0201_Alexander_MSWLF_CDLF_June2021GW_FID1740502_20221021

LLENR USE ONLY: I I ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR I IEnvironmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Municipal Engineering, Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Jonathan Pfohl Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Alexander County Active C&D and 2500 Paynes Dairy Road 02-01 .1600 June 28-30, 2022
Closed Unlined MSWLF Taylorsville, NC 28681
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring � Assessment Monitoring ❑X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify) MNA,Phyto. & LFG Extraction
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values-; NC 2L groundwater standard, NC 213'surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance -of any concentration.
❑ Yes; a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
S.J. Zimmerman, P.G. Project Manager [phone]
Name (Print) Title
Lo /Za22
Sig
P.O. Box 97, Garner, NC 27529
Facility Representative Address
NC PE Firm # F-0812 NC PG Firm # C-586
(Area Code) Telephone Nupib'er
Affix NC4-,ierlseti(.:Rrpfessio'rratiGe4logist Seal
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009 * NC 213 surface water standard not directly comparable. See text for more information.

Semi -Annual Water Quality Monitoring Report
with Corrective Action Update
June 2022
Prepared for
Alexander County Active Construction and Demolition Landfill
Closed Unlined Landfill
Taylorsville, North Carolina
Permit No. 02-01
Prepared by
Municipal Engineering, Inc.
P.O. BOX 97
Garner, North Carolina
MESCO Project Number: G22004.0
V,,J L '.
;'
Z5�3V4�
S. J. Am46rman, P.G. = ! = Jonathan Pfohl
-172
Project Manager ": `-' Environmental Specialist
jzimmerman(ae mesco.com [e-mail]
' (1L{t
'a:nlEOf.-i 2, 1u
J a 1 C I A t
MUNICIPAL ENGINEERING9 INC.
6B SHIPWASH DRIVE, GARNER, NC 27529 - PHONE: [phone]
P.O. Box 349, BOONE, NC 2B607 - PHONE: B2B-262-1767
C�/V E EF' LICENSE NUMBERS: F-OB 12 & C-5B6

TABLE OF CONTENTS
SECTION
Introduction....................................................................................................................................................................................................................................................................................................................................Page
1
Background....................................................................................................................................................................................................................................................................................................................................._Page
1
SamplingProcedures........................................................................................................................................................................................................................................................................................................Page
2
FieldParameter Data........................................................................................................................................................................................................................................................................................................Page
2
LaboratoryResults.............................................................................................................................................................................................................................................................................................................._Page
2
QualityControl Samples..........................................................................................................................................................................................................................................................................................Page
3
GroundwaterSamples Detected Above Standards..........................................................................................................................................................................................................Page
3
SHEETS
Topographic Map with Site Location.................................................................
Single Event Potentiometric Map of Uppermost Aquifer
FIGURES
1
2
VOC21, Exceedance Comparison Histograms............................................................................................................................................................................................................Figure
1
Total VOCs and Benzene Pre/Post Injection Comparison in AOC MW-26................................................................................................................Figure
2
Parameters in LFG Extraction Area Histograms (AOC MW-1B)...............................................................................................................................................Figure
3
TotalVOC Concentration Histograms.....................................................................................................................................................................................................................................Figure
4
TABLES
GroundwaterMonitoring Well Construction Table....................................................................................................................................................................................................Table
1
FieldObservations of Monitoring Locations.........................................................................................................................................................................................................................Table
2
FieldParameter Data Summary................................................................................................................................................................................................................................................................_Table
3
Samplingand Analysis Summary ............................................................................................................................................................................................................................................................Table
4
Groundwaterand QC Sample Detections..................................................................................................................................................................................................................................Table
5
SurfaceWater Sample Detections............................................................................................................................................................................................................................................................Table
6
Hydrologic Properties at Monitoring Well Locations.............................................................................................................................................................................................Table
7
APPENDICIES
FieldSampling Parameter Data Sheet(s)....................................................................................................................................................................................................................._Appendix A
Laboratory Analysis Report and Chains of Custody..................................................................................................................................................................................Appendix B
StatisticalAnalysis Calculations.................................................................................................................................................................................................................................................Appendix C

Introduction
On behalf of Alexander County, Municipal Engineering, Inc. (MESCO) is pleased to present this Semi -
Annual Water Quality Monitoring Report with Corrective Action Update for an event performed at
the Alexander County active construction and demolition (C&D) and closed municipal solid waste
landfill (MSWLF) between June 28-30, 2022. NCDEQ Solid Waste Rules 15A NCAC 13B.1632(i)
requires that Alexander County provide this report to the NC Solid Waste Section (SWS) on a semi-
annual basis. Laboratory analytical results indicate that samples collected from 18 wells contained
between one and three constituents above regulatory compliance Standards. Metal detections are
generally believed to originate from erosion of natural deposits. The source of VOCs is likely
anthropogenic. Cobalt was detected in levels that may be above surface water compliance values in two
downstream surface water samples. Corrective action to remediate VOCs in groundwater is ongoing
within the four areas of concern (AOC) with updated information presented herein. A Corrective Action
Evaluation Report (CAER) (DIN:27584) dated April 3, 2017 concluded groundwater quality has
improved. The SWS approved that corrective action may continue as proposed and implementation of the
contingency plan is not required.
Background
The Alexander County active C&D and closed MSWLF, is located at 2500 Paynes Dairy Road near
Taylorsville, North Carolina. The total waste footprint encompasses approximately 24 acres situated on
283 contiguous acres. The site location topographic map is depicted in the attached Sheet 1.
The closed MSWLF ceased operation prior to 1998 and the C&D landfill continues operation on the
eastern unit of the closed MSWLF. Both landfill areas are treated as a single unit in this report. Water
quality has been monitored at this facility on at least a semi-annual basis since 1990. MESCO submitted
two Assessment and Corrective Action (ACM) reports dated August 27, 2002 and April 11, 2008.
MESCO then developed a Corrective Action Plan -Revision I (CAP -Rev 1) on February 6, 2009. In
response to improved water quality and changing geochemical conditions the originally selected
remediation approach was amended by MESCO in a Corrective Action Plan -Addendum (CAP -Add) dated
December 20, 2010. Groundwater remediation efforts have been implemented at the four distinct areas of
concern (AOCs) which are identified as MW-lB, MW-16, MW-24 and MW-26. Remediation
technologies initiated to date with reference to their respective AOC include monitored natural
attenuation (MNA) (MW-16, MW-24, MW-26), phytoremediation (MW-24), enhanced bioremediation
via substrate injection (MW-26) and landfill gas (LFG) extraction (MW-1B).
Following establishment of the two-year MNA baseline MESCO completed a CAER (DIN 13596) on
March 22, 2011. Based on improved water quality conditions as demonstrated in the CAER the
parameters and frequencies of future monitoring events were established by the SWS CAER review
response (DIN 14150) dated June 16, 2011.
A second CAP -Add was submitted by MESCO dated May 30, 2013 as requested by the SWS in a letter
entitled Compliance Boundary (Relevant Point of Compliance) (DIN 18502) dated February 18, 2013. A
Request for Appendix II Groundwater Monitoring Modification (DIN 20137) was submitted by MESCO
dated November 8, 2013 which was subsequently approved by the SWS (DIN 20144) on November 13,
2013. A second CAER (DIN:27584) dated April 3, 2017 concluded that attenuation is occurring and no
corrective actions other than what has already been initiated are planned at this time as approved by the
NC SWS (DIN: 27678).
1

As specified within 15A NCAC 13B.1632(i), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contain sampling procedures, field and laboratory results, corrective action
update, ground/surface water characterization, and findings. Well construction summary table, field
observations table, field parameter data table, sampling and analysis summary table, detections compared
to Standards tables, a groundwater flow directions/rates table, potentiometric map, time -series graph,
quality assurance/quality control data, and laboratory analytical data results are enclosed herein.
Sampling Procedures
MESCO personnel performed this sampling event generally following the parameters and frequency
established in the Water Quality Monitoring Plan (WQMP) dated August 11, 2016. The water quality
monitoring program includes a combination of detection, assessment and corrective action monitoring
with specifically defined analysis.
Water samples were collected from all monitoring locations outlined in the CAP -Add and CAER.
Samples were collected from MW-IA which is atypical since it typically has insufficient recharge. MW-
3 and MW-7 were not sampled during this event since they are only tested annually in the winter.
Monitoring locations are depicted on the potentiometric surface map (Sheet 2).
Sampling was performed per the protocols outlined in the WQMP. A summary detailing the construction
of the water quality monitoring wells is presented in Table 1. The function and integrity of all monitoring
locations were visually evaluated and maintenance performed as documented in Table 2. The depth to
water in each well was electronically gaged prior to purging to quantify the static water level elevation.
Submersible pumping or bailing was utilized to purge the wells a minimum of three times the volume of
standing water in the well or until dry. Surface water samples were collected from previously designated
locations along discharge features. During well purging and surface water sample collection the required
stabilized field parameters were recorded. The samples were then placed into laboratory -prepared, pre -
preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and
transported to a NC -certified laboratory under proper chain of custody (C-O-C) protocols and within the
specified hold times for each analysis.
Field Parameter Data
Field parameters were recorded including depth to water, pH, specific conductance, temperature,
oxidation reduction potential (ORP), dissolved oxygen (DO), hardness and turbidity. A summary of the
field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix A.
Laboratory Results
Pace Analytical Services, Inc. (PACE) of Huntersville/Asheville, NC performed the laboratory analyses.
Groundwater, surface water and quality control samples were tested for a mix of Appendix I constituents,
and MNA performance parameters as prescribed in the approved WQMP. A few MNA parameters, that
are on an annual frequency, were inadvertently not tested during the previous event but were reported
during this event. Water samples were analyzed to the Method Detection Limits (MDL) and reported to
the Reporting Limit (RL) which are both established by the laboratory. Any value above the adjusted
MDL and below the RL was flagged as a "j-qualifier" which the laboratory defines as an estimated
concentration. Estimated concentrations are considered non -quantifiable and discretion should be made
prior to making decisions based solely on an approximate value. A sampling and analysis table
2

summarizing the locations, laboratory, target analytes and methods is presented as Table 4. Laboratory
results and C-O-Cs are presented in Appendix B.
Quality Control Samples
Acetone, a common laboratory induced contaminant, was detected below quantification levels in the EB
and FB samples. Acetone was not detected above any water quality standard in any other sample;
therefore, the presence of the artifact contaminant is largely inconsequential.
Groundwater Samples Detected Above Standards
Table 5 summarizes constituents detected in groundwater and QC samples compared to North Carolina
Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections
are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal
"Drinking Water Standard".
Metals
One or two total recoverable forms of metals were detected above their RL and respective NC 2L
Standard in samples collected from 18 wells, including the background well, as summarized below.
Metals Detected in Groundwater Samples Above RL and NC 2L Standard
Cadmium
Cobalt
NC 2L Standard
2
1
MW-1
6.2
MW-IA
2.4
35.3
MW-1B
52
MW-2
431
MW-4R
141
MW-6
12.8
MW-9
3.2
451
MW-11
128
MW-12
146
MW-14
148
MW-15
51.9
MW-16
332
MW-17
47
MW-21
9.1
MW-24
18.3
MW-26
5.1
119
MW-33
25.1
Concentrations in ug/L
3

VOCs
Benzene was detected above the RL and 2L Standard (1.0 ug/L) in samples collected from MW-2 (1. 1),
MW-5 (2.4), MW-9 (1.2), MW-11 (2.9), MW-12 (1.9), MW-15 (1.2), MW-16 (1.2) and MW-26 (1.8).
1,4-dichlorobenzene was found in sample MW-11 (6.5) which is above the NC 2L Standard (6 ug/L). A
bar graph and table comparing the most recent levels of VOCs exceeding the 2L Standard compared to
their respective maximum observed levels is presented on Figure 1. A site map depicting the spatial
distribution of VOC concentrations exceeding the 2L Standard during this sampling event is shown in
Sheet 2.
Surface Water Samples Detected Above Standards
Table 6 summarizes constituents that were detected above the MDL compared to compliance values
listed in the current version of the NC Division of Water Resources Surface Water Quality Standards,
Criteria & In -Stream Target Values (ISTV) tables dated July 26, 2021.
Total cobalt was detected in grab sample SW-3 (6.7 ug/L) and SW-5 (33.6 ug/L) which is above the
dissolved NC ISTV for chronic (1.6 ug/L) and acute (16 ug/L) impacts. However, because single grab
samples of the total form are reported rather than multiple samples of the dissolved form a direct
comparison to the cobalt NC ISTV for compliance purposes is inappropriate.
Groundwater and Surface Water Characterization
Groundwater flow direction generally mirrors topography; thus, flow direction is from higher to lower
elevations as shown on the potentiometric map included as Sheet 2. Locally, groundwater flow is
expected to be generally west toward the Lower Little River and south toward the Catawba River which
North Carolina classifies as a WS-IV; CA (Water Supply Class IV; Critical Area). Groundwater linear
velocity rates calculated using modified Darcy's equation varied greatly and were slower in the upper
bedrock fracture system than the less prominent regolith (Table 7). Streams at designated monitoring
points were visually observed to be of low seasonal volume, flow rate and low turbidity. Hydrogeologic
parameters appear generally consistent with historical observations.
Corrective Action Update
Groundwater remediation continues to be implemented at the four AOCs designated in the CAP -Add.
General background information and activities performed since the CAER and last semi-annual event are
briefly presented in the following sections.
MNA Analysis (ADCs MW-16, MW-24, MW-26)
Semi-annual MNA monitoring of 14 wells for the full suite of SWS recommended parameters was
initiated on June 30, 2009 and performed during four consecutive semi-annual events to establish a
baseline in accordance with the CAP -Revision 1. The number of wells requiring MNA analysis was
reduced to 10 wells. The parameters and frequency were also amended in accordance with the SWS
CAER review response (DIN 14150) dated June 16, 2011. A large number of MNA parameters were
targeted during this event and detections are presented on Table 5.
4

Following an acquisition of a 15.7-acre parcel from Crescent Resources on March 3, 2011, extension of
the eastern relative point of compliance downgradient of AOC MW-16 had been approved with
conditions by the SWS on February 18, 2013 (DIN:18502). Recordation of Survey Plat titled Survey for
Notice of Contaminated Site Alexander County Landfill and A Notice and SWS approved Declaration of
Perpetual Land Use Restrictions for this parcel has remained at the Alexander County Register of Deeds
Office since November 13, 2012. Alexander County purchased another 2.15-acre parcel that adjoins the
NE corner with deed recorded on March 26, 2018, which effectively increases the relevant compliance
boundary in a NE direction. The SWS approved CAP -Add and CAER (2017) clarifies that groundwater
remediation of AOC MW-16 will remain as MNA, rather than other technologies described in the
preceding CAP -Add.
Phytoremediation (AOC MW-24)
County personnel planted approximately 200 hybrid poplar and willow trees over an approximate one -
acre area between MW-7 and MW-12 in May 2010 in an effort to phytoremediate groundwater in the
MW-24 AOC. The County planted 25 additional hybrid willow trees in the spring of 2022 to replace
trees that have died. The County continued to maintain the fence -enclosed stand during this semi-annual
period which included supplemental watering and eradication of competing vegetation.
Total cumulative VOC concentrations in AOC MW-24 during this event have decreased 53% compared
to its respective 2-year baseline established in 2010 and a statistically decreasing trend is evident.
Assessment of the phytoremediation area, which includes tree measurements and the downloading of
groundwater fluctuation data from dedicated transducers was performed by MESCO. The majority of the
trees appear to be dying or have died. The additional trees planted this Spring is expected to compensate
for observed mortality.
Enhanced Bioremediation via Substrate Injection (AOC MW-26)
hi an attempt to remediate benzene as detected in MW-26, Bac-9 was injected 50 ft upgradient in IW-1 on
February 17, 2011 following conditions in the Underground Injection Control (UIC) Permit WI0300160.
The UIC permit was renewed and as directed by the UIC permit, post -injection water quality monitoring
of MW-3, MW-11, MW-26, MW-27 and MW-31 is required on a semi-annual basis. Most recent levels
of total VOCs and benzene downgradient of the injection point decreased 56% and 5% respectively
compared to the baseline established during the four events prior to injection (Figure 2). Additional
injections are not planned at this time.
Landfill Gas Extraction (AOC MW-1B)
Three LFG extraction wells (MEW-1, MEW-2, MEW-3) were installed screening the majority of the
vadose zone at the northern border of the closed landfill in the vicinity of the scale house. MEW-1 was
installed on August 17, 2010 with MEW-2 and MEW-3 installed on October 20, 2010. Well control
heads were plumbed to a header pipe by the County which was connected to a soil vacuum extraction
(SVE) unit on July 5, 2012. An active LFG blower system pilot study was performed by MESCO
between June 14, 2012 and July 12, 2012 to evaluate the effectiveness a vacuum would have on reducing
levels of LFG in the soil which may remediate the low-level VOCs detected in groundwater hydraulically
upgradient of the landfill. A comparison of LFG concentrations and pressures before and after vacuum
start-up indicated the system is capable of eliminating LFG migration at all locations monitored within
AOC MW-113. The active LFG Collection Control System (LFGCCS) has been in continuous operation
since November 1, 2012 and been verified and documented by MESCO personnel on at least a quarterly
5

basis to be mitigating LFG migration through the vadose at all locations monitored beyond the extraction
wells. Great improvement in groundwater quality has been observed in response to implementation of the
LFG extraction system as demonstrated by a reduction of benzene (94-96%), total VOCs (92-97%) and
dissolved methane (99%) as shown on Figure 3.
The LFGCCS is planned to remain in operation and will continue to be monitored and assessed on a
quarterly basis.
Findings
During this event there were 20 instances of metals detected in quantifiable concentrations above NC 2L
Standards which is typical for this site. Cobalt continues to be the most prevalent metal detected and was
found in 87% of the samples. All metal concentrations were found within their historically identified
range except for mercury in background sample MW-18. The source of metals may be attributed to
erosion of natural deposits however, it is unknown if the observed metals have leached in response to
changes in redox conditions, anoxic environments, pH, oxidation state of metals and microbial activities.
The laboratory results indicate that dissolved phase VOCs, consisting primarily of benzene and a few
low-level chlorinated solvents, continue to be detected in groundwater samples collected within 270 feet
of the waste boundary. All VOCs detected during this event remain within their own respective
historically identified range. Statistical Mann Kendall trend analysis performed at both a 90% and 95%
confidence interval indicate a stable or downward trend of total cumulative VOC concentrations at every
well except for MW-5. Total VOC concentrations during this event, compared to their own respective
averages calculated during the two-year baseline period (ended in 2010), exhibited a reduction in each of
the AOC's as shown on Figure 4. Statistical analysis calculations are found in Appendix C and
summarized below.
Total Cumulative VOCs Baseline Average Compared to June 2022
AOC
Total
VOCs
Baseline
(ug/L) 11
Total
VOCs
June 2022
(ug/L)
Change
(%)
Statistical
Trend
AOC MW-1B
12.16 11
0.69
-94
Downward
AOC MW-16
12.14
9.76
-20
Downward
AOC MW-24
7.92
3.72
-53
Downward
AOC MW-26
30.24
14.17
-53
Downward
AOC Undesignated
12.39
7.14
-42
Downward
All Wells
-::::]1
14.58
6.98
-52
Downward
Evaluation of current water quality data continues to support assertions drawn in previous reports. VOCs
persist in the upper portion of the aquifer but concentrations continue to decrease over time and distance
away from the landfill. MNA data and previous screening models indicate that the plumes within each
AOC are stabile and/or decreasing and there is evidence that natural attenuation is ongoing at the facility.
2

Implementation of the corrective action measures coupled with natural attenuation is expected to decrease
VOC concentrations in groundwater over time.
It is recommended that surface water samples be tested for dissolved metals if the total form is found
elevated compared to dissolved surface water Standards to better determine if surface waters are
impaired.
Closing
Water quality monitoring and corrective action is planned to continue in December 2022. During the next
event the full Appendix II list of constituents and select MNA performance parameters will be targeted.
A CAER, which is required every five years, is planned to be submitted on March 15, 2023.
7

Sheets

Topographic Map with Site Location
Alexander County Active C&D and Closed MSWLF
G6PARTMlM Of Me irciexioR nwm, [eR�/amKi
6EO100 �•S 911Vl�eY inert aF.ki 1
S ..-s'.:.�-„ram• IRk
' LANDFILL PROPERTY
•'yw, »4 �..:Y � � ,'� �'�. 'v4�.� .�I ,fir � �� '�
i
2500 Paynes Dairy Road QUADRANGLE LEGEND
ROAD CLASSIFICATION
Taylorsville NC 28681 Primary highway, Light -duty road, hard or
, hard surface ...................... improved surface........ _._
Lat:35-15-18 7246 hard surface
highway,
• Q Q • hard surface ............... Unimproved road.-
Long:-81-08-51.51.32 0Interstate Route 0 U. S. Route O State Route
Northing:767009.09
Easting:1363506.43 ,�2 i MILE SHEET 1

SW-4R
9s
O \
1960
MW-6
Cobalt - 12.8 ug/I
MW-2
Benzene - 1.1 ug/I
Cobalt - 431 ug/I
MW-14
Cobalt - 148 ug/I
MW--23 /f
GWE=932.56
M
MW-13
GWE=962.13
O0 j
i
I
M -24
G W=942.20
MW-24
O,
Cobalt - 18.3 ug/I d�
LEGEND
ESTIMATED WASTE LIMITS
FACILITY PROPERTY BOUNDARY
250
EXISTING TOPOGRAPHIC CONTOUR
COMPLIANCE BOUNDARY
Iw
INJECTION WELL
OBSERVATION WELL - OUT OF NETWORK
MONITORING WELL - IN NETWORK
sW
SURFACE WATER SAMPLING LOCATION
ACTIVE LANDFILL GAS EXTRACTION WELL
ROADS
TREE LINE
STREAM/CREEK
EQUIPOTENTIAL UPPERMOST GROUNDWATER
CONTOURS (JUNE 28-30, 2022)
GWE = 974.6
GROUNDWATER POTENTIOMETRIC ELEVATION
*NOTE: DEEP WELLS NOT USED FOR CONTOURS
LFG PASSIVE VENTING SYSTEM
PHYTOREMEDIATION AREA
oFNsF
100o -
M_W-6
GWE=981.03
MW-22
GWE=943.79
MW-141
6W=959.05
MW-12' n w
GWE=953.58
M_W
GWE
OF
1100 FILL AREA 2
90� so
1040
�1030\
MW-7
GWE=970.71 ,
MW-21 MW-17
Cobalt - 9.1 ug/I Cobalt - 47 ug/I
MW-21
' GWE=959.44 IE
-17\
=97 1.98
=64?6
.88
MW-1'
Benzene
Cobalt-,
MW-25 \
GWE=949.91
1010
1028
MW-15
Benzene - 2.2 ug/I
Cobalt - 51.9 ug/I
GWE=998.90
i
MW-20 MW-19
GWE=1007.34 GWE=1022.57
�O MW-1
Cobalt - 6.2 ug/I O
44
MEW-2
n
1
O � �
� FD
i
0
ACTIVE C&D OVER
MSW
0901,
o
00
' o
a �
'MW--3
GWE=999.15
010
MW-11 M
Benzene - 2.9 ug/I MW-11 -
1,4-DCB - 6.5 ug/I GWE=970.37
Cobalt - 128 ug/I
WE=966.56
4w_1
P-2 IW O P-3 7�77�
P- MW-26
MW-26 Benzene -1.8 ug/I
GWE=963.14 Cadmium - 5.1 ug/L
j- o Cobalt - 119 ug/L
TRANSFER STATION
MW
GWE
O
rn
rn
uo
o
n
1070-
1060-
-1050-
-1040
-1030 -
-1020-
- 1010-
- 1000
MW-27
GWE=971.38
h
O
0)
r
MW-9
G WE 984.56
MW-9
Benzene -1.2 ug/I
Cadmium - 3.2 ug/L
Cobalt - 451 ug/L
MW-1 B MW-1A
Cobalt - 52 ug/I Cadmium - 2.4 ug/I
Cobalt - 35.3 ug/I
GWE=1042 76 �//�/V_1A © MW-18
M GWE=1040.29 _ _ _ GWE=1038.74
lv/W--1
GWE=1045.33
MEW-1
CLOSED
MSWLF
o�
0
M
MEW-3
�j
I C>
OHO r �/
CD 1�
00
70,> M
MW-5
060 J GWE=1010.82
MW-16
1040 GWE=1007.24
M W-4 R4
Cobalt - 141 ug/I r st0
W--4R
GWE=996.95
SW-3
0
Ln
rn
MW-10
GWE=1003.93
MW-32
GWE=993.64
M_ W-33
GWE=994.34
�
SW SW-5
LFG VENTING SYSTEM
MW-5
Benzene - 2.4 ug/I
MW-34
GWE=1006.24
SW-6
MW-16
Benzene -1.2 ug/I
Cobalt - 332 ug/I
SW-5
Cobalt - 33.6 ug/I
GRAPHIC SCALE
100 0 50 100 200
( IN FEET
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Figures

Figure 1
VOC 2L Exceedance Comparisons Histograms
m
6
4
2
0
VOCs >211- Std (June 2022 Compared to Maximum)
■ BENZENE Max ■ 1,4-DCB Max BENZENE June 2022 ■ 1,4-DCB June 2022
Parameter Name
2L Std.
MW-2
MW-5
MW-9
MW-11
MW-12
MW-15
MW-16
MW-26
Jun-22
Max
Jun-22
Max
Jun-22
Max
Jun-22
Max
Jun-22
Max
Jun-22
Max
Jun-22
Max
Jun-22
Max
Benzene
1
2.4
2.5
1.2
6.1
2.9
7.8
1.9
8.2
2.2
5.3
1.2
4.9
1,4-Dichlorobenzene
6
�.5
6.5
11.6
Maximum=Highest ever reported (1995 through Dec. 2021)
NT = Not Tested in June 2022
4
2
Alexander County Active CDLF and Closed MSWLF Page 1 of 1

Figure 2
Total VOCs and Benzene Concentrations Pre/Post Injection Comparison in ACC MW-26
June 30, 2009 - June 30, 2022
Cumulative VOCs
Benzene
Total VOCs & Benzene Concentrations Pre/Post Iniection Comparison in AOC MW-26
Hydraulic
June 2009 (ug/L)
Dec. 2009 (ug/L)
July 2010 (ug/L)
Dec. 2010 (ug/L)
Average of Four
Events Preceding
Injection (ug/L)
Total Cumulative VOCs
Benzene
Gradient In
Relation to
Injection
Well (IW-1)
Well ID
All
VOCs
Benzene
All
VOCs
Benzene
All
VOCs
Benzene
All
VOCs
Benzene
All VOCs
Benzene
June
2022
(ug/L)
Change
(ug/L)
Change
%
June
2022
(ug/L)
Change
(ug/L)
Change
Up
MW-3
61.66
8.10
43.03
7.20
31.50
6.00
37.04
6.10
43.31
6.85
18.78*
-24.53
-57
4.4*
-2.45
-36
Up
MW-11
53.28
5.00
46.25
4.50
40.81
5.90
43.20
4.20
45.89
4.90
21.31
24.58
-54
2.90
-2.00
-41
Up
MW-27
23.70
0.00
20.20
0.00
24.60
0.00
28.00
0.00
24.13
0.00
16.10
-8.03
-33
0.00
0.00
0
Subtotal Upgradient
1 138.64
1 3.10
109.48
11.70
1 96.91
1 11.90
108.24
10.30
1 113.32
1 11.75
56.19
1 -57.13
-38
1 7.30
1 -4.45
1 -38
Down
MW-26
39.40
1 1.40
20.00
1 1.40
39.50
1 3.20
30.75
1 1.60
32.41
1 1.90
12.88
1 -19.53
-60
1 1.80
1 -0.10
5
Down
MW-31
0.00
1 0.00
0.00
1 0.00
0.00
1 0.00
4.61
1 0.00
1.15
1 0.00
1.80
1 0.65
56
1 0.00
1 0.00
0
Subtotal Downgradient
39.40
1.40
20.00
1.40
39.50
3.20
35.36
1.60
33.57
1.90
14.68
-18.89
-56
1.80
-0.10
-5
Up&Down Gradient Total 1 178.04
14.50
129.48
13.10
136.41
15.10
143.60
11.90
146.88
13.65
70.87
-76.01
-52
9.10
4.55
33
= Concentrations shown for MW3 from previous event (December ZUZi) since not required during June ZU22
Alexander County Active CDLF and Closed MSWLF Page 1 of 1

Figure 3
Histograms of Parameters in LFG Extraction Area (AOC-MW 1 B)
Dissolved Methane in Groundwater
4
z
■
■
[v
N
m
m
in
M
Lo
Lo
r-
r-
rti
Op
CO
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m
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7
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O
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Cl7
au
it
a
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O
N 7
m 7
■....... MW-1 113
is
u Be��e�e
REDUCTION SINCE LFG EXTRACTION BEGAN
WELL ID
DISSOLVED
METHANE
BENZENE
TOTAL
VOCS
N
N
N
MW-1
-99
-94
-92
�MW-1 B
-99
1 -96
1 -97
Alexander County Active CDLF and Closed MSWLF Page 1 of 1

Figure 4
Total VOC Concentrations Histograms
Baseline (June 24, 2009-December 9, 2010) Compared to June 2022
35
30
25
J
rn 20
15
10
TOTAL VOC(s) BASELINE AVERAGE COMPARED TO JUNE 2022
MW-16 VW-16 MW-26 MW-24 UNDESIGNATED SITEWIDE
AREA OF CONCERN ■ BASELINE AVERAGE
■ June M22
AOC ID
WELL ID
TOTAL
VOC(s)
BASELINE
AVERAGE
(June 2009-
Dec. 2010)
(ug/1)
TOTAL
VOC(s)
LATEST
June 2022
(ug/1)
DIFFERENCE
BETWEEN
LATEST AND
BASELINE (ug/L)
DIFFERENCE
BETWEEN
LATEST AND
BASELINE
(GAG)
STATISTICAL TREND*
Between June 2009-
June 2022
MW-1
27.86
2.19
-25.67
-92
�Downl
MW-1A
NS
0.74
-
-
++No Trend++
MW-1 B
17.31
0.53
-16.78
-97
Zowr ard.t-
MW-1 B
MW-18
0.00
0.00
0.00
0
HNo Trend++
MW-19
3.48
0.00
-3.48
-100
HNo Trend++
AOC AVG
12.16
0.69
-11.47
-94
IDownward.
MW-5
19.84
28.70
8.86
45
TUpwardT
MW-10
3.24
3.41
0.17
5
"No Trend++
MW-16
45.06
23.72
-21.34
-47
Zownward�
MW-16
MW-32
0.00
0.00
0.00
0
HNo Trend++
MW-33
4.40
2.31
-2.09
-48
HNo Trend++
MW-34
0.30
0.40
0.10
33
HNo Trend"
AOC AVG
12.14
9.76
-2.38
-20
�Downl
MW-6
0.00
0.00
0.00
0
HNo Trend++
MW-7
15.27
10.8 Deo21
-4.47
-29
Zowr ard.t-
MW-12
34.39
12.08
-22.31
-65
Zownward.
MW-24
MW-12D
1.00
0.96
-0.04
-4
HNo Trend++
MW-13
1.59
0.00
-1.59
-100
HNo Trend++
MW-24
3.18
0.00
-3.18
-100
Zowr ard.t-
MW-25
0.00
2.23
2.23
100
HNo Trend++
AOC AVG
7.92
3.72
-4.20
-53
Zownward�
MW-3
45.47
18.78 Deo21
-21.18
-59
IDowirl
MW-11
47.84
21.31
-20.18
-55
Zownl
MW-26
MW-26
32.41
12.88
-19.53
-60
"No Trend++
MW-27
24.32
16.10
-8.22
-34
Zownl
MW-31
1.15
1.80
0.65
57
HNo Trend++
AOC AVG
30.24
14.17
-16.07
-53
Zownward.
MW-2
30.99
31.60
-23.53
-70
HNo Trend++
MW-4R
26.73
7.91
-18.82
-70
IDowirl
MW-9
19.55
17.50
-2.05
-11
Zownl
MW-14
17.81
2.10
-15.71
-88
++No Trend++
Undesignated
MW-15
13.38
9.58
-3.80
-28
++No Trend++
(No
MW-17
10.55
2.11
-8.44
-80
HNo Trend++
Remediation)
MW-20
0.69
0.00
-0.69
-100
++No Trend++
MW-21
0.77
0.55
-0.22
-29
HNo Trend++
MW-22
2.70
0.00
-2.70
-100
++No Trend++
MW-23
0.68
0.00
-0.68
-100
HNo Trend++
AOC AVG
12.39
7.14
-5.25
-42
Zownward�
ALL WELLS
ALL WELLS AVG
14.58
6.98
-7.60
-52
Zownward.
NS = Not sampled since dry
* = Statistical trend analysis of all events between June 2009 and July 2021 via Mann Kendall Trend Analysis at both a 90 % or 95 % Confidence Level.
- = MW-3 and MW-7 not sampled since exempt. Data from previous event (12/21) used for calculations
Alexander County Active CDLF and Closed MSWLF Page 1 of 1

Tables

Table 1
Groundwater Monitoring Well Construction Table
June 28-30, 2022
Monitoring
Well
Date
Installed
Well
Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen
Length
Geology of
Screened
Interval
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth to
Water
Latitude
Longitude
(inches)
(ft bgs)
(ft bgs)
(ft)
(ft amsl)
(ft amsl)
(ft amsl)
(ft btoc)
MW-1
9/14/90
2
40.00
25.00
15
Soil & Rock
1080.54
1077.98
1045.33
35.21
35.8389
-81.1478
MWAA
9/30/94
2
47.50
32.50
15
Soil & Rock
1085.32
1083.28
1040.29
45.03
35.8389
-81.1478
MWAB
5/21/03
2
61.00
46.00
15
Rock
1082.56
1079.56
1042.76
39.80
35.8391
-81.1478
MW-2
9/6/90
2
30.00
15.00
15
Soil
1004.48
1002.28
981.23
23.25
35.8376
-81.1524
MW-3
9/19/90
2
33.00
13.00
20
Soil & Rock
1024.73
1024.23
999.15
25.58
35.8365
-81.1503
MW-4R
9/30/94
2
20.50
5.50
15
Soil & Rock
1012.64
1008.54
996.95
15.69
35.8366
-81.1479
MW-5
9/16/94
2
48.80
33.80
15
Soil & Rock
1051.26
1049.01
1010.82
40.44
35.8373
-81.1465
MW-6
9/29/94
2
41.00
26.00
15
Rock
1010.79
1008.29
981.03
29.76
35.8368
-81.1531
MW-7
9/29/94
2
53.00
38.00
15
Rock
1009.24
1005.84
970.71
38.53
35.8362
-81.1521
MW-9
10/24/00
2
31.50
16.50
15
Rock
996.27
993.76
984.56
11.71
35.8361
-81.1481
MW-10
10/25/00
2
91.00
76.00
15
Rock
1040.80
1037.83
1003.93
36.87
35.8366
-81.1469
MW-11
10/24/00
2
56.00
41.00
15
Rock
1011.96
1008.98
970.37
41.59
35.8359
-81.1505
MW-12
10/23/00
2
66.50
51.50
15
Soil
1007.35
1004.46
953.58
53.77
35.8357
-81.1526
MW-12D
6/9/00
2
100.00
90.00
10
Rock
1008.46
1006.03
946.88
61.58
35.8357
-81.1525
MW-13
10/25/00
2
60.50
45.50
15
Rock
1004.56
1001.63
962.13
42.43
35.8368
-81.1532
MW-14
10/26/00
2
40.50
25.50
15
Soil & Rock
997.44
994.06
959.05
38.39
35.8376
-81.1525
MW-15
10/25/00
2
35.00
20.00
15
Soil & Rock
1023.44
1020.81
998.90
24.54
35.8385
-81.1508
MW-16
12/20/07
2
40.25
25.25
15
Rock
1037.56
1034.94
1007.24
30.32
35.8371
-81.1465
MW-17
6/10/03
2
22.30
7.30
15
Rock
991.16
988.36
971.98
19.18
35.8386
-81.1511
MW-18
12/19/07
2
56.70
41.70
15
Rock
1084.33
1081.52
1038.74
45.59
35.8392
-81.1467
MW-19
12/20/07
2
63.92
48.92
15
Rock
1071.48
1068.67
1022.57
48.91
35.8391
-81.1487
MW-20
12/20/07
2
63.55
48.55
15
Rock
1046.92
1044.19
1007.34
39.58
35.8391
-81.1502
MW-21
12/19/07
2
41.05
26.05
15
Rock
990.00
987.08
959.44
30.56
35.8386
-81.1514
MW-22
12/19/07
2
18.12
8.12
10
Rock
958.97
956.21
943.79
15.18
35.8381
-81.1524
MW-23
12/19/07
2
21.54
6.54
15
Soil
950.48
947.83
932.56
17.92
35.8376
-81.1529
MW-24
12/20/07
2
35.35
20.35
15
Soil
974.04
971.29
942.20
31.84
35.8356
-81.1533
MW-25
12/19/07
2
44.48
29.48
15
Rock
981.93
979.93
949.91
32.02
35.8353
-81.1528
MW-26
12/20/07
2
49.80
34.80
15
Rock
990.69
988.08
963.14
27.55
35.8354
-81.1504
MW-27
12/20/07
2
49.82
34.82
15
Rock
992.19
989.19
971.38
20.81
35.8356
-81.1493
MW-31
8/16/10
2
32.56
17.56
15
Soil
985.42
982.42
962.24
23.18
35.8348
-81.1506
MW-32
8/16/10
2
42.70
27.7
15
Rock
1025.26
1022.26
993.64
31.62
35.8361
-81.1469
MW-33
4/27/13
2
21.38
6.38
15
PWR
1007.40
1004.40
994.34
13.06
35.8367
-81.1462
MW-34
4/27/13
2
21.19
6.19
15
PWR
1014.60
1011.60
1006.24
8.36
35.8373
-81.1459
IW-1
2/14/11
4
52.44
37.44
15
Rock
990.44
987.44
966.56
23.88
35,8356
-81.1504
NOTE:
bgs = below ground surface
amsl= above mean sea level
btoc = below top of casing (PVC well casing)
PWR = partially weathered rock
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 2
Field Observations of Monitoring Locations
June 28-30, 2022
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Locked
Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface
Pad
Effective
Comments
MW-1
Yes
Yes
Yes
Yes
No
Yes
MW-1A
Yes
Yes
Yes
Yes
Yes
Yes
First time sampled in years. Poor recharge
MW-1 B
Yes
Yes
Yes
Yes
Yes
Yes
Lock replaced
MW-2
Yes
Yes
Yes
Yes
Yes
Yes
MW-3
Yes
Yes
Yes
Yes
Yes
Yes
Not sampled this event since exempt
MW-4R
Yes
Yes
Yes
Yes
Yes
Yes
MW-5
Yes
Yes
Yes
Yes
Yes
Yes
Case previously repaired datum may have changed, black sedimen
MW-6
Yes
Yes
Yes
Yes
Yes
Yes
MW-7
Yes
Yes
Yes
Yes
Yes
Yes
Not sampled this event since exempt
MW-9
Yes
Yes
Yes
Yes
Yes
Yes
MW-10
Yes
Yes
Yes
Yes
Yes
Yes
Lock replaced
MW-11
Yes
Yes
Yes
Yes
Yes
Yes
MW-12
Yes
Yes
Yes
Yes
Yes
Yes
Purge water reducing odor
MW-12D
Yes
Yes
Yes
Yes
Yes
Yes
MW-13
Yes
Yes
Yes
Yes
Yes
Yes
MW-14
Yes
Yes
Yes
Yes
Yes
Yes
MW-15
Yes
Yes
Yes
Yes
Yes
Yes
MW-16
Yes
Yes
Yes
Yes
Yes
Yes
Orange purge water
MW-17
Yes
Yes
Yes
No
Yes
Yes
Well case hinge broken off
MW-18
Yes
Yes
Yes
Yes
Yes
Yes
MW-19
Yes
Yes
Yes
Yes
Yes
Yes
MW-20
Yes
Yes
Yes
Yes
Yes
Yes
MW-21
Yes
Yes
Yes
Yes
Yes
Yes
MW-22
Yes
Yes
Yes
Yes
Yes
Yes
Pad slightly cracked
MW-23
Yes
Yes
Yes
Yes
Yes
Yes
Pad has very small crack
MW-24
Yes
Yes
Yes
Yes
Yes
Yes
Orange purge water
MW-25
Yes
Yes
Yes
Yes
Yes
Yes
MW-26
Yes
Yes
Yes
Yes
Yes
Yes
MW-27
Yes
Yes
Yes
Yes
Yes
Yes
MW-31
Yes
Yes
Yes
Yes
Yes
Yes
MW-32
Yes
Yes
Yes
Yes
Yes
Yes
MW-33
Yes
Yes
Yes
Yes
Yes
Yes
MW-34
Yes
Yes
Yes
Yes
Yes
Yes
IW-1
Yes
Yes
Yes
Yes
Yes
Yes
Injection well. Not sampled this event.
SW-3
Yes
-
-
-
-
-
Very low gage height and flow rate
SW-4R
Yes
-
-
-
-
Very low gage height and flow rate
SW-5
Yes
-
-
-
Very low gage height and flow rate
SW-6
Yes
Very low qaqe height and flow rate
Any unusual field conditions, observations, or events:
LFG extraction system operating in AOC MW-1 B which is typical.
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 3
Field Parameter Data Summary
June 28-30, 2022
Parameter
Water
Depth
Water
Elevation
TOC
Elevation
ORP
DO
Temp.
pH
Specific
Conductance
Hardness
Turbidity of
Metal Sample
Units
ft (btoc)
ft (amsl)
ft (amsl)
mV
mg/L
C
SU
umhos/cm
mg/L
NTU
MW-1
35.21
1045.33
1080.54
NR
NR
16.9
6.84
411
NR
10.6
MW-1A
45.03
1037.98
1085.32
NR
NR
17.1
6.18
103
NR
73.7
MW-1B
39.80
1042.76
1082.56
NR
NR
18.9
5.64
51
NR
92.4
MW-2
23.25
981.23
1004.48
NR
NR
14.5
6.37
403
NR
3.75
MW-3
25.58
999.15
1024.73
NR
NR
NR
NR
NR
NR
NR
MW-4R
15.69
996.95
1012.64
NR
NR
16.0
6.81
583
NR
50.4
MW-5
40.44
1010.82
1051.26
21
0.91
16.2
7.15
363
NR
27.3
MW-6
29.76
981.03
1010.79
9
2.82
14.9
6.07
52
NR
1.67
MW-7
38.53
970.71
1009.24
NR
NR
NR
NR
NR
NR
NR
MW-9
11.71
984.56
996.27
NR
NR
15.7
6.97
684
NR
20.1
MW-10
36.87
1003.93
1040.80
NR
NR
15.8
7.02
560
NR
66.9
MW-11
41.59
970.37
1011.96
5
0.96
17.5
6.69
816
NR
153
MW-12
53.77
953.58
1007.35
3
0.64
17.8
6.25
386
NR
5.24
MW-12D
61.58
946.88
1008.46
-2
1.25
21.1
7.77
883
NR
80.9
MW-13
42.43
962.13
1004.56
-5
0.71
16.3
6.19
75
NR
14.0
MW-14
38.39
959.05
997.44
NR
NR
15.1
5.65
161
NR
34.0
MW-15
24.54
998.90
1023.44
NR
NR
15.4
6.36
406
NR
9.2
MW-16
30.32
1007.24
1037.56
12
1.19
16.1
5.86
142
NR
76.2
MW-17
19.18
971.98
991.16
NR
NR
14.9
5.65
78
NR
14.8
MW-18
45.59
1038.74
1084.33
NR
NR
16.1
5.86
25
NR
89.3
MW-19
48.91
1022.57
1071.48
NR
NR
15.2
6.83
54
NR
48.2
MW-20
39.58
1007.34
1046.92
NR
NR
16.1
6.38
64
NR
4.25
MW-21
30.56
959.44
990.00
NR
NR
14.9
6.08
55
NR
1.27
MW-22
15.18
943.79
958.97
NR
NR
14.4
6.28
42
NR
6.59
MW-23
17.92
932.56
950.48
NR
NR
17.1
6.41
101
NR
7.68
MW-24
31.84
942.20
974.04
27
3.27
15.5
6.59
138
NR
39.0
MW-25
32.02
949.91
981.93
63
1.81
15.2
6.45
139
NR
6.34
MW-26
27.55
963.14
990.69
4
0.21
16.4
6.46
600
NR
104
MW-27
20.81
971.38
992.19
23
0.71
16.3
6.52
372
NR
4.93
MW-31
23.18
962.24
985.42
91
2.26
15.6
6.16
128
NR
86.3
MW-32
31.62
993.64
1025.26
NR
NR
15.4
6.09
68
NR
20.5
MW-33
13.06
994.34
1007.40
NR
NR
15.1
5.70
51
NR
1.96
MW-34
8.36
1006.24
1014.60
NR
NR
14.5
5.70
37
NR
2.54
IW-1
23.88
966.56
990.44
NR
NR
NR
NR
NR
NR
NR
Minimum
8.36
932.56
950.48
-5
0.21
14.4
5.64
25
NR
1.27
Average
31.29
984.67
1016.02
21
1.40
16.1
6.35
259
NR
37.3
Maximum
61.58
1045.33
1085.32
91
3.27
21.1
7.77
883
NR
153
SW-3
-
-
-
NR
NR
18.7
6.92
122
68.4
4.31
SW-4R
-
-
-
NR
NR
17.1
6.98
59
34.2
9.15
SW-5
-
-
-
NR
NR
20.0
7.70
94
34.2
21.0
SW-6
-
-
-
NR
NR
18.8
7.15
41
34.2
8.21
Minimum
-
-
-
NR
NR
17.1
6.92
41
34.2
4.31
Average
-
-
-
NR
NR
18.7
7.19
79
42.8
10.7
Maximum
-
-
-
NR
NR
20.0
7.70
122
68.4
21.0
NR = No Reading Attempted
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 4
Sampling and Analysis Summary
June 28-30, 2022
App. I
Other
MNA Parameters
Field Parameters
>
>
o
a)
o
>
7
X
N
w
N
N
"O
N
O
L
O
O
N
a
>
7
..T.
U
76
+�+
N
C9
"
Q
O
U
0
LL
N
!a
'O
!2
Q
O
O
Y
7
LL
O
L
O
O
O
>
o
m
m
0
2
U
w
Q
0>
m
U
I—
U
m
2
�
z
l—
2
0
U
a
I—
O
w
0
0
0
m
CD
U
NCD
Cb
N
X
N
N
O
(j
Cry
It
a_0Lr)
O
m
0
m
x
m
LL
N
N
N
N
0)
0)
a)
O
O
N
O
U
O
L
AC)
N
N
N
w
w
w
O
NN
O
04
l
N
CO
N
O
M
Q
-0
-0
-0
Method
CL
<
Q
Q
w
0
0
Q
U
wM
LL
LL
LL
LL
L-OL
LL
MW-1
x
x
x
x
x
x
x
x
MWAA
x
x
x
x
x
x
x
MW-1 B
x
x
x
x
x
x
x
x
MW-2
x
x
x
x
x
x
x
MW-3
MW-4R
x
x
x
x
x
x
x
MW-5
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-6
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-7
MW-9
x
x
x
x
x
x
x
MW-10
x
x
x
x
x
x
x
MW-11
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-12
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-12D
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-13
x
x
x
x
x
x
x
x
x
MW-14
x
x
x
x
x
x
x
MW-15
x
x
x
x
x
x
x
MW-16
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-17
x
x
x
x
x
x
x
MW-18
x
x
x
x
x
x
x
MW-19
x
x
x
x
x
x
x
MW-20
x
x
x
x
x
x
x
MW-21
x
x
x
x
x
x
x
MW-22
x
x
x
x
x
x
x
MW-23
x
x
x
x
x
x
x
MW-24
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-25
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-26
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-27
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-31
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
x
MW-32
x
x
x
x
x
x
x
MW-33
x
x
x
x
x
x
x
MW-34
x
x
x
x
x
x
x
SW-3
x
x
x
x
x
x
x
x
SW-4R
x
x
x
x
x
x
x
x
SW-5
x
x
x
x
x
x
x
x
SW-6
x
x
x
x
x
x
x
x
EB
x
x
x
FB
I x
I
I x
App I = Appendix I constituents listed in current 40 CFR 258
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 5
Groundwater and Quality Control Sample Detections
June 29-30, 2022
MW-18
MWAA
W-1
M
MWAB
MW-2
MW-4R
MW-5
MW-6
MW-9
MW-10
MW-11
MW-12
MW-12D
MW-13
MW-14
MWA5
MWA6
MWA7
MWA9
MW-20
MW-21
MW-22
MW-23
MW-24
MW-25
MW-26
MW-27
MW-31
MW-32
MW-33
MW34
EB
FB
Parameter Name
MDL
RL
2L STANDARD
MCL
BG
I S
I S
S
I S
S
S
S
S
S
S
S
I S
S
S
I S
I S
S
S
I S
I S
S
S
I S
I S
S
S
S
I S
I S
I S
I QC
QC
Metals (Targeted 40CFR 258 Appendix I)
Arsenic, total
2.2
5
10
10
2.2J
3.3J
3.7J
3.3J
4.2J
3.5J
4.1J
4.3J
3.7J
3.5J
3.8J
Barium, total
0.67
5
700
2000
16.1
25.6
44.3
75.2
74
161
38.7
48.8
284
18.3
222
137
10.7
12.9
100
46.5
67.8
66.5
15.2
48.3
35.5
50.4
28
64.3
22.4
108
54.5
116
9.1
34.9
18.2
Beryllium, total
0.054
0.5
4
4
0.12 J
0.086 J
0.27 J
0.07 J
0.22 J
0.098 J
0.21 J
0.089 J
0.089 J
0.15 J
0.97
0.097 J
0.13 J
0.093 J
0.056 J
0.068 J
0.09 J
0.066 J
0.071 J
0.22 J
0.087 J
Cadmium, total
0.11
0.5
2
5
0.16 J
0.54
2.4(N)
0.91
0.45 J
0.46 J
0.36 J
3.2(L)
0.51
1.5
0.29 J
0.14 J
1.5
0.4 J
1.1
0.2 J
1.4
0.32 J
0.15 J
1.6
1.3
0.22 J
1.2
5.1(L)
0.27 J
1.9
1.5
0.32 J
0.28 J
Chromium, total
1.1
5
10
100
1.8J
4.3J
5.1
2.4J
2J
2.5J
2J
1.7J
2.8J
1.3J
1.3J
5
1.4J
Cobalt, total
0.39
5
1
NE
2.7 J
6.2(N)
35.3(N)
52(N)
431(L)
141(L)
0.69 J
12.8(N)
451(L)
128(L)
146(L)
0.45 J
2.2 J
148(L)
51.9(L)
332(L)
47(L)
0.64 J
9.1(N)
0.48 J
18.3(N)
2.2 J
119(L)
3.2 J
2.4 J
0.71 J
25.1(N)
Copper, total
1
5
1000
1300
4J
21.1
3.2J
1.5J
2J
1.11
53.6
6.3
2J
11
3.5J
2.2J
6.3
2.7J
4.9J
2.1J
1.3J
5.4
2.3J
3.5J
1.5J
Lead, total
0.89
1
15
15
3.5
1.9
1.8
0.95 J
0.96 J
Nickel, total
0.71
5
100
NE
3.7J
3.6J
3.5J
5.1
12.5
7.7
4.5J
48.5
1.91
13.5
11.1
2.2J
5.8
15.7
2.9J
14
6
2.2J
1.3J
2.2J
1.5J
1.4J
2.1J
3.2J
12.9
2.6J
3.9J
6
4.6J
1.5J
Thallium, total
0.18
1
0.28
2
0.37 J
0.32 J
0.23 J
Vanadium, total
1.9
10
0.3
NE
3 J
3.6 J
3.5 J
2.3 J
3.1 J
4.3 J
3.3 J
3.4 J
2J
Zinc, total
7
10
1000
NE
28.6
14.2
17.3
28.9
9.5 J
16.1
15.4
71.3
10.7
12.9
22.9
17.9
10.5
7.3 J
11.2
11.4
25.3
15.4
9.7 J
8.8 J
VOCs (Targeted 40CFR 258 Appendix I and 1,4-Dioxane)
1,1-Dichloroethane
0.37
1
6
NE
2.5
0.87 J
0.58 J
4.1
0.45 J
0.41 J
1,2-Dichlorobenzene
0.34
1
20
NE
0.51 J
0.38 J
1,2-Dichloropropane
0.36
1
0.6
5
0.51 J
1,4-Dichlorobenzene
0.33
1
6
75
1.6
0.74 J
0.53 J
1.8
3.4
6.5(L)
Acetone
5.1
25
6000
NE
27.8
10.9 J
12 J
Benzene
6.34
1
1
5
0.59 J
1.1(L)
0.6 J
2.4(L)
1.2(L)
0.71 J
2.9(L)
1.9(L)
0.41 J
2.2(L)
1.2(L)
0.51 J
0.58 J
1.8(L)
0.4 J
112.9
Chlorobenzene
0.28
1
50
100
0.81 J
1.8
cis-1,2-Dichloroethene
0.38
1
70
70
2.7
4.7
12.9
10.4
2.7
11.4
8.5
0.55 J
1
2.1
1 6.8
1 16.6
1.6
0.55 J
1.2
10.7
16.1
Tetrachloroethene
0.29
1
0.7
5
0.68 J
Trichloroethene
0.38
1
3
5
0.81 J
0.63 J
Vinyl chloride
0.39
1
0.03
2
0.7 J
MINA Performance Parameters
Acetic Acid
1200
5000
NE
NE
2000 J
-
-
-
COD
12500
25000
NE
NE
53500
81800
22706 J
27500
18000 J
-
15600 J
44000
132000
-
-
Chloride
500
1000
250000
NE
3150
3640
142000
19400
65400
9700
-
21600
5050
65700
35700
18600
-
-
Ethane
0.17
1
NE
NE
0.18 J
--
-
0.23 J
--
--
-
-
Formic acid
550
5000
NE
NE
51000
-
-
-
Hydrogen (nM)
0.49
1.9
NE
NE
21
2.1
-
11
2.9
-
-
Iron, Ferrous
40
500
NE
NE
14900
42900
31500
87 J
640
-
47 J
1101
4100
-
-
Lactic Acid
530
5000
NE
NE
2500 J
-
-
-
Methane
3.4
10
NE
NE
62.2
4930
4100
6210
3590
490
-
790
2400
5.4
103
-
-
Nitrate as N
10
40
NE
NE
274
10.6 J
21.8 J
-
334
61.1
315
444
-
-
Sulfate
500
1000
250000
NE
5
5
-
5
75
-
Alkalinity, total
5000
5000
NE
NE
128000
8850
172000
160000
399000
57600
-
36700
73700
193000
42600
33700
-
-
TOC
NE
NE
5130
1060
9380
1690
3720
1180
-
2280
531 J
5010
1530
1390
-
-
Notes:
Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established.
Bold Above RL and Established 2L STD recognized by NC SWS as regulatory groundwater Standard
Highlighted Above Established MCL Drinking Water Std. (No regulatory significance)
BG = Background Well Sample, S = Seminal Well Sample, QC = Quality Control Sample
MDL = Adusted Method Detection Limit established by the laboratory via a statistical calculation.
Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "" qualifier designation.
RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets proect requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix."
2L = NC 2L Groundater Standard 15A NCAC 02L .0202
MCL = Maximum Contaminant Level for drinking water established by the USEPA.
J = "J -qualified". Defined by the lab as "estimated concentration above the adusted method detection limit and below the adusted reporting limit".
(N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic.
(L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism.
A definitive source of the detections was not determined as part of this report.
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 6
Surface Water Sample Detections
June 29-30, 2022
Parameter Name
MDL
RL
NC 2B STD
EPA
NRWQC2
s
NC ISTV
a
MCL
SW-3
SW-4R
SW-5
SW-6
Downstream
Downstream
Downstream
Downstream
Metals & VOCs (Targeted 40CFR 258 Appendix I and 1,4-Dioxane)
Barium, total
0.67
5
1000
NE
21,000
2000
43.9
28.7
38.1
22.1
Cadmium, total
0.11
0.5
0.19c, 1.08A
NE
NE
NE
0.25 J
Chromium, total
1.1
5
30.78c, 236.63A
NE
NE
NE
1.1 J
Cobalt, total
0.39
5
NE
NE
1.6c, 16A
NE
6.7
33.6
4.6 J
Nickel, total
0.71
5
20.98c, 188.91", 25
NE
NE
NE
2.6 J
2.6 J
11
Vanadium, total
1.9
10
NE
NE
NE
NE
2.9 J
Hardness as CaCo3 (Field Measured)
Hardness m /L 17.1 NE I NE NE NE 1 34.2 34.2 34.2 34.2
Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established
J = "j -qualified". Defined by the lab as "Estimated concentration above the adusted method detection limit and below the adusted reporting limit".
Red Bold Above RL and a NC regulatory compliance value
Above Established Federal MCL Primary Drinking Water Std.
Receiving surface water is Catawba River 01467)) Class WS-IV 03040102 (8-Digit HUC).
NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Dated 7/26/21.
2B Standard listed for cadmium (dissolved) chronic from calculation: WER*[{1.101672-[In hardness](0.041838))*e^{0.7998[ln hardness]-4.4451)]
2B Standard listed for Chromium III (dissolved) chronic from calculation: WER*[0.860*e^(0.8190[ln hardness]+0.6848)]
2B Standard listed for Nickel (dissolved) chronic from calculation: WER*[0.997*e^{0.8460[ln hardness]+0.0584)]
2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health.
Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses
s NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DW R staff for further information.
NC ISTV for barium freshwater All waters (Class C),All waters Fresh & Salt (Class C & SC)
ISTV Standard listed is for dissolved Cobalt but total cobalt tested so comparison inappropriate.
° MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes.
c = Chronic
A = Acute
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Table 7
Hydrogeologic Proporties at Monitoring Well Locations
June 28-30, 2022
Monitoring
Well
Hydraulic
Conductivity
cm/sec
( )
Effective
Porosity
(% )
Hydraulic
Gradient
ft/ft
( )
Average
Linear
Velocity Rate
ft/ r
( y)
Flow
Direction
Depth to
Groundwater
ft BTOC
( )
Groundwater
Pot
levati on etric
Elevation
(ft amsl)
Screened
Interval
Lithology
MW-2
3.70E-06
28
0.22
3
S53E
23.25
981.23
UC
MW-12
n/a
28
0.03
n/a
S40W
53.77
953.58
UC
MW-16
8.72E-04
17
0.05
290
S43E
30.32
1007.24
UC
MW-17
n/a
17
0.16
n/a
S45E
19.18
971.98
UC
MW-21
3.77E-03
28
0.45
6332
S25E
30.56
959.44
UC
MW-22
6.04E-04
28
0.24
544
S66E
15.18
943.79
UC
MW-23
9.83E-04
28
0.24
872
S35E
17.92
932.56
UC
MW-24
1.33E-02
28
0.07
3255
N76W
31.84
942.20
UC
MW-31
n/a
28
0.02
n/a
S31 W
23.18
962.24
UC
MW-33
n/a
28
0.13
n/a
S41 E
13.06
994.34
UC
MW-34
n/a
28
0.02
n/a
S54E
8.36
1006.24
UC
Minimum
3.70E-06
17
0.02
3
8.36
932.56
-
Average
3.26E-03
26
0.15
1883
24.24
968.62
-
Maximum
1.33E-02
28
0.45
6332
-
53.77
1007.24
-
MW-1
5.60E-05
10
0.07
42
N61 W
35.21
1045.33
UC/UBR
MW-3
3.90E-06
10
0.13
5
S16W
25.58
999.15
UC/UBR
MW-4R
4.90E-04
10
0.09
445
S24W
15.69
996.95
UC/UBR
MW-5
6.40E-05
28
0.10
24
S37E
40.44
1010.82
UC/UBR
MW-14
n/a
10
0.29
n/a
S53E
38.39
959.05
UC/UBR
MW-15
n/a
10
0.07
n/a
S28E
24.54
998.90
UC/UBR
Minimum
3.90E-06
10
0.07
5
15.69
959.05
-
Average
1.53E-04
13
0.12
129
29.98
1001.70
-
Maximum
4.90E-04
28
0.29
445
40.44
1045.33
-
MW-1 B
n/a
10
0.09
n/a
N29W
39.80
1042.76
UBR
MW-6
2.40E-05
10
0.13
32
N84W
26.27
981.03
UBR
MW-7
1.60E-06
10
0.20
3
S16W
38.53
970.71
UBR
MW-9
n/a
10
0.12
n/a
S48E
11.71
984.56
UBR
MW-11
n/a
10
0.13
n/a
S22W
41.59
970.37
UBR
MW-13
n/a
10
0.16
n/a
S74W
42.43
962.13
UBR
MW-19
1.92E-06
10
0.10
2
S45E
48.91
1022.57
UBR
MW-20
5.49E-05
10
0.06
34
S50W
39.58
1007.34
UBR
MW-25
5.41 E-05
10
0.03
16
S39W
32.02
949.91
UBR
MW-26
1.16E-04
10
0.05
61
S37W
27.55
963.14
UBR
MW-27
2.83E-05
10
0.10
29
S14W
20.81
971.38
UBR
MW-32
n/a
10
0.06
n/a
S15E
31.62
993.64
UBR
Minimum
1.60E-06
10
0.03
2
11.71
949.91
-
Average
4.01 E-05
10
0.10
25
33.40
984.96
-
Maximum
1.16E-04
10
0.20
61
48.91
1042.76
-
MW-10
n/a
10
18.90
n/a
S15E
36.87
1003.93
LBR
MW-12D
n/a
10
n/a
n/a
n/a
61.58
946.88
LBR
MW-18
1.19E-04
10
0.12
n/a
N29W
45.59
1038.74
LBR
Minimum
1.19E-04
10
0.12
-
36.87
946.88
-
Average
1.19E-04
10
9.51
-
48.01
996.52
-
Maximum
1.19E-04
10
18.90
61.58
1038.74
-
NOTE: Values for hydraulic conductivity obtained from GAI Consultants Sampling Report (April, 1995) & MESCO ACM Report (2008).
Average Linear Groundwater Velocities calculated only for UC & UBR wells with hydraulic conductivity values.
UC = Unconfined/saprolite; UBR = Upper Bedrock fracture system; LBR = Lower Bedrock fracture system.
Wells screened in LBR not utilized for flow directions/gradients.
Hydrologic Gradient calculated from potentiometrc elevations recorded on June 28-30, 2022.
Flow rate (Q) calculated via modified Darcy's equation:
K= hydraulic conductivity
ny K A n e = effective porosity
�g dh= head difference
d1= horizontal distance
Alexander County Active C&D and Closed MSWLF Page 1 of 1

Appendix A
Field Sampling Parameter Data Sheet(s)

011111 low"
Project: Alexander Co Closed MSWLF & Active C&D LF Samplers: Page_1_0f 2
TS
Sampling
Parameters
Water
Quality
Parameters
Depth to
Depth to
Water
Goes
CH4.
Monitoring
Purge
Purge
Water
Sample
Sample
gTOP
( )
Volume
Sample
Dry
Total
CO2
DO
Temp.
Specific
TDS
�
Gas
Point
Date
Time
BTOP
( )
Date
Time
Sample
Purged
Type
During(mg/1)
Comments
Depth
m /L
( g )
ORP
pH
©
Cond.
m /L
( g )
wo
Vapors
Pre -Purge
Time
(Gal)
Purge
Expected(us/cm
(ppm)
aoa�,
aaa�
a17`'l�
MW-1
(i�I
. G
; . (!'
�`1'�
Ad
40
a '
i �l
ll .r3
q I
ci,, G
MW-1A
6�
al
.
4J
�
i ri
�,
DL
48.5
MW-16
f
•
�j, ,
0: `
1 �m !?
Iruce'"t6- V. vl,
61
MW-2
yam' L1>„G
9jL=
30
33
_
MW-4R
/�'
21.5
—
6, s
MW-5
r.
�;.t
�ir�, ��
49.1
Q
1't
- I
�6)
ill
�;_
1.
v
54
MW-9i,
"?
) a
set
t 1' �5
R
i�
31.5
MW-10
t�nj``
I� ��
a( �i
r�i3
91
—
-
��
;Py
MW-11
3
I
C', (1
vim*
w.=
r,
MWW12
in! 1G(
a;0�
`�,i�
r:
it
I Ijr
66.5
�['.'
3
Cr.�
)�.�'
3 ��
�-
�•���
�1;,,
MW-12D
�%
3W
102.5
+,
��,�
MW-13
%l e�'t
LID
10
a J (
L-r'
a� ;.
3
60.5
—
'= i
��
; 7
+: M
�-
_
_
i_ C
MW-14
<:�t7
k '?�
�.�`�
r{19
^1rz
40.5
y.f.
MW-15
(.(*
iL
35(,
)•r
> �(�MJ,rt
MW-16
(n I '^r��'
°'
�°
y ;;3
lJ
40.25
MW-17Iq`
Ic�'t!
��t`v✓
i'I
ee
f`.�
{" 6'Mr
�r,22.3
—
--
6 e
�,�-��
!
MW-18
�i•).Ct=(�
T�-
�`
56:71(f,
MW-19
�
; "
I ?:.
Cn :'
%;.
63,92
Comments
SS 6=Stefnless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry"
VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear i
NR=No Reading Attempted, NS=No Sample Obtained "clxrL

Sa piing ata Sheet �" -=
r� ��-��
Project: Alexander Co Closed MSWLF &Active C&D LF Samplers:. Page_2_of_2
g ._T:.
�, �'.:�:
Sampling
Parameters
Water
Quality
Parameters
Depth to
Depth to
'
Water
Goes
�
CH4
Monitoring
Purge
Purge
Water
Sample
Sample
(STOP)
Volume
Sample
Dry
Total
CO2
DO
Temp.
Specific
Hard-
�
as
Point
Date
Time
(STOP
Date
Time
Sam le
p
Pur ed
Type
During
Comments
De th
(mg/L)
ORP
pH
©
Cond.
Hess
Vap
Pre -Purge
(Gal)
Expected
(mg/I)
(us/cm
(mg/L)
�
�rs
(pP )
oaf
Time
Purge
J'"dt��
MW-20
���`�
I����E
�.��`'�
jd`i
Gt�'��d
_
I��
T-__._�;�
�
63.55
—
____
�- .��,
/� ,i
���
G "��Fz
MW-21
Fr
1'1'.�`f�.
�U,��,
�a.�vS.�
I.--d�-
i '
..�'..,,r'
41,05
—
�
-,
e'_E"v�"�'.
i�i,`�
�,,a
-
I-,�!�-.
MW-22
���a J �
�„����/
I �, (��
f�,� ��
I f�
�
� � `�`
i,� ���
18.12
—
`-
G .��`
�� , ��
��.�,
- >'��
�
I
MW-23
�
','�Ci
� �">�.
�� r��
� � ,� �-
,:�
21.54
—
b,`-) �
��� � 1
i 3 I
-
MW-24
{��'
< ���
�,,,��
_
C
�3t'-.k
i �.� �'�,
2�!
[.3ii»
t:�
35.35
3,<>"r
� �
�,
IS,�
i a �,,
-
;��,C�
MW-25
(�. �
'���`
,�`�
�`�.Q�--
�`.�f�
`m�" c`.�`
�°;
_;�,
p�./
r"
44.48
f <�-k
�
/4�
�,�.
Imo.°,
4 ��°
-
�.a(.�
MW-26
�?/d �a,
�t = Vic`
-°
�X
'?
�� �
='�
�'t'- ; l�
1J
I '_�f?.
�
49.8
�����
�
p � ��.�
� '�
,�.�
t' .
_
I� �_
MW-27
(
;�'t
i
�5:
�� �
I � �3
I -I
`' �
°„�
49.82
rj
e �
�,
_
P�"�
:�tf�
.
MW-31
�
'�� psi
�:�.���
r' � � -
� �:�
�i
F �`
i,,
32.56
d.�r�
��",-�
11°�
�©�':
-
�{,.0
f',_
�I
MW-32
�'�
��3()
1 (�';
(ol�r�z
�.�[:�1
�.�7�1�
/��
42.7
--
(,r'��i
Imo` ��
ts; �
-
a ��
MW-33
lC) �'f'
•
l� �:;%
��F
I�;��;'�
�{
fJ�
j'�..%
21.38
—
_
I�..l
'1
' -
I• fin
MW-34
lrolo'`t
�P(i`?
ICE �o
n �t��
�
1Ca'�sa�;
(�:
� -
21.19
--
_..
1`�.
I�-(, �
.�
-
s>L���`
_
SW-5
-
-
-
-
j.
,,�,
-
-
-
—"
�-, fi ��
nr�, �a�
`���-(fa
-
� -
-
.�
SW-6
-
-
J ;.,=
'C� �
gg;ft)
I i.�,l r�d "p -#
-
-
�1 \J !
_ -
-
-
--.-
�� 9G_:
_
�
� t, � �,
-M1 P1
�a�
��l ^�
i�,
�ny1.��j
V i Yi+..�
-
��'
EB-
-
-
-
-
�
-
-
-
-
-
-
-
-
-
-
-
-
FB
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Comments
SS B=Stainless Steel Baler, D B=Disposable Baler, P=how flow Pump, PD=Purged Dry
VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear
NR=No Reading Attempted, NS=No Sample Obtained
�� y�

Appendix B
Laboratory Analysis Reports
Chains of Custody

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
July 19, 2022
Mr. Jonathan Pfohl
Municipal Engineering Services, Inc.
68 Shipwash Dr.
Garner, NC 27529
RE: Project: Alexander Landfill
Pace Project No.: 92612809
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on July 01, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Gulf Coast
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Peachtree Corners, GA
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Zachary J Tierney for
Angela Baioni
[e-mail]
[phone]
Project Manager
Enclosures
cc: Accounts Payable, Municipal Engineering Services, Inc.
Jonathan Pfohl, Municipal Engineering Services
Jay Zimmerman, PG, Municipal Engineering Services, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Alexander Landfill
Pace Project No.: 92612809
Pace Analytical Gulf Coast
7979 Innovation Park Drive, Baton Rouge, LA 70820
Arkansas Certification #: 88-0655
DoD ELAP Certification #: 6429-01
Florida Certification #: E87854
Illinois Certification #: 004585
Kansas Certification #: E-10354
Louisiana/LELAP Certification #: 01955
North Carolina Certification #: 618
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
Pace Analytical Services Peachtree Corners
110 Technology Pkwy, Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
CERTIFICATIONS
North Dakota Certification #: R-195
Oklahoma Certification #: 2019-101
South Carolina Certification #: 73006001
Texas Certification #: T104704178-19-11
USDA Soil Permit # P330-19-00209
Virginia Certification #: 460215
Washington Certification #: C929
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
South Carolina Laboratory ID: 99030
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Certification #: 381
South Carolina Certification #: 98011001
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Alexander Landfill
Pace Project No.: 92612809
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92612809001
MW-6
Water
06/30/22 16:05
07/01/22 11:00
92612809002
MW-5
Water
06/30/22 14:56
07/01/22 11:00
92612809003
MW-12D
Water
06/30/2215:30
07/01/22 11:00
92612809004
MW-24
Water
06/30/2212:46
07/01/22 11:00
92612809005
MW-26
Water
06/30/2211:50
07/01/22 11:00
92612809006
MW-31
Water
06/30/2211:35
07/01/22 11:00
92612809007
MW-12
Water
06/30/22 07:40
07/01/22 11:00
92612809008
MW-25
Water
06/30/2217:15
07/01/22 11:00
92612809009
MW-27
Water
06/30/2211:13
07/01/22 11:00
92612809010
MW-11
Water
06/30/2217:05
07/01/22 11:00
92612809011
MW-16
Water
06/30/2216:51
07/01/22 11:00
92612809012
MW-13
Water
06/30/2216:10
07/01/22 11:00
92612809013
MW-14
Water
06/30/2216:07
07/01/22 11:00
92612809014
MW-15
Water
06/30/2216:35
07/01/22 11:00
92612809015
MW-17
Water
06/30/2213:23
07/01/22 11:00
92612809016
MW-18
Water
06/30/22 07:58
07/01/22 11:00
92612809017
MW-19
Water
06/30/2216:26
07/01/22 11:00
92612809018
MW-20
Water
06/30/22 12:52
07/01/22 11:00
92612809019
MW-21
Water
06/30/2213:17
07/01/22 11:00
92612809020
MW-22
Water
06/30/2213:12
07/01/22 11:00
92612809021
MW-23
Water
06/30/22 13:07
07/01/22 11:00
92612809022
MW-32
Water
06/29/2213:40
07/01/22 11:00
92612809023
MW-33
Water
06/30/22 10:08
07/01/22 11:00
92612809024
MW-34
Water
06/30/22 10:00
07/01/22 11:00
92612809025
SW-3
Water
06/30/22 10:30
07/01/22 11:00
92612809026
SW-4R
Water
06/29/2212:25
07/01/22 11:00
92612809027
SW-5
Water
06/30/22 10:33
07/01/22 11:00
92612809028
SW-6
Water
06/30/2210:14
07/01/22 11:00
92612809029
MW-1
Water
06/30/22 08:10
07/01/22 11:00
92612809030
MW-1B
Water
06/30/2216:22
07/01/22 11:00
92612809031
MW-2
Water
06/30/22 16:22
07/01/22 11:00
92612809032
MW-4R
Water
06/29/2213:26
07/01/22 11:00
92612809033
MW-10
Water
06/30/2216:48
07/01/22 11:00
92612809034
MW-9
Water
06/30/22 16:55
07/01/22 11:00
92612809035
MW-1A
Water
06/30/2216:24
07/01/22 11:00
92612809036
EB
Water
06/30/22 17:00
07/01/22 11:00
92612809037
FB
Water
06/30/22 17:03
07/01/22 11:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Alexander Landfill
Pace Project No.: 92612809
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92612809038
MW-11
Water
06/30/2217:05
07/01/2211:00
92612809039
MW-16
Water
06/30/2216:51
07/01/2211:00
92612809040
MW-25
Water
06/30/2217:15
07/01/2211:00
92612809041
MW-27
Water
06/30/2211:13
07/01/2211:00
92612809042
MW-12D
Water
06/30/2215:30
07/01/2211:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Alexander Landfill
92612809
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92612809001
MW-6
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809002
MW-5
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809003
MW-12D
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809004
MW-24
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Alexander Landfill
Pace Project No.: 92612809
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809005
MW-26
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809006
MW-31
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809007
MW-12
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Alexander Landfill
Pace Project No.:
92612809
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809008
MW-25
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809009
MW-27
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809010
MW-11
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809011
MW-16
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
SM 2320B-2011
SMS
1
PASI-A
SM 3500-Fe B-2011
JMH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Alexander Landfill
92612809
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
SM 4500-S2D-2011
JP1
1
PASI-A
EPA 300.0 Rev 2.1 1993
JCM
1
PASI-A
EPA 353.2 Rev 2.0 1993
MFO
1
PASI-A
SM 4500-CI-E-2011
ANM
1
PASI-A
SM 5220D-2011
JMH1
1
PASI-A
SM 531OB-2014
MJP
1
PASI-A
92612809012
MW-13
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809013
MW-14
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809014
MW-15
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809015
MW-17
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809016
MW-18
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809017
MW-19
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809018
MW-20
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809019
MW-21
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809020
MW-22
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809021
MW-23
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809022
MW-32
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809023
MW-33
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809024
MW-34
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809025
SW-3
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809026
SW-4R
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809027
SW-5
EPA6020B
CW1
15
PASI-GA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Alexander Landfill
Pace Project No.:
92612809
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 8260D
CL
51
PASI-C
92612809028
SW-6
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809029
MW-1
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809030
MW-113
RSK 175 Modified
LMB
1
PASI-C
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809031
MW-2
EPA6020B
CW1
15
PASI-GA
EPA 8260D
SAS
51
PASI-C
92612809032
MW-4R
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809033
MW-10
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809034
MW-9
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809035
MWAA
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809036
EB
EPA6020B
CW1
15
PASI-GA
EPA 8260D
CL
51
PASI-C
92612809037
FB
EPA 8260D
CL
51
PASI-C
92612809038
MW-11
AM20GAX
LMB
1
GCLA
AM20GAX
LMB
3
GCLA
92612809039
MW-16
AM20GAX
LMB
1
GCLA
AM20GAX
LMB
3
GCLA
92612809040
MW-25
AM20GAX
LMB
1
GCLA
AM20GAX
LMB
3
GCLA
92612809041
MW-27
AM20GAX
LMB
1
GCLA
AM20GAX
LMB
3
GCLA
92612809042
MW-12D
AM23G
SLL2
10
GCLA
GCLA = Pace Analytical Gulf Coast
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-GA = Pace Analytical Services - Peachtree Corners, GA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-6 Lab ID: 92612809001 Collected: 06/30/22 16:05 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND
ug/L
10.0
3.4
1
07/01/22 22:41
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/22 08:08
07/08/22 19:50
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/22 08:08
07/08/22 19:50
7440-38-2
Barium
48.8
ug/L
5.0
0.67
1 07/06/22 08:08
07/08/22 19:50
7440-39-3
Beryllium
0.0981
ug/L
0.50
0.054
1 07/06/22 08:08
07/08/22 19:50
7440-41-7
Cadmium
0.36J
ug/L
0.50
0.11
1 07/06/22 08:08
07/08/22 19:50
7440-43-9
Chromium
5.1
ug/L
5.0
1.1
1 07/06/22 08:08
07/08/22 19:50
7440-47-3
Cobalt
12.8
ug/L
5.0
0.39
1 07/06/22 08:08
07/08/22 19:50
7440-48-4
Copper
2.OJ
ug/L
5.0
1.0
1 07/06/22 08:08
07/08/22 19:50
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/22 08:08
07/08/22 19:50
7439-92-1
Nickel
4.5J
ug/L
5.0
0.71
1 07/06/22 08:08
07/08/22 19:50
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/22 08:08
07/08/22 19:50
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/22 08:08
07/08/22 19:50
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/22 08:08
07/08/22 19:50
7440-28-0
Vanadium
3.5J
ug/L
10.0
1.9
1 07/06/22 08:08
07/08/22 19:50
7440-62-2
Zinc
9.5J
ug/L
10.0
7.0
1 07/06/22 08:08
07/08/22 19:50
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 22:21
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 22:21
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 22:21
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 22:21
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 22:21
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 22:21
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 22:21
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 22:21
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 22:21
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 22:21
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 22:21
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 22:21
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 22:21
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 22:21
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 22:21
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 22:21
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 22:21
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 22:21
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 22:21
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 22:21
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 22:21
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 22:21
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 22:21
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-6 Lab ID: 92612809001 Collected: 06/30/22 16:05 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.35
1
07/05/22 22:21
75-35-4
ND ug/L 1.0
0.38
1
07/05/22 22:21
156-59-2
ND ug/L 1.0
0.40
1
07/05/22 22:21
156-60-5
ND ug/L 1.0
0.36
1
07/05/22 22:21
78-87-5
ND ug/L 1.0
0.36
1
07/05/22 22:21
10061-01-5
ND ug/L 1.0
0.36
1
07/05/22 22:21
10061-02-6
ND ug/L 150
38.7
1
07/05/22 22:21
123-91-1
ND ug/L 1.0
0.30
1
07/05/22 22:21
100-41-4
ND ug/L 5.0
0.48
1
07/05/22 22:21
591-78-6
ND ug/L 20.0
9.7
1
07/05/22 22:21
74-88-4
ND ug/L 5.0
2.0
1
07/05/22 22:21
75-09-2
ND ug/L 5.0
2.7
1
07/05/22 22:21
108-10-1
ND ug/L 1.0
0.29
1
07/05/22 22:21
100-42-5
ND ug/L 1.0
0.31
1
07/05/22 22:21
630-20-6
ND ug/L 1.0
0.22
1
07/05/22 22:21
79-34-5
ND ug/L 1.0
0.29
1
07/05/22 22:21
127-18-4
ND ug/L 1.0
0.48
1
07/05/22 22:21
108-88-3
ND ug/L 1.0
0.33
1
07/05/22 22:21
71-55-6
ND ug/L 1.0
0.32
1
07/05/22 22:21
79-00-5
ND ug/L 1.0
0.38
1
07/05/22 22:21
79-01-6
ND ug/L 1.0
0.30
1
07/05/22 22:21
75-69-4
ND ug/L 1.0
0.26
1
07/05/22 22:21
96-18-4
ND ug/L 2.0
1.3
1
07/05/22 22:21
108-05-4
ND ug/L 1.0
0.39
1
07/05/22 22:21
75-01-4
ND ug/L 1.0
0.34
1
07/05/22 22:21
1330-20-7
102 % 70-130
1
07/05/22 22:21
460-00-4
105 % 70-130
1
07/05/22 22:21
17060-07-0
103 % 70-130
1
07/05/22 22:21
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
8850 ug/L 5000
5000
1
07/02/22 21:11
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
ND mg/L 0.50
0.040
1
07/05/2215:14
H3,N2
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:01
18496-25-8 M1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
1960 ug/L 1000
500
1
07/04/22 05:06
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 154

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9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-6
Parameters
Lab ID: 92612809001 Collected:
Report
Results Units Limit
06/30/22 16:05
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
274 ug/L 40.0
10.0
1
07/02/22 00:24
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3640 ug/L 1000
500
1
07/11/2213:29
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:13
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1060 ug/L 1000
500
1
07/05/22 20:42
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 154

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9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-5 Lab ID: 92612809002 Collected: 06/30/22 14:56 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
4930
ug/L
10.0
3.4
1
07/01/22 22:57
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/22 08:08
07/08/22 19:56
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/22 08:08
07/08/22 19:56
7440-38-2
Barium
38.7
ug/L
5.0
0.67
1 07/06/22 08:08
07/08/22 19:56
7440-39-3
Beryllium
0.22J
ug/L
0.50
0.054
1 07/06/22 08:08
07/08/22 19:56
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/06/22 08:08
07/08/22 19:56
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/22 08:08
07/08/22 19:56
7440-47-3
Cobalt
0.69J
ug/L
5.0
0.39
1 07/06/22 08:08
07/08/22 19:56
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/06/22 08:08
07/08/22 19:56
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/22 08:08
07/08/22 19:56
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1 07/06/22 08:08
07/08/22 19:56
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/22 08:08
07/08/22 19:56
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/22 08:08
07/08/22 19:56
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/22 08:08
07/08/22 19:56
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/22 08:08
07/08/22 19:56
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/22 08:08
07/08/22 19:56
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
10.91
ug/L
25.0
5.1
1
07/05/22 14:32
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 14:32
107-13-1
Benzene
2.4
ug/L
1.0
0.34
1
07/05/22 14:32
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 14:32
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 14:32
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 14:32
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 14:32
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 14:32
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 14:32
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 14:32
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 14:32
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 14:32
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 14:32
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 14:32
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 14:32
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 14:32
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 14:32
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 14:32
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 14:32
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 14:32
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 14:32
110-57-6
1,1-Dichloroethane
2.5
ug/L
1.0
0.37
1
07/05/22 14:32
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 14:32
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 154

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[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-5 Lab ID: 92612809002 Collected: 06/30/22 14:56 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.35
1
07/05/2214:32
75-35-4
12.9 ug/L 1.0
0.38
1
07/05/2214:32
156-59-2
ND ug/L 1.0
0.40
1
07/05/2214:32
156-60-5
ND ug/L 1.0
0.36
1
07/05/2214:32
78-87-5
ND ug/L 1.0
0.36
1
07/05/22 14:32
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2214:32
10061-02-6
ND ug/L 150
38.7
1
07/05/2214:32
123-91-1
ND ug/L 1.0
0.30
1
07/05/2214:32
100-41-4
ND ug/L 5.0
0.48
1
07/05/2214:32
591-78-6
ND ug/L 20.0
9.7
1
07/05/2214:32
74-88-4
ND ug/L 5.0
2.0
1
07/05/2214:32
75-09-2
ND ug/L 5.0
2.7
1
07/05/2214:32
108-10-1
ND ug/L 1.0
0.29
1
07/05/2214:32
100-42-5
ND ug/L 1.0
0.31
1
07/05/2214:32
630-20-6
ND ug/L 1.0
0.22
1
07/05/2214:32
79-34-5
ND ug/L 1.0
0.29
1
07/05/2214:32
127-18-4
ND ug/L 1.0
0.48
1
07/05/2214:32
108-88-3
ND ug/L 1.0
0.33
1
07/05/2214:32
71-55-6
ND ug/L 1.0
0.32
1
07/05/2214:32
79-00-5
ND ug/L 1.0
0.38
1
07/05/2214:32
79-01-6
ND ug/L 1.0
0.30
1
07/05/2214:32
75-69-4
ND ug/L 1.0
0.26
1
07/05/2214:32
96-18-4
ND ug/L 2.0
1.3
1
07/05/2214:32
108-05-4
ND ug/L 1.0
0.39
1
07/05/2214:32
75-01-4
ND ug/L 1.0
0.34
1
07/05/2214:32
1330-20-7
99 % 70-130
1
07/05/2214:32
460-00-4
108 % 70-130
1
07/05/2214:32
17060-07-0
100 % 70-130
1
07/05/2214:32
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
128000 ug/L 5000
5000
1
07/02/22 21:17
M1
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
14.9 mg/L 2.5
0.20
5
07/05/2215:44
H3,N2
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:03
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
4460 ug/L 1000
500
1
07/04/22 05:22
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 154

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-5
Parameters
Lab ID: 92612809002 Collected:
Report
Results Units Limit
06/30/22 14:56
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
07/02/22 00:13
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3150 ug/L 1000
500
1
07/11/2213:29
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
53500 ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:13
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
5130 ug/L 1000
500
1
07/05/22 21:33
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 154

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12D Lab ID: 92612809003 Collected: 06/30/22 15:30 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
3590
ug/L
10.0
3.4
1
07/01/22 23:12
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/22 08:08
07/08/22 20:02
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/22 08:08
07/08/22 20:02
7440-38-2 B
Barium
10.7
ug/L
5.0
0.67
1 07/06/22 08:08
07/08/22 20:02
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/06/22 08:08
07/08/22 20:02
7440-41-7
Cadmium
0.29J
ug/L
0.50
0.11
1 07/06/22 08:08
07/08/22 20:02
7440-43-9
Chromium
2.OJ
ug/L
5.0
1.1
1 07/06/22 08:08
07/08/22 20:02
7440-47-3
Cobalt
0.45J
ug/L
5.0
0.39
1 07/06/22 08:08
07/08/22 20:02
7440-48-4
Copper
2.OJ
ug/L
5.0
1.0
1 07/06/22 08:08
07/08/22 20:02
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/22 08:08
07/08/22 20:02
7439-92-1
Nickel
2.2J
ug/L
5.0
0.71
1 07/06/22 08:08
07/08/22 20:02
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/22 08:08
07/08/22 20:02
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/22 08:08
07/08/22 20:02
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/22 08:08
07/08/22 20:02
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/22 08:08
07/08/22 20:02
7440-62-2
Zinc
12.9
ug/L
10.0
7.0
1 07/06/22 08:08
07/08/22 20:02
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 14:50
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 14:50
107-13-1
Benzene
0.41J
ug/L
1.0
0.34
1
07/05/22 14:50
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 14:50
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 14:50
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 14:50
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 14:50
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 14:50
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 14:50
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 14:50
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 14:50
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 14:50
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 14:50
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 14:50
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 14:50
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 14:50
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 14:50
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 14:50
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 14:50
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 14:50
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 14:50
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 14:50
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 14:50
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 154

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12D Lab ID: 92612809003 Collected: 06/30/22 15:30 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.35
1
07/05/2214:50
75-35-4
0.55.1 ug/L
1.0
0.38
1
07/05/2214:50
156-59-2
ND ug/L
1.0
0.40
1
07/05/2214:50
156-60-5
ND ug/L
1.0
0.36
1
07/05/2214:50
78-87-5
ND ug/L
1.0
0.36
1
07/05/22 14:50
10061-01-5
ND ug/L
1.0
0.36
1
07/05/2214:50
10061-02-6
ND ug/L
150
38.7
1
07/05/2214:50
123-91-1
ND ug/L
1.0
0.30
1
07/05/2214:50
100-41-4
ND ug/L
5.0
0.48
1
07/05/2214:50
591-78-6
ND ug/L
20.0
9.7
1
07/05/2214:50
74-88-4
ND ug/L
5.0
2.0
1
07/05/2214:50
75-09-2
ND ug/L
5.0
2.7
1
07/05/2214:50
108-10-1
ND ug/L
1.0
0.29
1
07/05/2214:50
100-42-5
ND ug/L
1.0
0.31
1
07/05/2214:50
630-20-6
ND ug/L
1.0
0.22
1
07/05/2214:50
79-34-5
ND ug/L
1.0
0.29
1
07/05/2214:50
127-18-4
ND ug/L
1.0
0.48
1
07/05/2214:50
108-88-3
ND ug/L
1.0
0.33
1
07/05/2214:50
71-55-6
ND ug/L
1.0
0.32
1
07/05/2214:50
79-00-5
ND ug/L
1.0
0.38
1
07/05/2214:50
79-01-6
ND ug/L
1.0
0.30
1
07/05/2214:50
75-69-4
ND ug/L
1.0
0.26
1
07/05/2214:50
96-18-4
ND ug/L
2.0
1.3
1
07/05/2214:50
108-05-4
ND ug/L
1.0
0.39
1
07/05/2214:50
75-01-4
ND ug/L
1.0
0.34
1
07/05/2214:50
1330-20-7
100 %
70-130
1
07/05/2214:50
460-00-4
112 %
70-130
1
07/05/2214:50
17060-07-0
102 %
70-130
1
07/05/2214:50
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
399000 ug/L
5000
5000
1
07/05/2213:47
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services
-Asheville
0.087.11 mg/L
0.50
0.040
1
07/05/2215:12
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
ND ug/L
100
50.0
1
07/02/22 02:03
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services
-Asheville
ND ug/L
1000
500
1
07/04/22 05:38
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 17 of 154

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12D
Parameters
Lab ID: 92612809003 Collected:
Report
Results Units Limit
06/30/22 15:30
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
10.6J ug/L 40.0
10.0
1
07/02/22 00:19
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
65400 ug/L 5000
2500
5
07/11/2214:11
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
27500 ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:13
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
3720 ug/L 1000
500
1
07/06/22 00:17
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-24 Lab ID: 92612809004 Collected: 06/30/22 12:46 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND
ug/L
10.0
3.4
1
07/01/22 23:27
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/22 08:08
07/08/22 20:08
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/22 08:08
07/08/22 20:08
7440-38-2
Barium
64.3
ug/L
5.0
0.67
1 07/06/22 08:08
07/08/22 20:08
7440-39-3
Beryllium
0.0901
ug/L
0.50
0.054
1 07/06/22 08:08
07/08/22 20:08
7440-41-7
Cadmium
0.22J
ug/L
0.50
0.11
1 07/06/22 08:08
07/08/22 20:08
7440-43-9
Chromium
1.3J
ug/L
5.0
1.1
1 07/06/22 08:08
07/08/22 20:08
7440-47-3
Cobalt
18.3
ug/L
5.0
0.39
1 07/06/22 08:08
07/08/22 20:08
7440-48-4
Copper
1.3J
ug/L
5.0
1.0
1 07/06/22 08:08
07/08/22 20:08
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/22 08:08
07/08/22 20:08
7439-92-1
Nickel
2.1J
ug/L
5.0
0.71
1 07/06/22 08:08
07/08/22 20:08
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/22 08:08
07/08/22 20:08
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/22 08:08
07/08/22 20:08
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/22 08:08
07/08/22 20:08
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/22 08:08
07/08/22 20:08
7440-62-2
Zinc
11.4
ug/L
10.0
7.0
1 07/06/22 08:08
07/08/22 20:08
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 15:09
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 15:09
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 15:09
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 15:09
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 15:09
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 15:09
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 15:09
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 15:09
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 15:09
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 15:09
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 15:09
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 15:09
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 15:09
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 15:09
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 15:09
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 15:09
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 15:09
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 15:09
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 15:09
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 15:09
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 15:09
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 15:09
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 15:09
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-24 Lab ID: 92612809004 Collected: 06/30/22 12:46 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.35
1
07/05/2215:09
75-35-4
ND ug/L
1.0
0.38
1
07/05/2215:09
156-59-2
ND ug/L
1.0
0.40
1
07/05/2215:09
156-60-5
ND ug/L
1.0
0.36
1
07/05/2215:09
78-87-5
ND ug/L
1.0
0.36
1
07/05/22 15:09
10061-01-5
ND ug/L
1.0
0.36
1
07/05/2215:09
10061-02-6
ND ug/L
150
38.7
1
07/05/2215:09
123-91-1
ND ug/L
1.0
0.30
1
07/05/2215:09
100-41-4
ND ug/L
5.0
0.48
1
07/05/2215:09
591-78-6
ND ug/L
20.0
9.7
1
07/05/2215:09
74-88-4
ND ug/L
5.0
2.0
1
07/05/2215:09
75-09-2
ND ug/L
5.0
2.7
1
07/05/2215:09
108-10-1
ND ug/L
1.0
0.29
1
07/05/2215:09
100-42-5
ND ug/L
1.0
0.31
1
07/05/2215:09
630-20-6
ND ug/L
1.0
0.22
1
07/05/2215:09
79-34-5
ND ug/L
1.0
0.29
1
07/05/2215:09
127-18-4
ND ug/L
1.0
0.48
1
07/05/2215:09
108-88-3
ND ug/L
1.0
0.33
1
07/05/2215:09
71-55-6
ND ug/L
1.0
0.32
1
07/05/2215:09
79-00-5
ND ug/L
1.0
0.38
1
07/05/2215:09
79-01-6
ND ug/L
1.0
0.30
1
07/05/2215:09
75-69-4
ND ug/L
1.0
0.26
1
07/05/2215:09
96-18-4
ND ug/L
2.0
1.3
1
07/05/2215:09
108-05-4
ND ug/L
1.0
0.39
1
07/05/2215:09
75-01-4
ND ug/L
1.0
0.34
1
07/05/2215:09
1330-20-7
103 %
70-130
1
07/05/2215:09
460-00-4
108 %
70-130
1
07/05/2215:09
17060-07-0
103 %
70-130
1
07/05/2215:09
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
36700 ug/L
5000
5000
1
07/02/22 21:48
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services
-Asheville
0.047.11 mg/L
0.50
0.040
1
07/05/2215:10
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
ND ug/L
100
50.0
1
07/02/22 02:04
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services
-Asheville
3630 ug/L
1000
500
1
07/04/22 05:54
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 20 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-24
Parameters
Lab ID: 92612809004 Collected:
Report
Results Units Limit
06/30/22 12:46
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
334 ug/L 40.0
10.0
1
07/02/22 00:11
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
21600 ug/L 1000
500
1
07/11/2213:31
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:13
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
2280 ug/L 1000
500
1
07/05/22 22:26
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-26 Lab ID: 92612809005 Collected: 06/30/22 11:50 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
2400
ug/L
10.0
3.4
1
07/01/22 23:43
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/22 08:08
07/08/22 20:14
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/22 08:08
07/08/22 20:14
7440-38-2
Barium
108
ug/L
5.0
0.67
1 07/06/22 08:08
07/08/22 20:14
7440-39-3
Beryllium
0.066J
ug/L
0.50
0.054
1 07/06/22 08:08
07/08/22 20:14
7440-41-7
Cadmium
5.1
ug/L
0.50
0.11
1 07/06/22 08:08
07/08/22 20:14
7440-43-9
Chromium
1.3J
ug/L
5.0
1.1
1 07/06/22 08:08
07/08/22 20:14
7440-47-3
Cobalt
119
ug/L
5.0
0.39
1 07/06/22 08:08
07/08/22 20:14
7440-48-4
Copper
5.4
ug/L
5.0
1.0
1 07/06/22 08:08
07/08/22 20:14
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/22 08:08
07/08/22 20:14
7439-92-1
Nickel
12.9
ug/L
5.0
0.71
1 07/06/22 08:08
07/08/22 20:14
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/22 08:08
07/08/22 20:14
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/22 08:08
07/08/22 20:14
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/22 08:08
07/08/22 20:14
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/22 08:08
07/08/22 20:14
7440-62-2
Zinc
25.3
ug/L
10.0
7.0
1 07/06/22 08:08
07/08/22 20:14
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 15:28
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 15:28
107-13-1
Benzene
1.8
ug/L
1.0
0.34
1
07/05/22 15:28
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 15:28
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 15:28
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 15:28
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 15:28
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 15:28
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 15:28
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 15:28
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 15:28
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 15:28
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 15:28
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 15:28
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 15:28
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 15:28
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 15:28
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 15:28
74-95-3
1,2-Dichlorobenzene
0.38J
ug/L
1.0
0.34
1
07/05/22 15:28
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 15:28
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 15:28
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 15:28
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 15:28
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-26 Lab ID: 92612809005 Collected: 06/30/22 11:50 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.35
1
07/05/2215:28
75-35-4
10.7 ug/L
1.0
0.38
1
07/05/2215:28
156-59-2
ND ug/L
1.0
0.40
1
07/05/2215:28
156-60-5
ND ug/L
1.0
0.36
1
07/05/2215:28
78-87-5
ND ug/L
1.0
0.36
1
07/05/22 15:28
10061-01-5
ND ug/L
1.0
0.36
1
07/05/2215:28
10061-02-6
ND ug/L
150
38.7
1
07/05/2215:28
123-91-1
ND ug/L
1.0
0.30
1
07/05/2215:28
100-41-4
ND ug/L
5.0
0.48
1
07/05/2215:28
591-78-6
ND ug/L
20.0
9.7
1
07/05/2215:28
74-88-4
ND ug/L
5.0
2.0
1
07/05/2215:28
75-09-2
ND ug/L
5.0
2.7
1
07/05/2215:28
108-10-1
ND ug/L
1.0
0.29
1
07/05/2215:28
100-42-5
ND ug/L
1.0
0.31
1
07/05/2215:28
630-20-6
ND ug/L
1.0
0.22
1
07/05/2215:28
79-34-5
ND ug/L
1.0
0.29
1
07/05/2215:28
127-18-4
ND ug/L
1.0
0.48
1
07/05/2215:28
108-88-3
ND ug/L
1.0
0.33
1
07/05/2215:28
71-55-6
ND ug/L
1.0
0.32
1
07/05/2215:28
79-00-5
ND ug/L
1.0
0.38
1
07/05/2215:28
79-01-6
ND ug/L
1.0
0.30
1
07/05/2215:28
75-69-4
ND ug/L
1.0
0.26
1
07/05/2215:28
96-18-4
ND ug/L
2.0
1.3
1
07/05/2215:28
108-05-4
ND ug/L
1.0
0.39
1
07/05/2215:28
75-01-4
ND ug/L
1.0
0.34
1
07/05/2215:28
1330-20-7
103 %
70-130
1
07/05/2215:28
460-00-4
109 %
70-130
1
07/05/2215:28
17060-07-0
106 %
70-130
1
07/05/2215:28
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
193000 ug/L
5000
5000
1
07/02/22 22:05
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services
-Asheville
4.1 mg/L
1.0
0.080
2
07/05/2215:28
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
ND ug/L
100
50.0
1
07/02/22 02:05
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services
-Asheville
5330 ug/L
1000
500
1
07/04/22 06:10
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 23 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-26
Parameters
Lab ID: 92612809005 Collected:
Report
Results Units Limit
06/30/22 11:50
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
07/02/22 00:06
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
65700 ug/L 5000
2500
5
07/11/2214:12
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
44000 ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:13
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
5010 ug/L 1000
500
1
07/05/22 22:44
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 24 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-31 Lab ID: 92612809006 Collected: 06/30/22 11:35 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
103
ug/L
10.0
3.4
1
07/01/22 23:58
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:07
7440-36-0
Arsenic
3.8J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:07
7440-38-2
Barium
116
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:07
7440-39-3
Beryllium
0.22J
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:07
7440-41-7
Cadmium
1.9
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:07
7440-43-9
Chromium
5.0
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:07
7440-47-3
Cobalt
2.4J
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:07
7440-48-4
Copper
2.3J
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:07
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:07
7439-92-1
Nickel
3.9J
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:07
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:07
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:07
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:07
7440-28-0
Vanadium
6.OJ
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:07
7440-62-2
Zinc
15.4
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:07
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 15:46
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 15:46
107-13-1
Benzene
0.40J
ug/L
1.0
0.34
1
07/05/22 15:46
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 15:46
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 15:46
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 15:46
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 15:46
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 15:46
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 15:46
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 15:46
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 15:46
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 15:46
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 15:46
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 15:46
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 15:46
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 15:46
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 15:46
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 15:46
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 15:46
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 15:46
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 15:46
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 15:46
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 15:46
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-31 Lab ID: 92612809006 Collected: 06/30/22 11:35 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L
1.0
0.35
1
07/05/2215:46
75-35-4
1.4 ug/L
1.0
0.38
1
07/05/2215:46
156-59-2
ND ug/L
1.0
0.40
1
07/05/2215:46
156-60-5
ND ug/L
1.0
0.36
1
07/05/2215:46
78-87-5
ND ug/L
1.0
0.36
1
07/05/22 15:46
10061-01-5
ND ug/L
1.0
0.36
1
07/05/2215:46
10061-02-6
ND ug/L
150
38.7
1
07/05/2215:46
123-91-1
ND ug/L
1.0
0.30
1
07/05/2215:46
100-41-4
ND ug/L
5.0
0.48
1
07/05/2215:46
591-78-6
ND ug/L
20.0
9.7
1
07/05/2215:46
74-88-4
ND ug/L
5.0
2.0
1
07/05/2215:46
75-09-2
ND ug/L
5.0
2.7
1
07/05/2215:46
108-10-1
ND ug/L
1.0
0.29
1
07/05/2215:46
100-42-5
ND ug/L
1.0
0.31
1
07/05/2215:46
630-20-6
ND ug/L
1.0
0.22
1
07/05/2215:46
79-34-5
ND ug/L
1.0
0.29
1
07/05/2215:46
127-18-4
ND ug/L
1.0
0.48
1
07/05/2215:46
108-88-3
ND ug/L
1.0
0.33
1
07/05/2215:46
71-55-6
ND ug/L
1.0
0.32
1
07/05/2215:46
79-00-5
ND ug/L
1.0
0.38
1
07/05/2215:46
79-01-6
ND ug/L
1.0
0.30
1
07/05/2215:46
75-69-4
ND ug/L
1.0
0.26
1
07/05/2215:46
96-18-4
ND ug/L
2.0
1.3
1
07/05/2215:46
108-05-4
ND ug/L
1.0
0.39
1
07/05/2215:46
75-01-4
ND ug/L
1.0
0.34
1
07/05/2215:46
1330-20-7
101 %
70-130
1
07/05/2215:46
460-00-4
104 %
70-130
1
07/05/2215:46
17060-07-0
101 %
70-130
1
07/05/2215:46
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services
-Asheville
33700 ug/L
5000
5000
1
07/02/22 22:21
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services
-Asheville
ND mg/L
0.50
0.040
1
07/05/2215:07
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services
-Asheville
ND ug/L
100
50.0
1
07/02/22 02:05
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services
-Asheville
875J ug/L
1000
500
1
07/04/22 06:57
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 26 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-31
Parameters
Lab ID: 92612809006 Collected:
Report
Results Units Limit
06/30/22 11:35
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
444 ug/L 40.0
10.0
1
07/02/22 00:05
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
18600 ug/L 1000
500
1
07/11/2213:34
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:14
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1390 ug/L 1000
500
1
07/05/22 23:04
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12 Lab ID: 92612809007 Collected: 06/30/22 07:40 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
6210
ug/L
10.0
3.4
1
07/06/22 20:25
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:13
7440-36-0
Arsenic
3.7J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:13
7440-38-2
Barium
137
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:13
7440-39-3
Beryllium
0.0891
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:13
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:13
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:13
7440-47-3
Cobalt
146
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:13
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:13
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:13
7439-92-1
Nickel
11.1
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:13
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:13
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:13
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:13
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:13
7440-62-2
Zinc
10.7
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:13
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 16:05
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 16:05
107-13-1
Benzene
1.9
ug/L
1.0
0.34
1
07/05/22 16:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 16:05
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 16:05
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 16:05
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 16:05
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 16:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 16:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 16:05
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 16:05
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 16:05
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 16:05
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 16:05
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 16:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 16:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 16:05
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 16:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 16:05
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 16:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 16:05
110-57-6
1,1-Dichloroethane
0.87J
ug/L
1.0
0.37
1
07/05/22 16:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 16:05
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12 Lab ID: 92612809007 Collected: 06/30/22 07:40 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.35
1
07/05/2216:05
75-35-4
8.5 ug/L 1.0
0.38
1
07/05/2216:05
156-59-2
ND ug/L 1.0
0.40
1
07/05/2216:05
156-60-5
ND ug/L 1.0
0.36
1
07/05/2216:05
78-87-5
ND ug/L 1.0
0.36
1
07/05/22 16:05
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2216:05
10061-02-6
ND ug/L 150
38.7
1
07/05/2216:05
123-91-1
ND ug/L 1.0
0.30
1
07/05/2216:05
100-41-4
ND ug/L 5.0
0.48
1
07/05/2216:05
591-78-6
ND ug/L 20.0
9.7
1
07/05/2216:05
74-88-4
ND ug/L 5.0
2.0
1
07/05/2216:05
75-09-2
ND ug/L 5.0
2.7
1
07/05/2216:05
108-10-1
ND ug/L 1.0
0.29
1
07/05/2216:05
100-42-5
ND ug/L 1.0
0.31
1
07/05/2216:05
630-20-6
ND ug/L 1.0
0.22
1
07/05/2216:05
79-34-5
ND ug/L 1.0
0.29
1
07/05/2216:05
127-18-4
ND ug/L 1.0
0.48
1
07/05/2216:05
108-88-3
ND ug/L 1.0
0.33
1
07/05/2216:05
71-55-6
ND ug/L 1.0
0.32
1
07/05/2216:05
79-00-5
0.811 ug/L 1.0
0.38
1
07/05/2216:05
79-01-6
ND ug/L 1.0
0.30
1
07/05/2216:05
75-69-4
ND ug/L 1.0
0.26
1
07/05/2216:05
96-18-4
ND ug/L 2.0
1.3
1
07/05/2216:05
108-05-4
ND ug/L 1.0
0.39
1
07/05/2216:05
75-01-4
ND ug/L 1.0
0.34
1
07/05/2216:05
1330-20-7
103 % 70-130
1
07/05/2216:05
460-00-4
105 % 70-130
1
07/05/2216:05
17060-07-0
103 % 70-130
1
07/05/2216:05
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
160000 ug/L 5000
5000
1
07/02/22 22:28
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
31.5 mg/L 12.5
1.0
25
07/05/2216:09
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:06
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
2560 ug/L 1000
500
1
07/04/22 07:45
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 29 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12
Parameters
Lab ID: 92612809007 Collected:
Report
Results Units Limit
06/30/22 07:40
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
07/02/22 00:01
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
19400 ug/L 1000
500
1
07/11/2213:37
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
22700J ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:14
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1690 ug/L 1000
500
1
07/05/22 23:22
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 30 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-25 Lab ID: 92612809008 Collected: 06/30/22 17:15 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:19
7440-36-0
Arsenic
3.7J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:19
7440-38-2
Barium
22.4
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:19
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:19
7440-41-7
Cadmium
1.2
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:19
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:19
7440-47-3
Cobalt
2.2.1
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:19
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:19
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:19
7439-92-1
Nickel
3.2.1
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:19
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:19
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:19
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:19
7440-28-0
Vanadium
2.0.1
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:19
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:19
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 16:24
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 16:24
107-13-1
Benzene
0.58J
ug/L
1.0
0.34
1
07/05/22 16:24
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 16:24
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 16:24
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 16:24
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 16:24
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 16:24
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 16:24
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 16:24
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 16:24
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 16:24
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 16:24
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 16:24
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 16:24
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 16:24
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 16:24
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 16:24
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 16:24
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 16:24
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 16:24
110-57-6
1,1-Dichloroethane
0.45J
ug/L
1.0
0.37
1
07/05/22 16:24
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 16:24
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 16:24
75-35-4
cis-1,2-Dichloroethene
1.2
ug/L
1.0
0.38
1
07/05/22 16:24
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 16:24
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 16:24
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-25 Lab ID: 92612809008 Collected: 06/30/22 17:15 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.36
1
07/05/22 16:24
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2216:24
10061-02-6
ND ug/L 150
38.7
1
07/05/2216:24
123-91-1
ND ug/L 1.0
0.30
1
07/05/2216:24
100-41-4
ND ug/L 5.0
0.48
1
07/05/2216:24
591-78-6
ND ug/L 20.0
9.7
1
07/05/2216:24
74-88-4
ND ug/L 5.0
2.0
1
07/05/2216:24
75-09-2
ND ug/L 5.0
2.7
1
07/05/2216:24
108-10-1
ND ug/L 1.0
0.29
1
07/05/2216:24
100-42-5
ND ug/L 1.0
0.31
1
07/05/2216:24
630-20-6
ND ug/L 1.0
0.22
1
07/05/2216:24
79-34-5
ND ug/L 1.0
0.29
1
07/05/2216:24
127-18-4
ND ug/L 1.0
0.48
1
07/05/2216:24
108-88-3
ND ug/L 1.0
0.33
1
07/05/2216:24
71-55-6
ND ug/L 1.0
0.32
1
07/05/2216:24
79-00-5
ND ug/L 1.0
0.38
1
07/05/2216:24
79-01-6
ND ug/L 1.0
0.30
1
07/05/2216:24
75-69-4
ND ug/L 1.0
0.26
1
07/05/2216:24
96-18-4
ND ug/L 2.0
1.3
1
07/05/2216:24
108-05-4
ND ug/L 1.0
0.39
1
07/05/2216:24
75-01-4
ND ug/L 1.0
0.34
1
07/05/2216:24
1330-20-7
98 % 70-130
1
07/05/2216:24
460-00-4
110 % 70-130
1
07/05/2216:24
17060-07-0
104 % 70-130
1
07/05/2216:24
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
73700 ug/L 5000
5000
1
07/02/22 22:45
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
0.111.1 mg/L 0.50
0.040
1
07/05/2215:17
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:06
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
2620 ug/L 1000
500
1
07/04/22 08:01
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 32 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-25
Parameters
Lab ID: 92612809008 Collected:
Report
Results Units Limit
06/30/22 17:15
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
61.1 ug/L 40.0
10.0
1
07/02/22 00:28
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
5050 ug/L 1000
500
1
07/11/2213:42
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
15600J ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:14
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
531J ug/L 1000
500
1
07/06/22 02:07
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 33 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-27 Lab ID: 92612809009 Collected: 06/30/22 11:13 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:25
7440-36-0
Arsenic
3.5J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:25
7440-38-2
Barium
54.5
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:25
7440-39-3
Beryllium
0.071J
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:25
7440-41-7
Cadmium
0.27J
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:25
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:25
7440-47-3
Cobalt
3.2.1
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:25
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:25
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:25
7439-92-1
Nickel
2.6.1
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:25
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:25
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:25
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:25
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:25
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:25
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 16:43
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 16:43
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 16:43
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 16:43
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 16:43
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 16:43
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 16:43
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 16:43
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 16:43
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 16:43
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 16:43
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 16:43
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 16:43
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 16:43
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 16:43
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 16:43
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 16:43
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 16:43
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 16:43
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 16:43
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 16:43
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 16:43
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 16:43
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 16:43
75-35-4
cis-1,2-Dichloroethene
16.1
ug/L
1.0
0.38
1
07/05/22 16:43
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 16:43
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 16:43
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-27 Lab ID: 92612809009 Collected: 06/30/22 11:13 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.36
1
07/05/22 16:43
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2216:43
10061-02-6
ND ug/L 150
38.7
1
07/05/2216:43
123-91-1
ND ug/L 1.0
0.30
1
07/05/2216:43
100-41-4
ND ug/L 5.0
0.48
1
07/05/2216:43
591-78-6
ND ug/L 20.0
9.7
1
07/05/2216:43
74-88-4
ND ug/L 5.0
2.0
1
07/05/2216:43
75-09-2
ND ug/L 5.0
2.7
1
07/05/2216:43
108-10-1
ND ug/L 1.0
0.29
1
07/05/2216:43
100-42-5
ND ug/L 1.0
0.31
1
07/05/2216:43
630-20-6
ND ug/L 1.0
0.22
1
07/05/2216:43
79-34-5
ND ug/L 1.0
0.29
1
07/05/2216:43
127-18-4
ND ug/L 1.0
0.48
1
07/05/2216:43
108-88-3
ND ug/L 1.0
0.33
1
07/05/2216:43
71-55-6
ND ug/L 1.0
0.32
1
07/05/2216:43
79-00-5
ND ug/L 1.0
0.38
1
07/05/2216:43
79-01-6
ND ug/L 1.0
0.30
1
07/05/2216:43
75-69-4
ND ug/L 1.0
0.26
1
07/05/2216:43
96-18-4
ND ug/L 2.0
1.3
1
07/05/2216:43
108-05-4
ND ug/L 1.0
0.39
1
07/05/2216:43
75-01-4
ND ug/L 1.0
0.34
1
07/05/2216:43
1330-20-7
101 % 70-130
1
07/05/2216:43
460-00-4
102 % 70-130
1
07/05/2216:43
17060-07-0
102 % 70-130
1
07/05/2216:43
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
42600 ug/L 5000
5000
1
07/02/22 22:55
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
ND mg/L 0.50
0.040
1
07/05/2215:05
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:06
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
4130 ug/L 1000
500
1
07/04/22 08:17
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 35 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-27
Parameters
Lab ID: 92612809009 Collected:
Report
Results Units Limit
06/30/22 11:13
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
315 ug/L 40.0
10.0
1
07/02/22 00:04
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
35700 ug/L 1000
500
1
07/11/2213:45
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
132000 ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:15
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1530 ug/L 1000
500
1
07/06/22 02:59
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 36 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-11 Lab ID: 92612809010 Collected: 06/30/22 17:05 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:31
7440-36-0
Arsenic
3.3J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:31
7440-38-2
Barium
222
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:31
7440-39-3
Beryllium
0.0891
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:31
7440-41-7
Cadmium
1.5
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:31
7440-43-9
Chromium
2.4J
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:31
7440-47-3
Cobalt
128
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:31
7440-48-4
Copper
6.3
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:31
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:31
7439-92-1
Nickel
13.5
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:31
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:31
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:31
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:31
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:31
7440-62-2
Zinc
71.3
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:31
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 17:02
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 17:02
107-13-1
Benzene
2.9
ug/L
1.0
0.34
1
07/05/22 17:02
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 17:02
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 17:02
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 17:02
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 17:02
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 17:02
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 17:02
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 17:02
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 17:02
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 17:02
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 17:02
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 17:02
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 17:02
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 17:02
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 17:02
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 17:02
74-95-3
1,2-Dichlorobenzene
0.51J
ug/L
1.0
0.34
1
07/05/22 17:02
95-50-1
1,4-Dichlorobenzene
6.5
ug/L
1.0
0.33
1
07/05/22 17:02
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 17:02
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 17:02
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:02
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 17:02
75-35-4
cis-1,2-Dichloroethene
11.4
ug/L
1.0
0.38
1
07/05/22 17:02
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 17:02
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 17:02
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-11 Lab ID: 92612809010 Collected: 06/30/22 17:05 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.36
1
07/05/22 17:02
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2217:02
10061-02-6
ND ug/L 150
38.7
1
07/05/2217:02
123-91-1
ND ug/L 1.0
0.30
1
07/05/2217:02
100-41-4
ND ug/L 5.0
0.48
1
07/05/2217:02
591-78-6
ND ug/L 20.0
9.7
1
07/05/2217:02
74-88-4
ND ug/L 5.0
2.0
1
07/05/2217:02
75-09-2
ND ug/L 5.0
2.7
1
07/05/2217:02
108-10-1
ND ug/L 1.0
0.29
1
07/05/2217:02
100-42-5
ND ug/L 1.0
0.31
1
07/05/2217:02
630-20-6
ND ug/L 1.0
0.22
1
07/05/2217:02
79-34-5
ND ug/L 1.0
0.29
1
07/05/2217:02
127-18-4
ND ug/L 1.0
0.48
1
07/05/2217:02
108-88-3
ND ug/L 1.0
0.33
1
07/05/2217:02
71-55-6
ND ug/L 1.0
0.32
1
07/05/2217:02
79-00-5
ND ug/L 1.0
0.38
1
07/05/2217:02
79-01-6
ND ug/L 1.0
0.30
1
07/05/2217:02
75-69-4
ND ug/L 1.0
0.26
1
07/05/2217:02
96-18-4
ND ug/L 2.0
1.3
1
07/05/2217:02
108-05-4
ND ug/L 1.0
0.39
1
07/05/2217:02
75-01-4
ND ug/L 1.0
0.34
1
07/05/2217:02
1330-20-7
99 % 70-130
1
07/05/2217:02
460-00-4
110 % 70-130
1
07/05/2217:02
17060-07-0
103 % 70-130
1
07/05/2217:02
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
172000 ug/L 5000
5000
1
07/05/2213:21
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
42.9 mg/L 12.5
1.0
25
07/05/2216:10
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:07
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
2580 ug/L 1000
500
1
07/04/22 08:33
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
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lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-11
Parameters
Lab ID: 92612809010 Collected:
Report
Results Units Limit
06/30/22 17:05
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
07/02/22 00:26
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
142000 ug/L 10000
5000
10
07/11/2214:13
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
81800 ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:15
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
9380 ug/L 1000
500
1
07/06/22 03:15
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 39 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-16 Lab ID: 92612809011 Collected: 06/30/22 16:51 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:37
7440-36-0
Arsenic
4.1J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:37
7440-38-2
Barium
67.8
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:37
7440-39-3
Beryllium
0.097J
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:37
7440-41-7
Cadmium
1.1
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:37
7440-43-9
Chromium
2.5J
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:37
7440-47-3
Cobalt
332
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:37
7440-48-4
Copper
6.3
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:37
7440-50-8
Lead
1.8
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:37
7439-92-1
Nickel
14.0
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:37
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:37
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:37
7440-22-4
Thallium
0.23J
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:37
7440-28-0
Vanadium
4.3.1
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:37
7440-62-2
Zinc
17.9
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:37
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 17:21
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 17:21
107-13-1
Benzene
1.2
ug/L
1.0
0.34
1
07/05/22 17:21
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 17:21
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 17:21
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 17:21
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 17:21
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 17:21
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 17:21
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 17:21
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 17:21
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 17:21
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 17:21
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 17:21
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 17:21
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 17:21
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 17:21
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 17:21
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 17:21
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 17:21
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 17:21
110-57-6
1,1-Dichloroethane
4.1
ug/L
1.0
0.37
1
07/05/22 17:21
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:21
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 17:21
75-35-4
cis-1,2-Dichloroethene
16.6
ug/L
1.0
0.38
1
07/05/22 17:21
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 17:21
156-60-5
1,2-Dichloropropane
0.51J
ug/L
1.0
0.36
1
07/05/22 17:21
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-16 Lab ID: 92612809011 Collected: 06/30/22 16:51 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
2320B Alkalinity
Alkalinity, Total as CaCO3
Iron, Ferrous
Iron, Ferrous
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND ug/L 1.0
0.36
1
07/05/22 17:21
10061-01-5
ND ug/L 1.0
0.36
1
07/05/2217:21
10061-02-6
ND ug/L 150
38.7
1
07/05/2217:21
123-91-1
ND ug/L 1.0
0.30
1
07/05/2217:21
100-41-4
ND ug/L 5.0
0.48
1
07/05/2217:21
591-78-6
ND ug/L 20.0
9.7
1
07/05/2217:21
74-88-4
ND ug/L 5.0
2.0
1
07/05/2217:21
75-09-2
ND ug/L 5.0
2.7
1
07/05/2217:21
108-10-1
ND ug/L 1.0
0.29
1
07/05/2217:21
100-42-5
ND ug/L 1.0
0.31
1
07/05/2217:21
630-20-6
ND ug/L 1.0
0.22
1
07/05/2217:21
79-34-5
0.68.1 ug/L 1.0
0.29
1
07/05/2217:21
127-18-4
ND ug/L 1.0
0.48
1
07/05/2217:21
108-88-3
ND ug/L 1.0
0.33
1
07/05/2217:21
71-55-6
ND ug/L 1.0
0.32
1
07/05/2217:21
79-00-5
0.63J ug/L 1.0
0.38
1
07/05/2217:21
79-01-6
ND ug/L 1.0
0.30
1
07/05/2217:21
75-69-4
ND ug/L 1.0
0.26
1
07/05/2217:21
96-18-4
ND ug/L 2.0
1.3
1
07/05/2217:21
108-05-4
ND ug/L 1.0
0.39
1
07/05/2217:21
75-01-4
ND ug/L 1.0
0.34
1
07/05/2217:21
1330-20-7
98 % 70-130
1
07/05/2217:21
460-00-4
110 % 70-130
1
07/05/2217:21
17060-07-0
102 % 70-130
1
07/05/2217:21
2037-26-5
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
57600 ug/L 5000
5000
1
07/02/22 23:14
Analytical Method: SM 3500-Fe B-2011
Pace Analytical Services -Asheville
0.64 mg/L 0.50
0.040
1
07/05/2215:14
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
ND ug/L 100
50.0
1
07/02/22 02:08
18496-25-8
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
6920 ug/L 1000
500
1
07/04/22 08:49
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
H3,N2
Page 41 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-16
Parameters
Lab ID: 92612809011 Collected:
Report
Results Units Limit
06/30/22 16:51
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
21.8J ug/L 40.0
10.0
1
07/02/22 00:25
14797-55-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
9700 ug/L 1000
500
1
07/11/2213:47
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
18000J ug/L 25000
12500
1
07/06/22 14:16 07/07/22 10:15
531013 TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services -Asheville
Total Organic Carbon
1180 ug/L 1000
500
1
07/06/22 03:35
7440-44-0
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 42 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-13 Lab ID: 92612809012 Collected: 06/30/22 16:10 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2218:43
7440-36-0
Arsenic
3.3J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2218:43
7440-38-2
Barium
12.9
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2218:43
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2218:43
7440-41-7
Cadmium
0.14J
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2218:43
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2218:43
7440-47-3
Cobalt
2.2.1
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2218:43
7440-48-4
Copper
1.0.1
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2218:43
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2218:43
7439-92-1
Nickel
5.8
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2218:43
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2218:43
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2218:43
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2218:43
7440-28-0
Vanadium
2.3.1
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2218:43
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2218:43
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 17:39
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 17:39
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 17:39
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 17:39
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 17:39
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 17:39
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 17:39
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 17:39
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 17:39
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 17:39
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 17:39
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 17:39
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 17:39
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 17:39
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 17:39
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 17:39
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 17:39
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 17:39
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 17:39
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 17:39
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 17:39
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 17:39
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:39
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 17:39
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 17:39
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 17:39
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 17:39
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-13
Parameters
Lab ID:
Results
92612809012
Units
Collected:
Report
Limit
06/30/22 16:10
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 17:39
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 17:39
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 17:39
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 17:39
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 17:39
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 17:39
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 17:39
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 17:39
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 17:39
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 17:39
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 17:39
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 17:39
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 17:39
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 17:39
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:39
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 17:39
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 17:39
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 17:39
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 17:39
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 17:39
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 17:39
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
103
%
70-130
1
07/05/22 17:39
460-00-4
1,2-Dichloroethane-d4 (S)
111
%
70-130
1
07/05/22 17:39
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
07/05/22 17:39
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 44 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-14 Lab ID: 92612809013 Collected: 06/30/22 16:07 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2219:00
7440-36-0
Arsenic
4.2J
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2219:00
7440-38-2
Barium
100
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2219:00
7440-39-3
Beryllium
0.15J
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2219:00
7440-41-7
Cadmium
1.5
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2219:00
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2219:00
7440-47-3
Cobalt
148
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2219:00
7440-48-4
Copper
3.5.1
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2219:00
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2219:00
7439-92-1
Nickel
15.7
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2219:00
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2219:00
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2219:00
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2219:00
7440-28-0
Vanadium
3.1J
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2219:00
7440-62-2
Zinc
22.9
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2219:00
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 17:58
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 17:58
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 17:58
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 17:58
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 17:58
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 17:58
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 17:58
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 17:58
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 17:58
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 17:58
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 17:58
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 17:58
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 17:58
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 17:58
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 17:58
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 17:58
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 17:58
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 17:58
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 17:58
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 17:58
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 17:58
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 17:58
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:58
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 17:58
75-35-4
cis-1,2-Dichloroethene
2.1
ug/L
1.0
0.38
1
07/05/22 17:58
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 17:58
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 17:58
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-14
Parameters
Lab ID:
Results
92612809013
Units
Collected:
Report
Limit
06/30/22 16:07
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 17:58
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 17:58
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 17:58
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 17:58
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 17:58
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 17:58
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 17:58
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 17:58
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 17:58
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 17:58
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 17:58
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 17:58
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 17:58
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 17:58
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 17:58
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 17:58
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 17:58
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 17:58
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 17:58
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 17:58
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 17:58
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
07/05/22 17:58
460-00-4
1,2-Dichloroethane-d4 (S)
108
%
70-130
1
07/05/22 17:58
17060-07-0
Toluene-d8 (S)
104
%
70-130
1
07/05/22 17:58
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 46 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-15 Lab ID: 92612809014 Collected: 06/30/22 16:35 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2219:06
7440-36-0
Arsenic
3.5.1
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2219:06
7440-38-2
Barium
46.5
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2219:06
7440-39-3
Beryllium
0.97
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2219:06
7440-41-7
Cadmium
0.40J
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2219:06
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2219:06
7440-47-3
Cobalt
51.9
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2219:06
7440-48-4
Copper
2.2J
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2219:06
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2219:06
7439-92-1
Nickel
2.9J
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2219:06
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2219:06
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2219:06
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2219:06
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2219:06
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2219:06
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 18:17
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 18:17
107-13-1
Benzene
2.2
ug/L
1.0
0.34
1
07/05/22 18:17
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 18:17
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 18:17
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 18:17
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 18:17
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 18:17
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 18:17
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 18:17
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 18:17
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 18:17
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 18:17
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 18:17
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 18:17
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 18:17
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 18:17
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 18:17
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 18:17
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 18:17
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 18:17
110-57-6
1,1-Dichloroethane
0.58J
ug/L
1.0
0.37
1
07/05/22 18:17
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:17
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 18:17
75-35-4
cis-1,2-Dichloroethene
6.8
ug/L
1.0
0.38
1
07/05/22 18:17
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 18:17
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 18:17
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-15
Parameters
Lab ID:
Results
92612809014
Units
Collected:
Report
Limit
06/30/22 16:35
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:17
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:17
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 18:17
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 18:17
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 18:17
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 18:17
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 18:17
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 18:17
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 18:17
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 18:17
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 18:17
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 18:17
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 18:17
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 18:17
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:17
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 18:17
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 18:17
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 18:17
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 18:17
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 18:17
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 18:17
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
07/05/22 18:17
460-00-4
1,2-Dichloroethane-d4 (S)
110
%
70-130
1
07/05/22 18:17
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
07/05/22 18:17
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 48 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-17 Lab ID: 92612809015 Collected: 06/30/22 13:23 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2219:12
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2219:12
7440-38-2
Barium
66.5
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2219:12
7440-39-3
Beryllium
0.13J
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2219:12
7440-41-7
Cadmium
0.20J
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2219:12
7440-43-9
Chromium
2.0.1
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2219:12
7440-47-3
Cobalt
47.0
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2219:12
7440-48-4
Copper
2.7.1
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2219:12
7440-50-8
Lead
0.95J
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2219:12
7439-92-1
Nickel
6.0
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2219:12
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2219:12
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2219:12
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2219:12
7440-28-0
Vanadium
3.3.1
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2219:12
7440-62-2
Zinc
10.5
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2219:12
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 18:36
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 18:36
107-13-1
Benzene
0.51J
ug/L
1.0
0.34
1
07/05/22 18:36
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 18:36
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 18:36
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 18:36
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 18:36
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 18:36
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 18:36
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 18:36
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 18:36
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 18:36
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 18:36
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 18:36
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 18:36
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 18:36
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 18:36
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 18:36
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 18:36
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 18:36
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 18:36
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 18:36
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:36
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 18:36
75-35-4
cis-1,2-Dichloroethene
1.6
ug/L
1.0
0.38
1
07/05/22 18:36
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 18:36
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 18:36
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-17
Parameters
Lab ID:
Results
92612809015
Units
Collected:
Report
Limit
06/30/22 13:23
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:36
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:36
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 18:36
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 18:36
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 18:36
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 18:36
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 18:36
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 18:36
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 18:36
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 18:36
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 18:36
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 18:36
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 18:36
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 18:36
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:36
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 18:36
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 18:36
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 18:36
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 18:36
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 18:36
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 18:36
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
07/05/22 18:36
460-00-4
1,2-Dichloroethane-d4 (S)
105
%
70-130
1
07/05/22 18:36
17060-07-0
Toluene-d8 (S)
107
%
70-130
1
07/05/22 18:36
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 50 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-18 Lab ID: 92612809016 Collected: 06/30/22 07:58 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2219:18
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2219:18
7440-38-2
Barium
16.1
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2219:18
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2219:18
7440-41-7
Cadmium
0.16J
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2219:18
7440-43-9
Chromium
1.81
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2219:18
7440-47-3
Cobalt
2.7.1
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2219:18
7440-48-4
Copper
4.0.1
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2219:18
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2219:18
7439-92-1
Nickel
3.7.1
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2219:18
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2219:18
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2219:18
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2219:18
7440-28-0
Vanadium
3.0.1
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2219:18
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2219:18
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 18:55
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 18:55
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 18:55
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 18:55
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 18:55
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 18:55
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 18:55
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 18:55
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 18:55
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 18:55
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 18:55
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 18:55
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 18:55
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 18:55
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 18:55
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 18:55
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 18:55
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 18:55
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 18:55
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 18:55
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 18:55
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 18:55
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:55
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 18:55
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 18:55
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 18:55
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 18:55
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-18
Parameters
Lab ID:
Results
92612809016
Units
Collected:
Report
Limit
06/30/22 07:58
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:55
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 18:55
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 18:55
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 18:55
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 18:55
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 18:55
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 18:55
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 18:55
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 18:55
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 18:55
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 18:55
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 18:55
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 18:55
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 18:55
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 18:55
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 18:55
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 18:55
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 18:55
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 18:55
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 18:55
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 18:55
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
07/05/22 18:55
460-00-4
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
07/05/22 18:55
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/05/22 18:55
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 52 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-19 Lab ID: 92612809017 Collected: 06/30/22 16:26 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/06/2211:43
07/07/2219:24
7440-36-0
Arsenic
4.3.1
ug/L
5.0
2.2
1 07/06/2211:43
07/07/2219:24
7440-38-2
Barium
15.2
ug/L
5.0
0.67
1 07/06/2211:43
07/07/2219:24
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/06/2211:43
07/07/2219:24
7440-41-7
Cadmium
1.4
ug/L
0.50
0.11
1 07/06/2211:43
07/07/2219:24
7440-43-9
Chromium
1.7.1
ug/L
5.0
1.1
1 07/06/2211:43
07/07/2219:24
7440-47-3
Cobalt
0.64J
ug/L
5.0
0.39
1 07/06/2211:43
07/07/2219:24
7440-48-4
Copper
4.9.1
ug/L
5.0
1.0
1 07/06/2211:43
07/07/2219:24
7440-50-8
Lead
0.96J
ug/L
1.0
0.89
1 07/06/2211:43
07/07/2219:24
7439-92-1
Nickel
2.2.1
ug/L
5.0
0.71
1 07/06/2211:43
07/07/2219:24
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/06/2211:43
07/07/2219:24
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/06/2211:43
07/07/2219:24
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/06/2211:43
07/07/2219:24
7440-28-0
Vanadium
3.4J
ug/L
10.0
1.9
1 07/06/2211:43
07/07/2219:24
7440-62-2
Zinc
7.3J
ug/L
10.0
7.0
1 07/06/2211:43
07/07/2219:24
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 19:14
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 19:14
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 19:14
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 19:14
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 19:14
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 19:14
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 19:14
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 19:14
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 19:14
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 19:14
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 19:14
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 19:14
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 19:14
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 19:14
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 19:14
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 19:14
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 19:14
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 19:14
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 19:14
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 19:14
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 19:14
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 19:14
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:14
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 19:14
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 19:14
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 19:14
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 19:14
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-19
Parameters
Lab ID:
Results
92612809017
Units
Collected:
Report
Limit
06/30/22 16:26
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:14
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:14
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 19:14
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 19:14
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 19:14
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 19:14
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 19:14
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 19:14
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 19:14
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 19:14
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 19:14
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 19:14
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 19:14
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 19:14
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:14
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 19:14
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 19:14
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 19:14
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 19:14
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 19:14
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 19:14
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
07/05/22 19:14
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
07/05/22 19:14
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
07/05/22 19:14
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 54 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-20 Lab ID: 92612809018 Collected: 06/30/22 12:52 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:17
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:17
7440-38-2
Barium
48.3
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:17
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:17
7440-41-7
Cadmium
0.32J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:17
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:17
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:17
7440-48-4
Copper
2.1J
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:17
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:17
7439-92-1
Nickel
1.3.1
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:17
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:17
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:17
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:17
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:17
7440-62-2
Zinc
11.2
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:17
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 19:32
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 19:32
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 19:32
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 19:32
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 19:32
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 19:32
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 19:32
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 19:32
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 19:32
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 19:32
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 19:32
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 19:32
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 19:32
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 19:32
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 19:32
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 19:32
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 19:32
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 19:32
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 19:32
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 19:32
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 19:32
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 19:32
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:32
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 19:32
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 19:32
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 19:32
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 19:32
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-20
Parameters
Lab ID:
Results
92612809018
Units
Collected:
Report
Limit
06/30/22 12:52
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:32
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:32
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 19:32
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 19:32
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 19:32
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 19:32
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 19:32
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 19:32
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 19:32
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 19:32
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 19:32
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 19:32
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 19:32
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 19:32
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:32
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 19:32
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 19:32
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 19:32
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 19:32
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 19:32
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 19:32
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
07/05/22 19:32
460-00-4
1,2-Dichloroethane-d4 (S)
109
%
70-130
1
07/05/22 19:32
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/05/22 19:32
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 56 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-21 Lab ID: 92612809019 Collected: 06/30/22 13:17 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:22
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:22
7440-38-2
Barium
35.5
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:22
7440-39-3
Beryllium
0.093J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:22
7440-41-7
Cadmium
0.15J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:22
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:22
7440-47-3
Cobalt
9.1
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:22
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:22
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:22
7439-92-1
Nickel
2.2.1
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:22
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:22
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:22
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:22
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:22
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:22
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 19:51
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 19:51
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 19:51
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 19:51
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 19:51
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 19:51
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 19:51
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 19:51
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 19:51
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 19:51
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 19:51
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 19:51
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 19:51
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 19:51
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 19:51
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 19:51
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 19:51
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 19:51
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 19:51
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 19:51
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 19:51
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 19:51
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:51
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 19:51
75-35-4
cis-1,2-Dichloroethene
0.55J
ug/L
1.0
0.38
1
07/05/22 19:51
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 19:51
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 19:51
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-21
Parameters
Lab ID:
Results
92612809019
Units
Collected:
Report
Limit
06/30/22 13:17
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:51
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 19:51
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 19:51
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 19:51
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 19:51
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 19:51
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 19:51
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 19:51
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 19:51
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 19:51
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 19:51
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 19:51
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 19:51
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 19:51
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 19:51
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 19:51
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 19:51
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 19:51
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 19:51
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 19:51
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 19:51
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/05/22 19:51
460-00-4
1,2-Dichloroethane-d4 (S)
106
%
70-130
1
07/05/22 19:51
17060-07-0
Toluene-d8 (S)
106
%
70-130
1
07/05/22 19:51
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 58 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-22 Lab ID: 92612809020 Collected: 06/30/22 13:12 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:28
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:28
7440-38-2
Barium
50.4
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:28
7440-39-3
Beryllium
0.056J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:28
7440-41-7
Cadmium
1.6
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:28
7440-43-9
Chromium
2.8.1
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:28
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:28
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:28
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:28
7439-92-1
Nickel
1.5.1
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:28
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:28
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:28
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:28
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:28
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:28
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 20:10
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 20:10
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 20:10
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 20:10
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 20:10
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 20:10
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 20:10
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 20:10
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 20:10
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 20:10
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 20:10
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 20:10
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 20:10
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 20:10
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 20:10
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 20:10
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 20:10
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 20:10
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 20:10
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 20:10
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 20:10
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 20:10
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:10
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 20:10
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:10
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 20:10
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 20:10
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-22
Parameters
Lab ID:
Results
92612809020
Units
Collected:
Report
Limit
06/30/22 13:12
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:10
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:10
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 20:10
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 20:10
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 20:10
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 20:10
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 20:10
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 20:10
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 20:10
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 20:10
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 20:10
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 20:10
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 20:10
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 20:10
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:10
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:10
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 20:10
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 20:10
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 20:10
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 20:10
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 20:10
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
07/05/22 20:10
460-00-4
1,2-Dichloroethane-d4 (S)
104
%
70-130
1
07/05/22 20:10
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
07/05/22 20:10
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 60 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-23 Lab ID: 92612809021 Collected: 06/30/22 13:07 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:34
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:34
7440-38-2
Barium
28.0
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:34
7440-39-3
Beryllium
0.068J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:34
7440-41-7
Cadmium
1.3
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:34
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:34
7440-47-3
Cobalt
0.48J
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:34
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:34
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:34
7439-92-1
Nickel
1.4J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:34
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:34
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:34
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:34
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:34
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:34
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 20:29
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 20:29
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 20:29
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 20:29
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 20:29
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 20:29
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 20:29
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 20:29
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 20:29
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 20:29
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 20:29
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 20:29
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 20:29
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 20:29
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 20:29
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 20:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 20:29
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 20:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 20:29
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 20:29
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 20:29
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 20:29
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:29
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 20:29
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:29
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 20:29
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 20:29
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-23
Parameters
Lab ID:
Results
92612809021
Units
Collected:
Report
Limit
06/30/22 13:07
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:29
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:29
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 20:29
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 20:29
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 20:29
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 20:29
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 20:29
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 20:29
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 20:29
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 20:29
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 20:29
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 20:29
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 20:29
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 20:29
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:29
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:29
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 20:29
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 20:29
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 20:29
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 20:29
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 20:29
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/05/22 20:29
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
07/05/22 20:29
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/05/22 20:29
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 62 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-32 Lab ID: 92612809022 Collected: 06/29/22 13:40 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:52
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:52
7440-38-2
Barium
9.1
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:52
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:52
7440-41-7
Cadmium
1.5
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:52
7440-43-9
Chromium
1.4J
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:52
7440-47-3
Cobalt
0.71J
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:52
7440-48-4
Copper
3.5.1
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:52
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:52
7439-92-1
Nickel
6.0
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:52
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:52
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:52
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:52
7440-28-0
Vanadium
1.91
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:52
7440-62-2
Zinc
9.7J
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:52
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 20:48
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 20:48
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 20:48
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 20:48
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 20:48
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 20:48
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 20:48
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 20:48
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 20:48
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 20:48
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 20:48
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 20:48
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 20:48
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 20:48
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 20:48
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 20:48
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 20:48
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 20:48
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 20:48
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 20:48
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 20:48
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 20:48
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:48
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 20:48
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:48
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 20:48
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 20:48
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-32
Parameters
Lab ID:
Results
92612809022
Units
Collected:
Report
Limit
06/29/22 13:40
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:48
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 20:48
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 20:48
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 20:48
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 20:48
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 20:48
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 20:48
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 20:48
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 20:48
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 20:48
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 20:48
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 20:48
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 20:48
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 20:48
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 20:48
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 20:48
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 20:48
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 20:48
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 20:48
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 20:48
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 20:48
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
07/05/22 20:48
460-00-4
1,2-Dichloroethane-d4 (S)
107
%
70-130
1
07/05/22 20:48
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
07/05/22 20:48
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 64 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-33 Lab ID: 92612809023 Collected: 06/30/22 10:08 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 14:58
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 14:58
7440-38-2
Barium
34.9
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 14:58
7440-39-3
Beryllium
0.087J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 14:58
7440-41-7
Cadmium
0.32J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 14:58
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 14:58
7440-47-3
Cobalt
25.1
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 14:58
7440-48-4
Copper
1.5J
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 14:58
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 14:58
7439-92-1
Nickel
4.6J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 14:58
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 14:58
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 14:58
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 14:58
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 14:58
7440-62-2
Zinc
8.81
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 14:58
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 21:07
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 21:07
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 21:07
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 21:07
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 21:07
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 21:07
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 21:07
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 21:07
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 21:07
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 21:07
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 21:07
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 21:07
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 21:07
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 21:07
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 21:07
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 21:07
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 21:07
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 21:07
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 21:07
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 21:07
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 21:07
110-57-6
1,1-Dichloroethane
0.41J
ug/L
1.0
0.37
1
07/05/22 21:07
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 21:07
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 21:07
75-35-4
cis-1,2-Dichloroethene
1.9
ug/L
1.0
0.38
1
07/05/22 21:07
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 21:07
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 21:07
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-33
Parameters
Lab ID:
Results
92612809023
Units
Collected:
Report
Limit
06/30/22 10:08
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 21:07
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 21:07
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 21:07
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 21:07
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 21:07
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 21:07
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 21:07
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 21:07
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 21:07
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 21:07
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 21:07
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 21:07
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 21:07
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 21:07
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 21:07
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 21:07
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 21:07
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 21:07
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 21:07
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 21:07
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 21:07
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
07/05/22 21:07
460-00-4
1,2-Dichloroethane-d4 (S)
106
%
70-130
1
07/05/22 21:07
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/05/22 21:07
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 66 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-34 Lab ID: 92612809024 Collected: 06/30/22 10:00 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:04
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:04
7440-38-2
Barium
18.2
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:04
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:04
7440-41-7
Cadmium
0.28J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:04
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:04
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:04
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:04
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:04
7439-92-1
Nickel
1.5.1
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:04
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:04
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:04
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:04
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:04
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:04
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/05/22 21:25
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 21:25
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/05/22 21:25
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 21:25
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 21:25
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 21:25
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 21:25
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 21:25
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 21:25
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 21:25
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 21:25
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 21:25
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 21:25
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 21:25
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 21:25
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 21:25
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 21:25
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 21:25
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 21:25
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 21:25
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 21:25
110-57-6
1,1-Dichloroethane
0.40J
ug/L
1.0
0.37
1
07/05/22 21:25
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 21:25
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 21:25
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 21:25
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 21:25
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 21:25
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-34
Parameters
Lab ID:
Results
92612809024
Units
Collected:
Report
Limit
06/30/22 10:00
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 21:25
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 21:25
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 21:25
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 21:25
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 21:25
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 21:25
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 21:25
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 21:25
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 21:25
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 21:25
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 21:25
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 21:25
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 21:25
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 21:25
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 21:25
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 21:25
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 21:25
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 21:25
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 21:25
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 21:25
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 21:25
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/05/22 21:25
460-00-4
1,2-Dichloroethane-d4 (S)
105
%
70-130
1
07/05/22 21:25
17060-07-0
Toluene-d8 (S)
103
%
70-130
1
07/05/22 21:25
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 68 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-3 Lab ID: 92612809025 Collected: 06/30/22 10:30 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:10
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:10
7440-38-2
Barium
43.9
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:10
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:10
7440-41-7
Cadmium
0.25J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:10
7440-43-9
Chromium
1.1J
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:10
7440-47-3
Cobalt
6.7
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:10
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:10
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:10
7439-92-1
Nickel
2.6J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:10
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:10
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:10
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:10
7440-28-0
Vanadium
2.9J
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:10
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:10
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/02/22 07:43
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/02/22 07:43
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/02/22 07:43
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/02/22 07:43
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/02/22 07:43
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/02/22 07:43
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/02/22 07:43
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/02/22 07:43
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/02/22 07:43
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/02/22 07:43
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/02/22 07:43
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/02/22 07:43
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/02/22 07:43
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/02/22 07:43
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/02/22 07:43
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/02/22 07:43
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/02/22 07:43
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/02/22 07:43
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/02/22 07:43
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/02/22 07:43
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/02/22 07:43
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/02/22 07:43
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 07:43
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/02/22 07:43
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 07:43
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/02/22 07:43
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/02/22 07:43
78-87-5
REPORT OF LABORATORY ANALYSIS
IK,L1
L1
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-3
Parameters
Lab ID:
Results
92612809025
Units
Collected:
Report
Limit
06/30/22 10:30
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 07:43
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 07:43
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/02/22 07:43
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/02/22 07:43
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/02/22 07:43
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/02/22 07:43
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/02/22 07:43
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/02/22 07:43
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/02/22 07:43
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/02/22 07:43
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/02/22 07:43
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/02/22 07:43
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/02/22 07:43
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/02/22 07:43
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 07:43
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 07:43
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/02/22 07:43
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/02/22 07:43
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/02/22 07:43
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/02/22 07:43
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/02/22 07:43
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
07/02/22 07:43
460-00-4
1,2-Dichloroethane-d4 (S)
109
%
70-130
1
07/02/22 07:43
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
07/02/22 07:43
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 70 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-4R Lab ID: 92612809026 Collected: 06/29/22 12:25 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:16
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:16
7440-38-2
Barium
28.7
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:16
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:16
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:16
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:16
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:16
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:16
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:16
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:16
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:16
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:16
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:16
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:16
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:16
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/02/22 08:01
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/02/22 08:01
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/02/22 08:01
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/02/22 08:01
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/02/22 08:01
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/02/22 08:01
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/02/22 08:01
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/02/22 08:01
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/02/22 08:01
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/02/22 08:01
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/02/22 08:01
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/02/22 08:01
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/02/22 08:01
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/02/22 08:01
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/02/22 08:01
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/02/22 08:01
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/02/22 08:01
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/02/22 08:01
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/02/22 08:01
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/02/22 08:01
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/02/22 08:01
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/02/22 08:01
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:01
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/02/22 08:01
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:01
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/02/22 08:01
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/02/22 08:01
78-87-5
REPORT OF LABORATORY ANALYSIS
IK,L1
L1
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-4R
Parameters
Lab ID:
Results
92612809026
Units
Collected:
Report
Limit
06/29/22 12:25
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:01
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:01
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/02/22 08:01
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/02/22 08:01
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/02/22 08:01
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/02/22 08:01
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/02/22 08:01
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/02/22 08:01
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/02/22 08:01
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/02/22 08:01
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/02/22 08:01
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/02/22 08:01
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/02/22 08:01
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/02/22 08:01
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:01
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:01
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/02/22 08:01
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/02/22 08:01
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/02/22 08:01
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/02/22 08:01
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/02/22 08:01
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
07/02/22 08:01
460-00-4
1,2-Dichloroethane-d4 (S)
112
%
70-130
1
07/02/22 08:01
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/02/22 08:01
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 72 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-5 Lab ID: 92612809027 Collected: 06/30/22 10:33 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:22
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:22
7440-38-2
Barium
38.1
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:22
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:22
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:22
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:22
7440-47-3
Cobalt
33.6
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:22
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:22
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:22
7439-92-1
Nickel
2.6J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:22
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:22
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:22
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:22
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:22
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:22
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/02/22 08:20
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/02/22 08:20
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/02/22 08:20
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/02/22 08:20
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/02/22 08:20
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/02/22 08:20
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/02/22 08:20
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/02/22 08:20
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/02/22 08:20
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/02/22 08:20
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/02/22 08:20
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/02/22 08:20
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/02/22 08:20
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/02/22 08:20
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/02/22 08:20
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/02/22 08:20
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/02/22 08:20
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/02/22 08:20
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/02/22 08:20
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/02/22 08:20
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/02/22 08:20
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/02/22 08:20
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:20
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/02/22 08:20
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:20
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/02/22 08:20
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/02/22 08:20
78-87-5
REPORT OF LABORATORY ANALYSIS
IK,L1
L1
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-5
Parameters
Lab ID:
Results
92612809027
Units
Collected:
Report
Limit
06/30/22 10:33
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:20
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:20
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/02/22 08:20
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/02/22 08:20
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/02/22 08:20
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/02/22 08:20
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/02/22 08:20
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/02/22 08:20
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/02/22 08:20
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/02/22 08:20
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/02/22 08:20
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/02/22 08:20
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/02/22 08:20
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/02/22 08:20
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:20
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:20
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/02/22 08:20
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/02/22 08:20
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/02/22 08:20
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/02/22 08:20
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/02/22 08:20
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/02/22 08:20
460-00-4
1,2-Dichloroethane-d4 (S)
111
%
70-130
1
07/02/22 08:20
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/02/22 08:20
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 74 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-6 Lab ID: 92612809028 Collected: 06/30/22 10:14 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:28
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:28
7440-38-2
Barium
22.1
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:28
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:28
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:28
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:28
7440-47-3
Cobalt
4.6J
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:28
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:28
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:28
7439-92-1
Nickel
1.0J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:28
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:28
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:28
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:28
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:28
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:28
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/02/22 08:38
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/02/22 08:38
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/02/22 08:38
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/02/22 08:38
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/02/22 08:38
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/02/22 08:38
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/02/22 08:38
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/02/22 08:38
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/02/22 08:38
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/02/22 08:38
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/02/22 08:38
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/02/22 08:38
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/02/22 08:38
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/02/22 08:38
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/02/22 08:38
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/02/22 08:38
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/02/22 08:38
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/02/22 08:38
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/02/22 08:38
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/02/22 08:38
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/02/22 08:38
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/02/22 08:38
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:38
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/02/22 08:38
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:38
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/02/22 08:38
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/02/22 08:38
78-87-5
REPORT OF LABORATORY ANALYSIS
IK,L1
L1
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: SW-6
Parameters
Lab ID:
Results
92612809028
Units
Collected:
Report
Limit
06/30/22 10:14
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:38
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 08:38
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/02/22 08:38
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/02/22 08:38
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/02/22 08:38
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/02/22 08:38
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/02/22 08:38
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/02/22 08:38
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/02/22 08:38
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/02/22 08:38
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/02/22 08:38
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/02/22 08:38
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/02/22 08:38
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/02/22 08:38
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 08:38
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 08:38
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/02/22 08:38
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/02/22 08:38
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/02/22 08:38
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/02/22 08:38
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/02/22 08:38
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
96
%
70-130
1
07/02/22 08:38
460-00-4
1,2-Dichloroethane-d4 (S)
108
%
70-130
1
07/02/22 08:38
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
07/02/22 08:38
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 76 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-1 Lab ID: 92612809029 Collected: 06/30/22 08:10 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
62.2
ug/L
10.0
3.4
1
07/06/22 20:40
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:34
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:34
7440-38-2
Barium
25.6
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:34
7440-39-3
Beryllium
0.12J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:34
7440-41-7
Cadmium
0.54
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:34
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:34
7440-47-3
Cobalt
6.2
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:34
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:34
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:34
7439-92-1
Nickel
3.6J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:34
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:34
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:34
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:34
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:34
7440-62-2
Zinc
28.6
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:34
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/07/22 04:49
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 04:49
107-13-1
Benzene
0.591
ug/L
1.0
0.34
1
07/07/22 04:49
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 04:49
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 04:49
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 04:49
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 04:49
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 04:49
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 04:49
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 04:49
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/07/22 04:49
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 04:49
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 04:49
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 04:49
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 04:49
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 04:49
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 04:49
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 04:49
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 04:49
95-50-1
1,4-Dichlorobenzene
1.6
ug/L
1.0
0.33
1
07/07/22 04:49
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 04:49
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 04:49
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 04:49
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 77 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-1 Lab ID: 92612809029 Collected: 06/30/22 08:10 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.35
1
07/07/22 04:49
75-35-4
ND
ug/L
1.0
0.38
1
07/07/22 04:49
156-59-2
ND
ug/L
1.0
0.40
1
07/07/22 04:49
156-60-5
ND
ug/L
1.0
0.36
1
07/07/22 04:49
78-87-5
ND
ug/L
1.0
0.36
1
07/07/22 04:49
10061-01-5
ND
ug/L
1.0
0.36
1
07/07/22 04:49
10061-02-6
ND
ug/L
150
38.7
1
07/07/22 04:49
123-91-1
ND
ug/L
1.0
0.30
1
07/07/22 04:49
100-41-4
ND
ug/L
5.0
0.48
1
07/07/22 04:49
591-78-6
ND
ug/L
20.0
9.7
1
07/07/22 04:49
74-88-4
ND
ug/L
5.0
2.0
1
07/07/22 04:49
75-09-2
ND
ug/L
5.0
2.7
1
07/07/22 04:49
108-10-1
ND
ug/L
1.0
0.29
1
07/07/22 04:49
100-42-5
ND
ug/L
1.0
0.31
1
07/07/22 04:49
630-20-6
ND
ug/L
1.0
0.22
1
07/07/22 04:49
79-34-5
ND
ug/L
1.0
0.29
1
07/07/22 04:49
127-18-4
ND
ug/L
1.0
0.48
1
07/07/22 04:49
108-88-3
ND
ug/L
1.0
0.33
1
07/07/22 04:49
71-55-6
ND
ug/L
1.0
0.32
1
07/07/22 04:49
79-00-5
ND
ug/L
1.0
0.38
1
07/07/22 04:49
79-01-6
ND
ug/L
1.0
0.30
1
07/07/22 04:49
75-69-4
ND
ug/L
1.0
0.26
1
07/07/22 04:49
96-18-4
ND
ug/L
2.0
1.3
1
07/07/22 04:49
108-05-4
ND
ug/L
1.0
0.39
1
07/07/22 04:49
75-01-4
ND
ug/L
1.0
0.34
1
07/07/22 04:49
1330-20-7
101
%
70-130
1
07/07/22 04:49
460-00-4
101
%
70-130
1
07/07/22 04:49
17060-07-0
99
%
70-130
1
07/07/22 04:49
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 78 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-1B Lab ID: 92612809030 Collected: 06/30/22 16:22 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND
ug/L
10.0
3.4
1
07/06/22 20:55
74-82-8
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3005A
Pace Analytical Services
- Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:40
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:40
7440-38-2
Barium
75.2
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:40
7440-39-3
Beryllium
0.27J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:40
7440-41-7
Cadmium
0.91
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:40
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:40
7440-47-3
Cobalt
52.0
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:40
7440-48-4
Copper
3.2J
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:40
7440-50-8
Lead
1.9
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:40
7439-92-1
Nickel
5.1
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:40
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:40
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:40
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:40
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:40
7440-62-2
Zinc
17.3
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:40
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/07/22 04:31
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 04:31
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/07/22 04:31
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 04:31
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 04:31
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 04:31
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 04:31
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 04:31
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 04:31
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 04:31
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/07/22 04:31
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 04:31
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 04:31
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 04:31
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 04:31
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 04:31
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 04:31
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 04:31
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 04:31
95-50-1
1,4-Dichlorobenzene
0.53J
ug/L
1.0
0.33
1
07/07/22 04:31
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 04:31
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 04:31
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 04:31
107-06-2
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 79 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-1B Lab ID: 92612809030 Collected: 06/30/22 16:22 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.35
1
07/07/22 04:31
75-35-4
ND
ug/L
1.0
0.38
1
07/07/22 04:31
156-59-2
ND
ug/L
1.0
0.40
1
07/07/22 04:31
156-60-5
ND
ug/L
1.0
0.36
1
07/07/22 04:31
78-87-5
ND
ug/L
1.0
0.36
1
07/07/22 04:31
10061-01-5
ND
ug/L
1.0
0.36
1
07/07/22 04:31
10061-02-6
ND
ug/L
150
38.7
1
07/07/22 04:31
123-91-1
ND
ug/L
1.0
0.30
1
07/07/22 04:31
100-41-4
ND
ug/L
5.0
0.48
1
07/07/22 04:31
591-78-6
ND
ug/L
20.0
9.7
1
07/07/22 04:31
74-88-4
ND
ug/L
5.0
2.0
1
07/07/22 04:31
75-09-2
ND
ug/L
5.0
2.7
1
07/07/22 04:31
108-10-1
ND
ug/L
1.0
0.29
1
07/07/22 04:31
100-42-5
ND
ug/L
1.0
0.31
1
07/07/22 04:31
630-20-6
ND
ug/L
1.0
0.22
1
07/07/22 04:31
79-34-5
ND
ug/L
1.0
0.29
1
07/07/22 04:31
127-18-4
ND
ug/L
1.0
0.48
1
07/07/22 04:31
108-88-3
ND
ug/L
1.0
0.33
1
07/07/22 04:31
71-55-6
ND
ug/L
1.0
0.32
1
07/07/22 04:31
79-00-5
ND
ug/L
1.0
0.38
1
07/07/22 04:31
79-01-6
ND
ug/L
1.0
0.30
1
07/07/22 04:31
75-69-4
ND
ug/L
1.0
0.26
1
07/07/22 04:31
96-18-4
ND
ug/L
2.0
1.3
1
07/07/22 04:31
108-05-4
ND
ug/L
1.0
0.39
1
07/07/22 04:31
75-01-4
ND
ug/L
1.0
0.34
1
07/07/22 04:31
1330-20-7
101
%
70-130
1
07/07/22 04:31
460-00-4
101
%
70-130
1
07/07/22 04:31
17060-07-0
100
%
70-130
1
07/07/22 04:31
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 80 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-2 Lab ID: 92612809031 Collected: 06/30/22 16:22 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 15:46
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 15:46
7440-38-2
Barium
74.0
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 15:46
7440-39-3
Beryllium
0.070J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 15:46
7440-41-7
Cadmium
0.45J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 15:46
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 15:46
7440-47-3
Cobalt
431
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 15:46
7440-48-4
Copper
1.5J
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 15:46
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 15:46
7439-92-1
Nickel
12.5
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 15:46
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 15:46
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 15:46
7440-22-4
Thallium
0.37J
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 15:46
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 15:46
7440-62-2
Zinc
28.9
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 15:46
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
27.8
ug/L
25.0
5.1
1
07/05/22 22:40
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/05/22 22:40
107-13-1
Benzene
1.1
ug/L
1.0
0.34
1
07/05/22 22:40
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/05/22 22:40
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/05/22 22:40
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/05/22 22:40
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/05/22 22:40
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/05/22 22:40
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/05/22 22:40
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/05/22 22:40
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/05/22 22:40
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/05/22 22:40
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/05/22 22:40
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/05/22 22:40
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/05/22 22:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/05/22 22:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/05/22 22:40
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/05/22 22:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/05/22 22:40
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/05/22 22:40
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/05/22 22:40
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/05/22 22:40
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 22:40
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/05/22 22:40
75-35-4
cis-1,2-Dichloroethene
2.7
ug/L
1.0
0.38
1
07/05/22 22:40
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/05/22 22:40
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/05/22 22:40
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-2
Parameters
Lab ID:
Results
92612809031
Units
Collected:
Report
Limit
06/30/22 16:22
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 22:40
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/05/22 22:40
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/05/22 22:40
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/05/22 22:40
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/05/22 22:40
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/05/22 22:40
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/05/22 22:40
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/05/22 22:40
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/05/22 22:40
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/05/22 22:40
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/05/22 22:40
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/05/22 22:40
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/05/22 22:40
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/05/22 22:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/05/22 22:40
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/05/22 22:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/05/22 22:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/05/22 22:40
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/05/22 22:40
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/05/22 22:40
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/05/22 22:40
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
103
%
70-130
1
07/05/22 22:40
460-00-4
1,2-Dichloroethane-d4 (S)
107
%
70-130
1
07/05/22 22:40
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/05/22 22:40
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 82 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-4R Lab ID: 92612809032 Collected: 06/29/22 13:26 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 16:09
7440-36-0
Arsenic
2.2J
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 16:09
7440-38-2
Barium
161
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 16:09
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 16:09
7440-41-7
Cadmium
0.46J
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 16:09
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 16:09
7440-47-3
Cobalt
141
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 16:09
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 16:09
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 16:09
7439-92-1
Nickel
7.7
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 16:09
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 16:09
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 16:09
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 16:09
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 16:09
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 16:09
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/02/22 15:07
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/02/22 15:07
107-13-1
Benzene
0.60J
ug/L
1.0
0.34
1
07/02/22 15:07
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/02/22 15:07
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/02/22 15:07
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/02/22 15:07
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/02/22 15:07
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/02/22 15:07
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/02/22 15:07
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/02/22 15:07
56-23-5
Chlorobenzene
0.81J
ug/L
1.0
0.28
1
07/02/22 15:07
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/02/22 15:07
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/02/22 15:07
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/02/22 15:07
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/02/22 15:07
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/02/22 15:07
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/02/22 15:07
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/02/22 15:07
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/02/22 15:07
95-50-1
1,4-Dichlorobenzene
1.8
ug/L
1.0
0.33
1
07/02/22 15:07
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/02/22 15:07
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/02/22 15:07
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 15:07
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/02/22 15:07
75-35-4
cis-1,2-Dichloroethene
4.7
ug/L
1.0
0.38
1
07/02/22 15:07
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/02/22 15:07
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/02/22 15:07
78-87-5
REPORT OF LABORATORY ANALYSIS
IK,L1
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-4R
Parameters
Lab ID:
Results
92612809032
Units
Collected:
Report
Limit
06/29/22 13:26
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 15:07
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/02/22 15:07
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/02/22 15:07
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/02/22 15:07
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/02/22 15:07
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/02/22 15:07
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/02/22 15:07
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/02/22 15:07
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/02/22 15:07
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/02/22 15:07
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/02/22 15:07
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/02/22 15:07
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/02/22 15:07
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/02/22 15:07
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/02/22 15:07
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/02/22 15:07
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/02/22 15:07
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/02/22 15:07
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/02/22 15:07
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/02/22 15:07
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/02/22 15:07
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
07/02/22 15:07
460-00-4
1,2-Dichloroethane-d4 (S)
110
%
70-130
1
07/02/22 15:07
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
07/02/22 15:07
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 84 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-10 Lab ID: 92612809033 Collected: 06/30/22 16:48 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 16:15
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 16:15
7440-38-2
Barium
18.3
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 16:15
7440-39-3
Beryllium
0.21J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 16:15
7440-41-7
Cadmium
0.51
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 16:15
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 16:15
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 16:15
7440-48-4
Copper
53.6
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 16:15
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 16:15
7439-92-1
Nickel
1.91
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 16:15
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 16:15
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 16:15
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 16:15
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 16:15
7440-62-2
Zinc
15.4
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 16:15
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/07/22 05:08
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 05:08
107-13-1
Benzene
0.71J
ug/L
1.0
0.34
1
07/07/22 05:08
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 05:08
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 05:08
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 05:08
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 05:08
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 05:08
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 05:08
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 05:08
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/07/22 05:08
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 05:08
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 05:08
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 05:08
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 05:08
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 05:08
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 05:08
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 05:08
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 05:08
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/07/22 05:08
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 05:08
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 05:08
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:08
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/07/22 05:08
75-35-4
cis-1,2-Dichloroethene
2.7
ug/L
1.0
0.38
1
07/07/22 05:08
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/07/22 05:08
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/07/22 05:08
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-10
Parameters
Lab ID:
Results
92612809033
Units
Collected:
Report
Limit
06/30/22 16:48
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:08
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:08
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/07/22 05:08
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/07/22 05:08
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/07/22 05:08
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/07/22 05:08
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/07/22 05:08
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/07/22 05:08
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/07/22 05:08
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/07/22 05:08
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/07/22 05:08
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/07/22 05:08
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/07/22 05:08
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/07/22 05:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:08
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 05:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/07/22 05:08
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/07/22 05:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/07/22 05:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/07/22 05:08
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/07/22 05:08
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/07/22 05:08
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
07/07/22 05:08
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
07/07/22 05:08
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 86 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-9 Lab ID: 92612809034 Collected: 06/30/22 16:55 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 16:21
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 16:21
7440-38-2
Barium
284
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 16:21
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 16:21
7440-41-7
Cadmium
3.2
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 16:21
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 16:21
7440-47-3
Cobalt
451
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 16:21
7440-48-4
Copper
1.1.1
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 16:21
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 16:21
7439-92-1
Nickel
48.5
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 16:21
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 16:21
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 16:21
7440-22-4
Thallium
0.32J
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 16:21
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 16:21
7440-62-2
Zinc
16.1
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 16:21
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/07/22 05:26
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 05:26
107-13-1
Benzene
1.2
ug/L
1.0
0.34
1
07/07/22 05:26
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 05:26
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 05:26
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 05:26
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 05:26
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 05:26
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 05:26
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 05:26
56-23-5
Chlorobenzene
1.8
ug/L
1.0
0.28
1
07/07/22 05:26
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 05:26
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 05:26
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 05:26
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 05:26
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 05:26
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 05:26
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 05:26
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 05:26
95-50-1
1,4-Dichlorobenzene
3.4
ug/L
1.0
0.33
1
07/07/22 05:26
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 05:26
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 05:26
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:26
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/07/22 05:26
75-35-4
cis-1,2-Dichloroethene
10.4
ug/L
1.0
0.38
1
07/07/22 05:26
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/07/22 05:26
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/07/22 05:26
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-9
Parameters
Lab ID:
Results
92612809034
Units
Collected:
Report
Limit
06/30/22 16:55
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:26
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:26
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/07/22 05:26
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/07/22 05:26
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/07/22 05:26
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/07/22 05:26
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/07/22 05:26
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/07/22 05:26
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/07/22 05:26
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/07/22 05:26
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/07/22 05:26
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/07/22 05:26
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/07/22 05:26
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/07/22 05:26
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:26
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 05:26
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/07/22 05:26
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/07/22 05:26
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/07/22 05:26
108-05-4
Vinyl chloride
0.70J
ug/L
1.0
0.39
1
07/07/22 05:26
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/07/22 05:26
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
07/07/22 05:26
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
07/07/22 05:26
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
07/07/22 05:26
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 88 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-1A Lab ID: 92612809035 Collected: 06/30/22 16:24 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 16:27
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 16:27
7440-38-2
Barium
44.3
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 16:27
7440-39-3
Beryllium
0.086J
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 16:27
7440-41-7
Cadmium
2.4
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 16:27
7440-43-9
Chromium
4.3J
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 16:27
7440-47-3
Cobalt
35.3
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 16:27
7440-48-4
Copper
21.1
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 16:27
7440-50-8
Lead
3.5
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 16:27
7439-92-1
Nickel
3.5J
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 16:27
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 16:27
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 16:27
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 16:27
7440-28-0
Vanadium
3.6.1
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 16:27
7440-62-2
Zinc
14.2
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 16:27
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
ND
ug/L
25.0
5.1
1
07/07/22 05:44
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 05:44
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/07/22 05:44
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 05:44
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 05:44
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 05:44
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 05:44
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 05:44
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 05:44
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 05:44
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/07/22 05:44
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 05:44
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 05:44
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 05:44
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 05:44
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 05:44
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 05:44
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 05:44
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 05:44
95-50-1
1,4-Dichlorobenzene
0.74J
ug/L
1.0
0.33
1
07/07/22 05:44
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 05:44
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 05:44
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:44
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/07/22 05:44
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 05:44
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/07/22 05:44
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/07/22 05:44
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MWAA
Parameters
Lab ID:
Results
92612809035
Units
Collected:
Report
Limit
06/30/22 16:24
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:44
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 05:44
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/07/22 05:44
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/07/22 05:44
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/07/22 05:44
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/07/22 05:44
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/07/22 05:44
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/07/22 05:44
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/07/22 05:44
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/07/22 05:44
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/07/22 05:44
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/07/22 05:44
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/07/22 05:44
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/07/22 05:44
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 05:44
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 05:44
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/07/22 05:44
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/07/22 05:44
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/07/22 05:44
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/07/22 05:44
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/07/22 05:44
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/07/22 05:44
460-00-4
1,2-Dichloroethane-d4 (S)
102
%
70-130
1
07/07/22 05:44
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
07/07/22 05:44
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 90 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: EB Lab ID: 92612809036 Collected: 06/30/22 17:00 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3005A
Pace Analytical Services - Peachtree Corners, GA
Antimony
ND
ug/L
3.0
0.78
1 07/07/22 08:30
07/08/22 16:39
7440-36-0
Arsenic
ND
ug/L
5.0
2.2
1 07/07/22 08:30
07/08/22 16:39
7440-38-2
Barium
ND
ug/L
5.0
0.67
1 07/07/22 08:30
07/08/22 16:39
7440-39-3
Beryllium
ND
ug/L
0.50
0.054
1 07/07/22 08:30
07/08/22 16:39
7440-41-7
Cadmium
ND
ug/L
0.50
0.11
1 07/07/22 08:30
07/08/22 16:39
7440-43-9
Chromium
ND
ug/L
5.0
1.1
1 07/07/22 08:30
07/08/22 16:39
7440-47-3
Cobalt
ND
ug/L
5.0
0.39
1 07/07/22 08:30
07/08/22 16:39
7440-48-4
Copper
ND
ug/L
5.0
1.0
1 07/07/22 08:30
07/08/22 16:39
7440-50-8
Lead
ND
ug/L
1.0
0.89
1 07/07/22 08:30
07/08/22 16:39
7439-92-1
Nickel
ND
ug/L
5.0
0.71
1 07/07/22 08:30
07/08/22 16:39
7440-02-0
Selenium
ND
ug/L
5.0
1.4
1 07/07/22 08:30
07/08/22 16:39
7782-49-2
Silver
ND
ug/L
5.0
0.44
1 07/07/22 08:30
07/08/22 16:39
7440-22-4
Thallium
ND
ug/L
1.0
0.18
1 07/07/22 08:30
07/08/22 16:39
7440-28-0
Vanadium
ND
ug/L
10.0
1.9
1 07/07/22 08:30
07/08/22 16:39
7440-62-2
Zinc
ND
ug/L
10.0
7.0
1 07/07/22 08:30
07/08/22 16:39
7440-66-6
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
Acetone
12.9J
ug/L
25.0
5.1
1
07/07/22 03:54
67-64-1
Acrylonitrile
ND
ug/L
10.0
1.8
1
07/07/22 03:54
107-13-1
Benzene
ND
ug/L
1.0
0.34
1
07/07/22 03:54
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.47
1
07/07/22 03:54
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.31
1
07/07/22 03:54
75-27-4
Bromoform
ND
ug/L
1.0
0.34
1
07/07/22 03:54
75-25-2
Bromomethane
ND
ug/L
2.0
1.7
1
07/07/22 03:54
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
4.0
1
07/07/22 03:54
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.36
1
07/07/22 03:54
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.33
1
07/07/22 03:54
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.28
1
07/07/22 03:54
108-90-7
Chloroethane
ND
ug/L
1.0
0.65
1
07/07/22 03:54
75-00-3
Chloroform
ND
ug/L
1.0
0.43
1
07/07/22 03:54
67-66-3
Chloromethane
ND
ug/L
1.0
0.54
1
07/07/22 03:54
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.34
1
07/07/22 03:54
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.36
1
07/07/22 03:54
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.27
1
07/07/22 03:54
106-93-4
Dibromomethane
ND
ug/L
1.0
0.39
1
07/07/22 03:54
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.34
1
07/07/22 03:54
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.33
1
07/07/22 03:54
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.56
1
07/07/22 03:54
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.37
1
07/07/22 03:54
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 03:54
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.35
1
07/07/22 03:54
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 03:54
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.40
1
07/07/22 03:54
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.36
1
07/07/22 03:54
78-87-5
REPORT OF LABORATORY ANALYSIS
CO
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: EB
Parameters
Lab ID:
Results
92612809036
Units
Collected:
Report
Limit
06/30/22 17:00
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 03:54
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.36
1
07/07/22 03:54
10061-02-6
1,4-Dioxane (p-Dioxane)
ND
ug/L
150
38.7
1
07/07/22 03:54
123-91-1
Ethylbenzene
ND
ug/L
1.0
0.30
1
07/07/22 03:54
100-41-4
2-Hexanone
ND
ug/L
5.0
0.48
1
07/07/22 03:54
591-78-6
lodomethane
ND
ug/L
20.0
9.7
1
07/07/22 03:54
74-88-4
Methylene Chloride
ND
ug/L
5.0
2.0
1
07/07/22 03:54
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
2.7
1
07/07/22 03:54
108-10-1
Styrene
ND
ug/L
1.0
0.29
1
07/07/22 03:54
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.31
1
07/07/22 03:54
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.22
1
07/07/22 03:54
79-34-5
Tetrachloroethene
ND
ug/L
1.0
0.29
1
07/07/22 03:54
127-18-4
Toluene
ND
ug/L
1.0
0.48
1
07/07/22 03:54
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
0.33
1
07/07/22 03:54
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
0.32
1
07/07/22 03:54
79-00-5
Trichloroethene
ND
ug/L
1.0
0.38
1
07/07/22 03:54
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.30
1
07/07/22 03:54
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.26
1
07/07/22 03:54
96-18-4
Vinyl acetate
ND
ug/L
2.0
1.3
1
07/07/22 03:54
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39
1
07/07/22 03:54
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34
1
07/07/22 03:54
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
07/07/22 03:54
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
07/07/22 03:54
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
07/07/22 03:54
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 92 of 154

lceAnalyircal
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ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: FB Lab ID: 92612809037 Collected: 06/30/22 17:03 Received: 07/01/22 11:00 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
1,4-Dioxane (p-Dioxane)
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Date: 07/19/2022 02:49 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
12.OJ
ug/L
25.0
5.1
1
07/07/22 04:13
67-64-1 CO
ND
ug/L
10.0
1.8
1
07/07/22 04:13
107-13-1
ND
ug/L
1.0
0.34
1
07/07/22 04:13
71-43-2
ND
ug/L
1.0
0.47
1
07/07/22 04:13
74-97-5
ND
ug/L
1.0
0.31
1
07/07/22 04:13
75-27-4
ND
ug/L
1.0
0.34
1
07/07/22 04:13
75-25-2
ND
ug/L
2.0
1.7
1
07/07/22 04:13
74-83-9
ND
ug/L
5.0
4.0
1
07/07/22 04:13
78-93-3
ND
ug/L
2.0
0.36
1
07/07/22 04:13
75-15-0
ND
ug/L
1.0
0.33
1
07/07/22 04:13
56-23-5
ND
ug/L
1.0
0.28
1
07/07/22 04:13
108-90-7
ND
ug/L
1.0
0.65
1
07/07/22 04:13
75-00-3
ND
ug/L
1.0
0.43
1
07/07/22 04:13
67-66-3
ND
ug/L
1.0
0.54
1
07/07/22 04:13
74-87-3
ND
ug/L
2.0
0.34
1
07/07/22 04:13
96-12-8
ND
ug/L
1.0
0.36
1
07/07/22 04:13
124-48-1
ND
ug/L
1.0
0.27
1
07/07/22 04:13
106-93-4
ND
ug/L
1.0
0.39
1
07/07/22 04:13
74-95-3
ND
ug/L
1.0
0.34
1
07/07/22 04:13
95-50-1
ND
ug/L
1.0
0.33
1
07/07/22 04:13
106-46-7
ND
ug/L
1.0
0.56
1
07/07/22 04:13
110-57-6
ND
ug/L
1.0
0.37
1
07/07/22 04:13
75-34-3
ND
ug/L
1.0
0.32
1
07/07/22 04:13
107-06-2
ND
ug/L
1.0
0.35
1
07/07/22 04:13
75-35-4
ND
ug/L
1.0
0.38
1
07/07/22 04:13
156-59-2
ND
ug/L
1.0
0.40
1
07/07/22 04:13
156-60-5
ND
ug/L
1.0
0.36
1
07/07/22 04:13
78-87-5
ND
ug/L
1.0
0.36
1
07/07/22 04:13
10061-01-5
ND
ug/L
1.0
0.36
1
07/07/22 04:13
10061-02-6
ND
ug/L
150
38.7
1
07/07/22 04:13
123-91-1
ND
ug/L
1.0
0.30
1
07/07/22 04:13
100-41-4
ND
ug/L
5.0
0.48
1
07/07/22 04:13
591-78-6
ND
ug/L
20.0
9.7
1
07/07/22 04:13
74-88-4
ND
ug/L
5.0
2.0
1
07/07/22 04:13
75-09-2
ND
ug/L
5.0
2.7
1
07/07/22 04:13
108-10-1
ND
ug/L
1.0
0.29
1
07/07/22 04:13
100-42-5
ND
ug/L
1.0
0.31
1
07/07/22 04:13
630-20-6
ND
ug/L
1.0
0.22
1
07/07/22 04:13
79-34-5
ND
ug/L
1.0
0.29
1
07/07/22 04:13
127-18-4
ND
ug/L
1.0
0.48
1
07/07/22 04:13
108-88-3
ND
ug/L
1.0
0.33
1
07/07/22 04:13
71-55-6
ND
ug/L
1.0
0.32
1
07/07/22 04:13
79-00-5
ND
ug/L
1.0
0.38
1
07/07/22 04:13
79-01-6
ND
ug/L
1.0
0.30
1
07/07/22 04:13
75-69-4
ND
ug/L
1.0
0.26
1
07/07/22 04:13
96-18-4
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 93 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: FB
Parameters
Lab ID:
Results
92612809037
Units
Collected:
Report
Limit
06/30/22 17:03
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Pace Analytical
Services
- Charlotte
Vinyl acetate
ND
ug/L
2.0
1.3 1
07/07/22 04:13
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.39 1
07/07/22 04:13
75-01-4
Xylene (Total)
ND
ug/L
1.0
0.34 1
07/07/22 04:13
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
07/07/22 04:13
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
07/07/22 04:13
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
07/07/22 04:13
2037-26-5
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 94 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-11
Parameters
Lab ID: 92612809038 Collected:
Report
Results Units Limit
06/30/22 17:05
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen
21 nM 1.9
0.49
1
07/14/2213:45
1333-74-0
Indicator Gases Water LHC
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Methane
4100 ug/L 5.0
2.0
1
07/14/2218:59
74-82-8
Ethane
0.181 ug/L 1.0
0.17
1
07/14/2218:59
74-84-0
Ethene
ND ug/L 1.0
0.24
1
07/14/2218:59
74-85-1
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 95 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-16
Parameters
Lab ID: 92612809039 Collected:
Report
Results Units Limit
06/30/22 16:51
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen
2.1 nM 1.9
0.49
1
07/14/2213:57
1333-74-0
Indicator Gases Water LHC
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Methane
490 ug/L 5.0
2.0
1
07/14/2219:10
74-82-8
Ethane
ND ug/L 1.0
0.17
1
07/14/2219:10
74-84-0
Ethene
ND ug/L 1.0
0.24
1
07/14/2219:10
74-85-1
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 96 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-25
Parameters
Lab ID: 92612809040 Collected:
Report
Results Units Limit
06/30/22 17:15
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen
11 nM 1.9
0.49
1
07/14/2214:09
1333-74-0
Indicator Gases Water LHC
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Methane
790 ug/L 5.0
2.0
1
07/14/2219:21
74-82-8
Ethane
0.23J ug/L 1.0
0.17
1
07/14/2219:21
74-84-0
Ethene
ND ug/L 1.0
0.24
1
07/14/2219:21
74-85-1
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 97 of 154

lceAnalyircal
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-27
Parameters
Lab ID: 92612809041 Collected:
Report
Results Units Limit
06/30/22 11:13
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
Indicator Gases Bubblestrip H2
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Hydrogen
2.9 nM 1.9
0.49
1
07/14/2214:21
1333-74-0
Indicator Gases Water LHC
Analytical Method: AM20GAX
Pace Analytical Gulf Coast
Methane
5.4 ug/L 5.0
2.0
1
07/14/2219:33
74-82-8
Ethane
ND ug/L 1.0
0.17
1
07/14/2219:33
74-84-0
Ethene
ND ug/L 1.0
0.24
1
07/14/2219:33
74-85-1
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 98 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Alexander Landfill
Pace Project No.: 92612809
Sample: MW-12D
Parameters
Lab ID:
Results
92612809042 Collected:
Report
Units Limit
06/30/22 15:30
MDL DF
Received: 07/01/22 11:00 Matrix: Water
Prepared Analyzed CAS No. Qual
Low Level Volatile Fatty Acids
Analytical
Method: AM23G
Pace Analytical
Gulf Coast
Lactic Acid
2.5J
mg/L
5.0
0.53
10
07/13/22 18:42
50-21-5
Acetic Acid
2.OJ
mg/L
5.0
1.2
10
07/13/22 18:42
64-19-7
Propionic Acid
ND
mg/L
5.0
0.53
10
07/13/22 18:42
79-09-4
Formic acid
51
mg/L
5.0
0.55
10
07/13/22 18:42
64-18-6
Butyric Acid
ND
mg/L
5.0
0.58
10
07/13/22 18:42
107-92-6
Pyruvic Acid
ND
mg/L
5.0
0.60
10
07/13/22 18:42
127-17-3
i-Pentanoic Acid
ND
mg/L
5.0
0.61
10
07/13/22 18:42
503-74-2
Pentanoic Acid
ND
mg/L
5.0
0.56
10
07/13/22 18:42
109-52-4
i-Hexanoic Acid
ND
mg/L
5.0
0.56
10
07/13/22 18:42
646-07-1
Hexanoic Acid
ND
mg/L
5.0
0.58
10
07/13/22 18:42
142-62-1
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 99 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 745382 Analysis Method: AM20GAX
QC Batch Method: AM20GAX Analysis Description: Indicator Gases Bubble Strip H2
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92612809038, 92612809039, 92612809040, 92612809041
METHOD BLANK: 2370942 Matrix: Air
Associated Lab Samples: 92612809038, 92612809039, 92612809040, 92612809041
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Hydrogen nM ND 1.9 0.49 07/14/2213:33
LABORATORY CONTROL SAMPLE & LCSD: 2370943 2370944
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Hydrogen nM 12 13 12 109 105 70-130 4 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 100 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 745352 Analysis Method: AM20GAX
QC Batch Method: AM20GAX Analysis Description: Indicator Gases Water LHC
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92612809038, 92612809039, 92612809040, 92612809041
METHOD BLANK: 2370684
Matrix: Water
Associated Lab Samples:
92612809038, 92612809039, 92612809040, 92612809041
Blank Reporting
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Methane
ug/L
ND 5.0
2.0 07/14/2217:51
Ethane
ug/L
0.35J 1.0
0.17 07/14/2217:51 BO
Ethene
ug/L
0.30J 1.0
0.24 07/14/2217:51 BO
LABORATORY CONTROL SAMPLE & LCSD:
2370685
2370686
Spike
LCS
LCSD
LCS LCSD
% Rec Max
Parameter
Units
Conc.
Result
Result
% Rec % Rec
Limits RPD RPD Qualifiers
Methane
ug/L
380
400
400
104 105
70-130 0 20
Ethane
ug/L
97
100
100
106 106
70-130 0 20
Ethene
ug/L
120
130
130
107 108
70-130 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 101 of 154

lV11.1 Analytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708386 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006
METHOD BLANK: 3694607
Matrix:
Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Methane
ug/L
ND
10.0
3.4 07/01/2215:19
LABORATORY CONTROL SAMPLE:
3694608
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Methane
ug/L
396
430 109
70-130
MATRIX SPIKE SAMPLE: 3695651
92612196005 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Methane ug/L ND 396 432 109 70-130 H1,HS
SAMPLE DUPLICATE: 3695650
92612196008 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L ND 1110 20 H1,HS
SAMPLE DUPLICATE: 3695652
92612809001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L ND ND 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708974 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809007, 92612809029, 92612809030
METHOD BLANK: 3697295
Matrix: Water
Associated Lab Samples: 92612809007, 92612809029, 92612809030
Blank Reporting
Parameter
Units
Result Limit
Methane
ug/L
ND 10.0
LABORATORY CONTROL SAMPLE:
3697296
Spike LCS
Parameter
Units
Conc. Result
Methane
ug/L
396 481
MATRIX SPIKE SAMPLE:
3698424
92613026002 Spike
Parameter
Units
Result Conc.
Methane
ug/L
ND 396
SAMPLE DUPLICATE: 3698423
92613026001 Dup
Parameter Units Result Result
Methane ug/L ND ND
MDL Analyzed Qualifiers
3.4 07/06/2219:08
LCS % Rec
% Rec Limits Qualifiers
122 70-130
MS MS % Rec
Result % Rec Limits Qualifiers
482 122 70-130
Max
RPD RPD Qualifiers
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708819 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005
METHOD BLANK: 3696535 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
Antimony
ug/L
ND
3.0
0.78
07/08/2217:27
Arsenic
ug/L
2AJ
5.0
2.2
07/08/2217:27
Barium
ug/L
ND
5.0
0.67
07/08/2217:27
Beryllium
ug/L
ND
0.50
0.054
07/08/2217:27
Cadmium
ug/L
ND
0.50
0.11
07/08/2217:27
Chromium
ug/L
ND
5.0
1.1
07/08/2217:27
Cobalt
ug/L
ND
5.0
0.39
07/08/2217:27
Copper
ug/L
ND
5.0
1.0
07/08/2217:27
Lead
ug/L
ND
1.0
0.89
07/08/2217:27
Nickel
ug/L
ND
5.0
0.71
07/08/2217:27
Selenium
ug/L
ND
5.0
1.4
07/08/2217:27
Silver
ug/L
ND
5.0
0.44
07/08/2217:27
Thallium
ug/L
ND
1.0
0.18
07/08/2217:27
Vanadium
ug/L
ND
10.0
1.9
07/08/2217:27
Zinc
ug/L
ND
10.0
7.0
07/08/2217:27
LABORATORY CONTROL SAMPLE:
Parameter
3696536
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
100
108
108
80-120
Arsenic
ug/L
100
100
100
80-120
Barium
ug/L
100
101
101
80-120
Beryllium
ug/L
100
103
103
80-120
Cadmium
ug/L
100
99.4
99
80-120
Chromium
ug/L
100
99.0
99
80-120
Cobalt
ug/L
100
96.6
97
80-120
Copper
ug/L
100
96.5
96
80-120
Lead
ug/L
100
104
104
80-120
Nickel
ug/L
100
98.3
98
80-120
Selenium
ug/L
100
96.4
96
80-120
Silver
ug/L
100
101
101
80-120
Thallium
ug/L
100
108
108
80-120
Vanadium
ug/L
100
99.6
100
80-120
Zinc
ug/L
100
102
102
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Alexander Landfill
92612809
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3696594
3696595
MS
MSD
92612593001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
110
114
110
114
75-125
3
20
Arsenic
ug/L
ND
100
100
102
105
100
103
75-125
3
20
Barium
ug/L
ND
100
100
117
120
104
107
75-125
2
20
Beryllium
ug/L
ND
100
100
107
111
107
111
75-125
3
20
Cadmium
ug/L
ND
100
100
103
104
103
104
75-125
1
20
Chromium
ug/L
ND
100
100
107
108
107
108
75-125
1
20
Cobalt
ug/L
ND
100
100
103
104
102
104
75-125
1
20
Copper
ug/L
ND
100
100
104
105
102
103
75-125
1
20
Lead
ug/L
ND
100
100
106
109
106
109
75-125
3
20
Nickel
ug/L
ND
100
100
103
104
103
104
75-125
1
20
Selenium
ug/L
ND
100
100
100
102
100
102
75-125
2
20
Silver
ug/L
ND
100
100
104
107
104
106
75-125
3
20
Thallium
ug/L
ND
100
100
110
113
110
113
75-125
3
20
Vanadium
ug/L
ND
100
100
110
111
109
110
75-125
1
20
Zinc
ug/L
ND
100
100
110
110
107
106
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 105 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708890 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92612809006,92612809007,92612809008,92612809009,92612809010,92612809011,92612809012,
92612809013,92612809014,92612809015,92612809016,92612809017
METHOD BLANK: 3696834 Matrix: Water
Associated Lab Samples: 92612809006,92612809007,92612809008,92612809009,92612809010,92612809011,92612809012,
92612809013,92612809014,92612809015,92612809016,92612809017
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
3.0
0.78
07/07/2216:30
Arsenic
ug/L
ND
5.0
2.2
07/07/2216:30
Barium
ug/L
ND
5.0
0.67
07/07/2216:30
Beryllium
ug/L
ND
0.50
0.054
07/07/2216:30
Cadmium
ug/L
ND
0.50
0.11
07/07/2216:30
Chromium
ug/L
ND
5.0
1.1
07/07/2216:30
Cobalt
ug/L
ND
5.0
0.39
07/07/2216:30
Copper
ug/L
ND
5.0
1.0
07/07/2216:30
Lead
ug/L
ND
1.0
0.89
07/07/2216:30
Nickel
ug/L
ND
5.0
0.71
07/07/2216:30
Selenium
ug/L
ND
5.0
1.4
07/07/2216:30
Silver
ug/L
ND
5.0
0.44
07/07/2216:30
Thallium
ug/L
ND
1.0
0.18
07/07/2216:30
Vanadium
ug/L
ND
10.0
1.9
07/07/2216:30
Zinc
ug/L
ND
10.0
7.0
07/07/2216:30
LABORATORY CONTROL SAMPLE:
Parameter
3696835
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
100
107
107
80-120
Arsenic
ug/L
100
98.4
98
80-120
Barium
ug/L
100
102
102
80-120
Beryllium
ug/L
100
94.9
95
80-120
Cadmium
ug/L
100
98.9
99
80-120
Chromium
ug/L
100
101
101
80-120
Cobalt
ug/L
100
98.2
98
80-120
Copper
ug/L
100
99.1
99
80-120
Lead
ug/L
100
98.3
98
80-120
Nickel
ug/L
100
99.0
99
80-120
Selenium
ug/L
100
98.5
99
80-120
Silver
ug/L
100
99.5
100
80-120
Thallium
ug/L
100
101
101
80-120
Vanadium
ug/L
100
100
100
80-120
Zinc
ug/L
100
99.6
100
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Alexander Landfill
92612809
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3697000
3697001
MS
MSD
92613008002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
112
106
111
106
75-125
5
20
Arsenic
ug/L
ND
100
100
101
101
101
101
75-125
0
20
Barium
ug/L
31.9
100
100
143
140
111
108
75-125
2
20
Beryllium
ug/L
ND
100
100
98.3
98.4
98
98
75-125
0
20
Cadmium
ug/L
ND
100
100
102
102
102
102
75-125
0
20
Chromium
ug/L
2.5J
100
100
108
103
105
101
75-125
4
20
Cobalt
ug/L
1.8J
100
100
104
102
103
100
75-125
2
20
Copper
ug/L
10.3
100
100
114
114
103
104
75-125
1
20
Lead
ug/L
ND
100
100
102
98.8
102
98
75-125
3
20
Nickel
ug/L
1 AJ
100
100
103
102
102
101
75-125
1
20
Selenium
ug/L
ND
100
100
99.7
98.4
99
98
75-125
1
20
Silver
ug/L
ND
100
100
104
99.6
104
100
75-125
5
20
Thallium
ug/L
ND
100
100
104
99.7
104
100
75-125
4
20
Vanadium
ug/L
13.0
100
100
118
116
105
103
75-125
2
20
Zinc
ug/L
8.8J
100
100
111
111
102
102
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 107 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 709042 Analysis Method: EPA 6020B
QC Batch Method: EPA 3005A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Peachtree Corners, GA
Associated Lab Samples: 92612809018,92612809019,92612809020,92612809021,92612809022,92612809023,92612809024,
92612809025, 92612809026, 92612809027, 92612809028, 92612809029, 92612809030, 92612809031,
92612809032,92612809033,92612809034,92612809035,92612809036
METHOD BLANK: 3697526 Matrix: Water
Associated Lab Samples: 92612809018,92612809019,92612809020,92612809021,92612809022,92612809023,92612809024,
92612809025, 92612809026, 92612809027, 92612809028, 92612809029, 92612809030, 92612809031,
92612809032,92612809033,92612809034,92612809035,92612809036
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
3.0
0.78
07/08/2213:41
Arsenic
ug/L
ND
5.0
2.2
07/08/2213:41
Barium
ug/L
ND
5.0
0.67
07/08/2213:41
Beryllium
ug/L
ND
0.50
0.054
07/08/2213:41
Cadmium
ug/L
ND
0.50
0.11
07/08/2213:41
Chromium
ug/L
ND
5.0
1.1
07/08/2213:41
Cobalt
ug/L
ND
5.0
0.39
07/08/2213:41
Copper
ug/L
ND
5.0
1.0
07/08/2213:41
Lead
ug/L
ND
1.0
0.89
07/08/2213:41
Nickel
ug/L
ND
5.0
0.71
07/08/2213:41
Selenium
ug/L
ND
5.0
1.4
07/08/2213:41
Silver
ug/L
ND
5.0
0.44
07/08/2213:41
Thallium
ug/L
ND
1.0
0.18
07/08/2213:41
Vanadium
ug/L
ND
10.0
1.9
07/08/2213:41
Zinc
ug/L
ND
10.0
7.0
07/08/2213:41
LABORATORY CONTROL SAMPLE:
Parameter
3697527
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
100
109
109
80-120
Arsenic
ug/L
100
101
101
80-120
Barium
ug/L
100
95.8
96
80-120
Beryllium
ug/L
100
107
107
80-120
Cadmium
ug/L
100
101
101
80-120
Chromium
ug/L
100
105
105
80-120
Cobalt
ug/L
100
102
102
80-120
Copper
ug/L
100
98.9
99
80-120
Lead
ug/L
100
98.0
98
80-120
Nickel
ug/L
100
101
101
80-120
Selenium
ug/L
100
95.7
96
80-120
Silver
ug/L
100
102
102
80-120
Thallium
ug/L
100
97.9
98
80-120
Vanadium
ug/L
100
105
105
80-120
Zinc
ug/L
100
99.2
99
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Alexander Landfill
92612809
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3697528
3697529
MS
MSD
92612077001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
100
100
115
114
114
113
75-125
1
20
Arsenic
ug/L
11.2
100
100
116
115
103
102
75-125
0
20
Barium
ug/L
79.4
100
100
204
203
125
123
75-125
1
20
Beryllium
ug/L
ND
100
100
108
112
108
112
75-125
4
20
Cadmium
ug/L
ND
100
100
99.7
101
100
100
75-125
1
20
Chromium
ug/L
ND
100
100
109
106
108
105
75-125
3
20
Cobalt
ug/L
6.6
100
100
115
110
108
103
75-125
5
20
Copper
ug/L
ND
100
100
104
99.5
103
98
75-125
5
20
Lead
ug/L
ND
100
100
101
97.0
100
96
75-125
4
20
Nickel
ug/L
6.1
100
100
112
108
106
102
75-125
4
20
Selenium
ug/L
ND
100
100
99.4
98.7
99
98
75-125
1
20
Silver
ug/L
ND
100
100
104
102
104
102
75-125
2
20
Thallium
ug/L
ND
100
100
101
97.9
101
97
75-125
3
20
Vanadium
ug/L
ND
100
100
117
110
113
106
75-125
6
20
Zinc
ug/L
707
100
100
819
805
112
98
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 109 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708452 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809025, 92612809026, 92612809027, 92612809028
METHOD BLANK: 3694992 Matrix: Water
Associated Lab Samples: 92612809025, 92612809026, 92612809027, 92612809028
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
07/02/22 05:52
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
07/02/22 05:52
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
07/02/22 05:52
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
07/02/22 05:52
1,1-Dichloroethane
ug/L
ND
1.0
0.37
07/02/22 05:52
1,1-Dichloroethene
ug/L
ND
1.0
0.35
07/02/22 05:52
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
07/02/22 05:52
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
07/02/22 05:52
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
07/02/22 05:52
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
07/02/22 05:52
1,2-Dichloroethane
ug/L
ND
1.0
0.32
07/02/22 05:52
1,2-Dichloropropane
ug/L
ND
1.0
0.36
07/02/22 05:52
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
07/02/22 05:52
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
07/02/22 05:52
2-Butanone (MEK)
ug/L
ND
5.0
4.0
07/02/22 05:52
2-Hexanone
ug/L
ND
5.0
0.48
07/02/22 05:52
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
07/02/22 05:52
Acetone
ug/L
ND
25.0
5.1
07/02/22 05:52
Acrylonitrile
ug/L
ND
10.0
1.8
07/02/22 05:52
Benzene
ug/L
ND
1.0
0.34
07/02/22 05:52
Bromochloromethane
ug/L
ND
1.0
0.47
07/02/22 05:52
Bromodichloromethane
ug/L
ND
1.0
0.31
07/02/22 05:52
Bromoform
ug/L
ND
1.0
0.34
07/02/22 05:52
Bromomethane
ug/L
ND
2.0
1.7
07/02/22 05:52
Carbon disulfide
ug/L
ND
2.0
0.36
07/02/22 05:52
Carbon tetrachloride
ug/L
ND
1.0
0.33
07/02/22 05:52
Chlorobenzene
ug/L
ND
1.0
0.28
07/02/22 05:52
Chloroethane
ug/L
ND
1.0
0.65
07/02/22 05:52
Chloroform
ug/L
ND
1.0
0.43
07/02/22 05:52
Chloromethane
ug/L
ND
1.0
0.54
07/02/22 05:52
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
07/02/22 05:52
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/02/22 05:52
Dibromochloromethane
ug/L
ND
1.0
0.36
07/02/22 05:52
Dibromomethane
ug/L
ND
1.0
0.39
07/02/22 05:52
Ethylbenzene
ug/L
ND
1.0
0.30
07/02/22 05:52
lodomethane
ug/L
ND
20.0
9.7
07/02/22 05:52
Methylene Chloride
ug/L
ND
5.0
2.0
07/02/22 05:52
Styrene
ug/L
ND
1.0
0.29
07/02/22 05:52
Tetrachloroethene
ug/L
ND
1.0
0.29
07/02/22 05:52
Toluene
ug/L
ND
1.0
0.48
07/02/22 05:52
IK
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
METHOD BLANK: 3694992 Matrix: Water
Associated Lab Samples: 92612809025, 92612809026, 92612809027, 92612809028
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
07/02/22 05:52
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/02/22 05:52
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
07/02/22 05:52
Trichloroethene
ug/L
ND
1.0
0.38
07/02/22 05:52
Trichlorofluoromethane
ug/L
ND
1.0
0.30
07/02/22 05:52
Vinyl acetate
ug/L
ND
2.0
1.3
07/02/22 05:52
Vinyl chloride
ug/L
ND
1.0
0.39
07/02/22 05:52
Xylene (Total)
ug/L
ND
1.0
0.34
07/02/22 05:52
1,2-Dichloroethane-d4 (S)
%
102
70-130
07/02/22 05:52
4-Bromofluorobenzene (S)
%
99
70-130
07/02/22 05:52
Toluene-d8 (S)
%
100
70-130
07/02/22 05:52
IAG1 Z•]:7\C•]:�YK•]i.rrz•]�y�ul»�cI:1rI�>rxi
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.8
110
70-130
1,1,1-Trichloroethane
ug/L
50
56.1
112
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
53.6
107
70-130
1,1,2-Trichloroethane
ug/L
50
50.7
101
70-130
1,1-Dichloroethane
ug/L
50
54.8
110
70-130
1,1-Dichloroethene
ug/L
50
57.5
115
70-132
1,2,3-Trichloropropane
ug/L
50
53.7
107
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
55.0
110
70-132
1,2-Dibromoethane (EDB)
ug/L
50
52.5
105
70-130
1,2-Dichlorobenzene
ug/L
50
52.3
105
70-130
1,2-Dichloroethane
ug/L
50
55.6
111
70-130
1,2-Dichloropropane
ug/L
50
55.4
111
70-130
1,4-Dichlorobenzene
ug/L
50
53.1
106
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
1260
126
70-137
2-Butanone (MEK)
ug/L
100
127
127
70-133
2-Hexanone
ug/L
100
127
127
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
116
116
70-130
Acetone
ug/L
100
122
122
70-144
Acrylonitrile
ug/L
250
302
121
70-130
Benzene
ug/L
50
52.4
105
70-130
Bromochloromethane
ug/L
50
55.1
110
70-130
Bromodichloromethane
ug/L
50
55.5
111
70-130
Bromoform
ug/L
50
67.2
134
70-131 IK,L1
Bromomethane
ug/L
50
63.2
126
30-177
Carbon disulfide
ug/L
50
57.6
115
70-133
Carbon tetrachloride
ug/L
50
55.2
110
70-130
Chlorobenzene
ug/L
50
53.6
107
70-130
Chloroethane
ug/L
50
67.9
136
46-131 L1
Chloroform
ug/L
50
53.6
107
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
LABORATORY CONTROL SAMPLE:
Parameter
3694993
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
50
58.3
117
49-130
cis-1,2-Dichloroethene
ug/L
50
57.5
115
70-130
cis-1,3-Dichloropropene
ug/L
50
57.9
116
70-130
Dibromochloromethane
ug/L
50
59.6
119
70-130
Dibromomethane
ug/L
50
51.5
103
70-130
Ethylbenzene
ug/L
50
54.0
108
70-130
lodomethane
ug/L
100
132
132
47-140
Methylene Chloride
ug/L
50
60.5
121
68-130
Styrene
ug/L
50
56.5
113
70-130
Tetrachloroethene
ug/L
50
47.7
95
70-130
Toluene
ug/L
50
50.8
102
70-130
trans-1,2-Dichloroethene
ug/L
50
59.0
118
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.6
109
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
58.5
117
25-200
Trichloroethene
ug/L
50
52.2
104
70-130
Trichlorofluoromethane
ug/L
50
58.9
118
61-130
Vinyl acetate
ug/L
100
131
131
70-140
Vinyl chloride
ug/L
50
58.5
117
59-142
Xylene (Total)
ug/L
150
165
110
70-130
1,2-Dichloroethane-d4 (S)
%
105
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3694994
MS
92612391028 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3694995
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
18.5
21.8
93
109
70-135
16
30
1,1,1-Trichloroethane
ug/L
ND
20
20
19.9
23.3
99
116
70-148
16
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
18.0
20.8
90
104
70-131
14
30
1,1,2-Trichloroethane
ug/L
ND
20
20
18.4
21.8
92
109
70-136
17
30
1,1-Dichloroethane
ug/L
ND
20
20
18.6
21.9
93
109
70-147
16
30
1,1-Dichloroethene
ug/L
ND
20
20
20.0
22.6
100
113
70-158
12
30
1,2,3-Trichloropropane
ug/L
ND
20
20
17.0
20.1
85
100
67-137
16
30
1,2-Dibromo-3-
ug/L
ND
20
20
18.3
21.5
92
107
69-136
16
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
17.5
20.8
88
104
70-137
17
30
1,2-Dichlorobenzene
ug/L
ND
20
20
18.2
21.2
91
106
70-133
15
30
1,2-Dichloroethane
ug/L
ND
20
20
18.5
21.8
92
109
67-138
16
30
1,2-Dichloropropane
ug/L
ND
20
20
18.8
22.2
94
111
70-138
17
30
1,4-Dichlorobenzene
ug/L
ND
20
20
18.0
20.6
90
103
70-133
13
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
382
447
95
112
69-146
16
30
2-Butanone (MEK)
ug/L
ND
40
40
37.9
44.6
95
111
61-147
16
30
2-Hexanone
ug/L
ND
40
40
40.1
47.0
100
117
67-139
16
30
4-Methyl-2-pentanone
ug/L
ND
40
40
37.3
44.7
93
112
67-136
18
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 112 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3694994
3694995
MS
MSD
92612391028
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
37.7
44.4
94
111
55-159
16
30
Acrylonitrile
ug/L
ND
100
100
93.1
110
93
110
68-140
17
30
Benzene
ug/L
ND
20
20
16.1
19.2
80
96
67-150
18
30
Bromochloromethane
ug/L
ND
20
20
18.6
22.2
93
111
70-146
18
30
Bromodichloromethane
ug/L
ND
20
20
18.4
21.9
92
110
70-138
18
30
Bromoform
ug/L
ND
20
20
18.6
21.8
93
109
57-138
16
30
Bromomethane
ug/L
ND
20
20
15.5
18.3
77
92
10-200
17
30 v3
Carbon disulfide
ug/L
ND
20
20
19.7
22.6
99
113
70-152
14
30
Carbon tetrachloride
ug/L
ND
20
20
19.7
22.7
99
114
70-147
14
30
Chlorobenzene
ug/L
ND
20
20
18.3
20.8
92
104
70-137
13
30
Chloroethane
ug/L
ND
20
20
20.0
23.1
100
116
51-166
14
30
Chloroform
ug/L
ND
20
20
19.0
22.2
95
111
70-144
16
30
Chloromethane
ug/L
ND
20
20
18.2
20.9
91
104
24-161
14
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
19.0
21.7
95
108
67-148
13
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
18.6
21.7
93
109
70-142
15
30
Dibromochloromethane
ug/L
ND
20
20
17.8
20.7
89
104
68-138
15
30
Dibromomethane
ug/L
ND
20
20
18.2
21.2
91
106
70-134
15
30
Ethylbenzene
ug/L
ND
20
20
18.3
20.7
91
103
68-143
13
30
lodomethane
ug/L
ND
40
40
20.1
28.2
50
70
20-161
34
30 R1,v3
Methylene Chloride
ug/L
ND
20
20
16.2
19.0
81
95
64-148
16
30
Styrene
ug/L
ND
20
20
18.1
20.9
91
105
70-136
14
30
Tetrachloroethene
ug/L
ND
20
20
18.3
21.2
91
106
70-139
15
30
Toluene
ug/L
ND
20
20
17.2
20.0
86
100
47-157
15
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
19.7
22.5
98
113
70-149
14
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
18.7
22.0
93
110
70-138
16
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
14.8
16.8
74
84
31-145
13
30
Trichloroethene
ug/L
ND
20
20
18.9
22.1
95
110
70-149
15
30
Trichlorofluoromethane
ug/L
ND
20
20
19.0
21.8
95
109
61-154
13
30
Vinyl acetate
ug/L
ND
40
40
38.1
45.8
95
115
48-156
18
30
Vinyl chloride
ug/L
ND
20
20
19.0
21.9
95
110
55-172
14
30
Xylene (Total)
ug/L
ND
60
60
54.5
62.0
91
103
66-145
13
30
1,2-Dichloroethane-d4 (S)
%
98
99
70-130
4-Bromofluorobenzene (S)
%
101
100
70-130
Toluene-d8 (S)
%
100
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 113 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708456 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809032
METHOD BLANK: 3695002
Associated Lab Samples: 92612809032
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
07/02/22 05:33
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
07/02/22 05:33
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
07/02/22 05:33
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
07/02/22 05:33
1,1-Dichloroethane
ug/L
ND
1.0
0.37
07/02/22 05:33
1,1-Dichloroethene
ug/L
ND
1.0
0.35
07/02/22 05:33
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
07/02/22 05:33
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
07/02/22 05:33
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
07/02/22 05:33
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
07/02/22 05:33
1,2-Dichloroethane
ug/L
ND
1.0
0.32
07/02/22 05:33
1,2-Dichloropropane
ug/L
ND
1.0
0.36
07/02/22 05:33
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
07/02/22 05:33
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
07/02/22 05:33
2-Butanone (MEK)
ug/L
ND
5.0
4.0
07/02/22 05:33
2-Hexanone
ug/L
ND
5.0
0.48
07/02/22 05:33
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
07/02/22 05:33
Acetone
ug/L
10.5J
25.0
5.1
07/02/22 05:33
Acrylonitrile
ug/L
ND
10.0
1.8
07/02/22 05:33
Benzene
ug/L
ND
1.0
0.34
07/02/22 05:33
Bromochloromethane
ug/L
ND
1.0
0.47
07/02/22 05:33
Bromodichloromethane
ug/L
ND
1.0
0.31
07/02/22 05:33
Bromoform
ug/L
ND
1.0
0.34
07/02/22 05:33
Bromomethane
ug/L
ND
2.0
1.7
07/02/22 05:33
Carbon disulfide
ug/L
ND
2.0
0.36
07/02/22 05:33
Carbon tetrachloride
ug/L
ND
1.0
0.33
07/02/22 05:33
Chlorobenzene
ug/L
ND
1.0
0.28
07/02/22 05:33
Chloroethane
ug/L
ND
1.0
0.65
07/02/22 05:33
Chloroform
ug/L
ND
1.0
0.43
07/02/22 05:33
Chloromethane
ug/L
ND
1.0
0.54
07/02/22 05:33
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
07/02/22 05:33
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/02/22 05:33
Dibromochloromethane
ug/L
ND
1.0
0.36
07/02/22 05:33
Dibromomethane
ug/L
ND
1.0
0.39
07/02/22 05:33
Ethylbenzene
ug/L
ND
1.0
0.30
07/02/22 05:33
lodomethane
ug/L
ND
20.0
9.7
07/02/22 05:33
Methylene Chloride
ug/L
ND
5.0
2.0
07/02/22 05:33
Styrene
ug/L
ND
1.0
0.29
07/02/22 05:33
Tetrachloroethene
ug/L
ND
1.0
0.29
07/02/22 05:33
Toluene
ug/L
ND
1.0
0.48
07/02/22 05:33
IK
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 114 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Alexander Landfill
Pace Project No.: 92612809
METHOD BLANK: 3695002
Associated Lab Samples: 92612809032
Parameter
Units
trans-1,2-Dichloroethene
ug/L
trans- 1,3-Dichloropropene
ug/L
trans-1,4-Dichloro-2-butene
ug/L
Trichloroethene
ug/L
Trichlorofluoromethane
ug/L
Vinyl acetate
ug/L
Vinyl chloride
ug/L
Xylene (Total)
ug/L
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
IAG1 Z•]:7\C•]:�YK•]i.rrz•]�y�ul»�d:1r�.'SeIexi
Parameter
QUALITY CONTROL DATA
Matrix: Water
Blank
Result
Reporting
Limit
ND
1.0
ND
1.0
ND
1.0
ND
1.0
ND
1.0
ND
2.0
ND
1.0
ND
1.0
105
70-130
101
70-130
98
70-130
Spike LCS
Units Conc. Result
MDL Analyzed
0.40
07/02/22 05:33
0.36
07/02/22 05:33
0.56
07/02/22 05:33
0.38
07/02/22 05:33
0.30
07/02/22 05:33
1.3
07/02/22 05:33
0.39
07/02/22 05:33
0.34
07/02/22 05:33
07/02/22 05:33
07/02/22 05:33
07/02/22 05:33
Qualifiers
LCS % Rec
% Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.8
110
70-130
1,1,1-Trichloroethane
ug/L
50
54.9
110
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
54.8
110
70-130
1,1,2-Trichloroethane
ug/L
50
51.1
102
70-130
1,1-Dichloroethane
ug/L
50
54.9
110
70-130
1,1-Dichloroethene
ug/L
50
55.5
111
70-132
1,2,3-Trichloropropane
ug/L
50
53.8
108
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
55.5
111
70-132
1,2-Dibromoethane (EDB)
ug/L
50
54.4
109
70-130
1,2-Dichlorobenzene
ug/L
50
52.3
105
70-130
1,2-Dichloroethane
ug/L
50
53.6
107
70-130
1,2-Dichloropropane
ug/L
50
55.3
111
70-130
1,4-Dichlorobenzene
ug/L
50
53.0
106
70-130
1,4-Dioxane (p-Dioxane)
ug/L
1000
1300
130
70-137
2-Butanone (MEK)
ug/L
100
122
122
70-133
2-Hexanone
ug/L
100
129
129
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
115
115
70-130
Acetone
ug/L
100
118
118
70-144
Acrylonitrile
ug/L
250
298
119
70-130
Benzene
ug/L
50
52.2
104
70-130
Bromochloromethane
ug/L
50
53.6
107
70-130
Bromodichloromethane
ug/L
50
55.9
112
70-130
Bromoform
ug/L
50
70.8
142
70-131 IK,L1
Bromomethane
ug/L
50
62.8
126
30-177
Carbon disulfide
ug/L
50
56.9
114
70-133
Carbon tetrachloride
ug/L
50
54.7
109
70-130
Chlorobenzene
ug/L
50
54.3
109
70-130
Chloroethane
ug/L
50
65.5
131
46-131
Chloroform
ug/L
50
54.5
109
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 115 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
LABORATORY CONTROL SAMPLE:
Parameter
3695003
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
50
59.4
119
49-130
cis-1,2-Dichloroethene
ug/L
50
54.9
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.8
118
70-130
Dibromochloromethane
ug/L
50
61.2
122
70-130
Dibromomethane
ug/L
50
52.2
104
70-130
Ethylbenzene
ug/L
50
54.7
109
70-130
lodomethane
ug/L
100
125
125
47-140
Methylene Chloride
ug/L
50
59.9
120
68-130
Styrene
ug/L
50
57.0
114
70-130
Tetrachloroethene
ug/L
50
48.7
97
70-130
Toluene
ug/L
50
50.0
100
70-130
trans-1,2-Dichloroethene
ug/L
50
57.3
115
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.9
110
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
61.2
122
25-200
Trichloroethene
ug/L
50
52.8
106
70-130
Trichlorofluoromethane
ug/L
50
57.2
114
61-130
Vinyl acetate
ug/L
100
129
129
70-140
Vinyl chloride
ug/L
50
57.1
114
59-142
Xylene (Total)
ug/L
150
166
110
70-130
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
100
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695004
MS
92612809032 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3695005
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.3
22.1
106
111
70-135
4
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.6
23.5
113
118
70-148
4
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.9
21.2
105
106
70-131
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.8
21.7
104
108
70-136
4
30
1,1-Dichloroethane
ug/L
ND
20
20
21.7
22.5
109
112
70-147
3
30
1,1-Dichloroethene
ug/L
ND
20
20
22.4
22.9
112
114
70-158
2
30
1,2,3-Trichloropropane
ug/L
ND
20
20
19.5
21.0
98
105
67-137
8
30
1,2-Dibromo-3-
ug/L
ND
20
20
19.7
20.9
99
104
69-136
6
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.6
21.6
103
108
70-137
5
30
1,2-Dichlorobenzene
ug/L
ND
20
20
20.3
21.4
102
107
70-133
5
30
1,2-Dichloroethane
ug/L
ND
20
20
21.6
22.0
108
110
67-138
2
30
1,2-Dichloropropane
ug/L
ND
20
20
21.5
22.3
107
112
70-138
4
30
1,4-Dichlorobenzene
ug/L
1.8
20
20
21.7
22.4
99
103
70-133
3
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
447
466
112
117
69-146
4
30
2-Butanone (MEK)
ug/L
ND
40
40
43.0
44.0
107
110
61-147
2
30
2-Hexanone
ug/L
ND
40
40
45.4
47.5
113
119
67-139
5
30
4-Methyl-2-pentanone
ug/L
ND
40
40
42.5
44.5
106
111
67-136
5
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 116 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3695004
3695005
MS
MSD
92612809032
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
45.5
46.5
114
116
55-159
2
30
Acrylonitrile
ug/L
ND
100
100
106
107
106
107
68-140
1
30
Benzene
ug/L
0.60J
20
20
19.1
19.8
93
96
67-150
3
30
Bromochloromethane
ug/L
ND
20
20
22.0
22.2
110
111
70-146
1
30
Bromodichloromethane
ug/L
ND
20
20
20.8
21.9
104
109
70-138
5
30
Bromoform
ug/L
ND
20
20
21.0
22.3
105
111
57-138
6
30
Bromomethane
ug/L
ND
20
20
17.9
18.7
89
93
10-200
4
30 v3
Carbon disulfide
ug/L
ND
20
20
21.9
22.4
110
112
70-152
2
30
Carbon tetrachloride
ug/L
ND
20
20
22.3
22.3
111
111
70-147
0
30
Chlorobenzene
ug/L
0.81J
20
20
21.1
21.9
102
106
70-137
4
30
Chloroethane
ug/L
ND
20
20
22.8
23.0
114
115
51-166
1
30
Chloroform
ug/L
ND
20
20
21.8
22.8
109
114
70-144
4
30
Chloromethane
ug/L
ND
20
20
20.1
20.0
101
100
24-161
1
30
cis-1,2-Dichloroethene
ug/L
4.7
20
20
25.7
26.9
105
111
67-148
5
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.3
22.1
106
110
70-142
4
30
Dibromochloromethane
ug/L
ND
20
20
20.6
21.3
103
106
68-138
3
30
Dibromomethane
ug/L
ND
20
20
20.6
21.6
103
108
70-134
4
30
Ethylbenzene
ug/L
ND
20
20
20.6
21.1
103
106
68-143
3
30
lodomethane
ug/L
ND
40
40
27.3
30.3
68
76
20-161
10
30 v3
Methylene Chloride
ug/L
ND
20
20
19.2
19.6
96
98
64-148
2
30
Styrene
ug/L
ND
20
20
20.7
20.9
104
105
70-136
1
30
Tetrachloroethene
ug/L
ND
20
20
20.5
21.2
102
106
70-139
4
30
Toluene
ug/L
ND
20
20
19.6
20.1
98
101
47-157
2
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.5
23.0
112
115
70-149
2
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.7
22.6
109
113
70-138
4
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
16.2
17.5
81
87
31-145
7
30
Trichloroethene
ug/L
ND
20
20
21.2
21.6
106
108
70-149
2
30
Trichlorofluoromethane
ug/L
ND
20
20
21.1
22.0
105
110
61-154
4
30
Vinyl acetate
ug/L
ND
40
40
44.9
46.3
112
116
48-156
3
30
Vinyl chloride
ug/L
ND
20
20
21.7
22.3
109
112
55-172
3
30
Xylene (Total)
ug/L
ND
60
60
61.2
63.0
102
105
66-145
3
30
1,2-Dichloroethane-d4 (S)
%
103
106
70-130
4-Bromofluorobenzene (S)
%
102
101
70-130
Toluene-d8 (S)
%
100
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 117 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708458 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007, 92612809008,
92612809009,92612809010,92612809011,92612809012,92612809013,92612809014,92612809015,
92612809016,92612809017,92612809018,92612809019,92612809020,92612809021
METHOD BLANK: 3695009 Matrix: Water
Associated Lab Samples: 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007, 92612809008,
92612809009,92612809010,92612809011,92612809012,92612809013,92612809014,92612809015,
92612809016,92612809017,92612809018,92612809019,92612809020,92612809021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
07/05/22 13:54
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
07/05/22 13:54
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
07/05/22 13:54
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
07/05/22 13:54
1,1-Dichloroethane
ug/L
ND
1.0
0.37
07/05/22 13:54
1,1-Dichloroethene
ug/L
ND
1.0
0.35
07/05/22 13:54
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
07/05/22 13:54
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
07/05/22 13:54
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
07/05/22 13:54
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
07/05/22 13:54
1,2-Dichloroethane
ug/L
ND
1.0
0.32
07/05/22 13:54
1,2-Dichloropropane
ug/L
ND
1.0
0.36
07/05/22 13:54
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
07/05/22 13:54
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
07/05/22 13:54
2-Butanone (MEK)
ug/L
ND
5.0
4.0
07/05/22 13:54
2-Hexanone
ug/L
ND
5.0
0.48
07/05/22 13:54
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
07/05/22 13:54
Acetone
ug/L
ND
25.0
5.1
07/05/22 13:54
Acrylonitrile
ug/L
ND
10.0
1.8
07/05/22 13:54
Benzene
ug/L
ND
1.0
0.34
07/05/22 13:54
Bromochloromethane
ug/L
ND
1.0
0.47
07/05/22 13:54
Bromodichloromethane
ug/L
ND
1.0
0.31
07/05/22 13:54
Bromoform
ug/L
ND
1.0
0.34
07/05/22 13:54
Bromomethane
ug/L
ND
2.0
1.7
07/05/22 13:54
Carbon disulfide
ug/L
ND
2.0
0.36
07/05/22 13:54
Carbon tetrachloride
ug/L
ND
1.0
0.33
07/05/22 13:54
Chlorobenzene
ug/L
ND
1.0
0.28
07/05/22 13:54
Chloroethane
ug/L
ND
1.0
0.65
07/05/22 13:54
Chloroform
ug/L
ND
1.0
0.43
07/05/22 13:54
Chloromethane
ug/L
ND
1.0
0.54
07/05/22 13:54
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
07/05/22 13:54
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/05/22 13:54
Dibromochloromethane
ug/L
ND
1.0
0.36
07/05/22 13:54
Dibromomethane
ug/L
ND
1.0
0.39
07/05/22 13:54
Ethylbenzene
ug/L
ND
1.0
0.30
07/05/22 13:54
lodomethane
ug/L
ND
20.0
9.7
07/05/22 13:54
Methylene Chloride
ug/L
ND
5.0
2.0
07/05/22 13:54
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 118 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
METHOD BLANK: 3695009 Matrix: Water
Associated Lab Samples: 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007, 92612809008,
92612809009,92612809010,92612809011,92612809012,92612809013,92612809014,92612809015,
92612809016,92612809017,92612809018,92612809019,92612809020,92612809021
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Styrene
ug/L
ND
1.0
0.29
07/05/22 13:54
Tetrachloroethene
ug/L
ND
1.0
0.29
07/05/22 13:54
Toluene
ug/L
ND
1.0
0.48
07/05/22 13:54
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
07/05/22 13:54
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/05/22 13:54
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
07/05/22 13:54
Trichloroethene
ug/L
ND
1.0
0.38
07/05/22 13:54
Trichlorofluoromethane
ug/L
ND
1.0
0.30
07/05/22 13:54
Vinyl acetate
ug/L
ND
2.0
1.3
07/05/22 13:54
Vinyl chloride
ug/L
ND
1.0
0.39
07/05/22 13:54
Xylene (Total)
ug/L
ND
1.0
0.34
07/05/22 13:54
1,2-Dichloroethane-d4 (S)
%
104
70-130
07/05/22 13:54
4-Bromofluorobenzene (S)
%
108
70-130
07/05/22 13:54
Toluene-d8 (S)
%
101
70-130
07/05/22 13:54
LABORATORY CONTROL SAMPLE:
Parameter
3695010
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.0
108
70-130
1,1,1-Trichloroethane
ug/L
50
48.9
98
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
51.2
102
70-130
1,1,2-Trichloroethane
ug/L
50
52.8
106
70-130
1,1-Dichloroethane
ug/L
50
46.6
93
70-130
1,1-Dichloroethene
ug/L
50
48.6
97
70-132
1,2,3-Trichloropropane
ug/L
50
50.4
101
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
61.9
124
70-132
1,2-Dibromoethane (EDB)
ug/L
50
52.6
105
70-130
1,2-Dichlorobenzene
ug/L
50
52.9
106
70-130
1,2-Dichloroethane
ug/L
50
47.7
95
70-130
1,2-Dichloropropane
ug/L
50
50.0
100
70-130
1,4-Dichlorobenzene
ug/L
50
49.7
99
70-130
1,4-Dioxane(p-Dioxane)
ug/L
1000
1140
114
70-137
2-Butanone (MEK)
ug/L
100
123
123
70-133
2-Hexanone
ug/L
100
120
120
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
117
117
70-130
Acetone
ug/L
100
111
111
70-144
Acrylonitrile
ug/L
250
287
115
70-130
Benzene
ug/L
50
48.2
96
70-130
Bromochloromethane
ug/L
50
48.2
96
70-130
Bromodichloromethane
ug/L
50
51.4
103
70-130
Bromoform
ug/L
50
52.7
105
70-131
Bromomethane
ug/L
50
45.8
92
30-177
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 119 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
LABORATORY CONTROL SAMPLE:
3695010
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Carbon disulfide
ug/L
50
51.3
103
70-133
Carbon tetrachloride
ug/L
50
50.5
101
70-130
Chlorobenzene
ug/L
50
48.7
97
70-130
Chloroethane
ug/L
50
51.6
103
46-131
Chloroform
ug/L
50
47.9
96
70-130
Chloromethane
ug/L
50
55.2
110
49-130
cis-1,2-Dichloroethene
ug/L
50
46.7
93
70-130
cis-1,3-Dichloropropene
ug/L
50
57.3
115
70-130
Dibromochloromethane
ug/L
50
58.6
117
70-130
Dibromomethane
ug/L
50
50.3
101
70-130
Ethylbenzene
ug/L
50
48.9
98
70-130
lodomethane
ug/L
100
101
101
47-140
Methylene Chloride
ug/L
50
43.3
87
68-130
Styrene
ug/L
50
50.8
102
70-130
Tetrachloroethene
ug/L
50
50.1
100
70-130
Toluene
ug/L
50
47.7
95
70-130
trans-1,2-Dichloroethene
ug/L
50
51.5
103
70-130
trans- 1,3-Dichloropropene
ug/L
50
57.8
116
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
61.0
122
25-200
Trichloroethene
ug/L
50
52.6
105
70-130
Trichlorofluoromethane
ug/L
50
47.7
95
61-130
Vinyl acetate
ug/L
100
112
112
70-140
Vinyl chloride
ug/L
50
59.2
118
59-142
Xylene (Total)
ug/L
150
145
97
70-130
1,2-Dichloroethane-d4 (S)
%
99
70-130
4-Bromofluorobenzene (S)
%
95
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3695011
3695012
MS
MSD
92612809021
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.4
21.4
107 107
70-135
0
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.2
22.6
111 113
70-148
2
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
21.1
21.1
106 105
70-131
0
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.7
22.6
104 113
70-136
9
30
1,1-Dichloroethane
ug/L
ND
20
20
20.4
21.7
102 108
70-147
6
30
1,1-Dichloroethene
ug/L
ND
20
20
20.7
21.9
103 109
70-158
6
30
1,2,3-Trichloropropane
ug/L
ND
20
20
19.9
21.0
100 105
67-137
5
30
1,2-Dibromo-3-
ug/L
ND
20
20
23.4
21.6
117 108
69-136
8
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.7
22.1
109 111
70-137
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
21.0
22.0
105 110
70-133
5
30
1,2-Dichloroethane
ug/L
ND
20
20
20.6
20.5
103 103
67-138
0
30
1,2-Dichloropropane
ug/L
ND
20
20
20.3
22.1
101 111
70-138
9
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 120 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3695011
3695012
MS
MSD
92612809021
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
20
20
20.8
20.9
104
105
70-133
1
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
374
419
94
105
69-146
11
30
2-Butanone (MEK)
ug/L
ND
40
40
48.5
48.9
121
122
61-147
1
30
2-Hexanone
ug/L
ND
40
40
45.9
46.2
115
116
67-139
1
30
4-Methyl-2-pentanone
ug/L
ND
40
40
43.6
46.2
109
116
67-136
6
30
(MIBK)
Acetone
ug/L
ND
40
40
42.9
47.9
107
120
55-159
11
30
Acrylonitrile
ug/L
ND
100
100
107
105
107
105
68-140
2
30
Benzene
ug/L
ND
20
20
19.6
21.8
98
109
67-150
10
30
Bromochloromethane
ug/L
ND
20
20
20.5
20.6
102
103
70-146
0
30
Bromodichloromethane
ug/L
ND
20
20
20.6
20.9
103
105
70-138
2
30
Bromoform
ug/L
ND
20
20
17.7
18.1
89
90
57-138
2
30
Bromomethane
ug/L
ND
20
20
18.9
19.6
95
98
10-200
4
30
Carbon disulfide
ug/L
ND
20
20
20.2
20.4
101
102
70-152
1
30
Carbon tetrachloride
ug/L
ND
20
20
21.0
21.6
105
108
70-147
3
30
Chlorobenzene
ug/L
ND
20
20
21.1
21.4
106
107
70-137
1
30
Chloroethane
ug/L
ND
20
20
23.8
20.6
119
103
51-166
14
30
Chloroform
ug/L
ND
20
20
20.8
21.1
104
106
70-144
2
30
Chloromethane
ug/L
ND
20
20
23.7
25.1
119
126
24-161
6
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
20.5
21.4
101
106
67-148
4
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.8
22.8
104
114
70-142
9
30
Dibromochloromethane
ug/L
ND
20
20
21.3
21.5
107
107
68-138
1
30
Dibromomethane
ug/L
ND
20
20
19.5
20.5
98
102
70-134
5
30
Ethylbenzene
ug/L
ND
20
20
21.2
21.6
106
108
68-143
2
30
lodomethane
ug/L
ND
40
40
39.4
44.7
99
112
20-161
13
30
Methylene Chloride
ug/L
ND
20
20
19.0
19.3
95
97
64-148
2
30
Styrene
ug/L
ND
20
20
21.2
21.2
106
106
70-136
0
30
Tetrachloroethene
ug/L
ND
20
20
21.6
21.2
108
106
70-139
2
30
Toluene
ug/L
ND
20
20
19.8
20.8
99
104
47-157
5
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.0
22.8
105
114
70-149
8
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.7
22.5
103
113
70-138
9
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
12.9
13.4
64
67
31-145
4
30
Trichloroethene
ug/L
ND
20
20
20.9
22.2
104
111
70-149
6
30
Trichlorofluoromethane
ug/L
ND
20
20
20.5
22.1
102
111
61-154
8
30
Vinyl acetate
ug/L
ND
40
40
43.1
42.9
108
107
48-156
0
30
Vinyl chloride
ug/L
ND
20
20
23.3
24.4
117
122
55-172
4
30
Xylene (Total)
ug/L
ND
60
60
63.9
64.1
107
107
66-145
0
30
1,2-Dichloroethane-d4 (S)
%
104
100
70-130
4-Bromofluorobenzene (S)
%
98
98
70-130
Toluene-d8 (S)
%
97
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 121 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708459 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809001, 92612809022, 92612809023, 92612809024, 92612809031
METHOD BLANK: 3695013 Matrix: Water
Associated Lab Samples: 92612809001, 92612809022, 92612809023, 92612809024, 92612809031
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
07/05/22 13:36
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
07/05/22 13:36
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
07/05/22 13:36
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
07/05/22 13:36
1,1-Dichloroethane
ug/L
ND
1.0
0.37
07/05/22 13:36
1,1-Dichloroethene
ug/L
ND
1.0
0.35
07/05/22 13:36
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
07/05/22 13:36
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
07/05/22 13:36
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
07/05/22 13:36
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
07/05/22 13:36
1,2-Dichloroethane
ug/L
ND
1.0
0.32
07/05/22 13:36
1,2-Dichloropropane
ug/L
ND
1.0
0.36
07/05/22 13:36
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
07/05/22 13:36
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
07/05/22 13:36
2-Butanone (MEK)
ug/L
ND
5.0
4.0
07/05/22 13:36
2-Hexanone
ug/L
ND
5.0
0.48
07/05/22 13:36
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
07/05/22 13:36
Acetone
ug/L
ND
25.0
5.1
07/05/22 13:36
Acrylonitrile
ug/L
ND
10.0
1.8
07/05/22 13:36
Benzene
ug/L
ND
1.0
0.34
07/05/22 13:36
Bromochloromethane
ug/L
ND
1.0
0.47
07/05/22 13:36
Bromodichloromethane
ug/L
ND
1.0
0.31
07/05/22 13:36
Bromoform
ug/L
ND
1.0
0.34
07/05/22 13:36
Bromomethane
ug/L
ND
2.0
1.7
07/05/22 13:36
Carbon disulfide
ug/L
ND
2.0
0.36
07/05/22 13:36
Carbon tetrachloride
ug/L
ND
1.0
0.33
07/05/22 13:36
Chlorobenzene
ug/L
ND
1.0
0.28
07/05/22 13:36
Chloroethane
ug/L
ND
1.0
0.65
07/05/22 13:36
Chloroform
ug/L
ND
1.0
0.43
07/05/22 13:36
Chloromethane
ug/L
ND
1.0
0.54
07/05/22 13:36
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
07/05/22 13:36
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/05/22 13:36
Dibromochloromethane
ug/L
ND
1.0
0.36
07/05/22 13:36
Dibromomethane
ug/L
ND
1.0
0.39
07/05/22 13:36
Ethylbenzene
ug/L
ND
1.0
0.30
07/05/22 13:36
lodomethane
ug/L
ND
20.0
9.7
07/05/22 13:36
Methylene Chloride
ug/L
ND
5.0
2.0
07/05/22 13:36
Styrene
ug/L
ND
1.0
0.29
07/05/22 13:36
Tetrachloroethene
ug/L
ND
1.0
0.29
07/05/22 13:36
Toluene
ug/L
ND
1.0
0.48
07/05/22 13:36
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 122 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
METHOD BLANK: 3695013 Matrix: Water
Associated Lab Samples: 92612809001, 92612809022, 92612809023, 92612809024, 92612809031
Blank Reporting
Parameter Units Result Limit MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
07/05/22 13:36
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/05/22 13:36
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
07/05/22 13:36
Trichloroethene
ug/L
ND
1.0
0.38
07/05/22 13:36
Trichlorofluoromethane
ug/L
ND
1.0
0.30
07/05/22 13:36
Vinyl acetate
ug/L
ND
2.0
1.3
07/05/22 13:36
Vinyl chloride
ug/L
ND
1.0
0.39
07/05/22 13:36
Xylene (Total)
ug/L
ND
1.0
0.34
07/05/22 13:36
1,2-Dichloroethane-d4 (S)
%
103
70-130
07/05/22 13:36
4-Bromofluorobenzene (S)
%
102
70-130
07/05/22 13:36
Toluene-d8 (S)
%
103
70-130
07/05/22 13:36
LABORATORY CONTROL SAMPLE:
3695014
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.8
108
70-130
1,1,1-Trichloroethane
ug/L
50
53.6
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
52.2
104
70-130
1,1,2-Trichloroethane
ug/L
50
52.7
105
70-130
1,1-Dichloroethane
ug/L
50
48.5
97
70-130
1,1-Dichloroethene
ug/L
50
50.9
102
70-132
1,2,3-Trichloropropane
ug/L
50
51.7
103
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
60.5
121
70-132
1,2-Dibromoethane (EDB)
ug/L
50
53.7
107
70-130
1,2-Dichlorobenzene
ug/L
50
53.6
107
70-130
1,2-Dichloroethane
ug/L
50
49.5
99
70-130
1,2-Dichloropropane
ug/L
50
51.8
104
70-130
1,4-Dichlorobenzene
ug/L
50
50.4
101
70-130
1,4-Dioxane(p-Dioxane)
ug/L
1000
1100
110
70-137
2-Butanone (MEK)
ug/L
100
128
128
70-133
2-Hexanone
ug/L
100
119
119
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
117
117
70-130
Acetone
ug/L
100
109
109
70-144
Acrylonitrile
ug/L
250
292
117
70-130
Benzene
ug/L
50
51.1
102
70-130
Bromochloromethane
ug/L
50
51.6
103
70-130
Bromodichloromethane
ug/L
50
53.1
106
70-130
Bromoform
ug/L
50
51.3
103
70-131
Bromomethane
ug/L
50
53.1
106
30-177
Carbon disulfide
ug/L
50
55.0
110
70-133
Carbon tetrachloride
ug/L
50
53.3
107
70-130
Chlorobenzene
ug/L
50
50.7
101
70-130
Chloroethane
ug/L
50
54.9
110
46-131
Chloroform
ug/L
50
50.7
101
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
LABORATORY CONTROL SAMPLE:
Parameter
3695014
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
50
59.9
120
49-130
cis-1,2-Dichloroethene
ug/L
50
49.1
98
70-130
cis-1,3-Dichloropropene
ug/L
50
57.7
115
70-130
Dibromochloromethane
ug/L
50
58.8
118
70-130
Dibromomethane
ug/L
50
51.0
102
70-130
Ethylbenzene
ug/L
50
51.2
102
70-130
lodomethane
ug/L
100
104
104
47-140
Methylene Chloride
ug/L
50
45.7
91
68-130
Styrene
ug/L
50
52.4
105
70-130
Tetrachloroethene
ug/L
50
52.6
105
70-130
Toluene
ug/L
50
49.5
99
70-130
trans-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
trans- 1,3-Dichloropropene
ug/L
50
58.8
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
61.3
123
25-200
Trichloroethene
ug/L
50
54.6
109
70-130
Trichlorofluoromethane
ug/L
50
49.8
100
61-130
Vinyl acetate
ug/L
100
115
115
70-140
Vinyl chloride
ug/L
50
62.0
124
59-142
Xylene (Total)
ug/L
150
152
101
70-130
1,2-Dichloroethane-d4 (S)
%
100
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695015
MS
92612809031 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3695016
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
21.8
21.5
109
108
70-135
1
30
1,1,1-Trichloroethane
ug/L
ND
20
20
21.2
22.5
106
113
70-148
6
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.9
21.7
104
108
70-131
4
30
1,1,2-Trichloroethane
ug/L
ND
20
20
21.7
21.8
108
109
70-136
0
30
1,1-Dichloroethane
ug/L
ND
20
20
21.1
22.9
106
114
70-147
8
30
1,1-Dichloroethene
ug/L
ND
20
20
21.4
22.0
107
110
70-158
3
30
1,2,3-Trichloropropane
ug/L
ND
20
20
20.8
20.9
104
104
67-137
1
30
1,2-Dibromo-3-
ug/L
ND
20
20
21.9
24.5
110
123
69-136
11
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
21.3
21.6
106
108
70-137
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
21.5
21.7
107
109
70-133
1
30
1,2-Dichloroethane
ug/L
ND
20
20
20.4
21.2
102
106
67-138
4
30
1,2-Dichloropropane
ug/L
ND
20
20
20.9
21.1
104
106
70-138
1
30
1,4-Dichlorobenzene
ug/L
ND
20
20
22.1
22.5
110
112
70-133
2
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
407
345
102
86
69-146
16
30
2-Butanone (MEK)
ug/L
ND
40
40
55.3
59.9
134
146
61-147
8
30
2-Hexanone
ug/L
ND
40
40
49.0
51.5
123
129
67-139
5
30
4-Methyl-2-pentanone
ug/L
ND
40
40
47.8
50.4
119
126
67-136
5
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 124 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3695015
3695016
MS
MSD
92612809031
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
27.8
40
40
77.2
76.3
123
121
55-159
1
30
Acrylonitrile
ug/L
ND
100
100
110
125
110
125
68-140
12
30
Benzene
ug/L
1.1
20
20
21.4
22.2
102
106
67-150
4
30
Bromochloromethane
ug/L
ND
20
20
22.0
20.9
110
105
70-146
5
30
Bromodichloromethane
ug/L
ND
20
20
19.7
21.4
98
107
70-138
9
30
Bromoform
ug/L
ND
20
20
18.6
19.1
93
95
57-138
3
30
Bromomethane
ug/L
ND
20
20
20.7
19.6
104
98
10-200
5
30
Carbon disulfide
ug/L
ND
20
20
20.8
21.0
104
105
70-152
1
30
Carbon tetrachloride
ug/L
ND
20
20
21.8
21.2
109
106
70-147
2
30
Chlorobenzene
ug/L
ND
20
20
22.0
21.8
110
109
70-137
1
30
Chloroethane
ug/L
ND
20
20
22.0
22.1
110
111
51-166
1
30
Chloroform
ug/L
ND
20
20
20.8
21.6
104
108
70-144
4
30
Chloromethane
ug/L
ND
20
20
23.9
23.2
120
116
24-161
3
30
cis-1,2-Dichloroethene
ug/L
2.7
20
20
23.0
24.4
101
108
67-148
6
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
21.4
22.5
107
112
70-142
5
30
Dibromochloromethane
ug/L
ND
20
20
22.0
21.3
110
106
68-138
3
30
Dibromomethane
ug/L
ND
20
20
20.4
20.6
102
103
70-134
1
30
Ethylbenzene
ug/L
ND
20
20
21.5
21.7
107
108
68-143
1
30
lodomethane
ug/L
ND
40
40
37.5
39.5
94
99
20-161
5
30
Methylene Chloride
ug/L
ND
20
20
18.3
20.1
92
100
64-148
9
30
Styrene
ug/L
ND
20
20
21.5
21.7
108
108
70-136
1
30
Tetrachloroethene
ug/L
ND
20
20
21.4
20.7
107
104
70-139
3
30
Toluene
ug/L
ND
20
20
20.1
20.4
100
102
47-157
2
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.4
22.5
107
113
70-149
5
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
21.7
22.8
109
114
70-138
5
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
15.7
15.9
78
80
31-145
1
30
Trichloroethene
ug/L
ND
20
20
21.0
23.3
105
117
70-149
10
30
Trichlorofluoromethane
ug/L
ND
20
20
20.4
21.9
102
110
61-154
7
30
Vinyl acetate
ug/L
ND
40
40
42.5
44.9
106
112
48-156
6
30
Vinyl chloride
ug/L
ND
20
20
24.0
25.3
120
126
55-172
5
30
Xylene (Total)
ug/L
ND
60
60
65.1
64.5
108
108
66-145
1
30
1,2-Dichloroethane-d4 (S)
%
99
103
70-130
4-Bromofluorobenzene (S)
%
100
99
70-130
Toluene-d8 (S)
%
97
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 125 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708979 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92612809029, 92612809030, 92612809033, 92612809034, 92612809035, 92612809036, 92612809037
METHOD BLANK: 3697344 Matrix: Water
Associated Lab Samples: 92612809029, 92612809030, 92612809033, 92612809034, 92612809035, 92612809036, 92612809037
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.31
07/07/22 03:36
1,1,1-Trichloroethane
ug/L
ND
1.0
0.33
07/07/22 03:36
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
07/07/22 03:36
1,1,2-Trichloroethane
ug/L
ND
1.0
0.32
07/07/22 03:36
1,1-Dichloroethane
ug/L
ND
1.0
0.37
07/07/22 03:36
1,1-Dichloroethene
ug/L
ND
1.0
0.35
07/07/22 03:36
1,2,3-Trichloropropane
ug/L
ND
1.0
0.26
07/07/22 03:36
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.34
07/07/22 03:36
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.27
07/07/22 03:36
1,2-Dichlorobenzene
ug/L
ND
1.0
0.34
07/07/22 03:36
1,2-Dichloroethane
ug/L
ND
1.0
0.32
07/07/22 03:36
1,2-Dichloropropane
ug/L
ND
1.0
0.36
07/07/22 03:36
1,4-Dichlorobenzene
ug/L
ND
1.0
0.33
07/07/22 03:36
1,4-Dioxane (p-Dioxane)
ug/L
ND
150
38.7
07/07/22 03:36
2-Butanone (MEK)
ug/L
ND
5.0
4.0
07/07/22 03:36
2-Hexanone
ug/L
ND
5.0
0.48
07/07/22 03:36
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
2.7
07/07/22 03:36
Acetone
ug/L
ND
25.0
5.1
07/07/22 03:36
Acrylonitrile
ug/L
ND
10.0
1.8
07/07/22 03:36
Benzene
ug/L
ND
1.0
0.34
07/07/22 03:36
Bromochloromethane
ug/L
ND
1.0
0.47
07/07/22 03:36
Bromodichloromethane
ug/L
ND
1.0
0.31
07/07/22 03:36
Bromoform
ug/L
ND
1.0
0.34
07/07/22 03:36
Bromomethane
ug/L
ND
2.0
1.7
07/07/22 03:36
Carbon disulfide
ug/L
ND
2.0
0.36
07/07/22 03:36
Carbon tetrachloride
ug/L
ND
1.0
0.33
07/07/22 03:36
Chlorobenzene
ug/L
ND
1.0
0.28
07/07/22 03:36
Chloroethane
ug/L
ND
1.0
0.65
07/07/22 03:36
Chloroform
ug/L
ND
1.0
0.43
07/07/22 03:36
Chloromethane
ug/L
ND
1.0
0.54
07/07/22 03:36
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.38
07/07/22 03:36
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/07/22 03:36
Dibromochloromethane
ug/L
ND
1.0
0.36
07/07/22 03:36
Dibromomethane
ug/L
ND
1.0
0.39
07/07/22 03:36
Ethylbenzene
ug/L
ND
1.0
0.30
07/07/22 03:36
lodomethane
ug/L
ND
20.0
9.7
07/07/22 03:36
Methylene Chloride
ug/L
ND
5.0
2.0
07/07/22 03:36
Styrene
ug/L
ND
1.0
0.29
07/07/22 03:36
Tetrachloroethene
ug/L
ND
1.0
0.29
07/07/22 03:36
Toluene
ug/L
ND
1.0
0.48
07/07/22 03:36
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 126 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
METHOD BLANK: 3697344 Matrix: Water
Associated Lab Samples: 92612809029, 92612809030, 92612809033, 92612809034, 92612809035, 92612809036, 92612809037
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.40
07/07/22 03:36
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.36
07/07/22 03:36
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.56
07/07/22 03:36
Trichloroethene
ug/L
ND
1.0
0.38
07/07/22 03:36
Trichlorofluoromethane
ug/L
ND
1.0
0.30
07/07/22 03:36
Vinyl acetate
ug/L
ND
2.0
1.3
07/07/22 03:36
Vinyl chloride
ug/L
ND
1.0
0.39
07/07/22 03:36
Xylene (Total)
ug/L
ND
1.0
0.34
07/07/22 03:36
1,2-Dichloroethane-d4 (S)
%
101
70-130
07/07/22 03:36
4-Bromofluorobenzene (S)
%
99
70-130
07/07/22 03:36
Toluene-d8 (S)
%
99
70-130
07/07/22 03:36
LABORATORY CONTROL SAMPLE:
3697345
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
55.6
111
70-130
1,1,1-Trichloroethane
ug/L
50
54.9
110
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
53.3
107
70-130
1,1,2-Trichloroethane
ug/L
50
53.9
108
70-130
1,1-Dichloroethane
ug/L
50
53.1
106
70-130
1,1-Dichloroethene
ug/L
50
53.9
108
70-132
1,2,3-Trichloropropane
ug/L
50
53.5
107
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
54.1
108
70-132
1,2-Dibromoethane (EDB)
ug/L
50
54.3
109
70-130
1,2-Dichlorobenzene
ug/L
50
54.1
108
70-130
1,2-Dichloroethane
ug/L
50
52.5
105
70-130
1,2-Dichloropropane
ug/L
50
54.3
109
70-130
1,4-Dichlorobenzene
ug/L
50
53.1
106
70-130
1,4-Dioxane(p-Dioxane)
ug/L
1000
1040
104
70-137
2-Butanone (MEK)
ug/L
100
111
111
70-133
2-Hexanone
ug/L
100
114
114
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
109
109
70-130
Acetone
ug/L
100
105
105
70-144
Acrylonitrile
ug/L
250
266
107
70-130
Benzene
ug/L
50
50.7
101
70-130
Bromochloromethane
ug/L
50
56.2
112
70-130
Bromodichloromethane
ug/L
50
55.0
110
70-130
Bromoform
ug/L
50
55.6
111
70-131
Bromomethane
ug/L
50
48.0
96
30-177
Carbon disulfide
ug/L
50
53.2
106
70-133
Carbon tetrachloride
ug/L
50
53.5
107
70-130
Chlorobenzene
ug/L
50
53.4
107
70-130
Chloroethane
ug/L
50
49.6
99
46-131
Chloroform
ug/L
50
52.6
105
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 127 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
LABORATORY CONTROL SAMPLE:
Parameter
3697345
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Chloromethane
ug/L
50
50.8
102
49-130
cis-1,2-Dichloroethene
ug/L
50
54.1
108
70-130
cis-1,3-Dichloropropene
ug/L
50
55.0
110
70-130
Dibromochloromethane
ug/L
50
55.5
111
70-130
Dibromomethane
ug/L
50
53.5
107
70-130
Ethylbenzene
ug/L
50
53.3
107
70-130
lodomethane
ug/L
100
115
115
47-140
Methylene Chloride
ug/L
50
47.6
95
68-130
Styrene
ug/L
50
55.1
110
70-130
Tetrachloroethene
ug/L
50
53.8
108
70-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.8
110
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
44.2
88
25-200
Trichloroethene
ug/L
50
53.9
108
70-130
Trichlorofluoromethane
ug/L
50
50.7
101
61-130
Vinyl acetate
ug/L
100
115
115
70-140
Vinyl chloride
ug/L
50
55.1
110
59-142
Xylene (Total)
ug/L
150
163
108
70-130
1,2-Dichloroethane-d4 (S)
%
104
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3697346
MS
92612809035 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3697347
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
22.8
22.4
114
112
70-135
2
30
1,1,1-Trichloroethane
ug/L
ND
20
20
23.7
22.8
118
114
70-148
4
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
22.4
21.6
112
108
70-131
3
30
1,1,2-Trichloroethane
ug/L
ND
20
20
22.4
22.1
112
111
70-136
1
30
1,1-Dichloroethane
ug/L
ND
20
20
22.4
21.5
112
108
70-147
4
30
1,1-Dichloroethene
ug/L
ND
20
20
23.8
22.7
119
113
70-158
5
30
1,2,3-Trichloropropane
ug/L
ND
20
20
23.3
20.9
116
104
67-137
11
30
1,2-Dibromo-3-
ug/L
ND
20
20
22.2
21.4
111
107
69-136
4
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
22.4
21.4
112
107
70-137
5
30
1,2-Dichlorobenzene
ug/L
ND
20
20
22.2
21.5
111
108
70-133
3
30
1,2-Dichloroethane
ug/L
ND
20
20
22.2
21.5
111
108
67-138
3
30
1,2-Dichloropropane
ug/L
ND
20
20
23.0
22.8
115
114
70-138
1
30
1,4-Dichlorobenzene
ug/L
0.74J
20
20
22.1
21.5
107
104
70-133
2
30
1,4-Dioxane (p-Dioxane)
ug/L
ND
400
400
471
446
118
111
69-146
6
30
2-Butanone (MEK)
ug/L
ND
40
40
41.3
39.7
103
99
61-147
4
30
2-Hexanone
ug/L
ND
40
40
48.1
46.0
120
115
67-139
4
30
4-Methyl-2-pentanone
ug/L
ND
40
40
44.0
41.7
110
104
67-136
5
30
(MIBK)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 128 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3697346
3697347
MS
MSD
92612809035
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Acetone
ug/L
ND
40
40
43.4
42.1
108
105
55-159
3
30
Acrylonitrile
ug/L
ND
100
100
101
95.9
101
96
68-140
5
30
Benzene
ug/L
ND
20
20
20.1
19.4
101
97
67-150
4
30
Bromochloromethane
ug/L
ND
20
20
22.7
21.8
113
109
70-146
4
30
Bromodichloromethane
ug/L
ND
20
20
22.6
21.6
113
108
70-138
4
30
Bromoform
ug/L
ND
20
20
22.9
22.3
115
112
57-138
3
30
Bromomethane
ug/L
ND
20
20
18.3
17.9
91
89
10-200
2
30 v3
Carbon disulfide
ug/L
ND
20
20
22.0
21.2
110
106
70-152
4
30
Carbon tetrachloride
ug/L
ND
20
20
24.1
23.2
120
116
70-147
4
30
Chlorobenzene
ug/L
ND
20
20
22.1
21.7
111
109
70-137
2
30
Chloroethane
ug/L
ND
20
20
24.7
23.4
123
117
51-166
5
30
Chloroform
ug/L
ND
20
20
22.8
21.8
114
109
70-144
4
30
Chloromethane
ug/L
ND
20
20
23.2
22.3
116
112
24-161
4
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.5
21.9
112
110
67-148
3
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
22.7
22.2
114
111
70-142
2
30
Dibromochloromethane
ug/L
ND
20
20
22.8
21.9
114
109
68-138
4
30
Dibromomethane
ug/L
ND
20
20
22.7
21.5
113
108
70-134
5
30
Ethylbenzene
ug/L
ND
20
20
22.2
21.8
111
109
68-143
2
30
lodomethane
ug/L
ND
40
40
30.6
27.4
77
69
20-161
11
30 v3
Methylene Chloride
ug/L
ND
20
20
19.8
19.1
99
96
64-148
4
30
Styrene
ug/L
ND
20
20
21.9
21.2
109
106
70-136
3
30
Tetrachloroethene
ug/L
ND
20
20
22.7
21.8
114
109
70-139
4
30
Toluene
ug/L
ND
20
20
21.1
20.4
106
102
47-157
4
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
23.3
22.2
117
111
70-149
5
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
23.5
22.6
118
113
70-138
4
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
17.4
16.1
87
81
31-145
7
30
Trichloroethene
ug/L
ND
20
20
23.5
22.6
117
113
70-149
4
30
Trichlorofluoromethane
ug/L
ND
20
20
22.5
22.3
112
111
61-154
1
30
Vinyl acetate
ug/L
ND
40
40
42.9
40.1
107
100
48-156
7
30
Vinyl chloride
ug/L
ND
20
20
24.3
23.1
121
116
55-172
5
30
Xylene (Total)
ug/L
ND
60
60
66.8
65.0
111
108
66-145
3
30
1,2-Dichloroethane-d4 (S)
%
97
94
70-130
4-Bromofluorobenzene (S)
%
102
101
70-130
Toluene-d8 (S)
%
100
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 129 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708485 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3695069 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L ND 5000 5000 07/02/22 19:14
LABORATORY CONTROL SAMPLE: 3695070
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 50600 101 80-120
LABORATORY CONTROL SAMPLE: 3695071
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 50800 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695072 3695073
MS MSD
92612546003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 197 mg/L 50000 50000 255000 256000 117 119 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695074 3695075
MS MSD
92612809002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 128000 50000 50000 138000 137000 20 17 80-120 1 25 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 130 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708591 Analysis Method: SM 3500-Fe B-2011
QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3695393 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Iron, Ferrous mg/L ND 0.50 0.040 07/05/22 14:53 N2
LABORATORY CONTROL SAMPLE: 3695394
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Iron, Ferrous mg/L 1.5 1.5 100 90-110 N2
SAMPLE DUPLICATE: 3695395
92612391020 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Iron, Ferrous mg/L ND ND 10 H3,N2
SAMPLE DUPLICATE: 3695396
92612391021 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Iron, Ferrous mg/L ND ND 10 H3,N2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 131 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708449 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3694982 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfide ug/L ND 100 50.0 07/02/22 01:57
LABORATORY CONTROL SAMPLE: 3694983
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide ug/L 500 500 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3694984 3694985
MS MSD
92612809001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 362 397 70 77 80-120 9 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3694986 3694987
MS MSD
92612810007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 520 528 102 104 80-120 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 132 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708542 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3695246 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Sulfate ug/L ND 1000 500 07/04/22 02:11
LABORATORY CONTROL SAMPLE: 3695247
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate ug/L 50000 52600 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695248 3695249
MS MSD
92612682003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 0.84J 50000 50000 51600 52300 102 103 90-110 1 10
mg/L
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695250 3695251
MS MSD
92612809006 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfate ug/L 875J 50000 50000 51400 52200 101 103 90-110 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 133 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708438 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3694964 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate ug/L ND 40.0 10.0 07/01/22 23:57
LABORATORY CONTROL SAMPLE: 3694965
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate ug/L 1500 1470 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3694968 3694969
MS MSD
92612616003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 0.72 mg/L 1500 1500 2210 2210 100 99 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3694975 3694976
MS MSD
92612809007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 974 977 65 65 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 134 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 709689 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006
METHOD BLANK: 3700741 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 500 07/11/2213:03
LABORATORY CONTROL SAMPLE: 3700742
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride ug/L 20000 20100 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3700743 3700744
MS MSD
92613126001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 24.1 mg/L 10000 10000 33200 33400 91 92 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3700745 3700746
MS MSD
92613128002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 77.1 mg/L 10000 10000 86300 85300 92 82 90-110 1 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 135 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 709690 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809007, 92612809008, 92612809009, 92612809010, 92612809011
METHOD BLANK: 3700747 Matrix: Water
Associated Lab Samples: 92612809007, 92612809008, 92612809009, 92612809010, 92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 500 07/11/2213:35
LABORATORY CONTROL SAMPLE: 3700748
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride ug/L 20000 20100 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3700749 3700750
MS MSD
92612809007 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 19400 10000 10000 29400 28900 100 95 90-110 2 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3700751 3700752
MS MSD
92612809008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chloride ug/L 5050 10000 10000 14900 14800 98 97 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 136 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708940 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
METHOD BLANK: 3697113 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007,
92612809008,92612809009,92612809010,92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand ug/L ND 25000 12500 07/07/22 10:09
LABORATORY CONTROL SAMPLE: 3697114
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand ug/L 750000 772000 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3697115 3697116
MS MSD
92612331001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L ND 100000 100000 22700J 34600 2 14 90-110 3 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3697117 3697118
MS MSD
92612483002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 2060000 100000 100000 2050000 2060000 -6 6 90-110 1 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 137 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708598 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007
METHOD BLANK: 3695424 Matrix: Water
Associated Lab Samples: 92612809001, 92612809002, 92612809003, 92612809004, 92612809005, 92612809006, 92612809007
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon ug/L ND 1000 500 07/05/22 14:22
LABORATORY CONTROL SAMPLE: 3695425
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon ug/L 25000 24000 96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695426 3695427
MS MSD
92612135001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 1.6 mg/L 25000 25000 25100 25400 94 95 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695428 3695429
MS MSD
92612752001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 77.8 mg/L 25000 25000 103000 108000 100 119 90-110 5 10 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 138 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 708599 Analysis Method: SM 531 OB-2014
QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92612809008, 92612809009, 92612809010, 92612809011
METHOD BLANK: 3695430 Matrix: Water
Associated Lab Samples: 92612809008, 92612809009, 92612809010, 92612809011
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon ug/L ND 1000 500 07/06/22 01:31
LABORATORY CONTROL SAMPLE: 3695431
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon ug/L 25000 24200 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3695432 3695433
MS MSD
92612809008 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 531J 25000 25000 24700 24800 96 97 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 139 of 154

lV11.1 Analytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Alexander Landfill
Pace Project No.: 92612809
QC Batch: 745268 Analysis Method: AM23G
QC Batch Method: AM23G Analysis Description: Low Level Volatile Fatty Acids
Laboratory: Pace Analytical Gulf Coast
Associated Lab Samples: 92612809042
METHOD BLANK: 2370011
Associated Lab Samples: 92612809042
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Lactic Acid
mg/L
ND
0.50
0.053
07/13/2211:52
Acetic Acid
mg/L
ND
0.50
0.12
07/13/2211:52
Propionic Acid
mg/L
ND
0.50
0.053
07/13/2211:52
Formic acid
mg/L
ND
0.50
0.055
07/13/22 11:52
Butyric Acid
mg/L
ND
0.50
0.058
07/13/2211:52
Pyruvic Acid
mg/L
ND
0.50
0.060
07/13/2211:52
i-Pentanoic Acid
mg/L
ND
0.50
0.061
07/13/2211:52
Pentanoic Acid
mg/L
ND
0.50
0.056
07/13/2211:52
i-Hexanoic Acid
mg/L
ND
0.50
0.056
07/13/2211:52
Hexanoic Acid
mg/L
ND
0.50
0.058
07/13/2211:52
Qualifiers
LABORATORY CONTROL SAMPLE & LCSD:
2370012
2370013
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qualifiers
Lactic Acid
mg/L
2
1.8
2.0
92
99
70-130
7
20
Acetic Acid
mg/L
2
1.8
1.9
91
94
70-130
4
20
Propionic Acid
mg/L
2
1.9
1.9
93
95
70-130
1
20
Formic acid
mg/L
2
1.7
1.7
84
84
70-130
0
20
Butyric Acid
mg/L
2
1.9
1.6
94
80
70-130
16
20
Pyruvic Acid
mg/L
2
1.5
1.5
77
77
70-130
0
20
i-Pentanoic Acid
mg/L
2
2.0
1.7
98
87
70-130
12
20
Pentanoic Acid
mg/L
2
1.7
1.7
87
86
70-130
0
20
i-Hexanoic Acid
mg/L
2
1.8
1.8
88
89
70-130
1
20
Hexanoic Acid
mg/L
2
1.9
1.7
94
87
70-130
9
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC.
Page 140 of 154

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Huntersville, NC 28078
0788
www.pacelabs.com [phone]
QUALIFIERS
Project: Alexander Landfill
Pace Project No.: 92612809
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
BO Analyte was detected in an associated blank at a concentration greater than the MDL.
CO Result confirmed by second analysis.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
HS Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A
complete list of accreditations/certifications is available upon request.
R1 RPD value was outside control limits.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 141 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Alexander Landfill
92612809
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92612809038
MW-11
AM20GAX
745382
92612809039
MW-16
AM20GAX
745382
92612809040
MW-25
AM20GAX
745382
92612809041
MW-27
AM20GAX
745382
92612809038
MW-11
AM20GAX
745352
92612809039
MW-16
AM20GAX
745352
92612809040
MW-25
AM20GAX
745352
92612809041
MW-27
AM20GAX
745352
92612809001
MW-6
RSK 175 Modified
708386
92612809002
MW-5
RSK 175 Modified
708386
92612809003
MW-12D
RSK 175 Modified
708386
92612809004
MW-24
RSK 175 Modified
708386
92612809005
MW-26
RSK 175 Modified
708386
92612809006
MW-31
RSK 175 Modified
708386
92612809007
MW-12
RSK 175 Modified
708974
92612809029
MW-1
RSK 175 Modified
708974
92612809030
MW-1B
RSK 175 Modified
708974
92612809001
MW-6
EPA 3005A
708819
EPA 6020B
708917
92612809002
MW-5
EPA 3005A
708819
EPA 6020B
708917
92612809003
MW-12D
EPA 3005A
708819
EPA 6020B
708917
92612809004
MW-24
EPA 3005A
708819
EPA 6020B
708917
92612809005
MW-26
EPA 3005A
708819
EPA 6020B
708917
92612809006
MW-31
EPA 3005A
708890
EPA 6020B
709035
92612809007
MW-12
EPA 3005A
708890
EPA 6020B
709035
92612809008
MW-25
EPA 3005A
708890
EPA 6020B
709035
92612809009
MW-27
EPA 3005A
708890
EPA 6020B
709035
92612809010
MW-11
EPA 3005A
708890
EPA 6020B
709035
92612809011
MW-16
EPA 3005A
708890
EPA 6020B
709035
92612809012
MW-13
EPA 3005A
708890
EPA 6020B
709035
92612809013
MW-14
EPA 3005A
708890
EPA 6020B
709035
92612809014
MW-15
EPA 3005A
708890
EPA 6020B
709035
92612809015
MW-17
EPA 3005A
708890
EPA 6020B
709035
92612809016
MW-18
EPA 3005A
708890
EPA 6020B
709035
92612809017
MW-19
EPA 3005A
708890
EPA 6020B
709035
92612809018
MW-20
EPA 3005A
709042
EPA 6020B
709131
92612809019
MW-21
EPA 3005A
709042
EPA 6020B
709131
92612809020
MW-22
EPA 3005A
709042
EPA 6020B
709131
92612809021
MW-23
EPA 3005A
709042
EPA 6020B
709131
92612809022
MW-32
EPA 3005A
709042
EPA 6020B
709131
92612809023
MW-33
EPA 3005A
709042
EPA 6020B
709131
92612809024
MW-34
EPA 3005A
709042
EPA 6020B
709131
92612809025
SW-3
EPA 3005A
709042
EPA 6020B
709131
92612809026
SW-4R
EPA 3005A
709042
EPA 6020B
709131
92612809027
SW-5
EPA 3005A
709042
EPA 6020B
709131
92612809028
SW-6
EPA 3005A
709042
EPA 6020B
709131
92612809029
MW-1
EPA 3005A
709042
EPA 6020B
709131
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 07/19/2022 02:49 PM
without the written consent of Pace Analytical Services, LLC.
Page 142 of 154

laneAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Alexander Landfill
Pace Project No.: 92612809
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92612809030
MW-1B
EPA 3005A
709042
EPA 6020B
709131
92612809031
MW-2
EPA 3005A
709042
EPA 6020B
709131
92612809032
MW-4R
EPA 3005A
709042
EPA 6020B
709131
92612809033
MW-10
EPA 3005A
709042
EPA 6020B
709131
92612809034
MW-9
EPA 3005A
709042
EPA 6020B
709131
92612809035
MW-1A
EPA 3005A
709042
EPA 6020B
709131
92612809036
EB
EPA 3005A
709042
EPA 6020B
709131
92612809001
MW-6
EPA 8260D
708459
92612809002
MW-5
EPA 8260D
708458
92612809003
MW-12D
EPA 8260D
708458
92612809004
MW-24
EPA 8260D
708458
92612809005
MW-26
EPA 8260D
708458
92612809006
MW-31
EPA 8260D
708458
92612809007
MW-12
EPA 8260D
708458
92612809008
MW-25
EPA 8260D
708458
92612809009
MW-27
EPA 8260D
708458
92612809010
MW-11
EPA 8260D
708458
92612809011
MW-16
EPA 8260D
708458
92612809012
MW-13
EPA 8260D
708458
92612809013
MW-14
EPA 8260D
708458
92612809014
MW-15
EPA 8260D
708458
92612809015
MW-17
EPA 8260D
708458
92612809016
MW-18
EPA 8260D
708458
92612809017
MW-19
EPA 8260D
708458
92612809018
MW-20
EPA 8260D
708458
92612809019
MW-21
EPA 8260D
708458
92612809020
MW-22
EPA 8260D
708458
92612809021
MW-23
EPA 8260D
708458
92612809022
MW-32
EPA 8260D
708459
92612809023
MW-33
EPA 8260D
708459
92612809024
MW-34
EPA 8260D
708459
92612809025
SW-3
EPA 8260D
708452
92612809026
SW-4R
EPA 8260D
708452
92612809027
SW-5
EPA 8260D
708452
92612809028
SW-6
EPA 8260D
708452
92612809029
MW-1
EPA 8260D
708979
92612809030
MW-1B
EPA 8260D
708979
92612809031
MW-2
EPA 8260D
708459
92612809032
MW-4R
EPA 8260D
708456
92612809033
MW-10
EPA 8260D
708979
92612809034
MW-9
EPA 8260D
708979
92612809035
MW-1A
EPA 8260D
708979
92612809036
EB
EPA 8260D
708979
92612809037
FB
EPA 8260D
708979
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 143 of 154

laneAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Alexander Landfill
Pace Project No.: 92612809
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92612809001
MW-6
SM
2320B-2011
708485
92612809002
MW-5
SM
2320B-2011
708485
92612809003
MW-12D
SM
2320B-2011
708485
92612809004
MW-24
SM
2320B-2011
708485
92612809005
MW-26
SM
2320B-2011
708485
92612809006
MW-31
SM
2320B-2011
708485
92612809007
MW-12
SM
2320B-2011
708485
92612809008
MW-25
SM
2320B-2011
708485
92612809009
MW-27
SM
2320B-2011
708485
92612809010
MW-11
SM
2320B-2011
708485
92612809011
MW-16
SM
2320B-2011
708485
92612809001
MW-6
SM 3500-Fe B-2011
708591
92612809002
MW-5
SM 3500-Fe B-2011
708591
92612809003
MW-12D
SM 3500-Fe B-2011
708591
92612809004
MW-24
SM 3500-Fe B-2011
708591
92612809005
MW-26
SM 3500-Fe B-2011
708591
92612809006
MW-31
SM 3500-Fe B-2011
708591
92612809007
MW-12
SM 3500-Fe B-2011
708591
92612809008
MW-25
SM 3500-Fe B-2011
708591
92612809009
MW-27
SM 3500-Fe B-2011
708591
92612809010
MW-11
SM 3500-Fe B-2011
708591
92612809011
MW-16
SM 3500-Fe B-2011
708591
92612809001
MW-6
SM 4500-S2D-2011
708449
92612809002
MW-5
SM 4500-S2D-2011
708449
92612809003
MW-12D
SM 4500-S2D-2011
708449
92612809004
MW-24
SM 4500-S2D-2011
708449
92612809005
MW-26
SM 4500-S2D-2011
708449
92612809006
MW-31
SM 4500-S2D-2011
708449
92612809007
MW-12
SM 4500-S2D-2011
708449
92612809008
MW-25
SM 4500-S2D-2011
708449
92612809009
MW-27
SM 4500-S2D-2011
708449
92612809010
MW-11
SM 4500-S2D-2011
708449
92612809011
MW-16
SM 4500-S2D-2011
708449
92612809001
MW-6
EPA 300.0 Rev 2.1 1993
708542
92612809002
MW-5
EPA 300.0 Rev 2.1 1993
708542
92612809003
MW-12D
EPA 300.0 Rev 2.1 1993
708542
92612809004
MW-24
EPA 300.0 Rev 2.1 1993
708542
92612809005
MW-26
EPA 300.0 Rev 2.1 1993
708542
92612809006
MW-31
EPA 300.0 Rev 2.1 1993
708542
92612809007
MW-12
EPA 300.0 Rev 2.1 1993
708542
92612809008
MW-25
EPA 300.0 Rev 2.1 1993
708542
92612809009
MW-27
EPA 300.0 Rev 2.1 1993
708542
92612809010
MW-11
EPA 300.0 Rev 2.1 1993
708542
92612809011
MW-16
EPA 300.0 Rev 2.1 1993
708542
92612809001
MW-6
EPA 353.2 Rev 2.0 1993
708438
92612809002
MW-5
EPA 353.2 Rev 2.0 1993
708438
92612809003
MW-12D
EPA 353.2 Rev 2.0 1993
708438
REPORT OF LABORATORY ANALYSIS
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Date: 07/19/2022 02:49 PM without the written consent of Pace Analytical Services, LLC. Page 144 of 154

lceAnalyircal
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Alexander Landfill
Pace Project No.:
92612809
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92612809004
MW-24
EPA 353.2 Rev 2.0 1993
708438
92612809005
MW-26
EPA 353.2 Rev 2.0 1993
708438
92612809006
MW-31
EPA 353.2 Rev 2.0 1993
708438
92612809007
MW-12
EPA 353.2 Rev 2.0 1993
708438
92612809008
MW-25
EPA 353.2 Rev 2.0 1993
708438
92612809009
MW-27
EPA 353.2 Rev 2.0 1993
708438
92612809010
MW-11
EPA 353.2 Rev 2.0 1993
708438
92612809011
MW-16
EPA 353.2 Rev 2.0 1993
708438
92612809001
MW-6
SM 4500-CI-E-2011
709689
92612809002
MW-5
SM 4500-CI-E-2011
709689
92612809003
MW-12D
SM 4500-CI-E-2011
709689
92612809004
MW-24
SM 4500-CI-E-2011
709689
92612809005
MW-26
SM 4500-CI-E-2011
709689
92612809006
MW-31
SM 4500-CI-E-2011
709689
92612809007
MW-12
SM 4500-CI-E-2011
709690
92612809008
MW-25
SM 4500-CI-E-2011
709690
92612809009
MW-27
SM 4500-CI-E-2011
709690
92612809010
MW-11
SM 4500-CI-E-2011
709690
92612809011
MW-16
SM 4500-CI-E-2011
709690
92612809001
MW-6
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809002
MW-5
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809003
MW-12D
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809004
MW-24
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809005
MW-26
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809006
MW-31
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809007
MW-12
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809008
MW-25
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809009
MW-27
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809010
MW-11
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809011
MW-16
SM 5220D-2011
708940
SM 5220D-2011
709076
92612809001
MW-6
SM 5310B-2014
708598
92612809002
MW-5
SM 5310B-2014
708598
92612809003
MW-12D
SM 5310B-2014
708598
92612809004
MW-24
SM 5310B-2014
708598
92612809005
MW-26
SM 5310B-2014
708598
92612809006
MW-31
SM 5310B-2014
708598
92612809007
MW-12
SM 5310B-2014
708598
92612809008
MW-25
SM 5310B-2014
708599
92612809009
MW-27
SM 5310B-2014
708599
92612809010
MW-11
SM 5310B-2014
708599
92612809011
MW-16
SM 5310B-2014
708599
92612809042
MW-12D
AM23G
745268
Date: 07/19/2022 02:49 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 145 of 154

.ir,-, 1kJJq 1"vvua vv f oample Lonaition Upon Receipt
-
Effective Date: 05/121202205/12/2022
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh[] Mechanicsville❑ Atlanta KernersvilleSample ❑
ConditionUpon Receipt —1Client Name:
MU01V21k-,.,Project {-1#: WO # : 92'.612809
Courier: ❑Fed Ex ❑U ❑USPS
❑ CommercialPace ❑Other: ❑client
Packing Material: ❑Bubble Wrap Bubble Bags ❑None Other
Thermometer;
ElIR Gun ID: �L I O U Lf
Type of Ice: Wet ❑Blue
n� r zz,1Eorrection factor.
Cooler Temp: t Add/Subtract VQ
Cooler Temp Corrected ('C1: `'S ZZ' z �3 3,
USDA Regulated Soil (06N/A, water sample) � Y f
Did samples nriginate in a quarantine zone within the United States: CA, NY, at SC
(check maps)? []yes ❑No
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (02 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match CDC?
-Includes DatelTime/ID/Analysts
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
UQ q U Z
i w-)'i i/Cad? oh_.
Ices
LINO
LIN/A
1.
i
Yes
ONO
❑N/A
2.
Yes
[]No
❑N/A
3.
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Qualtrax ID: 69614 Page i of 2 Page 146 of 154

Pace
%.uttutuuo upon mecelpr
Effective Date: 05/121202205/12/2022
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Page 147 of 154
Qualtrax ID: 69614 Page 2 of 2

..ve• �-vvva� Yv r varriVrC %QUIP RIVII IJIJUII 1' ucelpt
�' dace - � --
Effcctivo Date: 05/12/202205�12/2022
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Page 148 of 154
Qualtrax ID, 69614 Page 2 of 2

--
1 A a11r1.11C l.-vimmon upon Keceipt
;! Pace
— - -,.. ,r-fie -crrz•e: - -
Effective Date: 05/12/202205/12/2022
*Check mark top half of box if pH and/or dechlorination is verified and
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* *Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine 7
Project iWO • 92612809
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Qualtrax ID: 69614 Page 149 of 154
Page 2of2

/ QC — - _ ._._. —... ..".. , VW-LJ vV r_00111ple t.Uttultttrli tiluurt McCUIPT
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Effeclive Date: 051121202205/12/2022
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Page 150 of 154
QUaltrax ID: 69614 Page 2 of 2

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Page 154 of 154

Appendix C
Statistical Analyses Calculations

Alexander Co CDLF over MSWLF
Cumulative VOCs
Time -Series Graph of AOC (41 B)
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 1

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: AOC (MW-1 B)
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
36.8
84.83
-48.03
0
1
33.76
84.83
-51.07
0
2
41.36
84.83
-43.47
0
3
35.7
84.83
-49.13
0
4
44.37
84.83
-40.46
0
5
32.61
84.83
-52.22
0
6
42.67
84.83
-42.16
0
7
32.08
84.83
-52.75
0
8
21.71
84.83
-63.12
0
9
17.19
84.83
-67.64
0
10
16.35
84.83
-68.48
0
11
21.87
84.83
-62.96
0
12
13.66
84.83
-71.17
0
13
8.45
84.83
-76.38
0
14
13.51
84.83
-71.32
0
15
8.35
84.83
-76.48
0
16
10.26
84.83
-74.57
0
17
7.2
84.83
-77.63
0
18
2.31
84.83
-82.52
0
19
6.28
84.83
-78.55
0
20
4.84
84.83
-79.99
0
21
3.75
84.83
-81.08
0
22
0.85
84.83
-83.98
0
23
0.6
84.83
-84.23
0
24
0.78
84.83
-84.05
0
25
0.69
84.83
-84.14
0
26
33.76 36.8
-3.04
0 27
41.36 36.8
4.56
1 27
35.7 36.8
-1.1
1 28
44.37 36.8
7.57
2 28
32.61 36.8
-4.19
2 29
42.67 36.8
5.87
3 29
32.08 36.8
-4.72
3 30
21.71 36.8
-15.09
3 31
17.19 36.8
-19.61
3 32
16.35 36.8
-20.45
3 33
21.87 36.8
-14.93
3 34
13.66 36.8
-23.14
3 35
8.45 36.8
-28.35
3 36
13.51 36.8
-23.29
3 37
8.35 36.8
-28.45
3 38
10.26 36.8
-26.54
3 39
7.2 36.8
-29.6
3 40
2.31 36.8
-34.49
3 41
6.28 36.8
-30.52
3 42
4.84 36.8
-31.96
3 43
3.75 36.8
-33.05
3 44
0.85 36.8
-35.95
3 45
0.6 36.8
-36.2
3 46
0.78 36.8
-36.02
3 47
0.69 36.8
-36.11
3 48
41.36 33.76
7.6
4 48
35.7 33.76
1.94
5 48
44.37 33.76
10.61
6 48
32.61 33.76
-1.15
6 49
42.67 33.76
8.91
7 49
32.08 33.76
-1.68
7 50
21.71 33.76
-12.05
7 51
17.19 33.76
-16.57
7 52
16.35 33.76
-17.41
7 53
21.87 33.76
-11.89
7 54
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 2

Alexander Co CDLF over MSWLF
13.66 33.76
-20.1
7 55
8.45 33.76
-25.31
7 56
13.51 33.76
-20.25
7 57
8.35 33.76
-25.41
7 58
10.26 33.76
-23.5
7 59
7.2 33.76
-26.56
7 60
2.31 33.76
-31.45
7 61
6.28 33.76
-27.48
7 62
4.84 33.76
-28.92
7 63
3.75 33.76
-30.01
7 64
0.85 33.76
-32.91
7 65
0.6 33.76
-33.16
7 66
0.78 33.76
-32.98
7 67
0.69 33.76
-33.07
7 68
35.7 41.36
-5.66
7 69
44.37 41.36
3.01
8 69
32.61 41.36
-8.75
8 70
42.67 41.36
1.31
9 70
32.08 41.36
-9.28
9 71
21.71 41.36
-19.65
9 72
17.19 41.36
-24.17
9 73
16.35 41.36
-25.01
9 74
21.87 41.36
-19.49
9 75
13.66 41.36
-27.7
9 76
8.45 41.36
-32.91
9 77
13.51 41.36
-27.85
9 78
8.35 41.36
-33.01
9 79
10.26 41.36
-31.1
9 80
7.2 41.36
-34.16
9 81
2.31 41.36
-39.05
9 82
6.28 41.36
-35.08
9 83
4.84 41.36
-36.52
9 84
3.75 41.36
-37.61
9 85
0.85 41.36
-40.51
9 86
0.6 41.36
-40.76
9 87
0.78 41.36
-40.58
9 88
0.69 41.36
-40.67
9 89
44.37 35.7
8.67
10 89
32.61 35.7
-3.09
10 90
42.67 35.7
6.97
11 90
32.08 35.7
-3.62
11 91
21.71 35.7
-13.99
11 92
17.19 35.7
-18.51
11 93
16.35 35.7
-19.35
11 94
21.87 35.7
-13.83
11 95
13.66 35.7
-22.04
11 96
8.45 35.7
-27.25
11 97
13.51 35.7
-22.19
11 98
8.35 35.7
-27.35
11 99
10.26 35.7
-25.44
11 100
7.2 35.7
-28.5
11 101
2.31 35.7
-33.39
11 102
6.28 35.7
-29.42
11 103
4.84 35.7
-30.86
11 104
3.75 35.7
-31.95
11 105
0.85 35.7
-34.85
11 106
0.6 35.7
-35.1
11 107
0.78 35.7
-34.92
11 108
0.69 35.7
-35.01
11 109
32.61 44.37
-11.76
11 110
42.67 44.37
-1.7
11 111
32.08 44.37
-12.29
11 112
21.71 44.37
-22.66
11 113
17.19 44.37
-27.18
11 114
16.35 44.37
-28.02
11 115
21.87 44.37
-22.5
11 116
13.66 44.37
-30.71
11 117
8.45 44.37
-35.92
11 118
13.51 44.37
-30.86
11 119
8.35 44.37
-36.02
11 120
10.26 44.37
-34.11
11 121
7.2 44.37
-37.17
11 122
2.31 44.37
-42.06
11 123
6.28 44.37
-38.09
11 124
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 3

Alexander Co CDLF over MSWLF
4.84
44.37
-39.53
11
125
3.75
44.37
-40.62
11
126
0.85
44.37
-43.52
11
127
0.6
44.37
-43.77
11
128
0.78
44.37
-43.59
11
129
0.69
44.37
-43.68
11
130
42.67
32.61
10.06
12
130
32.08
32.61
-0.53
12
131
21.71
32.61
-10.9
12
132
17.19
32.61
-15.42
12
133
16.35
32.61
-16.26
12
134
21.87
32.61
-10.74
12
135
13.66
32.61
-18.95
12
136
8.45
32.61
-24.16
12
137
13.51
32.61
-19.1
12
138
8.35
32.61
-24.26
12
139
10.26
32.61
-22.35
12
140
7.2
32.61
-25.41
12
141
2.31
32.61
-30.3
12
142
6.28
32.61
-26.33
12
143
4.84
32.61
-27.77
12
144
3.75
32.61
-28.86
12
145
0.85
32.61
-31.76
12
146
0.6
32.61
-32.01
12
147
0.78
32.61
-31.83
12
148
0.69
32.61
-31.92
12
149
32.08
42.67
-10.59
12
150
21.71
42.67
-20.96
12
151
17.19
42.67
-25.48
12
152
16.35
42.67
-26.32
12
153
21.87
42.67
-20.8
12
154
13.66
42.67
-29.01
12
155
8.45
42.67
-34.22
12
156
13.51
42.67
-29.16
12
157
8.35
42.67
-34.32
12
158
10.26
42.67
-32.41
12
159
7.2
42.67
-35.47
12
160
2.31
42.67
-40.36
12
161
6.28
42.67
-36.39
12
162
4.84
42.67
-37.83
12
163
3.75
42.67
-38.92
12
164
0.85
42.67
-41.82
12
165
0.6
42.67
-42.07
12
166
0.78
42.67
-41.89
12
167
0.69
42.67
-41.98
12
168
21.71
32.08
-10.37
12
169
17.19
32.08
-14.89
12
170
16.35
32.08
-15.73
12
171
21.87
32.08
-10.21
12
172
13.66
32.08
-18.42
12
173
8.45
32.08
-23.63
12
174
13.51
32.08
-18.57
12
175
8.35
32.08
-23.73
12
176
10.26
32.08
-21.82
12
177
7.2
32.08
-24.88
12
178
2.31
32.08
-29.77
12
179
6.28
32.08
-25.8
12
180
4.84
32.08
-27.24
12
181
3.75
32.08
-28.33
12
182
0.85
32.08
-31.23
12
183
0.6
32.08
-31.48
12
184
0.78
32.08
-31.3
12
185
0.69
32.08
-31.39
12
186
17.19
21.71
-4.52
12
187
16.35
21.71
-5.36
12
188
21.87
21.71
0.16
13
188
13.66
21.71
-8.05
13
189
8.45
21.71
-13.26
13
190
13.51
21.71
-8.2
13
191
8.35
21.71
-13.36
13
192
10.26
21.71
-11.45
13
193
7.2
21.71
-14.51
13
194
2.31
21.71
-19.4
13
195
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 4

Alexander Co CDLF over MSWLF
6.28
21.71
-15.43
13
196
4.84
21.71
-16.87
13
197
3.75
21.71
-17.96
13
198
0.85
21.71
-20.86
13
199
0.6
21.71
-21.11
13
200
0.78
21.71
-20.93
13
201
0.69
21.71
-21.02
13
202
16.35
17.19
-0.84
13
203
21.87
17.19
4.68
14
203
13.66
17.19
-3.53
14
204
8.45
17.19
-8.74
14
205
13.51
17.19
-3.68
14
206
8.35
17.19
-8.84
14
207
10.26
17.19
-6.93
14
208
7.2
17.19
-9.99
14
209
2.31
17.19
-14.88
14
210
6.28
17.19
-10.91
14
211
4.84
17.19
-12.35
14
212
3.75
17.19
-13.44
14
213
0.85
17.19
-16.34
14
214
0.6
17.19
-16.59
14
215
0.78
17.19
-16.41
14
216
0.69
17.19
-16.5
14
217
21.87
16.35
5.52
15
217
13.66
16.35
-2.69
15
218
8.45
16.35
-7.9
15
219
13.51
16.35
-2.84
15
220
8.35
16.35
-8
15
221
10.26
16.35
-6.09
15
222
7.2
16.35
-9.15
15
223
2.31
16.35
-14.04
15
224
6.28
16.35
-10.07
15
225
4.84
16.35
-11.51
15
226
3.75
16.35
-12.6
15
227
0.85
16.35
-15.5
15
228
0.6
16.35
-15.75
15
229
0.78
16.35
-15.57
15
230
0.69
16.35
-15.66
15
231
13.66
21.87
-8.21
15
232
8.45
21.87
-13.42
15
233
13.51
21.87
-8.36
15
234
8.35
21.87
-13.52
15
235
10.26
21.87
-11.61
15
236
7.2
21.87
-14.67
15
237
2.31
21.87
-19.56
15
238
6.28
21.87
-15.59
15
239
4.84
21.87
-17.03
15
240
3.75
21.87
-18.12
15
241
0.85
21.87
-21.02
15
242
0.6
21.87
-21.27
15
243
0.78
21.87
-21.09
15
244
0.69
21.87
-21.18
15
245
8.45
13.66
-5.21
15
246
13.51
13.66
-0.15
15
247
8.35
13.66
-5.31
15
248
10.26
13.66
-3.4
15
249
7.2
13.66
-6.46
15
250
2.31
13.66
-11.35
15
251
6.28
13.66
-7.38
15
252
4.84
13.66
-8.82
15
253
3.75
13.66
-9.91
15
254
0.85
13.66
-12.81
15
255
0.6
13.66
-13.06
15
256
0.78
13.66
-12.88
15
257
0.69
13.66
-12.97
15
258
13.51
8.45
5.06
16
258
8.35
8.45
-0.1
16
259
10.26
8.45
1.81
17
259
7.2
8.45
-1.25
17
260
2.31
8.45
-6.14
17
261
6.28
8.45
-2.17
17
262
4.84
8.45
-3.61
17
263
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 5

Alexander Co CDLF over MSWLF
3.75
8.45
-4.7
17
264
0.85
8.45
-7.6
17
265
0.6
8.45
-7.85
17
266
0.78
8.45
-7.67
17
267
0.69
8.45
-7.76
17
268
8.35
13.51
-5.16
17
269
10.26
13.51
-3.25
17
270
7.2
13.51
-6.31
17
271
2.31
13.51
-11.2
17
272
6.28
13.51
-7.23
17
273
4.84
13.51
-8.67
17
274
3.75
13.51
-9.76
17
275
0.85
13.51
-12.66
17
276
0.6
13.51
-12.91
17
277
0.78
13.51
-12.73
17
278
0.69
13.51
-12.82
17
279
10.26
8.35
1.91
18
279
7.2
8.35
-1.15
18
280
2.31
8.35
-6.04
18
281
6.28
8.35
-2.07
18
282
4.84
8.35
-3.51
18
283
3.75
8.35
-4.6
18
284
0.85
8.35
-7.5
18
285
0.6
8.35
-7.75
18
286
0.78
8.35
-7.57
18
287
0.69
8.35
-7.66
18
288
7.2
10.26
-3.06
18
289
2.31
10.26
-7.95
18
290
6.28
10.26
-3.98
18
291
4.84
10.26
-5.42
18
292
3.75
10.26
-6.51
18
293
0.85
10.26
-9.41
18
294
0.6
10.26
-9.66
18
295
0.78
10.26
-9.48
18
296
0.69
10.26
-9.57
18
297
2.31
7.2
-4.89
18
298
6.28
7.2
-0.92
18
299
4.84
7.2
-2.36
18
300
3.75
7.2
-3.45
18
301
0.85
7.2
-6.35
18
302
0.6
7.2
-6.6
18
303
0.78
7.2
-6.42
18
304
0.69
7.2
-6.51
18
305
6.28
2.31
3.97
19
305
4.84
2.31
2.53
20
305
3.75
2.31
1.44
21
305
0.85
2.31
-1.46
21
306
0.6
2.31
-1.71
21
307
0.78
2.31
-1.53
21
308
0.69
2.31
-1.62
21
309
4.84
6.28
-1.44
21
310
3.75
6.28
-2.53
21
311
0.85
6.28
-5.43
21
312
0.6
6.28
-5.68
21
313
0.78
6.28
-5.5
21
314
0.69
6.28
-5.59
21
315
3.75
4.84
-1.09
21
316
0.85
4.84
-3.99
21
317
0.6
4.84
-4.24
21
318
0.78
4.84
-4.06
21
319
0.69
4.84
-4.15
21
320
0.85
3.75
-2.9
21
321
0.6
3.75
-3.15
21
322
0.78
3.75
-2.97
21
323
0.69
3.75
-3.06
21
324
0.6
0.85
-0.25
21
325
0.78
0.85
-0.07
21
326
0.69
0.85
-0.16
21
327
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 6

Alexander Co CDLF over MSWLF
0.78 0.6 0.18 22 327
0.69 0.6 0.09 23 327
0.69 0.78 -0.09 23 328
S Statistic = 23 - 328 = -305
Tied GroulValue Members
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
A=0
B=0
C=0
D=0
E=0
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2301
Z-Score =-6.33746
Comparison Level at 95% confidence level =-1.65463 (downward trend)
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 7

Alexander Co CDLF over MSWLF
Cumulative VOCs
Time -Series Graph of AOC (416�
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 8

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: AOC (MW-16)
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
58.96
74.55
-15.59
0
1
63.2
74.55
-11.35
0
2
75.84
74.55
1.29
1
2
70.57
74.55
-3.98
1
3
79.21
74.55
4.66
2
3
62.32
74.55
-12.23
2
4
59.16
74.55
-15.39
2
5
69.08
74.55
-5.47
2
6
58.34
74.55
-16.21
2
7
71.17
74.55
-3.38
2
8
89.27
74.55
14.72
3
8
76.95
74.55
2.4
4
8
67.17
74.55
-7.38
4
9
74.17
74.55
-0.38
4
10
72.75
74.55
-1.8
4
11
55.67
74.55
-18.88
4
12
50.36
74.55
-24.19
4
13
58.09
74.55
-16.46
4
14
49.71
74.55
-24.84
4
15
63.46
74.55
-11.09
4
16
56.66
74.55
-17.89
4
17
38.96
74.55
-35.59
4
18
3.76
74.55
-70.79
4
19
11.61
74.55
-62.94
4
20
12.44
74.55
-62.11
4
21
9.76
74.55
-64.79
4
22
63.2 58.96
4.24
5 22
75.84 58.96
16.88
6 22
70.57 58.96
11.61
7 22
79.21 58.96
20.25
8 22
62.32 58.96
3.36
9 22
59.16 58.96
0.2
10 22
69.08 58.96
10.12
11 22
58.34 58.96
-0.62
11 23
71.17 58.96
12.21
12 23
89.27 58.96
30.31
13 23
76.95 58.96
17.99
14 23
67.17 58.96
8.21
15 23
74.17 58.96
15.21
16 23
72.75 58.96
13.79
17 23
55.67 58.96
-3.29
17 24
50.36 58.96
-8.6
17 25
58.09 58.96
-0.87
17 26
49.71 58.96
-9.25
17 27
63.46 58.96
4.5
18 27
56.66 58.96
-2.3
18 28
38.96 58.96
-20
18 29
3.76 58.96
-55.2
18 30
11.61 58.96
-47.35
18 31
12.44 58.96
-46.52
18 32
9.76 58.96
-49.2
18 33
75.84 63.2
12.64
19 33
70.57 63.2
7.37
20 33
79.21 63.2
16.01
21 33
62.32 63.2
-0.88
21 34
59.16 63.2
-4.04
21 35
69.08 63.2
5.88
22 35
58.34 63.2
-4.86
22 36
71.17 63.2
7.97
23 36
89.27 63.2
26.07
24 36
76.95 63.2
13.75
25 36
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 9

Alexander Co CDLF over MSWLF
67.17 63.2
3.97
26 36
74.17 63.2
10.97
27 36
72.75 63.2
9.55
28 36
55.67 63.2
-7.53
28 37
50.36 63.2
-12.84
28 38
58.09 63.2
-5.11
28 39
49.71 63.2
-13.49
28 40
63.46 63.2
0.26
29 40
56.66 63.2
-6.54
29 41
38.96 63.2
-24.24
29 42
3.76 63.2
-59.44
29 43
11.61 63.2
-51.59
29 44
12.44 63.2
-50.76
29 45
9.76 63.2
-53.44
29 46
70.57 75.84
-5.27
29 47
79.21 75.84
3.37
30 47
62.32 75.84
-13.52
30 48
59.16 75.84
-16.68
30 49
69.08 75.84
-6.76
30 50
58.34 75.84
-17.5
30 51
71.17 75.84
-4.67
30 52
89.27 75.84
13.43
31 52
76.95 75.84
1.11
32 52
67.17 75.84
-8.67
32 53
74.17 75.84
-1.67
32 54
72.75 75.84
-3.09
32 55
55.67 75.84
-20.17
32 56
50.36 75.84
-25.48
32 57
58.09 75.84
-17.75
32 58
49.71 75.84
-26.13
32 59
63.46 75.84
-12.38
32 60
56.66 75.84
-19.18
32 61
38.96 75.84
-36.88
32 62
3.76 75.84
-72.08
32 63
11.61 75.84
-64.23
32 64
12.44 75.84
-63.4
32 65
9.76 75.84
-66.08
32 66
79.21 70.57
8.64
33 66
62.32 70.57
-8.25
33 67
59.16 70.57
-11.41
33 68
69.08 70.57
-1.49
33 69
58.34 70.57
-12.23
33 70
71.17 70.57
0.6
34 70
89.27 70.57
18.7
35 70
76.95 70.57
6.38
36 70
67.17 70.57
-3.4
36 71
74.17 70.57
3.6
37 71
72.75 70.57
2.18
38 71
55.67 70.57
-14.9
38 72
50.36 70.57
-20.21
38 73
58.09 70.57
-12.48
38 74
49.71 70.57
-20.86
38 75
63.46 70.57
-7.11
38 76
56.66 70.57
-13.91
38 77
38.96 70.57
-31.61
38 78
3.76 70.57
-66.81
38 79
11.61 70.57
-58.96
38 80
12.44 70.57
-58.13
38 81
9.76 70.57
-60.81
38 82
62.32 79.21
-16.89
38 83
59.16 79.21
-20.05
38 84
69.08 79.21
-10.13
38 85
58.34 79.21
-20.87
38 86
71.17 79.21
-8.04
38 87
89.27 79.21
10.06
39 87
76.95 79.21
-2.26
39 88
67.17 79.21
-12.04
39 89
74.17 79.21
-5.04
39 90
72.75 79.21
-6.46
39 91
55.67 79.21
-23.54
39 92
50.36 79.21
-28.85
39 93
58.09 79.21
-21.12
39 94
49.71 79.21
-29.5
39 95
63.46 79.21
-15.75
39 96
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 10

Alexander Co CDLF over MSWLF
56.66
79.21
-22.55
39
97
38.96
79.21
-40.25
39
98
3.76
79.21
-75.45
39
99
11.61
79.21
-67.6
39
100
12.44
79.21
-66.77
39
101
9.76
79.21
-69.45
39
102
59.16
62.32
-3.16
39
103
69.08
62.32
6.76
40
103
58.34
62.32
-3.98
40
104
71.17
62.32
8.85
41
104
89.27
62.32
26.95
42
104
76.95
62.32
14.63
43
104
67.17
62.32
4.85
44
104
74.17
62.32
11.85
45
104
72.75
62.32
10.43
46
104
55.67
62.32
-6.65
46
105
50.36
62.32
-11.96
46
106
58.09
62.32
-4.23
46
107
49.71
62.32
-12.61
46
108
63.46
62.32
1.14
47
108
56.66
62.32
-5.66
47
109
38.96
62.32
-23.36
47
110
3.76
62.32
-58.56
47
111
11.61
62.32
-50.71
47
112
12.44
62.32
-49.88
47
113
9.76
62.32
-52.56
47
114
69.08
59.16
9.92
48
114
58.34
59.16
-0.82
48
115
71.17
59.16
12.01
49
115
89.27
59.16
30.11
50
115
76.95
59.16
17.79
51
115
67.17
59.16
8.01
52
115
74.17
59.16
15.01
53
115
72.75
59.16
13.59
54
115
55.67
59.16
-3.49
54
116
50.36
59.16
-8.8
54
117
58.09
59.16
-1.07
54
118
49.71
59.16
-9.45
54
119
63.46
59.16
4.3
55
119
56.66
59.16
-2.5
55
120
38.96
59.16
-20.2
55
121
3.76
59.16
-55.4
55
122
11.61
59.16
-47.55
55
123
12.44
59.16
-46.72
55
124
9.76
59.16
-49.4
55
125
58.34
69.08
-10.74
55
126
71.17
69.08
2.09
56
126
89.27
69.08
20.19
57
126
76.95
69.08
7.87
58
126
67.17
69.08
-1.91
58
127
74.17
69.08
5.09
59
127
72.75
69.08
3.67
60
127
55.67
69.08
-13.41
60
128
50.36
69.08
-18.72
60
129
58.09
69.08
-10.99
60
130
49.71
69.08
-19.37
60
131
63.46
69.08
-5.62
60
132
56.66
69.08
-12.42
60
133
38.96
69.08
-30.12
60
134
3.76
69.08
-65.32
60
135
11.61
69.08
-57.47
60
136
12.44
69.08
-56.64
60
137
9.76
69.08
-59.32
60
138
71.17
58.34
12.83
61
138
89.27
58.34
30.93
62
138
76.95
58.34
18.61
63
138
67.17
58.34
8.83
64
138
74.17
58.34
15.83
65
138
72.75
58.34
14.41
66
138
55.67
58.34
-2.67
66
139
50.36
58.34
-7.98
66
140
58.09
58.34
-0.25
66
141
49.71
58.34
-8.63
66
142
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 11

Alexander Co CDLF over MSWLF
63.46
58.34
5.12
67
142
56.66
58.34
-1.68
67
143
38.96
58.34
-19.38
67
144
3.76
58.34
-54.58
67
145
11.61
58.34
-46.73
67
146
12.44
58.34
-45.9
67
147
9.76
58.34
-48.58
67
148
89.27
71.17
18.1
68
148
76.95
71.17
5.78
69
148
67.17
71.17
-4
69
149
74.17
71.17
3
70
149
72.75
71.17
1.58
71
149
55.67
71.17
-15.5
71
150
50.36
71.17
-20.81
71
151
58.09
71.17
-13.08
71
152
49.71
71.17
-21.46
71
153
63.46
71.17
-7.71
71
154
56.66
71.17
-14.51
71
155
38.96
71.17
-32.21
71
156
3.76
71.17
-67.41
71
157
11.61
71.17
-59.56
71
158
12.44
71.17
-58.73
71
159
9.76
71.17
-61.41
71
160
76.95
89.27
-12.32
71
161
67.17
89.27
-22.1
71
162
74.17
89.27
-15.1
71
163
72.75
89.27
-16.52
71
164
55.67
89.27
-33.6
71
165
50.36
89.27
-38.91
71
166
58.09
89.27
-31.18
71
167
49.71
89.27
-39.56
71
168
63.46
89.27
-25.81
71
169
56.66
89.27
-32.61
71
170
38.96
89.27
-50.31
71
171
3.76
89.27
-85.51
71
172
11.61
89.27
-77.66
71
173
12.44
89.27
-76.83
71
174
9.76
89.27
-79.51
71
175
67.17
76.95
-9.78
71
176
74.17
76.95
-2.78
71
177
72.75
76.95
-4.2
71
178
55.67
76.95
-21.28
71
179
50.36
76.95
-26.59
71
180
58.09
76.95
-18.86
71
181
49.71
76.95
-27.24
71
182
63.46
76.95
-13.49
71
183
56.66
76.95
-20.29
71
184
38.96
76.95
-37.99
71
185
3.76
76.95
-73.19
71
186
11.61
76.95
-65.34
71
187
12.44
76.95
-64.51
71
188
9.76
76.95
-67.19
71
189
74.17
67.17
7
72
189
72.75
67.17
5.58
73
189
55.67
67.17
-11.5
73
190
50.36
67.17
-16.81
73
191
58.09
67.17
-9.08
73
192
49.71
67.17
-17.46
73
193
63.46
67.17
-3.71
73
194
56.66
67.17
-10.51
73
195
38.96
67.17
-28.21
73
196
3.76
67.17
-63.41
73
197
11.61
67.17
-55.56
73
198
12.44
67.17
-54.73
73
199
9.76
67.17
-57.41
73
200
72.75
74.17
-1.42
73
201
55.67
74.17
-18.5
73
202
50.36
74.17
-23.81
73
203
58.09
74.17
-16.08
73
204
49.71
74.17
-24.46
73
205
63.46
74.17
-10.71
73
206
56.66
74.17
-17.51
73
207
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 12

Alexander Co CDLF over MSWLF
38.96
74.17
-35.21
73
208
3.76
74.17
-70.41
73
209
11.61
74.17
-62.56
73
210
12.44
74.17
-61.73
73
211
9.76
74.17
-64.41
73
212
55.67
72.75
-17.08
73
213
50.36
72.75
-22.39
73
214
58.09
72.75
-14.66
73
215
49.71
72.75
-23.04
73
216
63.46
72.75
-9.29
73
217
56.66
72.75
-16.09
73
218
38.96
72.75
-33.79
73
219
3.76
72.75
-68.99
73
220
11.61
72.75
-61.14
73
221
12.44
72.75
-60.31
73
222
9.76
72.75
-62.99
73
223
50.36
55.67
-5.31
73
224
58.09
55.67
2.42
74
224
49.71
55.67
-5.96
74
225
63.46
55.67
7.79
75
225
56.66
55.67
0.99
76
225
38.96
55.67
-16.71
76
226
3.76
55.67
-51.91
76
227
11.61
55.67
-44.06
76
228
12.44
55.67
-43.23
76
229
9.76
55.67
-45.91
76
230
58.09
50.36
7.73
77
230
49.71
50.36
-0.65
77
231
63.46
50.36
13.1
78
231
56.66
50.36
6.3
79
231
38.96
50.36
-11.4
79
232
3.76
50.36
-46.6
79
233
11.61
50.36
-38.75
79
234
12.44
50.36
-37.92
79
235
9.76
50.36
-40.6
79
236
49.71
58.09
-8.38
79
237
63.46
58.09
5.37
80
237
56.66
58.09
-1.43
80
238
38.96
58.09
-19.13
80
239
3.76
58.09
-54.33
80
240
11.61
58.09
-46.48
80
241
12.44
58.09
-45.65
80
242
9.76
58.09
-48.33
80
243
63.46
49.71
13.75
81
243
56.66
49.71
6.95
82
243
38.96
49.71
-10.75
82
244
3.76
49.71
-45.95
82
245
11.61
49.71
-38.1
82
246
12.44
49.71
-37.27
82
247
9.76
49.71
-39.95
82
248
56.66
63.46
-6.8
82
249
38.96
63.46
-24.5
82
250
3.76
63.46
-59.7
82
251
11.61
63.46
-51.85
82
252
12.44
63.46
-51.02
82
253
9.76
63.46
-53.7
82
254
38.96
56.66
-17.7
82
255
3.76
56.66
-52.9
82
256
11.61
56.66
-45.05
82
257
12.44
56.66
-44.22
82
258
9.76
56.66
-46.9
82
259
3.76
38.96
-35.2
82
260
11.61
38.96
-27.35
82
261
12.44
38.96
-26.52
82
262
9.76
38.96
-29.2
82
263
11.61
3.76
7.85
83
263
12.44
3.76
8.68
84
263
9.76
3.76
6
85
263
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 13

Alexander Co CDLF over MSWLF
12.44 11.61 0.83 86 263
9.76 11.61 -1.85 86 264
9.76 12.44 -2.68 86 265
S Statistic = 86 - 265 = -179
Tied GroulValue Members
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
A=0
B=0
C=0
D=0
E=0
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2301
Z-Score =-3.71075
Comparison Level at 95% confidence level =-1.65463 (downward trend)
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 14

Alexander Co CDLF over MSWLF
Cumulative VOCs
Time•Series Graph of AOC (&N2
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 15

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: AOC (MW-24)
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
43
63.53
-20.53
0
1
32.22
63.53
-31.31
0
2
76.57
63.53
13.04
1
2
51.69
63.53
-11.84
1
3
68.44
63.53
4.91
2
3
55.065
63.53
-8.465
2
4
61.89
63.53
-1.64
2
5
58.98
63.53
-4.55
2
6
49.41
63.53
-14.12
2
7
62.79
63.53
-0.74
2
8
54.44
63.53
-9.09
2
9
60.12
63.53
-3.41
2
10
40.99
63.53
-22.54
2
11
32.385
63.53
-31.145
2
12
53.78
63.53
-9.75
2
13
45.88
63.53
-17.65
2
14
42.54
63.53
-20.99
2
15
23.82
63.53
-39.71
2
16
19.82
63.53
-43.71
2
17
17.85
63.53
-45.68
2
18
37.48
63.53
-26.05
2
19
21.58
63.53
-41.95
2
20
4.3
63.53
-59.23
2
21
3.38
63.53
-60.15
2
22
3.38
63.53
-60.15
2
23
3.72
63.53
-59.81
2
24
32.22 43
-10.78
2 25
76.57 43
33.57
3 25
51.69 43
8.69
4 25
68.44 43
25.44
5 25
55.065 43
12.065
6 25
61.89 43
18.89
7 25
58.98 43
15.98
8 25
49.41 43
6.41
9 25
62.79 43
19.79
10 25
54.44 43
11.44
11 25
60.12 43
17.12
12 25
40.99 43
-2.01
12 26
32.385 43
-10.615
12 27
53.78 43
10.78
13 27
45.88 43
2.88
14 27
42.54 43
-0.46
14 28
23.82 43
-19.18
14 29
19.82 43
-23.18
14 30
17.85 43
-25.15
14 31
37.48 43
-5.52
14 32
21.58 43
-21.42
14 33
4.3 43
-38.7
14 34
3.38 43
-39.62
14 35
3.38 43
-39.62
14 36
3.72 43
-39.28
14 37
76.57 32.22
44.35
15 37
51.69 32.22
19.47
16 37
68.44 32.22
36.22
17 37
55.065 32.22
22.845
18 37
61.89 32.22
29.67
19 37
58.98 32.22
26.76
20 37
49.41 32.22
17.19
21 37
62.79 32.22
30.57
22 37
54.44 32.22
22.22
23 37
60.12 32.22
27.9
24 37
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 16

Alexander Co CDLF over MSWLF
40.99
32.22
8.77
25
37
32.385
32.22
0.165
26
37
53.78
32.22
21.56
27
37
45.88
32.22
13.66
28
37
42.54
32.22
10.32
29
37
23.82
32.22
-8.4
29
38
19.82
32.22
-12.4
29
39
17.85
32.22
-14.37
29
40
37.48
32.22
5.26
30
40
21.58
32.22
-10.64
30
41
4.3
32.22
-27.92
30
42
3.38
32.22
-28.84
30
43
3.38
32.22
-28.84
30
44
3.72
32.22
-28.5
30
45
51.69
76.57
-24.88
30
46
68.44
76.57
-8.13
30
47
55.065
76.57
-21.505
30
48
61.89
76.57
-14.68
30
49
58.98
76.57
-17.59
30
50
49.41
76.57
-27.16
30
51
62.79
76.57
-13.78
30
52
54.44
76.57
-22.13
30
53
60.12
76.57
-16.45
30
54
40.99
76.57
-35.58
30
55
32.385
76.57
-44.185
30
56
53.78
76.57
-22.79
30
57
45.88
76.57
-30.69
30
58
42.54
76.57
-34.03
30
59
23.82
76.57
-52.75
30
60
19.82
76.57
-56.75
30
61
17.85
76.57
-58.72
30
62
37.48
76.57
-39.09
30
63
21.58
76.57
-54.99
30
64
4.3
76.57
-72.27
30
65
3.38
76.57
-73.19
30
66
3.38
76.57
-73.19
30
67
3.72
76.57
-72.85
30
68
68.44
51.69
16.75
31
68
55.065
51.69
3.375
32
68
61.89
51.69
10.2
33
68
58.98
51.69
7.29
34
68
49.41
51.69
-2.28
34
69
62.79
51.69
11.1
35
69
54.44
51.69
2.75
36
69
60.12
51.69
8.43
37
69
40.99
51.69
-10.7
37
70
32.385
51.69
-19.305
37
71
53.78
51.69
2.09
38
71
45.88
51.69
-5.81
38
72
42.54
51.69
-9.15
38
73
23.82
51.69
-27.87
38
74
19.82
51.69
-31.87
38
75
17.85
51.69
-33.84
38
76
37.48
51.69
-14.21
38
77
21.58
51.69
-30.11
38
78
4.3
51.69
-47.39
38
79
3.38
51.69
-48.31
38
80
3.38
51.69
-48.31
38
81
3.72
51.69
-47.97
38
82
55.065
68.44
-13.375
38
83
61.89
68.44
-6.55
38
84
58.98
68.44
-9.46
38
85
49.41
68.44
-19.03
38
86
62.79
68.44
-5.65
38
87
54.44
68.44
-14
38
88
60.12
68.44
-8.32
38
89
40.99
68.44
-27.45
38
90
32.385
68.44
-36.055
38
91
53.78
68.44
-14.66
38
92
45.88
68.44
-22.56
38
93
42.54
68.44
-25.9
38
94
23.82
68.44
-44.62
38
95
19.82
68.44
-48.62
38
96
17.85
68.44
-50.59
38
97
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 17

Alexander Co CDLF over MSWLF
37.48
68.44
-30.96
38
98
21.58
68.44
-46.86
38
99
4.3
68.44
-64.14
38
100
3.38
68.44
-65.06
38
101
3.38
68.44
-65.06
38
102
3.72
68.44
-64.72
38
103
61.89
55.065
6.825
39
103
58.98
55.065
3.915
40
103
49.41
55.065
-5.655
40
104
62.79
55.065
7.725
41
104
54.44
55.065
-0.625
41
105
60.12
55.065
5.055
42
105
40.99
55.065
-14.075
42
106
32.385
55.065
-22.68
42
107
53.78
55.065
-1.285
42
108
45.88
55.065
-9.185
42
109
42.54
55.065
-12.525
42
110
23.82
55.065
-31.245
42
111
19.82
55.065
-35.245
42
112
17.85
55.065
-37.215
42
113
37.48
55.065
-17.585
42
114
21.58
55.065
-33.485
42
115
4.3
55.065
-50.765
42
116
3.38
55.065
-51.685
42
117
3.38
55.065
-51.685
42
118
3.72
55.065
-51.345
42
119
58.98
61.89
-2.91
42
120
49.41
61.89
-12.48
42
121
62.79
61.89
0.9
43
121
54.44
61.89
-7.45
43
122
60.12
61.89
-1.77
43
123
40.99
61.89
-20.9
43
124
32.385
61.89
-29.505
43
125
53.78
61.89
-8.11
43
126
45.88
61.89
-16.01
43
127
42.54
61.89
-19.35
43
128
23.82
61.89
-38.07
43
129
19.82
61.89
-42.07
43
130
17.85
61.89
-44.04
43
131
37.48
61.89
-24.41
43
132
21.58
61.89
-40.31
43
133
4.3
61.89
-57.59
43
134
3.38
61.89
-58.51
43
135
3.38
61.89
-58.51
43
136
3.72
61.89
-58.17
43
137
49.41
58.98
-9.57
43
138
62.79
58.98
3.81
44
138
54.44
58.98
-4.54
44
139
60.12
58.98
1.14
45
139
40.99
58.98
-17.99
45
140
32.385
58.98
-26.595
45
141
53.78
58.98
-5.2
45
142
45.88
58.98
-13.1
45
143
42.54
58.98
-16.44
45
144
23.82
58.98
-35.16
45
145
19.82
58.98
-39.16
45
146
17.85
58.98
-41.13
45
147
37.48
58.98
-21.5
45
148
21.58
58.98
-37.4
45
149
4.3
58.98
-54.68
45
150
3.38
58.98
-55.6
45
151
3.38
58.98
-55.6
45
152
3.72
58.98
-55.26
45
153
62.79
49.41
13.38
46
153
54.44
49.41
5.03
47
153
60.12
49.41
10.71
48
153
40.99
49.41
-8.42
48
154
32.385
49.41
-17.025
48
155
53.78
49.41
4.37
49
155
45.88
49.41
-3.53
49
156
42.54
49.41
-6.87
49
157
23.82
49.41
-25.59
49
158
19.82
49.41
-29.59
49
159
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 18

Alexander Co CDLF over MSWLF
17.85
49.41
-31.56
49
160
37.48
49.41
-11.93
49
161
21.58
49.41
-27.83
49
162
4.3
49.41
-45.11
49
163
3.38
49.41
-46.03
49
164
3.38
49.41
-46.03
49
165
3.72
49.41
-45.69
49
166
54.44
62.79
-8.35
49
167
60.12
62.79
-2.67
49
168
40.99
62.79
-21.8
49
169
32.385
62.79
-30.405
49
170
53.78
62.79
-9.01
49
171
45.88
62.79
-16.91
49
172
42.54
62.79
-20.25
49
173
23.82
62.79
-38.97
49
174
19.82
62.79
-42.97
49
175
17.85
62.79
-44.94
49
176
37.48
62.79
-25.31
49
177
21.58
62.79
-41.21
49
178
4.3
62.79
-58.49
49
179
3.38
62.79
-59.41
49
180
3.38
62.79
-59.41
49
181
3.72
62.79
-59.07
49
182
60.12
54.44
5.68
50
182
40.99
54.44
-13.45
50
183
32.385
54.44
-22.055
50
184
53.78
54.44
-0.66
50
185
45.88
54.44
-8.56
50
186
42.54
54.44
-11.9
50
187
23.82
54.44
-30.62
50
188
19.82
54.44
-34.62
50
189
17.85
54.44
-36.59
50
190
37.48
54.44
-16.96
50
191
21.58
54.44
-32.86
50
192
4.3
54.44
-50.14
50
193
3.38
54.44
-51.06
50
194
3.38
54.44
-51.06
50
195
3.72
54.44
-50.72
50
196
40.99
60.12
-19.13
50
197
32.385
60.12
-27.735
50
198
53.78
60.12
-6.34
50
199
45.88
60.12
-14.24
50
200
42.54
60.12
-17.58
50
201
23.82
60.12
-36.3
50
202
19.82
60.12
-40.3
50
203
17.85
60.12
-42.27
50
204
37.48
60.12
-22.64
50
205
21.58
60.12
-38.54
50
206
4.3
60.12
-55.82
50
207
3.38
60.12
-56.74
50
208
3.38
60.12
-56.74
50
209
3.72
60.12
-56.4
50
210
32.385
40.99
-8.605
50
211
53.78
40.99
12.79
51
211
45.88
40.99
4.89
52
211
42.54
40.99
1.55
53
211
23.82
40.99
-17.17
53
212
19.82
40.99
-21.17
53
213
17.85
40.99
-23.14
53
214
37.48
40.99
-3.51
53
215
21.58
40.99
-19.41
53
216
4.3
40.99
-36.69
53
217
3.38
40.99
-37.61
53
218
3.38
40.99
-37.61
53
219
3.72
40.99
-37.27
53
220
53.78
32.385
21.395
54
220
45.88
32.385
13.495
55
220
42.54
32.385
10.155
56
220
23.82
32.385
-8.565
56
221
19.82
32.385
-12.565
56
222
17.85
32.385
-14.535
56
223
37.48
32.385
5.095
57
223
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 19

Alexander Co CDLF over MSWLF
21.58
32.385
-10.805
57
224
4.3
32.385
-28.085
57
225
3.38
32.385
-29.005
57
226
3.38
32.385
-29.005
57
227
3.72
32.385
-28.665
57
228
45.88
53.78
-7.9
57
229
42.54
53.78
-11.24
57
230
23.82
53.78
-29.96
57
231
19.82
53.78
-33.96
57
232
17.85
53.78
-35.93
57
233
37.48
53.78
-16.3
57
234
21.58
53.78
-32.2
57
235
4.3
53.78
-49.48
57
236
3.38
53.78
-50.4
57
237
3.38
53.78
-50.4
57
238
3.72
53.78
-50.06
57
239
42.54
45.88
-3.34
57
240
23.82
45.88
-22.06
57
241
19.82
45.88
-26.06
57
242
17.85
45.88
-28.03
57
243
37.48
45.88
-8.4
57
244
21.58
45.88
-24.3
57
245
4.3
45.88
-41.58
57
246
3.38
45.88
-42.5
57
247
3.38
45.88
-42.5
57
248
3.72
45.88
-42.16
57
249
23.82
42.54
-18.72
57
250
19.82
42.54
-22.72
57
251
17.85
42.54
-24.69
57
252
37.48
42.54
-5.06
57
253
21.58
42.54
-20.96
57
254
4.3
42.54
-38.24
57
255
3.38
42.54
-39.16
57
256
3.38
42.54
-39.16
57
257
3.72
42.54
-38.82
57
258
19.82
23.82
-4
57
259
17.85
23.82
-5.97
57
260
37.48
23.82
13.66
58
260
21.58
23.82
-2.24
58
261
4.3
23.82
-19.52
58
262
3.38
23.82
-20.44
58
263
3.38
23.82
-20.44
58
264
3.72
23.82
-20.1
58
265
17.85
19.82
-1.97
58
266
37.48
19.82
17.66
59
266
21.58
19.82
1.76
60
266
4.3
19.82
-15.52
60
267
3.38
19.82
-16.44
60
268
3.38
19.82
-16.44
60
269
3.72
19.82
-16.1
60
270
37.48
17.85
19.63
61
270
21.58
17.85
3.73
62
270
4.3
17.85
-13.55
62
271
3.38
17.85
-14.47
62
272
3.38
17.85
-14.47
62
273
3.72
17.85
-14.13
62
274
21.58
37.48
-15.9
62
275
4.3
37.48
-33.18
62
276
3.38
37.48
-34.1
62
277
3.38
37.48
-34.1
62
278
3.72
37.48
-33.76
62
279
4.3
21.58
-17.28
62
280
3.38
21.58
-18.2
62
281
3.38
21.58
-18.2
62
282
3.72
21.58
-17.86
62
283
3.38
4.3
-0.92
62
284
3.38
4.3
-0.92
62
285
3.72
4.3
-0.58
62
286
Original Data (Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 20

Alexander Co CDLF over MSWLF
3.38 3.38 0 62 286
3.72 3.38 0.34 63 286
3.72 3.38 0.34 64 286
S Statistic = 64 - 286 = -222
Tied GroulValue Members
1 3.38 2
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
A=18
B=0
C=0
D=0
E=2
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2300
Z-Score =-4.60817
Comparison Level at 95% confidence level =-1.65463 (downward trend)
-4.60817 <-1.65463 indicating a downward trend
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 21

Alexander Co CDLF over MSWLF
Cumulative VOCs
Time•Series Graph of AOC (&H2
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 22

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: AOC (MW-26)
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
129.48
178.04
-48.56
0
1
136.41
178.04
-41.63
0
2
160.84
178.04
-17.2
0
3
137.92
178.04
-40.12
0
4
124.62
178.04
-53.42
0
5
112.2
178.04
-65.84
0
6
128.11
178.04
-49.93
0
7
112.47
178.04
-65.57
0
8
95.58
178.04
-82.46
0
9
128.48
178.04
-49.56
0
10
133.23
178.04
-44.81
0
11
134.77
178.04
-43.27
0
12
69.28
178.04
-108.76
0
13
105.42
178.04
-72.62
0
14
106.75
178.04
-71.29
0
15
72.54
178.04
-105.5
0
16
94.62
178.04
-83.42
0
17
91.51
178.04
-86.53
0
18
60
178.04
-118.04
0
19
69.25
178.04
-108.79
0
20
56.74
178.04
-121.3
0
21
61.48
178.04
-116.56
0
22
25.57
178.04
-152.47
0
23
25.09
178.04
-152.95
0
24
25.09
178.04
-152.95
0
25
14.17
178.04
-163.87
0
26
136.41 129.48
6.93
1 26
160.84 129.48
31.36
2 26
137.92 129.48
8.44
3 26
124.62 129.48
-4.86
3 27
112.2 129.48
-17.28
3 28
128.11 129.48
-1.37
3 29
112.47 129.48
-17.01
3 30
95.58 129.48
-33.9
3 31
128.48 129.48
-1
3 32
133.23 129.48
3.75
4 32
134.77 129.48
5.29
5 32
69.28 129.48
-60.2
5 33
105.42 129.48
-24.06
5 34
106.75 129.48
-22.73
5 35
72.54 129.48
-56.94
5 36
94.62 129.48
-34.86
5 37
91.51 129.48
-37.97
5 38
60 129.48
-69.48
5 39
69.25 129.48
-60.23
5 40
56.74 129.48
-72.74
5 41
61.48 129.48
-68
5 42
25.57 129.48
-103.91
5 43
25.09 129.48
-104.39
5 44
25.09 129.48
-104.39
5 45
14.17 129.48
-115.31
5 46
160.84 136.41
24.43
6 46
137.92 136.41
1.51
7 46
124.62 136.41
-11.79
7 47
112.2 136.41
-24.21
7 48
128.11 136.41
-8.3
7 49
112.47 136.41
-23.94
7 50
95.58 136.41
-40.83
7 51
128.48 136.41
-7.93
7 52
133.23 136.41
-3.18
7 53
134.77 136.41
-1.64
7 54
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 23

Alexander Co CDLF over MSWLF
69.28
136.41
-67.13
7
55
105.42
136.41
-30.99
7
56
106.75
136.41
-29.66
7
57
72.54
136.41
-63.87
7
58
94.62
136.41
-41.79
7
59
91.51
136.41
-44.9
7
60
60
136.41
-76.41
7
61
69.25
136.41
-67.16
7
62
56.74
136.41
-79.67
7
63
61.48
136.41
-74.93
7
64
25.57
136.41
-110.84
7
65
25.09
136.41
-111.32
7
66
25.09
136.41
-111.32
7
67
14.17
136.41
-122.24
7
68
137.92
160.84
-22.92
7
69
124.62
160.84
-36.22
7
70
112.2
160.84
-48.64
7
71
128.11
160.84
-32.73
7
72
112.47
160.84
-48.37
7
73
95.58
160.84
-65.26
7
74
128.48
160.84
-32.36
7
75
133.23
160.84
-27.61
7
76
134.77
160.84
-26.07
7
77
69.28
160.84
-91.56
7
78
105.42
160.84
-55.42
7
79
106.75
160.84
-54.09
7
80
72.54
160.84
-88.3
7
81
94.62
160.84
-66.22
7
82
91.51
160.84
-69.33
7
83
60
160.84
-100.84
7
84
69.25
160.84
-91.59
7
85
56.74
160.84
-104.1
7
86
61.48
160.84
-99.36
7
87
25.57
160.84
-135.27
7
88
25.09
160.84
-135.75
7
89
25.09
160.84
-135.75
7
90
14.17
160.84
-146.67
7
91
124.62
137.92
-13.3
7
92
112.2
137.92
-25.72
7
93
128.11
137.92
-9.81
7
94
112.47
137.92
-25.45
7
95
95.58
137.92
-42.34
7
96
128.48
137.92
-9.44
7
97
133.23
137.92
-4.69
7
98
134.77
137.92
-3.15
7
99
69.28
137.92
-68.64
7
100
105.42
137.92
-32.5
7
101
106.75
137.92
-31.17
7
102
72.54
137.92
-65.38
7
103
94.62
137.92
-43.3
7
104
91.51
137.92
-46.41
7
105
60
137.92
-77.92
7
106
69.25
137.92
-68.67
7
107
56.74
137.92
-81.18
7
108
61.48
137.92
-76.44
7
109
25.57
137.92
-112.35
7
110
25.09
137.92
-112.83
7
111
25.09
137.92
-112.83
7
112
14.17
137.92
-123.75
7
113
112.2
124.62
-12.42
7
114
128.11
124.62
3.49
8
114
112.47
124.62
-12.15
8
115
95.58
124.62
-29.04
8
116
128.48
124.62
3.86
9
116
133.23
124.62
8.61
10
116
134.77
124.62
10.15
11
116
69.28
124.62
-55.34
11
117
105.42
124.62
-19.2
11
118
106.75
124.62
-17.87
11
119
72.54
124.62
-52.08
11
120
94.62
124.62
-30
11
121
91.51
124.62
-33.11
11
122
60
124.62
-64.62
11
123
69.25
124.62
-55.37
11
124
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL Page 24

Alexander Co CDLF over MSWLF
56.74
124.62
-67.88
11
125
61.48
124.62
-63.14
11
126
25.57
124.62
-99.05
11
127
25.09
124.62
-99.53
11
128
25.09
124.62
-99.53
11
129
14.17
124.62
-110.45
11
130
128.11
112.2
15.91
12
130
112.47
112.2
0.27
13
130
95.58
112.2
-16.62
13
131
128.48
112.2
16.28
14
131
133.23
112.2
21.03
15
131
134.77
112.2
22.57
16
131
69.28
112.2
-42.92
16
132
105.42
112.2
-6.78
16
133
106.75
112.2
-5.45
16
134
72.54
112.2
-39.66
16
135
94.62
112.2
-17.58
16
136
91.51
112.2
-20.69
16
137
60
112.2
-52.2
16
138
69.25
112.2
-42.95
16
139
56.74
112.2
-55.46
16
140
61.48
112.2
-50.72
16
141
25.57
112.2
-86.63
16
142
25.09
112.2
-87.11
16
143
25.09
112.2
-87.11
16
144
14.17
112.2
-98.03
16
145
112.47
128.11
-15.64
16
146
95.58
128.11
-32.53
16
147
128.48
128.11
0.37
17
147
133.23
128.11
5.12
18
147
134.77
128.11
6.66
19
147
69.28
128.11
-58.83
19
148
105.42
128.11
-22.69
19
149
106.75
128.11
-21.36
19
150
72.54
128.11
-55.57
19
151
94.62
128.11
-33.49
19
152
91.51
128.11
-36.6
19
153
60
128.11
-68.11
19
154
69.25
128.11
-58.86
19
155
56.74
128.11
-71.37
19
156
61.48
128.11
-66.63
19
157
25.57
128.11
-102.54
19
158
25.09
128.11
-103.02
19
159
25.09
128.11
-103.02
19
160
14.17
128.11
-113.94
19
161
95.58
112.47
-16.89
19
162
128.48
112.47
16.01
20
162
133.23
112.47
20.76
21
162
134.77
112.47
22.3
22
162
69.28
112.47
-43.19
22
163
105.42
112.47
-7.05
22
164
106.75
112.47
-5.72
22
165
72.54
112.47
-39.93
22
166
94.62
112.47
-17.85
22
167
91.51
112.47
-20.96
22
168
60
112.47
-52.47
22
169
69.25
112.47
-43.22
22
170
56.74
112.47
-55.73
22
171
61.48
112.47
-50.99
22
172
25.57
112.47
-86.9
22
173
25.09
112.47
-87.38
22
174
25.09
112.47
-87.38
22
175
14.17
112.47
-98.3
22
176
128.48
95.58
32.9
23
176
133.23
95.58
37.65
24
176
134.77
95.58
39.19
25
176
69.28
95.58
-26.3
25
177
105.42
95.58
9.84
26
177
106.75
95.58
11.17
27
177
72.54
95.58
-23.04
27
178
94.62
95.58
-0.96
27
179
91.51
95.58
-4.07
27
180
60
95.58
-35.58
27
181
Original Data (Not Transformed) Non -Detects Replaced with 1 /2 DL Page 25

Alexander Co CDLF over MSWLF
69.25
95.58
-26.33
27
182
56.74
95.58
-38.84
27
183
61.48
95.58
-34.1
27
184
25.57
95.58
-70.01
27
185
25.09
95.58
-70.49
27
186
25.09
95.58
-70.49
27
187
14.17
95.58
-81.41
27
188
133.23
128.48
4.75
28
188
134.77
128.48
6.29
29
188
69.28
128.48
-59.2
29
189
105.42
128.48
-23.06
29
190
106.75
128.48
-21.73
29
191
72.54
128.48
-55.94
29
192
94.62
128.48
-33.86
29
193
91.51
128.48
-36.97
29
194
60
128.48
-68.48
29
195
69.25
128.48
-59.23
29
196
56.74
128.48
-71.74
29
197
61.48
128.48
-67
29
198
25.57
128.48
-102.91
29
199
25.09
128.48
-103.39
29
200
25.09
128.48
-103.39
29
201
14.17
128.48
-114.31
29
202
134.77
133.23
1.54
30
202
69.28
133.23
-63.95
30
203
105.42
133.23
-27.81
30
204
106.75
133.23
-26.48
30
205
72.54
133.23
-60.69
30
206
94.62
133.23
-38.61
30
207
91.51
133.23
-41.72
30
208
60
133.23
-73.23
30
209
69.25
133.23
-63.98
30
210
56.74
133.23
-76.49
30
211
61.48
133.23
-71.75
30
212
25.57
133.23
-107.66
30
213
25.09
133.23
-108.14
30
214
25.09
133.23
-108.14
30
215
14.17
133.23
-119.06
30
216
69.28
134.77
-65.49
30
217
105.42
134.77
-29.35
30
218
106.75
134.77
-28.02
30
219
72.54
134.77
-62.23
30
220
94.62
134.77
-40.15
30
221
91.51
134.77
-43.26
30
222
60
134.77
-74.77
30
223
69.25
134.77
-65.52
30
224
56.74
134.77
-78.03
30
225
61.48
134.77
-73.29
30
226
25.57
134.77
-109.2
30
227
25.09
134.77
-109.68
30
228
25.09
134.77
-109.68
30
229
14.17
134.77
-120.6
30
230
105.42
69.28
36.14
31
230
106.75
69.28
37.47
32
230
72.54
69.28
3.26
33
230
94.62
69.28
25.34
34
230
91.51
69.28
22.23
35
230
60
69.28
-9.28
35
231
69.25
69.28
-0.03
35
232
56.74
69.28
-12.54
35
233
61.48
69.28
-7.8
35
234
25.57
69.28
-43.71
35
235
25.09
69.28
-44.19
35
236
25.09
69.28
-44.19
35
237
14.17
69.28
-55.11
35
238
106.75
105.42
1.33
36
238
72.54
105.42
-32.88
36
239
94.62
105.42
-10.8
36
240
91.51
105.42
-13.91
36
241
60
105.42
-45.42
36
242
69.25
105.42
-36.17
36
243
56.74
105.42
-48.68
36
244
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 26

Alexander Co CDLF over MSWLF
61.48
105.42
-43.94
36
245
25.57
105.42
-79.85
36
246
25.09
105.42
-80.33
36
247
25.09
105.42
-80.33
36
248
14.17
105.42
-91.25
36
249
72.54
106.75
-34.21
36
250
94.62
106.75
-12.13
36
251
91.51
106.75
-15.24
36
252
60
106.75
-46.75
36
253
69.25
106.75
-37.5
36
254
56.74
106.75
-50.01
36
255
61.48
106.75
-45.27
36
256
25.57
106.75
-81.18
36
257
25.09
106.75
-81.66
36
258
25.09
106.75
-81.66
36
259
14.17
106.75
-92.58
36
260
94.62
72.54
22.08
37
260
91.51
72.54
18.97
38
260
60
72.54
-12.54
38
261
69.25
72.54
-3.29
38
262
56.74
72.54
-15.8
38
263
61.48
72.54
-11.06
38
264
25.57
72.54
-46.97
38
265
25.09
72.54
-47.45
38
266
25.09
72.54
-47.45
38
267
14.17
72.54
-58.37
38
268
91.51
94.62
-3.11
38
269
60
94.62
-34.62
38
270
69.25
94.62
-25.37
38
271
56.74
94.62
-37.88
38
272
61.48
94.62
-33.14
38
273
25.57
94.62
-69.05
38
274
25.09
94.62
-69.53
38
275
25.09
94.62
-69.53
38
276
14.17
94.62
-80.45
38
277
60
91.51
-31.51
38
278
69.25
91.51
-22.26
38
279
56.74
91.51
-34.77
38
280
61.48
91.51
-30.03
38
281
25.57
91.51
-65.94
38
282
25.09
91.51
-66.42
38
283
25.09
91.51
-66.42
38
284
14.17
91.51
-77.34
38
285
69.25
60
9.25
39
285
56.74
60
-3.26
39
286
61.48
60
1.48
40
286
25.57
60
-34.43
40
287
25.09
60
-34.91
40
288
25.09
60
-34.91
40
289
14.17
60
-45.83
40
290
56.74
69.25
-12.51
40
291
61.48
69.25
-7.77
40
292
25.57
69.25
-43.68
40
293
25.09
69.25
-44.16
40
294
25.09
69.25
-44.16
40
295
14.17
69.25
-55.08
40
296
61.48
56.74
4.74
41
296
25.57
56.74
-31.17
41
297
25.09
56.74
-31.65
41
298
25.09
56.74
-31.65
41
299
14.17
56.74
-42.57
41
300
25.57
61.48
-35.91
41
301
25.09
61.48
-36.39
41
302
25.09
61.48
-36.39
41
303
14.17
61.48
-47.31
41
304
25.09
25.57
-0.48
41
305
25.09
25.57
-0.48
41
306
14.17
25.57
-11.4
41
307
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 27

Alexander Co CDLF over MSWLF
25.09 25.09 0 41 307
14.17 25.09 -10.92 41 308
14.17 25.09 -10.92 41 309
S Statistic = 41 - 309 = -268
Tied GroulValue Members
1 25.09 2
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
A=18
B=0
C=0
D=0
E=2
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2300
Z-Score =-5.56733
Comparison Level at 95% confidence level =-1.65463 (downward trend)
-5.56733 <-1.65463 indicating a downward trend
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 28

Alexander Co CDLF over MSWLF
Cumulative VOCs
Time -Series Graph of AOC (UNDGNTD�
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 29

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: AOC (UNDGNTD)
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
66.57
161.23
-94.66
0
1
93
161.23
-68.23
0
2
180.22
161.23
18.99
1
2
99.9
161.23
-61.33
1
3
145.94
161.23
-15.29
1
4
94.55
161.23
-66.68
1
5
109.63
161.23
-51.6
1
6
118.06
161.23
-43.17
1
7
98.06
161.23
-63.17
1
8
89.36
161.23
-71.87
1
9
116.46
161.23
-44.77
1
10
93.51
161.23
-67.72
1
11
44.28
161.23
-116.95
1
12
83.59
161.23
-77.64
1
13
75.37
161.23
-85.86
1
14
69.51
161.23
-91.72
1
15
109.38
161.23
-51.85
1
16
58.09
161.23
-103.14
1
17
89.59
161.23
-71.64
1
18
78.62
161.23
-82.61
1
19
21.54
161.23
-139.69
1
20
61.83
161.23
-99.4
1
21
7.28
161.23
-153.95
1
22
7.88
161.23
-153.35
1
23
7.15
161.23
-154.08
1
24
7.14
161.23
-154.09
1
25
93 66.57
26.43
2 25
180.22 66.57
113.65
3 25
99.9 66.57
33.33
4 25
145.94 66.57
79.37
5 25
94.55 66.57
27.98
6 25
109.63 66.57
43.06
7 25
118.06 66.57
51.49
8 25
98.06 66.57
31.49
9 25
89.36 66.57
22.79
10 25
116.46 66.57
49.89
11 25
93.51 66.57
26.94
12 25
44.28 66.57
-22.29
12 26
83.59 66.57
17.02
13 26
75.37 66.57
8.8
14 26
69.51 66.57
2.94
15 26
109.38 66.57
42.81
16 26
58.09 66.57
-8.48
16 27
89.59 66.57
23.02
17 27
78.62 66.57
12.05
18 27
21.54 66.57
-45.03
18 28
61.83 66.57
-4.74
18 29
7.28 66.57
-59.29
18 30
7.88 66.57
-58.69
18 31
7.15 66.57
-59.42
18 32
7.14 66.57
-59.43
18 33
180.22 93
87.22
19 33
99.9 93
6.9
20 33
145.94 93
52.94
21 33
94.55 93
1.55
22 33
109.63 93
16.63
23 33
118.06 93
25.06
24 33
98.06 93
5.06
25 33
89.36 93
-3.64
25 34
116.46 93
23.46
26 34
93.51 93
0.51
27 34
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL Page 30

Alexander Co CDLF over MSWLF
44.28
93
-48.72
27
35
83.59
93
-9.41
27
36
75.37
93
-17.63
27
37
69.51
93
-23.49
27
38
109.38
93
16.38
28
38
58.09
93
-34.91
28
39
89.59
93
-3.41
28
40
78.62
93
-14.38
28
41
21.54
93
-71.46
28
42
61.83
93
-31.17
28
43
7.28
93
-85.72
28
44
7.88
93
-85.12
28
45
7.15
93
-85.85
28
46
7.14
93
-85.86
28
47
99.9
180.22
-80.32
28
48
145.94
180.22
-34.28
28
49
94.55
180.22
-85.67
28
50
109.63
180.22
-70.59
28
51
118.06
180.22
-62.16
28
52
98.06
180.22
-82.16
28
53
89.36
180.22
-90.86
28
54
116.46
180.22
-63.76
28
55
93.51
180.22
-86.71
28
56
44.28
180.22
-135.94
28
57
83.59
180.22
-96.63
28
58
75.37
180.22
-104.85
28
59
69.51
180.22
-110.71
28
60
109.38
180.22
-70.84
28
61
58.09
180.22
-122.13
28
62
89.59
180.22
-90.63
28
63
78.62
180.22
-101.6
28
64
21.54
180.22
-158.68
28
65
61.83
180.22
-118.39
28
66
7.28
180.22
-172.94
28
67
7.88
180.22
-172.34
28
68
7.15
180.22
-173.07
28
69
7.14
180.22
-173.08
28
70
145.94
99.9
46.04
29
70
94.55
99.9
-5.35
29
71
109.63
99.9
9.73
30
71
118.06
99.9
18.16
31
71
98.06
99.9
-1.84
31
72
89.36
99.9
-10.54
31
73
116.46
99.9
16.56
32
73
93.51
99.9
-6.39
32
74
44.28
99.9
-55.62
32
75
83.59
99.9
-16.31
32
76
75.37
99.9
-24.53
32
77
69.51
99.9
-30.39
32
78
109.38
99.9
9.48
33
78
58.09
99.9
-41.81
33
79
89.59
99.9
-10.31
33
80
78.62
99.9
-21.28
33
81
21.54
99.9
-78.36
33
82
61.83
99.9
-38.07
33
83
7.28
99.9
-92.62
33
84
7.88
99.9
-92.02
33
85
7.15
99.9
-92.75
33
86
7.14
99.9
-92.76
33
87
94.55
145.94
-51.39
33
88
109.63
145.94
-36.31
33
89
118.06
145.94
-27.88
33
90
98.06
145.94
-47.88
33
91
89.36
145.94
-56.58
33
92
116.46
145.94
-29.48
33
93
93.51
145.94
-52.43
33
94
44.28
145.94
-101.66
33
95
83.59
145.94
-62.35
33
96
75.37
145.94
-70.57
33
97
69.51
145.94
-76.43
33
98
109.38
145.94
-36.56
33
99
58.09
145.94
-87.85
33
100
89.59
145.94
-56.35
33
101
78.62
145.94
-67.32
33
102
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL Page 31

Alexander Co CDLF over MSWLF
21.54
145.94
-124.4
33
103
61.83
145.94
-84.11
33
104
7.28
145.94
-138.66
33
105
7.88
145.94
-138.06
33
106
7.15
145.94
-138.79
33
107
7.14
145.94
-138.8
33
108
109.63
94.55
15.08
34
108
118.06
94.55
23.51
35
108
98.06
94.55
3.51
36
108
89.36
94.55
-5.19
36
109
116.46
94.55
21.91
37
109
93.51
94.55
-1.04
37
110
44.28
94.55
-50.27
37
111
83.59
94.55
-10.96
37
112
75.37
94.55
-19.18
37
113
69.51
94.55
-25.04
37
114
109.38
94.55
14.83
38
114
58.09
94.55
-36.46
38
115
89.59
94.55
-4.96
38
116
78.62
94.55
-15.93
38
117
21.54
94.55
-73.01
38
118
61.83
94.55
-32.72
38
119
7.28
94.55
-87.27
38
120
7.88
94.55
-86.67
38
121
7.15
94.55
-87.4
38
122
7.14
94.55
-87.41
38
123
118.06
109.63
8.43
39
123
98.06
109.63
-11.57
39
124
89.36
109.63
-20.27
39
125
116.46
109.63
6.83
40
125
93.51
109.63
-16.12
40
126
44.28
109.63
-65.35
40
127
83.59
109.63
-26.04
40
128
75.37
109.63
-34.26
40
129
69.51
109.63
-40.12
40
130
109.38
109.63
-0.25
40
131
58.09
109.63
-51.54
40
132
89.59
109.63
-20.04
40
133
78.62
109.63
-31.01
40
134
21.54
109.63
-88.09
40
135
61.83
109.63
-47.8
40
136
7.28
109.63
-102.35
40
137
7.88
109.63
-101.75
40
138
7.15
109.63
-102.48
40
139
7.14
109.63
-102.49
40
140
98.06
118.06
-20
40
141
89.36
118.06
-28.7
40
142
116.46
118.06
-1.6
40
143
93.51
118.06
-24.55
40
144
44.28
118.06
-73.78
40
145
83.59
118.06
-34.47
40
146
75.37
118.06
-42.69
40
147
69.51
118.06
-48.55
40
148
109.38
118.06
-8.68
40
149
58.09
118.06
-59.97
40
150
89.59
118.06
-28.47
40
151
78.62
118.06
-39.44
40
152
21.54
118.06
-96.52
40
153
61.83
118.06
-56.23
40
154
7.28
118.06
-110.78
40
155
7.88
118.06
-110.18
40
156
7.15
118.06
-110.91
40
157
7.14
118.06
-110.92
40
158
89.36
98.06
-8.7
40
159
116.46
98.06
18.4
41
159
93.51
98.06
-4.55
41
160
44.28
98.06
-53.78
41
161
83.59
98.06
-14.47
41
162
75.37
98.06
-22.69
41
163
69.51
98.06
-28.55
41
164
109.38
98.06
11.32
42
164
58.09
98.06
-39.97
42
165
89.59
98.06
-8.47
42
166
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 32

Alexander Co CDLF over MSWLF
78.62
98.06
-19.44
42
167
21.54
98.06
-76.52
42
168
61.83
98.06
-36.23
42
169
7.28
98.06
-90.78
42
170
7.88
98.06
-90.18
42
171
7.15
98.06
-90.91
42
172
7.14
98.06
-90.92
42
173
116.46
89.36
27.1
43
173
93.51
89.36
4.15
44
173
44.28
89.36
-45.08
44
174
83.59
89.36
-5.77
44
175
75.37
89.36
-13.99
44
176
69.51
89.36
-19.85
44
177
109.38
89.36
20.02
45
177
58.09
89.36
-31.27
45
178
89.59
89.36
0.23
46
178
78.62
89.36
-10.74
46
179
21.54
89.36
-67.82
46
180
61.83
89.36
-27.53
46
181
7.28
89.36
-82.08
46
182
7.88
89.36
-81.48
46
183
7.15
89.36
-82.21
46
184
7.14
89.36
-82.22
46
185
93.51
116.46
-22.95
46
186
44.28
116.46
-72.18
46
187
83.59
116.46
-32.87
46
188
75.37
116.46
-41.09
46
189
69.51
116.46
-46.95
46
190
109.38
116.46
-7.08
46
191
58.09
116.46
-58.37
46
192
89.59
116.46
-26.87
46
193
78.62
116.46
-37.84
46
194
21.54
116.46
-94.92
46
195
61.83
116.46
-54.63
46
196
7.28
116.46
-109.18
46
197
7.88
116.46
-108.58
46
198
7.15
116.46
-109.31
46
199
7.14
116.46
-109.32
46
200
44.28
93.51
-49.23
46
201
83.59
93.51
-9.92
46
202
75.37
93.51
-18.14
46
203
69.51
93.51
-24
46
204
109.38
93.51
15.87
47
204
58.09
93.51
-35.42
47
205
89.59
93.51
-3.92
47
206
78.62
93.51
-14.89
47
207
21.54
93.51
-71.97
47
208
61.83
93.51
-31.68
47
209
7.28
93.51
-86.23
47
210
7.88
93.51
-85.63
47
211
7.15
93.51
-86.36
47
212
7.14
93.51
-86.37
47
213
83.59
44.28
39.31
48
213
75.37
44.28
31.09
49
213
69.51
44.28
25.23
50
213
109.38
44.28
65.1
51
213
58.09
44.28
13.81
52
213
89.59
44.28
45.31
53
213
78.62
44.28
34.34
54
213
21.54
44.28
-22.74
54
214
61.83
44.28
17.55
55
214
7.28
44.28
-37
55
215
7.88
44.28
-36.4
55
216
7.15
44.28
-37.13
55
217
7.14
44.28
-37.14
55
218
75.37
83.59
-8.22
55
219
69.51
83.59
-14.08
55
220
109.38
83.59
25.79
56
220
58.09
83.59
-25.5
56
221
89.59
83.59
6
57
221
78.62
83.59
-4.97
57
222
21.54
83.59
-62.05
57
223
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 33

Alexander Co CDLF over MSWLF
61.83
83.59
-21.76
57
224
7.28
83.59
-76.31
57
225
7.88
83.59
-75.71
57
226
7.15
83.59
-76.44
57
227
7.14
83.59
-76.45
57
228
69.51
75.37
-5.86
57
229
109.38
75.37
34.01
58
229
58.09
75.37
-17.28
58
230
89.59
75.37
14.22
59
230
78.62
75.37
3.25
60
230
21.54
75.37
-53.83
60
231
61.83
75.37
-13.54
60
232
7.28
75.37
-68.09
60
233
7.88
75.37
-67.49
60
234
7.15
75.37
-68.22
60
235
7.14
75.37
-68.23
60
236
109.38
69.51
39.87
61
236
58.09
69.51
-11.42
61
237
89.59
69.51
20.08
62
237
78.62
69.51
9.11
63
237
21.54
69.51
-47.97
63
238
61.83
69.51
-7.68
63
239
7.28
69.51
-62.23
63
240
7.88
69.51
-61.63
63
241
7.15
69.51
-62.36
63
242
7.14
69.51
-62.37
63
243
58.09
109.38
-51.29
63
244
89.59
109.38
-19.79
63
245
78.62
109.38
-30.76
63
246
21.54
109.38
-87.84
63
247
61.83
109.38
-47.55
63
248
7.28
109.38
-102.1
63
249
7.88
109.38
-101.5
63
250
7.15
109.38
-102.23
63
251
7.14
109.38
-102.24
63
252
89.59
58.09
31.5
64
252
78.62
58.09
20.53
65
252
21.54
58.09
-36.55
65
253
61.83
58.09
3.74
66
253
7.28
58.09
-50.81
66
254
7.88
58.09
-50.21
66
255
7.15
58.09
-50.94
66
256
7.14
58.09
-50.95
66
257
78.62
89.59
-10.97
66
258
21.54
89.59
-68.05
66
259
61.83
89.59
-27.76
66
260
7.28
89.59
-82.31
66
261
7.88
89.59
-81.71
66
262
7.15
89.59
-82.44
66
263
7.14
89.59
-82.45
66
264
21.54
78.62
-57.08
66
265
61.83
78.62
-16.79
66
266
7.28
78.62
-71.34
66
267
7.88
78.62
-70.74
66
268
7.15
78.62
-71.47
66
269
7.14
78.62
-71.48
66
270
61.83
21.54
40.29
67
270
7.28
21.54
-14.26
67
271
7.88
21.54
-13.66
67
272
7.15
21.54
-14.39
67
273
7.14
21.54
-14.4
67
274
7.28
61.83
-54.55
67
275
7.88
61.83
-53.95
67
276
7.15
61.83
-54.68
67
277
7.14
61.83
-54.69
67
278
7.88
7.28
0.6
68
278
7.15
7.28
-0.13
68
279
7.14
7.28
-0.14
68
280
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
Page 34

Alexander Co CDLF over MSWLF
7.15 7.88 -0.73 68 281
7.14 7.88 -0.74 68 282
7.14 7.15 -0.01 68 283
S Statistic = 68 - 283 = -215
Tied GroulValue Members
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
A=0
B=0
C=0
D=0
E=0
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2301
Z-Score =-4.46124
Comparison Level at 95% confidence level =-1.65463 (downward trend)
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 35

Alexander Co CDLF over MSWLF
Cumulative VOCs
Sg�Ne
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 36

Alexander Co CDLF over MSWLF
Mann -Kendall Trend Analysis
Parameter: Cumulative VOCs
Location: ALL WELLS
Original Data (Not Transformed)
Non -Detects Replaced with 1/2 DL
95% Confidence Level
Xj
Xk
Xj - Xk
Positives
Negatives
342.78
562.18
-219.4
0
1
368.21
562.18
-193.97
0
2
536.03
562.18
-26.15
0
3
395.274
562.18
-166.906
0
4
452.515
562.18
-109.665
0
5
361.245
562.18
-200.935
0
6
412.981
562.18
-149.199
0
7
390.266
562.18
-171.914
0
8
333.937
562.18
-228.243
0
9
366.65
562.18
-195.53
0
10
390.529
562.18
-171.651
0
11
379.611
562.18
-182.569
0
12
237.257
562.18
-324.923
0
13
285.937
562.18
-276.243
0
14
327.426
562.18
-234.754
0
15
234.72
562.18
-327.46
0
16
307.16
562.18
-255.02
0
17
250.61
562.18
-311.57
0
18
221.43
562.18
-340.75
0
19
202.64
562.18
-359.54
0
20
177.26
562.18
-384.92
0
21
187.6
562.18
-374.58
0
22
256.73
562.18
-305.45
0
23
227.3
562.18
-334.88
0
24
300.82
562.18
-261.36
0
25
229.55
562.18
-332.63
0
26
368.21
342.78
25.43
1
26
536.03
342.78
193.25
2
26
395.274
342.78
52.494
3
26
452.515
342.78
109.735
4
26
361.245
342.78
18.465
5
26
412.981
342.78
70.201
6
26
390.266
342.78
47.486
7
26
333.937
342.78
-8.843
7
27
366.65
342.78
23.87
8
27
390.529
342.78
47.749
9
27
379.611
342.78
36.831
10
27
237.257
342.78
-105.523
10
28
285.937
342.78
-56.843
10
29
327.426
342.78
-15.354
10
30
234.72
342.78
-108.06
10
31
307.16
342.78
-35.62
10
32
250.61
342.78
-92.17
10
33
221.43
342.78
-121.35
10
34
202.64
342.78
-140.14
10
35
177.26
342.78
-165.52
10
36
187.6
342.78
-155.18
10
37
256.73
342.78
-86.05
10
38
227.3
342.78
-115.48
10
39
300.82
342.78
-41.96
10
40
229.55
342.78
-113.23
10
41
536.03
368.21
167.82
11
41
395.274
368.21
27.064
12
41
452.515
368.21
84.305
13
41
361.245
368.21
-6.965
13
42
412.981
368.21
44.771
14
42
390.266
368.21
22.056
15
42
333.937
368.21
-34.273
15
43
366.65
368.21
-1.56
15
44
390.529
368.21
22.319
16
44
379.611
368.21
11.401
17
44
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL Page 37

Alexander Co CDLF over MSWLF
237.257
368.21
-130.953
17
45
285.937
368.21
-82.273
17
46
327.426
368.21
-40.784
17
47
234.72
368.21
-133.49
17
48
307.16
368.21
-61.05
17
49
250.61
368.21
-117.6
17
50
221.43
368.21
-146.78
17
51
202.64
368.21
-165.57
17
52
177.26
368.21
-190.95
17
53
187.6
368.21
-180.61
17
54
256.73
368.21
-111.48
17
55
227.3
368.21
-140.91
17
56
300.82
368.21
-67.39
17
57
229.55
368.21
-138.66
17
58
395.274
536.03
-140.756
17
59
452.515
536.03
-83.515
17
60
361.245
536.03
-174.785
17
61
412.981
536.03
-123.049
17
62
390.266
536.03
-145.764
17
63
333.937
536.03
-202.093
17
64
366.65
536.03
-169.38
17
65
390.529
536.03
-145.501
17
66
379.611
536.03
-156.419
17
67
237.257
536.03
-298.773
17
68
285.937
536.03
-250.093
17
69
327.426
536.03
-208.604
17
70
234.72
536.03
-301.31
17
71
307.16
536.03
-228.87
17
72
250.61
536.03
-285.42
17
73
221.43
536.03
-314.6
17
74
202.64
536.03
-333.39
17
75
177.26
536.03
-358.77
17
76
187.6
536.03
-348.43
17
77
256.73
536.03
-279.3
17
78
227.3
536.03
-308.73
17
79
300.82
536.03
-235.21
17
80
229.55
536.03
-306.48
17
81
452.515
395.274
57.241
18
81
361.245
395.274
-34.029
18
82
412.981
395.274
17.707
19
82
390.266
395.274
-5.008
19
83
333.937
395.274
-61.337
19
84
366.65
395.274
-28.624
19
85
390.529
395.274
-4.745
19
86
379.611
395.274
-15.663
19
87
237.257
395.274
-158.017
19
88
285.937
395.274
-109.337
19
89
327.426
395.274
-67.848
19
90
234.72
395.274
-160.554
19
91
307.16
395.274
-88.114
19
92
250.61
395.274
-144.664
19
93
221.43
395.274
-173.844
19
94
202.64
395.274
-192.634
19
95
177.26
395.274
-218.014
19
96
187.6
395.274
-207.674
19
97
256.73
395.274
-138.544
19
98
227.3
395.274
-167.974
19
99
300.82
395.274
-94.454
19
100
229.55
395.274
-165.724
19
101
361.245
452.515
-91.27
19
102
412.981
452.515
-39.534
19
103
390.266
452.515
-62.249
19
104
333.937
452.515
-118.578
19
105
366.65
452.515
-85.865
19
106
390.529
452.515
-61.986
19
107
379.611
452.515
-72.904
19
108
237.257
452.515
-215.258
19
109
285.937
452.515
-166.578
19
110
327.426
452.515
-125.089
19
111
234.72
452.515
-217.795
19
112
307.16
452.515
-145.355
19
113
250.61
452.515
-201.905
19
114
221.43
452.515
-231.085
19
115
202.64
452.515
-249.875
19
116
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL Page 38

Alexander Co CDLF over MSWLF
177.26
452.515
-275.255
19
117
187.6
452.515
-264.915
19
118
256.73
452.515
-195.785
19
119
227.3
452.515
-225.215
19
120
300.82
452.515
-151.695
19
121
229.55
452.515
-222.965
19
122
412.981
361.245
51.736
20
122
390.266
361.245
29.021
21
122
333.937
361.245
-27.308
21
123
366.65
361.245
5.405
22
123
390.529
361.245
29.284
23
123
379.611
361.245
18.366
24
123
237.257
361.245
-123.988
24
124
285.937
361.245
-75.308
24
125
327.426
361.245
-33.819
24
126
234.72
361.245
-126.525
24
127
307.16
361.245
-54.085
24
128
250.61
361.245
-110.635
24
129
221.43
361.245
-139.815
24
130
202.64
361.245
-158.605
24
131
177.26
361.245
-183.985
24
132
187.6
361.245
-173.645
24
133
256.73
361.245
-104.515
24
134
227.3
361.245
-133.945
24
135
300.82
361.245
-60.425
24
136
229.55
361.245
-131.695
24
137
390.266
412.981
-22.715
24
138
333.937
412.981
-79.044
24
139
366.65
412.981
-46.331
24
140
390.529
412.981
-22.452
24
141
379.611
412.981
-33.37
24
142
237.257
412.981
-175.724
24
143
285.937
412.981
-127.044
24
144
327.426
412.981
-85.555
24
145
234.72
412.981
-178.261
24
146
307.16
412.981
-105.821
24
147
250.61
412.981
-162.371
24
148
221.43
412.981
-191.551
24
149
202.64
412.981
-210.341
24
150
177.26
412.981
-235.721
24
151
187.6
412.981
-225.381
24
152
256.73
412.981
-156.251
24
153
227.3
412.981
-185.681
24
154
300.82
412.981
-112.161
24
155
229.55
412.981
-183.431
24
156
333.937
390.266
-56.329
24
157
366.65
390.266
-23.616
24
158
390.529
390.266
0.263
25
158
379.611
390.266
-10.655
25
159
237.257
390.266
-153.009
25
160
285.937
390.266
-104.329
25
161
327.426
390.266
-62.84
25
162
234.72
390.266
-155.546
25
163
307.16
390.266
-83.106
25
164
250.61
390.266
-139.656
25
165
221.43
390.266
-168.836
25
166
202.64
390.266
-187.626
25
167
177.26
390.266
-213.006
25
168
187.6
390.266
-202.666
25
169
256.73
390.266
-133.536
25
170
227.3
390.266
-162.966
25
171
300.82
390.266
-89.446
25
172
229.55
390.266
-160.716
25
173
366.65
333.937
32.713
26
173
390.529
333.937
56.592
27
173
379.611
333.937
45.674
28
173
237.257
333.937
-96.68
28
174
285.937
333.937
-48
28
175
327.426
333.937
-6.511
28
176
234.72
333.937
-99.217
28
177
307.16
333.937
-26.777
28
178
250.61
333.937
-83.327
28
179
221.43
333.937
-112.507
28
180
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 39

Alexander Co CDLF over MSWLF
202.64
333.937
-131.297
28
181
177.26
333.937
-156.677
28
182
187.6
333.937
-146.337
28
183
256.73
333.937
-77.207
28
184
227.3
333.937
-106.637
28
185
300.82
333.937
-33.117
28
186
229.55
333.937
-104.387
28
187
390.529
366.65
23.879
29
187
379.611
366.65
12.961
30
187
237.257
366.65
-129.393
30
188
285.937
366.65
-80.713
30
189
327.426
366.65
-39.224
30
190
234.72
366.65
-131.93
30
191
307.16
366.65
-59.49
30
192
250.61
366.65
-116.04
30
193
221.43
366.65
-145.22
30
194
202.64
366.65
-164.01
30
195
177.26
366.65
-189.39
30
196
187.6
366.65
-179.05
30
197
256.73
366.65
-109.92
30
198
227.3
366.65
-139.35
30
199
300.82
366.65
-65.83
30
200
229.55
366.65
-137.1
30
201
379.611
390.529
-10.918
30
202
237.257
390.529
-153.272
30
203
285.937
390.529
-104.592
30
204
327.426
390.529
-63.103
30
205
234.72
390.529
-155.809
30
206
307.16
390.529
-83.369
30
207
250.61
390.529
-139.919
30
208
221.43
390.529
-169.099
30
209
202.64
390.529
-187.889
30
210
177.26
390.529
-213.269
30
211
187.6
390.529
-202.929
30
212
256.73
390.529
-133.799
30
213
227.3
390.529
-163.229
30
214
300.82
390.529
-89.709
30
215
229.55
390.529
-160.979
30
216
237.257
379.611
-142.354
30
217
285.937
379.611
-93.674
30
218
327.426
379.611
-52.185
30
219
234.72
379.611
-144.891
30
220
307.16
379.611
-72.451
30
221
250.61
379.611
-129.001
30
222
221.43
379.611
-158.181
30
223
202.64
379.611
-176.971
30
224
177.26
379.611
-202.351
30
225
187.6
379.611
-192.011
30
226
256.73
379.611
-122.881
30
227
227.3
379.611
-152.311
30
228
300.82
379.611
-78.791
30
229
229.55
379.611
-150.061
30
230
285.937
237.257
48.68
31
230
327.426
237.257
90.169
32
230
234.72
237.257
-2.537
32
231
307.16
237.257
69.903
33
231
250.61
237.257
13.353
34
231
221.43
237.257
-15.827
34
232
202.64
237.257
-34.617
34
233
177.26
237.257
-59.997
34
234
187.6
237.257
-49.657
34
235
256.73
237.257
19.473
35
235
227.3
237.257
-9.957
35
236
300.82
237.257
63.563
36
236
229.55
237.257
-7.707
36
237
327.426
285.937
41.489
37
237
234.72
285.937
-51.217
37
238
307.16
285.937
21.223
38
238
250.61
285.937
-35.327
38
239
221.43
285.937
-64.507
38
240
202.64
285.937
-83.297
38
241
177.26
285.937
-108.677
38
242
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 40

Alexander Co CDLF over MSWLF
187.6
285.937
-98.337
38
243
256.73
285.937
-29.207
38
244
227.3
285.937
-58.637
38
245
300.82
285.937
14.883
39
245
229.55
285.937
-56.387
39
246
234.72
327.426
-92.706
39
247
307.16
327.426
-20.266
39
248
250.61
327.426
-76.816
39
249
221.43
327.426
-105.996
39
250
202.64
327.426
-124.786
39
251
177.26
327.426
-150.166
39
252
187.6
327.426
-139.826
39
253
256.73
327.426
-70.696
39
254
227.3
327.426
-100.126
39
255
300.82
327.426
-26.606
39
256
229.55
327.426
-97.876
39
257
307.16
234.72
72.44
40
257
250.61
234.72
15.89
41
257
221.43
234.72
-13.29
41
258
202.64
234.72
-32.08
41
259
177.26
234.72
-57.46
41
260
187.6
234.72
-47.12
41
261
256.73
234.72
22.01
42
261
227.3
234.72
-7.42
42
262
300.82
234.72
66.1
43
262
229.55
234.72
-5.17
43
263
250.61
307.16
-56.55
43
264
221.43
307.16
-85.73
43
265
202.64
307.16
-104.52
43
266
177.26
307.16
-129.9
43
267
187.6
307.16
-119.56
43
268
256.73
307.16
-50.43
43
269
227.3
307.16
-79.86
43
270
300.82
307.16
-6.34
43
271
229.55
307.16
-77.61
43
272
221.43
250.61
-29.18
43
273
202.64
250.61
-47.97
43
274
177.26
250.61
-73.35
43
275
187.6
250.61
-63.01
43
276
256.73
250.61
6.12
44
276
227.3
250.61
-23.31
44
277
300.82
250.61
50.21
45
277
229.55
250.61
-21.06
45
278
202.64
221.43
-18.79
45
279
177.26
221.43
-44.17
45
280
187.6
221.43
-33.83
45
281
256.73
221.43
35.3
46
281
227.3
221.43
5.87
47
281
300.82
221.43
79.39
48
281
229.55
221.43
8.12
49
281
177.26
202.64
-25.38
49
282
187.6
202.64
-15.04
49
283
256.73
202.64
54.09
50
283
227.3
202.64
24.66
51
283
300.82
202.64
98.18
52
283
229.55
202.64
26.91
53
283
187.6
177.26
10.34
54
283
256.73
177.26
79.47
55
283
227.3
177.26
50.04
56
283
300.82
177.26
123.56
57
283
229.55
177.26
52.29
58
283
256.73
187.6
69.13
59
283
227.3
187.6
39.7
60
283
300.82
187.6
113.22
61
283
229.55
187.6
41.95
62
283
227.3
256.73
-29.43
62
284
300.82
256.73
44.09
63
284
229.55
256.73
-27.18
63
285
Original Data
(Not Transformed)
Non -Detects Replaced with
1/2 DL
Page 41

Alexander Co CDLF over MSWLF
300.82 227.3 73.52 64 285
229.55 227.3 2.25 65 285
229.55 300.82 -71.27 65 286
S Statistic = 65 - 286 = -221
Tied GroulValue Members
Time Period
6/24/2009
12/15/2009
7/7/2010
12/8/2010
6/28/2011
12/13/2011
6/12/2012
12/10/2012
6/25/2013
12/16/2013
6/24/2014
12/2/2014
6/6/2015
1 /5/2016
7/1 /2016
12/29/2016
6/28/2017
12/28/2017
6/11 /2018
12/27/2018
6/18/2019
12/17/2019
7/15/2020
12/29/2020
7/9/2021
12/16/2021
6/30/2022
There are 0 time periods with multiple data
Observations
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A=0
B=0
C=0
D=0
E=0
F=0
a = 41418
b = 157950
c = 1404
Group Variance = 2301
Z-Score =-4.58632
Comparison Level at 95% confidence level =-1.65463 (downward trend)
Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Page 42