0501_AsheCoMSWclosed_June2022_FID1740669_20221004

i pENR USE ONLY. ElPa_er Report ❑Electronic Data - Email CD (data loaded: Yes /_NNo Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1, As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly -
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information _
Name of entity submitting data (laboratory, consultant, facility owner):
Municipal Engineering Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Jonathan Pfohl
E-mail: [e-mail]
Phone: [phone]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24. 2006)
Ashe County Closed Unlined 739 Fred Pugh Road 05-01 .0500 June 14-16, 2022
Landfill Crumpler, NC 28617
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring OX Detection Monitoring QX Assessment Monitoring �]X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells Methane gas monitoring data
Groundwater monitoring data from private water supply wells Corrective action data (specify) App I for MW-27, P3-1, P-12
Leachate monitoring data ❑
Surface water monitoring data Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NO Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
= A direct comparison to NC 2B Standards cannot be made since inadequate number of samples and/or dissolved form not reported.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
S.J. Zimmerman, P.G. Project Manager [phone]
Name (Print) Title
/o
P.O. Box 97, Garner, NC 27529
Facility Representative Address
NC PR Firm # F-0812 NC PG Firm # C-586
Date
(Area Code) Telephpne.Rumber;; .,
,9*,I' l �icfrnsedT..Professional Geologist Seal
ti•t� ,.1. `t o`a, f-
%
�} , ).,
cJf
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

June 2022
Prepared for
A.she County Closed. Unlined Landfill
Crumpler, North Carolina
Permit No. 05-01
Prepared by
Municipal Engineering, Inc.
P.O. BOX 97
Garner, North Carolina
MESCO Project Number: G22007.0
S. J. Zimmerman, P.G.
Senior Project Manager.
izimmermankmesco.corn- °
4.
�4l GJ6i�+.P ?:96nt
Jonathan Kohl
Environmental Specialist
fits ohlna mesco.com
MUNICIPAL ENGINEERING, INC.
r'®� Ui 68 5HIPWA5H DRIVE, GARNER, NC 27529 - PHONE: [phone]
% P.O. Sox 349, BOONE, NC 28607 - PHONE: [phone]
C�/V IE E� LICENSE NUMBERS: F-081 2 & C-586

Introduction
On behalf of Ashe County, Municipal Engineering, Inc. (MESCO) is pleased to present this Semi -Annual Water
Quality Monitoring Report for an event performed at the Ashe County Closed Unlined Landfill (SWS Permit No.
05-01) on June 14-16, 2022. The site is located at 739 Fred Pugh Road Crumpler, Ashe County, North Carolina.
The site location topographic map is depicted as Figure 1.
NCDEQ Solid Waste Rules 15ANCAC13B.0600 require that Ashe County provide this monitoring report to the
SWS on a semi-annual basis. In general accordance with 15A NCAC 13B .0601, the SWS Environmental
Monitoring Report Form and SWS memorandums, this report contains background information, sampling
locations, sampling procedures, field and laboratory results, ground and surface water characterization and
findings. Detection tables, a potentiometric map, field parameters and the laboratory analytical reports with
quality assurance/quality control data and chains -of -custody (COC) are also included.
During this event, between one and six volatile organic compounds (VOCs) were detected in concentrations
above the North Carolina groundwater (2L) Standard in samples collected from the areas north (MW-14), east (P-
1, P3-1, MW-27), south-central (MW-21), south-west (MW-6, MW-16, MW-17) and west (MW-4, MW-26D) of
the closed landfill. The origin of the VOCs is suspected to be anthropogenic. Between one and three metals were
also detected above compliance levels in samples collected from 11 wells during this event. Elevated levels of
cobalt continue to persist in samples collected from surface water point SW-2 and SW-2A.
Background
The site operated as an approximate 16-acre unlined sanitary landfill which stopped receiving waste prior to
January 1, 1995 in accordance with the Ashe County Transition Plan. A lined landfill also operates at the site
which is monitored concurrently but reported separately. The water quality monitoring program includes
sampling locations listed in the Water Quality Monitoring Plan (WQMP) dated December 8, 2020 and revised on
February 2, 2022. NC SWS previously approved a reduced frequency and locations for targeting 1,4-dioxane on
May 19, 2020 (FID:1406391). Active remediation of the groundwater east of the landfill was initiated in March
2008 through injection of hydrogen releasing compounds (HRC) into P3-15. In November 2008 an additional 11
wells (P-13S, P3-14, P3-16, P3-17, HRCM-17, HRCI-1, HRCI-2 HRCI-3, HRCI-7, HRCI-12 and HRCM-17)
were injected. Water quality monitoring has been performed semi-annually and recent data compared to all
known historical data compiled since 1992. Water quality at the landfill is being assessed and a report of the
findings has recently been submitted to NC SWS.
Sampling Locations
The water quality monitoring network includes 17 sentinel groundwater monitoring wells (MW-3, MW-4, MW-5,
MW-6, MW-8, MW-14, MW-16, MW-17, MW-20, MW-21, MW-23, MW-26, MW-26D, MW-27, P-1, P3-1 and
P-12), three upgradient background monitoring wells (MW-A, MW-18, MW-19) and four surface water locations
(SW-2, SW-2A, SW-4 and SW-5). Surface water points SW-B and SW-3 are assigned as part of the lined landfill
monitoring network but also represent water quality downstream of the closed landfill. Quality control measures
implemented during this event included analysis of an equipment blank (EB) and field blank (FB). A summary
detailing the construction of the water monitoring wells is presented in Table 1. Water monitoring locations are
depicted in Figure 2.
Semi -Annual Water Quality Monitoring Report -June 2022
Ashe County Closed Unlined Landfill Page 1

Sampling and Laboratory Procedures
MESCO personnel performed the sample collection using methodology outlined in the NCDENR SWS guidance
document Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April
2008. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2.
The depth to water in each well was electronically gaged prior to purging to quantify the static water level
elevation. Bailing or electric submersible pumping was utilized to purge the wells a minimum of three times the
volume of standing water in the well or until dry. Surface water samples were dipped from the surface of the un-
named tributaries of the North Fork of the New River at previously designated locations. Stabilized field
parameters were recorded during purging or directly from the surface water body. Samples were then placed into
laboratory -prepared, pre -preserved containers. Samples were kept on ice and transported to a NC -certified
laboratory under proper chain of custody (C-O-C) protocol within the specified hold times for each analysis.
Field Parameter Data
Stabilized field parameters were recorded and included pH, specific conductance, temperature, hardness and
turbidity. A summary of the field parameter data is presented in Table 3 and field data sheets are in Appendix A.
In general field parameter results remain consistent with previous events.
Laboratory Results
Pace Analytical Laboratories (PACE) (NC Cert. #12 & 40) performed the laboratory analysis. Pace reported their
procedures conformed to the most current, applicable TNI/NELAC standards and their Quality Assurance
Manual, where applicable; unless otherwise noted in the laboratory report.
All water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4-dioxane and MW-14 was
tested for constituents listed in 40 CFR 258 Appendix II. No sample could be obtained from MW-3 as it was
dry at the time of sampling. The lab failed to report results of samples collected from PZ-3 and
Appendix II metals from MW-14. A sampling and analysis table summarizing the locations, targeted
constituents and methods is presented in Table 4. Laboratory results and C-O-Cs are presented in Appendix B.
Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value
between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as with a "J"
which indicates an estimated concentration. "J-qualified" concentrations are considered non -quantifiable and
discretion should be made prior to making decisions based on a value that the laboratory considers an estimate.
Table 5 summarizes constituents detected in groundwater and QC samples compared to Interim Maximum
Allowable Concentrations (IMAC) values and North Carolina Groundwater Standards (2L) which are recognized
by the NC SWS as groundwater compliance Standards. Although not applicable for regulatory compliance
purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as
the Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared
with the NC Division of Water Resources "Surface Water Quality Standards, Criteria & Protected Values",
modified July 26, 2021.
Table 7 contains anaylte and turbidity values of background samples compared to Standards which may be used
in support of an ASD for metals.
Semi -Annual Water Quality Monitoring Report -June 2022
Ashe County Closed Unlined Landfill Page 2

Quality Control Samples
Acetone and methylene chloride were detected in the EB and FB; however, both were "J" qualified. These
constituents are common laboratory contaminants, and their presence, although qualified, may suggest induced
artifact contamination.
Groundwater Samples Above Standards
Metals
One to three total recoverable forms of metals were detected above their respective RL and NC 2L Standard in
samples collected from 11 wells as summarized below.
Metals Detected in Groundwater Samples Above RL and NC 2L Standard
Barium
Cadmium
Cobalt
Chromium
Vanadium
2L/IMAC
700
2
1
10
7
MW-4
15.8
MW-5
2.3
MW-6
2020
25.4
MW-16
1350
16.1
MW-17
1200
14.1
MW-20
8
MW-21
2090
55.8
20.4
MW-26D
896
2.7
13.5
MW-27
31.4
P-1
1500
31.9
P3-1
5.8
10.9
Concentrations in ug/L
Organics
One to six VOCs and 1,4-doxane were detected above the RL and NC 2L Standard in samples collected from 9
wells as summarized below.
Organics Detected in Groundwater Samples Above RL and NC 2L Standard
1,1-
DCA
1,2-
DCP
1,4-
DCB
Benzene
Methylene
Chloride
PCE
TCE
Vinyl
Chloride
1,4-
Dioxane
2L STD
6
0.6
6
1
5
0.7
3
0.03
3
MW-4
1.1
MW-6
4.9
81.9
MW-14
1.1
MW-16
2
17.1
MW-17
2
17.5
MW-21
1.4
MW-26D
2.5
4.2
MW-27
3.4
3.7
P-1
4.1
8.1
1.4
3
P3-1
49.4
5
1 12.1
1.3
3.5
8.9
Concentrations in ug/L
Semi -Annual Water Quality Monitoring Report -June 2022
Ashe County Closed Unlined Landfill Page 3

Surface Water Samples Above Standards
Grab samples were collected from six locations, two of which contained cobalt above an assigned 2B Standard.
A grab sample collected from SW-2 contained total cobalt at 20.9 ug/L which is above its NC ISTV values (1.6
ug/L chronic, 16 ug/L acute or 4 ug/L for fish consumption). Grab sample SW-2A, collected 935 feet
downstream of SW-2, also contained total cobalt at 6.5 ug/L which is greater than the ISTV value for chronic
toxicity and fish consumption referenced above. However, since analysis was performed on a single grab sample
for total recoverable cobalt rather than an average of multiple samples from the dissolved fraction, a direct
comparison to the NC ISTV is not possible hence inappropriate for determining compliance.
Groundwater and Surface Water Characterization
A potentiometric map of the uppermost aquifer from an extensive group of ground water elevations obtained
during this event is shown as Figure 2. Groundwater flow rates and directions were also calculated based upon
this data and is included on Table 8. A portion of the unlined landfill is situated upon a ridgetop which serves as
a recharge feature with groundwater flowing in a radial pattern in all directions. Uppermost groundwater flow
paths originating from the landfill appears to be the unnamed tributaries of the New River which are located
primarily within the property boundaries. Estimated linear groundwater flow velocity rates calculated from data
collected during this and previous events using modified Darcy's equation ranged from approximately 19 ft/yr
(MW-20) to 1,293 ft/yr (MW-5) with a site -wide average of approximately 335 ft/yr. The flow directions and
rates are generally consistent with historical observations.
Findings
Some of the inorganic detections may be a product of erosion of natural deposits rather than evidence of a landfill
release with substantiating information contained in an Alternative Source Demonstration (ASD)-Total Metals
drafted by MESCO dated July 26, 2017. As described in an ASD-Addendum Workplan/Timeline-Metals
(DIN:1285838) dated February 2, 2019 and approved by the NC SWS on March 5, 2019 (DIN:1285839) total
recoverable metals and associated turbidity levels collected from background wells and/or soil samples collected
during this, past and future events may be presented in an ASD-Addendum. However, since metal violations in
groundwater samples have predominately been limited to locations with VOCs, and concentrations of metals in
the background wells are insufficient, pursuing an ASD appears to be of limited value at this time.
The latest semi-annual laboratory results indicate that one or more metals and VOCs continue to persist in
concentrations above compliance standards in groundwater samples collected from all four compass directions of
the landfill. Water quality samples continue to detect the presence of cobalt in surface water sample locations
SW-2 and SW-2A, and groundwater samples from nearby wells MW-4 and MW-26D. Groundwater near P-1,
located near a segment of the eastern property line which serves as the compliance boundary, appears to be
impaired. Groundwater impacts east of the landfill, in the proposed future lined Phase 3 area, appear to remain
isolated to an approximate 1.7-acre area which is the same size and shape as delineated in previous years
suggesting the plume has stabilized. Recently completed statistical analysis and groundwater contaminant
transport modeling further supports the concept that the plume has stabilized, which was presented in a separate
report summarizing water quality conditions at the site. Test results indicate that VOCs have likely not advanced
vertically or horizontally beyond the valley floor which is 230 feet within the closest portion of the hydraulically
cross -gradient compliance boundary.
Approximately 1,100 feet of the northwest flowing unnamed tributary west of the closed landfill contained
elevated levels of total cobalt. Cobalt was not detected in samples collected from three locations further
downstream.
Semi -Annual Water Quality Monitoring Report -June 2022
Ashe County Closed Unlined Landfill Page 4

Closing
Water quality monitoring is planned to continue in the fall of 2022 per the current WQMP supplemented with
continued monitoring of PZ-3. During the next event MW-14 will be tested for Appendix II metals to compensate
for lack of analysis during this event. If you have any questions or comments regarding this report, please contact
us via phone or by email.
Semi -Annual Water Quality Monitoring Report -June 2022
Ashe County Closed Unlined Landfill Page 5

Figures

Topographic Map with Site Location
Ashe County Closed Unlined Landfill
Ashe County Active Lined Landfill
I�
ROAD CLASSIFICATION
739 Fred Pugh Road Primary highway, UgWAUty road, hard or
g hard surface improsrd surface
Crumpler, NC 28617 Secondary highway.
Lat:36-31-06.1639 hard S-Iace unimproved road ........
Long•-81-21-59.3447 0 Inlentale Rnule ❑ U. S. Rnale Cl Slate Rowde
Northing:1015914.08
Easting:1304557.23
NOTE. Topographic map assembled from the
Jefferson NC, Laurel Springs NC, Grassy Creek NC -VA, and Mouth of Wilson NC -VA USGS 7.5-min. quadrangles.
FIGURE I

COMPLIANCE BOUNDARY
LAGOON
MW-1
G WE=2633.33
SW-
,� s zsza
♦ �5ti zsgo
sw .. SW-3
WSW-2
J
J
looft
J 0
L z
o a �-
z J I► z
J � �
W OW
� J a
z W
ui W a V
J �
J
Ci
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pm
W uu
U
U)�
ui
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w
w
w �
}
uu
m
J
z
w
U)
a
0
SCALE: SEE BARSCALE
DATE: 1013122
DRWN. BY: J.PFOHL
CHKD. BY: J.ZIMMERMAN
PROJECT NUMBER
G22004.0
FIGURE
DRAWING NO. I SHEET NO.
FIGURE 2

Figure 3
Time Series Graphs of VOCs Detected in MW-2
MW-2 Benzene & Vinyl Chloride
6 r--
5 ■
3 3
A
Pr
1
.. +• AL
' �
a•
• 0 •r• Vinyl Chloride
5/1/13 5/1/14 5/1/15 5/1/16 5/1/17 5/1/18 5/1/19 5/1/20 5/1/21 5/1/22
• • ■ • Vinyl Chloride • • ■ • Benzene
Prior to 5/23/13 all non -detects (ND). All ND since represented as 0.
Ashe County Lined Landfill Page 1 of 1

Tables

Table 1
Groundwater Monitoring Well Construction Table
June 14-16, 2022
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen Geology of
Length Screened
Interval
(ft)
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
Latitude
Longitude
(inches)
(ft bgs)
(ft bgs)
(ft amsi)
(ft amsl)
(ft amsl)
(ft btoc)
MW-1
08/06/91
2
58
43
15
saprolite/rock
2682.11
2680.60
2633.33
48.78
36.523439
81.370683
MW-2
08/03/91
2
25
10
15
weathered rock
2696.80
2695.70
2677.35
19.45
36.520603
81.371078
MW-13
11/30/92
2
13
3
10
saprolite/rock
2604.79
2601.69
2596.60
8.19
36.524592
81.370633
MW-15
12/03/92
2
13
3
10
saprolite/rock
2653.45
2651.23
2645.96
7.49
36.522197
81.371561
MW-28
06/03/09
2
17.12
6.12
11
bedrock
2634.18
2630.52
2625.85
8.33
36.523722
81.370061
MW-29
06/19/04
2
74.6
59.6
15
weathered rock
2716.27
2713.27
2668.18
48.09
36.522263
81.367729
MW-30
11/03/10
2
28
18
10
saprolite
2715.98
2712.93
2695.80
20.18
36.522331
81.367681
MW-A
11/30/00
1 2
76
61
15
bedrock
2827.58
2824.57
---- -5
56.63
36.519225
81.366144
NOTE:
bgs = below ground surface
amsl= above mean sea level
btoc = below top of casing (PVC well casing)
Ashe County Lined Landfill Page 1 of 1

Table 2
Field Observations of Monitoring Locations
June 14-16, 2022
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Locked
Hinge/Hasp
Operational
Tagged or
Labeled
Concrete
Surface Pad
Effective
Comments
MW-1
Yes
Yes
Yes
Yes
Yes
Yes
MW-2
Yes
Yes
Yes
Yes
Yes
Yes
Monitors both lined & closed unlined landfill. Ant larva in well.
MW-13
Yes
Yes
Yes
Yes
Yes
Yes
MW-15
Yes
Yes
Yes
Yes
Yes
Yes
Pad cracked
MW-A
Yes
Yes
Yes
Yes
Yes
Yes
MW-28
Yes
Yes
Yes
Yes
Yes
Yes
MW-29
Yes
Yes
Yes
Yes
Yes
Yes
MW-30
Yes
Yes
Yes
Yes
Yes
Yes
Protective case installed by county in 5/2014
WSW-2
Yes
Premier sample collected from well head. Valve was very corrodated.
SW-3
Yes
Low seasonal gage & flow
SWA
Yes
Low seasonal gage & flow
SW-B
Yes
Low seasonal gage & flow
UDP
Yes
Sample from culvert outlet as usual.
LAGOON
Yes
Approximate equal composite of leachate from both inverts Ph 1 Ph2/4 . Slow dischar e
Any unusual field conditions, observations, or events:
Working face within Phase 4 with waste encompassing the entire footprint
Ashe County Lined Landfill Page 1 of 1

Table 3
Field Parameter Data Summary
June 14-16, 2022
Parameter
Units
Depth to
Water
ft (btoc)
Water
Elevation
ft (amsl)
TOC
Elevation
ft (amsl)
Temp.
C
pH
SU
Specific
Conductance
umhos/cm
Hardness
mg/L
Turbidity of
Metal Sample
NTU
MW-1
48.78
2633.33
2682.11
13.8
5.84
78
NR
13.1
MW-2
19.45
2677.35
2696.80
12.5
5.34
192
NR
37.0
MW-13
8.19
2596.60
2604.79
11.8
5.81
505
NR
1.07
MW-15
7.49
2645.96
2653.45
14.3
5.27
114
NR
4.86
MW-A
56.63
2770.95
2827.58
13.5
5.73
90
NR
5.73
MW-28
8.33
2625.85
2634.18
13.0
5.67
64
NR
50.0
MW-29
48.09
2668.18
2716.27
14.4
5.55
117
NR
7.00
MW-30
20.18
2695.75
2715.93
12.7
5.70
66
NR
38.7
WSW-2
-
-
-
13.0
6.64
74
NR
NR
Minimum
7.49
2596.60
2604.79
11.8
5.27
64
NR
1.07
Average
27.14
2664.25
2691.39
13.2
5.73
144
NR
19.7
Maximum
56.63
2770.95
2827.58
14.4
6.64
505
NR
50.0
UDP
-
-
-
18.1
6.76
103
34.2
80
SW -A
-
-
-
18.5
7.24
118
17.1
26.6
SW-2
-
-
-
16.1
6.84
1594
>342
685*
SW-2A
-
-
-
15.4
6.92
366
171
56.8
SW-3
-
-
-
18.8
7.67
121
34.2
40.2
SW-B
-
-
-
1 18.9
6.891
145
34.2
15.8
Minimum
-
-
-
15.4
6.76
103
17.1
15.8
Average
-
-
-
17.6
7.05
408
58.1
44
Maximum
-
-
-
18.9
7.67
1594
171
80
Notes:
btoc = below top of casing
amsl = above mean sea level
NR = No Reading Attempted
* SW-2 turbidity inaccurate. Although kept cold and measured within hold time sample darkened considerably
SW-2 turbidity not used in presented statistical calculations.
Ashe County Lined Landfill Page 1 of 1

Table 4
Sampling and Analysis Summary
June 15-16, 2022
App. I
Other
App. II
Field Parameter
Leachate
m
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a
c
(6
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O
I
O
0
q
0
LO
O
O
N
M
Lo
O
CO
Q
M M
W
(O
Q
<
Q
00
M
W
61
Q
M
i
O
i
O
N
L
N
M
O
M
(V
LO
(V
V)
M
Q
0-
a
Q Q
o o
Q
a
a
�
Q
0-
Q
CL
Q
CL
CL
N
N
Y
N
g
Q
a
Q
a
Q
IL
Q
0-
W
W
w w
W
W
w
U)
W
W
W
W
(n
W
W
W
o7
07
W
-0
-Q
-0 -0
�
V
�
Q
Q
Q
-0
J
J
J J
J
J
J
J
J
J
J
J
J
LL
LL
LL
S
LL
J
J
J
J
co
J
MW-A
x
x
x
x
x
x
x
MW-1
x
x
x
x
x
x
x
MW-2
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-13
x
x
x
x
x
x
x
MW-15
x
x
x
x
x
x
x
MW-28
x
x
x
x
x
x
x
MW-29
x
x
x
x
x
x
x
MW-30
x
x
x
x
x
x
x
WSW-2
x
x
x
x
x
x
SW-3
x
x
x
x
x
x
x
x
SW -A
x
x
x
x
x
x
x
x
SW-B
x
x
x
x
x
x
x
x
GOON
x
x
x
x
x
x
x
x
x
L
x
x
Appendix I & 11= List from current 40 CFR 258
Ashe County Lined Landfill Page 1 of 1

Table 5
Groundwater, Leachate and QC Sample Detections
June 15-16, 2022
Parameter Name
Parameter NameRL
FM7DLRL
STANDARD
MCL
MW-A
MW-1
MW-2
MW-13
MW-15
MW-28
MW-29
MW-30
WSW-2
LAGOON
EB
FB
BG
S
S
S
I S
S
S
S
WSW
I Leachate
QC
QC
Metals Tar eted
40CFR
258 Appendix I
Arsenic, total
2.2
5
10
10
3.4 J
3.3 J
Barium, total
0.67
5
700
2000
265
96.1
528
51.3
302
549
2080
291
166
1430
Beryllium, total
0.054
0.5
4
4
0.055 J
0.081 J
0.086 J
Cadmium, total
0.11
0.5
2
5
1.4
1.4
0.28 J
0.27 J
1.3
0.24 J
0.16 J
Chromium, total
1.1
5
10
100
1.2 J
1.7 J
25.1
3.1 J
5.5
Cobalt, total
0.39
5
1
NE
6.9
7.6
56.6
5.7
0.59 J
10.1
Copper, total
1
5
1000
1300
2.2 J
2.7 J
4.7 J
5.6
2.6 J
229
Lead, total
0.89
1
15
15
1
1
1
1
24.4(P)
Nickel, total
0.71
5
100
NE
IIJ
0.73 J
13.1
4.5 J
22.9
2.7 J
3.6 J
25.6
Selenium, total
1.4
5
20
50
1.8 J
Vanadium, total
1.9
10
7
NE
4.2 J
5.3 J
10.2
3.2 J
4.7 J
Zinc, total
7
10
1000
NE
11.1
13.9
17.3
284
VOCs (Target d 40CFR 258 Appendix I
and 1 4-Dioxane
1,1-Dichloroethane
0.37
1
6
NE
0.49 J
1,2-Dichloroethane
0.32
1
0.4
5
0.46 J
1,4-Dichlorobenzene
0.33
1
6
75
2.9
1,4-Dioxane
0.86
2
3
NE
<38.7
<38.7
--
<38.7
<38.7
<38.7
<38.7
<38.7
<38.7
20.6
<38.7
<38.7
Acetone
5.1
25
6000
NE
5.6 J
5.6 J
Benzene
0.34
1
1
5
4.1(L)
13.9
Chlorobenzene
0.28
1
50
100
2.1
cis-1,2-Dichloroethene
0.38
1
70
70
1.7
Ethylbenzene
0.3
1
600
700
21.2
2-Hexanone
0.48
5
40
NE
5.1
Methylene Chloride
2
5
5
5
2.1 J
2.2 J
Toluene
0.48
1
600
1000
2
Vinyl chloride
0.39
1
0.03
2
0.94 J
0.72 J
Xylene (Total)
0.34
1
500
10000
31.2
Tar
eted 40CFR
258 endix II not also listed
in Appendix
I
Cyanide 1.2 4 70
NE
5.7
Leachate Parameters
Sulfate
500
1000
250000
NE
810 J
BOD
2000
2000
NE
NE
17100
COD
12500
25000
NE
NE
-
453000
-
Phosphorus
25
50
NE
NE
-
590
-
Notes:
Units ug/L except for turbidity, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established
BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample
Bold Above RL and Established 2L Std. (Regulatory compliance Standard)
Green Highlighted Above Established MCL Drinking Water Std. (No regulatory significance)
MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation.
Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation.
RL = Reporting Limit established by the laboratory. The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix.
2L = NC 2L Groundater Standard 15A NCAC 02L .0202
MCL = Maximum Contaminant Level for drinking water established by the USEPA.
J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit'.
(L) Preliminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism.
(P) Preliminary source is believed to be from erosion of plumbing fittings between the well and the animal shelter fixture. Zinc levels drastically reduced in verifiation sample collected after prolonged purge.
A definitive source of the detections was not determined as part of this report.
Ashe County Lined Landfill Page 1 of 1

Table 6
Surface Water Sample Detections
June 15, 2022
Parameter Name
MDL
RL
NC 21B STD'
EPA
NRW C2
NC ISTV
MCL°
SW-2
SW-2A
SW-3
SW-4
SW-5
SW-B
I Downstream
Downstream
Downstream
Downstream
Downstream
Downstream
Metals (Targeted 40CFR 258 Appendix 1)
Antimony, total
0.78
3
NE
640
5300
6
11
Barium, total
0.67
5
NE
NE
21,000
2000
515
125
106
263
98.3
62.5
Beryllium, total
0.054
0.5
6.5c, 65A
NE
NE
4
0.075 J
Cadmium, total
0.11
0.5
0.68c, 4.75A
NE
NE
5
0.21 J
Chromium, total
1.1
5
>1.07c, >7.98A
NE
NE
100
2.8 J
1.1
5
30.78c, 236.63A
NE
NE
2.7 J
Cobalt, total
0.39
5
NE
NE
1.6c, 4, 16A
NE
20.9
6.5
1.5 J
3.2 J
Copper, total
1
5
3.58c, 4.89A
NE
NE
1300
2.3 J
0.71
5
>147.18c, >1325.11A
NE
NE
NE
7.7
Nickel, total
0.71
5
81.88c, 737.19A
NE
NE
4 J
0.71
5
20.98c, 188.91A
NE
NE
1.8 J
0.71
5
88.75c, 799.09A
NE
NE
1.4 J
Vanadium, total
1.9
10
NE
NE
NE
NE
6.5 J
2.3 J
Zinc, total
7
10
47.60c, 47.21A
NE
NE
NE
8.2 J
VOCs (Targeted 40CFR 258 Appendix 18.1,4-Dioxane)
1,1-Dichloroethane
0.37
1
100
NE
100
NE
2.5
1,4-Dichlorobenzene
0.33
1
NE
900
100
75
2.7
0.58 J
0.42 J
1,4-Dioxane
0.86/38.7
2/150
80
NE
NE
NE
<38.7/44.1
3.3
<38.7
3.8
<38.7
<38.7
Benzene
0.34
1
51
NE
NE
5
3.3
Chloroethane
0.65
1
5
5
5
NE
1.8
cis-1,2-Dichloroethene
0.38
1
720
NE
720
70
1.5
Ethylbenzene
0.3
1
97
NE
97
700
1.1
Vinyl chloride
0.39
1
2.4
NE
NE
2
1
Xylene (Total)
0.34
1
670
NE
670
10000
6.2
Hardness as CaCo3 (Field Measured)
Hardness (mg/L) 17.1 NE NE NE I NE 1 >342 171 34.2 188.1 102.6 34.2
Notes:
Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established
J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit".
Red Bold Above RL and Regulatory Compliance Value
Above Established Federal MCL Primary Drinking Water Std.
Receiving surface water is North Fork of New River 00-2421.5)) Class C:ORW 05050001 (8-Digit HUC).
' NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes.
2B Standards from All Waters (C & SC) or Class C. 2B Standard for some metals based on measured hardness values.
Cadmium (chronic) 2B Standard calculation:WER'[{1.136672-[In hardness](0.041838))`e^{0.9151[ln hardness]-3.14851]
Chromium (chronic) 2B Standard calculation:WER'[0.860`e^{0.8190[In hardness]+0.6848)]
Copper (chronic) 2B Standard calculation:WER'[0.960'e^(0.8545[In hardness]-1.702)]
Nickel (chronic) 2B Standard calculation:WER'[0.997'e^(0.8460[In hardness]+0.0584)]
Zinc 2B Standard (acute) calculation:WER'[0.978'e^(0.8473[In hardness]+0.884)]
2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health.
Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses
3 NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DW R staff for further information.
NC ISTV for barium fresh water All waters (Class C), for cobalt & 1,4-Dioxane All waters Fresh & Salt (Class C & SC)
" MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes
A = Acute 2B Standard
c = Chronic 2B Standard
Ashe County Closed Unlined Landfill Page 1 of 1

Table 7
Groundwater Sample Detections (Background)
June 15, 2022
Parameter Name
MDL
RL
2L STANDARD
MCL
MW-A
MW-18
MW-19
BG
BG
BG
Targeted 40CFR 258 Appendix I and 1,4-Dioxane
Barium, total
0.67
5
700
2000
265
223
269
Cadmium, total
0.11
0.5
2
5
1.4
0.43 J
1.5
Chromium, total
1.1
5
10
100
1.2 J
1.2 J
1.4 J
Cobalt, total
0.39
5
1
NE
3.2 J
Copper, total
1
5
1000
1300
2.2 J
2.6 J
2.3 J
Nickel, total
0.71
5
100
NE
11
4 J
1.2 J
Zinc, total
7
10
1000
NE
11.1
8.6 J
11.3
Turbidity (Field Measured)
Turbidity (NTU) 0.01 NE NE 1 5.73 5.06 9.16
Notes:
Units ug/L except for turbidity, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established
Bold Above RL and Established 21-Std. (Regulatory compliance Standard)
MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation.
Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation.
RL = Reporting Limit established by the laboratory. The lowest concentration value that meets project requirements for quantitative data with known precision and bias
for a specific analyte in a specific matrix.
2L = NC 2L Groundater Standard 15A NCAC 02L .0202
MCL = Maximum Contaminant Level for drinking water established by the USEPA. (No regulatory significance)
BG = Background Well Sample.
Ashe County Landfill Page 1 of 1

Table 8
Hydrologic Properties at Monitoring Well Location
June 14-15, 2022
Monitoring
Well
CHydraulic
onductivity
Effective
Porosity
Hydraulic
Gradient
Groundwater
Velocity Rate
Flow Direction
Depth to
Water
Groundwater Elevation
(cm/second)
N
(feet/feet)
(feet/year)
(ft btoc)
(ft amsl)
MW-1
1.30E-03
15
0.116
10
N61 W
48.78
2633.33
MW-2
1.10E-04
20
0.119
0.7
N68W
19.45
2677.35
MW-13
5.40E-04
15
0.148
6
N10W
8.19
2596.60
MW-15
8.40E-04
16
0.065
4
N39W
7.49
2645.96
MW-A
6.57E-05
5
Deep (Upper Bedrock) well not used for contouring
56.63
2770.95
MW-28
3.11E-04
5
0.085 6 N17E
8.33
2625.85
MW-29
3.61 E-05
5
Deep (Upper Bedrock) well not used for contouring
48.09
2668.18
MW-30
N/A
20
0.076
N/A
N20E
20.18
2695.75
Minimum
3.61 E-05
5
0.065
1
--
7.49
2596.60
Average
4.58E-04
13
0.102
5
--
27.14
2664.25
Maximum
1.30E-03
20
0.148
10
--
56.63
2770.95
NOTE: Conductivity data for italicized wells obtained from GAI Consultants' Water Sampling Report (April, 1995).
Conductivity data for remaining wells derived from Slug Tests performed by MESCO.
Effective porosity values are represented by averages for each Iithologic unit taken from MESCO's Hydrogeologic Design Studies.
Hydrogeologic gradient calculated from groundwater elevations recorded on June 14-15, 2022.
Average Linear Velocity rate (Q) is defined by modified Darcy's equation:
where Q - _ K X A
n e dl
K = hydraulic conductivity
n e = effective porosity
dh = head difference
dl = horizontal distance
Ashe County Lined Landfill Page 1 of 1

Appendix A
Field Sampling Parameter Data Sheet(s)

iM
0
Cd
ad t�,Na, �IJI L _ l:ng1 •dn�
. ...11� NC
Project:Ashe County Subtitle D Lined MSWLF, Ph 1, 2 & 4 Samplers:
Sampling Parameters
Water Quality Parameters
Depth to
Lab
Volume
Goes
Total
Depth
Total
Specific
CH4
g
e
Purge
g
Pure
g
Collect
Collect
Point
ate
Date
a
Time
Date
Time
Water
Parameters
Purged
Sample
"type
Dry
Measured
Depth
Comm
pH
Temp.
Cd .
on
IUS�
Gas
2022
ZBZZ
(BTCJP)
to be
(Gal)
During
as
Expected
ents
O
(us/cm
(mg/L,)
=
Vapors
Static
analyzed for
Purge
expected
-----
(ppm)
MW-1
1
[ VOCs &
--
—
--
_
58Metals
MW-2
App 2
27
�� a C)
MW-13
(� 1
P
�fi (i
��
° t{' �� �
jG t�
I vocs & Metals
i
/V
13
MW-15
• I 1
/
I VOCs & 19etals
_
j..'
_
15.5
a
MW-A
`, i
I VOcs&Metals
-�
76
�"'
I' �'
�•�
SW-1
"-,
N
- _
I VOcs & Metals
_
SW.A�
I VOcs & Metals
')
I
UDP
I VOcs &Metals
-
Sh
LAGOON
, '
`�
� I �fP�
„
� 3
-
Leaohate List
MW-29o"�
,
I VOcs & Metals
17.12
MW-29
�� ' ` �;
i� �1
1 VOCs &metals
_
74.6
MW-30
� �
�•
/ �
I�
�i
I VOOs&Metals
29.8
1.
P 45
_
WLR Only
-
-
-
_
P-41D
-
-
, '
wLR only
-
-
WSW-2
(JIG
Li. 10
_
�'U�
`�'�
HAB-1
Vocs App 2
SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry
VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear
NR=No Reading Attempted, NS=No Sample Obtained

ProjeaAshe County Surface Waters -Shared
Samplers:
Page_1
of 1
Sampling Parameters
Water Quality Parameters
Monitoring
Point
Sample
Date
Sample
Time
Depth to
Water
Lab Parameters
volume
Purged
Sample
Goes
Dry
GAGE HT.
FLOW
Comma
p H
Temp.
Specific
Cond.
HARDNE
ss
CH14 Gas
ar ors
Vapors � p
(13TOP)
(Static)
to be analyzed for
(Gal)
Type
During
RATE
nts
(us/cm
(mg/L)
(p pm)
(ppm)
Static
S
Purge
SW-2
I vocs & Metals
GS�
SW-2A
I vocs & Metals
SW-3
l
t
I vocs & Metals
SW-B
IA
I vocs & Metals
SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry
VT=Very Turbid, MT=Moderately Turbid, ST7-Slightly Turbid, C=Clear
NR=No Reading Attempted, NS=No Sample, Obtained

Appendix B
Laboratory Analysis Reports
Chains of Custody

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
July 02, 2022
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
RE: Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on June 17, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
• Pace National - Mt. Juliet
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 86

laneAnalytical
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification M CERT0086
Nebraska Certification #: NE-OS-15-05
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification M L18-597
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification M 618
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LAB0152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 998093910
Wyoming UST Certification #: via A21-A 2926.01
A21-A-ISO 17025 Certification #: 1461.01
A21-A-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
CERTIFICATIONS
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Certification #: 381
South Carolina Certification #: 98011001
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92610492001
MW-2
Water
06/16/2215:20
06/17/2212:50
92610492003
SW-13
Water
06/15/2216:35
06/17/2212:50
92610492004
SW-3
Water
06/15/2216:30
06/17/2212:50
92610492005
MW-1
Water
06/15/2216:35
06/17/2212:50
92610492006
MW-13
Water
06/15/2216:25
06/17/2212:50
92610492007
MW-15
Water
06/15/2216:45
06/17/2212:50
92610492008
MW-A
Water
06/15/2216:40
06/17/2212:50
92610492009
MW-28
Water
06/15/2216:45
06/17/2212:50
92610492010
MW-29
Water
06/15/2216:24
06/17/2212:50
92610492011
MW-30
Water
06/15/2216:19
06/17/2212:50
92610492012
MW-UDP
Water
06/15/2216:50
06/17/2212:50
92610492013
SW -A
Water
06/15/2216:40
06/17/2212:50
92610492014
WSW-2
Water
06/16/2217:01
06/17/2212:50
REPORT OF LABORATORY ANALYSIS
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Page 4 of 86

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SAMPLE ANALYTE COUNT
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92610492001 MW-2
EPA 8151
CCW
5
PAN
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 7470A
NMP
1
PASI-A
EPA 8270E
PKS
111
PASI-C
EPA 8260D
CL
65
PASI-C
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 335.4
SLL2
1
GCLA
92610492003 SW-B
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92610492004 SW-3
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92610492005 MW-1
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92610492006 MW-13
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92610492007 MW-15
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92610492008 MW-A
EPA6020B
CW1
15
PASI-GA
EPA 8260D
NSCQ
51
PASI-C
92610492009 MW-28
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92610492010 MW-29
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92610492011 MW-30
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92610492012 MW-UDP
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92610492013 SW -A
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92610492014 WSW-2
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
GCLA = Pace Analytical Gulf Coast
PAN = Pace National - Mt. Juliet
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
PASI-GA = Pace Analytical Services - Peachtree Corners, GA
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2
Lab ID:
92610492001
Collected:
06/16/22 15:20
Received: 06/17/22 12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151
Analytical
Method: EPA8151
Preparation
Method: 8151A
Pace National
- Mt. Juliet
2,4-D
ND
ug/L
2.00
0.547
1
06/20/22 10:18
06/22/22 20:31
94-75-7 LO
2,4,5-T
ND
ug/L
2.00
0.258
1
06/20/22 10:18
06/22/22 20:31
93-76-5 LO
2,4,5-TP (Silvex)
ND
ug/L
2.00
0.335
1
06/20/22 10:18
06/22/22 20:31
93-72-1 LO
Dinoseb
ND
ug/L
2.00
0.250
1
06/20/22 10:18
06/22/22 20:31
88-85-7
Surrogates
2,4-DCAA (S)
88.4
%
14.0-158
1
06/20/22 10:18
06/22/22 20:31
19719-28-9
8081 OC Pesticides RVE
Analytical
Method: EPA 8081
B Preparation Method: EPA 351 OC
Pace Analytical
Services
- Charlotte
Aldrin
ND
ug/L
0.050
0.014
1
06/22/22 19:01
06/23/22 13:45
309-00-2
alpha-BHC
ND
ug/L
0.050
0.012
1
06/22/22 19:01
06/23/22 13:45
319-84-6
beta-BHC
ND
ug/L
0.050
0.049
1
06/22/22 19:01
06/23/22 13:45
319-85-7
delta-BHC
ND
ug/L
0.050
0.014
1
06/22/22 19:01
06/23/22 13:45
319-86-8
gamma-BHC (Lindane)
ND
ug/L
0.050
0.012
1
06/22/22 19:01
06/23/22 13:45
58-89-9
Chlordane (Technical)
ND
ug/L
0.50
0.16
1
06/22/22 19:01
06/23/22 13:45
57-74-9
4,4'-DDD
ND
ug/L
0.050
0.017
1
06/22/22 19:01
06/23/22 13:45
72-54-8
4,4'-DDE
ND
ug/L
0.050
0.024
1
06/22/22 19:01
06/23/22 13:45
72-55-9
4,4'-DDT
ND
ug/L
0.050
0.026
1
06/22/22 19:01
06/23/22 13:45
50-29-3
Dieldrin
ND
ug/L
0.050
0.015
1
06/22/22 19:01
06/23/22 13:45
60-57-1
Endosulfan I
ND
ug/L
0.050
0.017
1
06/22/22 19:01
06/23/22 13:45
959-98-8
Endosulfan 11
ND
ug/L
0.050
0.016
1
06/22/22 19:01
06/23/22 13:45
33213-65-9
Endosulfan sulfate
ND
ug/L
0.050
0.015
1
06/22/22 19:01
06/23/22 13:45
1031-07-8
Endrin
ND
ug/L
0.050
0.018
1
06/22/22 19:01
06/23/22 13:45
72-20-8
Endrin aldehyde
ND
ug/L
0.050
0.016
1
06/22/22 19:01
06/23/22 13:45
7421-93-4
Heptachlor
ND
ug/L
0.050
0.020
1
06/22/22 19:01
06/23/22 13:45
76-44-8
Heptachlor epoxide
ND
ug/L
0.050
0.028
1
06/22/22 19:01
06/23/22 13:45
1024-57-3
Methoxychlor
ND
ug/L
0.15
0.042
1
06/22/22 19:01
06/23/22 13:45
72-43-5
Toxaphene
ND
ug/L
0.50
0.22
1
06/22/22 19:01
06/23/22 13:45
8001-35-2
Surrogates
Tetrachloro-m-xylene (S)
87
%
10-182
1
06/22/22 19:01
06/23/22 13:45
877-09-8
Decachlorobiphenyl (S)
185
%
10-200
1
06/22/22 19:01
06/23/22 13:45
2051-24-3
8082 GCS PCB RVE
Analytical
Method: EPA 8082A
Preparation Method:
EPA 351 OC
Pace Analytical
Services
- Charlotte
PCB-1016 (Aroclor 1016)
ND
ug/L
0.42
0.18
1
06/23/22 13:16
06/24/22 07:30
12674-11-2
PCB-1221 (Aroclor 1221)
ND
ug/L
0.42
0.19
1
06/23/22 13:16
06/24/22 07:30
11104-28-2
PCB-1232 (Aroclor 1232)
ND
ug/L
0.42
0.19
1
06/23/22 13:16
06/24/22 07:30
11141-16-5
PCB-1242 (Aroclor 1242)
ND
ug/L
0.42
0.21
1
06/23/22 13:16
06/24/22 07:30
53469-21-9
PCB-1248 (Aroclor 1248)
ND
ug/L
0.42
0.24
1
06/23/22 13:16
06/24/22 07:30
12672-29-6
PCB-1254 (Aroclor 1254)
ND
ug/L
0.42
0.18
1
06/23/22 13:16
06/24/22 07:30
11097-69-1
PCB-1260 (Aroclor 1260)
ND
ug/L
0.42
0.13
1
06/23/22 13:16
06/24/22 07:30
11096-82-5
Surrogates
Decachlorobiphenyl (S)
86
%
10-181
1
06/23/22 13:16
06/24/22 07:30
2051-24-3
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2 Lab ID: 92610492001 Collected: 06/16/22 15:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/22/2212:04
06/25/2218:00
7440-36-0
Arsenic
3.4.1
ug/L
5.0
2.2
1 06/22/2212:04
06/25/2218:00
7440-38-2
Barium
528
ug/L
5.0
0.67
1 06/22/2212:04
06/25/2218:00
7440-39-3
Beryllium
0.055J
ug/L
0.50
0.054
1 06/22/2212:04
06/25/2218:00
7440-41-7
Cadmium
0.28J
ug/L
0.50
0.11
1 06/22/2212:04
06/25/2218:00
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/22/2212:04
06/27/2213:43
7440-47-3
Cobalt
6.9
ug/L
5.0
0.39
1 06/22/2212:04
06/25/2218:00
7440-48-4
Copper
4.7J
ug/L
5.0
1.0
1 06/22/2212:04
06/25/2218:00
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/22/2212:04
06/25/2218:00
7439-92-1
Nickel
13.1
ug/L
5.0
0.71
1 06/22/2212:04
06/27/2213:43
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/22/2212:04
06/25/2218:00
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/22/2212:04
06/25/2218:00
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/22/2212:04
06/25/2218:00
7440-28-0
Vanadium
4.2.1
ug/L
10.0
1.9
1 06/22/2212:04
06/25/2218:00
7440-62-2
Zinc
13.9
ug/L
10.0
7.0
1 06/22/2212:04
06/25/2218:00
7440-66-6
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services
-Asheville
Mercury
ND
ug/L
0.20
0.12
1 06/30/2210:10
07/01/2210:08
7439-97-6
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA
3510C
Pace Analytical Services - Charlotte
Acenaphthene
ND
ug/L
8.3
1.7
1 06/21/22 10:50
06/22/22 23:51
83-32-9
Acenaphthylene
ND
ug/L
8.3
1.6
1 06/21/22 10:50
06/22/22 23:51
208-96-8
Acetophenone
ND
ug/L
8.3
1.2
1 06/21/22 10:50
06/22/22 23:51
98-86-2
2-Acetylaminofluorene
ND
ug/L
8.3
3.4
1 06/21/22 10:50
06/22/22 23:51
53-96-3
4-Aminobiphenyl
ND
ug/L
8.3
4.0
1 06/21/22 10:50
06/22/22 23:51
92-67-1
Anthracene
ND
ug/L
8.3
1.9
1 06/21/22 10:50
06/22/22 23:51
120-12-7
Benzo(a)anthracene
ND
ug/L
8.3
2.2
1 06/21/22 10:50
06/22/22 23:51
56-55-3 L1
Benzo(a)pyrene
ND
ug/L
8.3
2.3
1 06/21/22 10:50
06/22/22 23:51
50-32-8
Benzo(b)fluoranthene
ND
ug/L
8.3
2.2
1 06/21/22 10:50
06/22/22 23:51
205-99-2
Benzo(g,h,i)perylene
ND
ug/L
8.3
2.4
1 06/21/22 10:50
06/22/22 23:51
191-24-2
Benzo(k)fluoranthene
ND
ug/L
8.3
2.3
1 06/21/22 10:50
06/22/22 23:51
207-08-9
Benzyl alcohol
ND
ug/L
16.7
2.4
1 06/21/22 10:50
06/22/22 23:51
100-51-6
4-Bromophenylphenyl ether
ND
ug/L
8.3
1.5
1 06/21/22 10:50
06/22/22 23:51
101-55-3 L1
Butylbenzylphthalate
ND
ug/L
8.3
2.6
1 06/21/22 10:50
06/22/22 23:51
85-68-7
4-Chloro-3-methyl phenol
ND
ug/L
8.3
2.8
1 06/21/22 10:50
06/22/22 23:51
59-50-7 L1
4-Chloroaniline
ND
ug/L
16.7
3.0
1 06/21/22 10:50
06/22/22 23:51
106-47-8
Chlorobenzilate
ND
ug/L
8.3
3.2
1 06/21/22 10:50
06/22/22 23:51
510-15-6
bis(2-Chloroethoxy)methane
ND
ug/L
8.3
1.5
1 06/21/22 10:50
06/22/22 23:51
111-91-1
bis(2-Chloroethyl) ether
ND
ug/L
8.3
1.6
1 06/21/22 10:50
06/22/22 23:51
111-44-4
2-Chloronaphthalene
ND
ug/L
8.3
1.4
1 06/21/22 10:50
06/22/22 23:51
91-58-7
2-Chlorophenol
ND
ug/L
8.3
1.0
1 06/21/22 10:50
06/22/22 23:51
95-57-8
4-Chlorophenylphenyl ether
ND
ug/L
8.3
1.7
1 06/21/22 10:50
06/22/22 23:51
7005-72-3
Chrysene
ND
ug/L
8.3
2.3
1 06/21/22 10:50
06/22/22 23:51
218-01-9 L1
REPORT OF LABORATORY ANALYSIS
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Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 86

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[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2 Lab ID: 92610492001 Collected: 06/16/22 15:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
Diallate
ND
ug/L
8.3
2.8
1
06/21/22 10:50
06/22/22 23:51
2303-16-4
Dibenz(a,h)anthracene
ND
ug/L
8.3
2.5
1
06/21/22 10:50
06/22/22 23:51
53-70-3
Dibenzofuran
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
16.7
6.8
1
06/21/22 10:50
06/22/22 23:51
91-94-1
2,4-Dichlorophenol
ND
ug/L
8.3
1.2
1
06/21/22 10:50
06/22/22 23:51
120-83-2
2,6-Dichlorophenol
ND
ug/L
8.3
3.5
1
06/21/22 10:50
06/22/22 23:51
87-65-0
Diethylphthalate
ND
ug/L
8.3
1.7
1
06/21/22 10:50
06/22/22 23:51
84-66-2
Dimethoate
ND
ug/L
8.3
3.0
1
06/21/22 10:50
06/22/22 23:51
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
4.2
2.0
1
06/21/22 10:50
06/22/22 23:51
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
8.3
2.5
1
06/21/22 10:50
06/22/22 23:51
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
41.7
25.9
1
06/21/22 10:50
06/22/22 23:51
119-93-7
2,4-Dimethylphenol
ND
ug/L
8.3
1.4
1
06/21/22 10:50
06/22/22 23:51
105-67-9
Dimethylphthalate
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
131-11-3
Di-n-butylphthalate
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
16.7
6.5
1
06/21/22 10:50
06/22/22 23:51
534-52-1
1,3-Dinitrobenzene
ND
ug/L
8.3
3.1
1
06/21/22 10:50
06/22/22 23:51
99-65-0
2,4-Dinitrophenol
ND
ug/L
41.7
21.7
1
06/21/22 10:50
06/22/22 23:51
51-28-5
2,4-Dinitrotoluene
ND
ug/L
8.3
1.4
1
06/21/22 10:50
06/22/22 23:51
121-14-2
2,6-Dinitrotoluene
ND
ug/L
8.3
1.4
1
06/21/22 10:50
06/22/22 23:51
606-20-2
Di-n-octylphthalate
ND
ug/L
8.3
3.3
1
06/21/22 10:50
06/22/22 23:51
117-84-0
Diphenylamine
ND
ug/L
8.3
2.5
1
06/21/22 10:50
06/22/22 23:51
122-39-4
Disulfoton
ND
ug/L
8.3
3.9
1
06/21/22 10:50
06/22/22 23:51
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
5.0
3.1
1
06/21/22 10:50
06/22/22 23:51
117-81-7
Ethyl methanesulfonate
ND
ug/L
16.7
2.5
1
06/21/22 10:50
06/22/22 23:51
62-50-0
Famphur
ND
ug/L
8.3
5.1
1
06/21/22 10:50
06/22/22 23:51
52-85-7
Fluoranthene
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
206-44-0
Fluorene
ND
ug/L
8.3
1.7
1
06/21/22 10:50
06/22/22 23:51
86-73-7
Hexachlorobenzene
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
8.3
1.3
1
06/21/22 10:50
06/22/22 23:51
77-47-4
Hexachloroethane
ND
ug/L
8.3
1.2
1
06/21/22 10:50
06/22/22 23:51
67-72-1
Hexachloropropene
ND
ug/L
8.3
2.2
1
06/21/22 10:50
06/22/22 23:51
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
8.3
2.4
1
06/21/22 10:50
06/22/22 23:51
193-39-5
Isodrin
ND
ug/L
8.3
2.3
1
06/21/22 10:50
06/22/22 23:51
465-73-6
Isophorone
ND
ug/L
8.3
1.4
1
06/21/22 10:50
06/22/22 23:51
78-59-1
Isosafrole
ND
ug/L
8.3
2.1
1
06/21/22 10:50
06/22/22 23:51
120-58-1
Kepone
ND
ug/L
16.7
11.8
1
06/21/22 10:50
06/22/22 23:51
143-50-0
Methapyrilene
ND
ug/L
41.7
14.2
1
06/21/22 10:50
06/22/22 23:51
91-80-5
3-Methylcholanthrene
ND
ug/L
8.3
4.8
1
06/21/22 10:50
06/22/22 23:51
56-49-5
Methyl methanesulfonate
ND
ug/L
4.2
2.6
1
06/21/22 10:50
06/22/22 23:51
66-27-3
2-Methylnaphthalene
ND
ug/L
8.3
1.6
1
06/21/22 10:50
06/22/22 23:51
91-57-6
Methyl parathion
ND
ug/L
8.3
3.1
1
06/21/22 10:50
06/22/22 23:51
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
8.3
1.6
1
06/21/22 10:50
06/22/22 23:51
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
8.3
1.0
1
06/21/22 10:50
06/22/22 23:51
15831-10-4
1-Naphthalenamine
ND
ug/L
8.3
5.0
1
06/21/22 10:50
06/22/22 23:51
134-32-7
2-Naphthalenamine
ND
ug/L
8.3
4.5
1
06/21/22 10:50
06/22/22 23:51
91-59-8
REPORT OF LABORATORY ANALYSIS
L1
L1
IL
IH,L1
L1
L1
L1
IH
L1
L1
v1
L2
v1
v1
IH
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2 Lab ID: 92610492001 Collected: 06/16/22 15:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270E APP9 RV
1,4-Naphthoquinone
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O, O,O-Triethyl phosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
Pace Analytical Services - Charlotte
ND
ug/L
4.2
3.7
1
06/21/22 10:50
06/22/22 23:51
130-15-4
ND
ug/L
16.7
2.5
1
06/21/22 10:50
06/22/22 23:51
88-74-4
ND
ug/L
16.7
3.1
1
06/21/22 10:50
06/22/22 23:51
99-09-2
ND
ug/L
16.7
4.2
1
06/21/22 10:50
06/22/22 23:51
100-01-6
ND
ug/L
8.3
1.6
1
06/21/22 10:50
06/22/22 23:51
98-95-3
ND
ug/L
8.3
1.2
1
06/21/22 10:50
06/22/22 23:51
88-75-5
ND
ug/L
41.7
5.5
1
06/21/22 10:50
06/22/22 23:51
100-02-7
ND
ug/L
8.3
3.2
1
06/21/22 10:50
06/22/22 23:51
99-55-8
ND
ug/L
8.3
1.9
1
06/21/22 10:50
06/22/22 23:51
55-18-5
ND
ug/L
8.3
1.6
1
06/21/22 10:50
06/22/22 23:51
62-75-9
ND
ug/L
8.3
1.6
1
06/21/22 10:50
06/22/22 23:51
924-16-3
ND
ug/L
8.3
1.1
1
06/21/22 10:50
06/22/22 23:51
621-64-7
ND
ug/L
8.3
2.5
1
06/21/22 10:50
06/22/22 23:51
86-30-6
ND
ug/L
8.3
6.2
1
06/21/22 10:50
06/22/22 23:51
10595-95-6
ND
ug/L
8.3
2.1
1
06/21/22 10:50
06/22/22 23:51
100-75-4
ND
ug/L
8.3
2.6
1
06/21/22 10:50
06/22/22 23:51
930-55-2
ND
ug/L
8.3
2.1
1
06/21/22 10:50
06/22/22 23:51
126-68-1
ND
ug/L
8.3
0.96
1
06/21/22 10:50
06/22/22 23:51
108-60-1
ND
ug/L
8.3
3.2
1
06/21/22 10:50
06/22/22 23:51
56-38-2
ND
ug/L
8.3
2.8
1
06/21/22 10:50
06/22/22 23:51
608-93-5
ND
ug/L
8.3
2.7
1
06/21/22 10:50
06/22/22 23:51
82-68-8
ND
ug/L
16.7
3.1
1
06/21/22 10:50
06/22/22 23:51
87-86-5
ND
ug/L
8.3
3.0
1
06/21/22 10:50
06/22/22 23:51
62-44-2
ND
ug/L
8.3
1.7
1
06/21/22 10:50
06/22/22 23:51
85-01-8
ND
ug/L
8.3
1.1
1
06/21/22 10:50
06/22/22 23:51
108-95-2
ND
ug/L
8.3
8.3
1
06/21/22 10:50
06/22/22 23:51
106-50-3
ND
ug/L
8.3
3.0
1
06/21/22 10:50
06/22/22 23:51
298-02-2
ND
ug/L
8.3
2.6
1
06/21/22 10:50
06/22/22 23:51
23950-58-5
ND
ug/L
8.3
1.8
1
06/21/22 10:50
06/22/22 23:51
129-00-0
ND
ug/L
8.3
1.9
1
06/21/22 10:50
06/22/22 23:51
94-59-7
ND
ug/L
8.3
3.7
1
06/21/22 10:50
06/22/22 23:51
95-94-3
ND
ug/L
8.3
1.3
1
06/21/22 10:50
06/22/22 23:51
58-90-2
ND
ug/L
8.3
2.4
1
06/21/22 10:50
06/22/22 23:51
297-97-2
ND
ug/L
8.3
2.2
1
06/21/22 10:50
06/22/22 23:51
95-53-4
ND
ug/L
8.3
1.2
1
06/21/22 10:50
06/22/22 23:51
95-95-4
ND
ug/L
8.3
1.3
1
06/21/22 10:50
06/22/22 23:51
88-06-2
ND
ug/L
8.3
4.6
1
06/21/22 10:50
06/22/22 23:51
99-35-4
67
%
10-144
1
06/21/22 10:50
06/22/22 23:51
4165-60-0
41
%
10-130
1
06/21/22 10:50
06/22/22 23:51
321-60-8
123
%
34-163
1
06/21/22 10:50
06/22/22 23:51
1718-51-0
48
%
10-130
1
06/21/22 10:50
06/22/22 23:51
13127-88-3
61
%
10-130
1
06/21/22 10:50
06/22/22 23:51
367-12-4
109
%
10-144
1
06/21/22 10:50
06/22/22 23:51
118-79-6
REPORT OF LABORATORY ANALYSIS
IL
L1
L1
v1
L1
L1
L1
v1
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2 Lab ID: 92610492001 Collected: 06/16/22 15:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
Dibromochloromethane
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
Hexachloro-1,3-butadiene
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Date: 07/02/2022 01:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
5.1
1
06/20/22 20:33
67-64-1
ND
ug/L
50.0
24.8
1
06/20/22 20:33
75-05-8
ND
ug/L
10.0
8.5
1
06/20/22 20:33
107-02-8
ND
ug/L
10.0
1.8
1
06/20/22 20:33
107-13-1
ND
ug/L
2.0
0.50
1
06/20/22 20:33
107-05-1
4.1
ug/L
1.0
0.34
1
06/20/22 20:33
71-43-2
ND
ug/L
1.0
0.47
1
06/20/22 20:33
74-97-5
ND
ug/L
1.0
0.31
1
06/20/22 20:33
75-27-4
ND
ug/L
1.0
0.34
1
06/20/22 20:33
75-25-2
ND
ug/L
2.0
1.7
1
06/20/22 20:33
74-83-9
ND
ug/L
5.0
4.0
1
06/20/22 20:33
78-93-3
ND
ug/L
2.0
0.36
1
06/20/22 20:33
75-15-0
ND
ug/L
1.0
0.33
1
06/20/22 20:33
56-23-5
ND
ug/L
1.0
0.28
1
06/20/22 20:33
108-90-7
ND
ug/L
1.0
0.65
1
06/20/22 20:33
75-00-3
ND
ug/L
1.0
0.43
1
06/20/22 20:33
67-66-3
ND
ug/L
1.0
0.54
1
06/20/22 20:33
74-87-3
ND
ug/L
5.0
1.6
1
06/20/22 20:33
126-99-8
ND
ug/L
1.0
0.36
1
06/20/22 20:33
124-48-1
ND
ug/L
1.0
0.39
1
06/20/22 20:33
74-95-3
ND
ug/L
1.0
0.34
1
06/20/22 20:33
95-50-1
ND
ug/L
1.0
0.33
1
06/20/22 20:33
106-46-7
ND
ug/L
1.0
0.56
1
06/20/22 20:33
110-57-6
ND
ug/L
1.0
0.35
1
06/20/22 20:33
75-71-8
ND
ug/L
1.0
0.37
1
06/20/22 20:33
75-34-3
ND
ug/L
1.0
0.32
1
06/20/22 20:33
107-06-2
ND
ug/L
1.0
0.35
1
06/20/22 20:33
75-35-4
1.7
ug/L
1.0
0.38
1
06/20/22 20:33
156-59-2
ND
ug/L
1.0
0.40
1
06/20/22 20:33
156-60-5
ND
ug/L
1.0
0.36
1
06/20/22 20:33
78-87-5
ND
ug/L
1.0
0.28
1
06/20/22 20:33
142-28-9
ND
ug/L
1.0
0.39
1
06/20/22 20:33
594-20-7
ND
ug/L
1.0
0.43
1
06/20/22 20:33
563-58-6
ND
ug/L
1.0
0.36
1
06/20/22 20:33
10061-01-5
ND
ug/L
1.0
0.36
1
06/20/22 20:33
10061-02-6
ND
ug/L
1.0
0.30
1
06/20/22 20:33
100-41-4
ND
ug/L
1.0
0.28
1
06/20/22 20:33
97-63-2
ND
ug/L
2.0
1.5
1
06/20/22 20:33
87-68-3
5.1
ug/L
5.0
0.48
1
06/20/22 20:33
591-78-6
ND
ug/L
20.0
9.7
1
06/20/22 20:33
74-88-4
ND
ug/L
100
52.3
1
06/20/22 20:33
78-83-1
ND
ug/L
10.0
4.2
1
06/20/22 20:33
126-98-7
ND
ug/L
5.0
2.0
1
06/20/22 20:33
75-09-2
ND
ug/L
2.0
0.32
1
06/20/22 20:33
80-62-6
ND
ug/L
5.0
2.7
1
06/20/22 20:33
108-10-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
IK,L1,v1
v1
v1
v1
Page 11 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-2 Lab ID: 92610492001 Collected: 06/16/22 15:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S213 Sulfide Water
Sulfide
EPA 335.4
Cyanide
Date: 07/02/2022 01:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.64
1
ND ug/L
20.0
3.6
1
ND ug/L
1.0
0.29
1
ND ug/L
1.0
0.31
1
ND ug/L
1.0
0.22
1
ND ug/L
1.0
0.29
1
ND ug/L
1.0
0.48
1
ND ug/L
1.0
0.81
1
ND ug/L
1.0
0.64
1
ND ug/L
1.0
0.33
1
ND ug/L
1.0
0.32
1
ND ug/L
1.0
0.38
1
ND ug/L
1.0
0.30
1
ND ug/L
1.0
0.26
1
ND ug/L
2.0
1.3
1
0.94J ug/L
1.0
0.39
1
ND ug/L
1.0
0.34
1
99 %
70-130
1
99 %
70-130
1
100 %
70-130
1
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L
100
50.0
1
Analytical Method: EPA 335.4 Preparation Method: METHOD
Pace Analytical Gulf Coast
06/20/22 20:33 91-20-3
06/20/22 20:33 107-12-0
06/20/22 20:33 100-42-5
06/20/22 20:33 630-20-6
06/20/22 20:33 79-34-5
06/20/22 20:33 127-18-4
06/20/22 20:33 108-88-3
06/20/22 20:33 87-61-6
06/20/22 20:33 120-82-1
06/20/22 20:33 71-55-6
06/20/22 20:33 79-00-5
06/20/22 20:33 79-01-6
06/20/22 20:33 75-69-4
06/20/22 20:33 96-18-4
06/20/22 20:33 108-05-4
06/20/22 20:33 75-01-4
06/20/22 20:33 1330-20-7
06/20/22 20:33 460-00-4
06/20/22 20:33 17060-07-0
06/20/22 20:33 2037-26-5
06/18/22 04:37 18496-25-8
0.0057 mg/L 0.0040 0.0012 1 06/24/2210:48 06/27/2210:56 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW-B
Lab ID:
92610492003
Collected:
06/15/22 16:35
Received: 06/17/22
12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3005A
Pace Analytical
Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2211:05
06/28/2218:38
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2211:05
06/28/2218:38
7440-38-2
Barium
62.5
ug/L
5.0
0.67
1
06/21/2211:05
06/28/2218:38
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1
06/21/2211:05
06/28/2218:38
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/21/2211:05
06/28/2218:38
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1
06/21/2211:05
06/28/2218:38
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1
06/21/2211:05
06/28/2218:38
7440-48-4
Copper
ND
ug/L
5.0
1.0
1
06/21/2211:05
06/28/2218:38
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2211:05
06/28/2218:38
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1
06/21/2211:05
06/28/2218:38
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2211:05
06/28/2218:38
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2211:05
06/28/2218:38
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2211:05
06/28/2218:38
7440-28-0
Vanadium
2.3.1
ug/L
10.0
1.9
1
06/21/2211:05
06/28/2218:38
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1
06/21/2211:05
06/28/2218:38
7440-66-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/22/22 14:54
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/22/22 14:54
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/22/22 14:54
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/22/22 14:54
74-97-5
IK
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/22/22 14:54
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/22/22 14:54
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1.7
1
06/22/22 14:54
74-83-9
v1
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/22/22 14:54
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/22/22 14:54
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/22/22 14:54
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/22/22 14:54
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/22/22 14:54
75-00-3
v1
Chloroform
ND
ug/L
1.0
0.43
1
06/22/22 14:54
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/22/22 14:54
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/22/22 14:54
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/22/22 14:54
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/22/22 14:54
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/22/22 14:54
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/22/22 14:54
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/22/22 14:54
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/22/22 14:54
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/22/22 14:54
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 14:54
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/22/22 14:54
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 14:54
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/22/22 14:54
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/22/22 14:54
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW-B
Parameters
Lab ID:
Results
92610492003
Units
Collected:
Report
Limit
06/15/22 16:35
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 14:54
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 14:54
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/22/22 14:54
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/22/22 14:54
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/22/22 14:54
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/22/22 14:54
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/22/22 14:54
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/22/22 14:54
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/22/22 14:54
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/22/22 14:54
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/22/22 14:54
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/22/22 14:54
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/22/22 14:54
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/22/22 14:54
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 14:54
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 14:54
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/22/22 14:54
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/22/22 14:54
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/22/22 14:54
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/22/22 14:54
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/22/22 14:54
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
91
%
70-130
1
06/22/22 14:54
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
06/22/22 14:54
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
06/22/22 14:54
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW-3
Lab ID:
92610492004
Collected:
06/15/22 16:30
Received: 06/17/22
12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3005A
Pace Analytical
Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2211:05
06/28/2218:44
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2211:05
06/28/2218:44
7440-38-2
Barium
106
ug/L
5.0
0.67
1
06/21/2211:05
06/28/2218:44
7440-39-3
Beryllium
0.075J
ug/L
0.50
0.054
1
06/21/2211:05
06/28/2218:44
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/21/2211:05
06/28/2218:44
7440-43-9
Chromium
2.7.1
ug/L
5.0
1.1
1
06/21/2211:05
06/28/2218:44
7440-47-3
Cobalt
1.5.1
ug/L
5.0
0.39
1
06/21/2211:05
06/28/2218:44
7440-48-4
Copper
2.3J
ug/L
5.0
1.0
1
06/21/2211:05
06/28/2218:44
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2211:05
06/28/2218:44
7439-92-1
Nickel
1.81
ug/L
5.0
0.71
1
06/21/2211:05
06/28/2218:44
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2211:05
06/28/2218:44
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2211:05
06/28/2218:44
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2211:05
06/28/2218:44
7440-28-0
Vanadium
6.5J
ug/L
10.0
1.9
1
06/21/2211:05
06/28/2218:44
7440-62-2
Zinc
8.2J
ug/L
10.0
7.0
1
06/21/2211:05
06/28/2218:44
7440-66-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/22/22 15:12
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/22/22 15:12
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/22/22 15:12
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/22/22 15:12
74-97-5
IK
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/22/22 15:12
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/22/22 15:12
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1.7
1
06/22/22 15:12
74-83-9
v1
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/22/22 15:12
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/22/22 15:12
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/22/22 15:12
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/22/22 15:12
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/22/22 15:12
75-00-3
v1
Chloroform
ND
ug/L
1.0
0.43
1
06/22/22 15:12
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/22/22 15:12
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/22/22 15:12
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/22/22 15:12
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/22/22 15:12
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/22/22 15:12
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/22/22 15:12
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/22/22 15:12
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/22/22 15:12
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/22/22 15:12
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:12
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/22/22 15:12
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:12
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/22/22 15:12
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/22/22 15:12
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW-3
Parameters
Lab ID:
Results
92610492004
Units
Collected:
Report
Limit
06/15/22 16:30
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:12
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:12
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/22/22 15:12
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/22/22 15:12
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/22/22 15:12
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/22/22 15:12
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/22/22 15:12
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/22/22 15:12
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/22/22 15:12
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/22/22 15:12
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/22/22 15:12
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/22/22 15:12
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/22/22 15:12
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/22/22 15:12
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:12
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:12
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/22/22 15:12
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/22/22 15:12
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/22/22 15:12
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/22/22 15:12
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/22/22 15:12
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
91
%
70-130
1
06/22/22 15:12
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
06/22/22 15:12
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
06/22/22 15:12
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-1
Lab ID:
92610492005
Collected:
06/15/22 16:35
Received: 06/17/22
12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3005A
Pace Analytical
Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2211:05
06/28/2218:50
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2211:05
06/28/2218:50
7440-38-2
Barium
96.1
ug/L
5.0
0.67
1
06/21/2211:05
06/28/2218:50
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1
06/21/2211:05
06/28/2218:50
7440-41-7
Cadmium
1.4
ug/L
0.50
0.11
1
06/21/2211:05
06/28/2218:50
7440-43-9
Chromium
1.7.1
ug/L
5.0
1.1
1
06/21/2211:05
06/28/2218:50
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1
06/21/2211:05
06/28/2218:50
7440-48-4
Copper
2.7.1
ug/L
5.0
1.0
1
06/21/2211:05
06/28/2218:50
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2211:05
06/28/2218:50
7439-92-1
Nickel
0.73J
ug/L
5.0
0.71
1
06/21/2211:05
06/28/2218:50
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2211:05
06/28/2218:50
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2211:05
06/28/2218:50
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2211:05
06/28/2218:50
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1
06/21/2211:05
06/28/2218:50
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1
06/21/2211:05
06/28/2218:50
7440-66-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/22/22 15:30
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/22/22 15:30
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/22/22 15:30
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/22/22 15:30
74-97-5
IK
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/22/22 15:30
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/22/22 15:30
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1.7
1
06/22/22 15:30
74-83-9
v1
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/22/22 15:30
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/22/22 15:30
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/22/22 15:30
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/22/22 15:30
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/22/22 15:30
75-00-3
v1
Chloroform
ND
ug/L
1.0
0.43
1
06/22/22 15:30
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/22/22 15:30
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/22/22 15:30
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/22/22 15:30
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/22/22 15:30
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/22/22 15:30
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/22/22 15:30
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/22/22 15:30
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/22/22 15:30
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/22/22 15:30
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:30
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/22/22 15:30
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:30
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/22/22 15:30
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/22/22 15:30
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-1
Parameters
Lab ID:
Results
92610492005
Units
Collected:
Report
Limit
06/15/22 16:35
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:30
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:30
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/22/22 15:30
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/22/22 15:30
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/22/22 15:30
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/22/22 15:30
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/22/22 15:30
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/22/22 15:30
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/22/22 15:30
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/22/22 15:30
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/22/22 15:30
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/22/22 15:30
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/22/22 15:30
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/22/22 15:30
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:30
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:30
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/22/22 15:30
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/22/22 15:30
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/22/22 15:30
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/22/22 15:30
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/22/22 15:30
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
93
%
70-130
1
06/22/22 15:30
460-00-4
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
06/22/22 15:30
17060-07-0
Toluene-d8 (S)
97
%
70-130
1
06/22/22 15:30
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-13
Lab ID:
92610492006
Collected:
06/15/22 16:25
Received: 06/17/22
12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No.
Qual
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3005A
Pace Analytical
Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2211:05
06/28/2218:56
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2211:05
06/28/2218:56
7440-38-2
Barium
51.3
ug/L
5.0
0.67
1
06/21/2211:05
06/28/2218:56
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1
06/21/2211:05
06/28/2218:56
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/21/2211:05
06/28/2218:56
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1
06/21/2211:05
06/28/2218:56
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1
06/21/2211:05
06/28/2218:56
7440-48-4
Copper
ND
ug/L
5.0
1.0
1
06/21/2211:05
06/28/2218:56
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2211:05
06/28/2218:56
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1
06/21/2211:05
06/28/2218:56
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2211:05
06/28/2218:56
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2211:05
06/28/2218:56
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2211:05
06/28/2218:56
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1
06/21/2211:05
06/28/2218:56
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1
06/21/2211:05
06/28/2218:56
7440-66-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/22/22 15:48
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/22/22 15:48
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/22/22 15:48
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/22/22 15:48
74-97-5
IK
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/22/22 15:48
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/22/22 15:48
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1.7
1
06/22/22 15:48
74-83-9
v1
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/22/22 15:48
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/22/22 15:48
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/22/22 15:48
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/22/22 15:48
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/22/22 15:48
75-00-3
v1
Chloroform
ND
ug/L
1.0
0.43
1
06/22/22 15:48
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/22/22 15:48
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/22/22 15:48
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/22/22 15:48
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/22/22 15:48
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/22/22 15:48
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/22/22 15:48
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/22/22 15:48
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/22/22 15:48
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/22/22 15:48
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:48
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/22/22 15:48
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:48
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/22/22 15:48
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/22/22 15:48
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-13
Parameters
Lab ID:
Results
92610492006
Units
Collected:
Report
Limit
06/15/22 16:25
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:48
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 15:48
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/22/22 15:48
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/22/22 15:48
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/22/22 15:48
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/22/22 15:48
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/22/22 15:48
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/22/22 15:48
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/22/22 15:48
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/22/22 15:48
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/22/22 15:48
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/22/22 15:48
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/22/22 15:48
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/22/22 15:48
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 15:48
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 15:48
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/22/22 15:48
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/22/22 15:48
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/22/22 15:48
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/22/22 15:48
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/22/22 15:48
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
91
%
70-130
1
06/22/22 15:48
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
06/22/22 15:48
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
06/22/22 15:48
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-15 Lab ID: 92610492007 Collected: 06/15/22 16:45 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2218:42
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2218:42
7440-38-2
Barium
302
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2218:42
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2218:42
7440-41-7
Cadmium
0.27J
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2218:42
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2218:42
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2218:42
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2218:42
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2218:42
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2218:42
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2218:42
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2218:42
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2218:42
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2218:42
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2218:42
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/22/22 16:07
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/22/22 16:07
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/22/22 16:07
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/22/22 16:07
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/22/22 16:07
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/22/22 16:07
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/22/22 16:07
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/22/22 16:07
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/22/22 16:07
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/22/22 16:07
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/22/22 16:07
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/22/22 16:07
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/22/22 16:07
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/22/22 16:07
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/22/22 16:07
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/22/22 16:07
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/22/22 16:07
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/22/22 16:07
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/22/22 16:07
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/22/22 16:07
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/22/22 16:07
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/22/22 16:07
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 16:07
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/22/22 16:07
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 16:07
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/22/22 16:07
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/22/22 16:07
78-87-5
REPORT OF LABORATORY ANALYSIS
IK
IK
v1
v1
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-15
Parameters
Lab ID:
Results
92610492007
Units
Collected:
Report
Limit
06/15/22 16:45
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 16:07
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/22/22 16:07
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/22/22 16:07
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/22/22 16:07
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/22/22 16:07
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/22/22 16:07
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/22/22 16:07
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/22/22 16:07
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/22/22 16:07
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/22/22 16:07
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/22/22 16:07
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/22/22 16:07
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/22/22 16:07
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/22/22 16:07
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/22/22 16:07
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/22/22 16:07
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/22/22 16:07
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/22/22 16:07
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/22/22 16:07
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/22/22 16:07
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/22/22 16:07
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
92
%
70-130
1
06/22/22 16:07
460-00-4
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
06/22/22 16:07
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/22/22 16:07
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-A Lab ID: 92610492008 Collected: 06/15/22 16:40 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2218:48
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2218:48
7440-38-2
Barium
265
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2218:48
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2218:48
7440-41-7
Cadmium
1.4
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2218:48
7440-43-9
Chromium
1.2.1
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2218:48
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2218:48
7440-48-4
Copper
2.2J
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2218:48
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2218:48
7439-92-1
Nickel
1.0.1
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2218:48
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2218:48
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2218:48
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2218:48
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2218:48
7440-62-2
Zinc
11.1
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2218:48
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 06:55
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 06:55
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 06:55
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 06:55
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 06:55
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 06:55
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 06:55
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 06:55
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 06:55
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 06:55
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 06:55
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 06:55
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 06:55
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 06:55
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 06:55
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 06:55
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 06:55
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 06:55
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 06:55
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 06:55
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 06:55
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 06:55
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:55
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 06:55
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:55
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 06:55
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 06:55
78-87-5
REPORT OF LABORATORY ANALYSIS
v1
L1,v1
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-A
Parameters
Lab ID:
Results
92610492008
Units
Collected:
Report
Limit
06/15/22 16:40
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:55
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:55
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 06:55
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 06:55
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 06:55
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 06:55
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 06:55
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 06:55
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 06:55
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 06:55
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 06:55
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 06:55
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 06:55
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 06:55
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:55
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:55
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 06:55
75-69-4 L1,v1
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 06:55
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 06:55
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 06:55
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 06:55
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
06/23/22 06:55
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
06/23/22 06:55
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 06:55
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-28 Lab ID: 92610492009 Collected: 06/15/22 16:45 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2218:54
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2218:54
7440-38-2
Barium
549
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2218:54
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2218:54
7440-41-7
Cadmium
1.3
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2218:54
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2218:54
7440-47-3
Cobalt
7.6
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2218:54
7440-48-4
Copper
5.6
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2218:54
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2218:54
7439-92-1
Nickel
4.5.1
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2218:54
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2218:54
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2218:54
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2218:54
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2218:54
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2218:54
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 06:22
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 06:22
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 06:22
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 06:22
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 06:22
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 06:22
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 06:22
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 06:22
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 06:22
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 06:22
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 06:22
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 06:22
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 06:22
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 06:22
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 06:22
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 06:22
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 06:22
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 06:22
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 06:22
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 06:22
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 06:22
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 06:22
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:22
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 06:22
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:22
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 06:22
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 06:22
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-28
Parameters
Lab ID:
Results
92610492009
Units
Collected:
Report
Limit
06/15/22 16:45
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:22
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:22
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 06:22
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 06:22
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 06:22
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 06:22
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 06:22
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 06:22
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 06:22
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 06:22
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 06:22
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 06:22
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 06:22
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 06:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:22
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:22
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 06:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 06:22
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 06:22
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 06:22
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 06:22
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
06/23/22 06:22
460-00-4
1,2-Dichloroethane-d4 (S)
114
%
70-130
1
06/23/22 06:22
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 06:22
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-29 Lab ID: 92610492010 Collected: 06/15/22 16:24 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2213:52
06/29/2219:12
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2213:52
06/29/2219:12
7440-38-2
Barium
2080
ug/L
50.0
6.7
10
06/21/2213:52
06/30/2214:07
7440-39-3
Beryllium
0.081J
ug/L
0.50
0.054
1
06/21/2213:52
06/29/2219:12
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/21/2213:52
06/29/2219:12
7440-43-9
Chromium
25.1
ug/L
5.0
1.1
1
06/21/2213:52
06/29/2219:12
7440-47-3
Cobalt
56.6
ug/L
5.0
0.39
1
06/21/2213:52
06/29/2219:12
7440-48-4
Copper
2.6J
ug/L
5.0
1.0
1
06/21/2213:52
06/29/2219:12
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2213:52
06/29/2219:12
7439-92-1
Nickel
22.9
ug/L
5.0
0.71
1
06/21/2213:52
06/29/2219:12
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2213:52
06/29/2219:12
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2213:52
06/29/2219:12
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2213:52
06/29/2219:12
7440-28-0
Vanadium
5.3.1
ug/L
10.0
1.9
1
06/21/2213:52
06/29/2219:12
7440-62-2
Zinc
17.3
ug/L
10.0
7.0
1
06/21/2213:52
06/29/2219:12
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 06:40
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 06:40
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 06:40
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 06:40
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 06:40
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 06:40
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 06:40
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 06:40
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 06:40
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 06:40
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 06:40
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 06:40
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 06:40
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 06:40
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 06:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 06:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 06:40
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 06:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 06:40
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 06:40
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 06:40
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 06:40
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:40
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 06:40
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:40
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 06:40
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 06:40
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-29
Parameters
Lab ID:
Results
92610492010
Units
Collected:
Report
Limit
06/15/22 16:24
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:40
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:40
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 06:40
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 06:40
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 06:40
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 06:40
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 06:40
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 06:40
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 06:40
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 06:40
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 06:40
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 06:40
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 06:40
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 06:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:40
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 06:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 06:40
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 06:40
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 06:40
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 06:40
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
06/23/22 06:40
460-00-4
1,2-Dichloroethane-d4 (S)
114
%
70-130
1
06/23/22 06:40
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
06/23/22 06:40
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-30 Lab ID: 92610492011 Collected: 06/15/22 16:19 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2219:18
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2219:18
7440-38-2
Barium
291
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2219:18
7440-39-3
Beryllium
0.086.11
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2219:18
7440-41-7
Cadmium
0.24.11
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2219:18
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2219:18
7440-47-3
Cobalt
5.7
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2219:18
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2219:18
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2219:18
7439-92-1
Nickel
2.7.1
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2219:18
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2219:18
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2219:18
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2219:18
7440-28-0
Vanadium
10.2
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2219:18
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2219:18
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 06:59
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 06:59
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 06:59
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 06:59
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 06:59
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 06:59
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 06:59
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 06:59
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 06:59
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 06:59
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 06:59
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 06:59
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 06:59
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 06:59
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 06:59
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 06:59
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 06:59
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 06:59
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 06:59
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 06:59
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 06:59
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 06:59
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:59
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 06:59
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:59
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 06:59
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 06:59
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-30
Parameters
Lab ID:
Results
92610492011
Units
Collected:
Report
Limit
06/15/22 16:19
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:59
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 06:59
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 06:59
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 06:59
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 06:59
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 06:59
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 06:59
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 06:59
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 06:59
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 06:59
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 06:59
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 06:59
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 06:59
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 06:59
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 06:59
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 06:59
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 06:59
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 06:59
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 06:59
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 06:59
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 06:59
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
06/23/22 06:59
460-00-4
1,2-Dichloroethane-d4 (S)
113
%
70-130
1
06/23/22 06:59
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 06:59
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 30 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-UDP Lab ID: 92610492012 Collected: 06/15/22 16:50 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2219:24
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2219:24
7440-38-2
Barium
142
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2219:24
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2219:24
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2219:24
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2219:24
7440-47-3
Cobalt
2.7.1
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2219:24
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2219:24
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2219:24
7439-92-1
Nickel
1.2.1
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2219:24
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2219:24
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2219:24
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2219:24
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2219:24
7440-62-2
Zinc
18.6
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2219:24
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 07:17
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 07:17
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 07:17
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 07:17
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 07:17
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 07:17
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 07:17
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 07:17
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 07:17
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 07:17
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 07:17
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 07:17
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 07:17
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 07:17
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 07:17
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 07:17
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 07:17
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 07:17
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 07:17
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 07:17
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 07:17
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 07:17
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 07:17
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 07:17
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 07:17
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 07:17
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 07:17
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: MW-UDP
Parameters
Lab ID:
Results
92610492012
Units
Collected:
Report
Limit
06/15/22 16:50
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 07:17
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 07:17
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 07:17
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 07:17
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 07:17
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 07:17
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 07:17
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 07:17
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 07:17
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 07:17
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 07:17
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 07:17
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 07:17
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 07:17
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 07:17
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 07:17
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 07:17
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 07:17
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 07:17
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 07:17
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 07:17
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
06/23/22 07:17
460-00-4
1,2-Dichloroethane-d4 (S)
114
%
70-130
1
06/23/22 07:17
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
06/23/22 07:17
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 32 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW -A Lab ID: 92610492013 Collected: 06/15/22 16:40 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2219:30
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2219:30
7440-38-2
Barium
139
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2219:30
7440-39-3
Beryllium
0.056J
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2219:30
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2219:30
7440-43-9
Chromium
1.2.1
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2219:30
7440-47-3
Cobalt
1.5.1
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2219:30
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2219:30
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2219:30
7439-92-1
Nickel
0.83J
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2219:30
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2219:30
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2219:30
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2219:30
7440-28-0
Vanadium
2.7.1
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2219:30
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2219:30
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 07:35
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 07:35
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 07:35
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 07:35
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 07:35
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 07:35
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 07:35
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 07:35
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 07:35
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 07:35
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 07:35
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 07:35
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 07:35
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 07:35
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 07:35
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 07:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 07:35
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 07:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 07:35
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 07:35
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 07:35
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 07:35
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 07:35
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 07:35
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 07:35
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 07:35
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 07:35
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: SW -A
Parameters
Lab ID:
Results
92610492013
Units
Collected:
Report
Limit
06/15/22 16:40
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 07:35
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 07:35
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 07:35
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 07:35
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 07:35
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 07:35
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 07:35
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 07:35
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 07:35
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 07:35
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 07:35
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 07:35
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 07:35
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 07:35
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 07:35
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 07:35
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 07:35
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 07:35
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 07:35
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 07:35
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 07:35
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
103
%
70-130
1
06/23/22 07:35
460-00-4
1,2-Dichloroethane-d4 (S)
114
%
70-130
1
06/23/22 07:35
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 07:35
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 34 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: WSW-2 Lab ID: 92610492014 Collected: 06/16/22 17:01 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2219:36
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2219:36
7440-38-2
Barium
166
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2219:36
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2219:36
7440-41-7
Cadmium
0.16J
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2219:36
7440-43-9
Chromium
3.1J
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2219:36
7440-47-3
Cobalt
0.591
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2219:36
7440-48-4
Copper
229
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2219:36
7440-50-8
Lead
24.4
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2219:36
7439-92-1
Nickel
3.6J
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2219:36
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2219:36
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2219:36
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2219:36
7440-28-0
Vanadium
3.2.1
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2219:36
7440-62-2
Zinc
284
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2219:36
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 12:48
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 12:48
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 12:48
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 12:48
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 12:48
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 12:48
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 12:48
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 12:48
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 12:48
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 12:48
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 12:48
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 12:48
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 12:48
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 12:48
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 12:48
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 12:48
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 12:48
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 12:48
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 12:48
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 12:48
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 12:48
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 12:48
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 12:48
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 12:48
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 12:48
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 12:48
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 12:48
78-87-5
REPORT OF LABORATORY ANALYSIS
v2
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
Sample: WSW-2
Parameters
Lab ID:
Results
92610492014
Units
Collected:
Report
Limit
06/16/22 17:01
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 12:48
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
06/23/22 12:48
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
06/23/22 12:48
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
06/23/22 12:48
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
06/23/22 12:48
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
06/23/22 12:48
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
06/23/22 12:48
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
06/23/22 12:48
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
06/23/22 12:48
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
06/23/22 12:48
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
06/23/22 12:48
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
06/23/22 12:48
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
06/23/22 12:48
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
06/23/22 12:48
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 12:48
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 12:48
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
06/23/22 12:48
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
06/23/22 12:48
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
06/23/22 12:48
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39
1
06/23/22 12:48
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
06/23/22 12:48
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
06/23/22 12:48
460-00-4
1,2-Dichloroethane-d4 (S)
116
%
70-130
1
06/23/22 12:48
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 12:48
2037-26-5
Date: 07/02/2022 01:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 1882062 Analysis Method: EPA 8151
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151
Laboratory: Pace National - Mt. Juliet
Associated Lab Samples: 92610492001
METHOD BLANK: R3806324-1
Matrix:
Water
Associated Lab Samples: 92610492001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
2,4-D
ug/L
ND
2.00
0.547
06/22/22 13:48
2,4,5-T
ug/L
ND
2.00
0.258
06/22/22 13:48
2,4,5-TP (Silvex)
ug/L
ND
2.00
0.335
06/22/22 13:48
Dinoseb
ug/L
ND
2.00
0.250
06/22/22 13:48
2,4-DCAA (S)
%
96.6
14.0-158
06/22/22 13:48
LABORATORY CONTROL SAMPLE:
R3806324-2
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
2,4-D
ug/L
5.00
6.30
126
50.0-120 E,LO
2,4,5-T
ug/L
5.00
6.13
123
54.0-120 E,L0,P9
2,4,5-TP (Silvex)
ug/L
5.00
8.03
161
50.0-125 E,L0,P9
Dinoseb
ug/L
5.00
4.53
90.6
36.0-134
2,4-DCAA (S)
%
109
14.0-158
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: R3806324-3
R3806324-4
MS
MSD
L1506162-33
Spike
Spike
MS
MSD
MS
MSD % Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec Limits
RPD
RPD Qual
2,4-D
ug/L
ND
5.25
5.55
6.12
6.08
117
110 50.0-120
0.656
20 E
2,4,5-T
ug/L
ND
5.25
5.55
5.88
5.62
112
101 54.0-120
4.52
20 E
2,4,5-TP (Silvex)
ug/L
ND
5.25
5.55
6.44
6.36
123
115 50.0-125
1.25
20 E
Dinoseb
ug/L
ND
5.25
5.55
4.36
4.36
83.0
78.6 36.0-134
0.00
20
2,4-DCAA (S)
%
98.9
87.9 14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 37 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705851 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610492003, 92610492004, 92610492005, 92610492006
METHOD BLANK: 3682656 Matrix: Water
Associated Lab Samples: 92610492003, 92610492004, 92610492005, 92610492006
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
3.0
Arsenic
ug/L
ND
5.0
Barium
ug/L
ND
5.0
Beryllium
ug/L
ND
0.50
Cadmium
ug/L
ND
0.50
Chromium
ug/L
ND
5.0
Cobalt
ug/L
ND
5.0
Copper
ug/L
ND
5.0
Lead
ug/L
ND
1.0
Nickel
ug/L
ND
5.0
Selenium
ug/L
ND
5.0
Silver
ug/L
ND
5.0
Thallium
ug/L
ND
1.0
Vanadium
ug/L
ND
10.0
Zinc
ug/L
ND
10.0
MDL Analyzed
0.78
06/28/22 15:46
2.2
06/28/22 15:46
0.67
06/28/22 15:46
0.054
06/28/22 15:46
0.11
06/28/22 15:46
1.1
06/28/22 15:46
0.39
06/28/22 15:46
1.0
06/28/22 15:46
0.89
06/28/22 15:46
0.71
06/28/22 15:46
1.4
06/28/22 15:46
0.44
06/28/22 15:46
0.18
06/28/22 15:46
1.9
06/28/22 15:46
7.0
06/28/22 15:46
LABORATORY CONTROL SAMPLE:
Parameter
3682657
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
101
101
80-120
Arsenic
ug/L
100
96.8
97
80-120
Barium
ug/L
100
95.9
96
80-120
Beryllium
ug/L
100
95.9
96
80-120
Cadmium
ug/L
100
101
101
80-120
Chromium
ug/L
100
98.2
98
80-120
Cobalt
ug/L
100
95.3
95
80-120
Copper
ug/L
100
98.2
98
80-120
Lead
ug/L
100
97.0
97
80-120
Nickel
ug/L
100
97.6
98
80-120
Selenium
ug/L
100
96.3
96
80-120
Silver
ug/L
100
98.2
98
80-120
Thallium
ug/L
100
97.1
97
80-120
Vanadium
ug/L
100
100
100
80-120
Zinc
ug/L
100
101
101
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO LINED MSWLF
92610492
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3682658
3682659
MS
MSD
92610659002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
99.7
98.6
100
98
75-125
1
20
Arsenic
ug/L
6.9
100
100
106
104
99
97
75-125
2
20
Barium
ug/L
108
100
100
204
209
96
101
75-125
3
20
Beryllium
ug/L
0.21J
100
100
101
100
100
100
75-125
0
20
Cadmium
ug/L
ND
100
100
101
100
101
100
75-125
1
20
Chromium
ug/L
2AJ
100
100
111
111
108
108
75-125
0
20
Cobalt
ug/L
3.5J
100
100
105
108
101
104
75-125
3
20
Copper
ug/L
ND
100
100
102
102
101
101
75-125
0
20
Lead
ug/L
1.5
100
100
98.0
98.4
97
97
75-125
0
20
Nickel
ug/L
2.6J
100
100
105
109
102
106
75-125
3
20
Selenium
ug/L
ND
100
100
94.2
93.8
93
93
75-125
0
20
Silver
ug/L
ND
100
100
96.6
96.6
97
97
75-125
0
20
Thallium
ug/L
ND
100
100
97.4
96.5
97
96
75-125
1
20
Vanadium
ug/L
41.6
100
100
153
157
112
115
75-125
2
20
Zinc
ug/L
8.5J
100
100
109
111
101
102
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705856 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610492007,92610492008,92610492009,92610492010,92610492011,92610492012,92610492013,
92610492014
METHOD BLANK: 3682687 Matrix: Water
Associated Lab Samples: 92610492007,92610492008,92610492009,92610492010,92610492011,92610492012,92610492013,
92610492014
Parameter
Units
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Cadmium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Lead
ug/L
Nickel
ug/L
Selenium
ug/L
Silver
ug/L
Thallium
ug/L
Vanadium
ug/L
Zinc
ug/L
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
3.0
0.78
06/29/22 16:41
ND
5.0
2.2
06/29/22 16:41
ND
5.0
0.67
06/29/22 16:41
ND
0.50
0.054
06/29/22 16:41
ND
0.50
0.11
06/29/22 16:41
ND
5.0
1.1
06/29/22 16:41
ND
5.0
0.39
06/29/22 16:41
ND
5.0
1.0
06/29/22 16:41
ND
1.0
0.89
06/29/22 16:41
ND
5.0
0.71
06/29/22 16:41
ND
5.0
1.4
06/29/22 16:41
ND
5.0
0.44
06/29/22 16:41
ND
1.0
0.18
06/29/22 16:41
ND
10.0
1.9
06/29/22 16:41
ND
10.0
7.0
06/29/22 16:41
LABORATORY CONTROL SAMPLE:
Parameter
3682688
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
106
106
80-120
Arsenic
ug/L
100
99.3
99
80-120
Barium
ug/L
100
102
102
80-120
Beryllium
ug/L
100
101
101
80-120
Cadmium
ug/L
100
101
101
80-120
Chromium
ug/L
100
98.9
99
80-120
Cobalt
ug/L
100
96.6
97
80-120
Copper
ug/L
100
96.6
97
80-120
Lead
ug/L
100
100
100
80-120
Nickel
ug/L
100
98.6
99
80-120
Selenium
ug/L
100
99.3
99
80-120
Silver
ug/L
100
101
101
80-120
Thallium
ug/L
100
98.5
98
80-120
Vanadium
ug/L
100
98.1
98
80-120
Zinc
ug/L
100
101
101
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO LINED MSWLF
92610492
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3682689
3682690
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
108
104
108
104
75-125
4
20
Arsenic
ug/L
ND
100
100
101
98.2
101
98
75-125
3
20
Barium
ug/L
515
100
100
594
572
79
57
75-125
4
20 M1
Beryllium
ug/L
ND
100
100
99.3
94.9
99
95
75-125
5
20
Cadmium
ug/L
ND
100
100
103
101
103
101
75-125
2
20
Chromium
ug/L
2.8J
100
100
104
98.0
102
95
75-125
6
20
Cobalt
ug/L
20.9
100
100
118
111
97
90
75-125
6
20
Copper
ug/L
ND
100
100
98.2
92.1
98
92
75-125
6
20
Lead
ug/L
ND
100
100
99.8
97.1
100
97
75-125
3
20
Nickel
ug/L
7.7
100
100
107
100
99
93
75-125
6
20
Selenium
ug/L
ND
100
100
101
97.7
100
98
75-125
3
20
Silver
ug/L
ND
100
100
96.5
95.0
96
95
75-125
2
20
Thallium
ug/L
ND
100
100
100
97.7
100
98
75-125
2
20
Vanadium
ug/L
ND
100
100
104
98.3
104
98
75-125
6
20
Zinc
ug/L
ND
100
100
103
97.2
101
96
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 41 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706160 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610492001
METHOD BLANK: 3684049
Associated Lab Samples: 92610492001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
3.0
0.78
06/25/2216:37
Arsenic
ug/L
ND
5.0
2.2
06/25/2216:37
Barium
ug/L
ND
5.0
0.67
06/25/2216:37
Beryllium
ug/L
ND
0.50
0.054
06/25/2216:37
Cadmium
ug/L
ND
0.50
0.11
06/25/2216:37
Chromium
ug/L
ND
5.0
1.1
06/27/2213:19
Cobalt
ug/L
ND
5.0
0.39
06/25/2216:37
Copper
ug/L
ND
5.0
1.0
06/25/2216:37
Lead
ug/L
ND
1.0
0.89
06/25/2216:37
Nickel
ug/L
ND
5.0
0.71
06/27/2213:19
Selenium
ug/L
ND
5.0
1.4
06/25/2216:37
Silver
ug/L
ND
5.0
0.44
06/25/2216:37
Thallium
ug/L
ND
1.0
0.18
06/25/2216:37
Vanadium
ug/L
ND
10.0
1.9
06/25/2216:37
Zinc
ug/L
ND
10.0
7.0
06/25/2216:37
LABORATORY CONTROL SAMPLE:
Parameter
3684050
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
108
108
80-120
Arsenic
ug/L
100
101
101
80-120
Barium
ug/L
100
101
101
80-120
Beryllium
ug/L
100
103
103
80-120
Cadmium
ug/L
100
98.5
98
80-120
Chromium
ug/L
100
106
106
80-120
Cobalt
ug/L
100
98.3
98
80-120
Copper
ug/L
100
97.1
97
80-120
Lead
ug/L
100
98.4
98
80-120
Nickel
ug/L
100
103
103
80-120
Selenium
ug/L
100
101
101
80-120
Silver
ug/L
100
100
100
80-120
Thallium
ug/L
100
99.0
99
80-120
Vanadium
ug/L
100
105
105
80-120
Zinc
ug/L
100
97.9
98
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO LINED MSWLF
92610492
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3684383
3684384
MS
MSD
92607724001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
101
105
101
104
75-125
3
20
Arsenic
ug/L
ND
100
100
102
102
99
100
75-125
1
20
Barium
ug/L
136
100
100
237
239
101
103
75-125
1
20
Beryllium
ug/L
ND
100
100
93.2
93.8
93
93
75-125
1
20
Cadmium
ug/L
ND
100
100
99.1
99.8
99
100
75-125
1
20
Chromium
ug/L
9.8
100
100
112
113
102
103
75-125
1
20
Cobalt
ug/L
11.7
100
100
115
112
103
101
75-125
2
20
Copper
ug/L
399
100
100
505
509
107
111
75-125
1
20
Lead
ug/L
ND
100
100
107
108
97
99
75-125
1
20
Nickel
ug/L
7.5
100
100
108
107
100
99
75-125
1
20
Selenium
ug/L
ND
100
100
100
102
99
101
75-125
2
20
Silver
ug/L
ND
100
100
99.2
101
99
100
75-125
1
20
Thallium
ug/L
0.191
100
100
97.1
99.2
97
99
75-125
2
20
Vanadium
ug/L
31.4
100
100
140
140
108
109
75-125
0
20
Zinc
ug/L
35.3
100
100
143
141
107
106
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 707951 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610492001
METHOD BLANK: 3692218
Matrix:
Water
Associated Lab Samples: 92610492001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Mercury
ug/L
ND
0.20
0.12 07/01/2210:02
LABORATORY CONTROL SAMPLE:
3692219
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.6 104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3692220 3692221
MS MSD
92610492001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.5 2.5 97 97 75-125 0 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705509 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492001
METHOD BLANK: 3681218
Associated Lab Samples: 92610492001
Parameter Units
1,1,1,2-Tetrachloroethane
ug/L
1,1,1-Trichloroethane
ug/L
1,1,2,2-Tetrachloroethane
ug/L
1,1,2-Trichloroethane
ug/L
1,1-Dichloroethane
ug/L
1,1-Dichloroethene
ug/L
1,1-Dichloropropene
ug/L
1,2,3-Trichlorobenzene
ug/L
1,2,3-Trichloropropane
ug/L
1,2,4-Trichlorobenzene
ug/L
1,2-Dichlorobenzene
ug/L
1,2-Dichloroethane
ug/L
1,2-Dichloropropane
ug/L
1,3-Dichloropropane
ug/L
1,4-Dichlorobenzene
ug/L
2,2-Dichloropropane
ug/L
2-Butanone (MEK)
ug/L
2-Hexanone
ug/L
4-Methyl-2-pentanone (MIBK)
ug/L
Acetone
ug/L
Acetonitrile
ug/L
Acrolein
ug/L
Acrylonitrile
ug/L
Allyl chloride
ug/L
Benzene
ug/L
Bromochloromethane
ug/L
Bromodichloromethane
ug/L
Bromoform
ug/L
Bromomethane
ug/L
Carbon disulfide
ug/L
Carbon tetrachloride
ug/L
Chlorobenzene
ug/L
Chloroethane
ug/L
Chloroform
ug/L
Chloromethane
ug/L
Chloroprene
ug/L
cis-1,2-Dichloroethene
ug/L
cis-1,3-Dichloropropene
ug/L
Dibromochloromethane
ug/L
Dibromomethane
ug/L
Matrix: Water
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
1.0
0.31
06/20/22 16:33
ND
1.0
0.33
06/20/22 16:33
ND
1.0
0.22
06/20/22 16:33
ND
1.0
0.32
06/20/22 16:33
ND
1.0
0.37
06/20/22 16:33
ND
1.0
0.35
06/20/22 16:33
ND
1.0
0.43
06/20/22 16:33
ND
1.0
0.81
06/20/22 16:33
ND
1.0
0.26
06/20/22 16:33
ND
1.0
0.64
06/20/22 16:33
ND
1.0
0.34
06/20/22 16:33
ND
1.0
0.32
06/20/22 16:33
ND
1.0
0.36
06/20/22 16:33
ND
1.0
0.28
06/20/22 16:33
ND
1.0
0.33
06/20/22 16:33
ND
1.0
0.39
06/20/22 16:33
ND
5.0
4.0
06/20/22 16:33
ND
5.0
0.48
06/20/22 16:33
ND
5.0
2.7
06/20/22 16:33
ND
25.0
5.1
06/20/22 16:33
ND
50.0
24.8
06/20/22 16:33
ND
10.0
8.5
06/20/22 16:33
ND
10.0
1.8
06/20/22 16:33
ND
2.0
0.50
06/20/22 16:33
ND
1.0
0.34
06/20/22 16:33
ND
1.0
0.47
06/20/22 16:33
ND
1.0
0.31
06/20/22 16:33
ND
1.0
0.34
06/20/22 16:33 IK,v1
ND
2.0
1.7
06/20/22 16:33
ND
2.0
0.36
06/20/22 16:33
ND
1.0
0.33
06/20/22 16:33
ND
1.0
0.28
06/20/22 16:33
ND
1.0
0.65
06/20/22 16:33
ND
1.0
0.43
06/20/22 16:33
ND
1.0
0.54
06/20/22 16:33
ND
5.0
1.6
06/20/22 16:33
ND
1.0
0.38
06/20/22 16:33
ND
1.0
0.36
06/20/22 16:33
ND
1.0
0.36
06/20/22 16:33 v1
ND
1.0
0.39
06/20/22 16:33
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 45 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3681218
Associated Lab Samples: 92610492001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Dichlorodifluoromethane
ug/L
ND
1.0
0.35
06/20/22 16:33
Ethyl methacrylate
ug/L
ND
1.0
0.28
06/20/22 16:33
Ethylbenzene
ug/L
ND
1.0
0.30
06/20/22 16:33
Hexachloro-1,3-butadiene
ug/L
ND
2.0
1.5
06/20/22 16:33
lodomethane
ug/L
ND
20.0
9.7
06/20/22 16:33
Isobutanol
ug/L
ND
100
52.3
06/20/22 16:33
Methacrylonitrile
ug/L
ND
10.0
4.2
06/20/22 16:33
Methyl methacrylate
ug/L
ND
2.0
0.32
06/20/22 16:33
Methylene Chloride
ug/L
ND
5.0
2.0
06/20/22 16:33
Naphthalene
ug/L
ND
1.0
0.64
06/20/22 16:33
Propionitrile
ug/L
ND
20.0
3.6
06/20/22 16:33
Styrene
ug/L
ND
1.0
0.29
06/20/22 16:33
Tetrachloroethene
ug/L
ND
1.0
0.29
06/20/22 16:33
Toluene
ug/L
ND
1.0
0.48
06/20/22 16:33
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/20/22 16:33
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/20/22 16:33
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/20/22 16:33
Trichloroethene
ug/L
ND
1.0
0.38
06/20/22 16:33
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/20/22 16:33
Vinyl acetate
ug/L
ND
2.0
1.3
06/20/22 16:33
Vinyl chloride
ug/L
ND
1.0
0.39
06/20/22 16:33
Xylene (Total)
ug/L
ND
1.0
0.34
06/20/22 16:33
1,2-Dichloroethane-d4 (S)
%
104
70-130
06/20/22 16:33
4-Bromofluorobenzene (S)
%
112
70-130
06/20/22 16:33
Toluene-d8 (S)
%
101
70-130
06/20/22 16:33
LABORATORY CONTROL SAMPLE:
Parameter
3681219
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
56.5
113
70-130
1,1,1-Trichloroethane
ug/L
50
52.0
104
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
52.2
104
70-130
1,1,2-Trichloroethane
ug/L
50
49.7
99
70-130
1,1-Dichloroethane
ug/L
50
49.9
100
70-130
1,1-Dichloroethene
ug/L
50
50.3
101
70-132
1,1-Dichloropropene
ug/L
50
54.5
109
70-131
1,2,3-Trichlorobenzene
ug/L
50
52.0
104
70-134
1,2,3-Trichloropropane
ug/L
50
51.7
103
70-130
1,2,4-Trichlorobenzene
ug/L
50
50.4
101
70-130
1,2-Dichlorobenzene
ug/L
50
51.9
104
70-130
1,2-Dichloroethane
ug/L
50
50.6
101
70-130
1,2-Dichloropropane
ug/L
50
51.6
103
70-130
1,3-Dichloropropane
ug/L
50
46.4
93
70-130
1,4-Dichlorobenzene
ug/L
50
51.9
104
70-130
Qualifiers
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE: 3681219
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,2-Dichloropropane
ug/L
50
63.6
127
70-130
2-Butanone (MEK)
ug/L
100
114
114
70-133
2-Hexanone
ug/L
100
109
109
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
105
105
70-130
Acetone
ug/L
100
110
110
70-144
Acetonitrile
ug/L
500
529
106
68-134
Acrolein
ug/L
250
364
146
32-200
Acrylonitrile
ug/L
250
273
109
70-130
Allyl chloride
ug/L
50
56.7
113
70-134
Benzene
ug/L
50
49.6
99
70-130
Bromochloromethane
ug/L
50
51.5
103
70-130
Bromodichloromethane
ug/L
50
54.5
109
70-130
Bromoform
ug/L
50
79.7
159
70-131 IK,L1,v1
Bromomethane
ug/L
50
51.9
104
30-177
Carbon disulfide
ug/L
50
55.3
111
70-133
Carbon tetrachloride
ug/L
50
54.2
108
70-130
Chlorobenzene
ug/L
50
53.9
108
70-130
Chloroethane
ug/L
50
53.5
107
46-131
Chloroform
ug/L
50
50.5
101
70-130
Chloromethane
ug/L
50
56.7
113
49-130
Chloroprene
ug/L
50
54.5
109
70-130
cis-1,2-Dichloroethene
ug/L
50
51.0
102
70-130
cis-1,3-Dichloropropene
ug/L
50
59.2
118
70-130
Dibromochloromethane
ug/L
50
57.4
115
70-130 v1
Dibromomethane
ug/L
50
53.0
106
70-130
Dichlorodifluoromethane
ug/L
50
50.6
101
52-134
Ethyl methacrylate
ug/L
50
48.1
96
70-130
Ethylbenzene
ug/L
50
53.4
107
70-130
Hexachloro-1,3-butadiene
ug/L
50
51.3
103
70-131
lodomethane
ug/L
100
113
113
47-140
Isobutanol
ug/L
1000
1220
122
62-136 v1
Methacrylonitrile
ug/L
500
549
110
70-130
Methyl methacrylate
ug/L
50
53.8
108
70-130
Methylene Chloride
ug/L
50
51.7
103
68-130
Naphthalene
ug/L
50
53.4
107
70-133
Propionitrile
ug/L
500
554
111
70-130
Styrene
ug/L
50
53.6
107
70-130
Tetrachloroethene
ug/L
50
45.5
91
70-130
Toluene
ug/L
50
48.3
97
70-130
trans-1,2-Dichloroethene
ug/L
50
50.7
101
70-130
trans- 1,3-Dichloropropene
ug/L
50
55.9
112
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
78.4
157
25-200 v1
Trichloroethene
ug/L
50
52.0
104
70-130
Trichlorofluoromethane
ug/L
50
50.3
101
61-130
Vinyl acetate
ug/L
100
112
112
70-140
Vinyl chloride
ug/L
50
52.6
105
59-142
Xylene (Total)
ug/L
150
158
105
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
3681219
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
1,2-Dichloroethane-d4 (S)
%
94
70-130
4-Bromofluorobenzene (S)
%
103
70-130
Toluene-d8 (S)
%
96
70-130
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3681220
3681221
MS
MSD
92610492002
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.9
23.5
119
118
70-135
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
25.2
25.1
126
125
70-148
1
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
22.6
22.5
113
112
70-131
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
23.1
22.9
115
115
70-136
1
30
1,1-Dichloroethane
ug/L
ND
20
20
25.4
25.3
127
126
70-147
0
30
1,1-Dichloroethene
ug/L
ND
20
20
26.0
25.9
130
129
70-158
0
30
1,1-Dichloropropene
ug/L
ND
20
20
26.5
26.3
132
131
70-149
1
30
1,2,3-Trichlorobenzene
ug/L
ND
20
20
21.6
21.5
108
107
68-140
1
30
1,2,3-Trichooropropane
ug/L
ND
20
20
22.3
22.2
111
111
67-137
0
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
22.0
21.8
110
109
70-139
1
30
1,2-Dichlorobenzene
ug/L
ND
20
20
22.6
22.4
113
112
70-133
1
30
1,2-Dichloroethane
ug/L
ND
20
20
24.6
24.4
123
122
67-138
1
30
1,2-Dichloropropane
ug/L
ND
20
20
24.5
24.3
123
122
70-138
1
30
1,3-Dichloropropane
ug/L
ND
20
20
23.7
23.4
118
117
70-136
1
30
1,4-Dichlorobenzene
ug/L
0.35J
20
20
22.5
22.3
111
110
70-133
1
30
2,2-Dichloropropane
ug/L
ND
20
20
25.0
24.6
125
123
52-155
2
30
2-Butanone (MEK)
ug/L
ND
40
40
54.7
54.8
137
137
61-147
0
30
2-Hexanone
ug/L
ND
40
40
47.5
48.0
119
120
67-139
1
30
4- Methyl -2-pentanone
ug/L
ND
40
40
44.7
45.7
112
114
67-136
2
30
(MIBK)
Acetone
ug/L
ND
40
40
53.2
53.8
133
135
55-159
1
30
Acetonitrile
ug/L
ND
200
200
265
266
133
133
66-145
0
30
Acrolein
ug/L
ND
100
100
129
130
129
130
10-200
1
30
Acrylonitrile
ug/L
ND
100
100
126
127
126
127
68-140
1
30
Allyl chloride
ug/L
ND
20
20
28.2
28.0
141
140
70-147
1
30
Benzene
ug/L
0.77J
20
20
24.0
23.9
116
116
67-150
0
30
Bromochloromethane
ug/L
ND
20
20
25.1
24.9
126
125
70-146
1
30
Bromodichloromethane
ug/L
ND
20
20
23.3
23.3
117
117
70-138
0
30
Bromoform
ug/L
ND
20
20
22.8
22.8
114
114
57-138
0
30
Bromomethane
ug/L
ND
20
20
19.7
19.5
98
98
10-200
1
30 v3
Carbon disulfide
ug/L
ND
20
20
25.6
25.2
128
126
70-152
2
30
Carbon tetrachloride
ug/L
ND
20
20
23.8
23.8
119
119
70-147
0
30
Chlorobenzene
ug/L
ND
20
20
23.5
23.1
117
116
70-137
2
30
Chloroethane
ug/L
ND
20
20
26.5
26.1
132
130
51-166
1
30
Chloroform
ug/L
ND
20
20
25.2
25.3
126
127
70-144
1
30
Chloromethane
ug/L
ND
20
20
26.2
25.9
131
129
24-161
1
30
Chloroprene
ug/L
ND
20
20
26.8
26.6
134
133
70-143
1
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 48 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3681220
MS
92610492002 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3681221
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
cis-1,2-Dichloroethene
ug/L
1.7
20
20
27.4
26.9
128
126
67-148
2
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
23.6
23.8
118
119
70-142
1
30
Dibromochloromethane
ug/L
ND
20
20
23.1
23.0
116
115
68-138
0
30
Dibromomethane
ug/L
ND
20
20
22.4
22.3
112
111
70-134
0
30
Dichlorodifluoromethane
ug/L
ND
20
20
29.7
29.6
149
148
43-155
0
30
Ethyl methacrylate
ug/L
ND
20
20
23.8
23.6
119
118
70-137
1
30
Ethylbenzene
ug/L
ND
20
20
23.8
23.5
119
118
68-143
1
30
Hexachloro-1,3-butadiene
ug/L
ND
20
20
22.2
22.1
111
111
62-151
0
30
lodomethane
ug/L
ND
40
40
50.7
48.4
127
121
20-161
5
30
Isobutanol
ug/L
ND
400
400
471
483
118
121
44-145
3
30
Methacrylonitrile
ug/L
ND
200
200
239
241
120
120
67-139
1
30
Methyl methacrylate
ug/L
ND
20
20
23.6
23.9
118
120
70-130
1
30
Methylene Chloride
ug/L
ND
20
20
22.5
22.3
112
112
64-148
1
30
Naphthalene
ug/L
ND
20
20
24.1
23.3
121
116
57-150
4
30
Propionitrile
ug/L
ND
200
200
240
244
120
122
70-138
2
30
Styrene
ug/L
ND
20
20
22.6
22.3
113
112
70-136
1
30
Tetrachloroethene
ug/L
ND
20
20
22.2
21.9
111
109
70-139
2
30
Toluene
ug/L
ND
20
20
21.8
22.1
109
110
47-157
1
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
26.3
26.0
131
130
70-149
1
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
23.9
23.6
119
118
70-138
1
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
22.1
19.4
110
97
31-145
13
30
Trichloroethene
ug/L
ND
20
20
23.6
23.7
118
119
70-149
1
30
Trichlorofluoromethane
ug/L
ND
20
20
23.4
23.2
117
116
61-154
1
30
Vinyl acetate
ug/L
ND
40
40
49.2
48.3
123
121
48-156
2
30
Vinyl chloride
ug/L
ND
20
20
27.9
27.5
139
138
55-172
1
30
Xylene (Total)
ug/L
ND
60
60
71.7
70.7
119
118
66-145
1
30
1,2-Dichloroethane-d4 (S)
%
108
107
70-130
4-Bromofluorobenzene (S)
%
103
103
70-130
Toluene-d8 (S)
%
99
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 49 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705835 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492003, 92610492004, 92610492005, 92610492006, 92610492007
METHOD BLANK: 3682556 Matrix: Water
Associated Lab Samples: 92610492003, 92610492004, 92610492005, 92610492006, 92610492007
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/22/22 10:21
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/22/22 10:21
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/22/22 10:21
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/22/22 10:21
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/22/22 10:21
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/22/22 10:21
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/22/22 10:21
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/22/22 10:21
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/22/22 10:21
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/22/22 10:21
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/22/22 10:21
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/22/22 10:21
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/22/22 10:21
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/22/22 10:21
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/22/22 10:21
2-Hexanone
ug/L
ND
5.0
0.48
06/22/22 10:21
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/22/22 10:21
Acetone
ug/L
ND
25.0
5.1
06/22/22 10:21
Acrylonitrile
ug/L
ND
10.0
1.8
06/22/22 10:21
Benzene
ug/L
ND
1.0
0.34
06/22/22 10:21
Bromochloromethane
ug/L
ND
1.0
0.47
06/22/22 10:21
Bromodichloromethane
ug/L
ND
1.0
0.31
06/22/22 10:21
Bromoform
ug/L
ND
1.0
0.34
06/22/22 10:21
Bromomethane
ug/L
ND
2.0
1.7
06/22/22 10:21
Carbon disulfide
ug/L
ND
2.0
0.36
06/22/22 10:21
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/22/22 10:21
Chlorobenzene
ug/L
ND
1.0
0.28
06/22/22 10:21
Chloroethane
ug/L
ND
1.0
0.65
06/22/22 10:21
Chloroform
ug/L
ND
1.0
0.43
06/22/22 10:21
Chloromethane
ug/L
ND
1.0
0.54
06/22/22 10:21
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/22/22 10:21
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/22/22 10:21
Dibromochloromethane
ug/L
ND
1.0
0.36
06/22/22 10:21
Dibromomethane
ug/L
ND
1.0
0.39
06/22/22 10:21
Ethylbenzene
ug/L
ND
1.0
0.30
06/22/22 10:21
lodomethane
ug/L
ND
20.0
9.7
06/22/22 10:21
Methylene Chloride
ug/L
ND
5.0
2.0
06/22/22 10:21
Styrene
ug/L
ND
1.0
0.29
06/22/22 10:21
Tetrachloroethene
ug/L
ND
1.0
0.29
06/22/22 10:21
Toluene
ug/L
ND
1.0
0.48
06/22/22 10:21
IK
IK
v1
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3682556 Matrix: Water
Associated Lab Samples: 92610492003, 92610492004, 92610492005, 92610492006, 92610492007
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/22/22 10:21
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/22/22 10:21
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/22/22 10:21
Trichloroethene
ug/L
ND
1.0
0.38
06/22/22 10:21
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/22/22 10:21
Vinyl acetate
ug/L
ND
2.0
1.3
06/22/22 10:21
Vinyl chloride
ug/L
ND
1.0
0.39
06/22/22 10:21
Xylene (Total)
ug/L
ND
1.0
0.34
06/22/22 10:21
1,2-Dichloroethane-d4 (S)
%
104
70-130
06/22/22 10:21
4-Bromofluorobenzene (S)
%
97
70-130
06/22/22 10:21
Toluene-d8 (S)
%
100
70-130
06/22/22 10:21
LABORATORY CONTROL SAMPLE:
Parameter
3682557
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
59.1
118
70-130
1,1,1-Trichloroethane
ug/L
50
48.2
96
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
57.6
115
70-130
1,1,2-Trichloroethane
ug/L
50
52.2
104
70-130
1,1-Dichloroethane
ug/L
50
45.2
90
70-130
1,1-Dichloroethene
ug/L
50
49.4
99
70-132
1,2,3-Trichloropropane
ug/L
50
56.5
113
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.3
99
70-132
1,2-Dibromoethane (EDB)
ug/L
50
55.4
111
70-130
1,2-Dichlorobenzene
ug/L
50
52.3
105
70-130
1,2-Dichloroethane
ug/L
50
47.8
96
70-130
1,2-Dichloropropane
ug/L
50
52.2
104
70-130
1,4-Dichlorobenzene
ug/L
50
51.4
103
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
1000
100
70-137
2-Butanone (MEK)
ug/L
100
104
104
70-133
2-Hexanone
ug/L
100
105
105
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
91.7
92
70-144
Acrylonitrile
ug/L
250
235
94
70-130
Benzene
ug/L
50
51.2
102
70-130
Bromochloromethane
ug/L
50
54.3
109
70-130lK
Bromodichloromethane
ug/L
50
53.3
107
70-130
Bromoform
ug/L
50
50.6
101
70-131 IK
Bromomethane
ug/L
50
63.2
126
30-177 v1
Carbon disulfide
ug/L
50
45.6
91
70-133
Carbon tetrachloride
ug/L
50
53.0
106
70-130
Chlorobenzene
ug/L
50
54.6
109
70-130
Chloroethane
ug/L
50
61.8
124
46-131 v1
Chloroform
ug/L
50
45.3
91
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
Parameter
3682557
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
50
53.4
107
49-130
cis-1,2-Dichloroethene
ug/L
50
47.0
94
70-130
cis-1,3-Dichloropropene
ug/L
50
53.5
107
70-130
Dibromochloromethane
ug/L
50
55.9
112
70-130
Dibromomethane
ug/L
50
51.6
103
70-130
Ethylbenzene
ug/L
50
55.5
111
70-130
lodomethane
ug/L
100
114
114
47-140
Methylene Chloride
ug/L
50
45.0
90
68-130
Styrene
ug/L
50
59.3
119
70-130
Tetrachloroethene
ug/L
50
53.0
106
70-130
Toluene
ug/L
50
50.8
102
70-130
trans-1,2-Dichloroethene
ug/L
50
47.7
95
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.0
108
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
51.2
102
25-200
Trichloroethene
ug/L
50
52.3
105
70-130
Trichlorofluoromethane
ug/L
50
56.3
113
61-130
Vinyl acetate
ug/L
100
90.3
90
70-140
Vinyl chloride
ug/L
50
48.2
96
59-142
Xylene (Total)
ug/L
150
170
113
70-130
1,2-Dichloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
108
70-130
Toluene-d8 (S)
%
97
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3682558
MS
92610345010 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3682559
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
<0.62
40
40
44.7
46.3
112
116
70-135
4
30
1,1,1-Trichloroethane
ug/L
26.6
40
40
68.3
67.2
104
101
70-148
2
30
1,1,2,2-Tetrachloroethane
ug/L
<0.45
40
40
43.1
43.9
108
110
70-131
2
30
1,1,2-Trichloroethane
ug/L
0.71J
40
40
44.2
43.9
109
108
70-136
1
30
1,1-Dichloroethane
ug/L
17.8
40
40
58.6
59.3
102
104
70-147
1
30
1,1-Dichloroethene
ug/L
90.0
40
40
132
133
104
108
70-158
1
30
1,2,3-Trichloropropane
ug/L
<0.52
40
40
41.8
42.0
104
105
67-137
1
30
1,2-Dibromo-3-
ug/L
<0.68
40
40
38.9
41.5
97
104
69-136
6
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
<0.54
40
40
43.9
43.4
110
109
70-137
1
30
1,2-Dichlorobenzene
ug/L
<0.68
40
40
41.2
42.3
103
106
70-133
3
30
1,2-Dichloroethane
ug/L
0.72J
40
40
45.1
44.6
111
110
67-138
1
30
1,2-Dichloropropane
ug/L
<0.71
40
40
45.7
44.6
114
111
70-138
3
30
1,4-Dichlorobenzene
ug/L
<0.67
40
40
39.9
42.1
100
105
70-133
5
30
1,4-Dioxane(p-Dioxane)
ug/L
<77.4
800
800
851
833
106
104
69-146
2
30
2-Butanone (MEK)
ug/L
<7.9
80
80
105
105
131
132
61-147
1
30
2-Hexanone
ug/L
<0.95
80
80
84.9
87.4
106
109
67-139
3
30
4-Methyl-2-pentanone
ug/L
<5.4
80
80
84.5
81.4
106
102
67-136
4
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 52 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3682558
3682559
MS
MSD
92610345010
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
<10.2
80
80
101
99.3
126
124
55-159
2
30
Acrylonitrile
ug/L
<3.7
200
200
213
214
106
107
68-140
1
30
Benzene
ug/L
<0.69
40
40
41.9
41.6
105
104
67-150
1
30
Bromochloromethane
ug/L
<0.94
40
40
54.7
54.3
137
136
70-146
1
30 IK
Bromodichloromethane
ug/L
<0.61
40
40
44.8
43.3
112
108
70-138
3
30
Bromoform
ug/L
<0.68
40
40
34.0
34.2
85
85
57-138
1
30 IK
Bromomethane
ug/L
<3.3
40
40
62.6
66.7
157
167
10-200
6
30 v1
Carbon disulfide
ug/L
<0.72
40
40
42.3
42.6
106
107
70-152
1
30
Carbon tetrachloride
ug/L
<0.67
40
40
44.8
44.2
112
111
70-147
1
30
Chlorobenzene
ug/L
<0.57
40
40
43.3
43.5
108
109
70-137
0
30
Chloroethane
ug/L
<1.3
40
40
64.7
61.9
162
155
51-166
4
30 v1
Chloroform
ug/L
3.6
40
40
46.6
44.6
108
103
70-144
4
30
Chloromethane
ug/L
<1.1
40
40
44.8
47.5
112
119
24-161
6
30
cis-1,2-Dichloroethene
ug/L
36.3
40
40
76.6
77.7
101
104
67-148
1
30
cis-1,3-Dichloropropene
ug/L
<0.73
40
40
39.7
39.1
99
98
70-142
1
30
Dibromochloromethane
ug/L
<0.72
40
40
42.6
43.8
107
110
68-138
3
30
Dibromomethane
ug/L
<0.79
40
40
43.0
42.8
108
107
70-134
1
30
Ethylbenzene
ug/L
<0.61
40
40
43.4
44.1
109
110
68-143
2
30
lodomethane
ug/L
<19.4
80
80
84.5
95.2
99
112
20-161
12
30
Methylene Chloride
ug/L
<3.9
40
40
42.8
44.2
107
110
64-148
3
30
Styrene
ug/L
<0.58
40
40
41.1
43.3
103
108
70-136
5
30
Tetrachloroethene
ug/L
167
40
40
205
204
95
94
70-139
0
30
Toluene
ug/L
<0.97
40
40
42.6
41.2
107
103
47-157
4
30
trans-1,2-Dichloroethene
ug/L
<0.79
40
40
42.6
44.8
107
112
70-149
5
30
trans-1,3-Dichloropropene
ug/L
<0.73
40
40
40.6
39.4
101
98
70-138
3
30
trans-1,4-Dichloro-2-butene
ug/L
<1.1
40
40
32.1
36.7
80
92
31-145
14
30
Trichloroethene
ug/L
42.6
40
40
86.8
85.0
111
106
70-149
2
30
Trichlorofluoromethane
ug/L
<0.60
40
40
46.4
45.6
116
114
61-154
2
30
Vinyl acetate
ug/L
<2.6
80
80
65.0
66.8
81
83
48-156
3
30
Vinyl chloride
ug/L
<0.77
40
40
43.7
45.8
109
114
55-172
5
30
Xylene (Total)
ug/L
<0.68
120
120
127
133
106
111
66-145
5
30
1,2-Dichloroethane-d4 (S)
%
96
98
70-130
4-Bromofluorobenzene (S)
%
97
98
70-130
Toluene-d8 (S)
%
99
95
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 53 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706201 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492008
METHOD BLANK: 3684177
Associated Lab Samples: 92610492008
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 03:32
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 03:32
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 03:32
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 03:32
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 03:32
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 03:32
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 03:32
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 03:32
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 03:32
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 03:32
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 03:32
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 03:32
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 03:32
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 03:32
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 03:32
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 03:32
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 03:32
Acetone
ug/L
ND
25.0
5.1
06/23/22 03:32
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 03:32
Benzene
ug/L
ND
1.0
0.34
06/23/22 03:32
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 03:32
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 03:32
Bromoform
ug/L
ND
1.0
0.34
06/23/22 03:32
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 03:32 v1
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 03:32
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 03:32
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 03:32
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 03:32 v1
Chloroform
ug/L
ND
1.0
0.43
06/23/22 03:32
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 03:32
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 03:32
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 03:32
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 03:32
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 03:32
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 03:32
lodomethane
ug/L
ND
20.0
9.7
06/23/22 03:32
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 03:32
Styrene
ug/L
ND
1.0
0.29
06/23/22 03:32
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 03:32
Toluene
ug/L
ND
1.0
0.48
06/23/22 03:32
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 54 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3684177
Associated Lab Samples: 92610492008
Parameter
Units
trans-1,2-Dichloroethene
ug/L
trans- 1,3-Dichloropropene
ug/L
trans-1,4-Dichloro-2-butene
ug/L
Trichloroethene
ug/L
Trichlorofluoromethane
ug/L
Vinyl acetate
ug/L
Vinyl chloride
ug/L
Xylene (Total)
ug/L
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
IA_1 Z�7:7\Cwl:�-�K.�i.rr:Zwl�ylul»�d�L�ir'E:3
Parameter
QUALITY CONTROL DATA
Matrix: Water
Blank
Result
Reporting
Limit
ND
1.0
ND
1.0
ND
1.0
ND
1.0
ND
1.0
ND
2.0
ND
1.0
ND
1.0
93
70-130
102
70-130
100
70-130
Spike LCS
Units Conc. Result
MDL
Analyzed
0.40
06/23/22 03:32
0.36
06/23/22 03:32
0.56
06/23/22 03:32
0.38
06/23/22 03:32
0.30
06/23/22 03:32 v1
1.3
06/23/22 03:32
0.39
06/23/22 03:32
0.34
06/23/22 03:32
06/23/22 03:32
06/23/22 03:32
06/23/22 03:32
Qualifiers
LCS % Rec
% Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
50.4
101
70-130
1,1,1-Trichloroethane
ug/L
50
49.8
100
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.8
98
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
47.2
94
70-130
1,1-Dichloroethene
ug/L
50
56.7
113
70-132
1,2,3-Trichloropropane
ug/L
50
47.8
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
43.0
86
70-132
1,2-Dibromoethane (EDB)
ug/L
50
48.2
96
70-130
1,2-Dichlorobenzene
ug/L
50
47.1
94
70-130
1,2-Dichloroethane
ug/L
50
47.7
95
70-130
1,2-Dichloropropane
ug/L
50
51.0
102
70-130
1,4-Dichlorobenzene
ug/L
50
47.4
95
70-130
1,4-Dioxane(p-Dioxane)
ug/L
1000
1010
101
70-137
2-Butanone (MEK)
ug/L
100
96.3
96
70-133
2-Hexanone
ug/L
100
87.8
88
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
98.1
98
70-130
Acetone
ug/L
100
94.5
95
70-144
Acrylonitrile
ug/L
250
240
96
70-130
Benzene
ug/L
50
49.9
100
70-130
Bromochloromethane
ug/L
50
52.3
105
70-130
Bromodichloromethane
ug/L
50
50.5
101
70-130
Bromoform
ug/L
50
46.0
92
70-131
Bromomethane
ug/L
50
73.1
146
30-177 v1
Carbon disulfide
ug/L
50
52.0
104
70-133
Carbon tetrachloride
ug/L
50
53.1
106
70-130
Chlorobenzene
ug/L
50
48.9
98
70-130
Chloroethane
ug/L
50
86.4
173
46-131 L1,v1
Chloroform
ug/L
50
48.6
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
Parameter
3684178
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
53.9
cis-1,2-Dichloroethene
ug/L
50
47.7
cis-1,3-Dichloropropene
ug/L
50
50.3
Dibromochloromethane
ug/L
50
46.2
Dibromomethane
ug/L
50
56.4
Ethylbenzene
ug/L
50
47.4
lodomethane
ug/L
100
116
Methylene Chloride
ug/L
50
47.2
Styrene
ug/L
50
48.5
Tetrachloroethene
ug/L
50
48.5
Toluene
ug/L
50
51.8
trans-1,2-Dichloroethene
ug/L
50
50.3
trans- 1,3-Dichloropropene
ug/L
50
50.7
trans-1,4-Dichloro-2-butene
ug/L
50
48.8
Trichloroethene
ug/L
50
55.3
Trichlorofluoromethane
ug/L
50
69.8
Vinyl acetate
ug/L
100
91.7
Vinyl chloride
ug/L
50
55.6
Xylene (Total)
ug/L
150
142
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
108
49-130
95
70-130
101
70-130
92
70-130
113
70-130
95
70-130
116
47-140
94
68-130
97
70-130
97
70-130
104
70-130
101
70-130
101
70-130
98
25-200
111
70-130
140
61-130 L1,v1
92
70-140
111
59-142
94
70-130
83
70-130
99
70-130
100
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684179
MS
92610351005 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3684180
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
<0.31
20
20
22.4
21.3
112
106
70-135
5
30
1,1,1-Trichloroethane
ug/L
<0.33
20
20
20.0
19.0
100
95
70-148
5
30
1,1,2,2-Tetrachloroethane
ug/L
<0.22
20
20
21.5
20.1
108
100
70-131
7
30
1,1,2-Trichloroethane
ug/L
<0.32
20
20
19.7
18.8
99
94
70-136
5
30
1,1-Dichloroethane
ug/L
97.1
20
20
18.2
17.2
-395
-400
70-147
6
30 M1
1,1-Dichloroethene
ug/L
80.1
20
20
22.9
21.6
-286
-292
70-158
6
30 M1
1,2,3-Trichloropropane
ug/L
<0.26
20
20
21.3
19.7
107
99
67-137
8
30
1,2-Dibromo-3-
ug/L
<0.34
20
20
20.7
19.3
104
96
69-136
7
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
<0.27
20
20
21.3
20.4
107
102
70-137
5
30
1,2-Dichlorobenzene
ug/L
<0.34
20
20
21.8
20.7
109
103
70-133
5
30
1,2-Dichloroethane
ug/L
0.40J
20
20
18.5
17.3
91
84
67-138
7
30
1,2-Dichloropropane
ug/L
<0.36
20
20
19.6
18.3
98
91
70-138
7
30
1,4-Dichlorobenzene
ug/L
<0.33
20
20
22.6
21.2
113
106
70-133
6
30
1,4-Dioxane(p-Dioxane)
ug/L
<38.7
400
400
416
374
104
94
69-146
11
30
2-Butanone (MEK)
ug/L
<4.0
40
40
37.7
34.6
94
86
61-147
9
30
2-Hexanone
ug/L
<0.48
40
40
41.0
37.6
103
94
67-139
9
30
4-Methyl-2-pentanone
ug/L
<2.7
40
40
37.6
34.8
94
87
67-136
8
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 56 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3684179
3684180
MS
MSD
92610351005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
<5.1
40
40
38.3
33.8
96
84
55-159
13
30
Acrylonitrile
ug/L
<1.8
100
100
87.2
80.5
87
81
68-140
8
30
Benzene
ug/L
<0.34
20
20
19.7
18.5
98
92
67-150
6
30
Bromochloromethane
ug/L
<0.47
20
20
19.9
18.9
100
94
70-146
5
30
Bromodichloromethane
ug/L
<0.31
20
20
19.4
18.4
97
92
70-138
5
30
Bromoform
ug/L
<0.34
20
20
19.8
18.7
99
93
57-138
6
30
Bromomethane
ug/L
<1.7
20
20
29.3
28.0
146
140
10-200
4
30
Carbon disulfide
ug/L
<0.36
20
20
21.1
19.8
105
99
70-152
6
30
Carbon tetrachloride
ug/L
<0.33
20
20
21.6
20.5
108
102
70-147
5
30
Chlorobenzene
ug/L
<0.28
20
20
22.1
21.2
111
106
70-137
4
30
Chloroethane
ug/L
<0.65
20
20
30.3
28.4
152
142
51-166
6
30
Chloroform
ug/L
<0.43
20
20
19.0
18.4
95
92
70-144
3
30
Chloromethane
ug/L
<0.54
20
20
21.1
19.9
105
100
24-161
6
30 v2
cis-1,2-Dichloroethene
ug/L
12.1
20
20
18.3
17.3
31
26
67-148
5
30 M1
cis-1,3-Dichloropropene
ug/L
<0.36
20
20
18.7
18.0
94
90
70-142
4
30
Dibromochloromethane
ug/L
<0.36
20
20
20.2
19.1
101
95
68-138
6
30
Dibromomethane
ug/L
<0.39
20
20
21.8
20.4
109
102
70-134
7
30
Ethylbenzene
ug/L
<0.30
20
20
21.8
21.0
109
105
68-143
4
30
lodomethane
ug/L
<9.7
40
40
39.3
37.2
98
93
20-161
6
30
Methylene Chloride
ug/L
<2.0
20
20
18.3
17.4
87
82
64-148
5
30
Styrene
ug/L
<0.29
20
20
21.6
20.6
108
103
70-136
4
30
Tetrachloroethene
ug/L
92.5
20
20
23.1
22.2
-347
-352
70-139
4
30 M1
Toluene
ug/L
<0.48
20
20
20.1
18.8
100
94
47-157
7
30
trans-1,2-Dichloroethene
ug/L
<0.40
20
20
19.8
18.2
99
91
70-149
9
30
trans-1,3-Dichloropropene
ug/L
<0.36
20
20
19.1
18.0
95
90
70-138
6
30
trans-1,4-Dichloro-2-butene
ug/L
<0.56
20
20
19.5
18.0
97
90
31-145
8
30
Trichloroethene
ug/L
40.9
20
20
22.1
20.7
-94
-101
70-149
7
30 M1
Trichlorofluoromethane
ug/L
<0.30
20
20
26.0
24.3
130
121
61-154
7
30
Vinyl acetate
ug/L
<1.3
40
40
35.3
32.8
88
82
48-156
7
30
Vinyl chloride
ug/L
0.57J
20
20
22.9
21.7
112
106
55-172
6
30 v2
Xylene (Total)
ug/L
<0.34
60
60
66.0
62.4
110
104
66-145
6
30
1,2-Dichloroethane-d4 (S)
%
96
96
70-130
4-Bromofluorobenzene (S)
%
95
95
70-130
Toluene-d8 (S)
%
97
95
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 57 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706240 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492009, 92610492010, 92610492011, 92610492012, 92610492013
METHOD BLANK: 3684436 Matrix: Water
Associated Lab Samples: 92610492009, 92610492010, 92610492011, 92610492012, 92610492013
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 05:27
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 05:27
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 05:27
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 05:27
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 05:27
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 05:27
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 05:27
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 05:27
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 05:27
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 05:27
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 05:27
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 05:27
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 05:27
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 05:27
Acetone
ug/L
ND
25.0
5.1
06/23/22 05:27
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 05:27
Benzene
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 05:27
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 05:27
Bromoform
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 05:27
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 05:27
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 05:27
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 05:27
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 05:27
Chloroform
ug/L
ND
1.0
0.43
06/23/22 05:27
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 05:27
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 05:27
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 05:27
lodomethane
ug/L
ND
20.0
9.7
06/23/22 05:27
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 05:27
Styrene
ug/L
ND
1.0
0.29
06/23/22 05:27
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 05:27
Toluene
ug/L
ND
1.0
0.48
06/23/22 05:27
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3684436 Matrix: Water
Associated Lab Samples: 92610492009, 92610492010, 92610492011, 92610492012, 92610492013
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/23/22 05:27
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/23/22 05:27
Trichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/23/22 05:27
Vinyl acetate
ug/L
ND
2.0
1.3
06/23/22 05:27 v1
Vinyl chloride
ug/L
ND
1.0
0.39
06/23/22 05:27
Xylene (Total)
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane-d4 (S)
%
113
70-130
06/23/22 05:27
4-Bromofluorobenzene (S)
%
103
70-130
06/23/22 05:27
Toluene-d8 (S)
%
100
70-130
06/23/22 05:27
LABORATORY CONTROL SAMPLE:
Parameter
3684437
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.1
106
70-130
1,1,1-Trichloroethane
ug/L
50
55.8
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.4
103
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
57.2
114
70-130
1,1-Dichloroethene
ug/L
50
58.9
118
70-132
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
70-130
1,2-Dichlorobenzene
ug/L
50
51.0
102
70-130
1,2-Dichloroethane
ug/L
50
56.5
113
70-130
1,2-Dichloropropane
ug/L
50
55.8
112
70-130
1,4-Dichlorobenzene
ug/L
50
49.5
99
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
962
96
70-137
2-Butanone (MEK)
ug/L
100
118
118
70-133
2-Hexanone
ug/L
100
110
110
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
107
107
70-130
Acetone
ug/L
100
107
107
70-144
Acrylonitrile
ug/L
250
296
118
70-130
Benzene
ug/L
50
51.3
103
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
54.7
109
70-130
Bromoform
ug/L
50
52.9
106
70-131
Bromomethane
ug/L
50
41.3
83
30-177 v3
Carbon disulfide
ug/L
50
57.2
114
70-133
Carbon tetrachloride
ug/L
50
52.0
104
70-130
Chlorobenzene
ug/L
50
51.0
102
70-130
Chloroethane
ug/L
50
52.0
104
46-131
Chloroform
ug/L
50
57.1
114
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
Parameter
3684437
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
58.7
cis-1,2-Dichloroethene
ug/L
50
58.2
cis-1,3-Dichloropropene
ug/L
50
55.4
Dibromochloromethane
ug/L
50
53.1
Dibromomethane
ug/L
50
49.5
Ethylbenzene
ug/L
50
52.2
lodomethane
ug/L
100
119
Methylene Chloride
ug/L
50
51.7
Styrene
ug/L
50
51.4
Tetrachloroethene
ug/L
50
47.7
Toluene
ug/L
50
49.5
trans-1,2-Dichloroethene
ug/L
50
59.5
trans- 1,3-Dichloropropene
ug/L
50
55.4
trans-1,4-Dichloro-2-butene
ug/L
50
48.6
Trichloroethene
ug/L
50
51.2
Trichlorofluoromethane
ug/L
50
50.7
Vinyl acetate
ug/L
100
124
Vinyl chloride
ug/L
50
61.6
Xylene (Total)
ug/L
150
158
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
117
49-130
116
70-130
111
70-130
106
70-130
99
70-130
104
70-130
119
47-140
103
68-130
103
70-130
95
70-130
99
70-130
119
70-130
111
70-130
97
25-200
102
70-130
101
61-130
124
70-140 v1
123
59-142
105
70-130
114
70-130
103
70-130
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684438
MS
92610701001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3684439
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
25.6
23.8
128
119
70-135
7
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.8
21.2
114
106
70-148
7
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
24.9
22.8
125
114
70-131
9
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.9
21.3
115
106
70-136
8
30
1,1-Dichloroethane
ug/L
2.5
20
20
23.2
21.4
103
94
70-147
8
30
1,1-Dichloroethene
ug/L
ND
20
20
25.9
24.1
130
120
70-158
7
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.2
22.2
121
111
67-137
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.4
22.5
117
112
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
25.0
22.9
125
114
70-137
9
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.2
23.6
126
118
70-133
6
30
1,2-Dichloroethane
ug/L
ND
20
20
21.4
19.9
107
100
67-138
7
30
1,2-Dichloropropane
ug/L
ND
20
20
22.5
20.4
113
102
70-138
10
30
1,4-Dichlorobenzene
ug/L
2.7
20
20
28.1
27.0
127
122
70-133
4
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
559
540
140
135
69-146
3
30
2-Butanone (MEK)
ug/L
ND
40
40
46.6
43.3
117
108
61-147
7
30
2-Hexanone
ug/L
ND
40
40
49.3
47.3
123
118
67-139
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
44.8
42.2
112
106
67-136
6
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 60 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3684438
3684439
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
45.7
43.7
114
109
55-159
4
30
Acrylonitrile
ug/L
ND
100
100
99.5
96.4
100
96
68-140
3
30
Benzene
ug/L
3.3
20
20
25.5
23.8
111
102
67-150
7
30
Bromochloromethane
ug/L
ND
20
20
22.6
21.0
113
105
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
22.1
20.5
111
102
70-138
8
30
Bromoform
ug/L
ND
20
20
20.9
19.1
104
96
57-138
9
30
Bromomethane
ug/L
ND
20
20
36.6
34.5
183
173
10-200
6
30 v1
Carbon disulfide
ug/L
ND
20
20
23.7
22.2
119
111
70-152
7
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
22.8
123
114
70-147
8
30
Chlorobenzene
ug/L
ND
20
20
25.5
23.6
128
118
70-137
8
30
Chloroethane
ug/L
1.8
20
20
41.1
38.2
197
182
51-166
7
30 M1,v1
Chloroform
ug/L
ND
20
20
22.0
20.3
110
102
70-144
8
30
Chloromethane
ug/L
ND
20
20
25.6
23.3
128
116
24-161
10
30
cis-1,2-Dichloroethene
ug/L
1.5
20
20
22.4
20.8
104
96
67-148
7
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.2
19.5
106
98
70-142
8
30
Dibromochloromethane
ug/L
ND
20
20
22.8
21.0
114
105
68-138
8
30
Dibromomethane
ug/L
ND
20
20
24.8
23.0
124
115
70-134
8
30
Ethylbenzene
ug/L
1.1
20
20
25.9
24.1
124
115
68-143
7
30
lodomethane
ug/L
ND
40
40
47.5
43.2
119
108
20-161
9
30
Methylene Chloride
ug/L
ND
20
20
21.0
19.6
105
98
64-148
7
30
Styrene
ug/L
ND
20
20
24.8
22.6
124
113
70-136
9
30
Tetrachloroethene
ug/L
ND
20
20
25.8
23.5
129
118
70-139
9
30
Toluene
ug/L
ND
20
20
23.0
21.3
115
107
47-157
8
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.4
20.4
112
102
70-149
9
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.5
19.9
108
100
70-138
8
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.6
19.2
98
96
31-145
2
30
Trichloroethene
ug/L
ND
20
20
25.0
23.0
125
115
70-149
8
30
Trichlorofluoromethane
ug/L
ND
20
20
29.8
28.2
149
141
61-154
5
30 v1
Vinyl acetate
ug/L
ND
40
40
37.8
36.0
94
90
48-156
5
30
Vinyl chloride
ug/L
1.0
20
20
26.5
24.8
127
119
55-172
6
30
Xylene (Total)
ug/L
6.2
60
60
80.9
74.8
125
114
66-145
8
30
1,2-Dichloroethane-d4 (S)
%
95
96
70-130
4-Bromofluorobenzene (S)
%
95
95
70-130
Toluene-d8 (S)
%
97
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 61 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706351 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492014
METHOD BLANK: 3685200
Associated Lab Samples: 92610492014
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 05:08
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 05:08
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 05:08
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:08
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 05:08
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 05:08
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 05:08
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 05:08
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 05:08
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 05:08
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:08
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 05:08
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 05:08
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 05:08
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 05:08
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 05:08
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 05:08
Acetone
ug/L
ND
25.0
5.1
06/23/22 05:08
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 05:08
Benzene
ug/L
ND
1.0
0.34
06/23/22 05:08
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 05:08
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 05:08
Bromoform
ug/L
ND
1.0
0.34
06/23/22 05:08
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 05:08 v2
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 05:08
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 05:08
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 05:08
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 05:08
Chloroform
ug/L
ND
1.0
0.43
06/23/22 05:08
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 05:08
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:08
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:08
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 05:08
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 05:08
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 05:08
lodomethane
ug/L
ND
20.0
9.7
06/23/22 05:08
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 05:08
Styrene
ug/L
ND
1.0
0.29
06/23/22 05:08
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 05:08
Toluene
ug/L
ND
1.0
0.48
06/23/22 05:08
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 62 of 86

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3685200
Matrix:
Water
Associated Lab Samples: 92610492014
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/23/22 05:08
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:08
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/23/22 05:08
Trichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:08
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/23/22 05:08
Vinyl acetate
ug/L
ND
2.0
1.3
06/23/22 05:08 v1
Vinyl chloride
ug/L
ND
1.0
0.39
06/23/22 05:08
Xylene (Total)
ug/L
ND
1.0
0.34
06/23/22 05:08
1,2-Dichloroethane-d4 (S)
%
113
70-130
06/23/22 05:08
4-Bromofluorobenzene (S)
%
104
70-130
06/23/22 05:08
Toluene-d8 (S)
%
100
70-130
06/23/22 05:08
LABORATORY CONTROL SAMPLE: 3685201
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.1
106
70-130
1,1,1-Trichloroethane
ug/L
50
55.5
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.8
104
70-130
1,1,2-Trichloroethane
ug/L
50
52.4
105
70-130
1,1-Dichloroethane
ug/L
50
56.9
114
70-130
1,1-Dichloroethene
ug/L
50
58.7
117
70-132
1,2,3-Trichloropropane
ug/L
50
50.9
102
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
50.1
100
70-132
1,2-Dibromoethane (EDB)
ug/L
50
52.8
106
70-130
1,2-Dichlorobenzene
ug/L
50
51.6
103
70-130
1,2-Dichloroethane
ug/L
50
55.8
112
70-130
1,2-Dichloropropane
ug/L
50
55.3
111
70-130
1,4-Dichlorobenzene
ug/L
50
49.9
100
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
999
100
70-137
2-Butanone (MEK)
ug/L
100
118
118
70-133
2-Hexanone
ug/L
100
108
108
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
106
106
70-130
Acetone
ug/L
100
106
106
70-144
Acrylonitrile
ug/L
250
298
119
70-130
Benzene
ug/L
50
50.8
102
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
54.3
109
70-130
Bromoform
ug/L
50
53.6
107
70-131
Bromomethane
ug/L
50
43.5
87
30-177 v3
Carbon disulfide
ug/L
50
56.7
113
70-133
Carbon tetrachloride
ug/L
50
51.9
104
70-130
Chlorobenzene
ug/L
50
51.3
103
70-130
Chloroethane
ug/L
50
51.1
102
46-131
Chloroform
ug/L
50
56.8
114
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
Parameter
3685201
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
59.1
cis-1,2-Dichloroethene
ug/L
50
58.0
cis-1,3-Dichloropropene
ug/L
50
55.3
Dibromochloromethane
ug/L
50
53.3
Dibromomethane
ug/L
50
49.6
Ethylbenzene
ug/L
50
51.6
lodomethane
ug/L
100
114
Methylene Chloride
ug/L
50
51.1
Styrene
ug/L
50
51.1
Tetrachloroethene
ug/L
50
47.7
Toluene
ug/L
50
49.2
trans-1,2-Dichloroethene
ug/L
50
59.3
trans- 1,3-Dichloropropene
ug/L
50
55.3
trans-1,4-Dichloro-2-butene
ug/L
50
49.1
Trichloroethene
ug/L
50
50.8
Trichlorofluoromethane
ug/L
50
49.9
Vinyl acetate
ug/L
100
123
Vinyl chloride
ug/L
50
61.8
Xylene (Total)
ug/L
150
157
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
118
49-130
116
70-130
111
70-130
107
70-130
99
70-130
103
70-130
114
47-140
102
68-130
102
70-130
95
70-130
98
70-130
119
70-130
111
70-130
98
25-200
102
70-130
100
61-130
123
70-140 v1
124
59-142
105
70-130
113
70-130
103
70-130
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3685202
MS
92610707013 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3685203
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
23.0
23.7
115
118
70-135
3
30
1,1,1-Trichloroethane
ug/L
ND
20
20
20.5
21.4
102
107
70-148
4
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.8
22.6
109
113
70-131
4
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.7
21.3
104
107
70-136
3
30
1,1-Dichloroethane
ug/L
ND
20
20
18.9
19.7
95
99
70-147
4
30
1,1-Dichloroethene
ug/L
ND
20
20
23.0
24.0
115
120
70-158
4
30
1,2,3-Trichloropropane
ug/L
ND
20
20
21.5
22.1
107
110
67-137
3
30
1,2-Dibromo-3-
ug/L
ND
20
20
21.2
22.1
106
111
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
22.3
22.8
112
114
70-137
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
22.4
22.8
112
114
70-133
2
30
1,2-Dichloroethane
ug/L
ND
20
20
18.8
20.0
94
100
67-138
6
30
1,2-Dichloropropane
ug/L
ND
20
20
20.1
20.8
100
104
70-138
4
30
1,4-Dichlorobenzene
ug/L
0.41J
20
20
22.7
23.8
112
117
70-133
5
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
432
433
108
108
69-146
0
30
2-Butanone (MEK)
ug/L
ND
40
40
40.9
42.0
102
105
61-147
3
30
2-Hexanone
ug/L
ND
40
40
41.2
42.4
103
106
67-139
3
30
4-Methyl-2-pentanone
ug/L
ND
40
40
38.6
40.0
97
100
67-136
3
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 64 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3685202
3685203
MS
MSD
92610707013
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
38.3
39.4
96
98
55-159
3
30
Acrylonitrile
ug/L
ND
100
100
91.9
94.9
92
95
68-140
3
30
Benzene
ug/L
ND
20
20
19.9
20.4
100
102
67-150
2
30
Bromochloromethane
ug/L
ND
20
20
20.3
21.2
102
106
70-146
4
30
Bromodichloromethane
ug/L
ND
20
20
20.4
20.9
102
105
70-138
3
30
Bromoform
ug/L
ND
20
20
20.8
21.3
104
107
57-138
3
30
Bromomethane
ug/L
ND
20
20
33.2
35.1
166
176
10-200
6
30 v1
Carbon disulfide
ug/L
ND
20
20
21.2
21.8
106
109
70-152
3
30
Carbon tetrachloride
ug/L
ND
20
20
22.0
22.8
110
114
70-147
3
30
Chlorobenzene
ug/L
ND
20
20
22.6
23.7
113
119
70-137
5
30
Chloroethane
ug/L
ND
20
20
34.7
36.4
173
182
51-166
5
30 M1,v1
Chloroform
ug/L
ND
20
20
20.0
20.6
100
103
70-144
3
30
Chloromethane
ug/L
ND
20
20
21.9
22.7
109
114
24-161
4
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
18.8
19.7
94
98
67-148
4
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
19.5
20.2
97
101
70-142
3
30
Dibromochloromethane
ug/L
ND
20
20
21.2
21.8
106
109
68-138
3
30
Dibromomethane
ug/L
ND
20
20
21.8
23.1
109
115
70-134
6
30
Ethylbenzene
ug/L
ND
20
20
21.9
22.6
109
113
68-143
4
30
lodomethane
ug/L
ND
40
40
41.2
43.4
103
108
20-161
5
30
Methylene Chloride
ug/L
ND
20
20
19.0
19.5
95
98
64-148
3
30
Styrene
ug/L
ND
20
20
21.6
22.5
108
112
70-136
4
30
Tetrachloroethene
ug/L
ND
20
20
22.7
23.2
113
116
70-139
2
30
Toluene
ug/L
ND
20
20
20.3
21.0
101
105
47-157
4
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
19.6
20.3
98
101
70-149
3
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
19.6
20.5
98
103
70-138
5
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.4
19.6
97
98
31-145
1
30
Trichloroethene
ug/L
ND
20
20
21.9
23.1
109
116
70-149
5
30
Trichlorofluoromethane
ug/L
ND
20
20
26.3
27.3
132
137
61-154
4
30 v1
Vinyl acetate
ug/L
ND
40
40
33.5
35.1
84
88
48-156
4
30
Vinyl chloride
ug/L
ND
20
20
22.9
23.8
114
119
55-172
4
30
Xylene (Total)
ug/L
ND
60
60
65.5
68.1
109
114
66-145
4
30
1,2-Dichloroethane-d4 (S)
%
96
91
70-130
4-Bromofluorobenzene (S)
%
95
94
70-130
Toluene-d8 (S)
%
96
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 65 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706322 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 OC Pesticides Red Vol
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492001
METHOD BLANK: 3684991
Associated Lab Samples: 92610492001
Parameter
4,4'-DDD
4,4'-DDE
4,4'-DDT
Aldrin
alpha-BHC
beta-BHC
Chlordane (Technical)
delta-BHC
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
gamma-BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
Matrix: Water
Units
Blank
Result
Reporting
Limit
MDL
Analyzed
ug/L
ND
0.050
0.017
06/23/22 14:48
ug/L
ND
0.050
0.024
06/23/22 14:48
ug/L
ND
0.050
0.026
06/23/22 14:48
ug/L
ND
0.050
0.014
06/23/22 14:48
ug/L
ND
0.050
0.012
06/23/22 14:48
ug/L
ND
0.050
0.049
06/23/22 14:48
ug/L
ND
0.50
0.16
06/23/22 14:48
ug/L
ND
0.050
0.014
06/23/22 14:48
ug/L
ND
0.050
0.015
06/23/22 14:48
ug/L
ND
0.050
0.017
06/23/22 14:48
ug/L
ND
0.050
0.016
06/23/22 14:48
ug/L
ND
0.050
0.015
06/23/22 14:48
ug/L
ND
0.050
0.018
06/23/22 14:48
ug/L
ND
0.050
0.016
06/23/22 14:48
ug/L
ND
0.050
0.012
06/23/22 14:48
ug/L
ND
0.050
0.020
06/23/22 14:48
ug/L
ND
0.050
0.028
06/23/22 14:48
ug/L
ND
0.15
0.042
06/23/22 14:48
ug/L
ND
0.50
0.22
06/23/22 14:48
%
150
10-200
06/23/22 14:48
%
61
10-182
06/23/22 14:48
LABORATORY CONTROL SAMPLE: 3684992
Qualifiers
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
4,4'-DDD
ug/L
0.25
0.30
119
50-178
4,4'-DDE
ug/L
0.25
0.27
106
43-164
4,4'-DDT
ug/L
0.25
0.35
141
23-198
Aldrin
ug/L
0.25
0.17
68
13-137
alpha-BHC
ug/L
0.25
0.21
84
32-161
beta-BHC
ug/L
0.25
0.22
88
54-180
delta-BHC
ug/L
0.25
0.21
84
42-169
Dieldrin
ug/L
0.25
0.29
115
42-173
Endosulfan I
ug/L
0.25
0.22
88
44-168
Endosulfan II
ug/L
0.25
0.23
91
45-176
Endosulfan sulfate
ug/L
0.25
0.26
104
48-178
Endrin
ug/L
0.25
0.30
121
46-178
Endrin aldehyde
ug/L
0.25
0.23
90
35-168
gamma-BHC (Lindane)
ug/L
0.25
0.21
85
38-162
Results presented on
this page are in the units
indicated by the "Units"
column except
where an alternate unit
is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 66 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
3684992
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Heptachlor
ug/L
0.25
0.22
87
25-153
Heptachlor epoxide
ug/L
0.25
0.22
87
43-170
Methoxychlor
ug/L
0.75
0.76
102
37-187
Decachlorobiphenyl (S)
%
163
10-200
Tetrachloro-m-xylene (S)
%
75
10-182
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3684993
3684994
MS
MSD
92610492001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
4,4'-DDD
ug/L
ND
0.5
0.5
0.64
0.56
129
113
13-200
13
30
4,4'-DDE
ug/L
ND
0.5
0.5
0.61
0.52
122
104
10-182
16
30
4,4'-DDT
ug/L
ND
0.5
0.5
0.74
0.64
149
127
10-200
16
30
Aldrin
ug/L
ND
0.5
0.5
0.45
0.34
90
68
10-161
27
30
alpha-BHC
ug/L
ND
0.5
0.5
0.48
0.40
97
81
10-186
18
30
beta-BHC
ug/L
ND
0.5
0.5
0.73
0.64
146
129
10-200
12
30
delta-BHC
ug/L
ND
0.5
0.5
0.44
0.37
88
74
11-199
17
30
Dieldrin
ug/L
ND
0.5
0.5
0.63
0.54
125
107
10-185
15
30
Endosulfan I
ug/L
ND
0.5
0.5
0.50
0.43
100
85
10-191
15
30
Endosulfan II
ug/L
ND
0.5
0.5
0.48
0.42
96
83
10-200
15
30
Endosulfan sulfate
ug/L
ND
0.5
0.5
0.58
0.49
115
99
17-199
15
30
Endrin
ug/L
ND
0.5
0.5
0.65
0.57
130
113
11-193
14
30
Endrin aldehyde
ug/L
ND
0.5
0.5
0.48
0.40
95
80
10-198
17
30
gamma-BHC (Lindane)
ug/L
ND
0.5
0.5
0.49
0.42
98
84
10-190
15
30
Heptachlor
ug/L
ND
0.5
0.5
0.49
0.41
99
81
13-166
20
30
Heptachlor epoxide
ug/L
ND
0.5
0.5
0.46
0.40
93
80
10-200
15
30
Methoxychlor
ug/L
ND
1.5
1.5
1.8
1.5
119
103
10-200
15
30
Decachlorobiphenyl (S)
%
151
161
10-200
Tetrachloro-m-xylene (S)
%
91
67
10-182
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 67 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 706460 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492001
METHOD BLANK: 3685469
Matrix:
Water
Associated Lab Samples: 92610492001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.21
06/24/22 08:20
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.23
06/24/22 08:20
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.23
06/24/22 08:20
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.25
06/24/22 08:20
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.29
06/24/22 08:20
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.21
06/24/22 08:20
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.16
06/24/22 08:20
Decachlorobiphenyl (S)
%
101
10-181
06/24/22 08:20
LABORATORY CONTROL SAMPLE: 3685470
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
PCB-1016 (Aroclor 1016) ug/L 5 4.0 81 33-160
PCB-1260 (Aroclor 1260) ug/L 5 4.3 86 40-157
Decachlorobiphenyl (S) % 124 10-181
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3685471
3685472
MS
MSD
92610492001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD RPD Qual
PCB-1016 (Aroclor 1016)
ug/L ND 8.3
8.3
6.2
6.1
75
73
16-178
3 30
PCB-1260 (Aroclor 1260)
ug/L ND 8.3
8.3
6.9
7.4
83
89
10-171
7 30
Decachlorobiphenyl (S)
%
112
123
10-181
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 68 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705807 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E Water APP9 RV MSSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610492001
METHOD BLANK: 3682468
Associated Lab Samples: 92610492001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
4.5
06/22/22 16:35
1,3,5-Trinitrobenzene
ug/L
ND
10.0
5.5
06/22/22 16:35 v1
1,3-Dinitrobenzene
ug/L
ND
10.0
3.8
06/22/22 16:35
1,4-Naphthoquinone
ug/L
ND
5.0
4.4
06/22/22 16:35
1-Naphthalenamine
ug/L
ND
10.0
6.0
06/22/22 16:35
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
1.2
06/22/22 16:35
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
1.5
06/22/22 16:35
2,4,5-Trichlorophenol
ug/L
ND
10.0
1.4
06/22/22 16:35
2,4,6-Trichlorophenol
ug/L
ND
10.0
1.6
06/22/22 16:35
2,4-Dichlorophenol
ug/L
ND
10.0
1.4
06/22/22 16:35
2,4-Dimethylphenol
ug/L
ND
10.0
1.7
06/22/22 16:35
2,4-Dinitrophenol
ug/L
ND
50.0
26.0
06/22/22 16:35
2,4-Dinitrotoluene
ug/L
ND
10.0
1.6
06/22/22 16:35
2,6-Dichlorophenol
ug/L
ND
10.0
4.2
06/22/22 16:35
2,6-Dinitrotoluene
ug/L
ND
10.0
1.7
06/22/22 16:35
2-Acetylaminofluorene
ug/L
ND
10.0
4.1
06/22/22 16:35
2-Chloronaphthalene
ug/L
ND
10.0
1.7
06/22/22 16:35
2-Chlorophenol
ug/L
ND
10.0
1.2
06/22/22 16:35
2-Methylnaphthalene
ug/L
ND
10.0
1.9
06/22/22 16:35
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
1.9
06/22/22 16:35
2-Naphthalenamine
ug/L
ND
10.0
5.4
06/22/22 16:35
2-Nitroaniline
ug/L
ND
20.0
3.0
06/22/22 16:35
2-Nitrophenol
ug/L
ND
10.0
1.4
06/22/22 16:35
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
1.2
06/22/22 16:35
3,3'-Dichlorobenzidine
ug/L
ND
20.0
8.1
06/22/22 16:35
3,3'-Dimethylbenzidine
ug/L
ND
50.0
31.1
06/22/22 16:35 IH
3-Methylcholanthrene
ug/L
ND
10.0
5.8
06/22/22 16:35
3-Nitroaniline
ug/L
ND
20.0
3.8
06/22/22 16:35 IL
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
7.8
06/22/22 16:35
4-Aminobiphenyl
ug/L
ND
10.0
4.7
06/22/22 16:35
4-Bromophenylphenyl ether
ug/L
ND
10.0
1.8
06/22/22 16:35
4-ChIoro-3-methyl phenol
ug/L
ND
10.0
3.3
06/22/22 16:35
4-Chloroaniline
ug/L
ND
20.0
3.6
06/22/22 16:35
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.0
06/22/22 16:35
4-Nitroaniline
ug/L
ND
20.0
5.1
06/22/22 16:35
4-Nitrophenol
ug/L
ND
50.0
6.6
06/22/22 16:35
5-Nitro-o-toluidine
ug/L
ND
10.0
3.8
06/22/22 16:35
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
3.0
06/22/22 16:35
Acenaphthene
ug/L
ND
10.0
2.0
06/22/22 16:35
Acenaphthylene
ug/L
ND
10.0
2.0
06/22/22 16:35
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 69 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3682468
Associated Lab Samples: 92610492001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Acetophenone
ug/L
ND
10.0
1.5
06/22/22 16:35
Anthracene
ug/L
ND
10.0
2.3
06/22/22 16:35
Benzo(a)anthracene
ug/L
ND
10.0
2.7
06/22/22 16:35
Benzo(a)pyrene
ug/L
ND
10.0
2.8
06/22/22 16:35
Benzo(b)fluoranthene
ug/L
ND
10.0
2.6
06/22/22 16:35
Benzo(g,h,i)perylene
ug/L
ND
10.0
2.8
06/22/22 16:35
Benzo(k)fluoranthene
ug/L
ND
10.0
2.7
06/22/22 16:35
Benzyl alcohol
ug/L
ND
20.0
2.9
06/22/22 16:35
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
1.8
06/22/22 16:35
bis(2-Chloroethyl) ether
ug/L
ND
10.0
1.9
06/22/22 16:35
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
3.7
06/22/22 16:35
Butylbenzylphthalate
ug/L
ND
10.0
3.1
06/22/22 16:35
Chlorobenzilate
ug/L
ND
10.0
3.8
06/22/22 16:35
Chrysene
ug/L
ND
10.0
2.8
06/22/22 16:35
Di-n-butylphthalate
ug/L
ND
10.0
2.2
06/22/22 16:35
Di-n-octylphthalate
ug/L
ND
10.0
3.9
06/22/22 16:35
Diallate
ug/L
ND
10.0
3.4
06/22/22 16:35
Dibenz(a,h)anthracene
ug/L
ND
10.0
3.0
06/22/22 16:35
Dibenzofuran
ug/L
ND
10.0
2.1
06/22/22 16:35
Diethylphthalate
ug/L
ND
10.0
2.0
06/22/22 16:35
Dimethoate
ug/L
ND
10.0
3.7
06/22/22 16:35
Dimethylphthalate
ug/L
ND
10.0
2.1
06/22/22 16:35
Diphenylamine
ug/L
ND
10.0
3.0
06/22/22 16:35
Disulfoton
ug/L
ND
10.0
4.6
06/22/22 16:35
Ethyl methanesulfonate
ug/L
ND
20.0
3.0
06/22/22 16:35
Famphur
ug/L
ND
10.0
6.1
06/22/22 16:35
Fluoranthene
ug/L
ND
10.0
2.2
06/22/22 16:35
Fluorene
ug/L
ND
10.0
2.1
06/22/22 16:35
Hexachlorobenzene
ug/L
ND
10.0
2.2
06/22/22 16:35
Hexachlorocyclopentadiene
ug/L
ND
10.0
1.6
06/22/22 16:35
Hexachloroethane
ug/L
ND
10.0
1.4
06/22/22 16:35
Hexachloropropene
ug/L
ND
10.0
2.7
06/22/22 16:35
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
2.9
06/22/22 16:35
Isodrin
ug/L
ND
10.0
2.8
06/22/22 16:35
Isophorone
ug/L
ND
10.0
1.7
06/22/22 16:35
Isosafrole
ug/L
ND
10.0
2.5
06/22/22 16:35
Kepone
ug/L
ND
20.0
14.1
06/22/22 16:35
Methapyrilene
ug/L
ND
50.0
17.0
06/22/22 16:35
Methyl methanesulfonate
ug/L
ND
5.0
3.1
06/22/22 16:35
Methyl parathion
ug/L
ND
10.0
3.7
06/22/22 16:35
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.0
06/22/22 16:35
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
1.3
06/22/22 16:35
N-Nitrosodiethylamine
ug/L
ND
10.0
2.3
06/22/22 16:35
N-Nitrosodimethylamine
ug/L
ND
10.0
1.9
06/22/22 16:35
N-Nitrosodiphenylamine
ug/L
ND
10.0
3.0
06/22/22 16:35
C.
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 86

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
METHOD BLANK: 3682468
Associated Lab Samples: 92610492001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
N-Nitrosomethylethylamine
ug/L
ND
10.0
7.5
06/22/22 16:35
N-Nitrosopiperidine
ug/L
ND
10.0
2.5
06/22/22 16:35
N-Nitrosopyrrolidine
ug/L
ND
10.0
3.1
06/22/22 16:35
Nitrobenzene
ug/L
ND
10.0
1.9
06/22/22 16:35
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
2.6
06/22/22 16:35
O-Toluidine
ug/L
ND
10.0
2.6
06/22/22 16:35
P-Dimethylaminoazobenzene
ug/L
ND
5.0
2.4
06/22/22 16:35 IL
p-Phenylenediamine
ug/L
ND
10.0
10.0
06/22/22 16:35
Parathion (Ethyl parathion)
ug/L
ND
10.0
3.9
06/22/22 16:35
Pentachlorobenzene
ug/L
ND
10.0
3.4
06/22/22 16:35
Pentachloronitrobenzene
ug/L
ND
10.0
3.3
06/22/22 16:35
Pentachlorophenol
ug/L
ND
20.0
3.8
06/22/22 16:35
Phenacetin
ug/L
ND
10.0
3.6
06/22/22 16:35
Phenanthrene
ug/L
ND
10.0
2.0
06/22/22 16:35
Phenol
ug/L
ND
10.0
1.4
06/22/22 16:35
Phorate
ug/L
ND
10.0
3.6
06/22/22 16:35 v1
Pronamide
ug/L
ND
10.0
3.1
06/22/22 16:35
Pyrene
ug/L
ND
10.0
2.2
06/22/22 16:35
Safrole
ug/L
ND
10.0
2.3
06/22/22 16:35
Thionazin
ug/L
ND
10.0
2.9
06/22/22 16:35
2,4,6-Tribromophenol (S)
%
90
10-144
06/22/22 16:35
2-Fluorobiphenyl (S)
%
68
10-130
06/22/22 16:35
2-Fluorophenol (S)
%
50
10-130
06/22/22 16:35
Nitrobenzene-d5 (S)
%
64
10-144
06/22/22 16:35
Phenol-d6 (S)
%
44
10-130
06/22/22 16:35
Terphenyl-d14 (S)
%
124
34-163
06/22/22 16:35
LABORATORY CONTROL SAMPLE:
Parameter
3682469
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
34.9
70
17-130
1,3,5-Trinitrobenzene
ug/L
50
87.8
176
44-200 v1
1,3-Dinitrobenzene
ug/L
50
65.0
130
39-159
1,4-Naphthoquinone
ug/L
50
53.0
106
10-159
1-Naphthalenamine
ug/L
50
46.1
92
10-130
2,2'-Oxybis(1-chloropropane)
ug/L
50
33.2
66
28-130
2,3,4,6-Tetrachlorophenol
ug/L
50
72.7
145
10-200
2,4,5-Trichlorophenol
ug/L
50
69.9
140
35-130 L1
2,4,6-Trichlorophenol
ug/L
50
69.8
140
31-130 L1
2,4-Dichlorophenol
ug/L
50
58.6
117
35-130
2,4-Dimethylphenol
ug/L
50
58.6
117
34-130
2,4-Dinitrophenol
ug/L
250
366
146
10-153
2,4-Dinitrotoluene
ug/L
50
73.6
147
37-136 L1
2,6-Dichlorophenol
ug/L
50
50.4
101
31-139
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE: 3682469
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
73.9
148
33-136 L1
2-Acetylaminofluorene
ug/L
50
60.4
121
19-181
2-Chloronaphthalene
ug/L
50
46.8
94
26-130
2-Chlorophenol
ug/L
50
44.7
89
37-130
2-Methylnaphthalene
ug/L
50
36.0
72
29-130
2-Methylphenol(o-Cresol)
ug/L
50
51.6
103
35-130
2-Naphthalenamine
ug/L
50
47.6
95
10-136
2-Nitroaniline
ug/L
100
124
124
37-130
2-Nitrophenol
ug/L
50
55.4
111
32-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
55.4
111
34-130
3,3'-Dichlorobenzidine
ug/L
100
145
145
34-136 L1
3,3'-Dimethylbenzidine
ug/L
100
222
222
10-200lH,L1
3-Methylcholanthrene
ug/L
50
57.0
114
39-190
3-Nitroaniline
ug/L
100
136
136
37-138IL
4,6-Dinitro-2-methyl phenol
ug/L
100
144
144
21-157
4-Aminobiphenyl
ug/L
50
53.0
106
17-137
4-Bromophenylphenyl ether
ug/L
50
70.9
142
38-130 L1
4-Chloro-3-methylphenol
ug/L
100
132
132
37-130 L1
4-Chloroaniline
ug/L
100
109
109
38-130
4-Chlorophenylphenyl ether
ug/L
50
64.0
128
33-130
4-Nitroaniline
ug/L
100
129
129
42-137
4-Nitrophenol
ug/L
250
207
83
10-130
5-Nitro-o-toluidine
ug/L
50
61.1
122
39-170
7,12-Dimethylbenz(a)anthracene
ug/L
50
49.1
98
33-139
Acenaphthene
ug/L
50
56.4
113
33-130
Acenaphthylene
ug/L
50
57.2
114
35-130
Acetophenone
ug/L
50
47.7
95
36-130
Anthracene
ug/L
50
62.4
125
48-130
Benzo(a)anthracene
ug/L
50
74.4
149
48-137 L1
Benzo(a)pyrene
ug/L
50
58.1
116
49-138
Benzo(b)fluoranthene
ug/L
50
58.3
117
52-138
Benzo(g,h,i)perylene
ug/L
50
53.3
107
48-140
Benzo(k)fluoranthene
ug/L
50
57.5
115
48-139
Benzyl alcohol
ug/L
100
97.1
97
35-130
bis(2-Chloroethoxy)methane
ug/L
50
52.7
105
34-130
bis(2-Chloroethyl) ether
ug/L
50
44.6
89
36-130
bis(2-Ethylhexyl)phthalate
ug/L
50
76.9
154
32-165
Butylbenzylphthalate
ug/L
50
79.2
158
34-161
Chlorobenzilate
ug/L
50
66.5
133
43-176
Chrysene
ug/L
50
71.1
142
47-131 L1
Di-n-butylphthalate
ug/L
50
71.7
143
39-144
Di-n-octylphthalate
ug/L
50
70.3
141
30-170
Diallate
ug/L
50
57.9
116
33-143
Dibenz(a,h)anthracene
ug/L
50
58.8
118
49-138
Dibenzofuran
ug/L
50
61.5
123
33-130
Diethylphthalate
ug/L
50
67.1
134
38-131 L1
Dimethoate
ug/L
50
60.5
121
46-173
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 86

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
Parameter
3682469
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
67.5
135
37-130 L1
Diphenylamine
ug/L
50
67.3
135
35-135
Disulfoton
ug/L
50
47.5
95
34-139
Ethyl methanesulfonate
ug/L
50
39.8
80
33-133
Famphur
ug/L
100
97.7
98
10-1301H
Fluoranthene
ug/L
50
70.2
140
46-137 L1
Fluorene
ug/L
50
63.4
127
37-130
Hexachlorobenzene
ug/L
50
66.7
133
38-130 L1
Hexachlorocyclopentadiene
ug/L
50
22.4
45
10-130 v1
Hexachloroethane
ug/L
50
4.5J
9
14-130 L2
Hexachloropropene
ug/L
50
8.OJ
16
10-130 v1
Indeno(1,2,3-cd)pyrene
ug/L
50
55.9
112
41-130
Isodrin
ug/L
50
59.3
119
36-139
Isophorone
ug/L
50
54.0
108
33-130
Isosafrole
ug/L
50
41.5
83
22-130
Kepone
ug/L
100
71.5
71
10-130 v1
Methapyrilene
ug/L
50
31.1J
62
10-1731H
Methyl methanesulfonate
ug/L
50
36.2
72
33-130
Methyl parathion
ug/L
50
65.7
131
39-200
N-Nitroso-di-n-butylamine
ug/L
50
38.1
76
22-130
N-Nitroso-di-n-propylamine
ug/L
50
51.0
102
36-130
N-Nitrosodiethylamine
ug/L
50
41.2
82
23-136
N-Nitrosodimethylamine
ug/L
50
38.5
77
34-130
N-Nitrosodiphenylamine
ug/L
50
67.3
135
37-130 L1
N-Nitrosomethylethylamine
ug/L
50
37.5
75
18-137
N-Nitrosopiperidine
ug/L
50
46.7
93
25-142
N-Nitrosopyrrolidine
ug/L
50
41.7
83
24-146
Nitrobenzene
ug/L
50
47.7
95
36-130
O,O,O-Triethylphosphorothioate
ug/L
50
37.7
75
29-130
O-Toluidine
ug/L
50
38.8
78
27-132
P-Dimethylaminoazobenzene
ug/L
50
31.4
63
17-130IL
p-Phenylenediamine
ug/L
ND
Parathion (Ethyl parathion)
ug/L
50
64.8
130
32-200
Pentachlorobenzene
ug/L
50
51.2
102
27-130
Pentachloronitrobenzene
ug/L
50
81.3
163
47-164
Pentachlorophenol
ug/L
100
132
132
23-149
Phenacetin
ug/L
50
60.3
121
44-181
Phenanthrene
ug/L
50
66.7
133
44-130 L1
Phenol
ug/L
50
38.6
77
18-130
Phorate
ug/L
50
77.2
154
18-183 v1
Pronamide
ug/L
50
70.1
140
45-163
Pyrene
ug/L
50
75.6
151
47-134 L1
Safrole
ug/L
50
36.8
74
27-130
Thionazin
ug/L
50
56.6
113
36-162
2,4,6-Tribromophenol (S)
%
161
10-144 SO
2-Fluorobiphenyl (S)
%
70
10-130
2-Fluorophenol (S)
%
68
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
LABORATORY CONTROL SAMPLE:
3682469
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrobenzene-d5 (S)
%
97
10-144
Phenol-d6 (S)
%
73
10-130
Terphenyl-d14 (S)
%
159
34-163
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3682470
3682471
MS
MSD
92610563001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result % Rec % Rec
Limits
RPD
RPD Qual
1,2,4,5-Tetrachlorobenzene
ug/L
ND
50
50
33.5
22.5
67
45
10-130
39
30 R1
1,3,5-Trinitrobenzene
ug/L
ND
50
50
74.4
66.1
149
132
50-200
12
30 v1
1,3-Dinitrobenzene
ug/L
ND
50
50
57.1
47.8
114
96
43-161
18
30
1,4-Naphthoquinone
ug/L
ND
50
50
44.2
40.9
88
82
10-184
8
30
1-Naphthalenamine
ug/L
ND
50
50
36.1
48.4
72
97
10-130
29
30
2,2'-Oxybis(1-
ug/L
ND
50
50
31.0
24.9
62
50
12-142
22
30
chloropropane)
2,3,4,6-Tetrachlorophenol
ug/L
ND
50
50
26.6
30.9
53
62
10-198
15
30
2,4,5-Trichlorophenol
ug/L
ND
50
50
46.4
43.3
93
87
10-143
7
30
2,4,6-Trichlorophenol
ug/L
ND
50
50
33.1
32.5
66
65
10-147
2
30
2,4-Dichlorophenol
ug/L
ND
50
50
45.0
36.9
90
74
10-138
20
30
2,4-Dimethylphenol
ug/L
ND
50
50
49.9
38.0
100
76
25-130
27
30
2,4-Dinitrophenol
ug/L
ND
250
250
ND
34AJ
9
14
10-165
30 M1
2,4-Dinitrotoluene
ug/L
ND
50
50
62.0
53.6
124
107
29-148
14
30
2,6-Dichlorophenol
ug/L
ND
50
50
26.5
27.3
53
55
33-139
3
30
2,6-Dinitrotoluene
ug/L
ND
50
50
64.7
52.4
129
105
26-146
21
30
2-Acetylam inofl uorene
ug/L
ND
50
50
41.2
37.6
82
75
27-172
9
30
2-Chloronaphthalene
ug/L
ND
50
50
46.5
32.3
93
65
11-130
36
30 R1
2-Chlorophenol
ug/L
ND
50
50
35.5
30.0
71
60
10-133
17
30
2-Methyl naphthalene
ug/L
ND
50
50
37.9
26.6
76
53
13-130
35
30 R1
2-Methyl phenol(o-Cresol)
ug/L
ND
50
50
45.3
34.1
91
68
20-130
28
30
2-Naphthalenamine
ug/L
ND
50
50
7.5J
ND
15
4
10-135
30 M1
2-Nitroaniline
ug/L
ND
100
100
109
84.7
109
85
24-136
25
30
2-Nitrophenol
ug/L
ND
50
50
42.0
36.6
84
73
10-153
14
30
3&4-Methylphenol(m&p
ug/L
ND
50
50
46.0
34.5
92
69
16-130
29
30
Cresol)
3,3'-Dichlorobenzidine
ug/L
ND
100
100
123
111
123
111
10-153
11
30
3,3'-Dimethylbenzidine
ug/L
ND
100
100
79.3
144
79
144
10-200
58
30 IH,R1
3-Methylcholanthrene
ug/L
ND
50
50
51.9
44.9
104
90
53-181
15
30
3-Nitroaniline
ug/L
ND
100
100
113
108
113
108
22-151
4
30 IL
4,6-Dinitro-2-methylphenol
ug/L
ND
100
100
20.9
30.8
21
31
10-180
38
30 R1
4-Aminobiphenyl
ug/L
ND
50
50
45.0
49.8
90
100
10-139
10
30
4-Bromophenylphenyl ether
ug/L
ND
50
50
63.1
49.4
126
99
25-130
24
30
4-Chloro-3-methylphenol
ug/L
ND
100
100
112
90.0
112
90
25-133
22
30
4-Chloroaniline
ug/L
ND
100
100
74.1
92.6
74
93
14-132
22
30
4-Chlorophenylphenyl ether
ug/L
ND
50
50
57.9
45.6
116
91
19-130
24
30
4-Nitroaniline
ug/L
ND
100
100
110
97.0
110
97
29-150
13
30
4-Nitrophenol
ug/L
ND
250
250
18.7J
ND
7
0
10-130
30 M1
Results presented
on this page are in the units
indicated by the
"Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall not be reproduced,
except
in full,
Date: 07/02/2022 01:16 PM
without
the written consent of Pace Analytical Services, LLC.
Page 74 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3682470
MS
92610563001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3682471
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
5-Nitro-o-toluidine
ug/L
ND
50
50
49.6
46.0
99
92
48-163
7
30
7,12-
ug/L
ND
50
50
43.8
37.3
88
75
40-140
16
30
Dimethylbenz(a)anthracene
Acenaphthene
ug/L
ND
50
50
52.3
38.8
105
78
16-130
30
30
Acenaphthylene
ug/L
ND
50
50
52.7
39.4
105
79
15-137
29
30
Acetophenone
ug/L
ND
50
50
41.3
33.4
83
67
28-130
21
30
Anthracene
ug/L
ND
50
50
55.5
46.0
111
92
37-136
19
30
Benzo(a)anth race ne
ug/L
ND
50
50
66.0
56.7
132
113
40-145
15
30
Benzo(a)pyrene
ug/L
ND
50
50
53.0
44.8
106
90
41-146
17
30
Benzo(b)fluoranthene
ug/L
ND
50
50
53.4
44.8
107
90
39-151
18
30
Benzo(g,h,i)perylene
ug/L
ND
50
50
48.2
42.1
96
84
40-147
14
30
Benzo(k)fluoranthene
ug/L
ND
50
50
52.5
43.9
105
88
40-146
18
30
Benzyl alcohol
ug/L
ND
100
100
88.5
63.6
88
64
25-130
33
30 R1
bis(2-
ug/L
ND
50
50
43.4
34.7
87
69
23-130
22
30
Chloroethoxy)methane
bis(2-Chloroethyl) ether
ug/L
ND
50
50
39.9
32.6
80
65
25-130
20
30
bis(2- Ethyl hexyl)phthalate
ug/L
ND
50
50
68.1
59.0
136
118
28-166
14
30
Butylbenzylphthalate
ug/L
ND
50
50
71.2
60.2
142
120
33-165
17
30
Chlorobenzilate
ug/L
ND
50
50
59.0
50.7
118
101
55-170
15
30
Chrysene
ug/L
ND
50
50
62.5
53.6
125
107
38-141
15
30
Di-n-butylphthalate
ug/L
ND
50
50
63.7
56.0
127
112
32-153
13
30
Di-n-octylphthalate
ug/L
ND
50
50
62.1
54.1
124
108
30-175
14
30
Diallate
ug/L
ND
50
50
50.9
41.8
102
84
39-141
20
30
Dibenz(a,h)anthracene
ug/L
ND
50
50
51.8
43.7
104
87
39-148
17
30
Dibenzofuran
ug/L
ND
50
50
55.7
42.7
111
85
20-130
26
30
Diethylphthalate
ug/L
ND
50
50
59.3
51.4
119
103
28-142
14
30
Dimethoate
ug/L
ND
50
50
54.5
46.7
109
93
57-167
15
30
Dimethylphthalate
ug/L
ND
50
50
59.0
48.5
118
97
26-136
20
30
Diphenylamine
ug/L
ND
50
50
59.2
47.7
118
95
38-132
22
30
Disulfoton
ug/L
ND
50
50
44.1
39.0
88
78
40-140
12
30
Ethyl methanesulfonate
ug/L
ND
50
50
34.6
28.7
69
57
38-134
19
30
Famphur
ug/L
ND
100
100
74.9
56.2
75
56
10-130
29
30 IH
Fluoranthene
ug/L
ND
50
50
62.2
55.6
124
111
39-143
11
30
Fluorene
ug/L
ND
50
50
56.9
44.7
114
89
24-132
24
30
Hexachlorobenzene
ug/L
ND
50
50
60.0
47.3
120
95
29-130
24
30
Hexachlorocyclopentadiene
ug/L
ND
50
50
29.5
15.2
59
30
10-130
64
30 R1,v1
Hexachloroethane
ug/L
ND
50
50
5.9J
8.91
12
18
10-130
30
Hexachloropropene
ug/L
ND
50
50
11.7
4.7J
23
9
10-130
30 M1,v1
Indeno(1,2,3-cd)pyrene
ug/L
ND
50
50
50.7
43.7
101
87
39-148
15
30
Isodrin
ug/L
ND
50
50
51.5
45.2
103
90
45-138
13
30
Isophorone
ug/L
ND
50
50
45.2
36.5
90
73
23-130
21
30
Isosafrole
ug/L
ND
50
50
35.8
27.3
72
55
25-130
27
30
Kepone
ug/L
ND
100
100
63.6
47.6
64
48
10-130
29
30 v1
Methapyrilene
ug/L
ND
50
50
59.6
69.0
119
138
10-181
15
30 IH
Methyl methanesulfonate
ug/L
ND
50
50
33.6
25.9
67
52
31-130
26
30
Methyl parathion
ug/L
ND
50
50
57.3
51.8
115
104
53-197
10
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 75 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3682470
3682471
MS
MSD
92610563001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
N-Nitroso-di-n-butylamine
ug/L
ND
50
50
32.8
26.5
66
53
28-130
21
30
N-Nitroso-di-n-propylamine
ug/L
ND
50
50
44.7
36.4
89
73
25-130
20
30
N-Nitrosodiethylamine
ug/L
ND
50
50
34.9
30.1
70
60
29-132
15
30
N-Nitrosodimethylamine
ug/L
ND
50
50
36.2
26.2
72
52
22-130
32
30 R1
N-Nitrosodiphenylamine
ug/L
ND
50
50
59.2
47.7
118
95
26-134
22
30
N-Nitrosomethylethylamine
ug/L
ND
50
50
37.9
30.1
76
60
24-133
23
30
N-Nitrosopiperidine
ug/L
ND
50
50
38.8
33.0
78
66
29-141
16
30
N-Nitrosopyrrolidine
ug/L
ND
50
50
37.1
28.2
74
56
29-140
27
30
Nitrobenzene
ug/L
ND
50
50
42.0
33.2
84
66
25-130
23
30
0,0,0-
ug/L
ND
50
50
31.3
28.7
63
57
30-130
9
30
Triethylphosphorothioate
O-Toluidine
ug/L
ND
50
50
26.1
29.0
52
58
27-130
11
30
P-
ug/L
ND
50
50
28.1
23.4
56
47
20-130
18
30 IL
Dimethylaminoazobenzene
p-Phenylenediamine
ug/L
ND
ND
14.2
30
Parathion (Ethyl parathion)
ug/L
ND
50
50
56.7
51.9
113
104
48-200
9
30
Pentachlorobenzene
ug/L
ND
50
50
45.0
34.6
90
69
23-130
26
30
Pentachloronitrobenzene
ug/L
ND
50
50
64.8
57.3
130
115
57-159
12
30
Pentachlorophenol
ug/L
ND
100
100
36.2
48.3
36
48
10-175
29
30
Phenacetin
ug/L
ND
50
50
55.5
47.4
111
95
57-179
16
30
Phenanthrene
ug/L
ND
50
50
59.3
49.1
119
98
36-133
19
30
Phenol
ug/L
ND
50
50
33.2
25.0
66
50
10-130
28
30
Phorate
ug/L
ND
50
50
68.2
56.9
136
114
21-192
18
30 v1
Pronamide
ug/L
ND
50
50
62.3
54.5
125
109
55-162
13
30
Pyrene
ug/L
ND
50
50
67.3
54.8
135
110
40-143
20
30
Safrole
ug/L
ND
50
50
33.0
25.9
66
52
25-130
24
30
Thionazin
ug/L
ND
50
50
49.8
44.6
100
89
50-157
11
30
2,4,6-Tribromophenol (S)
%
103
99
10-144
2-Fluorobiphenyl (S)
%
76
53
10-130
2-Fluorophenol (S)
%
48
42
10-130
Nitrobenzene-d5 (S)
%
92
74
10-144
Phenol-d6 (S)
%
65
47
10-130
Terphenyl-d14 (S)
%
136
109
34-163
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 76 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 705431 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610492001
METHOD BLANK: 3680967
Matrix:
Water
Associated Lab Samples: 92610492001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Sulfide
ug/L
ND
100
50.0 06/18/22 04:34
LABORATORY CONTROL SAMPLE:
3680968
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Sulfide
ug/L
500
502 100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3680969 3680970
MS MSD
92610036001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 496 514 95 98 80-120 4 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3680971 3680972
MS MSD
92610068001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 485 502 95 99 80-120 3 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC.
Page 77 of 86

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
QC Batch: 743955 Analysis Method: EPA 335.4
QC Batch Method: METHOD Analysis Description: EPA 335.4 Cyanide Water
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92610492001
METHOD BLANK: 2363113 Matrix: Water
Associated Lab Samples: 92610492001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide mg/L 0.0013J 0.0040 0.0012 06/27/22 09:56
LABORATORY CONTROL SAMPLE & LCSD: 2363115 2363116
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Cyanide mg/L 0.1 0.095 0.095 95 95 80-120
LABORATORY CONTROL SAMPLE: 2363114
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide mg/L 0.02 0.020 100 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
SAMPLE QUALIFIERS
Sample: L1506162-33
Ill Chlorinated Acid Herbicides (GC) by Method 8151 - Dilution due to sample volume.
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be
considered an estimated value.
LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
P9 RPD between the primary and confirmatory analysis exceeded 40%.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 86

Pace Analytical Services, LLC
ceAnalytrcal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: ASHE CO LINED MSWLF
Pace Project No.: 92610492
ANALYTE QUALIFIERS
R1 RPD value was outside control limits.
SO Surrogate recovery outside laboratory control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
ASHE CO LINED MSWLF
92610492
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92610492001
MW-2
8151A
1882062
EPA8151
1882062
92610492001
MW-2
EPA 3510C
706322
EPA 8081 B
706467
92610492001
MW-2
EPA 3510C
706460
EPA 8082A
706697
92610492001
MW-2
EPA 3005A
706160
EPA 6020B
706279
92610492003
SW-13
EPA 3005A
705851
EPA 6020B
705960
92610492004
SW-3
EPA 3005A
705851
EPA 6020B
705960
92610492005
MW-1
EPA 3005A
705851
EPA 6020B
705960
92610492006
MW-13
EPA 3005A
705851
EPA 6020B
705960
92610492007
MW-15
EPA 3005A
705856
EPA 6020B
706020
92610492008
MW-A
EPA 3005A
705856
EPA 6020B
706020
92610492009
MW-28
EPA 3005A
705856
EPA 6020B
706020
92610492010
MW-29
EPA 3005A
705856
EPA 6020B
706020
92610492011
MW-30
EPA 3005A
705856
EPA 6020B
706020
92610492012
MW-UDP
EPA 3005A
705856
EPA 6020B
706020
92610492013
SW -A
EPA 3005A
705856
EPA 6020B
706020
92610492014
WSW-2
EPA 3005A
705856
EPA 6020B
706020
92610492001
MW-2
EPA 7470A
707951
EPA 7470A
708236
92610492001
MW-2
EPA 3510C
705807
EPA 8270E
705956
92610492001
MW-2
EPA 8260D
705509
92610492003
SW-13
EPA 8260D
705835
92610492004
SW-3
EPA 8260D
705835
92610492005
MW-1
EPA 8260D
705835
92610492006
MW-13
EPA 8260D
705835
92610492007
MW-15
EPA 8260D
705835
92610492008
MW-A
EPA 8260D
706201
92610492009
MW-28
EPA 8260D
706240
92610492010
MW-29
EPA 8260D
706240
92610492011
MW-30
EPA 8260D
706240
92610492012
MW-UDP
EPA 8260D
706240
92610492013
SW -A
EPA 8260D
706240
92610492014
WSW-2
EPA 8260D
706351
92610492001
MW-2
SM 4500-S2D-2011
705431
92610492001
MW-2
METHOD
743955
EPA 335.4
744095
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/02/2022 01:16 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 86

aUEX Title: ENV-FRM-HUN1-0083 v01 -
Sample Condition Upon Receipt
ce
n. "A -i'
Effective Date: 05/12/202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville 2r' Raleigh[] Mechanicsville❑ Atlanta) —I �o�..��-• -�
• Client Name,
-
Upon • ' W0 9261049
Project !i: '
Courier: ❑Fed Ex PS ❑USP5
_,-❑Client
❑ Commercial ce ❑Other:
92610492
Custody Seal Present? ❑Yes D �o Seals Intact? ❑Yes
f '
Date/Initials Person Examining
Packing Material: ❑Bubble Wrap 2113,bble Bags ❑None
❑ Other Biological Tissue �Fro" 7
Thermomet ❑Yes []No L-fNC
ET IR Gun ID: V/ C4
2 y Type of Ice: ei ❑I31ue ❑None
Correction Factor:
Cooler Temp: 7 Add/Subtract(IC)
Cooler Temp Corrected VQ
USDA Regulated Soil ( /A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
(check maps)? ❑Yes ❑No
Chain of Custody Present? ye
Samples Arrived within Hold Time?
3 s
Short Hold Time Analysis ([72 h►.)?
El Yes
Rush Turn Around Time Requested?
❑yes
Sufficient Voiume?
2<
Correct Containers Used?
-Pace Containers Used?
es
es
Containers Intact?
es
Dissolved analysis: Samples Field Filtered?
❑Yes
Sample labels Match CDC?
vex
-Includes Date/Time/lD/Analysis Matrix: `rV 1
❑No ❑N/A
❑No MN/A
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rica J? ❑Yes [:]No
Comments/Dlscrenanev-
1.
2.
3-
4.
5,
6.
LJNo UN/A 7.
[:]No N/A 8.
❑No ❑N/A 9.
Headspace in VOA Vials (s5-6mm)? ❑Yes No
Trip Blank Present? ❑yes EJNr—
Trip Blank Custody Seals Present? Dyes ❑No
COMMENTSISAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
_.rrpject Manager 5RF Review:
10.
Lot ID of split containers:
Date/Time;
Date:
Oate:
Field Data Required? []yes. ❑No
Page 82 of 86
Qualtrax ID; 69614 Page 1 of 2

uG4 Title: ENV-FRM-HUN1-0083 v01 Sample Condition Upon Receipt
ace
Effective Date: 05112/202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and Project # WO# : 9261049
within the acceptance range for preservation samples. PM: AMB 2
Exceptions: VOA, Coliform, TOC, Oil and Grease, DR0/8015 (water) DOC, Wig Due Date: 07/01/2,
**Bottom half of box is to list number of bottles CLIENT: 92-Municipal
***Check all unpreserved Nitrates for chlorine
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PH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot p
adjusted I added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 83 of 86
Qualtrax ID: 69614 Page 2 of 2

Pace YV r 0011IPIV LVIPURIVlt upult Mecelpt
Effectivo Dale: 051121202205/12/2022
*Check mark tap half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {waters OOC, LUIg
*"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project It
PM: AMB Due Dale: 07/01/22
CLIENT: 92-Municipal
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a copy of this form will be sent to the North Carolina D£NR CertiftUlion Office (i.e.
Qualtrax ID: 69614 Page 2 of 2 Page 84 of 86

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Page 85 of 86

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Page 86 of 86

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
July 01, 2022
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
RE: Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on June 17, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a*a` `yl. L�orU
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
North Carolina Certification #: 381
South Carolina Certification #: 98011001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92610701001
92610701002
SW-2
SW-2A
Water
Water
06/16/22 09:55
06/16/22 08:20
06/17/22 12:50
06/17/22 12:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92610701001 SW-2
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92610701002 SW-2A
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
PASI-C = Pace Analytical Services - Charlotte
PASI-GA = Pace Analytical Services - Peachtree Corners, GA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Sample: SW-2
Lab ID:
92610701001
Collected:
06/16/22 09:55
Received: 06/17/22 12:50 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared
Analyzed
CAS No. Qual
6020 MET ICPMS
Analytical
Method: EPA 6020E
Preparation Method: EPA 3005A
Pace Analytical
Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/21/2213:52
06/29/2216:53
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1
06/21/2213:52
06/29/2216:53
7440-38-2
Barium
515
ug/L
5.0
0.67
1
06/21/2213:52
06/29/2216:53
7440-39-3 M1
Beryllium
ND
ug/L
0.50
0.054
1
06/21/2213:52
06/29/2216:53
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/21/2213:52
06/29/2216:53
7440-43-9
Chromium
2.8.1
ug/L
5.0
1.1
1
06/21/2213:52
06/29/2216:53
7440-47-3
Cobalt
20.9
ug/L
5.0
0.39
1
06/21/2213:52
06/29/2216:53
7440-48-4
Copper
ND
ug/L
5.0
1.0
1
06/21/2213:52
06/29/2216:53
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/21/2213:52
06/29/2216:53
7439-92-1
Nickel
7.7
ug/L
5.0
0.71
1
06/21/2213:52
06/29/2216:53
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1
06/21/2213:52
06/29/2216:53
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/21/2213:52
06/29/2216:53
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/21/2213:52
06/29/2216:53
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1
06/21/2213:52
06/29/2216:53
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1
06/21/2213:52
06/29/2216:53
7440-66-6
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 08:12
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 08:12
107-13-1
Benzene
3.3
ug/L
1.0
0.34
1
06/23/22 08:12
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 08:12
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 08:12
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 08:12
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 08:12
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 08:12
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 08:12
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 08:12
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 08:12
108-90-7
Chloroethane
1.8
ug/L
1.0
0.65
1
06/23/22 08:12
75-00-3 M1
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 08:12
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 08:12
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 08:12
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 08:12
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 08:12
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 08:12
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 08:12
95-50-1
1,4-Dichlorobenzene
2.7
ug/L
1.0
0.33
1
06/23/22 08:12
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 08:12
110-57-6
1,1-Dichloroethane
2.5
ug/L
1.0
0.37
1
06/23/22 08:12
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 08:12
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 08:12
75-35-4
cis-1,2-Dichloroethene
1.5
ug/L
1.0
0.38
1
06/23/22 08:12
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 08:12
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 08:12
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Sample: SW-2 Lab ID: 92610701001 Collected: 06/16/22 09:55 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
E:Y�:i111 e7 �, 6yyL91 �,
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 07/01 /2022 02:47 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
150
1.1
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
5.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
1.0
ug/L
1.0
6.2
ug/L
1.0
102
%
70-130
112
%
70-130
99
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
44.1
ug/L
2.0
97
%
70-130
88
%
70-130
0.36
1
06/23/22 08:12
10061-01-5
0.36
1
06/23/22 08:12
10061-02-6
38.7
1
06/23/22 08:12
123-91-1
0.30
1
06/23/22 08:12
100-41-4
0.48
1
06/23/22 08:12
591-78-6
9.7
1
06/23/22 08:12
74-88-4
2.0
1
06/23/22 08:12
75-09-2
2.7
1
06/23/22 08:12
108-10-1
0.29
1
06/23/22 08:12
100-42-5
0.31
1
06/23/22 08:12
630-20-6
0.22
1
06/23/22 08:12
79-34-5
0.29
1
06/23/22 08:12
127-18-4
0.48
1
06/23/22 08:12
108-88-3
0.33
1
06/23/22 08:12
71-55-6
0.32
1
06/23/22 08:12
79-00-5
0.38
1
06/23/22 08:12
79-01-6
0.30
1
06/23/22 08:12
75-69-4
0.26
1
06/23/22 08:12
96-18-4
1.3
1
06/23/22 08:12
108-05-4
0.39
1
06/23/22 08:12
75-01-4
0.34
1
06/23/22 08:12
1330-20-7
1
06/23/22 08:12
460-00-4
1
06/23/22 08:12
17060-07-0
1
06/23/22 08:12
2037-26-5
0.86 1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
06/20/22 20:54 123-91-1
06/20/22 20:54 17060-07-0
06/20/22 20:54 2037-26-5
v1
Page 6 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Sample: SW-2A Lab ID: 92610701002 Collected: 06/16/22 08:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
1.0J
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2217:17
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2217:17
7440-38-2
Barium
125
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2217:17
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2217:17
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2217:17
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2217:17
7440-47-3
Cobalt
6.5
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2217:17
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2217:17
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2217:17
7439-92-1
Nickel
4.0.1
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2217:17
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2217:17
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2217:17
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2217:17
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2217:17
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2217:17
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 08:31
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 08:31
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 08:31
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 08:31
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 08:31
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 08:31
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 08:31
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 08:31
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 08:31
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 08:31
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 08:31
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 08:31
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 08:31
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 08:31
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 08:31
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 08:31
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 08:31
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 08:31
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 08:31
95-50-1
1,4-Dichlorobenzene
0.58J
ug/L
1.0
0.33
1
06/23/22 08:31
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 08:31
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 08:31
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 08:31
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 08:31
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 08:31
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 08:31
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 08:31
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Sample: SW-2A Lab ID: 92610701002 Collected: 06/16/22 08:20 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
E:Y�:i111 e7 �, 6yyL91 �,
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 07/01 /2022 02:47 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
150
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
5.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
101
%
70-130
115
%
70-130
100
%
70-130
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
3.3
ug/L
2.0
96
%
70-130
89
%
70-130
0.36
1
06/23/22 08:31
10061-01-5
0.36
1
06/23/22 08:31
10061-02-6
38.7
1
06/23/22 08:31
123-91-1
0.30
1
06/23/22 08:31
100-41-4
0.48
1
06/23/22 08:31
591-78-6
9.7
1
06/23/22 08:31
74-88-4
2.0
1
06/23/22 08:31
75-09-2
2.7
1
06/23/22 08:31
108-10-1
0.29
1
06/23/22 08:31
100-42-5
0.31
1
06/23/22 08:31
630-20-6
0.22
1
06/23/22 08:31
79-34-5
0.29
1
06/23/22 08:31
127-18-4
0.48
1
06/23/22 08:31
108-88-3
0.33
1
06/23/22 08:31
71-55-6
0.32
1
06/23/22 08:31
79-00-5
0.38
1
06/23/22 08:31
79-01-6
0.30
1
06/23/22 08:31
75-69-4
0.26
1
06/23/22 08:31
96-18-4
1.3
1
06/23/22 08:31
108-05-4
0.39
1
06/23/22 08:31
75-01-4
0.34
1
06/23/22 08:31
1330-20-7
1
06/23/22 08:31
460-00-4
1
06/23/22 08:31
17060-07-0
1
06/23/22 08:31
2037-26-5
0.86 1
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
06/20/22 23:28 123-91-1
06/20/22 23:28 17060-07-0
06/20/22 23:28 2037-26-5
v1
Page 8 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
QC Batch: 705856 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610701001, 92610701002
METHOD BLANK: 3682687
Associated Lab Samples: 92610701001, 92610701002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
3.0
0.78
06/29/2216:41
Arsenic
ug/L
ND
5.0
2.2
06/29/2216:41
Barium
ug/L
ND
5.0
0.67
06/29/2216:41
Beryllium
ug/L
ND
0.50
0.054
06/29/2216:41
Cadmium
ug/L
ND
0.50
0.11
06/29/2216:41
Chromium
ug/L
ND
5.0
1.1
06/29/2216:41
Cobalt
ug/L
ND
5.0
0.39
06/29/2216:41
Copper
ug/L
ND
5.0
1.0
06/29/2216:41
Lead
ug/L
ND
1.0
0.89
06/29/2216:41
Nickel
ug/L
ND
5.0
0.71
06/29/2216:41
Selenium
ug/L
ND
5.0
1.4
06/29/2216:41
Silver
ug/L
ND
5.0
0.44
06/29/2216:41
Thallium
ug/L
ND
1.0
0.18
06/29/2216:41
Vanadium
ug/L
ND
10.0
1.9
06/29/2216:41
Zinc
ug/L
ND
10.0
7.0
06/29/2216:41
LABORATORY CONTROL SAMPLE:
Parameter
3682688
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
106
106
80-120
Arsenic
ug/L
100
99.3
99
80-120
Barium
ug/L
100
102
102
80-120
Beryllium
ug/L
100
101
101
80-120
Cadmium
ug/L
100
101
101
80-120
Chromium
ug/L
100
98.9
99
80-120
Cobalt
ug/L
100
96.6
97
80-120
Copper
ug/L
100
96.6
97
80-120
Lead
ug/L
100
100
100
80-120
Nickel
ug/L
100
98.6
99
80-120
Selenium
ug/L
100
99.3
99
80-120
Silver
ug/L
100
101
101
80-120
Thallium
ug/L
100
98.5
98
80-120
Vanadium
ug/L
100
98.1
98
80-120
Zinc
ug/L
100
101
101
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO MSWLF (SWs)
92610701
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3682689
3682690
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
108
104
108
104
75-125
4
20
Arsenic
ug/L
ND
100
100
101
98.2
101
98
75-125
3
20
Barium
ug/L
515
100
100
594
572
79
57
75-125
4
20 M1
Beryllium
ug/L
ND
100
100
99.3
94.9
99
95
75-125
5
20
Cadmium
ug/L
ND
100
100
103
101
103
101
75-125
2
20
Chromium
ug/L
2.8J
100
100
104
98.0
102
95
75-125
6
20
Cobalt
ug/L
20.9
100
100
118
111
97
90
75-125
6
20
Copper
ug/L
ND
100
100
98.2
92.1
98
92
75-125
6
20
Lead
ug/L
ND
100
100
99.8
97.1
100
97
75-125
3
20
Nickel
ug/L
7.7
100
100
107
100
99
93
75-125
6
20
Selenium
ug/L
ND
100
100
101
97.7
100
98
75-125
3
20
Silver
ug/L
ND
100
100
96.5
95.0
96
95
75-125
2
20
Thallium
ug/L
ND
100
100
100
97.7
100
98
75-125
2
20
Vanadium
ug/L
ND
100
100
104
98.3
104
98
75-125
6
20
Zinc
ug/L
ND
100
100
103
97.2
101
96
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
QC Batch: 706240 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610701001, 92610701002
METHOD BLANK: 3684436
Associated Lab Samples: 92610701001, 92610701002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 05:27
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 05:27
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 05:27
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 05:27
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 05:27
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 05:27
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 05:27
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 05:27
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 05:27
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 05:27
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 05:27
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 05:27
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 05:27
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 05:27
Acetone
ug/L
ND
25.0
5.1
06/23/22 05:27
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 05:27
Benzene
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 05:27
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 05:27
Bromoform
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 05:27 v2
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 05:27
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 05:27
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 05:27
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 05:27
Chloroform
ug/L
ND
1.0
0.43
06/23/22 05:27
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 05:27
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 05:27
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 05:27
lodomethane
ug/L
ND
20.0
9.7
06/23/22 05:27
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 05:27
Styrene
ug/L
ND
1.0
0.29
06/23/22 05:27
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 05:27
Toluene
ug/L
ND
1.0
0.48
06/23/22 05:27
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 20

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
METHOD BLANK: 3684436
Matrix:
Water
Associated Lab Samples: 92610701001, 92610701002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/23/22 05:27
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/23/22 05:27
Trichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/23/22 05:27
Vinyl acetate
ug/L
ND
2.0
1.3
06/23/22 05:27 v1
Vinyl chloride
ug/L
ND
1.0
0.39
06/23/22 05:27
Xylene (Total)
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane-d4 (S)
%
113
70-130
06/23/22 05:27
4-Bromofluorobenzene (S)
%
103
70-130
06/23/22 05:27
Toluene-d8 (S)
%
100
70-130
06/23/22 05:27
LABORATORY CONTROL SAMPLE:
3684437
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.1
106
70-130
1,1,1-Trichloroethane
ug/L
50
55.8
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.4
103
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
57.2
114
70-130
1,1-Dichloroethene
ug/L
50
58.9
118
70-132
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
70-130
1,2-Dichlorobenzene
ug/L
50
51.0
102
70-130
1,2-Dichloroethane
ug/L
50
56.5
113
70-130
1,2-Dichloropropane
ug/L
50
55.8
112
70-130
1,4-Dichlorobenzene
ug/L
50
49.5
99
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
962
96
70-137
2-Butanone (MEK)
ug/L
100
118
118
70-133
2-Hexanone
ug/L
100
110
110
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
107
107
70-130
Acetone
ug/L
100
107
107
70-144
Acrylonitrile
ug/L
250
296
118
70-130
Benzene
ug/L
50
51.3
103
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
54.7
109
70-130
Bromoform
ug/L
50
52.9
106
70-131
Bromomethane
ug/L
50
41.3
83
30-177 v3
Carbon disulfide
ug/L
50
57.2
114
70-133
Carbon tetrachloride
ug/L
50
52.0
104
70-130
Chlorobenzene
ug/L
50
51.0
102
70-130
Chloroethane
ug/L
50
52.0
104
46-131
Chloroform
ug/L
50
57.1
114
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
LABORATORY CONTROL SAMPLE:
Parameter
3684437
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
58.7
cis-1,2-Dichloroethene
ug/L
50
58.2
cis-1,3-Dichloropropene
ug/L
50
55.4
Dibromochloromethane
ug/L
50
53.1
Dibromomethane
ug/L
50
49.5
Ethylbenzene
ug/L
50
52.2
lodomethane
ug/L
100
119
Methylene Chloride
ug/L
50
51.7
Styrene
ug/L
50
51.4
Tetrachloroethene
ug/L
50
47.7
Toluene
ug/L
50
49.5
trans-1,2-Dichloroethene
ug/L
50
59.5
trans- 1,3-Dichloropropene
ug/L
50
55.4
trans-1,4-Dichloro-2-butene
ug/L
50
48.6
Trichloroethene
ug/L
50
51.2
Trichlorofluoromethane
ug/L
50
50.7
Vinyl acetate
ug/L
100
124
Vinyl chloride
ug/L
50
61.6
Xylene (Total)
ug/L
150
158
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
117
49-130
116
70-130
111
70-130
106
70-130
99
70-130
104
70-130
119
47-140
103
68-130
103
70-130
95
70-130
99
70-130
119
70-130
111
70-130
97
25-200
102
70-130
101
61-130
124
70-140 v1
123
59-142
105
70-130
114
70-130
103
70-130
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684438
MS
92610701001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3684439
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
25.6
23.8
128
119
70-135
7
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.8
21.2
114
106
70-148
7
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
24.9
22.8
125
114
70-131
9
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.9
21.3
115
106
70-136
8
30
1,1-Dichloroethane
ug/L
2.5
20
20
23.2
21.4
103
94
70-147
8
30
1,1-Dichloroethene
ug/L
ND
20
20
25.9
24.1
130
120
70-158
7
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.2
22.2
121
111
67-137
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.4
22.5
117
112
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
25.0
22.9
125
114
70-137
9
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.2
23.6
126
118
70-133
6
30
1,2-Dichloroethane
ug/L
ND
20
20
21.4
19.9
107
100
67-138
7
30
1,2-Dichloropropane
ug/L
ND
20
20
22.5
20.4
113
102
70-138
10
30
1,4-Dichlorobenzene
ug/L
2.7
20
20
28.1
27.0
127
122
70-133
4
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
559
540
140
135
69-146
3
30
2-Butanone (MEK)
ug/L
ND
40
40
46.6
43.3
117
108
61-147
7
30
2-Hexanone
ug/L
ND
40
40
49.3
47.3
123
118
67-139
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
44.8
42.2
112
106
67-136
6
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3684438
3684439
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
45.7
43.7
114
109
55-159
4
30
Acrylonitrile
ug/L
ND
100
100
99.5
96.4
100
96
68-140
3
30
Benzene
ug/L
3.3
20
20
25.5
23.8
111
102
67-150
7
30
Bromochloromethane
ug/L
ND
20
20
22.6
21.0
113
105
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
22.1
20.5
111
102
70-138
8
30
Bromoform
ug/L
ND
20
20
20.9
19.1
104
96
57-138
9
30
Bromomethane
ug/L
ND
20
20
36.6
34.5
183
173
10-200
6
30 v1
Carbon disulfide
ug/L
ND
20
20
23.7
22.2
119
111
70-152
7
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
22.8
123
114
70-147
8
30
Chlorobenzene
ug/L
ND
20
20
25.5
23.6
128
118
70-137
8
30
Chloroethane
ug/L
1.8
20
20
41.1
38.2
197
182
51-166
7
30 M1,v1
Chloroform
ug/L
ND
20
20
22.0
20.3
110
102
70-144
8
30
Chloromethane
ug/L
ND
20
20
25.6
23.3
128
116
24-161
10
30
cis-1,2-Dichloroethene
ug/L
1.5
20
20
22.4
20.8
104
96
67-148
7
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.2
19.5
106
98
70-142
8
30
Dibromochloromethane
ug/L
ND
20
20
22.8
21.0
114
105
68-138
8
30
Dibromomethane
ug/L
ND
20
20
24.8
23.0
124
115
70-134
8
30
Ethylbenzene
ug/L
1.1
20
20
25.9
24.1
124
115
68-143
7
30
lodomethane
ug/L
ND
40
40
47.5
43.2
119
108
20-161
9
30
Methylene Chloride
ug/L
ND
20
20
21.0
19.6
105
98
64-148
7
30
Styrene
ug/L
ND
20
20
24.8
22.6
124
113
70-136
9
30
Tetrachloroethene
ug/L
ND
20
20
25.8
23.5
129
118
70-139
9
30
Toluene
ug/L
ND
20
20
23.0
21.3
115
107
47-157
8
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.4
20.4
112
102
70-149
9
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.5
19.9
108
100
70-138
8
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.6
19.2
98
96
31-145
2
30
Trichloroethene
ug/L
ND
20
20
25.0
23.0
125
115
70-149
8
30
Trichlorofluoromethane
ug/L
ND
20
20
29.8
28.2
149
141
61-154
5
30 v1
Vinyl acetate
ug/L
ND
40
40
37.8
36.0
94
90
48-156
5
30
Vinyl chloride
ug/L
1.0
20
20
26.5
24.8
127
119
55-172
6
30
Xylene (Total)
ug/L
6.2
60
60
80.9
74.8
125
114
66-145
8
30
1,2-Dichloroethane-d4 (S)
%
95
96
70-130
4-Bromofluorobenzene (S)
%
95
95
70-130
Toluene-d8 (S)
%
97
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
QC Batch: 705745 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610701001, 92610701002
METHOD BLANK: 3682380
Matrix:
Water
Associated Lab Samples:
92610701001, 92610701002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 06/20/22 18:02
1,2-Dichloroethane-d4 (S)
%
101
70-130
06/20/22 18:02
Toluene-d8 (S)
%
92
70-130
06/20/22 18:02
LABORATORY CONTROL SAMPLE: 3682381
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.5 102 70-130
1,2-Dichloroethane-d4 (S) % 87 70-130
Toluene-d8 (S) % 88 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3682382
3682383
MS
MSD
92610701001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 44.1 20
20 60.2 62.0
80
90
63-136
3 30
1,2-Dichloroethane-d4 (S)
%
112
105
70-130
30
Toluene-d8 (S)
%
92
93
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:47 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: ASHE CO MSWLF (SWs)
Pace Project No.: 92610701
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
Batch
92610701001
SW-2
EPA 3005A
705856 EPA 6020B
706020
92610701002
SW-2A
EPA 3005A
705856 EPA 6020B
706020
92610701001
SW-2
EPA 8260D
706240
92610701002
SW-2A
EPA 8260D
706240
92610701001
SW-2
EPA 8260D Mod.
705745
92610701002
SW-2A
EPA 8260D Mod.
705745
Date: 07/01 /2022 02:47 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 20

A-duu
Effective Date: 05/12/202205/12/2022
Laboratory receiving samples:
Asheville ❑. Eden❑ Greenwood ❑ Huntersville Raleigh[] Meehmni«villen Atlanta❑ Kernersville❑
ConditionSample Client Name: iUpon Receipt Proiert#: WO# : 92610701
Courier: ❑Fed Ex ❑UPS ❑.U5P5
❑ Commercial ❑Race ❑other: 92610701 11 1
Custody Seal Present? [—]Yes o :ubble
ls Inta. 7 []YesQateflnitials Person Examining Contents:
Packing Material: ❑Bubble Wrap Bags ❑None ❑ Other Biological Tissue Frozen?
Thermon; ❑Yes ❑No ❑N/A
IRGunID:
Type of Ice: ❑Wet ❑Blue []Noce
Correction Factor:
Cooler Temp: Add/Subtract(°C) G Tem�sl,ouIdbeabovefreezingto6"C
115arnples out of temp criteria. Samples on ice, cooling process
Cooler Temp CorrectePin
has begun
USDA Regulated Sail (A, water sample)
Did samples originsquarantine zone within the United States: CA, NY, or SC Did sarnples originate from a Foreign source Oternatianajly;
(check maps)? ❑Yes ❑No intruding Hawaii and Puerto Rico)? ❑Yes No
Chain of Custody Present?
es
EJNo
❑N/A
1.
Samples Arrived within. Hold Time?
I
No
❑N!A
2.
Short Hold Time Analysis (<7Z hr.)?
s
❑No
[:]N/A
3.
Rush Turn Around Time Requested?
❑Yes
o
❑N/A
4.
Sufficient Volume?
es
❑Na
❑NJA
5.
Correct Containers Used?
❑No
❑N'A
6.
-Pace Containers. Used?
L94 af�'
[-]No❑NIA
Containers Intact?
Yes
❑
❑NJA
7.
Dissolved analysis: Samples Field Filtered?
❑
ZNo
❑N/A
S.
Sample Labels Match COC?
Yes
❑No
❑N/A
9.
-Includes Date/Tirne/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)? es ❑N ❑N/A 10.
Trip Blank Present? ❑Yes ZNo ❑N/A 11.
Trip Blank Custody Seals Present?
❑Yas p ❑ N/A
COMMENTS/SAMPLE DISCREPANCY If % Fleld Data Required? []Yes ❑No
p
_A J n v�
Lot ID of split containers:
f rcnFrnrnTFr'GATIQPk/RE56ElJfleN
Plenum rontartml' _ _ fate Tinne.
Project Manager SCURF Review:
PrO PaLL r]anagecSIRE Review. --- ---- _ _ --- --- — -
Date;
Qualtrax ID: 69614 Page 18 of 20
Page 1 of 2

I/ Pace -vvv.i vv r ...rarrFvre t.ultuluuu wuri meceipt
Effective Date: 05/12/202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples.
Exceptions: VOA, Cofiform, TDC, oil and Grease, ORO/9015 (water) DOC, Wig
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
2
3
4
5
6
7
8
9
10
11
12
WO#:92610701
Project /f
PM: AMB Due Date: 07/01/22
CLIENT: 92-Municipal
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Page 19 of 20
Qualtrax ID; 69614 Page 2 Of 2

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Page 20 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
June 30, 2022
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
RE: Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on June 17, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a*a-
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 26

laneAnalytical
www,pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Certification #: 381
South Carolina Certification #: 98011001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92610496001
92610496002
LAGOON
LAGOON
Water
Water
06/16/2213:40
06/16/2213:40
06/17/2212:50
06/17/2212:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92610496001 LAGOON
SM 521OB-2016
NFW
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
92610496002 LAGOON
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 365.1 Rev 2.0 1993
SMT
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-GA = Pace Analytical Services - Peachtree Corners, GA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Sample: LAGOON
Lab ID: 92610496001 Collected:
06/16/22 13:40
Received: 06/17/22 12:50 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
5210B BOD, 5 day
Analytical Method: SM 521OB-2016
Pace Analytical Services -Asheville
BOD, 5 day
17100 ug/L 2000
2000 1
06/18/22 06:52 06/23/22 05:11
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0 1
06/17/22 23:59 14797-55-8
Date: 06/30/2022 03:17 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Sample: LAGOON Lab ID: 92610496002 Collected: 06/16/22 13:40 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1
06/22/2212:04
06/25/2218:06
7440-36-0
Arsenic
3.3J
ug/L
5.0
2.2
1
06/22/2212:04
06/25/2218:06
7440-38-2
Barium
1430
ug/L
50.0
6.7
10
06/22/2212:04
06/27/2215:12
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1
06/22/2212:04
06/25/2218:06
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1
06/22/2212:04
06/25/2218:06
7440-43-9
Chromium
5.5
ug/L
5.0
1.1
1
06/22/2212:04
06/27/2213:49
7440-47-3
Cobalt
10.1
ug/L
5.0
0.39
1
06/22/2212:04
06/25/2218:06
7440-48-4
Copper
ND
ug/L
5.0
1.0
1
06/22/2212:04
06/25/2218:06
7440-50-8
Lead
ND
ug/L
1.0
0.89
1
06/22/2212:04
06/25/2218:06
7439-92-1
Nickel
25.6
ug/L
5.0
0.71
1
06/22/2212:04
06/27/2213:49
7440-02-0
Selenium
1.81
ug/L
5.0
1.4
1
06/22/2212:04
06/25/2218:06
7782-49-2
Silver
ND
ug/L
5.0
0.44
1
06/22/2212:04
06/25/2218:06
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1
06/22/2212:04
06/25/2218:06
7440-28-0
Vanadium
4.7.1
ug/L
10.0
1.9
1
06/22/2212:04
06/25/2218:06
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1
06/22/2212:04
06/25/2218:06
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
06/23/22 11:35
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 11:35
107-13-1
Benzene
13.9
ug/L
1.0
0.34
1
06/23/22 11:35
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 11:35
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 11:35
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 11:35
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 11:35
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 11:35
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 11:35
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 11:35
56-23-5
Chlorobenzene
2.1
ug/L
1.0
0.28
1
06/23/22 11:35
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 11:35
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 11:35
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 11:35
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 11:35
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 11:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 11:35
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 11:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 11:35
95-50-1
1,4-Dichlorobenzene
2.9
ug/L
1.0
0.33
1
06/23/22 11:35
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 11:35
110-57-6
1,1-Dichloroethane
0.49J
ug/L
1.0
0.37
1
06/23/22 11:35
75-34-3
1,2-Dichloroethane
0.46J
ug/L
1.0
0.32
1
06/23/22 11:35
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
06/23/22 11:35
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
06/23/22 11:35
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
06/23/22 11:35
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
06/23/22 11:35
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Sample: LAGOON Lab ID: 92610496002 Collected: 06/16/22 13:40 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
E:Y�*111 e7 �, Riy&i I �,
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
300.0 IC Anions 28 Days
Sulfate
365.1 Phosphorus, Total
Phosphorus
5220D COD
Chemical Oxygen Demand
Date: 06/30/2022 03:17 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.36
1
06/23/22 11:35
10061-01-5
ND
ug/L
1.0
0.36
1
06/23/2211:35
10061-02-6
ND
ug/L
150
38.7
1
06/23/2211:35
123-91-1
21.2
ug/L
1.0
0.30
1
06/23/2211:35
100-41-4
ND
ug/L
5.0
0.48
1
06/23/2211:35
591-78-6
ND
ug/L
20.0
9.7
1
06/23/2211:35
74-88-4
ND
ug/L
5.0
2.0
1
06/23/2211:35
75-09-2
ND
ug/L
5.0
2.7
1
06/23/2211:35
108-10-1
ND
ug/L
1.0
0.29
1
06/23/2211:35
100-42-5
ND
ug/L
1.0
0.31
1
06/23/2211:35
630-20-6
ND
ug/L
1.0
0.22
1
06/23/2211:35
79-34-5
ND
ug/L
1.0
0.29
1
06/23/2211:35
127-18-4
2.0
ug/L
1.0
0.48
1
06/23/2211:35
108-88-3
ND
ug/L
1.0
0.33
1
06/23/2211:35
71-55-6
ND
ug/L
1.0
0.32
1
06/23/2211:35
79-00-5
ND
ug/L
1.0
0.38
1
06/23/2211:35
79-01-6
ND
ug/L
1.0
0.30
1
06/23/2211:35
75-69-4
ND
ug/L
1.0
0.26
1
06/23/2211:35
96-18-4
ND
ug/L
2.0
1.3
1
06/23/2211:35
108-05-4
0.72J
ug/L
1.0
0.39
1
06/23/2211:35
75-01-4
31.2
ug/L
1.0
0.34
1
06/23/2211:35
1330-20-7
101
%
70-130
1
06/23/2211:35
460-00-4
114
%
70-130
1
06/23/2211:35
17060-07-0
100
%
70-130
1
06/23/2211:35
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
20.6
ug/L
2.0
0.86
1
06/20/22 23:08
123-91-1
114 % 70-130 1 06/20/22 23:08 17060-07-0
94 % 70-130 1 06/20/22 23:08 2037-26-5
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
8101 ug/L 1000 500 1 06/23/2215:32 14808-79-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.59 mg/L 0.050 0.025 1 06/28/2217:43 06/29/2219:21 7723-14-0
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Pace Analytical Services -Asheville
453000 ug/L 25000 12500 1 06/28/22 01:44 06/28/22 05:29
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 7 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 706160 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610496002
METHOD BLANK: 3684049
Associated Lab Samples: 92610496002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
3.0
0.78
06/25/2216:37
Arsenic
ug/L
ND
5.0
2.2
06/25/2216:37
Barium
ug/L
ND
5.0
0.67
06/25/2216:37
Beryllium
ug/L
ND
0.50
0.054
06/25/2216:37
Cadmium
ug/L
ND
0.50
0.11
06/25/2216:37
Chromium
ug/L
ND
5.0
1.1
06/27/2213:19
Cobalt
ug/L
ND
5.0
0.39
06/25/2216:37
Copper
ug/L
ND
5.0
1.0
06/25/2216:37
Lead
ug/L
ND
1.0
0.89
06/25/2216:37
Nickel
ug/L
ND
5.0
0.71
06/27/2213:19
Selenium
ug/L
ND
5.0
1.4
06/25/2216:37
Silver
ug/L
ND
5.0
0.44
06/25/2216:37
Thallium
ug/L
ND
1.0
0.18
06/25/2216:37
Vanadium
ug/L
ND
10.0
1.9
06/25/2216:37
Zinc
ug/L
ND
10.0
7.0
06/25/2216:37
LABORATORY CONTROL SAMPLE:
Parameter
3684050
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
108
108
80-120
Arsenic
ug/L
100
101
101
80-120
Barium
ug/L
100
101
101
80-120
Beryllium
ug/L
100
103
103
80-120
Cadmium
ug/L
100
98.5
98
80-120
Chromium
ug/L
100
106
106
80-120
Cobalt
ug/L
100
98.3
98
80-120
Copper
ug/L
100
97.1
97
80-120
Lead
ug/L
100
98.4
98
80-120
Nickel
ug/L
100
103
103
80-120
Selenium
ug/L
100
101
101
80-120
Silver
ug/L
100
100
100
80-120
Thallium
ug/L
100
99.0
99
80-120
Vanadium
ug/L
100
105
105
80-120
Zinc
ug/L
100
97.9
98
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO LEACHATE
92610496
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3684383
3684384
MS
MSD
92607724001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
101
105
101
104
75-125
3
20
Arsenic
ug/L
ND
100
100
102
102
99
100
75-125
1
20
Barium
ug/L
136
100
100
237
239
101
103
75-125
1
20
Beryllium
ug/L
ND
100
100
93.2
93.8
93
93
75-125
1
20
Cadmium
ug/L
ND
100
100
99.1
99.8
99
100
75-125
1
20
Chromium
ug/L
9.8
100
100
112
113
102
103
75-125
1
20
Cobalt
ug/L
11.7
100
100
115
112
103
101
75-125
2
20
Copper
ug/L
399
100
100
505
509
107
111
75-125
1
20
Lead
ug/L
ND
100
100
107
108
97
99
75-125
1
20
Nickel
ug/L
7.5
100
100
108
107
100
99
75-125
1
20
Selenium
ug/L
ND
100
100
100
102
99
101
75-125
2
20
Silver
ug/L
ND
100
100
99.2
101
99
100
75-125
1
20
Thallium
ug/L
0.191
100
100
97.1
99.2
97
99
75-125
2
20
Vanadium
ug/L
31.4
100
100
140
140
108
109
75-125
0
20
Zinc
ug/L
35.3
100
100
143
141
107
106
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 706240 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610496002
METHOD BLANK: 3684436
Associated Lab Samples: 92610496002
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 05:27
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 05:27
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 05:27
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 05:27
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 05:27
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 05:27
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 05:27
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 05:27
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 05:27
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 05:27
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 05:27
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 05:27
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 05:27
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 05:27
Acetone
ug/L
ND
25.0
5.1
06/23/22 05:27
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 05:27
Benzene
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 05:27
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 05:27
Bromoform
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 05:27 v2
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 05:27
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 05:27
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 05:27
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 05:27
Chloroform
ug/L
ND
1.0
0.43
06/23/22 05:27
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 05:27
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 05:27
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 05:27
lodomethane
ug/L
ND
20.0
9.7
06/23/22 05:27
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 05:27
Styrene
ug/L
ND
1.0
0.29
06/23/22 05:27
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 05:27
Toluene
ug/L
ND
1.0
0.48
06/23/22 05:27
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 26

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
METHOD BLANK: 3684436
Matrix:
Water
Associated Lab Samples: 92610496002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/23/22 05:27
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/23/22 05:27
Trichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/23/22 05:27
Vinyl acetate
ug/L
ND
2.0
1.3
06/23/22 05:27 v1
Vinyl chloride
ug/L
ND
1.0
0.39
06/23/22 05:27
Xylene (Total)
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane-d4 (S)
%
113
70-130
06/23/22 05:27
4-Bromofluorobenzene (S)
%
103
70-130
06/23/22 05:27
Toluene-d8 (S)
%
100
70-130
06/23/22 05:27
LABORATORY CONTROL SAMPLE: 3684437
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.1
106
70-130
1,1,1-Trichloroethane
ug/L
50
55.8
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.4
103
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
57.2
114
70-130
1,1-Dichloroethene
ug/L
50
58.9
118
70-132
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
70-130
1,2-Dichlorobenzene
ug/L
50
51.0
102
70-130
1,2-Dichloroethane
ug/L
50
56.5
113
70-130
1,2-Dichloropropane
ug/L
50
55.8
112
70-130
1,4-Dichlorobenzene
ug/L
50
49.5
99
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
962
96
70-137
2-Butanone (MEK)
ug/L
100
118
118
70-133
2-Hexanone
ug/L
100
110
110
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
107
107
70-130
Acetone
ug/L
100
107
107
70-144
Acrylonitrile
ug/L
250
296
118
70-130
Benzene
ug/L
50
51.3
103
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
54.7
109
70-130
Bromoform
ug/L
50
52.9
106
70-131
Bromomethane
ug/L
50
41.3
83
30-177 v3
Carbon disulfide
ug/L
50
57.2
114
70-133
Carbon tetrachloride
ug/L
50
52.0
104
70-130
Chlorobenzene
ug/L
50
51.0
102
70-130
Chloroethane
ug/L
50
52.0
104
46-131
Chloroform
ug/L
50
57.1
114
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
LABORATORY CONTROL SAMPLE:
Parameter
3684437
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
58.7
cis-1,2-Dichloroethene
ug/L
50
58.2
cis-1,3-Dichloropropene
ug/L
50
55.4
Dibromochloromethane
ug/L
50
53.1
Dibromomethane
ug/L
50
49.5
Ethylbenzene
ug/L
50
52.2
lodomethane
ug/L
100
119
Methylene Chloride
ug/L
50
51.7
Styrene
ug/L
50
51.4
Tetrachloroethene
ug/L
50
47.7
Toluene
ug/L
50
49.5
trans-1,2-Dichloroethene
ug/L
50
59.5
trans- 1,3-Dichloropropene
ug/L
50
55.4
trans-1,4-Dichloro-2-butene
ug/L
50
48.6
Trichloroethene
ug/L
50
51.2
Trichlorofluoromethane
ug/L
50
50.7
Vinyl acetate
ug/L
100
124
Vinyl chloride
ug/L
50
61.6
Xylene (Total)
ug/L
150
158
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
117
49-130
116
70-130
111
70-130
106
70-130
99
70-130
104
70-130
119
47-140
103
68-130
103
70-130
95
70-130
99
70-130
119
70-130
111
70-130
97
25-200
102
70-130
101
61-130
124
70-140 v1
123
59-142
105
70-130
114
70-130
103
70-130
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684438
MS
92610701001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3684439
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
25.6
23.8
128
119
70-135
7
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.8
21.2
114
106
70-148
7
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
24.9
22.8
125
114
70-131
9
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.9
21.3
115
106
70-136
8
30
1,1-Dichloroethane
ug/L
2.5
20
20
23.2
21.4
103
94
70-147
8
30
1,1-Dichloroethene
ug/L
ND
20
20
25.9
24.1
130
120
70-158
7
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.2
22.2
121
111
67-137
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.4
22.5
117
112
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
25.0
22.9
125
114
70-137
9
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.2
23.6
126
118
70-133
6
30
1,2-Dichloroethane
ug/L
ND
20
20
21.4
19.9
107
100
67-138
7
30
1,2-Dichloropropane
ug/L
ND
20
20
22.5
20.4
113
102
70-138
10
30
1,4-Dichlorobenzene
ug/L
2.7
20
20
28.1
27.0
127
122
70-133
4
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
559
540
140
135
69-146
3
30
2-Butanone (MEK)
ug/L
ND
40
40
46.6
43.3
117
108
61-147
7
30
2-Hexanone
ug/L
ND
40
40
49.3
47.3
123
118
67-139
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
44.8
42.2
112
106
67-136
6
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3684438
3684439
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
45.7
43.7
114
109
55-159
4
30
Acrylonitrile
ug/L
ND
100
100
99.5
96.4
100
96
68-140
3
30
Benzene
ug/L
3.3
20
20
25.5
23.8
111
102
67-150
7
30
Bromochloromethane
ug/L
ND
20
20
22.6
21.0
113
105
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
22.1
20.5
111
102
70-138
8
30
Bromoform
ug/L
ND
20
20
20.9
19.1
104
96
57-138
9
30
Bromomethane
ug/L
ND
20
20
36.6
34.5
183
173
10-200
6
30 v1
Carbon disulfide
ug/L
ND
20
20
23.7
22.2
119
111
70-152
7
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
22.8
123
114
70-147
8
30
Chlorobenzene
ug/L
ND
20
20
25.5
23.6
128
118
70-137
8
30
Chloroethane
ug/L
1.8
20
20
41.1
38.2
197
182
51-166
7
30 M1,v1
Chloroform
ug/L
ND
20
20
22.0
20.3
110
102
70-144
8
30
Chloromethane
ug/L
ND
20
20
25.6
23.3
128
116
24-161
10
30
cis-1,2-Dichloroethene
ug/L
1.5
20
20
22.4
20.8
104
96
67-148
7
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.2
19.5
106
98
70-142
8
30
Dibromochloromethane
ug/L
ND
20
20
22.8
21.0
114
105
68-138
8
30
Dibromomethane
ug/L
ND
20
20
24.8
23.0
124
115
70-134
8
30
Ethylbenzene
ug/L
1.1
20
20
25.9
24.1
124
115
68-143
7
30
lodomethane
ug/L
ND
40
40
47.5
43.2
119
108
20-161
9
30
Methylene Chloride
ug/L
ND
20
20
21.0
19.6
105
98
64-148
7
30
Styrene
ug/L
ND
20
20
24.8
22.6
124
113
70-136
9
30
Tetrachloroethene
ug/L
ND
20
20
25.8
23.5
129
118
70-139
9
30
Toluene
ug/L
ND
20
20
23.0
21.3
115
107
47-157
8
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.4
20.4
112
102
70-149
9
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.5
19.9
108
100
70-138
8
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.6
19.2
98
96
31-145
2
30
Trichloroethene
ug/L
ND
20
20
25.0
23.0
125
115
70-149
8
30
Trichlorofluoromethane
ug/L
ND
20
20
29.8
28.2
149
141
61-154
5
30 v1
Vinyl acetate
ug/L
ND
40
40
37.8
36.0
94
90
48-156
5
30
Vinyl chloride
ug/L
1.0
20
20
26.5
24.8
127
119
55-172
6
30
Xylene (Total)
ug/L
6.2
60
60
80.9
74.8
125
114
66-145
8
30
1,2-Dichloroethane-d4 (S)
%
95
96
70-130
4-Bromofluorobenzene (S)
%
95
95
70-130
Toluene-d8 (S)
%
97
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 705745 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610496002
METHOD BLANK: 3682380
Matrix:
Water
Associated Lab Samples: 92610496002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
0.86 06/20/22 18:02
1,2-Dichloroethane-d4 (S)
%
101
70-130
06/20/22 18:02
Toluene-d8 (S)
%
92
70-130
06/20/22 18:02
LABORATORY CONTROL SAMPLE: 3682381
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.5 102 70-130
1,2-Dichloroethane-d4 (S) % 87 70-130
Toluene-d8 (S) % 88 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3682382
3682383
MS
MSD
92610701001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 44.1 20
20 60.2 62.0
80
90
63-136
3 30
1,2-Dichloroethane-d4 (S)
%
112
105
70-130
30
Toluene-d8 (S)
%
92
93
70-130
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 705435 Analysis Method: SM 521 OB-2016
QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610496001
METHOD BLANK: 3680978
Matrix:
Water
Associated Lab Samples: 92610496001
Blank
Reporting
Parameter
Units
Result
Limit
BOD, 5 day
ug/L
ND
2000
LABORATORY CONTROL SAMPLE:
3680980
Spike
LCS
Parameter
Units
Conc.
Result
BOD, 5 day
ug/L
198000
185000
SAMPLE DUPLICATE: 3680981
92610555001
Dup
Parameter
Units
Result
Result
BOD, 5 day
ug/L
112 mg/L
143000
MDL Analyzed Qualifiers
2000 06/23/22 04:45
LCS % Rec
% Rec Limits Qualifiers
94 84.6-115
Max
RPD RPD Qualifiers
25 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 706343 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610496002
METHOD BLANK: 3685186
Matrix:
Water
Associated Lab Samples: 92610496002
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Sulfate
ug/L
ND
1000
500 06/22/22 23:52
LABORATORY CONTROL SAMPLE:
3685187
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Sulfate
ug/L
50000
51800 104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3685188 3685189
MS MSD
92610903002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 87.9 mg/L 50000 50000 109000 108000 42 41 90-110 1 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 705422 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610496001
METHOD BLANK: 3680952
Associated Lab Samples: 92610496001
Parameter Units
Nitrogen, Nitrate ug/L
LABORATORY CONTROL SAMPLE: 3680953
Parameter Units
Nitrogen, Nitrate ug/L
Matrix: Water
Blank Reporting
Result Limit
ND 40.0
Spike LCS
Conc. Result
1500 1480
MDL Analyzed Qualifiers
10.0 06/17/22 23:55
LCS % Rec
% Rec Limits Qualifiers
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3680954 3680955
MS MSD
92610496001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 1060 1050 71 70 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 707447 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610496002
METHOD BLANK: 3689950
Associated Lab Samples: 92610496002
Parameter Units
Phosphorus mg/L
LABORATORY CONTROL SAMPLE: 3689951
Parameter Units
Phosphorus mg/L
Matrix: Water
Blank Reporting
Result Limit
ND 0.050
Spike LCS
Conc. Result
2.5 2.6
MDL Analyzed Qualifiers
0.025 06/29/2219:06
LCS % Rec
% Rec Limits Qualifiers
104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3689952 3689953
MS MSD
92610377001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/L 2.9 2.5 2.5 5.6 5.6 107 109 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3689954 3689955
MS MSD
92610437001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Phosphorus mg/L 0.069 2.5 2.5 2.7 2.7 106 106 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 26

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
QC Batch: 707273 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92610496002
METHOD BLANK: 3689280 Matrix: Water
Associated Lab Samples: 92610496002
Blank Reporting
Parameter Units Result Limit
Chemical Oxygen Demand ug/L ND 25000
LABORATORY CONTROL SAMPLE: 3689281
Spike LCS
Parameter Units Conc. Result
Chemical Oxygen Demand ug/L 750000 771000
MDL Analyzed Qualifiers
12500 06/28/22 05:26
LCS % Rec
% Rec Limits Qualifiers
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3689282 3689283
MS MSD
92610503002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 52.2 mg/L 100000 100000 145000 159000 93 107 90-110 9 3 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3689284
3689285
MS
MSD
92611297001
Spike
Spike
MS MSD MS MSD % Rec Max
Parameter Units Result
Conc.
Conc.
Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 12100
100000
100000
1190000 1190000 -232 -186 90-110 0 3 M1
mg/L
0 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 26

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/30/2022 03:17 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 26

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: ASHE CO LEACHATE
Pace Project No.: 92610496
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92610496002
LAGOON
EPA 3005A
706160
EPA 6020B
706279
92610496002
LAGOON
EPA 8260D
706240
92610496002
LAGOON
EPA 8260D Mod.
705745
92610496001
LAGOON
SM 521OB-2016
705435
SM 521OB-2016
705448
92610496002
LAGOON
EPA 300.0 Rev 2.1 1993
706343
92610496001
LAGOON
EPA 353.2 Rev 2.0 1993
705422
92610496002
LAGOON
EPA 365.1 Rev 2.0 1993
707447
EPA 365.1 Rev 2.0 1993
707522
92610496002
LAGOON
SM 5220D-2011
707273
SM 5220D-2011
707280
Date: 06/30/2022 03:17 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 26

,fra,,�� GE' DC## Title: ENV-FRM-HUN1-0083 v01 TSample Condition Upon Receipt
Effective Date: 05/121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Ralelgh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
ConditionSample Client e:
Upon Receipt M V / Z, project #: W0# : 92:610496
❑Courier: ❑Fe Ex ❑UPS CUSPS [:]Client 11111111111111111111111111111111111111
Commercial ace ❑Other:
s261a-4s6
Custody Seal present? [—]Yes FINo seals Intact? ❑Yes 2INo L
Packing Material: ❑Bubble Wrap ubble Bags ❑None ❑ Other
Thermometer: � � "I'
`.. .
Gun iD; 'F"f/� Type of Ice: el -]Blue
Correction factor:
Cooler Temp: J Add/Subtract�('C)
Cooler Temp Corrected ('Cl;,-- v e
USDA Regulated Sail ( N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC
(check maos)? ❑lYes MNo
Date/Initials Person Examining Contents
Biological Tissue Fr n?
❑Yes []No /A
❑None
Temp should be above freezing to VC
[]Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
Comments/Discrepancy:
Chain of Custody Present?
Ycs
❑No
❑N/A
1,
Samples Arrived within Hold Time?
es
No
[I N/A
2.
Short Hold Time Analysis (02 hr.)?
2 es
❑No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
o
❑N/A
4.
Sufficient Volume?
es
El No
[]N/A
S.
Correct Containers Used?
-Pace Containers Used?
s
s
❑No
[]No
❑N/A
❑N/A
6.
Containers Intact?
es
❑No
❑N/
7,
Dissolved analysis: Samples Field Filtered?
[]Yes
[:]No
N/A
8,
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
Yes
v J
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
[I Yes
❑No
N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
o
❑No
❑N/A -
/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manages SRF Review:
Lot ID of split containers:
Rate/Time:
Date:
Date:
Field Data Required? ❑Yes []No
Page 22 of 26
Qualtrax ID: 69614 Pagel 01`2

uUT—Title; ENV-FRM-HUN1-0083 v01 Sample C
V ampondition Upon Receipt
ce — .
Effective Date: 05/121202205/12/2022
*Check mark top half of box if pH and/or clechlorination is verified and project k WO�� ; �L'6 i V�T.JV
within the acceptance range for preservation samples.
Exceptions: VOA, Coliform, roc, Oil and Grease, DRO/8015 [water) DOC, LLHg PM: 101I18 Due Date: 07/01/22
*"Bottom half of box is to list number of bottles MEW: 92—Municipal
***Check all unpreserved Nitrates for chlorine
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7
a
a
_
Q
?
N
S
O
A
J
E
O
N
D
to
a
z
A
?
m
Z
m
a
j
E
Q
E
O
V
]
M
o
1
I
2
3
4
5
6
7
8
4
10
11
12
PH Adjustment Log for Preserved Samples
Sample [D Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot q
adf listed added
0
Nate: Wheaevei& Were is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (Le.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 23 of 26
Qualtrax ID: 69614 Page 2 of 2

Effective Date: 05/12/202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Hurttersville Raleigh❑ Mechanicsville[] Atlanta❑ Kernersviile❑
SamUP011 Receipt
• ' Condition Client Dame: r WO# : 92s 1049fi
�(i �i Project #:
Courler: []Fed Ex OURS ❑USPS nt PM: AMB Due Date: 07/01/22
❑Commercial ❑Pace ❑Other: CLIENT: 82—Municipal
Custody Seal Present? [-]Yes a Seals Inta ? []yes
Date/Initials Person Examining Contents:
Packing Material: _- ❑Bubhfe Wrap ubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermomet' Dyes []No ❑N/A
IA Gunie_ fV
Type of Ice: ❑4Uet ❑Blue ❑None
y Correction Factor:
Cooler Temp: Add/Subtract (°CJ l J
Temp slsould beabove freezing to 6°C
ElSarnples out of temp criteria. Samples on ice, cooling process
Cooler Temp Correcte j°C : has begun
USDA Regulated Soil ( A, water sample)
Did samples origina in a quarantine zone within the United States: CA, NY, or SC Did samples originate from a foreign source (internationally;
(check maps)?❑Yes ❑No including Hawaii and Puerto Rico)? ❑Yes ONO
Chain. of Custody Present?
ja es
❑No
❑N/A
1.
Samples Arrived within. Hold Time?
Lis
No
[I N/A
2.
Short Hold Time Analysis (02 hr.)?
s
El
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
a
❑N/A
4.
Sufficient Volume?
es
❑Nn
❑N/A
S.
Correct Containers Used?
Giew,❑No
❑N/A
6.
-Pace Containers Used?
[]No
❑N/A
Containers intact?
y..
❑
❑N/A
?
Dissolved analysis: Samples Field Filtered?
❑ s
ONO
❑N/A
8..
Sample -Labels Match COE?
Yes
[]No
[-]NIA
9.
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials{>5-6mm)? es ©N ❑N/A 10.
Trip Blank Present? ❑Yes NQ ❑N/A 11.
Trip Blank Custody Seals Present? ❑Yes n ❑N/A
COMMENTS/SAMPLE DISCREPANCY / Field Data Required? Oyes ❑ND
�m6 ,.,w
vJ
Lot ID of split containers:
—�LtEarr-Harirls�7t�a�;�t�salrt�IeiV .
PRrcon contacted Qa,teil fine:
Project Manager SCURF Review:
ProjeaM,ariager-SRE.Review. — - -_..---
Date:
Qualtrax I©:69614
Page T of 2 Page 24 of 26

Pace��. r-........ vv F 00IIFiJIC LUFIUItI(JII VIVU11 MUCelp[
Effective Date: 05/12/202205/12/2022
"Check mark top }calf of box if pH and/or dechlorination is verified and project y
within the acceptance range for preservation samples,
Exceptions: VOA, Coliform, TDC, Oil and Grease, OACIAOI5 {water) DOC, Wig
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
u 0 ij QJ = a
z z z _ z a z
Z ry ry 2 nr �
i a V T n = v N Z N v
m v x a
N ar a v o v o a z
CL a a m O p x m m a a a O Q
7 c r4 = z Oro a 0. C �� Z 2
V V V J x N z -0 =
J U L V t y Z U
N N ro N N •� N N 7 a a R A =
a aC a a CL a a E E Q E ¢ Q
E E E 4 E E J wo Q Q E Q J
in o o a; E E E o " E y E E
N O N .., O O E
H N tan A I'+! 1�y N ri fV ,� to n1 0
D J 7 Y7 Z N m LL 7 2 R
a a a a a n "� a .i
m m m co@ m 3 a a a a a (D p
� t
z
3
4
5
6
7
3
9
10
11
12
PH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon recelpt Date preservation adjusted Time preservation Amount of Pre servative
adjusted added
Note:-WhettevtirtlT@Tai�8lscrepancyaT ec ing o h-Caroling tantF
Out of hold, incorrect preservative, out of temp, incorrect containers.
L) 4
n z
rA ? M
o Z z
N `I fp 61
N
2 C C CL
z a
u w _w
M
¢ 15
Z E
E E J Q
LM O O O O
rA N 7
M in
ca Q ? . O
Lot H
a copy of this Form will be sent to the North Carolina DENR Certification Office (i.e.
Page 25 of 26
Qualtrax ID: 69614 Page 2 of 2

i
i
A 7 m 4 F ;a rn
7
n
N
i
i O r0 m �1 QF rJ1 A W (y i
ITEM #
0 r✓
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n n
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a
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fll
m p
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r
w OyD�pm v� �g�a
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o m a o a ai
0 a
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D
MATRIX CODE (see valid codes to left)
=° o R
u
SAMPLE TYPE (G=GRAB C=COMP)
y 3
o
m
A
o
m
'-2
L
m 3
m x
O
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s
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SAMPLE TEMP AT COLLECTION
N c
N �
m
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NOF CONTAINERS
D
y u m n 0 g t m i1
m ro m a 3 o '�
m
Unprewvad
."-
v O y m o B. y N
v
H2SO4
fp' ' 0 m
d o 0
HNO3
� m
m Rdo
N
w7 a m r
HCI N
n 0
NaOH v
o C
ry
Na2S203 CD
a K
Methanol
ITT
m
Other
D a
Analyses Test YIN
73
C
in X
Q
5
i
x
VOC by 8260
m T y
mz
x
1, 4 Rioxere by 8260 SIM
" C
A O Q
x
Total Metals-ARp
7
3 o CL
rt
0o
c y
n
x
BOO 5-day
a N D
�1
x
CODCr
1
yy''
y
t7
x
Phosphorus, Total
Or 0
b (1
y
~
ro
x
Turbddily
v
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= CD
w
Nilrale
'
`
x
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a a
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y
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am
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TEMP in C
W y
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A
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a
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Intact
Page 26 of 26
b

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
July 01, 2022
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
RE: Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on June 17, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
a*a` `yl. L�orU
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
CERTIFICATIONS
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
VirginiaNELAP Certification #: 460221
North Carolina Certification #: 381
South Carolina Certification #: 98011001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92610702001
92610702002
EB
FB
Water
Water
06/16/2214:10
06/16/2214:05
06/17/2212:50
06/17/2212:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92610702001 EB
EPA6020B
CW1
15
PASI-GA
EPA 7470A
VB
1
PASI-GA
EPA 8260D
CL
51
PASI-C
92610702002 FB
EPA 8260D
CL
51
PASI-C
PASI-C = Pace Analytical Services - Charlotte
PASI-GA = Pace Analytical Services - Peachtree Corners, GA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Sample: EB Lab ID: 92610702001 Collected: 06/16/22 14:10 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 06/21/2213:52
06/29/2217:23
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 06/21/2213:52
06/29/2217:23
7440-38-2
Barium
ND
ug/L
5.0
0.67
1 06/21/2213:52
06/29/2217:23
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 06/21/2213:52
06/29/2217:23
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 06/21/2213:52
06/29/2217:23
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 06/21/2213:52
06/29/2217:23
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 06/21/2213:52
06/29/2217:23
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 06/21/2213:52
06/29/2217:23
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 06/21/2213:52
06/29/2217:23
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1 06/21/2213:52
06/29/2217:23
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 06/21/2213:52
06/29/2217:23
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 06/21/2213:52
06/29/2217:23
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 06/21/2213:52
06/29/2217:23
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 06/21/2213:52
06/29/2217:23
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 06/21/2213:52
06/29/2217:23
7440-66-6
7470 Mercury
Analytical Method: EPA 7470A Preparation Method: EPA
7470A
Pace Analytical Services
- Peachtree Corners, GA
Mercury
ND
ug/L
0.20
0.13
1 06/28/22 15:15
06/29/22 09:50
7439-97-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
5.6J
ug/L
25.0
5.1
1
06/23/22 05:45
67-64-1 CO
Acrylonitrile
ND
ug/L
10.0
1.8
1
06/23/22 05:45
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
06/23/22 05:45
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
06/23/22 05:45
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
06/23/22 05:45
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
06/23/22 05:45
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
06/23/22 05:45
74-83-9 v2
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
06/23/22 05:45
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
06/23/22 05:45
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
06/23/22 05:45
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
06/23/22 05:45
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
06/23/22 05:45
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
06/23/22 05:45
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
06/23/22 05:45
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
06/23/22 05:45
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
06/23/22 05:45
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
06/23/22 05:45
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
06/23/22 05:45
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
06/23/22 05:45
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
06/23/22 05:45
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
06/23/22 05:45
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
06/23/22 05:45
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
06/23/22 05:45
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Sample: EB Lab ID: 92610702001 Collected: 06/16/22 14:10 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 07/01 /2022 02:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.35
1
06/23/22 05:45
75-35-4
ND
ug/L
1.0
0.38
1
06/23/22 05:45
156-59-2
ND
ug/L
1.0
0.40
1
06/23/22 05:45
156-60-5
ND
ug/L
1.0
0.36
1
06/23/22 05:45
78-87-5
ND
ug/L
1.0
0.36
1
06/23/22 05:45
10061-01-5
ND
ug/L
1.0
0.36
1
06/23/22 05:45
10061-02-6
ND
ug/L
150
38.7
1
06/23/22 05:45
123-91-1
ND
ug/L
1.0
0.30
1
06/23/22 05:45
100-41-4
ND
ug/L
5.0
0.48
1
06/23/22 05:45
591-78-6
ND
ug/L
20.0
9.7
1
06/23/22 05:45
74-88-4
2.1J
ug/L
5.0
2.0
1
06/23/22 05:45
75-09-2
ND
ug/L
5.0
2.7
1
06/23/22 05:45
108-10-1
ND
ug/L
1.0
0.29
1
06/23/22 05:45
100-42-5
ND
ug/L
1.0
0.31
1
06/23/22 05:45
630-20-6
ND
ug/L
1.0
0.22
1
06/23/22 05:45
79-34-5
ND
ug/L
1.0
0.29
1
06/23/22 05:45
127-18-4
ND
ug/L
1.0
0.48
1
06/23/22 05:45
108-88-3
ND
ug/L
1.0
0.33
1
06/23/22 05:45
71-55-6
ND
ug/L
1.0
0.32
1
06/23/22 05:45
79-00-5
ND
ug/L
1.0
0.38
1
06/23/22 05:45
79-01-6
ND
ug/L
1.0
0.30
1
06/23/22 05:45
75-69-4
ND
ug/L
1.0
0.26
1
06/23/22 05:45
96-18-4
ND
ug/L
2.0
1.3
1
06/23/22 05:45
108-05-4
ND
ug/L
1.0
0.39
1
06/23/22 05:45
75-01-4
ND
ug/L
1.0
0.34
1
06/23/22 05:45
1330-20-7
101
%
70-130
1
06/23/22 05:45
460-00-4
113
%
70-130
1
06/23/22 05:45
17060-07-0
100
%
70-130
1
06/23/22 05:45
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
CO,C9
v1
Page 6 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Sample: FB Lab ID: 92610702002 Collected: 06/16/22 14:05 Received: 06/17/22 12:50 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Date: 07/01 /2022 02:48 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
5.6J
ug/L
25.0
5.1
1
06/23/22 06:03
67-64-1 CO
ND
ug/L
10.0
1.8
1
06/23/22 06:03
107-13-1
ND
ug/L
1.0
0.34
1
06/23/22 06:03
71-43-2
ND
ug/L
1.0
0.47
1
06/23/22 06:03
74-97-5
ND
ug/L
1.0
0.31
1
06/23/22 06:03
75-27-4
ND
ug/L
1.0
0.34
1
06/23/22 06:03
75-25-2
ND
ug/L
2.0
1.7
1
06/23/22 06:03
74-83-9 v2
ND
ug/L
5.0
4.0
1
06/23/22 06:03
78-93-3
ND
ug/L
2.0
0.36
1
06/23/22 06:03
75-15-0
ND
ug/L
1.0
0.33
1
06/23/22 06:03
56-23-5
ND
ug/L
1.0
0.28
1
06/23/22 06:03
108-90-7
ND
ug/L
1.0
0.65
1
06/23/22 06:03
75-00-3
ND
ug/L
1.0
0.43
1
06/23/22 06:03
67-66-3
ND
ug/L
1.0
0.54
1
06/23/22 06:03
74-87-3
ND
ug/L
2.0
0.34
1
06/23/22 06:03
96-12-8
ND
ug/L
1.0
0.36
1
06/23/22 06:03
124-48-1
ND
ug/L
1.0
0.27
1
06/23/22 06:03
106-93-4
ND
ug/L
1.0
0.39
1
06/23/22 06:03
74-95-3
ND
ug/L
1.0
0.34
1
06/23/22 06:03
95-50-1
ND
ug/L
1.0
0.33
1
06/23/22 06:03
106-46-7
ND
ug/L
1.0
0.56
1
06/23/22 06:03
110-57-6
ND
ug/L
1.0
0.37
1
06/23/22 06:03
75-34-3
ND
ug/L
1.0
0.32
1
06/23/22 06:03
107-06-2
ND
ug/L
1.0
0.35
1
06/23/22 06:03
75-35-4
ND
ug/L
1.0
0.38
1
06/23/22 06:03
156-59-2
ND
ug/L
1.0
0.40
1
06/23/22 06:03
156-60-5
ND
ug/L
1.0
0.36
1
06/23/22 06:03
78-87-5
ND
ug/L
1.0
0.36
1
06/23/22 06:03
10061-01-5
ND
ug/L
1.0
0.36
1
06/23/22 06:03
10061-02-6
ND
ug/L
150
38.7
1
06/23/22 06:03
123-91-1
ND
ug/L
1.0
0.30
1
06/23/22 06:03
100-41-4
ND
ug/L
5.0
0.48
1
06/23/22 06:03
591-78-6
ND
ug/L
20.0
9.7
1
06/23/22 06:03
74-88-4
2.2J
ug/L
5.0
2.0
1
06/23/22 06:03
75-09-2 CO,C9
ND
ug/L
5.0
2.7
1
06/23/22 06:03
108-10-1
ND
ug/L
1.0
0.29
1
06/23/22 06:03
100-42-5
ND
ug/L
1.0
0.31
1
06/23/22 06:03
630-20-6
ND
ug/L
1.0
0.22
1
06/23/22 06:03
79-34-5
ND
ug/L
1.0
0.29
1
06/23/22 06:03
127-18-4
ND
ug/L
1.0
0.48
1
06/23/22 06:03
108-88-3
ND
ug/L
1.0
0.33
1
06/23/22 06:03
71-55-6
ND
ug/L
1.0
0.32
1
06/23/22 06:03
79-00-5
ND
ug/L
1.0
0.38
1
06/23/22 06:03
79-01-6
ND
ug/L
1.0
0.30
1
06/23/22 06:03
75-69-4
ND
ug/L
1.0
0.26
1
06/23/22 06:03
96-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
Sample: FB
Parameters
Lab ID:
Results
92610702002
Units
Collected:
Report
Limit
06/16/22 14:05
MDL DF
Received: 06/17/22 12:50 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Vinyl acetate
ND
ug/L
2.0
1.3 1
06/23/22 06:03
108-05-4 v1
Vinyl chloride
ND
ug/L
1.0
0.39 1
06/23/22 06:03
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34 1
06/23/22 06:03
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
06/23/22 06:03
460-00-4
1,2-Dichloroethane-d4 (S)
113
%
70-130
1
06/23/22 06:03
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
06/23/22 06:03
2037-26-5
Date: 07/01 /2022 02:48 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
QC Batch: 705856 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610702001
METHOD BLANK: 3682687
Associated Lab Samples: 92610702001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
3.0
0.78
06/29/2216:41
Arsenic
ug/L
ND
5.0
2.2
06/29/2216:41
Barium
ug/L
ND
5.0
0.67
06/29/2216:41
Beryllium
ug/L
ND
0.50
0.054
06/29/2216:41
Cadmium
ug/L
ND
0.50
0.11
06/29/2216:41
Chromium
ug/L
ND
5.0
1.1
06/29/2216:41
Cobalt
ug/L
ND
5.0
0.39
06/29/2216:41
Copper
ug/L
ND
5.0
1.0
06/29/2216:41
Lead
ug/L
ND
1.0
0.89
06/29/2216:41
Nickel
ug/L
ND
5.0
0.71
06/29/2216:41
Selenium
ug/L
ND
5.0
1.4
06/29/2216:41
Silver
ug/L
ND
5.0
0.44
06/29/2216:41
Thallium
ug/L
ND
1.0
0.18
06/29/2216:41
Vanadium
ug/L
ND
10.0
1.9
06/29/2216:41
Zinc
ug/L
ND
10.0
7.0
06/29/2216:41
LABORATORY CONTROL SAMPLE:
Parameter
3682688
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
100
106
106
80-120
Arsenic
ug/L
100
99.3
99
80-120
Barium
ug/L
100
102
102
80-120
Beryllium
ug/L
100
101
101
80-120
Cadmium
ug/L
100
101
101
80-120
Chromium
ug/L
100
98.9
99
80-120
Cobalt
ug/L
100
96.6
97
80-120
Copper
ug/L
100
96.6
97
80-120
Lead
ug/L
100
100
100
80-120
Nickel
ug/L
100
98.6
99
80-120
Selenium
ug/L
100
99.3
99
80-120
Silver
ug/L
100
101
101
80-120
Thallium
ug/L
100
98.5
98
80-120
Vanadium
ug/L
100
98.1
98
80-120
Zinc
ug/L
100
101
101
80-120
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
ASHE CO MSWLF BLANKS
92610702
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3682689
3682690
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
108
104
108
104
75-125
4
20
Arsenic
ug/L
ND
100
100
101
98.2
101
98
75-125
3
20
Barium
ug/L
515
100
100
594
572
79
57
75-125
4
20 M1
Beryllium
ug/L
ND
100
100
99.3
94.9
99
95
75-125
5
20
Cadmium
ug/L
ND
100
100
103
101
103
101
75-125
2
20
Chromium
ug/L
2.8J
100
100
104
98.0
102
95
75-125
6
20
Cobalt
ug/L
20.9
100
100
118
111
97
90
75-125
6
20
Copper
ug/L
ND
100
100
98.2
92.1
98
92
75-125
6
20
Lead
ug/L
ND
100
100
99.8
97.1
100
97
75-125
3
20
Nickel
ug/L
7.7
100
100
107
100
99
93
75-125
6
20
Selenium
ug/L
ND
100
100
101
97.7
100
98
75-125
3
20
Silver
ug/L
ND
100
100
96.5
95.0
96
95
75-125
2
20
Thallium
ug/L
ND
100
100
100
97.7
100
98
75-125
2
20
Vanadium
ug/L
ND
100
100
104
98.3
104
98
75-125
6
20
Zinc
ug/L
ND
100
100
103
97.2
101
96
75-125
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
QC Batch: 707444 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92610702001
METHOD BLANK: 3689927
Matrix:
Water
Associated Lab Samples: 92610702001
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Mercury
ug/L
ND
0.20
0.13 06/29/22 08:42
LABORATORY CONTROL SAMPLE:
3689928
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Mercury
ug/L
2.5
2.5 101
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3689929 3689930
MS MSD
92607624001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L <0.13 2.5 2.5 2.7 2.6 107 104 75-125 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
QC Batch: 706240 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92610702001, 92610702002
METHOD BLANK: 3684436
Associated Lab Samples: 92610702001, 92610702002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
06/23/22 05:27
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
06/23/22 05:27
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
06/23/22 05:27
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,1-Dichloroethane
ug/L
ND
1.0
0.37
06/23/22 05:27
1,1-Dichloroethene
ug/L
ND
1.0
0.35
06/23/22 05:27
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
06/23/22 05:27
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
06/23/22 05:27
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
06/23/22 05:27
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane
ug/L
ND
1.0
0.32
06/23/22 05:27
1,2-Dichloropropane
ug/L
ND
1.0
0.36
06/23/22 05:27
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
06/23/22 05:27
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
06/23/22 05:27
2-Butanone (MEK)
ug/L
ND
5.0
4.0
06/23/22 05:27
2-Hexanone
ug/L
ND
5.0
0.48
06/23/22 05:27
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
06/23/22 05:27
Acetone
ug/L
ND
25.0
5.1
06/23/22 05:27
Acrylonitrile
ug/L
ND
10.0
1.8
06/23/22 05:27
Benzene
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromochloromethane
ug/L
ND
1.0
0.47
06/23/22 05:27
Bromodichloromethane
ug/L
ND
1.0
0.31
06/23/22 05:27
Bromoform
ug/L
ND
1.0
0.34
06/23/22 05:27
Bromomethane
ug/L
ND
2.0
1.7
06/23/22 05:27 v2
Carbon disulfide
ug/L
ND
2.0
0.36
06/23/22 05:27
Carbon tetrachloride
ug/L
ND
1.0
0.33
06/23/22 05:27
Chlorobenzene
ug/L
ND
1.0
0.28
06/23/22 05:27
Chloroethane
ug/L
ND
1.0
0.65
06/23/22 05:27
Chloroform
ug/L
ND
1.0
0.43
06/23/22 05:27
Chloromethane
ug/L
ND
1.0
0.54
06/23/22 05:27
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromochloromethane
ug/L
ND
1.0
0.36
06/23/22 05:27
Dibromomethane
ug/L
ND
1.0
0.39
06/23/22 05:27
Ethylbenzene
ug/L
ND
1.0
0.30
06/23/22 05:27
lodomethane
ug/L
ND
20.0
9.7
06/23/22 05:27
Methylene Chloride
ug/L
ND
5.0
2.0
06/23/22 05:27
Styrene
ug/L
ND
1.0
0.29
06/23/22 05:27
Tetrachloroethene
ug/L
ND
1.0
0.29
06/23/22 05:27
Toluene
ug/L
ND
1.0
0.48
06/23/22 05:27
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 20

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
METHOD BLANK: 3684436
Matrix:
Water
Associated Lab Samples: 92610702001, 92610702002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
06/23/22 05:27
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
06/23/22 05:27
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
06/23/22 05:27
Trichloroethene
ug/L
ND
1.0
0.38
06/23/22 05:27
Trichlorofluoromethane
ug/L
ND
1.0
0.30
06/23/22 05:27
Vinyl acetate
ug/L
ND
2.0
1.3
06/23/22 05:27 v1
Vinyl chloride
ug/L
ND
1.0
0.39
06/23/22 05:27
Xylene (Total)
ug/L
ND
1.0
0.34
06/23/22 05:27
1,2-Dichloroethane-d4 (S)
%
113
70-130
06/23/22 05:27
4-Bromofluorobenzene (S)
%
103
70-130
06/23/22 05:27
Toluene-d8 (S)
%
100
70-130
06/23/22 05:27
LABORATORY CONTROL SAMPLE:
3684437
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.1
106
70-130
1,1,1-Trichloroethane
ug/L
50
55.8
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.4
103
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
57.2
114
70-130
1,1-Dichloroethene
ug/L
50
58.9
118
70-132
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.0
106
70-130
1,2-Dichlorobenzene
ug/L
50
51.0
102
70-130
1,2-Dichloroethane
ug/L
50
56.5
113
70-130
1,2-Dichloropropane
ug/L
50
55.8
112
70-130
1,4-Dichlorobenzene
ug/L
50
49.5
99
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
962
96
70-137
2-Butanone (MEK)
ug/L
100
118
118
70-133
2-Hexanone
ug/L
100
110
110
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
107
107
70-130
Acetone
ug/L
100
107
107
70-144
Acrylonitrile
ug/L
250
296
118
70-130
Benzene
ug/L
50
51.3
103
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
54.7
109
70-130
Bromoform
ug/L
50
52.9
106
70-131
Bromomethane
ug/L
50
41.3
83
30-177 v3
Carbon disulfide
ug/L
50
57.2
114
70-133
Carbon tetrachloride
ug/L
50
52.0
104
70-130
Chlorobenzene
ug/L
50
51.0
102
70-130
Chloroethane
ug/L
50
52.0
104
46-131
Chloroform
ug/L
50
57.1
114
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
LABORATORY CONTROL SAMPLE:
Parameter
3684437
Units
Spike
Conc.
LCS LCS
Result % Rec
Chloromethane
ug/L
50
58.7
cis-1,2-Dichloroethene
ug/L
50
58.2
cis-1,3-Dichloropropene
ug/L
50
55.4
Dibromochloromethane
ug/L
50
53.1
Dibromomethane
ug/L
50
49.5
Ethylbenzene
ug/L
50
52.2
lodomethane
ug/L
100
119
Methylene Chloride
ug/L
50
51.7
Styrene
ug/L
50
51.4
Tetrachloroethene
ug/L
50
47.7
Toluene
ug/L
50
49.5
trans-1,2-Dichloroethene
ug/L
50
59.5
trans- 1,3-Dichloropropene
ug/L
50
55.4
trans-1,4-Dichloro-2-butene
ug/L
50
48.6
Trichloroethene
ug/L
50
51.2
Trichlorofluoromethane
ug/L
50
50.7
Vinyl acetate
ug/L
100
124
Vinyl chloride
ug/L
50
61.6
Xylene (Total)
ug/L
150
158
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
% Rec
Limits Qualifiers
117
49-130
116
70-130
111
70-130
106
70-130
99
70-130
104
70-130
119
47-140
103
68-130
103
70-130
95
70-130
99
70-130
119
70-130
111
70-130
97
25-200
102
70-130
101
61-130
124
70-140 v1
123
59-142
105
70-130
114
70-130
103
70-130
101
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3684438
MS
92610701001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3684439
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
25.6
23.8
128
119
70-135
7
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.8
21.2
114
106
70-148
7
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
24.9
22.8
125
114
70-131
9
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.9
21.3
115
106
70-136
8
30
1,1-Dichloroethane
ug/L
2.5
20
20
23.2
21.4
103
94
70-147
8
30
1,1-Dichloroethene
ug/L
ND
20
20
25.9
24.1
130
120
70-158
7
30
1,2,3-Trichloropropane
ug/L
ND
20
20
24.2
22.2
121
111
67-137
9
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.4
22.5
117
112
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
25.0
22.9
125
114
70-137
9
30
1,2-Dichlorobenzene
ug/L
ND
20
20
25.2
23.6
126
118
70-133
6
30
1,2-Dichloroethane
ug/L
ND
20
20
21.4
19.9
107
100
67-138
7
30
1,2-Dichloropropane
ug/L
ND
20
20
22.5
20.4
113
102
70-138
10
30
1,4-Dichlorobenzene
ug/L
2.7
20
20
28.1
27.0
127
122
70-133
4
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
559
540
140
135
69-146
3
30
2-Butanone (MEK)
ug/L
ND
40
40
46.6
43.3
117
108
61-147
7
30
2-Hexanone
ug/L
ND
40
40
49.3
47.3
123
118
67-139
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
44.8
42.2
112
106
67-136
6
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 20

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3684438
3684439
MS
MSD
92610701001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
45.7
43.7
114
109
55-159
4
30
Acrylonitrile
ug/L
ND
100
100
99.5
96.4
100
96
68-140
3
30
Benzene
ug/L
3.3
20
20
25.5
23.8
111
102
67-150
7
30
Bromochloromethane
ug/L
ND
20
20
22.6
21.0
113
105
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
22.1
20.5
111
102
70-138
8
30
Bromoform
ug/L
ND
20
20
20.9
19.1
104
96
57-138
9
30
Bromomethane
ug/L
ND
20
20
36.6
34.5
183
173
10-200
6
30 v1
Carbon disulfide
ug/L
ND
20
20
23.7
22.2
119
111
70-152
7
30
Carbon tetrachloride
ug/L
ND
20
20
24.6
22.8
123
114
70-147
8
30
Chlorobenzene
ug/L
ND
20
20
25.5
23.6
128
118
70-137
8
30
Chloroethane
ug/L
1.8
20
20
41.1
38.2
197
182
51-166
7
30 M1,v1
Chloroform
ug/L
ND
20
20
22.0
20.3
110
102
70-144
8
30
Chloromethane
ug/L
ND
20
20
25.6
23.3
128
116
24-161
10
30
cis-1,2-Dichloroethene
ug/L
1.5
20
20
22.4
20.8
104
96
67-148
7
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.2
19.5
106
98
70-142
8
30
Dibromochloromethane
ug/L
ND
20
20
22.8
21.0
114
105
68-138
8
30
Dibromomethane
ug/L
ND
20
20
24.8
23.0
124
115
70-134
8
30
Ethylbenzene
ug/L
1.1
20
20
25.9
24.1
124
115
68-143
7
30
lodomethane
ug/L
ND
40
40
47.5
43.2
119
108
20-161
9
30
Methylene Chloride
ug/L
ND
20
20
21.0
19.6
105
98
64-148
7
30
Styrene
ug/L
ND
20
20
24.8
22.6
124
113
70-136
9
30
Tetrachloroethene
ug/L
ND
20
20
25.8
23.5
129
118
70-139
9
30
Toluene
ug/L
ND
20
20
23.0
21.3
115
107
47-157
8
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.4
20.4
112
102
70-149
9
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.5
19.9
108
100
70-138
8
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
19.6
19.2
98
96
31-145
2
30
Trichloroethene
ug/L
ND
20
20
25.0
23.0
125
115
70-149
8
30
Trichlorofluoromethane
ug/L
ND
20
20
29.8
28.2
149
141
61-154
5
30 v1
Vinyl acetate
ug/L
ND
40
40
37.8
36.0
94
90
48-156
5
30
Vinyl chloride
ug/L
1.0
20
20
26.5
24.8
127
119
55-172
6
30
Xylene (Total)
ug/L
6.2
60
60
80.9
74.8
125
114
66-145
8
30
1,2-Dichloroethane-d4 (S)
%
95
96
70-130
4-Bromofluorobenzene (S)
%
95
95
70-130
Toluene-d8 (S)
%
97
97
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 20

Pace Analytical Services, LLC
9800
lCtaac,Analyfical ® Kiney Ave. Suite 100
Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: ASHE CO MSWLF BLANKS
Pace Project No.: 92610702
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
C9 Common Laboratory Contaminant.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 20

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
ASHE CO MSWLF BLANKS
92610702
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
Batch
92610702001
EB
EPA 3005A
705856 EPA 6020B
706020
92610702001
EB
EPA 7470A
707444 EPA 7470A
707568
92610702001
EB
EPA 8260D
706240
92610702002
FB
EPA 8260D
706240
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/01 /2022 02:48 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 20

Effective Date: 05/1-21202205112/2022
Laboratory receiving.samples;
fthevilke 0. Eden[] Greenwood ❑; HuntersvNie RaleighEj Medianicsville❑ AtlantaF KernersvilleFl
Sample• • Client Name: WO# : 92610702
- -- - -_ Project
Courier:. LJFedEx QUPS OILJSPS J nt Ij III II III I I�� I, III
Q Commercial []Pace 00ther:
92610702
Custody Seal Present? Dyes o Seals Info 7 Elyes o-
I}ateflnitiWs Person Examining-03ntents
Packing Waterlah E]ffubble Wrap ubbte Bags ❑Harie. 0 Othet
Thermonset
IH G.,,,.- �V U�
'type of Ise: ❑Wet
�} Earrectlbn Factor:
Cooler Temp: `i' t Add/Subtract {°Cj
Cooler. Temp Correcte °C t
USDA Regulated Soil ( A, water sample)
Did sarnples arigina in a "q'
uarantine Torte within the united States, CA, NY, or SC
m feheck:aos1.7 —)Yes f7No -
❑Blue ❑€bie
Biological Tissue Frozen?
❑Yes QNo EN/A
Tern�sltauld. beabove freezfngto 5°C
05arnpits out of ternp ariferia. Samples.on ice, cooling process
hashegun
Did urnpks Wginate from a foreign source (€nternationallyi
Comments/Discrepancy:
Chain;oi Custody Oesent?
es
allo
[:]N/A
I
Samples Arrived withihHold Time?
D�IbNo
E N/A
2.
Short Hold: Time Ana IvAs [c72 hr.j?
s:
El No
ZQNJA
3.
Rush Turn Around Tlme Requested?
❑Yes
o
❑N/A
4.
Sufficient Volume?
es
❑Na
❑N/A
Coerect Containers Used?
949511
❑N-
I]N¢A
8.
-Pace. Containers Used?-
01.6d
❑Ho
❑N/A
Containers IntactT
Yes
EINd
QN/A
7-
Dissolved anaiys€s: Samples Field Filtered?
❑ . s
Nn:
❑N}A
S..
Sample-1abels Match COC?
Yes
CINo
El NIA
9.
-Includes pate/Tfinell D/ArraiysIs Matrix:
��A
Headspace in VOA mats.(>5-Grim)?
es
Dy
[J{3/4
1t7
Trip Blank Present?
❑Yes
N'n
QN/A
11.
Trip Blank Custody Seals Present?
Des
u
I]N/A.
COMMENTS/SAMPLE DISCREPANCY,
Lot ID of spit containers:
_� . nlnrl rlrn�ln•i lneen�.n
Project Manager SCURF Review,
Elate:
Pco1ect NianagaESHE_Eeieiev� ate.
Field Data Required? ❑Yes. ONO
Qualtrax ID: 69614 page 1 of 2 Page 18 of 20

Pace-uvvv vu , —licit IIVIC t.U[1UltlQll UfJV11 Mecelpt
Effectivo Date: 06/12/202205/12/2022
*'Check mark top half of box if pH and/or dechlorination is verified and
within the acceptance range for preservation samples,
Exceptions: VGA, Coliform, TOC, Oil and Grease, OR018015 (water) OOC, Wig
"Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
Project fit WO# " 92610702
PM: AMS Due Dale: 07/01/22
CLIENT: 92-Municipal
n
T -' m V U w �
U O U v Q 1 ¢ n Z
m Z _
a a b "� '� Z z ro ri3 Z ro
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a c x z N z v G u 'A N z ? O a O a a x c c c
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a a a m —° —° m M o M n E a E E ¢ 4 ( -c Q x c = .. a = �
a o. E q E a E a ¢ 0 O 0 O p ;; y _m E c E
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pH Adjustment Log for Preserved Samples
sample l0 I Type of Preservative pH upon receipt bate preservation adjusted Time preservalion Amount of Preservative Lot ll
adjusted added
Note:-Wherteverttrii Incy �f ecC ling fTa ,]inc, pprance samples, a copy of this form will be sent to the North Carolina DENRCertificalion Gffice (i.e
Out of hold, incorrect preservative, out of temp, incorrect containers,
Page 19 of 20
Qualtrax U 69614 Page 2 of 2

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