End Time: Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: To convert ORP to Eh, add 205 mV to ORP. Measuring Point: Top of Casing Depth to Water: ft-TOC Total Well Depth: ft-TOC Height of Water Column: feet Screen Length: feet Stickup: ft-GRD Well Volume Well Diameter 2 inch Water Volume Gal 3 *Well Volume Gal 5 *Well Volume Gal Purge Method: Peristaltic Pump Start Time: 9:00 End Time: 9:00 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: ft-TOC Water Column Above Pump Intake: feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: ft-TOC Comments: Final Volume Purged: Gallons Used YSI Pro Plus, Final Volume Purge Rate: mL/min Well Purged Dry?: No (Yes/No) ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- ---------- Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 Caswell County Landfill Landfill Road, Yanceyville, INC 1584-07-034 phase 26 Purge Date: April 29, 2022 Project Name: Project Location: Project Number: Source Well: 1701-SW3 Purge Time: 0 Minutes Locked?: No Sample Date: April 29, 2022 Sampled By: Gary Simcox Sample Time: 12:15 Weather: Overcast Air Temp: 60° F Water Level Well Data We Purging Information Field Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow-throughcellvolume) Final: 12:15 13.0 7.1 127 10.7 67 6.5 End of Purging Sample Method: Bailer Sample Start Time: 12:15 Sample End Time: Analytical Data (1) Gary Simcox 5/2/2022 Notes: To convert ORP to Eh, add 205 mV to ORP. Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: ft-TOC Total Well Depth: ft-TOC Height of Water Column: feet Screen Length: feet Stickup: ft-GRD Well Volume Well Diameter 2 inch Water Volume Gal 3 *Well Volume Gal 5 *Well Volume Gal Purge Method: Peristaltic Pump Start Time: 12:15 End Time: 12:15 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: ft-TOC Water Column Above Pump Intake: feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: ft-TOC Comments: Final Volume Purged: Gallons Used YSI Pro Plus, Final Volume Purge Rate: mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 12:15 0.0 --- --- --- --- --- --- --- --- Start Purging 12:15 13.0 7.1 127 10.7 67 6.46 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Caswell County Landfill Landfill Road, Yanceyville, NC Project Name: Project Location: Project Number: 1584-07-034 phase 26 Purge Date: April 29, 2022 Source Well: 1701-MW1 Purge Time: 30 Minutes Locked?: Yes Sample Date: April 29, 2022 Sampled By: Gary Simcox Sample Time: 9:05 Weather: Overcast Air Temp: 50° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow -through cell volume) Final: 09:00 0.8 100 16.51 13.2 6.4 644 1.4 64 9.2 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 09:05 Sample End Time: 09:15 Analytical Data (1) Gary Simcox 5/2/2022 Notes: The well and protective cover are in good condition. Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 16.18 ft-TOC Total Well Depth: 24.50 ft-TOC Height of Water Column: 8.32 feet Screen Length: 10 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 1.4 Gal 3 *Well Volume 4.07 Gal 5 *Well Volume 6.79 Gal Purge Method: Peristaltic Pump Start Time: 8:30 End Time: 9:00 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 24.0 ft-TOC Water Column Above Pump Intake: 7.82 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 18.14 ft-TOC Comments: Final Volume Purged: 0.8 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 08:30 0.0 --- --- --- --- --- --- --- --- Start Purging 08:35 0.1 100 16.38 12.9 6.5 663 2.3 64 13.8 08:40 0.3 100 16.42 13.1 6.4 657 1.9 65 9.34 08:45 0.4 100 16.45 13.1 6.5 646 1.6 67 9.41 08:50 0.5 100 16.48 13.1 6.4 643 1.6 67 9.80 08:55 0.7 100 16.49 13.2 6.4 643 1.4 65 9.53 09:00 0.8 100 16.51 13.2 6.4 644 1.4 64 9.15 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCl 8 RCRA Metals 1 250mL P HNO3 s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW2 Purge Time: 30 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 13:30 Weather: Sunny Air Temp: 70° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Final: 33.25 0.8 100 20.90 16.1 6.3 1,150 0.4 -64 3.0 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 13:30 Sample End Time: 13:35 Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: The well and protective cover are in good condition. Measuring Point: Top of Casing Depth to Water: 20.13 ft-TOC Total Well Depth: 22.30 ft-TOC Height of Water Column: 2.17 feet Screen Length: 10 feet Stickup: 1.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 0.4 Gal 3 *Well Volume 1.06 Gal 5 *Well Volume 1.77 Gal Purge Method: Peristaltic Pump Start Time: 12:55 End Time: 13:25 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 22.0 ft-TOC Water Column Above Pump Intake: 1.87 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 20.60 ft-TOC Comments: Final Volume Purged: 0.8 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 12:55 0.0 --- --- --- --- --- --- --- --- Start Purging 13:00 0.1 100 20.55 16.8 6.3 1,092 1.8 -20 44.7 13:05 0.3 100 20.77 17.4 6.3 1,100 0.9 -34 26.6 13:10 0.4 100 20.80 16.5 6.3 1,131 0.5 -49 46.3 13:15 0.5 100 20.88 16.3 6.3 1,143 0.4 -59 9.32 13:20 0.7 100 20.89 16.2 6.3 1,147 0.4 -61 5.88 13:25 0.8 100 20.90 16.1 6.3 1,150 0.4 -64 3.02 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 F A, Project Name: Caswell County Landfill rs Project Location: Landfill Road, Yanceyville, NC t Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW3 Purge Time: 80 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Gary Simcox Sample Time: 11:20 Weather: Sunny Air Temp: 60° F Water Level & Well Data Field Parameters (Taken at time intervals _> 5 minutes an purge volumes _> 1 flow -through cell volume) Final: 11:15 1.7 80 13.41 15.0 6.0 545 0.6 62 40.5 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 11:20 Sample End Time: 11:35 Analytical Data Name Signature Date (1) Gary Simcox 6/17/2022 Notes: The well and protective cover are in good condition. I emptied the flow cell at 1142 hours (too much Turbidy). Measuring Point: Top of Casing Depth to Water: 10.45 ft-TOC Total Well Depth: 17.80 ft-TOC Height of Water Column: 7.35 feet Screen Length: 10 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 1.2 Gal 3 *Well Volume 3.60 Gal 5 *Well Volume 6.00 Gal Purge Method: Peristaltic Pump Start Time: 9:55 End Time: 11:15 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 16.0 ft-TOC Water Column Above Pump Intake: 5.55 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 11.84 ft-TOC Comments: Final Volume Purged: 1.7 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 80 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water A Temp (°C) pH (s.u.) Spec. Cond. (PS/CM) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 09:55 0.0 --- --- --- --- --- --- --- --- Start Purging 10:05 0.2 80 11.23 13.6 5.9 530 1.0 63 59.5 10:15 0.4 80 11.98 13.8 6.0 539 0.5 57 35.8 10:25 0.6 80 12.34 13.9 6.0 540 0.5 56 39.6 10:35 0.8 80 12.75 14.3 6.0 536 0.6 56 50.4 10:45 1.1 80 13.09 14.3 6.0 538 0.5 55 44.3 10:55 1.3 80 13.31 14.5 6.0 538 0.6 56 46.1 11:05 1.5 80 13.39 15.1 6.0 541 0.6 60 41.1 11:15 1.7 80 13.41 15.0 6.0 545 0.6 62 40.5 Method Oty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 Caswell County Landfill Landfill Road, Yanceyville, NC Project Name: Project Location: Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW4 Purge Time: 30 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Gary Simcox Sample Time: 13:00 Weather: Sunny Air Temp: 75° F Water Level & Well Data We Purging Information Field Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow -through cell volume) Final: 12:55 0.8 100 27.33 17.8 6.3 1,197 0.7 -103 4.8 End of Purging Sample Method: Bladder Pump Sample Start Time: 13:00 Sample End Time: 13:10 Analytical Data (1) Gary Simcox 5/2/2022 Notes: The well is in good condition. Static water level before pump install (24.02).1 left the pump in apprx. 15 minutes before recording second water level and started ur in . Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 23.25 ft-TOC Total Well Depth: 36.10 ft-TOC Height of Water Column: 12.85 feet Screen Length: 5 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 2.1 Gal 3 *Well Volume 6.29 Gal 5 *Well Volume 10.48 Gal Purge Method: Bladder Pump Start Time: 12:25 End Time: 12:55 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 34.0 ft-TOC Water Column Above Pump Intake: 10.75 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 25.94 ft-TOC Comments: Final Volume Purged: 0.8 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 12:25 0.0 --- --- --- --- --- --- --- --- Start Purging 12:30 0.1 100 24.46 17.7 6.1 982 1.5 -58 34.3 12:35 0.3 100 25.02 17.5 6.3 1,195 0.9 -93 10.8 12:40 0.4 100 25.65 17.8 6.3 1,203 0.8 -98 5.54 12:45 0.5 100 26.14 17.9 6.3 1,207 0.7 -101 5.22 12:50 0.7 100 26.68 17.9 6.3 1,200 0.7 -103 4.82 12:55 0.8 100 27.33 17.8 6.3 1,197 0.7 -103 4.83 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 3 40mL VOAs HCl 8 RCRA Metals 1 250mL P HNO3 s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW5 Purge Time: 55 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 12:00 Weather: Sunny Air Temp: 65° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Final: 1155 1.5 100 16.69 14.1 6.3 994 0.6 -11 86.8 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 12:00 Sample End Time: 12:15 Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: The well is in good condition but the hinge on the protective cover is broken. I collected the duplicate sample from this location. (Red bacteria/algae suspended in water causingturbidityto rise). 1145- Lifted tubingto et turbidity<10 NTUs. Measuring Point: Top of Casing Depth to Water: 8.57 ft-TOC Total Well Depth: 24.70 ft-TOC Height of Water Column: 16.13 feet Screen Length: 10 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 2.6 Gal 3 *Well Volume 7.90 Gal 5 *Well Volume 13.16 Gal Purge Method: Peristaltic Pump Start Time: 11:00 End Time: 11:55 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 22.0 ft-TOC Water Column Above Pump Intake: 13.43 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 11.93 ft-TOC Comments: Final Volume Purged: 1.5 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 11:00 0.0 --- --- --- --- --- --- --- --- Start Purging 11:10 0.3 100 10.53 13.8 6.4 998 0.7 -6 92.9 11:15 0.4 100 11.11 13.8 6.3 995 0.5 -7 46.9 11:20 0.5 100 11.81 13.9 6.3 995 0.5 -8 46.4 11:25 0.7 100 12.68 14.0 6.3 993 0.5 -8 43.3 11:30 0.8 100 13.44 13.9 6.3 993 0.5 -9 61.1 11:35 0.9 100 14.07 13.7 6.3 997 0.7 -9 52.2 11:40 1.1 100 14.95 13.9 6.3 994 0.8 -9 42.9 11:45 1.2 100 15.60 14.0 6.3 994 0.7 -10 61.5 11:50 1.3 100 16.09 14.3 6.3 993 0.9 -10 101 11:55 1.5 100 16.69 14.1 6.3 994 0.6 -11 86.8 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034C phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW5D Purge Time: 35 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 10:30 Weather: Sunny Air Temp: 65° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Purging Sample Method: Bladder Pump Sample Start Time: 10:30 Sample End Time: 10:40 Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: The well and protective cover are in good condition. Measuring Point: Top of Casing Depth to Water: 8.99 ft-TOC Total Well Depth: 75.70 ft-TOC Height of Water Column: 66.71 feet Screen Length: 10 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 10.9 Gal 3 *Well Volume 32.66 Gal 5 *Well Volume 54.43 Gal Purge Method: Peristaltic Pump Start Time: 9:50 End Time: 10:25 (If Used) Bladder Pump Control Settings: On (sec): 5 Off (sec): 30 Pressure: psi Pump Intake Depth from Top of Casing: 73.0 ft-TOC Water Column Above Pump Intake: 64.01 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 24.99 ft-TOC Comments: Final Volume Purged: 0.9 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 09:50 0.0 --- --- --- --- --- --- --- --- Start Purging 09:55 0.1 100 9.84 13.7 6.8 1,025 1.1 -20 0.75 10:00 0.3 100 10.43 13.7 6.7 1,021 1.3 -28 0.46 10:05 0.4 100 11.05 13.9 6.7 1,018 2.6 -31 0.35 10:10 0.5 100 11.71 14.3 6.7 1,019 1.7 -33 0.75 10:15 0.7 100 12.61 14.3 6.7 1,017 1.5 -35 0.36 10:20 0.8 100 13.09 14.3 6.7 1,017 1.3 -36 0.11 10:25 0.9 100 13.50 14.4 6.6 1,013 1.1 -37 0.36 ative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 Caswell County Landfill Landfill Road, Yanceyville, NC Project Name: Project Location: Project Number: 1584-07-034 phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW6 Purge Time: 30 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Gary Simcox Sample Time: 9:30 Weather: Sunny Air Temp: 50° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow -through cell volume) Final: 09:25 0.8 100 10.50 13.2 6.2 113 3.4 72 3.6 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 09:30 Sample End Time: 09:40 Analytical Data (1) Gary Simcox 5/2/2022 Notes: The well and protective cover are in good condition. Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 7.83 ft-TOC Total Well Depth: 16.20 ft-TOC Height of Water Column: 8.37 feet Screen Length: 10 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 1.4 Gal 3 *Well Volume 4.10 Gal 5 *Well Volume 6.83 Gal Purge Method: Peristaltic Pump Start Time: 8:55 End Time: 9:25 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 15.0 ft-TOC Water Column Above Pump Intake: 7.17 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 9.62 ft-TOC Comments: Final Volume Purged: 0.8 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 08:55 0.0 --- --- --- --- --- --- --- --- Start Purging 09:00 0.1 100 8.45 12.7 6.3 121 4.2 61 5.44 09:05 0.3 100 8.91 12.8 6.2 115 3.6 63 6.01 09:10 0.4 100 9.27 13.2 6.2 114 3.5 66 3.63 09:15 0.5 100 9.86 13.2 6.2 113 3.3 69 5.14 09:20 0.7 100 10.22 13.1 6.2 113 3.3 71 4.01 09:25 0.8 100 10.50 13.2 6.2 113 3.4 72 3.59 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCl 8 RCRA Metals 1 250mL P HNO3 Caswell County Landfill Landfill Road, Yanceyville, NC Project Name: Project Location: Project Number: 1584-07-034C phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW7 Purge Time: 110 Minutes Locked?: Yes Sample Date: April 1, 1948 Sampled By: Gary Simcox Sample Time: 15:40 Weather: Sunny Air Temp: 75° F Water Level & Well Data We Purging Information Field Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow -through cell volume) Final: 15:35 2.9 100 33.34 17.8 6.4 568 0.5 9 54.9 End of Purging Sample Method: Bladder Pump Sample Start Time: 15:40 Sample End Time: 15:50 Analytical Data (1) Gary Simcox 5/2/2022 Notes: The well is in good condition. Static water level before pump install (19.59).1 left the pump in apprx. 15 minutes before recording second water level and started ur in . Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 19.38 ft-TOC Total Well Depth: 39.90 ft-TOC Height of Water Column: 20.52 feet Screen Length: 25 feet Stickup: 3 ft-GRD Well Volume Well Diameter 2 inch Water Volume 3.3 Gal 3 *Well Volume 10.05 Gal 5 *Well Volume 16.74 Gal Purge Method: Bladder Pump Start Time: 13:45 End Time: 15:35 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 38.0 ft-TOC Water Column Above Pump Intake: 18.62 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 24.04 ft-TOC Comments: Final Volume Purged: 2.9 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 13:45 0.0 --- --- --- --- --- --- --- --- Start Purging 13:50 0.1 100 19.60 20.0 6.4 909 3.4 -70 89.1 13:55 0.3 100 19.76 17.5 6.5 595 1.2 -34 109 14:00 0.4 100 19.88 17.4 6.5 583 0.8 -25 124 14:05 0.5 100 20.05 17.3 6.4 580 0.6 -19 125 14:10 0.7 100 20.21 17.4 6.4 577 0.6 -15 123 14:15 0.8 100 20.37 17.4 6.4 578 0.6 -12 120 14:25 1.1 100 20.71 17.4 6.4 576 0.5 -7 114 14:35 1.3 100 21.00 17.4 6.4 575 0.4 -5 112 14:45 1.6 100 21.28 17.5 6.4 573 0.4 -2 100 14:55 1.8 100 21.54 17.6 6.5 572 0.4 0 91.1 15:05 2.1 100 21.71 17.7 6.4 571 0.4 1 76.1 15:15 2.4 100 21.87 17.8 6.4 570 0.5 6 67.0 15:25 2.6 100 22.14 17.8 6.4 569 0.5 8 61.4 15:35 2.9 100 33.34 17.8 6.4 568 0.5 9 54.9 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCl 8 RCRA Metals 1 250mL P HNO3 s AN 0 Project Name: Caswell County Landfill Rr Project Location: Landfill Road, Yanceyville, NC I I E Project Number: 1584-07-034C phase 26 Purge Date: April 28, 2022 Source Well: 1701-MW8 Purge Time: 55 Minutes Locked?: Yes Sample Date: April 28, 2022 Sampled By: Cody McMechen Sample Time: 15:15 Weather: Sunny Air Temp: 70° F Water Level & Well Data We Purging Information Fie Parameters (Taken at time intervals a minutes an purge volumes >_ 1 flow -through cellvolume) Final: 15:10 1.5 100 24.12 16.7 5.8 161 0.2 -1 8.1 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 15:15 Sample End Time: 15:20 Analytical Data Name Signature Date (1) Cody McMechen 4/28/2022 Notes: The well and protective cover are in good condition. Measuring Point: Top of Casing Depth to Water: 23.91 ft-TOC Total Well Depth: 32.80 ft-TOC Height of Water Column: 8.89 feet Screen Length: 20 feet Stickup: 3 ft-GRD Well Volume Well Diameter 2 inch Water Volume 1.5 Gal 3 *Well Volume 4.35 Gal 5 *Well Volume 7.25 Gal Purge Method: Bladder Pump Start Time: 14:15 End Time: 15:10 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 30.0 ft-TOC Water Column Above Pump Intake: 6.09 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 25.43 ft-TOC Comments: Final Volume Purged: 1.5 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 100 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 14:15 0.0 --- --- --- --- --- --- --- --- Start Purging 14:20 0.1 100 24.03 17.3 5.9 108 0.8 33 57.8 14:25 0.3 100 24.05 17.4 5.6 117 0.5 29 52.6 14:30 0.4 100 24.05 17.0 5.6 131 0.3 19 31.9 14:35 0.5 100 24.06 16.8 5.6 131 0.3 19 29.5 14:40 0.7 100 24.07 16.7 5.7 138 0.2 13 21.5 14:45 0.8 100 24.07 16.8 5.7 146 0.3 4 17.5 14:50 0.9 100 24.08 16.7 5.7 150 0.2 3 14.2 14:55 1.1 100 24.09 16.8 5.8 153 0.2 -1 11.7 15:00 1.2 100 24.10 16.8 5.8 155 0.2 -3 10.3 15:05 1.3 100 24.11 16.8 5.8 158 0.2 -4 7.67 15:10 1.5 100 24.12 16.7 5.8 161 0.2 -1 8.06 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Form Revision Date: 2/12/18 16:00 Caswell County Landfill Landfill Road, Yanceyville, NC Project Name: Project Location: Project Number: 1584-07-034 phase 26 Purge Date: April 29, 2022 Source Well: 1701-MW9 Purge Time: 60 Minutes Locked?: Yes Sample Date: April 29, 2022 Sampled By: Gary Simcox Sample Time: 11:40 Weather: Overcast Air Temp: 55° F Water Level & Well Data We Purging Information Field Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow -through cell volume) Final: 11:35 4.8 300 20.76 15.2 5.8 187 4.8 84 27.2 End of Purging Sample Method: Submersible Pump Sample Start Time: 11:40 Sample End Time: 11:45 Analytical Data (1) Gary Simcox A� J.i�rirox 5/2/2022 Notes: The well and protective cover are in good condition. I installed new dedicated bonded tubing for the bladder pump at this location. Static water level before um install (20.32). 1 left the um in a rx. 15 minutes before recordingsecond water level and startedpurging. Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 20.30 ft-TOC Total Well Depth: 37.50 ft-TOC Height of Water Column: 17.20 feet Screen Length: 30 feet Stickup: 2.5 ft-GRD Well Volume Well Diameter 2 inch Water Volume 2.8 Gal 3 *Well Volume 8.42 Gal 5 *Well Volume 14.03 Gal Purge Method: Submersible Pump Start Time: 10:35 End Time: 11:35 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 34.0 ft-TOC Water Column Above Pump Intake: 13.70 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 23.73 ft-TOC Comments: Final Volume Purged: 4.8 Gallons Used YSI Pro Plus, Final Volume Purge Rate: 300 mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 10:35 0.0 --- --- --- --- --- --- --- --- Start Purging 10:40 0.4 300 20.75 15.1 5.9 243 6.7 88 755 10:45 0.8 300 20.76 15.0 5.9 227 6.2 89 763 10:50 1.2 300 20.76 14.9 5.9 214 5.8 89 375 10:55 1.6 300 20.76 15.1 5.9 212 5.4 88 315 11:00 2.0 300 20.76 15.2 5.8 206 5.5 88 237 11:05 2.4 300 20.76 15.3 5.8 200 5.5 87 182 11:10 2.8 300 20.76 15.1 5.8 195 4.9 87 133 11:15 3.2 300 20.76 15.2 5.8 192 4.9 86 103 11:20 3.6 300 20.76 15.2 5.8 191 4.9 85 73.6 11:25 4.0 300 20.76 15.2 5.8 189 4.9 85 51.7 11:30 4.4 300 20.76 15.1 5.8 187 4.9 85 41.0 11:35 4.8 300 20.76 15.2 5.8 187 4.8 84 27.2 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCl 8 RCRA Metals 1 250mL P HNO3 Caswell County Landfill Landfill Road, Yanceyville, INC 1584-07-034 phase 26 Purge Date: April 29, 2022 Project Name: Project Location: Project Number: Source Well: 1701-MW10 Purge Time: 0 Minutes Locked?: Yes Sample Date: April 29, 2022 Sampled By: Gary Simcox Sample Time: 12:45 Weather: Overcast Air Temp: 60° F Water Level Well Data We Purging Information Field Parameters (Taken at time intervals >_ 5 minutes and purge volumes >_ 1 flow-throughcellvolume) Final: 12:55 14.9 6.2 444 0.5 10 4.4 End of Purging Sample Method: Peristaltic Pump Sample Start Time: 12:45 Sample End Time: 12:55 Analytical Data (1) Gary Simcox �a �timedx 5/2/2022 Notes: The well and protective cover are in good condition. Form Revision Date: 2/12/18 16:00 Measuring Point: Top of Casing Depth to Water: 7.13 ft-TOC Total Well Depth: 50.30 ft-TOC Height of Water Column: 43.17 feet Screen Length: 30 feet Stickup: 2.5 ft-GRID Well Volume Well Diameter 2 inch Water Volume 7.0 Gal 3 *Well Volume 21.13 Gal 5 *Well Volume 35.22 Gal Purge Method: Start Time: 12:55 End Time: 12:55 (If Used) Bladder Pump Control Settings: On (sec): Off (sec): Pressure: psi Pump Intake Depth from Top of Casing: 33.0 ft-TOC Water Column Above Pump Intake: 25.87 feet Flow Through Cell Vol: 200 mL DTW-TOC at 25% Drawdown of WC Above Pump: 13.60 ft-TOC Comments: Final Volume Purged: Gallons Used YSI Pro Plus, Final Volume Purge Rate: mL/min Well Purged Dry?: No (Yes/No) Time Volume Purged (gal) Flow Rate (mL/min) Depth to Water (ft) Temp (°C) pH (s.u.) Spec. Cond. (PS/cm) Dissolved Oxygen (mg/L) ORP* (mV) Turbidity (NTU) Comment 12:55 0.0 --- --- --- --- --- --- --- --- Start Purging 12:55 14.9 6.2 444 0.5 10 4.44 Method Qty Container Preservative Method Qty Container Preservative 8260 VOC App I 6 40mL VOAs HCI 8 RCRA Metals 1 250mL P HNO3 Appendix IV - Laboratory Analytical Report leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 June 08, 2022 Aubrey Fuqua Caswell County Landfill 162 Landfill Road Yanceyville, NC 27379 RE: Project: Caswell County Pace Project No.: 92601940 Dear Aubrey Fuqua: Enclosed are the analytical results for sample(s) received by the laboratory on April 29, 2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte • Pace Analytical Services - Peachtree Corners, GA If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Mr. Ed Henriques, S&ME, Inc. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 Pace Analytical Services Peachtree Corners 110 Technology Pkwy, Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 North Carolina Certification #: 381 South Carolina Certification #: 98011001 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE ANALYTE COUNT Project: Pace Project No.: Caswell County 92601940 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92601940001 1701-MW1 EPA 6010D DRB 7 PASI-GA EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940002 1701-MW2 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940003 1701-MW3 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940004 1701-MW4 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940005 1701-MW5 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940006 1701-MW5D EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940007 1701-MW6 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940008 1701-MW7 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940009 1701-MW8 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940010 1701-9 EPA 6010D RDT 7 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 SAMPLE ANALYTE COUNT Project: Caswell County Pace Project No.: 92601940 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940011 MWA701-10 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940012 1701-SW1 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940013 1701-SW2 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940014 1701-SW3 EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940015 1701-Duplicate EPA 6010D RDT 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92601940016 1701-Trip Blank EPA 8260D CL 52 PASI-C EPA 8260D Mod. LMB 3 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte PASI-GA = Pace Analytical Services - Peachtree Corners, GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW1 Parameters ANALYTICAL RESULTS Lab ID: 92601940001 Collected: 04/29/22 09:05 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010D ATL ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services - Peachtree Corners, GA Arsenic ND ug/L 30.0 1 06/07/2210:57 06/07/2218:02 7440-38-2 Barium 37.3 ug/L 10.0 1 06/07/2210:57 06/07/2218:02 7440-39-3 Cadmium ND ug/L 10.0 1 06/07/2210:57 06/07/2218:02 7440-43-9 Chromium ND ug/L 10.0 1 06/07/2210:57 06/07/2218:02 7440-47-3 Silver ND ug/L 10.0 1 06/07/2210:57 06/07/2218:02 7440-22-4 Lead ND ug/L 20.0 1 06/07/2210:57 06/07/2218:02 7439-92-1 Selenium ND ug/L 40.0 1 06/07/2210:57 06/07/2218:02 7782-49-2 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury 1.2 ug/L 0.20 1 05/14/22 23:07 05/16/22 14:19 7439-97-6 M1 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 17:31 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 17:31 107-13-1 Benzene ND ug/L 1.0 1 05/03/22 17:31 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 17:31 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 17:31 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 17:31 75-25-2 IK Bromomethane ND ug/L 2.0 1 05/03/22 17:31 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 17:31 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 17:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 17:31 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/03/22 17:31 108-90-7 Chloroethane ND ug/L 1.0 1 05/03/22 17:31 75-00-3 v2 Chloroform ND ug/L 1.0 1 05/03/22 17:31 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 17:31 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 17:31 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 17:31 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 17:31 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 17:31 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 05/03/22 17:31 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 1 05/03/22 17:31 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 17:31 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 17:31 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 17:31 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 17:31 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 17:31 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 17:31 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 17:31 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 17:31 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 17:31 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 17:31 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 17:31 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW1 Lab ID: 92601940001 Collected: 04/29/22 09:05 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane ND ug/L 20.0 1 05/03/22 17:31 74-88-4 Methylene Chloride ND ug/L 5.0 1 05/03/22 17:31 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/03/22 17:31 108-10-1 Styrene ND ug/L 1.0 1 05/03/22 17:31 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/03/22 17:31 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/03/22 17:31 79-34-5 Tetrachloroethene ND ug/L 1.0 1 05/03/22 17:31 127-18-4 Toluene ND ug/L 1.0 1 05/03/22 17:31 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 1 05/03/22 17:31 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1 05/03/22 17:31 79-00-5 Trichloroethene ND ug/L 1.0 1 05/03/22 17:31 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/03/22 17:31 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/03/22 17:31 96-18-4 Vinyl acetate ND ug/L 2.0 1 05/03/22 17:31 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/03/22 17:31 75-01-4 Xylene (Total) ND ug/L 1.0 1 05/03/22 17:31 1330-20-7 m&p-Xylene ND ug/L 2.0 1 05/03/22 17:31 179601-23-1 o-Xylene ND ug/L 1.0 1 05/03/22 17:31 95-47-6 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 05/03/22 17:31 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 05/03/22 17:31 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 05/03/22 17:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/03/22 22:51 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 05/03/22 22:51 17060-07-0 Toluene-d8(S) 97 % 70-130 1 05/03/22 22:51 2037-26-5 Date: 06/08/2022 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW2 Parameters ANALYTICAL RESULTS Lab ID: 92601940002 Collected: 04/29/22 13:30 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:41 7440-38-2 Barium 87.8 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:41 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:41 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:41 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:41 7439-92-1 Selenium 7.2J ug/L 10.0 1 05/11/22 10:42 05/19/22 00:41 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:41 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:27 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 10:04 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 10:04 107-13-1 Benzene 2.0 ug/L 1.0 1 05/03/22 10:04 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 10:04 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 10:04 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 10:04 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 10:04 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 10:04 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 10:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 10:04 56-23-5 Chlorobenzene 27.2 ug/L 1.0 1 05/03/22 10:04 108-90-7 Chloroethane 1.2 ug/L 1.0 1 05/03/22 10:04 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 10:04 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 10:04 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 10:04 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 10:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 10:04 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 10:04 74-95-3 1,2-Dichlorobenzene 1.2 ug/L 1.0 1 05/03/22 10:04 95-50-1 1,4-Dichlorobenzene 9.0 ug/L 1.0 1 05/03/22 10:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 10:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 10:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 10:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 10:04 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 10:04 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 10:04 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 10:04 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 10:04 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 10:04 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 10:04 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 10:04 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW2 Lab ID: 92601940002 Collected: 04/29/22 13:30 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte lodomethane ND ug/L 20.0 1 05/03/22 10:04 74-88-4 Methylene Chloride ND ug/L 5.0 1 05/03/22 10:04 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/03/22 10:04 108-10-1 Styrene ND ug/L 1.0 1 05/03/22 10:04 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/03/22 10:04 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/03/22 10:04 79-34-5 Tetrachloroethene ND ug/L 1.0 1 05/03/22 10:04 127-18-4 Toluene ND ug/L 1.0 1 05/03/22 10:04 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 1 05/03/22 10:04 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1 05/03/22 10:04 79-00-5 Trichloroethene ND ug/L 1.0 1 05/03/22 10:04 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/03/22 10:04 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/03/22 10:04 96-18-4 Vinyl acetate ND ug/L 2.0 1 05/03/22 10:04 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/03/22 10:04 75-01-4 Xylene (Total) ND ug/L 1.0 1 05/03/22 10:04 1330-20-7 m&p-Xylene ND ug/L 2.0 1 05/03/22 10:04 179601-23-1 o-Xylene ND ug/L 1.0 1 05/03/22 10:04 95-47-6 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 05/03/22 10:04 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-130 1 05/03/22 10:04 17060-07-0 Toluene-d8 (S) 105 % 70-130 1 05/03/22 10:04 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 1,4-Dioxane (p-Dioxane) 7.1 ug/L 2.0 1 05/04/22 20:19 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 05/04/22 20:19 17060-07-0 Toluene-d8 (S) 92 % 70-130 1 05/04/22 20:19 2037-26-5 Date: 06/08/2022 11:50 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW3 Parameters ANALYTICAL RESULTS Lab ID: 92601940003 Collected: 04/29/22 11:20 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:44 7440-38-2 Barium 58.5 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:44 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:44 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:44 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:44 7439-92-1 Selenium 6.5J ug/L 10.0 1 05/11/22 10:42 05/19/22 00:44 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:44 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:30 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 17:49 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 17:49 107-13-1 Benzene 0.45J ug/L 1.0 1 05/03/22 17:49 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 17:49 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 17:49 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 17:49 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 17:49 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 17:49 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 17:49 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 17:49 56-23-5 Chlorobenzene 15.4 ug/L 1.0 1 05/03/22 17:49 108-90-7 Chloroethane ND ug/L 1.0 1 05/03/22 17:49 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 17:49 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 17:49 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 17:49 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 17:49 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 17:49 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 17:49 74-95-3 1,2-Dichlorobenzene 0.72J ug/L 1.0 1 05/03/22 17:49 95-50-1 1,4-Dichlorobenzene 3.2 ug/L 1.0 1 05/03/22 17:49 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 17:49 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 17:49 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 17:49 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 17:49 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 17:49 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 17:49 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 17:49 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 17:49 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 17:49 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 17:49 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 17:49 591-78-6 REPORT OF LABORATORY ANALYSIS IK v2 This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW3 Lab ID: 92601940003 Collected: 04/29/22 11:20 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2022 11:50 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 % 98 % 97 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 6.6 ug/L 106 % 98 % 20.0 1 05/03/22 17:49 74-88-4 5.0 1 05/03/22 17:49 75-09-2 5.0 1 05/03/22 17:49 108-10-1 1.0 1 05/03/22 17:49 100-42-5 1.0 1 05/03/22 17:49 630-20-6 1.0 1 05/03/22 17:49 79-34-5 1.0 1 05/03/22 17:49 127-18-4 1.0 1 05/03/22 17:49 108-88-3 1.0 1 05/03/22 17:49 71-55-6 1.0 1 05/03/22 17:49 79-00-5 1.0 1 05/03/22 17:49 79-01-6 1.0 1 05/03/22 17:49 75-69-4 1.0 1 05/03/22 17:49 96-18-4 2.0 1 05/03/22 17:49 108-05-4 1.0 1 05/03/22 17:49 75-01-4 1.0 1 05/03/22 17:49 1330-20-7 2.0 1 05/03/22 17:49 179601-23-1 1.0 1 05/03/22 17:49 95-47-6 70-130 1 70-130 1 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/03/22 17:49 460-00-4 05/03/22 17:49 17060-07-0 05/03/22 17:49 2037-26-5 [eI.'i 1*1F ��eIei[e10MPaS4 N 05/04/22 00:09 17060-07-0 05/04/22 00:09 2037-26-5 Page 10 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW4 Parameters ANALYTICAL RESULTS Lab ID: 92601940004 Collected: 04/29/22 13:00 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:48 7440-38-2 Barium 57.2 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:48 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:48 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:48 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:48 7439-92-1 Selenium ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:48 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:48 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:32 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 18:08 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 18:08 107-13-1 Benzene 1.4 ug/L 1.0 1 05/03/22 18:08 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 18:08 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 18:08 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 18:08 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 18:08 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 18:08 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 18:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 18:08 56-23-5 Chlorobenzene 9.2 ug/L 1.0 1 05/03/22 18:08 108-90-7 Chloroethane 0.66J ug/L 1.0 1 05/03/22 18:08 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 18:08 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 18:08 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 18:08 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 18:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 18:08 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 18:08 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 05/03/22 18:08 95-50-1 1,4-Dichlorobenzene 1.7 ug/L 1.0 1 05/03/22 18:08 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 18:08 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 18:08 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 18:08 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 18:08 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:08 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 18:08 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:08 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 18:08 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 18:08 591-78-6 REPORT OF LABORATORY ANALYSIS IK v2 This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW4 Lab ID: 92601940004 Collected: 04/29/22 13:00 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2022 11:50 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 0.60J ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 % 98 % 96 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 7.6 ug/L 106 % 97 % 20.0 1 05/03/22 18:08 74-88-4 5.0 1 05/03/22 18:08 75-09-2 5.0 1 05/03/22 18:08 108-10-1 1.0 1 05/03/22 18:08 100-42-5 1.0 1 05/03/22 18:08 630-20-6 1.0 1 05/03/22 18:08 79-34-5 1.0 1 05/03/22 18:08 127-18-4 1.0 1 05/03/22 18:08 108-88-3 1.0 1 05/03/22 18:08 71-55-6 1.0 1 05/03/22 18:08 79-00-5 1.0 1 05/03/22 18:08 79-01-6 1.0 1 05/03/22 18:08 75-69-4 1.0 1 05/03/22 18:08 96-18-4 2.0 1 05/03/22 18:08 108-05-4 1.0 1 05/03/22 18:08 75-01-4 1.0 1 05/03/22 18:08 1330-20-7 2.0 1 05/03/22 18:08 179601-23-1 1.0 1 05/03/22 18:08 95-47-6 70-130 1 70-130 1 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/03/22 18:08 460-00-4 05/03/22 18:08 17060-07-0 05/03/22 18:08 2037-26-5 [eI.'iLeLlf���eIe7Y�:�iN�c�;SQiI 05/04/22 00:28 17060-07-0 05/04/22 00:28 2037-26-5 Page 12 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW5 Parameters ANALYTICAL RESULTS Lab ID: 92601940005 Collected: 04/28/22 12:00 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:51 7440-38-2 Barium 28.2 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:51 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:51 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:51 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:51 7439-92-1 Selenium ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:51 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:51 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:41 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 18:26 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 18:26 107-13-1 Benzene 1.8 ug/L 1.0 1 05/03/22 18:26 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 18:26 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 18:26 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 18:26 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 18:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 18:26 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 18:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 18:26 56-23-5 Chlorobenzene 18.8 ug/L 1.0 1 05/03/22 18:26 108-90-7 Chloroethane 0.77J ug/L 1.0 1 05/03/22 18:26 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 18:26 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 18:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 18:26 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 18:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 18:26 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 18:26 74-95-3 1,2-Dichlorobenzene 1.9 ug/L 1.0 1 05/03/22 18:26 95-50-1 1,4-Dichlorobenzene 14.5 ug/L 1.0 1 05/03/22 18:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 18:26 110-57-6 1,1-Dichloroethane 0.37J ug/L 1.0 1 05/03/22 18:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 18:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 18:26 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:26 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:26 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 18:26 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:26 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 18:26 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 18:26 591-78-6 REPORT OF LABORATORY ANALYSIS IK v2 This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW5 Lab ID: 92601940005 Collected: 04/28/22 12:00 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2022 11:50 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 0.37J ug/L ND ug/L 0.37J ug/L 98 % 99 % 96 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 14.8 ug/L 107 % 96 % 20.0 1 05/03/22 18:26 74-88-4 5.0 1 05/03/22 18:26 75-09-2 5.0 1 05/03/22 18:26 108-10-1 1.0 1 05/03/22 18:26 100-42-5 1.0 1 05/03/22 18:26 630-20-6 1.0 1 05/03/22 18:26 79-34-5 1.0 1 05/03/22 18:26 127-18-4 1.0 1 05/03/22 18:26 108-88-3 1.0 1 05/03/22 18:26 71-55-6 1.0 1 05/03/22 18:26 79-00-5 1.0 1 05/03/22 18:26 79-01-6 1.0 1 05/03/22 18:26 75-69-4 1.0 1 05/03/22 18:26 96-18-4 2.0 1 05/03/22 18:26 108-05-4 1.0 1 05/03/22 18:26 75-01-4 1.0 1 05/03/22 18:26 1330-20-7 2.0 1 05/03/22 18:26 179601-23-1 1.0 1 05/03/22 18:26 95-47-6 70-130 1 70-130 1 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/03/22 18:26 460-00-4 05/03/22 18:26 17060-07-0 05/03/22 18:26 2037-26-5 [eI.'iLeLlf��►�eIeiCl/tiN�c�;SQiI 05/04/22 00:47 17060-07-0 05/04/22 00:47 2037-26-5 Page 14 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW5D Parameters ANALYTICAL RESULTS Lab ID: 92601940006 Collected: 04/28/22 10:30 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic 5.7J ug/L 10.0 1 05/11/22 10:42 05/19/22 00:55 7440-38-2 Barium 57.0 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:55 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:55 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:55 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:55 7439-92-1 Selenium ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:55 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:55 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:43 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 18:44 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 18:44 107-13-1 Benzene 0.75J ug/L 1.0 1 05/03/22 18:44 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 18:44 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 18:44 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 18:44 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 18:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 18:44 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 18:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 18:44 56-23-5 Chlorobenzene 2.1 ug/L 1.0 1 05/03/22 18:44 108-90-7 Chloroethane ND ug/L 1.0 1 05/03/22 18:44 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 18:44 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 18:44 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 18:44 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 18:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 18:44 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 18:44 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 05/03/22 18:44 95-50-1 1,4-Dichlorobenzene 0.511 ug/L 1.0 1 05/03/22 18:44 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 18:44 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 18:44 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 18:44 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 18:44 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 18:44 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 18:44 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:44 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 18:44 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 18:44 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 18:44 591-78-6 REPORT OF LABORATORY ANALYSIS IK v2 This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 ANALYTICAL RESULTS Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW5D Lab ID: 92601940006 Collected: 04/28/22 10:30 Received: 04/29/22 13:30 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/08/2022 11:50 AM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 % 99 % 97 % Analytical Method: EPA 8260D Mod. Pace Analytical Services - Charlotte 6.9 ug/L 103 % 96 % 20.0 1 05/03/22 18:44 74-88-4 5.0 1 05/03/22 18:44 75-09-2 5.0 1 05/03/22 18:44 108-10-1 1.0 1 05/03/22 18:44 100-42-5 1.0 1 05/03/22 18:44 630-20-6 1.0 1 05/03/22 18:44 79-34-5 1.0 1 05/03/22 18:44 127-18-4 1.0 1 05/03/22 18:44 108-88-3 1.0 1 05/03/22 18:44 71-55-6 1.0 1 05/03/22 18:44 79-00-5 1.0 1 05/03/22 18:44 79-01-6 1.0 1 05/03/22 18:44 75-69-4 1.0 1 05/03/22 18:44 96-18-4 2.0 1 05/03/22 18:44 108-05-4 1.0 1 05/03/22 18:44 75-01-4 1.0 1 05/03/22 18:44 1330-20-7 2.0 1 05/03/22 18:44 179601-23-1 1.0 1 05/03/22 18:44 95-47-6 70-130 1 70-130 1 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/03/22 18:44 460-00-4 05/03/22 18:44 17060-07-0 05/03/22 18:44 2037-26-5 05/04/22 01:07 17060-07-0 05/04/22 01:07 2037-26-5 Page 16 of 58 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 205 East Meadow Road - Suite A Eden, NC 27288 (336)623-8921 Project: Caswell County Pace Project No.: 92601940 Sample: 1701-MW6 Parameters ANALYTICAL RESULTS Lab ID: 92601940007 Collected: 04/28/22 09:30 Received: 04/29/22 13:30 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Pace Analytical Services -Asheville Arsenic ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:58 7440-38-2 Barium 8.7 ug/L 5.0 1 05/11/22 10:42 05/19/22 00:58 7440-39-3 Cadmium ND ug/L 1.0 1 05/11/22 10:42 05/19/22 00:58 7440-43-9 Chromium ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:58 7440-47-3 Lead ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:58 7439-92-1 Selenium ND ug/L 10.0 1 05/11/22 10:42 05/19/22 00:58 7782-49-2 Silver ND ug/L 5.0 1 05/11/22 10:42 05/19/22 00:58 7440-22-4 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville Mercury ND ug/L 0.20 1 05/14/22 23:07 05/16/22 14:46 7439-97-6 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 1 05/03/22 19:02 67-64-1 Acrylonitrile ND ug/L 10.0 1 05/03/22 19:02 107-13-1 Benzene ND ug/L 1.0 1 05/03/22 19:02 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/03/22 19:02 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/03/22 19:02 75-27-4 Bromoform ND ug/L 1.0 1 05/03/22 19:02 75-25-2 Bromomethane ND ug/L 2.0 1 05/03/22 19:02 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 05/03/22 19:02 78-93-3 Carbon disulfide ND ug/L 2.0 1 05/03/22 19:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/03/22 19:02 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/03/22 19:02 108-90-7 Chloroethane ND ug/L 1.0 1 05/03/22 19:02 75-00-3 Chloroform ND ug/L 1.0 1 05/03/22 19:02 67-66-3 Chloromethane ND ug/L 1.0 1 05/03/22 19:02 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/03/22 19:02 96-12-8 Dibromochloromethane ND ug/L 1.0 1 05/03/22 19:02 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 05/03/22 19:02 106-93-4 Dibromomethane ND ug/L 1.0 1 05/03/22 19:02 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 05/03/22 19:02 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 1 05/03/22 19:02 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1 05/03/22 19:02 110-57-6 1,1-Dichloroethane ND ug/L 1.0 1 05/03/22 19:02 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 05/03/22 19:02 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 05/03/22 19:02 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 19:02 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/03/22 19:02 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 05/03/22 19:02 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 19:02 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/03/22 19:02 10061-02-6 Ethylbenzene ND ug/L 1.0 1 05/03/22 19:02 100-41-4 2-Hexanone ND ug/L 5.0 1 05/03/22 19:02 591-78-6 REPORT OF LABORATORY ANALYSIS IK v2 This report shall not be reproduced, except in full, Date: 06/08/2022 11:50 AM without the written consent of Pace Analytical Services, LLC. 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