0901_BladenMSW_Dec21_Monitoring_FID1741304_20220714

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DENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Smith Gardner, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Seth C. Rickerts, P.G.
E-mail: [e-mail]
Phone: [phone] x 135
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Bladen Co. Closed MSW Landfill 1522
52 Mercer Mill Road, Elizabethtown, 09-01 .0500 December 22, 2021
NC
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells ❑
Leachate monitoring data El
water monitoring data
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Seth C. Rickerts, P.G. Project Geologist 919-828-0577 x 135
Name (Print)
14 N. Boylan Ave, Raleigh, NC 27603
Title
Facility Representative Address
C0828
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
7/14/2022
Date
(Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
NSF
�SEALQ
7/14/2822
2'7S8Al L0
=
C. BIG. *��.

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DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
December 2021 Annual Groundwater Monitoring Report
Bladen County Closed MSW Landfill
NC Solid Waste Permit No. o9-ol
Prepared for:
Bladen County Solid Waste Management
1522 Mercer Mill Road
Elizabethtown, North Carolina 28337
0
July 2022
Prepared by:
NCBCARF-1370 (FNGINFERING)
SMITH GARDNER
14 N. Boylan Avenue, Raleigh NC 27633 1919,828 0577
? PRINTED CN 100% RECYCLED PAPER
0=SmithGardner Inc.
This document is intended for the sole use of the client for which it was prepared and
for the purpose agreed on by the client and Smith Gardner, Inc.

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DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
December2021 Groundwater Monitoring Report
Bladen County Closed MSW Landfill
Solid Waste Permit No. 09-01
Prepared For:
Bladen County Solid Waste Management
Elizabethtown, North Carolina
S+G Project No. Bladen 08-04
'^\D o c u S i g n e dbb y:
�1`Z.hi e.i V {QVLi�1�ieA
B7-3BBA€�Q'nn�...
DanielJ. Pantaleo
Staff Environmental Technician
DocuSigned by::
Scan c— iZ1el�ct�5
05GP78€A4E5...
Seth C. Rickerts, P.G.
Project Geologist
July 2022
,,. N C A q •-.,
SEAL 7/ /zDzz
2758 =
NCLICARF-1370 (EVN£ERING)
SMITH GARDNER
14 N. Buyk Avenue Raleigh NC N633 1 919,828 8577

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DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
Bladen County Closed MSW Landfill
NC Solid Waste Permit No. 09-01
December2021 Groundwater Monitoring Report
Table of Contents
Paqe
1.0 INTRODUCTION.............................................................................................................
2.0 SITE GEOLOGY...............................................................................................................
3.0 SAMPLING LOCATIONS.................................................................................................
4.0 SAMPLING PROCEDURES.............................................................................................
5.0 FIELD AND LABORATORY RESULTS..............................................................................
5.1 Field Parameter Results........................................................................................
5.2 Laboratory Results................................................................................................
5.2.1 Inorganic Constituent Results...................................................................
5.2.2 Organic Constituent Results......................................................................
5.2.3 Surface Water Results...............................................................................
6.0 GROUNDWATER CHARACTERIZATION..........................................................................
7.0 SITE ASSESSMENT........................................................................................................
8.0 CONCLUSIONS..............................................................................................................
FIGURE
Figure 1
TABLES
Table 1
Table 2
Table 3
Table 4
APPENDICES
Appendix A
Appendix B
Bladen County Closed MSW Landfill
July 2022
Groundwater Potentiometric Map
Groundwater Elevation Data
Field Parameters
Detected Inorganic Constituents
Detected Organic Constituents
Laboratory Analytical Report
Time vs Concentration Graphs
3
3
3
3
4
4
4
4
4
5
5
5
5
December 2021 Groundwater Monitoring Report
Page 1

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1.0 INTRODUCTION
The closed, unlined Bladen County Municipal Solid Waste (MSW) Landfill (Solid Waste Permit #
09-01) requires semi-annual groundwater monitoring as a condition of the water quality
monitoring program. This report, prepared by Smith Gardner, Inc. (S+G), presents the
December 22, 2021 monitoring event results. This event was performed in compliance with NC
Solid Waste Regulations.
As specified in the October 2006 Electronic Deliverables Memo' and the November 5, 2014
Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal
Mem02, this report includes a Solid Waste Section (SWS) Environmental Monitoring Report
Form and field procedure and laboratory analyses summaries for the closed MSW site. A
potentiometric surface map, summary tables and laboratory analytical report are also included.
2.0 SITE GEOLOGY
The Bladen County MSW Landfill is located off Highway 87 just east of Elizabethtown in the
Coastal Plain physiographic province. According to the Geologic Map of North Carolina 119851,
this area is underlain by the Black Creek Formation, which is characterized by gray to black
lignitic clay with thin beds of fine grained sands and thick lenses of cross-grained sand.
3.0 SAMPLING LOCATIONS
The groundwater monitoring network for the MSW landfill includes seven groundwater
monitoring wells (MW-1, MW-3, MW-4, MW-5A, MW-7, MW-8 and MW-91 and three surface
water locations (SW-1, SW-2, and SW-31. MW-1 serves as the background location. SW-3 is
located downstream of MW-9 and was incorporated into the monitoring network when the site
assessement moinitoring plan' was approved in 2019. Figure 1 illustrates the sampling
locations. The sampling event was reportedly performed by Environment 1, Inc. (Greenville, NC)
personnel on December 22, 2021.
4.0 SAMPLING PROCEDURES
Sampling methods followed the protocol outlined in the North Carolina Water Quality
Monitoring Guidance Document for Solid Waste Facilities (Department of Environmental Quality
(DEQ), Division of Waste Management (DWM)). The depth to water in each well was gauged
' New Guidelines for Electronic Submittal of Environmental Monitoring Data Memo, NCDENR - Solid Waste Section,
October 27, 2006
2 Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal, NCDENR - Solid
Waste Section, November 5, 2014.
3 Water Quality Assessment Action Workplan - Approval, Letter from Perry Sugg, P.G. to Kip McClary August 14, 2019
Bladen County Closed MSW Landfill December 2021 Groundwater Monitoring Report
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prior to purging and sampling. Field parameters for pH, specific conductivity, temperature and
turbidity were analyzed at each sampling location using direct read instruments. Turbidity was
not monitored at surface water locations this event. Water table elevations are included in Table
1.
Samples were collected by Environment 1, Inc. personnel in laboratory prepared containers.
Groundwater samples were properly preserved, placed on ice and transported to the laboratory
facility (Environment 1, Inc.), within the specified hold times for each analysis.
5.0 FIELD AND LABORATORY RESULTS
5.1 Field Parameter Results
Temperature, pH, specific conductance, and turbidity were measured in the field at the
time of sampling. The field parameter results are summarized in Table 2 and have
remained generally consistent with previously reported sampling events.
5.2 Laboratory Results
Samples were transported to the laboratory facility under proper chain of custody and
analyzed to the laboratory established Method Detection Limits (MDL) for each
parameter. Groundwater sample analytical results were compared with the North
Carolina Administrative Code (NCAC) 2L.0200 2L Standard (2L), Solid Waste Section
Groundwater Protection (GWP) Standards, NC DWM Solid Waste Section Limits (SWSL) 4
and Federal Maximum Contaminant Limits (MCL). Surface water sample analytical
results were compared with the 15A NCAC 213 Standard (213) for Class C waters. MW-9
and SW-3 were specifically analyzed for Appendix II constituents and were non -
detectable.
Tables 3 and 4 summarizes the detected constituent list. Several constituents were
detected above their MDL at concentrations below the laboratory's method reporting
limits (MRL) and are listed as "Y' values on the tables.. The laboratory report is included
as Appendix A.
5.2.1 Inorganic Constituent Results
No inorganic constituents were detected in collected samples above their NC21-
or GWP standards this event.
5.2.2 Organic Constituent Results
4 New Guidelines for electronic submittal of environmental monitoring data memo, NCDENR DWM, Solid Waste Section, October 27, 2006.
Bladen County Closed MSW Landfill December 2021 Groundwater Monitoring Report
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Three organic constituents were detected in collected samples above their NC21-
standard during this event.
• Benzene (MW-9);
• Vinyl Chloride (MW-9); and
• 1,4-Dioxane (MW-9).
5.2.3 Surface Water Results
There were no detections of inorganic or organic constituents above their 2B
standards in samples from the surface water locations this event. This includes
the newly established SW-3 downstream of MW-9.
6.0 GROUNDWATER CHARACTERIZATION
A potentiometric map (Figure 21 for the uppermost aquifer, was prepared from the groundwater
elevation data for this sampling event. The data indicates that groundwater is flowing generally
north to northwest across most of the site. Hydraulic conductivity data is not available for these
wells so groundwater velocities could not be calculated.
7.0 SITE ASSESSMENT
In August 2019 S+G submitted a water quality assessment plans that was later approved by the
NCDEQ1. This plan included the addition of a surface water monitoring location (SW-3) adjacent
to monitoring well MW-9 which has exhibited water quality issues in the past. This assessment
is ongoing, however, this report indicates that concentrations of constituents detected in MW-9
are not impacting the quality of surface water at SW-3.
8.0 CONCLUSIONS
Elevated concentrations of organic constituents continue to be exhibited at MW-9. It is believed
that these elevated concentrations are due to the monitoring well's immediate proximity to the
waste boundary. 1,4-Dioxane was detected above the NC21- standard in only MW-9 this event
compared to 5 monitoring wells last event. 1,4-Dioxane will continue to be monitored during
future sampling events. Concenetrations of benzene and vinyl chloride are consistent with
historic detections.
It should be noted that SW-3, adjacent to and downstream of MW-9, showed no measurable
concentrations of the organic constituents present in MW-9. Additionally, the inorganic
constituents present in SW-3 were detected below their respective 213 standards. The
groundwater monitoring program is currently operating under an approved water quality
5 Smith Gardner, Inc. Water Quality Assessment Plan Bladen County Closed MSW Landfill, August 2019
6 Water Quality Assessment Action Workplan - Approval, Letter from Perry Sugg, P.G. to Kip McCLary August 14, 2019
Bladen County Closed MSW Landfill December 2021 Groundwater Monitoring Report
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assessment plan to address the water quality in the area of MW-9 and will report findings under
separate cover. The next groundwater monitoring event is scheduled for Spring 2022. Following
receipt of laboratory data a report will be prepared and submitted to NCDEQ and Bladen County.
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1 [dil;l p
December 2021 Groundwater Monitoring Report
Bladen County Closed MSW Landfill
NC Solid Waste Permit No. o9-ol

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_ 1. WELL LOCATIONS FROM FIELD SURVEY DATED 10/27/08 BY WALKER o c�
\ \_/ \ \ SURVEYING COMPANY, ELIZABETHTOWN, NC. o
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`N ���\ \ ' I i �/J ON LIDAR DATA DATED MARCH 2O05. °O a
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© 2022 Smith/Gardner, Inc.

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DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
December2021 Groundwater Monitoring Report
Bladen County Closed MSW Landfill
Solid Waste Permit No. 09-01

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SMITH#GARQ'NER
:.•- to : •
By: DJP
Date: 6/ 23/ 2022
Ground
TOCDepth
Well
Well
Total Well
to
Screen
Surface
Elevation
Groundwater
Screen
Well
Installation
Latitude
Longitude
Diameter
Depth
Water
Interval (feet
Elevation
(feet
Elevation (feet)
Geology
Date
(inches)
(feet bgs)
(feet)
bgs)
(feet amsl)
amsl)
M W-1
NA
34.60291
78.61027
2.0
41.12
124.52
124.98
16.7
108.28
31- 41
NA
M W- 3
NA
34.60541
78.60985
2.0
21.52
97.00
98.57
9.83
88.74
11.5- 21.5
NA
MW-4
NA
34.60658
78.60856
2.0
44.32
107.34
108.89
35.21
73.68
34.5-44.5
NA
M W- 5A
NA
34.60722
78.60939
2.0
31.74
90.35
92.43
24.42
68.01
22- 32
NA
MW-7
NA
34.60886
78.61308
2.0
15.14
62.06
63.72
1.21
62.51
5 - 15
NA
M W- 8
NA
34.60758
78.61542
2.0
30
77.49
79.05
17.41
61.64
20- 30
NA
MW-9
NA
34.60692
78.61536
2.0
17.58
72.09
74.05
8.82
65.23
7.5-17.5
NA
NOTE:
1. Well locations and elevations provided by Walker Surveying Co., Elizabethtown, NC from field survey conducted on 10/27/08.
2. Total Well Depth and Depth to Water from Environment 1 laboratory report dated 12/22/2021, Client ID# 6072.
3. Screened interval is assumed to be 10 feet. Nowell construction data is currently available.
4. NA -Not Available

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
SMITH#GARQ'NER
By: DJ P
Date: 6/23/2022
Well
Temperature
('Celsius)
Specific Conductivity
(US/cm)
pH
(Standard Units)
Turbidity (NTUs)
MW-1
17
239
5.4
7.05
MW-3
16
25
6.2
82.3
MW-4
16
450
7.1
8.05
MW-5A
16
1543
6.8
7.45
MW-7
14
650
6.7
4.07
M W- 8
18
556
6.4
25.7
MW- 9
17
1810
6.5
4.99
SW-1
10
146
5.9
-
SW- 2
9
266
7.9
SW-3
13
380
7.4
-
NOTE: Data from Environment 1 laboratory report dated 12/22/2021, Client ID# 6072.
Bold indicates turbidity>10 NTUs
Turbidity was not measured at SW locations this event.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
SMITH BRUNER e3 YM
R#atedllvoc(irAittats Ci#eC723'M
eadmQ uIyAB�ll
D�71,M
Monitoring Results
Station Name
Units
NC2L
NC2B
NC2B-P
MW-1
MW-3
MW-4
MW-5A
MW-7
MW-8
MW-9
SW-1
SW-2
SW-3
Sample Date
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
12/22/2021
Metals
Arsenic
u /I
10
150
NE
2.7J
0.12J
1.11
0.18J
0.64J
1.8J
Barium
u / I
700
NE
21000
172
43.4
79.7
193
32.4
66.8
86.1
23.7
42.4
54
Cadmium
u /I
2
8.8
NE
1 0.15J
1 0.06J
1 0.16J
0.38J
1 0.08J
1
1 0.18J
0.1 J
Chromium
u /I
10
NE
NE
0.21 J
0.28J
0.44J
0.12J
0.2J
0.36J
0.44J
0.46J
1.4J
11
Lead
u/ I
1 15
1 25
1 NE
1 1.4 J
1
1 0.24 J
1
1 0.05 J
1 0.08 J
1
1 0.3 J
1 3.3 J
1 0.26 J
Selenium
u /I
1 20
1 5
1 NE
1 3.7J
I
1 0.11
1
1
1 0.11 J
1 0.05J
1
1 0.25J
1 2.1 J
NOTES:
ug/L = micrograms per liter
BOLD = Constituent exceeds NCACO2L or GVVP regulatory I imits
BaD = Constituent exceeds NCACO2B or 2B Protection regulatory limits
J = Lab estimated concentration
BDL = constituent is below laboratory detection limits

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
SMITH#GARQ'NER
Monitoring Results
"6" 1 - m
M15M
Station Name
Units
NC2L
MW-3
MW-5A
MW-9
Sample Date
12/22/2021
12/22/2021
12/22/2021
Other
1,2-cis-Dichloroethylene
ug/I
70
1.81 J
1,2-Dichloroethane
u /I
0.4
0.07 J
1,2-Dichloropropane
u /I
0.6
0.22
1,4-Dioxane
u /I
3
23.2
Acetone
u /I
6000
31.2 J
Benzene
u /I
1
0.83 J
1.23
Chlorobenzene
u /I
50
0.46 J
3.27
Vinyl chloride
u /I
0.03
2.6
NOTES:
ug/L = micrograms per liter
BOLD = Constituent exceeds NCACO2L or GWP regulatory limits
BGL' D = Constituent exceeds NCACO2B or 2B Protection regulatory limits
J = Lab estimated concentration
BDL =constituent is below laboratory detection limits

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
Appendix A
Laboratory Analytical Report
December 2021 Groundwater Monitoring Report
Bladen County Closed MSW Landfill
Solid Waste Permit No. 09-01

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
This page intentionally left blank.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
EfiW'nRffM&W % h(Dr;wP(bT@1gd
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE
GREENVILLE, N.C. 27858
BLADEN COUNTY MSW
MS. JOAN SMYTH
SMITH GARDNER, INC.
14 NORTH BOYLAN AVE.
RALEIGH, NC 27603
MW-1
PARAMETERS
MDL
MRL
PH (field measurement), Units
5.4
Arsenic, ug/1
0.08
5.0
--- U
Barium, ug/1
0.04
10.0
172
Barium, ug/1
0.04
10.0
Cadmium, ug/1
0.04
1.0
0.15 J
Total Chromium, ug/1
0.12
5.0
0.21 J
Total Chromium, ug/1
0.12
5.0
Lead, ug/1
0.03
5.0
1.4 J
Mercury, ug/l
0.05
0.20
--- U
Selenium, ug/1
0.05
10.0
3.7 J
Silver, ug/1
0.22
5.0
--- U
Silver, ug/l
0.22
5.0
Conductivity (at 25c), uMhos/cm
1.0
1.0
239
Temperature, °C
17
Static Water Level, feet
16.70
Well Depth, feet
41.12
Turbidity (Field), NTU
1.0
1.0
7.05
PHONE [phone]
FAX [phone]
ID#: 6072
DATE COLLECTED: 12/22/21
DATE REPORTED : 06/17/22
REVIEWED
BY: �w
MW-3
MW-4
MW-5A
MW-7 Analysis Method
Date Analyst Code
6.2
7.1
6.8
6.7 12/22/21 PJC 4500HB-11
2.7 J
--- U
--- U
0.12 J 12/29/21 NAB EPA200.8
193
01/11/22 NAB EPA200.8
43.4
79.7
32.4 01/06/22 NAB EPA200.8
0.06 J
0.16 J
0.38 J
0.08 J 12/29/21 NAB EPA200.8
0.28 J
0.12 J
01/06/22 NAB EPA200.8
0.44 J
0.20 J 12/29/21 NAB EPA200.8
--- U
0.24 J
--- U
0.05 J 12/29/21 NAB EPA200.8
--- U
--- U
--- U
--- U 01/13/22 MTM 245.1 R3-94
--- U
0.10 J
--- U
--- U 12/29/21 NAB EPA200.8
U
01/11/22 NAB EPA200.8
--- U
--- U
--- U 01/18/22 NAB EPA200.8
25
450
1543
650 12/22/21 PJC 2510E-11
16
16
16
14 12/22/21 PJC 255OB-10
9.83
35.21
24.42
1.21 12/22/21 PJC
21.52
44.32
31.74
15.14 12/22/21 PJC
82.30
8.05
7.45
4.07 12/22/21 PJC 213OB-11
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
EfinhIMEM Flo hopTPOTENd
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE
GREENVILLE, N.C. 27858
BLADEN COUNTY MSW
MS. JOAN SMYTH
SMITH GARDNER, INC.
14 NORTH BOYLAN AVE.
RALEIGH, NC 27603
PARAMETERS
PH (field measurement), Units
Arsenic, ug/l
Barium, ug/l
Cadmium, ug/l
Total Chromium, ug/1
Lead, ug/l
Mercury, ug/l
Selenium, ug/1
Silver, ug/1
Conductivity (at 25c), uMhos/cm
Temperature, °C
Static Water Level, feet
Well Depth, feet
Turbidity (Field), NTU
MW-8
MDL MRL
0.08
0.04
0.04
0.12
0.03
0.05
0.05
0.22
1.0
5.0
10.0
1.0
5.0
5.0
0.20
10.0
5.0
1.0
1.0 1.0
6.4
--- U
66.8
--- U
0.36 J
0.08 J
--- U
0.11 J
--- U
556
18
17.41
30.00
25.70
PHONE [phone]
FAX [phone]
ID#: 6072
DATE COLLECTED: 12/22/21
DATE REPORTED : 06/17/22
REVIEWED BY:
✓/
MW-9
SW-1
SW-2 SW-3
Analysis Method
Date Analyst Code
6.5
5.9
7.9
7.4 12/22/21 PJC 4500HB-11
1.1J
0.18 J
0.64 J
1.8 J 12/29/21 NAB EPA200.8
86.1
23.7
42.4
54.0 01/06/22 NAB EPA200.8
--- U
--- U
0.18 J
0.10 J 12/29/21 NAB EPA200.8
0.44 J
0.46 J
1.4 J
1.0 J 01/06/22 NAB EPA200.8
--- U
0.30 J
3.3 J
0.26 J 12/29/21 NAB EPA200.8
--- U
--- U
--- U
--- U 01/13/22 MTM 245.1 R3-94
0.05 J
--- U
0.25 J
2.1J 12/29/21 NAB EPA200.8
--- U
--- U
--- U
--- U 01/18/22 NAB EPA200.8
1810
146
266
380 12/22/21 PJC 2510E-11
17
10
9
13 12/22/21 PJC 2550B-10
8.82
12/22/21 PJC
17.58
12/22/21 PJC
4.99
12/22/21 PJC 213OB-11
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
�flw'nm(@M Flo k(mTP(MTM%d
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE
GREENVILLE, N.C. 27858
PHONE [phone]
FAX [phone]
CLIENT: BLADEN COUNTY MSW CLIENT ID: 6072
MS. JOAN SMYTH
SMITH GARDNER, INC. ANALYST: JAP
14 NORTH BOYLAN AVE. DATE COLLECTED: 12/22/21 Page: 1
RALEIGH, NC 276 3 DATE ANALYZED: 01/03/22
DATE REPORTED: 06/17/22
REVIEWED BY: \
VOLATILE ORGANICS
F.PA METHOD 8260D R4(18)
PARAMETERS, ug/1
MDL
MRL
MW-1
MW-3
MW-4
MW-5A
KW-7
1.
Chloromethane
0.77
3,000
---
U
---
U
---
U
---
U
---
U
2.
Vinyl Chloride
0.12
0.200
---
U
---
U
---
U
---
U
---
U
3.
Bromomethane
0.67
10.000
---
U
---
U
---
U
---
U
---
U
4.
Chloroethane
0.48
10.000
---
U
---
U
---
U
---
U
---
U
5,
Trichlorofluoromethane
0.24
1,000
---
U
---
U
---
U
---
U
---
U
6.
1,1-Dichloroethene
0.17
5.000
---
U
---
U
---
U
---
U
---
U
7.
Acetone
9.06
100.000
---
U
---
U
---
U
31.20
J
---
U
B.
iodomethane
0.26
10.000
---
U
---
U
---
U
---
U
---
U
9.
Carbon Disulfide
0.23
100.000
---
U
---
U
---
U
---
U
---
U
10.
Methylene Chloride
0.64
1.000
---
U
---
U
---
U
---
U
---
U
11.
trans-1,2-Dichloroethene
0.23
5.000
---
U
---
U
---
U
---
U
---
U
12.
1,1-Dichloroethane
0.20
5.000
---
U
---
U
---
U
---
U
---
U
13.
Vinyl Acetate
0.20
50.000
---
U
---
U
---
U
---
U
---
U
14.
Cis-1,2-Dichloroethene
0.25
5.000
---
U
---
U
---
U
---
U
---
U
15.
2-Butanone
2.21
100.000
---
U
---
U
---
U
---
U
---
U
16.
Bromochloromethane
0.27
3.000
---
U
---
U
---
U
---
U
---
U
17.
Chloroform
0.25
5.000
---
U
---
U
---
U
---
U
---
U
18.
1,1,1-Trichloroethane
0.19
1.000
---
U
---
U
---
U
---
U
---
U
19.
Carbon Tetrachloride
0.04
0,200
---
U
---
U
---
U
---
U
---
U
20.
Benzene
0.24
1.000
---
U
0.83
J
---
U
---
U
---
U
21.
1,2-Dichloroethane
0.02
0.200
---
U
---
U
---
U
---
U
---
U
22.
Trichloroethene
0.23
1.000
---
U
---
U
---
U
---
U
-'-
U
23.
1,2-Dichloropropane
0.04
0.200
---
U
---
U
---
U
---
U
---
U
24.
Bromodichloromethane
0.04
0.200
---
U
---
U
---
U
---
U
U
25.
Cie-1,3-Dichloropropene
0.06
0.200
---
U
---
U
---
U
---
U
---
U
26.
4-Methyl-2-Pentanone
1.19
100.000
---
U
---
U
---
U
---
U
---
U
27.
Toluene
0.23
1.000
---
U
---
U
---
U
---
U
---
U
28.
trans-1,3-Dichloropropene
0.04
0.200
---
U
---
U
---
U
---
U
---
U
29.
1,1,2-Trichloroethane
0.03
0.200
---
U
---
U
---
U
---
U
---
U
30,
Tetrachloroethene
0.10
0.200
---
U
---
U
---
U
---
U
---
U
31.
2-Hexanone
1.57
40.000
---
U
---
U
---
U
---
U
U
32.
Dibromochloromethane
0.03
0.200
---
U
---
U
---
U
---
U
---
U
33.
1,2-Dibromoethane
0.03
0.200
---
U
---
U
---
U
---
U
---
U
34,
Chlorobenzene
0.30
3.000
---
U
0.46
J
---
U
---
U
---
U
35.
1,1,1,2-Tetrachloroethane
0.22
1.000
---
U
---
U
---
U
---
U
---
Ti
36.
Ethylbenzene
0.21
1.000
---
U
---
U
---
U
---
U
---
U
37.
Xylenes
0.68
5.000
---
U
---
U
---
U
---
U
---
U
38.
Dibromomethane
0.28
10.000
---
U
---
U
---
U
---
U
---
U
39.
Styrene
0.19
1.000
---
U
---
U
---
U
---
U
---
U
40.
Bromoform
0.20
3.000
---
U
---
U
---
U
---
U
---
U
41.
1,1,2,2-Tetrachloroethane
0.03
0.200
---
U
---
U
---
U
---
U
---
U
42.
1,2,3-Trichloropropane
0.09
0.200
---
U
---
U
---
U
---
U
---
U
43.
1,4-Dichlorobenzene
0.39
1.000
---
U
---
U
---
U
---
U
-
U
44.
1,2-Dichlorobenzene
0.32
5.000
---
U
---
U
---
U
---
U
---
U
45.
1,2-Dibromo-3-Chloropropane
0.07
0.200
---
U
---
U
---
U
---
U
---
U
46.
Acrylonitrile
2.72
200.000
---
U
---
U
---
U
---
U
-
U
47.
trans-1,4-Dichloro-2-Butene
0.42
100.000
---
U
---
U
---
U
---
U
---
U
48.
1,4-Dioxane
2.71
3.000
---
U
---
U
---
U
---
U
-
U
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
IEmdo•rghm.-�� �p kompnOW
ow
114 OAKMONT DRIVE
GREENVILLE, N.C. 27858
Drinking Water ID: 37715
Wastewater ID: 10
PHONE [phone]
FAX [phone]
CLIENT: BLADEN COUNTY MSW CLIENT ID: 6072
MS. JOAN SMYTH
SMITH GARDNER, INC. ANALYST: JAP
14 NORTH BOYLAN AVE. DATE COLLECTED: 12/22/21 Page: 2
RALEIGH, NC 27603 DATE ANALYZED: 01/03/22
DATE REPORTED: 06/17/22
REVIEWED BY:
VOLATILE ORGANICS
wnn 7Aym=nrN R79nn R4 (1 R)
PARAMETERS, Ug/l
MDL
MRL
MW-8
MW-9
SW-1
SW-2
SW-3
1.
Chloromethane
0.77
3.000
---
U
---
U
---
U
-
U
-
U
2.
Vinyl Chloride
0.12
0.200
---
U
2.60
---
U
---
U
---
U
3.
Bromomethane
0.67
10.000
---
U
---
U
---
U
---
U
---
U
4.
Chloroethane
0.48
10,000
---
U
---
U
---
U
-
U
-
U
5.
Trichlorofluoromethane
0.24
1.000
---
U
---
U
---
U
-
U
-
U
6.
1,1-Dichloroethene
0.17
5.000
---
U
---
U
---
U
---
U
---
U
7.
Acetone
9.06
100.000
---
U
---
U
---
U
---
U
---
U
8.
Iodomethane
0.26
10.000
---
U
---
U
"--
U
-
U
-
U
9.
Carbon Disulfide
0.23
100.000
---
U
---
U
---
U
---
U
---
U
10.
Methylene Chloride
0.64
1.000
---
U
---
U
---
U
U
U
11,
trans-1,2-Dichloroethene
0.23
5.000
---
U
---
U
---
U
---
U
---
U
12.
1,1-Dichloroethane
0.20
5.000
---
U
---
U
---
U
-
U
-
U
13.
Vinyl Acetate
0.20
50.000
---
U
---
U
---
U
---
U
---
U
14.
Cis-1,2-Dichloroethene
0.25
5.000
---
U
1.81
J
---
U
" '
U
"--
U
15.
2-Butanone
2.-21
100.000
---
U
---
U
---
U
-
U
U
U
16,
Bromochloromethane
0.27
3.000
---
U
---
U
---
U
-
U
-
17.
Chloroform
0.25
5.000
---
U
---
U
---
U
-
U
-
U
18,
1,1,1-Trichloroethane
0.19
1.000
---
U
---
U
"--
U
-
U
-
U
19.
Carbon Tetrachloride
0.04
0.200
---
U
---
U
--"
U
-
U
-
U
0.24
1.000
---
U
1.23
---
U
---
U
---
U
20.
Benzene
---
U
---
U
---
U
21.
1,2-Dichloroethane
0.02
0.200
---
U
0.07
J
22,
Trichloroethene
0.23
1.000
---
U
---
U
---
U
-
U
-
U
23.
1,2-Dichloropropane
0.04
0.200
---
U
0.22
---
U
--'
U
-"-
U
24,
Bromodichloromethane
0.04
0.200
---
U
---
U
---
U
---
U
U
25.
Cie-1,3-Dichloropropene
0.06
0.200
---
U
---
U
---
U
- -
U
-
U
26.
4-Methyl-2-Pentanone
1.19
100.000
---
U
---
U
---
U
-
U
U
27.
Toluene
0.23
1.000
---
U
---
U
-"-
U
---
U
---
U
28.
trans-1,3-Dichloropropene
0.04
0.200
---
U
---
U
---
U
---
U
---
U
29.
1,1,2-Trichloroethane
0.03
0.200
---
U
---
U
---
U
-
U
-
U
30.
Tetrachloroethene
0.10
0.200
---
U
---
U
---
U
-
U
U
31.
2-Hexanone
1.57
40.000
---
U
---
U
---
U
-
U
U
32.
Dibromochloromethane
0.03
0.200
---
U
---
U
---
U
-
U
-
U
33,
1,2-Dibromoethane
0.03
0.200
---
U
---
U
---
U
-
U
U
34.
Chlorobenzene
0.30
3.000
---
U
3.27
---
U
---
U
---
U
35.
1,1,1,2-Tetrachloroethane
0.22
1.000
---
U
---
U
---
U
---
U
__ -
U
36.
Ethylbenzene
0.21
1.000
---
U
---
U
---
U
-
U
-
U
37.
xylenes
0.68
5.000
---
U
---
U
---
U
-
U
U
38.
Dibromomethane
0.28
10.000
---
U
---
U
---
U
-
U
U
39.
Styrene
0.19
1.000
---
U
---
U
---
U
---
U
-
U
U
40,
Bromoform
0.20
3.000
---
U
---
U
---
U
- -
U
41.
1,1,2,2-Tetrachloroethane
0.03
0.200
---
U
---
U
---
U
-
U
U
42.
1,2,3-Trichloropropane
0.09
0.200
---
U
---
U
---
U
---
U
---
U
43,
1,4-Dichlorobenzene
0.39
1.000
---
U
---
U
---
U
-
U
-
U
44.
1,2-Dichlorobenzene
0.32
5.000
---
U
---
U
---
U
- -
U
-
U
45.
1,2-Dibromo-3-Chloropropane
0.07
0.200
--- U
---
U
---
U
U
U
46.
Acrylonitrile
2.72
200.000
---
U
---
U
---
U
-
U
U
47,
trans-1,4-Dichloro-2-Butene
0.42
100.000
--- U
---
U
---
U
-
U
U
48.
1,4-Dioxane
2.71
3.000
--- U
23.20
---
U
-"-
U
--- U
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
Drinking Water ID: 37715
Wastewater ID: 10
114 OAKMONT DRIVE
GREENVILLE, N.C. 27858
PHONE [phone]
FAX [phone]
CLIENT: BLADEN COUNTY MSW CLIENT ID: 6072
MS. JOAN SMYTH
SMITH GARDNER, INC. ANALYST: JAP
14 NORTH BOYLAN AVE. DATE COLLECTED: 12/22/21 Page: 3
RALEIGH, NC 27603 DATE ANALYZED: 01/03/22
REVIEWED BY: DATE REPORTED: 06/17/22
/( /�
VOLATILE ORGANICS
EPA METHOD 8260D R4(18)
PARAMETERS, ug/l
MDL
:MRTLBlank
Trip
1.
Chloromethane
0.77
3.000
---
U
2.
Vinyl Chloride
0.12
0.200
---
U
3.
Bromomethane
0.67
10.000
---
U
4.
Chloroethane
0.48
10,000
---
U
5,
Trichlorofluoromethane
0.24
1.000
---
U
6.
1,1-Dichloroethene
0.17
5.000
---
U
7.
Acetone
9.06
100.000
---
U
8.
Iodomethane
0.26
10.000
---
U
9.
Carbon Disulfide
0.23
100.000
---
U
10.
Methylene Chloride
0.64
1.000
---
U
11,
trans-1,2-Dichloroethene
0.23
5.000
---
U
12.
1,1-Dichloroethane
0.20
5.000
---
U
13.
Vinyl Acetate
0.20
50.000
---
U
14.
Cis-1,2-Dichloroethene
0.25
5.000
---
U
15.
2-Butanone
2.21
100.000
---
U
16.
Bromochloromethane
0.27
3.000
---
U
17.
Chloroform
0.25
5.000
---
U
18.
1,1,1-Trichloroethane
0.19
1.000
---
U
19.
Carbon Tetrachloride
0.04
0.200
---
U
20.
Benzene
0.24
1.000
---
U
21.
1,2-Dichloroethane
0.02
0.200
---
U
22.
Trichloroethene
0.23
1.000
---
U
23.
1,2-Dichloropropane
0.04
0.200
---
U
24.
Bromodichloromethane
0.04
0.200
---
U
25.
Cis-1,3-Dichloropropene
0.06
0.200
---
U
26.
4-Methyl-2-Pentanone
1.19
100.000
---
U
27,
Toluene
0.23
1,000
---
U
28.
trans-1,3-Dichloropropene
0.04
0,200
---
U
29.
1,1,2-Trichloroethane
0.03
0.200
---
U
30,
Tetrachloroethene
0.10
0.200
---
U
31.
2-Hexanone
1.57
40.000
---
U
32.
Dibromochloromethane
0.03
0.200
---
U
33.
1,2-Dibromoethane
0.03
0.200
---
U
34,
Chlorobenzene
0.30
3.000
---
U
35.
1,1,1,2-Tetrachloroethane
0.22
1.000
---
U
36.
Ethylbenzene
0.21
1,000
---
U
37.
Xylenes
0.68
5.000
---
U
38.
Dibromomethane
0.28
10.000
---
U
39.
Styrene
0.19
1.000
---
U
40.
Bromoform
0.20
3.000
---
U
41,
1,1,2,2-Tetrachloroethane
0.03
0.200
--- U
42,
1,2,3-Trichloropropane
0.09
0.200
--- U
43.
1,4-Dichlorobenzene
0.39
1.000
--- U
44.
1,2-Dichlorobenzene
0.32
5.000
--- U
45.
1,2-Dibromo-3-Chloropropane
0.07
0.200
--- U
46.
Acrylonitrile
2,72
200.000
--- U
47.
trans-1,4-Dichloro-2-Butene
0.42
100.000
---
U
48.
1,4-Dioxane
2.71
3.000
--- U
J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits.

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DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
Appendix
Time Versus Concentration Graphs
December 2021 Groundwater Monitoring Report
Bladen County Closed MSW Landfill
Solid Waste Permit No. 09-01

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
This page intentionally left blank.

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
1,4-Dioxane
25
20
15
c
0
m
c
a
10
0
u
0 r
oti oti oti oti oti oti oti oti oti oti otio oti oti° oti° oti° oti° oti° oti° oti° oti° oti° oti° oti° oti° otiti otiti otiti otiti otiti otiti otiti otiti otiti otiti otiti otiti
ti�y\L ti�y\L 3�ti\L b\y�L h�y\L 0\y�L ^\y�L b\y�L �,�y\Lti°�y\Ltiti�y\Ltiti�y\L ti�y\L ti�y\L 3�ti\L b�y\L h�y\L 0�y\L ��y\L b�y\L Ci\,y\Lti°�y\Ltiti�y\Ltiti�y\L ti�y\L ti�Y\L 3�y\L b�y\L h�y\L rO�y\L 1�y\L ��ti\L cr\Lti°�y\Ltiti�y\Ltiti�y\L
Date
MW-9
2L Standard

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
1
m
c 0.8
0
m
b 0.6
c
v
u
0 0.4
v
0.2
0
Benzene
in in Ln Ln Ln �D w w �o �o �D r` r` r` r` n r` oo oo oo oo oo oo m m m m m m o 0 0 0 0 0
0 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0
O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O
N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N N
In Ln n (3) m if r, m m Il r, m m if r, m n Il n D\1 1-4 1-4 m 11 n a) 1-4 1-4 ro 11 n m c\
N ci c-i c-i ti ti ci
Date
-MW-3 -MW-9-2LStandard

DocuSign Envelope ID: 840782D7-6C41-42F6-8638-F974169C2064
Vinyl Chloride
4.5
3.5
ego
3
0
% 2.5
0.5
0 T
OHO OHO OHO OHO O�y O�y O�y O�y "P 6� ,
�\ti�ti �\ti�ti�\ti�ti �\ti�ti y\ti�ti y\ti�ti �\ti�ti �\ti�ti�\ti�ti �\ti�ti y\ti�ti y\ti�ti �\ti�ti �\ti�ti�\ti�ti �\ti�ti y\ti�ti y\ti�ti �\ti�ti �\ti�ti �\ti�ti �\ti�ti y\ti�ti y\ti�ti �\ti�ti �\ti�ti �\ti�ti �\ti�ti y\ti�ti y\ti�ti �\ti�ti �\ti�ti \ti �\ti\ti ti y\\T y\ti\T xv \T \T \T y\ti\Y
Date
BMW-4 BMW-9 -2LStandard